TW202308845A - Multilayer optical film - Google Patents

Abstract

A multilayer optical film (X) according to the present invention is sequentially provided with an optical film (10), an adhesive layer (30) and an optical film (20) in the thickness direction (H). The adhesive layer (30) is bonded to the optical film (10), while also being bonded to the optical film (20). The adhesive layer (30) has an extended end part (30a). The extended end part (30a) extends outwardly beyond an edge (11) of the optical film (10) and an edge (21) of the optical film (20) in a plane direction that is perpendicular to the thickness direction (H).

Description

Laminated Optical Film

The invention relates to a laminated optical film.

The display panel has, for example, a laminated structure including a pixel panel, a touch panel, a surface protection cover, and the like. The laminated structure of the display panel also includes various functional optical films with predetermined optical functions. Examples of functional optical films include polarizer films and retardation films. A functional optical film is, for example, incorporated into a laminated structure in a state where it is bonded to another optical film such as a protective film through an adhesive, that is, in the form of a laminated optical film. Such a laminated optical film is described, for example, in Patent Document 1 below. prior art literature patent documents

Patent Document 1: Japanese Patent Laid-Open No. 2019-147865

The problem to be solved by the invention Along with the thinning of display panels, the thinning of optical films continues to progress. The thinner the optical film of the laminated optical film is, the easier it is to cause damage such as cracks at the end of the laminated optical film due to external force. When a crack occurs at the edge of the laminated optical film, the crack grows, for example, extending toward the inner region in the surface direction of the film. Cracks generated at the ends are not preferable because they cause the above-mentioned large cracks. In addition, since the display function of a non-rectangular shaped display panel is utilized to the edge of the panel, it is strongly required to suppress cracks at the edge. In the case of special-shaped display panels such as smartphones, due to the long-term use of the device incorporating the panel, the tiny cracks at the edge of the panel at the peripheral part of the special-shaped processing will progress to the inside of the panel, and it is easy to cause brightness on the display screen of the device. Wire. Therefore, it is strongly required to suppress the undesirable situation.

The present invention provides a laminated optical film suitable for suppressing damage at the end of the optical film.

means to solve problems The present invention [1] includes a laminated optical film comprising a first optical film, an adhesive layer, and a second optical film sequentially in the thickness direction; the adhesive layer is joined to the first optical film, and is bonded to the aforementioned Bonding of the second optical film; the aforementioned adhesive layer has an extended end portion, and in the plane direction perpendicular to the aforementioned thickness direction, the extended end portion is shorter than the first edge of the aforementioned first optical film and the edge of the aforementioned second optical film The second end edge is further extended outward.

In this laminated optical film, as described above, the adhesive layer sandwiched by the first optical film and the second optical film has an extended end portion that extends outwardly beyond the two optical films. Where there is the extended end, for example, when the external member approaches the laminated optical film from the surface direction and collides with it, the extended end that is longer than the two optical films will receive the impact of the external member. Thereby, further approach of the external member can be prevented, and collision of the external member with respect to the first end edge of the first optical film and the second end edge of the second optical film can be prevented. Or, even if the external member collides with the first end edge and/or the second end edge, the impact force on these end portions can still be mitigated. The above-mentioned prevention of impact and mitigation of impact force are suitable for suppressing damage to the end of the optical film in the laminated optical film. In addition, the fact that the adhesive layer of this laminated optical film has extended end portions is suitable for suppressing the occurrence and growth of microcracks at the end portions of the first and second optical films.

The present invention [2] includes the laminated optical film according to the above [1], wherein the first optical film is a polarizer film, and the first edge is located outside the second edge in the plane direction.

Such a configuration is suitable for suppressing damage to the second edge of the second optical film in the laminated optical film.

The present invention [3] includes the laminated optical film according to the above [1] or [2], wherein the extension length of the extended end portion from the first edge in the surface direction is 0.01 µm or more and 5 µm or less.

Such a configuration is suitable for achieving both the suppression of damage and the suppression of peeling at the first edge of the first optical film.

The present invention [4] includes the laminated optical film according to any one of the above [1] to [3], wherein the extended length of the extended end portion from the second end edge in the direction of the surface is 0.03 µm or more and 10 µm the following.

Such a configuration is suitable for both the suppression of damage and the suppression of peeling at the second edge of the second optical film.

The present invention [5] includes the laminated optical film according to any one of the above [1] to [4], wherein the above-mentioned adhesive layer has an indentation elastic modulus E1 at 25°C and the above-mentioned adhesive layer has an indentation elastic modulus of 80°C The indentation elastic modulus E2 below satisfies 0.05≦E2/E1≦0.25.

This configuration is suitable for forming the above-mentioned extended end portion when the laminated optical film is manufactured through film shape processing in which the temperature of the end portion of the laminated optical film is increased.

A laminated optical film X which is an embodiment of the laminated optical film of the present invention includes an optical film 10 (first optical film), an optical film 20 (second optical film) and an adhesive layer 30 as shown in FIG. 1 . The laminated optical film X has a sheet shape with a predetermined thickness, and expands in a direction (surface direction) perpendicular to the thickness direction H. Specifically, the laminated optical film X includes an optical film 10 , an adhesive layer 30 , and an optical film 20 in this order in the thickness direction H. The adhesive layer 30 is used to join between the optical films 10 and 20 . Also, the laminated optical film X is a composite film incorporated into the laminated structure of the display panel. The laminated optical film X may be in the form of a single sheet or a roll.

The optical film 10 is a functional optical film in this embodiment. Examples of functional optical films include polarizer films and retardation films.

The polarizer film can be, for example, a hydrophilic polymer film that has been dyed with a dichroic substance and then stretched. Examples of dichroic substances include iodine and dichroic dyes. Examples of the hydrophilic polymer film include polyvinyl alcohol (PVA) film, partially formalized PVA film, and partially saponified film of ethylene-vinyl acetate copolymer. The polarizer film may also be a polyene oriented film. The material of the polyene oriented film can be, for example, dehydrated PVA and dehydrochloridized polyvinyl chloride. In view of excellent optical properties such as polarizing properties, the polarizer film is preferably a PVA film that has been dyed with iodine and then uniaxially stretched.

From the viewpoint of thinning, the thickness of the optical film 10 as a polarizer film is preferably not more than 15 µm, more preferably not more than 12 µm, more preferably not more than 10 µm, and especially preferably not more than 8 µm. Thin polarizer film has excellent visibility due to less variation in thickness, and has excellent durability against thermal shock due to small dimensional changes due to temperature changes. From the viewpoint of strength, the thickness of the optical film 10 as a polarizer film is preferably 3 µm or more, more preferably 5 µm or more.

As a retardation film, a λ/2 wavelength film, a λ/4 wavelength film, and a viewing angle compensation film are mentioned, for example. The material of the retardation film can be, for example, a polymer film that is birefringent by stretching. Examples of polymer films include cellulose films and polyester films. The cellulose film may, for example, be a cellulose triacetate film. Examples of polyester films include polyethylene terephthalate films and polyethylene naphthalate films. The thickness of the optical film 10 as a retardation film is, for example, 20 µm or more and, for example, 150 µm or less. In addition, as the retardation film, a film including a substrate such as a cellulose film and an alignment layer of a liquid crystal compound such as a liquid crystal polymer on the substrate can also be suitably used.

The optical film 20 is a transparent protective film in this embodiment. The transparent protective film is, for example, a flexible transparent resin film. The material of the transparent protective film includes, for example, polyolefin, polyester, polyamide, polyimide, polyvinyl chloride, polyvinyl chloride, cellulose, modified cellulose, polystyrene and polycarbonate. Examples of polyolefins include cycloolefin polymers (COP), polyethylene, polypropylene, ethylene-propylene copolymers, ethylene-vinyl acetate copolymers, and ethylene-vinyl alcohol copolymers. Examples of polyester include polyethylene terephthalate, polyethylene naphthalate, and polybutylene terephthalate. The polyamide can be, for example, polyamide 6, polyamide 6,6 and partially aromatic polyamide. Modified cellulose may, for example, be cellulose triacetate. These materials may be used alone or in combination of two or more. From the viewpoint of cleanliness, it is preferable to use polyolefin as the material of the transparent protective film, and it is more preferable to use COP. Also, the optical film 20 is preferably a uniaxially stretched film or a biaxially stretched film.

From the viewpoint of the strength of the laminated optical film X, the thickness of the optical film 20 is preferably at least 5 µm, more preferably at least 10 µm, and more preferably at least 20 µm. From the viewpoint of thinning the laminated optical film X, the thickness of the optical film 20 is preferably 100 µm or less, more preferably 70 µm or less, more preferably 50 µm or less.

The adhesive layer 30 is a cured product of the adhesive composition. The adhesive layer 30 is directly bonded to the optical film 10 and directly bonded to the optical film 20 . The adhesive composition contains a curable resin. The components of the adhesive composition are specifically described below.

From the viewpoint of bonding force between the optical films 10 and 20, the thickness T1 of the adhesive layer 30 is preferably at least 0.1 µm, more preferably at least 0.4 µm, more preferably at least 0.7 µm, and particularly preferably at least 0.8 µm. From the viewpoint of thinning the laminated optical film X, the thickness T1 of the adhesive layer 30 is preferably not more than 5 µm, more preferably not more than 3 µm, more preferably not more than 1.5 µm, and most preferably not more than 1 µm.

As shown in FIG. 2, the adhesive layer 30 has an extended end portion 30a on at least a part of the peripheral edge. On the surface direction perpendicular to the thickness direction H, the extended end portion 30a is more outward than the edge 11 (first edge) of the optical film 10 or the edge 21 (second edge) of the optical film 20 (Fig. 2 is the extended part in the left direction of the figure). In the laminated optical film X, where the extended end portion 30a exists, for example, as shown in FIG. The extended extension end portion 30a will bear the impact of the external member M. As shown in FIG. Thereby, further approach of the external member M can be prevented, thereby preventing the external member M from colliding with the end edge 11 of the optical film 10 and the end edge 21 of the optical film 20 . Alternatively, even if the outer member M collides against the end edges 11 and/or the end edges 21, the impact force against the end edges 11, 21 can still be mitigated. The prevention of the collision and the relaxation of the collision force are suitable for suppressing the damage of the end portions of the optical films 10 and 20 in the laminated optical film X. Furthermore, the fact that the adhesive layer 30 of the laminated optical film X has the extended end portion 30 a is suitable for suppressing the occurrence and growth of microcracks at the end portions of the optical films 10 and 20 .

When the optical film 10 is a polarizer film and the optical film 20 is a transparent protective film, the end edge 11 is preferably located more outward than the end edge 21 in the plane direction. Such a configuration is suitable for suppressing damage to the edge 21 of the optical film 20 in the laminated optical film X.

The extended length L1 of the extended end portion 30a from the edge 11 in the plane direction is preferably at least 0.01 µm, more preferably at least 0.05 µm, more preferably at least 0.1 µm, and especially preferably at least 0.3 µm. Such a configuration is suitable for suppressing damage to the edge 11 of the optical film 10 . Further, the extended length L1 is preferably not more than 8 µm, more preferably not more than 5 µm, more preferably not more than 4 µm, still more preferably not more than 3 µm, and particularly preferably not more than 1 µm. The above structure is suitable for suppressing the generation of adhesive residue at the edge of the panel due to the excessively extended adhesive during shape processing when the laminated optical film X is incorporated into a display panel such as a smartphone, and is suitable for suppressing display unevenness caused by the adhesive residue . The extension length L1 is specifically the distance in the plane direction between the edge 11 of the optical film 10 and the edge 31 of the adhesive layer 30 .

The extended length L2 of the extended end portion 30a from the edge 21 in the plane direction is preferably at least 0.03 µm, more preferably at least 0.1 µm, more preferably at least 0.3 µm, and especially preferably at least 0.5 µm. Such a configuration is suitable for suppressing damage to the edge 21 of the optical film 20 . Also, the extended length L2 is preferably not more than 10 µm, more preferably not more than 7 µm, more preferably not more than 5 µm, and particularly preferably not more than 3 µm. Such a configuration is suitable for suppressing peeling from the adhesive layer 30 at the edge 21 of the optical film 20 . The extension length L2 is specifically the distance in the plane direction between the edge 21 of the optical film 20 and the edge 31 of the adhesive layer 30 .

The ratio (L2/L1) of the extended length L2 to the extended length L1 is preferably at least 1.1, more preferably at least 1.5, more preferably at least 2, and particularly preferably at least 2.5. The ratio (L2/L1) is preferably 10 or less, more preferably 8 or less, more preferably 7 or less, particularly preferably 5 or less. These configurations suitably achieve both the aforementioned damage suppression and peeling suppression of the optical films 10 and 20 .

The indentation elastic modulus (indentation elastic modulus E1) of the adhesive layer 30 measured by nanoindentation method at 25°C is preferably 0.5 GPa or above, more preferably 1 GPa or above, more preferably 1.5 GPa or above, especially It is above 2GPa. Such a configuration is preferable from the viewpoint of ensuring bonding force between the optical films 10 and 20 . In addition, the above configuration is suitable for ensuring the above-mentioned function of preventing impact and buffering impact force of the extended end portion 30a, and helps to achieve both the above-mentioned damage suppression and peeling suppression of the optical films 10 and 20 . The indentation elastic modulus E1 is preferably not more than 7 GPa, more preferably not more than 5 GPa, more preferably not more than 3 GPa. Such a configuration is suitable for securing the flexibility of the adhesive layer 30 when the laminated optical film X is used in a repeatedly bendable (foldable) display panel. The method of adjusting the indentation elastic modulus of the adhesive layer 30 may, for example, adjust the composition of the adhesive composition. Specifically, the effective method for adjusting the indentation elastic modulus of the adhesive layer 30 is to adjust the number of functional groups of the polymeric compound described later in the adhesive composition forming the adhesive layer 30, that is, to adjust the acryl group equivalent of the polymeric compound or epoxy equivalent.

The nanoindentation method refers to the method of measuring various physical properties of the sample at the nanometer scale. In this embodiment, the nanoindentation method is carried out in accordance with ISO14577. The nanoindentation method is to implement the process of pressing the indenter into the sample installed on the stage (load application process), and then pull the indenter out of the sample (unloading process), and measure a series of processes The load acting between the indenter and the sample and the relative displacement of the indenter to the sample (load-displacement measurement). From this, a load-displacement curve can be obtained. From this load-displacement curve, various physical properties of the measurement sample can be determined based on nanoscale measurement. The load-displacement measurement of the cross section of the adhesive layer by the nanoindentation method can use, for example, a nanoindenter (trade name "Triboindenter", manufactured by Hysitron Corporation). Specifically, it is as described in the examples below.

The indentation elastic modulus (indentation elastic modulus E2) of the adhesive layer 30 measured by nanoindentation method at 80°C is preferably 0.05GPa or above, more preferably 0.1GPa or above, more preferably 0.2GPa or above, especially It is preferably 0.3 GPa or more. This configuration is suitable for forming the above-mentioned extended end portion 30a by suppressing thermal shrinkage of the adhesive layer 30 during film shape processing in which the end portion of the laminated optical film X is heated. From the viewpoint of the processing resistance of the adhesive layer 30, the indentation elastic modulus E2 is preferably 0.7 GPa or less, more preferably 0.5 GPa or less, and more preferably 0.4 GPa or less.

The indentation elastic modulus E1 and E2 should satisfy 0.05≦E2/E1≦0.25. This configuration is suitable for forming the above-mentioned extended end portion 30a by suppressing thermal shrinkage of the adhesive layer 30 during film shape processing in which the end portion of the laminated optical film X is heated. The value of E2/E1 is preferably not less than 0.1, more preferably not less than 0.12, and is more preferably not more than 0.2, more preferably not more than 0.18.

In the laminated optical film X, the 90° peel strength of the optical film 20 against the optical film 10 at 25°C is preferably at least 1N/15mm, more preferably at least 1.2N/15mm, more preferably at least 1.5N/15mm. The above configuration is suitable for achieving good bonding force between the optical films 10 and 20 , and is particularly suitable for securing the bonding force between the optical films 10 and 20 for foldable display panels. The 90° peel strength is, for example, 10 N/15 mm or less. The 90° peel strength can be measured using, for example, a TENSILON universal testing machine (product name "RTC", manufactured by A&D Company, Limited). In this measurement, the measurement temperature was 25° C., the peeling angle was 90°, and the peeling speed was 1000 mm/min. Also, the method of adjusting the 90° peel strength can be, for example, adjusting the composition of the adhesive composition. Specifically, the method of adjusting the 90° peel strength can be, for example, adjusting the number of functional groups of the polymerizable compound described later in the adhesive composition, that is, adjusting the acryl equivalent or epoxy equivalent of the polymerizable compound.

The ratio of the above 90° peel strength (N/15mm) to the indentation modulus E2 (GPa) is preferably 5 or more, more preferably 10 or more, more preferably 15 or more, and preferably 30 or less, more preferably 25 the following. Such a configuration is preferable from the viewpoint of the processing resistance of the adhesive layer 30 .

The adhesive layer 30 is, for example, a cured product of an adhesive composition (active energy ray-curable composition) containing an active energy ray-curable curable resin. The active energy ray curable composition includes, for example, an electron beam curable composition, an ultraviolet ray curable composition, and a visible ray curable composition. In addition, the active energy ray-curable composition is either or both of a radical polymerizable composition and a cationic polymerizable composition in this embodiment.

When the active energy ray-curable composition is a radical polymer composition, the composition contains a radical polymerizable compound as a monomer. The radically polymerizable compound is a compound having a radically polymerizable functional group. As a radical polymerizable functional group, the group containing an ethylenic unsaturated bond is mentioned, for example. The ethylenically unsaturated bond-containing group includes, for example, a (meth)acryl group, a vinyl group, and an allyl group. (Meth)acryl means acryl and/or methacryl. From the viewpoint of the curability of the active energy ray-curable composition, the active energy ray-curable composition preferably contains a radically polymerizable compound having a (meth)acryl group as a main component. The principal component means the most numerous component in terms of mass ratio. The ratio of the (meth)acryl group-containing radically polymerizable compound in the active energy ray-curable composition is, for example, 50% by mass or more, preferably 70% by mass or more, more preferably 80% by mass or more. Moreover, examples of the radical polymerizable compound include monofunctional radical polymerizable compounds and polyfunctional radical polymerizable compounds having more than two functions.

As a monofunctional radically polymerizable compound, the (meth)acrylamide derivative which has a (meth)acrylamide group is mentioned, for example. Examples of (meth)acrylamide derivatives include N-alkyl-containing (meth)acrylamide derivatives, N-hydroxyalkyl-containing (meth)acrylamide derivatives, N-aminoalkyl-containing (meth)acrylamide derivatives containing N-alkoxy groups, (meth)acrylamide derivatives containing N-alkoxy groups, and (meth)acrylamide derivatives containing N-mercaptoalkyl groups. N-alkyl-containing (meth)acrylamide derivatives include, for example: N-methyl(meth)acrylamide, N,N-dimethyl(meth)acrylamide, N,N- Diethyl (meth)acrylamide, N-isopropyl (meth)acrylamide, N-butyl (meth)acrylamide and N-hexyl (meth)acrylamide, preferably N , N-Diethylacrylamide. Examples of (meth)acrylamide derivatives containing N-hydroxyalkyl include: N-methylol (meth)acrylamide, N-hydroxyethyl (meth)acrylamide and N-methylol (meth)acrylamide N-propane (meth)acrylamide, preferably N-hydroxyethylacrylamide. The (meth)acrylamide derivatives may be used alone or in combination of two or more.

As a monofunctional radically polymerizable compound, the (meth)acrylic acid derivative which has a (meth)acryloxy group is mentioned, for example. Examples of the (meth)acrylic acid derivative include (meth)acrylic acid derivatives other than alkyl (meth)acrylate and alkyl (meth)acrylate. The (meth)acrylic acid derivatives may be used alone or in combination of two or more.

Alkyl (meth)acrylates include, for example: methyl (meth)acrylate, ethyl (meth)acrylate, n-propyl (meth)acrylate, isopropyl (meth)acrylate, (meth)acrylate ) n-butyl acrylate, isobutyl (meth) acrylate, n-pentyl (meth) acrylate, 2,2-dimethyl butyl (meth) acrylate, n-hexyl (meth) acrylate, (meth) ) n-octyl acrylate, 2-ethylhexyl (meth)acrylate, 4-methyl-2-propylpentyl (meth)acrylate and n-octadecyl (meth)acrylate.

Examples of (meth)acrylic acid derivatives other than alkyl (meth)acrylates include cycloalkyl (meth)acrylates, aralkyl (meth)acrylates, and hydroxyl-containing (meth)acrylic acid derivatives. , Alkoxy-containing (meth)acrylic acid derivatives and phenoxy-containing (meth)acrylic acid derivatives. As cycloalkyl (meth)acrylate, cyclohexyl (meth)acrylate and cyclopentyl (meth)acrylate are mentioned, for example. Examples of aralkyl (meth)acrylate include benzyl (meth)acrylate and 3-phenoxybenzyl (meth)acrylate. Examples of hydroxyl-containing (meth)acrylic acid derivatives include: 2-hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, 3-hydroxypropyl (meth)acrylate, (meth)acrylate ) 2-hydroxybutyl acrylate, 4-hydroxybutyl (meth)acrylate, [4-(hydroxymethyl)cyclohexyl]methacrylate and 2-hydroxy-3-phenoxypropyl (methyl) Acrylate. Alkoxy-containing (meth)acrylic acid derivatives include, for example, 2-methoxyethyl (meth)acrylate, 2-ethoxyethyl (meth)acrylate and 3-methoxybutyl (meth)acrylates. Examples of phenoxy-containing (meth)acrylic acid derivatives include phenoxyethyl (meth)acrylate and phenoxydiethylene glycol (meth)acrylate. (Meth)acrylic acid derivatives other than alkyl (meth)acrylates are preferably selected from 3-phenoxybenzyl acrylate, 2-hydroxy-3-phenoxypropyl acrylate and phenoxy At least one of the group consisting of diethylene glycol acrylate.

Carboxyl group-containing monomers are also mentioned as a monofunctional radically polymerizable compound. Examples of carboxyl group-containing monomers include (meth)acrylic acid, carboxyethyl acrylate, carboxypentyl acrylate, itaconic acid, maleic acid, fumaric acid, crotonic acid, and isocrotonic acid.

Examples of the monofunctional radically polymerizable compound include lactamide-based vinyl monomers. Examples of lactam-based vinyl monomers include N-vinyl-2-pyrrolidone, N-vinyl-ε-caprolactam, and methylvinylpyrrolidone.

As the monofunctional radically polymerizable compound, a vinyl-based monomer having a nitrogen-containing heterocycle can also be mentioned. Examples of such monomers include vinylpyridine, vinylpiperidone, vinylpyrimidine, vinylpiperidone, vinylpyridine, vinylpyrrole, vinylimidazole, vinyloxazole, and vinylmorphine.

As the polyfunctional radically polymerizable compound, for example, tripropylene glycol di(meth)acrylate, tetraethylene glycol di(meth)acrylate, 1,6-hexanediol di(meth)acrylate, 1, 9-nonanediol di(meth)acrylate, 1,10-decanediol diacrylate, 2-Eth-2-butylpropanediol di(meth)acrylate, neopentyl glycol di(meth)acrylate Acrylates, tricyclodecane dimethanol di(meth)acrylate, cyclic trimethylolpropane formal (meth)acrylate, dioxanediol di(meth)acrylate, trimethylolpropane trimethylolpropane (Meth)acrylate, neopentylthritol tri(meth)acrylate, neopentylthritol tetra(meth)acrylate, diperythritol penta(meth)acrylate and diperythritol hexa(meth)acrylate As (meth)acrylate, tripropylene glycol diacrylate is preferably used. The polyfunctional radically polymerizable compound may be used alone or in combination of two or more. A polyfunctional radically polymerizable compound can function as a crosslinking agent.

化合物。二苯基酮化合物可舉例如苄基、二苯基酮、苯甲醯苯甲酸及3,3'-二甲基-4-甲氧基二苯基酮。苯偶姻醚化合物可舉例如苯偶姻甲醚、苯偶姻乙醚、苯偶姻異丙醚及苯偶姻異丁醚。9-氧硫𠮿

化合物可列舉例如：9-氧硫𠮿

、2-氯9-氧硫𠮿

、2-甲基9-氧硫𠮿

、2,4-二甲基9-氧硫𠮿

、異丙基9-氧硫𠮿

、2,4-二氯9-氧硫𠮿

、2,4-二乙基9-氧硫𠮿

、2,4-二異丙基9-氧硫𠮿

及十二基9-氧硫𠮿

。When the active energy ray-curable composition is an ultraviolet ray-curable composition or a visible ray-curable composition, the active energy ray-curable composition preferably contains a photopolymerization initiator. Photopolymerization initiators can be, for example, benzophenone compounds, benzoin ether compounds and 9-oxothiophene

compound. Examples of the diphenyl ketone compound include benzyl, diphenyl ketone, benzoylbenzoic acid and 3,3'-dimethyl-4-methoxy diphenyl ketone. Examples of benzoin ether compounds include benzoin methyl ether, benzoin ethyl ether, benzoin isopropyl ether and benzoin isobutyl ether. 9-oxosulfur

Compounds can be listed for example: 9-oxosulfur

, 2-Chloro9-oxosulfur 𠮿

, 2-methyl 9-oxosulfur 𠮿

, 2,4-Dimethyl 9-oxosulfur 𠮿

, Isopropyl 9-oxosulfur

, 2,4-dichloro-9-oxosulfur 𠮿

, 2,4-Diethyl 9-oxosulfur 𠮿

, 2,4-Diisopropyl 9-oxosulfur 𠮿

and dodecyl 9-oxosulfur

.

When the active energy ray curable composition is a visible ray curable composition, it is preferable to use a photopolymerization initiator having high sensitivity to light of 380 nm or more. The photopolymerization initiator can be exemplified, for example: 2-methyl-1-(4-methylthiophenyl)-2-morpholinopropan-1-one, 2-benzyl-2-dimethylamino-1 -(4-morpholinylphenyl)-butan-1-one, 2-(dimethylamino)-2-[(4-methylphenyl)methyl]-1-[4-(4- Morpholinyl)phenyl]-1-butanone, 2,4,6-trimethylbenzoyl-diphenyl-phosphine oxide, bis(2,4,6-trimethylbenzoyl base)-phenylphosphine oxide and bis(η5-2,4-cyclopentadien-1-yl)-bis(2,6-difluoro-3-(1H-pyrrol-1-yl)-phenyl )titanium.

、及/或2-甲基-1-(4-甲硫基苯基)-2-嗎福林基丙-1-酮。The photopolymerization initiator should use 2,4-diethyl 9-oxosulfur

, and/or 2-methyl-1-(4-methylthiophenyl)-2-morpholinopropan-1-one.

The content of the photopolymerization initiator in the active energy ray-curable composition is preferably at least 0.1 parts by mass, more preferably at least 0.05 parts by mass, more preferably 0.1 parts by mass relative to 100 parts by mass of the curable component (radical polymerizable compound). More than 20 parts by mass, preferably less than 10 parts by mass, more preferably less than 5 parts by mass.

When the active energy ray-curable composition is a cationic polymer composition, the composition contains a cationic polymerizable compound as a monomer. The cationic polymerizable compound is a compound having a cationic polymerizable functional group, which includes a monofunctional cationic polymerizable compound with one cationic polymerizable functional group and a multifunctional cationic polymerizable compound with two or more cationic polymerizable functional groups. The liquid viscosity of the monofunctional cationic polymerizable compound is relatively low. By blending the monofunctional cationic polymerizable compound into the resin composition, the viscosity of the resin composition can be reduced. Moreover, many monofunctional cationically polymerizable compounds have functional groups capable of exhibiting various functions. By blending the monofunctional cationic polymerizable compound into the resin composition, the resin composition and/or the cured product of the resin composition can exhibit various functions. On the other hand, a cured product having a three-dimensional crosslinked portion can be obtained by curing a resin composition blended with a polyfunctional cationic polymerizable compound (the polyfunctional cationic polymerizable compound functions as a crosslinking agent). From such a viewpoint, it is preferable to use a polyfunctional cation polymerizable compound. When a monofunctional cation polymerizable compound and a polyfunctional cation polymerizable compound are used together, the amount of the polyfunctional cation polymerizable compound is, for example, 10 parts by mass or more and, for example, 1000 parts by mass or less with respect to 100 parts by mass of the monofunctional cation polymerizable compound . The cationic polymerizable functional group may, for example, be an epoxy group, an oxetanyl group or a vinyl ether group. The compound having an epoxy group includes, for example, aliphatic epoxy compounds, alicyclic epoxy compounds, and aromatic epoxy compounds. From the viewpoint of hardening and adhesiveness of the cationic polymer composition, it is preferable to use an alicyclic epoxy compound as the compound having an epoxy group. Alicyclic epoxy compounds can be, for example: 3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexanecarboxylate, or 3,4-epoxycyclohexylmethyl-3,4- Caprolactone-modified, trimethylcaprolactone-modified, and valerolactone-modified substances of epoxycyclohexane carboxylate. Commercially available alicyclic epoxy compounds include, for example, CELLOXIDE 2021, CELLOXIDE 2021A, CELLOXIDE 2021P, CELLOXIDE 2081, CELLOXIDE 2083, and CELLOXIDE 2085 (manufactured by DAICEL Chemical Industry Co., Ltd.), and Cyracure UVR-6105, Cyracure UVR -6107, Cyracure 30 and R-6110 (the above are manufactured by DOW CHEMICAL Japan Co., Ltd.). From the standpoint of improving the curability and reducing the viscosity of the cationic polymer composition, it is preferable to use a compound having an oxetanyl group and/or a compound having a vinyl ether group. Compounds with an oxetane group include, for example: 3-E-3-hydroxymethyl oxetane, 1,4-bis[(3-E-3-oxetane)methoxy Methyl]benzene, 3-Eth-3-(phenoxymethyl)oxetane, bis[(3-Eth-3-oxetanyl)methyl]ether, 3-Eth- 3-(2-Ethylhexyloxymethyl)oxetane, phenol novolac oxetane, etc. Commercially available compounds having an oxetane group include, for example: ARON OXETANE OXT-101, ARON OXETANE OXT-121, ARON OXETANE OXT-211, ARON OXETANE OXT-221, ARON OXETANE OXT-212 (above, East Asia synthetic company). Compounds having a vinyl ether group include, for example: 2-hydroxyethyl vinyl ether, diethylene glycol monovinyl ether, 4-hydroxybutyl vinyl ether, diethylene glycol monovinyl ether, triethylene glycol Alcohol divinyl ether, cyclohexanedimethanol divinyl ether, cyclohexanedimethanol monovinyl ether, tricyclodecane vinyl ether, cyclohexyl vinyl ether, methoxyethyl vinyl ether, ethyl Oxyethyl vinyl ether and neopentylthritol tetravinyl ether.

When the active energy ray-curable composition is an ultraviolet ray-curable composition or a visible ray-curable composition, the active energy ray-curable composition contains a photocationic polymerization initiator. When the photocationic polymerization initiator is irradiated by active energy rays (visible light, ultraviolet rays, X-rays, electron beams, etc.), it will generate cationic species or Lewis acid, and initiate the polymerization reaction of cationic polymerizable functional groups. Examples of photocationic polymerization initiators include photoacid generators and photobase generators, preferably photoacid generators. Active energy ray curable composition When a visible ray curable composition is used, it is particularly preferable to use a photocationic polymerization initiator that is highly sensitive to light above 380 nm. Moreover, when using a photocationic polymerization initiator, it is preferable to use together the photosensitizer which shows the maximum absorption with respect to the light of wavelength longer than 380 nm. A photocationic polymerization initiator is generally a compound that exhibits maximum absorption in a wavelength region near 300nm or shorter, so by using a photosensitizer that exhibits maximum absorption at a wavelength longer than 380nm, the wavelength can be effectively used Light longer than 380nm is used to promote the generation of cationic species or Lewis acids from photocationic polymerization initiators. Examples of photosensitizers include anthracene compounds, pyrene compounds, carbonyl compounds, organosulfur compounds, persulfide compounds, redox compounds, azo compounds, disazo compounds, halogen compounds, and photoreducible dyes. These may be used alone or in combination of two or more. In particular, an anthracene compound is preferable because of its excellent photosensitization effect. Commercially available products of an anthracene compound as a photosensitizer include, for example, ANTHRACURE UVS-1331 and ANTHRACURE UVS-1221 (manufactured by Kawasaki Chemical Co., Ltd.). The content of the photosensitizer in the composition is, for example, 0.1 to 5% by weight.

The active energy ray curable composition may also contain an oligomer. Examples of oligomers include acrylic oligomers, fluorine oligomers, and polysiloxane oligomers, preferably acrylic oligomers. The blending of the oligomer into the active energy ray curable composition helps to suppress the shrinkage of the composition when cured. Suppression of curing shrinkage of the active energy ray-curable composition is suitable for reducing the interface stress between the formed adhesive layer 30 and the optical films 10 and 20 . Suppression of interfacial stress helps to secure the bonding force between the optical films 10 and 20 .

Examples of (meth)acrylic monomers that form acrylic acid oligomers include alkyl (meth)acrylates with 1 to 20 carbon atoms, cycloalkyl (meth)acrylates, and aralkyl (meth)acrylates. esters, polycyclic (meth)acrylates, hydroxyl-containing (meth)acrylates and halogen-containing (meth)acrylates. Alkyl (meth)acrylates include, for example: methyl (meth)acrylate, ethyl (meth)acrylate, n-propyl (meth)acrylate, isopropyl (meth)acrylate, 2-methyl- 2-Nitropropyl (meth)acrylate, n-butyl (meth)acrylate, isobutyl (meth)acrylate, S-butyl (meth)acrylate, tertiary butyl (meth)acrylate, n-pentyl (meth)acrylate, tertiary pentyl (meth)acrylate, 3-pentyl (meth)acrylate, 2,2-dimethylbutyl (meth)acrylate, (meth)acrylic acid n-hexyl ester, cetyl (meth)acrylate, n-octyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, 4-methyl-2-propylpentyl (meth)acrylate and N-octadecyl(meth)acrylate. As cycloalkyl (meth)acrylate, cyclohexyl (meth)acrylate and cyclopentyl (meth)acrylate are mentioned, for example. As for aralkyl (meth)acrylate, benzyl (meth)acrylate is mentioned, for example. Polycyclic (meth)acrylates can be exemplified by 2-isobornyl (meth)acrylate, 2-norbornyl methyl (meth)acrylate, 5-norbornen-2-yl-methyl (meth)acrylate base) acrylate and 3-methyl-2-norbornyl methyl (meth)acrylate. Hydroxyl-containing (meth)acrylates include, for example, hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, 2,3-dihydroxypropylmethyl-butyl (meth)methacrylate base acrylate. Halogen-containing (meth)acrylates include, for example: 2,2,2-trifluoroethyl (meth)acrylate, 2,2,2-trifluoroethylethyl (meth)acrylate, tetrafluoroethyl (meth)acrylate, Fluoropropyl (meth)acrylate, hexafluoropropyl (meth)acrylate, octafluoropentyl (meth)acrylate, heptadecylfluorodecyl (meth)acrylate. These (meth)acrylates may be used alone or in combination of two or more.

The weight average molecular weight (Mw) of the acrylic acid oligomer is preferably 15,000 or less, more preferably 10,000 or less, more preferably 5,000 or less. The Mw of the acrylic acid oligomer is preferably not less than 500, more preferably not less than 1000, more preferably not less than 1500.

The content of the acrylic acid oligomer in the active energy ray curable composition is preferably at least 2% by mass, more preferably at least 4% by mass, and is preferably at most 20% by mass, more preferably at most 15% by mass.

The active energy ray curing composition may contain other components. Other components include silane coupling agent, leveling agent, surfactant, plasticizer and ultraviolet absorber. The blending amount of the other components is preferably not more than 10 parts by mass, more preferably not more than 5 parts by mass, more preferably not more than 3 parts by mass, and for example, not less than 0.01 parts by mass relative to 100 parts by mass of the hardening component.

From the viewpoint of coatability in the coating step described later, the viscosity of the active energy ray-curable composition at 25°C is preferably 3 mPa·s or higher, more preferably 5 mPa·s or higher, more preferably 10 mPa·s Above, and preferably below 100mPa·s, more preferably below 50mPa·s, more preferably below 30mPa·s. The viscosity of the composition is the measured value measured with an E-type viscometer (cone-plate viscometer).

The laminated optical film X can be produced, for example, as follows.

First, an active energy ray-curable composition is coated on one side (surface to be joined) of one of the optical films (optical film 10 or optical film 20 ) to form a coating film of the composition (coating step). Before this coating step, the surface to be joined of the optical film may also be subjected to surface modification treatment. Surface modifying treatments include corona treatment, plasma treatment, excimer treatment and flame treatment. The coating method in this step may be, for example, a reverse coater, a gravure coater, a rod reverse coater, a roll coater, a die coater, a rod coater, and a rod coater.

Next, the other optical film (optical film 20 or optical film 10 ) is bonded to one of the optical films via the composition coating film. For bonding, a roll laminator can be used, for example.

Next, the composition coating film between the optical films 10 and 20 is irradiated with active energy rays to harden the coating film (active energy ray-curable composition) to form the adhesive layer 30 (the adhesive layer 30 is not a pressure-sensitive adhesive layer. ). Thereby, the optical films 10 and 20 are bonded through the adhesive layer 30, and the original film of the laminated optical film X is obtained. From the viewpoint of suppressing deterioration of the optical film 10 which is a functional optical film, it is preferable to irradiate active energy rays from the optical film 30 side in this step. Active energy rays can use electron beams, ultraviolet rays, and visible rays. The electron beam irradiation mechanism may, for example, be an electron beam accelerator. Examples of light sources for ultraviolet and visible light include: LED LIGHT, gallium-filled metal halide lamps, low-pressure mercury lamps, medium-pressure mercury lamps, high-pressure mercury lamps, ultra-high pressure mercury lamps, xenon lamps, halogen lamps, and gallium lamps. In this step, a wavelength cutoff filter may also be used as required to cut off the wavelength region of a part of the ultraviolet and/or visible light emitted from the light source.

Next, at least a part of the peripheral end portion of the original film is subjected to contour processing (contour processing step). For example, one end in the longitudinal direction of a roll-shaped original film is trimmed. For example, a roll-shaped raw film is cut and processed into individual sheets. Such shape processing methods include, for example, laser processing by CO ₂ laser irradiation, cutting by a punching knife, and end mill processing. The optical film 10, 20 undergoes large heat shrinkage at the shape processing place of the original film to form the extended end portion 30a. Specifically, the ends of the optical films 10 and 20 are shrunk so that the edges 11 and 21 of the optical films 10 and 20 recede from the edges 31 of the adhesive layer 30 toward the inside in the plane direction at the ends of the original film, forming an extended end 30a. The contracted length of the ends of the optical films 10 and 20 , that is, the extended lengths L1 and L2 of the extended ends 30 a can be adjusted by adjusting the material (dimensional shrinkage rate) and thickness of the optical films 10 and 20 and processing conditions. Processing conditions include, for example, adjustment of elongation ratio.

For example, the laminated optical film X can be produced in the above manner.

Example Examples are shown below to specifically illustrate the present invention. The present invention is not limited by the Examples. In addition, specific values such as the blending amount (content), physical property values, and parameters described below can be replaced by the corresponding blending amount (content), physical property values, and parameters described in the above "Forms for Implementing the Invention" The upper limit (the value defined as "below" or "less than") or the lower limit (the value defined as "above" or "greater than").

[Example 1] The following components were mixed at 25°C for 1 hour to prepare an adhesive composition (preparation step).

(品名「KAYACURE DETX-S」，光聚合引發劑，日本化藥公司製) 5質量份之丙烯酸寡聚物(品名「ARUFON 1190」，黏度6000mPa・s(25℃)，Mw1700，Tg-50℃，東亞合成公司製) 0.5質量份之具有丙烯醯基之改質聚二甲基矽氧烷(品名「BYK-UV3505」，調平劑，BYK公司製) 45 parts by mass of 3-phenoxybenzyl acrylate (product name "LIGHT ACRYLATE POB-A", monomer, manufactured by Kyoeisha Chemical Co., Ltd.) 25 parts by mass of phenoxydiethylene glycol acrylate (product name "LIGHT ACRYLATE POB-A", ACRYLATE P2H-A", monomer, manufactured by Kyoeisha Chemical Co., Ltd.) 15 parts by mass of tripropylene glycol diacrylate (product name "ARONIX M-220", monomer, manufactured by Toagosei Co., Ltd.) 10 parts by mass of 2-hydroxy- 3-phenoxypropyl acrylate (product name "ARONIX M-5700", monomer, manufactured by Toagosei Co., Ltd.) 5 parts by mass of hydroxyethylacrylamide (product name "HEAA", monomer, manufactured by KJ Chemicals Corporation) 5 Parts by mass of diethylacrylamide (product name "DEAA", monomer, manufactured by KJ Chemicals Corporation) 3 parts by mass of 2-methyl-1-(4-methylthiophenyl)-2-morpholinopropane -1-ketone (product name "OMINIRAD907", photopolymerization initiator, manufactured by IGM Resins Co., Ltd.) 3 parts by mass of 2,4-diethyl 9-oxysulfide

(product name "KAYACURE DETX-S", photopolymerization initiator, manufactured by Nippon Kayaku Co., Ltd.) 5 parts by mass of acrylic acid oligomer (product name "ARUFON 1190", viscosity 6000mPa·s (25°C), Mw1700, Tg-50°C , Toagosei Co., Ltd.) 0.5 parts by mass of modified polydimethylsiloxane with acryl group (product name "BYK-UV3505", leveling agent, BYK Co., Ltd.)

Next, the adhesive composition was coated on a 23 µm thick COP film (product name "Zeonor Film ZF14", manufactured by ZEON Corporation, Japan) as a transparent protective film to form an adhesive coating film with a thickness of 1 µm. The coating system used an MCD coater (manufactured by Fuji Machinery Co., Ltd.) (groove shape: honeycomb shape, gravure roll line number 1000 lines/inch, rotation speed 140%/line speed). Next, the polarizer film is bonded to the transparent protective film through the adhesive coating film on the film. Next, by irradiating the adhesive coating film with ultraviolet light from the side of the transparent protective film, the adhesive coating film between the films is cured. In the ultraviolet irradiation, an ultraviolet irradiation apparatus (product name "Light HAMMER10", bulb: V bulb, manufactured by Fusion UV Systems, Inc.) equipped with a gallium-filled metal halide lamp was used as a light source. In ultraviolet irradiation, the peak illuminance was 1600mW/cm ² , and the cumulative irradiance was 1000mJ/cm ² (wavelength 380-440nm) (the illuminance was measured using the "Sola-Check system" manufactured by Solatell). Thereby, a laminated optical film is obtained by bonding the transparent conductive film and the polarizer film.

Next, the laminated optical film is subjected to contour processing (contour processing step). Specifically, the laminated optical film is cut in the thickness direction by irradiating CO ₂ laser to obtain a predetermined plan view shape of the laminated optical film. In _CO2 laser irradiation, the wavelength was set to 9.4 µm, the output was set to 48 W, and the scanning speed was set to 500 mm/sec. Next, the laminated optical film was left at room temperature for 24 hours.

In the above manner, the laminated optical film of Example 1 was produced. The laminated optical film of Example 1 is sequentially provided with a polarizer film (5 µm in thickness), an adhesive layer, and a transparent protective film (23 µm in thickness) in the thickness direction.

[Example 2] Except for the following matters, the laminated optical film of Example 2 (polarizer film/adhesive layer/transparent protective film) was produced in the same manner as the laminated optical film of Example 1. In the preparation step, the blending amount of "ARONIX M-220" was set to 5 parts by mass instead of 15 parts by mass, and the thickness of the adhesive layer coating formed on the transparent protective film was set to 1 µm.

[Example 3] The laminated optical film of Example 3 (polarizer film/second adhesive layer/transparent protective film) was produced in the same manner as the laminated optical film of Example 1 except for the following matters.

In the preparation step, set the blending amount of "LIGHT ACRYLATE POB-A" to 43 parts by mass, the blending amount of "LIGHT ACRYLATE P2H-A" to 29 parts by mass, and the blending amount of "ARONIX M-220" The mixing amount was set to 3 parts by mass. In the coating step, the thickness of the coating film of the adhesive layer to be formed on the transparent protective film was set to 1 µm.

[Comparative example 1] The laminated optical film of Comparative Example 1 (polarizer film/adhesive layer/transparent protective film) was produced in the same manner as the laminated optical film of Example 1 except for the following matters.

In the preparation step, 36 parts by mass of "LIGHT ACRYLATE 1.9ND-A" (1,9-nonanediol diacrylate) manufactured by Kyoeisha Chemical Co., Ltd. and "LIGHT ACRYLATE HPP-A" manufactured by Kyoeisha Chemical Co., Ltd. were used (Hydroxytrimethylacetic acid neopentyl glycol acrylate adduct) 12.5 parts by mass to replace "LIGHT ACRYLATE POB-A" and "LIGHT ACRYLATE P2H-A", and do not use "ARONIX M-220", and put The blending amount of "ARONIX M-5700" was 22 parts by mass, the blending amount of "HEAA" was 12.5 parts by mass, the blending amount of "DEAA" was 6 parts by mass, and the blending amount of "HEAA" The blending amount was set to 12.5 parts by mass, and the blending amount of "ARUFON 1190" was set to 10 parts by mass.

＜Observation at the end＞ The vertical cross-sectional shape of the edge part was investigated about each laminated optical film of Examples 1-3 and Comparative Example 1. First, a longitudinal section for observation is formed by cutting at an arbitrarily selected portion from the peripheral end of the laminated optical film in the thickness direction. Next, the longitudinal section was observed and photographed with an optical microscope. Then, in each observed cross-section, it was confirmed that the adhesive layer had a portion extending outward from the edge (first edge) of the polarizer film and the edge (second edge) of the transparent protective film in the direction of the film surface. (extended end). Also, the extension length L1 of the extension end portion from the first edge in the plane direction and the extension length L2 of the extension end portion from the second end edge in the plane direction were measured in each observed section. The results are shown in Table 1.

In addition, the suppression of damage to the laminated optical film was evaluated on the following basis: the situation where no damage (cracks, cracks, etc.) occurred on both the polarizer film and the transparent protective film in the above-mentioned observation section was evaluated as "good", and The case where at least one of the polarizer film and the transparent protective film was damaged was evaluated as "defective". The results are shown in Table 1.

<Indentation modulus of elasticity> The indentation modulus of elasticity of the adhesive layer in each laminated optical film of Examples 1 to 3 and Comparative Example 1 was measured by the nanoindentation method (measurement of the first modulus of elasticity). Specifically, first, a film sheet (laminated optical film) with a size of 5 mm×10 mm is cut out from the laminated optical film. Next, the laminated optical film was cut by the frozen section method. Specifically, after cooling the laminated optical film to -30°C, use a hard cutter to cut upward along the thickness direction of the film, and then return to room temperature. Thereby, a sample for measurement is obtained. Next, use a nanoindentation tester (product name "TI950 Triboindenter", manufactured by Hysitron Corporation) to perform a load-displacement measurement on the exposed surface of the adhesive layer in the test sample in accordance with JIS Z 2255:2003, and obtain a load-displacement curve . In this measurement, the measurement mode is set to single indentation measurement, the measurement temperature is set to 25°C, the indenter used is a Berkovich (triangular pyramid) diamond indenter, and the maximum indentation depth of the indenter on the test sample during the load application process ( The maximum displacement hmax) is set to 50nm, the indenter's indentation speed is set to 10nm/sec, and the indenter's pull-out speed from the test sample is set to 10nm/sec during the unloading process. Then, use the dedicated analysis software (Ver. 9.4.0.1) of "TI950 Triboindenter" to process the obtained measurement data. Specifically, according to the load (f)-displacement (h) curve obtained: the maximum load fmax (the load acting on the indenter with the maximum displacement hmax), the contact projected area S (the distance between the indenter and the sample at the maximum load) The projected area of the contact area between them), and the slope D of the tangent to the load-displacement curve at the beginning of unloading. Then, the indentation elastic modulus (=(π ^1/2 D)/(2S ^1/2 )) of the adhesive layer was calculated from the slope D and the contact projected area S. This value is shown in Table 1 as the indentation elastic modulus E1 (GPa).

In addition, except that the measurement temperature of the indentation elastic modulus at 80°C of the adhesive layer in each of the laminated optical films of Examples 1 to 3 and Comparative Example 1 was set to 80°C instead of 25°C, the same method as in the first Elastic modulus measurement was performed in the same manner (measurement of the second elastic modulus). This value is shown in Table 1 as the indentation elastic modulus E2 (GPa). Table 1 also shows the ratio (E2/E1) of the indentation modulus E2 at 80°C to the indentation modulus E1 at 25°C.

[Table 1]

X:Laminated optical film 10: Optical film (1st optical film) 11: The edge of the optical film 10 (the first edge) 20: Optical film (2nd optical film) 21: the edge of the optical film 20 (the second edge) 30: Adhesive layer 30a: Extended end 31: The edge of the adhesive layer L1, L2: extended length H: Thickness direction M: external components

Fig. 1 is a schematic cross-sectional view of an embodiment of the laminated optical film of the present invention. FIG. 2 is a partially enlarged cross-sectional view of an end portion of the laminated optical film shown in FIG. 1. FIG. Figure 3 shows a function of the extended end of the adhesive layer.

10: Optical film (1st optical film)

11: The edge of the optical film 10 (the first edge)

20: Optical film (2nd optical film)

21: the edge of the optical film 20 (the second edge)

30: Adhesive layer

30a: Extended end

31: The edge of the adhesive layer

L1, L2: extended length

H: Thickness direction

Claims (5)

A laminated optical film comprising a first optical film, an adhesive layer and a second optical film sequentially in the thickness direction; The aforementioned adhesive layer is bonded to the aforementioned first optical film and bonded to the aforementioned second optical film; The aforementioned adhesive layer has an extended end portion, and in the direction perpendicular to the thickness direction, the extended end portion is farther from the first end edge of the first optical film and the second end edge of the second optical film. Outer extension. The laminated optical film according to claim 1, wherein the first optical film is a polarizer film, and in the direction of the plane, the first edge is located more outside than the second edge. The laminated optical film according to claim 1, wherein the extended length of the extended end portion from the first edge in the direction of the surface is not less than 0.01 µm and not more than 5 µm. The laminated optical film according to claim 1, wherein the extended length of the extended end portion from the second edge in the direction of the surface is not less than 0.03 µm and not more than 10 µm. The laminated optical film according to any one of claims 1 to 4, wherein the indentation modulus E1 of the adhesive layer at 25°C and the indentation modulus E2 of the adhesive layer at 80°C satisfy 0.05≦E2/E1≦0.25.

Images