TW212200B - - Google Patents

Description

212200 A6 B6 Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of the invention (1) The present invention is familiar with new isolator compounds and their preparation methods. In particular, the present invention still has advantages with the Kuma ion compound that can be used as a surfactant for washing hair or body, and its preparation method, which is very gentle to the skin, and has strong foaming ability and cleaning ability. Two or more cleaning agents or cleaning compositions of the present invention, which can only produce light olives for the skin and the head, and its ability to clean, foam and clarify is suitable for bath essences and shampoos For refined use. In recent years, surfactants that can be used as detergents not only require the interface activity, but also hope that they can have some excellent properties, such as biodegradability, safety, etc. To a minimum. The fermented amino acid surfactants and myrazole "4 Interfacial Activity_" are surfactants that have been widely used in recent years and meet these requirements. However, although some surfactants usually have high safety properties, their foaming ability and cleansing ability (these properties are important for the interface activity λ) are not enough; therefore, they are usually not used unicast It is used as a component of shampoo and other products, but is used together with a de-ionizing interface activity, such as alkyl sulfate or alkyl sulfate. Such anionic surfactants, which will strongly attack the skin, will roughen the skin. On the other hand, cationic interfacial active thins have never been used as cleaning agents because they usually strongly irritate skin, and cationic interfacial active thins have not been found to have high foaming capacity and safety Sexual cleaning agent base. Under such conditions, the extreme chamber will develop a cationic surfactant with high foaming ability and cleaning ability. If you can develop this kind of sun (please read the precautions on the back and then fill out this page) • Green · This paper scale is applicable to China National Standard (CNS) A 4 specifications (210x297 mm) 212200 A6 B6 V. Description of invention ( 2) The special m of the ionic interface active sub property printed by the employee consumer cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs is generated. In recent years. Sexual properties (such as the requirement of omnipotent biodegradation. Although the anionic alkylbenzene sulfonate ethylene alkyl anchovy sulfuric acid component, and it has the pungent nature of the user's eyes Alkyl acid salts (Achillea aurantium propionate and N-fermented cleansers are required for their properties, although they are suitable for skin and skin cleansing and foaming surfactants (such as the single main ingredient. Therefore, the portion. Therefore, the current hair and skin care The quality of the cleansing foam and anti-hardening agent can be used as a new cleansing thin to show hurricanes. In addition, it is expected that there will be some new uses for the foaming and cleansing of human steamed buns. Ability and kitchen eye grinding surfactants (LAS), alkyl esters (AES) and α superior cleaning effect grinding and Pi Yong. Used in interface activity, Ν-acetyl glutamic acid group-Ν- 院 基 甘 素For example, in addition to the requirement of cleanliness and cleaning agents in the interface, the anti-hard water slaves only have the ability to withdraw lightly. In addition to the requirements of the active substance in the interface, it is also strongly used as a clear sulfonate olefin for the low stimulus level of Anhe Sulfonate and S-Square such as monoalkane, Η-amino acid degree, prickly Mono- or dialkyltrimethylammonium did not use them as detergents (such as soaps) (AS), acid esters (AOS)] foaming ability, but in the face, those recognized as phosphoric acid esters and N-enzymes Base-Η- 焼 基, they do not have foaming capacity and cleaning. In addition, it is difficult to use the ionization salt from thorns) as the cleaning composition, the main linear gasification they will be only fermented ammonia -4-Trace points have the ability, the main components of the degree of cleanliness .................................. .. ^ ........... ¾ .............................. . # .............................. lacquer (Please read the precautions on the back before filling this page) Developed a type that will only irritate the user's head with excellent cleaning and foaming capabilities and properties. The size of this paper, which needs water and conditioning, is applicable to the Chinese National Standard (CNS) A4 specifications (210X297 mm) 212200 A6 B6 V. Description of the invention (3) Under the above-mentioned circumstances, it is excellent After intensive observation of the cleansing ability and foaming ability and high safety of the gold and the compound that can be used for hair and body, after intensive observation, the inventor of the present invention found that the purpose of the present invention can be The novel cationic compound of formula (I) is achieved, and the present invention can be completed by this discovery. The present invention can provide a «ion compound as defined by the chemical formula (I): 0 R2 II I © R'CN- (CHz)« N- (CH2) »CHCH2N-R: A © (I)

G

E R4 where R1 is a straight or branched alkyl group having 7 to 15 atoms or a straight bond or branched alkylene group having 7 to 15 atoms; R «, R3 and R4 are each V is independent and is an alkyl group having 1 to 3 gallo atoms; G is a hydrogen atom, an alkyl group having 1 to 3 polyatoms, or a hydroxyalkyl group having 1 to 3 gallo atoms; E is a cyanide atom , Alkyl groups with 1 to 3 value atoms, hydroxyalkyl groups with 1 to 3 nitrate atoms, or ammonium groups as in formula (II): Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs I ©-(CH2 ) „CHCH2N-R3 · A Θ IIY R4 (II) is a hydrogen atom or a hydroxyl group, A is a hydroxyl group, a halogen atom or has 1 to 5 The paper size is applicable to the Chinese National Standard (CNS) A 4 specifications (210X297 mm) ................................. i ............... .. ^ .............................. t ................ ........... ^ (please read the precautions on the back before filling in this page) 212200 A6 B6 foot, and description of invention (4 slopping nitrogen mono-tilted alkyl also: Such as amine and one another. Y or alkylsulfonate such as chemical reagent is 2 or 3. , Number, if (1) when G is alkyl or not hydroxyalkyl, and (2) when η is 1, when η is 0, 2, 3, 4 or 5, 1T is not a halogen atom. Provide a method for manufacturing the amines of the above chemical formula (2) and / or cationization such as the chemical formula (4) A method for manufacturing the compound (chemical formula is hydroxy) includes amination of the sleeping chemical formula (3) Amine and a reaction step. When R'-C; η is 〇 or a hydroxyalkyl group between 1 and 5, then Ε is not, Υ is a hydrogen atom or a hydroxyl 〇 compound preparation method, which includes the chemical formula (3 ) Of the amidation reagent reaction step cost [. U). And where η is 1 cyclic amines of formula (2) and / kuma ions of chemical formula (5) (2) (please read the precautions on the back first (Fill in this page). 笟 · 0 II ”CN- (CH2)„ ΝΗ (3) • Order · R: Θ Z- (CHz) n CHCH2N-R3 * A © (4) .Line · Employee of Central Bureau of Standards, Ministry of Economic Affairs Printed by consumer cooperatives I Θ ch2-ch-ch2-nr: \ 〆 ^ A0 (5) 6 This paper scale is applicable to the Chinese National Standard (CNS) A 4 specifications (210X297 mm) A6 213300 ___ ^-Λ, description of invention (5 ) The present invention provides a A mixture of kumquat ionic compounds, that is, a sculptural interfacially active «I composition, which contains (a) a kind of rhododendron ion compound of formula (I), where G is a hydrogen atom and E is A hydrogen atom, an alkyl group having 1 to 3 sulfon atoms, or a hydroxyalkyl group having 1 to 3 atoms; (b) another cationic compound of formula (I) wherein G is a hydrogen atom and has 1 An alkyl group up to 3 atoms, or a hydroxyalkyl group having 1 to 3 atoms, E is an ammonium group as in formula (II). G and E cannot be hydrogen atoms at the same time. The composition still contains a compound of the formula (〇, Kuma ionic, G in this compound is an alkyl group having 1 to 3 atoms, or a hydroxyalkyl group having 1 to 3 atoms, and E is It is a K atom. The Yangzizizi compound in the present invention includes two squiggles: one is a compound of formula (I), wherein R1 is a linear or branched alkyl group having 7 to 15 stuffed atoms, or With straight or branched alkyl groups with 7 to 15 pour atoms; R *, 1? 3 and! ^ Are independent, and are alkyl groups with 1 to 3 lanthanum atoms; G is Hydrogen atom; E is an alkyl group having 1 to 3 helium atoms. Or a hydroxyalkyl group having 1 to 3 sesame atoms; Y is a hydrogen atom or a hydroxyl group; A is a hydroxyl group, a halogen atom or has 1 to 4 Alkyl sulfonate of a large atom; 2 or 3; η is zero or a whole number between 1 and 5; if η is 1 angstrom, then Υ is a hydrogen atom or a hydroxyl group, and if η is zero, 2 , 3, 4 or 5, then Υ is a hydrogen atom. In the chemical formula (I) of the consumer consumption cooperation of the Central Bureau of Standards of the Ministry of Economic Affairs Du Yinbao S-insult strip: R1 is a straight bond with 7 to 15 ® sulfonic atoms Or a branched alkyl group, or a straight or branched alkylene group with 7 to 15 tantalum atoms; R *, R3, and R4 are independent of each other, and are applicable to the Chinese National Standard (CNS) ) A4 specifications (210X297 public love) 212200 A6 B6 V. Description of the invention (6) alkyl groups with 1 to 3 atoms; G is an alkyl group with 1 to 3 atoms, or 1 to 3 Hydroxyalkyl with a large atom; E is a hydrogen atom, or an ammonium group as in formula (II): Y is a hydroxy group; A is a halogen or an alkylsulfonate with 1 to 4 sulfo atoms: 2 or 3; η is zero or a value integer between 1 and 5, and the conditions are the same as those in the above paragraph. The present invention provides a cleansing composition, which contains such a _ ion compound and a loaded metal. Another cleaning The composition consists of an ion-limited compound and other amphoteric surfactants or nonionic surfactants. This cleaning composition also contains an additive for shampooing. This cleaning composition also contains a water-soluble Polymer, anionic polymer, other kinds of meteorological interfacial surfactant or a kind of water Dispersed silica compound. The present invention provides another cleaning composition ~ it includes a cationic compound of formula (I ') and a carrier; the Kuma ion compound has the same general formula as formula (I), but for The definition of substituents is different, where R1 is a straight or branched alkyl group with 7 to 21 atoms or a straight chain or branched alkyl group with 7 to 21 atoms; R *,! 13 and 1 ^ are independent of each other, and are alkyl groups having 1 to 4 halo atoms, or hydroxyalkyl groups having 1 to 4 tilt atoms; G is a hydrogen atom; E is a Xiang ethyl; Υ is a hydroxyl group; A is a halogen atom or an organic anion; is 2; and η is 1. (Please read the precautions on the back before filling in this page) • Installed ... Threads · Printed by the Staff Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. The paper size is compliant with China National Standards (CNS) Grade 4 (210x297 mm) 2122G0 A6 B6 5. Description of the invention (7) 0 Rz II-RlCN- (CH,) «N- (CHz). CHCH2N-R3 · A © (I ·)

G The present invention provides a new ion-limiting compound • The surfactant prepared therefrom • The cationic compound can be represented by the general formula (〇 to represent

〇 R * II 丨 Θ Λ RON-CCHx). N- (CHz). CHCHzN-R5 * P (!)

G where R * represents a straight or branched bond with 7 to 15 tilt atoms > »alkyl or alkylene; R *, R3 and R4 may be the same or different from each other, and each of the Alkyl groups with 1 to 3 nitrate atoms; G stands for Η or alkyl or hydroxyalkyl groups with 1 to 3 atoms; E stands for Η or alkyl or hydroxyalkyl groups with 1 to 3 atoms , Or as the base of the following chemical formula: Β * — (CHz) «CHCH2N-R3 · A ® Ministry of Economic Affairs t Central Standards Bureau employee consumption cooperation du printing and its accompanying conditions are as follows: when G represents 1 to 3 sulfonate Atomic Academy 9

The size of this paper is in accordance with Chinese National Standard (CNS) Grade 4 (210x297mm) 212200

Si U A6 B6 V. Description of the invention (8) When the group or hydroxyalkyl group, E can not be an alkyl or hydroxyalkyl group having 1 to 3 nitrile atoms; Y represents Η or hydroxy group; A represents 0H, halogen cut The alkylsulfonic acid group of atoms, | represents a one-valued integer between 2 or 3, 5, and its accompanying conditions are as follows: is a radical, and when η is 0, 2, 3.4, or 5, it is a hydrogen atom. The present invention will now be described in more detail. The atom has either 1 to 4 and η represents 0 or 1 to η. When η is 1, Υ is Η or, and G and E are not synonymous at the same time. There is no new compound in the literature or patent publications. The meteorological compounds in the above general formula (I) have not been reported to be mildew, so the cationic compounds of the present invention. Examples of such cationic compounds include the following compounds: [Chemical Formula 11] 0 CU3I! C,, H23CNH- (Cflz) ϊΝ- (CH,) s-N-CH:

Cl © (Please read the precautions on the back before filling in this page). Install * CHtCHtOH CH:

0 II

C ,, H *, CK- (CH2) * N) CHzCHzOB, CH3 (CHz) a-N-CHj I CH *

N

Cl〇 0 CH3 Η I® C ,, H, 3CN- (CH2) t N-CCH ^ s-N-CH:

Cl ©

CBsCHzOH CH: • Line · 10 copies of the paper printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs are applicable to the Chinese National Standard (CNS) A 4 specifications (210x297 mm) 212 ^ 00 A6 B6 V. Description of the invention (9) OH CH3 C13H27cnh- (CH *) 3 N-CH «CHCHz-N-CH3 ♦ Cl © CHzCHtOH CHS, OH CH3 1 丨 ® c CH2CHCH2-N-CH3 · C10 I, CHi

0 II C13H27, CN_ (CH *) 3 ch2ch * 〇h 〇OH CH3 II I! © Cl, H? 7CN- (CH2) 3 N-CHzCHCH * -N-CH3 Cl〇13 2 / 丨 Η I CHtCHtOH CH3 (Please read the precautions on the back before filling in this page) • Installation · The cationic compound of the present invention represented by the above general formula (I) printed by the Consumer Labor Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs can be described below Production method < 1> and < 2 > one of the production methods: 鄱 法 >: The cationic compound of the present invention represented by the above general formula (I) can be obtained by using the cyclic amine of the general formula (2) [ Chemical formula 1 2] 11 This paper scale is applicable to the Chinese National Standard (CNS) A4 specifications (210x297 mm) • Ordered • • Green. 9Λ2200 A6 B6 5. Description of the invention (10) R * -C ^ (CHt) i ⑵ where R1 and ra are as defined above, and G3 is an alkyl or hydroxyalkyl group having 1 to 3 atom atoms or an acylaminoamine such as the general formula (3) (the "starting amine compound" will be used in the following paragraphs to represent the acylamide The term "aminoamine": [Chemical formula 1 3] 0 11 R * CN- (CHt) «NH IIG * G * ⑶ Where R1 and * are as defined above, and G1 and 62 represent Η or have 1 to 3, respectively Worthwhile Alkyl or hydroxyalkyl, but at least one of G1 and G »is an alkyl or hydroxyalkyl group with 1 to 3 carbon atoms, which is obtained by reacting with a cationizing agent of general formula (4) ： [Chemical Formula Μ] (Please read the precautions on the back before filling in this page) • Issuing, Ordering and Printing R * Z- (CHt) „CHCKtN-R3 * A © (4) 12 The size of this paper is in accordance with Chinese National Standard (CNS) A4 specifications (210X297 mm) 2122C0 A6 B6 • δ, description of invention (Ή where R8, R3, R *, γ, / ^ and η are defined as above • while Z Represents a halogen atom; the amount of cationization reagent used per mole of starting amine compound is 1 to 3 moles. This value can be explained by the following reaction circle: [Chemical formula 15] and / or ⑵ 0 II R «CN- (CH,). NH IIG * G * (3) R * Z- (CHx). CHCHxN-R3 * (β II y r4 (4) (Please read the notes on the back of« I first Fill in this page) * Pack. 0 Rz II I® lCN- （CH *) · N- （CH *) „CHCH * N-R3. A ©

G

B (1) • J ^ :: where R1, R2, R3, R4 .G.G1 .G2, G3, £, 1 steam,》 1,11 and 2 are as defined above. In the reaction of the starting amine compound and the reagent (4), it is preferable to adjust the pH of the reaction mixture to 7 to 12 after dropping the aqueous solution of the test SI (4) into the alcohol solution of the starting amine compound. between. For this reason, if necessary, an ageing solution can be added to the reaction solution, such as argon or sodium hydroxide. In order to allow the starting amine to react with the Kuma ionization reagent (4), the pH value of the reaction system is maintained within the above range during the reaction. From the 13th paper standard, the Chinese National Standard (CNS) Grade 4 (210X297 mm) is applicable. • Practice-Printed by the Employees ’Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs A6 B6 Printed by the Employees’ Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs

212200 Table, invention description (12) From the perspective of response rate, the preferred PH value is at least 7. When the PH value exceeds 12, the Kuma ionization test (4) will undergo an unfavorable hydrolysis reaction. Although this reaction can proceed even under room temperature, the higher the temperature, the faster the reaction rate. However, high temperature or high PH value will accelerate the ionization test (4) for hydrolysis reaction. Therefore, the temperature should not be higher than preferably 9 0 ¾ 0. In this cracking process, the molar ratio of the cationizing agent relative to the starting amine compound is usually preferably in the range of 1/1 to 3/1, And 1.1 / 1 to 1.5 / 1 is the better range. When the amount of cationizing reagent (4) is lower than the above range, the conversion rate will be reduced; conversely, if the amount of use is higher than the above range, the reaction mixture will contain a large amount of cationizing reagent (4), or It is to make the cationizing agent undergo unfavorable hydrolysis reaction. Whether the reaction of the ionization test (4) is finished or not can be known by analyzing the residual amount of the starting amine with a high-performance liquid chromatograph during the reaction. ”In the preparation method of the present invention, the counter-inverted solution may be an aqueous solution, or a mixture of water and a lower alcohol (such as ethyl alcohol or isopropyl alcohol) or a second enzyme (such as 1,3-propanediol or propylene glycol). Solution. In the preparation method of the present invention, the amine (2) and the amidoamine (3) used as the starting limb compounds are generally manufactured by the following preparation method: [Synthesis of cyclic amine (2)] (6) Fatty acids or their esters [Chemical Formula 16] This paper scale is applicable to the Chinese National Standard (CNS) A4 specifications (21〇 < 297mm)

G 2 03 1

V. Description of Invention Π 3)

A B

0 II 'COT ⑹ where R1 is as defined above. T represents Η or an alkyl group having 1 to 3 sulfonic atoms and reacts with the diamines of general formula (7):

H2N (CH2) n NH-G ⑺ (Please read the precautions on the back before filling in this page)-¾ .. where G8 and as defined above, the molar ratio of the reaction is 1/1 to 1/3 After the reaction, cyclic amine (2) can be obtained. This insult reaction can be expressed by the following chemical reaction equation: [Chemical Formula 1 7] 0

T0H

-> fi * -C

II R'COT H, N (Cfli) m NH-G: ⑹ ⑺ ⑵ • Line · Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy where R1 .T.G1 * and are defined as before. The reaction of fatty acids or their esters (6) and diamines (7) is carried out under reduced pressure and heating. • By dehydration or removal of lower alcohols (T〇H; T fixed 15) This paper size is applicable Chinese National Standard (CNS) A4 specifications (210x297 mm) 212200 A6B6 Λ-., Description of invention Μ 4) Same as above) and was able to synthesize cyclic amine (2). [Synthesis of Aldiamine Amine (3)] The amidated amine (3) can be produced by hydrolyzing the amine (2) under acidic or ageing conditions; or it can be produced from fatty acids or their esters (6) It reacts with diamine (7), and then hydrolyzes the obtained unseparated amine (2) to obtain Ο. These counters can be represented by the following chemical inverse equation: [Chemical Formula 18]

Rl-C t0 0 IIR'CN-CCH *). ΜΗ (Please read the precautions on the back before filling this page) ⑵ (3)

0 II

BlC0T + H2N (CHZ) · NH-G (6) (7) (i) -T0H (ii) Hz. The employee consumption cooperation of the Central Bureau of Standards of the Ministry of Economic Affairs is printed by R1.G1, G2, G3, T, B The definition is the same as above. 馎 法 <: 2 >: The cationic compound as shown in the general formula (1-1) (equivalent to the cationic compound (1) of the present invention +). Where η is 1 and Y is hydroxyl, which can be The starting amine compound [cyclic amine (2) and / or fermented aminated amine (3)] is reacted with a cationizing reagent of general formula (5) to prepare: 16 -— This paper scale is applicable to the Chinese National Standard (CNS) A 4 Specification (210X297 public goods) A6 B6 212200 V. Description of invention Π 5) [Chemical formula 1 9] R1 {0 CHZ — CH-CH2-N-Rs · A® 1〇s4 ⑸ where Ra, R3, R4 and A The definition is the same as above. The molar ratio of the cationic reagent (5) to the amine compound is between 1/1 and 3/1. The manufacturing process can be illustrated by the following diagrammatic reaction: [Chemical Formula 2 0] Bu CO),

G ⑵ 0 II and / or WCN— (CH2) e NH II G1 Gx (3) (please read the precautions on the back before filling this page) • Anyway, CH: — CH —CHz ~ N * —fi3 * A ® Order… ψ 0 R * II ιΘ

R'CN-iCHz). N-CH2CHCH2N-R3 > A0 I III G E OH R4 (1-1) where Ri, R2, R3, R *, G, Gi, G2 G3 are as defined above. 17 The size of this paper applies to China National Standard (CNS) Grade 4 (210X297mm). Line · A6 B6 212200 Λ printed by Beigong Consumer Cooperative, Central Standards Bureau, Ministry of Economic Affairs The molar ratio of the cationic compound (5) relative to the starting amine compound is between 1/1 and 3/1. When the molar ratio is lower than this range, the anti-plaque property will decrease. Conversely, if the molar ratio is higher than this range, the reaction mixture will contain a large amount of hydrolysate of the Kuma ionization reagent (5). This is very disadvantageous. The reaction temperature is about 30 to 120P, and preferably 50 to 90 * 0. When the reaction temperature is lower than this range, the reaction will be slower. On the contrary, if it is higher than this range, the coloring phenomenon is likely to occur 7Hi reactivity, and make the starting amine compound and cationizing agent (5) To carry out the desired reaction, it is preferable to use an appropriate amount of ageing aqueous solution so as to maintain the pH within the range of 7 to 12. When the PH value is lower than this range, the reaction rate will decrease. Conversely, if the PH value exceeds this range, a large amount of by-products will be formed, which reduces the yield. The preparation method of the starting amine compound used in the synthesis method < 2 > is the same as that used in the method < 1 >. All reactions in the present invention can be carried out in air or in an inert gas atmosphere and the like. However, from the viewpoint of avoiding the occurrence of coloring, etc., the latter is the better choice. Examples of fatty acids or their esters represented by the above general formula (6) used in the present invention include: caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid and coconut acid or their lower alcohol esters class. Examples of the diamines represented by the above general formula (7) include: ethylenediamine, M-methylethylenediamine, N-ethylethylenediamine, H-isopropylethylenediamine, aminoethyl Ethanolamine, H- (2-hydroxypropyl) -ethylenediamine, H- (3-hydroxypropyl) -ethylenediamine, H-methylpropylenediamine, N-ethylpropylenediamine and N- Propylenediamine. 18 This paper scale is applicable to China National Standard (CNS) Grade 4 (210x297 mm) (please read the precautions on the back before filling out this page). Installation ·-Line · Printed by the Staff Consumer Cooperative of the Ministry of Economic Affairs Central Standards Bureau

212200

Cooperate with Consumers and Consumers

R Λ., Description of the invention (17) The above-mentioned cationic compound having interface activity is used as the surfactant. Surfactants containing a mixture of the following cationic compounds (a) and (b) (or a mixture formed by further mixing with the cationic compound (c)) are particularly preferred: (a) As shown in the above general formula (1) A cationic compound, where G is H, and E is an alkyl or alkyl group having 1 to 3 charm carbon atoms; (b) a cationic compound as described in the general formula (1) above, wherein G is having 1 to 3 Atomic alkyl or hydroxyalkyl, and E is the base of the following chemical formula; [Chemical formula 2 1]-(CHz) n CHCH2N-R3 · ΑΘ Υ where 1? 9,1? 3,! ^,?, The definitions of 4 and 11 are the same as above. And (c) The cationic compound of the above general formula (1), wherein υ is an alkyl group having 1 to 3 ole atoms or a hydroxyalkyl group having 1 to 3® atoms. E is H. The present invention provides a clean or clean composition containing a cationic compound (chemical formula (I) or (I,)) as an active ingredient. This composition will only cause slight irritation to the use of human skin and hair. It can be improved in foaming ability, cleaning ability and resistance to hard water. 19 This paper scale is applicable to the Chinese National Standard (CNS) A4 specifications (210x297 mm) Printed by the Central Bureau of Standards of the Ministry of Economic Affairs 8 Industrial and Consumer Cooperatives 212200 V. Description of the invention (ia The cleaning composition of the present invention contains the general formula (I ) Quaternary ammonium salt compound, which is used as the main cleaning base, this composition is very suitable for baby shampoo or shower gel, shampoo used by people who wash their hair every day. A shampoo used by people who come into contact with shampoo for a while, a mild cleaner for fibers such as wool, or a mild surface cleaner for metal or tableware. When the cleaner is a liquid brew, then The preferred use amount of the quaternary ammonium salt compound (as shown in the general formula (I) above) in the cleaning composition of the present invention is 0.1 to 50 weight percent; when the cleaning agent The preferred usage amount is 0.1 to βΟΧ weight fraction, or when the cleaning agent is solid ram or powder, the preferred usage amount is 50 to 99¾ weight fraction. The foam properties of the cleaning composition of the present invention It can be obtained by combining the fourth-grade compounds (as described above (Formula (I)) and general amphoteric surfactants or #ionic surfactants can be improved by mixing them. Examples of amphoteric surfactants include an ide betaine, an ide betaine, Carbobetaine, sulfobetaine, phosphobetaine, hydroxysulfobetaine. Non-difficult surfactant Examples include amine gasification agents, sugar nonionic surfactants, such as alkyl sucrose, and mono- and di-alkanases. The cleaning composition of the present invention is in addition to the above four levels of general formula (I) In addition to the ammonium salt compound and the above surfactants, it may contain certain polymers as conditioning ingredients, such as water-soluble polymers, such as carboxymethyl ore, and anionic polymers, such as acrylic acid polymerization. 20 sheets of paper that are separable from water are compatible with the Chinese National Standard (CNS) A4 specifications (210x297 mm) (please read the precautions on the back side and write this page). ¾ ... A6 B6 212200 Description (19) Silicon Oxygen Derivatives. In addition, cationic surfactants and high-grade enzymes can also be added to the composition. If necessary, flavors, colors, preservatives, anti-corrosion agents can be added to the composition Chemicals, boosters, medicinal ingredients • such as scalp removing agents, bactericides, fire retardants and vitamins, as well as the ingredients listed in the washing ^ n ^ m (Micelle sold). The description of the composition of the cationic compound of (I) can also be applied to the quintic form of the chemical formula U '). The quaternary ammonium salt compound represented by the above general formula (1) is preferably a compound wherein 1 ^ is a linear or branched alkyl group or alkylene group having 11 to 17 tso atoms. More preferably, the R30- group in the chemical formula is lauryl or myristyl, and R », 1 ^ and 1? * Represent methyl groups, respectively. In addition, this composition may also contain other kinds of RS ionic interface active thin I, such as the quaternary ammonium salt represented by the chemical formula (15) or (16), in the chemical formula Re, Re, RT and R · at least one Values are alkyl or alkylene groups (each of which is independent), and each compound may contain substituents such as alkyl raffinyl groups, alkylene gas groups, alkanolamine groups, and alkanolamine groups (a total of β to 28 Deshuo atoms, and _ below is a base), an alkyl group with 1 to 5 americium atoms or a hydroxyalkyl group with 1 to 5 sulfonic atoms; R * is an alkylene group with 2 to 3 tilted atoms ; X is a dentin ion or an organic ion; η is an integer ranging from 1 to 20. As the quaternary ammonium salt of the chemical formula (15), the preferred scorpions include the chemical formulas (17), (18) , The compound shown in (19). In the chemical formula · Ri. Is a mixture of (a) and (b) (to be defined separately below), and (a) is relative to the total amount of (a) and (b) The ratio is between 10J: to 100X. (A) is a branched silver carp alkyl group with the following chemical formula: CHa- (CHB) P-CH (Rie) CHa- 21 This paper scale is applicable to the Chinese National Standard (CNS) A 4 specifications (210x297 public goods) ... ..................... ί ................... ^ .. ............................ Order ....................................... ... itching (please read the notes on the back and then write this page) A6 B6 U22G0 printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs V. Invention Instructions (20) ί Please read the notes on the back Matters are written in this book). Rie is methyl or ethyl, P is an integer and its value can make the total number of atoms in the alkyl group between 8 and 16; (b) is a straight-chain comprehensive base as the following chemical formula: CH *-(CH «) q-, q is an integer between 7 and 15. Rii and Ri «are gentyl groups, alkyl or hydroxyalkyl groups with 1 to 3 atoms, R " and are alkyl groups with 2 to 12 atoms, R 丨 β is Ri3-CH» -CHa-CH (Ri4) CHa-, or an alkyl group with 1 to 3 large atoms, is CHa-CCDs-CH (CHa)-(CHa) t or an alkyl group with 1 to 3 atomic atoms · s is 2 to An integer between 14 and t is a shovel integer between 3 and 11. The sum of s and t is between 9 and 12, and X is a halogen ion or an organic ion. For example, the quaternary ammonium salt of the branch of chemical formula (17) is obtained from a ketone enzyme having 8 to 16 te sulfur atoms. Preferred ones include dialkyl dimethyl ammonium salt, dialkyl methyl hydroxyethyl ammonium salt and di Alkyl methyl ammonium salts, and the alkyl groups in these compounds are derived from keto alcohols. The degree of branching of R »» in the chemical formula (17) is preferably between 10% and 50%, and the distribution of its atomic number is preferably in the following cases: C · to * is 53: or less than 5Ϊ, C " is between 10 and 35J: C13 is between 15 and 40X, Ch is between 20 and 45J: between. (: 1 (1 is between 5 and 30J: and Ci «is 5X or below 5ί Ο Among the above compounds, the dialkyl dimethyl ammonium gasification compound having an alkyl group of 8 to 16 atoms and a branching degree of 10 X to 5 0 3: in the chemical formula is the better choice. The Central Bureau of Standards of the Ministry of Economic Affairs Employee consumer cooperatives print ammonium salts such as the chemical formula (18) obtained from gelatine enzymes with 8 to 28 atoms, preferably including alkyl trimethyl ammonium salts, such as 2-decyltetradecyl tris Methyl ammonium vapor and 2-dodecylhexadecyltrimethylammonium vapor; alkyl dimethyl 22 This paper scale is applicable to China National Standard (CNS) A 4 specifications (210X297 mm) A6 B6 21220 V. Invention Description (21) Base ammonium salt, dialkyl dimethyl ammonium salt. Such as di-2-hexyldecyl dimethyl ammonium vapor and di-2-octyl dodecyl dimethyl chloride; two Alkyl methylhydroxyethyl Salts and dialkylmethyl ammonium salts; each alkyl group is derived from ketosaccharomyces cerevisiae. The methyl quaternary ammonium chloride as shown in the chemical formula (19) is a compound with an absolute sum of 15 X, which can be used as a relative ion, includes halogen ions, such as atmosphere, iodine, and bromine, and organic anions, such as methyl sulfate, ethyl sulfate, methyl phosphate, and ethyl phosphate. The cleaning composition of the present invention may still contain one Water-soluble polymer with anionic groups. This polymer includes orepin derivatives such as carboxymethyl cellulose, chitin derivatives such as carboxymethyl chitin, xanthogen and carrageenan Polymers or copolymers of cabbage, alloys and alginic acid derivatives, acrylic acid derivatives or N-methacryloylethyl-M, N-dimethylammonium-H-methyl-carboxytrimethylammonium lactone. The cleaning composition of the present invention may further contain a silicone derivative, such as dimethyl polysilane as shown in chemical formula (21), where η is 3 to 20,000; methylbenzyl poly as shown in chemical formula (22) Silane, where η 'is 1 to 20,000, and the sum of a and b is 1 to 500; polyether represented by chemical formula (23) Modified silica, where R * is-(CHa) 3-0- (C «H40) xl- (C3He0) yl-A, A is alkyl or hydrogen with 1 to 12 atoms, and xl is 0 to 50, yl is from 0 to 50, and the sum of xl and yl is 1 or more, el is from 1 to 2000, and nl is from 1 to 1000; cyclic gasification compound-modified silica shown in chemical formula (24), where x2 is from 1 to 500, preferably from 1 to 250, y2 is from 1 to 50, preferably from 1 to 30 23 The paper size is applicable to China National Standard (CNS) A 4 specifications (210 X 297 public) (please first M Read the precautions on the back and fill in this page) -¾. A6 B6 212200 Λ printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs, invention description (22), and Re is an alkylene group with 1 to 3 nitrile atoms; chemical formula Fluorine-modified silicon gas shown in (25), where X3 is 1 to 400. Preferably it is 1 to 250; alcohol-modified silicon oxide shown in chemical formula (26), where x4 and is 1 to 500, preferably 1 to 2 0 0. R «is C n " Η ·" ", and η "is 0 to 4; alkyl group-modified silica shown by the chemical formula (2 7), wherein χ5 And y5 is from 1 to 500, preferably from 1 to 200, Rt is a yard with 2 to 18 atoms, Re is Cn " Han, η "is 0 to 4. and% is an alkyl group having 10 to 16 primary atoms; the alkane group represented by the chemical formula (28) -modified silicone, in which a methyl group or a phenyl group, has 1 to 28 The alkyl group with a large atom is preferably 12 to 22 atoms, and k is 0, or an integer ranging from 1 to 6; and the atmosphere group-modified silica represented by the chemical formula (29), Where R * »is methyl or hydroxyl, R * 3 is methyl or hydrogen, Rk is, or -RH-ddi-aHCiUCDdrdeh.Z-, Rie is a divalent hydrocarbon group · R1T is -0CH« CH «-, -0CH (CHa) CH«-. -0CH, CH (0H) CHs- or -0CH8CH (CH, 0H)-, Rie and Rh are hydrogen or monovalent ye groups, d and e are 0 or a sine integer between 1 and 6. Z- is a halogen ion or an organic ion. Rle is a hydroxyl group, a hydroxyalkyl group, a gasified alkylene group or a polygasified alkylene group, 19, ^ and ^ It is an integer depending on the molecular weight, and each has its own chemical formula. Such amino-modified silica includes body strips such as formulas (30) and (31). (Please read the precautions on the back before filling out this page). Insects. • Line. Printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs © -NR, 0 24 (! 5) This paper standard is applicable to China National Standard (CNS) A 4 specifications (210x297 gong) 212200 A6 B6 Λ, invention description (23)

(R, 〇) „H I —N-Ra I (R9〇) nH © Θ 06) R., ®

Ri: d7) (21) (22) (23)

Rm Ri3-CHzCH2CHCH2 ... R ,, CHmCH4CHz) t \ / R called ® θi X x CH3 r17 / \ R1Z J (CH3) 3SiO 〔(CH3) zSiO〕 n Si (Cli3) 3 (CH3) 3S1O (c6h; © < 8) • 09) (Please read the precautions on the back before filling out this page) • Crazy.

SiO) „Si (CH3) 3 (CH3) 3SiO [(CH3) 2SiO] a i (C6H5) 2SiO] b Si (CH3) CH3-Si-0 I ch3 l 3 I Si-0 I, ch3

Si-0 ch3 I -Si-CH: I, ch3 • Order ::

R Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 3-03 H i H c I s — c

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Si-0 CH: S3 c ,. i H s I c o-^ Cii3, I Si-0 I \ ch3

R 3-H i c I SIC

-3 1 H / CH:

Η C-线--Si-0 I \ R '25 This paper scale is applicable to China National Standard (CNS) A 4 specifications (210x297 mm)

i Η SIC

R 212200 A6B6 Λ, Description of the invention (24) (24) (Cli3) 3SiO ((Cli3) 2SiO] x2 [CH3SiO) y2Si (CH3) 3'-CH-CIi; \ / (25) (CH3) 3SiO (CH3SiO) x3Si (CH3)

I (CH2) 2 I cf3H0 (CHz). R6-[(CH3) zSiO] x4 (CH3) 2SiR6-CH2OH (CH3) 3SiO ((CH3) zSiO] x < (CH3SiO) y < Si (CH3)-IR6- CH · OH ICH3 (27) (CH3) 3SiO (CH3SiO) x5 (Cli3SiO) y5Si (CH3) 3 (26) (co «X s 3 \ i / 3 (cl o • 14 s

5 X H c 1 / o • i s. S c (please read the notes on the back before filling out this page) 8 2

9 R R I ο · Subscribe · H c H i H CIS 1 c o o 0-1 * 1 R I s.

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R 29

R 3 o 3 3 o 3 nu i Η H i H c I s I c c — s — c

4 0 5 3 0 4 i * 1 — r11 · l 1 R 1 SIR c — s — R • line.

3 0 5 Hi! C I s — R

R β 6 2 The size of the paper is in accordance with the Chinese National Standard (CNS) A 4 specifications (210x297 mm) 212200 A6 B6 Λ, invention description (25) 30 o Jl

o H -n s

—ClCH—silCH nu · 1 ί n ο — s IR Ή. (C. Η NH I (CII2) 2 IL NHz Jn3 printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economy [Example] The following example will be further developed The present invention, but by no means restricts the present invention. Example 1 Synthesis of 26β g (1 mol) of hydroxyethyl-2-undecyl zirconium by a general method, 54 g Water and 1.2 grams of hydrogen are placed in a four-neck flask with a volume of one liter and equipped with a mixer, condenser, dropping funnel and thermometer, and heated to this temperature with stirring Continue to stir for about two hours at the bottom. Use f to open the ring of 眯 azole # to obtain N-lauryl-N '-(2-hydroxyethyl) ethylenediamine. Then add 200 grams of ethanol. The temperature is increased to 80 TO. In order to determine the pH value of the anti-hybrid mixture, the PH electrode is inserted into the liquid. Drop 40% NaOH aqueous solution, (please read the precautions on the back before filling this page). * • Margin · 27 The size of this paper is in accordance with Chinese National Standard (CNS) A 4 specifications (210x297 mm) A6 B6 212200 V. Description of invention (26) The H value is rounded to 10. After that, 50 χ of 3-amino-2-hydroxypropyl-H, Η, Ν-trimethylammonium ammonium chloride aqueous solution 489 g (1.3 mol) is added dropwise for two hours, while an appropriate amount Add 40: NaOH aqueous solution to maintain the PH value of 10. After the 3-amino-2-hydroxypropyl-Ν, Ιί, Ν-trimethylammonium vapor is completely added, the PH value remains at 10, And at this temperature, the ore is held and stirred, and the residual amount of N-lauryl-N '-(2-hydroxyethyl) ethylenediamine can be measured by a high-performance liquid chromatograph every hour. -N-lauryl group-N '-(2-hydroxyethyl) ethylenediamine in the reaction system after six hours after -nitro-2-hydroxypropyl-N, N, H-trimethylammonium helide was completely added Will drop to U or lower, and indeed make the reaction complete. Purify the reaction solution by electrolysis, partially evaporate to dryness and dissolve in ethanol. The resulting solution is analyzed by high performance liquid chromatography, and The following three components were found to be the main components: ΓChemical formula 22] 0 CHtCHzOH CH3 I! I! Θ (a) C ,, H23CNHCH2CH2HCHxCHCH2-N-CH3 · Cl ©

II OH CHs (98% by weight based on the solids obtained by evaporation) > TR analysis and analysis results: < IR analysis > 1650 (5111- ^ (6.06 //) position can be observed It has a particularly strong absorption peak for acetamide. 28 This paper scale is applicable to the Chinese National Standard (CNS) A4 specifications (210x297 public treasure) (please read the precautions on the back before filling this page). A6 B6 212200 Λ printed by the Central Bureau of Standards' Staff Consumer Cooperative, Invention Description (27) < Mass Spectrometry > (The mass spectrometry analysis mentioned below is performed by you under the following conditions) Instrument: Made by JE0L SX-102 mass spectrometer measurement conditions: placement method: direct ionization method: FAB (Fast Atomic Impact Method) analysis results: the molecular weight of ion fragmentation M is 4 0 2, 2 2 6 A total of two main absorptions were observed Peak, 40 2 is a carbohydrate absorption peak (ΪΓ-Cl), confirming that this product is a cationic compound of the above structure. [Chemical Formula 23] 0 ch3 II 1 © (b) CiiHraCN-CHzCKtN- ^ CHzCHCHi-N-CHa · Cl ©) *

III CHzCHzOH OH CHa * »(1 weight 3ί, you use the solid obtained by evaporation as the basis of calculation) IR analysis The result of the analysis: <IR analysis> At 1650〇« 〃 (6.06 &lt; /) A particularly strong absorption peak for amide can be observed. &lt; Mass Spectrometry &gt; Analysis result: The molecular weight of ion fragment Η is 458, 2 7 0 [Chemical formula 24] 29 This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210x297 mm) (please read the notes on the back first Please fill out this page again) * Xiang · Line. Printed by the Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs Α6 212200_Ββ Λ, Invention Description (28) 〇CH3 II 'Θ (c) CnHi3CN-CH * CH * N—CH * CHCH2- N-CH3 · Cl〇

\ Η II CHzCKtOH 〇H CH3 (1 resuspended X, which is based on the evaporation of the solid as a calculation basis) TR analysis and the results of Xi europium analysis: &lt; IR analysis &gt; can be observed at the position of 16500111-46.06 //) To a particularly strong absorption peak for enzymes. &lt; Mass Spectrometry &gt; Analysis results: The molecular weight of the ion fragment Η is 4 0 2, 2 7 0 β 2 * except that 1-hydroxyethyl-2-tridecyl myrazole is used instead of the spider used in Example 1 1-hydroxyethyl-2-undecyl myrazole, repeat the steps in Example 1; and 1-hydroxyethyl-2-tridecyl myrazole,; ti you start with myristic acid Originally synthesized by fatty acids. In the same manner as in Example 1, it was confirmed that the obtained three compounds having the following structures were the main components. [Chemical formula 25] 0 CHxCHtOH CH, printed by the Employees ’Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page). Order. Line · il II® ⑻ C, 3Hz7CNHCH2CHzN-CH2CHCHi-N-CH3 -Cl ©

II OH Cfia 30 This paper scale is applicable to the Chinese National Standard (CNS) A 4 specifications (210X297 mm) A6 B6 212200 V .., Description of invention (29) (98 weight J: It is based on the solid obtained by evaporation as the calculation basis ) &Lt; Mass Spectrometry &gt; Analysis result: The molecular weight of ion fragment Η is 430, 254 0 Cfl3 II I © (b) C13HZ7CNCH2CH2N- (CHZCHCH2-N —CH3 .Cl〇) z

III CHzCH20R OH CHa (1 reset its customary calculation based on the solid obtained by evaporation) &lt; mass spectrometry analysis &gt; Analysis results: The molecular weight of ion fragment Η is 486, 298 0 CHq II ΙΘ (C) C, 3Hz7CNCH2CH2N-CH2CHCH2- N-CH3 · C10 1 Η II * CUzCHzOH OH CH3 (1 weight 3 !, which is replaced by the solid obtained by evaporation as the calculation basis) &lt; mass spectrometry analysis &gt; Analysis results: The molecular weight of ion fragmented Η is 430, 298 Example 3 except The procedure in Example 1 was repeated except that hydroxyethyl-2-pentadecyl azole was substituted for hydroxyethyl-2-undecyl azole at the first embodiment; Ethyl-2-pentadecyl quinazoline 4 wood pseudo using palmitic acid as the starting fatty acid 31 This paper scale is applicable to China National Standard (CNS) A 4 specifications (210X297 mm). Please read the notes on the back before filling in Hundreds) • Installed.-Line. It is synthesized by the 212200 Α6 Β6 Λ printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs, and the invention description (30). In the same manner as in Example 1, it was confirmed that the obtained three-value compound having the following structure was the main component. [Chemical Formula 2 6] (a) 0 CHzCHzOH CH3II I Ιθ C, sH3iCNHCH * CHxNCHzCHCH2 —N-CHj ♦ Cl.

OH CH: (98% of the weight is based on the solid obtained by evaporation) &lt; mass spectrometry analysis &gt; Analysis result: The molecular weight of ion fragment Η is 458, 282 (b) 0 CHaII I © C, 3H3iCN-CHrCH2N- (CH2CHCHt -N-CH:

Cl ©) * (please read the notes on the back before filling out this page).

CHtCHzOH OH CH: (1 weight 3: It is based on solids obtained by evaporation) &lt; mass spectrometry analysis &gt; Analysis result: molecular weight of ion fragmented Η is 514, 326 • Order · Employee consumption of Central Bureau of Standards, Ministry of Economic Affairs Printed by the cooperative (c) 0 CHsII 10CisH3iCH-CH2CH2N-CH2-CHCH * -N-CH:

CKzCHzOH I OH CH: • Green. Ci〇32 This paper scale is applicable to the Chinese National Standard (CNS) A 4 specifications (210X297 mm) A6 2122G0 _ ^ _ printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of the invention (31) (1 weight X, which is based on the solid obtained by evaporation) &lt; Quality analysis &gt; Analysis results: The molecular weight of the ion fragment is 458, 326 Example 4 Except for N- (3-laurel ~ enzyme aminopropyl- Propylamine) as the starting diamine and 3-glycopropyl-Η, Η, Η- 三甲% ^^ # cationization test thin |, repeat the steps in Example 1. And Ν- (3-laurin (Aminopropyl-propylamine) is synthesized from N-propyl-1,3-propanediamine. In the same manner as in Example 1, it was confirmed that the obtained Sanyu compound having the following structure was the main component. [Chemical Formula 27] 0 CHtCHzCH3 CH3 .. II I * θ Λ (a) CnHzjCNHCfizCHtCHiNCHzCHzCHz-N-CH, · Cl ©

I CH3 (98 weight 2, which is calculated based on the solid obtained by evaporation) TR is divided into cobalt and temporary analysis of cobalt. · &Lt; IR analysis &gt; can be observed at the position of 1650c «rl (6.06 / z) The particularly strong absorption peak of Yi sleep amine. &lt; Mass Spectrometry &gt; 33 This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210x297 mm) (please read the precautions on the f side before filling in this hundred). Therefore · · · · · · · · · · 2122G0 A6 B6_ V. Description of the invention (32) Mass spectrometry was performed under the same conditions as in Example 1. Analysis results: The molecular weight of the ion fragment is 3 98, 24 0. Two main absorption peaks are observed, and 398 is the absorption peak of (IT-C1) hetero, which confirms that this product is a cationic compound of the above structure. [Chemical Formula 2 8] 〇 CH, II * Θ 0. (B) ChH23CNCHzCH * CH2N-(-CH2CHiCHzN-CH3 · C10) 2

I I CH2CR2CHa CH3 (1 weight X, which is calculated based on the solid obtained by evaporation) 0 CHa II I © (c) Cj.HisCNCHiCfijCRzN-CRzCHtCHxH-CHa

\ Η I chzcb &lt; cr3 ch, (1 weight SI, its weight is calculated based on the solid snake obtained by evaporation) Example 5 Except for the substitution of 2,3-fluoropropyl-Ν, Ν, Ν-trimethylammonium gasification 3- The gas-based 2-hydroxypropyl-Ν, Ν, Ν-trimethylammonium gasification compound is used as an ionizing reagent for Kuma • Repeat the steps in Example 1. In the same manner as in Example 1, it was confirmed that the obtained compound was the same as the three components obtained in Example 1. 34 This paper scale is applicable to China National Standard (CNS) Grade 4 (210X297mm) (please read the precautions on the back before filling out this page). Paralyzed. • Order ·-Line-Employee Consumer Cooperative of Central Bureau of Standards, Ministry of Economic Affairs Printing correction Douyue 0 A 6 7__ B6 Λ-, Description of the invention (33) Example 6 Dissolve 50 3ί of 3-amino-2-hydroxypropyl-H, Ν, Ν-Trimethylammonium Amino Acid in water 7 5 2 grams (2 mols) and 800 grams of water were placed in a four-liter flask with a two-liter volume and equipped with a value stirrer, condenser, dropping funnel, and rent meter. Raise the temperature to 70t ;. 26-8 g (1 mol) of 1-hydroxyethyl-2-undecylpyrazol, synthesized by the general method, was dropped into it for 2 hours while the temperature was kept at 7010. To determine the pH value of the reaction mixture, PHIg was inserted into the liquid. A 40 X NaOH aqueous solution was added dropwise, and the pH value was adjusted to 10. The aging reaction was carried out at this temperature for about six hours, during which an appropriate amount of 40 × aqueous solution of HaOH was added to maintain the pH at 10. The residual children of N-lauraldehyde-N ’-(2-hydroxyethyl) ethylenediamine can be measured by high-performance liquid chromatography every hour. When the concentration of N-lauraldehyde-N '-(2-hydroxyethyl) ethylenediamine in the reaction system drops to U or lower, the reaction is determined to reach completion. The reaction solution was purified by electrolysis, partially evaporated to dryness and dissolved in ethanol. The resulting solution was analyzed with a Gordon liquid chromatograph, and the following three components were found to be the main components: [Chemical Formula 2 9] 〇ch2ch: oh ch3 (&amp;) Cj iH23CNHCHzCHzN —CH2CHCHz-N—CH3 * Cl® ( Please «5 · Read the precautions on the back and then fill out this page) • 笟 ·

OH

Η 1C quasi-basic calculation is derived from the solid solids. The amount of t Z 3 3 3 This paper scale is applicable to the Chinese National Standard (CNS) A 4 specification (210 &gt; &lt; 297 male cage)

A B 212200 Λ, Description of the invention (〇 ch3 II I © (b) Ci, HZ3CNCH2CHrN- (CHzCHCH2-N-CH3 · Cl ©) *

I I I CH, CH20H OH CHa (90 weight 2, which is calculated based on the solid solid obtained by evaporation) 〇 CHs II I © (c) C ,, Ht3CN-CH * CH2N-CHzCHCH, -N-CH3 · Cl ©

I Η II CHxCHxOH OH CH, (5 weight 3 ;, the image is based on the solids obtained by evaporation as a calculation basis> Example 7 • Green · Ministry of Economy Central Standards Bureau employee consumption cooperative printed 50 J: 3-gas- Aqueous solution of 2-hydroxypropyl-Ν, Ν, Ν-trimethylammonium 376 g (1 chile) and β00 g of water was placed in a four-necked burning temple with a volume of 2 litres Stirrer, condenser, dropping funnel and composition meter. Raise the temperature to 70 scoops. 268 g (1-mole) of 1-xiangethyl-2-undecylpyrazole spider synthesized by the general method ) Dropwise for two hours while the temperature is maintained at 70 C. In order to determine the pH value of the reaction mixture, the pH of the hibiscus is inserted into the liquid. Dropwise add 40 X NaOH aqueous solution. Adjust the pH value to 10. At this temperature Carry out the aging reaction for about six hours, during which an appropriate amount of 40 × NaOH aqueous solution is added to maintain the PH value at 10. The residual amount of N-lauryl-N ′-(2-hydroxyethyl) ethylenediamine can be changed every One hour by high-performance liquid chromatography _36 This paper scale is applicable to China National Standard (CNS) A 4 specifications (210x297 mm) A6 B6 212200 A, invention description (35) When the concentration of N-lauryl-N '-(2-hydroxyethyl) ethylenediamine in the reaction system drops to IX or lower, the reaction is determined to be complete. Purify this reaction solution, and partially evaporate it to dryness. From the results of IR and mass spectrometry, the product obtained is a mixture of the following three components, and its main component is lauryl-N- with the following structure (2-hydroxyethyl) -K'- [3-OT trimethylammonium) -2-hydroxypropyl-ethylenediamine amine compound (c): [Chemical formula 30] (Please read the precautions on the back before filling in this Hundred) (a) 0 CH * CH * 0H CH3 II ... 丨 &lt; Θ C, jHtaCN-CHxCHiN-CHrCHCHz-N-CH, Η I 1 OH CH3

Cl © _wo. (5 weight is based on the solids obtained by evaporation) 〇 ch3 (b)

Cl ©): II ιΘ

Ci iHzaCN-CBiCHzN-iCHzCHCHz-N-CH ^

CHtCUtOH OH CH: Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (35 weight! Ϊ, 傜 is calculated based on the solids evaporated) (c) 〇ch3 1! I © C ,, H23CN-CH * CH2NHCH * CHCHz -N-CH3 ♦ Cl ©

CtfzCHtOH 〇H CH: 37 • Line, the paper scale is applicable to the Chinese National Standard (CNS) A 4 specifications (210x297 mm) 212200_ Manganese A, invention description (36) (60 weight ί, which is generally calculated based on the solids obtained by evaporation Benchmark) The test examples evaluate the surfactants prepared in Examples 1 to 4 and 6 and 7 and the control compounds 1 and 2 known to have mild effects on the skin, and The ability of Control Compound 3 with high foaming ability in terms of irritability, foaming ability and cleaning effect on the skin. The evaluation results are shown in Table 1. &lt; Control Compound 1 &gt; Softazolin CH (N-Coconutyl-Ν'-Hydroxyethyl-Ν'-Methyl-Ling-Propionate) produced by Kawaken Fine Chemicals Co., Ltd. &lt; Control compound 2 &gt; Alanon ALE (N-laurylmethyl- / 3-alanine sodium) produced by Kawaken Fine Chemicals Co., Ltd. &lt; Control compound 3 &gt;, EnalTD (lauryl sulfate palladium) produced by Kao Corporation. &lt; Evaluation method &gt; Test on the irritability of the skinny: Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling in the hundred) Use the subject for 24-hour local close-up test. In this test, the waist sticking ointment used for local testing was impregnated with 0.1 ml of an aqueous solution of 0.2¾ interface active agent as an active ingredient, and was applied to 20 subjects for 24 hours. After 24 hours, the mash sticking ointment was removed, and the skin was inspected. When a clear erythema is observed, the I test result is considered positive. The evaluation result is expressed as a positive degree. 38 This paper scale is applicable to China National Standard (CNS) A4 specifications (210x297 mm) 212200 A6 B6 Printed by the Consumer Standardization Bureau of the Central Standards Bureau of the Ministry of Economic Affairs A, invention description (37; foaming ability test: 4 * DH of hard water Dilute the active ingredient of the interfacial active ingredient to a final concentration of 0.23 !, and determine its foaming ability by the reverse mixing method. In the case of 40 * C and the test solution containing 0.33: lanolin Under the foaming ability test, and the test result is expressed in the amount of foam (ml). Cleaning ability test: will contain the same composition of gray ash. If it contains 23: carbon black scalp fat (that contains 123 : The composition of spleen, 21X wax ester, 263; triglyceride, 325; higher fatty acid, 5J: cholesterol and 23: glycerol monoacid cooler>, added at 5 cm X 5 cm On a large dry wool cotton cloth. Place this piece into a ® volume of 100 ml and contain 500 ml of cleaning solution (containing 0.63: the active ingredient in the surfactant, and the PH value is 7. 0. The hardness is DH ) In the stainless steel pin ring barrel. Place this barrel in a temperature of 40¾ Shake for six minutes in a warm water bath. Then rinse the cotton cloth with tap water and dry it. Measure the number of reflections of the cotton cloth. The cleaning rate is determined by the following formula: cleaning rate (%) = (after washing Reflective pseudo-number) One (reflected vulgar number before cleaning)-X 10 (the original number of reflective wains of cotton cloth) one (reflected virgin number before cleaning) (please read the precautions on the back before filling the nest This page) -Installed. .Ordered. • Thread · 39 This paper scale is applicable to the Chinese National Standard (CNS) A 4 specifications (210X297 mm) 212200 A6 B6 Λ, Invention description (38) [Table 1] Characteristic example Comparative example 1 2 3 4 5 6 7 1 2 3 Anti-pigmentation 0 0 5 10 0 0 0 15 10 90 Foaming capacity (ml) 125 165 150 120 125 J30 130 110 85 175 Cleaning rate (%) 40 45 40 40 40 40 40 45 20 20 f Please read the precautions on the back before filling in this alfalfa) Printed Example 8 Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 8 The formation of the favorite meeting: 200 g (《«: 200,1 Mol) with cinnamic acid and 135.2 g (11 »1: 104, 1.3 mol) of aminoethylacetamide (AEEA) water and 1.2 g of hydrogen Sodium is put into a four-neck flask with a volume of one liter. It is equipped with a stirrer *, reflux condenser, thermometer and pressure gauge. This mixture is stirred and heated to 14 0 Ϊ: At the same time 8 0 * 0 water flows into the reflux condenser. Then set the reaction pressure to 400 mmHg in one hour. • Allow it to undergo aldination for 2 hours. Then, within 1.5 hours, the reaction temperature and pressure were changed to 200 ¾ and 200 mm Hg, respectively, and aging was conducted under these conditions for one hour. Then reduce the pressure to 10 mm Hg in about two hours, and perform a two-hour reaction under these conditions to remove excess AEEA; however, the water vapor and excess AEEA formed in this step Vapor will be collected by the soda que and cooled with dry ice / methanol. Line. 40 This paper scale is applicable to China National Standard (CNS) Grade 4 (210x297 mm) 212200

AB V. Description of the invention (39) The 268 grams of reaction product thus obtained mainly includes 1-hydroxyethyl-2-ylimidazole tetracycline, and then the four-neck flask meter and drip of phenylpyridazole When the flask was wicked with ethanol and &quot; C, an aqueous solution of one substance for 100 g hours. Then in the 2Ϊ gas in the above example, equipped with a funnel. In this 25 g hour, 3 7 6 g was dripped in three hours to obtain 2 68 g (1 mol) of 18 g of sodium ethoxylate solution. Put it into a stern mixer, In the case of reflux mixing, the temperature is increased for two hours. Add the same water to the flask here. When the temperature is 50 X, 3-amino-2-hydroxypropyl-2-undecanoyl is a one-liter condenser, and the temperature is raised to 80 * C, and the temperature is raised 250 times to 80 trimethylammonium atmosphere. The aging reaction of argon gasification and water release into the flask. Then slowly drop 40 Ϊ into it and make it carry out 2-hydroxy-3-[(2-hydroxyethyl) [2-[(1-gasododecyl) amino] ethyl with the following chemical formula 】 Amino] propyl-N, N, N. Trimethylammonium carboxide 35 3: Aqueous solution:

CH3 i © Θ N -CH3 Cl OH CH3 (please read the precautions on the back before writing this page) k: -line. Printed example 9 of the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 9 ·. Except that myristic acid is used as the starting fatty acid, the same as in Example 8 41. The paper size is applicable to the Chinese National Standard (CNS) A4 specifications (210x297 Gongchu ·) 212200 A6 B6 V. Description of invention (厶 〇 ) Method to prepare hydroxyethyl-2-tridecyl quinazoline tetrazolium. Reaction: In addition to using the above hydroxyethyl-2-tridecyl quinazolium as the starting anisole 4 • The reaction was carried out under the same conditions as in Reference Example 1. 2-Hydroxy-3-[(2-hydroxyethyl) [2- [U-aminotetradecyl) amino] ethyl with the following chemical formula was obtained 】 Amino】 propyl-Ν, Ν, Ν-trimethylammonium gasification 35 3; aqueous solution: H CH3 II © © (please read the precautions on the back before filling in Benja) Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs Preparation Example 1 Ο Formation of amidine compound: 1-hydroxyethyl-2-coconut was prepared in the same manner as Example 8 except that coconut fatty acid was used as the starting fatty acid Imidazole ^^ Tetrahybrid bitter bite: In addition to the use of the above 1-hydroxyethyl-2-coconut benzoxazole # as the starting odorazole • bad, the reaction was carried out under the same conditions as in Example 8, and An aqueous solution of compound 3 5 3; with the following chemical formula is available: CH3 I © © N -CHa ClI CH3

. Order • Line.

This paper scale is applicable to China National Standard (CNS) Grade A (210x297 mm) printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. A6213200_ B6_ V. Description of Invention 7 1) The RC0-like represents the residue of coconut fatty acids. Example 1 1 Squint 丨) Formation of meeting matter: Under the same reaction conditions as in Example 8, hydroxyethyl-2-undecyl myrazole, Lin's myrazole, and mu compounds were prepared. Four Newtons should: _ Then the hydroxyethyl-2-undecyl squint produced by the above method was 4 ^ 2 68 g (1 mol) and 22 g of vaporized sodium hydroxide aqueous solution 18 g Placed in a four-neck flask with a volume of two liters, and equipped with a tilting stirrer, condenser, thermometer and dropping funnel. With stirring, raise the temperature to 80 ° C and maintain the flask at this temperature for two hours. Then add 250 grams of ethanol and 250 grams of water to the flask at the same time. When the temperature rises again to 80t !, 50S: N- (3-Amino-2-hydroxypropyl) -N-hydroxyethyl-N, N-dimethylammonium helium compound (molecular weight: 218) of 436 grams of aqueous solution was dropped into the flask within one hour. The volatile compound was composed of 92.5 grams of epigas alcohol (molecular child 92.5 grams, 1 mole), 35 3; hydrochloric acid aqueous solution 104 grams (molecular weight is 36.5 g, 1 mol) and 150 g of ion-exchanged water. Then, 100 grams of 40 χ sodium hydroxide aqueous solution was dropped into the flask within three hours, and the product had to be aged for eight hours. From the above steps, 2-hydroxy-3-[(2-hydroxyethyl M2 [(1-hydroxydodecyl) amino] ethyl] -amino] propyl-N-hydroxyethyl Aqueous-Ν, Η-dimethylammonium oxide solution in water, with a degree of 35 Ϊ: (please read the precautions on the back before writing this page), browse · _ 定 _. 线. This paper size applies to Chinese national standards (CNS) A 4 specifications (210X297mm) 212200 A6 B6 A., Description of invention (42)

OH Γθ θ κ -ch3 Cl Example 1 2 About the following quaternary ammonium salt cationic surfactants and comparative surfactants, the foaming properties, the resistance to the skin, the cleaning ability and the resistance to hard water are all Test with the test method described below. The test results are listed in Table 2. &lt; Surfactant used &gt; Surfactant 1 of the present invention:

C, 3H

ch3 I © Θ Ν—CH3 C1 (please read the precautions on the back before filling in this page) • Ordering • Surfactant of the invention 2 Η Printed ch2〇h I © * Θ by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs线. C j 3 Η 2 1 ο

-CHti Cl OH CHa kk This paper scale is applicable to the Chinese National Standard (CNS) A4 specifications (210x297 mm) 212200 A6 B6 Printed Λ, invention description by the employee consumer cooperative of the Central Standards Bureau of the Ministry of Economic Affairs (43) Comparative surfactant 1: Surfactant for comparison of H-laurelyl-H-methyl- / 3-naphthylpropionate 2: Comparison of lauryl triethanolate (T rietha η ο 1 aine 1 aury 1 su 1 fate) Surfactant 3 used: Cetyltrieethyla ^ iionieB chloride (Cetyltrieethyla ^ iionieB chlorid) &lt; Test method &gt; In the same way as the evaluation method, the foaming properties, skin irritability and cleaning ability are carried out in the same way as the evaluation method. test. The quality of the foam is evaluated according to the following criteria: ○: Creamy △: Slightly rough X: Rough hard water resistance test: &gt; Addition of vaporized calcium to a 0.U interface active thin I aqueous solution In order to adjust the hardness to 10 (T Dl, the appearance of this aqueous solution was observed with the naked eye at room temperature. ○: Obtain a transparent solution X: The solution contains Yuandian or flocculent lubricating properties: 20X surfactant 1g of the aqueous solution of the active ingredient is used on the hair of a Japanese female subject weighing 20g. After foaming, rinse with 40¾ of water and blow dry with a hair dryer, and the lubricating effect is by five Occupational assessment committee to evaluate. ○: Excellent lubrication effect (please read the precautions on the back before filling out this page). Tobacco .. Order · • Green · _._ A5 This paper standard is applicable to China National Standards (CNS ) A4 specifications (210x297 mm) 212200 A6 B6 V. Description of invention (

足 不 έΗΚ. 1 Γ 1 Very good, slightly unsatisfactory, moisturizing Δ X 2 Table 1 Comparative Example 1 2 1 2 〇Excitability to skin 5 5 10 90 90 Foam amount (ml) 165 165 85 165 40 Foam quality 〇〇Δ X 〇 Cleaning rate (%) 40 30 20 10 Hard water resistance 〇XX 〇 Lubrication effect 〇XX 〇 Please read the notes on the back before writing this page) • Inch:…: Power Bubbling and 0K. Body cleansing. Clean and fine hair should be washed, and the phases should be grouped, fine, hair, and hair washed, and it should be made. 3 cases of TX produced by the Ministry of Economy, Central Bureau of Standards, Employee and Consumer Cooperatives printed it. The light and astringent hair is made into hair, and the head body is washed when it feels right. It will wash only and concurrently; the washability will be hard in water, and it will be hard to resist. When the touch is good, the group of objects &lt; Ligong 461297 X ο T1 2 / IV specification 4 A \ 1/5 CN Appropriate ruler paper and on-line. Standard line * 212200 V., Description of invention (45) A6 B6

OH CH3 lauryl dimethyl ammonium vapor gas hexadecyl trimethyl ammonium oxychloride carboxymethyl cellulose "1 hydroxyethyl hung vitamin" s sodium benzoate colorant fragrance citric acid water PH value 15 weight 3 2 the right amount the right amount The total amount is 6.5 (please read the precautions on the back and then fill in this page). 浞 · • Order · Made by the Central Bureau of Economic Affairs of the Ministry of Economic Affairs, consumer cooperation cooperation

Note) * 1: No 1310 produced by Da icel company * 2: SE-850K produced by Daicel company Example 1 4 Manufacture bath essence containing the following composition. The bath essence obtained has a very good cleaning effect and lathering ability, and it will only cause irritating stimulation to the human body. After taking a bath with shower gel, the user will have a smooth and comfortable stool. 47 This paper scale applies the Chinese National Standard (CNS) V4 specification (210X297 mm) 212200 A6 B6 4. Description of the invention (46) &lt; Composition &gt; Η I C · 3 Η ζ ΤΓ χ N 0

CH3 Ιθ θ N -CH, CL Lauryl dimethyl ammonium gasification polyoxyethylene (3) methyl glucose into glycerol sucrose fatty acid ester methylparaben colorant flavor citric acid ^ water PH value 15% by weight 3 5 5 1 0.3 Appropriate amount Appropriate amount Appropriate amount is sufficient to make the total amount even 1002 (please read the precautions on the back before filling in this page) Order · Printed by the Ministry of Economic Affairs Central Bureau of Standards for Consumer Consumption 48 This paper standard is applicable to China National Standard (CNS) A 4 Specifications (210x297 mm) 21 ^ Q0 Amend the comparison data in Patent Case No. 80106500 According to the synthesis method described in the cited document "Principle and Application of Surfactant", this compound was synthesized (hereinafter referred to as the cited document compound) 0II CiiH23CNHC2 H4 NHCa H4 ch3 I Θ -N-CH3I CH3 ce 0

OH H CUH2SCNC2H4NC2H4NH2 C11H23COOH λ + ---- ^ + NH2C2H41iIC2H4NH2 steamed NCH2 HC 11H23C, I 2 Ν C Η2 C2H4NH2 N aOH (cat) in a flask equipped with a stirrer, thermometer, cooling tube, 1 liter Mix 200 g (1 mol) of lauric acid and 652 g (6.3 mol) of diethylenetriamine, and mix at 180 t for 18 hours. The excess triamine was removed under reduced pressure, and a mixture of compound 1 and compound 2 was obtained by distillation. Distillation boiling point 236 ~ 273t / 0.4mBiHg. Next, in a 500 m four-necked flask equipped with a seed mixer, thermometer, and reflux cooling tube, add 200 g (equivalent to 0.7 mol) of distilled water, 42 g of water, 1 g of sodium hydroxide, and 100 g of isopropanol , And stirred at 80 = 10 for 1 hour to hydrolyze the imidazoline compound 2 (the product is compound L). The end of the reaction is based on IR from Mizoline OH H CllH23CNC2H4lSiC2H4NH2

3 CH3C 1 —-> Quaternization Cited literature compound 212200 C = N near 1 600cm-1 absorption is confirmed by the fact that it moves to 1 640cib- from amide C = 0. The above reaction solution (compound 1 is equivalent to 0.7 mol): 151.5 g (2.1 lniol) methyl chloride was charged into a 1 liter autoclave, heated at 80¾, and 11 7 m 1 (1.4 m ο 1) of 4 8 S! Hydrogenated sodium hydroxide solution was pressed in for 2 hours and stirred at 80 t for 5 hours. After the end of the reaction, cool and filter the precipitated sodium oxychloride, collect the filtrate, minus ® concentration, and obtain the cited literature compounds. The performance comparison results are shown in the table below. The method is the same as Table 2 in this case. Citation Document of the Invention Compound 1 2 is irritating to skin 5 5 90 Foam amount (ml) 165 165 50 Foam quality 0 0 0 Cleaning rate (96) 40 30 10 Hard water resistance 0 0 0 Lubricating effect 0 0 0 --- .-φντ ί. Q t ^ 2 ^ 82. 4 2 ^ -1 29 CH3-CH2-CH2-OH2-CH2-CH2-CHYCH2-CH2-CH2-CH2-cz-CHZ-CH2-2HICin2-c3: -CH2 -2 * (CH3 &gt; 14 23 32 〃 』25¾ [73 one with two 7 53 S67 s-CH2-ci c 14 ΰ 32

0 II o'r 29 .25is? I73 Iδs CH2-CI 51 Ξ 59 £ s 54 o = YOSI05IOS.OSIOS.03 &lt; OX ^ OIVOX ^ S ^ .OIZIO ^^ OS.Z ^ OrMio? Ox5 * ^ σ &gt; J4 ΰis ¾ 0 one one 39 s

OH I Ξ 64 s cmrciH s 60 54 CS3-C H2-C H * fc H2-C HVCH2-C H2-C H2IC H2-C H2-C H2-C-2 HC H2-C H2-NC H 2—c HC H 2-NM c H3 &gt; 3 (a &gt; 0

OH 2 212200 29 51 61

CHS-CH2-0H2-CH2-CH2-CH2-CH2-CH2-CH2-CH2-CH2-CH2-CH2-CN-CH2-CH2-2H-CH2-CH-CH2-N * {CH3 &gt; 3 14 23 32, '25 33 173 1 ft 47 532¾s-CHZ-CI -c. 14- 2SW «O-

OH ¾ 25isS3 l ± s CH2-CH20H 51 2 592: ¾ 54 C H3-C H2-CH2-0 H2-C H2-C H2-C H2-C H2-C H2-C H 2-QH2-C H2- C Hz-CM—C H2-C H2-2 + C H2-C HC H2-Z + (c H3) 3 (b) 29 7 23is

0 II 25 3 2 74 39 s

OH 54 CH3-CH2icH2-cn2nIi2-CH2-CH2-CH2-CH2-CH2-CH2-CH2-CH2-c-2H-CH2-CH2-N-CH2-CH-ca: 2-z- (CHJ> 3 -ffl ο

OH Kai J: 2 212200 CH3-cn2-CH2-CH2-CH2-CH2 ~ CH2-CH2-CH2-CH2-CH2-CH2 &lt; CH2-CH2-CH2-? Rv-CH2-CH2-2; H-CH2-CH -CH2-2 :, (CH3) 3 Η Bv »2 ·, 25 33 175 1¾ 47 53 64 67 54 --- M ~ ^ Cm-QSOH 29 51«) 14 23¾ 29

O

OS 25 33 i73 ~ 44 s CH2-CH20H 51 2 59 W 67 54 CH3-CH2-CK2-CH2-CH2-CH2-CH2-CH2-CH2-CH2-CH2-CH2-s2-ctc2 ~ ca: 2-cM- CH2-CH2-2: f CH2-CH-CH2-2 * (CH3> 3 (b) 14 23W2 B.

OII

OH 29

οII 39 60 15? 64 s CH2—-0H20H 5B s

OH 2 2 212200

(c &gt; 0IIC H3-0H2-CH2-C H2_c H2-C H2-C H2-C H2-C Hvc H2-C H2-C-Z1C H2-C H2-C H2-2H-C H2-C H2-CK2 -2 * (C H3 &gt; 3 J4- 23 32 ”'25 s .Is IS521 46 47s¾s-^ CH2-CH2-C5 29 49 22 U? 23u &gt; 2 ¾ 25 33 175 I * s53 CH2-CH2-CH5 ¾n 11 53 24¾ 54 C H3-C H2-C H2-C H2-C H26H26H2-C H2-C Hvc H2IC H2-CNC mC H2-C H2-Z-+-CHZ-C H2-C H2-N * (C H3 &gt; 3 (b &gt; 14-κ32 29 Ο ¾27 53 M3 s 67 CH2 丨 CH2-CH3 56ΰc 54 to C5-C H2-CH2-C H2-C H2-C H2-C H2-C H2-C H2-C H2 -C H2-C-ZH-C sc H2-C H2-NC H2-C: H2-C X2-N * (C Η》) 3

Claims (1)

6. Application for amendments to the patent application park A7 B7-C7 D7 IfT No. 801 06500 Patent Case for "Cationic Compounds and Detergents" (Amended in March 1982) 1. A cationic compound of formula (I): 0 RZ II I © R'CN- (C1U) "N- (CHz)" CHCH.N-R3 · A © III GEY (I) where R1 is a linear or branched alkyl group having 7 to 15 sulfonic atoms; R2 , R3 and R4 are each independently an alkyl group having 1 to 3 Y atoms: G is a hydrogen atom, an alkyl group having 1 to 3 N atoms, or an alkyl group having 1 to 3 N atoms; E is hydrogen Atom, alkyl group with 1 to 3 atoms, "alkyl group or ammonium group with formula (II) with 1 to 3 atoms: R2 • θ-(C1I2)„ chch2n-r: II γ R4 Θ (II) Printed by an employee consumer cooperative of the Central Standards Bureau of the Ministry of Economic Affairs, Y is a hydrogen atom or a radical, A is a halogen atom, b is 2 or 3, n is 0 or an integer from 1 to 5, but if (1) is G is alkyl or "alkyl", then E is neither alkyl nor alkyl. (2) G and E are not hydrogen atoms at the same time, and (3) when η is 1, Y is a radium atom or "Base; and when η is 0, 2, 3, 4 or 5, then Υ is hydrogen 2. For a method of preparing a compound as claimed in Item 1 of the patent scope, the step fee [including a amine represented by the chemical formula (2) .................. ......................... A ..... 5i ............ ............ tr .............- ............ φ (please read first The precautions on the back page are on this page.) The paper size is applicable to China National Standard #CN (CNS) 4 specifications (210X297mm) 2ι1 · ^ βθ · Α7 Β7 C7 D7 VI. Scope of patent application Printed by the Beigong Xiaozhi Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs, where R1, nr are as defined in Patent Application No. 1; and G3 is an alkyl or hydroxyalkyl group having 1 to 3 sulfon atoms and / or a chemical formula such as (3) Enzymatic amine shown 0 II R ^ N-CCHz) ,,, KH (3) IIG * G * where R1 and b are as defined in item 1 of the patent application park; and G1 and G2 are K atom * alkyl group having 1 to 3 iodine atoms or alkyl groups and stipulating that at least one of G1 and G2 is an alkyl group having 1 to 3 tungsten atoms or an alkyl group and a decay as shown in the chemical formula (4) Ionization reagent • θ Z- (CIU) n CHCHhN-R3 · ΑΘ ⑷ IIY R4 where R2 * R3, Y, A and n are as defined in the first item of the patent application park; and Z is a halogen atom, in water, low-level fermentation , The second enzyme or its mixture is reacted, and the pH value of the reverse solution is adjusted to 7-12 with the age solution. If necessary, the temperature of the reverse enzyme is not higher than 100¾. Use 1 to 3 ears per mole of the compound, compared with Preferably 1.1 to 1.5 moles of cationizing reagent (4). 3. A method for the preparation of the first compound of the patent application, where η is 1 and Y is the base, the steps include the application of the patent application for the application of patent application No. -2- (please read the notes on the back first (Revisit this page) • Installed. .. The size of the paper is used in the Chinese National Standard (CNS) A 4 specifications (210x297 mm) A7 B7 C7 D7 21.2.20Q 6. Apply for a patent fan park (please read the notes on the back first Please fill in the "quote" on this page) The amine represented by the chemical formula (2) defined in item 2 and / or the aldamine amine represented by the chemical formula (3) defined in item 2 of the patent application model and the chemical formula ( 5) Limitation shown in the ionization test R2 I CH2-CH-CH2-H®-R3 · Αθ ⑸ \ / I 0 R4 where R2, R3, R4 and Α are as defined in the first item of the application scope; Yu Shui , The lower alcohol, the second enzyme or its mixture, and the pH of the reaction solution is adjusted to 7-12 with the age solution, if necessary, the reverse temperature is in the range of 30 to 120 C, per mol of the amine compound. 1 to 3 mols, preferably 1.1 to 1.5 qi yang maleization reagent (5). Printed by the Employee Consumer Cooperative of the Ministry of Economic Affairs, Bureau of Standards, 4 a Kuma ionic surfactant composition, which includes (a) a cationic compound as shown in the chemical formula (I) as defined in item 1 of the application park, where G is Hydrogen atom, E is an alkyl group having 1 to 3 stern atoms or an alkyl group having 1 to 3 stern atoms; Kuma ionic compounds, where G is an alkyl group having 1 to 3 yoshio atoms or an alkyl group having 1 to 3 sulfo atoms and E is an ammonium group as in formula (II), and (a>: (b) The proportion of the model garden is (99 ~ 5): (1-95). 5. If the composition of item 4 of the patent application garden, it includes (c) the chemical formula (U shown in item 1 of the scope of patent application) A cationic compound, wherein G is an alkyl group having 1 to 3 atoms or an alkyl group having 1 to 3 sulfo atoms and E is a hydrogen atom, and (a): (b): (c) -3 -This paper scale is applicable to China National Standard (CNS) A4 specifications (210x297mm) A7 B7 C7 D7 aim 6. The range of patent application scope is (99 ~ 3): (0.5 ~ 95): (0.5- 70). (Please read the precautions on the back before filling in this page) 6.-A kind of detergent composition, which includes a cationic compound and a carrier as defined in item 1 of the application scope. Pouring from water-soluble polymers and anionic polymers Or water-dispersible silicone compound, for example, 0.05 to 5.0 tb of the whole composition. 7. A kind of detergent composition, which includes the Kuma ion compound as defined in item 1 of the patent application scope. When the substance is a liquid cleaning agent, a paste cleaning agent, or a solid or powdery cleaning agent, the proportions are 0.1-50wt35, 0.1-80wt! U or 50-99wtS; Agent, when the cleaning agent composition is a body cleaning agent, a paste cleaning agent, or a solid or powder cleaning agent, the proportions are 0.05-10wt% »0.05-20wt! Ugg 0.05-20wtS! 〇8. For example, if you apply for the No. 6 cleaning agent composition, it will include a shampoo additive. 9. If you apply for the No. 6 patent cleaning composition, it will also include a water-soluble polymer, Anionic polymer, another cationic surfactant or water-dispersible silicon Ketone compounds. Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 10 as the cationic compound of the first item of the patent application, where R1 is a straight bond or branched alkyl group with 7 to 15 atoms; R2, R3 R4 and R4 are each independently an alkyl group having 1 to 3 atoms; G is a hydrogen atom; E is an alkyl group having 1 to 3 atoms or a drag alkyl group having 1 to 3 atoms; Y is a hydrogen atom Or residues, A is a halogen atom; η is 2 or 3; η is zero or an integer from 1 to 5, but if η is 1, then Y is hydrogen. This paper scale is applicable to China ’s B Family Standard (CNS ) A 4 specifications (210X297 mm) / 777 AB c D-VI. Application for a patented atom or hydroxyl group; and when η is Ο, 2, 3, 4 or 5, Y is a hydrogen atom. (Please read the precautions on the back before writing this page) 11 For example, the cationic compound in the first item of the patent scope, where R1 is a straight or branched alkyl group with 7 to 15 large atoms; R2, R3 and R4 is each independently an alkyl group having 1 to 3 atom atoms; G is a hydrogen atom; E is an ethyl group; Υ is a base; A is a halogen atom; m is 2; and η is 1 ° Composition, which includes a cationic compound of formula (I ') 0 Rz II 1〇R'CN- (CHt) «N- (CHz)„ CHCH2N-R3 · fi © αΜ II II GE y R4 Printed by the Staff Consumer Cooperative of the Bureau of Standards where R1 is a straight-chain or branched alkyl group with 7 to 21 sulfon atoms or a straight-chain or branched alkenyl group with 7 to 21 W atoms; R2 · R3 and R4 Each is independently an alkyl group having 1 to 4 valence atoms or a "alkyl group having a sulfo atom of 1 to 4; G is a hydrogen atom; E is a branched ethyl group; Y is a« group; A is a bismuth atom, having 1 5 * alkyl or alkylsulfonate up to 4 atoms; η is 2; and η is 1, when the cleaning agent composition is liquid cleaning agent, paste cleaning agent, or solid or powdery Cleanser The proportions are 0.1-50vtX, 0.1-80wtX or 50-99wtX; and a carrier-loaded, S self-water-soluble polymer, anion polymer or water-dispersible silicone compound, with a total composition of 0.05-5.0wtS : Proportion. -5- This paper size is applicable to China National Standard (CNS) T4 (210x297mm)