TW301670B - Oil-in-water emulsion type detergent composition for washing laundries made of silk or wool - Google Patents

Abstract

An oil-in-water emulsion type detergent composition for washing laundries made of silk or wool comprising: from 15 to 45 parts by weight of non-ionic surfactant; from 15 to 35 parts by weight of hydrocarbon solvent containing normal paraffine and/or limonene for laundering; from 25 to 50 parts by weight of water; from 0.3 to 0.7 parts by weight of tetra-alkyl ammonium chloride; from 0.2 to 0.7 parts by weight of protease maintaing a titer at a pH of from 6.0 to 8.0; from 0.3 to 0.8 parts by weight of lipase; from 0.3 to 0.7 parts by weight of carboxymethyl cellulose; and from 6 to 10 parts by weight of butyl diglycol.

Description

ο • 7'ri. ϋ 3-.. A- ^ s? τ? 穆 6 日 II 12. Fang statement stated that the hair and the face of the Wujingbei Mingfa domain of the Mingfa legalized method of living face wash and wash The milk should be used to contain the inclusions, the composition of the composition of the group of cleaning agents to clean the seeds of a kind of cleaning products. Or Sansi's use of water polyester and lotion to dissolve, the main part of the agent is used as a liquid emulsion, which should be used and the French polyester washing machine's polyester washing technology is self-study. 2 The use of methods such as damage to non-dimensional damage products, washing and damage to the surface of the student ’s clothing and the damage to the surface of the surface of the surface of the surface of the silk-making liquid dimension maintenance, dissolution of the clothing is equivalent to the hair Ml by This is as if, by Wei Yi Shi, Ji Rong distilled the main reason for his washing. In order to wait for the water to be white_ Wash the oil in the polyester with a light methacrylic acid removing vinegar to clean and lose the dimensionality, and reduce the loss of the Qinghui fibril system. The listed application is ft. It should be used as a stone, so that the polyester-based washing water can be used for drying, such as alkene, nitrate, acetylene, carbon, and carbon trichloride. 1 'for 1' portions, dichloromethane, dichloromethane, trichlorinated oil 1-brain ΙΕ 1 '(Read the note f on the back, then fill out the page) The Central Government Bureau of Economic Affairs, Employee Consumer Cooperative Printed its own The method of washing and drying with the legal equipment should be passed on. The shop agent dissolves the washing agent and moves it freely. Entering the world, including the shop or clothes; washing isotonic objects' fatty tea B components are contaminated by the objects of the main items of clothes and washing. To the next attachment, such as sticky spots, lack of first dry head, if the fat is washed, the US TN 8 is removed, and only the wash is dried, stained, and stained. Intangible substance-melting water machine and insoluble substance-dissolved white water egg and the degreased and removed substance are not white, the egg quality and the clean substance are not washed, and the old laundry is still in the polyester store after washing. , Hand over this and due to the goods 0 items, the clothes are washed and preserved in the "Yuyouliu" and the second paper. The standard of the paper is in accordance with the Chinese National Standard ([Milk] 84 specifications (210 '297 Gongmeng)) 4 Amendment page 85.12. 1 6

w M Printed by the Employee Consumer Cooperative of the Central Standardization Bureau of the Ministry of Economic Affairs 51 V. Description of the invention (2 products are washed together, the transfer of bacteria or contaminants will occur * It is not hygienic. Third, because laundry items must be entrusted to automatic laundry The store is time-consuming, inconvenient and expensive. When washing K eggs & quality-based fibers such as hair and silk, and the dimensional damage such as rayon and acetate, etc. The suspicion phenomenon is explained as follows. Since traditional detergents include 20 ~ 30 weights of X-interface activated cocoons and dependent materials, when cleaning_dissolved in appropriate water, the concentration of interface-activated cornice reaches 0.2 ~ 0.3 weight S :, which can Provides the best washing effect. At this time, the pH reaches 10-11. Washing with an interface activator in an alkaline solution can provide good performance. However, the peptide-knot structure in protein-based fibers will be partially hydrolyzed to carboxylic acid The functional groups and amine functional groups or the remaining fatty substances will lose *, thus eliminating the gloss of the grade dimension and shrinking the fiber due to the special shrinkage characteristics of the wool fiber. The peptide bonding structure will also be hydrolyzed in the acid solution to cause the period dimension. Harmful. The natural water used for washing is acidic. Natural water is a carbonized water that maintains a balance with the carbon dioxide gas in the atmosphere and maintains a pH of 5.6, so it will damage the K protein-based main dimension. Another phenomenon that occurs when washing and cleaning with traditional detergents is protein-based entanglement. The washing water or washing water penetrates the pores in the dimensional dimension through capillaries (these pores have the shape of capillary tubes, which It is formed by isolating the fat material filled in the animal hair). The infiltrated water will damage the inner surface of the fiber pores and promote the shrinkage of the dimension. Most of the transfer agents include ionic interface activators and high electrolysis The electrolyte has a considerable interfacial tension. These are promoted by the capillary infiltration into the capillary pores of the hairy dimension (please read the precautions on the back before filling this page)

L This paper scale applies the Chinese National Standard (CNS) Λ4 specification (2IOX297mm) 5 Amendments -........:-supplementary of the Ministry of Economic Affairs Central Standardization Bureau Male Workers Consumers ’Cooperative Society Vatican V. , Description of the invention (3) 1 Damage 〇1 1 1 Therefore, there is a need for household laundry detergent 1 1 m agent that can be used for wool or m laundry items. In the United States_ Zaili 4, 7, 50, 907 (awarded to lie i η Ｍ Ｍ. Vi 1 sberg) 中 ^ -V jing1 先 1 * Reveal the cleaning agent for washing wool or silk laundry items. Reveal the cleaning agent reading 1 The back includes one of the alkyl glyoxylate sodium sulfate__鈒 C, 2 " * -C 1 Θ fermentation as deionization \ ij of 1 injection interface activator and sodium benzene sulfonate as the main components. However, due to the negative ion 1 ionic interface activator generates foam and reduces the washing ability and in After washing, it will not fill in the item and fill 1 person to clean * Needs large Μ water for cleaning. Therefore, the water and wool or silk m dimension becomes long. Page 1 Time contact and there is the possibility of dimensional collection m. In addition, the anion interface is active '-1. The chemical agent and calcium ion are in natural water The reaction reduces the washing ability and produces insolubilities. 1 1 m m 搠 W m into 'β dye 0 1 In addition to washing m household cleaners for laundry items made of m or wool have entered 1 order I entered the market and for example by Japanese D rysenka (Γ 1 trade name) manufactured by In te Γ Or 1 0 η company is--Example 1 This product includes oil / water emulsion as the main component of 11 parts, but it also includes anionic interface activator such as He η ζ The patent described 1 丄 1 and cationic interface activator and anion interface activation m together 9 and unpleasant fc, producing insoluble fatty substances. The present invention does not know the detailed composition of Dr y-senka 1. I Therefore, the present inventors have made various efforts to prevent fiber damage and fiber 1 I shrink and remove egg pollutants-based contaminants and water-soluble substances produced by dry cleaning 1 I Inorganic contaminants combined with dissolution of non-carbohydrate interfaces Activator and Dangdang solution 1 1 in water and mixed with m-dimensional softener and other composite detergent composition 1 I can overcome the shortcomings of traditional water washing and dry cleaning. Therefore, the present invention 1 was completed 〇1 1 Summary of the invention 1 The paper size is suitable for the Chinese National Standard (CNS) Λ4 specification (210X297 gf) 6 A7 B7 printed by the employee consumer cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of the invention () Therefore, the purpose of the invention In order to provide a novel detergent composition, it can use a domestic washing machine to wash laundry items made of silk or wool. Another object of the present invention is to provide a washing method using the above detergent composition. In order to achieve the object of the present invention, an oil / water emulsion type detergent composition is provided, comprising: (a) about 15 to about 45 parts by weight of a nonionic interface activator; (b) about 15 to about 35 parts by weight containing The hydrocarbon solvent of n-alkane and / or alkenyl is used for laundry; (c) about 25 to about 50 parts by weight of water; and (d) about 0 to about 10 parts by weight of additives. In particular, the detergent composition according to the present invention comprises: (a) about 15 to about 45 parts by weight of a nonionic interface activator; (b) about 25 to about 50 parts by weight of water; (c) about 0.3 ~ About 0.7 parts by weight of tetraalkylammonium chloride; (d) about 0.2 to about 0.7 parts by weight of protease, which can maintain a potency at a pH of 6.0 to 8.0; (e) about 0.3 to about 0.8 parts by weight of lipase (F) about 0.3 to about 0.7 parts by weight of carboxymethyl cellulose; and (g) about 6 to about 10 parts by weight of diethylene glycol butyl ether; in order to achieve another object of the present invention, according to the present invention provides a use Method for washing laundry articles made of silk or wool with an oil / water emulsion type detergent composition, the composition containing about 15 to about 45 parts by weight of a nonionic interface activator, and about 15 to about 35 parts by weight of n-paraffin And / or hydrocarbon solvents used for the washing of paper. The standard of China's national standard (CNS) A4 specification (210 X 297 mm) _ Ί _ (please read the precautions on the back before filling out this page) . 丄 s Λ7 " 丄 1-year h Printed by the member of the Bureau of Standards, Economic Lang, X and the Consumer Cooperative. V. Description of the invention (5) Clothing »About 25 ~ about 50 parts of water and 0 ~ about 10 parts of the weight added surface 3 After adding the agent composition to the sink with a rotary blade, the mm composition Lai Jiangdi-. 逋ft Water is introduced into the washing eaves and then diluted with a rotating scraper. Then the water is adjusted to the second best by introducing more water into the washing tank for washing and guiding laundry items made of silk or wool into the washing 〇Turn the rotary blade to produce a stream of pandan water for washing laundry items 0 The detergent composition of the present invention relies on a non-ionic interface activator that uses emulsion as the main ingredient and combines ideal emulsifying enzymes > Ingredients are prepared as a special solvent and a large amount of water. Using the cleaning agent composition of the present invention is a high-end clothing traditionally made of dry cleaning and washing m's hair> silk and regenerative fiber The armpits can be advantageously washed with a domestic washing machine. Additives such as m-dimensional softener ·> antistatic agent> protease fat_dispersant, m thickener, etc. can be added to the cleaning agent composition. Proteins that cannot be removed by dry washing The main contaminants can be removed by adding protease to remove water-soluble contaminants. The contaminants can be removed by washing with water containing the detergent composition. In addition, the fatty acid glycerol contaminants widely secreted by the white human skin can also be added by cells and laurel. Ion interface activator and solvent emulsion are removed and are clearer than the method of adding traditional interface activator or solvent dry cleaning. Effective description of the drawings. Refer to the drawings for detailed description of the preferred specific examples. The advantages and advantages can be more clearly understood, where the gardens 1 A and 1 B are flow surfaces used to illustrate according to the invention Specific example of the soo tank method 〇 (Jing first read the $ item on the back and then fill in this page) The wooden paper size is applicable to the mid-threshold country falcon (CNS) Λ4 specifications (2! OX297mm), grade 8-correction page ^ 〇lC7〇a7 B7 V. Description of the invention (i;) Figure 2 is a block diagram showing the structure of a washing machine implementing the method of the present invention. Detailed Description of the Invention The present invention will be described in detail below. The detergent composition of the present invention includes about 15 to about 45 parts by weight of a non-ionic interface activator, about 15 to about 35 parts by weight of a hydrocarbon solvent containing n-alkanes and / or alkenes for washing, and about 25 to about 50 parts by weight Parts of water and 0 to about 10 parts by weight of additives. The detergent composition of the present invention includes about 15 to about 45 parts by weight of a nonionic interface activator. Examples of non-ionic interface activators can be described as coconut fatty acid alcohol amines in oxyethylene and alkanolamide surfactants containing 12 carbon atoms of lauryl alcohol. In the detergent composition of the present invention, it is preferable to use about 15 to about 45 parts by weight of 100 ¾ of a laurel-based interface activator with high washing power. When the interface activator is diluted in water to a degree of lg / Ι, the concentration of the interface activator becomes 0.2 ~ 0.3 weight》: which is the optimal concentration for washing. At this concentration, it can prevent damage to the soft Jiwei and can maximize the washing effect, while minimizing skin damage. Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page) The non-ionic interfacial activator of laurel powder has the advantages that it produces a small amount of foam, does not affect enzyme activity, has strong surface activity and Strong penetration into the diluted solution. In particular, this interfacial activator dissociates into ions in aqueous solution and has a good effect of removing fat contaminants. In addition, the interfacial activator greatly reduces the interfacial tension and arbitrarily adjusts the balance between hydrophilic and hydrophobic functional groups. At this time, if the amount of the interfacial activator lauryl alcohol oxyethylene and fatty acid alcohol acetamine is less than about 15 parts by weight *, sufficient surface activity cannot be obtained. If -9- This paper scale applies the Chinese National Standard (CNS ) A4 specification (210X297mm) 5. Description of the invention (< 7 The most super-unwanted portion of the whole amount. It is preferably about 15 weights of fatty acids.

. --------- .. ----- .---· -ImM decreases by about 4 5 weight. Although the Ministry is around this time, Laurel 1 2 ~ about 30 re-enzymatic glutamine in non-parts, more preferably about the traditional cleaning agent Ming detergent Ming detergent can reduce the hair fraction due to excessive surface activity • washing ability As a result, the amount of the interfacial activator is 15 ~ 45 parts by weight based on Zircon, preferably about 20 ~ 40 reoxygenated oxyethylene in the non-ionic interfacial activation. It is 15 to about 23 ft. Parts * Coconut ion interface activator is preferably about 3 to about 5 to about 11 parts by weight. Include anionic interface activator as interface activation 9! The composition includes only nonionic interface activator. Therefore, it has a lower chemical impact and a relatively low surface activation dimension, and penetrates into the pores of Maodian * to prevent Mao from being susceptible (please read note f on the back and fill in this page). The damage caused by cooperative printing and reproduction. The composition of the wood invention includes at least one solvent I of n-alkane solvent, which contains 9 to 12 carbons, and is used as a hydrocarbon-based solvent-dissolving cocoon and an unsaturated sulfonane-based solvent. The n-decane is preferred, and n-decane is preferred. At this time, the hydrocarbon-based solvent is about 12 to about 36 parts by weight, preferably about 18 to 30 parts by weight. As for the solvent mainly composed of unsaturated oxiranes, there can be exemplified longiene extracted from the orange skin and being a natural aromatic unsaturated oxiane solvent. Hitting ene further increases the washing power of fatty substances. In addition, the addition of trioxane-based solvent can crucify the washing capacity of n-alkane. Therefore, in the composition of the present invention, it is preferable to use a normal paraffin and an unsaturated naphthene-based solvent together. The ratio of n-arane to the mixture of unsaturated and naphthenic solvents is about 1.5 to about 2.5, preferably about 2. If the total weight of noodles and panene is more than the above ratio, the washing capacity and fat washing performance of n-alkanes are based on the paper standard universal threshold threshold standard falcon (CNS) Λ4 specification (Ή0Χ 297mm) 10 Amend to buy 3_? 0 A7 __B7 V. Description of invention (8) The power will be reduced. At this time, if the amount of normal alkane solvent is less than about 8 parts by weight, the amount of fat washed is 4 times the weight of Lr and the amount of shock is about 4%. Dissolved alkanes have a low ring drop and will not be fully saturated. If it is increased, the timing of the primary alkane is S 3 2 1A, and the excess is about i. The amount is about the approximate amount, if the amount is equal, the alkane is lower. Will be positive force, the amount of tb Μ detergent washing solution costs this factor 2. Approximately increase ~ increase by 12 will be about Jiajia better comparison, the portion is £ H_ 3 weight 2 3 1 4 J 2 about 4 portions i weight ο 1X about the surface of the system-the main separation of Zili is yeast laurel Borrowing material and lanthanum compound are clean and clear, 6-fat _ for this chemical is about heavier than the blended portion (please read the precautions on the back and fill in this page) into a water form Use the agent that can make the adult species into three groups of products, water cleaning polyester, suitable for cleaning and the Mingcheng system, and this is all used for the purpose of dissolving and removing the dissolved water. After making the clothing or agent made. Dissolve the instinct to remove the agent Π, make the quality more timely than the washing machine, dry by the method, clean by the master, remove it, pass it and the leather body to wash the human body, and use the real liquid of the seedable hair cells. The milk-washing re-water and the traces of the water on the home's traces of the lotion are used to make the world become a borrower and can be secreted. It is printed as isoenzyme by the employee consumer cooperative of the Central Standardization Bureau of the Ministry of Economic Affairs. The chain-strength milk is able to neutralize and wash the water in the organic solvent. It has the fat agent special fat clean special ester clear and the oil agent glycinated acid. Depends on the fat, but it ’s not necessary to get rid of the pollution. 5 9 l · 9 After the night, the amount of chlorine in the superalkane tetrachloride S ο 7 is 0. The number is approximately ~) 3 Solution ο Divided parcel The product is generated in the group M. The water is clean and waste is in the s!

The gain of the effective electric resistance and the softening of the soft fiber is not obtained when the method is used-the amount of S S increases the cost and the amount of time when the fiber is too variable to change the size of the fiber i S 7.

1X 1X This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) A7 B7 The i U agent composition printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy preferably contains about 0.2 ~-about 0.7 parts by weight of eggs 1 1 Leukase 〇Protease is available on the market and should have a retention of 1 at a pH of 6.0,-about 8 * 0 1 1 price 〇1 Usually »In addition to some water-soluble protein contaminants K Xi Bu, a variety of protein-based please 1 1 First dirt 1 It remains in the laundry items 9 Such as peeling skin flakes, blood stained egg reading 1 White-based food molds, etc. can hardly be dissolved or dispersed in organic dissolution ιδ 1 I 1 I agent or borrowed Removed by the reaction of the interfacial activator. 〇You can use the enzyme and there is> Wang Yi 1 1-matter 1 to be removed advantageously 0 by adding about 0.2-about 0.7% by weight protease, which is a protein item- JL lead decomposition enzyme f is used to break down proteins into Water-soluble amino acid, protein-based dirt, ancient costumes I can be completely removed by the action of enzymes 〇Η 1 1 I At this time, if the amount of protease is less than 0.2 parts by weight, the enzyme action is too weak and 1 1 protein decomposition It will be difficult if the amount exceeds 0.7 parts by weight, it is not economical. 1 The detergent composition of the present invention preferably contains from about 0.3 to about 0.8 parts by weight of lipase I. lipase. 0 lipase is an enzyme that can decompose fat into glycerol and fatty acid 1 I. Therefore, Adding lipase to the detergent composition of the present invention can promote the removal of 1 1 into the fat stains. If the amount of lipase is less than 0.3 parts by weight, the decomposition of m 1 fat will be difficult if the amount exceeds 0. δ It is not economical by weight. 1 The detergent composition of the present invention contains about 0.3 to about 0.7 parts by weight of carboxymethyl 1 I cellulose as a dispersant. The dispersant can promote the separation of dirt and can stop Contamination 1 1 | The substance adheres to the fiber or the sink t again. It adheres to the drainage pipe or the gutter at the time of discharge 1 1 〇This agent also plays a role as a thickener 〇1 1 The detergent composition of the present invention contains About 6 "-about 10 parts by weight of diethylene glycol butadiene 1 I m as a thickener 0 thickener added to increase the internal The viscosity of the substance and the perceived effect of improving 1 I. If the amount of thickener is less than about 6 parts by weight, 1 I -1 2-1 1 1 can not be obtained. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 Mm) Printed by the Central Committee of the Ministry of Consumer Affairs, only printed by the F-cooperative Fifth, description of the invention (10 effect of increasing the degree) > if its maximum exceeds about 10 parts by weight, the f-viscosity becomes too high, which is not economical 〇The detergent composition of the present invention is adjusted to a pH of 7.1, that is, neutral 9 and applied to laundry items in the dispersed state of the oil-water emulsion 9 to reduce the magnification of the capillary phenomenon due to reduced interfacial tension 9 In order to reduce the damage of the male dimension. The male interface activator contained in the general cleaning agent mainly reacts in the m solution. However, for the cleaning composition of the present invention, although the solution maintains the pH 7 · 1 is neutral > but it can prevent the damage of protein dimension. And when comparing the washing using the test solution, the combined washing effect of the ionic interface activator and the solvent can increase the washing effect. According to the present invention Provide a method for washing laundry articles made of silk or wool using an automatic detergent composition in an automatic washing machine. Add the detergent composition to a washing tank with a rotating blade 9 and then introduce an appropriate amount of water to rotate the washing tank The scraper M dilutes the detergent composition. Add more water to the sink to adjust the water level to an appropriate amount for washing. Then put the laundry items made of wool or silk into the sink. 0 Rotate the scraper to generate water flow for washing. 〇 醑1 Α and 1B are flow charts that outline the -1, specific example of the washing method according to the present invention. 9 FIG. 2 is a block _ Gu Shixiao dragging the washing method of the present invention The structure of the clothes bundle 〇Μ under> using the above-mentioned cleaning agent sister t explains the method of washing the washing items made of wool or hide. The method of washing the laundry items made of wool (dry cleaning horizontal washing «process) (Please read the precautions on the back and then fill out this page) This paper size is applicable to the Chinese National Standard (CNS) Λ4 specification Π10Χ297 public order> 1 13 · Revision page, 1T Printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic and Consumer Affairs 2. Description of the invention (u) After turning on the power of the washing machine, put the detergent composition into the washing tank 100, and press the horizontal dry cleaning selection button on the key array part 170. When the microcomputer 200 receives a signal to select the dry cleaning mode from the array portion 170, the method of performing the dry cleaning process is implemented to wash laundry items. In particular, in the step of selecting the washing mode, the key array part 170 sends the dry-cleaning mode selection signal to the microcomputer 200 (S 3), which judges whether the water level reaches the first level (S s), Then send the water guide command signal to the drive member 160, K to open the water guide valve 1 2 0 (SB). Then, a small amount of washing water is introduced into the washing tank 100 through the water guiding pipe. When a person dilutes the appropriate amount of cleaning agent, the microcomputer 200 drives the motor 150 by the driving member 160 for a predetermined period of time * to rotate the rotary blade 1 10 at a low rotation speed. Due to the rotation of the rotary blade 110, a water flow M is generated to dilute the cleaning agent. At the same time, a predetermined amount of water is sequentially introduced into the washing tank 100 (SB). When an appropriate amount of water (at this time, the concentration of the cleaning agent is about 0.5g / l) is guided into the washing tank (S7) to complete the dilution of the cleaning agent, the detector 140 detects a sufficient amount of M to perform the washing step of the washing items The water level and send the signal to the microcomputer 200. Then, the microcomputer 200 sends the water guide stop command signal and the motor rotation stop command signal to the driving member 160 (S3). The driving member 160 closes the water guide valve 120 according to the water guide stop command signal, and stops the motor 150 so that the rotary blade 100 does not rotate any more. In addition, the microcomputer 200 determines that the washing mode is the dry-cleaning horizontal mode (S1D), and displays a signal to the display unit 180, so that the guide unit 180 displays "dry cleaning" (S ti), and sends a buzzer-generating signal to The speaker 1 9 0, K produces a buzzer on the speaker 1 9 0 (S, 3). When the user hears the buzzer (please read the notes on the back before filling this page)

The size of wood paper is suitable for tWW's home standard K'NS) ΜCurrent grid (210Χ2ί; 7 public power) 14 Amendment to print the A7 ____ B7 in the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs V. Invention description (12) ~, which will Laundry items are placed in the sink 100, and then the activation button of the array part 170 is pressed. The microcomputer 200 judges whether a start signal is input from the key array section 170 ($ 14). When the microcomputer 200 senses the start signal, the signal to perform the washing step is transmitted to the driving member to start the dry cleaning washing process. Within 1 minute, when the activation signal is not input from the key array part 170 to the microcomputer 200, the microcomputer 200 sends a buzzer generation signal to the speaker 190, and K generates another peak sound (Sis). In a state where the washing article is in the washing tank 100, when the start signal is applied, the driving member 160 drives the motor 150 to rotate the rotary blade 110 for a predetermined period of time. In particular, the rotary blade 110 rotates in the right direction for about 2 to 4 seconds, stands still for about 5 to 6 seconds, M rotates in the left direction for about 2 to 4 seconds, and then stands still for about 5 to 6 seconds, which is repeated as a cycle for a predetermined period of time Time (for example, about 6 minutes) M washing the washing items (Sie). When the washing step is completed, the microcomputer 200 sends a drain command signal to the driving member 160, which opens the drain valve 130 to discharge the washing water from the washing tank through the drain pipe. When the drainage is completed, the microcomputer 200 sends a water guiding command signal to the driving member 160. Then, the drain valve 130 is opened and closed, and the water guide valve 120 is opened to introduce fresh washing water into the washing tank 100, which is suitable for washing washing items. When the water guide is completed, the water guide valve 120 is closed and the motor 150 M is driven to rotate the rotary blade 110 for a predetermined period of time to generate a water flow suitable for washing the washing items (S17). K generates the water flow required for the washing step in the same manner as the washing step. That is, the rotary blade 1 1 0 K rotates in the right direction for about 2 to 4 seconds and stands still for about 5 to 6 seconds. It rotates in the left direction for about 2 to 4 seconds and then stands still for about 5 to 6 seconds. 15-_ This paper scale is applicable to the Zhongguanjia Standard (CNS) A4 specification (21GX297mm) " (Binding 丨 ji (please read the precautions on the back before filling this page) Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs Print A7 __B7 5. The description ring of the invention is continuously repeated for about 2 minutes. This cleaning step is performed twice, so that all the dirt (spots and detergent) left on the washing items are removed. When the cleaning step is completed, The microcomputer 200 sends a drain command signal to the driving member 160 to open the drain valve 130. Then, the washing water remaining in the wash 100 is drained, and the dehydration step starts. In the dehydration step, the microcomputer 200 applies a rotary blade 100 is mechanically combined with the washing tank 100, and then the driving motor 150M rotates the washing tank (S i B) at a rotation speed of about 100 ~ 150r.pm. The dehydration step is to rotate the washing tank 100 in the left or right direction for about 3 ~ 5 seconds, The static sink 100 is about 5 to 6 seconds, repeated about 7 times a Process, which includes the steps of (i) rotating the washing tank 100 in the left or right direction for about 2 ~ 3 seconds and (Π) stationary washing tank 100 for about 5 ~ 6 seconds, and then rotating the washing tank 1 in the left or right direction 0 0 takes about 1 to 3 seconds. When the dehydration step M is completed and the washing of the washing items is terminated, the microcomputer 200 generates a buzzer through the phone 190 to make the user pay attention. The completed washing is made of wool Washing method for washing items. Washing method for washing laundry items made of silk (silk washing mode washing process) The washing method shown in FIGS. 1A and 1B and the washing machine made of silk laundry items shown in FIG. 2 are used for washing The process is carried out as follows. The detergent composition M suitable for silk according to the present invention is introduced in an amount suitable for washing laundry items (St), and then presses the button (S2) for selecting the silk mode of the row portion 170 . When the microcomputer 200 receives this paper from the key array part 170, the paper size is applicable to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) —_ (please read the precautions on the back before filling out this page). βτ Μ Jing Manlang t Central Standards Bureau Beigong Consumer Cooperation Du System 85.12.1 θ ^ ;; jii. Year Λ _ V. Description of the invention (14) When the signal of the silk mode is selected, the method of performing the silk washing process is performed to wash laundry items made of green. In particular, in In the step of selecting the washing mode, the * array part 1 7 ○ sends the silk horizontal selection signal to the microcomputer 200 (S3), which judges that the moss water level reaches the first level (S5) and sends the water guide command signal to The driving member 160 M opens the water guide valve 120. Then * Introduce a small amount of washing water into the washing tank 100 through the water pipe (S s). When the optimum water for diluting the cleaning agent is introduced, the microcomputer 200 drives the motor 150 by the driving member 160 for a predetermined period of time, and K rotates the rotary blade 110 at a low rotation speed. Due to the rotation of the rotary blade 110, the water flow is generated with M diluted detergent (SB). At the same time, a predetermined amount of water is introduced into the washing tank 100 in sequence. 0 When an appropriate amount of water (at this time, the cleaning agent is approximately 0.5g / l) is introduced into the water tank and the cleaning agent is diluted, the detector 1 40 Detect the water level of the washing step of the washing items with one foot K and send the signal to the microcomputer 200 (S 7). Then, the microcomputer 200 sends the water guide stop command signal and the motor screw stop command signal to the drive member 160. The drive member 1 6 0 closes the water guide valve 1 2 0 according to the water guide stop command signal, and stops the motor 1 5 0 so that the rotary blade 1 0 0 does not rotate (S 3). In addition, the microcomputer 200 judges that the tub washing mode is the silk washing mode (S1D), and sends a display signal to the display 180, so that the display 180 displays "silk washing" (S12), and sends a buzzer-generating signal to The speaker 190 to generate a buzzer on the speaker 190 (S13). When the user hears the buzzing sound, he puts the laundry articles made of silk into the sink 100. Then presses the button array part 1 7 0 to start pressing the girl. Microcomputer 2 0 0 judge whether the start signal is from (please read the precautions on the back before filling this page)

This paper scale is applicable to China Valves National Elephants (C: NS) Λ4 specification (2 丨 0X297 gong) -17-Amended to buy this standard printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. The paper scale is applicable to the Chinese National Standard (CNS) A4 Specifications (210X297mm) A7 B7 5. Description of the invention (1Γ〇 key array part 170 input. When the microcomputer 200 senses the start signal (S14), the signal of the washing step is transmitted to the driver 160, M start Silk washing process. Within 1 minute, when the start signal is not input to the microcomputer 200 from the key array part 170, the microcomputer 200 sends a buzzer generation signal to the speaker 190, and M generates another buzzer (S15 ). In the state where the washing article is in the washing tank 100, when the start signal is applied, the driving member 160 drives the motor 150 to rotate the rotary blade 110 for a predetermined period of time. In particular, the rotary blade 1 10 Μ right The direction rotates for about 0.3 ~ 0.5 seconds, the rest is about 5 ~ 6 seconds, the left direction rotates for about 0.3 ~ 0.5 seconds, and then rests for about 5 ~ 6 seconds, which is repeated as a cycle for a predetermined time (For example, about 4 minutes) K washing Products (S1G). Washing items made of silk will not sink into the washing water, but will float above the washing water. In the traditional washing machine, a rotating water flow is generated. It is not related to the type of fabric of the washing item. In this case * When rotating water is generated for a long time, the washing items sink due to the rotating water flow and come into contact with the bottom of the rotating blade 110 or the sink 100. Therefore * the washing items are damaged. However, in this specific example, the rotating blade is Rotate for about 0.3 ~ 0.5 seconds. Then, the washing items sink to the lower part of the washing water and are washed due to the rotating friction. However, because the water flow is generated for a short time, the washing items will not be separated from the rotary blade 110 or the sink 100. The bottom is in contact, even if the washing items sink into the washing water. Therefore, the washing items are not damaged. After rotating the rotary blade 1 1 0 for about 0.3 ~ 0.5 seconds, the rotary blade 11 0 is still for about 5 ~ 6 At this time, the pressure generated by the rotating water flow is reduced, and the washing items sinking due to the rotating water flow rise to the washing water table Μ- (please read the precautions on the back before filling this page ) Installation--a Printed by the Ministry of Economy Central Standards Bureau Employee Consumer Cooperatives 150 A7 B7 V. Description of the invention (jf,). In this state, the rotary blade 110K rotates in the reverse direction of M to produce a rotating water flow. Then, The washing items sink again and are washed due to the rotational friction of the water flow. When the washing step is completed, the microcomputer 200 sends a drain command signal to the driving member 160, which opens the drain valve 130M to drain the washing water from the washing tank through the drain pipe. When the drainage is completed, the microcomputer 200 sends a water guide command signal to the driving member 160. Then, the drain valve 1 3 0 is opened and closed, and the water valve 1 2 0 'M is opened to introduce fresh washing water into the washing tank 100, which is suitable for washing laundry. When the water guide is completed, the water guide valve 120 is closed and the motor 150 is driven to rotate the rotary blade 110 for a predetermined period of time. K generates a water flow suitable for washing the washing items to generate the water flow required for the washing step in the same manner as the washing step. That is, 'rotating blade 11 〇M rotates in the right direction for about 0.3 ~ 0.5 seconds', stands still for about 5 ~ 6 seconds 'Μ rotates in the left direction for about 0.3 ~ 0.5 seconds, and then stands still for about 5 ~ 6 seconds' The cycle is repeated continuously for about 2 minutes (S17) ° This cleaning step is performed twice, so that all dirt (spots and detergents) remaining on the washing items are removed. When the cleaning step is completed, the microcomputer 200 sends a drain command signal to the driving member 160, and K opens the drain valve 130. Then, the washing water remaining in the washing tank 100 is discharged, and the dehydration step starts. In the dehydration step, the microcomputer 200 mechanically combines the rotary blade 100 with the sink 100, and then drives the motor 150W to rotate the sink at a speed of about 100 ~. The paper size is applicable to the Chinese National Standard (CNS) A4 size (210X297mm) 19 (Please read the notes on the back before filling this page)

A7 B7 Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of the invention (Γ η J The dehydration step is M. Rotate the washing tank 100 in the left or right direction for about 35 seconds, and the static I 1 washing tank 1 0 0 for about 5 6 seconds. Repeat period] 7 times a process 9 which includes the steps of 1 1 (ί) Μ left or right direction no & tank 1 00 about 2 ~ 3 seconds and (ii) still washing tank /-SI 10 0 about 5 After 6 seconds, the left or right side (6) rotate the washing tank 100 for about 1 to 3 seconds and please read 1 first 1 (S 1 Θ) 0 璜 背 1 side I When 7C becomes a dehydration step to terminate the washing items When washing »Microcomputer 1 I * 1 I 20 0 generates a buzzer 9 through the phone 190 to make the user pay attention to this accomplishment 1 I again. 1 washing method for washing washing items made of silk 0 polyester Fill% This package consists of using the cleaning agent of the present invention The advantages obtained by the method of washing laundry articles according to the present invention '-^ 1 I products are as follows: 0 1 1 1 The first high-grade clothes can be washed with water. Generally only dry-cleaning is made of wool Λ silk 1 regenerated cellulose fibers, etc. The armpits of the finished clothes can be washed in water at home. 1 The second protein-based stains can be removed. 0 The dry protein-based stains that cannot be removed can be completely removed by adding protease. 1 1 Water-insoluble inorganic materials can be removed. The water-insoluble dirt removed by dry cleaning can be removed by washing with water. No. 1 Ivv. Fourth, the strong washing capacity of the fat stains available. White human skin m And 1 1 fatty acid glyceride fatty soil that becomes the main dirt on the fiber can be borrowed from 1 1 Gui non-ionic interface activator and organic solvent The emulsion can be removed more effectively than water washing using traditional I 1 1 surface activators or dry cleaning using solvents. [Fifth> This can reduce costs. Household laundry with water is convenient and hygienic and economical. 1 1 The following is a detailed description of the preferred embodiments of the present invention. However, the present invention is not limited by these I and other embodiments. The paper size is applicable to the Chinese National Sample Standard (CMS) A4 specification (210X 297 mm) A7 7 Β Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of the invention (丨 ⑴ Examples 1 to 5 The cleaning agent composition is a mixture of non-ionic interfacial activator of bay laurel, n-decane is n-alkane, alkylene It is prepared for unsaturated aromatic hydrocarbon, tetraalkylammonium chloride, protease, lipase, carboxymethyl cellulose and diethylene glycol butyl ether, as shown in Table 1. Table 1 Examples Ingredients 1 2 3 4 5 Lauryloxyethylene 23 20 15 15 19 Coconut fatty acid alkanolamide 5 5 5 7 11 _f n-decane 18 12 20 14 16 Phenene 9 6 10 7 8! Tetrachloride Yard saddle 0.3 0.5 0.6 0.4 0.7 Protease 0.7 0.5 .5 0.2 0.3 0.6 Lipase 0.7 0.5 0.8 0.6 0.3 Carboxymethorphan 0.4 0.5 0.3 0.7 0.6 Dibutyl glycol 6 10 8 7 9 Water 36.9 45 40.1 41 34.8 Comparative example 1 Preparation of commercially available laundry detergents, hydrocarbon solvents in full atmosphere ethylene, and cylindrical washing machines for dry cleaning. Comparative Example 2 Dry-senka (model name: manufactured by Japan Inter Orion) was prepared on the market. Shrinkage test to prepare pure laundry samples of 30απ width and 40cm length and 20αη width and 30αη length. The paper size is applicable to China National Standard (CNS) A4 specification (210X 297mm) (please read the precautions on the back before filling this page ) Case

I ^^ tG7〇 A7 Β7 Fifth, the invention description (1 Η) pure wool laundry sample. These samples were cleaned by the dry cleaning mode and the silk washing horizontal washing process using the detergent compositions according to Examples 1 to 5 and Comparative Example 2. For the washing machine, use DWF-6650F (trade name; manufactured by Dae Woo Electronics Co., Ltd., Korea), and wash by the above dry cleaning mode and silk washing mode. The water level in the washing machine was adjusted to the standard water level of 591 and the amount of detergent used was 29.5g. In addition, the samples were washed with the cleaning agent of Comparative Example 1 by a traditional dry cleaning method in a laundromat. After the samples used the detergent compositions of Examples 1 to 5 and Comparative Example 2 and used the above-mentioned laundry process, and the other samples were washed with the detergent composition and solvent of Comparative Example 1 according to the traditional dry-cleaning process, various samples were not creped The bottom is placed in a cool and smooth place and naturally dried. Measure the length and width of the sample and calculate the shrinkage according to the following equation (1). Shrinkage (¾) = length before washing-length after washing X 100 (please read the precautions on the back before filling in this page). Installed. -S ° Printed by Employee Consumer Cooperative of Central Bureau of Standards, Ministry of Economic Affairs (1) Washing The result of the previous length is τρ: in Table 2 Table 2 Example Example 1 Example 2 〇〇〇〇ο ο kkik ο ο k ο ο 1 k ο ο k ο ο k 22 This paper size is suitable for Chinese national standards (CNS) A4 specification (210X 297mm) 5. Description of the invention (20)

丄 刀 * 丨 " ...... " fa W 0 0 0 0 0 0 1 0 0 0 0 1 1 0 Λ 7 5 7 1 8 3 1 1 9 8 8 4 3 8 • 7 6 9 7 5 Ί 5 7 0 5 1 2 5 5 L 0 ϋ 0 1 0 1 0 2 2 1, 1 2 2 2 A 5 0 5 5 7 8 9 1 0 9 5 7 1 1 • 4 4 2 0, 4 0 0 7 9 5 0 3 0 8 DuPont Printing by the National Bureau of Standards of the Ministry of Economic Affairs *. In Table 2, W. A. represents the shrinkage rate for width measurement and L. A. represents the shrinkage rate for fear measurement. As can be seen from Table 2, the shrinkage rate of silk or wool laundry articles obtained by washing with the detergent composition of the present invention is similar to that obtained by dry-cleaning washing in an automatic laundry. Test of washing ability (1) Preparation of contaminated hoe prepared silk or wool with initial reflectivity of 70,0, and cut into 15αη X 20ca 丨 size. In a 50ml container, add 0.5 ~ 0.8g of hardened oil (melting point; 57T: or above M, iodine value; 3 or less, saponification value; 90 ~ 93) and flowing paraffin. Then, add lamp black to it, and use an oil rod to stir the mixture evenly for a predetermined time or number of times. The resulting mixture was dispersed in 800 g of carbon tetrachloride into 1,1,1-trioxane to contaminate the liquid hip. In a dyeing bath of 15cfflX20cm, add 400g of contaminated liquid and keep it at a temperature of 15 ~ 30T :. The cutting object was contaminated for 60 seconds, and at the same time it was properly turned on the object. Adjust the lamp black to reflect the reflectance of the suspect 30% 2% 〇 (2) Measure the reflectance (Jing first read the precautions on the back and fill this page)

• L —The size of the revised paper is applicable to the Chinese National Standard (CNS) Λ4 specification (210X 297 public money) -23 revised page station, Fu Zheng k month _ · g ~-V. Description of invention (21) _ supplementary use of photometer, Light retroreflectometer, spectral photometric calculation, using 510 ~ 5 5 Onm wavelength to measure the reflectivity on the surface of the fabric. The reflectance of the vaporized magnesium whiteboard is regarded as 100¾, and the reflectance of the black body is regarded as 0%. The reflectance of the contaminated fabric is measured at two positions on each front side and rear side. All four reflectances are measured, and the average value is regarded as the reflectance of the fabric. (3) Washing of contaminated fabrics The contaminated hoe was prepared as a sample, and the detergent compositions of Examples 1 to 5 and Comparative Example 2 were used and washed in the dry cleaning mode and the silk washing horizontal washing process. For the washing machine, DWF-6650F (trade name; manufactured by Korea Daewoo Electronics Co., Ltd.) was used, and the samples were washed in the above dry cleaning mode. The water level was adjusted to the level of 5 9 1 wash, the amount of detergent used was 29.5 g. In addition, the detergent and solvent of Comparative Example 1 were used in a launderette to wash the samples by the dry cleaning method. Printed by the Consumer Labor Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions before filling in this page) After washing, the detergent compositions of Examples 1 to 5 and Comparative Example 2 will be used and the above washing method will be used The washed samples, together with other samples washed by the conventional dry-cleaning method using the detergent composition of Comparative Example 1 were placed in a cool and smooth place without creases, and allowed to dry naturally. Measure the reflectance of the washed tear and calculate the washing capacity according to the following equation (2). Washing capacity (ί!) = Reflectance U) before washing — Reflectance U) after washing x 100 Reflectance of the original village (3;)-Reflectance U before washing) (2) The result It is shown in Table 3. The paper size is suitable for the Chinese National Standard (CNS) Λ4 specification (210X 297 mm). 24-Amendment Page A7 B7 Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy. V. Invention Instructions (U) Table 3 Implementation Example 1 2 3 4 5 Comparative Example 1. Comparative Example 2 wswswswswswsws 〇i 0 i 0 i O ioi O ioio 1 o 1 o 1 o 1 o 1 o 1 o 1 1 k 1 k 1 k 1 k 1 k 1 k 1 k R 2 3 3 3 2 3 2 3 2 3 2 3 2 3 * 8 1 1 1 7 0 9 0 8 1 8 1 8 0 B • • • • • • • • • • • • • • • 3 4 5 7 9 7 6 0 8 8 9 4 6 2 R 3 4 4 4 3 4 3 3 3 4 3 4 3 3 • 7 1 1 1 7 0 8 9 8 1 8 1 7 9 A ί 5 4 5 8 3 3 5 7 2 6 7 8 4 7 W 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 • 2 1 1 1 3 1 0 2 2 0 3 3 0 1 A • 5 8 7 8 6 2 0 3 6 8 9 1 7 4 (Please read the precautions on the back before filling out this page) National standard (CNS) A4 specification (210X297mm) 24a Α7 Β7 5. Description of invention (ϋ) * In Table 3, RB represents the reflectance before washing 'RA · represents the reflectance after washing and catching, WA represents the washing ability . As can be seen from Table 3, when compared with the traditional dry cleaning of a laundromat, the similar washing ability of laundry articles made of silk or wool can be obtained by using the detergent composition of the present invention. In addition, since the cleaning agent composition of the present invention includes a nonionic interface activator with good washing ability, no insoluble salt is generated, even when a pipe is used for water supply. In the case of washing laundry articles made of silk or wool using the detergent composition of the present invention, the same effect as the conventional washing situation of an automatic laundry shop can be obtained in terms of shrinkage and washing ability. Therefore, 'when the cleaning composition of the present invention is used, simple washing without damaging the fibers' can be obtained, and therefore cost can be saved. In addition, the unhealthy problem of washing with other laundry items in the sink can also be solved, and a clean and satisfactory wearing can be achieved. (Please read the precautions on the back and then fill out this page) Clothing., Βτ Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy This paper scale is applicable to the Chinese National Standard (CNS) Α4 specification (2 丨 0X297mm)

Claims (1)

3〇tG? 〇; ν i, mouth this Λ8 B8 C8 D8 85.12. 1 4 Amendments to the patent scope of this application Group of cleansing type liquid emulsion / oil fabrics for making wool or silk polyester: washing seed packs 1. 1. fabrics for dissolving hydrocarbons to wash the supplied ene ^ 0 agent π J and the surface of the alkane boundary chain is separated from the non-contained portion of the amount of BB 華 望 8 agent is Η Ρ; in ammonium and its four enzyme whitening; Chlorine egg moisture content ft eR 8 fi 3 Over 8 7 7 ΠΟΤΗ · Keep the price and the vitamin weight; the carboxylase of the cellulase-based fatty methyl ester is heavy (please read the precautions on the back and then fill out this page) Finishing of oil clothes. Items of washing with wool or silk. 11th Fan Li, please ask as little as possible. The group of the living group of the agent group is separated from the amine and the amine is not _ this yeast in the guiqiyue 'and the material ene into the group B gas agent alcohol Jiegui yueyue plastic selection of milk and water from the liquid 1 item of the first range Li Zhuan asked for the production of wool or silk polyester as a clothing agent. The cleansing type liquid emulsion is added with alkene 0. The alkane chain is among the central standards of the Ministry of Economic Affairs. The printed paper is of the same size as the national standard (CNS) Λ4 specification (210X297mm)