JPH0234693A - Powdery detergent composition for clothing - Google Patents
Powdery detergent composition for clothingInfo
- Publication number
- JPH0234693A JPH0234693A JP18317488A JP18317488A JPH0234693A JP H0234693 A JPH0234693 A JP H0234693A JP 18317488 A JP18317488 A JP 18317488A JP 18317488 A JP18317488 A JP 18317488A JP H0234693 A JPH0234693 A JP H0234693A
- Authority
- JP
- Japan
- Prior art keywords
- cyclodextrin
- fatty acid
- weight
- detergent composition
- clothing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003599 detergent Substances 0.000 title claims abstract description 25
- 239000000203 mixture Substances 0.000 title claims abstract description 21
- -1 fatty acid salt Chemical class 0.000 claims abstract description 21
- 229920000858 Cyclodextrin Polymers 0.000 claims abstract description 17
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 11
- 239000000194 fatty acid Substances 0.000 claims abstract description 11
- 229930195729 fatty acid Natural products 0.000 claims abstract description 11
- 150000005215 alkyl ethers Chemical class 0.000 claims abstract description 8
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 7
- 239000000843 powder Substances 0.000 claims description 12
- 239000003945 anionic surfactant Substances 0.000 claims description 3
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 abstract description 5
- 239000001116 FEMA 4028 Substances 0.000 abstract description 3
- 125000000129 anionic group Chemical group 0.000 abstract description 3
- 239000002585 base Substances 0.000 abstract description 3
- 235000011175 beta-cyclodextrine Nutrition 0.000 abstract description 3
- 229960004853 betadex Drugs 0.000 abstract description 3
- 239000004094 surface-active agent Substances 0.000 abstract description 3
- 229910052783 alkali metal Inorganic materials 0.000 abstract description 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract description 2
- 150000004671 saturated fatty acids Chemical class 0.000 abstract description 2
- 150000003333 secondary alcohols Chemical class 0.000 abstract description 2
- 150000003138 primary alcohols Chemical class 0.000 abstract 1
- 239000000344 soap Substances 0.000 description 9
- 238000005406 washing Methods 0.000 description 9
- 239000007788 liquid Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000006260 foam Substances 0.000 description 4
- 238000005187 foaming Methods 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000007850 fluorescent dye Substances 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 229920001450 Alpha-Cyclodextrin Polymers 0.000 description 1
- 108091005658 Basic proteases Proteins 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- HFHDHCJBZVLPGP-RWMJIURBSA-N alpha-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO HFHDHCJBZVLPGP-RWMJIURBSA-N 0.000 description 1
- 229940043377 alpha-cyclodextrin Drugs 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000012000 cholesterol Nutrition 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- PMPJQLCPEQFEJW-GNTLFSRWSA-L disodium;2-[(z)-2-[4-[4-[(z)-2-(2-sulfonatophenyl)ethenyl]phenyl]phenyl]ethenyl]benzenesulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC=CC=C1\C=C/C1=CC=C(C=2C=CC(\C=C/C=3C(=CC=CC=3)S([O-])(=O)=O)=CC=2)C=C1 PMPJQLCPEQFEJW-GNTLFSRWSA-L 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000002979 fabric softener Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 125000000075 primary alcohol group Chemical group 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は衣料用粉末洗浄剤組成物に関し、詳しくは、す
すぎ性が著しく改良された衣料用粉末洗浄剤組成物に関
する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a powder detergent composition for clothing, and more particularly to a powder detergent composition for clothing with significantly improved rinsability.
［従来の技術及び発明が解決しようとする課題１日本に
おける衣料用粉末洗浄剤には起泡性が要求されているた
め、従来より主界面活性剤としてアニオン界面活性剤が
使われてきた。近年全自動洗濯機の普及が目覚しい。全
自動洗濯機に従来の高起泡性洗剤を使うと洗濯時に泡が
あふれることがある。また従来の洗濯機の場合すすぎ液
の濁りを目で確認しすすぎの完了を確認しているが、全
自動洗濯機の場合このような確認がされない為、中〜低
泡性であり、かつすすぎ性の良好なアニオン洗剤が要求
されてきた。[Prior art and problems to be solved by the invention 1 Since powder detergents for clothing in Japan are required to have foaming properties, anionic surfactants have traditionally been used as the main surfactant. In recent years, the spread of fully automatic washing machines has been remarkable. If you use a conventional high-foaming detergent in a fully automatic washing machine, foam may overflow during washing. In addition, in conventional washing machines, the completion of rinsing is confirmed by visually checking the turbidity of the rinsing liquid, but in the case of fully automatic washing machines, this kind of confirmation is not performed, so the rinsing liquid is medium to low foaming, and the rinsing is completed. There has been a demand for anionic detergents with good properties.
この課題を解決するため現在の粉末洗剤にはシリコーン
又は石けん等の消泡剤が配合されている。シリコーンは
少量の添加で効果があるが、コストの問題及び油性であ
るため粉末物性を損なうなど使いにくい面があり、石け
んが主として使われている。To solve this problem, current powder detergents contain antifoaming agents such as silicone or soap. Silicone is effective when added in small amounts, but it is difficult to use due to its cost and oily nature, which impairs the physical properties of the powder, so soap is mainly used.
石けんは良好な抑泡効果を示すが、すすぎ性の面では必
らずしも充分と言えなかった。Soaps exhibit good foam-inhibiting effects, but they are not always sufficient in terms of rinsability.
本発明者らは上記の課題を解決すべく鋭意研究の結果、
石けん（高級脂肪酸塩）とともに特定のノニオン界面活
性剤とサイクロデキストリンを併用して用いればすすぎ
性が著るしく改良されることを見出し本発明を完成した
。As a result of intensive research by the present inventors to solve the above problems,
We have completed the present invention by discovering that rinsing properties can be significantly improved by using a specific nonionic surfactant and cyclodextrin together with soap (higher fatty acid salt).
即ち、本発明は、合成アニオン界面活性剤を主洗浄基剤
とする衣料用粉末洗浄剤組成物において、
（ａ） 高級脂肪酸塩 １〜６重量％（ｂ） ポリ
オキシエチレン（エチレンオキサイトノ平均付加モル数
８〜２０）アルキルエーテル０．５〜６重量％、および
（ｃ） サイクロデキストリン ０．１〜５重量％を
含有することを特徴とする衣料用粉末洗浄剤組成物を提
供するものである。That is, the present invention provides a powder detergent composition for clothing having a synthetic anionic surfactant as the main detergent base, (a) higher fatty acid salt 1 to 6% by weight (b) polyoxyethylene (average ethylene oxide The present invention provides a powder detergent composition for clothing, characterized in that it contains (additional mole number: 8 to 20) 0.5 to 6% by weight of alkyl ether, and (c) 0.1 to 5% by weight of cyclodextrin. be.
本発明に用いられる高級脂肪酸塩としては、平均炭素数
１０〜２０、好ましくは１６〜１８の飽和又は不飽和脂
肪酸のアルカリ金属塩等が挙げられる。洗浄剤組成物中
の高級脂肪酸塩の配合量が１重量％未満では充分な抑泡
すすぎ効果が得られず、６重量％を越えると洗濯衣類に
つく石けん臭を抑制できない。高級脂肪酸塩を約３重量
％以上配合すると洗濯衣類に石けん臭がつく傾向がある
が、本願発明の洗浄剤組成物では臭気包接能を有するサ
イクロデキストリンを併用しているので６重量％までで
あれば充分に石けん臭を抑制できる。Examples of higher fatty acid salts used in the present invention include alkali metal salts of saturated or unsaturated fatty acids having an average carbon number of 10 to 20, preferably 16 to 18. If the amount of higher fatty acid salt in the detergent composition is less than 1% by weight, a sufficient foam-inhibiting rinsing effect cannot be obtained, and if it exceeds 6% by weight, soap odor on washed clothes cannot be suppressed. If higher fatty acid salts are added in an amount of about 3% by weight or more, washed clothes tend to have a soap odor, but since the detergent composition of the present invention also uses cyclodextrin, which has odor inclusion ability, it can be added up to 6% by weight. This will be sufficient to suppress soap odor.
本発明に用いられる（ｂ）成分のポリオキシエチレン（
エチレンオキサイド平均付加モル数８〜２０）アルキル
エーテルとしては、炭素数８〜１８の１級又は２級アル
コールにエチレンオキサイドを平均８〜２０モル付加さ
せたノニオン界面活性剤が挙げられる。エチレンオキサ
イドの平均付加モル数が８モル未満ではすすぎ性改良効
果が乏しく、２０モルを越えると洗剤製造上の不都合を
生ずる。ポリオキシエチレン（エチレンオキサイド平均
付加モル数８〜２０）アルキルエーテルは本発明の洗浄
剤組成物中に０．５〜６重量重量合される。配合量が０
．５重量％未満であるとすすぎ性の改良効果が乏しく、
６重量％を越えると泡ぎれが悪くなってしまう。The polyoxyethylene (b) component used in the present invention (
Average number of moles of ethylene oxide added: 8 to 20) Examples of the alkyl ether include nonionic surfactants in which an average of 8 to 20 moles of ethylene oxide is added to a primary or secondary alcohol having 8 to 18 carbon atoms. If the average number of moles of ethylene oxide added is less than 8 moles, the effect of improving rinsing properties will be poor, and if it exceeds 20 moles, problems will arise in detergent production. The polyoxyethylene (average number of added moles of ethylene oxide 8 to 20) alkyl ether is incorporated in the cleaning composition of the present invention in an amount of 0.5 to 6 by weight. Blend amount is 0
．． If it is less than 5% by weight, the effect of improving rinsing properties will be poor;
If it exceeds 6% by weight, foaming will become worse.
本発明に用いられるサイクロデキストリンとしてはβ−
サイクロデキストリン、メチル化βサイクロデキストリ
ンの如きβ−サイクロデキストリン誘導体、α−サイク
ロデキストリン、Ｔ−サイクロデキストリンなどが挙げ
られる。The cyclodextrin used in the present invention is β-
Examples include cyclodextrin, β-cyclodextrin derivatives such as methylated β-cyclodextrin, α-cyclodextrin, and T-cyclodextrin.
就中β−サイクロデキストリンが好ましい。サイクロデ
キストリンは本発明の洗浄剤組成物中に０．１〜５重量
％、好ましくは１．０〜３．０重量％配合される。サイ
クロデキストリンの配合量が０．１重量％未満であると
石けん臭を充分に抑制することができず、また５重量％
を越えると経済的に不利である。サイクロデキストリン
は粉体として、又は増量剤、バインダーなどと共に造粒
して用いることができる。なお、サイクロデキストリン
は液体香料を包接させて用いても本発明の目的は充分達
成され、また、そのようにして用いた方が石けん臭マス
キングの効果も期待できる。Among these, β-cyclodextrin is preferred. Cyclodextrin is blended in the cleaning composition of the present invention in an amount of 0.1 to 5% by weight, preferably 1.0 to 3.0% by weight. If the amount of cyclodextrin is less than 0.1% by weight, soap odor cannot be sufficiently suppressed, and if the amount of cyclodextrin is less than 0.1% by weight,
Exceeding this is economically disadvantageous. Cyclodextrin can be used in the form of a powder or in the form of granules together with fillers, binders, and the like. Note that the object of the present invention can be sufficiently achieved even when cyclodextrin is used with a liquid fragrance included therein, and the effect of masking soap odor can also be expected by using it in this way.
本発明の洗浄剤組成物において、その他の洗剤組成は特
に限定されるものではないが、日本における洗剤は一般
にアルキルベンゼンスルホン酸ソーダ、アルキル硫酸ソ
ーダ、オレフィンスルホン酸ソーダ、アルキルエーテル
硫酸ソーダなどのアニオン界面活性剤１０〜５０重量％
、炭酸ソーダ、珪酸ソーダ、硫酸ソーダ及びゼオライト
などの無機ピルグー類３０〜８０重量％、及びポリエチ
レングリコール、カルボキシメチルセルロースなどの再
汚染防止剤、螢光染料、酵素、香料からなっており、ま
た漂白洗剤では過炭酸塩、過硼素酸塩、柔軟洗剤ではジ
長鎖アルキル型第４級アンモニウム塩が添加されている
が、本発明の洗浄剤組成物もこのような配合とすること
ができる。In the detergent composition of the present invention, other detergent compositions are not particularly limited, but detergents in Japan generally contain anionic materials such as sodium alkylbenzene sulfonate, sodium alkyl sulfate, sodium olefin sulfonate, and sodium alkyl ether sulfate. Activator 10-50% by weight
, 30 to 80% by weight of inorganic pilates such as soda carbonate, sodium silicate, sodium sulfate, and zeolite, anti-recontamination agents such as polyethylene glycol and carboxymethyl cellulose, fluorescent dyes, enzymes, fragrances, and bleaching detergents. Although percarbonate, perborate, and di-long chain alkyl type quaternary ammonium salt are added to the fabric softener, the detergent composition of the present invention can also be formulated in this manner.
以下に実施例を挙げて本発明を説明するが、本発明はこ
れらの実施例に限定されるものではない。The present invention will be described below with reference to Examples, but the present invention is not limited to these Examples.
尚、例中の部、％はそれぞれ重量基準である。Note that parts and percentages in the examples are based on weight.
実施例１
下記組成の粉末洗浄剤組成物を用いて、下記方法により
すすぎ性の評価を行った。Example 1 Rinseability was evaluated by the following method using a powder cleaning composition having the composition shown below.
結果を表＝１に示す。The results are shown in Table 1.
〈粉末洗浄剤組成物〉
ドデシルベンゼンスルホン酸ソーダ １６％ポリオ
キシエチレンアルキルエーテル 表−１高級脂肪酸塩１
１ 表−１β−サイクロデキス
トリン０ 表−１炭酸ソーダ
１０．０％２号珪酸ソーダ
７．５％４Ａ型ゼオライト
３０．０％硫酸ソーダ バ
ランスポリエチレングリコール（ＭＷ ６０００）
１．０％カルボキシメチルセルロース
１．２％螢光染料（チノパールＣＢＳ）
０．３％酵素（アルカリプロテアーゼ）１．０％水分
４．５％＊ｌ：高級脂
肪酸塩
硬化牛脂アルキル脂肪酸ソーダ
傘２二日本食品加工株式会社製
セルデックスＮ
くずすぎ性評価法〉
装 置：洗濯機 東芝製銀河２．２ ｋｇ実験条件：
洗剤濃度： ０．１３３％
水温：２０°Ｃ
使用水：水道水 ４０リツトル
浴 比： １ ／２５（Ｔ／Ｃワイシャツ６４０ ｇ
、綿肌着９６０ｇ）
汚 れ：モデル汚れ ３．２ｇ
（組成）
綿実油 ６０％
コレステロール １０％
オレイン酸 １０％
パルミチン酸 １０％
液体及び固体パラフィン １０％
実験手順：
ｌ）洗濯機に水４０リットルをいれる。<Powder cleaning composition> Sodium dodecylbenzenesulfonate 16% polyoxyethylene alkyl ether Table 1 Higher fatty acid salt 1
1 Table-1 β-cyclodextrin 0 Table-1 Sodium carbonate
10.0% No. 2 Sodium Silicate
7.5% 4A type zeolite
30.0% Sodium Sulfate Balanced Polyethylene Glycol (MW 6000)
1.0% carboxymethyl cellulose
1.2% fluorescent dye (Tinopal CBS)
0.3% enzyme (alkaline protease) 1.0% water
4.5%*l: Higher fatty acid salt cured beef tallow alkyl fatty acid soda Umbrella 22 Celldex N manufactured by Nippon Shokuhin Kako Co., Ltd. Evaluation method for rinsing property> Equipment: Washing machine Toshiba Galaxy 2.2 kg Experimental conditions: Detergent concentration : 0.133% Water temperature: 20°C Water used: Tap water 40 liter bath Ratio: 1/25 (T/C shirt 640 g
, cotton underwear 960g) Soil: Model stain 3.2g (Composition) Cottonseed oil 60% Cholesterol 10% Oleic acid 10% Palmitic acid 10% Liquid and solid paraffin 10% Experimental procedure: l) Pour 40 liters of water into the washing machine.
２）洗剤を投入し、３分間撹拌する。2) Add detergent and stir for 3 minutes.
３）衣類とモデル汚れを入れ、洗濯を開始する。3) Add the clothes and model dirt and start washing.
４）洗濯を５分間行う。4) Wash for 5 minutes.
５） 排水しながら、洗濯物を脱水槽に移し、１分間脱
水する。洗濯槽をよく洗い泡を流す。5) While draining the water, transfer the laundry to the dehydration tank and spin it for 1 minute. Wash the washing tub thoroughly and remove the suds.
６） すすぎ水を４０リットル入れ、洗濯物をほぐして
加える。6) Pour 40 liters of rinse water, loosen the laundry and add.
７）３分撹拌し、泡ですすぎ性を評価する。7) Stir for 3 minutes and evaluate rinsing properties with foam.
８） ５）、６）、７）をもう１回繰り返す。8) Repeat steps 5), 6), and 7) one more time.
すすぎ性評価： ５ 液面全体に泡が残る ４ 液面に２程度の泡が残る ３ 液面に２程度の泡が残る ２ 液面に細かい泡が残る ｌ 泡がないRinseability evaluation: 5 Bubbles remain on the entire liquid surface 4 Approximately 2 bubbles remain on the liquid surface 3 Approximately 2 bubbles remain on the liquid surface 2 Fine bubbles remain on the liquid surface l No bubbles
Claims (1)
粉末洗浄剤組成物において、 （ａ）高級脂肪酸塩１〜６重量％ （ｂ）ポリオキシエチレン（エチレンオキサイドの平均
付加モル数８〜２０）アルキルエーテル０．５〜６重量
％、および （ｃ）サイクロデキストリン０．１〜５重量％を含有す
ることを特徴とする衣料用粉末洗浄剤組成物。[Scope of Claims] 1. A powder detergent composition for clothing containing a synthetic anionic surfactant as the main detergent base, comprising: (a) 1 to 6% by weight of a higher fatty acid salt; (b) polyoxyethylene (of ethylene oxide); A powder detergent composition for clothing, characterized in that it contains (average added mole number: 8 to 20) 0.5 to 6% by weight of an alkyl ether, and (c) 0.1 to 5% by weight of cyclodextrin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63183174A JP2513794B2 (en) | 1988-07-22 | 1988-07-22 | Powder detergent composition for clothing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63183174A JP2513794B2 (en) | 1988-07-22 | 1988-07-22 | Powder detergent composition for clothing |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0234693A true JPH0234693A (en) | 1990-02-05 |
| JP2513794B2 JP2513794B2 (en) | 1996-07-03 |
Family
ID=16131074
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63183174A Expired - Fee Related JP2513794B2 (en) | 1988-07-22 | 1988-07-22 | Powder detergent composition for clothing |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2513794B2 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998013456A1 (en) * | 1996-09-26 | 1998-04-02 | Henkel-Ecolab Gmbh & Co. Ohg | Washing or laundering post-treatment agents |
| WO1998050511A1 (en) * | 1997-05-05 | 1998-11-12 | Henkel Kommanditgesellschaft Auf Aktien | Method for preventing colours from running in textiles during washing |
| EP0878334A1 (en) | 1997-05-12 | 1998-11-18 | Firma Muhr und Bender | Stabilizer |
| WO2001018163A1 (en) * | 1999-09-03 | 2001-03-15 | The Procter & Gamble Company | Detergent composition having granular cyclodextrin |
| WO2001016265A3 (en) * | 1999-09-02 | 2001-10-11 | Procter & Gamble | Methods for odor control and concentrated, non-liquid compositions therefor |
| WO2001088076A1 (en) * | 2000-05-15 | 2001-11-22 | The Procter & Gamble Company | Compositions comprising cyclodextrin |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55102411A (en) * | 1978-09-09 | 1980-08-05 | Procter & Gamble | Composition for inhibiting foaming and detergent containing said composition |
-
1988
- 1988-07-22 JP JP63183174A patent/JP2513794B2/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55102411A (en) * | 1978-09-09 | 1980-08-05 | Procter & Gamble | Composition for inhibiting foaming and detergent containing said composition |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998013456A1 (en) * | 1996-09-26 | 1998-04-02 | Henkel-Ecolab Gmbh & Co. Ohg | Washing or laundering post-treatment agents |
| WO1998050511A1 (en) * | 1997-05-05 | 1998-11-12 | Henkel Kommanditgesellschaft Auf Aktien | Method for preventing colours from running in textiles during washing |
| EP0878334A1 (en) | 1997-05-12 | 1998-11-18 | Firma Muhr und Bender | Stabilizer |
| EP0878334B1 (en) * | 1997-05-12 | 2003-09-24 | Firma Muhr und Bender | Stabilizer |
| WO2001016265A3 (en) * | 1999-09-02 | 2001-10-11 | Procter & Gamble | Methods for odor control and concentrated, non-liquid compositions therefor |
| WO2001018163A1 (en) * | 1999-09-03 | 2001-03-15 | The Procter & Gamble Company | Detergent composition having granular cyclodextrin |
| US6881712B2 (en) | 1999-09-03 | 2005-04-19 | The Procter & Gamble Company | Laundry detergent composition having granular cyclodextrin for removing malodor from laundered items and process for making and using same |
| US7049280B2 (en) | 1999-09-03 | 2006-05-23 | The Procter & Gamble Company | Process for making laundry detergent composition having granular cyclodextrin for removing malodor from laundered items |
| WO2001088076A1 (en) * | 2000-05-15 | 2001-11-22 | The Procter & Gamble Company | Compositions comprising cyclodextrin |
| KR100767983B1 (en) * | 2000-05-15 | 2007-10-18 | 더 프록터 앤드 갬블 캄파니 | Compositions comprising cyclodextrin |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2513794B2 (en) | 1996-07-03 |
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