TW202313858A - Colored curable composition - Google Patents

Abstract

The present invention addresses the problem of providing a colored curable composition which, even after storage, gives patterns having a reduced line-width change, that is, providing a colored curable composition which, even after storage, is satisfactory in terms of pattern stability. This colored curable composition comprises a colorant, a resin, a polymerizable compound, a polymerization initiator, and a latent antioxidant, wherein the colorant comprises an aluminum phthalocyanine compound and the polymerization initiator comprises an oxime compound.

Description

Colored curable composition

The present invention relates to a colored curable composition.

Display devices such as liquid crystal display devices, electroluminescence display devices, and plasma displays, and charge-coupled device (Charge Coupled Device, CCD) or complementary metal-oxide-semiconductor (Complementary Metal-Oxide-Semiconductor, CMOS) sensors, etc. Color filters used in solid-state imaging devices and the like are produced from colored curable compositions. Various coloring agents are contained in curable colored compositions, for example, curable colored compositions containing aluminum phthalocyanine compounds are known (Patent Document 1, Patent Document 2). [Prior art literature] [Patent Document]

[Patent Document 1] Japanese Patent Laid-Open No. 2018-091916 [Patent Document 2] Japanese Patent Laid-Open No. 2016-075837

[Problem to be Solved by the Invention]

However, when a colored curable composition containing an aluminum phthalocyanine compound is stored for a certain period of time to form a pattern, compared with the case of forming a pattern without storing, there is a problem that the line width of the obtained pattern becomes smaller or the pattern disappears. . Therefore, an object of the present invention is to provide a curable colored composition having a small rate of change in the line width of the pattern obtained even when the curable colored composition is used after storage, that is, to provide a curable colored composition that, even after storage, A curable colored composition with good pattern stability. [Means to solve the problem]

[化2]

[式（Xa）中， Z表示羥基、氯原子、-OP(=O)R ^a1R ^a2、-O-SiR ^a3R ^a4R ^a5、-OC(=O)R ^a13或-OS(=O) ₂R ^a14； R ^a1～R ^a5及R ^a13～R ^a14分別獨立地表示氫原子、羥基、可具有取代基的碳數1～20的烴基或可具有取代基的碳數1～20的雜環基，R ^a1與R ^a2或R ^a3～R ^a5的任意兩個可相互鍵結而形成環；於該烴基的碳數為2～20且該烴基具有-CH ₂-的情況下，該-CH ₂-可經取代為-O-、-S-或-CO-； X ^x1～X ^x4分別獨立地表示-R ^x4、-OR ^x4、-SR ^x4、-SO ₃H、-SO ₃ ^-T ⁺、-SO ₃R ^X10、-SO ₂NR ^X11R ^X12、鹵素原子或硝基； R ^x4表示可具有取代基的碳數1～20的烴基，於該烴基的碳數為2～20且該烴基具有-CH ₂-的情況下，該-CH ₂-可經取代為-O-、-S-或-CO-； T ⁺表示 ⁺N(R ^X13) ₄或鹼金屬離子，R ^X13分別獨立地表示氫原子或碳數1～20的烴基； R ^X10表示碳數1～20的飽和烴基； R ^X11及R ^X12分別獨立地表示氫原子或可具有取代基的碳數1～20的烴基； nx1～nx4分別獨立地表示0～4的整數； 式（Xb）中， L表示-O-SiR ^a6R ^a7-O-、-O-SiR ^a8R ^a9-O-SiR ^a10R ^a11-O-或-O-P(=O)R ^a12-O-； R ^a6～R ^a12分別獨立地表示氫原子、羥基、可具有取代基的碳數1～20的烴基或可具有取代基的碳數1～20的雜環基，R ^a6與R ^a7、R ^a8與R ^a9或R ^a10與R ^a11可相互鍵結而形成環；於該烴基的碳數為2～20且該烴基具有-CH ₂-的情況下，該-CH ₂-可經取代為-O-、-S-或-CO-； X ^x5～X ^x12分別獨立地表示-R ^x5、-OR ^x5、-SR ^x5、-SO ₃H、-SO ₃ ^-Q ⁺、-SO ₃R ^X14、-SO ₂NR ^X15R ^X16、鹵素原子或硝基； R ^x5表示可具有取代基的碳數1～20的烴基，於該烴基的碳數為2～20且該烴基具有-CH ₂-的情況下，該-CH ₂-可經取代為-O-、-S-或-CO-； Q ⁺表示 ⁺N(R ^X17) ₄或鹼金屬離子，R ^X17分別獨立地表示氫原子或碳數1～20的烴基； R ^X14表示碳數1～20的飽和烴基； R ^X15及R ^X16分別獨立地表示氫原子或可具有取代基的碳數1～20的烴基； nx5～nx12分別獨立地表示0～4的整數] [4] 如[3]所述的著色硬化性組成物，其中所述式（Xa）所表示的化合物為式（X0）或式（XI）所表示的化合物，式（Xb）所表示的化合物為式（XII）所表示的化合物。 [化3]

[化4]

[化5]

[式（XI）中， R ^x1表示可具有取代基的碳數2～20的脂肪族不飽和烴基或可具有取代基的碳數6～20的芳香族烴基，R ^x2表示氫原子、可具有取代基的碳數1～20的烴基或將Z ^x2與R ^x1連結的單鍵； Z ^x1及Z ^x2分別獨立地表示單鍵或氧原子； 式（X0）及式（XI）中， X ^x1～X ^x4、nx1～nx4與所述相同； 式（XII）中， R ^x3表示可具有取代基的碳數2～20的脂肪族不飽和烴基或可具有取代基的碳數6～20的芳香族烴基； Z ^x3表示單鍵或氧原子； X ^x5～X ^x12、nx5～nx12與所述相同] [5] 如[3]或[4]所述的著色硬化性組成物，其中nx1～nx12為0。 [6] 一種彩色濾光片，由如[1]至[5]中任一項所述的著色硬化性組成物形成。 [7] 一種顯示裝置，包括如[6]所述的彩色濾光片。 [8] 一種固體攝像元件，包括如[6]所述的彩色濾光片。 [發明的效果] The present invention includes the following inventions. [1] A colored curable composition comprising a colorant, a resin, a polymerizable compound, a polymerization initiator, and a latent antioxidant, wherein the colorant includes an aluminum phthalocyanine compound, and the polymerization initiator includes an oxime compound. [2] The colored curable composition according to [1], wherein the latent antioxidant is a compound in which a phenolic hydroxyl group of a phenolic antioxidant is protected with a protecting group. [3] The colored curable composition according to [1] or [2], wherein the aluminum phthalocyanine compound is a compound represented by formula (Xa) or formula (Xb). [chemical 1]

[Chem 2]

[In the formula (Xa), Z represents a hydroxyl group, a chlorine atom, -OP(=O)R ^a1 R ^a2 , -O-SiR ^a3 R ^a4 R ^a5 , -OC(=O)R ^a13 or -OS(=O) ₂ R ^a14 ; R ^a1 to R ^a5 and R ^a13 to R ^a14 each independently represent a hydrogen atom, a hydroxyl group, a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent, or a heterocyclic ring having 1 to 20 carbon atoms which may have a substituent R ^a1 and R ^a2 or any two of R ^a3 to R ^a5 can be bonded to each other to form a ring; when the carbon number of the hydrocarbon group is 2 to 20 and the hydrocarbon group has -CH ₂ -, the -CH _2- can be substituted with -O-, -S- or -CO-; X ^x1 ~ X ^x4 independently represent -R ^x4 , -OR ^x4 , -SR ^x4 , -SO ₃ H, -SO ₃ ^- T ⁺ , -SO ₃ R ^X10 , -SO ₂ NR ^X11 R ^X12 , a halogen atom or a nitro group; R ^x4 represents a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent, and the hydrocarbon group has 2 to 20 carbon atoms and the hydrocarbon group In the case of -CH ₂ -, the -CH ₂ - can be substituted with -O-, -S- or -CO-; T ⁺ means ⁺ N(R ^X13 ) ₄ or an alkali metal ion, and R ^X13 are independently Represents a hydrogen atom or a hydrocarbon group with 1 to 20 carbons; R ^X10 represents a saturated hydrocarbon group with 1 to 20 carbons; R ^X11 and R ^X12 independently represent a hydrogen atom or a hydrocarbon group with 1 to 20 carbons that may have substituents; nx1 ~nx4 each independently represent an integer of 0 to 4; In formula (Xb), L represents -O-SiR ^a6 R ^a7 -O-, -O-SiR ^a8 R ^a9 -O-SiR ^a10 R ^a11 -O- or - OP(=O)R ^a12 -O-; R ^a6 to R ^a12 each independently represent a hydrogen atom, a hydroxyl group, a hydrocarbon group with 1 to 20 carbons that may have a substituent, or a heterogeneous group with 1 to 20 carbons that may have a substituent; Cyclic group, R ^a6 and R ^a7 , R ^a8 and R ^a9 or R ^a10 and R ^a11 can be bonded to each other to form a ring; when the carbon number of the hydrocarbon group is 2 to 20 and the hydrocarbon group has -CH ₂ -, The -CH ₂ - can be substituted with -O-, -S- or -CO-; X ^x5 ~ X ^x12 independently represent -R ^x5 , -OR ^x5 , -SR ^x5 , -SO ₃ H, -SO ₃ ^- Q ⁺ , -SO ₃ R ^X14 , -SO ₂ NR ^X15 R ^X16 , a halogen atom or a nitro group; R ^x5 represents a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent, and the carbon number of the hydrocarbon group is 2 to 20 And when the hydrocarbon group has -CH ₂ -, the -CH ₂ - can be substituted with -O-, -S- or -CO-; Q ⁺ means ⁺ N(R ^X17 ) ₄ or an alkali metal ion, R ^X17 Each independently represents a hydrogen atom or a hydrocarbon group with 1 to 20 carbons; R ^X14 represents a saturated hydrocarbon group with 1 to 20 carbons; R ^X15 and R ^X16 each independently represent a hydrogen atom or a hydrocarbon group with 1 to 20 carbons that may have a substituent hydrocarbon group; nx5-nx12 each independently represent an integer of 0-4] [4] The colored curable composition as described in [3], wherein the compound represented by the formula (Xa) is the formula (X0) or the formula ( The compound represented by XI), the compound represented by formula (Xb) is the compound represented by formula (XII). [Chem 3]

[chemical 4]

[chemical 5]

[In formula (XI), R ^x1 represents an aliphatic unsaturated hydrocarbon group having 2 to 20 carbon atoms which may have a substituent or an aromatic hydrocarbon group having 6 to 20 carbon atoms which may have a substituent, and R ^x2 represents a hydrogen atom, which may have A hydrocarbon group with 1 to 20 carbon atoms in the substituent or a single bond connecting Z ^x2 and R ^x1 ; Z ^x1 and Z ^x2 independently represent a single bond or an oxygen atom; in formula (X0) and formula (XI), X ^x1 ～X ^x4 , nx1～nx4 are the same as described above; In formula (XII), R ^x3 represents an aliphatic unsaturated hydrocarbon group with 2 to 20 carbon atoms that may have a substituent or an aromatic group with 6 to 20 carbon atoms that may have a substituent Z ^x3 represents a single bond or an oxygen atom; X ^x5 ~ X ^x12 , nx5 ~ nx12 are the same as described above] [5] The colored hardening composition as described in [3] or [4], wherein nx1 ~ nx12 is 0. [6] A color filter formed of the colored curable composition according to any one of [1] to [5]. [7] A display device including the color filter as described in [6]. [8] A solid-state imaging device including the color filter described in [6]. [Effect of the invention]

According to the present invention, it is possible to provide a coloring curable composition having a small rate of change in the line width of the pattern obtained even when the coloring curable composition is used after storage, that is, to provide a coloring curable composition that has a stable pattern even after storage. It is also a good coloring hardening composition.

＜＜Coloring curable composition＞＞ The present invention includes a colored curable composition containing a colorant (hereinafter, sometimes referred to as colorant (A)), a resin (hereinafter, sometimes referred to as resin (B)), a polymerizable compound (hereinafter, sometimes referred to as a polymerizable compound (C)), a polymerization initiator (hereinafter, sometimes referred to as a polymerization initiator (D)), and a potential antioxidant (hereinafter, sometimes referred to as a latent antioxidant (E)), the colorant (A) contains an aluminum phthalocyanine compound, and the polymerization initiator (D) contains an oxime compound. The curable colored composition of the present invention may contain a leveling agent (hereinafter, may be referred to as a leveling agent (F)). The curable colored composition of the present invention may also contain a solvent (hereinafter, may be referred to as a solvent (G)). In this specification, unless otherwise specified, the compound illustrated as each component can be used individually or in combination of multiple types.

＜Coloring agent (A)＞ The colored curable composition of the present invention contains an aluminum phthalocyanine compound as a colorant. The aluminum phthalocyanine compound specifically refers to a compound having a phthalocyanine skeleton and forming a complex with aluminum.

Specifically, the aluminum phthalocyanine compound is preferably a compound represented by formula (Xa) or formula (Xb). Hereinafter, the present invention will be more specifically described by citing partial structures of compounds represented by formula (Xa) or formula (Xb). Furthermore, definitions common to formula (X0), formula (XI) or formula (XII) will be described below.

[chemical 6]

[chemical 7]

[In the formula (Xa), Z represents a hydroxyl group, a chlorine atom, -OP(=O)R ^a1 R ^a2 , -O-SiR ^a3 R ^a4 R ^a5 , -OC(=O)R ^a13 or -OS(=O) ₂ R ^a14 ; R ^a1 to R ^a5 and R ^a13 to R ^a14 each independently represent a hydrogen atom, a hydroxyl group, a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent, or a heterocyclic ring having 1 to 20 carbon atoms which may have a substituent R ^a1 and R ^a2 or any two of R ^a3 to R ^a5 can be bonded to each other to form a ring; when the carbon number of the hydrocarbon group is 2 to 20 and the hydrocarbon group has -CH ₂ -, the -CH _2- can be substituted with -O-, -S- or -CO-; X ^x1 ~ X ^x4 independently represent -R ^x4 , -OR ^x4 , -SR ^x4 , -SO ₃ H, -SO ₃ ^- T ⁺ , -SO ₃ R ^X10 , -SO ₂ NR ^X11 R ^X12 , a halogen atom or a nitro group; R ^x4 represents a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent, and the hydrocarbon group has 2 to 20 carbon atoms and the hydrocarbon group In the case of -CH ₂ -, the -CH ₂ - can be substituted with -O-, -S- or -CO-; T ⁺ means ⁺ N(R ^X13 ) ₄ or an alkali metal ion, and R ^X13 are independently Represents a hydrogen atom or a hydrocarbon group with 1 to 20 carbons; R ^X10 represents a saturated hydrocarbon group with 1 to 20 carbons; R ^X11 and R ^X12 independently represent a hydrogen atom or a hydrocarbon group with 1 to 20 carbons that may have substituents; nx1 ~nx4 each independently represent an integer of 0 to 4; In formula (Xb), L represents -O-SiR ^a6 R ^a7 -O-, -O-SiR ^a8 R ^a9 -O-SiR ^a10 R ^a11 -O- or - OP(=O)R ^a12 -O-; R ^a6 to R ^a12 each independently represent a hydrogen atom, a hydroxyl group, a hydrocarbon group with 1 to 20 carbons that may have a substituent, or a heterogeneous group with 1 to 20 carbons that may have a substituent; Cyclic group, R ^a6 and R ^a7 , R ^a8 and R ^a9 or R ^a10 and R ^a11 can be bonded to each other to form a ring; when the carbon number of the hydrocarbon group is 2 to 20 and the hydrocarbon group has -CH ₂ -, The -CH ₂ - can be substituted with -O-, -S- or -CO-; X ^x5 ~ X ^x12 independently represent -R ^x5 , -OR ^x5 , -SR ^x5 , -SO ₃ H, -SO ₃ ^- Q ⁺ , -SO ₃ R ^X14 , -SO ₂ NR ^X15 R ^X16 , a halogen atom or a nitro group; R ^x5 represents a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent, and the carbon number of the hydrocarbon group is 2 to 20 And when the hydrocarbon group has -CH ₂ -, the -CH ₂ - can be substituted with -O-, -S- or -CO-; Q ⁺ means ⁺ N(R ^X17 ) ₄ or an alkali metal ion, R ^X17 Each independently represents a hydrogen atom or a hydrocarbon group with 1 to 20 carbons; R ^X14 represents a saturated hydrocarbon group with 1 to 20 carbons; R ^X15 and R ^X16 each independently represent a hydrogen atom or a hydrocarbon group with 1 to 20 carbons that may have a substituent Hydrocarbon group; nx5～nx12 each independently represent an integer of 0～4]

In formula (Xa), Z is preferably hydroxyl or -OP(=O)R ^a1 R ^a2 . R ^a1 is preferably -R ^b1 , -OR ^b1 , -SR ^b1 or -CO-R ^b1 . R ^a2 is preferably -R ^b2 , -OR ^b2 , -SR ^b2 or -CO-R ^b2 . R ^b1 and R ^b2 represent a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent, and R ^b1 and R ^b2 may be bonded to each other to form a ring.

In formula (Xb), L is preferably -OP(=O)R ^a12 -O-. R ^a12 is preferably -R ^b3 , -OR ^b3 , -SR ^b3 or -CO-R ^b3 . R ^b3 represents a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent.

The compound represented by formula (Xa) is preferably a compound represented by formula (X0) or formula (XI). In addition, the compound represented by the formula (Xb) is preferably a compound represented by the formula (XII). Hereinafter, the present invention will be more specifically described by citing partial structures of compounds represented by formula (X0), formula (XI) or formula (XII).

[chemical 8]

[chemical 9]

[chemical 10]

[In formula (XI), R ^x1 represents an aliphatic unsaturated hydrocarbon group having 2 to 20 carbon atoms which may have a substituent or an aromatic hydrocarbon group having 6 to 20 carbon atoms which may have a substituent, and R ^x2 represents a hydrogen atom, which may have A hydrocarbon group with 1 to 20 carbon atoms in the substituent or a single bond connecting Z ^x2 and R ^x1 ; Z ^x1 and Z ^x2 independently represent a single bond or an oxygen atom; in formula (X0) and formula (XI), X ^x1 ～X ^x4 , nx1～nx4 are the same as described above; In formula (XII), R ^x3 represents an aliphatic unsaturated hydrocarbon group with 2 to 20 carbon atoms that may have a substituent or an aromatic group with 6 to 20 carbon atoms that may have a substituent A group of hydrocarbon groups; Z ^x3 represents a single bond or an oxygen atom; X ^x5 ~ X ^x12 , nx5 ~ nx12 are the same as described]

In addition, the aluminum phthalocyanine compound is also preferably a compound represented by formula (YI) or formula (YII). Hereinafter, the present invention will be more specifically described by citing partial structures of compounds represented by formula (YI) or formula (YII).

[chemical 11]

[chemical 12]

[In the formula (YI), R ^y1 represents a hydrogen atom or a hydrocarbon group with a carbon number of 1 to 20 that may have a substituent; R ^y2 represents a hydrogen atom, a hydrocarbon group with a carbon number of 1 to 20 that may have a substituent, or Z ^y3 and R A single bond linked by ^y1 ; Y ¹ and Z ^y1 independently represent an oxygen atom or a sulfur atom; Z ^y2 and Z ^y3 independently represent a single bond, an oxygen atom or a sulfur atom; wherein, Y ¹ , Z ^y1 , Z ^y2 and At least one of Z ^y3 represents a sulfur atom; X ^y1 to X ^y4 each independently represent -R ^y4 , -OR ^y4 , -SR ^y4 , -SO ₃ H, -SO ₃ ^- M ⁺ , -SO ₃ R ^y10 , - SO ₂ NR ^y11 R ^y12 , a halogen atom or a nitro group; R ^y4 represents a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent; M ⁺ represents ⁺ N(R ^y13 ) ₄ or an alkali metal ion, and R ^y13 independently represents A hydrogen atom or a hydrocarbon group with a carbon number of 1 to 20; R ^y10 represents a saturated hydrocarbon group with a carbon number of 1 to 20; R ^y11 and R ^y12 independently represent a hydrogen atom or a hydrocarbon group with a carbon number of 1 to 20 that may have a substituent; ny1～ ny4 each independently represents an integer of 0 to 4; in formula (YII), R ^y3 represents a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent; Y ² and Z ^y4 each independently represent an oxygen atom or a sulfur atom ; Z ^y5 represents a single bond, an oxygen atom or a sulfur atom; wherein, at least one of Y ² , Z ^y4 and Z ^y5 represents a sulfur atom; X ^y5 to X ^y12 independently represent -R ^y5 , -OR ^y5 , -SR ^y5 , -SO ₃ H, -SO ₃ ^{-W +} , -SO ₃ R ^y14 , -SO ₂ NR ^y15 R ^y16 , a halogen atom or a nitro group; R ^y5 represents a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent; W ⁺ represents ⁺ N(R ^y17 ) ₄ or an alkali metal ion, R ^y17 independently represents a hydrogen atom or a hydrocarbon group with 1 to 20 carbons; R ^y14 represents a saturated hydrocarbon group with 1 to 20 carbons; R ^y15 and R ^y16 are respectively independently represent a hydrogen atom or a hydrocarbon group with 1 to 20 carbon atoms that may have a substituent; ny5 to ny12 each independently represent an integer of 0 to 4]

Furthermore, the compound represented by the formula (YI) includes the compound having a resonance structure represented by the formula (YIa) or the compound represented by the formula (YIb) in a balanced relationship, and the compound represented by the formula (YII) A compound having a resonance structure represented by formula (YIIa) or a compound in equilibrium relation represented by formula (YIIb) is included.

[chemical 13]

[chemical 14]

[In formula (YI), formula (YIa) and formula (YIb), R ^y1 , R ^y2 , Y ¹ , Z ^y1 , Z ^y2 , Z ^y3 , X ^y1 to X ^y4 and ny1 to ny4 are the same as described above; In (YII), formula (YIIa) and formula (YIIb), R ^y3 , Y ² , Z ^y4 , Z ^y5 , X ^y5 to X ^y12 and ny5 to ny12 are the same as described above]

The carbon number of the aliphatic unsaturated hydrocarbon group represented by ^Rx1 and ^Rx3 is 2-20, More preferably, it is 2-10, More preferably, it is 2-7, Most preferably, it is 2-5.

The aliphatic unsaturated hydrocarbon group represented by R ^x1 and R ^x3 may be chain or cyclic (alicyclic hydrocarbon group).

The unsaturated chain hydrocarbon groups represented by R ^x1 and R ^x3 may be linear or branched, specifically, vinyl (vinyl), propenyl (for example, 1-propenyl, 2-propenyl) propenyl (allyl), 1-methylvinyl, butenyl (eg, 1-butenyl, 2-butenyl, 3-butenyl), 3-methyl-1-butene Base, 1-methyl-1-butenyl, 3-methyl-2-butenyl, 1,3-butadienyl, 3-methyl-1,2-butadienyl, 1-( 2-propenyl) vinyl, 1-(1-methyl vinyl) vinyl, 1,1-dimethyl-2-propenyl, 1,2-dimethyl-1-propenyl, 1-ethyl -2-propenyl, pentenyl (e.g., 1-pentenyl, 2-pentenyl, 3-pentenyl, 4-pentenyl), 1-(1,1-dimethylethyl ) vinyl, 1,3-dimethyl-1-butenyl, hexenyl (eg, 1-hexenyl, 5-hexenyl), heptenyl (eg, 1-heptenyl, 6 -heptenyl), octenyl (e.g., 1-octenyl, 7-octenyl), nonenyl (e.g., 1-nonenyl, 8-nonenyl), decenyl (e.g., 1-decenyl, 9-decenyl), undecenyl, dodecenyl, tridecenyl, tetradecenyl, pentadecenyl, hexadecenyl, tendecenyl alkenyl such as heptadecenyl, octadecenyl, nonadecenyl, eicosenyl; ethynyl, propynyl (eg, 1-propynyl, 2-propynyl), butynyl (e.g., 1-butynyl, 2-butynyl, 3-butynyl), pentynyl (e.g., 2-pentynyl, 3-pentynyl, 4-pentynyl), 1- Methyl-3-butynyl, 1,1-dimethyl-2-propynyl, hexynyl (eg, 2-hexynyl, 5-hexynyl), 1-ethyl-3-butane Alkynyl, heptynyl (e.g., 2-heptynyl, 6-heptynyl), 1-ethyl-3-pentynyl, octynyl (e.g., 1-octynyl, 2-octynyl , 7-octynyl), nonynyl (e.g., 2-nonynyl, 8-nonynyl), decynyl (e.g., 2-decynyl, 9-decynyl), undecyne base, dodecynyl, tridecynyl, tetradecynyl, pentadecynyl, hexadecynyl, heptadecynyl, octadecynyl, nonadecynyl and Eicosynyl etc. alkynyl etc.

Examples of unsaturated alicyclic hydrocarbon groups represented by R ^x1 and R ^x3 include: cyclohexenyl (for example, cyclohex-1-en-1-yl, cyclohex-2-en-1-yl, cyclohexenyl -3-en-1-yl), cycloheptenyl and cyclooctenyl and other cycloalkenyl groups; norbornenyl and other unsaturated polycyclic hydrocarbon groups, etc.

The aliphatic unsaturated hydrocarbon group having 2 to 20 carbon atoms represented by R ^x1 and R ^x3 may have a substituent. Examples of substituents for the aliphatic unsaturated hydrocarbon groups having 2 to 20 carbon atoms represented by ^Rx1 and ^Rx3 include aromatic hydrocarbon groups having 6 to 20 carbon atoms which may have substituents, heterocyclic groups which may have substituents , halogen atom, nitro group, cyano group, -OR ^xa1 , -CO ₂ R ^xa1 , -SR ^xa1 , -SO ₃ R ^xa1 , -SO ₂ NR ^xa1 R ^xa2 and -NR ^xa1 R ^xa2 etc. Here, R ^xa1 and R ^xa2 each independently represent a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms. The hydrocarbon groups having 1 to 20 carbons represented by R ^xa1 and R ^xa2 are the same as the hydrocarbon groups having 1 to 20 carbons represented by R ^b1 to R ^b3 , R ^x2 , R ^x4 , R ^x5 and R ^y1 to R ^y5 described later . Furthermore, when the aliphatic unsaturated hydrocarbon group has an aromatic hydrocarbon group as a substituent, the total number of carbon atoms of the aliphatic unsaturated hydrocarbon group and the carbon number of the substituent aromatic hydrocarbon group is preferably 20 or less.

Examples of aromatic hydrocarbon groups having 6 to 20 carbon atoms used as substituents for aliphatic unsaturated hydrocarbon groups having 2 to 20 carbon atoms represented by R ^x1 and R ^x3 include: phenyl, o-tolyl, and m-tolyl , p-tolyl, 2-ethylphenyl, 3-ethylphenyl, 4-ethylphenyl, 2,3-dimethylphenyl, 2,4-dimethylphenyl, 2,5- Dimethylphenyl, 2,6-dimethylphenyl, 3,4-dimethylphenyl, 3,5-dimethylphenyl, 4-vinylphenyl, o-isopropylphenyl, m-isopropylphenyl, p-isopropylphenyl, o-tert-butylphenyl, m-tert-butylphenyl, p-tert-butylphenyl, 3,5-di(tert-butyl)benzene Base, 3,5-bis(tert-butyl)-4-methylphenyl, 4-butylphenyl, 4-pentylphenyl, 2,6-bis(1-methylethyl)phenyl , 2,4,6-tri(1-methylethyl)phenyl, 4-cyclohexylphenyl, 2,4,6-trimethylphenyl, 4-octylphenyl, 4-(1, 1,3,3-tetramethylbutyl)phenyl, 1-naphthyl, 2-naphthyl, 6-methyl-2-naphthyl, 5,6,7,8-tetrahydro-1-naphthyl , 5,6,7,8-tetrahydro-2-naphthyl, fluorenyl, phenanthrenyl, anthracenyl, 2-dodecylphenyl, 3-dodecylphenyl, 4-dodecyl Phenyl, perylene, fenyl and pyrenyl, etc. The carbon number of the aromatic hydrocarbon group is preferably 6-10, more preferably 6-8. The aromatic hydrocarbon group may have a substituent, and examples of the substituent include: a halogen atom, a nitro group, a cyano group, -OR ^xa1 , -CO ₂ R ^xa1 , -SR ^xa1 , -SO ₃ R ^xa1 , -SO ₂ NR ^xa1 R ^xa2 and -NR ^xa1 R ^xa2 etc. (wherein, R ^xa1 and R ^xa2 are the same as above).

The heterocyclic group used as a substituent for the aliphatic unsaturated hydrocarbon group having 2 to 20 carbon atoms represented by ^Rx1 and ^Rx3 may be monocyclic or polycyclic, and preferably contains a heteroatom as a constituent of the ring. of heterocycles. As a hetero atom, a nitrogen atom, an oxygen atom, a sulfur atom, etc. are mentioned. As for heterocycles containing only nitrogen atoms as heteroatoms, examples include monocyclic saturated heterocycles such as aziridine, azetidine, pyrrolidine, piperidine, and piperazine; pyrrole, pyrazole, imidazole, 1 ,2,3-triazole, 1,2,4-triazole and other 5-membered unsaturated heterocycles, pyridine, pyridazine, pyrimidine, pyrazine, 1,3,5-triazine and other 6-membered unsaturated heterocycles Monocyclic unsaturated heterocycles such as saturated heterocycles; indazole, indoline, isoindoline, isoindoline-1,3-dione, indole, indoxazine, benzimidazole, quinoline, Isoquinoline, quinoxaline, quinazoline, cinnoline, phthalazine, naphthyridine, purine, pteridine, benzopyrazole, benzopiperidine and other condensed bicyclic heterocycles; carbazole, acridine, phenanthrene Condensation of tricyclic heterocycles such as oxazine, etc. Regarding heterocyclic rings containing only oxygen atoms as heteroatoms, monocyclic rings such as oxirane, oxetane, tetrahydrofuran, tetrahydropyran, 1,3-dioxane, and 1,4-dioxane, etc. Ring system saturated heterocycle; bicyclic saturated heterocycle such as 1,4-dioxaspiro[4.5]decane, 1,4-dioxaspiro[4.5]nonane; α-acetyl lactone, β-propiolactone, γ-butyrolactone, δ-valerolactone and other lactone-based heterocycles; 5-membered unsaturated heterocycles such as furan; 6-membered rings such as 2H-pyran and 4H-pyran Monocyclic unsaturated heterocycles such as saturated heterocycles; condensed bicyclic rings such as 1-benzofuran, benzopyran, benzodioxole, chromane, and isochromane Heterocyclic rings; condensed tricyclic heterocyclic rings such as xanthene, dibenzofuran, etc. Regarding the heterocycle containing only a sulfur atom as a heteroatom, there are 5-membered saturated heterocycles such as dithiolane, and 6-membered saturated heterocycles such as thiane and 1,3-dithiane. Monocyclic saturated heterocycles such as rings; 5-membered unsaturated heterocycles such as thiophene, 6-membered unsaturated heterocycles such as 4H-thiopyran and other monocyclic unsaturated heterocycles; benzotetrahydrothiophene Condensed bicyclic heterocycles such as benzothiopyran and benzothiophene; condensed tricyclic heterocycles such as thianthrene and dibenzothiophene. Regarding heterocyclic rings containing nitrogen atoms and oxygen atoms as heteroatoms, examples include monocyclic saturated heterocyclic rings such as morpholine, 2-pyrrolidone, and 2-piperidone; monocyclic saturated heterocyclic rings such as oxazole and isoxazole; Saturated heterocycles; condensed bicyclic heterocycles such as benzoxazole, benzisoxazole, benzoxazine, benzodioxane, and benzimidazoline; condensed tricyclic heterocycles such as phenoxazine, etc. The heterocyclic ring containing a nitrogen atom and a sulfur atom as a heteroatom includes monocyclic unsaturated heterocyclic rings such as thiazole; condensed bicyclic heterocyclic rings such as benzothiazole; and condensed tricyclic heterocyclic rings such as phenthiazine. The carbon number of the heterocyclic group is preferably 2-30, more preferably 3-22, and still more preferably 3-20. This heterocyclic group may have a substituent, and the substituent includes a halogen atom, a nitro group, a cyano group, -OR ^xa1 , -CO ₂ R ^xa1 , -SR ^xa1 , -SO ₃ R ^xa1 , -SO ₂ NR ^xa1 R ^xa2 and -NR ^xa1 R ^xa2 etc. (wherein, R ^xa1 and R ^xa2 are the same as above). In addition, the bonding site of the heterocyclic ring is a part from which any hydrogen atom contained in each ring is removed.

Examples of the halogen atom used as the substituent of the aliphatic unsaturated hydrocarbon group having 2 to 20 carbon atoms represented by ^Rx1 and ^Rx3 include a fluorine atom, a chlorine atom, a bromine atom, and an iodine atom.

The carbon number of the aromatic hydrocarbon group represented by ^Rx1 and ^Rx3 is 6-20, More preferably, it is 6-10, More preferably, it is 6-8, Most preferably, it is 6.

Examples of the aromatic hydrocarbon group represented by ^Rx1 and ^Rx3 include an aromatic hydrocarbon group having 6 to 20 carbon atoms used as a substituent for an aliphatic unsaturated hydrocarbon group having 2 to 20 carbon atoms represented by ^Rx1 and ^Rx3 And the aromatic hydrocarbon group etc. are illustrated.

The aromatic hydrocarbon group having 6 to 20 carbon atoms represented by R ^x1 and R ^x3 may have a substituent. Examples of substituents for the aromatic hydrocarbon groups having 6 to 20 carbon atoms represented by R ^x1 and R ^x3 include halogen atoms such as fluorine atoms, chlorine atoms, bromine atoms, and iodine atoms, nitro groups, cyano groups, -OR ^xa1 , -CO ₂ R ^xa1 , -SR ^xa1 , -SO ₃ R ^xa1 , -SO ₂ NR ^xa1 R ^xa2 , -NR ^xa1 R ^xa2 and the like (wherein, R ^xa1 and R ^xa2 are the same as above).

R ^a1 ~R ^a14 , R ^b1 ~R ^b3 , R ^x2 , R ^x4 , R ^x5 , R ^{X11 ~R X13 ,} R ^X15 ~R ^X17 , R ^y1 ~R ^y5 , R ^y11 ~R ^y13 and R ^y15 ~R ^y17 The carbon number of the hydrocarbon group represented is 1-21, More preferably, it is 1-15.

R ^a1 ~R ^a14 , R ^b1 ~R ^b3 , R ^x2 , R ^x4 , R ^x5 , R ^{X11 ~R X13 ,} R ^X15 ~R ^X17 , R ^y1 ~R ^y5 , R ^y11 ~R ^y13 and R ^y15 ~R ^y17 The represented hydrocarbon group having 1 to 20 carbons may be an aliphatic hydrocarbon group or an aromatic hydrocarbon group, and the aliphatic hydrocarbon group may be saturated or unsaturated, and may be chain or cyclic (alicyclic hydrocarbon group).

As R ^a1 to R ^a14 , R ^b1 to R b3 , R ^x2 , R ^{x4 ,} R ^x5 , R ^X11 to R ^X13 , R ^X15 to R ^X17 , R ^y1 to R ^{y5 , R y11 to} R ^y13 and R ^y15 to R The saturated or unsaturated chain hydrocarbon groups represented by ^y17 include: methyl, ethyl, n-propyl, n-butyl, n-pentyl, n-hexyl, n-heptyl, n-octyl, n-nonyl, n-decyl Base, n-undecyl, n-twelve bases, n-thirteen bases, n-fourteen bases, n-fifteen bases, n-hexadecyl bases, n-heptadecyl bases, n-octacyl bases, n-nineteen bases and n-twenty bases Straight-chain alkyl groups such as radicals; isopropyl, isobutyl, second butyl, third butyl, 2-ethylbutyl, 3,3-dimethylbutyl, 1,1,3,3 -Tetramethylbutyl, 1-methylbutyl, 1-ethylpropyl, 3-methylbutyl, neopentyl, 1,1-dimethylpropyl, 1,1,2-trimethyl Propyl, 2-methylpentyl, 3-ethylpentyl, 1,3-dimethylbutyl, 2-propylpentyl, 1-ethyl-1,2-dimethylpropyl, 1-methylpentyl, 4-methylpentyl, 4-methylhexyl, 5-methylhexyl, 2-ethylhexyl, 1-methylhexyl, 1-ethylpentyl, 1-propylbutyl Base, 3-ethylheptyl, 2,2-dimethylheptyl, 1-methylheptyl, 1-ethylhexyl, 1-propylpentyl, 1-methyloctyl, 1-ethyl Heptyl, 1-propylhexyl, 1-butylpentyl, 1-methylnonyl, 1-ethyloctyl, 1-propylheptyl, 1-butylhexyl and other branched alkyl groups; ethylene Vinyl, propenyl (e.g., 1-propenyl, 2-propenyl (allyl)), 1-methylvinyl, butenyl (e.g., 1-butenyl, 2-butenyl , 3-butenyl), 3-methyl-1-butenyl, 1-methyl-1-butenyl, 3-methyl-2-butenyl, 1,3-butadienyl, 3-Methyl-1,2-butadienyl, 1-(2-propenyl)ethenyl, 1-(1-methylethenyl)ethenyl, 1,1-dimethyl-2-propenyl , 1,2-dimethyl-1-propenyl, 1-ethyl-2-propenyl, pentenyl (for example, 1-pentenyl, 2-pentenyl, 3-pentenyl, 4- pentenyl), 1-(1,1-dimethylethyl)ethenyl, 1,3-dimethyl-1-butenyl, hexenyl (for example, 1-hexenyl, 5-hex alkenyl), heptenyl (e.g., 1-heptenyl, 6-heptenyl), octenyl (e.g., 1-octenyl, 7-octenyl), nonenyl (e.g., 1- Nonenyl, 8-nonenyl), decenyl (eg, 1-decenyl, 9-decenyl), undecenyl, dodecenyl, tridecenyl, tetradecenyl Carbenyl, pentadecenyl, hexadecenyl, heptadecenyl, octadecenyl, nonadecenyl, eicosenyl and other alkenyl groups; ethynyl, propynyl ( For example, 1-propynyl, 2-propynyl), butynyl (for example, 1-butynyl, 2-butynyl, 3-butynyl), pentynyl (for example, 2-pentynyl , 3-pentynyl, 4-pentynyl), 1-methyl-3-butynyl, 1,1-dimethyl-2-propynyl, hexynyl (for example, 2-hexynyl , 5-hexynyl), 1-ethyl-3-butynyl, heptynyl (e.g., 2-heptynyl, 6-heptynyl), 1-ethyl-3-pentynyl, Octynyl (e.g., 1-octynyl, 2-octynyl, 7-octynyl), nonynyl (e.g., 2-nonynyl, 8-nonynyl), decynyl (e.g., 2-decynyl, 9-decynyl), undecynyl, dodecynyl, tridecynyl, tetradecynyl, pentadecynyl, hexadecynyl, tendecynyl Alkynyl groups such as heptadecynyl, octadecynyl, nonadecenyl and eicosynyl, etc. R ^a1 ~R ^a14 , R ^b1 ~R ^b3 , R ^x2 , R ^x4 , R ^x5 , R ^{X11 ~R X13 ,} R ^X15 ~R ^X17 , R ^y1 ~R ^y5 , R ^y11 ~R ^y13 and R ^y15 ~R ^y17 The carbon number of the saturated chain hydrocarbon group shown is preferably 1-10, more preferably 1-7, and still more preferably 1-5. R ^a1 ~R ^a14 , R ^b1 ~R ^b3 , R ^x2 , R ^x4 , R ^x5 , R ^{X11 ~R X13 ,} R ^X15 ~R ^X17 , R ^y1 ~R ^y5 , R ^y11 ~R ^y13 and R ^y15 ~R ^y17 The carbon number of the unsaturated chain hydrocarbon group shown is preferably 2-10, more preferably 2-7, and still more preferably 2-5.

R ^a1 ~R ^a14 , R ^b1 ~R ^b3 , R ^x2 , R ^x4 , R ^x5 , R ^{X11 ~R X13 ,} R ^X15 ~R ^X17 , R ^y1 ~R ^y5 , R ^y11 ~R ^y13 and R ^y15 ~R ^y17 The represented saturated or unsaturated alicyclic hydrocarbon groups include: cyclopropyl, 1-methylcyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl, 1-methylcyclohexyl, 2 -Methylcyclohexyl, 3-methylcyclohexyl, 4-methylcyclohexyl, 1,2-dimethylcyclohexyl, 1,3-dimethylcyclohexyl, 1,4-dimethylcyclohexyl, 2,3-Dimethylcyclohexyl, 2,4-Dimethylcyclohexyl, 2,5-Dimethylcyclohexyl, 2,6-Dimethylcyclohexyl, 3,4-Dimethylcyclohexyl, 3,5-dimethylcyclohexyl, 2,2-dimethylcyclohexyl, 3,3-dimethylcyclohexyl, 4,4-dimethylcyclohexyl, cyclooctyl, 2,4,6- Trimethylcyclohexyl, 2,2,6,6-tetramethylcyclohexyl, 3,3,5,5-tetramethylcyclohexyl, 4-pentylcyclohexyl, 4-octylcyclohexyl and 4- Cycloalkyl such as cyclohexylcyclohexyl; cyclohexenyl (for example, cyclohex-1-en-1-yl, cyclohex-2-en-1-yl, cyclohex-3-en-1-yl), Cycloalkenyl groups such as cycloheptenyl and cyclooctenyl; Saturated or unsaturated polycyclic hydrocarbon groups such as norbornyl, norbornenyl, adamantyl and bicyclo[2.2.2]octyl, etc. R ^a1 ~R ^a14 , R ^b1 ~R ^b3 , R ^x2 , R ^x4 , R ^x5 , R ^{X11 ~R X13 ,} R ^X15 ~R ^X17 , R ^y1 ~R ^y5 , R ^y11 ~R ^y13 and R ^y15 ~R ^y17 The carbon number of the saturated or unsaturated alicyclic hydrocarbon group is preferably 3-10.

As R ^a1 to R ^a14 , R ^b1 to R b3 , R ^x2 , R ^{x4 ,} R ^x5 , R ^X11 to R ^X13 , R ^X15 to R ^X17 , R ^y1 to R ^{y5 , R y11 to} R ^y13 and R ^y15 to R The aromatic hydrocarbon group represented by ^y17 includes the aromatic hydrocarbon group exemplified as the aromatic hydrocarbon group having 6 to 20 carbon atoms used as a substituent for the aliphatic unsaturated hydrocarbon group having 2 to 20 carbon atoms represented by ^Rx1 and ^Rx3 . Hydrocarbyl etc. R ^a1 ~R ^a14 , R ^b1 ~R ^b3 , R ^x2 , R ^x4 , R ^x5 , R ^{X11 ~R X13 ,} R ^X15 ~R ^X17 , R ^y1 ~R ^y5 , R ^y11 ~R ^y13 and R ^y15 ~R ^y17 The number of carbon atoms in the represented aromatic hydrocarbon group is preferably 6-20, more preferably 6-10, and still more preferably 6-8.

R ^a1 ~R ^a14 , R ^b1 ~R ^b3 , R ^x2 , R ^x4 , R ^x5 , R ^{X11 ~R X13 ,} R ^X15 ~R ^X17 , R ^y1 ~R ^y5 , R ^y11 ~R ^y13 and R ^y15 ~R ^y17 The hydrocarbon group represented may be a group formed by combining the listed hydrocarbon groups (for example, an aromatic hydrocarbon group and at least one of an aromatic hydrocarbon group, a chain hydrocarbon group, and an alicyclic hydrocarbon group), and may include: benzyl, (2 -Methylphenyl)methyl, (3-methylphenyl)methyl, (4-methylphenyl)methyl, (2-ethylphenyl)methyl, (3-ethylphenyl) Methyl, (4-ethylphenyl)methyl, (2-(tertiary butyl)phenyl)methyl, (3-(tertiary butyl)phenyl)methyl, (4-(tertiary Butyl)phenyl)methyl, (3,5-dimethylphenyl)methyl, 1-phenylethyl, 1-methyl-1-phenylethyl, 1,1-diphenylethyl Aralkyl groups such as (1-naphthyl)methyl, (2-naphthyl)methyl and 9-fluorenylmethyl; 1-phenylvinyl, 2-phenylethenyl (phenyl ethyl) aryl alkenyl such as phenyl vinyl), 2,2-diphenylvinyl, 2-phenyl-2-(1-naphthyl) vinyl, etc.; arylalkynyl such as phenylethynyl; Biphenyl, terphenyl, and the like are phenyl groups in which one or more phenyl groups are bonded; cyclohexylmethylphenyl, benzylphenyl, (dimethyl(phenyl)methyl)phenyl, and the like. These carbon numbers are preferably 7-18, more preferably 7-15.

About R ^a1 ~R ^a14 , R ^b1 ~R ^b3 , R ^x2 , R ^x4 , R ^x5 , R ^X11 ~R ^X13 , R ^X15 ~R ^X17 , R ^y1 ~R ^y5 , R ^y11 ~R ^y13 and R ^y15 ~R The group represented by ^y17 , as a group formed by combining the listed hydrocarbon groups (for example, a chain hydrocarbon group and an alicyclic hydrocarbon group), for example, may be: cyclopropylmethyl, cyclopropylethyl, cyclobutylmethyl , cyclobutylethyl, cyclopentylmethyl, cyclopentylethyl, cyclohexylmethyl, (2-methylcyclohexyl)methyl, cyclohexylethyl, adamantylmethyl, etc. have a bond The alkyl group of the above alicyclic hydrocarbon group. These carbon numbers are preferably 4-15, more preferably 4-10.

When the carbon number of the hydrocarbon group represented by R ^a1 to R ^a14 , R ^x4 and R ^x5 is 2 to 20 and the hydrocarbon group has -CH ₂ -, the -CH ₂ - may be substituted with -O-, -S -or-CO-. Wherein, in the hydrocarbon group with 2 to 20 carbons, the adjacent -CH ₂ - will not be substituted with -O- and/or -S- at the same time, and the terminal -CH ₂ - will not be substituted with -O-, -S- or -CO-.

Furthermore, when -CH ₂ - in a hydrocarbon group with 1 to 20 carbons is substituted with -O-, -S- or -CO-, the group substituted with -O-, -S- or -CO- The carbon number refers to the carbon number in the hydrocarbon group before being substituted with -O-, -S- or -CO-. For example, *-O-CH ₂ -CH ₂ -CH ₃ group is a group in which -CH ₂ - in a hydrocarbon group with 4 carbons (*-CH ₂ -CH ₂ -CH ₂ -CH ₃ ) is substituted with -O- . In addition, if a plurality of -CH ₂ - that can be substituted exists in the hydrocarbon group having 1 to 20 carbons, the number of substitutions is not necessarily limited to one. For example, two -CH ₂ - in a hydrocarbon group with 4 carbons (*-CH ₂ -CH ₂ -CH ₂ -CH ₃ ) can be substituted with -O- to become *-O-CH ₂ -O- _CH3 . That is, like *-O-CH ₂ -O-CH ₃ , groups in which two or more -CH ₂ - are substituted with -O-, -S- or -CO- are also included in the "optionally substituted carbon A group in which -CH ₂ - in the hydrocarbon group of the number 1 to 20 is substituted with -O-, -S- or -CO-."

R ^a1 ~R ^a14 , R ^b1 ~R ^b3 , R ^x2 , R ^x4 , R ^x5 , R ^X11 , R ^X12 , R ^X15 , R ^X16 , R ^y1 ~R y5 , R ^y11 , ^{R y12 ,} R ^y15 and R ^y16 The represented hydrocarbon group having 1 to 20 carbon atoms may have a substituent. As R ^a1 to R ^a14 , R ^b1 to R b3 , R ^x2 , R ^{x4 ,} R ^x5 , R ^X11 , R ^X12 , R ^X15 , R ^X16 , R ^y1 to R ^{y5 , R y11 , R y12 , R y15} and R The substituent of the hydrocarbon group having 1 to 20 carbon atoms represented by ^y16 includes a heterocyclic group which may have a substituent, a halogen atom, a nitro group, a cyano group, -OR ^xa1 , -CO ₂ R ^xa1 , -SR ^xa1 , -SO ₃ R ^xa1 , -SO ₂ NR ^xa1 R ^xa2 , and -NR ^xa1 R ^xa2 etc. (wherein R ^xa1 and R ^xa2 are the same as above).

As R ^a1 to R ^a14 , R ^b1 to R b3 , R ^x2 , R ^{x4 ,} R ^x5 , R ^X11 , R ^X12 , R ^X15 , R ^X16 , R ^y1 to R ^{y5 , R y11 , R y12 , R y15} and R The heterocyclic group used as a substituent of the hydrocarbon group having 1 to 20 carbon atoms represented by ^y16 may be monocyclic or polycyclic, and is preferably a heterocyclic group containing a heteroatom as a ring constituent. As a hetero atom, a nitrogen atom, an oxygen atom, a sulfur atom, etc. are mentioned. Examples of the heterocyclic ring include the same ones as the heterocyclic group used as the substituent of the aliphatic unsaturated hydrocarbon group having 2 to 20 carbon atoms represented by ^Rx1 and ^Rx3 . The carbon number of the heterocyclic group is preferably 2-30, more preferably 3-22, and still more preferably 3-20. This heterocyclic group may have a substituent, and examples of the substituent include: a halogen atom, a nitro group, a cyano group, -OR ^xa1 , -CO ₂ R ^xa1 , -SR ^xa1 , -SO ₃ R ^xa1 , -SO ₂ NR ^xa1 R ^xa2 and -NR ^xa1 R ^xa2 etc. (wherein, R ^xa1 and R ^xa2 are the same as above). In addition, the bonding site of the heterocyclic ring is a part from which any hydrogen atom contained in each ring is removed.

As R ^a1 to R ^a14 , R ^b1 to R b3 , R ^x2 , R ^{x4 ,} R ^x5 , R ^X11 , R ^X12 , R ^X15 , R ^X16 , R ^y1 to R ^{y5 , R y11 , R y12 , R y15} and R Examples of the halogen atom used as the substituent of the hydrocarbon group having 1 to 20 carbon atoms represented by ^y16 include a fluorine atom, a chlorine atom, a bromine atom, and an iodine atom.

Examples of saturated hydrocarbon groups having 1 to 20 carbon atoms represented by R ^X10 , R ^X14 , R ^y10 and X ^y14 include R ^a1 to R ^a14 , R ^b1 to R ^b3 , R ^x2 , R ^x4 , R ^x5 , and R ^{X11 Linear alkyl , branched alkyl , cycloalkyl and saturated} A group exemplified as a polycyclic hydrocarbon group.

The heterocyclic group having 1 to 20 carbon atoms represented by R ^a1 to R ^a14 may be monocyclic or polycyclic, and is preferably a heterocyclic ring containing a heteroatom as a ring constituent. As a hetero atom, a nitrogen atom, an oxygen atom, a sulfur atom, etc. are mentioned. Examples of the heterocyclic ring include the same ones as the heterocyclic group used as the substituent of the aliphatic unsaturated hydrocarbon group having 2 to 20 carbon atoms represented by ^Rx1 and ^Rx3 . The carbon number of the heterocyclic group is preferably 3-20. This heterocyclic group may have a substituent, and examples of the substituent include: a halogen atom, a nitro group, a cyano group, an alkyl group having 1 to 10 carbon atoms, -OR ^xa1 , -CO ₂ R ^xa1 , -SR ^xa1 , -SO ₃ R ^xa1 , -SO ₂ NR ^xa1 R ^xa2 and -NR ^xa1 R ^xa2 etc. (wherein, R ^xa1 and R ^xa2 are the same as above). In addition, the bonding site of the heterocyclic ring is a part from which any hydrogen atom contained in each ring is removed.

When R ^x2 is a single bond linking Z ^x2 and R ^x1 , part or all of R ^x1 forms a ring together with *-Z ^x2 -P(=O)-Z ^x1 -* (* indicates a bond). That is, when ^Rx2 is a single bond linking ^Zx2 and ^Rx1 , any carbon atom in the aliphatic unsaturated hydrocarbon group having 2 to 20 carbon atoms that may have a substituent represented by ^Rx1 or any carbon atom that may have a substituent A pair of electrons are shared between any carbon atom in an aromatic hydrocarbon group with 6 to 20 carbons (preferably any carbon atom in an aliphatic unsaturated hydrocarbon group with 2 to 20 carbons that may have substituents) and Z ^x2 And the bond formed is equivalent to the single bond represented by ^Rx2 .

In the case where R ^x1 is an aliphatic unsaturated hydrocarbon group having 2 to 20 carbon atoms which may have a substituent, part or all of R ^x1 and *-Z ^x2 -P(=O)-Z ^x1 -* (* represents In the ring formed together, an unsaturated bond may be formed between carbon atoms that are members of the ring, or between a carbon atom that is a member of the ring and a carbon atom that is not a member of the ring An unsaturated bond may be formed between them, and an unsaturated bond may be formed between carbon atoms other than the constituent members of the ring.

In addition, when R ^y2 is a single bond connecting Z ^y3 and R ^y1 , R ^y1 is a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent, and part or all of R ^y1 is combined with *-Z ^y3 -P(=Z ^y1 )-Z ^y2- * (* means bonding bond) together form a ring. That is, when R ^y2 is a single bond connecting Z ^y3 and R ^y1 , a pair of electrons are shared between any carbon atom in the hydrocarbon group having 1 to 20 carbon atoms that may have substituents represented by R ^y1 and Z ^y3 The bond formed corresponds to a single bond represented by R ^y2 .

nx1-nx12 and ny1-ny12 each independently represent the integer of 0-4. nx1～nx4 can be the same or different, preferably the same, nx5～nx12 can be the same or different, preferably the same, ny1～ny4 can be the same or different, preferably the same, ny5～ny12 can be the same or different , preferably the same. When nx1 represents an integer of 2 or more, a plurality of X ^x1 may be the same or different. The same applies to a plurality of X ^x2 to X x12 and X ^y1 to X ^y12 when nx2 to nx12 and ^ny1 to ny12 represent an integer of 2 or more.

The substitution position of X ^x1 is not particularly limited. When nx1 is 1, it is preferably the 2-position or 3-position position in the following partial structural formula. When nx1 is 2, it is preferably the following structure The position of 2 and 3 in the formula. The same applies to the substitution positions of X ^x2 to X ^x12 and X ^y1 to X ^y12 . In addition, in the following partial structural formula, * represents a bond.

[chemical 15]

Examples of the halogen atoms represented by X ^x1 to X ^x12 and X ^y1 to X ^y12 include fluorine atoms, chlorine atoms, bromine atoms, and iodine atoms, and are preferably fluorine atoms.

-R ^x4 represented by X ^x1 to X ^x4 , ^-R x5 represented by X ^x5 to X ^x12 , -R ^y4 represented by X ^y1 to X ^y4 , or -R ^y5 represented by X ^y5 to X ^y12 are preferably An aliphatic hydrocarbon group with 1 to 20 carbons, more preferably a saturated chain hydrocarbon group with 1 to 20 carbons, more preferably a saturated chain hydrocarbon group with 1 to 10 carbons, and even more preferably a branched chain with 1 to 5 carbons Like alkyl, particularly preferably tertiary butyl.

R ^X13 , R ^X17 , R ^y13 and R ^y17 are each independently preferably a hydrogen atom or a saturated chain hydrocarbon group with 1 to 20 carbons, more preferably a hydrogen atom or a saturated chain hydrocarbon group with 1 to 10 carbons, More preferably, it is a hydrogen atom or a saturated chain hydrocarbon group having 1 to 5 carbon atoms.

The alkali metal ions represented by T ⁺ , Q ⁺ , M ⁺ , and W ⁺ are independently preferably lithium ions, sodium ions, or potassium ions.

The saturated hydrocarbon group having 1 to 20 carbons represented by R ^X10 , R ^X14 , R ^y10 and R ^y14 is preferably a linear or branched alkyl group having 1 to 20 carbons, more preferably 1 carbon. ~10 straight-chain alkyl groups.

R ^X11 , R ^X12 , R ^X15 , R ^X16 , R ^y11 , R ^y12 , R ^y15 and R ^y16 are each independently preferably a hydrogen atom or a saturated chain hydrocarbon group with 1 to 20 carbons, more preferably a hydrogen atom Or a saturated chain hydrocarbon group having 1 to 10 carbons, more preferably a hydrogen atom or a saturated chain hydrocarbon group having 1 to 5 carbons.

In formula (XI), R ^x1 is preferably an unsaturated chain hydrocarbon group with 2 to 20 carbons that may have substituents or an aromatic hydrocarbon group with 6 to 10 carbons that may have substituents, more preferably An unsaturated chain hydrocarbon group having 2 to 10 carbon atoms or an aromatic hydrocarbon group having 6 to 8 carbon atoms that may have a substituent, more preferably an unsaturated chain hydrocarbon group having 2 to 7 carbon atoms that may have a substituent Or an aromatic hydrocarbon group having 6 to 7 carbon atoms that may have a substituent, particularly preferably a vinyl group that may have a substituent, a propenyl group that may have a substituent, a butenyl group that may have a substituent, or a 3 -Methyl-2-butenyl, optionally substituted 3-methyl-1,2-butadienyl, optionally substituted heptenyl, optionally substituted ethynyl, optionally substituted a propynyl group, a butynyl group which may have a substituent, or a phenyl group which may have a substituent. When the aliphatic unsaturated hydrocarbon group having 2 to 20 carbon atoms represented by R ^x1 has a substituent, the substituent is preferably a phenyl group. R ^x2 is preferably an optionally substituted aromatic hydrocarbon group having 6 to 20 carbon atoms or an optionally substituted aliphatic unsaturated hydrocarbon group having 2 to 20 carbon atoms. Here, examples of the aliphatic unsaturated hydrocarbon group having 2 to 20 carbon atoms include those described as the alkenyl group, alkynyl group, and unsaturated alicyclic hydrocarbon group. Examples of substituents that the aliphatic unsaturated hydrocarbon group having 2 to 20 carbon atoms may have include those described as substituents that the aliphatic unsaturated hydrocarbon group having 2 to 20 carbon atoms represented by R ^x1 and R ^x3 may have. base. However, when the aliphatic unsaturated hydrocarbon group has an aromatic hydrocarbon group as a substituent, the sum of the carbon number of the aliphatic unsaturated hydrocarbon group and the carbon number of the aromatic hydrocarbon group as the substituent is 20 or less. Regarding the aliphatic unsaturated hydrocarbon group having an aromatic hydrocarbon group as a substituent, specifically, groups exemplified as an arylalkenyl group and an arylalkynyl group are mentioned. Among them, R ^x2 is more preferably an aromatic hydrocarbon group having 6 to 10 carbon atoms which may have substituents or an unsaturated chain hydrocarbon group having 2 to 20 carbon atoms which may have substituents (ie, alkenyl, alkynyl), Furthermore, it is preferably an aromatic hydrocarbon group having 6 to 8 carbon atoms which may have a substituent or an unsaturated chain hydrocarbon group having 2 to 7 carbon atoms which may have a substituent, particularly preferably a phenyl group which may have a substituent, a phenyl group which may have a substituent vinyl, optionally substituted propenyl, optionally substituted butenyl, optionally substituted 3-methyl-2-butenyl, optionally substituted 3-methyl-1,2 - butadienyl, optionally substituted heptenyl, optionally substituted ethynyl, optionally substituted propynyl, or optionally substituted butynyl. When the aliphatic unsaturated hydrocarbon group having 2 to 20 carbons represented by R ^x2 has a substituent, the substituent is preferably an aromatic hydrocarbon group having 6 to 10 carbons, more preferably a phenyl group.

In formula (Xa), formula (X0) and formula (XI), X ^x1 to X ^x4 are each independently preferably -R ^x4 or a halogen atom, more preferably a linear or branched chain with 1 to 10 carbons -like alkyl group or halogen atom, more preferably branched chain alkyl group or halogen atom having 1 to 5 carbon atoms, particularly preferably tertiary butyl group, fluorine atom, chlorine atom or bromine atom. nx1-nx4 are each independently, for example, 0-2 or 4, Preferably it is 0-2, More preferably, it is 0-1, More preferably, it is 0.

In formula (XII), regarding R ^x3 , it is preferably an unsaturated chain hydrocarbon group with 2 to 20 carbons that may have substituents or an aromatic hydrocarbon group with 6 to 10 carbons that may have substituents, more preferably An unsaturated chain hydrocarbon group with 2 to 10 carbons having substituents or an aromatic hydrocarbon group with 6 to 8 carbons that may have substituents, more preferably an unsaturated chain hydrocarbon group with 2 to 5 carbons that may have substituents Or an aromatic hydrocarbon group having 6 to 7 carbon atoms that may have a substituent, particularly preferably a vinyl group that may have a substituent, a propenyl group that may have a substituent, a butenyl group that may have a substituent, or an acetylene group that may have a substituent group, a propynyl group which may have a substituent, a butynyl group which may have a substituent, or a phenyl group which may have a substituent. When the aliphatic unsaturated hydrocarbon group having 2 to 20 carbons represented by R ^x3 has a substituent, the substituent is preferably an aromatic hydrocarbon group having 6 to 10 carbons, more preferably a phenyl group.

In formula (Xb) or formula (XII), X ^x5 to X ^x12 are each independently preferably -R ^x5 or a halogen atom, more preferably a linear or branched alkyl group with 1 to 10 carbons, or a halogen atom, more preferably a branched chain alkyl group having 1 to 5 carbon atoms or a halogen atom, particularly preferably a tert-butyl group, a fluorine atom, a chlorine atom or a bromine atom. nx5-nx12 are each independently, for example, 0-2 or 4, preferably 0-2, more preferably 0-1, still more preferably 0.

The compound represented by formula (X0) is preferably a compound represented by formula (X0A) to formula (X0E).

[chemical 16]

[chemical 17]

[chemical 18]

[chemical 19]

[chemical 20]

The compound represented by formula (XI) is preferably a compound represented by formula (XIA) to formula (XIE).

[chem 21]

[chem 22]

[chem 23]

[chem 24]

[chem 25]

[In formula (XIA) to formula (XIE), R ^x1 , R ^x2 , Z ^x1 and Z ^x2 are the same as above]

Examples of the compound represented by formula (XIA) include compounds represented by formula (XIA-1) to formula (XIA-190) shown in Tables 1 to 4. Examples of the compound represented by formula (XIB) include compounds represented by formula (XIB-1) to formula (XIB-190) shown in Tables 5 to 8. Examples of the compound represented by formula (XIC) include compounds represented by formula (XIC-1) to formula (XIC-190) shown in Tables 9 to 12. Examples of the compound represented by the formula (XID) include compounds represented by the formula (XID-1) to the formula (XID-190) shown in Tables 13 to 16. Examples of the compound represented by formula (XIE) include compounds represented by formula (XIE-1) to formula (XIE-190) shown in Tables 17 to 20. Furthermore, the symbols described in the column "R ^x1 " and "R ^x2 " in Tables 1 to 3, Tables 5 to 7, Tables 9 to 11, Tables 13 to 15, and Tables 17 to 19 are respectively It corresponds to the groups represented by formula (xi-1) to formula (xi-22) and formula (xii-1). In addition, the symbols described in the "groups formed by R ^x1 and R ^x2 " in Table 4, Table 8, Table 12, Table 16, and Table 20 correspond to formula (xca-1) to formula (xca-2), respectively , the group represented by formula (xcb-1), formula (xcc-1). Furthermore, "the base formed by R ^x1 and R ^x2 " means that when R ^x2 is a single bond linking Z ^x2 and R ^x1 , it can be combined with *-Z ^x2 -P(=O)-Z ^x1 -* (* indicates a bond bond) in bond*bond's base. In formula (xca-1) to formula (xca-2), R ^x6 and R ^x7 independently represent a hydrogen atom or a hydrocarbon group with 1 to 20 carbon atoms that may have a substituent, and the carbon number of the substituent may be The hydrocarbon groups of 1 to 20 include the same ones as the hydrocarbon groups of 1 to 20 carbons which may have substituents represented by R ^b1 to R ^b3 , R ^x2 , R ^x4 , R ^{x5 ,} and R ^y1 to R ^y5 . R ^x6 and R ^x7 are each independently preferably a hydrogen atom or a linear or branched alkyl group having 1 to 10 carbons. * Indicates a bonded bond.

[chem 26]

[chem 27]

[chem 28]

[chem 29]

[Table 1] Z ^x1 Z ^x2 R ^x1 R ^x2 Z ^x1 Z ^x2 R ^x1 R ^x2 ( XIA-1 ) single bond single bond xi-1 xii-1 ( XIA-31 ) single bond single bond xi-8 xi-2 ( XIA-2 ) single bond single bond xi-2 xii-1 ( XIA-32 ) single bond single bond xi-9 xi-2 ( XIA-3 ) single bond single bond xi-3 xii-1 ( XIA-33 ) single bond single bond xi-10 xi-2 ( XIA-4 ) single bond single bond xi-4 xii-1 ( XIA-34 ) single bond single bond xi-11 xi-2 ( XIA-5 ) single bond single bond xi-5 xii-1 ( XIA-35 ) single bond single bond xi-12 xi-2 ( XIA-6 ) single bond single bond xi-6 xii-1 ( XIA-36 ) single bond single bond xi-3 xi-3 ( XIA-7 ) single bond single bond xi-7 xii-1 ( XIA-37 ) single bond single bond xi-4 xi-3 ( XIA-8 ) single bond single bond xi-8 xii-1 ( XIA-38 ) single bond single bond xi-5 xi-3 ( XIA-9 ) single bond single bond xi-9 xii-1 ( XIA-39 ) single bond single bond xi-6 xi-3 ( XIA-10 ) single bond single bond xi-10 xii-1 ( XIA-40 ) single bond single bond xi-7 xi-3 ( XIA-11 ) single bond single bond xi-11 xii-1 ( XIA-41 ) single bond single bond xi-8 xi-3 ( XIA-12 ) single bond single bond xi-12 xii-1 ( XIA-42 ) single bond single bond xi-9 xi-3 ( XIA-13 ) single bond single bond xi-1 xi-1 ( XIA-43 ) single bond single bond xi-10 xi-3 ( XIA-14 ) single bond single bond xi-2 xi-1 ( XIA-44 ) single bond single bond xi-11 xi-3 ( XIA-15 ) single bond single bond xi-3 xi-1 ( XIA-45 ) single bond single bond xi-12 xi-3 ( XIA-16 ) single bond single bond xi-4 xi-1 ( XIA-46 ) single bond single bond xi-4 xi-4 ( XIA-17 ) single bond single bond xi-5 xi-1 ( XIA-47 ) single bond single bond xi-5 xi-4 ( XIA-18 ) single bond single bond xi-6 xi-1 ( XIA-48 ) single bond single bond xi-6 xi-4 ( XIA-19 ) single bond single bond xi-7 xi-1 ( XIA-49 ) single bond single bond xi-7 xi-4 ( XIA-20 ) single bond single bond xi-8 xi-1 ( XIA-50 ) single bond single bond xi-8 xi-4 ( XIA-21 ) single bond single bond xi-9 xi-1 ( XIA-51 ) single bond single bond xi-9 xi-4 ( XIA-22 ) single bond single bond xi-10 xi-1 ( XIA-52 ) single bond single bond xi-10 xi-4 ( XIA-23 ) single bond single bond xi-11 xi-1 ( XIA-53 ) single bond single bond xi-11 xi-4 ( XIA-24 ) single bond single bond xi-12 xi-1 ( XIA-54 ) single bond single bond xi-12 xi-4 ( XIA-25 ) single bond single bond xi-2 xi-2 ( XIA-55 ) single bond single bond xi-5 xi-5 ( XIA-26 ) single bond single bond xi-3 xi-2 ( XIA-56 ) single bond single bond xi-6 xi-5 ( XIA-27 ) single bond single bond xi-4 xi-2 ( XIA-57 ) single bond single bond xi-7 xi-5 ( XIA-28 ) single bond single bond xi-5 xi-2 ( XIA-58 ) single bond single bond xi-8 xi-5 ( XIA-29 ) single bond single bond xi-6 xi-2 ( XIA-59 ) single bond single bond xi-9 xi-5 ( XIA-30 ) single bond single bond xi-7 xi-2 ( XIA-60 ) single bond single bond xi-10 xi-5

[Table 2] Z ^x1 Z ^x2 R ^x1 R ^x2 Z ^x1 Z ^x2 R ^x1 R ^x2 ( XIA-61 ) single bond single bond xi-11 xi-5 ( XIA-91 ) Oxygen atom Oxygen atom xi-1 xii-1 ( XIA-62 ) single bond single bond xi-12 xi-5 ( XIA-92 ) Oxygen atom Oxygen atom xi-2 xii-1 ( XIA-63 ) single bond single bond xi-6 xi-6 ( XIA-93 ) Oxygen atom Oxygen atom xi-3 xii-1 ( XIA-64 ) single bond single bond xi-7 xi-6 ( XIA-94 ) Oxygen atom Oxygen atom xi-4 xii-1 ( XIA-65 ) single bond single bond xi-8 xi-6 ( XIA-95 ) Oxygen atom Oxygen atom xi-5 xii-1 ( XIA-66 ) single bond single bond xi-9 xi-6 ( XIA-96 ) Oxygen atom Oxygen atom xi-6 xii-1 ( XIA-67 ) single bond single bond xi-10 xi-6 ( XIA-97 ) Oxygen atom Oxygen atom xi-7 xii-1 ( XIA-68 ) single bond single bond xi-11 xi-6 ( XIA-98 ) Oxygen atom Oxygen atom xi-8 xii-1 ( XIA-69 ) single bond single bond xi-12 xi-6 ( XIA-99 ) Oxygen atom Oxygen atom xi-9 xii-1 ( XIA-70 ) single bond single bond xi-7 xi-7 ( XIA-100 ) Oxygen atom Oxygen atom xi-10 xii-1 ( XIA-71 ) single bond single bond xi-8 xi-7 ( XIA-101 ) Oxygen atom Oxygen atom xi-11 xii-1 ( XIA-72 ) single bond single bond xi-9 xi-7 ( XIA-102 ) Oxygen atom Oxygen atom xi-12 xii-1 ( XIA-73 ) single bond single bond xi-10 xi-7 ( XIA-103 ) Oxygen atom Oxygen atom xi-1 xi-1 ( XIA-74 ) single bond single bond xi-11 xi-7 ( XIA-104 ) Oxygen atom Oxygen atom xi-2 xi-1 ( XIA-75 ) single bond single bond xi-12 xi-7 ( XIA-105 ) Oxygen atom Oxygen atom xi-3 xi-1 ( XIA-76 ) single bond single bond xi-8 xi-8 ( XIA-106 ) Oxygen atom Oxygen atom xi-4 xi-1 ( XIA-77 ) single bond single bond xi-9 xi-8 ( XIA-107 ) Oxygen atom Oxygen atom xi-5 xi-1 ( XIA-78 ) single bond single bond xi-10 xi-8 ( XIA-108 ) Oxygen atom Oxygen atom xi-6 xi-1 ( XIA-79 ) single bond single bond xi-11 xi-8 ( XIA-109 ) Oxygen atom Oxygen atom xi-7 xi-1 ( XIA-80 ) single bond single bond xi-12 xi-8 ( XIA-110 ) Oxygen atom Oxygen atom xi-8 xi-1 ( XIA-81 ) single bond single bond xi-9 xi-9 ( XIA-111 ) Oxygen atom Oxygen atom xi-9 xi-1 ( XIA-82 ) single bond single bond xi-10 xi-9 ( XIA-112 ) Oxygen atom Oxygen atom xi-10 xi-1 ( XIA-83 ) single bond single bond xi-11 xi-9 ( XIA-113 ) Oxygen atom Oxygen atom xi-11 xi-1 ( XIA-84 ) single bond single bond xi-12 xi-9 ( XIA-114 ) Oxygen atom Oxygen atom xi-12 xi-1 ( XIA-85 ) single bond single bond xi-10 xi-10 ( XIA-115 ) Oxygen atom Oxygen atom xi-2 xi-2 ( XIA-86 ) single bond single bond xi-11 xi-10 ( XIA-116 ) Oxygen atom Oxygen atom xi-3 xi-2 ( XIA-87 ) single bond single bond xi-12 xi-10 ( XIA-117 ) Oxygen atom Oxygen atom xi-4 xi-2 ( XIA-88 ) single bond single bond xi-11 xi-11 ( XIA-118 ) Oxygen atom Oxygen atom xi-5 xi-2 ( XIA-89 ) single bond single bond xi-12 xi-11 ( XIA-119 ) Oxygen atom Oxygen atom xi-6 xi-2 ( XIA-90 ) single bond single bond xi-12 xi-12 ( XIA-120 ) Oxygen atom Oxygen atom xi-7 xi-2

[table 3] Z ^x1 Z ^x2 R ^x1 R ^x2 Z ^x1 Z ^x2 R ^x1 R ^x2 ( XIA-121 ) Oxygen atom Oxygen atom xi-8 xi-2 ( XIA-151 ) Oxygen atom Oxygen atom xi-11 xi-5 ( XIA-122 ) Oxygen atom Oxygen atom xi-9 xi-2 ( XIA-152 ) Oxygen atom Oxygen atom xi-12 xi-5 ( XIA-123 ) Oxygen atom Oxygen atom xi-10 xi-2 ( XIA-153 ) Oxygen atom Oxygen atom xi-6 xi-6 ( XIA-124 ) Oxygen atom Oxygen atom xi-11 xi-2 ( XIA-154 ) Oxygen atom Oxygen atom xi-7 xi-6 ( XIA-125 ) Oxygen atom Oxygen atom xi-12 xi-2 ( XIA-155 ) Oxygen atom Oxygen atom xi-8 xi-6 ( XIA-126 ) Oxygen atom Oxygen atom xi-3 xi-3 ( XIA-156 ) Oxygen atom Oxygen atom xi-9 xi-6 ( XIA-127 ) Oxygen atom Oxygen atom xi-4 xi-3 ( XIA-157 ) Oxygen atom Oxygen atom xi-10 xi-6 ( XIA-128 ) Oxygen atom Oxygen atom xi-5 xi-3 ( XIA-158 ) Oxygen atom Oxygen atom xi-11 xi-6 ( XIA-129 ) Oxygen atom Oxygen atom xi-6 xi-3 ( XIA-159 ) Oxygen atom Oxygen atom xi-12 xi-6 ( XIA-130 ) Oxygen atom Oxygen atom xi-7 xi-3 ( XIA-160 ) Oxygen atom Oxygen atom xi-7 xi-7 ( XIA-131 ) Oxygen atom Oxygen atom xi-8 xi-3 ( XIA-161 ) Oxygen atom Oxygen atom xi-8 xi-7 ( XIA-132 ) Oxygen atom Oxygen atom xi-9 xi-3 ( XIA-162 ) Oxygen atom Oxygen atom xi-9 xi-7 ( XIA-133 ) Oxygen atom Oxygen atom xi-10 xi-3 ( XIA-163 ) Oxygen atom Oxygen atom xi-10 xi-7 ( XIA-134 ) Oxygen atom Oxygen atom xi-11 xi-3 ( XIA-164 ) Oxygen atom Oxygen atom xi-11 xi-7 ( XIA-135 ) Oxygen atom Oxygen atom xi-12 xi-3 ( XIA-165 ) Oxygen atom Oxygen atom xi-12 xi-7 ( XIA-136 ) Oxygen atom Oxygen atom xi-4 xi-4 ( XIA-166 ) Oxygen atom Oxygen atom xi-8 xi-8 ( XIA-137 ) Oxygen atom Oxygen atom xi-5 xi-4 ( XIA-167 ) Oxygen atom Oxygen atom xi-9 xi-8 ( XIA-138 ) Oxygen atom Oxygen atom xi-6 xi-4 ( XIA-168 ) Oxygen atom Oxygen atom xi-10 xi-8 ( XIA-139 ) Oxygen atom Oxygen atom xi-7 xi-4 ( XIA-169 ) Oxygen atom Oxygen atom xi-11 xi-8 ( XIA-140 ) Oxygen atom Oxygen atom xi-8 xi-4 ( XIA-170 ) Oxygen atom Oxygen atom xi-12 xi-8 ( XIA-141 ) Oxygen atom Oxygen atom xi-9 xi-4 ( XIA-171 ) Oxygen atom Oxygen atom xi-9 xi-9 ( XIA-142 ) Oxygen atom Oxygen atom xi-10 xi-4 ( XIA-172 ) Oxygen atom Oxygen atom xi-10 xi-9 ( XIA-143 ) Oxygen atom Oxygen atom xi-11 xi-4 ( XIA-173 ) Oxygen atom Oxygen atom xi-11 xi-9 ( XIA-144 ) Oxygen atom Oxygen atom xi-12 xi-4 ( XIA-174 ) Oxygen atom Oxygen atom xi-12 xi-9 ( XIA-145 ) Oxygen atom Oxygen atom xi-5 xi-5 ( XIA-175 ) Oxygen atom Oxygen atom xi-10 xi-10 ( XIA-146 ) Oxygen atom Oxygen atom xi-6 xi-5 ( XIA-176 ) Oxygen atom Oxygen atom xi-11 xi-10 ( XIA-147 ) Oxygen atom Oxygen atom xi-7 xi-5 ( XIA-177 ) Oxygen atom Oxygen atom xi-12 xi-10 ( XIA-148 ) Oxygen atom Oxygen atom xi-8 xi-5 ( XIA-178 ) Oxygen atom Oxygen atom xi-11 xi-11 ( XIA-149 ) Oxygen atom Oxygen atom xi-9 xi-5 ( XIA-179 ) Oxygen atom Oxygen atom xi-12 xi-11 ( XIA-150 ) Oxygen atom Oxygen atom xi-10 xi-5 ( XIA-180 ) Oxygen atom Oxygen atom xi-12 xi-12 ( XIA-181 ) single bond single bond xii-1 xii-1 ( XIA-182 ) Oxygen atom Oxygen atom xii-1 xii-1

[Table 4] Z ^x1 Z ^x2 The basis formed by R ^x1 and R ^x2 Z ^x1 Z ^x2 The basis formed by R ^x1 and R ^x2 R ^{x8 Rx9} ( XIA-183 ) Oxygen atom Oxygen atom xca-1 ( XIA-187 ) Oxygen atom Oxygen atom xcb-1 xcc-1 Oh ( XIA-184 ) Oxygen atom Oxygen atom xca-2 ( XIA-188 ) single bond single bond xcb-1 xcc-1 Oh ( XIA-185 ) single bond single bond xca-1 ( XIA-189 ) Oxygen atom Oxygen atom xcb-1 xcc-1 h ( XIA-186 ) single bond single bond xca-2 ( XIA-190 ) single bond single bond xcb-1 xcc-1 h

As a compound represented by formula (XIA), Preferably formula (XIA-1) ~ formula (XIA-12), formula (XIA-91) ~ formula (XIA-102), formula (XIA-103) ~ formula (XIA-108), formula (XIA-115 ) ~ formula (XIA-119), formula (XIA-126) ~ formula (XIA-129), formula (XIA-136) ~ formula (XIA-138), formula (XIA-145) ~ formula (XIA-146) , compounds represented by formula (XIA-153), formula (XIA-181) to formula (XIA-190), More preferably formula (XIA-1) ~ formula (XIA-12), formula (XIA-103) ~ formula (XIA-105), formula (XIA-115) ~ formula (XIA-116), formula (XIA-126 ), formula (XIA-136) ~ formula (XIA-138), formula (XIA-145) ~ formula (XIA-146), formula (XIA-153), formula (XIA-181) ~ formula (XIA-182) , compounds represented by formula (XIA-183) to formula (XIA-184), formula (XIA-187) to formula (XIA-188), Further preferred are formula (XIA-1), formula (XIA-10), formula (XIA-11), formula (XIA-12), formula (XIA-115), formula (XIA-126), formula (XIA-145 ), Formula (XIA-153), Formula (XIA-181), Formula (XIA-182), Formula (XIA-183), Formula (XIA-184), Formula (XIA-187) represented compounds, Still more preferable are compounds represented by formula (XIA-115), formula (XIA-126), and formula (XIA-182).

[table 5] Z ^x1 Z ^x2 R ^x1 R ^x2 Z ^x1 Z ^x2 R ^x1 R ^x2 ( XIB-1 ) single bond single bond xi-1 xii-1 ( XIB-31 ) single bond single bond xi-8 xi-2 ( XIB-2 ) single bond single bond xi-2 xii-1 ( XIB-32 ) single bond single bond xi-9 xi-2 ( XIB-3 ) single bond single bond xi-3 xii-1 ( XIB-33 ) single bond single bond xi-10 xi-2 ( XIB-4 ) single bond single bond xi-4 xii-1 ( XIB-34 ) single bond single bond xi-11 xi-2 ( XIB-5 ) single bond single bond xi-5 xii-1 ( XIB-35 ) single bond single bond xi-12 xi-2 ( XIB-6 ) single bond single bond xi-6 xii-1 ( XIB-36 ) single bond single bond xi-3 xi-3 ( XIB-7 ) single bond single bond xi-7 xii-1 ( XIB-37 ) single bond single bond xi-4 xi-3 ( XIB-8 ) single bond single bond xi-8 xii-1 ( XIB-38 ) single bond single bond xi-5 xi-3 ( XIB-9 ) single bond single bond xi-9 xii-1 ( XIB-39 ) single bond single bond xi-6 xi-3 ( XIB-10 ) single bond single bond xi-10 xii-1 ( XIB-40 ) single bond single bond xi-7 xi-3 ( XIB-11 ) single bond single bond xi-11 xii-1 ( XIB-41 ) single bond single bond xi-8 xi-3 ( XIB-12 ) single bond single bond xi-12 xii-1 ( XIB-42 ) single bond single bond xi-9 xi-3 ( XIB-13 ) single bond single bond xi-1 xi-1 ( XIB-43 ) single bond single bond xi-10 xi-3 ( XIB-14 ) single bond single bond xi-2 xi-1 ( XIB-44 ) single bond single bond xi-11 xi-3 ( XIB-15 ) single bond single bond xi-3 xi-1 ( XIB-45 ) single bond single bond xi-12 xi-3 ( XIB-16 ) single bond single bond xi-4 xi-1 ( XIB-46 ) single bond single bond xi-4 xi-4 ( XIB-17 ) single bond single bond xi-5 xi-1 ( XIB-47 ) single bond single bond xi-5 xi-4 ( XIB-18 ) single bond single bond xi-6 xi-1 ( XIB-48 ) single bond single bond xi-6 xi-4 ( XIB-19 ) single bond single bond xi-7 xi-1 ( XIB-49 ) single bond single bond xi-7 xi-4 ( XIB-20 ) single bond single bond xi-8 xi-1 ( XIB-50 ) single bond single bond xi-8 xi-4 ( XIB-21 ) single bond single bond xi-9 xi-1 ( XIB-51 ) single bond single bond xi-9 xi-4 ( XIB-22 ) single bond single bond xi-10 xi-1 ( XIB-52 ) single bond single bond xi-10 xi-4 ( XIB-23 ) single bond single bond xi-11 xi-1 ( XIB-53 ) single bond single bond xi-11 xi-4 ( XIB-24 ) single bond single bond xi-12 xi-1 ( XIB-54 ) single bond single bond xi-12 xi-4 ( XIB-25 ) single bond single bond xi-2 xi-2 ( XIB-55 ) single bond single bond xi-5 xi-5 ( XIB-26 ) single bond single bond xi-3 xi-2 ( XIB-56 ) single bond single bond xi-6 xi-5 ( XIB-27 ) single bond single bond xi-4 xi-2 ( XIB-57 ) single bond single bond xi-7 xi-5 ( XIB-28 ) single bond single bond xi-5 xi-2 ( XIB-58 ) single bond single bond xi-8 xi-5 ( XIB-29 ) single bond single bond xi-6 xi-2 ( XIB-59 ) single bond single bond xi-9 xi-5 ( XIB-30 ) single bond single bond xi-7 xi-2 ( XIB-60 ) single bond single bond xi-10 xi-5

[Table 6] Z ^x1 Z ^x2 R ^x1 R ^x2 Z ^x1 Z ^x2 R ^x1 R ^x2 ( XIB-61 ) single bond single bond xi-11 xi-5 ( XIB-91 ) Oxygen atom Oxygen atom xi-1 xii-1 ( XIB-62 ) single bond single bond xi-12 xi-5 ( XIB-92 ) Oxygen atom Oxygen atom xi-2 xii-1 ( XIB-63 ) single bond single bond xi-6 xi-6 ( XIB-93 ) Oxygen atom Oxygen atom xi-3 xii-1 ( XIB-64 ) single bond single bond xi-7 xi-6 ( XIB-94 ) Oxygen atom Oxygen atom xi-4 xii-1 ( XIB-65 ) single bond single bond xi-8 xi-6 ( XIB-95 ) Oxygen atom Oxygen atom xi-5 xii-1 ( XIB-66 ) single bond single bond xi-9 xi-6 ( XIB-96 ) Oxygen atom Oxygen atom xi-6 xii-1 ( XIB-67 ) single bond single bond xi-10 xi-6 ( XIB-97 ) Oxygen atom Oxygen atom xi-7 xii-1 ( XIB-68 ) single bond single bond xi-11 xi-6 ( XIB-98 ) Oxygen atom Oxygen atom xi-8 xii-1 ( XIB-69 ) single bond single bond xi-12 xi-6 ( XIB-99 ) Oxygen atom Oxygen atom xi-9 xii-1 ( XIB-70 ) single bond single bond xi-7 xi-7 ( XIB-100 ) Oxygen atom Oxygen atom xi-10 xii-1 ( XIB-71 ) single bond single bond xi-8 xi-7 ( XIB-101 ) Oxygen atom Oxygen atom xi-11 xii-1 ( XIB-72 ) single bond single bond xi-9 xi-7 ( XIB-102 ) Oxygen atom Oxygen atom xi-12 xii-1 ( XIB-73 ) single bond single bond xi-10 xi-7 ( XIB-103 ) Oxygen atom Oxygen atom xi-1 xi-1 ( XIB-74 ) single bond single bond xi-11 xi-7 ( XIB-104 ) Oxygen atom Oxygen atom xi-2 xi-1 ( XIB-75 ) single bond single bond xi-12 xi-7 ( XIB-105 ) Oxygen atom Oxygen atom xi-3 xi-1 ( XIB-76 ) single bond single bond xi-8 xi-8 ( XIB-106 ) Oxygen atom Oxygen atom xi-4 xi-1 ( XIB-77 ) single bond single bond xi-9 xi-8 ( XIB-107 ) Oxygen atom Oxygen atom xi-5 xi-1 ( XIB-78 ) single bond single bond xi-10 xi-8 ( XIB-108 ) Oxygen atom Oxygen atom xi-6 xi-1 ( XIB-79 ) single bond single bond xi-11 xi-8 ( XIB-109 ) Oxygen atom Oxygen atom xi-7 xi-1 ( XIB-80 ) single bond single bond xi-12 xi-8 ( XIB-110 ) Oxygen atom Oxygen atom xi-8 xi-1 ( XIB-81 ) single bond single bond xi-9 xi-9 ( XIB-111 ) Oxygen atom Oxygen atom xi-9 xi-1 ( XIB-82 ) single bond single bond xi-10 xi-9 ( XIB-112 ) Oxygen atom Oxygen atom xi-10 xi-1 ( XIB-83 ) single bond single bond xi-11 xi-9 ( XIB-113 ) Oxygen atom Oxygen atom xi-11 xi-1 ( XIB-84 ) single bond single bond xi-12 xi-9 ( XIB-114 ) Oxygen atom Oxygen atom xi-12 xi-1 ( XIB-85 ) single bond single bond xi-10 xi-10 ( XIB-115 ) Oxygen atom Oxygen atom xi-2 xi-2 ( XIB-86 ) single bond single bond xi-11 xi-10 ( XIB-116 ) Oxygen atom Oxygen atom xi-3 xi-2 ( XIB-87 ) single bond single bond xi-12 xi-10 ( XIB-117 ) Oxygen atom Oxygen atom xi-4 xi-2 ( XIB-88 ) single bond single bond xi-11 xi-11 ( XIB-118 ) Oxygen atom Oxygen atom xi-5 xi-2 ( XIB-89 ) single bond single bond xi-12 xi-11 ( XIB-119 ) Oxygen atom Oxygen atom xi-6 xi-2 ( XIB-90 ) single bond single bond xi-12 xi-12 ( XIB-120 ) Oxygen atom Oxygen atom xi-7 xi-2

[Table 7] Z ^x1 Z ^x2 R ^x1 R ^x2 Z ^x1 Z ^x2 R ^x1 R ^x2 ( XIB-121 ) Oxygen atom Oxygen atom xi-8 xi-2 ( XIB-151 ) Oxygen atom Oxygen atom xi-11 xi-5 ( XIB-122 ) Oxygen atom Oxygen atom xi-9 xi-2 ( XIB-152 ) Oxygen atom Oxygen atom xi-12 xi-5 ( XIB-123 ) Oxygen atom Oxygen atom xi-10 xi-2 ( XIB-153 ) Oxygen atom Oxygen atom xi-6 xi-6 ( XIB-124 ) Oxygen atom Oxygen atom xi-11 xi-2 ( XIB-154 ) Oxygen atom Oxygen atom xi-7 xi-6 ( XIB-125 ) Oxygen atom Oxygen atom xi-12 xi-2 ( XIB-155 ) Oxygen atom Oxygen atom xi-8 xi-6 ( XIB-126 ) Oxygen atom Oxygen atom xi-3 xi-3 ( XIB-156 ) Oxygen atom Oxygen atom xi-9 xi-6 ( XIB-127 ) Oxygen atom Oxygen atom xi-4 xi-3 ( XIB-157 ) Oxygen atom Oxygen atom xi-10 xi-6 ( XIB-128 ) Oxygen atom Oxygen atom xi-5 xi-3 ( XIB-158 ) Oxygen atom Oxygen atom xi-11 xi-6 ( XIB-129 ) Oxygen atom Oxygen atom xi-6 xi-3 ( XIB-159 ) Oxygen atom Oxygen atom xi-12 xi-6 ( XIB-130 ) Oxygen atom Oxygen atom xi-7 xi-3 ( XIB-160 ) Oxygen atom Oxygen atom xi-7 xi-7 ( XIB-131 ) Oxygen atom Oxygen atom xi-8 xi-3 ( XIB-161 ) Oxygen atom Oxygen atom xi-8 xi-7 ( XIB-132 ) Oxygen atom Oxygen atom xi-9 xi-3 ( XIB-162 ) Oxygen atom Oxygen atom xi-9 xi-7 ( XIB-133 ) Oxygen atom Oxygen atom xi-10 xi-3 ( XIB-163 ) Oxygen atom Oxygen atom xi-10 xi-7 ( XIB-134 ) Oxygen atom Oxygen atom xi-11 xi-3 ( XIB-164 ) Oxygen atom Oxygen atom xi-11 xi-7 ( XIB-135 ) Oxygen atom Oxygen atom xi-12 xi-3 ( XIB-165 ) Oxygen atom Oxygen atom xi-12 xi-7 ( XIB-136 ) Oxygen atom Oxygen atom xi-4 xi-4 ( XIB-166 ) Oxygen atom Oxygen atom xi-8 xi-8 ( XIB-137 ) Oxygen atom Oxygen atom xi-5 xi-4 ( XIB-167 ) Oxygen atom Oxygen atom xi-9 xi-8 ( XIB-138 ) Oxygen atom Oxygen atom xi-6 xi-4 ( XIB-168 ) Oxygen atom Oxygen atom xi-10 xi-8 ( XIB-139 ) Oxygen atom Oxygen atom xi-7 xi-4 ( XIB-169 ) Oxygen atom Oxygen atom xi-11 xi-8 ( XIB-140 ) Oxygen atom Oxygen atom xi-8 xi-4 ( XIB-170 ) Oxygen atom Oxygen atom xi-12 xi-8 ( XIB-141 ) Oxygen atom Oxygen atom xi-9 xi-4 ( XIB-171 ) Oxygen atom Oxygen atom xi-9 xi-9 ( XIB-142 ) Oxygen atom Oxygen atom xi-10 xi-4 ( XIB-172 ) Oxygen atom Oxygen atom xi-10 xi-9 ( XIB-143 ) Oxygen atom Oxygen atom xi-11 xi-4 ( XIB-173 ) Oxygen atom Oxygen atom xi-11 xi-9 ( XIB-144 ) Oxygen atom Oxygen atom xi-12 xi-4 ( XIB-174 ) Oxygen atom Oxygen atom xi-12 xi-9 ( XIB-145 ) Oxygen atom Oxygen atom xi-5 xi-5 ( XIB-175 ) Oxygen atom Oxygen atom xi-10 xi-10 ( XIB-146 ) Oxygen atom Oxygen atom xi-6 xi-5 ( XIB-176 ) Oxygen atom Oxygen atom xi-11 xi-10 ( XIB-147 ) Oxygen atom Oxygen atom xi-7 xi-5 ( XIB-177 ) Oxygen atom Oxygen atom xi-12 xi-10 ( XIB-148 ) Oxygen atom Oxygen atom xi-8 xi-5 ( XIB-178 ) Oxygen atom Oxygen atom xi-11 xi-11 ( XIB-149 ) Oxygen atom Oxygen atom xi-9 xi-5 ( XIB-179 ) Oxygen atom Oxygen atom xi-12 xi-11 ( XIB-150 ) Oxygen atom Oxygen atom xi-10 xi-5 ( XIB-180 ) Oxygen atom Oxygen atom xi-12 xi-12 ( XIB-181 ) single bond single bond xii-1 xii-1 ( XIB-182 ) Oxygen atom Oxygen atom xii-1 xii-1

[Table 8] Z ^x1 Z ^x2 The basis formed by R ^x1 and R ^x2 Z ^x1 Z ^x2 The basis formed by R ^x1 and R ^x2 R ^{x8 Rx9} ( XIB-183 ) Oxygen atom Oxygen atom xca-1 ( XIB-187 ) Oxygen atom Oxygen atom xcb-1 xcc-1 Oh ( XIB-184 ) Oxygen atom Oxygen atom xca-2 ( XIB-188 ) single bond single bond xcb-1 xcc-1 Oh ( XIB-185 ) single bond single bond xca-1 ( XIB-189 ) Oxygen atom Oxygen atom xcb-1 xcc-1 h ( XIB-186 ) single bond single bond xca-2 ( XIB-190 ) single bond single bond xcb-1 xcc-1 h

As a compound represented by formula (XIB), Preferably formula (XIB-1) ~ formula (XIB-12), formula (XIB-91) ~ formula (XIB-102), formula (XIB-103) ~ formula (XIB-108), formula (XIB-115 ) ~ formula (XIB-119), formula (XIB-126) ~ formula (XIB-129), formula (XIB-136) ~ formula (XIB-138), formula (XIB-145) ~ formula (XIB-146) , compounds represented by formula (XIB-153), formula (XIB-181) to formula (XIB-190), More preferably, it is a compound represented by formula (XIB-1) to formula (XIB-12), More preferably, it is a compound represented by formula (XIB-1).

[Table 9] Z ^x1 Z ^x2 R ^x1 R ^x2 Z ^x1 Z ^x2 R ^x1 R ^x2 ( XIC-1 ) single bond single bond xi-1 xii-1 ( XIC-31 ) single bond single bond xi-8 xi-2 ( XIC-2 ) single bond single bond xi-2 xii-1 ( XIC-32 ) single bond single bond xi-9 xi-2 ( XIC-3 ) single bond single bond xi-3 xii-1 ( XIC-33 ) single bond single bond xi-10 xi-2 ( XIC-4 ) single bond single bond xi-4 xii-1 ( XIC-34 ) single bond single bond xi-11 xi-2 ( XIC-5 ) single bond single bond xi-5 xii-1 ( XIC-35 ) single bond single bond xi-12 xi-2 ( XIC-6 ) single bond single bond xi-6 xii-1 ( XIC-36 ) single bond single bond xi-3 xi-3 ( XIC-7 ) single bond single bond xi-7 xii-1 ( XIC-37 ) single bond single bond xi-4 xi-3 ( XIC-8 ) single bond single bond xi-8 xii-1 ( XIC-38 ) single bond single bond xi-5 xi-3 ( XIC-9 ) single bond single bond xi-9 xii-1 ( XIC-39 ) single bond single bond xi-6 xi-3 ( XIC-10 ) single bond single bond xi-10 xii-1 ( XIC-40 ) single bond single bond xi-7 xi-3 ( XIC-11 ) single bond single bond xi-11 xii-1 ( XIC-41 ) single bond single bond xi-8 xi-3 ( XIC-12 ) single bond single bond xi-12 xii-1 ( XIC-42 ) single bond single bond xi-9 xi-3 ( XIC-13 ) single bond single bond xi-1 xi-1 ( XIC-43 ) single bond single bond xi-10 xi-3 ( XIC-14 ) single bond single bond xi-2 xi-1 ( XIC-44 ) single bond single bond xi-11 xi-3 ( XIC-15 ) single bond single bond xi-3 xi-1 ( XIC-45 ) single bond single bond xi-12 xi-3 ( XIC-16 ) single bond single bond xi-4 xi-1 ( XIC-46 ) single bond single bond xi-4 xi-4 ( XIC-17 ) single bond single bond xi-5 xi-1 ( XIC-47 ) single bond single bond xi-5 xi-4 ( XIC-18 ) single bond single bond xi-6 xi-1 ( XIC-48 ) single bond single bond xi-6 xi-4 ( XIC-19 ) single bond single bond xi-7 xi-1 ( XIC-49 ) single bond single bond xi-7 xi-4 ( XIC-20 ) single bond single bond xi-8 xi-1 ( XIC-50 ) single bond single bond xi-8 xi-4 ( XIC-21 ) single bond single bond xi-9 xi-1 ( XIC-51 ) single bond single bond xi-9 xi-4 ( XIC-22 ) single bond single bond xi-10 xi-1 ( XIC-52 ) single bond single bond xi-10 xi-4 ( XIC-23 ) single bond single bond xi-11 xi-1 ( XIC-53 ) single bond single bond xi-11 xi-4 ( XIC-24 ) single bond single bond xi-12 xi-1 ( XIC-54 ) single bond single bond xi-12 xi-4 ( XIC-25 ) single bond single bond xi-2 xi-2 ( XIC-55 ) single bond single bond xi-5 xi-5 ( XIC-26 ) single bond single bond xi-3 xi-2 ( XIC-56 ) single bond single bond xi-6 xi-5 ( XIC-27 ) single bond single bond xi-4 xi-2 ( XIC-57 ) single bond single bond xi-7 xi-5 ( XIC-28 ) single bond single bond xi-5 xi-2 ( XIC-58 ) single bond single bond xi-8 xi-5 ( XIC-29 ) single bond single bond xi-6 xi-2 ( XIC-59 ) single bond single bond xi-9 xi-5 ( XIC-30 ) single bond single bond xi-7 xi-2 ( XIC-60 ) single bond single bond xi-10 xi-5

[Table 10] Z ^x1 Z ^x2 R ^x1 R ^x2 Z ^x1 Z ^x2 R ^x1 R ^x2 ( XIC-61 ) single bond single bond xi-11 xi-5 ( XIC-91 ) Oxygen atom Oxygen atom xi-1 xii-1 ( XIC-62 ) single bond single bond xi-12 xi-5 ( XIC-92 ) Oxygen atom Oxygen atom xi-2 xii-1 ( XIC-63 ) single bond single bond xi-6 xi-6 ( XIC-93 ) Oxygen atom Oxygen atom xi-3 xii-1 ( XIC-64 ) single bond single bond xi-7 xi-6 ( XIC-94 ) Oxygen atom Oxygen atom xi-4 xii-1 ( XIC-65 ) single bond single bond xi-8 xi-6 ( XIC-95 ) Oxygen atom Oxygen atom xi-5 xii-1 ( XIC-66 ) single bond single bond xi-9 xi-6 ( XIC-96 ) Oxygen atom Oxygen atom xi-6 xii-1 ( XIC-67 ) single bond single bond xi-10 xi-6 ( XIC-97 ) Oxygen atom Oxygen atom xi-7 xii-1 ( XIC-68 ) single bond single bond xi-11 xi-6 ( XIC-98 ) Oxygen atom Oxygen atom xi-8 xii-1 ( XIC-69 ) single bond single bond xi-12 xi-6 ( XIC-99 ) Oxygen atom Oxygen atom xi-9 xii-1 ( XIC-70 ) single bond single bond xi-7 xi-7 ( XIC-100 ) Oxygen atom Oxygen atom xi-10 xii-1 ( XIC-71 ) single bond single bond xi-8 xi-7 ( XIC-101 ) Oxygen atom Oxygen atom xi-11 xii-1 ( XIC-72 ) single bond single bond xi-9 xi-7 ( XIC-102 ) Oxygen atom Oxygen atom xi-12 xii-1 ( XIC-73 ) single bond single bond xi-10 xi-7 ( XIC-103 ) Oxygen atom Oxygen atom xi-1 xi-1 ( XIC-74 ) single bond single bond xi-11 xi-7 ( XIC-104 ) Oxygen atom Oxygen atom xi-2 xi-1 ( XIC-75 ) single bond single bond xi-12 xi-7 ( XIC-105 ) Oxygen atom Oxygen atom xi-3 xi-1 ( XIC-76 ) single bond single bond xi-8 xi-8 ( XIC-106 ) Oxygen atom Oxygen atom xi-4 xi-1 ( XIC-77 ) single bond single bond xi-9 xi-8 ( XIC-107 ) Oxygen atom Oxygen atom xi-5 xi-1 ( XIC-78 ) single bond single bond xi-10 xi-8 ( XIC-108 ) Oxygen atom Oxygen atom xi-6 xi-1 ( XIC-79 ) single bond single bond xi-11 xi-8 ( XIC-109 ) Oxygen atom Oxygen atom xi-7 xi-1 ( XIC-80 ) single bond single bond xi-12 xi-8 ( XIC-110 ) Oxygen atom Oxygen atom xi-8 xi-1 ( XIC-81 ) single bond single bond xi-9 xi-9 ( XIC-111 ) Oxygen atom Oxygen atom xi-9 xi-1 ( XIC-82 ) single bond single bond xi-10 xi-9 ( XIC-112 ) Oxygen atom Oxygen atom xi-10 xi-1 ( XIC-83 ) single bond single bond xi-11 xi-9 ( XIC-113 ) Oxygen atom Oxygen atom xi-11 xi-1 ( XIC-84 ) single bond single bond xi-12 xi-9 ( XIC-114 ) Oxygen atom Oxygen atom xi-12 xi-1 ( XIC-85 ) single bond single bond xi-10 xi-10 ( XIC-115 ) Oxygen atom Oxygen atom xi-2 xi-2 ( XIC-86 ) single bond single bond xi-11 xi-10 ( XIC-116 ) Oxygen atom Oxygen atom xi-3 xi-2 ( XIC-87 ) single bond single bond xi-12 xi-10 ( XIC-117 ) Oxygen atom Oxygen atom xi-4 xi-2 ( XIC-88 ) single bond single bond xi-11 xi-11 ( XIC-118 ) Oxygen atom Oxygen atom xi-5 xi-2 ( XIC-89 ) single bond single bond xi-12 xi-11 ( XIC-119 ) Oxygen atom Oxygen atom xi-6 xi-2 ( XIC-90 ) single bond single bond xi-12 xi-12 ( XIC-120 ) Oxygen atom Oxygen atom xi-7 xi-2

[Table 11] Z ^x1 Z ^x2 R ^x1 R ^x2 Z ^x1 Z ^x2 R ^x1 R ^x2 ( XIC-121 ) Oxygen atom Oxygen atom xi-8 xi-2 ( XIC-151 ) Oxygen atom Oxygen atom xi-11 xi-5 ( XIC-122 ) Oxygen atom Oxygen atom xi-9 xi-2 ( XIC-152 ) Oxygen atom Oxygen atom xi-12 xi-5 ( XIC-123 ) Oxygen atom Oxygen atom xi-10 xi-2 ( XIC-153 ) Oxygen atom Oxygen atom xi-6 xi-6 ( XIC-124 ) Oxygen atom Oxygen atom xi-11 xi-2 ( XIC-154 ) Oxygen atom Oxygen atom xi-7 xi-6 ( XIC-125 ) Oxygen atom Oxygen atom xi-12 xi-2 ( XIC-155 ) Oxygen atom Oxygen atom xi-8 xi-6 ( XIC-126 ) Oxygen atom Oxygen atom xi-3 xi-3 ( XIC-156 ) Oxygen atom Oxygen atom xi-9 xi-6 ( XIC-127 ) Oxygen atom Oxygen atom xi-4 xi-3 ( XIC-157 ) Oxygen atom Oxygen atom xi-10 xi-6 ( XIC-128 ) Oxygen atom Oxygen atom xi-5 xi-3 ( XIC-158 ) Oxygen atom Oxygen atom xi-11 xi-6 ( XIC-129 ) Oxygen atom Oxygen atom xi-6 xi-3 ( XIC-159 ) Oxygen atom Oxygen atom xi-12 xi-6 ( XIC-130 ) Oxygen atom Oxygen atom xi-7 xi-3 ( XIC-160 ) Oxygen atom Oxygen atom xi-7 xi-7 ( XIC-131 ) Oxygen atom Oxygen atom xi-8 xi-3 ( XIC-161 ) Oxygen atom Oxygen atom xi-8 xi-7 ( XIC-132 ) Oxygen atom Oxygen atom xi-9 xi-3 ( XIC-162 ) Oxygen atom Oxygen atom xi-9 xi-7 ( XIC-133 ) Oxygen atom Oxygen atom xi-10 xi-3 ( XIC-163 ) Oxygen atom Oxygen atom xi-10 xi-7 ( XIC-134 ) Oxygen atom Oxygen atom xi-11 xi-3 ( XIC-164 ) Oxygen atom Oxygen atom xi-11 xi-7 ( XIC-135 ) Oxygen atom Oxygen atom xi-12 xi-3 ( XIC-165 ) Oxygen atom Oxygen atom xi-12 xi-7 ( XIC-136 ) Oxygen atom Oxygen atom xi-4 xi-4 ( XIC-166 ) Oxygen atom Oxygen atom xi-8 xi-8 ( XIC-137 ) Oxygen atom Oxygen atom xi-5 xi-4 ( XIC-167 ) Oxygen atom Oxygen atom xi-9 xi-8 ( XIC-138 ) Oxygen atom Oxygen atom xi-6 xi-4 ( XIC-168 ) Oxygen atom Oxygen atom xi-10 xi-8 ( XIC-139 ) Oxygen atom Oxygen atom xi-7 xi-4 ( XIC-169 ) Oxygen atom Oxygen atom xi-11 xi-8 ( XIC-140 ) Oxygen atom Oxygen atom xi-8 xi-4 ( XIC-170 ) Oxygen atom Oxygen atom xi-12 xi-8 ( XIC-141 ) Oxygen atom Oxygen atom xi-9 xi-4 ( XIC-171 ) Oxygen atom Oxygen atom xi-9 xi-9 ( XIC-142 ) Oxygen atom Oxygen atom xi-10 xi-4 ( XIC-172 ) Oxygen atom Oxygen atom xi-10 xi-9 ( XIC-143 ) Oxygen atom Oxygen atom xi-11 xi-4 ( XIC-173 ) Oxygen atom Oxygen atom xi-11 xi-9 ( XIC-144 ) Oxygen atom Oxygen atom xi-12 xi-4 ( XIC-174 ) Oxygen atom Oxygen atom xi-12 xi-9 ( XIC-145 ) Oxygen atom Oxygen atom xi-5 xi-5 ( XIC-175 ) Oxygen atom Oxygen atom xi-10 xi-10 ( XIC-146 ) Oxygen atom Oxygen atom xi-6 xi-5 ( XIC-176 ) Oxygen atom Oxygen atom xi-11 xi-10 ( XIC-147 ) Oxygen atom Oxygen atom xi-7 xi-5 ( XIC-177 ) Oxygen atom Oxygen atom xi-12 xi-10 ( XIC-148 ) Oxygen atom Oxygen atom xi-8 xi-5 ( XIC-178 ) Oxygen atom Oxygen atom xi-11 xi-11 ( XIC-149 ) Oxygen atom Oxygen atom xi-9 xi-5 ( XIC-179 ) Oxygen atom Oxygen atom xi-12 xi-11 ( XIC-150 ) Oxygen atom Oxygen atom xi-10 xi-5 ( XIC-180 ) Oxygen atom Oxygen atom xi-12 xi-12 ( XIC-181 ) single bond single bond xii-1 xii-1 ( XIC-182 ) Oxygen atom Oxygen atom xii-1 xii-1

[Table 12] Z ^x1 Z ^x2 The basis formed by R ^x1 and R ^x2 Z ^x1 Z ^x2 The basis formed by R ^x1 and R ^x2 R ^{x8 Rx9} ( XIC-183 ) Oxygen atom Oxygen atom xca-1 ( XIC-187 ) Oxygen atom Oxygen atom xcb-1 xcc-1 Oh ( XIC-184 ) Oxygen atom Oxygen atom xca-2 ( XIC-188 ) single bond single bond xcb-1 xcc-1 Oh ( XIC-185 ) single bond single bond xca-1 ( XIC-189 ) Oxygen atom Oxygen atom xcb-1 xcc-1 h ( XIC-186 ) single bond single bond xca-2 ( XIC-190 ) single bond single bond xcb-1 xcc-1 h

As a compound represented by formula (XIC), Preferably formula (XIC-1) ~ formula (XIC-12), formula (XIC-91) ~ formula (XIC-102), formula (XIC-103) ~ formula (XIC-108), formula (XIC-115 ) ~ formula (XIC-119), formula (XIC-126) ~ formula (XIC-129), formula (XIC-136) ~ formula (XIC-138), formula (XIC-145) ~ formula (XIC-146) , compounds represented by formula (XIC-153), formula (XIC-181) to formula (XIC-190), More preferably formula (XIC-1) ~ formula (XIC-12), formula (XIC-103) ~ formula (XIC-105), formula (XIC-115) ~ formula (XIC-116), formula (XIC-126 ) represented by the compound, Further preferred are compounds represented by formula (XIC-1) and formula (XIC-115).

[Table 13] Z ^x1 Z ^x2 R ^x1 R ^x2 Z ^x1 Z ^x2 R ^x1 R ^x2 ( XID-1 ) single bond single bond xi-1 xii-1 ( XID-31 ) single bond single bond xi-8 xi-2 ( XID-2 ) single bond single bond xi-2 xii-1 ( XID-32 ) single bond single bond xi-9 xi-2 ( XID-3 ) single bond single bond xi-3 xii-1 ( XID-33 ) single bond single bond xi-10 xi-2 ( XID-4 ) single bond single bond xi-4 xii-1 ( XID-34 ) single bond single bond xi-11 xi-2 ( XID-5 ) single bond single bond xi-5 xii-1 ( XID-35 ) single bond single bond xi-12 xi-2 ( XID-6 ) single bond single bond xi-6 xii-1 ( XID-36 ) single bond single bond xi-3 xi-3 ( XID-7 ) single bond single bond xi-7 xii-1 ( XID-37 ) single bond single bond xi-4 xi-3 ( XID-8 ) single bond single bond xi-8 xii-1 ( XID-38 ) single bond single bond xi-5 xi-3 ( XID-9 ) single bond single bond xi-9 xii-1 ( XID-39 ) single bond single bond xi-6 xi-3 ( XID-10 ) single bond single bond xi-10 xii-1 ( XID-40 ) single bond single bond xi-7 xi-3 ( XID-11 ) single bond single bond xi-11 xii-1 ( XID-41 ) single bond single bond xi-8 xi-3 ( XID-12 ) single bond single bond xi-12 xii-1 ( XID-42 ) single bond single bond xi-9 xi-3 ( XID-13 ) single bond single bond xi-1 xi-1 ( XID-43 ) single bond single bond xi-10 xi-3 ( XID-14 ) single bond single bond xi-2 xi-1 ( XID-44 ) single bond single bond xi-11 xi-3 ( XID-15 ) single bond single bond xi-3 xi-1 ( XID-45 ) single bond single bond xi-12 xi-3 ( XID-16 ) single bond single bond xi-4 xi-1 ( XID-46 ) single bond single bond xi-4 xi-4 ( XID-17 ) single bond single bond xi-5 xi-1 ( XID-47 ) single bond single bond xi-5 xi-4 ( XID-18 ) single bond single bond xi-6 xi-1 ( XID-48 ) single bond single bond xi-6 xi-4 ( XID-19 ) single bond single bond xi-7 xi-1 ( XID-49 ) single bond single bond xi-7 xi-4 ( XID-20 ) single bond single bond xi-8 xi-1 ( XID-50 ) single bond single bond xi-8 xi-4 ( XID-21 ) single bond single bond xi-9 xi-1 ( XID-51 ) single bond single bond xi-9 xi-4 ( XID-22 ) single bond single bond xi-10 xi-1 ( XID-52 ) single bond single bond xi-10 xi-4 ( XID-23 ) single bond single bond xi-11 xi-1 ( XID-53 ) single bond single bond xi-11 xi-4 ( XID-24 ) single bond single bond xi-12 xi-1 ( XID-54 ) single bond single bond xi-12 xi-4 ( XID-25 ) single bond single bond xi-2 xi-2 ( XID-55 ) single bond single bond xi-5 xi-5 ( XID-26 ) single bond single bond xi-3 xi-2 ( XID-56 ) single bond single bond xi-6 xi-5 ( XID-27 ) single bond single bond xi-4 xi-2 ( XID-57 ) single bond single bond xi-7 xi-5 ( XID-28 ) single bond single bond xi-5 xi-2 ( XID-58 ) single bond single bond xi-8 xi-5 ( XID-29 ) single bond single bond xi-6 xi-2 ( XID-59 ) single bond single bond xi-9 xi-5 ( XID-30 ) single bond single bond xi-7 xi-2 ( XID-60 ) single bond single bond xi-10 xi-5

[Table 14] Z ^x1 Z ^x2 R ^x1 R ^x2 Z ^x1 Z ^x2 R ^x1 R ^x2 ( XID-61 ) single bond single bond xi-11 xi-5 ( XID-91 ) Oxygen atom Oxygen atom xi-1 xii-1 ( XID-62 ) single bond single bond xi-12 xi-5 ( XID-92 ) Oxygen atom Oxygen atom xi-2 xii-1 ( XID-63 ) single bond single bond xi-6 xi-6 ( XID-93 ) Oxygen atom Oxygen atom xi-3 xii-1 ( XID-64 ) single bond single bond xi-7 xi-6 ( XID-94 ) Oxygen atom Oxygen atom xi-4 xii-1 ( XID-65 ) single bond single bond xi-8 xi-6 ( XID-95 ) Oxygen atom Oxygen atom xi-5 xii-1 ( XID-66 ) single bond single bond xi-9 xi-6 ( XID-96 ) Oxygen atom Oxygen atom xi-6 xii-1 ( XID-67 ) single bond single bond xi-10 xi-6 ( XID-97 ) Oxygen atom Oxygen atom xi-7 xii-1 ( XID-68 ) single bond single bond xi-11 xi-6 ( XID-98 ) Oxygen atom Oxygen atom xi-8 xii-1 ( XID-69 ) single bond single bond xi-12 xi-6 ( XID-99 ) Oxygen atom Oxygen atom xi-9 xii-1 ( XID-70 ) single bond single bond xi-7 xi-7 ( XID-100 ) Oxygen atom Oxygen atom xi-10 xii-1 ( XID-71 ) single bond single bond xi-8 xi-7 ( XID-101 ) Oxygen atom Oxygen atom xi-11 xii-1 ( XID-72 ) single bond single bond xi-9 xi-7 ( XID-102 ) Oxygen atom Oxygen atom xi-12 xii-1 ( XID-73 ) single bond single bond xi-10 xi-7 ( XID-103 ) Oxygen atom Oxygen atom xi-1 xi-1 ( XID-74 ) single bond single bond xi-11 xi-7 ( XID-104 ) Oxygen atom Oxygen atom xi-2 xi-1 ( XID-75 ) single bond single bond xi-12 xi-7 ( XID-105 ) Oxygen atom Oxygen atom xi-3 xi-1 ( XID-76 ) single bond single bond xi-8 xi-8 ( XID-106 ) Oxygen atom Oxygen atom xi-4 xi-1 ( XID-77 ) single bond single bond xi-9 xi-8 ( XID-107 ) Oxygen atom Oxygen atom xi-5 xi-1 ( XID-78 ) single bond single bond xi-10 xi-8 ( XID-108 ) Oxygen atom Oxygen atom xi-6 xi-1 ( XID-79 ) single bond single bond xi-11 xi-8 ( XID-109 ) Oxygen atom Oxygen atom xi-7 xi-1 ( XID-80 ) single bond single bond xi-12 xi-8 ( XID-110 ) Oxygen atom Oxygen atom xi-8 xi-1 ( XID-81 ) single bond single bond xi-9 xi-9 ( XID-111 ) Oxygen atom Oxygen atom xi-9 xi-1 ( XID-82 ) single bond single bond xi-10 xi-9 ( XID-112 ) Oxygen atom Oxygen atom xi-10 xi-1 ( XID-83 ) single bond single bond xi-11 xi-9 ( XID-113 ) Oxygen atom Oxygen atom xi-11 xi-1 ( XID-84 ) single bond single bond xi-12 xi-9 ( XID-114 ) Oxygen atom Oxygen atom xi-12 xi-1 ( XID-85 ) single bond single bond xi-10 xi-10 ( XID-115 ) Oxygen atom Oxygen atom xi-2 xi-2 ( XID-86 ) single bond single bond xi-11 xi-10 ( XID-116 ) Oxygen atom Oxygen atom xi-3 xi-2 ( XID-87 ) single bond single bond xi-12 xi-10 ( XID-117 ) Oxygen atom Oxygen atom xi-4 xi-2 ( XID-88 ) single bond single bond xi-11 xi-11 ( XID-118 ) Oxygen atom Oxygen atom xi-5 xi-2 ( XID-89 ) single bond single bond xi-12 xi-11 ( XID-119 ) Oxygen atom Oxygen atom xi-6 xi-2 ( XID-90 ) single bond single bond xi-12 xi-12 ( XID-120 ) Oxygen atom Oxygen atom xi-7 xi-2

[Table 15] Z ^x1 Z ^x2 R ^x1 R ^x2 Z ^x1 Z ^x2 R ^x1 R ^x2 ( XID-121 ) Oxygen atom Oxygen atom xi-8 xi-2 ( XID-151 ) Oxygen atom Oxygen atom xi-11 xi-5 ( XID-122 ) Oxygen atom Oxygen atom xi-9 xi-2 ( XID-152 ) Oxygen atom Oxygen atom xi-12 xi-5 ( XID-123 ) Oxygen atom Oxygen atom xi-10 xi-2 ( XID-153 ) Oxygen atom Oxygen atom xi-6 xi-6 ( XID-124 ) Oxygen atom Oxygen atom xi-11 xi-2 ( XID-154 ) Oxygen atom Oxygen atom xi-7 xi-6 ( XID-125 ) Oxygen atom Oxygen atom xi-12 xi-2 ( XID-155 ) Oxygen atom Oxygen atom xi-8 xi-6 ( XID-126 ) Oxygen atom Oxygen atom xi-3 xi-3 ( XID-156 ) Oxygen atom Oxygen atom xi-9 xi-6 ( XID-127 ) Oxygen atom Oxygen atom xi-4 xi-3 ( XID-157 ) Oxygen atom Oxygen atom xi-10 xi-6 ( XID-128 ) Oxygen atom Oxygen atom xi-5 xi-3 ( XID-158 ) Oxygen atom Oxygen atom xi-11 xi-6 ( XID-129 ) Oxygen atom Oxygen atom xi-6 xi-3 ( XID-159 ) Oxygen atom Oxygen atom xi-12 xi-6 ( XID-130 ) Oxygen atom Oxygen atom xi-7 xi-3 ( XID-160 ) Oxygen atom Oxygen atom xi-7 xi-7 ( XID-131 ) Oxygen atom Oxygen atom xi-8 xi-3 ( XID-161 ) Oxygen atom Oxygen atom xi-8 xi-7 ( XID-132 ) Oxygen atom Oxygen atom xi-9 xi-3 ( XID-162 ) Oxygen atom Oxygen atom xi-9 xi-7 ( XID-133 ) Oxygen atom Oxygen atom xi-10 xi-3 ( XID-163 ) Oxygen atom Oxygen atom xi-10 xi-7 ( XID-134 ) Oxygen atom Oxygen atom xi-11 xi-3 ( XID-164 ) Oxygen atom Oxygen atom xi-11 xi-7 ( XID-135 ) Oxygen atom Oxygen atom xi-12 xi-3 ( XID-165 ) Oxygen atom Oxygen atom xi-12 xi-7 ( XID-136 ) Oxygen atom Oxygen atom xi-4 xi-4 ( XID-166 ) Oxygen atom Oxygen atom xi-8 xi-8 ( XID-137 ) Oxygen atom Oxygen atom xi-5 xi-4 ( XID-167 ) Oxygen atom Oxygen atom xi-9 xi-8 ( XID-138 ) Oxygen atom Oxygen atom xi-6 xi-4 ( XID-168 ) Oxygen atom Oxygen atom xi-10 xi-8 ( XID-139 ) Oxygen atom Oxygen atom xi-7 xi-4 ( XID-169 ) Oxygen atom Oxygen atom xi-11 xi-8 ( XID-140 ) Oxygen atom Oxygen atom xi-8 xi-4 ( XID-170 ) Oxygen atom Oxygen atom xi-12 xi-8 ( XID-141 ) Oxygen atom Oxygen atom xi-9 xi-4 ( XID-171 ) Oxygen atom Oxygen atom xi-9 xi-9 ( XID-142 ) Oxygen atom Oxygen atom xi-10 xi-4 ( XID-172 ) Oxygen atom Oxygen atom xi-10 xi-9 ( XID-143 ) Oxygen atom Oxygen atom xi-11 xi-4 ( XID-173 ) Oxygen atom Oxygen atom xi-11 xi-9 ( XID-144 ) Oxygen atom Oxygen atom xi-12 xi-4 ( XID-174 ) Oxygen atom Oxygen atom xi-12 xi-9 ( XID-145 ) Oxygen atom Oxygen atom xi-5 xi-5 ( XID-175 ) Oxygen atom Oxygen atom xi-10 xi-10 ( XID-146 ) Oxygen atom Oxygen atom xi-6 xi-5 ( XID-176 ) Oxygen atom Oxygen atom xi-11 xi-10 ( XID-147 ) Oxygen atom Oxygen atom xi-7 xi-5 ( XID-177 ) Oxygen atom Oxygen atom xi-12 xi-10 ( XID-148 ) Oxygen atom Oxygen atom xi-8 xi-5 ( XID-178 ) Oxygen atom Oxygen atom xi-11 xi-11 ( XID-149 ) Oxygen atom Oxygen atom xi-9 xi-5 ( XID-179 ) Oxygen atom Oxygen atom xi-12 xi-11 ( XID-150 ) Oxygen atom Oxygen atom xi-10 xi-5 ( XID-180 ) Oxygen atom Oxygen atom xi-12 xi-12 ( XID-181 ) single bond single bond xii-1 xii-1 ( XID-182 ) Oxygen atom Oxygen atom xii-1 xii-1

[Table 16] Z ^x1 Z ^x2 The basis formed by R ^x1 and R ^x2 Z ^x1 Z ^x2 The basis formed by R ^x1 and R ^x2 R ^{x8 Rx9} ( XID-183 ) Oxygen atom Oxygen atom xca-1 ( XID-187 ) Oxygen atom Oxygen atom xcb-1 xcc-1 Oh ( XID-184 ) Oxygen atom Oxygen atom xca-2 ( XID-188 ) single bond single bond xcb-1 xcc-1 Oh ( XID-185 ) single bond single bond xca-1 ( XID-189 ) Oxygen atom Oxygen atom xcb-1 xcc-1 h ( XID-186 ) single bond single bond xca-2 ( XID-190 ) single bond single bond xcb-1 xcc-1 h

As a compound represented by formula (XID), Preferably formula (XID-1) ~ formula (XID-12), formula (XID-91) ~ formula (XID-102), formula (XID-103) ~ formula (XID-108), formula (XID-115 ) ~ formula (XID-119), formula (XID-126) ~ formula (XID-129), formula (XID-136) ~ formula (XID-138), formula (XID-145) ~ formula (XID-146) , compounds represented by formula (XID-153), formula (XID-181) ~ formula (XID-190), More preferably, it is a compound represented by formula (XID-1) to formula (XID-12), More preferably, it is a compound represented by formula (XID-1).

[Table 17] Z ^x1 Z ^x2 R ^x1 R ^x2 Z ^x1 Z ^x2 R ^x1 R ^x2 ( XIE-1 ) single bond single bond xi-1 xii-1 ( XIE-31 ) single bond single bond xi-8 xi-2 ( XIE-2 ) single bond single bond xi-2 xii-1 ( XIE-32 ) single bond single bond xi-9 xi-2 ( XIE-3 ) single bond single bond xi-3 xii-1 ( XIE-33 ) single bond single bond xi-10 xi-2 ( XIE-4 ) single bond single bond xi-4 xii-1 ( XIE-34 ) single bond single bond xi-11 xi-2 ( XIE-5 ) single bond single bond xi-5 xii-1 ( XIE-35 ) single bond single bond xi-12 xi-2 ( XIE-6 ) single bond single bond xi-6 xii-1 ( XIE-36 ) single bond single bond xi-3 xi-3 ( XIE-7 ) single bond single bond xi-7 xii-1 ( XIE-37 ) single bond single bond xi-4 xi-3 ( XIE-8 ) single bond single bond xi-8 xii-1 ( XIE-38 ) single bond single bond xi-5 xi-3 ( XIE-9 ) single bond single bond xi-9 xii-1 ( XIE-39 ) single bond single bond xi-6 xi-3 ( XIE-10 ) single bond single bond xi-10 xii-1 ( XIE-40 ) single bond single bond xi-7 xi-3 ( XIE-11 ) single bond single bond xi-11 xii-1 ( XIE-41 ) single bond single bond xi-8 xi-3 ( XIE-12 ) single bond single bond xi-12 xii-1 ( XIE-42 ) single bond single bond xi-9 xi-3 ( XIE-13 ) single bond single bond xi-1 xi-1 ( XIE-43 ) single bond single bond xi-10 xi-3 ( XIE-14 ) single bond single bond xi-2 xi-1 ( XIE-44 ) single bond single bond xi-11 xi-3 ( XIE-15 ) single bond single bond xi-3 xi-1 ( XIE-45 ) single bond single bond xi-12 xi-3 ( XIE-16 ) single bond single bond xi-4 xi-1 ( XIE-46 ) single bond single bond xi-4 xi-4 ( XIE-17 ) single bond single bond xi-5 xi-1 ( XIE-47 ) single bond single bond xi-5 xi-4 ( XIE-18 ) single bond single bond xi-6 xi-1 ( XIE-48 ) single bond single bond xi-6 xi-4 ( XIE-19 ) single bond single bond xi-7 xi-1 ( XIE-49 ) single bond single bond xi-7 xi-4 ( XIE-20 ) single bond single bond xi-8 xi-1 ( XIE-50 ) single bond single bond xi-8 xi-4 ( XIE-21 ) single bond single bond xi-9 xi-1 ( XIE-51 ) single bond single bond xi-9 xi-4 ( XIE-22 ) single bond single bond xi-10 xi-1 ( XIE-52 ) single bond single bond xi-10 xi-4 ( XIE-23 ) single bond single bond xi-11 xi-1 ( XIE-53 ) single bond single bond xi-11 xi-4 ( XIE-24 ) single bond single bond xi-12 xi-1 ( XIE-54 ) single bond single bond xi-12 xi-4 ( XIE-25 ) single bond single bond xi-2 xi-2 ( XIE-55 ) single bond single bond xi-5 xi-5 ( XIE-26 ) single bond single bond xi-3 xi-2 ( XIE-56 ) single bond single bond xi-6 xi-5 ( XIE-27 ) single bond single bond xi-4 xi-2 ( XIE-57 ) single bond single bond xi-7 xi-5 ( XIE-28 ) single bond single bond xi-5 xi-2 ( XIE-58 ) single bond single bond xi-8 xi-5 ( XIE-29 ) single bond single bond xi-6 xi-2 ( XIE-59 ) single bond single bond xi-9 xi-5 ( XIE-30 ) single bond single bond xi-7 xi-2 ( XIE-60 ) single bond single bond xi-10 xi-5

[Table 18] Z ^x1 Z ^x2 R ^x1 R ^x2 Z ^x1 Z ^x2 R ^x1 R ^x2 ( XIE-61 ) single bond single bond xi-11 xi-5 ( XIE-91 ) Oxygen atom Oxygen atom xi-1 xii-1 ( XIE-62 ) single bond single bond xi-12 xi-5 ( XIE-92 ) Oxygen atom Oxygen atom xi-2 xii-1 ( XIE-63 ) single bond single bond xi-6 xi-6 ( XIE-93 ) Oxygen atom Oxygen atom xi-3 xii-1 ( XIE-64 ) single bond single bond xi-7 xi-6 ( XIE-94 ) Oxygen atom Oxygen atom xi-4 xii-1 ( XIE-65 ) single bond single bond xi-8 xi-6 ( XIE-95 ) Oxygen atom Oxygen atom xi-5 xii-1 ( XIE-66 ) single bond single bond xi-9 xi-6 ( XIE-96 ) Oxygen atom Oxygen atom xi-6 xii-1 ( XIE-67 ) single bond single bond xi-10 xi-6 ( XIE-97 ) Oxygen atom Oxygen atom xi-7 xii-1 ( XIE-68 ) single bond single bond xi-11 xi-6 ( XIE-98 ) Oxygen atom Oxygen atom xi-8 xii-1 ( XIE-69 ) single bond single bond xi-12 xi-6 ( XIE-99 ) Oxygen atom Oxygen atom xi-9 xii-1 ( XIE-70 ) single bond single bond xi-7 xi-7 ( XIE-100 ) Oxygen atom Oxygen atom xi-10 xii-1 ( XIE-71 ) single bond single bond xi-8 xi-7 ( XIE-101 ) Oxygen atom Oxygen atom xi-11 xii-1 ( XIE-72 ) single bond single bond xi-9 xi-7 ( XIE-102 ) Oxygen atom Oxygen atom xi-12 xii-1 ( XIE-73 ) single bond single bond xi-10 xi-7 ( XIE-103 ) Oxygen atom Oxygen atom xi-1 xi-1 ( XIE-74 ) single bond single bond xi-11 xi-7 ( XIE-104 ) Oxygen atom Oxygen atom xi-2 xi-1 ( XIE-75 ) single bond single bond xi-12 xi-7 ( XIE-105 ) Oxygen atom Oxygen atom xi-3 xi-1 ( XIE-76 ) single bond single bond xi-8 xi-8 ( XIE-106 ) Oxygen atom Oxygen atom xi-4 xi-1 ( XIE-77 ) single bond single bond xi-9 xi-8 ( XIE-107 ) Oxygen atom Oxygen atom xi-5 xi-1 ( XIE-78 ) single bond single bond xi-10 xi-8 ( XIE-108 ) Oxygen atom Oxygen atom xi-6 xi-1 ( XIE-79 ) single bond single bond xi-11 xi-8 ( XIE-109 ) Oxygen atom Oxygen atom xi-7 xi-1 ( XIE-80 ) single bond single bond xi-12 xi-8 ( XIE-110 ) Oxygen atom Oxygen atom xi-8 xi-1 ( XIE-81 ) single bond single bond xi-9 xi-9 ( XIE-111 ) Oxygen atom Oxygen atom xi-9 xi-1 ( XIE-82 ) single bond single bond xi-10 xi-9 ( XIE-112 ) Oxygen atom Oxygen atom xi-10 xi-1 ( XIE-83 ) single bond single bond xi-11 xi-9 ( XIE-113 ) Oxygen atom Oxygen atom xi-11 xi-1 ( XIE-84 ) single bond single bond xi-12 xi-9 ( XIE-114 ) Oxygen atom Oxygen atom xi-12 xi-1 ( XIE-85 ) single bond single bond xi-10 xi-10 ( XIE-115 ) Oxygen atom Oxygen atom xi-2 xi-2 ( XIE-86 ) single bond single bond xi-11 xi-10 ( XIE-116 ) Oxygen atom Oxygen atom xi-3 xi-2 ( XIE-87 ) single bond single bond xi-12 xi-10 ( XIE-117 ) Oxygen atom Oxygen atom xi-4 xi-2 ( XIE-88 ) single bond single bond xi-11 xi-11 ( XIE-118 ) Oxygen atom Oxygen atom xi-5 xi-2 ( XIE-89 ) single bond single bond xi-12 xi-11 ( XIE-119 ) Oxygen atom Oxygen atom xi-6 xi-2 ( XIE-90 ) single bond single bond xi-12 xi-12 ( XIE-120 ) Oxygen atom Oxygen atom xi-7 xi-2

[Table 19] Z ^x1 Z ^x2 R ^x1 R ^x2 Z ^x1 Z ^x2 R ^x1 R ^x2 ( XIE-121 ) Oxygen atom Oxygen atom xi-8 xi-2 ( XIE-151 ) Oxygen atom Oxygen atom xi-11 xi-5 ( XIE-122 ) Oxygen atom Oxygen atom xi-9 xi-2 ( XIE-152 ) Oxygen atom Oxygen atom xi-12 xi-5 ( XIE-123 ) Oxygen atom Oxygen atom xi-10 xi-2 ( XIE-153 ) Oxygen atom Oxygen atom xi-6 xi-6 ( XIE-124 ) Oxygen atom Oxygen atom xi-11 xi-2 ( XIE-154 ) Oxygen atom Oxygen atom xi-7 xi-6 ( XIE-125 ) Oxygen atom Oxygen atom xi-12 xi-2 ( XIE-155 ) Oxygen atom Oxygen atom xi-8 xi-6 ( XIE-126 ) Oxygen atom Oxygen atom xi-3 xi-3 ( XIE-156 ) Oxygen atom Oxygen atom xi-9 xi-6 ( XIE-127 ) Oxygen atom Oxygen atom xi-4 xi-3 ( XIE-157 ) Oxygen atom Oxygen atom xi-10 xi-6 ( XIE-128 ) Oxygen atom Oxygen atom xi-5 xi-3 ( XIE-158 ) Oxygen atom Oxygen atom xi-11 xi-6 ( XIE-129 ) Oxygen atom Oxygen atom xi-6 xi-3 ( XIE-159 ) Oxygen atom Oxygen atom xi-12 xi-6 ( XIE-130 ) Oxygen atom Oxygen atom xi-7 xi-3 ( XIE-160 ) Oxygen atom Oxygen atom xi-7 xi-7 ( XIE-131 ) Oxygen atom Oxygen atom xi-8 xi-3 ( XIE-161 ) Oxygen atom Oxygen atom xi-8 xi-7 ( XIE-132 ) Oxygen atom Oxygen atom xi-9 xi-3 ( XIE-162 ) Oxygen atom Oxygen atom xi-9 xi-7 ( XIE-133 ) Oxygen atom Oxygen atom xi-10 xi-3 ( XIE-163 ) Oxygen atom Oxygen atom xi-10 xi-7 ( XIE-134 ) Oxygen atom Oxygen atom xi-11 xi-3 ( XIE-164 ) Oxygen atom Oxygen atom xi-11 xi-7 ( XIE-135 ) Oxygen atom Oxygen atom xi-12 xi-3 ( XIE-165 ) Oxygen atom Oxygen atom xi-12 xi-7 ( XIE-136 ) Oxygen atom Oxygen atom xi-4 xi-4 ( XIE-166 ) Oxygen atom Oxygen atom xi-8 xi-8 ( XIE-137 ) Oxygen atom Oxygen atom xi-5 xi-4 ( XIE-167 ) Oxygen atom Oxygen atom xi-9 xi-8 ( XIE-138 ) Oxygen atom Oxygen atom xi-6 xi-4 ( XIE-168 ) Oxygen atom Oxygen atom xi-10 xi-8 ( XIE-139 ) Oxygen atom Oxygen atom xi-7 xi-4 ( XIE-169 ) Oxygen atom Oxygen atom xi-11 xi-8 ( XIE-140 ) Oxygen atom Oxygen atom xi-8 xi-4 ( XIE-170 ) Oxygen atom Oxygen atom xi-12 xi-8 ( XIE-141 ) Oxygen atom Oxygen atom xi-9 xi-4 ( XIE-171 ) Oxygen atom Oxygen atom xi-9 xi-9 ( XIE-142 ) Oxygen atom Oxygen atom xi-10 xi-4 ( XIE-172 ) Oxygen atom Oxygen atom xi-10 xi-9 ( XIE-143 ) Oxygen atom Oxygen atom xi-11 xi-4 ( XIE-173 ) Oxygen atom Oxygen atom xi-11 xi-9 ( XIE-144 ) Oxygen atom Oxygen atom xi-12 xi-4 ( XIE-174 ) Oxygen atom Oxygen atom xi-12 xi-9 ( XIE-145 ) Oxygen atom Oxygen atom xi-5 xi-5 ( XIE-175 ) Oxygen atom Oxygen atom xi-10 xi-10 ( XIE-146 ) Oxygen atom Oxygen atom xi-6 xi-5 ( XIE-176 ) Oxygen atom Oxygen atom xi-11 xi-10 ( XIE-147 ) Oxygen atom Oxygen atom xi-7 xi-5 ( XIE-177 ) Oxygen atom Oxygen atom xi-12 xi-10 ( XIE-148 ) Oxygen atom Oxygen atom xi-8 xi-5 ( XIE-178 ) Oxygen atom Oxygen atom xi-11 xi-11 ( XIE-149 ) Oxygen atom Oxygen atom xi-9 xi-5 ( XIE-179 ) Oxygen atom Oxygen atom xi-12 xi-11 ( XIE-150 ) Oxygen atom Oxygen atom xi-10 xi-5 ( XIE-180 ) Oxygen atom Oxygen atom xi-12 xi-12 ( XIE-181 ) single bond single bond xii-1 xii-1 ( XIE-182 ) Oxygen atom Oxygen atom xii-1 xii-1

[Table 20] Z ^x1 Z ^x2 The basis formed by R ^x1 and R ^x2 Z ^x1 Z ^x2 The basis formed by R ^x1 and R ^x2 R ^{x8 Rx9} ( XIE-183 ) Oxygen atom Oxygen atom xca-1 ( XIE-187 ) Oxygen atom Oxygen atom xcb-1 xcc-1 Oh ( XIE-184 ) Oxygen atom Oxygen atom xca-2 ( XIE-188 ) single bond single bond xcb-1 xcc-1 Oh ( XIE-185 ) single bond single bond xca-1 ( XIE-189 ) Oxygen atom Oxygen atom xcb-1 xcc-1 h ( XIE-186 ) single bond single bond xca-2 ( XIE-190 ) single bond single bond xcb-1 xcc-1 h

As a compound represented by formula (XIE), Preferably formula (XIE-1) ~ formula (XIE-12), formula (XIE-91) ~ formula (XIE-102), formula (XIE-103) ~ formula (XIE-108), formula (XIE-115 ) ~ formula (XIE-119), formula (XIE-126) ~ formula (XIE-129), formula (XIE-136) ~ formula (XIE-138), formula (XIE-145) ~ formula (XIE-146) , compounds represented by formula (XIE-153), formula (XIE-181) ~ formula (XIE-190), More preferably formula (XIE-1) ~ formula (XIE-12), formula (XIE-103) ~ formula (XIE-105), formula (XIE-115) ~ formula (XIE-116), formula (XIE-126 ) represented by the compound, Further preferred are compounds represented by formula (XIE-1) and formula (XIE-115).

The compound represented by formula (XII) is preferably a compound represented by formula (XIIA) to formula (XIIE).

[chem 30]

[chem 31]

[chem 32]

[chem 33]

[chem 34]

[In formula (XIIA) to formula (XIIE), R ^x3 and Z ^x3 are the same as above]

Examples of the compound represented by formula (XIIA) include compounds represented by formula (XIIA-1) to formula (XIIA-18) shown in Table 21. Examples of the compound represented by formula (XIIB) include compounds represented by formula (XIIB-1) to formula (XIIB-18) shown in Table 22. Examples of the compound represented by formula (XIIC) include compounds represented by formula (XIIC-1) to formula (XIIC-18) shown in Table 23. Examples of the compound represented by formula (XIID) include compounds represented by formula (XIID-1) to formula (XIID-18) shown in Table 24. Examples of the compound represented by formula (XIIE) include compounds represented by formula (XIIE-1) to formula (XIIE-18) shown in Table 25. In addition, the symbols described in the "R ^x3 " column in Table 21 to Table 25 correspond to groups represented by formula (xiii-1) to formula (xiii-9). * Indicates a bonded bond.

[chem 35]

[Table 21] Z ^x3 R ^x3 Z ^x3 R ^x3 ( XIIA-1 ) single bond xiii-1 ( XIIA-10 ) Oxygen atom xiii-1 ( XIIA-2 ) single bond xiii-2 ( XIIA-11 ) Oxygen atom xiii-2 ( XIIA-3 ) single bond xiii-3 ( XIIA-12 ) Oxygen atom xiii-3 ( XIIA-4 ) single bond xiii-4 ( XIIA-13 ) Oxygen atom xiii-4 ( XIIA-5 ) single bond xiii-5 ( XIIA-14 ) Oxygen atom xiii-5 ( XIIA-6 ) single bond xiii-6 ( XIIA-15 ) Oxygen atom xiii-6 ( XIIA-7 ) single bond xiii-7 ( XIIA-16 ) Oxygen atom xiii-7 ( XIIA-8 ) single bond xiii-8 ( XIIA-17 ) Oxygen atom xiii-8 ( XIIA-9 ) single bond xiii-9 ( XIIA-18 ) Oxygen atom xiii-9

As a compound represented by formula (XIIA), Preferred are compounds represented by formula (XIIA-1) to formula (XIIA-6), and formula (XIIA-10) to formula (XIIA-15).

[Table 22] Z ^x3 R ^x3 Z ^x3 R ^x3 ( XIIB-1 ) single bond xiii-1 ( XIIB-10 ) Oxygen atom xiii-1 ( XIIB-2 ) single bond xiii-2 ( XIIB-11 ) Oxygen atom xiii-2 ( XIIB-3 ) single bond xiii-3 ( XIIB-12 ) Oxygen atom xiii-3 ( XIIB-4 ) single bond xiii-4 ( XIIB-13 ) Oxygen atom xiii-4 ( XIIB-5 ) single bond xiii-5 ( XIIB-14 ) Oxygen atom xiii-5 ( XIIB-6 ) single bond xiii-6 ( XIIB-15 ) Oxygen atom xiii-6 ( XIIB-7 ) single bond xiii-7 ( XIIB-16 ) Oxygen atom xiii-7 ( XIIB-8 ) single bond xiii-8 ( XIIB-17 ) Oxygen atom xiii-8 ( XIIB-9 ) single bond xiii-9 ( XIIB-18 ) Oxygen atom xiii-9

As a compound represented by formula (XIIB), Preferred are compounds represented by formula (XIIB-1) to formula (XIIB-6), and formula (XIIB-10) to formula (XIIB-15).

[Table 23] Z ^x3 R ^x3 Z ^x3 R ^x3 ( XIIC-1 ) single bond xiii-1 ( XIIC-10 ) Oxygen atom xiii-1 ( XIIC-2 ) single bond xiii-2 ( XIIC-11 ) Oxygen atom xiii-2 ( XIIC-3 ) single bond xiii-3 ( XIIC-12 ) Oxygen atom xiii-3 ( XIIC-4 ) single bond xiii-4 ( XIIC-13 ) Oxygen atom xiii-4 ( XIIC-5 ) single bond xiii-5 ( XIIC-14 ) Oxygen atom xiii-5 ( XIIC-6 ) single bond xiii-6 ( XIIC-15 ) Oxygen atom xiii-6 ( XIIC-7 ) single bond xiii-7 ( XIIC-16 ) Oxygen atom xiii-7 ( XIIC-8 ) single bond xiii-8 ( XIIC-17 ) Oxygen atom xiii-8 ( XIIC-9 ) single bond xiii-9 ( XIIC-18 ) Oxygen atom xiii-9

As a compound represented by formula (XIIC), Preferred are compounds represented by formula (XIIC-1) to formula (XIIC-6), and formula (XIIC-10) to formula (XIIC-15).

[Table 24] Z ^x3 R ^x3 Z ^x3 R ^x3 ( XIID-1 ) single bond xiii-1 ( XIID-10 ) Oxygen atom xiii-1 ( XIID-2 ) single bond xiii-2 ( XIID-11 ) Oxygen atom xiii-2 ( XIID-3 ) single bond xiii-3 ( XIID-12 ) Oxygen atom xiii-3 ( XIID-4 ) single bond xiii-4 ( XIID-13 ) Oxygen atom xiii-4 ( XIID-5 ) single bond xiii-5 ( XIID-14 ) Oxygen atom xiii-5 ( XIID-6 ) single bond xiii-6 ( XIID-15 ) Oxygen atom xiii-6 ( XIID-7 ) single bond xiii-7 ( XIID-16 ) Oxygen atom xiii-7 ( XIID-8 ) single bond xiii-8 ( XIID-17 ) Oxygen atom xiii-8 ( XIID-9 ) single bond xiii-9 ( XIID-18 ) Oxygen atom xiii-9

As a compound represented by formula (XIID), Preferred are compounds represented by formula (XIID-1) to formula (XIID-6), and formula (XIID-10) to formula (XIID-15).

[Table 25] Z ^x3 R ^x3 Z ^x3 R ^x3 ( XIIE-1 ) single bond xiii-1 ( XIIE-10 ) Oxygen atom xiii-1 ( XIIE-2 ) single bond xiii-2 ( XIIE-11 ) Oxygen atom xiii-2 ( XIIE-3 ) single bond xiii-3 ( XIIE-12 ) Oxygen atom xiii-3 ( XIIE-4 ) single bond xiii-4 ( XIIE-13 ) Oxygen atom xiii-4 ( XIIE-5 ) single bond xiii-5 ( XIIE-14 ) Oxygen atom xiii-5 ( XIIE-6 ) single bond xiii-6 ( XIIE-15 ) Oxygen atom xiii-6 ( XIIE-7 ) single bond xiii-7 ( XIIE-16 ) Oxygen atom xiii-7 ( XIIE-8 ) single bond xiii-8 ( XIIE-17 ) Oxygen atom xiii-8 ( XIIE-9 ) single bond xiii-9 ( XIIE-18 ) Oxygen atom xiii-9

As a compound represented by formula (XIIE), Preferred are compounds represented by formula (XIIE-1) to formula (XIIE-6), and formula (XIIE-10) to formula (XIIE-15).

The compound represented by the formula (X0) can be produced, for example, by appropriately reacting the compound represented by the formula (XIII) with concentrated sulfuric acid. The compound represented by the formula (XI) can be produced, for example, by appropriately reacting the compound represented by the formula (XIII) and the compound represented by the formula (XIV). In addition, the compound represented by the formula (XII) can be produced, for example, by appropriately reacting the compound represented by the formula (XIIIa), the compound represented by the formula (XIIIb), and the compound represented by the formula (XV).

[chem 36]

[In formula (XI), formula (XIII) and formula (XIV), R ^x1 , R ^x2 , Z ^x1 , Z ^x2 , X ^x1 to X ^x4 and nx1 to nx4 are the same as described above]

[chem 37]

[In formula (XII), formula (XIIIa), formula (XIIIb) and formula (XV), R ^x3 , Z ^x3 , X ^x7 to X ^x12 and nx7 to nx12 are the same as described above]

In formula (YI), R ^y1 is preferably an aromatic hydrocarbon group having 6 to 20 carbon atoms that may have a substituent, more preferably an aromatic hydrocarbon group having 6 to 10 carbon atoms that may have a substituent, and even more preferably The aromatic hydrocarbon group having 6 to 8 carbon atoms which may have a substituent is particularly preferably a phenyl group which may have a substituent. R ^y2 is preferably an optionally substituted aliphatic unsaturated hydrocarbon group having 2 to 20 carbons or an optionally substituted aromatic hydrocarbon group having 6 to 20 carbons. Here, examples of the aliphatic unsaturated hydrocarbon group having 2 to 20 carbon atoms in preferred aspects of R ^y2 and R ^y3 described later include those described above as the alkenyl group, alkynyl group, and unsaturated alicyclic hydrocarbon group. base. Examples of substituents that the aliphatic unsaturated hydrocarbon group having 2 to 20 carbon atoms may have include those described as substituents that the aliphatic unsaturated hydrocarbon group having 2 to 20 carbon atoms represented by R ^x1 and R ^x3 may have. . However, when the aliphatic unsaturated hydrocarbon group has an aromatic hydrocarbon group as a substituent, the sum of the carbon number of the aliphatic unsaturated hydrocarbon group and the carbon number of the aromatic hydrocarbon group as the substituent is 20 or less. Regarding the aliphatic unsaturated hydrocarbon group having an aromatic hydrocarbon group as a substituent, specifically, groups exemplified as an arylalkenyl group and an arylalkynyl group are mentioned. Among them, R ^y2 is more preferably an unsaturated chain hydrocarbon group having 2 to 10 carbon atoms (ie, alkenyl, alkynyl) which may have a substituent or an aromatic hydrocarbon group having 6 to 10 carbon atoms which may have a substituent, Further preferred is an unsaturated chain hydrocarbon group having 2 to 7 carbon atoms which may have a substituent or an aromatic hydrocarbon group having 6 to 8 carbon atoms which may have a substituent, and even more preferably an unsaturated chain hydrocarbon group having 2 to 7 carbon atoms which may have a substituent An alkenyl group or an optionally substituted aromatic hydrocarbon group having 6 to 8 carbon atoms, particularly preferably an optionally substituted vinyl group or an optionally substituted phenyl group. ny1-ny4 are each independently, for example, 0-2 or 4, Preferably they are 0-2, More preferably, they are 0-1, More preferably, they are 0. X ^y1 to X ^y4 are each independently preferably -R ^y4 or a halogen atom, more preferably a straight-chain or branched chain alkyl group with 1 to 10 carbons, or a halogen atom, and still more preferably 1 to 5 carbons A branched chain alkyl group or a halogen atom, particularly preferably a tert-butyl group, a fluorine atom, a chlorine atom or a bromine atom. At least one of Y ¹ , Z ^y1 , Z ^y2 and Z ^y3 represents a sulfur atom, and it is preferable that Y ¹ is a sulfur atom and Z ^y1 is an oxygen atom, and Y ¹ is an oxygen atom and Z ^y1 is a sulfur atom. And Z ^y2 and Z ^y3 are at least one of the forms of sulfur atoms. Among them, when R ^y2 is an aliphatic unsaturated hydrocarbon group, Z ^y2 and Z ^y3 are preferably single bonds.

In formula (YII), R ^y3 is preferably an aliphatic unsaturated hydrocarbon group with 2 to 20 carbons that may have substituents or an aromatic hydrocarbon group with 6 to 20 carbons that may have substituents, more preferably An unsaturated chain hydrocarbon group having 2 to 10 carbon atoms with a substituent or an aromatic hydrocarbon group with 6 to 10 carbon atoms that may have a substituent, more preferably an unsaturated chain hydrocarbon group with 2 to 7 carbon atoms that may have a substituent Or an aromatic hydrocarbon group having 6 to 8 carbon atoms that may have a substituent, more preferably an alkenyl group having 2 to 7 carbon atoms that may have a substituent or an aromatic hydrocarbon group having 6 to 8 carbon atoms that may have a substituent, especially Preferable is a vinyl group which may have a substituent or a phenyl group which may have a substituent. ny5-ny12 are each independently, for example, 0-2 or 4, preferably 0-2, more preferably 0-1, still more preferably 0. X ^y5 to X ^y12 are each independently preferably -R ^y5 or a halogen atom, more preferably a linear or branched chain alkyl group with 1 to 10 carbons, or a halogen atom, and further preferably a carbon number 1 to 5 A branched chain alkyl group or a halogen atom, particularly preferably a tert-butyl group, a fluorine atom, a chlorine atom or a bromine atom. At least one of Y ² , Z ^y4 and Z ^y5 represents a sulfur atom. Among them, when R ^y3 is an aliphatic unsaturated hydrocarbon group, Z ^y5 is preferably a single bond.

Examples of the compound represented by formula (YI) include compounds represented by formula (YIA) to formula (YIE).

[chem 38]

[chem 39]

[chemical 40]

[chem 41]

[chem 42]

[In formula (YIA) to formula (YIE), R ^y1 , R ^y2 , Y ¹ , Z ^y1 , Z ^y2 and Z ^y3 are the same as described above]

Examples of the compound represented by formula (YIA) include compounds represented by formula (YIA-1) to formula (YIA-24) shown in Table 26. Examples of the compound represented by formula (YIB) include compounds represented by formula (YIB-1) to formula (YIB-24) shown in Table 27. Examples of the compound represented by formula (YIC) include compounds represented by formula (YIC-1) to formula (YIC-24) shown in Table 28. Examples of the compound represented by formula (YID) include compounds represented by formula (YID-1) to formula (YID-24) shown in Table 29. Examples of the compound represented by formula (YIE) include compounds represented by formula (YIE-1) to formula (YIE-24) shown in Table 30. In addition, "yi-1" in Tables 26 to 30 represents a phenyl group, and "yi-2" represents a vinyl group.

[Table 26] Y ¹ Z ^y1 Z ^{y2 Z} R ^y1 R ^y2 ( YIA-1 ) sulfur atom Oxygen atom single bond single bond yi-1 yi-1 ( YIA-2 ) sulfur atom Oxygen atom single bond Oxygen atom yi-1 yi-1 ( YIA-3 ) sulfur atom Oxygen atom single bond sulfur atom yi-1 yi-1 ( YIA-4 ) sulfur atom Oxygen atom Oxygen atom Oxygen atom yi-1 yi-1 ( YIA-5 ) sulfur atom Oxygen atom Oxygen atom sulfur atom yi-1 yi-1 ( YIA-6 ) sulfur atom Oxygen atom sulfur atom sulfur atom yi-1 yi-1 ( YIA-7 ) sulfur atom sulfur atom single bond single bond yi-1 yi-1 ( YIA-8 ) sulfur atom sulfur atom single bond Oxygen atom yi-1 yi-1 ( YIA-9 ) sulfur atom sulfur atom single bond sulfur atom yi-1 yi-1 ( YIA-10 ) sulfur atom sulfur atom Oxygen atom Oxygen atom yi-1 yi-1 ( YIA-11 ) sulfur atom sulfur atom Oxygen atom sulfur atom yi-1 yi-1 ( YIA-12 ) sulfur atom sulfur atom sulfur atom sulfur atom yi-1 yi-1 ( YIA-13 ) Oxygen atom sulfur atom single bond single bond yi-1 yi-1 ( YIA-14 ) Oxygen atom sulfur atom single bond Oxygen atom yi-1 yi-1 ( YIA-15 ) Oxygen atom sulfur atom single bond sulfur atom yi-1 yi-1 ( YIA-16 ) Oxygen atom sulfur atom Oxygen atom Oxygen atom yi-1 yi-1 ( YIA-17 ) Oxygen atom sulfur atom Oxygen atom sulfur atom yi-1 yi-1 ( YIA-18 ) Oxygen atom sulfur atom sulfur atom sulfur atom yi-1 yi-1 ( YIA-19 ) Oxygen atom Oxygen atom single bond sulfur atom yi-1 yi-1 ( YIA-20 ) Oxygen atom Oxygen atom Oxygen atom sulfur atom yi-1 yi-1 ( YIA-21 ) Oxygen atom Oxygen atom sulfur atom sulfur atom yi-1 yi-1 ( YIA-22 ) sulfur atom Oxygen atom single bond single bond yi-1 yi-2 ( YIA-23 ) sulfur atom sulfur atom single bond single bond yi-1 yi-2 ( YIA-24 ) Oxygen atom sulfur atom single bond single bond yi-1 yi-2

As a compound represented by formula (YIA), Preferably formula (YIA-1) ~ formula (YIA-6), formula (YIA-13) ~ formula (YIA-18), formula (YIA-21), formula (YIA-22) ~ formula (YIA-24 ) represented by the compound, More preferred are compounds represented by formula (YIA-1), formula (YIA-13), formula (YIA-21), formula (YIA-23), and formula (YIA-24).

[Table 27] Y ¹ Z ^y1 Z ^{y2 Z} R ^y1 R ^y2 ( YIB-1 ) sulfur atom Oxygen atom single bond single bond yi-1 yi-1 ( YIB-2 ) sulfur atom Oxygen atom single bond Oxygen atom yi-1 yi-1 ( YIB-3 ) sulfur atom Oxygen atom single bond sulfur atom yi-1 yi-1 ( YIB-4 ) sulfur atom Oxygen atom Oxygen atom Oxygen atom yi-1 yi-1 ( YIB-5 ) sulfur atom Oxygen atom Oxygen atom sulfur atom yi-1 yi-1 ( YIB-6 ) sulfur atom Oxygen atom sulfur atom sulfur atom yi-1 yi-1 ( YIB-7 ) sulfur atom sulfur atom single bond single bond yi-1 yi-1 ( YIB-8 ) sulfur atom sulfur atom single bond Oxygen atom yi-1 yi-1 ( YIB-9 ) sulfur atom sulfur atom single bond sulfur atom yi-1 yi-1 ( YIB-10 ) sulfur atom sulfur atom Oxygen atom Oxygen atom yi-1 yi-1 ( YIB-11 ) sulfur atom sulfur atom Oxygen atom sulfur atom yi-1 yi-1 ( YIB-12 ) sulfur atom sulfur atom sulfur atom sulfur atom yi-1 yi-1 ( YIB-13 ) Oxygen atom sulfur atom single bond single bond yi-1 yi-1 ( YIB-14 ) Oxygen atom sulfur atom single bond Oxygen atom yi-1 yi-1 ( YIB-15 ) Oxygen atom sulfur atom single bond sulfur atom yi-1 yi-1 ( YIB-16 ) Oxygen atom sulfur atom Oxygen atom Oxygen atom yi-1 yi-1 ( YIB-17 ) Oxygen atom sulfur atom Oxygen atom sulfur atom yi-1 yi-1 ( YIB-18 ) Oxygen atom sulfur atom sulfur atom sulfur atom yi-1 yi-1 ( YIB-19 ) Oxygen atom Oxygen atom single bond sulfur atom yi-1 yi-1 ( YIB-20 ) Oxygen atom Oxygen atom Oxygen atom sulfur atom yi-1 yi-1 ( YIB-21 ) Oxygen atom Oxygen atom sulfur atom sulfur atom yi-1 yi-1 ( YIB-22 ) sulfur atom Oxygen atom single bond single bond yi-1 yi-2 ( YIB-23 ) sulfur atom sulfur atom single bond single bond yi-1 yi-2 ( YIB-24 ) Oxygen atom sulfur atom single bond single bond yi-1 yi-2

As a compound represented by the formula (YIB), Preferably formula (YIB-1) ~ formula (YIB-6), formula (YIB-13) ~ formula (YIB-18), formula (YIB-21), formula (YIB-22) ~ formula (YIB-24 ) represented by the compound, More preferred are compounds represented by formula (YIB-1), formula (YIB-13), formula (YIB-21), formula (YIB-23), and formula (YIB-24).

[Table 28] Y ¹ Z ^y1 Z ^{y2 Z} R ^y1 R ^y2 ( YIC-1 ) sulfur atom Oxygen atom single bond single bond yi-1 yi-1 ( YIC-2 ) sulfur atom Oxygen atom single bond Oxygen atom yi-1 yi-1 ( YIC-3 ) sulfur atom Oxygen atom single bond sulfur atom yi-1 yi-1 ( YIC-4 ) sulfur atom Oxygen atom Oxygen atom Oxygen atom yi-1 yi-1 ( YIC-5 ) sulfur atom Oxygen atom Oxygen atom sulfur atom yi-1 yi-1 ( YIC-6 ) sulfur atom Oxygen atom sulfur atom sulfur atom yi-1 yi-1 ( YIC-7 ) sulfur atom sulfur atom single bond single bond yi-1 yi-1 ( YIC-8 ) sulfur atom sulfur atom single bond Oxygen atom yi-1 yi-1 ( YIC-9 ) sulfur atom sulfur atom single bond sulfur atom yi-1 yi-1 ( YIC-10 ) sulfur atom sulfur atom Oxygen atom Oxygen atom yi-1 yi-1 ( YIC-11 ) sulfur atom sulfur atom Oxygen atom sulfur atom yi-1 yi-1 ( YIC-12 ) sulfur atom sulfur atom sulfur atom sulfur atom yi-1 yi-1 ( YIC-13 ) Oxygen atom sulfur atom single bond single bond yi-1 yi-1 ( YIC-14 ) Oxygen atom sulfur atom single bond Oxygen atom yi-1 yi-1 ( YIC-15 ) Oxygen atom sulfur atom single bond sulfur atom yi-1 yi-1 ( YIC-16 ) Oxygen atom sulfur atom Oxygen atom Oxygen atom yi-1 yi-1 ( YIC-17 ) Oxygen atom sulfur atom Oxygen atom sulfur atom yi-1 yi-1 ( YIC-18 ) Oxygen atom sulfur atom sulfur atom sulfur atom yi-1 yi-1 ( YIC-19 ) Oxygen atom Oxygen atom single bond sulfur atom yi-1 yi-1 ( YIC-20 ) Oxygen atom Oxygen atom Oxygen atom sulfur atom yi-1 yi-1 ( YIC-21 ) Oxygen atom Oxygen atom sulfur atom sulfur atom yi-1 yi-1 ( YIC-22 ) sulfur atom Oxygen atom single bond single bond yi-1 yi-2 ( YIC-23 ) sulfur atom sulfur atom single bond single bond yi-1 yi-2 ( YIC-24 ) Oxygen atom sulfur atom single bond single bond yi-1 yi-2

As a compound represented by the formula (YIC), Preferably formula (YIC-1) ~ formula (YIC-6), formula (YIC-13) ~ formula (YIC-18), formula (YIC-21), formula (YIC-22) ~ formula (YIC-24 ) represented by the compound, More preferred are compounds represented by formula (YIC-1), formula (YIC-13), formula (YIC-21), formula (YIC-23), and formula (YIC-24).

[Table 29] Y ¹ Z ^y1 Z ^{y2 Z} R ^y1 R ^y2 ( YID-1 ) sulfur atom Oxygen atom single bond single bond yi-1 yi-1 ( YID-2 ) sulfur atom Oxygen atom single bond Oxygen atom yi-1 yi-1 ( YID-3 ) sulfur atom Oxygen atom single bond sulfur atom yi-1 yi-1 ( YID-4 ) sulfur atom Oxygen atom Oxygen atom Oxygen atom yi-1 yi-1 ( YID-5 ) sulfur atom Oxygen atom Oxygen atom sulfur atom yi-1 yi-1 ( YID-6 ) sulfur atom Oxygen atom sulfur atom sulfur atom yi-1 yi-1 ( YID-7 ) sulfur atom sulfur atom single bond single bond yi-1 yi-1 ( YID-8 ) sulfur atom sulfur atom single bond Oxygen atom yi-1 yi-1 ( YID-9 ) sulfur atom sulfur atom single bond sulfur atom yi-1 yi-1 ( YID-10 ) sulfur atom sulfur atom Oxygen atom Oxygen atom yi-1 yi-1 ( YID-11 ) sulfur atom sulfur atom Oxygen atom sulfur atom yi-1 yi-1 ( YID-12 ) sulfur atom sulfur atom sulfur atom sulfur atom yi-1 yi-1 ( YID-13 ) Oxygen atom sulfur atom single bond single bond yi-1 yi-1 ( YID-14 ) Oxygen atom sulfur atom single bond Oxygen atom yi-1 yi-1 ( YID-15 ) Oxygen atom sulfur atom single bond sulfur atom yi-1 yi-1 ( YID-16 ) Oxygen atom sulfur atom Oxygen atom Oxygen atom yi-1 yi-1 ( YID-17 ) Oxygen atom sulfur atom Oxygen atom sulfur atom yi-1 yi-1 ( YID-18 ) Oxygen atom sulfur atom sulfur atom sulfur atom yi-1 yi-1 ( YID-19 ) Oxygen atom Oxygen atom single bond sulfur atom yi-1 yi-1 ( YID-20 ) Oxygen atom Oxygen atom Oxygen atom sulfur atom yi-1 yi-1 ( YID-21 ) Oxygen atom Oxygen atom sulfur atom sulfur atom yi-1 yi-1 ( YID-22 ) sulfur atom Oxygen atom single bond single bond yi-1 yi-2 ( YID-23 ) sulfur atom sulfur atom single bond single bond yi-1 yi-2 ( YID-24 ) Oxygen atom sulfur atom single bond single bond yi-1 yi-2

As a compound represented by the formula (YID), Preferably formula (YID-1) ~ formula (YID-6), formula (YID-13) ~ formula (YID-18), formula (YID-21), formula (YID-22) ~ formula (YID-24 ) represented by the compound, More preferred are compounds represented by formula (YID-1), formula (YID-13), formula (YID-21), formula (YID-23), and formula (YID-24).

[Table 30] Y ¹ Z ^y1 Z ^{y2 Z} R ^y1 R ^y2 ( YIE-1 ) sulfur atom Oxygen atom single bond single bond yi-1 yi-1 ( YIE-2 ) sulfur atom Oxygen atom single bond Oxygen atom yi-1 yi-1 ( YIE-3 ) sulfur atom Oxygen atom single bond sulfur atom yi-1 yi-1 ( YIE-4 ) sulfur atom Oxygen atom Oxygen atom Oxygen atom yi-1 yi-1 ( YIE-5 ) sulfur atom Oxygen atom Oxygen atom sulfur atom yi-1 yi-1 ( YIE-6 ) sulfur atom Oxygen atom sulfur atom sulfur atom yi-1 yi-1 ( YIE-7 ) sulfur atom sulfur atom single bond single bond yi-1 yi-1 ( YIE-8 ) sulfur atom sulfur atom single bond Oxygen atom yi-1 yi-1 ( YIE-9 ) sulfur atom sulfur atom single bond sulfur atom yi-1 yi-1 ( YIE-10 ) sulfur atom sulfur atom Oxygen atom Oxygen atom yi-1 yi-1 ( YIE-11 ) sulfur atom sulfur atom Oxygen atom sulfur atom yi-1 yi-1 ( YIE-12 ) sulfur atom sulfur atom sulfur atom sulfur atom yi-1 yi-1 ( YIE-13 ) Oxygen atom sulfur atom single bond single bond yi-1 yi-1 ( YIE-14 ) Oxygen atom sulfur atom single bond Oxygen atom yi-1 yi-1 ( YIE-15 ) Oxygen atom sulfur atom single bond sulfur atom yi-1 yi-1 ( YIE-16 ) Oxygen atom sulfur atom Oxygen atom Oxygen atom yi-1 yi-1 ( YIE-17 ) Oxygen atom sulfur atom Oxygen atom sulfur atom yi-1 yi-1 ( YIE-18 ) Oxygen atom sulfur atom sulfur atom sulfur atom yi-1 yi-1 ( YIE-19 ) Oxygen atom Oxygen atom single bond sulfur atom yi-1 yi-1 ( YIE-20 ) Oxygen atom Oxygen atom Oxygen atom sulfur atom yi-1 yi-1 ( YIE-21 ) Oxygen atom Oxygen atom sulfur atom sulfur atom yi-1 yi-1 ( YIE-22 ) sulfur atom Oxygen atom single bond single bond yi-1 yi-2 ( YIE-23 ) sulfur atom sulfur atom single bond single bond yi-1 yi-2 ( YIE-24 ) Oxygen atom sulfur atom single bond single bond yi-1 yi-2

As a compound represented by formula (YIE), Preferably formula (YIE-1) ~ formula (YIE-6), formula (YIE-13) ~ formula (YIE-18), formula (YIE-21), formula (YIE-22) ~ formula (YIE-24 ) represented by the compound, More preferred are compounds represented by formula (YIE-1), formula (YIE-13), formula (YIE-21), formula (YIE-23), and formula (YIE-24).

Examples of the compound represented by formula (YII) include compounds represented by formula (YIIA) to formula (YIIE).

[chem 43]

[chem 44]

[chem 45]

[chem 46]

[chem 47]

[In formula (YIIA) to formula (YIIE), R ^y3 , Y ² , Z ^y4 and Z ^y5 are the same as described above]

Examples of the compound represented by formula (YIIA) include compounds represented by formula (YIIA-1) to formula (YIIA-13) shown in Table 31. Examples of the compound represented by formula (YIIB) include compounds represented by formula (YIIB-1) to formula (YIIB-13) shown in Table 32. Examples of the compound represented by formula (YIIC) include compounds represented by formula (YIIC-1) to formula (YIIC-13) shown in Table 33. Examples of the compound represented by formula (YIID) include compounds represented by formula (YIID-1) to formula (YIID-13) shown in Table 34. Examples of the compound represented by formula (YIIE) include compounds represented by formula (YIIE-1) to formula (YIIE-13) shown in Table 35. In addition, "yi-1" in Table 31 to Table 35 represents a phenyl group, and "yi-2" represents a vinyl group.

[Table 31] Y ^{2 Z Y5 Y3} ( YIIA-1 ) sulfur atom Oxygen atom single bond yi-1 ( YIIA-2 ) sulfur atom Oxygen atom Oxygen atom yi-1 ( YIIA-3 ) sulfur atom Oxygen atom sulfur atom yi-1 ( YIIA-4 ) sulfur atom sulfur atom single bond yi-1 ( YIIA-5 ) sulfur atom sulfur atom Oxygen atom yi-1 ( YIIA-6 ) sulfur atom sulfur atom sulfur atom yi-1 ( YIIA-7 ) Oxygen atom Oxygen atom sulfur atom yi-1 ( YIIA-8 ) Oxygen atom sulfur atom single bond yi-1 ( YIIA-9 ) Oxygen atom sulfur atom Oxygen atom yi-1 ( YIIA-10 ) Oxygen atom sulfur atom sulfur atom yi-1 ( YIIA-11 ) sulfur atom Oxygen atom single bond yi-2 ( YIIA-12 ) sulfur atom sulfur atom single bond yi-2 ( YIIA-13 ) Oxygen atom sulfur atom single bond yi-2

As a compound represented by formula (YIIA), Preferably it is a compound represented by formula (YIIA-1), formula (YIIA-2), formula (YIIA-8), formula (YIIA-9), formula (YIIA-12), formula (YIIA-13), More preferred are compounds represented by formula (YIIA-1), formula (YIIA-8), formula (YIIA-12), and formula (YIIA-13).

[Table 32] Y ^{2 Z Y5 Y3} ( YIIB-1 ) sulfur atom Oxygen atom single bond yi-1 ( YIIB-2 ) sulfur atom Oxygen atom Oxygen atom yi-1 ( YIIB-3 ) sulfur atom Oxygen atom sulfur atom yi-1 ( YIIB-4 ) sulfur atom sulfur atom single bond yi-1 ( YIIB-5 ) sulfur atom sulfur atom Oxygen atom yi-1 ( YIIB-6 ) sulfur atom sulfur atom sulfur atom yi-1 ( YIIB-7 ) Oxygen atom Oxygen atom sulfur atom yi-1 ( YIIB-8 ) Oxygen atom sulfur atom single bond yi-1 ( YIIB-9 ) Oxygen atom sulfur atom Oxygen atom yi-1 ( YIIB-10 ) Oxygen atom sulfur atom sulfur atom yi-1 ( YIIB-11 ) sulfur atom Oxygen atom single bond yi-2 ( YIIB-12 ) sulfur atom sulfur atom single bond yi-2 ( YIIB-13 ) Oxygen atom sulfur atom single bond yi-2

As a compound represented by formula (YIIB), Preferably it is a compound represented by formula (YIIB-1), formula (YIIB-2), formula (YIIB-8), formula (YIIB-9), formula (YIIB-12), formula (YIIB-13), More preferred are compounds represented by formula (YIIB-1), formula (YIIB-8), formula (YIIB-12), and formula (YIIB-13).

[Table 33] Y ^{2 Z Y5 Y3} ( YIIC-1 ) sulfur atom Oxygen atom single bond yi-1 ( YIIC-2 ) sulfur atom Oxygen atom Oxygen atom yi-1 ( YIIC-3 ) sulfur atom Oxygen atom sulfur atom yi-1 ( YIIC-4 ) sulfur atom sulfur atom single bond yi-1 ( YIIC-5 ) sulfur atom sulfur atom Oxygen atom yi-1 ( YIIC-6 ) sulfur atom sulfur atom sulfur atom yi-1 ( YIIC-7 ) Oxygen atom Oxygen atom sulfur atom yi-1 ( YIIC-8 ) Oxygen atom sulfur atom single bond yi-1 ( YIIC-9 ) Oxygen atom sulfur atom Oxygen atom yi-1 ( YIIC-10 ) Oxygen atom sulfur atom sulfur atom yi-1 ( YIIC-11 ) sulfur atom Oxygen atom single bond yi-2 ( YIIC-12 ) sulfur atom sulfur atom single bond yi-2 ( YIIC-13 ) Oxygen atom sulfur atom single bond yi-2

As a compound represented by formula (YIIC), Preferably it is a compound represented by formula (YIIC-1), formula (YIIC-2), formula (YIIC-8), formula (YIIC-9), formula (YIIC-12), formula (YIIC-13), More preferred are compounds represented by formula (YIIC-1), formula (YIIC-8), formula (YIIC-12), and formula (YIIC-13).

[Table 34] Y ^{2 Z Y5 Y3} ( YIID-1 ) sulfur atom Oxygen atom single bond yi-1 ( YIID-2 ) sulfur atom Oxygen atom Oxygen atom yi-1 ( YIID-3 ) sulfur atom Oxygen atom sulfur atom yi-1 ( YIID-4 ) sulfur atom sulfur atom single bond yi-1 ( YIID-5 ) sulfur atom sulfur atom Oxygen atom yi-1 ( YIID-6 ) sulfur atom sulfur atom sulfur atom yi-1 ( YIID-7 ) Oxygen atom Oxygen atom sulfur atom yi-1 ( YIID-8 ) Oxygen atom sulfur atom single bond yi-1 ( YIID-9 ) Oxygen atom sulfur atom Oxygen atom yi-1 ( YIID-10 ) Oxygen atom sulfur atom sulfur atom yi-1 ( YIID-11 ) sulfur atom Oxygen atom single bond yi-2 ( YIID-12 ) sulfur atom sulfur atom single bond yi-2 ( YIID-13 ) Oxygen atom sulfur atom single bond yi-2

As a compound represented by formula (YIID), Preferably it is a compound represented by formula (YIID-1), formula (YIID-2), formula (YIID-8), formula (YIID-9), formula (YIID-12), formula (YIID-13), More preferred are compounds represented by formula (YIID-1), formula (YIID-8), formula (YIID-12), and formula (YIID-13).

[Table 35] Y ^{2 Z Y5 Y3} ( YIIE-1 ) sulfur atom Oxygen atom single bond yi-1 ( YIIE-2 ) sulfur atom Oxygen atom Oxygen atom yi-1 ( YIIE-3 ) sulfur atom Oxygen atom sulfur atom yi-1 ( YIIE-4 ) sulfur atom sulfur atom single bond yi-1 ( YIIE-5 ) sulfur atom sulfur atom Oxygen atom yi-1 ( YIIE-6 ) sulfur atom sulfur atom sulfur atom yi-1 ( YIIE-7 ) Oxygen atom Oxygen atom sulfur atom yi-1 ( YIIE-8 ) Oxygen atom sulfur atom single bond yi-1 ( YIIE-9 ) Oxygen atom sulfur atom Oxygen atom yi-1 ( YIIE-10 ) Oxygen atom sulfur atom sulfur atom yi-1 ( YIIE-11 ) sulfur atom Oxygen atom single bond yi-2 ( YIIE-12 ) sulfur atom sulfur atom single bond yi-2 ( YIIE-13 ) Oxygen atom sulfur atom single bond yi-2

As a compound represented by formula (YIIE), Preferably it is a compound represented by formula (YIIE-1), formula (YIIE-2), formula (YIIE-8), formula (YIIE-9), formula (YIIE-12), formula (YIIE-13), More preferred are compounds represented by formula (YIIE-1), formula (YIIE-8), formula (YIIE-12), and formula (YIIE-13).

The compound represented by the formula (YI) can be produced, for example, by appropriately reacting the compound represented by the formula (YIII) and the compound represented by the formula (YIV). In addition, the compound represented by formula (YII) can be produced, for example, by appropriately reacting the compound represented by formula (YIIIa) and formula (YIIIb) with the compound represented by formula (YV).

[chem 48]

[In formula (YI), formula (YIII) and formula (YIV), R ^y1 , R ^y2 , Y ¹ , Z ^y1 , Z ^y2 , Z ^y3 , X ^y1 to X ^y4 and ny1 to ny4 are the same as described above]

[chem 49]

[In formula (YII), formula (YIIIa), formula (YIIIb) and formula (YV), R ^y3 , Y ² , Z ^y4 , Z ^y5 , X ^y5 to X ^y12 and ny5 to ny12 are the same as described above]

The aluminum phthalocyanine compound can be made into a dispersion liquid in a uniformly dispersed state in a dispersant solution by containing a dispersant and performing a dispersion treatment. The aluminum phthalocyanine compound may be dispersed alone, or may be mixed and dispersed in two or more types.

As a dispersant, the thing similar to the pigment dispersant mentioned later is mentioned.

When a dispersant is used, the amount used is preferably from 10 parts by mass to 200 parts by mass, more preferably from 15 parts by mass to 180 parts by mass, relative to 100 parts by mass of the aluminum phthalocyanine compound in the dispersion. , and more preferably not less than 20 parts by mass and not more than 160 parts by mass. When the usage-amount of a dispersing agent exists in the said range, it exists in the tendency for the dispersion liquid of a more uniform dispersion state to be obtained.

The content of the aluminum phthalocyanine compound is preferably from 0.5% by mass to 70% by mass, more preferably from 1% by mass to 55% by mass, and still more preferably from 2% by mass to 50% by mass, based on the total solid content of the colored curable composition. quality%. In addition, the content of the aluminum phthalocyanine compound may be 0.5% by mass to 20% by mass in the total amount of solid content of the colored curable composition. In addition, in this specification, "the total amount of solid content" means the total amount of the component which removed the solvent from the colored curable composition of this invention. The total amount of solid content and the content of each component relative thereto can be measured by known analysis methods such as liquid chromatography (Liquid Chromatography) and gas chromatography (Gas Chromatography), for example.

In addition, the content of the aluminum phthalocyanine compound is preferably from 1% by mass to 100% by mass, more preferably from 3% by mass to 80% by mass, and still more preferably from 5% by mass to 70% by mass, based on the total amount of the colorant (A). %, and more preferably 5 mass % to 60 mass %.

The coloring agent (A) may further contain a coloring agent different from the aluminum phthalocyanine compound (hereinafter, it may be referred to as a coloring agent (A2)).

The coloring agent (A2) may be any one of a dye and a pigment, or may be a mixture of these.

Examples of dyes include compounds classified as those having hue other than pigments in the Color Index (published by The Society of Dyers and Colourists), or dyeing notes (color dyeing companies) known dyes.

As dyes, for example, azo dyes, cyanine dyes, triphenylmethane dyes, thiazole dyes, oxazine dyes, quinophthalone dyes, anthraquinone dyes, naphthoquinone dyes, quinone imine dyes, methine known dyes such as azomethinedye, squarylium dye, acridine dye, styryl dye, coumarin dye, quinoline dye, and nitro dye .

Specific examples of dyes include C.I. solvent yellow (solvent yellow) 4 (hereinafter, the description of C.I. solvent yellow is omitted, and only the number is described; otherwise the same), 14, 15, 23, 24, 38, 62, 63, 68, 82, 94, 99, 117, 162, 163, 167, 189; C.I. solvent red (solvent red) 111, 125, 130, 143, 145, 146, 150, 151, 155, 168, 169, 172, 175, 181, 207, 222, 227, 230, 245, 247; C.I. solvent orange (solvent orange) 2, 7, 11, 15, 26, 56, 77, 86; C.I. solvent violet (solvent violet) 11, 13, 14, 26, 31, 36, 37, 38, 45, 47, 48, 51, 59, 60; C.I. solvent blue (solvent blue) 4, 5, 14, 18, 35, 36, 37, 45, 58, 59, 59: 1, 63, 68, 69, 78, 79, 83, 90, 94, 97, 98 , 100, 101, 102, 104, 105, 111, 112, 122, 128, 132, 136, 139; C.I. solvent green (solvent green) 1, 3, 5, 7, 28, 29, 32, 33, 34, 35 and other C.I. solvent dyes; C.I. acid yellow 1, 3, 7, 9, 11, 17, 23, 25, 29, 34, 36, 38, 40, 42, 54, 65, 72, 73, 76, 79, 98, 99 ,111,112,113,114,116,119,123,128,134,135,138,139,140,144,150,155,157,160,161,163,168,169,172,177,178 ,179,184,190,193,196,197,199,202,203,204,205,207,212,214,220,221,228,230,232,235,238,240,242,243,251 ; C.I. acid red (acid red) 1, 4, 8, 14, 17, 18, 26, 27, 29, 31, 33, 34, 35, 37, 40, 42, 44, 57, 66, 73, 76, 80 ,88,97,103,106,111,114,129,133,134,138,143,145,150,151,155,158,160,172,176,182,183,195,198,206,211 ,215,216,217,227,228,249,252,257,258,260,261,266,268,270,274,277,280,281,308,312,315,316,339,341,345 , 346, 349, 382, 383, 394, 401, 412, 417, 418, 422, 426; C.I. acid orange (acid orange) 6, 7, 8, 10, 12, 26, 50, 51, 52, 56, 62, 63, 64, 74, 75, 94, 95, 107, 108, 169, 173; C.I. acid violet (acid violet) 6B, 7, 15, 16, 17, 19, 21, 23, 24, 25, 34, 38, 49, 72; C.I. acid blue 1, 3, 5, 7, 9, 11, 13, 15, 17, 18, 22, 23, 24, 25, 26, 27, 29, 34, 38, 40, 41, 42 , 43, 45, 48, 51, 54, 59, 60, 62, 70, 72, 74, 75, 78, 80, 82, 83, 86, 87, 88, 90, 90: 1, 91, 92, 93 ,93:1,96,99,100,102,103,104,108,109,110,112,113,117,119,120,123,126,127,129,130,131,138,140,142 ,143,147,150,151,154,158,161,166,167,168,170,171,175,182,183,184,187,192,199,203,204,205,210,213,229 , 234, 236, 256, 259, 267, 269, 278, 280, 285, 290, 296, 315, 324: 1, 335, 340; C.I. acid green 1, 3, 5, 6, 7, 8, 9, 11, 13, 14, 15, 16, 22, 25, 27, 28, 41, 50, 50: 1, 58, 63 , 65, 80, 104, 105, 106, 109 and other C.I. acid dyes; C.I. direct yellow (direct yellow) 2, 33, 34, 35, 38, 39, 43, 47, 50, 54, 58, 68, 69, 70, 71, 86, 93, 94, 95, 98, 102, 108 , 109, 129, 136, 138, 141; C.I. direct red (direct red) 79, 82, 83, 84, 91, 92, 96, 97, 98, 99, 105, 106, 107, 172, 173, 176, 177, 179, 181, 182, 184, 204 , 207, 211, 213, 218, 220, 221, 222, 232, 233, 234, 241, 243, 246, 250; C.I. direct orange (direct orange) 26, 34, 39, 41, 46, 50, 52, 56, 57, 61, 64, 65, 68, 70, 96, 97, 106, 107; C.I. direct violet (direct violet) 47, 52, 54, 59, 60, 65, 66, 79, 80, 81, 82, 84, 89, 90, 93, 95, 96, 103, 104; C.I. direct blue (direct blue) 1, 2, 3, 6, 8, 15, 22, 25, 28, 29, 40, 41, 42, 47, 52, 55, 57, 71, 76, 77, 78, 80 ,81,84,85,90,93,94,95,97,98,99,100,101,106,107,108,109,113,114,115,117,119,120,137,149,150 ,153,155,156,158,159,160,161,162,163,164,165,166,167,168,170,171,172,173,188,190,192,193,194,195,196 ,198,200,201,202,203,207,209,210,212,213,214,222,225,226,228,229,236,237,238,242,243,244,245,246,247 , 248, 249, 250, 251, 252, 256, 257, 259, 260, 268, 274, 275, 293; C.I. direct green (direct green) 25, 27, 31, 32, 34, 37, 63, 65, 66, 67, 68, 69, 72, 77, 79, 82 and other C.I. direct dyes; C.I. disperse yellow (disperse yellow) 51, 54, 76; C.I. disperse violet (disperse violet) 26, 27; C.I. disperse blue (disperse blue) 1, 14, 56, 60 and other C.I. disperse dyes; C.I. basic blue (basic blue) 1, 3, 5, 7, 9, 19, 21, 22, 24, 25, 26, 28, 29, 40, 41, 45, 47, 54, 58, 59, 60, 64, 65, 66, 67, 68, 81, 83, 88, 89; C.I. basic violet (basic violet) 2; C.I. basic red (basic red) 9; C.I. basic green (basic green) 1 and other C.I. basic dyes; C.I. reactive yellow 2, 76, 116; C.I. reactive orange 16; C.I. Reactive dyes such as C.I. reactive red (reactive red) 36; C.I. Mordant yellow (mordant yellow) 5, 8, 10, 16, 20, 26, 30, 31, 33, 42, 43, 45, 56, 61, 62, 65; C.I. Mordant red (mordant red) 1, 2, 3, 4, 9, 11, 12, 14, 17, 18, 19, 22, 23, 24, 25, 26, 29, 30, 32, 33, 36, 37 , 38, 39, 41, 42, 43, 45, 46, 48, 52, 53, 56, 62, 63, 71, 74, 76, 78, 85, 86, 88, 90, 94, 95; C.I. Mordant orange 3, 4, 5, 8, 12, 13, 14, 20, 21, 23, 24, 28, 29, 32, 34, 35, 36, 37, 42, 43, 47, 48 ; C.I. Mordant violet 1, 1:1, 2, 3, 4, 5, 6, 7, 8, 10, 11, 14, 15, 16, 17, 18, 19, 21, 22, 23, 24 , 27, 28, 30, 31, 32, 33, 36, 37, 39, 40, 41, 44, 45, 47, 48, 49, 53, 58; C.I. Mordant blue 1, 2, 3, 7, 8, 9, 12, 13, 15, 16, 19, 20, 21, 22, 23, 24, 26, 30, 31, 32, 39, 40 , 41, 43, 44, 48, 49, 53, 61, 74, 83, 84; C.I. Mordant green (mordant green) 1, 3, 4, 5, 10, 13, 15, 19, 21, 23, 26, 29, 31, 33, 34, 35, 41, 43, 53 and other C.I. mordant dyes; C.I. Vat green (vat green) 1, etc. C.I. Vat dyes, etc. For these dyes, one type of dye or a plurality of dyes may be used for each color, and dyes of various colors may be combined.

Examples of pigments include pigments classified as pigments in the Color Index (published by The Society of Dyers and Colourists), and the following pigments are exemplified.

Green pigments: C.I. pigment green (pigment green) 7, 36, 58, 59, etc. Yellow pigment: C.I. pigment yellow (pigment yellow) 1, 3, 12, 13, 14, 15, 16, 17, 20, 24, 31, 53, 83, 86, 93, 94, 109, 110, 117, 125, 128, 129, 137, 138, 139, 147, 148, 150, 153, 154, 166, 173, 185, 194, 214, etc. Orange pigment: C.I. pigment orange (pigment orange) 13, 31, 36, 38, 40, 42, 43, 51, 55, 59, 61, 64, 65, 71, 73, etc. Red pigment: C.I. pigment red (pigment red) 9, 97, 105, 122, 144, 149, 166, 168, 176, 177, 180, 192, 209, 215, 216, 242, 254, 255, 264, 265, etc. Blue pigment: C.I. pigment blue (pigment blue) 15, 15:1, 15:2, 15:3, 15:4, 15:6, 16, 60, etc. Purple pigment: C.I. pigment violet (pigment violet) 19, 23, 29, 32, 36, 38, etc. These pigments may use one type of pigment or several types of pigments for each color, and may combine the pigments of various colors.

Regarding pigments, if necessary, rosin treatment, surface treatment using pigment derivatives introduced with acidic groups or basic groups, etc., grafting treatment on the surface of pigments with polymer compounds, etc., micronization with sulfuric acid, etc. Micronization treatment, cleaning treatment with organic solvents or water to remove impurities, treatment to remove ionic impurities by ion exchange method, etc. The particle size of the pigment is preferably substantially uniform. The pigment can be made into a dispersion liquid in a uniformly dispersed state in a dispersant solution by containing a pigment dispersant and performing a dispersion treatment. Pigments may be dispersed individually or in combination of multiple pigments.

Examples of the pigment dispersant include surfactants and the like, and any of cationic, anionic, nonionic, and amphoteric surfactants may be used. Specifically, surfactants such as polyester-based, polyamine-based, and acrylic-based surfactants, and the like are exemplified. These dispersants may be used alone or in combination of two or more. As a dispersant, when expressed by a trade name, KP (manufactured by Shin-Etsu Chemical Co., Ltd.), Flowlen (manufactured by Kyoeisha Chemical Co., Ltd.), Solsperse (registered trademark) (manufactured by Zeneca Co., Ltd.), EFKA (registered trademark) (manufactured by BASF Corporation), Ajisper (registered trademark) (Ajinomoto Precision Technology Co., Ltd. (manufactured by Ajinomoto Fine-Techno Co., Ltd.), Disperbyk (registered trademark), BYK (registered trademark) (manufactured by BYK-Chemie), etc.

In the case of using a pigment dispersant, the amount used is preferably from 10 parts by mass to 200 parts by mass, more preferably from 15 parts by mass to 180 parts by mass, with respect to 100 parts by mass of the pigment in the dispersion liquid, and further Preferably, it is 20 mass parts or more and 160 mass parts or less. When the usage-amount of a pigment dispersant exists in the said range, it exists in the tendency for the dispersion liquid of a more uniform dispersion state to be obtained.

When the colorant (A) contains the colorant (A2), the content of the colorant (A2) is preferably 1% by mass to 99% by mass, more preferably 1% by mass, of the total amount of the colorant (A). % to 97% by mass, more preferably 20% to 95% by mass. In addition, the content of the coloring agent (A2) may be 20% by mass to 97% by mass, 30% by mass to 95% by mass, or 40% by mass to 95% by mass of the total amount of the colorant (A). %.

The content of the coloring agent (A) in the coloring curable composition is preferably 0.5% by mass to 80% by mass, more preferably 5% by mass to 70% by mass, and still more preferably 10% by mass relative to the total amount of solid content. % to 55% by mass. When the content rate of the coloring agent (A) is within the above-mentioned range, it becomes easier to obtain desired light spectrum or color density.

＜Resin (B)＞ The resin (B) is not particularly limited, but is preferably an alkali-soluble resin. As resin (B), the following resin [K1] - resin [K6] etc. are mentioned. Resin [K1]: at least one (a) selected from the group consisting of unsaturated carboxylic acids and unsaturated carboxylic anhydrides (hereinafter, sometimes referred to as "(a)"), and resins having 2 to 4 carbon atoms Copolymers of monomer (b) (hereinafter, sometimes referred to as "(b)") having a cyclic ether structure and an ethylenically unsaturated bond; Resin [K2]: (a), (b) and monomer (c) copolymerizable with (a) (which is different from (a) and (b)) (hereinafter sometimes referred to as "(c)" ) copolymers; Resin [K3]: a copolymer of (a) and (c); Resin [K4]: a resin obtained by reacting a copolymer of (a) and (c) with (b); Resin [K5]: a resin obtained by reacting a copolymer of (b) and (c) with (a); Resin [K6]: a resin obtained by reacting a copolymer of (b) and (c) with (a), and further reacting with polyvalent carboxylic acid and/or carboxylic acid anhydride.

Examples of (a) specifically include unsaturated monocarboxylic acids such as acrylic acid, methacrylic acid, crotonic acid, o-vinylbenzoic acid, m-vinylbenzoic acid, and p-vinylbenzoic acid; Maleic acid, fumaric acid, citraconic acid, mesaconic acid, itaconic acid, 3-vinylphthalic acid, 4-vinylphthalic acid, 3,4,5,6-tetrahydrophthalic acid Dicarboxylic acid, 1,2,3,6-tetrahydrophthalic acid, dimethyltetrahydrophthalic acid, 1,4-cyclohexene dicarboxylic acid and other unsaturated dicarboxylic acids; Methyl-5-norbornene-2,3-dicarboxylic acid, 5-carboxybicyclo[2.2.1]hept-2-ene, 5,6-dicarboxybicyclo[2.2.1]hept-2-ene, 5-carboxy-5-methylbicyclo[2.2.1]hept-2-ene, 5-carboxy-5-ethylbicyclo[2.2.1]hept-2-ene, 5-carboxy-6-methylbicyclo[ 2.2.1] Hept-2-ene, 5-carboxy-6-ethylbicyclo[2.2.1]hept-2-ene and other carboxyl-containing bicyclic unsaturated compounds; Maleic anhydride, citraconic anhydride, itaconic anhydride, 3-vinylphthalic anhydride, 4-vinylphthalic anhydride, 3,4,5,6-tetrahydrophthalic anhydride, 1, 2,3,6-tetrahydrophthalic anhydride, dimethyltetrahydrophthalic anhydride, 5,6-dicarboxybicyclo[2.2.1]hept-2-ene anhydride and other unsaturated dicarboxylic anhydrides ; Mono-[2-(meth)acryloxyethyl] succinate, mono-[2-(meth)acryloxyethyl] phthalate, and other dibasic or higher polycarboxylic acids Unsaturated mono[(meth)acryloxyalkyl]esters; Unsaturated acrylic esters containing a hydroxyl group and a carboxyl group in the same molecule, such as α-(hydroxymethyl)acrylic acid. Among these, acrylic acid, methacrylic acid, maleic anhydride, and the like are preferable from the viewpoint of copolymerization reactivity or the solubility of the obtained resin in an alkaline aqueous solution.

(b) means, for example, a cyclic ether structure having 2 to 4 carbon atoms (for example, at least one selected from the group consisting of an oxirane ring, an oxetane ring, and a tetrahydrofuran ring) and ethylenic A polymeric compound with an unsaturated bond. (b) It is preferably a monomer having a cyclic ether having 2 to 4 carbon atoms and a (meth)acryloxy group. In addition, in this specification, "(meth)acrylic acid" means at least 1 sort(s) chosen from the group which consists of acrylic acid and methacrylic acid. Expressions such as "(meth)acryl" and "(meth)acrylate" also have the same meaning.

Examples of (b) include monomers (b1) having an oxetanyl group and an ethylenically unsaturated bond (hereinafter sometimes referred to as "(b1)"), monomers having an oxetanyl group and an ethylenically unsaturated bond, Monomer (b2) having an unsaturated bond (hereinafter, sometimes referred to as "(b2)"), monomer (b3) having a tetrahydrofuryl group and an ethylenically unsaturated bond (hereinafter, sometimes referred to as "(b3)") )wait.

Examples of (b1) include monomers (b1-1) having a structure obtained by epoxidizing a linear or branched aliphatic unsaturated hydrocarbon (hereinafter sometimes referred to as "(b1-1) ”), a monomer (b1-2) having a structure obtained by epoxidizing an alicyclic unsaturated hydrocarbon (hereinafter, sometimes referred to as “(b1-2)”).

Examples of (b1-1) include: glycidyl (meth)acrylate, β-methylglycidyl (meth)acrylate, β-ethylglycidyl (meth)acrylate, glycidyl vinyl Ether, o-vinylbenzyl glycidyl ether, m-vinylbenzyl glycidyl ether, p-vinylbenzyl glycidyl ether, α-methyl-o-vinylbenzyl glycidyl ether, α-methyl-methylene Benzyl benzyl glycidyl ether, α-methyl-p-vinylbenzyl glycidyl ether, 2,3-bis(glycidyloxymethyl)styrene, 2,4-bis(glycidyloxymethyl) base) styrene, 2,5-bis(glycidyloxymethyl)styrene, 2,6-bis(glycidyloxymethyl)styrene, 2,3,4-tris(glycidyl oxymethyl)styrene, 2,3,5-tris(glycidyloxymethyl)styrene, 2,3,6-tris(glycidyloxymethyl)styrene, 3,4, 5-tris(glycidyloxymethyl)styrene, 2,4,6-tris(glycidyloxymethyl)styrene and the like.

Examples of (b1-2) include: vinylcyclohexene monooxide, 1,2-epoxy-4-vinylcyclohexane (for example, Celloxide 2000; Daicel (manufactured by Daicel Co., Ltd.), 3,4-epoxycyclohexylmethyl (meth)acrylate (for example, Cyclomer A400; manufactured by Daicel Co., Ltd.), 3,4-epoxycyclohexyl (meth)acrylate Cyclohexyl methyl ester (for example, Cyclomer M100; manufactured by Daicel Co., Ltd.), 3,4-epoxytricyclo[5.2.1.0 ^2,6 ]decyl (meth)acrylate, formula (R1) The compound represented by and the compound represented by formula (R2), etc.

[chemical 50]

[In formula (R1) and formula (R2), R ^ra and R ^rb represent a hydrogen atom or an alkyl group with 1 to 4 carbons, and the hydrogen atom contained in the alkyl group can be replaced by a hydroxyl group; X ^ra and X ^rb represent a single Bond, *-R ^rc -, *-R ^rc -O-, *-R ^rc -S- or *-R ^rc -NH-; R ^rc represents an alkanediyl group with 1 to 6 carbons; * represents the combination with O bond key]

Examples of the alkyl group having 1 to 4 carbon atoms include methyl group, ethyl group, n-propyl group, isopropyl group, n-butyl group, sec-butyl group, and tert-butyl group. Examples of the alkyl group in which a hydrogen atom is substituted with a hydroxyl group include: hydroxymethyl, 1-hydroxyethyl, 2-hydroxyethyl, 1-hydroxypropyl, 2-hydroxypropyl, 3-hydroxypropyl, 1-hydroxy -1-methylethyl, 2-hydroxy-1-methylethyl, 1-hydroxybutyl, 2-hydroxybutyl, 3-hydroxybutyl, 4-hydroxybutyl and the like. R ^ra and R ^rb preferably include a hydrogen atom, a methyl group, a hydroxymethyl group, 1-hydroxyethyl group, and 2-hydroxyethyl group, more preferably a hydrogen atom and a methyl group.

Examples of the alkanediyl group include methylene, ethylidene, propane-1,2-diyl, propane-1,3-diyl, butane-1,4-diyl, pentane-1,5 -diyl, hexane-1,6-diyl, etc. As X ^ra and X ^rb , preferably a single bond, methylene, ethylidene, *-CH ₂ -O- and *-CH ₂ CH ₂ -O-, more preferably a single bond, * -CH ₂ CH ₂ -O- (* indicates a bonding bond with O).

Examples of the compound represented by formula (R1) include compounds represented by any one of formula (R1-1) to formula (R1-15), and the like. Among them, formula (R1-1), formula (R1-3), formula (R1-5), formula (R1-7), formula (R1-9) or formula (R1-11) ~ formula (R1 The compound represented by -15) is more preferably a compound represented by formula (R1-1), formula (R1-7), formula (R1-9) or formula (R1-15).

[Chemical 51]

[Chemical 52]

Examples of the compound represented by formula (R2) include compounds represented by any one of formula (R2-1) to formula (R2-15), and the like. Among them, formula (R2-1), formula (R2-3), formula (R2-5), formula (R2-7), formula (R2-9) or formula (R2-11) ~ formula (R2 The compound represented by -15) is more preferably a compound represented by formula (R2-1), formula (R2-7), formula (R2-9) or formula (R2-15).

[Chemical 53]

[Chemical 54]

(b2) is more preferably a monomer having an oxetanyl group and a (meth)acryloxy group. Examples of (b2) include: 3-methyl-3-methacryloxymethyloxetane, 3-methyl-3-acryloxymethyloxetane, 3-Ethyl-3-methacryloxymethyloxetane, 3-ethyl-3-acryloxymethyloxetane, 3-methyl-3-methyl Acryloxyethyl oxetane, 3-methyl-3-acryloxyethyl oxetane, 3-ethyl-3-methacryloxyethyl Oxetane, 3-ethyl-3-acryloyloxyethyl oxetane and the like.

(b3) is more preferably a monomer having a tetrahydrofuryl group and a (meth)acryloxy group. Specific examples of (b3) include tetrahydrofurfuryl acrylate (for example, Viscoat V#150, manufactured by Osaka Organic Chemical Industry Co., Ltd.), tetrahydrofurfuryl methacrylate, and the like.

As (b), (b1) is preferable at the point which can further improve reliability, such as heat resistance and chemical resistance, of the obtained color filter. Furthermore, (b1-2) is more preferable at the point which is more excellent in the storage stability of a coloring curable composition.

Examples of (c) include methyl (meth)acrylate, ethyl (meth)acrylate, n-butyl (meth)acrylate, second-butyl (meth)acrylate, second-butyl (meth)acrylate, Tributyl, 2-ethylhexyl (meth)acrylate, lauryl (meth)acrylate, stearyl (meth)acrylate, cyclopentyl (meth)acrylate , cyclohexyl (meth)acrylate, 2-methylcyclohexyl (meth)acrylate, tricyclo[5.2.1.0 ^2,6 ]decane-8-yl (meth)acrylate (in this technical field , known as "dicyclopentyl (meth)acrylate" as a common name; in addition, sometimes called "tricyclodecanyl (meth)acrylate"), tricyclo[5.2.1.0 ^{2 ,6} ] Decen-8-yl ester (known as "dicyclopentenyl (meth)acrylate" as a common name in this technical field), dicyclopentyloxyethyl (meth)acrylate, ( Isobornyl Methacrylate, Adamantyl (Meth)acrylate, Allyl (Meth)acrylate, Propargyl (Meth)acrylate, Phenyl (Meth)acrylate, Naphthyl (Meth)acrylate , (meth)acrylates such as benzyl (meth)acrylate; 2-hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate and other hydroxyl-containing (meth)acrylates; Diethyl maleate, diethyl fumarate, diethyl itaconate and other dicarboxylic acid diesters; bicyclo[2.2.1]hept-2-ene, 5-methylbicyclo[2.2.1]heptane -2-ene, 5-ethylbicyclo[2.2.1]hept-2-ene, 5-hydroxybicyclo[2.2.1]hept-2-ene, 5-hydroxymethylbicyclo[2.2.1]hept-2 -ene, 5-(2'-hydroxyethyl)bicyclo[2.2.1]hept-2-ene, 5-methoxybicyclo[2.2.1]hept-2-ene, 5-ethoxybicyclo[2.2 .1]hept-2-ene, 5,6-dihydroxybicyclo[2.2.1]hept-2-ene, 5,6-di(hydroxymethyl)bicyclo[2.2.1]hept-2-ene, 5 ,6-bis(2'-hydroxyethyl)bicyclo[2.2.1]hept-2-ene, 5,6-dimethoxybicyclo[2.2.1]hept-2-ene, 5,6-diethyl Oxybicyclo[2.2.1]hept-2-ene, 5-hydroxy-5-methylbicyclo[2.2.1]hept-2-ene, 5-hydroxy-5-ethylbicyclo[2.2.1]hept- 2-ene, 5-hydroxymethyl-5-methylbicyclo[2.2.1]hept-2-ene, 5-tert-butoxycarbonylbicyclo[2.2.1]hept-2-ene, 5-cyclohexyl Oxycarbonylbicyclo[2.2.1]hept-2-ene, 5-phenoxycarbonylbicyclo[2.2.1]hept-2-ene, 5,6-bis(tertiary butoxycarbonyl)bicyclo[2.2. 1] Hept-2-ene, 5,6-bis(cyclohexyloxycarbonyl)bicyclo[2.2.1]hept-2-ene and other bicyclic unsaturated compounds; N-phenylmaleimide, N- Cyclohexylmaleimide, N-Benzylmaleimide, N-succinimidyl-3-maleimide benzoate, N-succinimidyl-4-maleimide N-succinimidyl butyrate, N-succinimidyl-6-maleimide hexanoate, N-succinimidyl-3-maleimide propionate, N-(9- Acridyl) maleimide and other dicarbonyl imide derivatives; Styrene, α-methylstyrene, m-methylstyrene, p-methylstyrene, vinyl toluene, p-methoxybenzene Ethylene, acrylonitrile, methacrylonitrile, vinyl chloride, vinylidene chloride, acrylamide, methacrylamide, vinyl acetate, 1,3-butadiene, isoprene, 2,3-di Methyl-1,3-butadiene, etc. As (c), preferred are 2-ethylhexyl (meth)acrylate, dicyclopentyl (meth)acrylate, benzyl (meth)acrylate, styrene, vinyl toluene, N-phenylmethane Laimide, N-cyclohexylmaleimide, N-benzylmaleimide, bicyclo[2.2.1]hept-2-ene, etc., in terms of copolymerization reactivity and heat resistance, More preferably styrene, vinyltoluene, N-phenylmaleimide, N-cyclohexylmaleimide, N-benzylmaleimide, bicyclo[2.2.1]hept-2- ene etc.

Among all the structural units constituting the resin [K1], the ratio of the structural units derived from each in the resin [K1] is preferably: Structural unit derived from (a): 2 mol% to 60 mol% Structural unit derived from (b): 40 mol% to 98 mol% Even better: Structural unit derived from (a): 10 mol% to 50 mol% Structural unit derived from (b): 50 mol% to 90 mol%. When the ratio of the structural unit of the resin [K1] is within the above range, the storage stability of the colored curable composition, the developability when forming a colored pattern, and the solvent resistance of the obtained color filter tend to be excellent. .

Resin [K1], for example, can refer to the method described in the document "Experimental Method for Polymer Synthesis" (Takayuki Otsu, Chemical Doujin Publishing Co., Ltd., 1st Edition, 1st Printing Issue, March 1, 1972) and the method described in this document. Manufactured from cited references.

Concretely, the method of putting predetermined amounts of (a) and (b), a polymerization initiator, a solvent, and the like into a reaction vessel, and replacing oxygen with nitrogen, for example, thereby creating a deoxygenated environment, While stirring, heat and keep warm. In addition, the polymerization initiator, solvent, etc. used here are not specifically limited, Those commonly used in this field can be used. Examples of polymerization initiators include azo compounds (2,2'-azobisisobutyronitrile, 2,2'-azobis(2,4-dimethylvaleronitrile), etc.) and organic peroxides. The solvent (benzoyl peroxide, etc.) may be any solvent as long as it dissolves each monomer, and solvents described later may be mentioned as the solvent (G).

Furthermore, the obtained copolymer may be used as it is after the reaction, may be used as a concentrated or diluted solution, or may be taken out as a solid (powder) by reprecipitation or the like. In particular, the solvent contained in the curable colored composition is used as a solvent during the polymerization, so that the solution after the reaction can be directly used in the preparation of the curable colored composition, so that the production process of the curable colored composition can be simplified. simplify.

Among all the structural units constituting the resin [K2], the ratio of the structural units derived from each in the resin [K2] is preferably: Structural unit derived from (a): 2 mol% to 45 mol% Structural unit derived from (b): 2 mol% to 95 mol% Structural unit derived from (c): 1 mol% to 65 mol% Even better: Structural unit derived from (a): 5 mol% to 40 mol% Structural unit derived from (b): 5 mol% to 80 mol% Structural unit derived from (c): 5 mol% to 60 mol%. When the ratio of the structural unit of the resin [K2] is within the above range, the storage stability of the colored curable composition, the developability when forming a colored pattern, and the solvent resistance and heat resistance of the obtained color filter and a tendency to be excellent in mechanical strength.

Resin [K2] can be produced, for example, in the same manner as the method described as the production method of resin [K1].

Among all the structural units constituting the resin [K3], the ratio of the structural units derived from each in the resin [K3] is preferably: Structural unit derived from (a): 2 mol% to 60 mol% Structural unit derived from (c): 40 mol% to 98 mol% Even better: Structural unit derived from (a): 10 mol% to 50 mol% Structural unit derived from (c): 50 mol% to 90 mol%. Resin [K3] can be produced, for example, in the same manner as the method described as the production method of resin [K1].

Resin [K4] can be obtained by obtaining a copolymer of (a) and (c) and adding a cyclic ether having 2 to 4 carbon atoms in (b) to the carboxylic acid and/or carboxyl in (a). Manufactured from acid anhydrides. First, the copolymer of (a) and (c) was produced in the same manner as the method described as the production method of resin [K1]. In this case, the ratio of the structural units derived from each is preferably the same ratio as listed in the resin [K3].

Next, the cyclic ether having 2 to 4 carbon atoms contained in (b) is reacted with a part of the carboxylic acid and/or carboxylic anhydride derived from (a) in the copolymer. After producing the copolymer of (a) and (c), the atmosphere in the flask was replaced from nitrogen to air, and the reaction catalyst of (b), carboxylic acid or carboxylic acid anhydride and cyclic ether (for example, tris(dimethyl Aminomethyl)phenol, triphenylphosphine, etc.) and polymerization inhibitors (such as hydroquinone, hydroquinone monomethyl ether (methoquinone, etc.) Resin [K4] can be produced by reacting for 1 hour to 10 hours. The usage-amount of (b) is preferably 5 mol to 80 mol, more preferably 10 mol to 75 mol, based on 100 mol of (a). By setting it as this range, there exists a tendency for the balance of the storage stability of a coloring curable composition, the developability at the time of pattern formation, and the solvent resistance of the obtained pattern, heat resistance, mechanical strength, and sensitivity to become favorable. As (b) used for resin [K4], (b1) is preferable, and (b1-1) is more preferable at the point which the reactivity of a cyclic ether is high and unreacted (b) does not remain easily. The amount of the reaction catalyst used is preferably 0.001 to 5 parts by mass relative to 100 parts by mass of the total amount of (a), (b) and (c). The amount of the polymerization inhibitor used is preferably 0.001 parts by mass to 5 parts by mass relative to 100 parts by mass of the total amount of (a), (b) and (c). Reaction conditions, such as a charging method, reaction temperature, and time, can be appropriately adjusted in consideration of production facilities, heat generation due to polymerization, and the like. In addition, similarly to the polymerization conditions, the charging method and the reaction temperature can be appropriately adjusted in consideration of production facilities, heat generation due to polymerization, and the like.

Regarding the resin [K5], as a first stage, a copolymer of (b) and (c) was obtained in the same manner as the method for producing the resin [K1]. Similar to the above, the obtained copolymer may be used as a solution after the reaction, may be used as a concentrated or diluted solution, or may be taken out as a solid (powder) by reprecipitation or the like. The ratios of the structural units derived from (b) and (c) relative to the total molar number of all structural units constituting the copolymer are preferably: Structural unit derived from (b): 5 mol% to 95 mol% Structural unit derived from (c): 5 mol% to 95 mol% Even better: Structural unit derived from (b): 10 mol% to 90 mol% Structural unit derived from (c): 10 mol% to 90 mol%.

Furthermore, the carboxylic acid or carboxylic acid anhydride contained in (a) and the cyclic ether derived from (b) contained in the copolymer of (b) and (c) are prepared under the same conditions as the production method of resin [K4]. Reaction, whereby the resin [K5] can be obtained. The amount of (a) used to react with the copolymer is preferably 5 mol to 100 mol relative to 100 mol of (b). (b1) is preferable as (b1) used for resin [K5], and (b1-1) is more preferable at the point that the reactivity of a cyclic ether is high and unreacted (b) is hard to remain|survive.

Resin [K6] is resin obtained by further reacting carboxylic anhydride and resin [K5]. The carboxylic anhydride is reacted with a hydroxyl group generated by the reaction of a cyclic ether with a carboxylic acid or carboxylic anhydride. Examples of carboxylic anhydrides include succinic anhydride, maleic anhydride, citraconic anhydride, itaconic anhydride, 3-vinylphthalic anhydride, 4-vinylphthalic anhydride, 3,4,5,6- Tetrahydrophthalic anhydride, 1,2,3,6-tetrahydrophthalic anhydride, dimethyltetrahydrophthalic anhydride, 5,6-dicarboxybicyclo[2.2.1]hept-2 -Alkenic anhydride, etc. The usage-amount of carboxylic anhydride is preferably 0.1-1 mole with respect to 1 mole of the usage-amount of (a).

Specific resins (B) include: 3,4-epoxycyclohexylmethyl (meth)acrylate/(meth)acrylic acid copolymer, 3,4-epoxytricyclo[5.2.1.0 ^{2, 6} ]decyl ester/(meth)acrylic acid copolymer and other resins [K1]; 3,4-epoxytricyclo[ ^5.2.1.02,6 ]decyl acrylate/benzyl (meth)acrylate/(meth)acrylate Acrylic copolymer, glycidyl (meth)acrylate/benzyl (meth)acrylate/(meth)acrylic acid copolymer, glycidyl (meth)acrylate/styrene/(meth)acrylic acid copolymer, acrylic acid 3,4-epoxytricyclo[5.2.1.0 ^2,6 ]decyl ester/(meth)acrylic acid/N-cyclohexylmaleimide copolymer, 3,4-epoxytricyclo[5.2.1.0 acrylic acid ^2,6 ]decyl ester/(meth)acrylic acid/N-cyclohexylmaleimide/2-hydroxyethyl (meth)acrylate copolymer, 3-methyl-3-(meth)acryl Resins such as oxymethyloxetane/(meth)acrylic acid/styrene copolymer [K2]; benzyl (meth)acrylate/(meth)acrylic acid copolymer, styrene/(meth)acrylic acid Resins such as copolymers [K3]; resins obtained by adding glycidyl (meth)acrylate to benzyl (meth)acrylate/(meth)acrylic acid copolymers, tricyclodecanyl (meth)acrylate/ Resin obtained by adding glycidyl (meth)acrylate to styrene/(meth)acrylic acid copolymer, tricyclodecanyl (meth)acrylate/benzyl (meth)acrylate/(meth)acrylic acid copolymer Resins such as resins obtained by adding glycidyl (meth)acrylate to substances [K4]; reacting (meth)acrylic acid with a copolymer of tricyclodecanyl (meth)acrylate/glycidyl (meth)acrylate Resins such as resins obtained by reacting (meth)acrylic acid with a copolymer of tricyclodecanyl (meth)acrylate/styrene/glycidyl (meth)acrylate [K5]; base) acrylic acid and tricyclodecanyl (meth)acrylate/glycidyl (meth)acrylate copolymer reacted with tetrahydrophthalic anhydride resin, the (meth) Resin obtained by reacting copolymer of acrylic acid and 2-ethylhexyl (meth)acrylate/glycidyl (meth)acrylate/dicyclopentanyl (meth)acrylate, further reacted with succinic anhydride, etc. Resin [K6] and so on. Among them, the resin (B) preferably contains a structural unit derived from at least one selected from the group consisting of unsaturated carboxylic acids and unsaturated carboxylic acid anhydrides and a cyclic ether structure having 2 to 4 carbon atoms and A copolymer (resin [K1] or resin [K2]) or resin [K6] of structural units of ethylenically unsaturated bonds.

The polystyrene conversion weight average molecular weight of resin (B) becomes like this. Preferably it is 500-100,000, More preferably, it is 600-50,000, More preferably, it is 700-30,000. When the molecular weight is within the above range, the hardness of the color filter increases, the remaining film rate increases, the solubility of the unexposed portion to the developing solution becomes favorable, and the resolution of the colored pattern tends to improve.

The degree of dispersion [weight average molecular weight (Mw)/number average molecular weight (Mn)] of the resin (B) is preferably from 1.1 to 6, more preferably from 1.2 to 4.

The acid value of the resin (B) in terms of solid content is preferably 10 mg-KOH/g to 170 mg-KOH/g, more preferably 20 mg-KOH/g to 150 mg-KOH/g, and more preferably 30 mg-KOH/g～135 mg-KOH/g. Here, the acid value is a value measured as the amount (mg) of potassium hydroxide required to neutralize 1 g of the resin (B), and can be determined, for example, by titration using an aqueous potassium hydroxide solution.

The content of the resin (B) is preferably from 7 mass % to 80 mass %, more preferably from 13 mass % to 75 mass %, further preferably from 17 mass % to 70 mass %, and still more preferably from 17 mass % to 70 mass %, based on the total amount of solid content. Preferably, it is 17 mass % - 55 mass %. When the content of the resin (B) is within the above range, a colored pattern can be formed, and the resolution and residual film ratio of the colored pattern tend to be improved.

＜Polymerizable compound (C)＞ The polymerizable compound (C) is a compound that can be polymerized by active radicals and/or acids generated from the polymerization initiator (D), for example, a polymerizable compound having an ethylenically unsaturated bond, etc., preferably It is a (meth)acrylate compound.

Among them, the polymerizable compound (C) is preferably a polymerizable compound having three or more ethylenically unsaturated bonds. Examples of such polymerizable compounds include trimethylolpropane tri(meth)acrylate, pentaerythritol tri(meth)acrylate, pentaerythritol tetra(meth)acrylate, and dipentaerythritol penta(meth)acrylate. Dipentaerythritol hexa(meth)acrylate, tripentaerythritol octa(meth)acrylate, tripentaerythritol hepta(meth)acrylate, tetrapentaerythritol deca(meth)acrylate, tetrapentaerythritol nona(meth)acrylate ester, tris(2-(meth)acryloxyethyl)isocyanurate, pentaerythritol tetra(meth)acrylate modified with ethylene oxide, dipentaerythritol hexa(meth)acrylate modified with ethylene oxide base) acrylate, propylene glycol modified pentaerythritol tetra(meth)acrylate, propylene glycol modified dipentaerythritol hexa(meth)acrylate, caprolactone modified pentaerythritol tetra(meth)acrylate, caprolactone modified di Pentaerythritol hexa(meth)acrylate, etc. Among them, preferably selected from trimethylolpropane tri(meth)acrylate, dipentaerythritol penta(meth)acrylate, dipentaerythritol hexa(meth)acrylate and ethylene oxide modified dipentaerythritol hexa( At least one of the group consisting of meth)acrylates.

The weight average molecular weight of the polymerizable compound (C) is preferably from 150 to 2,900, more preferably from 250 to 1,500.

The content of the polymerizable compound (C) is preferably from 7% by mass to 65% by mass, more preferably from 10% by mass to 60% by mass, and still more preferably from 12% by mass to 55% by mass, based on the total amount of solid content. When the content of the polymerizable compound (C) is within the above-mentioned range, the remaining film rate during formation of the colored pattern and the chemical resistance of the color filter tend to be improved.

＜Polymerization initiator (D)＞ The polymerization initiator (D) is a compound capable of generating active radicals, acids, etc. by the action of light or heat to initiate polymerization. The colored curable composition of the present invention contains an oxime compound as a polymerization initiator (D).

The oxime compound is preferably an O-acyl oxime compound having a partial structure represented by formula (d1). Hereinafter, * represents a bonding key.

[Chemical 55]

Examples of the oxime compound include N-benzoyloxy-1-(4-phenylthiophenyl)butan-1-one-2-imine, N-benzoyloxy -1-(4-phenylthiophenyl)octan-1-one-2-imine, N-benzoyloxy-1-(4-phenylthiophenyl)-3-cyclopentyl Propan-1-one-2-imine, N-acetyloxy-1-[9-ethyl-6-(2-methylbenzoyl)-9H-carbazol-3-yl]ethane -1-imine, N-acetyloxy-1-[9-ethyl-6-{2-methyl-4-(3,3-dimethyl-2,4-dioxolane methyloxy)benzoyl}-9H-carbazol-3-yl]ethane-1-imine, N-acetyloxy-1-[9-ethyl-6-(2-methyl N-benzoyloxy)-9H-carbazol-3-yl]-3-cyclopentylpropane-1-imine, N-benzoyloxy-1-[9-ethyl-6-(2 -methylbenzoyl)-9H-carbazol-3-yl]-3-cyclopentylpropane-1-one-2-imine, N-acetyloxy-1-[4-(2 -Hydroxyethyloxy)phenylthiophenyl]propan-1-one-2-imine, N-acetyloxy-1-(4-phenylthiophenyl)-3-cyclohexylpropane- 1-keto-2-imine, 2-[(acetyloxy)imino]-3-cyclohexyl-1-[4-(phenylthio)phenyl]propan-1-one and the like. Irgacure OXE01, OXE02, OXE03 (manufactured by BASF), N-1919 (manufactured by ADEKA), PBG-314, PBG-317, PBG-326, PBG can also be used -327, PBG-329 (the above are manufactured by Changzhou Qiangli Electronic New Material Co., Ltd.) and other commercially available products. Among them, the oxime compound is preferably selected from N-acetyloxy-1-[4-(2-hydroxyethyloxy)phenylthiophenyl]propan-1-one-2-imine, N- Acetyloxy-1-(4-phenylthiophenyl)-3-cyclohexylpropan-1-one-2-imine, 2-[(acetyloxy)imino]-3- Cyclohexyl-1-[4-(phenylthio)phenyl]propan-1-one, N-benzoyloxy-1-(4-phenylthiophenyl)butan-1-one-2 -imine, N-benzoyloxy-1-(4-phenylthiophenyl)octan-1-one-2-imine and N-benzoyloxy-1-(4- At least one of the group consisting of phenylthiophenyl)-3-cyclopentylpropane-1-one-2-imine, more preferably selected from the group consisting of 2-[(acetyloxy)imino ]-3-cyclohexyl-1-[4-(phenylthio)phenyl]propan-1-one, N-benzoyloxy-1-(4-phenylthiophenyl)octane-1 At least one of the group consisting of -keto-2-imine and N-acetyloxy-1-(4-phenylthiophenyl)-3-cyclohexylpropane-1-one-2-imine A sort of. These oxime compounds tend to provide a high-brightness color filter.

In addition, the curable colored composition of the present invention may contain other polymerization initiators other than oxime compounds as the polymerization initiator (D). Examples of other polymerization initiators include phenalkone compounds, triazine compounds, and Compounds, acyl phosphine oxide compounds and biimidazole compounds are polymerization initiators that generate active free radicals.

The phenylalkyl ketone compound is a compound having a partial structure represented by formula (d2) or a partial structure represented by formula (d3). In these partial structures, the benzene ring may have a substituent.

[Chemical 56]

As a compound having a partial structure represented by the formula (d2), for example, 2-methyl-2-morpholinyl-1-(4-methylthiophenyl)propan-1-one, 2-dimethyl Amino-1-(4-morpholinylphenyl)-2-benzylbutan-1-one, 2-(dimethylamino)-2-[(4-methylphenyl)methyl ]-1-[4-(4-morpholinyl)phenyl]butan-1-one, etc. Commercially available products such as Irgacure 369, 907, and 379 (the above are manufactured by BASF) can also be used.

As a compound having a partial structure represented by formula (d3), for example, 2-hydroxy-2-methyl-1-phenylpropane-1-one, 2-hydroxy-2-methyl-1-[4 -(2-Hydroxyethoxy)phenyl]propan-1-one, 1-hydroxycyclohexylphenylketone, 2-hydroxy-2-methyl-1-(4-isopropenylphenyl)propane-1 - Ketone oligomers, α,α-diethoxyacetophenone, benzoyl dimethyl ketal, etc. In terms of sensitivity, the phenalkyl ketone compound is preferably a compound having a partial structure represented by formula (d2).

As the triazine compound, for example, 2,4-bis(trichloromethyl)-6-(4-methoxyphenyl)-1,3,5-triazine, 2,4-bis( Trichloromethyl)-6-(4-methoxynaphthyl)-1,3,5-triazine, 2,4-bis(trichloromethyl)-6-piperonyl-1,3,5- Triazine, 2,4-bis(trichloromethyl)-6-(4-methoxystyryl)-1,3,5-triazine, 2,4-bis(trichloromethyl)-6 -[2-(5-methylfuran-2-yl)vinyl]-1,3,5-triazine, 2,4-bis(trichloromethyl)-6-[2-(furan-2- Base) vinyl]-1,3,5-triazine, 2,4-bis(trichloromethyl)-6-[2-(4-diethylamino-2-methylphenyl)ethenyl ]-1,3,5-triazine, 2,4-bis(trichloromethyl)-6-[2-(3,4-dimethoxyphenyl)ethenyl]-1,3,5- Triazine etc.

Examples of the acylphosphine oxide compound include 2,4,6-trimethylbenzoyldiphenylphosphine oxide and the like. Commercially available items such as Irgacure (registered trademark) 819 (manufactured by BASF) may also be used.

Examples of the biimidazole compound include: 2,2'-bis(2-chlorophenyl)-4,4',5,5'-tetraphenylbiimidazole, 2,2'-bis(2, 3-dichlorophenyl)-4,4',5,5'-tetraphenylbiimidazole (for example, refer to Japanese Patent Laid-Open No. 6-75372, Japanese Patent Laid-Open No. 6-75373, etc.), 2 ,2'-bis(2-chlorophenyl)-4,4',5,5'-tetra(alkoxyphenyl)biimidazole, 2,2'-bis(2-chlorophenyl)-4, 4',5,5'-tetra(dialkoxyphenyl)biimidazole, 2,2'-bis(2-chlorophenyl)-4,4',5,5'-tetrakis(trialkoxy) Phenyl)biimidazole (for example, refer to Japanese Patent Publication No. 48-38403, Japanese Patent Application Publication No. 62-174204, etc.), 4,4', 5,5'-position phenyl is composed of alkoxycarbonyl (carboalkoxy) substituted biimidazole compounds (for example, refer to Japanese Patent Application Laid-Open No. 7-10913, etc.) and the like.

Furthermore, as other polymerization initiators, benzoin compounds such as benzoin, benzoin methyl ether, benzoin ethyl ether, benzoin isopropyl ether, and benzoin isobutyl ether; benzophenone, methyl o-benzoylbenzoate, 4 -Phenylbenzophenone, 4-benzoyl-4'-methyldiphenylsulfide, 3,3',4,4'-tetrakis(tert-butylcarbonylperoxy)benzophenone , 2,4,6-trimethylbenzophenone and other benzophenone compounds; 9,10-phenanthrenequinone, 2-ethylanthraquinone, camphorquinone and other quinone compounds; 10-butyl-2-chloroacridine Pyridone, benzoyl, methyl phenylglyoxylate, titanocene compound, etc. These are preferably used in combination with a polymerization initiation aid (D1) (especially an amine compound) described later.

In addition, examples of other polymerization initiators include: 4-hydroxyphenyldimethylcolumbite p-toluenesulfonate, 4-hydroxyphenyldimethylcolumbite hexafluoroantimonate, 4-acetyloxybenzene Dimethyl percited toluenesulfonate, 4-acetyloxyphenylmethyl benzyl percite hexafluoroantimonate, triphenyl percited toluene sulfonate, triphenyl percite hexafluoroantimonate, Acid-generating polymerization initiators such as onium salts such as diphenyliodonium p-toluenesulfonate and diphenyliodonium hexafluoroantimonate, or nitrobenzyltoluenesulfonate and benzoin toluenesulfonate.

In the polymerization initiator (D), the content of the oxime compound is preferably at least 50% by mass, more preferably at least 80% by mass, still more preferably at least 90% by mass, still more preferably at least 95% by mass, particularly preferably at least 98% by mass. Mass % or more may be 100 mass %.

The content of the polymerization initiator (D) is preferably from 0.1 to 30 parts by mass, more preferably from 1 to 20 parts by mass, based on 100 parts by mass of the total amount of the resin (B) and the polymerizable compound (C). . When content of a polymerization initiator (D) exists in the said range, since there exists a tendency for sensitivity to become high and exposure time to be shortened, productivity of a color filter improves.

＜Polymerization Initiation Auxiliary (D1)＞ The polymerization initiation aid (D1) is a compound or a sensitizer for accelerating the polymerization of a polymerizable compound whose polymerization is started by a polymerization initiator. In the case of containing the polymerization initiation aid (D1), it is usually used in combination with the polymerization initiator (D). As a polymerization start aid (D1), an amine compound, an alkoxy anthracene compound, a thioxanthone compound, a carboxylic acid compound, etc. are mentioned.

Examples of the amine compound include: triethanolamine, methyldiethanolamine, triisopropanolamine, methyl 4-dimethylaminobenzoate, ethyl 4-dimethylaminobenzoate, 4-dimethylaminobenzoate, Isoamyl methylaminobenzoate, 2-dimethylaminoethyl benzoate, 2-ethylhexyl 4-dimethylaminobenzoate, N,N-dimethyl-p-toluidine, 4 ,4'-bis(dimethylamino)benzophenone (commonly known as Michler's ketone), 4,4'-bis(diethylamino)benzophenone, 4,4' - Bis(ethylmethylamino)benzophenone and the like, among which 4,4'-bis(diethylamino)benzophenone is preferred. Commercially available products such as EAB-F (manufactured by Hodogaya Chemical Co., Ltd.) can also be used.

Examples of the alkoxyanthracene compound include: 9,10-dimethoxyanthracene, 2-ethyl-9,10-dimethoxyanthracene, 9,10-diethoxyanthracene, 2-ethyl-9,10-dimethoxyanthracene, Base-9,10-diethoxyanthracene, 9,10-dibutoxyanthracene, 2-ethyl-9,10-dibutoxyanthracene, etc.

Examples of the thioxanthone compound include: 2-isopropylthioxanthone, 4-isopropylthioxanthone, 2,4-diethylthioxanthone, 2,4-dichlorothioxanthone, 1-Chloro-4-propoxythioxanthone, etc.

Examples of the carboxylic acid compound include: phenylthioacetic acid, methylphenylthioacetic acid, ethylphenylthioacetic acid, methylethylphenylthioacetic acid, dimethylphenylthioacetic acid, methoxybenzene Thioacetic acid, dimethoxyphenylthioacetic acid, chlorophenylthioacetic acid, dichlorophenylthioacetic acid, N-phenylglycine, phenoxyacetic acid, naphthylthioacetic acid, N-naphthylglycine acid, naphthyloxyacetic acid, etc.

When using the above-mentioned polymerization initiation aid (D1), the content thereof is preferably 0.1 to 30 parts by mass with respect to 100 parts by mass of the total amount of the resin (B) and the polymerizable compound (C), and more preferably Preferably, it is 1 mass part - 20 mass parts. When the amount of the polymerization initiation auxiliary agent (D1) is within the above range, a colored pattern can be formed with high sensitivity, and the productivity of the color filter tends to improve.

＜Potential antioxidant (E)＞ The latent antioxidant (E) is a compound in which the active group possessed by the antioxidant is protected by a protecting group. The latent antioxidant (E) is preferably a compound in which the phenolic hydroxyl group of the phenolic antioxidant is protected with a protecting group, more preferably a compound in which the phenolic hydroxyl group of the hindered phenolic antioxidant is protected with a protecting group.

As the protecting group for protecting the phenolic hydroxyl group, ether-based protecting group, acetal-based protecting group, acyl-based protecting group, carbonate-based protecting group and silane-based protecting group, etc., are preferred. Department of protection base.

The ether-based protecting group is preferably a group represented by -R p1 ⁱⁿ -OR ^p1 (O represents an oxygen atom constituting a phenolic hydroxyl group; R ^p1 represents a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent). Examples of the hydrocarbon group having 1 to 20 carbon atoms represented by R ^p1 include R ^b1 to R ^b3 , R ^x2 , R ^x4 , R ^x5 , R ^X11 to R ^X13 , R ^X15 to R ^X17 , R ^y1 to R ^y5 , Examples of hydrocarbon groups having 1 to 20 carbon atoms represented by R ^y11 to R ^y13 and R ^y15 to R ^y17 include saturated chain hydrocarbon groups such as straight-chain alkyl groups and branched-chain alkyl groups, alkenyl groups, and alkynyl groups. Unsaturated chain hydrocarbon groups, saturated alicyclic hydrocarbon groups such as cycloalkyl groups, unsaturated alicyclic hydrocarbon groups such as cycloalkenyl groups, and aliphatic hydrocarbon groups such as saturated or unsaturated polycyclic hydrocarbon groups; aromatic hydrocarbon groups; and aralkyl groups , arylalkenyl, phenyl to which one or more phenyl groups are bonded, etc., any of the above-mentioned hydrocarbon groups combined.

The hydrocarbon group having 1 to 20 carbon atoms represented by R ^p1 may have a substituent, and examples of the substituent include halogen atoms such as fluorine atoms, chlorine atoms, bromine atoms, and iodine atoms, nitro groups, cyano groups, -OR ^xa1 , -CO ₂ R ^xa1 , -SR ^xa1 , -SO ₂ R ^xa1 , -SO ₃ R ^xa1 , -SO ₂ NR ^xa1 R ^xa2 , -NR ^xa1 R ^xa2 and the like (wherein, R ^xa1 and R ^xa2 are the same as above).

R ^p1 is preferably an optionally substituted linear or branched alkyl group having 1 to 20 carbon atoms, an optionally substituted aromatic hydrocarbon group having 6 to 20 carbon atoms, or an optionally substituted carbon group. An aralkyl group having a number of 7 to 20, more preferably a linear or branched alkyl group having a carbon number of 1 to 10 which may have a substituent, an aromatic hydrocarbon group having a carbon number of 6 to 10 which may have a substituent or an optional An aralkyl group having 7 to 10 carbon atoms having a substituent, more preferably methyl, ethyl, tert-butyl, phenyl, benzyl or p-methoxybenzyl.

The acetal-based protecting group is preferably -O ¹ -L ^p2 -O ² -R ^p2 (O ¹ represents the oxygen atom constituting the phenolic hydroxyl group; O ² represents the oxygen atom constituting the protecting group; L ^p2 represents the carbon number of 1 to 10 R ^p2 represents a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent; L ^p2 and R ^p2 may be bonded to each other to form a ring) The group represented by -L ^p2 -O ² -R ^p2 .

L ^p2 is preferably a straight-chain alkylene group having 1 to 10 carbon atoms, more preferably a straight-chain alkylene group having 1 to 5 carbon atoms, further preferably a methylene group, an ethylidene group, or a propylidene group. .

Examples of the optionally substituted hydrocarbon group having 1 to 20 carbons represented by R ^p2 include those described as the optionally substituted hydrocarbon group having 1 to 20 carbons represented by R ^p1 .

R ^p2 is preferably an optionally substituted linear or branched alkyl group having 1 to 20 carbon atoms, an optionally substituted aromatic hydrocarbon group having 6 to 20 carbon atoms, or an optionally substituted carbon group. An aralkyl group having a number of 7 to 20, more preferably a linear or branched alkyl group having 1 to 10 carbon atoms which may have a substituent or an aralkyl group having 7 to 10 carbon atoms which may have a substituent, and further Preferred is methyl, ethyl, propyl, butyl, benzyl, methoxymethyl, 2-methoxyethyl, ethoxymethyl or ethoxyethyl.

Specific examples of the acetal-based protecting group include methoxymethyl, ethoxymethyl, propoxymethyl, butoxyethyl, benzyloxyethyl, methoxymethoxy ethoxyethyl, 2-methoxyethoxymethyl, ethoxymethoxyethyl, ethoxyethoxyethyl, 2-tetrahydropyranyl, etc.

The acyl-based protecting group is preferably -C in -OC(=O)R ^p3 (O represents an oxygen atom constituting a phenolic hydroxyl group; R ^p3 represents a hydrogen atom or a hydrocarbon group with a carbon number of 1 to 20 that may have a substituent) The group represented by (=O)R ^p3 .

Examples of the optionally substituted hydrocarbon group having 1 to 20 carbons represented by R ^p3 include those described as the optionally substituted hydrocarbon group having 1 to 20 carbons represented by R ^p1 .

R ^p3 is preferably a hydrogen atom, an optionally substituted saturated or unsaturated chain hydrocarbon group having 1 to 20 carbon atoms, an optionally substituted aromatic hydrocarbon group having 6 to 20 carbon atoms, or an optionally substituted carbon group. An aralkyl group with a number of 7 to 20, more preferably a hydrogen atom, a saturated or unsaturated chain hydrocarbon group with a carbon number of 1 to 10 which may have a substituent, or an aromatic hydrocarbon group with a carbon number of 6 to 10 which may have a substituent, Further preferred is a hydrogen atom, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, vinyl, 1-methylvinyl, propenyl or phenyl.

Specific examples of the acyl-based protecting group include formyl, acetyl, propionyl, butyryl, pivaloyl, acryl, methacryl, and crotonyl. base, benzoyl group, etc.

The carbonate-based protecting group is preferably -O ¹ -C(=O ² )O ³ R ^p4 (O ¹ represents the oxygen atom constituting the phenolic hydroxyl group; O ² and O ³ represent the oxygen atom constituting the protecting group; R ^p4 represents A group represented by -C(=O ² )O ³ R ^p4 in a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent).

Examples of the optionally substituted hydrocarbon group having 1 to 20 carbons represented by R ^p4 include those described as the optionally substituted hydrocarbon group having 1 to 20 carbons represented by R ^p1 .

R ^p4 is preferably a saturated or unsaturated chain hydrocarbon group having 1 to 20 carbon atoms which may have a substituent, an aromatic hydrocarbon group having 6 to 20 carbon atoms which may have a substituent, or an optionally substituted aromatic hydrocarbon group having 7 to 20 carbon atoms. An aralkyl group of 20, more preferably a saturated or unsaturated chain hydrocarbon group having 1 to 10 carbon atoms which may have a substituent, or an aralkyl group having 7 to 15 carbon atoms which may have a substituent, further preferably a halogen atomic methyl, ethyl which may have a halogen atom, tert-butyl, allyl, benzyl or 9-fluorenylmethyl which may have a halogen atom.

As the carbonate-based protecting group, specifically, tert-butyloxycarbonyl, 2,2,2-trichloroethyloxycarbonyl, allyloxycarbonyl, benzyloxycarbonyl, 9 -Fluorenylmethyloxycarbonyl and the like.

The silane-based protecting group is preferably -O-Si(R ^p5 ) ₃ (O represents an oxygen atom constituting a phenolic hydroxyl group; R ^p5 represents a hydrocarbon group with a carbon number of 1 to 20 that may have a substituent; multiple R ^p5 can be the same may also be different), the group represented by -Si(R ^p5 ) ₃ .

Examples of the optionally substituted hydrocarbon group having 1 to 20 carbons represented by R ^p5 include those described as the optionally substituted hydrocarbon group having 1 to 20 carbons represented by R ^p1 .

R ^p5 is each independently preferably a linear or branched alkyl group having 1 to 20 carbons which may have a substituent, an aromatic hydrocarbon group having 6 to 20 carbons which may have a substituent, or an optionally substituted An aralkyl group having 7 to 20 carbon atoms as a group is independently more preferably a straight-chain or branched chain alkyl group having 1 to 10 carbon atoms which may have a substituent or an alkyl group having 6 to 10 carbon atoms which may have a substituent The aromatic hydrocarbon groups are independently further preferably methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl or phenyl.

As the silane-based protecting group, specifically, trimethylsilyl, triethylsilyl, tert-butyldimethylsilyl, triisopropylsilyl, tert-butyldiphenyl Silane, etc.

The latent antioxidant (E) is more preferably a compound represented by formula (E-1).

[式（E-1）中， X ^a表示n價有機基； n表示1～4的整數； X ⁰表示酚性羥基的保護基； m表示1～4的整數； X ⁴表示可具有取代基的碳數1～20的烴基，於m為2以上的情況下，存在有多個的X ⁴可相互相同亦可不同] [Chemical 57]

[In formula (E-1), X ^a represents an n-valent organic group; n represents an integer of 1 to 4; X ⁰ represents a protecting group for a phenolic hydroxyl group; m represents an integer of 1 to 4; X ⁴ represents an optional substituent A hydrocarbon group with 1 to 20 carbon atoms, when m is 2 or more, there are a plurality of X ⁴ may be the same or different from each other]

The n-valent organic group represented by X ^a is not particularly limited, but the following aspects (a) to (d) are preferable.

(a) When n=1 When n=1, X ^a is preferably a hydrocarbon group having 1 to 20 carbon atoms. Furthermore, when the carbon number of the hydrocarbon group is 2 to 20 and the hydrocarbon group has -CH ₂ -, the -CH ₂ - may be substituted with -O-, -CO-, -O-CO- or -CO- O-. However, the adjacent -CH ₂ -s are not substituted at the same time, and the terminal -CH ₂ - is not substituted.

Examples of the hydrocarbon group having 1 to 20 carbon atoms include R ^b1 to R ^b3 , R ^x2 , R ^x4 , R ^x5 , R ^X11 to R ^X13 , R ^X15 to R ^X17 , R ^y1 to R ^y5 , R ^y11 to R ^y13 and hydrocarbon groups having 1 to 20 carbon atoms represented by R ^y15 to R ^y17 may be saturated chain hydrocarbon groups such as linear alkyl groups and branched chain alkyl groups, unsaturated chain hydrocarbon groups such as alkenyl groups and alkynyl groups, etc. Saturated alicyclic hydrocarbon groups such as hydrocarbon groups and cycloalkyl groups, unsaturated alicyclic hydrocarbon groups such as cycloalkenyl groups, and aliphatic hydrocarbon groups such as saturated or unsaturated polycyclic hydrocarbon groups; aromatic hydrocarbon groups; and aralkyl groups and aryl alkenyl groups Any of the above-mentioned hydrocarbon groups such as a phenyl group, a phenyl group having one or more phenyl groups bonded thereto, and the like.

When n=1, X ^a is preferably a linear or branched alkyl group having 1 to 8 carbon atoms, at least one of -CH ₂ - constituting the alkyl group may be substituted with -O- CO- or -CO-O- group, a cycloalkyl group having 3 to 10 carbon atoms, or an aralkyl group having 7 to 10 carbon atoms, at least one of -CH ₂ - constituting the aralkyl group may be substituted with - A group of O-CO- or -CO-O-.

(b) When n=2 In the case of n=2, X ^a is preferably a group represented by the formula (e-2).

*-Z ¹ -Y ^e2 -Z ² -* (e-2) [wherein, Z ¹ and Z ² are each independently a single bond or an alkylene group having 1 to 20 carbon atoms, and the At least one of -CH ₂ - can be substituted with -O-, -CO-, -O-CO- or -CO-O-; wherein, the adjacent -CH ₂ - will not be substituted at the same time; Y ^e2 represents the number of carbons 1 to 30 (preferably 1 to 20) divalent hydrocarbon groups; when the hydrocarbon group has -CH ₂ -, at least one of the -CH ₂ - may be substituted with -O-, -S-, - CO-, -O-CO- or -CO-O-; wherein, the adjacent -CH ₂ - will not be substituted at the same time; * represents a bond]

Examples of divalent hydrocarbon groups having 1 to 20 carbon atoms represented by Y ^e2 include R ^b1 to R ^b3 , R ^x2 , R ^x4 , R ^x5 , R ^X11 to R ^X13 , R ^X15 to R ^X17 , R ^y1 to R ^y5 , The hydrocarbon groups represented by R ^y11 to R ^y13 and R ^y15 to R ^y17 are groups in which one of the hydrogen atoms in the exemplified groups is substituted with a bond, or the like.

The group represented by formula (e-2) is preferably any one of the groups represented by formula (eb-1) to formula (eb-20).

[式中， Z ¹及Z ²與所述相同； p表示1～19的整數，q表示1～3的整數，r表示0～3的整數； *表示鍵結鍵] [Chemical 58]

[wherein, Z ¹ and Z ² are the same as described above; p represents an integer of 1 to 19, q represents an integer of 1 to 3, and r represents an integer of 0 to 3; * represents a bond]

(c) When n=3 When n=3, X ^a is preferably a group represented by formula (e-3).

[式中， Z ³～Z ⁵分別獨立地為單鍵或碳數1～20的伸烷基，構成所述伸烷基的-CH ₂-的至少一個可經取代為-O-、-CO-、-O-CO-或-CO-O-；其中，鄰接的-CH ₂-不會同時進行取代； Y ^e3表示碳數1～20的三價烴基或碳數1～20的三價雜環基；於所述烴基及雜環基具有-CH ₂-的情況下，該-CH ₂-的至少一個可經取代為-O-、-CO-、-O-CO-或-CO-O-；其中，鄰接的-CH ₂-不會同時進行取代； *表示鍵結鍵] [Chemical 59]

[In the formula, Z ³ to Z ⁵ are each independently a single bond or an alkylene group with 1 to 20 carbons, and at least one of the -CH ₂ - constituting the alkylene group can be substituted with -O-, -CO -, -O-CO- or -CO-O-; Among them, the adjacent -CH ₂ - will not be substituted at the same time; Y ^e3 represents a trivalent hydrocarbon group with 1 to 20 carbons or a trivalent heterogeneous group with 1 to 20 carbons Cyclic group; when the hydrocarbon group and heterocyclic group have -CH ₂ -, at least one of the -CH ₂ - may be substituted with -O-, -CO-, -O-CO- or -CO-O -; wherein, the adjacent -CH ₂ - will not be substituted at the same time; * represents a bonding bond]

Examples of trivalent hydrocarbon groups having 1 to 20 carbon atoms represented by Y ^e3 include R ^b1 to R ^b3 , R ^x2 , R ^x4 , R ^x5 , R ^X11 to R ^X13 , R ^X15 to R ^X17 , R ^y1 to R ^y5 , The hydrocarbon groups represented by R ^y11 to R ^y13 and R ^y15 to R ^{y17 are} groups in which two of the hydrogen atoms in the exemplified groups are substituted with bonding bonds, or the like. Examples of the heterocyclic ring constituting the trivalent heterocyclic group having 1 to 20 carbon atoms represented by Y ^e3 include those used as substituents for the aliphatic unsaturated hydrocarbon group having 2 to 20 carbon atoms represented by R ^x1 and R ^x3 The heterocyclic ring and the like described in the heterocyclic group.

The group represented by formula (e-3) is preferably any one of the groups represented by formula (ec-1) to formula (ec-15).

[式中， Z ³～Z ⁵與所述相同； R ^ec1～R ^ec3分別獨立地表示氫原子或碳數1～20的烴基； p及r與所述相同； *表示鍵結鍵] [Chemical 60]

[wherein, Z ³ to Z ⁵ are the same as described above; R ^ec1 to R ^ec3 independently represent a hydrogen atom or a hydrocarbon group with 1 to 20 carbons; p and r are the same as described above; * represents a bond]

(d) When n=4 When n=4, X ^a is preferably a group represented by formula (e-4).

[式中， Z ⁶～Z ⁹分別獨立地為單鍵或碳數1～20的伸烷基，構成所述伸烷基的-CH ₂-的至少一個可經取代為-O-、-CO-、-O-CO-或-CO-O-；其中，鄰接的-CH ₂-不會同時進行取代； Y ^e4表示碳數1～20的四價烴基；於所述烴基具有-CH ₂-的情況下，該-CH ₂-的至少一個可經取代為-O-、-CO-、-O-CO-或-CO-O-；其中，鄰接的-CH ₂-不會同時進行取代； *表示鍵結鍵] [Chemical 61]

[In the formula, Z ⁶ to Z ⁹ are each independently a single bond or an alkylene group with 1 to 20 carbons, and at least one of the -CH ₂ - constituting the alkylene group can be substituted with -O-, -CO -, -O-CO- or -CO-O-; wherein, the adjacent -CH ₂ - will not be substituted at the same time; Y ^e4 represents a tetravalent hydrocarbon group with 1 to 20 carbons; the hydrocarbon group has -CH ₂ - In the case of , at least one of the -CH ₂ - may be substituted with -O-, -CO-, -O-CO- or -CO-O-; wherein, the adjacent -CH ₂ - will not be substituted at the same time; * indicates bonded key]

The tetravalent hydrocarbon groups having 1 to 20 carbon atoms represented by Y ^e4 include R ^b1 to R ^b3 , R ^x2 , R ^x4 , R ^x5 , R ^X11 to R ^X13 , R ^X15 to R ^X17 , R ^y1 to R ^y5 , The hydrocarbon groups represented by R ^y11 to R ^y13 and R ^y15 to R ^y17 are groups in which three of the hydrogen atoms in the exemplified groups are substituted with bonded bonds, or the like.

The group represented by formula (e-4) is preferably any one of the groups represented by formula (ed-1) to formula (ed-5).

[式中， Z ⁶～Z ⁹與所述相同； Z表示碳數1～10的伸烷基，構成所述伸烷基的-CH ₂-的至少一個可經取代為-O-、-CO-、-O-CO-或-CO-O-；其中，鄰接的-CH ₂-不會同時進行取代； R ^ed1及R ^ed2分別獨立地表示氫原子或碳數1～20的烴基； *表示鍵結鍵] [chem 62]

[In the formula, Z ⁶ to Z ⁹ are the same as described above; Z represents an alkylene group with 1 to 10 carbons, and at least one of the -CH ₂ - constituting the alkylene group can be substituted with -O-, -CO -, -O-CO- or -CO-O-; Among them, the adjacent -CH ₂ - will not be substituted at the same time; R ^ed1 and R ^ed2 independently represent a hydrogen atom or a hydrocarbon group with 1 to 20 carbons; * represents bond key]

The alkylene group represented by Z ¹ to Z ⁹ and Z may be linear or branched. The alkylene groups represented by Z ¹ to Z ⁹ and Z are independently preferably alkylene groups having 1 to 8 carbon atoms such as methylene, ethylidene, propylidene, butylene, and the like.

Z ¹ to Z ⁹ are each independently preferably a single bond or an alkylene group having 1 to 8 carbon atoms. At least one of -CH ₂ - constituting the alkylene group may be substituted with -O-, -CO The groups of -, -O-CO- or -CO-O- are each independently more preferably a single bond or at least one of -CH ₂ - constituting the alkylene group may be a single bond or an alkylene group having 1 to 8 carbon atoms. A group substituted with -O-CO- or -CO-O-. Z ¹ to Z ⁹ may be the same or different, Z ¹ and Z ² are preferably the same, Z ³ to Z ⁵ are preferably the same, and Z ⁶ to Z ⁹ are preferably the same.

Z is preferably an alkylene group having 1 to 8 carbon atoms.

Examples of hydrocarbon groups having 1 to 20 carbon atoms represented by R ^ec1 to R ^ec3 , R ^ed1 and R ^ed2 include R ^b1 to R ^b3 , R ^x2 , R ^x4 , R ^x5 , R ^X11 to R ^X13 , and R ^X15 to R The hydrocarbon groups represented by ^X17 , R ^y1 to R ^y5 , R ^y11 to R ^y13 and R ^y15 to R ^y17 are exemplified by saturated chain hydrocarbon groups such as straight-chain alkyls and branched-chain alkyls, alkenyl groups, Unsaturated chain hydrocarbon groups such as alkynyl groups, saturated alicyclic hydrocarbon groups such as cycloalkyl groups, unsaturated alicyclic hydrocarbon groups such as cycloalkenyl groups, and aliphatic hydrocarbon groups such as saturated or unsaturated polycyclic hydrocarbon groups; aromatic hydrocarbon groups; and aromatic hydrocarbon groups; Any of the above-mentioned hydrocarbon groups such as an alkyl group, an aryl alkenyl group, a phenyl group to which one or more phenyl groups are bonded, and the like. The carbon number of the hydrocarbon groups represented by R ^ec1 to R ^ec3 , R ^ed1 and R ^ed2 is preferably 1-10, more preferably 1-8, and still more preferably 1-4.

R ^ec1 to R ^ec3 , R ^ed1 and R ^ed2 are each independently preferably a hydrogen atom, a linear or branched alkyl group having 1 to 8 carbons (preferably 1 to 4), or a carbon number 3-8 cycloalkyl groups.

X ^a is preferably any one of the groups represented by formula (ec-1) to formula (ec-15) and formula (ed-1) to formula (ed-5), more preferably formula (ed-1 ) to any one of the groups represented by the formula (ed-5), more preferably the group represented by the formula (ed-1).

The bonding position of X ^a is not particularly limited, but it is preferably bonded at the para position with respect to the bonding position of the oxygen atom.

As X ⁰ , the groups described as the protecting group for protecting the above-mentioned phenolic hydroxyl group are mentioned, and the preferred aspects are also the same.

m is preferably 1 or 2.

Examples of the hydrocarbon group having 1 to 20 carbon atoms represented by X ⁴ include R ^b1 to R ^b3 , R ^x2 , R ^x4 , R ^x5 , R ^X11 to R ^X13 , R ^X15 to R ^X17 , R ^y1 to R ^y5 , The hydrocarbon groups represented by R ^y11 to R ^y13 and R ^y15 to R ^y17 are exemplified by saturated chain hydrocarbon groups such as linear alkyl groups and branched chain alkyl groups, and unsaturated chain hydrocarbon groups such as alkenyl groups and alkynyl groups. , cycloalkyl and other saturated alicyclic hydrocarbon groups, cycloalkenyl and other unsaturated alicyclic hydrocarbon groups and saturated or unsaturated polycyclic hydrocarbon groups and other aliphatic hydrocarbon groups; aromatic hydrocarbon groups; and aralkyl, aryl alkenyl, Any of a combination of the above-mentioned hydrocarbon groups such as a phenyl group to which one or more phenyl groups are bonded.

The hydrocarbon group having 1 to 20 carbon atoms represented by X ⁴ may have a substituent, and examples of the substituent include halogen atoms such as fluorine atom, chlorine atom, bromine atom, iodine atom, nitro group, cyano group, -OR ^xa1 , -COR ^xa1 , -OCOR ^xa1 , -CO ₂ R ^xa1 , -SR ^xa1 , -SO ₂ R ^xa1 , -SO ₃ R ^xa1 , -SO ₂ NR ^{xa1 R xa2} , -NR ^xa1 R ^xa2 , -CONR ^xa1 R ^xa2 etc. (wherein, R ^xa1 and R ^xa2 are the same as described above).

X ⁴ is preferably a linear or branched alkyl group having 1 to 20 carbons which may have a substituent, more preferably a linear or branched alkyl group having 1 to 10 carbons, and further A linear or branched alkyl group having 1 to 4 carbon atoms is preferable. In addition, it is preferred that at least one of the m X ⁴ is a tertiary alkyl group with 4 to 10 carbons, and it is particularly preferred that at least one of the m X ⁴ is a tertiary butyl group or a tertiary pentyl group.

The substitution position of X ⁴ is not particularly limited, but X 4 is preferably bonded to at least one ortho position with respect to the position to ^{which the oxygen atom is bonded, more preferably X 4 is} bonded to two ortho positions.

As a potential antioxidant (E), it is more preferably a compound represented by formula (E-2).

[式（E-2）中， X ¹、X ²及X ³分別獨立地表示碳數1～10的烴基； X ^a、n、X ⁴及m與所述相同] [chem 63]

[In formula (E-2), X ¹ , X ² and X ³ independently represent a hydrocarbon group with 1 to 10 carbon atoms; X ^a , n, X ⁴ and m are the same as above]

Examples of the hydrocarbon groups having 1 to 10 carbon atoms represented by X ¹ to X ³ include R ^b1 to R ^b3 , R ^x2 , R ^x4 , R ^x5 , R ^X11 to R ^{X13 , R X15 to} R ^X17 , R ^y1 to The hydrocarbon groups represented by R ^y5 , R ^y11 to R ^y13 and R ^y15 to R ^y17 are exemplified groups having 1 to 10 carbon atoms, which may be saturated chain hydrocarbon groups such as straight-chain alkyl groups and branched-chain alkyl groups. , alkenyl, alkynyl and other unsaturated chain hydrocarbon groups, cycloalkyl and other saturated alicyclic hydrocarbon groups, cycloalkenyl and other unsaturated alicyclic hydrocarbon groups, and saturated or unsaturated polycyclic hydrocarbon groups and other aliphatic hydrocarbon groups; aromatic hydrocarbon groups ; and any of a combination of hydrocarbon groups such as an aralkyl group, an arylalkenyl group, or a phenyl group to which one or more phenyl groups are bonded.

X ¹ to X ³ are each independently preferably a straight-chain or branched alkyl group having 1 to 10 carbons which may have a substituent, and each independently more preferably a straight-chain alkyl group having 1 to 4 carbons. The alkyl groups are independently further preferably methyl or ethyl.

As a latent antioxidant (E), the compound represented by formula (E-3) is especially preferable.

[式（E-3）中， X ¹⁰表示碳數4～20的三級烷基； s表示0～3的整數； X ^a、n及X ¹～X ⁴與所述相同] [chem 64]

[In formula (E-3), X ¹⁰ represents a tertiary alkyl group with 4 to 20 carbons; s represents an integer of 0 to 3; X ^a , n and X ¹ to X ⁴ are the same as described above]

X ¹⁰ is preferably a tertiary alkyl group having 4 to 10 carbon atoms, more preferably a tertiary butyl group or a tertiary pentyl group.

s is preferably 0 or 1. When s is 1, X ⁴ is preferably bonded at an ortho position with respect to the position to which the oxygen atom is bonded. In this case, X ⁴ is preferably a tertiary alkyl group having 4 to 10 carbons, more preferably a tertiary butyl group or a tertiary pentyl group.

The content of the latent antioxidant (E) is, for example, 1% by mass or more, preferably 2% by mass or more, more preferably 3% by mass or more, and, for example, 20% by mass or less with respect to the total amount of solid content. Preferably it is 15 mass % or less, More preferably, it is 10 mass % or less. In addition, the content of the latent antioxidant (E) is, for example, 25 parts by mass or more, preferably 100 parts by mass or more, more preferably 150 parts by mass or more, and still more preferably 180 parts by mass with respect to 100 parts by mass of the aluminum phthalocyanine compound. part or more, and, for example, 350 parts by mass or less, preferably 300 parts by mass or less, more preferably 250 parts by mass or less. Furthermore, the content ratio of the latent antioxidant (E) to the polymerization initiator (D) (potential antioxidant (E)/polymerization initiator (D)) is, for example, 0.5 or more, preferably 1 or more, and more preferably It is preferably 2 or more, and, for example, 10 or less, preferably 8 or less, more preferably 5 or less. When the amount of the latent antioxidant (E) is within the above range, it is possible to provide a curable colored composition having better pattern stability even after storage.

＜Leveling agent (F)＞ Examples of the leveling agent (F) include silicone-based surfactants, fluorine-based surfactants, silicone-based surfactants having a fluorine atom, and the like. These may have a polymeric group on a side chain. Examples of the silicone-based surfactant include those having a siloxane bond in the molecule, and the like. Specifically, Toray silicone DC3PA, Toray silicone SH7PA, Toray silicone DC11PA, Toray silicone SH21PA, Toray silicone Toray silicone SH28PA, Toray silicone SH29PA, Toray silicone SH30PA, Toray silicone SH8400 (trade name; Toray Dow Corning (shares) ) manufacturing), KP321, KP322, KP323, KP324, KP326, KP340, KP341 (Shin-Etsu Chemical Industry Co., Ltd. material (Momentive Performance Materials Japan) Co., Ltd.) etc.

As said fluorine-type surfactant, the thing which has a fluorocarbon chain in a molecule|numerator, etc. are mentioned. Specifically, examples include: Fluorad (registered trademark) FC430, Fluorad (Fluorad) FC431 (manufactured by Sumitomo 3M Co., Ltd.), Megafac (registered trademark) F142D, Megafac ) F171, Megafac F172, Megafac F173, Megafac F177, Megafac F183, Megafac F554, Megafac R30, Megafac RS-718-K (manufactured by DIC), Eftop (registered trademark) EF301, Eftop EF303, Eftop EF351, Eftop ) EF352 (manufactured by Mitsubishi Materials Corporation), Surflon (registered trademark) S381, Surflon S382, Surflon SC101, Surflon SC105 (AGC (stock) (manufactured by former Asahi Glass Co., Ltd.) and E5844 (manufactured by Daikin Fine Chemical Research Institute (stock)), etc.

Examples of the silicone-based surfactant having a fluorine atom include a surfactant having a siloxane bond and a fluorocarbon chain in the molecule, and the like. Specifically, examples include: Megafac (registered trademark) R08, Megafac BL20, Megafac F475, Megafac F477 and Megafac F443 (DIC ) (share) manufacturing) etc.

The content of the leveling agent (F) is preferably from 0.001% by mass to 0.2% by mass, more preferably from 0.002% by mass to 0.1% by mass, and still more preferably from 0.005% by mass to 0.05% by mass, based on the total amount of the colored curable composition. quality%. In addition, this content rate does not include the content rate of the said pigment dispersant. When the content rate of a leveling agent (F) exists in the said range, the flatness of a color filter can be made favorable.

<Solvent (G)> The solvent (G) is not particularly limited, and solvents generally used in this field can be used. For example, ester solvents (solvents containing -COO- and not containing -O- in the molecule), ether solvents (solvents containing -O- and not containing -COO- in the molecule), ether ester solvents (solvents containing -O- in the molecule) Solvents containing -COO- and -O-), ketone solvents (solvents containing -CO- and not containing -COO- in the molecule), alcohol solvents (containing OH in the molecule and not containing -O-, -CO - and -COO- solvents), aromatic hydrocarbon solvents, amide solvents, dimethyl sulfide, etc.

Examples of ester solvents include methyl lactate, ethyl lactate, butyl lactate, methyl 2-hydroxyisobutyrate, ethyl acetate, n-butyl acetate, isobutyl acetate, amyl formate, isoamyl acetate , butyl propionate, isopropyl butyrate, ethyl butyrate, butyl butyrate, methyl pyruvate, ethyl pyruvate, propyl pyruvate, methyl acetyl acetate, ethyl acetyl acetate, cyclo Hexanol acetate and γ-butyrolactone, etc.

Examples of ether solvents include ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monopropyl ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, Ethylene glycol monobutyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monopropyl ether, propylene glycol monobutyl ether, 3-methoxy-1-butanol, 3-methoxy-3-methylbutanol, Tetrahydrofuran, tetrahydropyran, 1,4-dioxane, diethylene glycol dimethyl ether, diethylene glycol diethyl ether, diethylene glycol methyl ethyl ether, diethylene glycol dipropyl ether, diethyl ether Diol dibutyl ether, anisole, phenetole and methyl anisole, etc.

Examples of ether ester solvents include: methyl methoxyacetate, ethyl methoxyacetate, butyl methoxyacetate, methyl ethoxyacetate, ethyl ethoxyacetate, and 3-methoxypropionic acid Methyl ester, ethyl 3-methoxypropionate, methyl 3-ethoxypropionate, ethyl 3-ethoxypropionate, methyl 2-methoxypropionate, 2-methoxypropionate Ethyl ester, propyl 2-methoxypropionate, methyl 2-ethoxypropionate, ethyl 2-ethoxypropionate, methyl 2-methoxy-2-methylpropionate, 2- Ethoxy-2-methylpropionate, 3-methoxybutyl acetate, 3-methyl-3-methoxybutyl acetate, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate , Propylene glycol monopropyl ether acetate, ethylene glycol monomethyl ether acetate, ethylene glycol monoethyl ether acetate, diethylene glycol monoethyl ether acetate and diethylene glycol monobutyl ether acetate, etc.

Examples of ketone solvents include: 4-hydroxy-4-methyl-2-pentanone (sometimes called diacetone alcohol), acetone, 2-butanone, 2-heptanone, 3-heptanone, 4-heptanone Ketone, 4-methyl-2-pentanone, cyclopentanone, cyclohexanone and isophorone, etc.

Examples of the alcohol solvent include methanol, ethanol, propanol, butanol, hexanol, cyclohexanol, ethylene glycol, propylene glycol, and glycerin.

Examples of the aromatic hydrocarbon solvent include benzene, toluene, xylene, and mesitylene.

Examples of the amide solvent include N,N-dimethylformamide, N,N-dimethylacetamide, N-methylpyrrolidone, and the like.

The solvent (G) is preferably at least one selected from the group consisting of ether solvents, ether ester solvents and amide solvents, more preferably includes ether solvents, ether ester solvents and amide solvents, and further preferably includes diethyl Glycol methyl ethyl ether, propylene glycol monomethyl ether acetate and N-methylpyrrolidone. In addition, the solvent (G) preferably contains one or more types selected from the group consisting of ether ester solvents and ketone solvents.

In addition, among the above-mentioned solvents, organic solvents having a boiling point at 1 atm of 120° C. to 180° C. are preferable from the viewpoint of coating properties and drying properties. As such a solvent, it is preferably selected from the group consisting of propylene glycol monomethyl ether acetate, ethyl lactate, propylene glycol monomethyl ether, 3-ethoxy ethyl propionate, ethylene glycol monomethyl ether, diethylene glycol monomethyl At least one selected from the group consisting of ether, diethylene glycol monoethyl ether, 4-hydroxy-4-methyl-2-pentanone and N,N-dimethylformamide, more preferably selected from propylene glycol monoethyl ether At least one selected from the group consisting of methyl ether acetate, propylene glycol monomethyl ether, ethyl lactate, ethyl 3-ethoxypropionate and 4-hydroxy-4-methyl-2-pentanone.

The content of the solvent (G) is preferably from 70% by mass to 95% by mass, more preferably from 75% by mass to 92% by mass, based on the total amount of the curable colored composition. In other words, the solid content of the colored curable composition is preferably 5% by mass to 30% by mass, more preferably 8% by mass to 25% by mass. If the content of the solvent (G) is within the above range, the flatness at the time of coating will be good, and the color density will not be insufficient when forming a color filter, so the display characteristics tend to be good.

＜Other ingredients＞ The colored curable composition may also contain additives known in the technical field such as fillers, other polymer compounds, adhesion promoters, antioxidants, light stabilizers, and chain transfer agents as necessary.

<Manufacturing method of colored curable composition> The colored curable composition can be obtained by, for example, combining a colorant (A) containing an aluminum phthalocyanine compound, a resin (B), a polymerizable compound (C), a polymerization initiator (D) and a latent antioxidant (E) and Prepared by mixing the polymerization initiation aid (D1), leveling agent (F), solvent (G) and other components as needed. The aluminum phthalocyanine compound may be contained in the dispersion in advance. In addition, when a pigment is contained, the pigment may be previously contained in the dispersion liquid. In the case of including a pigment, the aluminum phthalocyanine compound and the pigment may be prepared as one dispersion or as separate dispersions. By mixing the remaining components in the dispersion liquid so as to have a predetermined concentration, the intended colored curable composition can be prepared. When the dye is contained, the dye may be dissolved in part or all of the solvent (G) in advance to prepare a solution. Preferably, the solution is filtered with a filter having a pore size of about 0.01 μm to 1 μm. It is preferable to filter the colored curable composition after mixing with a filter having a pore diameter of about 0.01 μm to 10 μm.

＜＜Color Filter＞＞ Examples of the method for producing a colored pattern of a color filter from the colored curable composition of the present invention include a photolithography method, an inkjet method, a printing method, and the like. Among them, photolithography is preferred. Photolithography is a method of applying the colored curable composition on a substrate, drying it to form a composition layer, and exposing and developing the composition layer through a photomask. In photolithography, a colored coating film that is a hardened product of the composition layer can be formed by not using a mask and/or developing during exposure. The colored pattern or colored coating film formed in this way is the color filter of this invention.

The film thickness of the color filter (colored coating film) is, for example, 30 μm or less, preferably 20 μm or less, more preferably 6 μm or less, further preferably 3 μm or less, still more preferably 1.5 μm or less, particularly preferably 0.5 μm or less, preferably 0.1 μm or more, more preferably 0.2 μm or more, still more preferably 0.3 μm or more.

As the substrate, glass plates such as quartz glass, borosilicate glass, alumina silicate glass, and soda lime glass whose surface is coated with silica; or polycarbonate, polymethyl methacrylate, poly Resin plates such as ethylene terephthalate; silicon; aluminum, silver, silver/copper/palladium alloy thin films, etc. formed on the above-mentioned substrates. Other color filter layers, resin layers, transistors, circuits, etc. may also be formed on these substrates. In addition, a substrate obtained by treating a silicon substrate with hexamethyldisilazane (HMDS) may also be used.

The formation of pixels of each color by photolithography can be performed by known or commonly used devices or conditions. For example, it can be produced as follows. First, a colored curable composition is applied on a substrate, and then dried by heat drying (prebaking) and/or reduced pressure drying to remove volatile components such as solvents to obtain a smooth composition layer. As a coating method, a spin coating method, a slit coating method, a slit and spin coating method, etc. are mentioned. The temperature at the time of heating and drying is preferably from 30°C to 120°C, more preferably from 50°C to 110°C. In addition, the heating time is preferably from 10 seconds to 60 minutes, more preferably from 30 seconds to 30 minutes. When performing reduced-pressure drying, it is preferable to carry out at the temperature range of 20-25 degreeC under the pressure of 50 Pa-150 Pa. The film thickness of the composition layer is not particularly limited, and may be appropriately selected according to the film thickness of the intended color filter.

Next, the composition layer is exposed through a photomask for forming a target colored pattern. The pattern on this photomask is not specifically limited, The pattern according to the intended use can be used. As a light source used for exposure, the light source which generate|occur|produces the light of the wavelength of 250 nm - 450 nm is preferable. For example, for light less than 350 nm, use a filter that cuts off this wavelength range, or for light near 436 nm, 408 nm, or 365 nm, use a bandpass filter that extracts these wavelength ranges. Selective extraction. Specifically, a mercury lamp, a light emitting diode, a metal halide lamp, a halogen lamp, etc. are mentioned. In order to uniformly irradiate the entire exposure surface with parallel light rays or perform accurate alignment between the mask and the substrate, it is preferable to use a reduction projection exposure device such as a mask aligner and a stepper, or a proximity type (proximity) exposure device.

The exposed composition layer is developed by contacting a developer to form a colored pattern on the substrate. By developing, the unexposed portion of the composition layer is dissolved in a developing solution and removed. As a developing solution, for example, an aqueous solution of a basic compound such as potassium hydroxide, sodium bicarbonate, sodium carbonate, tetramethylammonium hydroxide, or the like is preferable. The concentration of these basic compounds in the aqueous solution is preferably 0.01% by mass to 10% by mass, more preferably 0.03% by mass to 5% by mass. Furthermore, the developer may also contain a surfactant. The developing method may be any one of a liquid covering method, a dipping method, a spraying method, and the like. Furthermore, it is also possible to incline a board|substrate at an arbitrary angle at the time of image development. After image development, it is preferable to perform water washing.

Furthermore, it is preferable to post-bak the obtained colored pattern. The post-baking temperature is preferably from 80°C to 250°C, more preferably from 100°C to 245°C. The post-baking time is preferably from 1 minute to 120 minutes, more preferably from 2 minutes to 30 minutes.

The thus-obtained colored pattern and colored coating film are effectively used as a color filter, and the color filter is effectively used as a display device (for example, a liquid crystal display device, an organic electroluminescence (EL) device, etc.), electronic paper, Color filters used in solid-state imaging devices, etc. [Example]

Hereinafter, examples are given to illustrate the present invention in more detail, but the present invention is of course not limited to the following examples. In the examples, "part" means "mass part" and "%" means "mass %" unless otherwise specified.

(Synthesis Example 1) A compound represented by the following formula (x1) (hereinafter referred to as compound (x1)) was obtained by the method of paragraph 0185 of Japanese Patent Application Publication No. 2016-75837.

[chem 65]

(Synthesis Example 2) A compound represented by the following formula (x2) (hereinafter referred to as compound (x2)) was obtained by the method described in Japanese Patent Application Publication No. 2016-75837.

[chem 66]

(Resin Synthesis Example 1) An appropriate amount of nitrogen gas was flowed into a flask including a reflux cooler, a dropping funnel, and a stirrer to replace it with a nitrogen atmosphere, and 340 parts of propylene glycol monomethyl ether acetate was put in, and heated to 80° C. while stirring. Then, 57 parts of acrylic acid, 3,4-epoxytricyclo[5.2.1.0 ^2,6 ]decane-8-yl acrylate and 3,4-epoxytricyclo[5.2.1.0 ^{2 , 6} ] A mixture of 54 parts of a mixture of decane-9-yl esters (with a molar ratio of 1:1), 239 parts of benzyl methacrylate, and 73 parts of propylene glycol monomethyl ether acetate. On the other hand, a solution obtained by dissolving 40 parts of the polymerization initiator 2,2-azobis(2,4-dimethylvaleronitrile) in 197 parts of propylene glycol monomethyl ether acetate was added dropwise over 6 hours. . After the dropwise addition of the solution containing the polymerization initiator was completed, it was kept at 80°C for 3 hours, and then cooled to room temperature to obtain a viscosity of 137 mPa·s and a solid content of 36.8% by weight of a copolymer (resin (B-1)) solution. The produced copolymer had a polystyrene-equivalent weight average molecular weight of 1.0×10 ³ , a degree of dispersion of 1.97, and a solid content-equivalent acid value of 111 mg-KOH/g. Resin (B-1) has the following structural units.

[chem 67]

(Resin Synthesis Example 2) 276.8 parts of propylene glycol monomethyl ether acetate was charged into a flask including a stirring device, dropping funnel, condenser, thermometer, and gas introduction tube, stirred while replacing nitrogen gas, and heated to 120°C . Then, the following solution was added from the dropping funnel over 2 hours to a monomer mixture containing 92.4 parts of 2-ethylhexyl acrylate, 184.9 parts of glycidyl methacrylate and 12.3 parts of dicyclopentanyl methacrylate. A solution comprising 35.3 parts of tert-butyl peroxy-2-ethylhexanoate (polymerization initiator) was dropped into the flask. After completion of the dropwise addition, the mixture was further stirred at 120° C. for 30 minutes to carry out a copolymerization reaction to produce an addition copolymer. Thereafter, the inside of the flask was replaced with air, and 93.7 parts of acrylic acid, 1.5 parts of triphenylphosphine (catalyst) and 0.8 parts of hydroquinone monomethyl ether (polymerization inhibitor) were put into the addition copolymer solution, The reaction is continued at 110°C for 10 hours, and the epoxy group is cleaved by the reaction of the epoxy group derived from glycidyl methacrylate with acrylic acid, and at the same time, a polymerizable unsaturated bond is introduced into the side chain of the polymer middle. Next, 24.2 parts of succinic anhydride was added to the reaction system, and the reaction was continued at 110° C. for 1 hour to react the hydroxyl groups generated by the cleavage of epoxy groups with succinic anhydride to introduce carboxyl groups into side chains to obtain polymers. Finally, 383.3 parts of propylene glycol monomethyl ether acetate were added to the reaction solution to obtain a polymer (resin (B-2)) solution having a polymer solid content of 40%. The produced copolymer (polymer; resin (B-2)) had a weight average molecular weight Mw of 6.3×10 ³ and an acid value in terms of solid content of 34 mg-KOH/g.

(Preparation of dispersion liquid 1) 12.0 parts of C.I. Pigment Blue 15:4, 3.6 parts of dispersant (BYKLPN-6919 manufactured by BYK), 5.4 parts of resin (B-1) (solid content conversion), propylene glycol monomethyl ether acetate 79 parts were mixed, 300 parts of 0.4 mm zirconia beads were added, and shaken for 1 hour using a paint conditioner (manufactured by LAU). Thereafter, the zirconia beads were removed by filtration to obtain a dispersion liquid 1 .

(Preparation of dispersion liquid 2) Mix 5.0 parts of compound (x1), 4.0 parts of dispersant (BYKLPN-6919 manufactured by BYK), 4.0 parts of resin (B-1) (in terms of solid content), and 87 parts of propylene glycol monomethyl ether acetate , and 300 parts of 0.4 mm zirconia beads were added, and shaken for 1 hour using a paint conditioner (manufactured by LAU). Thereafter, the zirconia beads were removed by filtration to obtain a dispersion 2.

(Preparation of Dispersion 3) Mix 5.0 parts of compound (x2), 4.0 parts of dispersant (BYKLPN-6919 manufactured by BYK), 4.0 parts of resin (B-1) (in terms of solid content), and 87 parts of propylene glycol monomethyl ether acetate , and 300 parts of 0.4 mm zirconia beads were added, and shaken for 1 hour using a paint conditioner (manufactured by LAU). Thereafter, the zirconia beads were removed by filtration to obtain a dispersion liquid 3 .

[Example 1 to Example 2, Comparative Example 1] (Preparation of Colored Curable Composition) The components shown in Table 36 were mixed to obtain each colored curable composition.

[Table 36] Unit is part Comparative example 1 Example 1 Example 2 Colorant A-1 668 733 A-2 93 102 77 A-3 555 resin B-2 38.2 35.2 43.7 polymeric compound C-1 30 30 30 polymerization initiator D-1 3.5 3.5 4.0 potential antioxidant E-1 10 10 leveling agent F-1 0.1 0.1 0.1 solvent G-1 131 143 319 G-2 521 572 428

In Table 36, each component is as follows. Colorant (A-1): Dispersion 1 Colorant (A-2): Dispersion 2 Colorant (A-3): Dispersion 3 Resin (B-2): Resin (B-2) (solid content conversion) Polymerizable compound (C-1): Ethylene oxide-modified dipentaerythritol hexaacrylate ("A-DPH12E" manufactured by Shin-Nakamura Chemical Co., Ltd., number of ethylene oxide chains: 6, solid content conversion) Polymerization initiator (D-1): N-acetyloxy-1-(4-phenylthiophenyl)-3-cyclohexylpropane-1-one-2-imine (Changzhou Qiangli Electronic New Material "TR-PBG327" manufactured by the company) Potential antioxidant (E-1): GPA-5001 (manufactured by ADEKA, molecular weight = 1578) (solid content conversion) Leveling agent (F-1): polyether modified silicone oil; trade name Toray Silicone (Toray Silicone) SH8400; manufactured by Toray Dow Corning (stock) (solid content conversion) Solvent (G-1): diacetone alcohol Solvent (G-2): Propylene glycol monomethyl ether acetate

(Preparation of colored patterns) On a 4-inch silicon substrate, each of the colored curable compositions of Examples and Comparative Examples was coated by spin coating so that the film thickness after post-baking became 0.8 μm, and then Pre-baking at 80° C. for 2 minutes to obtain a colored composition layer. After cooling, the substrate on which the colored composition layer was formed was irradiated with light at an exposure dose of 300 mJ/cm ² (based on 365 nm) using an exposure machine (NSR-1755i7A; manufactured by Nikon Co., Ltd.). As the photomask, a 2.0 μm square photomask on which a dot pattern was formed was used. The colored composition layer after light irradiation was dipped and developed in an aqueous developer solution containing tetramethylammonium hydroxide at 23°C for 30 seconds. After washing with water, the developed (before baking) substrate was post-baked at 230°C Bake for 10 minutes to obtain Coloring Pattern I after post-baking. In addition, after storing the colored curable compositions of Example 1 and Comparative Example 1 at 40° C. for 3 days, the colored pattern II after post-baking was obtained by the same method as described above. After storing the curable colored composition of Example 2 at 40° C. for one day, the post-baked colored pattern II was obtained by the same method as described above.

(Evaluation of hemability of coloring patterns) For the obtained silicon wafer substrate with colored pattern I or colored pattern II, use an electron microscope (S-4100, manufactured by Hitachi Technology Co., Ltd.) to observe the formed colored pattern at a magnification of 30,000 times, based on the following formula The change rate of the line width was evaluated. The results are shown in Table 37. The closer the line width change rate is to 1 (ie, 100%), the more the decrease in the line width of the pattern is suppressed, which is preferable. Line width change rate = (line width of coloring pattern II/line width of coloring pattern I) × 100

[Table 37] line width change rate Comparative example 1 0% Example 1 95% Example 2 87%

In the comparative example not containing a latent antioxidant, no pattern was formed when the preserved colored curable composition was used. On the other hand, in the example containing a latent antioxidant, even when using the curable coloring composition after storage, the reduction of the line width of a pattern was suppressed.

Claims (8)

A colored curable composition, containing colorants, resins, polymerizable compounds, polymerization initiators and latent antioxidants, The colorant comprises an aluminum phthalocyanine compound, The polymerization initiator includes an oxime compound. The colored curable composition according to claim 1, wherein the latent antioxidant is a compound in which a phenolic hydroxyl group of a phenolic antioxidant is protected by a protecting group. The colored curable composition according to claim 1, wherein the aluminum phthalocyanine compound is a compound represented by formula (Xa) or formula (Xb);

[In the formula (Xa), Z represents a hydroxyl group, a chlorine atom, -OP(=O)R ^a1 R ^a2 , -O-SiR ^a3 R ^a4 R ^a5 , -OC(=O)R ^a13 or -OS(=O) ₂ R ^a14 ; R ^a1 to R ^a5 and R ^a13 to R ^a14 each independently represent a hydrogen atom, a hydroxyl group, a hydrocarbon group with 1 to 20 carbons which may have a substituent, or a heterocyclic ring with 1 to 20 carbons which may have a substituent R ^a1 and R ^a2 or any two of R ^a3 to R ^a5 can be bonded to each other to form a ring; when the carbon number of the hydrocarbon group is 2 to 20 and the hydrocarbon group has -CH ₂ -, the The -CH ₂ - can be substituted with -O-, -S- or -CO-; X ^x1 ~ X ^x4 independently represent -R ^x4 , -OR ^x4 , -SR ^x4 , -SO ₃ H, -SO ₃ ^- T ⁺ , -SO ₃ R ^X10 , -SO ₂ NR ^X11 R ^X12 , a halogen atom or a nitro group; R ^x4 represents a hydrocarbon group with a carbon number of 1 to 20 that may have a substituent, and the carbon number of the hydrocarbon group is 2 to 2 20 and when the hydrocarbon group has -CH ₂ -, the -CH ₂ - may be substituted with -O-, -S- or -CO-; T ⁺ means ⁺ N(R ^X13 ) ₄ or an alkali metal ion , R ^X13 each independently represents a hydrogen atom or a hydrocarbon group with 1 to 20 carbons; R ^X10 represents a saturated hydrocarbon group with 1 to 20 carbons; R ^X11 and R ^X12 each independently represent a hydrogen atom or a carbon number 1 that may have a substituent ~20 hydrocarbon groups; nx1~nx4 independently represent an integer of 0~4; in formula (Xb), L represents -O-SiR ^a6 R ^a7 -O-, -O-SiR ^a8 R ^a9 -O-SiR ^a10 R ^a11 -O- or -OP(=O)R ^a12 -O-; R ^a6 to R ^a12 each independently represent a hydrogen atom, a hydroxyl group, a hydrocarbon group with 1 to 20 carbons that may have a substituent, or a carbon that may have a substituent A heterocyclic group with a number of 1 to 20, R ^a6 and R ^a7 , R ^a8 and R ^a9 or R ^a10 and R ^a11 can be bonded to each other to form a ring; when the carbon number of the hydrocarbon group is 2 to 20 and the hydrocarbon group has In the case of -CH ₂ -, the -CH ₂ - may be substituted with -O-, -S- or -CO-; X ^x5 to X ^x12 independently represent -R ^x5 , -OR ^x5 , -SR ^x5 , -SO ₃ H, -SO ₃ ^{-Q +} , -SO ₃ R ^X14 , -SO ₂ NR ^X15 R ^X16 , a halogen atom or a nitro group; R ^x5 represents a hydrocarbon group with a carbon number of 1 to 20 that may have substituents. When the carbon number of the hydrocarbon group is 2-20 and the hydrocarbon group has -CH ₂ -, the -CH ₂ - may be substituted with -O-, -S- or -CO-; Q ⁺ means ⁺ N (R ^X17 ) ₄ or an alkali metal ion, R ^X17 each independently represents a hydrogen atom or a hydrocarbon group with 1 to 20 carbons; R ^X14 represents a saturated hydrocarbon group with 1 to 20 carbons; R ^X15 and R ^X16 each independently represent a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms which may have a substituent; nx5 to nx12 each independently represent an integer of 0 to 4]. The colored curable composition according to claim 3, wherein the compound represented by the formula (Xa) is the compound represented by the formula (X0) or the formula (XI), and the compound represented by the formula (Xb) is the compound represented by the formula ( Compounds represented by XII);

[In formula (XI), R ^x1 represents an aliphatic unsaturated hydrocarbon group having 2 to 20 carbon atoms which may have a substituent or an aromatic hydrocarbon group having 6 to 20 carbon atoms which may have a substituent, and R ^x2 represents a hydrogen atom, which may have A hydrocarbon group with 1 to 20 carbon atoms in the substituent or a single bond connecting Z ^x2 and R ^x1 ; Z ^x1 and Z ^x2 independently represent a single bond or an oxygen atom; in formula (X0) and formula (XI), X ^x1 ～X ^x4 , nx1～nx4 are the same as described above; in formula (XII), R ^x3 represents an aliphatic unsaturated hydrocarbon group with 2 to 20 carbon atoms that may have substituents or an aromatic group with 6 to 20 carbon atoms that may have substituents family hydrocarbon group; Z ^x3 represents a single bond or an oxygen atom; X ^x5 ~ X ^x12 , nx5 ~ nx12 are the same as described]. The colored curable composition according to claim 3, wherein nx1-nx12 are 0. A color filter formed of the colored curable composition according to any one of claim 1 to claim 5. A display device comprising the color filter as claimed in Claim 6. A solid-state imaging device, comprising the color filter described in claim 6.