TW300157B - Herbicide compositions - Google Patents

Herbicide compositions Download PDF

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TW300157B
TW300157B TW83102210A TW83102210A TW300157B TW 300157 B TW300157 B TW 300157B TW 83102210 A TW83102210 A TW 83102210A TW 83102210 A TW83102210 A TW 83102210A TW 300157 B TW300157 B TW 300157B
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Taiwan
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growth
methyl
herbicides
inhibitor
dimethenamid
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TW83102210A
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Chinese (zh)
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Melvin Fenderson John
Ben O'neal William
Quaghebeur Theo
Schumm Karl-Christof
Van-Loocke Walter
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Sandoz Ltd
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Abstract

The present application relates to a method of controlling undesired plant growth which comprises co-application to the locus of the undesired plants growth dimethenamid and at least one other herbicide selected from the group comprising the growth regulator dicamba; the photo synthesis inhibitors metamitron, metribuzin, benacil, bentazon, atrazine, phenmedipham, pyridate,diuron; the pigment inhibitors norflurazon, chloridazon, amitrole;the growth inhibitor prodiamine; the amino acid synthesis inhibitors glyphosphate, nicosulfuron, triflusulfuron, chlorimuron; the lipid inhibitors dichlofop-methyl, haloxyfop-methyl, fenoxaprop-ethyl,clodinafop-propargyl; and sulcotrione; in a herbicidally effectiveaggregate amount.

Description

鲤濟部't央梂準局員工消費合作社印製 A7 _B7__ 五、發明説明（v) 本發明係闞於使用噻草胺（dimethenamid)和至少一 種其他除草劑结合施用防治有害植物生長的方法；其中闢 於含有噻草胺和至少一種其他除草劑的除草組合物及所述 組合物在防治有害植物中的應用。 噻草胺（dimethenamid) (F RONT I E R®)的 化學名稱為2 —氮一N — （2，4一二甲基一3 — _吩基 )-N - (2 —甲氧基一1 一甲基乙基）一乙醢胺，它的 生產方法、含有它的除草組合物和其作為除草劑的用途描 述於美國專利4，666，502中，其内容作為參考文 獻并入本文。由於存在兩個手性（chiral)中心，睡草胺 有4個立體異構體形式，因此它可以以單一異構體的形式 存在，也可以Μ非對映髖混合物〔（IS * aRS (稱為 S —噻草胺）和1R，aRS (稱作R —噻草胺）〕和外 消旋混合物（IRS，aRS)形式存在。除非另外指明 ，本文中提及的睡箄胺是包括其各種形式，在非對映體混 合物中* S —噻草胺混合物是較佳的。 本文中使用的術語除草劑，為殺滅或防治有害植物生 長的化合物。根據除草劑對植物作用的基本類型和方式， 逭類化合物可分成亞類。例如根據Purdue University, Indiana, USA，的G.F. Warren所述，除草劑可被分類為 生長素輪送抑制劑、生長調節除草劑、光合作用抑制劑、 色素抑制劑、生長抑制劑、氨基酸合成抑制劑、類脂物生 物合成抑制劑、细胞壁生物合成抑制劑、细胞膜快速破裂 本纸張尺度逋用中國國家標準（CNS ) A4規格（210X2.97公釐） IL------------訂 II 卜 lull (請先閲讀背面之注意事項再填寫本頁) 經 t 央 樣 準 局 Ά 工 消 费 合 作 社 印 製 300157五、發明説明（>) A7 B7 劑以及不能列 現在令人 结合施用能得 有害植物生長 Effect)本身 本身的劑量明 劑的劑量。而 入上述 驚奇地 到更好 的控制 顯示出 顯低於 且，在 高於K同一劑董的單A7 _B7__ printed by the Employee Consumers ’Cooperative of the Ministry of Carriage and Economic Development. V. Description of the invention (v) The present invention is a method of using dimethenamid in combination with at least one other herbicide to control the growth of harmful plants Among them are herbicidal compositions containing teclofen and at least one other herbicide and the use of the compositions in controlling harmful plants. The chemical name of dimethenamid (F RONT IER®) is 2-nitro-N- (2,4-dimethyl-2,3-phenyl) -N- (2-methoxy-1,1-methyl Ethylethyl) -ethylacetamide, its method of production, herbicidal compositions containing it and its use as a herbicide are described in US Patent 4,666,502, the contents of which are incorporated herein by reference. Due to the presence of two chiral centers, clinochlor has four stereoisomers, so it can exist as a single isomer or as a diastereomeric mixture [(IS * aRS (called Are S-thiachlor) and 1R, aRS (called R-thiachlor)) and racemic mixtures (IRS, aRS). Unless otherwise specified, the sleep amines mentioned in this article include all kinds of In the form of a mixture of diastereomers, * S-thiachlor is preferred. The term herbicide as used herein is a compound that kills or controls the growth of harmful plants. According to the basic types of herbicides acting on plants and In this way, Japanese compounds can be divided into subclasses. For example, according to GF Warren of Purdue University, Indiana, USA, herbicides can be classified as auxin rotation inhibitors, growth regulating herbicides, photosynthesis inhibitors, pigment inhibition Agents, growth inhibitors, amino acid synthesis inhibitors, lipid biosynthesis inhibitors, cell wall biosynthesis inhibitors, and rapid cell membrane rupture. This paper scale uses the Chinese National Standard (CNS) A4 specifications 210X2.97mm) IL ------------ Order II Bu lull (please read the precautions on the back and then fill out this page). Printed by the Central Bureau of Standards and Technology Co., Ltd. 300157 2. Description of the invention (>) A7 B7 agent and the dosage of the dosage agent that cannot be used in combination with the application of the effective dosage of harmful plant growth itself. And into the above, surprisingly, the better control shows that it is significantly lower than

Effect)。在 提高《和/或 雜草。 增效作用 果簞獨腌用某 夠獲得滿意的 施用噻草胺和 施用預先 mixes )，同 或施用各單一 一些情 可防治 目錄的“各 發現，唾草 的效果，且 。這種增效 :在高防治 獲得相同防 任何給定的 獨成分獲得 況下活性的 在經濟劑董 種和樣”的除草劑。 胺和至少一棰其它除草劑 在一些情況下能夠延長對 效應（Synergistic 率的混用劑量下，各藥劑 治效果所需的每種單一藥 混用劑置下的防治水平均 的加合效果（Additive 速度和防治的效果都可以 下各單一成分不能防治的 使得每種成分以較低的施用劑量，甚至以如 一具體成分得不到有效防治的劑量水平，能 防治效果。而且，可獲得較長的殘效。结合 除草劑具有明顯的經濟和環境的優點。 製備的各單一活性成分的桶混合物（tank 時或依次（較佳1 一 2天）施用上述制劑* 活性成分的預製的固定的預混組合物，均可 用的目的。 明，可與噻草胺结合施用的除草劑的實例包 以達到结合應 根據本發 括： 1 *生長素（auxin)輸送抑制劑，例如，抑箄生（ napta 1 ai) ; 本紙浪又度適用中國國家梯準（CNS ) A4規格（210X297公釐） — L------------訂！ hlull (请先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局貝工消費合作社印製 A7 B7______ 五、發明説明（> ) 2·生長調節劑*包括：1)苯甲酸類、例如，麥草 畏（dicamba ) ; b)苯氧基酸i)乙酸型，例如2，4 一D，MCPA， i i)丙酸型，例如，2，4一DP， MCPP， ί i i) 丁酸型，例如，2，4一DB， M C P B ; c )吡啶甲酸和相關化合物|例如，毒莠定（ picloram)、綠草定（triclopyr)'、氟草定（fluroxypr )、克羅 ttt 樂利（clopyralid); 3·光合作用抑制劑，包括a) S—三嗪類，i)氛 取代物，例如，阿特拉津（atrazine)、西瑪津（ simazine)、草淨津（cyanazine ) ，i i )甲氧基取代 物，例如，撲滅通（proaeton) ，i i i )甲硫基取代物 ，例如，薄滅津（ametryn )、撲草淨（prometry.n ); b)其它三嗪類，例如，六嗪同（hexazinone)、饔克津 (metribuzin) ; c)取代脲類，例如，敵草隆（diuron )、伏草降（fluonetruon )、利穀隆（linuron )、特 丁赛草隆（tebuthiuron )、賽苯隆（thidiazuron )、 佛克羅芥隆（forchlorfenuron) ; d)尿喃唾類，例如， 除草定（bromacil)、特草定（terbacil) ; e)其它類 ，例如》噻草平（bentazon )、甜菜安（desmidepham) 、甜菜寧（phenmedipham)、敵稗（propanil)、殺草敏 (pyrazon )、達草止(pyridate); 4 ·色素抑制劑，包括：a)噠嗪_類（ pyridazinones)，例如達草滅（norflurazon) ; b)異 本紙張尺度逋用中國國家標準（CNS ) A4规格（210X297公釐） LI—-----ο------訂---r|_!|4 (請先閲讀背面之注意事項再填寫本頁) B7 % 央 標 準 局 負 工 消 費 合 作 社 五、發明説明.（冬） 噁唑酮類（i s ο X a ζ ο 1 ο n e s) ’例如廣滅寧（c 1 〇 m a ζ ο n e); c)其它類，例如殺草強（afflitr〇le)、氟箄同（ fluridone); 5.生長抑制劑，包括：a)分裂破壊劑，i)二硝 基苯胺類（ dinitroanilines )，例如，氟禾蜜（ t r i f 1 u r a 1 i η )、普二胺（P r 〇 d i a m i n e )、乙 丁氟番（ benefin ) 、丁氟消草（ethalfluralin )、異樂蜜（ i s opr opa 1 i η )、胺碌靈（oryza 1 in )、胺硝草（ pendinethalin) ，i i )其它類，例如 * 敵草索（DCPA) 、二硫匹（dithiopyr )、唾唑匹（thiazopyr)、拿草特 (pronamide ) ; b)秧苗發芽抑制劑，i )硫代氨基甲酸 酯（thiocarbamates )，例如，撲箄滅（EPTC)、蘇達滅 (butylate )、草滅特（cycloate )、草達樂（ molinate )、克草猛（pebulate )、殺草丹（ thiobencarb )、野麥畏（triallate )、滅草猛（ vernolate ) ; c)苗根抑制劑，例如，地散磷（ b e n s u 1 i d e )、草蔡胺（n a p r 〇 p a m i d e )、環草隆（ siduron ) ; d)苗根和芽抑制劑，包括氮乙釀胺類，例如 *甲基胺、乙基乙草胺（acetochlor)、異丙甲草胺（ metolachlor )、安塔（diethatyl )、撲草胺（ P r 〇 p a c h 1 〇 r )、去草胺（b u t a c h 1 〇 r )、丙草胺（ pretilachlor ) 、（ft 草胺（netazachlor )、克草胺（ d i n e t h a c h 1 o r )、和其它類，例如，噁庚草垸（ -7- 本纸張尺度適用中國困家橾準（CNS ) A4规格（210X297公釐） (請先閲讀背面之注意事項再填寫本頁) 經濟部中央揉準局w：工消费合作杜印製 A7 B7 五、發明説明（<) cinmethyl in ).; 6·氨基酸合成抑制劑，包括：a)草甘膦（ glyphosate)、草按膜（glufosate) ; b )硬醢腿 類，例如：瑞磺隆（rimsulfuron)、甲磺隆（ metsul f uron )、尼可磺隆（nicosu 1 f uron)、醚苯磺隆 (triasulfuron ) 、[ft 嘧磺隆（primisulfuron)、苄哺 磺隆（ bensulfuron )、氛嘧磺隆（chlorimuron)、氯 磺隆（c h 1 o r s u 1 f u r ο η )、喃硬隆（s u 1 f o m e t u r ο η)、暖 吩確隆（ t h i f e n s u 1 f ur ο π )、噻本隆（t h i b e nu r ο η)、 乙騫美磺隆（ethametsulfuron )、三氰磺隆（ t r· i f 1 u s u 1 f u r ο η)、克羅匹爾確隆（c 1 o p y i* a s u 1 f u r o n ) 、匹羅雜磺隆（pyrazasulfuron )、普羅磺隆（ prosulfuron， CGA-152005 )、哈羅硝隆（ halosulfuron )，甲確隆一甲基（metsulfuron-B.ethyl )、氰味顏隆一乙基（chlorimuron-ethyl) ; c )碌醯 胺 * 例如，佛美速蘭（flu metsul am， a.k.a.DE498 ) ;d)咪唑啉萌類，例如乙馬雜昆（iinazaquin)、乙馬雜 美養本（ imazamethabenz )、乙馬雜匹（iraazapyr ) 、普殺特（imazethapyr ); 7 ·脂類生物合成抑制劑，包括：a)環己二酮類， 例如，稀禾定（sethoxydim)、稀草調（clethodim) ; b )芳氧苯氧類，洌如，精吡氟禾草靈（fluazif〇p-P-butyl )、稀草嗣、禾草番（d i c 1 〇 f 〇 p - is e t h y 1)、蓋草能（ -8 - 本紙乐尺度逋用中國困家標準（CNS ) M規格（210X 297公釐） ----------¢-.水-- (請先閲讀背面之注$項再填寫本頁) 訂 A7 ___B7_ 五、發明説明（) h a 1 ο X y f ο P - in e t h y 1)、喹禾 g ( q u i z a 1 〇 f 〇 p ) ; c )其它 類·例如嗎哇禾草 S (fe'noxaprop-ethyl); (請先閲讀背面之注意事項再填寫本頁) 8 ·细胞壁生物合成抑制劑，例如，敵草腈（ dichlobenil)、異喔草胺（isoxaben); 9 ·细胞膜快速破裂劑，包括：a)聪吡啶鎗類（ b i p y r i d 1 i n in s)，例如，對草快（p a r a q u a t)、敵草快（ diquat; b )二苯魅類，例如，氟鎖草魅（acifluorfen) 、氟.確胺草链（fomesafen)、克關樂（lactofen)、氟硝 草醚（oxyfluorfen) ;c)穀醢胺合成酶抑制劑，例如， 草銨磷（glufosinate) ; d)其它類，例如，噁草_ ( oxadiazon); 1 0.*其它類，包括：a)截基甲酸酷（carba.mates )，例如黃草番（asulam) ; b)腈類，例如溴苯膀（ b r 〇 m ο X y n i 1 )、磺苯腈（i ο X y n i 1 ) ; c )海因類（ hydantocidin)及其衍生物；d)雜類，例如，多致唑（ paclobutrazol)、哩陡草（ethofumesate)、快殺稗（ quinclorac [a.k.a.BAS514])、燕麥枯（difenzoquat) 、草藻滅（endothall)、調節膦（fosaraine)、甲胂納（ DSMA)、甲胂納（MSMA); 1 1 ·其它類 a)下述文獻中所述的三酮和二酮類，逭些文獻是： 美國専利 4，695，673 ; 4，869，748 ; 4 ，921，526;5，006，150;5，089， -9- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 300157 五、發明説明（丫） 046，美國專利申請07 A-338 > 992):和 P-A-394，889 和 Μ 及 EP — A— 137 > 9 18 ; ΕΡ-Α-186， 120 ; ΕΡ-Α-249 ，898 ;本文中结合參考 和二酮的例子是：如撒可三 DO®)，其化學名稱為2 苯甲醢基）一1 ，3—環己 氧基一 2 —硝基苯甲醮基） —1 ，3 —環己烷二酮；3 硝基苯甲醢基）—雙環〔3 嗣；3 - (4 —甲磺醢 3，2，1〕辛烷一2，4 硝基苯甲醮基）一2，6, 噁嗪一3*5 — （4H，6 基一2_硝基苯甲醢基）一 1 ，2 —噁嗪一3，5 —( 4一甲硫基一2—硝基苯甲 辛焼—2，4 —二酮；4一 苯甲醢基）—2，6，6 — -3，5 - ( 4 Η · 6 Η ) Α7 Β7 訂 經濟部中央橾準局負工消費合作社印裝 / 4 1 1 I 0 8 6 ( 和 E P 一 0 7 / 9 9 4 » 0 4 8 ( 和 Ε E Ρ — A — 5 0 6 4 9 0 7 ) 6 3 E P — A — 1 8 6 > 1 1 1 9 i E Ρ — A — 1 8 6 9 9 1 5 0 Ε Ρ — A — 3 3 6 了 上 述 文 獻 内 容 0 上 述 的 三 酮 酮 ( S υ ,1 c 〇 t r i .ο η ；e) (Μ ： [K A — ( 2 一 氯 — 4 — 甲 烷 磺 醢 基 烷 二 酮 » 2 — ( 4 — 甲 基 磺 醢 — 4 » 4 * 6 » 6 » — 四 甲 基 — ( 4 — 甲 基 磺 醢 氧 基 — 2 — • 2 • 1 ] 辛 烷 — 2 $ 4 — 二 2 — 硝 基 苯 甲 醢 基 ) — 雙 環 [ — 二 嗣 » 4 — ( 4 — 氛 — 2 — 6 — 二 甲 基 — 2 Η — 1 9 2 — Η ) — 二 嗣 9 4 — ( 4 — 甲 硫 2 6 > 6 — 二 甲 基 — 2 Η — 4 Η 9 6 Η ) — 二 酮 t 3 — C 醢 基 ) — 雙 環 C 3 9 2 9 1 3 ( 2 — 硝 基 — 4 — 三 氟 甲 氧 基 — 甲 基 一 2 Η 一 1 9 2 一 噁 嗪 -二酮； 10- ---------Tf I (請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X297公釐） 經濟部't央揉準局真工消费合作杜印製 A7 B7 五、發明説明（》） b)美國專利申請08/036 ，006 (EP — A -461，079和£卩-厶-549，524) 、EP -A-315，889 和 PCT 申請 91/10653 號 中所述類型的化合物，上述文獻的内容并入本文中作參考 。所述化合物包括：例如3— 〔 （4，6—二甲氧基一2 一嘧啶基）羥甲基〕一N —甲基一 2 — at啶甲醯胺；4， 7 —二氮一 3 — （4，6 —二甲氧基一 2 —嘧啶基）—3 一己醢氧基一 2 —苯并〔c〕呋哺酮；3 — 〔 （4，6 — 二甲氧基一2 —嘧啶基）羰基〕_N，N —二甲基一 2_ 吡啶甲醢胺；3，6_二氢一 2— 〔 （4，6-二甲氧基 —2 —嘧啶基羰基〕苯酸；6 —氛一 2 — 〔 （4，6 —二 甲氧基一 2 —嘧啶基）硫基〕苯甲酸（a.k.a.DPX-PE 3 5 0或 pyrithiobac)及它們的塩。 因此本發明係瞄於殺滅或防治有害植物生長或諝節植 物生長的方法，該方法包括在需要上述殺滅或防治的植物 生長地结合施用除草或調節植物生長合計有效量的睡草胺 和至少一種其它除草劑。 當然结合施用的劑曇將視乎氣候條件、季節、土壤生 態、要被殺滅的雜草等而定，然而，在结合施用中，例如 使用0 ‘ 1至3 ♦ Oks/ha ，較佳是0 * 1至2 . 0kg /ha ，特別是 0 · 2 5'至 1 · 5kg/ha ，例如 0 . 9 至1 劑量的曈草胺與單獨使用時建議用量或 明顯低於該推荐置的其它除草劑一起懕用，可獲得很好的 -11- 本紙張尺度適用中國國家標準（CNS ) A4规格（210X2.97公釐） —l·——-----Ο------訂——卜|_14 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央揉準局貝工消費合作社印装 A7 B7 五、發明説明（/) 效果。 當然，對於長苗前或長苗後结合施用的適合性和選擇 性將取決於所選擇的除草劑。 上述的專利中描述了唾草胺的活性與之合用的除草劑 的活性描述於文獻中或其商品說明書上，例如，參見：（ 亦參見 C R 0 P P R 0 T E C T I 0 N C Η Ε Μ I C A L S R E F E R E N C E，第九版（ 1993) Chemical & Pharmaceutical Press, ΝΥ,ΝΥ; The Pesticide Manual,第九版（1991 ) .British Crop Protecion Council, London; Ag Chem New Product Review, Ag Chem Information Services, Indianapolis, Indiana; Farm Chemicals Handbook, 1 9 9 3 edition, Meister Publishing Company, Willoughby, Ohio^) 〇 本發明埋提供了含有除草缌計有效量的噻草胺和至少 一種其它除草劑的除草组合物或植物生長調節组合物。 上述组合物含有活性物霣及農業上可接受的稀釋劑。 组合物可Μ與常規稀釋劑结合K固ffi或液體形式使用。例 如可濕性粉劑或可乳化的濃縮物形式。上述組合物可Μ常 規方式生產*例如通過將活性成分與稀釋劑或可選擇的其 它製劑成分如表面活性劑和油混合。 本文中使用的術語「稀釋爾J是指可被加入到活性组 分的任何液體或固體的農業上可接受的物質，Κ提供更方 便的或改進的施用劑型，或獲得有用或需要的活性強度。 稀釋劑的例子為滑石（talc)、高嶺土 （kaloin)、矽藻 -12- 本紙張尺度適用中國國家標準（CNS >A4規格（210X297公釐） (請先閲讀背面之注意事項再填寫本頁) .H^· 訂 經濟部中央揉準局貝工消费合作社印裝 A7 _B7 五、發明説明（ 土 （diatomaceous earth)、二甲苯（xylene)、非植物 毒性的油、或水。 以嗔霧形式施用的具體製劑（如水乳液或可濕粉）可 含有表面活性劑如濕潤和分散劑，例如，甲醛與萘磺酸塩 的縮合產物、烷基芳基磺酸塩、木質素磺酸塩、脂肪烷基 硫酸塩、乙氧基化烷基酚或乙氧基化脂肪醇。 通常，製劑包括0·01至90% (重量）的活性成 分和0至20% (重量）的適合農業上的表面活性劑，所 述活性成分由噻草胺和至少一種其它除草劑組成。姐合物 的濃縮形式通常含有大約2至9 0%，較佳是大約5至 8 0% (重量）的活性成分，製劑的施用形式可含有例如 0·01至20% (重量）的活性成分。 當同時直接依次或桶混合應用時，必要時可Μ商業上 可獲得的形式使用混合除草劑，施用的各除草劑的劑量相 當於或較佳為底於製造商或上述引用文獻中推荐用量。也 可ΜΜ商業上可得到的形式（例如，如F RONT I ER ®除草劑）或配製形式（例如，上述USP4，666， 502中所述）施用噻箄胺。 當依照本發明结合施用時，邐可包括其它具有生物活 性的化合物。例如具有殺蠱或殺真菌活性的化合物。 較佳的施用方式是桶混製備物，例如通過將噻草胺加 入到含有其它混用除草萷和缠合於所遘擇的混合除草劑類 型的表面活性劑的桶中而製得。反過來也是這樣。最好在 -1 3- 本紙張尺度適用中國國家標準（CNS ) Α4規格（210Χ297公釐） ----------^'¥.-- (請先閲讀背面之注意事項再填寫本頁) 訂 經濟部中央標準局只工消費合作社印製 A7 B7 五、發明説明（以） 混合前査看混合除草劑的商標並進行相容性實驗。 視乎所選擇的混用除草劑，可K獲得在大範圍種類的 臛葉和禾本科雜草上的長苗前和長苗後活性。上述雜草的 霣例是：Effect). In raising "and / or weeds." The synergistic effect is to pickle with a certain enough to obtain satisfactory application of thiachlor and the application of pre-mixes), the same or the application of each single situation can control the catalog of "each discovery, the effect of salvia, and such synergies: Herbicides that are active in the economic agent Dong Zong He Yan, which are active under the condition of high control to obtain the same control against any given single ingredient. Amine and at least one other herbicide can in some cases prolong the effect (Additive speed of the control level under the mixed dose of Synergistic rate, each single drug combination required for the treatment effect of each drug) It can be controlled and controlled by the single component, so that each component can be controlled at a lower dosage, even at a dosage level that cannot be effectively controlled by a specific component. Moreover, a longer residual effect can be obtained The combination of herbicides has obvious economic and environmental advantages. The barrel mixtures of the single active ingredients prepared (tank or sequentially (preferably 1 to 2 days) are applied to the above-mentioned preparations * pre-made fixed pre-mixed compositions of active ingredients , All available for use. It is clear that examples of herbicides that can be applied in combination with chlorfenapyr to achieve binding should include according to the present invention: 1 * auxin delivery inhibitors, for example, napta 1 ai ); This paper wave is applicable to China National Standard (CNS) A4 specification (210X297mm) — L ------------ ordered! Hlull (please read the notes on the back first Item and then fill out this page) A7 B7______ printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of the invention (>) 2. Growth regulator * includes: 1) Benzoic acids, for example, dicamba; b ) Phenoxy acid i) acetic acid type, for example, 2,4-D, MCPA, ii) propionic acid type, for example, 2,4-DP, MCPP, ii) butyric acid type, for example, 2,4-DB, MCPB; c) picolinic acid and related compounds | For example, picloram, triclopyr ', fluroxypr, clopyralid; 3. Photosynthesis inhibitors, including a) S-triazines, i) atmosphere substitutes, for example, atrazine, simazine, cyanazine, ii) methoxy substitutes, for example, promethazine (Proaeton), iii) methylthio substituents, such as ametryn, prometry.n; b) other triazines, for example, hexazinone, hexazinone metribuzin); c) instead of ureas, for example, diuron, fluonetruon, linuron, tedin Tebuthiuron, thidiazuron, forchlorfenuron; d) uran saliva, for example, bromacil, terbacil; e) other species, for example, thiodipine (Bentazon), bemid (desmidepham), phenmedipham (phenmedipham), propanil (propanil), pyrazon (pyrazon), pyridate (pyridate); 4. Pigment inhibitors, including: a) pyridazine (Pyridazinones), for example, norflurazon; b) The size of the different papers uses the Chinese National Standard (CNS) A4 specification (210X297mm) LI —----- ο ------ Subscribe --- r | _! | 4 (Please read the precautions on the back before filling in this page) B7% Central Standards Bureau Negative Consumers Cooperative V. Description of invention. (Winter) Oxazolones (is ο X a ζ ο 1 ο nes ) 'For example Guangmiaoning (c 1 〇ma ζ ο ne); c) Other categories, such as chlortetracycline (afflitrole), fluoxone (fluridone); 5. Growth inhibitors, including: a) splitting broken Agents, i) dinitroanilines (dinitroanilines), for example, trifluramide (trif 1 ura 1 i η), diamine (P r 〇 d iamine), benefin (benefin), butflux (ethalfluralin), heterophile (is opr opa 1 i η), amine luling (oryza 1 in), pendinethalin (pendinethalin), ii) others Classes, for example * DCPA, dithiopyr, thiazopyr, pronamide; b) seedling germination inhibitors, i) thiocarbamates , For example, EPTC, butylate, cycloate, molinate, pebulate, thiobencarb, and triallate ), Vernolate; c) seedling root inhibitors, for example, disan phosphate (bensu 1 ide), naproxamide (napr 〇pamide), cyclic grass long (siduron); d) seedling root and bud inhibition Agents, including nitrosamines, such as * methylamine, ethylacetochlor, acetochlor, metolachlor, diethatyl, prochloraz (Pr 〇pach 1 〇r ), Butachlor (butach 1 〇r), propachlor (pretilachlor), (ft azachlor (netazac hlor), ketochlor (dinethach 1 or), and other categories, for example, oxiancao embankment (-7- this paper scale applies to China ’s sleepy family standard (CNS) A4 specifications (210X297 mm) (please read Note on the back and then fill out this page) Central Bureau of Economic Development of the Ministry of Economic Affairs w: Industrial and Consumer Cooperation Du Printed A7 B7 V. Description of invention (<) cinmethyl in) .; 6. Inhibitors of amino acid synthesis, including: a) grass Glyphosate, glufosate; b) hard legs, such as: rimsulfuron (rimsulfuron), metsulfuron (metsul f uron), nicosulfuron (nicosu 1 f uron), ether Trisulfuron (triasulfuron), [ft pyrisulfuron (primisulfuron), benzylsulfuron (bennsulfuron), chlorimuron (chlorimuron), chlorsulfuron (ch 1 orsu 1 fur ο η), nitrosulfuron (su 1 fometur ο η), thifensu 1 f ur ο π, thibe nu r ο η, ethametsulfuron, tr · if 1 usu 1 fur ο η), cloperilone (c 1 opyi * asu 1 furon), pirosulfuron pyrazasulfuron), prosulfuron (prosulfuron, CGA-152005), halosulfuron (halosulfuron), metsulfuron-B.ethyl, chlorimuron-ethyl; c) Acetamide * For example, flu metsul am (flumetsul am, akaDE498); d) Imidazoline sprouting species, such as iinazaquin, imazamethabenz, and iraazapyr ), Imazethapyr; 7 · Lipid biosynthesis inhibitors, including: a) Cyclohexanedione, for example, sethoxydim (sethoxydim), sparse grass (clethodim); b) aryloxyphenoxy Class, such as, fluazifop-butyl (fluazif〇p-butyl), dilute grass roots, grass grass (dic 1 〇f 〇p-is ethy 1), cover grass can (-8-the paper paper scale Use the Chinese Standard for Sleepy Family (CNS) M specifications (210X 297mm) ---------- ¢-. Water-- (please read the note $ item on the back and fill in this page) Order A7 ___B7_ 5 , Description of the invention () ha 1 ο X yf ο P-in ethy 1), quino g (quiza 1 〇f 〇p); c) Others · For example, Mowa grass S (fe'noxaprop- ethyl); (Please read the precautions on the back before filling in this page) 8 · Cell wall biosynthesis inhibitors, such as dichlobenil, isoxaben; 9 · Rapid cell membrane rupture agent, including: a) Pyridine guns (bipyrid 1 in in s), for example, paraquat, diquat; b) diphenyl charms, for example, acifluorfen, fluor. Fomesafen, lactofen, oxyfluorfen; c) glutamine synthetase inhibitors, for example, glufosinate; d) other classes, for example, oxadia (oxadiazon); 1 0. * Other categories, including: a) carba.mates, such as asulam; b) nitriles, such as bromobenzene (br 〇m ο X yni 1 ), Sulfobenzonitrile (i ο X yni 1); c) hydantocidin and its derivatives; d) miscellaneous, for example, paclobutrazol, ethofumesate, barnyardgrass (Quinclorac [akaBAS514]), difenzoquat, endothall, fosaraine, arsonine DSMA), methylarsine (MSMA); 1 1 · Other categories a) The triketones and diketones described in the following documents, some of the documents are: American Keli 4,695,673; 4,869,748; 4, 921,526; 5,006,150; 5,089, -9- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) 300157 V. Description of invention (Ya) 046, US Patent Application 07 A-338 > 992): and PA-394, 889 and M and EP-A-137 > 9 18; ΕΡ-Α-186, 120; ΕΡ-Α-249, 898; combined reference and dione Examples are: such as Sacosan DO®), whose chemical name is 2 benzoyl)) 1, 1, 3-cyclohexyloxy-2-nitrobenzoyl) -1, 3-cyclohexane di Ketone; 3 nitrobenzyl))-bicyclic [3 heirs; 3-(4-mesylate 3,2,1] octane 2,4 nitrobenzyl)) 2,6, oxazine One 3 * 5 — (4H, 6 yl-2-nitrobenzyl) one 1,2-oxazine one 3,5 — (4 one methylthio one 2-nitrobenzyl octane-2, 4-dione; 4-benzylidene)-2, 6, 6--3, 5-(4 Η · 6 Η) Α7 Β7 in the Ministry of Economy Printed and printed by the Central Bureau of Prejudicial Consumer Cooperatives / 4 1 1 I 0 8 6 (and EP 1 0 7/9 9 4 »0 4 8 (and Ε E Ρ — A — 5 0 6 4 9 0 7) 6 3 EP — A — 1 8 6 > 1 1 1 9 i E Ρ — A — 1 8 6 9 9 1 5 0 Ε Ρ — A — 3 3 6 The above document content 0 The above triketone (S υ, 1 c 〇tri .ο η; e) (Μ: [KA — (2 monochloro — 4 — methanesulfonyl alkanedione »2 — (4 — methylsulfonamide — 4» 4 * 6 »6» — four Methyl — (4 — methylsulfonyloxy — 2 — • 2 • 1] octane — 2 $ 4 — di 2 — nitrobenzyl) — bicyclic [— disi »» 4 — (4 — atmosphere — 2 — 6 — Dimethyl — 2 Η — 1 9 2 — Η) — Di Si 9 4 — (4 — Methylsulfide 2 6 > 6 — Dimethyl — 2 Η — 4 Η 9 6 Η) — Di Ketone t 3 — C acetyl) — bicyclic C 3 9 2 9 1 3 (2 — nitro — 4 — trifluoromethoxy — methyl mono 2 Η — 1 9 2 monooxazine-dione; 10-- -------- Tf I (Please read the notes on the back first (Fill in this page again) This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210 X297 mm). The Ministry of Economic Affairs' Central Bureau of Accreditation and Real Estate Consumer Cooperation cooperates to print A7 B7. V. Invention Description (》) b) United States Patent applications 08 / 036,006 (EP — A-461,079 and £-厶 -549,524), EP-A-315,889 and PCT application No. 91/10653 of the compounds described in the above documents The content is incorporated into this article for reference. The compound includes, for example, 3-[(4,6-dimethoxy-2-pyrimidinyl) hydroxymethyl] -N-methyl-2-pyridinecarboxamide; 4,7-diazamono-3 — (4,6-dimethoxy-2-pyrimidinyl) -3-hexyloxy-2-benzofuranone; 3-[(4,6-dimethoxy-2-pyrimidine Group) carbonyl] _N, N-dimethyl-2-pyridinemethanamine; 3,6-dihydro-2-([4,6-dimethoxy-2-pyrimidinylcarbonyl] benzoic acid; 6-ambient A 2-[[4,6-dimethoxy-2-pyrimidinyl] thio] benzoic acid (akaDPX-PE 3 50 or pyrithiobac) and their bases. Therefore, the present invention is aimed at killing or preventing A method for the growth of harmful plants or for the growth of plants in the knots, which method includes the combined application of herbicides or a total effective amount of hylachlor and at least one other herbicide in the place where the plants need to be killed or controlled to grow. The agent will depend on climatic conditions, seasons, soil ecology, weeds to be killed, etc. However, in combination application, for example, use 0 '1 to 3 Oks / ha, preferably 0 * 1 to 2.0 kg / ha, especially 0. 2 5' to 1.5 kg / ha, for example 0.9 to 1 dose of alachlor and separate The recommended dosage during use or significantly lower than the recommended other herbicides can be used together to obtain a good -11- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X2.97mm) —l · — —----- Ο ------ 定 —— 卜 | _14 (Please read the precautions on the back before filling in this page) Printed A7 B7 by the Beigong Consumer Cooperative of the Central Bureau of Economic Development of the Ministry of Economic Affairs (/) Effect. Of course, the suitability and selectivity of the combined application before or after seedling growth will depend on the herbicide selected. The above patents describe the activity of salivamide combined with herbicides The activity is described in the literature or on its commercial instructions, for example, see: (also see CR 0 PPR 0 TECTI 0 NC Η Ε Μ ICALSREFERENCE, ninth edition (1993) Chemical & Pharmaceutical Press, ΝΥ, ΝΥ; The Pesticide Manual, Ninth Edition (1991). British Crop Protecion Council, London; Ag Chem New Product Review, Ag Chem Information Services, Indianapolis, Indiana; Farm Chemicals Handbook, 1 9 9 3 edition, Meister Publishing Company, Willoughby, Ohio ^) The present invention provides a herbicide-containing effective amount of clothianidin and at least A herbicidal composition or plant growth regulating composition of another herbicide. The above composition contains an active substance and an agriculturally acceptable diluent. The composition can be used in combination with conventional diluents in a solid form or in liquid form. For example, in the form of wettable powders or emulsifiable concentrates. The above-mentioned composition can be produced in a conventional manner * for example by mixing the active ingredient with a diluent or optionally other formulation ingredients such as surfactant and oil. The term "diluted J" as used herein refers to any liquid or solid agriculturally acceptable substance that can be added to the active ingredient, K provides a more convenient or improved application dosage form, or obtains a useful or required active strength Examples of thinners are talc, kaloin, and diatom. -12- This paper scale is applicable to the Chinese National Standard (CNS & A4 specifications (210X297 mm) (please read the precautions on the back before filling in this Page) .H ^ · Order A7 _B7 printed by the Beigong Consumer Cooperative of the Ministry of Economic Affairs, Central Bureau of Economic Development V. Description of the invention (diatomaceous earth, xylene, non-phytotoxic oil, or water. Specific formulations applied in the form (such as aqueous emulsions or wettable powders) may contain surfactants such as wetting and dispersing agents, for example, condensation products of formaldehyde and naphthalenesulfonate, alkylarylsulfonate, ligninsulfonate, Fatty alkyl sulfates, ethoxylated alkylphenols or ethoxylated fatty alcohols. Generally, the formulation includes 0.01 to 90% by weight of active ingredients and 0 to 20% by weight of agriculturally suitable Surfactant, The active ingredient consists of teclofen and at least one other herbicide. The concentrated form of the sister compound usually contains about 2 to 90%, preferably about 5 to 80% by weight of the active ingredient, application of the formulation The form may contain, for example, 0.01 to 20% (by weight) of the active ingredient. When applied directly or sequentially in a tank at the same time, a mixed herbicide may be used in a commercially available form if necessary, and the dosage of each herbicide applied is equivalent It is better to use the dosage recommended by the manufacturer or the references cited above. It can also be in a commercially available form (eg, F RONT I ER ® herbicide) or formulated form (eg, USP 4,666, 502 above) Described in)) application of thiamine. When applied in combination in accordance with the present invention, Lian may include other compounds with biological activity. For example, compounds with cockroicidal or fungicidal activity. The preferred method of application is a tank-mix preparation, for example It is prepared by adding chlorfenapyr to a bucket containing other mixed herbicides and surfactants entangled in the selected mixed herbicide type. The reverse is also true. It is better This paper scale is applicable to China National Standard (CNS) Α4 specification (210Χ297mm) ---------- ^ '¥ .-- (Please read the precautions on the back before filling in this page) A7 B7 printed by the Bureau of Standards and Consumers Co., Ltd. V. Description of the invention (in order) Check the trademark of the mixed herbicide and perform the compatibility experiment before mixing. Depending on the selected mixed herbicide, K can be obtained in a wide range of types Pre-emergence and post-emergence activity on the leaves and gramineous weeds. Examples of the above-mentioned weeds are:

Agropyron repens _ 葡萄冰草（quackgrass)Agropyron repens _ quackgrass

Brachiaria platyphylla _ 闊葉臂形草（broadleaf signalgrass)Brachiaria platyphylla _ broadleaf signalgrass

Bromus spp —例如旱雀麥（downybrome)Bromus spp — such as downybrome

Cenchrus spp. - 例如剌漢黎草（southern sandbur)、蔑花羡 黎草（sandbur)、海岸娱藜草（fieldsandbur) Dactyloctenium aegyptium -龍爪茅（crowfootgrass)Cenchrus spp.-Such as southern sandbur, sandbur, fieldsandbur Dactyloctenium aegyptium -crowfootgrass

Digitaria spp -例如，馬唐（crabgrass)、止血馬唐 (s»ooth crabgrass)、升馬唐（large crabgrass)Digitaria spp-for example, crabgrass, hemostatic crabgrass (s »ooth crabgrass), and crab crabs (large crabgrass)

Echinochloa crus-galli -稗草（barnyardgrass)Echinochloa crus-galli-barnyard grass (barnyardgrass)

Eleusine indica _ 牛筋草（goosegrass)Eleusine indica _ goosegrass

Eriochloa spp -例如，繼细野黍（southwestern cupgi*ass)， prairi cupgrass，賊毛野黍（woolly cupgrass)Eriochloa spp-for example, following fine wild millet (southwestern cupgi * ass), prairi cupgrass, woolly cupgrass (woolly cupgrass)

Leptochlos filif〇prais 一捵子草（red spangletop)Leptochlos filif〇prais a red spangletop

Oryza sativa -赤米（red rice)Oryza sativa-red rice

Panicum spp -例如，毛城稷和秋稷，browntop panicua和 得克薩斯稷，稷（wild proso millet) -14- 本纸張又度適用中國國家榡準（〇^)八4規格（21〇、_<297公釐） ---------d装-- (請先閲讀背面之注意事項再填寫本頁) 訂 A7 B7Panicum spp-for example, Mao Cheng Ji and Ji Ji, browntop panicua and Texas Ji, wild proso millet -14- This paper is again applicable to the Chinese National Standard (〇 ^) 8.4 specifications (21〇, _ < 297 Ali) --------- d installed-- (Please read the precautions on the back before filling out this page) Order A7 B7

Poa annua Setaria sppPoa annua Setaria spp

Sorghum almui Sorghum bicolor Sorghum halepense Urochloa panicoides Acanthospermum hispidum Araaranthus spp 經濟部中央橾準局員工消费合作社印製Printed by Sorghum almui Sorghum bicolor Sorghum halepense Urochloa panicoides Acanthospermum hispidum Araaranthus spp Printed by the Consumer Consortium of the Central Bureau of the Ministry of Economic Affairs

Ambrosia artemisiifolia Bidens pilosa Capsella bursa-pastoris Chenopodium album Cleone monophylla Commelina spp Crotalaria sphaerocarpa Datura stranionium Desnodium tortuosum 一早热禾（annual bluegrass) —例如費化狗尾草（giant foxtail)、谷子 (foxtail millet)、金狗尾草（yellow foxtail) 、 bristly foxtail -sorghum almuni 一二色蜀黍（shattercane) —阿刺伯高梁（seedling «johnson grass) -liverseedgrass 一硬毛刺苞菊（bristly starbur·) -例如鄉村藜（pigweed)、白莧（tumble pigweed)、小莫(smooth pigweed)、 反枝莧（redroot pigneed)、藜莧. (prostrate pigweed)、水麻（vaterhemp) 剌莧(spiny amaranthe) -膝箄（common ragweed) -三葉鬼針草（hairy beggarticks) -替菜（shepherdspurse) 一黎（common lambsquarters) -spindlepod -例如野跖草（dayflower) -曼陀羅 Uimsonweed) -扭曲山馬幢（Florida beggarweed) •15- 本紙張尺度適用中國國家標準（CNS > Α4规格（210X297公釐） ---1------^裝-- {請先閲讀背面之注意事項再填寫本頁) ,ιτ A7 B7 五、發明説明（以） Euphorbia nutans Euphorbia maculata Galinsoga parviflora Ipomea spp Laoium purpureua Matricaria chanomilla Mollugo verticillata Papaver rhoeas Polygonum sppAmbrosia artemisiifolia Bidens pilosa Capsella bursa-pastoris Chenopodium album Cleone monophylla Commelina spp Crotalaria sphaerocarpa Datura stranionium Desnodium tortuosum (annual bluegrass) —for example, foxtail, foxtail, and foxtail bristly foxtail -sorghum almuni one or two-color sorghum (shattercane)-A thorn sorghum (seedling «johnson grass) -liverseedgrass-a hard bristle thorn chrysanthemum (bristly starbur ·)-for example, village quinoa (pigweed), amaranth (tumble pigweed) Smooth pigweed, redroot pigneed, quinoa. (Prostrate pigweed), vagerhemp (spiny amaranthe)-common ragweed (hairy beggarticks) ) -Shepherdspurse (common lambsquarters) -spindlepod -such as wildflower (dayflower) -Datura Uimsonweed) -Twisted Mountain Horse (Florida beggarweed) • 15- This paper scale is applicable to China National Standards (CNS > Α4 specification (210X297mm) --- 1 ------ ^ installed-- {please Read the precautions on the back before filling this page), ιτ A7 B7 V. Description of the invention (in order) Euphorbia nutans Euphorbia maculata Galinsoga parviflora Ipomea spp Laoium purpureua Matricaria chanomilla Mollugo verticillata Papaver rhoeas Polygonum spp

Portulaca oleracea Richardia scabra Schkuhria pinnata Sida spinosa Solanum spp 經濟部中央標準局貝工消費合作社印装Portulaca oleracea Richardia scabra Schkuhria pinnata Sida spinosa Solanum spp Printed by Beigong Consumer Cooperative, Central Bureau of Standards, Ministry of Economic Affairs

Stellaria nedia Tagetes minuta Cyperus esculentis Cyperus iria -俯垂大戟（Nodding spurge) 一美洲地綿草（spotted surge) 一硬毛辣子草（smallflower galinsoga) 一例如，裂葉牽牛(ivyleaf)、 圓葉（tall)牽牛、多 （pitted)牽牛 -小野芝麻（purple deadnettle) -5¾ (wild chamomile) 一輪生粟米草（carpetweed) 一虜美人（corn poppy) -例如水H(sniartweed)，annual smatweed， 爾麥蔓（wild buckwheat)、扁蓄 (prostrate knotweed) -馬齒莧（c〇BB〇n purslane) 一佛羅里達馬蹄蓮（Florida pusley) —dwarf Marigold 一刺黃花稔（prickly sida) 一例如龍 II (black nightshade)、E. black nightshade 毛龍藥（hairy nightshade)、 銀毛龍努（silver nightshade) 一繁縷（common chickweed) -小萬壽菊（wild marigold/khaki weed) _鐵荸番（yellow nutsedge) 一碎米莎草（rice flatsedge) 16- 本紙張尺度適用中國國家棣準（CNS ) A4规格（210X297公釐） (請先閲讀背面之注意事項再填寫本頁) -rH袭. 訂 經 •中 央 標 隼 % 工 消 费 合 作 社 印 製 五、發明説明（/士） 草 A7 B7 另外，當使用適當的混用除草劑時，也可防治下述雜Stellaria nedia Tagetes minuta Cyperus esculentis Cyperus iria-Nodding spurge, spotted surge, small flower galinsoga, for example, ivyleaf, round leaf (tall) Morning glory, pitted morning glory-purple deadnettle-5¾ (wild chamomile) round raw cornweed (carpetweed) corn poppy-for example water H (sniartweed), annual smatweed, wild wheat (wild buckwheat), flat storage (prostrate knotweed)-Portulaca oleracea (c〇BB〇n purslane)-Florida calla (Florida pusley)-dwarf Marigold one prickly yellow flowers (prickly sida) (for example, Dragon II (black nightshade), E . black nightshade hairy nightshade, silver nightshade common chickweed-wild marigold / khaki weed _ 黃 荸 番 (yellow nutsedge) (Rice flatsedge) 16- This paper scale is applicable to China National Standard (CNS) A4 specification (210X297mm) (Please read the precautions on the back before filling this page) -rH 攻Ordering • Printed by the Central Standard Falcon% Cooperative Society V. Description of Invention (/ Shi) Grass A7 B7 In addition, when the appropriate mixed herbicide is used, the following impurities can also be controlled

Abutilon theophrasti Hibiscus trionui Avena fatua Sinapis alba Xanthium strumarium Cassia obtusifolia Apera spica-venti Campsis radicans Rottboellia exaltata Cynodon dactylon Lespedeza spp Trifolium spp Hippuris vulgaris Asclepias spp Salvia spp Salsola iberica Convolvulus arvensis Cirsium arvense Proboscidea louisianica Senecio spp Chorispora tennela 一茼麻（velvetleaf) -野西瓜苗（Venice mallow) —野燕麥（wild oats) -田白芥（white mustard) -蒼耳（Common cocklebur) 一鈍葉決明（sicklepod) 一風草（windgrass) -美洲凌霄花（trumpet creeper) 一羅代草（itchgrass) -狗牙根（bermudagrass) 一例如，鐵馬鞭（Iespedezas) 一例如，車軸草（cilovers) 一杉葉藻（marestail) -例如，敘利亞馬利筋（milkweeds) —例如，鼠尾草（lanceleaf sage) 一猪毛菜（russian thistle) —田旋花（field bindweed) —田M (Canada thistle) 一角胡麻（devilsclaw) -例如，歐洲千里光（common groundsel) -離子草（blue mustard) -17- 本紙張尺度適用中國國家標準（CNS ) A4规格（210X297公釐） ----------^装-- (請先閲讀背面之注意事項再填寫本頁)Abutilon theophrasti Hibiscus trionui Avena fatua Sinapis alba Xanthium strumarium Cassia obtusifolia Apera spica-venti Campsis radicans Rottboellia exaltata Cynodon dactylon Lespedeza spp Trifolium spp Hippuris vulgaris Asclepias spp Salvia spp Salsola iberica Convolvulus arvensis Cirsium arvense Proboscidea louisianica Senecio spp Chorispora tennela a velvetleaf (velvetleaf) -Venice mallow -Wild oats -White mustard -Common cocklebur -Sicklepod -Windgrass -Trumpet creeper Itchgrass-bermudagrass-for example, Iespedezas-for example, cilovers-marestail-for example, Syrian milkweeds-for example, rats Lanceleaf sage-Russian thistle-field bindweed-Tian M (Canada thistle)-devilsclaw-for example, common groundsel-blue mustard ) -1 7- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) ---------- ^ installed-- (please read the precautions on the back before filling this page)

C 經濟部肀央橾準局—工消費合作社印装 A7 B7 五、發明説明（β)C Printed by the Central Committee of the Ministry of Economic Affairs, Central Bureau of Industry and Consumers A7 B7 V. Description of invention (β)

Alopecurus rayosuroides 一鼠尾看麥娘（backgrass)Alopecurus rayosuroides A backgrass

Sisyabrium altissimum -田蒜芥（tumble mustard)Sisyabrium altissimum-tumble mustard

Caperionia palustris -德卅草（texasweed) 作物選擇性通常也視乎所選擇的混用除草劑。唾草胺 對玉米、大豆和幾種其它作物具有極好的選擇性。 與噻草胺结合施用的具體的混合除草劑的霣例選自以 下a)至w)列出的一種或多種類型： a ·苯甲酸類，例如，麥草畏（dicamba); b · tft啶甲酸和相瞄化合物類，例如，毒莠定（ P i c 1 〇 r a m)、綠草定（t r i c 1 〇 p y r)、氟草定（ fluroxypur)、克羅[ft 樂利（clopyralid); c *苯氧化物類，例如2，4 一 D、2，4 一 DB、 綠草定（1；1^(；1〇?丫1〇、1^匚？八、1^〇卩卩、2*4 — D P、M C P B ; d ♦其它氯乙醢胺類，例如，甲箄胺（alachlor)、 乙基乙草胺（acetochlor)、異丙甲草胺（metolachlor) 、安塔（diethatyl)、撲草胺（Pr〇Pachlor)、去草胺（ butach 1 〇r)、丙草胺（Preti 1 ach 1 〇r)、吡草胺（ metazachlor)、克草胺（dimethachlor)，特別是異丙甲 草胺（metolachlor)、甲草胺（alachlor)、乙基乙草胺 (acetochlor) ; e .醯胺類，例如，敵稗（Propanil)、抑草生（ -18* 本紙張尺度適用中國國家標準（CNS〉A4说格（公釐） I--------「装-- (請先閲讀背*之注意事項再填寫本瓦) 訂 A7 B7 300157 五、發明説明（t ^) naptalam); f ·氨基甲酸酯（c a r b a m a t e)類，例如，黃草S ( asu 1 an) ; g ·硫代氨基甲酸酯類，例如，撲草滅（EPTC) 、蘇達滅（butylate)、草滅特（cycloate)、草達滅（ m ο 1 i n a t e)、克箄猛（p e b u 1 a t e)、殺草丹（t h i 〇 b e n c a r b )、野麥畏（t r i a 11 a t e)、滅草猛（v e r η ο 1 a t e); h .腈類，例如溴苯蹰（bromoxynil)、碘苯腸（ i o x y n i 1) ; i ·脲類，例如敵草隆（diuron)、饗苯隆（ thidazuron)、伏草隆（fluoneturon)、利谷降（ 1 i n u r ο η)、特丁 饗草隆（t e b u t h i u r ο η)、 forchlorfenuron : j .三嚷類，例如，阿特拉津（atrazine)、賽克 津（metribuzin)、草淨津（cyanazine)、西瑪津（ simazine)、撲滅通（prometon)、莠滅津（ametryn)、 撲草津（pr〇ffl_etryn)、六嗪同（hexazinone); k，二苯醚類，例如，氟鎖草醚（acifluorfen)、氟 磺胺草醚（foiesafen)、克闊樂（lactofen)、氟硝箄醚 (oxyfluorfen) ; 1 ·二硝基苯胺類，例如，氰樂靈（trifluralin)、 prodiamine、乙丁氟靈（benefin) 、丁氟消草（ ethalfluralin)、異樂番（isopropalin)、胺磺靈（ -19- 本紙張又度適用中國國家標準（CNS ) A4規格（210X2.97公釐） ---------1装-- (請先閲讀背面之注意事項再填寫本頁) 訂 t 經濟部中央揉準局貝工消費合作社印製 五、發明説明（vp A7 B7 o x y z a 1 i η)、胺硝草（p e n d i in e t h a 1 i η); m ·磺醯胺類，例如瑞磺隆（r imsulfuron)、甲磺隆 (raetsul furon)、尼可磺隆（nicosulfuron)、醚苯磺 隆（triasulfuron )、毗喃磺隆（primisulfuron)、苄 啼碌隆（bensulfuron )、氛啼磺隆（chlorimuron)、氛 碌隆（c h 1 〇 r s u 1 f u r ο η )、喷碌隆（sul f ometur on)、唾 吩確隆（t h i f e n s u 1 f u r ο n)、噻本隆（t h i b e n u r ο n) » 乙 饗美硬隆（ e t hara e t su 1 f uron )，三氟確隆（ triflusulfuron)，克羅匹碌隆（clopyrasulfuron )， 匹羅雜磺隆（pyrazasulfuron),普羅確隆（prosulfuron )，氛嘧磺隆-乙基（CGA- 1 5 2 0 0 5 )，哈羅磺隆（ halosulfuron)'甲碌降一甲基（metsulfuronmet.hyl ) ，氮嘧磺隆 -乙基(chlorimuron-ethyl); η ♦味哩啉嗣類*例如，乙馬雜昆（imazaquin)、 乙馬雜美賽本（imazain ethabenz)、乙馬雜匹（imazapyr )、撲殺特（imazethapyr); (請先閱讀背面之注意事項再填寫本頁)Caperionia palustris-texasweed (texasweed) crop selection usually depends on the selected mixed herbicide. Salidomide has excellent selectivity for corn, soybeans and several other crops. Examples of specific mixed herbicides applied in combination with alachlor are selected from one or more types listed in a) to w) below: a · Benzoic acids, for example, dicamba; b · tft And phase-targeting compounds, for example, icoridine (Pic 1 〇ram), chlorpyridine (tric 1 〇pyr), fluroxydine (fluroxypur), Keluo [ft Leli (clopyralid); c * benzene oxide Classes, such as 2,4-D, 2,4-DB, green grass (1; 1 ^ (; 1〇? 雅 10, 1 ^ 匚? 八, 1 ^ 〇 卩 卩, 2 * 4-DP, MCPB; d ♦ Other chloracetamides, for example, alachlor, acetochlor, metolachlor, diethatyl, prochlorfen (Pr. Pachlor), butachlor (Butach 1 〇r), alachlor (Preti 1 ach 1 〇r), metazachlor (metachlor), dimethachlor (dimethachlor), especially metolachlor (metolachlor), Alachlor (acechlor), ethyl acetochlor (acetochlor); e. Acetamides, for example, propanil (Propanil), herbicide (-18 * This paper scale is applicable to the Chinese National Standard (CNS> A4 Grid (mm) I -------- "installed-- (please read the notes on the back * and then fill in this tile) Order A7 B7 300157 5. Description of the invention (t ^) naptalam); f · Amino Carbamates, for example, yellow grass S (asu 1 an); g · thiocarbamates, for example, EPTC, butylate, cycloate , Cao Damian (m ο 1 inate), Ke Luomeng (pebu 1 ate), dicabadan (thi 〇bencarb), wild wheat fear (tria 11 ate), zaomeng (ver η ο 1 ate); h . Nitriles, such as bromoxynil, ioxyni 1; i · Urea, such as diuron, thidazuron, fluoneturon, and Ligujiang (1 inur ο η), tebuthiur ο η), forchlorfenuron: j. Three crocodilians, for example, atrazine, metribuzin, cyanazine, Simazine, proton, prometryn, ametryn, promethazine, hexazinone; k, two Ethers, such as acifluorfen, foiesafen, lactofen, oxyfluorfen; 1. Dinitroanilides, such as trifluralin ), Prodiamine, benefin (benefin), butafluralin (isohalfluralin), isopropalin (isopropalin), sulfamethoxazole (-19- This paper is also applicable to the Chinese National Standard (CNS) A4 specification (210X2. 97mm) --------- 1 installed-- (please read the precautions on the back before filling in this page) Order t Printed by the Ministry of Economic Affairs Central Bureau of Customs and Industry Beigong Consumer Cooperatives V. Invention Instructions (vp A7 B7 oxyza 1 i η), pendimethalin (pendi in etha 1 i η); m · sulfonamides such as r imsulfuron, raetsul furon, nicosulfuron ), Triasulfuron, trimisulfuron, bensulfuron, bensulfuron, chlorimuron, ch 1 〇rsu 1 fur ο η, spray Sul f ometur on, thifensu 1 fur ο n, thibenur ο n) »et hara et su 1 f uron, triflusulfuron, clopyrasulfuron, pyrazasulfuron, prosulfuron ), Chlorsulfuron-ethyl (CGA- 1 5 2 0 0 5), halosulfuron (halosulfuron) 'methylsulfonon methyl (metsulfuronmet.hyl), azasulfuron-ethyl (chlorimuron- ethyl); η ♦ Tamicoline * For example, imazaquin (imazaquin), imazain ethabenz (imazain ethabenz), imazapyr (imazapyr), imazethapyr; (please read first (Notes on the back then fill this page)

T 装· .ΤΓ 經濟部中央梂準局貝工消费合作社印装T outfit · .TΓ Printed by the Beigong Consumer Cooperative of the Central Bureau of Economic Affairs of the Ministry of Economic Affairs

ox靈 th草 se禾 ( 氟 定at 禾， 稀如 ’ 例 如， 例類 . 物 類化 酮氧 二苯 烷基 己氧 環芳 O P fluazifop) ; q ·聯at啶銥類（bipyridilums)，例如對草快（ paraquat)、敵草快（diquat); r ·嚙嗪酮類，例如，達草滅（norflurazon); s ·尿唾陡類，例如，除草定（bronacil)、特草定 -20- 本紙張尺度適用中國國家標準（CNS ) A4規格（210X2.97公釐） 經濟.-ip中央橾準局工消費合作社印製 A7 B7___ 五、發明説明（〖g) (t e r b a c i 1); t ·異噪哩酮類（isoxazolones)，例如，廣禾番（ clomazone) ; u ·雜類，例如草甘膦（glyphosate)，草胺磷（ .glufosinate }，美沙嗤（Bethazole )，多致唾（ paclobutrazol)，睡草平（bentazon)，底斯美戴芬（ d e s m e d i p h a b )，甜菜寧（p h e π in e d i p h a m )，殺草敏（ pyrazon)，達草止（ pyridate)，殺箄強（amitrole )* 氟草同（fluridone ) ， DCPA，二硫匹（ dithiopyr )，拿草特（pronamide )，地敗 85 ( bensul ide )，草萘胺（napropamide )，環草隆（ siduron)，佛美速蘭（ f 1 u m e t s u 1 a m )，稀.箄嗣（ clethodim)，禾草靈（diclofop-methyl )，噁哩禾草 露（fenoxaprop-ethyl )，蓋草能（haloxyfor-methyl )，喹禾靈（quizalofop)，敵草腈（diclobenil)，ox lingth grass se grass (fludinidine at grass, rare like) For example, examples. Types of ketooxy diphenyl alkyl hexyl ring aromatic OP fluazifop; q · Bi atridium iridium (bipyridilums), for example Paraquat, diquat; r · Rozazinone, for example, norflurazon; s · Urinary salipid, for example, bromocil (bronacil), Tetradin-20- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X2.97mm) Economy.-ip Printed by the Central Bureau of Industry and Consumer Cooperatives A7 B7___ V. Description of invention (〖g) (terbaci 1); t Isoxazolones (for example, clomazone); u · Miscellaneous, for example, glyphosate (glyphosate), glufosinate (.glufosinate), methadone (Bethazole), polycloza (paclobutrazol) , Bentazon, desmediphab, phe π in edipham, pyrazon, pyridate, and amitrole fluridone), DCPA, dithiopyr (dithiopyr), pronamide (pronamide), 85 (bensul ide), napropamide, siduron, f 1 umetsu 1 am, clethodim, diclofop-methyl, Fenoxaprop-ethyl, haloxyfor-methyl, quizalofop, diclobenil,

異聘草胺’（isoxabenz)，聘草嗣（oxadiazon)，多致 哩（p a c 1 〇 b u t r a ζ ο 1 )，哩 草（e t h 〇 f u m e s a t e)，快 殺蜱（quinclorac)，燕麥枯（difenzoquat )，草藻 滅（entothall)，調節膜（fosamine) * DSMA ， M S M A v ·與上述的其它類1 1 a相同； w ·與上述的其它類lib相同。 在上組a)至w)中特別好的混用除草劑是m)和v -2 1- 本紙張尺度適用中國國家標準（CNS ) A4規格（210Χ2.97公釐） I.-------(装-- (請先閲讀背面之注意事項再填寫本頁) 訂 A7 B7 五、發明説明（〖/) )組的那些除草劑，即磺醯脲類和三酮類和二酮類。 (請先閲讀背面之注意事項再填寫本頁) 根據本發明，將暖草胺和三酮類結合施用特別適合於 單子葉植物*如毅物、玉米和水稻等。然而，施用於畏滿 單子雜草和雙子葉雜草的玉米作物是最有益的，同時藥劑 對作物的有害作用並沒有提高，用這較佳的混用組合物在 長苗前和長苗後均可施用於有害雜草。但在玉米田中，較 佳的施用時間是玉米苗出現後。 當然结合施用噬草胺和三嗣或二酮的施用劑量將根據 氣候條件、季節、土壤生態、要被殺滅的雜箄等變化，然 而，例如，在结合施用中，三酮的劑量明顯低於其單獮使 用時的推荐劑量可獲得成功的结果，三酮的使用量例如為 0 · 01至2ks/ha ，較佳是0 · 1至lks/h夺，特 別是 0 * 1 至 0 · 6kg/ha。 在上組混合組合物中較佳的是：其中三酮或二嗣選自 4 一 （4 一氛一 2 —硝基苯甲醢基）一2 ，6 ，6 —三甲 基一 2H-1 ，2 —噁嗪—3，5 — (4H，6H)二酮 ，和撒可三酮（ sulcotrione )，用撒可三酮（ sulcotrione)更佳。 此類最佳的混用組合物是撒可三酮（sulcotrione)和 «草胺的組合物。根據具體應用的土壤，作物和氣候條件 確定混合物比率。例如结合施用的比率可在0 . 9至1 . 5kg/ha 的噻草胺和 〇 . 15 至 0 .45kg/ha Sulcotrione的範圍内，在组合物中活性成分噻草胺與撤可 -22- 本紙張尺度逋用中國國家揉準（CNS ) A4規格（2〖0X297公釐） 經濟部中央樣率局貝工消費合作社印製 A7 B7 五、發明説明（x°) 三嗣Sulcotrione的重量比為1 : 2至1 : 1 0。 就較佳的含有睡草胺和V)組的一種三觸和二酮的三 元混合物的结合施用而言，第三種成分最好選自《5 )組， 即三嗪除草劑組。在典型的三元混合物中、三嗪成分相對 於噻草胺含量的比例為3 : 1至1 ·· 3，噻草胺過量是較 佳的，即較佳的比例為1 : 1至1 : 3，例如1 : 1 ，5 。在瑄種類型的三元混合物中，較佳的三嗪除草劑是阿特 拉津（atrazine)。 本發明中结合施用睡草胺和磺醢脲類的混用組合物對 單子葉作物如毅物、玉米、甘蔗和水稻特別適合。例如， 在長滿單子葉雜草和雙子葉雜草的甘蔗田中施用是特別有 益的。在不提高對作物的有害作物的情況下，能非筲有效 地防治雜草。因此混用組合物在長苗前和長苗後均可施用 於有害雜草。可是在甘蔗田中較佳的施用時間為甘蔗苗出 現後，或甘蔗截根苗的移栽後。 當然，结合施用噻草胺和磺醢脲混合物的施用劑量將 視乎氣候條件、季節、土壤生態、要被殺滅的雜草等而定 。然而，例如在结合施用中，磺醢脲的劑量明顯低於其軍 獨使用的推荐劑量，磺醢脲的使用量為例如1至1 50s /ha，較佳為10至100g/ha。 在瑄組防治甘蔗田雜草的混用組合物中，較佳的是其 中磺醢脲為氯嘧磺隆的組合物。根據施用時具體的土壤、 作物和氣候條件可確定混合物比例。例如结合施用比率的 -23- 本紙張尺度逍用中國國家標準（CNS ) A4规格（210X297公釐） ---------(1装-- (請先閲讀背面之注意Ϋ項再填寫本頁) 訂Isoxabenz, oxadiazon, pac 1 〇butra ζ ο 1), eth 〇fumesate, quinclorac, difenzoquat, Entothall, fosamine * DSMA, MSMA v · same as other classes 1 1 a above; w · same as other classes lib above. The particularly good mixed herbicides in the above groups a) to w) are m) and v -2 1- This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210Χ2.97mm) I .----- -(Installed-- (please read the precautions on the back before filling in this page) Order A7 B7 V. Invention Instructions (〖/)) Those herbicides in the group, namely sulfonylurea and triketones and diketones . (Please read the precautions on the back before filling in this page) According to the present invention, the combined application of warm grass amine and triones is particularly suitable for monocotyledonous plants * such as refractory plants, corn and rice. However, it is most beneficial to apply to corn crops that are full of monocotyledonous weeds and dicotyledonous weeds, and at the same time, the harmful effects of the pesticide on the crops have not been improved. This better mixed composition is used both before and after seedling growth. Can be applied to harmful weeds. However, in corn fields, the better application time is after the emergence of corn seedlings. Of course, the combined dosage of glufosinate and tris-dione or dione will vary according to the climatic conditions, seasons, soil ecology, and hybrids to be killed. However, for example, in the combined application, the dosage of triketone is significantly lower The recommended dosage for monotonic use can achieve successful results. The amount of triketone used is, for example, 0.01 to 2ks / ha, preferably 0.1 to lks / h, especially 0 * 1 to 0. 6kg / ha. In the above mixed composition, it is preferred that the triketone or dioxin is selected from 4-one (4-ambient 2-nitrobenzyl) -2,6,6-trimethyl-2H-1 , 2-oxazine-3,5- (4H, 6H) dione, and sulcotrione, sulcotrione is better. The best mixed composition of this type is a combination of sulcotrione and «oxachlor. The mixture ratio is determined according to the specific application of soil, crops and climatic conditions. For example, the combined application rate may be in the range of 0.9 to 1.5 kg / ha of alafen and 0.15 to 0.45 kg / ha Sulcotrione. The size of this paper is printed using the Chinese National Standard (CNS) A4 (2 〖0X297mm). The A7 B7 is printed by the Beigong Consumer Cooperative of the Central Sample Bureau of the Ministry of Economic Affairs. 5. Description of the invention (x °) The weight ratio of Sanji Sulcotrione is 1: 2 to 1: 1 0. For the preferred combined application of a ternary mixture of triamcinol and diketone containing hylachlor and group V), the third component is preferably selected from group "5), namely the triazine herbicide group. In a typical ternary mixture, the ratio of the triazine component relative to the content of alafen is 3: 1 to 1 · 3, and the excess of alafen is preferred, that is, the preferred ratio is 1: 1 to 1: 3, for example 1: 1, 5. Among the ternary mixtures of Xuan types, the preferred triazine herbicide is atrazine. In the present invention, the combined application of a combination of hylachlor and sulfonylureas is particularly suitable for monocotyledonous crops such as refractory plants, corn, sugarcane and rice. For example, application in sugarcane fields overgrown with monocotyledonous and dicotyledonous weeds is particularly beneficial. It can effectively control weeds without increasing harmful crops. Therefore, the mixed composition can be applied to harmful weeds before and after seedling growth. However, the preferred application time in sugarcane fields is after the emergence of sugarcane seedlings, or after the transplantation of sugarcane root cuttings. Of course, the combined application dosage of the mixture of chlorfenapyr and sulfonylurea will depend on climatic conditions, seasons, soil ecology, weeds to be killed, etc. However, in combination administration, for example, the dose of sulfonylurea is significantly lower than the recommended dose for military use alone, and the amount of sulfonylurea used is, for example, 1 to 150 s / ha, preferably 10 to 100 g / ha. In the mixed composition for controlling weeds in sugarcane fields in the Xuan group, a composition in which sulfonylurea is chlorimuron-methyl is preferred. The mixture ratio can be determined according to the specific soil, crop and climatic conditions at the time of application. For example, in combination with the application rate of -23- this paper scale is easy to use the Chinese National Standard (CNS) A4 specification (210X297 mm) --------- (1 pack-- (please read the note Ϋ item on the back first Fill in this page)

C A7 B7 300157 五、發明说明（〆） 實例是在〇 ‘ 9至3 · Okg/ha的暖草胺和1 0至1 0 〇容/11&的氛喃確隆（（：111〇1*181111>011) 範圍内。就殺滅 甘蔗作物中的莎草科雜草（cyperus spp )而言，例如混 用組合物可為2 · 0至3 · 0 kg/ ha的噻草胺和50至 9 0 g. / h a的氛啼磺隆（chlorimuron )。在組合物中 活性成分氯嘧磺隆（chlorimuron )和噻草胺的重量比在 1 : 3000至1 : 20之間，較佳為1 : 30至1 : 6 〇，例如1:34或1:38或1:45。 就較佳的含有噻草胺和m)組的一種磺醢脲的三元混 合物的结合施用而言，第三種成分最好選自i )組，即脲 類除草劑組。在典型的三元混合物中，脲類成分相對於睡 草胺含量的比例為2 : 1至1 : 4 *用過董的唾草胺是較 佳的，即較佳的比例為1 : 1至1 : 3，例如1 : 2。在 瑄種類型的三元混合物中，較佳的脲類除草劑是敵草隆。 顯而易見，睡草胺與多於一種的除草劑的混合物，例 如，三元混合物也包含在本發明範圍内。 具體的混用除草劑的實例可選自下述的例子：對草快 (paraquat)(例如 G R A Μ 0 X 0 N E ® 或 GRAM〇X0NE®EXTRA)，西瑪津（sifflazine )(例如 PRINCE P®)、箄甘膦（glyphosate)( 例如，ROUNDUP®)、草銨膦（glufosinate)( 例如B A S T A ® )(第I組化合物）° 更具體的混.用除草劑的實例可選自下述實洌：阿特拉 -24- 本紙珉尺度適用中國國家橾準（CNS > A4规格（210X297公釐） ---------1 II (請先閱讀背面之注意事項再填寫本頁) 訂 經濟部中央揉準扃負工消费合作社印装 經濟部中央標準局負工消费合作社印簟 A7 ____B7__ 五、發明説明（分） 津（atrazine)、草淨津（cyanazine)(例如 BLADEX®或與阿特拉津一起的extRAZ I NE ®SE XT RAZ I N E ® I)、特丁津（terbutylazine ')、安硝草（pendimethalin)(例如 PROWL®)、嚷 草釅（metribuzin)、利谷隆（linuron)(第I組化合物 )。 更具强的混用除草劑的實例可選自下述實例： 尼可磺隆（nicosulfuron)(例如 ACCENT®)、瑞 磺隆（rinsulfuron)(例如T I TUS®)和吡嘧磺隆（ primisulfuron)(例如 BEACON®)(第 HI 組化合 物）0 更具體的混用除草劑的實例可選自：撲殺特（. imazethapyr )(例如 PURSUIT®) 、iieazaquin (例如 SCEPTER®)、草滅平（chloramben)、苯 草醚（aclonifen)(第IV組化合物）。 更具體的混用除草劑的實例可選自··麥箄畏（dicamba )〔例如BANVEL®，CLARITY® (MDGA 塩形式）或與阿特拉津Utrazine) —起稱 MARKSMAN®] ° 更具體的混用除草劑的實例可選自：稀禾定（ sethoxydim)(例如 POAST®) 、tt 氟禾草® ( fluazifop)(例如 FUSILADE®)(第 V 組化合物 )0 -2 5- 本紙張尺度逋用中國國家標準（CNS ) A4规格（210X297公董) ---------ΛΛ衣-- (請先閲讀背面之注意事項再填寫本頁) 訂 經濟部中央揉準局負工消费合作社印裝 A7 B7 五、發明説明（乃） 更具體的混用除箄劑的實例可選自：撤可三酮（ sulcotrione)例如 MIKADO®)和 4 - (4 -氮一2 一硝基一苯甲醢基）一2，6，6 —三甲基一 2H — 1 ， 2 —噁嗪一 3，5 — （4H，6H)二嗣（第VI組化合物 )。 3 —元混合物更具賭的混用除草劑實例為撒可三酮（ sulcotrione)(例如 MIKADO ®)和阿特拉津（ atrazine)(例如 GESAPRIM®)(第 Via 組化合 物）。 更具體的混用除草劑的實例包括氱嘧磺隆（ chlorinuron)(例如C L A S S I C ®或與敵草隆一起的 三元混合物稱FRONT®)(第W組化合物）。. 根據需要防治的雜草譜（weed spectrum )、施用時 間等，列於上述a)至w)組的其它具體除草劑也可為缠 合的混合除草劑的具體實例。 實施例1 稱璽活性成分並溶於由1:1丙酮：去雄子水，和5 %由1 : 1 : 1 表面活性劑 SPAN®20 : TWEEN ®20 : TWEEN®8 5組成的輔肋混合物組成的原疲 中。稀釋此原液以進行噴霧液的製備，噴霉液由單劑量的 單獨和混合活性成分組成，借肋線性霧化嗔霧器K6 0 0 升/公頃噴孩體積同時施用各種劑量，長苗後施用至所選 擇種類的雜草苗的葉面，且長苗前用至事先播種種子表面 -26- 本紙張尺度適用中國國家揉準（CNS ) A4规格（210X297公釐） ---------Λ装-- (請先閲讀背面之注意事項再填寫本頁) 訂C A7 B7 300157 V. Description of the invention (〆) Examples are warm grass amine at 〇 '9 to 3 · Okg / ha and 10 to 10 〇 Rong / 11 & 181111 > 011). In terms of killing cyperus spp in sugarcane crops, for example, the mixed composition may be 2 · 0 to 3.0 kg / ha of clothianidin and 50 to 9 0 g./ha of chlorimuron. The weight ratio of chlorimuron and chlorfenuron in the composition is between 1: 3000 and 1:20, preferably 1: 30 to 1: 6 〇, such as 1:34 or 1:38 or 1:45. For the preferred combined application of a ternary mixture containing sulfasal and m) group sulfonylurea, the third The ingredients are preferably selected from group i), namely the urea herbicide group. In a typical ternary mixture, the ratio of the urea component relative to the content of sleepy amine is 2: 1 to 1: 4 * used salidomide of Dong is preferred, that is, the preferred ratio is 1: 1 to 1: 3, for example 1: 2. In the ternary mixture of Xuan type, the preferred urea herbicide is diuron. Obviously, a mixture of hylachlor and more than one herbicide, for example, a ternary mixture is also included within the scope of the present invention. Examples of specific mixed herbicides can be selected from the following examples: paraquat (eg GRA Μ 0 X 0 NE ® or GRAM〇X0NE® EXTRA), sifflazine (eg PRINCE P®) , Glyphosate (for example, ROUNDUP®), glufosinate (for example, BASTA ®) (Group I compounds) ° More specific mixing. Examples of herbicides can be selected from the following: Atla-24- This paper Min standard is applicable to China National Standard (CNS & A4 specifications (210X297mm) --------- 1 II (please read the precautions on the back before filling in this page) Printed by the Central Ministry of Economic Affairs, Negative Workers ’Consumer Cooperative Printed A7 ____B7__ of the Ministry of Economic Affairs, Central Bureau of Standards, and the Negative Workers’ Consumer Cooperative Fifth. Invention Description (Minutes) Atrazine, Caojingjin (eg BLADEX® or ExtRAZ I NE ® SE XT RAZ INE ® I) with terazin, terbutylazine ', pendimethalin (eg PROWL®), metribuzin, linuron (Group I compounds). Examples of stronger mixed herbicides can be selected from the following examples: Nicole Nicosulfuron (e.g. ACCENT®), rinsulfuron (e.g. TI TUS®) and primisulfuron (e.g. BEACON®) (Group HI compounds) 0 More specific mixed herbicides Examples may be selected from: imazethapyr (eg PURSUIT®), iieazaquin (eg SCEPTER®), chloramben, aclonifen (Group IV compounds). More specific mixed herbicides Examples can be selected from dicamba (eg BANVEL®, CLARITY® (MDGA 塩 form) or with Atrazine Utrazine)-known as MARKSMAN®] ° More specific examples of mixed herbicides are optional From: sethoxydim (e.g. POAST®), tt fluazifop (fluazifop) (e.g. FUSILADE®) (Group V compounds) 0 -2 5- This paper scale uses the Chinese National Standard (CNS) A4 Specifications (210X297 public director) --------- ΛΛ clothing-- (please read the notes on the back before filling in this page) Order A7 B7 Printed by the Ministry of Economic Affairs Central Counseling Bureau Cooperative Consumer Cooperative V. Invention Description (NO) More specific examples of mixed scavengers can be selected from: withdrawal triketone (s ulcotrione) such as MIKADO® and 4-(4 -nitrogen 2 -nitronitrobenzyl)-2,6,6-trimethyl mono 2H-1, 2, 2-oxazine mono 3, 5-(4H , 6H) Er Si (Group VI compound). Examples of 3-component mixed herbicides are sulcotrione (eg MIKADO®) and atrazine (eg GESAPRIM®) (Group Via compounds). More specific examples of mixed herbicides include chlorinuron (eg CLASSIC® or the ternary mixture with diuron called FRONT®) (Group W compounds). . According to the weed spectrum to be controlled (weed spectrum), application time, etc., other specific herbicides listed in groups a) to w) above may also be specific examples of entangled mixed herbicides. Example 1 The active ingredient of the seal is weighed and dissolved in a 1: 1 acetone: deionizing water, and 5% auxiliary rib mixture consisting of 1: 1 surfactant SPAN®20: TWEEN®20: TWEEN®85 The original fatigue. This stock solution was diluted to prepare a spray solution. The mold spray solution consisted of a single dose of separate and mixed active ingredients. The rib linear atomizer mist sprayer K600 liter / ha spray volume applied various doses simultaneously, after the seedlings were applied To the leaf surface of the selected species of weed seedlings, and use them before planting to the surface of the seeds sowed in advance -26- This paper size is applicable to the Chinese National Standard (CNS) A4 (210X297mm) ------- --Λ 装-(Please read the precautions on the back before filling this page)

央 揉 準 局 貝 工 A7 B7 消 费 合 作 社 五、 發明説明（xf) -1 1 〇 使 用 的秧 苗 培着至 植物 株 發 育 的 二 葉 期 或三 葉 早 期 0 記 1 1 錄 施 用 時每 種 苗的發 育葉 期 0 施 用 後 將 處理 植 物 移 溫 室 1 請 | 至 實 驗结 束 保持四 周。 長 苗 後 施 用 後 二 和十 天 和 長 苗 v 刖 先 閲 I 施 用 後 十四 天 記鏵損 害的 症 狀 0 長 苗 後 施 用十 和 二 十 八 天 讀 背 1 Λ I 和 長 苗 則施 用 十四和 二十 八 天 巨 測 作 物 傷害 和 雜 草 防 治 之 注 | 意 I 百 分 率 〇 事 項 1 I 混 用噻 草 胺和如 上述 概 括 的 其 它 具 體 活性 成 分 與 施 再 填 1 Λ 本 装 用 每 種 單獨 活 性成分 相比 產 生 了 提 高 的 除 草效 果 0 頁 1 I 實 施 例 2 1 1 使 用噻 草 胺（F R 0 N T I E R ® ) 7 . 5 乳 油 和 尼 1 1 可 磺 隆 (n i c 〇 sulfuron) ( A C C E N T ® ) 7 5 水 分 散 1 订 1 I 粒 劑 進 行田 間 追综試 驗在 玉 米 田 防 治 馬 唐 (la rge C Γ abgrass) < >在雑草的長苗後早基 (3和4葉期） 施用桶 1 混 組 合 物， 活 性成分 的施 用 劑 量 為 1 5 和0 7 5 k8 / 1 1 h a 的 唾草 胺 和 3 7 . 2 和 1 9 2 / h a 的 尼 可 磺 1 隆 (n i c 〇 s u If uron) *混 合 施 用 0 7 5 kg / h a 的 唾 草 1 1 胺 和 1 9 . 2 s / h a的 尼 可 磺 隆 (ni C 0 sulfur ο η ) 得 到 1 1 f 8 5 % 的防 治 率，對 玉米 的 損 害 微 不 足 道 ，與 之 相 比 單 獨 1 1 施 用 1 9 . 2 8 / h a的 尼 可 磺 隆 ( n i C 0 sulfur on) 防 治 1 1 率 為 3 5 % 〇 且在稍 高的 劑 量 1 • 2 5 S / h a 施 用 睡 草 1 I 胺 的 防 治率 為 7 2 % ，在 略 高 劑 1 的 睡 草 胺與 3 7 ♦ 2 1 1 1 / h a 的尼 可 磺隆（ n i c 〇 S U 1 f ur on) 混 合 施用 得 到 了 更 1 1 顯 著 的 效果 9 防治率 為9 5 % 相 比 之 下 ，各 單 獮 施 用 1 1 - 27 • 1 1 本紙張尺度適用中國國家揉準（CNS ) A4規格（2丨0X297公釐） 經濟部-t央橾準局—工消费合作社印裂 A7 _B7____ 五、發明説明（^) 噻草胺的防治率為7 2%且尼可磺隆（nicosul fur on)僅 為 4 5 %。 實施例3 在玉米用單位小區中，用噻草胺和撤可三酮（ sulcotrione )的桶混懸浮疲噴蓀處理長滿稗草（ echinochloa crus galli )和龍葵（solanum nigrum)。 雜草的生長階段為稗草完全分蘖（ful 1 tillering)且龍 葵為“ 8 —葉期”。小區的大小為8米長和3米寬。施用 劑量為1 * lkg/ha的噻草胺和0 · 15kg/ha撒可 三酮（sulcotrione)，處理t天後評價對雜草的防治率和 作物的耐受性。 在此試驗的三次重複中，對稗草的防治率在9 3和 98%之間·且對龍葵的防治率在9 1和93%之間，同 時對玉米植物的損害全部低於1 0%。 實施例4 在玉米田單位小區中，用唾草胺（dimethanamid)， 撖可三酮（sulcotrione)和阿特拉津（atrazine)的桶混 懸浮液*處理長滿的稗草、龍葵和藜（chenopodium)。雜 草的生長期為稗草M完全分蘖”且龍努和藜為“6 - 8葉 期”，小區的大小為8米長和3米寬。施用劑量為1·0 8kg/ha的噻草胺，150或2 10g/ha的撤可三 _ (sulcotrione)和 750 g/h a的阿特拉津，處理 14天後評價處理效率。结果（防治百分率）如下逑： -2 8 - 本紙3L尺度適用中國國家標準（CNS ) A4规格（210X297公釐） 11_·----------訂丨丨^——io (請先閲讀背面之注意事項再填寫本頁)A7 B7 Consumer Cooperatives of the Central Administration Bureau V. Invention description (xf) -1 1 〇The seedlings used are cultivated to the second or early three-leaf stage of the plant development. 0 Move the treated plants to the greenhouse after application. 1 Please keep it for four weeks until the end of the experiment. Two and ten days after the application of long seedlings and long seedlings v. First reading I. Fourteen days after the application of the symptom of the damage of the 0 0 Ten and twenty-eight days after the application of the seedlings. 1 Λ I and fourteen of the long seedlings And 28-day test of crop damage and weed control | Italian I Percentage ○ Matter 1 I Mix chlorfenapyr and other specific active ingredients as outlined above and refill 1 Λ This package uses each individual active ingredient phase The herbicidal effect is improved than 0. Page 1 I Example 2 1 1 Using tefenazone (FR 0 NTIER ®) 7.5 Emulsion and nicolasulfonate (nic 〇sulfuron) (ACCENT ®) 7 5 Water dispersion 1 set 1 I granules for field follow-up test in the corn field to control horse tang (la rge C Γ abgrass) < > Apply the bucket 1 mixed composition to the early base (3 and 4 leaf stage) of the long grass after the seedling growth, The dosage of active ingredient is 1 5 and 0 7 5 k8 / 1 1 ha of salidomide and 3 7.2 and 1 9 2 / ha of niclosulone (nic 〇su If uron) * Mixed application of 0 7 5 kg / ha of saliva 1 1 Amine and 19.2 s / ha nicosulfuron (ni C 0 sulfur ο η) gave a control rate of 1 1 f 8 5%, and the damage to the corn was negligible, compared with 1 1 alone applied 1 9. 2 8 / ha ni C 0 sulfur on (ni C 0 sulfur on) control 1 1 rate is 35% 〇 and at a slightly higher dose 1 • 2 5 S / ha application of sleeping grass 1 I amine control rate 7 2 %, The mixed application of clinamide in the slightly higher agent 1 and 3 7 ♦ 2 1 1 1 / ha niclosuron (nic 〇SU 1 f ur on) gave a more significant effect 1 1 a significant effect 9 a control rate of 9 5% By comparison, each paper application is 1 1-27 • 1 1 The paper size is applicable to the Chinese National Standard (CNS) A4 (2 丨 0X297mm) Ministry of Economic Affairs-Tyangju Bureau of Industry-Consumer Cooperative印 裂 A7 _B7____ V. Description of the invention (^) The control rate of tefenacet is 7 2% Mesosulfuron (nicosul fur on) was only 45%. Example 3 In a unit plot for corn, the barnyardgrass (echinochloa crus galli) and nightshade (solanum nigrum) were treated with bucket suspension of tetrochlor and sulcotrione. The growth stage of weeds is full barnyardgrass (ful 1 tillering) and the nightshade is "8-leaf stage". The size of the cell is 8 meters long and 3 meters wide. The application dose was 1 * lkg / ha alafenamide and 0.15kg / ha sulcotrione, and the treatment rate and weed tolerance were evaluated after t days of treatment. In the three repeats of this experiment, the control rate of barnyard grass was between 93 and 98%, and the control rate of solanum was between 91 and 93%, while the damage to corn plants was all less than 1 0 %. Example 4 In a cornfield unit plot, the overgrown barnyard grass, solanum and quinoa were treated with a barrel mixed suspension of dimethanamid, sulcotrione and atrazine (Chenopodium). The growing period of weeds is barnyard grass M complete tiller "and Longnu and Chenopodium are" 6-8 leaf stage ", the size of the plot is 8 meters long and 3 meters wide. The application dose is 1.08 kg / ha of chlorfenapyr , 150 or 2 10g / ha withdrawing three _ (sulcotrione) and 750 g / ha atrazine, after 14 days of treatment to evaluate the treatment efficiency. The results (percentage of prevention) are as follows: -2 8-This paper is applicable to the 3L scale China National Standard (CNS) A4 Specification (210X297mm) 11_ · ---------- Subscribe 丨 丨 ^ ---- io (Please read the notes on the back before filling this page)

7 B 五、發明説明（>) 經濟部中央橾準局工消费合作社印製 化合物a. i. /ha 稗草 防治率 預期的 加合效果 增效 作用 阿特拉津1500 23 一 噻草胺/阿特拉津1080/750 30 — 撤可三酮（sulcotrione)/ 阿特拉津1 50/7 50 26 — 撒可三酮（sulcotrione)/ 阿特拉津210/750 33 — 噻草胺/撤可三嗣（sulcotrione) 阿特拉津 /1080/ 1 50/7 50 95 56 + 39 噻草胺/撒可三酮（sulcotrione) 阿特拉津1080/21Q/750 97 59 + 42 龍葵/藜 -29- 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐） ---------4装-- (請先閲讀背面之注意事項再填寫本頁) 訂 t A7 B7 五、發明説明（） 睡特拉津1500 16 噻草胺/阿特拉津1080/750 36 一 撒可三酮（sulcotrione)/ 阿特拉津150/750 23 一 撤可三萌（sulcotrione)/ 阿特拉津210/750 53 一 噻草胺/撒可三酮（sulcotrione) 阿特拉津 1080/ 150/750 97 53 .+44 睡箄胺/撤可三嗣（sulcotrione) 阿特拉津108Q/21Q/750 100 89 + 11 ---------A^c------訂------A (請先閲讀背面之注$項再填寫本頁) 經 央 橾 準 局 合 作 社 印 製 在較低劑量的撖可三酮（sulcotrione)下，增效作用（ synergistic effect)淸晰或可見，與期望的加合作用·（ additive effect )相比，结果接近兩倍的防治率，在較 高劑董的撤可三酮（sulcotrione) (> 3 0 0 g/ha) 由於總的防治率為1 00%，僅可見加合效果。 實施例5 在種植有甘蔗的小區上（2X2 Om)進行田間追踪 -30-本紙浪尺度逋用中國國家標準（CNS > A4規格（210X297公釐）7 B V. Description of the invention (>) The compound ai / ha barnyardgrass control rate printed by the Ministry of Economic Affairs, Central Bureau of Industry and Consumer Cooperatives, the expected additive effect, synergistic effect, atrazine 1500 23 monothiachlor / art Lazine 1080/750 30 — sulcotrione / atrazine 1 50/7 50 26 — sulcotrione / atrazine 210/750 33 — alafenamide / withdrawal three Sulcotrione atrazine / 1080/1 50/7 50 95 56 + 39 thiachlor / sulcotrione atrazine 1080 / 21Q / 750 97 59 + 42 solanum / quinoa-29 -This paper scale is applicable to China National Standard (CNS) Α4 specification (210X297mm) --------- 4 packs-- (please read the precautions on the back before filling this page) Order t A7 B7 5. Description of the invention () Sleeping atrazine 1500 16 alafenamide / atrazine 1080/750 36 sulcotrione / atrazine 150/750 23 sulcotrione / atr Lazin 210/750 53 monothiachlor / sulcotrione Atrazine 1080 / 150/750 97 53. + 44 sleptamine / sulcotrione Ater Jin 108Q / 21Q / 750 100 89 + 11 --------- A ^ c ------ order ------ A (please read the note $ item on the back before filling this page) Printed at a lower dose of sulcotrione by the Central Cooperative Bureau of Cooperative Bureau, the synergistic effect is clear or visible, and the results are close to the expected additive effect With twice the control rate, the sulcotrione (> 3 0 0 g / ha) in the higher agent Dong can only see the additive effect due to the total control rate of 100%. Example 5 Field tracking is carried out on the plot (2X2 Om) where sugarcane is planted -30-This paper uses the Chinese national standard (CNS > A4 specification (210X297mm)

A B7 五、發明説明（>3) 試驗，小區長滿第一或第二生長階段的香附子（cyperus rotundus)，並用背負式唄霧器噴霧不同濃度的桶混合物 。唄霧液量為400 Ι/ha。施用劑量為2 · 7kg/ h a的睡草胺和6 0 s/h a的氣嘧磺隆（chlorimuron) ，或和1 · 6丨《 / ha的固定比例的氯嘧磺隆和敵草隆（ diuron) (1 : 19)的混合物，該混合物可從商業上的 F R 0 N T ®得到。處理3 0或6 0天後（D A T )目測 評價防治百分率。根據Colby方法計算預期的加合作用： ---------M装-- (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標率局負工消费合作社印裝 化合物條件 香附子（cyperus) 預期的加合 增效效果 防治率（DAT) 效果 輕鬆培養土 «草胺2.7kg 19(60DAT) 一 氯嘧磺隆/敵草隆1.6kg 45(60DAT) 一 睡草胺/氮嘧磺隆/ 敵草隆2.7 + 1.61¾ 76(60DAT) 55 + 21 粘重土 唾草胺2.71« 10(60DAT) 一 氯嘧磺隆/敵草隆1.6kg 37(60DAT) _ 睡草胺/氮嘧磺隆/ -31- 本纸張尺度逋用中國國家梂準（CNS ) A4規格（210X297公釐）A B7 V. Description of the invention (> 3) In the experiment, the plot was overgrown with Cyperus rotundus in the first or second growth stage, and a knapsack mist sprayer was used to spray the barrel mixture of different concentrations. The amount of mist is 400 Ι / ha. The application dose is 2.7 kg / ha of clinochlor and 60 s / ha of chlorimuron, or a fixed ratio of chlorimuron and diuron of 1. 6 ) (1: 19) mixture, which is commercially available from FR 0 NT ®. After 30 or 60 days of treatment (D A T), visually evaluate the percentage of prevention and treatment. Calculate the expected additive cooperation according to the Colby method: --------- M equipment-- (Please read the precautions on the back before filling in this page) The conditions for printing compound compounds of the Consumer Labor Cooperative of the Central Standard Rating Bureau of the Ministry of Economic Affairs Cyperus (cyperus) Expected additive synergistic effect control rate (DAT) effect Easily cultivate soil «oxachlor 2.7kg 19 (60DAT) chlorsulfuron / diuron 1.6kg 45 (60DAT) asleep grass / nitrogen Sulsulfuron / Diuron 2.7 + 1.61¾ 76 (60DAT) 55 + 21 Claytonyl Salidomide 2.71 «10 (60DAT) Chlorimuron / Diuron 1.6kg 37 (60DAT) _ Sleeping grass / Azurasulfuron / -31- This paper uses the Chinese National Standards (CNS) A4 specifications (210X297mm)

、1T 經濟部中央樣準局負工消费合作社印装 A7 B7 五、發明説明ph 敵草隆2.7 + 1.6kg 74(60DAT) 43 + 31 輕鬆培養土 噻草胺2·. 25kg 23(30DAT) — 氛啼磺隆/敵草隆1.2kg 48(30DAT) — 睡草胺/氛嘧磺隆/ 敵草隆 2.25 + 1.21¾ 80(30DAT) 60 + 20 輕鬆培養土 噻草胺2.7kg 27(30DAT) — 氮嘧磺隆/敵草隆1.6kg 48(30DAT) — 噻草胺/氛嘧磺隆/ 敵草隆2.7 + 1.2kg 88(30DAT) 62 + 26 輕鬆培養土 噻草胺2.7kg 27(30DAT) — 氛嘧磺隆Q.06kg 58(30DAT) 一 睡草胺/氛嘧磺隆 2.7 + 0.06kg 93(30DAT) 69 + 24 獲得的结果表明2元混合物（噻草胺/氛嘧磺隆）， K及3元混合物（噻草胺/氮嘧磺隆/敵草隆）都具有增 效效果。 -32- 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X 297公釐） ^装 訂 ^ΛΓ (請先閲讀背面之注意事項再填寫本頁) 公 Μ -—~ 1 一 補充 附件 除草性試驗報告 除草__草胺與一或二種其他除草活性成分之多種组 合型式，已針對共闻旌用於雜草時的活性進行謂査。得到 的结果輿嚐草胺及其他除草ϋ單獨廳用時的活性進行比較 。组合型式之期望活性自根雄Colby的方法（Weeds, 15, 1967 ,第20至22頁）所達成的结果計算出來，而使用下列 計算式： 針對兩種成分的濡合物 E = 100 -〔（100-An) ( 1 0 0 - B m ) /10 0〕 針對三種成分的混合物 > E=100 -〔（100-An) ( 1 0 0 - B m ) (100-Ck) /100〕、 1T Printed by the Ministry of Economic Affairs, Central Bureau of Samples and Consumers Cooperatives A7 B7 V. Description of the invention ph diuron 2.7 + 1.6kg 74 (60DAT) 43 + 31 Easily cultivate terachlor 2. 25kg 23 (30DAT) — Texasulfuron / Diuron 1.2kg 48 (30DAT) — Pyridoxine / Fensulfuron / Diuron 2.25 + 1.21¾ 80 (30DAT) 60 + 20 Easily cultivate chlorfenapyr 2.7kg 27 (30DAT) — Azurasulfuron / Diuron 1.6kg 48 (30DAT) — Thiachlor / Fensulfuron / Diuron 2.7 + 1.2kg 88 (30DAT) 62 + 26 Easily cultivate chlorfenapyr 2.7kg 27 (30DAT ) — Sulfasulfuron Q.06kg 58 (30DAT) Monoclofen / pyrsulfuron 2.7 + 0.06kg 93 (30DAT) 69 + 24 The results obtained indicate a binary mixture (thiachlor / fensulfuron), K and ternary mixtures (thiachlor / azasulfuron / diuron) have synergistic effects. -32- This paper scale is applicable to China National Standard (CNS) Α4 specification (210X 297mm) ^ Binding ^ ΛΓ (please read the precautions on the back before filling in this page) Gong Μ -— ~ 1 A supplementary attachment for weeding The test report herbicide __ various combinations of glufosinate and one or two other herbicidal active ingredients. The results obtained were compared with the activity of tasting amine and other herbicides when used alone. The expected activity of the combined type is calculated from the results obtained by the method of the root male Colby (Weeds, 15, 1967, pages 20 to 22), and the following formula is used: for the two-component compound E = 100-[ (100-An) (1 0 0-B m) / 10 0] For a mixture of three components> E = 100-[(100-An) (1 0 0-B m) (100-Ck) / 100]

在逋些混合《期望活性之計算方法中 E表示包含比例η之化合物A 比例m之化合物B及（若為三種成份的混 合物> 比例k之化合物C 之混合物的期望活性》 力法：長苗後除草性施用 将活性成份稱重，並溶解於包括丙酮：去離子水為1 :1及Ο. 5%佐爾滙合物之貯備溶液中，該佐_混合物 包活界面活性劑SPAN®20 : TWEEN®20 : TWEEN®85 1 : 1 : 1。來自該貯備溶液之稀釋 液可供包括瘺別或馨合活性成份之單一投麵两量嗔灌溶液 之製備。當施用時，毎種投_薄量經由鎳性軌道«灞罌闻 時施用，将6 0 0公升/公頃噴钃腰稹翰送至經挑灌雜草 苗種的葉及土壤表面。使用的幼苗經培餐至植物發育到用 葉或早期三藥階段後，施用受試化合物的组合型式。在施 用期間記錄毎株幼苗之發育指段。喷漏施用後，《理遍的 植物進入鸛室並維持到在四週内的實驗结束。施用後第2 天及第10天記錄損傷的表徽。對照组雜草於施用後二至 四通進行肉眼百分比分级。 受試雜草為： 2In some mixtures, "In the calculation method of the expected activity, E represents the compound A containing the ratio η, the compound B in the ratio m, and (if it is a mixture of three components> the desired activity in the mixture of the compound C in the ratio k." After the herbicidal application, the active ingredients are weighed and dissolved in a stock solution including acetone: deionized water of 1: 1 and 0.5% Zor conjugate, the adjuvant mixture contains the active surfactant SPAN® 20 : TWEEN®20: TWEEN®85 1: 1: 1. The diluent from this stock solution can be used to prepare two doses of single-dose irrigation solution including fistula or fragrant active ingredients. When applied, each dose _The thin amount is applied through the nickel track «Ba Pian Wen Wen, and 600 liters / hectare is sprayed to the leaves and soil surface of the pickled weed seedlings. The seedlings used are cultivated to plant development After the use of leaves or the early three-drug stage, the combination type of the test compound was applied. During the application period, the development finger segments of each seedling were recorded. After the spray application, "the plants that entered the stork room were maintained and maintained within four weeks. End of the experiment. On the 2nd and 10th day after application Table emblem weed control injury was visually graded percentage after administration two to four-way test weeds: 2

種 類 俗 名 代 碼 Abutilon theophrasti velvetleaf ABUTH Capsella bursa-pastoris shepherdspurse CAPBP Cassia obtusifolia sicklepod CASOB Chenopodium album common lambsquarters CHEAL Galium aparine catchweed bedstraw GALAP Matricaria chamomilla wild chamomile MATCH . Ipomoea purpurea tall morning glory PHBPU Polygonum aviculare prostate knotweed POLAV Portulaca oleracea common purslane POROL Senecio vulgaris common groundsel SENVU Sida spinosa pricldy sida SIDSP Solanum nigrum black night-shade SOLNI Stellaria mechia common chickweed STEME Xanthium strumarium common cocklebur XANST Alopecurus myosuroides slender foxtail ALOMY Avena fatua wild oats AVEFA Brachiaria platyphylla broadleaf signalgrass BRAPP Bromus tectorum downy brome BROTE Panicum miliaceum proso millet PANMI Poa annua annual bluegrass POAAN Setaria faberi giant foxtail SETFA Sorghum halepense johnsongrass SORHA -3- 133-0706 受試化合物以商業上可用型式加以施用Type common name code Abutilon theophrasti velvetleaf ABUTH Capsella bursa-pastoris shepherdspurse CAPBP Cassia obtusifolia sicklepod CASOB Chenopodium album common lambsquarters CHEAL Galium aparine catchweed bedstraw GALAP Matricaria chamomilla wild chamomile MATCH. vulgaris common groundsel SENVU Sida spinosa pricldy sida SIDSP Solanum nigrum black night-shade SOLNI Stellaria mechia common chickweed STEME Xanthium strumarium common cocklebur XANST Alopecurus myosuroides slender foxtail ALOMY Avena fatua wild oats AVEFA Brachiaria broadleaf aria FAs PANMI Poa annua annual bluegrass POAAN Setaria faberi giant foxtail SETFA Sorghum halepense johnsongrass SORHA -3- 133-0706 The test compound was applied in a commercially available form

Dimethenamid, 以 FRONTIER 900 EC 施用 Chloridazon, PYRAMIN 65 WP 以 施用 Norflurazon, 以 ZORIAL 80 WP 施用 Phenmedipham, 以 BETANAL 157 EC AllS /TJ 施用 Metamitron, 以 GOLTRIX 70 WG 施用 Bentazone, 以 BASAGRAN 480 EC 施用 Metribuzin, 以 SENCOR 70 WG 施用 Triflusulfuron-methyl, 以 SAFARI 50 WG 施用 Nicosulfuron, 以 .ACCENT 75 WG 施用 Haloxyfop-R-methyl, 以 ELOGE 104 EC 施用 Fenoxaprop-P-ethyl, 以 PUMA S 75 EC 施用 Clodinafop-propargyl, 以 TOPIK 300 EC 施用 Diclofop-methyl, 以 ELLOXAN 360 EC· 施用 Prodiamine, 以 RIDES 50 WP 施用 Glyphosate, 以 ROUNDUP 360 SL 施用 Lenacil, 以 VENZAR 80 WP 施用 Dicamba, 以 BANVEL 480 SL 施用 Pyridate, 以 LENTAGRAN 45 WP 施用 Pyridate/Dicamba, 以 LENTAGRAN 450 EC/BANVEL 480 SL Amitrole, 以 AMITRIL TL 240 EC 施用 施用 得到的結果如下 -4- 133-0706 表_1 ··:除草性效果_Dimethenamid, FRONTIER 900 EC, Chloridazon, PYRAMIN 65 WP, Norflurazon, ZORIAL 80 WP, Phenmedipham, BETANAL 157 EC AllS / TJ, Metamitron, GOLTRIX 70 WG, Bentazone, BASAGRAN 480 EC, Metribuzin Triflusulfuron-methyl for WG, Nicosulfuron for SAFARI 50 WG, Haloxyfop-R-methyl for ACCENT 75 WG, Fenoxaprop-P-ethyl for ELOGE 104 EC, Clodinafop-propargyl for PUMA S 75 EC, TOPIK 300 EC Diclofop-methyl, Prodiamine as ELLOXAN 360 EC, Glyphosate as RIDES 50 WP, Lenacil as ROUNDUP 360 SL, Dicamba as VENZAR 80 WP, Pyridate as BANVEL 480 SL, Pyridate / Dicamba as LENTAGRAN 45 WP, The results obtained by applying LENTAGRAN 450 EC / BANVEL 480 SL Amitrole and applying AMITRIL TL 240 EC are as follows-4- 133-0706 Table_1 ·: Herbicidal effect_

Dimethenamid/Chloridazon 處理後評估2 2天Dimethenamid / Chloridazon evaluation 2 2 days after treatment

Chloridazon 克活性成份 /公頃 0 4( Μβ Ifi Dim 30 發湞値 ethenamid 6( 期望嗔 克活性成ί X) 發;;Ιτ暄 &/公頃 8C 期望暄 )0 發漓値 GALAP 0 0 0 0 0 1200 0 0 100 0 100 0 100 1800 70 70 100 70 100 70 100 2400 100 100 100 100 100 100 90 MATCH 0. 0 0 10 10 1200 80 80 70 82 100 82 100 1800 70 70 80 73 100 83 90 2400 90 90 100 . 91 100 91 100 CHEAL 0 0 0 0 0 1200 10 10 30 10 50 10 40 1800 20 20 20 20 60 20 70 2400 30 30 60 30 70 30 70 CASOB 0 0 0 0 0 1200 30 30 30 30 40 30 40 1800 40 40 80 40 80 40 100 2400 40 40 60 40 80 40 80 300157 -5- 133-0706 BROTE 0 1200 1800 2400 0 0 0 10 0 0 10 0 30 30 10 20 20 28 20 10 60 70 • 30 30 37 30 40 60 90 SORHA 0 0 0 0 10 1200 0 0 60 0 60 10 60 1800 10 10 60 10 60 19 70 2400 0 0 0 0 30 10 70 BRAPP 0 0 0 60 30 1200 0 0 30 60 70 30 80 1800 0 0 5 60 90 30 90 2400 20 20 50 68 90 44 80 表2:除草性效果Chloridazon g active ingredient / hectare 0 4 (Μβ Ifi Dim 30 絈 値 ethenamid 6 (desired gram active into X) hair ;; Ιτ 暄 & / hectare 8C expected 暄) 0 hairy GALAP 0 0 0 0 0 1200 0 0 100 0 100 0 100 1800 70 70 100 70 100 70 100 2400 100 100 100 100 100 100 90 MATCH 0. 0 0 10 10 1200 80 80 70 82 100 82 100 1800 70 70 80 73 100 83 90 2400 90 90 100. 91 100 91 100 CHEAL 0 0 0 0 0 1200 10 10 30 10 50 10 40 1800 20 20 20 20 60 20 70 2400 30 30 60 30 70 30 70 CASOB 0 0 0 0 0 1200 30 30 30 30 40 30 40 1800 40 40 80 40 80 40 100 2400 40 40 60 40 80 40 80 300 157 -5- 133-0706 BROTE 0 1200 1800 2400 0 0 0 10 0 0 10 0 30 30 10 20 20 28 20 10 60 70 • 30 30 37 30 40 60 90 SORHA 0 0 0 0 10 1200 0 0 60 0 60 10 60 1800 10 10 60 10 60 19 70 2400 0 0 0 0 30 10 70 BRAPP 0 0 0 60 30 1200 0 0 30 60 70 30 80 1800 0 0 5 60 90 30 90 2400 20 20 50 68 90 44 80 Table 2: Herbicidal effect

Dimethenamid/Norflurazon 處理後評估2 2天Dimethenamid / Norflurazon evaluation 2 2 days after treatment

Norflurazon g a.i./ha 0 4( 期望値 Dime X) 發喊値 thenamid g 6( 期望値 a.i./ha X) 發現値 80( 凋望値 ) 發涵(I XANST 0 0 0 0 0 400 10 10 60 10 60 10 80 600 70 70 70 70 90 70 90 800 80 80 100 80 80 80 90 -6- 133-0706 表3 :舞草性效果Norflurazon g ai / ha 0 4 (expectation value Dime X) screaming value thenamid g 6 (expectation value ai / ha X) found value 80 (withering value) hairline (I XANST 0 0 0 0 0 400 10 10 60 10 60 10 80 600 70 70 70 70 90 70 90 800 80 80 100 80 80 80 90 -6- 133-0706 Table 3: Dancing effect

Dimethenamid/Phenmedipham 施甩後評估22天Dimethenamid / Phenmedipham evaluation after 22 days

Phenmedipham Dimethenamid g a.i./ha g a.i./ha 0 400 600 800 期望値 發現値 期望値. 發現値 期望値 發現値 SETFA 0 0 70 80 80 400 20 76 90 84 100 84 100 600 20 76 100 84 100 84 100 800 10 73 100 82 100 82 100 SORHA 0 0 0 10 0 400 0 0 60 10 60 0 10 600 0 0 30 10 80 0 90 800 0 0 30 10 90 0 60 CAPBP 0 0 0 0 0 400 50 50 90 50 100 50 98 600 60 60 100 60 100 60 - 800 100 100 100 100 100 100 98 CHEAL 0 0 0 0 0 400 0 0 60 0 50 0 30 600 20 20 60 20 70 20 50 800 60 60 60 60 80 60 50 133-0706 GALAP 0 400 600 800 0 0 20 20 20 36 36 20 98 80 98 0 20 20 0 20 40 50 0 20 20 0 20 50 50 MATCH 0 0 0 0 0 400 0 0 95 0 70 0 30 600 0 0 60 0 100 0 70 800 0 0 100 0 99 0 80 POLAV 0 0 0 0 0 400 0 0 40 0 40 0 40 600 0 0 50 0 80 0 40 800 30 30 60 30 50 30 50 STEME 0 0 0 0 0 400 0 0 60 . 0 20 0 98 600 30 30 95 30 70 30 90 800 60 60 95 60 98 60 80 -8- 133-0706 表4:除草性效果Phenmedipham Dimethenamid g ai / ha g ai / ha 0 400 600 800 Expected value found value Expected value. Found value expected value found value SETFA 0 0 70 80 80 400 20 76 90 84 100 84 100 600 20 76 100 84 100 84 100 800 10 73 100 82 100 82 100 SORHA 0 0 0 10 0 400 0 0 60 10 60 0 10 600 0 0 30 10 80 0 90 800 0 0 30 10 90 0 60 CAPBP 0 0 0 0 0 400 50 50 90 50 100 50 98 600 60 60 100 60 100 60-800 100 100 100 100 100 100 98 98 CHEAL 0 0 0 0 0 400 0 0 60 0 50 0 30 600 20 20 60 20 70 20 50 800 60 60 60 60 80 60 50 133-0706 GALAP 0 400 600 800 0 0 20 20 20 36 36 20 98 80 98 0 20 20 0 20 40 50 0 20 20 0 20 50 50 MATCH 0 0 0 0 0 400 0 0 95 0 70 0 30 600 0 0 60 0 100 0 70 800 0 0 100 0 99 0 80 POLAV 0 0 0 0 0 0 400 0 0 40 0 40 0 40 600 0 0 50 0 80 0 40 800 30 30 60 30 50 30 50 STEME 0 0 0 0 0 400 0 0 60 . 0 20 0 98 600 30 30 95 30 70 30 90 800 60 60 95 60 98 60 80 -8- 133-0706 Table 4: Herbicidal effect

Dimethenamid/Metamitron 處理後評估18天―Dimethenamid / Metamitron evaluation 18 days after treatment ―

Metamitron g a.i./ha 0 4( 期望値 Dim* K) 發現値 sthenamid g 6( 斯望値 r a.i./ha )0 發現値 8C 期望値 K) 發現貧 CHEAL 0 0 0 0 0 1200 20 20 50 20 60 20 70 1800 20 20 50 20 70 20 70 2400 50 50 50 50 50 50 60 表.5: •除草性效果.Metamitron g ai / ha 0 4 (expected value Dim * K) found value sthenamid g 6 (斯 望 値 r ai / ha) 0 found value 8C expected value K) found poor CHAL 0 0 0 0 0 1200 20 20 50 20 60 20 70 1800 20 20 50 20 70 20 70 2400 50 50 50 50 50 50 60 Table. 5: • Herbicidal effect.

Dimethenamid/Bentazone 處理後評估18天Dimethenamid / Bentazone evaluation 18 days after treatment

Bentazone Dimethenamid g a.i./ha g a.i./ha 0 400 600 800 期.望値 發現値 期望値: 發現値 期望値 發現値 CHEAL 0 0 0 0 0 500 0 0 50 0 80 0 90 750 0 0 80 0 60 0 70 1000 0 0 90 0 100 0 100 SOLNI 0 0 10 30 40 500 0 10 100 30 100 40 100 750 10 19 100 37 100 46 90 1000 0 10 90 30 20 40 100 -9- 133-0706 STEME 0 500 750 1000 0 60 80 70 68 84 76 20 90 90 100 60 80 70 0 100 100 90 68 84 76 20 100 90 100 GALAP 0 0 0 0 70 500 60 60 70 60 90 88 90 750 60 60 90 60 100 88 100 1000 100 100 100 100 100 100 100 表6:除草性效果Bentazone Dimethenamid g ai / ha g ai / ha 0 400 600 800 period. Wang value discovery value expectation value: discovery value expectation value discovery value CHEAL 0 0 0 0 0 500 0 0 50 0 80 0 90 750 0 0 80 0 60 0 70 1000 0 0 90 0 100 0 100 SOLNI 0 0 10 30 40 500 0 10 100 30 100 40 100 750 10 19 100 37 100 46 90 1000 0 10 90 30 20 40 100 -9- 133-0706 STEME 0 500 750 1000 0 60 80 70 68 84 76 20 90 90 100 60 80 70 0 100 100 90 68 84 76 20 100 90 100 GALAP 0 0 0 0 70 500 60 60 70 60 90 88 90 750 60 60 90 60 100 88 100 1000 100 100 100 100 100 100 100 Table 6: Herbicidal effects

Dimethenamid/Metribuzin 處理後評估1 8天Dimethenamid / Metribuzin evaluation after 18 days

Metribuzin Dimethenamid g a.i./ha g a.i./ha 0 400 600 800 期望.i寧 發現値 期望暄 發現値 期望値 發現値 GALAP 0 0 0 10 10 250 0 0 40 10 30 10 40 375 20 20 60 28 60 28 70 500 50 50 80 55 50 55 80 -ΙΟ Ι 33-0706 -表7..除草性效果Metribuzin Dimethenamid g ai / ha g ai / ha 0 400 600 800 Expectations. I Ning found value expectation finds value expectation value discovery value GALAP 0 0 0 10 10 250 0 0 40 10 30 10 40 375 20 20 60 28 60 28 70 500 50 50 80 55 50 55 80 -ΙΟΙ 33-0706-Table 7: Herbicidal effect

Dimethenamid/T risulfuron-methy 1 處理後評估18天Dimethenamid / T risulfuron-methy 1 18 days after treatment

Trisulfuron-methyl g a.i./ha 0 4( 期莫値： Dim( 30 發現値 sthenamid 6( 期望値： a.i./ha 〕0 發現値 8C 期望値· K) 發現値 CASOB 0 0 0 0 0 4 50 50 60 50 60 50 70 8 0 0 50 0 60 0 80 16 30 30 50 30 60 30 70 XANST 0 0 0 0 0 4 20 20 30 20 50 20 70 8 30 30 70 30 80 30 100 16 50 50 60 50 90 50 100 除草性效果L Dimethenamid/Pyridate 處理後評估is.天Trisulfuron-methyl g ai / ha 0 4 (Period Mo value: Dim (30 discovery value sthenamid 6 (Expected value: ai / ha) 0 Discovery value 8C Expected value · K) Discovery value CASOB 0 0 0 0 0 0 4 50 50 60 50 60 50 70 8 0 0 50 0 60 0 80 16 30 30 50 30 60 30 70 XANST 0 0 0 0 0 4 20 20 30 20 50 20 70 8 30 30 70 30 80 30 100 16 50 50 60 50 90 50 100 Herbicidal effect L Dimethenamid / Pyridate evaluation after treatment is. Days

Pyridate Dimethenamid g a.i./ha g a.i./ha 0 400 600 800 期望値： 發現値 期望値 發現値 期望値 發現値 SIDSP 0 0 0 0 0 300 70 70 90 70 100 70 100 4500 90 90 90 90 100 90 100 600 90 90 100 90 90 90 100 -11- 133-0706 SETFA 0 0 30 40 30 300 0 30 20 40 40 30 50 450 10 37 30 46 50 33 50 600 10 37 70 46 70 33 60 表' 9:除草性效茱Pyridate Dimethenamid g ai / ha g ai / ha 0 400 600 800 Expected value: Discovery value Expected value Discovery value Expected value Discovery value SIDSP 0 0 0 0 0 300 70 70 90 70 100 70 100 4500 90 90 90 90 100 90 100 600 90 90 100 90 90 90 100 -11- 133-0706 SETFA 0 0 30 40 30 300 0 30 20 40 40 30 50 450 10 37 30 46 50 33 50 600 10 37 70 46 70 33 60 Table 9: Herbicidal effect cornelian cherry

Dimethenamid/Nicosulfuron 處理後評估22天Dimethenamid / Nicosulfuron evaluation 22 days after treatment

Nicosulfuron Dimethenamid g a.i./ha g a.i./ha 0 400 600 800 期望値 發現値 期望鼇 發現値 期望値： 驶現値 ABUTH 0 0 0 0 0 10 20 20 30 20 40 20 40 20 30 30 50 30 60 30 60 40 30 30 60 30 70 30 70 CHEAL 0 0 0 0 0 10 40 40 80 40 80 40 80 20 60 60 80 60 90 60 90 40 70 70 90 70 90 70 90 SENVU 0 0 0 0 0 10 50 50 60 50 70 50 70 20 50 50 60 50 70 50 70 40 60 60 70 60 90 60 90 -12- 133-0706 表10:除草性效果Nicosulfuron Dimethenamid g ai / ha g ai / ha 0 400 600 800 Expected Value Discovery Expected Value Discovery Expected Value: Driving Value ABUTH 0 0 0 0 0 10 20 20 30 20 40 20 40 20 30 30 50 30 60 30 60 40 30 30 60 30 70 30 70 CHEAL 0 0 0 0 0 10 40 40 80 40 80 40 80 20 60 60 80 60 90 60 90 40 70 70 90 70 90 70 90 SENVU 0 0 0 0 0 10 50 50 60 50 70 50 70 20 50 50 60 50 70 50 70 40 60 60 70 60 90 60 90 -12- 133-0706 Table 10: Herbicidal effect

Dimethenamid/Amitrole 黢理後評估2 5天Dimethenamid / Amitrole post-treatment evaluation 2 5 days

Amitrole Dimethenamid g a.i./ha g a.i./ha 0 400 600 800 期望暄 發現値 氣望値 發現値 期望値 發魂値 CHEAL 0 0 0 0 0 400 60 60 90 60 90 60 90 PHBPU 0 0 0 0 30 400 30 30 50 30 60 51 70 XANST 0 0 0 0 0 400 50 50 70 50 80 50 90 表11 :除草性效果Amitrole Dimethenamid g ai / ha g ai / ha 0 400 600 800 Expectation discovery, discovery, expectation, discovery, expectation, and expectation. CHEAL 0 0 0 0 0 400 60 60 90 60 90 60 90 PHBPU 0 0 0 0 30 400 30 30 50 30 60 51 70 XANST 0 0 0 0 0 400 50 50 70 50 80 50 90 Table 11: Herbicidal effect

Dimethenamid/Haloxyfop-R-methyl 處理後評估18天Dimethenamid / Haloxyfop-R-methyl evaluation 18 days after treatment

Haloxyfop- Dimethenamid g a.i./ha - R-methyl g a.i./ha 0 400 600 800 期望値 發魂値 期望f 發現f 期望値 發現値 ALOMY 0 0 60 60 70 20 20 68 90 68 90 76 100 30 80 92 90 92 90 94 100 40 90 96 90 96 100 97 100 -13- 133-0706 BROTE 0 20 30 40 0 0 90 90 60 96 96 60 80 90 90 40 94 94 40 80 100 90 60 96 96 60 100 100 100 SORHA 0 0 50 70 80 20 30 65 90 79 100 86 90 40 70 85 100 91 100 94 100 60 90 95 100 97 100 98 100 表 12:除草性效果Haloxyfop- Dimethenamid g ai / ha-R-methyl g ai / ha 0 400 600 800 Expected volcanic soul Expected f Expected f Expected Exploratory discovered ALOMY 0 0 60 60 70 20 20 68 90 68 90 76 100 30 80 92 90 92 90 94 100 40 90 96 90 96 100 97 100 -13- 133-0706 BROTE 0 20 30 40 0 0 90 90 60 96 96 60 80 90 90 40 94 94 40 80 100 90 60 96 96 60 100 100 100 SORHA 0 0 50 70 80 20 30 65 90 79 100 86 90 40 70 85 100 91 100 94 100 60 90 95 100 97 100 98 100 Table 12: Herbicidal effect

Dimethenamid/Fenoxaprop-P-ethyl 處理後評估2】_天 -Dimethenamid / Fenoxaprop-P-ethyl evaluation after treatment 2] _ 天-

Fenoxyprop- Dimethenamid g a.i./ha P-ethyl g a.i./ha 0 400 600 800 枭望傳 發現値 ifc望値 發現値 期望値 發現f POAAN 0 0 20 70 80 30 0 20 80 70 80 80 80 60 0 20 70 70 80 80 90 90 0 20 70 70 80 80 95 -14- 133-0706 表13:餘草性效果Fenoxyprop- Dimethenamid g ai / ha P-ethyl g ai / ha 0 400 600 800 Observational discovery ifc Wangfu discovery and expectation discovery POAAN 0 0 20 70 80 30 0 20 80 70 80 80 80 60 0 20 70 70 80 80 90 90 0 20 70 70 80 80 95 -14- 133-0706 Table 13: Residual effect

Dimethenamid/Clodinafop-propargyl 處理後評估21天Dimethenamid / Clodinafop-propargyl evaluated 21 days after treatment

Clodinafop- Dimethenamid g a.i./ha propargyl 0 400 600 800 g a.i./ha 期望値： 發現値 期望値 發現値 期望値' 發現遁 POAAN 0 0 20 70 80 20 0 20 70 70 90 80 90 40 0 20 80 70 90 95 95 60 0 20 90 70 95 95 95 $ 14·.除草性效果·Clodinafop- Dimethenamid g ai / ha propargyl 0 400 600 800 g ai / ha Expected value: found value expected value found value expected value found POAAN 0 0 20 70 80 20 0 20 70 70 90 80 90 40 0 20 80 70 90 95 95 60 0 20 90 70 95 95 95 $ 14 · Herbicidal effect ·

Dimethenamid/Diclofop-methyl 處理後評估21天-Dimethenamid / Diclofop-methyl evaluation 21 days after treatment-

Diclofop-methyl g a.i./ha 0 4( 期望値 Dim( X) 發現値 sthenamid g 6( 期望値 a.i./ha )0 發現値 8C 期望値· K) 發現値 POAAN 0 0 20 70 80 400 0 20 90 70 80 80 95 600 5 24 70 71 90 81 95 800 5 24 70 71 90 81 90 -15- 133-0706 表15 :除草性效果：Diclofop-methyl g ai / ha 0 4 (Expected value Dim (X) Discovery value sthenamid g 6 (Expectation value ai / ha) 0 Discovery value 8C Expected value · K) Discovery value POAAN 0 0 20 70 80 400 0 20 90 70 80 80 95 600 5 24 70 71 90 81 95 800 5 24 70 71 90 81 90 -15- 133-0706 Table 15: Herbicidal effects:

Dimethenamid/Prodiamine 處理後評估2 1天Dimethenamid / Prodiamine evaluation 2 1 day after treatment

Prodiamine Dimethenamid g a.i./ha g a.i./ha 0 400 600 800 期望値 發現値 期望値 發現値 期望値 發現.値 CAPBP 0 0 20 20 30 500 20 36 30 36 40 44 60 750 30 44 70 44 70 51 80 1000 30 44 40 44 70 51 80 POROL 0 0 0 0 0 500 60 60 60 60 80 60 80 750 50 50 60 50 70 50 80 1000 50 50 50 50 60 50 60 SIDSP 0 0 0 20 30 500 50 50 60 60 80 65 80 750 40 40 50 52 70 58 80 1000 70 70 70 76 80 79 80 SETFA 0 0 30 50 60 500 0 30 50 50 70 60 80 750 20 44 40 60 50 68 60 1000 20 44 70 60 70 68 70 300157 -16- 133-0706 表]6:除草性效果Prodiamine Dimethenamid g ai / ha g ai / ha 0 400 600 800 Expected Value Discovery Expected Value Discovery Expected Value Discovery CAPBP 0 0 20 20 30 500 20 36 30 36 40 44 60 750 30 44 70 44 70 51 80 1000 30 44 40 44 70 51 80 POROL 0 0 0 0 0 500 60 60 60 60 80 60 80 750 50 50 60 50 70 50 80 1000 50 50 50 50 60 50 60 SIDSP 0 0 0 20 30 500 50 50 60 60 80 65 80 750 40 40 50 52 70 58 80 1000 70 70 70 76 80 79 80 SETFA 0 0 30 50 60 500 0 30 50 50 70 60 80 750 20 44 40 60 50 68 60 1000 20 44 70 60 70 68 70 300 157 -16 -133-0706 Table] 6: Herbicidal effect

Dimethenamid/Glyphosate 處理後評估15天Dimethenamid / Glyphosate evaluation 15 days after treatment

Glyphosate Dimethenamid g a.i./ha g a.i./ha 0 400 600 800 期望値 發現-値 期望値· 發現値 期望値 發現値 CHEAL 0 0 0 0 0 100 30 30 60 30 60 30 70 200 60 60 80 60 80 60 80 400 90 90 90 .90 90 90 90 SENVU 0 0 0 0 0 100 30 30 40 30 60 30 70 200 70 70 70 70 100 70 100 400 80 80 80 80 90 80 90 XANST 0 0 0 0 0 100 30 30 50 30 60 30 70 200 50 50 60 50 70 50 90 400 50 50 60 50 70 50 90 -17- 133-0706 表—17:徐草性效果..Glyphosate Dimethenamid g ai / ha g ai / ha 0 400 600 800 Expected Value Discovery-Expected Value Discovery Discovery Value Expected Discovery Value CHAL 0 0 0 0 0 100 30 30 60 30 60 30 70 200 60 60 80 60 80 60 80 400 90 90 90 .90 90 90 90 SENVU 0 0 0 0 0 100 30 30 40 30 60 30 70 200 70 70 70 70 100 70 100 400 80 80 80 80 90 80 90 XANST 0 0 0 0 0 100 30 30 50 30 60 30 70 200 50 50 60 50 70 50 90 400 50 50 60 50 70 50 90 -17- 133-0706 Table-17: Xucao effect ..

Dimethenamid/Lenacil 處理後評估18天Dimethenamid / Lenacil evaluation 18 days after treatment

Lenacil Dimethenamid g a.i./ha g a.i./ha 0 400 600 800 發:現値 勘望値 發PJP 期望値 發現f MATCH 0 0 60 30 20 150 40 76 90 58 80 52 90 300 30 72 90 51 100 44 90 600 90 96 80 93 100 92 100 CASOB 0 0 0 0 0 150 10 10 90 10 90 10 100 300 10 10 60 10 100 10 70 600 50 50 60 50 100 50 80 PANMI 0 0 60 60 70 150 0 60 90 60 100 70 90 300 20 68 90 68 100 76 100 600 80 92 60 92 100 94 100 表18:脍草性效果iLenacil Dimethenamid g ai / ha g ai / ha 0 400 600 800 Issued: the current survey is issued and the PJP expectation is found f MATCH 0 0 60 30 20 150 40 76 90 58 80 52 90 300 30 72 90 51 100 44 90 600 90 96 80 93 100 92 100 CASOB 0 0 0 0 0 150 10 10 90 10 90 10 100 300 10 10 60 10 100 10 70 600 50 50 60 50 100 50 80 PANMI 0 0 60 60 70 150 0 60 90 60 100 70 90 300 20 68 90 68 100 76 100 600 80 92 60 92 100 94 100 Table 18: Stevia effect i

Dimethenamid/Dicamba/Pyridate 鼷理·後評估22天- 在下列試驗中，二ft胺混合物類通常出現的濃度比例為600克活性成份 /公頃。二噻胺單獮存在的除草性效果對抗AL0MY為20知，對抗BR0TE為 6 0 % ,且對抗 AVEFA 為 5 0 %。 -18- 133-0706Dimethenamid / Dicamba / Pyridate post-evaluation · 22 days after evaluation-In the following test, the concentration ratio of diftamine mixtures is usually 600 g active ingredient / ha. The herbicidal effect of dithiamine monocerene was 20% against AL0MY, 60% against BR0TE, and 50% against AVEFA. -18- 133-0706

Dimethenamid 600 g a.i./ha Pyridate Dicamba g a.i./ha g a.i./ha 0 50 100 150 期望暄 imu :期望暄 發現暄 劢望値 發現傕 ALOMY 20 (Dime- thenamid 單濁存在） 0 0 0 0 150 0 20 40 20 40 20 50 300 0 20 50 20 60 20 60 600 20 36 20 36 30 36 60 BROTE 60 (Dime- thenamid 單獨存$ 0 0 0 0 300 0 60 80 60 80 60 80 450 0 60 90 60 90 60 90 600 0 60 40 60 50 60 90 AVEFA 50 (Dime- thenamid 單濁存在） 0 0 0 0 300 0 50 70 50 70 50 80 450 0 50 70 50 80 50 90 600 0 50 80 50 80 50 80 结諭： . 二钂胺與一或二種其他除草_之受試混合物對抗許多不喜雜草均願示 明顯之協乘性效果。 300157 逋《發現指出並支持本發明二《胺輿其他除草_之混合物 在雜草植株之長苗後早基陏段施用於不軎雜草時，將表現 協乘性促進之除草活性。此種本發明混合物之協乘生交互 作用令人十分訝異及意料未及，就縝別已知除草劑之習知 活性範圓而言。 -19-Dimethenamid 600 g ai / ha Pyridate Dicamba g ai / ha g ai / ha 0 50 100 150 Expectation Xuan imu: Expectation Xuan Xuan Wang Xuan Wang found ALOMY 20 (Dime-thenamid single turbidity exists) 0 0 0 0 150 0 20 40 20 40 20 50 300 0 20 50 20 60 20 60 600 20 36 20 36 30 36 60 BROTE 60 (Dime- thenamid separate deposit $ 0 0 0 0 0 300 0 60 80 60 80 60 80 450 0 60 90 60 90 60 90 600 0 60 40 60 50 60 90 AVEFA 50 (Dime-thenamid single turbidity exists) 0 0 0 0 300 0 50 70 50 70 50 80 450 0 50 70 50 80 50 90 600 0 50 80 50 80 50 80 The test mixture of dioxin and one or two other herbicides against many undesirable weeds is willing to show a clear synergistic effect. 300157 逋 "Discovery points out and supports the present invention. When the early seedlings of the weed plants are applied to the non-stamp weeds, the synergistically promoted herbicidal activity will be exhibited. The synergistic interaction of this mixture of the present invention is very surprising and unexpected It is not known herbicides Zhen conventional circular range in terms of activity. -19-

Claims (1)

300157 公告本 A8 B8 8^-¾修正 Co D8 補案 六、申請專利範圍300157 Bulletin A8 B8 8 ^ -¾ Amendment to Co D8 Supplement VI. Patent application scope 1·一種防治不喜植物生長的方法，該方法包括向所 述的不軎植物的生長地共同施用總計除草有效量的唾草胺 (dimethenamid)和至少一種其它除草劑，其它的除草劑 係選自生長調節除草劑麥草畏（dicanba)、光合作用抑制 劑+美他米強（netamitron)，饗克津（metribuzin)，本 那松（benacil)，睡草平（bentazon)，阿特拉津（ atrazine )，甜菜寧（ phenmed i pham )，達草止（ pyridate )，敵草隆（diuron )、色素抑制劑達草滅（ norfiurazon)，克羅芮達宗（chloridazon)，殺箄強（ anitrol)、生長抑制劑普二胺（prodiamine)、氨基酸合 成抑制劑草甘膦（ glyphosphate ) ，Jg可磺隆（ n i c 〇 s u 1 f u r ο η )，三鑛确隆（t r i f 1 u s u 1 f u r ο η)，氧喷硬 隆（chloriiuron )、脂類抑制爾（dichlofop-methyl )，蓋箄能（ haloxyfop-methyl )，喔唑禾草靈（ fenoxaprop-ethyl )，克羅啶弗-炔丙基（ c 1 〇 d i π a f 〇 p - p r 〇 p a r g y )及撤可三酮（s u 1 c 〇 t r i ο π e ) 〇 2 ·如申請專利範圃第1項的方法，其中睡箄胺的用 經 濟 部 中 央 標 準 局 Ά 工 消 費 合 作 社 印 製 量為0 * 1至3 · 0公斤/公頃。 3 · —種除草組合物，其中含有總計除草有效量的唄 草胺和至少一種其它除箄劑及農業上可接受的載劑；其中 % 其它除草劑選自： 生長調節除草_麥草畏（dicamba)、光合作用抑制劑美他 米強（netanitron)，賽克津.（netribuzin)，本那松（ 本纸張尺度適用中國國家標準（CNS > A4規格（210X297公釐） A8 B8 C8 D8 申請專利範圍 benacil)，睡草平（bentazon)，阿特拉津（atrazine) ，甜菜寧（phenmediphan)，達草止（pyridate)，敵草 隆（diuron)、色素抑制劑達草滅（norfiurazon)，克羅 芮達宗（chloridazon)，殺草強（araitrol)、生長抑制 劑普二胺（prodiaraine)、氨基酸合成抑制劑（ glyphosphate)，尼可確隆（nicosulfuron)，三氟碌隆 (triflusulfuron) ，Μ喷磺降（chlorimuron)、脂類抑 制劑（dichlofop-methyl)，蓋草能（haloxyfop-methyl )，嗯唑禾草靈（f e η ο X a p !· 〇 p - e t h y 1)，克羅啶弗-炔丙 基（c 1 o d i π a f ο p - p r o p a r g y)及撒可三酮（s u 1 c o t r i ο n e) 請 先 閲 背 面 之 注 意 事 項 再』 裝 經濟部中央橾準局負工消费合作社印製 4 ·如申請專利範第3項的組合物，其中含有睡草 胺和撇可三醑（sulcotrione)作為活性成分。 5 ·如申請專利範園第3項的組合物，其中含有噻草 胺和氛唯磺隆（chloriBuron)作為有效成分。 6 *如申請專利範画第3項的組合物，其中含有噻草 胺、氯嘧磺隆和敵草隆（diuron)作為有效成分。 7 ·如申請專利範園第1項的方法，其中噻草胺的用 量為0·25至1·5公斤/公頃。 訂 了線 本紙張尺度適用中國國家標準（CNS ) A4规格（210X297公釐）1. A method for controlling the growth of undesirable plants, the method comprising co-application of a total herbicidal effective amount of dimethenamid and at least one other herbicide to the growth site of the non-stubble plants. Other herbicides are selected Self-growth-regulating herbicides dicanba, photosynthesis inhibitor + netamitron, metribuzin, benacil, bentazon, atrazine ), Phenmed i pham, pyridate, diuron, pigment inhibitor norfiurazon, chloridazon, anitrol, growth inhibition Prodiamine (prodiamine), amino acid synthesis inhibitor glyphosate (glyphosphate), Jg kesulfuron (nic 〇su 1 fur ο η), Mine ore (trif 1 usu 1 fur ο η), oxygen spray hard Chloriiuron, dichlofop-methyl, haloxyfop-methyl, fenoxaprop-ethyl, crotidine-propargyl (c 1 〇di π af 〇p-pr 〇pa rgy) and withdrawal triketone (su 1 c 〇tri ο π e) 〇2 · For example, the method of applying for the first item of the patent model nursery, in which the sleep amine is printed by the Central Bureau of Standards of the Ministry of Economic Affairs. 0 * 1 to 3. 0 kg / ha. 3. A herbicidal composition, which contains a total herbicidal effective amount of alachlor and at least one other herbicide and an agriculturally acceptable carrier; where% other herbicides are selected from: growth regulating herbicides_dicamba (dicamba ). Photosynthesis inhibitors metanitron, netribuzin, benazon (this paper size is applicable to China National Standards (CNS > A4 specification (210X297mm) A8 B8 C8 D8 application Patent scope: benacil, bentazon, atrazine, phenmediphan, pyridate, diuron, and norfiurazon, a pigment inhibitor Chloridazon, araitrol, growth inhibitor prodiaraine, amino acid synthesis inhibitor (glyphosphate), nicosulfuron, niflusulfuron, triflusulfuron, M sulfonate Chlorimuron, lipid inhibitor (dichlofop-methyl), haloxyfop-methyl, haloxyfop-methyl (fe η ο X ap! · 〇p-ethy 1), crotivin-yne Propyl (c 1 odi π af ο p-propargy) and sacotrione (su 1 cotri ο ne) Please read the precautions on the back first. Printed by the Ministry of Economic Affairs, Central Bureau of Preservation and Consumer Cooperatives 4 · If you apply for a patent The composition of item 3, which contains hylachlor and sulcotrione as active ingredients. 5 · The composition of item 3 of the patent application, which contains alachlor and chloriBuron As an active ingredient. 6 * The composition as described in item 3 of the patent application model, which contains tefenacet, chlorsulfuron and diuron as active ingredients. Method, in which the dosage of clothianidin is 0.25 to 1.5 kg / ha. The size of the lined paper is set to the Chinese National Standard (CNS) A4 specification (210X297 mm)
TW83102210A 1994-03-15 1994-03-15 Herbicide compositions TW300157B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5885933A (en) * 1993-02-18 1999-03-23 Sandoz Ltd. Herbicidal compositions comprising dimethenamid and bentazone
US5888936A (en) * 1993-02-18 1999-03-30 Sandoz Ltd. Synergistic herbicidal compositions of dimethenamid and phenmedipham
CN104872148A (en) * 2006-12-21 2015-09-02 组合化学工业株式会社 Herbicide composition

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5885933A (en) * 1993-02-18 1999-03-23 Sandoz Ltd. Herbicidal compositions comprising dimethenamid and bentazone
US5888936A (en) * 1993-02-18 1999-03-30 Sandoz Ltd. Synergistic herbicidal compositions of dimethenamid and phenmedipham
US5888935A (en) * 1993-02-18 1999-03-30 Sandoz Ltd. Synergistic herbicidal compositions of dimethenamid and glyphosate
CN104872148A (en) * 2006-12-21 2015-09-02 组合化学工业株式会社 Herbicide composition

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