CN1098250A - Composition pesticide - Google Patents
Composition pesticide Download PDFInfo
- Publication number
- CN1098250A CN1098250A CN94108116A CN94108116A CN1098250A CN 1098250 A CN1098250 A CN 1098250A CN 94108116 A CN94108116 A CN 94108116A CN 94108116 A CN94108116 A CN 94108116A CN 1098250 A CN1098250 A CN 1098250A
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- composition
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- prochloraz
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
- A01N43/38—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings condensed with carbocyclic rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
- A01N43/42—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings condensed with carbocyclic rings
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Disclose a kind of composition pesticide and preparation method thereof, it is characterized in that in containing the water that sulfonation degree is not higher than 2.5 lignosulphonic acid based surfactants Fen San You oxolinic acid, emulsification and be dissolved in the Prochloraz of hydrophobic organic solvent.
Description
The present invention relates to a kind of new pesticide combination, wherein in containing the water that sulfonation degree on average is not more than 2.5 lignosulphonic acid based surfactants, Fen San You oxolinic acid and emulsification be dissolved in Prochloraz in the hydrophobic organic solvent.This composition pesticide is suitable for use as bactericide and is used for seed treatment.
Known so far 5-ethyl-5,8-dihydro-8-oxo-1,3-Er Evil luxuriant also [4,5-g] quinoline-7-formic acid (oxolinic acid) and N-propyl group-N-[2-(2,4,6-Trichlorophenoxy) ethyl] imidazoles-1-formamide (Prochloraz) has bactericidal activity.
You Yu oxolinic acid and Prochloraz have bactericidal activity, and they once were considered as the active component of bactericide in the seed treatment.But You Yu oxolinic acid is that dystectic solid matter and the solvability in water and hydrophobic organic solvent are not high, and Prochloraz is semi-solid at normal temperatures, so make stable pack preparation and acquire a certain degree of difficulty by mixing these two kinds of compounds.
The present inventor considers that the mix preparation of Cai Yong oxolinic acid and Prochloraz is as the bactericide that has wide bactericidal range in the seed treatment.Through to being applicable to that seed soaks or the further investigation of the pack preparation of spraying, found that a kind of advantageous property pack preparation composition pesticide (back claims composition of the present invention) of (comprising that good storage stability, active compound component do not precipitate) that has, wherein Fen San oxolinic acid, emulsification are dissolved in the Prochloraz of hydrophobic organic solvent, thereby have finished the present invention Zhong containing the water that sulfonation degree on average is not more than 2.5 lignosulphonic acid based surfactants.Composition of the present invention also has the good characteristics of favourable redispersibility, after seed soaking for being easy to discharge residue or for not stopping up the nozzle of sprayer, these characteristics are essential.
Used " sulfonation degree on average is not more than 2.5 lignosulphonic acid based surfactants " refers to a kind of like this surfactant of lignosulphonic acid base among the present invention, the sulfonic acid group number of wherein per 1000 unit formula amount lignins on average is no more than 2.5, is generally 0.2～2.5.Generally speaking, the surfactant of this class lignosulphonic acid base is alkali metal salt (as sylvite and sodium salt), alkali salt (as calcium salt) of lignosulphonic acid etc.The surfactant of these lignosulphonic acid bases is for using separately or two or more are used in combination.Its consumption is to be enough to the Prochloraz that Fen San oxolinic acid therein and emulsification are dissolved in hydrophobic organic solvent.More particularly, consumption is 1～15wt% scope of the present composition, is preferably 2～10wt% scope.
In the present invention, be used to dissolve hydrophobic organic solvent water-soluble of Prochloraz at 10 ü
Shi Tongchang is not more than 300ppm, and dissolving is not less than the 20wt% Prochloraz at normal temperatures.This class representative examples of organic comprises aromatic hydrocarbons, as alkylbenzene (for example dimethylbenzene, phenyl xylyl ethane), and the ester class, as the O-phthalic acid alkyl ester.These hydrophobic organic solvents can use separately or two or more are used in combination.
The amount of acid of quinoline and Prochloraz is respectively about 5～40wt% and 1～15wt% in composition of the present invention.The consumption of above-mentioned hydrophobic organic solvent is the amount that is enough to dissolve Prochloraz, for example is about 1～30wt% of present composition total amount.
Composition of the present invention also can contain the multiple auxiliary agent of preparation, as thickener, wetting agent, antifreezing agent and preservative.The example of thickener comprises xanthans, locust bean gum, guar gum, carrageenan, alginic acid and salt thereof, bassora gum, aluminium-magnesium silicate, bentonite, colloidal silica or the like.Its content is generally about 0.02～5wt% with respect to the total amount of the present composition, preferred 0.05～2wt% scope.
Wetting agent comprises for example polyoxyethylene alkyl phenyl ether (as NONIN HS 240), polyoxyethylene alkyl ether (as polyoxyethylene lauryl ether), polyxyethylated ester (as polyoxyethylene oleoyl ester (Polyoxyethylene oleyl ester)) etc.Its content is about 0.01～0.5wt% with respect to the total amount of the present composition, is preferably 0.05～0.2wt% scope.
Antifreeze comprises ethylene glycol, propane diols, glycerine etc.Its content is generally about 3～15wt% with respect to the total amount of the present composition, preferred about 5～10wt% scope.Preservative comprises formalin, 1,2-benzisothiazole-3-ketone etc., and its content is generally 0.005～2wt% with respect to the total amount of the present composition, preferred 0.01～0.5wt% scope.
In order when carrying out seed treatment, to be easy to confirm the deposition of the present composition on seed, in composition of the present invention, can contain dyestuff or pigment.The example of dyestuff or pigment comprises diazo dyestuff, phthalocyanine dye, anthraquinone dye He Jia Evil dyestuff.
The present composition is for example by following step preparation.
Oxolinic acid is scattered in contains in the water of surfactant that sulfonation degree on average is not higher than 2.5 lignosulphonic acid base, use " ball mill " (bead-mill) to wait and carry out wet-milling then, obtain slurry.Perhaps also available pneumatic grinding machine (dry grind, and is distributed to then to contain in the water of surfactant that sulfonation degree on average is no more than 2.5 lignosulphonic acid base, obtains slurry by oxolinic acid such as Dui such as air mill) Deng.And Prochloraz is dissolved in the hydrophobic organic solvent, makes it and contains the water that sulfonation degree is no more than 2.5 lignosulphonic acid based surfactants and mix and emulsification therein with blender then, mixes with above-mentioned slurry De oxolinic acid then.If desired, also further mix preparation auxiliary agent obtains composition of the present invention with this.
Perhaps also can prepare composition of the present invention in the following manner: system is equipped with the oxolinic acid slurry in a manner described, when mixing, in slurry, add the Prochloraz that is dissolved in the hydrophobic organic solvent, and further mix described auxiliary agent if necessary with blender.
Perhaps can also following manner prepare composition of the present invention: Fen San oxolinic acid Zhong containing the water that sulfonation degree on average is no more than 2.5 lignosulphonic acid based surfactants, and in disperse system, add the Prochloraz be dissolved in the hydrophobic organic solvent, carry out wet-milling with ball mill etc. then, and further mix described auxiliary agent if necessary.
In above-mentioned preparation method, blender preferably adopts those with big shearing force, as disperser and ball mill.
Composition of the present invention is applicable to makes bactericide in the seed treatment, be diluted with water in about 1: 10～10000 the composition as seed is immersed, or directly composition of the present invention be administered on the seed, perhaps sprays 1: 2～100 water diluent on seed.
The present invention is illustrated in greater detail by example of formulations and EXPERIMENTAL EXAMPLE, but they should not be construed as and limit the invention to this.
Example of formulations 1
Sodium lignosulfonate, the Westv 8Co of 80 gram Reax 85A(sulfonation degree average out to 1.0 are made) be dissolved in 800 gram distilled water, to wherein adding 400 Ke oxolinic acids, obtain slurry with the ball mill fine grinding then.With M type Auto-Homomixer(Tokushu Kika Kogyo K.K) stirring 600 gram gained slurries, simultaneously be dissolved in a kind of aromatic hydrocarbons of 50 gram Solvesso 150(Exxon Corp. systems to wherein adding 50 gram Prochlorazs) solution that forms, mix then, pulverize, disperseed-liquid of emulsification.In addition, in 980 gram distilled water, add a kind of xanthans that 20 gram Kelzan S(Sansho K.K. provide), be heated to 60 ü
Make it dissolving, obtain thickening solution.In the liquid of above-mentioned dispersion-emulsification, add 50 gram propane diols and 125 gram thickening solutions, further add distilled water then, make 1000 grams composition of the present invention.Composition microscopic examination of the present invention shown find no aggregated particle.
Example of formulations 2
Repeat example of formulations 1, the different just sodium lignosulfonate of 160 gram Reax 83A(Westv 8Co system sulfonation degree average out to 2.1) be dissolved in 720 gram distilled water rather than 80 gram Reax 85A be dissolved in 800 gram distilled water, obtain composition of the present invention like this.The microscopic examination of said composition shown almost do not find aggregated particle.
Example of formulations 3
Repeat example of formulations 1, different is the sodium lignosulfonate of making sulfonation degree average out to 2.0 with 80 gram Reax 82(Westv 8Co) replace 80 gram Reax 85A, thus make composition of the present invention.The microscopic examination of said composition shown almost do not find aggregated particle.
Example of formulations 4
Repeat example of formulations 1, different is the sodium lignosulfonate of making sulfonation degree average out to 1.9 with 80 gram Reax 81A(Westv 8Co) replace 80 gram Reax 85A, thus make composition of the present invention.The microscopic examination of said composition shown almost do not find aggregated particle.
Example of formulations 5
Repeat example of formulations 1, different is the sodium lignosulfonate of making sulfonation degree average out to 1.2 with 80 gram Polyfon 0(Westv 8Co) replace 80 gram Reax 85A, thus make composition of the present invention.The microscopic examination of said composition shown almost do not find aggregated particle.
Example of formulations 6
Repeat example of formulations 1, different is the sodium lignosulfonate of making sulfonation degree average out to 1.7 with 80 gram Reax 910(Westv 8Co) replace 80 gram Reax 85A, thus make composition of the present invention.The microscopic examination of said composition shown almost do not find aggregated particle.
Example of formulations 7
Repeat example of formulations 1, different is the sodium lignosulfonate of making sulfonation degree average out to 0.5 with 80 gram Polyfon H(Westv 8Co) replace 80 gram Reax 85A, thus make composition of the present invention.The microscopic examination of said composition shown do not find aggregated particle.
Example of formulations 8
Repeat example of formulations 1, different is to replace 50 to restrain propane diols with 50 gram ethylene glycol, the microscopic examination of resulting composition is shown do not find aggregated particle.
Example of formulations 9
Repeat example of formulations 1, the different aluminium-magnesium silicate that just provides with 10 gram Kelzan S and 10 gram Veegum R(Sansho K.K.) replace 20 to restrain Kelzan S.The microscopic examination of the resulting present composition shown do not find aggregated particle.
Example of formulations 10
80 gram Reax 85A are dissolved in 800 gram distilled water,, make by Shinmal EnterprisesCorp. with KDL type Dyno-mill(then to wherein adding 400 Ke oxolinic acids and disperseing) fine grinding, obtain slurry.When stirring the slurry that 200 grams obtain, be dissolved in the solution that forms among the 50 gram Solvesso 150, mix then and pulverize, disperseed-liquid of emulsification to wherein adding 50 gram Prochlorazs with M type Auto-Homomixer.In addition, 20 gram Kelzan S are joined in the 980 gram distilled water, and be heated to 60 ü
Make its dissolving, obtain thickening solution.In the liquid of above-mentioned dispersion-emulsification, add 50 gram propane diols and 400 gram thickening solutions, further add distilled water then and make 1000 grams composition of the present invention.The microscopic examination of composition of the present invention shown do not find aggregated particle.
Example of formulations 11
150 gram Reax 85A are dissolved in 650 gram distilled water,, use KDL type Dyno-mill fine grinding then, obtain slurry to wherein adding 1200 Ke oxolinic acids and disperseing.When stirring the slurry that 650 grams obtain, be dissolved in the solution that forms among the 50 gram Solvesso 150, mix then and pulverize, disperseed-liquid of emulsification to wherein adding 50 gram Prochlorazs with M type Auto-Homomixer.In addition, 20 gram Kelzan S are joined in the 980 gram distilled water, and be heated to 60 ü
Make its dissolving, obtain thickening solution.In the liquid of above-mentioned dispersion-emulsification, add 50 gram propane diols and 50 gram thickening solutions, further add distilled water then and make 1000 grams composition of the present invention.The microscopic examination of composition of the present invention shown do not find aggregated particle.
Example of formulations 12
80 gram Reax 85A are dissolved in 800 gram distilled water,, use KDL type Dyno-mill fine grinding then, obtain slurry to wherein adding 400 Ke oxolinic acids and disperseing.When stirring the slurry that 600 grams obtain, be dissolved in the solution that forms among the 90 gram Solvesso 150, mix then and pulverize, disperseed-liquid of emulsification to wherein adding 10 gram Prochlorazs with M type Auto-Homomixer.In addition, 20 gram Kelzan S are joined in the 980 gram distilled water, and be heated to 60 ü
Make its dissolving, obtain thickening solution.In the liquid of above-mentioned dispersion-emulsification, add 50 gram propane diols and 125 gram thickening solutions, further add distilled water then and make 1000 grams composition of the present invention.The microscopic examination of composition of the present invention shown do not find aggregated particle.
Example of formulations 13
80 gram Reax 85A are dissolved in 800 gram distilled water,, use KDL type Dyno-mill fine grinding then, obtain slurry to wherein adding 400 Ke oxolinic acids and disperseing.When stirring the slurry that 500 grams obtain, be dissolved in the solution that forms among the 150 gram Solvesso 150, mix then and pulverize, disperseed-liquid of emulsification to wherein adding 150 gram Prochlorazs with M type Auto-Homomixer.In addition, 20 gram Kelzan S are joined in the 980 gram distilled water, and be heated to 60 ü
Make its dissolving, obtain thickening solution.In the liquid of above-mentioned dispersion-emulsification, add 50 gram propane diols and 50 gram thickening solutions, further add distilled water then and make 1000 grams composition of the present invention.The microscopic examination of composition of the present invention shown do not find aggregated particle.
Example of formulations 14
With 80 gram Reax 85A and 2 gram Sorpol 8043(Toho Chemical Co., the polyoxyethylene alkyl phenyl ether of Ltd system) be dissolved in 718 gram distilled water, to wherein adding 400 Ke oxolinic acids and disperseing, use KDL type Dyno-mill fine grinding then, obtain slurry.When restraining the slurry that obtains with M type Auto-Homomixer stirring 600, be dissolved in 150 gram Hisol SAS-296(Nippon Petro-Chemicals Co. to wherein adding 50 gram Prochlorazs, Ltd system phenyl xylyl ethane) solution that forms in, mix then and pulverize, disperseed-liquid of emulsification.In addition, 10 gram Kelzan S and 20 gram Veegum R are joined in the 970 gram distilled water, and be heated to 60 ü
Make Kelzan S dissolving, obtain thickening solution.In the liquid of above-mentioned dispersion-emulsification, add 50 gram propane diols and 100 gram thickening solutions, further add distilled water then and make 1000 grams composition of the present invention.The microscopic examination of composition of the present invention shown do not find aggregated particle.
Reference preparation embodiment 1
Repeat example of formulations 1, different just with the sodium lignosulfonate of 80 gram Reax 88B(Westv 8Co system sulfonation degree average out to 3.8) replace 80 to restrain Reax 85A, thereby make comparative composition.When Prochloraz solution in slurry during emulsification, it is very sticking that resulting mixture becomes.Comparative composition contains big aggregated particle.
Reference preparation embodiment 2
Repeat example of formulations 1, different just with the sodium lignosulfonate of 80 gram Reax 100M(Westv 8Co system sulfonation degree average out to 4.7) replace 80 to restrain Reax 85A, thereby make comparative composition.When Prochloraz solution in slurry during emulsification, it is very sticking that resulting mixture becomes.Comparative composition contains big aggregated particle.
As from the foregoing, when adopting the bigger lignosulphonic acid based surfactants of sulfonation degree, can not obtain the emulsion (Sus po-emulsion) of high-quality water suspendible.
Reference preparation embodiment 3
Repeat example of formulations 1, different just with the aryl sulfonic acid sodium of 80 gram Demol SNB(Kao Corp. systems and formalin condensation and surfactant) replace 80 to restrain Reax 85A.When Prochloraz solution in slurry during emulsification, it is very sticking that resulting mixture becomes.Also produce big aggregated particle in addition.Therefore, can not obtain the composition pesticide of homogeneous.
Reference preparation embodiment 4
Repeat example of formulations 1, the different surfactant that just makes with 80 gram Soprophor FL(Rhne-Poulenc, be three (styryl) phenol phosphate addition product of PEO) replace 80 to restrain Reax 85A.As a result, when Prochloraz solution in slurry during emulsification, it is very sticking that resulting mixture becomes.In addition, also produce big aggregated particle.Therefore, can not obtain the composition pesticide of homogeneous.
Reference preparation embodiment 5
Repeat example of formulations 1, different just with 80 gram neopelexes generations 80 restrain Reax 85A.When Prochloraz solution in slurry during emulsification, it is very sticking that the gained mixture becomes.In addition, also produce big aggregated particle.Therefore, can not obtain the homogeneous composition pesticide.
Reference preparation embodiment 6
Repeat example of formulations 1, different just with 80 gram New Pole PE-108(Sanyo Chemical Industries Ltd. manufacture-illegal ionic surfactants, polyox-yethylene-polyoxypropylene block copolymer) replace 80 to restrain Reax 85A.When Prochloraz solution in slurry during emulsification, it is very sticking that the gained mixture becomes.In addition, also produce big aggregated particle.Therefore, can not obtain the homogeneous composition pesticide.
Reference preparation embodiment 7
Repeat example of formulations 1, different just with 80 gram Gohsenol GL-05(Nippon Synthetic Chemical Industry Co., Ltd make polyvinyl alcohol) replacement 80 restrains Reax 85A.When Prochloraz solution in slurry during emulsification, it is very sticking that the gained mixture becomes.In addition, also produce big aggregated particle.Therefore, can not obtain the homogeneous composition pesticide.
Reference preparation embodiment 8
Repeat example of formulations 1, different just with 80 gram Geropon T-36(Rhne-Poulenc system polycarboxylic acids sodium type surfactants) replace 80 to restrain Reax 85A.When Prochloraz solution in slurry during emulsification, it is very sticking that the gained mixture becomes.Also produce big aggregated particle in addition.Therefore, can not obtain the homogeneous composition pesticide.
Therefore, if do not adopt the lignosulphonic acid salt surfactant with other various surfactants, the emulsion of the water suspendible that then can not obtain.
EXPERIMENTAL EXAMPLE 1
Example of formulations 1 or 2 composition prepared are diluted with water to 1: 5, and the 100ml dilution is charged at the 100ml place to be had in the mixed cylinder (messcylinder) of lid, and this mixed cylinder is left standstill.After 24 hours, put upside down this mixed cylinder with the speed of per minute 30 times, record disperses the required number of times of putting upside down fully again, with the redispersibility of the composition of check experiment.As a result, composition prepared needs 2 times in the example of formulations 1, and composition prepared needs 4 times in the example of formulations 2.
Han You oxolinic acid of the present invention and Prochloraz are stable liquid type pesticidal preparations as the composition of active component, and are a kind of outstanding compositions that does not have particle aggregation and crystal settling.
Claims (2)
1, a kind of composition pesticide, it is characterized in that in containing the water that sulfonation degree on average is not higher than 2.5 lignosulphonic acid based surfactants, being dispersed with 5-ethyl-5,8-dihydro-8-oxo-1,3-Er Evil luxuriant also [4,5-g] quinoline-7-formic acid (oxolinic acid) and emulsification be dissolved in N-propyl group-N-[2-(2 in the hydrophobic organic solvent, 4, the 6-Trichlorophenoxy) ethyl] imidazoles-1-formamide (Prochloraz).
2, the method for preparing composition pesticide, it is characterized in that in containing the water that sulfonation degree on average is not higher than 2.5 lignosulphonic acid based surfactants, disperseing 5-ethyl-5,8-dihydro-8-oxo-1,3-Er Evil luxuriant also [4,5-g] quinoline-7-formic acid (oxolinic acid), emulsification is dissolved in the N-propyl group-N-[2-(2 in the hydrophobic organic solvent, 4, the 6-Trichlorophenoxy) ethyl] imidazoles-1-formamide (Prochloraz).
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP164708/93 | 1993-07-02 | ||
| JP16470893A JP3331679B2 (en) | 1993-07-02 | 1993-07-02 | Pesticide composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1098250A true CN1098250A (en) | 1995-02-08 |
Family
ID=15798378
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN94108116A Pending CN1098250A (en) | 1993-07-02 | 1994-07-02 | Composition pesticide |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP3331679B2 (en) |
| KR (1) | KR100289544B1 (en) |
| CN (1) | CN1098250A (en) |
| TW (1) | TW307660B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1092485C (en) * | 1996-09-20 | 2002-10-16 | 英国阿格里沃有限公司 | Farm biocide composition |
| CN100508750C (en) * | 2002-08-07 | 2009-07-08 | 日本曹达株式会社 | Agricultural chemical composition in granular form |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6508220B1 (en) | 1999-08-25 | 2003-01-21 | Kioritz Corporation | Starter |
| EP1283009B1 (en) * | 2000-04-28 | 2008-07-02 | Sumitomo Chemical Company, Limited | Insecticidal and acaricidal composition |
| TWI249377B (en) * | 2000-09-07 | 2006-02-21 | Sumitomo Chemical Co | Anti-bacterial composition and method of adding an anti-bacterial property |
| JP2002327666A (en) | 2001-03-01 | 2002-11-15 | Starting Ind Co Ltd | Starter device |
| JP5235255B2 (en) * | 2001-07-19 | 2013-07-10 | クミアイ化学工業株式会社 | Seed disinfection method |
| JP2003148305A (en) | 2001-11-16 | 2003-05-21 | Starting Ind Co Ltd | Recoil starter |
| JP4014998B2 (en) | 2002-10-21 | 2007-11-28 | スターテング工業株式会社 | Recoil starter |
| WO2010127142A2 (en) * | 2009-04-29 | 2010-11-04 | Lignotech Usa, Inc. | Use of lignosulfonates in suspo-emulsions for producing pesticide compositions |
| KR102274105B1 (en) * | 2020-10-23 | 2021-07-06 | 주식회사동방아그로 | Tree injection composition for controlling fire blight comprising oxolinic acid having soluble concentrate type as effective component and uses thereof |
-
1993
- 1993-07-02 JP JP16470893A patent/JP3331679B2/en not_active Expired - Lifetime
-
1994
- 1994-06-14 TW TW083105350A patent/TW307660B/zh not_active IP Right Cessation
- 1994-07-01 KR KR1019940015810A patent/KR100289544B1/en not_active IP Right Cessation
- 1994-07-02 CN CN94108116A patent/CN1098250A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1092485C (en) * | 1996-09-20 | 2002-10-16 | 英国阿格里沃有限公司 | Farm biocide composition |
| CN100508750C (en) * | 2002-08-07 | 2009-07-08 | 日本曹达株式会社 | Agricultural chemical composition in granular form |
Also Published As
| Publication number | Publication date |
|---|---|
| TW307660B (en) | 1997-06-11 |
| KR950002583A (en) | 1995-02-16 |
| JP3331679B2 (en) | 2002-10-07 |
| KR100289544B1 (en) | 2001-11-30 |
| JPH0717810A (en) | 1995-01-20 |
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