201112949 六、發明說明： 【發明所屬之技術領域】 本發明係關於一種殺蟲水性懸浮濃縮物。 【先前技術】 殺蟲水性懸浮濃縮物係一種已知之殺蟲劑調配物。 在某些情況下，含某一組分之殺蟲水性懸浮濃縮物無法 安定地保持懸浮態而經歷「結塊」。 氯-噻唑-5-基甲基）·3_甲基硝基胍（通用 名：可尼丁（dothianidin))係一種已知之具有殺昆蟲活性之 殺蟲活性化合物（參見（例如）日本專利特許公開申請案（Jp_ A)第 03-157308號）。 【發明内容】 本發明提供一種殺蟲水性懸浮濃縮物，其含有可尼丁 (clothianidin)且具有抗結塊性。 本發明係關於以下各項： [1] 一種包含可尼丁、含聚氧伸烷基芳基苯基醚結構 之界面活性劑、聚丙烯酸鹽、木質素磺酸鹽、及多醣聚合 物質之殺蟲水性懸浮濃縮物； [2 ]如[1 ]項之殺蟲水性懸浮濃縮物，其中該可尼丁含 量係占該殺蟲水性懸浮濃縮物之總量的1至5 〇重量％ ; [3]如[1]項之殺蟲水性懸浮濃縮物，其中基於該殺蟲 水性懸浮濃縮物之總量計，該可尼丁含量係i至50重量 %，該含聚氧伸炫基芳基苯基喊結構之界面活性劑含量係 〇. 1至10重量％ ’該聚丙烯酸鹽含量係〇.〖至丨0重量％、該木 150222.doc 201112949 質素磺酸鹽含量係0.1至10重量％，該多醣聚合物質含量係 0.01至5重量。/◦，且該水含量係3〇至9〇重量0/〇 ; [4] 如Π]至[3]項中任一項之殺蟲水性懸浮濃縮物，其 中該含聚氧伸院基芳基苯基醚結構之界面活性劑包括至少 一種選自由聚氧伸烷基芳基苯基醚及聚氧伸烷基芳基苯基 趟硫酸鹽組成之群之物質； [5] 如[丨]至[4]項中任一項之殺蟲水性懸浮濃縮物，其 中該含聚氧伸烷基芳基苯基醚結構之界面活性劑具有8至 48個氧伸烷基結構單元/界面活性劑分子； [6] 如Π]至[5]項中任一項之殺蟲水性懸浮濃縮物，其 中該聚丙烯酸鹽係分子量為3,〇〇〇至6〇,〇〇〇之聚丙烯酸鈉； [7] 如Π]至[6]項中任一項之殺蟲水性懸浮濃縮物，其 中该木質素磺酸鹽係分子量為1，〇〇〇至80,000之木質素磺酸 鈉； [8] 如Π]至[7]項中任一項之殺蟲水性懸浮濃縮物，其 中該多醣聚合物質包括至少一種選自由黃原膠、阿拉伯 膠、鼠李糖膠、刺槐豆膠、角叉菜膠、威蘭膠（welan gum)、殿粉、及m甲基纖維素鹽組成之群之物質；及 [9] 如[1 ]至[7]項中任一項之殺蟲水性懸浮濃縮物，其 中该多SI聚合物質係黃原膠，其i重量％水溶液在⑽ 下’用配備有3號轉子之布魯克菲爾德黏度計以⑼啊之 旋轉速度所測得之黏度為500至2,000 mPa.s。 本發明殺蟲水性懸浮濃縮物安定地保持其懸浮態且避免 結塊。 150222.doc 201112949 本發明殺蟲水性懸浮濃縮物含有可尼丁、含聚氧伸烷基 芳基苯基醚結構之界面活性劑、聚丙烯酸鹽、木質素磺酸 鹽、及多醣聚合物質。 使用含聚氧伸烷基芳基苯基醚結構之界面活性劑作為本 發明殺蟲水性懸浮濃縮物中所含之至少一種界面活性劑。 該含聚氧伸烷基芳基苯基醚結構之界面活性劑之實例包括 具有聚氧伸烷基芳基苯基醚分子結構之界面活性劑及具有 聚氧伸烷基芳基苯基醚結構作為一部分結構且具有另一取 代基之界面活性劑。該聚氧伸烷基芳基苯基醚結構之氧伸 烷基之實例包括氧伸乙基及氧伸丙基。用於本發明之一實 施例之含聚氧伸烷基芳基苯基醚結構之界面活性劑一般具 有3至120個氧伸烷基結構單元/界面活性劑分子，較佳係8 至48個氧伸烷基結構單元/界面活性劑分子。 聚氧伸烷基芳基苯基醚之特定實例包括NEWKALGEN FS-1(聚氧伸烷基芳基苯基醚，由TAKEMOTO OIL & FAT Co.，Ltd·製造）、SORPOL T-10(聚氧伸乙基三苯乙烯基苯 基醚，由 TOHO Chemical Industry Co.，LTD.製造）、 SORPOL T-15(聚氧伸乙基三苯乙烯基苯基醚，由TOHO Chemical Industry Co.，LTD.製造）、SORPOL T-20(聚氧伸 乙基三苯乙稀基苯基醚，由TOHO Chemical Industry Co.， LTD.製造）、SORPOL T-26(聚氧伸乙基三苯乙烯基苯基 it，由 TOHO Chemical Industry Co., LTD.製造）、SORPOL T-32(聚氧伸乙基三苯乙烯基苯基醚，由TOHO Chemical Industry Co·, LTD.製造）、SORPOL T-18D(聚氧伸乙基二苯 150222.doc 201112949 乙烯基苯基醚，由 TOHO Chemical Industry Co.，LTD.製 造）、NOIGEN EA-137(聚氧伸乙基二苯乙烯基醚，*DAI-ICHI KOGYO SEIYAKU CO.，LTD.製造）、NOIGEN EA-157(聚氧伸乙基二苯乙烯基醚’由DAI-ICHI KOGYO SEIYAKU CO.，LTD.製造）、NOIGEN EA-167(聚氧伸乙基 二苯乙烯基醚，由 DAI-ICHI KOGYO SEIYAKU CO.，LTD. 製造）、NOIGEN EA-177(聚氧伸乙基二苯乙烯基醚，由 DAI-ICHI KOGYO SEIYAKU CO·, LTD.製造）、NOIGEN EA_197(聚氧伸乙基二苯乙烯基醚，由DAI-ICHI KOGYO SEIYAKU CO” LTD.製造）、EMULGEN A-60(聚氧伸乙基 二苯乙稀基苯基鱗）、EMULGEN A-90(聚氧伸乙基二笨乙 烯基苯基醚）、及EMULGEN A-500(聚氧伸乙基二苯乙稀基 苯基醚）。 該具有聚氧伸炫> 基^•基苯基趟結構作為一部分結構且具 有另一取代基之界面活性劑之實例包括聚氧伸烷基芳基苯 基醚填酸鹽及聚氧伸烧基芳基苯基峻硫酸鹽。聚氧伸烧基 芳基苯基醚填酸鹽或聚氧伸烧基芳基苯基醚硫酸鹽之實例 包括NEWKALGEN FS-7PG(聚氧伸烷基芳基苯基醚硫酸銨 鹽，由 TAKEMOTO OIL & FAT c〇.，Ltd.製造）、201112949 6. INSTRUCTIONS OF THE INVENTION: TECHNICAL FIELD OF THE INVENTION The present invention relates to an insecticidal aqueous suspension concentrate. [Prior Art] A pesticidal aqueous suspension concentrate is a known insecticide formulation. In some cases, a pesticidal aqueous suspension concentrate containing a component does not remain stable in a suspended state and undergoes "caking". Chloro-thiazol-5-ylmethyl)·3-methylnitroguanidine (common name: dothianidin) is a known insecticidal active compound having insecticidal activity (see, for example, Japanese Patent License) Published Application (Jp_A) No. 03-157308). SUMMARY OF THE INVENTION The present invention provides an insecticidal aqueous suspension concentrate comprising a clothianidin and having anti-caking properties. The present invention relates to the following items: [1] A surfactant comprising a structure of a cotinidine, a polyoxyalkylene phenyl ether, a polyacrylate, a lignosulfonate, and a polysaccharide polymer. [2] an insecticidal aqueous suspension concentrate according to [1], wherein the cotinide content is from 1 to 5% by weight of the total amount of the insecticidal aqueous suspension concentrate; [3] The insecticidal aqueous suspension concentrate according to [1], wherein the cotinide content is from i to 50% by weight based on the total amount of the insecticidal aqueous suspension concentrate, and the polyoxygenated arylbenzene The surfactant content of the base structure is 〇. 1 to 10% by weight 'The polyacrylate content is 〇. 丨 to 0% by weight, the wood 150222.doc 201112949 The sulfonate content is 0.1 to 10% by weight, The polysaccharide has a polymer content of 0.01 to 5 parts by weight. / ◦, and the water content is 3 〇 to 9 〇 重量 0 / 〇; [4] The insecticidal aqueous suspension concentrate of any one of [3] to [3], wherein the polyoxygen extension base The surfactant of the phenyl ether structure includes at least one selected from the group consisting of polyoxyalkylene phenyl ethers and polyoxyalkylene phenyl sulfonates; [5] such as [丨] The insecticidal aqueous suspension concentrate according to any one of [4], wherein the surfactant containing a polyoxyalkylene phenyl ether structure has 8 to 48 oxygen alkyl structural units/surfactants [6] The insecticidal aqueous suspension concentrate according to any one of [5], wherein the polyacrylate has a molecular weight of 3, 〇〇〇 to 6 〇, and sodium polyacrylate; [7] The insecticidal aqueous suspension concentrate according to any one of [6], wherein the lignosulfonate is a sodium lignosulfonate having a molecular weight of 1, 〇〇〇 to 80,000; [8] The insecticidal aqueous suspension concentrate according to any one of [7], wherein the polysaccharide polymeric substance comprises at least one selected from the group consisting of xanthan gum, gum arabic, rhamnose gum, locust bean gum, and horn fork a substance consisting of a gel, a welan gum, a temple powder, and a m-methylcellulose salt; and [9] an insecticidal aqueous suspension concentrate according to any one of [1] to [7] , wherein the multi-SI polymer system xanthan gum, the i weight% aqueous solution is (10), the viscosity measured by the Brookfield viscometer equipped with the No. 3 rotor at a rotation speed of (9) is 500 to 2,000 mPa.s. . The insecticidal aqueous suspension concentrate of the present invention is stable in its suspended state and avoids agglomeration. 150222.doc 201112949 The insecticidal aqueous suspension concentrate of the present invention comprises a cotinide, a polyoxyalkylene aryl phenyl ether-containing surfactant, a polyacrylate, a lignosulfonate, and a polysaccharide polymer. A surfactant containing a polyoxyalkylene phenyl ether structure is used as at least one surfactant contained in the insecticidal aqueous suspension concentrate of the present invention. Examples of the surfactant containing a polyoxyalkylene phenyl ether structure include a surfactant having a molecular structure of a polyoxyalkylene phenyl ether and a polyoxyalkylene phenyl ether structure. A surfactant which is a part of the structure and has another substituent. Examples of the oxygen-extended alkyl group of the polyoxyalkylene phenyl ether structure include an oxygen-extended ethyl group and an oxygen-extended propyl group. The surfactant containing the polyoxyalkylene phenyl ether structure used in one embodiment of the present invention generally has 3 to 120 oxygen-extended alkyl structural unit/surfactant molecules, preferably 8 to 48 Oxyalkylene alkyl structural unit/surfactant molecule. Specific examples of the polyoxyalkylene phenyl ether include NEWKALGEN FS-1 (polyoxyalkylene phenyl ether, manufactured by TAKEMOTO OIL & FAT Co., Ltd.), SORPOL T-10 (poly Oxygen-extended ethyltristyrylphenyl ether, manufactured by TOHO Chemical Industry Co., LTD.), SORPOL T-15 (polyoxy-extended ethyltristyrylphenyl ether, by TOHO Chemical Industry Co., LTD) .Manufacture), SORPOL T-20 (polyoxyethylene ethyltriphenyl phenyl ether, manufactured by TOHO Chemical Industry Co., LTD.), SORPOL T-26 (polyoxyethylene striphenylstyrene) Base it, manufactured by TOHO Chemical Industry Co., LTD.), SORPOL T-32 (polyoxy-extension ethyltristyrylphenyl ether, manufactured by TOHO Chemical Industry Co., LTD.), SORPOL T-18D ( Polyoxyethylene ethylbenzene 150222.doc 201112949 vinyl phenyl ether, manufactured by TOHO Chemical Industry Co., LTD.), NOIGEN EA-137 (polyoxyethylene distyryl ether, *DAI-ICHI KOGYO) Manufactured by SEIYAKU CO., LTD., NOIGEN EA-157 (polyoxyethylene distyryl ether) manufactured by DAI-ICHI KOGYO SEIYAKU CO., LTD., NOIGEN EA-167 ( Oxygen extended ethyl distyryl ether, manufactured by DAI-ICHI KOGYO SEIYAKU CO., LTD.), NOIGEN EA-177 (polyoxyethylene distyryl ether, by DAI-ICHI KOGYO SEIYAKU CO·, LTD . Manufactured), NOIGEN EA_197 (polyoxyethylene distyryl ether, manufactured by DAI-ICHI KOGYO SEIYAKU CO" LTD.), EMULGEN A-60 (polyoxyethylene ethylbenzene) , EMULGEN A-90 (polyoxyethylene ethyl phenyl ether), and EMULGEN A-500 (polyoxyethylidene phenyl ether). Examples of the surfactant which is a part of the structure and has another substituent include a polyoxyalkylene phenyl ether ether salt and a polyoxyalkylene aryl phenyl sulfate. Examples of polyoxyalkylene aryl phenyl ether sulphate or polyoxyalkyl phenyl ether ether sulfate include NEWKALGEN FS-7PG (polyoxyalkylene aryl phenyl ether sulfate ammonium salt, by TAKEMOTO) OIL & FAT c〇., Ltd.),
NEWKALGEN FS-3PG(聚氧伸烷基芳基笨基醚磷酸銨鹽， 由 TAKEMOTO 〇IL & FAT Co.，Ltd·製造）、s〇pr〇ph〇r FLK (聚氧伸乙基二笨乙烯基笨基醚磷酸鉀鹽，由Rh〇dia Nicca 製造）、Sorpol T-10SPG(聚氧伸乙基三笨乙烯基苯基醚硫 酸銨鹽’由 TOHO Chemical Industry Co. LTD 製造）、 I50222.doc 201112949NEWKALGEN FS-3PG (polyoxyalkylene aryl strepyl ether ammonium phosphate, manufactured by TAKEMOTO 〇IL & FAT Co., Ltd.), s〇pr〇ph〇r FLK (polyoxyethyl ether) Vinyl stupyl ether potassium phosphate salt, manufactured by Rh〇dia Nicca), Sorpol T-10SPG (polyoxyethylene ethyl succinyl vinyl phenyl ether sulfate ammonium salt manufactured by TOHO Chemical Industry Co. LTD), I50222. Doc 201112949
Sorpol T-15SPG(聚氧伸乙基三苯乙烯基苯基醚硫酸銨鹽， 由 TOHO Chemical Industry Co·, LTD·製造）、Sorpol T-20SPG(聚氧伸乙基三苯乙烯基苯基醚硫酸銨鹽，由TOHO Chemical Industry Co.，LTD.製造）、DIKSSOL 60A(聚氧伸 乙基二苯乙烯基醚硫酸銨鹽，由DAI-ICHI KOGYO SEIYAKU CO·，LTD.製造）、及F-6205H(聚氧伸乙基二苯乙 烯基醚硫酸銨鹽，由 DAI-ICHI KOGYO SEIYAKU CO.， LTD.製造）。 本發明殺蟲水性懸浮濃縮物含有至少一種具有聚氧伸烷 基芳基苯基醚結構之界面活性劑，即，含聚氧伸烷基芳基 苯基醚結構之界面活性劑。在本發明之一實施例中，該含 聚氧伸烷基芳基笨基醚結構之界面活性劑之含量一般係占 該殺蟲水性懸浮濃縮物總量的0.05至1 5重量％，較佳係0.1 至10重量％。 本發明殺蟲水性懸浮濃縮物含有聚丙烯酸鹽。該聚丙烯 酸鹽之實例包括聚丙烯酸鈉、聚丙烯酸鉀、及聚丙烯酸 銨。在本發明之一項實施例中，所使用聚丙烯酸鹽之分子 量一般為1,000至150,000，較隹係3,000至60,000。該丙烯 酸鹽之特定實例包括TOXANON GR-31A(聚丙烯酸鈉，分 子量為約 10,000，由 Sanyo Chemical Industries，Ltd.製 造）、TOXANON GR-30(聚丙烯酸鈉，分子量為約10,000， 由 Sanyo Chemical Industries, Ltd.製造）、SANSPEARL PS-30(聚丙烯酸銨，分子量為約20,000，由Sanyo Chemical Industries，Ltd.製造）、及 SN-DISPERSANT 5468(聚丙稀酸 150222.doc 201112949 锻，分子量為約 10,000 ’ 由 Sanyo Chemical Industries, Ltd. 製造）。 在本發明之一實施例中，該聚丙烯酸鹽含量一般係占該 殺蟲水性懸浮濃縮物總量的0·01至15重量％ ’較佳係〇. 1至 1 〇重量％。 本發明殺蟲水性懸浮濃縮物含有木質素磺酸鹽。該木質 素磺酸鹽之實例包括木質素磺酸鈉、木質素磺酸鉀、及木 質素磺酸鈣。在本發明之一項實施例中，所使用木質素磺 酸鹽之分子量一般為500至150,000 ’較佳係1，000至 80,000 »該木質素磺酸鹽之特定實例包括NEWKALGEN WG-4(木質素績酸鈉，由 TAKEMOTO OIL & FAT Co.，Ltd. 製造）、NEWKALGEN RX-B(木質素磺酸鈉，由TAKEMOTO OIL & FAT Co.，Ltd.製造）、REAX 910(木質素磺酸鈉，由 MeadWestvaco Corporation製造）、SANXP201(木質素石夤酸 鈣，由 NIPPON PAPER CHEMICALS CO.，LTD·製造）、 SANX P252(木質素磺酸鈉，由 NIPPON PAPER CHEMICALS CO.，LTD.製造）、SANX P321(木質素磺酸鎂，由NIPPON PAPER CHEMICALS CO.，LTD.製造）、VANILLEX N(木質 素磺酸鈉，由 NIPPON PAPER CHEMICALS CO.，LTD.製 造）、VANILLEX RN(木質素磺酸鈉，分子量，由NIPPON PAPER CHEMICALS CO.，LTD.製造）、及PERLLEX NP(木 質素磺酸鈉，分子量，由NIPPON PAPER CHEMICALS CO.，LTD.製造）。 在本發明之一實施例中，該木質素磺酸鹽含量一般係占 150222.doc 201112949 該殺蟲水性懸浮濃縮物之總量的0.02至15重量％，較佳係 0·1至10重量。/〇。 本發明殺蟲水性懸浮濃縮物含有多醣聚合物質。該多醣 聚合物質之實例包括黃原膠、阿拉伯膠、鼠李糖膠、刺槐 豆膠、角叉菜膠、威蘭膠、澱粉、及羧曱基纖維素鹽。在 本發明之一實施例中，較佳使用黃原膠作為該多醣聚合物 質。用於本發明之一實施例之黃原膠較佳係使得1重量％ 之κ原膠水 >谷液之黏度通常為3 00至3，000 mPa. s，較佳係 500至2,000 mpa.s(在2〇。(：下，用具有3號轉子之布魯克菲 爾德黏度計以60 rpm之旋轉速度測得）。黃原膠之特定實 例包括Rhodopol 23(由Rhodia Nicca製造，在2〇t下，用配 備有3號轉子之布魯克菲爾德黏度計以6〇 rpm之旋轉速度Sorpol T-15SPG (polyoxyethylene striphenylstyrene ether sulfate, manufactured by TOHO Chemical Industry Co., LTD.), Sorpol T-20SPG (polyoxyethylene striphenylstyrene ether) Ammonium sulfate salt, manufactured by TOHO Chemical Industry Co., LTD., DIKSSOL 60A (polyoxyethylene distyryl ether sulfate, manufactured by DAI-ICHI KOGYO SEIYAKU CO., LTD.), and F- 6205H (polyoxyethylene ethyl distyryl ether sulfate, manufactured by DAI-ICHI KOGYO SEIYAKU CO., LTD.). The insecticidal aqueous suspension concentrate of the present invention contains at least one surfactant having a polyoxyalkylene arylphenyl ether structure, i.e., a surfactant containing a polyoxyalkylene phenyl ether structure. In one embodiment of the present invention, the content of the surfactant containing the polyoxyalkylene aryl stearyl ether structure is generally from 0.05 to 15% by weight based on the total amount of the insecticidal aqueous suspension concentrate, preferably. It is from 0.1 to 10% by weight. The insecticidal aqueous suspension concentrate of the present invention contains a polyacrylate. Examples of the polyacrylate include sodium polyacrylate, potassium polyacrylate, and ammonium polyacrylate. In one embodiment of the invention, the molecular weight of the polyacrylate used is generally from 1,000 to 150,000, more than 3,000 to 60,000. Specific examples of the acrylate include TOXANON GR-31A (sodium polyacrylate, molecular weight of about 10,000, manufactured by Sanyo Chemical Industries, Ltd.), TOXANON GR-30 (sodium polyacrylate, molecular weight of about 10,000, by Sanyo Chemical Industries, Ltd.), SANSPEARL PS-30 (ammonium polyacrylate, molecular weight of about 20,000, manufactured by Sanyo Chemical Industries, Ltd.), and SN-DISPERSANT 5468 (polyacrylic acid 150222.doc 201112949 forging, molecular weight of about 10,000 ' Sanyo Chemical Industries, Ltd.). In one embodiment of the invention, the polyacrylate salt content is generally from 0.01 to 15% by weight of the total amount of the insecticidal aqueous suspension concentrate, preferably from 1 to 1% by weight. The insecticidal aqueous suspension concentrate of the present invention contains a lignosulfonate. Examples of the lignosulfonate include sodium lignosulfonate, potassium lignosulfonate, and calcium ligninsulfonate. In one embodiment of the invention, the molecular weight of the lignosulfonate used is generally from 500 to 150,000 'preferably from 1,000 to 80,000» Specific examples of the lignosulfonate include NEWKALGEN WG-4 (wood Sodium sulphate, manufactured by TAKEMOTO OIL & FAT Co., Ltd., NEWKALGEN RX-B (sodium lignosulfonate, manufactured by TAKEMOTO OIL & FAT Co., Ltd.), REAX 910 (lignin sulfonate) Sodium sulphate, manufactured by MeadWestvaco Corporation, SANXP201 (calcium lignin citrate, manufactured by NIPPON PAPER CHEMICALS CO., LTD.), SANX P252 (sodium lignosulfonate, manufactured by NIPPON PAPER CHEMICALS CO., LTD.) , SANX P321 (magnesium lignosulfonate, manufactured by NIPPON PAPER CHEMICALS CO., LTD.), VANILLEX N (sodium lignosulfonate, manufactured by NIPPON PAPER CHEMICALS CO., LTD.), VANILLEX RN (ligninsulfonic acid) Sodium, molecular weight, manufactured by NIPPON PAPER CHEMICALS CO., LTD., and PERLLEX NP (sodium lignosulfonate, molecular weight, manufactured by NIPPON PAPER CHEMICALS CO., LTD.). In one embodiment of the invention, the lignosulfonate content is generally from 0.02 to 15% by weight, preferably from 0.11 to 10% by weight of the total of the insecticidal aqueous suspension concentrate of 150222.doc 201112949. /〇. The insecticidal aqueous suspension concentrate of the present invention contains a polysaccharide polymer. Examples of the polysaccharide polymeric substance include xanthan gum, gum arabic, rhamnose gum, locust bean gum, carrageenan, welan gum, starch, and carboxymethyl cellulose salts. In an embodiment of the invention, xanthan gum is preferably used as the polysaccharide polymer. The xanthan gum used in one embodiment of the present invention is preferably such that the viscosity of 1% by weight of κ raw gum water > valley liquid is usually from 300 to 3,000 mPa·s, preferably from 500 to 2,000 mpa.s. (At 2〇. (:, measured with a Brookfield viscometer with a No. 3 rotor at 60 rpm). Specific examples of xanthan gum include Rhodopol 23 (manufactured by Rhodia Nicca, at 2〇t, Rotary speed of 6 rpm with a Brookfield viscometer equipped with a No. 3 rotor
測得黏度為 1，200 至 i，8〇〇 mpa.s)及 KELZAN S(由 SANSHOMeasured viscosity is 1,200 to i, 8〇〇 mpa.s) and KELZAN S (by SANSHO
Co·，Ltd.製造，在20t：下，用配備有3號轉子之布魯克菲爾 德黏度計以60 rpm之旋轉速度測得黏度為9〇〇至丨，2〇〇 mPa.s)。 本發明殺蟲水性懸浮濃縮物可另外含有另一增稠劑。另 一增稠劑之實例包括聚乙二醇及蒙脫石鈉。當本發明殺蟲 水性懸浮濃縮物含有另一增稠劑時，該增稠劑的含量一般 係占該殺蟲水性懸浮濃縮物之總量的〇 〇丨至5重量％。 若需要，本發明殺蟲水性懸浮濃縮物可含有其他調配物 助劑。此調配物助劑之實例包括抗;東劑、阳調 劑、及防腐劑。 '' 抗束劑之實例包括乙二醇、二乙二醇 ^ 砰汉内—醇。pH調節 150222.doc 201112949 劑之實例包括硫酸及磷酸。 在本發明之一實施例中’該殺蟲水性懸浮濃縮物係一種 含有可尼丁、含聚氧伸烷基芳基苯基醚結構之界面活性 劑、聚丙烯酸鹽、木質素磺酸鹽、及多醣聚合物質'及視 情況選用之另一增稠劑及可選用之調配物助劑之組合物， 其係分散於或溶於水性介質中。在本發明之一實施例中， 可使用自來水、井水、離子交換水、或任何用於一般殺蟲 水性懸洋濃縮物之其他類型的水製備該殺蟲水性懸浮濃縮 物。玄水S里般係占5玄殺蟲水性懸浮濃縮物之總量的3 〇 至90重量％，較佳係5〇至8〇重量〇/0。 以下係本發明殺蟲水性懸浮濃縮物之實例。 一種包含可尼丁、含聚氧伸烷基芳基苯基醚結構之界面 活性劑、聚丙烯酸鹽、木質素磺酸鹽、及多醣聚合物質之 殺蟲水性懸浮濃縮物，且基於該殺蟲水性懸浮濃縮物之總 量=，該可尼丁含量係丨至5〇重量％，該含聚氧伸烷基芳 基苯基醚結構之界面活性劑含量係〇1至1〇重量％，該聚丙 婦酸鹽含量係(M至1G重量％ ’該木f素績酸鹽含量係〇1 至10重量％，該多醣聚合物質含量係001至5重量％，且該 水含量係30至90重量〇/〇。 一種包含可尼丁、含聚氧伸炫基芳基苯基鱗結構之界面 活性劑、聚丙烯酸鹽、木質素續酸鹽、丙二醇及多醣聚合 物質之殺蟲水性懸浮濃縮物’且基於該殺蟲水性懸浮濃縮 物之總量計’該可尼丁含量们至％重量％，該含聚氧伸 坑基方基苯基㈣構之界面活性劑含量係Ha重量。^ I50222.doc 201112949 該聚丙烯酸鹽含量係⑴丨至⑺重量％，該木質素磺酸鹽含量 係0.1至10重量％，該多醣聚合物質含量係〇〇1至5重量％， 該丙二醇含量係3至1〇重量％且該水含量係3〇至9〇重量％。 -種包含可尼丁、含聚氧伸烷基芳基苯基醚結構之界面 活性劑、聚丙烯酸鹽、木質素磺酸鹽、蒙脫石鈉及多醣聚 合物質之殺蟲水性懸浮濃縮物，且基於該殺蟲水性懸浮濃 縮物之總量計，該可尼丁含量係i至5〇重量％，該含聚氧 伸烷基芳基苯基醚結構之界面活性劑含量係〇1至1〇重量 %，該聚丙烯酸鹽含量係(^丨至⑺重量％，該木質素磺酸鹽 含量係0.1至10重量％，該多醣聚合物質含量係〇 〇1至5重 量％，該蒙脫石鈉含量係0.01至5重量％且該水含量係3〇至 90重量％。 一種包含可尼丁、含聚氧伸烷基芳基苯基醚結構之界面 活性劑、聚丙烯酸鹽 '木質素磺酸鹽、丙二醇、蒙脫石鈉 及多醣聚合物質之殺蟲水性懸浮濃縮物，且基於該殺蟲水 性懸浮濃縮物之總量計，該可尼丁含量係1至5 〇重量％， 该含聚氧伸烧基芳基笨基醚結構之界面活性劑含量係 至1 0重量％，該聚丙烯酸鹽含量係〇丨至丨〇重量％，該木質 素磺酸鹽含量係0· 1至1 〇重量％，該多醣聚合物質含量係 0.01至5重量％ ’該丙二醇含量係3至1〇重量。/。，該蒙脫石 鈉含量係0.01至5重量％且該水含量係3 〇至9 〇重量％。 一種包含可尼丁、含聚氧伸烷基芳基苯基醚結構之界面 活性劑、聚丙烯酸鹽、木質素磺酸鹽、丙二醇及黃原膠之 殺蟲水性懸浮濃縮物’且基於該殺蟲水性懸浮濃縮物之總 150222.doc -11 - 201112949 量計’該可尼丁含量係1至5 〇會吾。/ #八；^二 王川重量/〇,該含聚氧伸烷基芳 基苯基醚結構之界面活性劑含量係〇1至1〇重量。4，該聚丙 稀酸鹽含量係(ΜΜΟ重量％，素㈣鹽含&系〇1 至10重量％’該黃原膠含量係0.01至5重量％，該丙二醇含 量係3至1 〇重量％且該水含量係3 〇至9〇重量％。 一種包含可尼丁、含聚氧伸烷基芳基苯基醚結構之界面 活性劑、聚丙烯酸鹽、木質素磺酸鹽、蒙脫石鈉及黃原膠 之殺蟲水性懸浮濃縮物，且基於該殺蟲水性懸浮濃縮物之 總量計，該可尼丁含量係1至50重量％，該含聚氧伸烷基 芳基苯基醚結構之界面活性劑含量係〇.丨至丨〇重量％，該聚 丙烯酸鹽含1係0.1至1〇重量％ ’該木質素續酸鹽含量係 0.1至10重量’該黃原膠含量係0 0i至5重量％，該蒙脫石 鈉含量係0.01至5重量％且該水含量係3〇至90重量％。 一種包含可尼丁、含聚氧伸烷基芳基苯基醚結構之界面 活性劑、聚丙烯酸鹽、木質素磺酸鹽、丙二醇、蒙脫石納 及黃原膠之殺蟲水性懸浮濃縮物，且基於該殺蟲水性懸浮 濃縮物之總量計，該可尼丁含量係1至50重量％，該含聚 氧伸烧基芳基苯基喊結構之界面活性劑含量係0 1至1 〇重 量％，該聚丙烯酸鹽含量係0_1至10重量％，該木質素續酸 鹽含量係0.1至10重量％，該黃原膠含量係0.01至5重量％， 該丙二醇含量係3至10重量％，該蒙脫石鈉含量係〇.〇1至5 重量％且該水含量係30至90重量％。 舉例而言，可藉由下述方法製備本發明殺蟲水性懸浮濃 縮物。 150222.doc -12· 201112949 製備方法1 將可尼丁、含聚氧伸烷基芳基苯基醚結構之界面活性 劑、聚丙烯酸鹽、木質素磺酸鹽、及多醣聚合物質、及視 情況選用之另一增稠劑及可選用之調配物助劑添加至水 中。使用高速攪拌器攪拌所得混合物。隨後，使用濕磨機 (如 Dyno Mill 或 Microfluidizer)粉磨該混合物。 製備方法2 使用乾磨機（如Jet Mizer)粉磨可尼丁。將經粉磨之可尼 丁、含聚氧伸烷基芳基苯基醚結構之界面活性劑、聚丙烯 酸鹽、木質素磺酸鹽、及多醣聚合物質、及視情況選用之 另一增稠劑及可選用之調配物助劑添加至水中。使用高速 攪拌器攪拌所得混合物約30至約9〇分鐘。 製備方法3 將可尼丁、含聚氧伸烷基芳基苯基醚結構之界面活性 劑、聚丙烯酸鹽、木質素磺酸鹽、及視情況選用之另一增 稠劑及可選用之調配物助劑添加至水中。使用高速攪拌器 攪拌所得混合物。隨後，使用濕磨機（如Dyn〇 Miu或Manufactured by Co., Ltd., at 20t:, the viscosity was measured from a Brookfield Philometer equipped with a No. 3 rotor at a rotational speed of 60 rpm of 9 〇〇 to 2 〇〇, 2 〇〇 mPa.s). The pesticidal aqueous suspension concentrate of the present invention may additionally contain another thickening agent. Examples of another thickener include polyethylene glycol and smectite sodium. When the insecticidal aqueous suspension concentrate of the present invention contains another thickener, the thickener is generally present in an amount of from 〇 to 5% by weight based on the total amount of the insecticidal aqueous suspension concentrate. If desired, the pesticidal aqueous suspension concentrates of the present invention may contain other formulation auxiliaries. Examples of such formulation adjuvants include anti-drugs, cations, and preservatives. Examples of ''anti-binders include ethylene glycol, diethylene glycol ^ 砰内内-alcohol. pH adjustment 150222.doc Examples of 201112949 agents include sulfuric acid and phosphoric acid. In one embodiment of the present invention, the insecticidal aqueous suspension concentrate is a surfactant containing a structure of cotinine, a polyoxyalkylene phenyl ether, a polyacrylate, a lignosulfonate, And a polysaccharide polymer material' and a combination of another thickening agent and optionally a formulation adjuvant, optionally dispersed or dissolved in an aqueous medium. In one embodiment of the invention, the insecticidal aqueous suspension concentrate can be prepared using tap water, well water, ion exchange water, or any other type of water used in conventional insecticidal aqueous suspension concentrates. The water of the Xuan Shui is 3 〇 to 90% by weight, preferably 5 〇 to 8 〇 〇 /0, of the total amount of the 5 杀 insecticidal aqueous suspension concentrate. The following are examples of the insecticidal aqueous suspension concentrates of the present invention. An insecticidal aqueous suspension concentrate comprising a nitinine, a polyoxyalkylene phenyl ether-containing surfactant, a polyacrylate, a lignosulfonate, and a polysaccharide polymer, and based on the insecticidal The total amount of the aqueous suspension concentrate =, the content of the nitrile is 〇 to 5% by weight, and the content of the surfactant containing the structure of the polyoxyalkylene phenyl ether is 〇1 to 1% by weight, The polyglycolate content (M to 1 G wt% 'the wood f-acid salt content is 〇1 to 10% by weight, the polysaccharide polymer content is 001 to 5% by weight, and the water content is 30 to 90% by weight 〇/〇. An insecticidal aqueous suspension concentrate containing cotinine, a surfactant containing polyoxynexyl aryl phenyl scales, polyacrylate, lignin hydrochloride, propylene glycol and polysaccharide polymer And based on the total amount of the insecticidal aqueous suspension concentrate, the content of the cotinide content to % by weight, the surfactant content of the polyoxyphenylene-containing phenyl group (tetra) is Ha weight. ^ I50222. Doc 201112949 The polyacrylate content is (1) 丨 to (7)% by weight, the wood The sulfonate content is from 0.1 to 10% by weight, the polysaccharide polymer content is from 1 to 5% by weight, the propylene glycol content is from 3 to 1% by weight and the water content is from 3 to 9% by weight. An insecticidal aqueous suspension concentrate comprising a nitinine, a polyoxyalkylene phenyl ether-containing surfactant, a polyacrylate, a lignosulfonate, a smectite sodium, and a polysaccharide polymer, and The cotinide content is from i to 5% by weight based on the total amount of the insecticidal aqueous suspension concentrate, and the surfactant content of the polyoxyalkylene phenyl ether structure is 〇1 to 1〇 % by weight, the polyacrylate content is from (7)% by weight, the lignosulfonate content is from 0.1 to 10% by weight, the polysaccharide polymer content is from 1 to 5% by weight, the smectite sodium The content is 0.01 to 5% by weight and the water content is 3 to 90% by weight. A surfactant comprising a structure of cotinine, a polyoxyalkylene phenyl ether, polyacrylate 'lignin sulfonic acid An insecticidal aqueous suspension concentrate of salt, propylene glycol, smectite sodium and polysaccharide polymer, and The cotinide content is 1 to 5% by weight based on the total amount of the insecticidal aqueous suspension concentrate, and the surfactant content of the polyoxyalkylene aryl stupyl ether structure is 10% by weight. The polyacrylate content is from 〇丨 to 丨〇 by weight, the lignosulfonate content is from 0.1 to 1% by weight, and the polysaccharide polymer content is from 0.01 to 5% by weight. The propylene glycol content is 3 to 1〇重量。 The smectite sodium content is 0.01 to 5% by weight and the water content is 3 〇 to 9 〇 by weight. A structure comprising a nicidine, a polyoxyalkylene phenyl ether structure An insecticidal aqueous suspension concentrate of a surfactant, a polyacrylate, a lignosulfonate, a propylene glycol, and a xanthan gum, and based on the total amount of the insecticidal aqueous suspension concentrate, 150222.doc -11 - 201112949 The content of cotinine is 1 to 5 〇 〇. / #八;^二王川重量/〇, the surfactant content of the polyoxyalkylene phenyl ether structure is 〇1 to 1〇 by weight. 4, the polyacrylic acid salt content (% by weight of the bismuth, the content of the bismuth (4) salt & 〇1 to 10% by weight of the xanthan gum content is 0.01 to 5% by weight, the propylene glycol content is 3 to 1% by weight And the water content is from 3 〇 to 9 〇 by weight. A surfactant comprising a structure of konidine, a polyoxyalkylene phenyl ether, polyacrylate, lignosulfonate, sodium montmorillonite And an insecticidal aqueous suspension concentrate of xanthan gum, and based on the total amount of the insecticidal aqueous suspension concentrate, the nitrile content is from 1 to 50% by weight, and the polyoxyalkylene phenyl ether is contained The surfactant content of the structure is 〇.丨 to 丨〇% by weight, the polyacrylate contains 1 series 0.1 to 1% by weight 'The lignin content is 0.1 to 10% by weight'. The xanthan gum content is 0. 0i to 5% by weight, the smectite sodium content is 0.01 to 5% by weight and the water content is 3 〇 to 90% by weight. An interface comprising a structure of konidine and a polyoxyalkylene phenyl ether Insecticidal aqueous suspension concentration of active agent, polyacrylate, lignosulfonate, propylene glycol, montmorillonite and xanthan gum And based on the total amount of the insecticidal aqueous suspension concentrate, the content of the cotinide is 1 to 50% by weight, and the content of the surfactant containing the polyoxyalkylene arylphenyl group is 0 1 to 1 〇% by weight, the polyacrylate content is 0_1 to 10% by weight, the lignin content is 0.1 to 10% by weight, the xanthan content is 0.01 to 5% by weight, and the propylene glycol content is 3 to 10% by weight. %, the smectite sodium content is from 1 to 5% by weight and the water content is from 30 to 90% by weight. For example, the insecticidal aqueous suspension concentrate of the present invention can be prepared by the following method. Doc -12· 201112949 Preparation Method 1 Cotinide, surfactant containing polyoxyalkylene phenyl ether structure, polyacrylate, lignosulfonate, and polysaccharide polymer, and optionally Another thickener and optional formulation aid are added to the water. The resulting mixture is stirred using a high speed stirrer. The mixture is then ground using a wet mill such as Dyno Mill or Microfluidizer. Preparation 2 Dry mill (such as Jet Mizer) grinding cannidine. Grinded cannidine, a surfactant containing a polyoxyalkylene phenyl ether structure, a polyacrylate, a lignosulfonate, and a polysaccharide polymer, and optionally another thickener and An optional formulation aid is added to the water. The resulting mixture is stirred using a high speed stirrer for about 30 to about 9 minutes. Method 3 Preparation of cotinide, a polyoxyalkylene phenyl ether structure-containing surfactant Polyacrylate, lignosulfonate, and optionally another thickener and optional formulation aid are added to the water. The mixture is stirred using a high speed stirrer. Subsequently, a wet mill (such as Dyn) is used. 〇Miu or
MiCr〇fluidizer)粉磨該混合物，以獲得經研磨之懸浮液。 將多醣聚合物質添加至水中，以獲得多醣聚合物質水溶 液。 將該經研磨之懸浮液與該多畴聚合物質水溶液混合，以 獲得本發明殺蟲水性懸浮濃縮物。 八，本發明殺蟲水性懸浮濃縮物中，可尼丁係呈微粒形式 刀政於水中，且該微粒可具有i〇 pm或更少（較佳係〇 2至5 150222.doc 201112949 μιη)之體積中值直徑。 可用水稀釋本發明殺蟲水㈣浮濃縮物，且該稀釋液可 喷麗使用。該稀釋比通常係在1:24至1:5_之範圍内，如 約1:1 0 0 0。使用時，通f jj玄士 η ^逋吊將本發明殺蟲水性懸浮濃縮物之 水稀釋液喷灑於土壤表面、或莖及葉上。 本發明殺蟲水性懸浮濃縮物之水稀釋液通常係用於水 田、旱田、果園、草坪'及非農業用地。 本發明殺蟲水性懸浮濃縮物之水騎液亦可用於種子處 理、育苗箱處理等等。 可將本發明殺蟲水性懸浮濃縮物不經稀釋地散佈於水田 上。當將本發明殺蟲水性懸浮濃縮物不經稀釋地散佈於水 田或其他田地上時，在使用之前輕微搖晃含有本發明殺蟲 水眭懸浮》辰縮物之容器，且隨後沿田堤以少量形式散佈本 發明殺蟲水性懸浮濃縮物。 【實施方式】 實例 接著’藉由以下實例將更明確地描述本發明，其不意欲 限制本發明之範嘴。 除非另外說明’否則術語「份」或「份數」意指重量份 或份數8 首先’以下顯示本發明殺蟲水性懸浮濃縮物之製備實 例。 製備實例1 將20.6份可尼丁（ci〇thianidin)、0.08份異噻唑啉-3-酮衍 150222.doc • 14· 201112949 生物（BIOHOPE L，由 K I CHEMICAL INDUSTRY CO., LTD.製造）、0.3份聚矽氧消泡劑（ANTIFOAM E-20，由Kao Corp or at ion製造）、6.0份丙二醇、2.0份聚氧伸院基芳基苯 基醚硫酸銨（NEWKALGEN FS-7PG，由 TAKEMOTO OIL & FAT Co·, Ltd.製造）、1.0份木質素磺酸鹽（NEWKALGEN WG-4，由 TAKEMOTO OIL & FAT Co·，Ltd.製造）、2.5份聚 丙烯酸鈉之水溶液（43重量％之聚丙烯酸鈉；TOXANON GR-31A，由 Sanyo Chemical Industries，LTD.製造）、0.6份 蒙脫石鈉（Kunipia F，由 KUNIMINE INDUSTRIES CO.， LTD.製造）、及0.9份35%硫酸水溶液添加至46.02份離子交 換水中並攪拌，然後使用DYNO-MILL KDL(由Shinmaru Enterprises Corporation製造）濕研磨該混合物，以獲得含 有可尼丁之研磨懸浮液（下文稱為研磨懸浮液（a))。 另一方面，將0.14份黃原膠（Rhodopol 23，由Rhodia Nicca製造）及0.02份異噻唑啉-3-酮衍生物（BIOHOPE L，由 K I CHEMICAL INDUSTRY CO.，LTD_製造）溶於 19_84份離 子交換水中，以獲得黃原膠水溶液（下文稱為黃原膠水溶 液（A)) 〇 將20份黃原膠水溶液（A)添加至80份研磨懸浮液（a)中並 攪拌，以獲得殺蟲水性懸浮濃縮物（下文稱為本發明組合 物（1))。 製備實例2 將20.6份可尼丁、〇.〇8份異噻唑啉-3-酮衍生物 (BIOHOPE L，由 K.I CHEMICAL INDUSTRY CO.，LTD. 150222.doc •15- 201112949 製造）、0.3份聚矽氧消泡劑（ANTIFOAM E-20，由Kao Corporation製造）、6.0份丙二醇、1.0份聚氧伸烷基芳基苯 基醚（NEWKALGEN FS-1，由 TAKEMOTO OIL & FAT Co.， Ltd.製造）、0·2份木質素磺酸鹽（NEWKALGEN RX-B，由 TAKEMOTO OIL & FAT Co.，Ltd·製造）、2·0份聚丙烯酸鈉 之水溶液（43重量％之聚丙烯酸鈉；TOXANON GR-3 1A， 由 Sanyo Chemical Industries, Ltd.製造）、0·6份蒙脫石鈉 (Kunipia F，由 KUNIMINE INDUSTRIES CO.，LTD.製 造）、3.0 份聚乙二醇（PEG 6000S，由 Sanyo Chemical Industries，Ltd.製造）、及0.3份35%硫酸水溶液添加至45.92 份離子交換水中並攪拌，然後使用DYNO-MILL KDL(由 Shinmaru Enterprises Corporation製造）濕研磨該混合物， 以獲得含有可尼丁之研磨懸浮液（下文稱為研磨懸浮液 (b))。 另一方面，將0.12份黃原膠（Rhodopol 23，由Rhodia Nicca製造）及0.02份異噻唑啉-3-酮衍生物（BIOHOPE L，由 Κ·Ι CHEMICAL INDUSTRY CO.，LTD.製造）溶於 19.86 份離 子交換水中，以獲得黃原膠水溶液（下文稱為黃原膠水溶 液（B))。 將20份黃原膠水溶液（B)添加至80份研磨懸浮液（b)中並 攪拌，以獲得殺蟲水性懸浮濃縮物（下文稱為本發明組合 物（2))。 接著，以下顯示製備對照殺蟲水性懸浮濃縮物之參考實 例0 150222.doc -16- 201112949 參考製備實例1 將20.6份可尼丁、0.08份異噻唑啉-3-酮衍生物 (BIOHOPE L，由 K.I CHEMICAL INDUSTRY CO.，LTD. 製造）、0.3份聚矽氧消泡劑（ANTIFOAM E-20，由Kao Corporation製造）' 6.0份丙二醇、1.0份聚氧伸烧基芳基笨 基醚（NEWKALGEN FS-1，由 TAKEMOTO OIL & FAT Co., Ltd.製造）、1.0份木質素磺酸鹽（NEWKALGEN WG-4，由 TAKEMOTO OIL & FAT Co·，Ltd.製造）、0·7份蒙脫石鈉 (Kunipia F，由 KUNIMINE INDUSTRIES CO.，LTD.製 造）、及0.1份35%硫酸水溶液添加至50.22份離子交換水中 並授拌，然後使用 DYNO-MILL KDL(由 Shinmaru Enterprises Corporation製造）漁研磨該混合物，以獲得含有可尼丁之研 磨懸浮液（下文稱為研磨懸浮液（c))。 另一方面，將0.1份黃原膠（Rhodopol 23，由Rhodia Nicca製造）及0.02份異噻唑啉-3-酮衍生物（BIOHOPE L，由 K I CHEMICAL INDUSTRY CO·，LTD.製造）溶於 19.88份離 子交換水中，以獲得黃原膠水溶液（下文稱為黃原膠水溶 液（C))。 將20份黃原膠水溶液（C)添加至80份研磨懸浮液（c)中並 攪拌，以獲得殺蟲水性懸浮濃縮物（下文稱為對照組合物 ⑴）。 參考製備實例2 將20.6份可尼丁、0.08份異噻唑啉-3-酮衍生物 (BIOHOPE L，由 K.I CHEMICAL INDUSTRY CO.，LTD.製 150222.doc 17 201112949 造）、0.3份聚矽氧消泡劑（ANTIFOAM E-20，由Kao Corporation製造）、6.0份丙二醇、2.0份聚氧伸烷基芳基苯 基醚硫酸銨（NEWKALGEN FS-7PG，由 TAKEMOTO OIL & FAT Co.，Ltd·製造）、3.0份聚丙烯酸鈉之水溶液（43重量％ 之聚丙稀酸納；TOXANON GR-31A，由 Sanyo Chemical Industries, Ltd.製造）、0.6 份蒙脫石鈉（Kunipia F，由 KUNIMINE INDUSTRIES CO.，LTD·製造）、及 1_0份 35%硫 酸水溶液添加至46.42份離子交換水中並攪拌，然後使用 DYNO-MILL KDL(由 Shinmaru Enterprises Corporation 製 造）濕研磨該混合物，以獲得含有可尼丁之研磨懸浮液（下 文稱為研磨懸浮液（d))。 另一方面，將0.08份黃原膠（Rhodopol 23，由Rhodia Nicca製造）及0_02份異噻唑啉-3-酮衍生物（BIOHOPE L，由 K-I CHEMICAL INDUSTRY CO_，LTD.製造）溶於 19·9 份離 子交換水中，以獲得黃原膠水溶液（下文稱為黃原膠水溶 液⑼）。 將20份黃原膠水溶液（D)添加至80份研磨懸浮液（d)中並 攪拌，以獲得殺蟲水性懸浮濃縮物（下文稱為對照組合物 P))。 接著，使用如上所述般製備之殺蟲水性懸浮濃縮物進行 測試實例1至4。 測試實例1 (測量體積中值直徑） 使用雷射繞射類型粒度分佈計（HERO & RODOS，由 Janpan Laser Corp.製造，測量條件：20 mm焦距，分散介 I50222.doc •18- 201112949 質為離子交換水）測量體積中值直徑。 測試實例2(測量pH) 使用pH計（型號F-22，由HORIBA Ltd.製造）測量該等殺 蟲水性懸浮濃縮物之pH。 測試實例3 在25 C下’使用布魯克菲爾德黏度計（型號RB-85L ,由 TOKI SANGYO CO·，LTD.製造，配備有2號轉子，轉數為6 rpm或60 rpm)測量該等殺蟲水性懸浮濃縮物之黏度。 測試實例4(測量結塊數量） 將約40 g之各殺蟲水性懸浮濃縮物添加至5〇⑺丨離心管中 並以900 rpm之轉數離心6小時。離心之後，將該殺蟲水性 懸浮濃縮物倒出，同時保持該離心管垂直，並使開口向 下。當下落液滴之間的時間間隔超過丨〇秒時，停止倒出。 在停止倒出時，測量仍留在該離心管中之殺蟲水性懸浮濃 縮物之重里，並將藉由該測得的重量除以用於該測試中之 殺蟲水性懸浮濃縮物之總重量所獲得之百分比算作結塊 率。 各測試實例之結果係示於表1中。 表1 本發明組合物 _(1) 本發明組合物 對照組合物 (1) 對照組合物 (2) 體積中值直徑 (μιη) 2.0 — 2.4 2.1 1.5 pH 5.1 6 6 5.1 5.6 黏度(mPa-s) 6 rpm/60 rpm 795/167 6.3 ------- 945/212 ~----------- 8 〇 2600/339 4310/497 結塊率％ 71.0 29.8 150222.doc •19· 201112949 工業應用 本發明殺蟲水性懸浮濃縮物具有抗結塊性且可用作殺蟲 劑調配物。 150222.doc -20-The mixture was ground by MiCr〇fluidizer to obtain a ground suspension. The polysaccharide polymeraceous substance is added to water to obtain a polysaccharide polymer aqueous solution. The milled suspension is mixed with the multi-domain polymeric aqueous solution to obtain the insecticidal aqueous suspension concentrate of the present invention. 8. In the insecticidal aqueous suspension concentrate of the present invention, the nitinine is in the form of microparticles in water, and the microparticles may have i〇pm or less (preferably, the system is 2 to 5 150222.doc 201112949 μιη). Volume median diameter. The insecticidal water (IV) float concentrate of the present invention can be diluted with water, and the diluent can be used in a spray. The dilution ratio is usually in the range of 1:24 to 1:5, such as about 1:1 0 0 0. When in use, the water dilution of the insecticidal aqueous suspension concentrate of the present invention is sprayed on the soil surface, or on the stems and leaves, by means of a jj 玄 逋 逋 。. The aqueous dilution of the insecticidal aqueous suspension concentrate of the present invention is generally used in paddy fields, dry fields, orchards, lawns, and non-agricultural land. The water riding liquid of the insecticidal aqueous suspension concentrate of the present invention can also be used for seed treatment, seedling box treatment and the like. The insecticidal aqueous suspension concentrate of the present invention can be dispersed on the paddy field without dilution. When the insecticidal aqueous suspension concentrate of the present invention is dispersed in a paddy field or other field without dilution, the container containing the suspension of the insecticidal water hydrazine of the present invention is slightly shaken before use, and then a small amount is along the field bank. The insecticidal aqueous suspension concentrate of the present invention is dispersed in the form. [Embodiment] EXAMPLES Next, the present invention will be more specifically described by the following examples, which are not intended to limit the scope of the invention. Unless otherwise stated, the terms "parts" or "parts" mean parts by weight or parts. 8 First, the following examples show the preparation of the insecticidal aqueous suspension concentrate of the present invention. Preparation Example 1 20.6 parts of ci〇thianidin, 0.08 parts of isothiazolin-3-one derivative 150222.doc • 14·201112949 organism (BIOHOPE L, manufactured by KI CHEMICAL INDUSTRY CO., LTD.), 0.3 Polyoxyl antifoam (ANTIFOAM E-20, manufactured by Kao Corp or at ion), 6.0 parts of propylene glycol, 2.0 parts of polyoxyl phenyl phenyl ether sulfate (NEWKALGEN FS-7PG, by TAKEMOTO OIL & ; FAT Co., Ltd.), 1.0 part of lignosulfonate (NEWKALGEN WG-4, manufactured by TAKEMOTO OIL & FAT Co., Ltd.), 2.5 parts of sodium polyacrylate solution (43% by weight) Sodium acrylate; TOXANON GR-31A, manufactured by Sanyo Chemical Industries, LTD.), 0.6 parts of smectite sodium (Kunipia F, manufactured by KUNIMINE INDUSTRIES CO., LTD.), and 0.9 part of a 35% aqueous solution of sulfuric acid added to 46.02 parts The mixture was stirred in ion-exchanged water, and then the mixture was wet-milled using DYNO-MILL KDL (manufactured by Shinmaru Enterprises Corporation) to obtain a grinding suspension containing konidine (hereinafter referred to as grinding suspension (a)). On the other hand, 0.14 parts of xanthan gum (Rhodopol 23, manufactured by Rhodia Nicca) and 0.02 parts of isothiazolin-3-one derivative (BIOHOPE L, manufactured by KI CHEMICAL INDUSTRY CO., LTD.) were dissolved in 19-84 parts. Ion exchange water to obtain an aqueous solution of xanthan gum (hereinafter referred to as xanthan gum aqueous solution (A)) 20 Add 20 parts of aqueous solution of xanthan gum (A) to 80 parts of grinding suspension (a) and stir to obtain killing An aqueous suspension concentrate (hereinafter referred to as the composition (1) of the present invention). Preparation Example 2 20.6 parts of cotinine, 〇. 8 parts of isothiazolin-3-one derivative (BIOHOPE L, manufactured by KI CHEMICAL INDUSTRY CO., LTD. 150222.doc •15-201112949), 0.3 parts of poly An oxygen defoamer (ANTIFOAM E-20, manufactured by Kao Corporation), 6.0 parts of propylene glycol, 1.0 part of polyoxyalkylene phenyl ether (NEWKALGEN FS-1, by TAKEMOTO OIL & FAT Co., Ltd. Manufactured, 0. 2 parts of lignosulfonate (NEWKALGEN RX-B, manufactured by TAKEMOTO OIL & FAT Co., Ltd.), 2.0 parts of sodium polyacrylate aqueous solution (43% by weight of sodium polyacrylate; TOXANON GR-3 1A, manufactured by Sanyo Chemical Industries, Ltd.), 0.6 parts of smectite sodium (Kunipia F, manufactured by KUNIMINE INDUSTRIES CO., LTD.), 3.0 parts of polyethylene glycol (PEG 6000S, Sanyo Chemical Industries, Ltd.), and 0.3 part of a 35% aqueous sulfuric acid solution were added to 45.92 parts of ion-exchanged water and stirred, and then the mixture was wet-milled using DYNO-MILL KDL (manufactured by Shinmaru Enterprises Corporation) to obtain a nicotine-containing mixture. Grinding suspension (hereinafter referred to as grinding suspension) (b)). On the other hand, 0.12 parts of xanthan gum (Rhodopol 23, manufactured by Rhodia Nicca) and 0.02 parts of isothiazolin-3-one derivative (BIOHOPE L, manufactured by INDUSTRY·Ι CHEMICAL INDUSTRY CO., LTD.) were dissolved. 19.86 parts of ion-exchanged water to obtain an aqueous solution of xanthan gum (hereinafter referred to as xanthan gum aqueous solution (B)). 20 parts of the aqueous solution of xanthan gum (B) was added to 80 parts of the grinding suspension (b) and stirred to obtain an insecticidal aqueous suspension concentrate (hereinafter referred to as the composition (2) of the present invention). Next, a reference example for preparing a control insecticidal aqueous suspension concentrate is shown below. 0 150222.doc -16- 201112949 Reference Preparation Example 1 20.6 parts of cotinine, 0.08 parts of isothiazolin-3-one derivative (BIOHOPE L, by KI CHEMICAL INDUSTRY CO., LTD. Manufactured, 0.3 parts of polyfluorene defoamer (ANTIFOAM E-20, manufactured by Kao Corporation) '6.0 parts of propylene glycol, 1.0 part of polyoxyalkylene aryl stupyl ether (NEWKALGEN FS -1, manufactured by TAKEMOTO OIL & FAT Co., Ltd.), 1.0 part of lignosulfonate (NEWKALGEN WG-4, manufactured by TAKEMOTO OIL & FAT Co., Ltd.), 0. 7 parts of montmorillon Sodium (Kunipia F, manufactured by KUNIMINE INDUSTRIES CO., LTD.), and 0.1 part of a 35% aqueous solution of sulfuric acid were added to 50.22 parts of ion-exchanged water and mixed, and then DYNO-MILL KDL (manufactured by Shinmaru Enterprises Corporation) was used for grinding. This mixture is obtained to obtain a grinding suspension containing cotinine (hereinafter referred to as grinding suspension (c)). On the other hand, 0.1 part of xanthan gum (Rhodopol 23, manufactured by Rhodia Nicca) and 0.02 parts of isothiazolin-3-one derivative (BIOHOPE L, manufactured by KI CHEMICAL INDUSTRY CO., LTD.) were dissolved in 19.88 parts. The ion exchange water was used to obtain an aqueous solution of xanthan gum (hereinafter referred to as xanthan gum aqueous solution (C)). 20 parts of the aqueous solution of xanthan gum (C) was added to 80 parts of the grinding suspension (c) and stirred to obtain an insecticidal aqueous suspension concentrate (hereinafter referred to as a control composition (1)). Reference Preparation Example 2 20.6 parts of cotinine, 0.08 parts of isothiazolin-3-one derivative (BIOHOPE L, manufactured by KI CHEMICAL INDUSTRY CO., LTD. 150222.doc 17 201112949), 0.3 parts of polyoxyl Foaming agent (ANTIFOAM E-20, manufactured by Kao Corporation), 6.0 parts of propylene glycol, 2.0 parts of polyoxyalkylene alkyl phenyl ether sulfate (NEWKALGEN FS-7PG, manufactured by TAKEMOTO OIL & FAT Co., Ltd.) ), 3.0 parts of an aqueous solution of sodium polyacrylate (43% by weight of sodium polyacrylate; TOXANON GR-31A, manufactured by Sanyo Chemical Industries, Ltd.), 0.6 parts of sodium montmorillonite (Kunipia F, by KUNIMINE INDUSTRIES CO., LTD. Manufactured, and 1_0 part of a 35% aqueous solution of sulfuric acid was added to 46.42 parts of ion-exchanged water and stirred, and then the mixture was wet-milled using DYNO-MILL KDL (manufactured by Shinmaru Enterprises Corporation) to obtain a grinding suspension containing cotinine. (hereinafter referred to as grinding suspension (d)). On the other hand, 0.08 parts of xanthan gum (Rhodopol 23, manufactured by Rhodia Nicca) and 0-02 parts of isothiazolin-3-one derivative (BIOHOPE L, manufactured by KI CHEMICAL INDUSTRY CO_, LTD.) were dissolved in 19.9. The ion exchange water was used to obtain an aqueous solution of xanthan gum (hereinafter referred to as xanthan gum aqueous solution (9)). 20 parts of the aqueous solution of xanthan gum (D) was added to 80 parts of the grinding suspension (d) and stirred to obtain an insecticidal aqueous suspension concentrate (hereinafter referred to as a comparative composition P). Next, Test Examples 1 to 4 were carried out using the insecticidal aqueous suspension concentrate prepared as described above. Test Example 1 (measuring volume median diameter) Using a laser diffraction type particle size distribution meter (HERO & RODOS, manufactured by Janpan Laser Corp., measuring conditions: 20 mm focal length, dispersion I50222.doc • 18-201112949 quality Ion exchange water) measures the volume median diameter. Test Example 2 (Measurement of pH) The pH of these insecticidal aqueous suspension concentrates was measured using a pH meter (Model F-22, manufactured by HORIBA Ltd.). Test Example 3 At 25 C, the insecticidal water was measured using a Brookfield viscometer (model RB-85L, manufactured by TOKI SANGYO CO., LTD. equipped with a No. 2 rotor, a number of revolutions of 6 rpm or 60 rpm). The viscosity of the suspension concentrate. Test Example 4 (Measurement of agglomeration number) About 40 g of each of the insecticidal aqueous suspension concentrates was added to a 5 Torr (7) 丨 centrifuge tube and centrifuged at 900 rpm for 6 hours. After centrifugation, the insecticidal aqueous suspension concentrate was poured while keeping the centrifuge tube vertical and the opening down. When the time interval between falling drops exceeds the leap second, the pouring is stopped. When the pouring is stopped, the weight of the insecticidal aqueous suspension concentrate remaining in the centrifuge tube is measured, and the measured weight is divided by the total weight of the insecticidal aqueous suspension concentrate used in the test. The percentage obtained is counted as the blocking rate. The results of the respective test examples are shown in Table 1. Table 1 Composition of the Invention - (1) Composition of the composition of the present invention (1) Control composition (2) Volume median diameter (μιη) 2.0 - 2.4 2.1 1.5 pH 5.1 6 6 5.1 5.6 Viscosity (mPa-s) 6 rpm/60 rpm 795/167 6.3 ------- 945/212 ~----------- 8 〇2600/339 4310/497 Agglomeration rate % 71.0 29.8 150222.doc •19 · 201112949 Industrial Applicability The insecticidal aqueous suspension concentrate of the present invention is anti-caking and can be used as a pesticide formulation. 150222.doc -20-