TW202333649A - Oil-in-water emulsion cosmetic - Google Patents

Abstract

To provide an oil-in-water emulsion cosmetic that is exceptional in terms of having no disparity between the color of appearance and the application color, not releasing water at high temperature, achieving uniformity in a cosmetic film, providing a smooth transition, and having no change in feel of use during application. Provided is an oil-in-water emulsion cosmetic characterized by containing components (A)-(E), specifically (A) 0.5-10 mass% of tranexamic acid, (B) 1-10 mass% of niacinamide, (C) 1-30 mass% of a metal oxide, (D) a C12-20 fatty acid or ester thereof, and (E) a water-soluble polymer, the total amount of the component (A) and the component (B) being 3-14 mass%, and the component (C) being contained at least in an outer aqueous phase.

Description

Oil-in-water emulsified cosmetics

The present invention relates to oil-in-water emulsified cosmetics.

Make-up cosmetics such as foundation and makeup primer have an immediate function of making the skin look even through its skin-correcting effect. In recent years, active ingredients blended in quasi-drugs have been blended into makeup products such as foundations and makeup primers. In addition to immediate skin correction effects, they are also praised for their long-lasting effects. The demand for products that use active ingredients to improve skin is rising. For example, nicotinamide is one of the vitamins that has effects on the skin such as wrinkle improvement, skin barrier improvement, whitening, and skin improvement. It is known that tranexamic acid has an anti-inflammatory effect and is used as an active ingredient in pharmaceuticals. It is also known to have an effect of inhibiting melanin production. A composition containing these two ingredients with different effects is expected to bring various effects to various skin troubles. However, since these active ingredients are electrolytes and are mixed into makeup cosmetics such as foundation and makeup primer, they will impair the powder dispersion, so there is a problem that the appearance color and the application color are easy to produce a gap. In particular, these problems appear particularly prominently in oil-in-water cosmetics containing both these electrolytes and metal oxides in the water phase. Until now, various studies have been conducted on methods for improving powder dispersibility.

There are known techniques for improving dispersibility by treating powder with a silane coupling agent and compounding it with a specific hydrophilic resin (for example, Patent Document 1); and coating the surface of the powder with polyethylene. A method using pyrrolidone treatment (for example, Patent Document 2). [Prior technical literature] [Patent Document]

Patent Document 1: Japanese Patent Application Publication No. 10-45949 Patent Document 2: Japanese Patent Application Publication No. 2001-48731

[Problem to be solved by the invention]

However, although the dispersibility of the powder can be improved by using the above-mentioned technology, the oil-in-water emulsion composition may have a situation where the feeling of use gradually changes when it is spread out during application. Along with this, the makeup film may become uneven, the smoothness of the stop may be poor, and the stability may be poor such as drainage at high temperatures.

Therefore, the present invention provides an oil-in-water emulsified cosmetic that is excellent in that there is no difference between the appearance color and the applied color, no drainage at high temperatures, uniformity of the makeup film, smoothness of stopping, and no change in the feeling of use during application. [Means used to solve problems]

In view of the above-mentioned actual situation, the inventors of the present invention have made repeated efforts to study in order to solve the above-mentioned problems, and found that by combining tranexamic acid, nicotinamide, metal oxides, saturated fatty acids or their esters, and water-soluble polymers, The present invention was completed by obtaining an oil-in-water cosmetic that is excellent in that there is no difference between the appearance color and the application color, no drainage at high temperatures, uniformity of the makeup film, smoothness of the stop, and no change in the feeling of use during application.

That is, the present invention is: [1] Provide an oil-in-water emulsion cosmetic, characterized by containing the following ingredients (A) to (E): (A) Tranexamic acid 0.5 to 10% by mass, (B) Nicotinamide 1 to 10% by mass, (C) Metal oxide 1 to 30% by mass, (D) Fatty acids with 12 to 20 carbon atoms or their esters, (E) Water-soluble polymer, The total mass content of the component (A) and the component (B) is 3 to 14% by mass, and at least the external water phase contains the component (C). [2] Provide the oil-in-water type emulsified cosmetics as described in [1], wherein the metal oxide of the component (C) is one or more selected from the group consisting of titanium dioxide, zinc oxide, and iron oxide. [3] Provide the oil-in-water type emulsified cosmetics as described in [1] or [2], wherein the fatty acid of the component (D) is selected from the group consisting of lauric acid, myristic acid, palmitic acid, and stearic acid. One or more than two kinds. [4] Provides the oil-in-water type emulsified cosmetics according to [1] or [2], which further contains component (F) a phosphoric acid-based surfactant. [5] Provide an oil-in-water emulsion cosmetic as described in [1] or [2], which contains the aforementioned component (C) in an external water phase and an internal oil phase, and the internal oil phase contains the aforementioned component (C) The ratio of the content mass to the content of the aforementioned ingredient (C) in the cosmetic is 0.35 to 0.8. [Effects of the invention]

According to the present invention, it is possible to provide an oil-in-water emulsified cosmetic that has no difference in appearance color and application color, no drainage at high temperatures, uniformity of the makeup film, smoothness of stop, and no change in the feel of use during application. , so it can be used in makeup primer, foundation, etc.

[Form used to implement the invention]

Hereinafter, preferred embodiments of the present invention will be described in detail. However, the present invention is not limited to the following preferred embodiments, and can be freely modified within the scope of the present invention. In addition, in this specification, "%" means "mass %" unless otherwise specified. Also, when "~" is used to indicate a numerical range, the range includes the values at both ends.

The component (A) tranexamic acid in the present invention is one of the amino acids represented by trans-4-(aminomethyl)cyclohexane-1-carboxylic acid. Tranexamic acid is sometimes used for skin whitening and anti-inflammatory effects, and is sometimes used as a hemostatic agent.

The content of component (A) in the present invention is 0.5 to 10% by mass (hereinafter, only "%" is abbreviated). Preferably it is 1% or more, More preferably, it is 2% or more. Moreover, it is preferably 8% or less, more preferably 5% or less. Moreover, 1 to 8% is preferable, and 2 to 5% is more preferable. If it is within this range, it is more excellent in terms of no drainage at high temperatures, smoothness of stopping, and no change in the feeling of use during application, so it is more preferable. If the content of component (A) is less than 0.5%, there may be cases where there is no change in the feeling of use when applied. If it exceeds 10%, there may be problems with drainage at high temperatures, smoothness of stopping, etc. .

The component (B) nicotinic acid amide used in the present invention is an amide compound of nicotinic acid (vitamin B3/niacin). Nicotinamide is a water-soluble vitamin and a well-known substance that is one of the B vitamins. It can be extracted from natural products (rice bran, etc.) or synthesized by well-known methods. Specifically, those included in the 17th edition of the Japanese Pharmacopoeia can be used.

The content of component (B) in the present invention is 1 to 10%. More preferably, it is 3% or more, and more preferably, it is 4% or more. Moreover, it is preferably 10% or less, more preferably 9% or less. Furthermore, 3 to 10% is preferred, and 4 to 9% is more preferred. If it is within this range, it is more excellent in terms of no high-temperature discharge and no change in the feeling of use during application, so it is more preferable. If the content of component (B) is less than 1%, it may not be possible to obtain a change in the feeling of use when applied. If it exceeds 10%, there may be problems with drainage at high temperatures, smoothness of stopping, etc. .

Moreover, the total mass content of component (A) and component (B) is 3-14 mass %. Preferably, it is 4-10%, More preferably, it is 5-8%. If it is within this range, it is excellent from the viewpoint of smoothness of stopping and so on, so it is more preferable.

As long as the metal oxide of component (C) in the present invention can be used in ordinary cosmetics, it is not particularly limited by the shape of spheres, plates, needles, etc., the particle size of smoke, fine particles, pigment grade, etc. It is limited by the particle structure such as porous or non-porous, but any one can be used. The metal oxide is not particularly limited, but examples thereof include zinc oxide, iron oxide, titanium dioxide, zirconium oxide, cerium oxide, chromium oxide, and the like, and one or more of these may be used. Among these, from the viewpoint of the uniformity of the cosmetic film, one or two or more types selected from the group consisting of zinc oxide, titanium dioxide, and iron oxide are more preferred. The particle size is not particularly limited and can be selected according to the purpose of use. In the present invention, from the viewpoint of the uniformity of the cosmetic film, it is more preferable if the average particle diameter is in the range of 0.01 to 1 μm. The average particle diameter refers to the median diameter D50 value obtained by measurement using an image analysis device (LUZEX AP, manufactured by NIRECO). In the case of an asymmetric shape, in the present invention, the median diameter D50 obtained from the distribution of the maximum particle diameter is regarded as the average particle diameter.

The metal oxide of component (C) may also be used if its surface is in a hydrophobized state. Examples include methyl hydrogen polysiloxane treatment, polysiloxane treatment such as dimethyl polysiloxane treatment, alkyl alkoxysilane treatment such as triethoxyoctylsiloxane treatment, perfluoroalkyl phosphate treatment, Fluorine treatment such as perfluoroalkyl alkoxysilane treatment, isopropyl titanium triisostearate treatment, stearic acid treatment, myristic acid treatment and other fatty acid treatment, lauryl lysine acid treatment , dilauryl glutamate lysine Na treatment, stearyl glutamate 2Na treatment, lauryl aspartate Na and other N-acyl amino acid treatments, lecithin treatment, hydrogenated lecithin treatment Phospholipid treatment, polyoxyalkylene treatment such as polyethylene oxide, ceramide treatment, metal soap treatment, etc. can be used alone or in combination of two or more. The treatment amount of the treatment agent used in the hydrophobization treatment is not particularly limited, but from the viewpoint of no difference between the appearance color and the painting color, 0.1 to 20% of the metal oxide is preferred, and 0.3 to 10% is more preferred. %.

The content of component (C) in the present invention is 1 to 30%, preferably 1% or more, more preferably 2% or more, further preferably 3% or more. Moreover, it is preferably 25% or less, more preferably 22% or less, and still more preferably 20% or less. Moreover, 1-25% is preferable, 2-22% is more preferable, and 3-20% is further more preferable. If it is within this range, it is better because there is no difference between the appearance color and the applied color, and the uniformity of the makeup mask is better.

Ingredient (C) in the present invention is contained in the external aqueous phase. From the viewpoint of no difference between the appearance color and the applied color, and no feeling of use, etc., the component (C) is preferably contained in the external water phase and the internal oil phase, and the content mass of the component (C) in the internal oil phase is preferably The content ratio of the aforementioned component (C) in cosmetics is preferably 0.35 to 0.8, more preferably 0.5 to 0.7. If it is within this range, it is more excellent in that there is no difference between the appearance color and the application color, and there is no usability, so it is better.

Component (D) in the present invention is a fatty acid having 12 to 20 carbon atoms or an ester thereof, which is a fatty acid having 12 to 20 carbon atoms, or an ester of a fatty acid and a compound having at least one hydroxyl group. Examples of compounds having at least one hydroxyl group include monohydric alcohols, polyhydric alcohols, glycerin, and derivatives thereof. The fatty acid system (D) has a carbon number of 12 to 20 and can be a linear or branched saturated or unsaturated fatty acid. Examples include lauric acid, myristic acid, palmitic acid, stearic acid, and isostearic acid. , 12-hydroxystearic acid, palmitoleic acid, oleic acid, linoleic acid, hypolinoleic acid, arachidonic acid, eicosapentaenoic acid, isohexadecanoic acid, etc., but are not limited to these. Among them, saturated fatty acids having 12 to 20 carbon atoms are preferred, lauric acid, myristic acid, palmitic acid, and stearic acid are more preferred, and palmitic acid and stearic acid are still more preferred. Examples of fatty acid esters include dilauric acid PEG-8, lauric acid PEG-12, lauric acid PEG-30 hydrogenated castor oil, lauric acid PEG-40 hydrogenated castor oil, lauric acid PEG-50 hydrogenated castor oil, and lauric acid PEG-50 hydrogenated castor oil. Acid PEG-60 hydrogenated castor oil, PEG-12 dilaurate, PEG-16 dilaurate, sorbitan stearate, PEG-5 stearate, PEG-5 glyceryl stearate, PEG stearate -10, PEG-10 glyceryl stearate, PEG-15 glyceryl stearate, PEG-30 stearate, PEG-40 stearate, PEG-55 stearate, PEG-150 stearate, hard PEG-100 fatty acid, PEG-30 glyceryl stearate, PEG-40 glyceryl stearate, PEG-150 distearate, PEG-6 isostearate, PEG-8 glyceryl isostearate, PEG-10 isostearate, PEG-15 glyceryl isostearate, PEG-12 isostearate, PEG-25 glyceryl isostearate, PEG-60 glyceryl isostearate, PEG-60 glycerin Diisostearate, triisostearate PEG-50 trimethylolpropane, oleic acid sorbitan, oleic acid PEG-6, oleic acid PEG-10, oleic acid PEG-40 sorbitan, PCA Glycereth-25 Isostearate, Sorbeth-150 Hexastearate, PEG-40 Glyceryl Trioleate ), triolein PEG-60, etc. Among them, the ester of stearic acid and PEG having 12 to 20 carbon atoms is preferred, and stearic acid PEG-40 and stearic acid PEG-55 are more preferred.

Examples of commercially available products of the component (D) include purified stearic acid 700V (manufactured by Kao Co., Ltd.), stearic acid 65 (manufactured by Miyoshi Oil & Fat Co., Ltd.), and isostearic acid EX (KOKYU ALCOHOL KOGYO CO., LTD.), EDENOR series (EMERY OLEOCHEMICALS MALAYSIA), NIKKOL MYS-40V, NIKKOL MYS-55V series (Nikko Chemicals Co., Ltd.), EMALEX series (Nihon Emulsion Co.) , Ltd.) etc.

The content of component (D) in the present invention is not particularly limited, but it is preferably 0.1% or more, more preferably 0.5% or more, based on the entire oil-in-water emulsified cosmetic. Moreover, it is preferably 5% or less, more preferably 3% or less. Moreover, 0.1-5% is preferable, and 0.5-3% is more preferable. If it is within this range, it is better because there is no difference between the appearance color and the painted color, so it is better.

As long as the water-soluble polymer of component (E) in the present invention can be used in ordinary cosmetics, any one can be used. The water-soluble polymer is not particularly limited, but it is preferable to blend one, or two or more types selected from the group consisting of acrylamide copolymers and carboxyvinyl polymers. Examples of the acrylamide-based copolymer include polymers containing at least one structural unit (so-called monomer unit) derived from acrylamide dimethyltaurate. Examples of the above-mentioned acryldimethyltaurate include sodium acryldimethyltaurate and the like. For example, copolymers of acrylic acid and acrylic dimethyl taurate, copolymers of hydroxyethyl acrylate and acrylic dimethyl taurate, acrylic acid and acrylic acid salts and acrylamide and acrylic dimethyl taurate. Copolymers of methyl taurate, etc. Examples of commercially available products include SIMULGEL EG (manufactured by SEPPICSA Co., Ltd., (Na acrylate/acryloyldimethyltaurate Na) copolymer), SIMULGEL NS (manufactured by SEPPIC SA Co., Ltd., (hydroxyethyl acrylate/ Acrylyldimethyltaurate Na) copolymer), etc. The carboxyvinyl polymer can be used without particular restrictions on its monomer composition, molecular weight, etc., and various commercially available carboxyvinyl polymers can be used without particular limitations. Examples of such commercially available products include Carbopol 940, Carbopol 941, Carbopol 934, Carbopol 980, Carbopol 981, Carbopol 2984, Carbopol 5940, Carbopol ETD2050, and Carbopol Ultrez10 sold by Lubrizol Co., Ltd.; Cintalen K, Cintalen L, Cintalen M, etc. sold by Koko Pure Chemical Industries, Ltd.

The content of component (E) in the present invention is not particularly limited, but relative to the total amount of oil-in-water emulsified cosmetics, it is preferably 0.05% or more, and more preferably 0.15% or more. Moreover, it is preferably 0.45% or less, more preferably 0.35% or less. Moreover, 0.05-0.45% is preferable, and 0.15-0.35% is more preferable. If it is within this range, it is better because there is no difference between the appearance color and the applied color, and the uniformity of the makeup film is superior.

In the present invention, component (F) phosphoric acid-based surfactant can be further blended. Phosphoric acid-based surfactants refer to products obtained by phosphate-esterifying the terminals of higher alcohols or polyoxyalkylene derivatives thereof, and include salts in which residual hydroxyl groups are neutralized with an appropriate base. . Among them, polyoxyethylene-added alkyl ether phosphoric acids and their salts are preferred, but they are not limited thereto, and one type or two or more types may be used in combination. In terms of content, 0.01 to 1% is preferable from the viewpoint of no change in the feeling of use during application. Commercially available products include HOSTAPHAT KW340D, HOSTAPHAT KL340D (manufactured by Clariant (Japan) K.K.), and the like.

The oil-in-water type emulsified cosmetics of the present invention may appropriately contain, in addition to the above-mentioned components (A) to (F), components commonly used in external skin preparations within a range that does not impair the effects of the present invention. May contain, for example, higher alcohols, hydrocarbon oils, ester oils, waxes, silicone oils and other oils, surfactants, water-soluble polymers, polyols, lower alcohols and other water-based ingredients, powders other than ingredient (C), and ultraviolet rays Absorbents, antioxidants, antibacterial agents, preservatives, moisturizers, pH adjusters, cooling agents, vitamins, beauty ingredients, fragrances, etc.

The oil-in-water emulsified cosmetic of the present invention is not particularly limited and can be produced according to ordinary methods. For example, a method of preparing by uniformly dissolving and mixing the aqueous component containing the components (A), (B), (C), and (E), and uniformly dissolving and mixing the oily component containing (D), can be cited, Here, water-soluble ingredients are added and mixed to emulsify, and if necessary, any of the above-mentioned ingredients are added and mixed.

The oil-in-water type emulsified cosmetic of the present invention is not particularly limited, and may be in any form such as liquid, solid, gel, emulsion, or cream.

The oil-in-water type emulsified cosmetics of the present invention is not particularly limited, but can be used as cosmetics for skin, for example, lotions, emulsions, creams, beauty lotions, massage agents, dressings, hand creams, body lotions, Body cream, sunscreen, makeup primer, foundation, BB cream, etc., preferably makeup primer, foundation, BB cream, etc.

In addition, the present invention may also adopt the following configuration. <1> An oil-in-water emulsified cosmetic, characterized by containing the following ingredients (A) to (E): (A) Tranexamic acid 0.5 to 10% by mass, (B) Nicotinamide 1 to 10% by mass, (C) Metal oxide 1 to 30% by mass, (D) Fatty acids with 12 to 20 carbon atoms or their esters, (E) Water-soluble polymer, The total mass content of the component (A) and the component (B) is 3 to 14% by mass, and at least the external water phase contains the component (C). <2> The oil-in-water type emulsified cosmetics according to <1>, wherein the metal oxide of the component (C) is one or more selected from the group consisting of titanium dioxide, zinc oxide, and iron oxide. <3> The oil-in-water emulsion cosmetic as described in <1> or <2>, wherein the fatty acid of the component (D) is selected from the group consisting of lauric acid, myristic acid, palmitic acid, and stearic acid. One or more than two types. <4> The oil-in-water type emulsified cosmetics according to any one of <1> to <3>, which further contains component (F) a phosphoric acid-based surfactant. <5> The oil-in-water emulsified cosmetics according to any one of <1> to <4>, which contains the aforementioned component (C) in the external water phase and the internal oil phase, and the aforementioned component (C) in the internal oil phase The ratio of the content mass of C) to the content of the aforementioned ingredient (C) in the cosmetic is 0.35 to 0.8. [Example]

The following examples are given to illustrate the present invention in detail. In addition, these do not limit the present invention in any way.

Examples 1 to 20 and Comparative Examples 1 to 6: Oil-in-water emulsified cosmetics (foundation) Examples 1 to 20 and Comparative Examples 1 to 6 were prepared according to the manufacturing method shown below. A. No difference between appearance color and application color, B. No drainage at high temperature, C. Uniformity of cosmetic film, D. Stop. E. There is no change in the feeling of use when applying, and the smoothness is evaluated by the following evaluation method.

[Table 1] (%) No Element Example 1 2 3 4 5 6 7 8 9 10 external aqueous phase 1 Tranexamic acid 3 0.5 10 3 3 3 3 3 3 3 2 Nicotinamide 4 4 4 1 10 4 4 4 4 4 3 red iron oxide 0.2 0.2 0.2 0.2 0.2 0.1 1.44 0.05 0.05 0.1 4 yellow iron oxide 0.8 0.8 0.8 0.8 0.8 0.4 5.76 0.15 0.25 0.7 5 Lecithin treated titanium oxide 4 4 4 4 4 0.5 22.8 0.8 1.35 2.7 6 Sodium acrylate･Sodium acrylodimethyltaurate copolymer 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 0.25 7 xanthan gum - - - - - - - - - - 8 carboxyvinyl polymer - - - - - - - - - - 9 pure water residual amount residual amount residual amount residual amount residual amount residual amount residual amount residual amount residual amount residual amount 10 ethanol 2 2 2 2 2 2 2 2 2 2 11 1,3-butanediol 15 15 15 15 15 15 15 15 15 15 internal oil phase 12 red iron oxide - - - - - - - 0.15 0.1 0.05 13 yellow iron oxide - - - - - - - 0.65 0.7 0.25 14 Lecithin treated titanium oxide - - - - - - - 3.2 2.7 1.35 15 stearic acid 1.3 1.3 1.3 1.3 1.3 1.3 1.3 1.3 1.3 1.3 16 Stearic acid PEG-55 - - - - - - - - - - 17 Oleic acid - - - - - - - - - - 18 behenic acid - - - - - - - - - - 19 Polyoxyethylene stearyl ether phosphate 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 20 Sorbitan sesquioleate - - - - - - - - - - twenty one 2-ethylhexyl p-methoxycinnamate 6 6 6 6 6 6 6 6 6 6 twenty two Glyceryl tri(ethylhexanoate) 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 twenty three flowing paraffin 1 1 1 1 1 1 1 1 1 1 twenty four dipententerythritol fatty acid ester 1 1 1 1 1 1 1 1 1 1 25 Diglyceryl triisostearate 1 1 1 1 1 1 1 1 1 1 26 Methylparaben 0.15 0.15 0.15 0.15 0.15 0.15 0.15 0.15 0.15 0.15 (Containing mass of ingredient (C) in the internal oil phase)/ (Containing mass of ingredient (C) in cosmetics) 0 0 0 0 0 0 0 0.8 0.68 0.32 Evaluation items and judgment results A There is no difference between the appearance color and the painted color ○ ○ ○ ○ ○ ○ ○ ◎ ◎ ◎ B No draining under high temperature ◎ ◎ ○ ○ ◎ ○ ◎ ◎ ◎ ○ C Uniformity of makeup mask ○ ○ ○ ○ ○ ◎ ◎ ○ ◎ ◎ D Stop smoothness ◎ ◎ ○ ◎ ◎ ◎ ◎ ◎ ◎ ◎ E No change in feel when applying ○ ○ ◎ ◎ ○ ○ ○ ○ ◎ ◎

[Table 2] (%) No Element Example 11 12 13 14 15 16 17 18 19 20 external aqueous phase 1 Tranexamic acid 3 3 3 3 3 3 3 3 3 3 2 Nicotinamide 4 4 4 4 4 4 4 4 4 4 3 red iron oxide 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 4 yellow iron oxide 0.8 0.8 0.8 0.8 0.8 0.8 0.8 0.8 0.8 0.8 5 Lecithin treated titanium oxide 4 4 4 4 4 4 4 4 4 4 6 Sodium acrylate･Sodium acrylodimethyltaurate copolymer 0.01 0.5 - - 0.25 0.25 0.25 0.25 0.25 0.25 7 xanthan gum - - 0.25 - - - - - - - 8 carboxyvinyl polymer - - - 0.25 - - - - - - 9 pure water residual amount residual amount residual amount residual amount residual amount residual amount residual amount residual amount residual amount residual amount 10 ethanol 2 2 2 2 2 2 2 2 2 2 11 1,3-butanediol 15 15 15 15 15 15 15 15 15 15 internal oil phase 12 red iron oxide - - - - - - - - - - 13 yellow iron oxide - - - - - - - - - - 14 Lecithin treated titanium oxide - - - - - - - - - - 15 stearic acid 1.3 1.3 1.3 1.3 0.1 5 - - 1.3 1.3 16 Stearic acid PEG-55 - - - - - - 1.3 - - - 17 Oleic acid - - - - - - - 1.3 - - 18 behenic acid - - - - - - - - - - 19 Polyoxyethylene stearyl ether phosphate 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 - 20 Sorbitan sesquioleate - - - - - - - - - 0.5 twenty one 2-ethylhexyl p-methoxycinnamate 6 6 6 6 6 6 6 6 6 6 twenty two Glyceryl tri(ethylhexanoate) 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 twenty three flowing paraffin 1 1 1 1 1 1 1 1 1 1 twenty four dipententerythritol fatty acid ester 1 1 1 1 1 1 1 1 1 1 25 Diglyceryl triisostearate 1 1 1 1 1 1 1 1 1 1 26 Methylparaben 0.15 0.15 0.15 0.15 0.15 0.15 0.15 0.15 0.15 0.15 (Containing mass of ingredient (C) in the internal oil phase)/ (Containing mass of ingredient (C) in cosmetics) 0 0 0 0 0 0 0 0 0 0 Evaluation items and judgment results A There is no difference between the appearance color and the painted color ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ B No draining under high temperature ○ ◎ ○ ○ ○ ◎ ○ ○ ○ ○ C Uniformity of makeup mask ◎ ○ ◎ ◎ ◎ ◎ ◎ ◎ ○ ◎ D Stop smoothness ◎ ○ ○ ○ ◎ ○ ○ ○ ○ ○ E No change in feel when applying ◎ ○ ○ ○ ◎ ○ ○ ○ ○ ○

[table 3] (%) No Element Comparative example 1 2 3 4 5 6 external aqueous phase 1 Tranexamic acid 15 3 0.2 3 3 3 2 Nicotinamide 4 15 0.5 4 4 4 3 red iron oxide 0.2 0.2 0.2 0.2 0.2 - 4 yellow iron oxide 0.8 0.8 0.8 0.8 0.8 - 5 Lecithin treated titanium oxide 4 4 4 4 4 - 6 Sodium acrylate･Sodium acrylodimethyltaurate copolymer 0.25 0.25 0.25 0.25 0.25 0.25 7 xanthan gum - - - - - - 8 carboxyvinyl polymer - - - - - - 9 pure water residual amount residual amount residual amount residual amount residual amount residual amount 10 ethanol 2 2 2 2 2 2 11 1,3-butanediol 15 15 15 15 15 15 internal oil phase 12 red iron oxide - - - - - 0.2 13 yellow iron oxide - - - - - 0.8 14 Lecithin treated titanium oxide - - - - - 4 15 stearic acid 1.3 1.3 1.3 - - 1.3 16 Stearic acid PEG-55 - - - - - - 17 Oleic acid - - - - - - 18 behenic acid - - - - 1.3 - 19 Polyoxyethylene stearyl ether phosphate 0.5 0.5 0.5 0.5 0.5 0.5 20 Sorbitan sesquioleate - - - - - - twenty one 2-ethylhexyl p-methoxycinnamate 6 6 6 6 6 6 twenty two Glyceryl tri(ethylhexanoate) 2.5 2.5 2.5 2.5 2.5 2.5 twenty three flowing paraffin 1 1 1 1 1 1 twenty four dipententerythritol fatty acid ester 1 1 1 1 1 1 25 Diglyceryl triisostearate 1 1 1 1 1 1 26 Methylparaben 0.15 0.15 0.15 0.15 0.15 0.15 (Containing mass of ingredient (C) in the internal oil phase)/ (Containing mass of ingredient (C) in cosmetics) 0 0 0 0 0 1 Evaluation items and judgment results A There is no difference between the appearance color and the painted color △ △ ○ △ ○ ○ B No draining under high temperature × × ○ × △ △ C Uniformity of makeup mask ○ △ × × △ △ D Stop smoothness × × ○ ○ ○ ○ E No change in feel when applying × × △ ○ ○ ○

(manufacturing method) A. Mix ingredients (1) to (11) evenly. B. Heat ingredients (12) to (26) to 80°C and mix them uniformly. C. Add A to B and emulsify at 80°C. D. Fill C in the container to obtain oil-in-water emulsified cosmetics.

(evaluation method) A. There is no difference between the appearance color and the painted color Select 10 women aged 20 to 40 who have received sensory evaluation training to form a specialized group that can evaluate based on certain standards. Based on the following absolute evaluation standards, this panel evaluated the difference in color between the appearance of each sample before use and the color difference after spreading 10 mg of each sample 10 times back and forth on the forearm with fingers, and gave scores in five stages. For each sample, the scores of all panel members are summed up to calculate the average value, and the judgment is made based on the following four-stage judgment criteria. (evaluation criteria) (Rating): (evaluation) 5: No gap 4: Almost no gap 3: There is a slight gap 2: There is a gap 1: There is a big gap (Judgment criteria) (Judgment): (average point of ratings) ◎: higher than 4.5 ○: More than 3.5 and less than 4.5 △: More than 2.5 and less than 3.5 ×: 2.5 or less

B. No drainage under high temperature A dedicated evaluator visually evaluates the drained state when each sample is filled into a glass bottle and stored in a constant temperature bath at 50°C for 1 month. Based on the following absolute evaluation standards, a 5-stage evaluation is performed and a score is given. The judgment is based on the following 4 stages. judge based on benchmarks. (evaluation criteria) (Rating): (evaluation) 5: Drainage was not observed. 4: Almost no drainage was observed. 3: Drainage was slightly observed. 2: Drainage is observed. 1: Considerable drainage was observed. (Judgment criteria) (Judgment): (average point of ratings) ◎: higher than 4.5 ○: More than 3.5 and less than 4.5 △: More than 2.5 and less than 3.5 ×: 2.5 or less

C. Uniformity of makeup film Select 10 women aged 20 to 40 who have received sensory evaluation training to form a specialized group that can evaluate based on certain standards. Based on the following absolute evaluation standards, this panel evaluated and graded the uniformity of the cosmetic film when 10 mg of each sample was spread on the forearm 10 times with fingers in 5 stages. For each sample, the scores of all panel members are summed up to calculate the average value, and the judgment is made based on the following four-stage judgment criteria. (evaluation criteria) (Rating): (evaluation) 5: Very good 4: Good 3: Normal 2: Slightly worse 1: Poor (Judgment criteria) (Judgment): (average point of ratings) ◎: higher than 4.5 ○: More than 3.5 and less than 4.5 △: More than 2.5 and less than 3.5 ×: 2.5 or less

D.Smoothness of stopping Select 10 women aged 20 to 40 who have received sensory evaluation training to form a specialized group that can evaluate based on certain standards. Based on the following absolute evaluation standards, this panel evaluated and graded the smoothness of stopping when 10 mg of each sample was stretched back and forth 10 times on the forearm with fingers in 5 stages. For each sample, the scores of all panel members are summed up to calculate the average value, and the judgment is made based on the following four-stage judgment criteria. (evaluation criteria) (Rating): (evaluation) 5: Very good 4: Good 3: Normal 2: Slightly worse 1: Poor (Judgment criteria) (Judgment): (average point of ratings) ◎: higher than 4.5 ○: More than 3.5 and less than 4.5 △: More than 2.5 and less than 3.5 ×: 2.5 or less

E. There is no change in the feeling of use when applying it Select 10 women aged 20 to 40 who have received sensory evaluation training to form a specialized group that can evaluate based on certain standards. Based on the following absolute evaluation standards, this panel evaluated and rated the results in five stages, including no change in the feeling of use when 10 mg of each sample was stretched back and forth on the forearm 10 times with fingers. For each sample, the scores of all panel members are summed up to calculate the average value, and the judgment is made based on the following four-stage judgment criteria. (evaluation criteria) (Rating): (evaluation) 5: Very good 4: Good 3: Normal 2: Slightly worse 1: Poor (Judgment criteria) (Judgment): (average point of ratings) ◎: higher than 4.5 ○: More than 3.5 and less than 4.5 △: More than 2.5 and less than 3.5 ×: 2.5 or less

From the results in Table 1, it is clear that the oil-in-water type emulsified cosmetics of products 1 to 20 of the present invention have "no difference in appearance color and application color" when compared with the oil-in-water type emulsified cosmetics of Comparative Examples 1 to 6. , "No drainage at high temperatures", "Uniformity of the makeup film", "Smoothness of stopping", "No change in feel during application" are all excellent. On the other hand, Comparative Example 1, which contains an excessive amount of component (A), has "no difference between the appearance color and the application color", "no drainage at high temperatures", "smoothness of stopping", and "no feeling of use when applying." "Change" is not good. Comparative Example 2, which contains an excessive amount of ingredient (B), is based on "no difference between the appearance color and the applied color", "no drainage at high temperatures", "uniformity of the makeup film", "smoothness of stopping", "during application" "Changes without a sense of use" are considered poor quality. Comparative Example 3, which blended a small amount of Component (A) and Component (B), was unsatisfactory in terms of "uniformity of the makeup film" and "no change in feel during application". Comparative Example 4, which does not contain ingredient (D), was poor in terms of "no difference between the appearance color and the applied color", "no drainage at high temperatures", and "uniformity of the makeup film". Comparative Example 5, which contains a fatty acid with a carbon number other than 12 to 20 in place of component (D), was poor in terms of "no drainage at high temperatures" and "uniformity of the cosmetic film". The oil-in-water type emulsified cosmetics of Comparative Example 6, which contained the entire amount of component (C) in the oil system, was poor in "drainage without high temperature" and "uniformity of the cosmetic film".

Example 21 Oil-in-water liquid foundation (Element) (%) 1. Tranexamic acid 3 2.Nicotinamide 4 3.Sodium acrylate‧Acrylyldimethyl Sodium taurate copolymer mixture※1 0.66 4. Remaining amount of pure water 5.Ethanol                           2 6.1,3-Butanediol 15 7. Red iron oxide 0.2 8. Yellow iron oxide 0.8 9. Titanium oxide treated with lecithin 4 10. Stearic acid 1.3 11. Polyoxyethylene stearyl ether phosphate ※2           0.5 12. 2-Ethylhexyl p-methoxycinnamate 6 13. Glyceryl tris(ethylhexanoate) 2.5 14.Mobile paraffin 1 15. Dineopenterythritol fatty acid ester 1 16. Diglyceryl triisostearate 1 17. Methyl parahydroxybenzoate 0.15 ※1: SIMULGEL EG QD (SEPPIC company) ※2: HOSTAPHAT KL340D (Clariant (Japan) K.K.)

(manufacturing method) A. Mix ingredients (1) to (9) evenly. B. Heat ingredients (10) to (17) to 80°C and mix evenly. C. Add A to B and emulsify at 80°C. D. Fill C in the container to obtain oil-in-water liquid foundation.

The oil-in-water liquid foundation obtained by proceeding as above is characterized by no difference between the appearance color and the applied color, no drainage at high temperatures, uniformity of the makeup film, smoothness of the stop, and no change in the feeling of use during application. Outstanding ones.

Example 22 Oil-in-water liquid foundation (Element) (%) 1. Tranexamic acid 4 2.Nicotinamide 6 3.Xanthan gum 0.25 4. Remaining amount of pure water 5.Ethanol                           2 6.1,3-Butanediol 15 7. Red iron oxide 0.1 8. Yellow iron oxide 0.4 9. Titanium oxide treated with lecithin 2 10.Ethylhexylglycerin※3               0.2 11.Chlorphenesin 0.1 12. Red iron oxide 0.1 13. Yellow iron oxide 0.4 14. Titanium oxide treated with lecithin 2 15.Polyurethane gel composition※4 2 16. Boron nitride 2 17.N-lauryl-L-lysine acid 3 18.Sorbitan monooleate (HLB4.3)※5 0.5 19. 2-ethylhexyl p-methoxycinnamate 6 20. Glyceryl tri(ethylhexanoate) 1 21. Diisostearyl malate 2.5 22. High melting point polyethylene powder 1 23.Mobile paraffin 1 24. Dineopenterythritol fatty acid ester 1 25. Diglyceryl triisostearate 1 26. Hexagonal plate-shaped zinc oxide (average particle size 0.3μm) 1 ※3: ADEKA NOL GE-RF (made by ADEKA Corporation) ※4: OILKEMIA 5S CC POLYMER (manufactured by Japan Lubrizol Corporation) ※5: NIKKOL SO-10V (manufactured by Nikko Chemicals Co.)

(manufacturing method) A. Mix ingredients (1) to (11) evenly. B. Heat ingredients (12) to (26) to 80°C and mix evenly. C. Add A to B and emulsify at 80°C. D. Fill C in the container to obtain oil-in-water liquid foundation.

The oil-in-water liquid foundation obtained by proceeding as above is characterized by no difference between the appearance color and the applied color, no drainage at high temperatures, uniformity of the makeup film, smoothness of the stop, and no change in the feeling of use during application. Outstanding ones.

Example 23 Oil-in-water liquid concealer (Element) (%) 1. Tranexamic acid 2 2.Nicotinamide 7 3. Carboxyvinyl polymer                                                                                                                                                                                                                                                         4. Remaining amount of pure water 5.Ethanol 3 6.1,3-Butanediol 10 7. Phenoxyethanol 0.2 8. Red iron oxide 0.6 9. Yellow iron oxide 2.4 10. Titanium oxide treated with ceramide 12 11. Palmitic acid 1.8 12. Squalane 0.1 13. Propylene carbonate 0.1 14.Polyoxyethylene stearyl ether phosphate ※2           0.5 15. Glyceryl tris(ethylhexanoate) 2.5 16.Mobile paraffin 1 17. Diglyceryl triisostearate 1

(manufacturing method) A. Mix ingredients (1) to (9) evenly. B. Heat ingredients (10) to (17) to 80°C and mix evenly. C. Add A to B and emulsify at 80°C. D. Fill C in the container to obtain oil-in-water liquid concealer.

The oil-in-water liquid concealer obtained by carrying out the above process has no gap between the appearance color and the applied color, no drainage at high temperatures, uniform makeup film, smooth stop, and no feeling of use when applying. Excellent in change.

Example 24: Oil-in-water foundation (ingredients) (%) 1. Polysorbate 80 0.5 2. Glyceryl stearate 0.5 3. Sorbitan sesquioleate 0.5 4. Sorbitan palmitate 0.5 5. Stearic acid 1.5 6. Lecithin 0.1 7. Tris (ceteeareth-4 phosphate) 0.3 8. Behenyl alcohol 0.5 9. Methoxycinnamic acid ethyl Hexyl ester (ethylhexyl methoxycinnamate) 5 10. Bisethylhexyloxyphenol methoxyphenyltri (bisethylhexyloxyphenol methoxyphenyltriazine) 1 11. Triethylhexanoin 1 12. Polyglyceryl-2 triisostearate (polyglyceryl-2 triisostearate) 3 13. Mineral oil 0.5 14. Dineopentylene tetrazine Alcohol hexa(hydroxystearic acid/stearic acid/rosin acid) ester 0.5 15. Laurylglutamic acid bis(octyldodecyl/phytosterol/bisyl) 2 16. Paraffin*6 1 17. Dimethicone＊7 3 18. Titanium oxide (average particle size 250nm)＊8 5 19. Iron oxide＊9 1 20. Pure water residual 21. BG 15 22. Ethanol 5 23 .TEA 1 24. Phenoxyethanol 0.2 25. 2Na phosphate 0.1 26. Na phosphate 0.1 27. EDTA-2Na 0.1 28. (Acrylic acid/alkyl acrylate (C10-C30)) copolymer 0.01 29. carbomer ) 0.2 30. Crystalline cellulose 0.005 31. Gellan gum 0.005 32. ACRYLATES COPOLYMER 0.1 33. Talc 0.5 34. Synthetic phlogopite 1 35. Anhydrous silicic acid 3 36. Bentonite 0.001 37. Tranexamic acid 3 38. Nicotinamide 3 ＊6: PARACERA 256 (manufactured by PARAMELT Co., Ltd.) ＊7: Silicon KF-96A (20CS) (manufactured by Shin-Etsu Chemical Industry Co., Ltd.) ＊8: Treated with 2% lecithin CR-50 (Ishihara Sangyo) *9: Red iron oxide treated with isopropyl triisostearoyl titanate 2%: Isopropyl triisostearoyl titanate 2% % treated yellow iron oxide: black iron oxide treated with 2% isopropyl triisostearyl titanate = 0.15:0.8:0.05 mixture

＜Manufacturing method＞ A. Mix ingredients (1) to (17) uniformly at 75°C. B. Mix ingredients (18) to (38) uniformly at 75°C. C. Add A to B at 75°C to emulsify, then cool to 30°C to obtain an oil-in-water foundation.

The oil-in-water foundation obtained by proceeding as above is excellent in that there is no difference between the appearance color and the applied color, no drainage at high temperatures, uniformity of the makeup film, smoothness of stopping, and no change in the feeling of use during application. .

Example 25 Makeup primer (ingredients) (%) 1.1,3-butanediol 10 2. Glycerin 5 3. Tris(cetearyl ether-4) phosphate 0.1 4. Polysorbate 80 1 5. Titanium oxide treated with lauryl glutamic acid Na*10 4 6. Red iron oxide treated with 2Na stearylglutamic acid*11 0.1 7. Treated with 2Na stearylglutamic acid Yellow iron oxide*12 0.1 8. Black iron oxide treated with stearyl glutamic acid 2Na*13 0.1 9. Triethanolamine 0.9 10. Remaining pure water 11. Tranexamic acid 3 12. Nicotinamide 5 13 .Stearic acid 1 14. Cetearyl alcohol 0.3 15. Sesquioleic acid sorbitan 0.3 16. Polydimethylsiloxane (dynamic viscosity 10mm ² /s) 2 17. Ethyl methoxycinnamate Hexyl ester 5 18. Neopentyl glycol didecanoate 1 19.2,4-bis[{4-(2-ethylhexyloxy)-2-hydroxy}-phenyl]-6-(4-methoxy phenyl)-(1,3,5)-tri 0.5 20.2-2'-Methylenebis{6-(benzotriazol-2-yl)-4-(1,1,3,3-tetramethylbutyl)phenol} 3 21.(Polydimethyl (vinyl polydimethylsiloxane) cross-linked polymer/polydimethylsiloxane*14 2 22. Carboxy vinyl polymer 0.15 23. Xanthan gum 0.03 24. Acrylic ester copolymer Material 0.1 25. Acrylic acid Na cross-linked polymer 0.3 26. Ascorbic acid 2-glucoside (ascorbic acid 2-glucoside) 0.3 27. Appropriate amount of fragrance 28. (Acrylates/alkyl acrylate (C10-30)) cross-linked polymer 0.2 29. Cellulose＊15 1 30. Hollow silica＊16 0.7 31. Titanium oxide-coated mica＊17 1 32. Phenoxyethanol 0.1 33. Capsules containing ethylhexyl methoxycinnamate 4 ＊10 : ASL-1 TiO2 MP-1133 (manufactured by Daito Chemical Industry Co., Ltd.) *11: NAI-red R-516PS (100%) (manufactured by Miyoshi Chemical Co., Ltd.) *12: NAI yellow LL-100P (100%) (Miyoshi Chemical Co., Ltd. (manufactured by Shin-Etsu Chemical Industry Co., Ltd.) *13: NAI-black BL-100P (100%) (manufactured by Miyoshi Chemical Industry Co., Ltd.) *14: KSG-16 (manufactured by Shin-Etsu Chemical Industry Co., Ltd.) *15: CELLULOBEADS S-10 (manufactured by Daito Chemical Industry Co., Ltd.) *16 : SILICA MICROBEAD BA-4 (manufactured by JGC C&C) *17: COSMETICA SUPER RED N-5401S (manufactured by CQV)

(manufacturing method) A: Evenly process ingredients (1) to (8) with a three-roller machine. B: Mix A and components (9) to (12) evenly. C: Evenly disperse ingredients (13) to (21) at 75°C. D: Add C to B and emulsify at 75°C. E: Cool D to 60°C. F: Add ingredients (22) to (33) to E and mix evenly. G: Cool F to 40°C. H: Add A to G and mix evenly. I: After filling the container with H, a makeup primer is obtained.

The oil-in-water foundation obtained by proceeding as above is excellent in that there is no difference between the appearance color and the applied color, no drainage at high temperatures, uniformity of the makeup film, smoothness of stopping, and no change in the feeling of use during application. .

Example 26 BB cream (ingredients) (%) 1. PEG-10 hydrogenated castor oil 0.05 2. Sorbitan sesquioleate 0.03 3. 1,3-butanediol 0.5 4. Titanium oxide treated with polyoxyethylene 6 5. Talc treated with hydrogenated lecithin 0.2 6. Red iron oxide (R-516-P: manufactured by Titanium Industrial Co., Ltd.) 0.3 7. Yellow iron oxide (LL-100P: manufactured by Titanium Industrial Co., Ltd.) 0.3 8. Black iron oxide (BL-100P: Made by Titanium Industrial Co., Ltd.) 0.3 9. Remaining pure water 10. Dipropylene glycol 9 11. Triethanolamine 0.35 12. Stearic acid 1 13. Behenyl alcohol 1 14. Polydimethylsiloxane ( Kinematic viscosity 6mm ² /s) 1 15. Mobile paraffin 1 16. Isotridecyl isononanoate 4 17. Decamethylcyclopentasiloxane (decamethylcyclopentasiloxane) 3 18. Neopentyl glycol di-2-ethyl neopentyl glycol di-2-ethylhexanoate 1 19. Microparticle titanium oxide treated with polysiloxane 3 20. PEG-9 polydimethylsiloxane 0.4 21. p-Methoxycinnamic acid 2-ethyl Hexyl benzoate 5 22.2-{4-(diethylamino)-2-hydroxybenzoyl}hexyl benzoate 1 23.(Polydimethylsiloxane/phenylpolydimethylsiloxane /)Cross-linked polymer/diphenylsilyloxyphenyltrimethylsiloxane 3 24.Carboxyvinyl polymer 0.3 25.Ammonium acrylyldimethyltaurate/vinylpyrrolidone ) Copolymer 0.7 26. Carbomer Na 0.5 27. Tranexamic acid 3 28. Nicotinamide 1 29. Appropriate amount of spices

(manufacturing method) A: Evenly process ingredients (1) to (8) with a three-roller machine. B: Dissolve ingredients (9) to (11) uniformly. C: Disperse components (12) to (23) uniformly at 75°C. D: Add C to B and emulsify at 75°C. E: Cool D to 50°C. F: Add ingredients (24) to (29) to E and mix evenly. G: Add A to F and mix evenly. H: After filling the container with G, BB cream is obtained.

The BB cream obtained by proceeding as above is excellent in that there is no difference between the appearance color and the applied color, no drainage at high temperatures, uniformity of the makeup film, smoothness of stopping, and no change in the feeling of use during application.

Example 27 Oil-in-water solid blush (Element) (%) 1. Titanium oxide treated with 3% lecithin 3 2. Titanium mica treated with 3% lecithin 3 3. Sericite treated with 3% lecithin 4 4. Talc treated with 3% lecithin 10 5. Polyoxyethylene (3) hardened castor oil 1 6. Soybean phospholipid 1 7. Sucrose fatty acid ester                   0.5 8.Isocetyl stearate 5.5 9. Appropriate amount of spices 10. Methyl parahydroxybenzoate 0.1 11.1,3-Butanediol 5 12. Agar 2 13. Glycerin 3 14. Diglycerol 1 15. Remaining amount of pure water 16.Nicotinamide 3 17. Tranexamic acid 4 18. Iron oxide 2

(making method) A. Mix ingredients (5) to (9) evenly. B. Mix ingredients (11) to (18) evenly. C. Add (1) to (4) to A and mix and disperse. D. Add C to B to emulsify, add components (9) to (10) and mix uniformly. E. Fill D into a container and cool it to obtain an oil-in-water solid blush.

The oil-in-water solid blush obtained by proceeding as above has no gap between the appearance color and the applied color, no drainage at high temperatures, uniformity of the makeup film, smoothness of stopping, and no change in the feel of use during application. Excellent ones.

without

without.

without.

Claims (5)

An oil-in-water emulsified cosmetic, characterized by containing the following ingredients (A) to (E): (A) Tranexamic acid 0.5 to 10% by mass, (B) Nicotinamide 1 to 10% by mass, (C) Metal oxide 1 to 30% by mass, (D) Fatty acids with 12 to 20 carbon atoms or their esters, (E) Water-soluble polymer, The total mass content of the component (A) and the component (B) is 3 to 14% by mass, and at least the component (C) is contained in the external water phase. For example, in the oil-in-water emulsified cosmetics of claim 1, the metal oxide of component (C) is one or more types selected from the group consisting of titanium dioxide, zinc oxide, and iron oxide. For example, the oil-in-water emulsified cosmetic of claim 1 or 2, wherein the fatty acid of component (D) is one or more selected from the group consisting of lauric acid, myristic acid, palmitic acid, and stearic acid. For example, the oil-in-water emulsified cosmetic according to claim 1 or 2 further contains component (F) a phosphoric acid surfactant. For example, the oil-in-water emulsified cosmetics of claim 1 or 2 contain the component (C) in the external water phase and the internal oil phase, and the content of the component (C) in the internal oil phase has a significant impact on the content of the component (C) in the cosmetic. The content ratio of component (C) is 0.35 to 0.8.