TW202248486A - Structure and manufacturing process of environmentally friendly solvent-free heavyweight fabrics which has advantages of good firmness, cost reduction, yield improvement, smooth cloth surface, and environmentally friendly with no solvents - Google Patents

Structure and manufacturing process of environmentally friendly solvent-free heavyweight fabrics which has advantages of good firmness, cost reduction, yield improvement, smooth cloth surface, and environmentally friendly with no solvents Download PDF

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TW202248486A
TW202248486A TW110121182A TW110121182A TW202248486A TW 202248486 A TW202248486 A TW 202248486A TW 110121182 A TW110121182 A TW 110121182A TW 110121182 A TW110121182 A TW 110121182A TW 202248486 A TW202248486 A TW 202248486A
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raw silk
polyester raw
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polyester
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TWI817136B (en
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許仁興
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富泰企業股份有限公司
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Abstract

The present invention relates to the structure and manufacturing process of an environmentally friendly solvent-free heavyweight fabric. During manufacturing, a high-denier polyester raw silk base material made of plain weave in the form of a weft-heavy flat weave pattern forms a plurality of three-dimensional protrusions arranged in a network on the polyester raw silk base material, and then the polyester raw silk base material is wound on a hollow bobbin with multiple openings so as to form a warp beam dyeing part on the polyester raw silk base material by controlling the density of the rolled cloth and the value of the dyeing pressure difference, and the polyester raw silk base material is then calendered twice using a three-axis hot press. Finally, a first coating module and a second coating module are used to introduce a TPU heat-molded imitation laminate layer and the polyester raw silk base material respectively, and to apply a moisture-hardening polyurethane hot-melt adhesive. By one-time full lamination, the polyester raw silk base material and the imitation laminate layer are compositely formed, and the composite coating has advantages of good firmness, cost reduction, yield improvement, smooth cloth surface, and environmentally friendly with no solvents.

Description

環保無溶劑重磅織物之結構及其製程 The structure and manufacturing process of environmentally friendly solvent-free heavyweight fabric

本發明為提供一種環保無溶劑重磅織物之結構及其製程,尤指一種複合塗層牢固度佳、經緯組織強度高、布面立體飽滿、染色均勻飽和、表面平整光滑、製程環保無溶劑、及可降低製造成本的環保無溶劑重磅織物之結構及其製程。 The present invention provides an environment-friendly solvent-free heavy fabric structure and its manufacturing process, especially a composite coating with good firmness, high warp and weft weave strength, three-dimensional and full cloth surface, uniform and saturated dyeing, smooth surface, and environmentally friendly solvent-free manufacturing process. And the structure and manufacturing process of the environment-friendly solvent-free heavy fabric that can reduce the manufacturing cost.

按,近年來袋包材不再以皮革為主,改利用織物設計,使袋包符合潮流、實用性、美觀及個性化等市場需求,而袋包在使用過程中會受到各種不同的外界因素作用,產生如表面磨損影響其性能、折皺彎曲影響耐用性、織物表面起毛球、強度不足導致勾絲斷裂、及外觀持久度不佳等問題。 Press, in recent years, the bags are no longer mainly made of leather, but instead use fabric design, so that the bags meet the market needs such as fashion, practicality, beauty and personalization, and the bags will be affected by various external factors during use. Effects, such as surface wear affects its performance, wrinkle and bending affect durability, fabric surface pilling, insufficient strength leads to snagging breakage, and poor appearance durability.

為解決上述問題,傳統製程包括組織設計、織造、染色、壓光、塗膠、及縫合測試等。如第一圖所示,係為傳統織物加工流程圖,其中組織設計與織造部份,傳統方法是採用吹撚變形(Air Textured Yarn,ATY)或上漿提高抱合力,但吹撚過的長絲91物性下降,直接影響拉力及撕裂強度,甚至有毛圈多、不耐磨、無光澤等問題,且上漿工程複雜、成本高,還會影響染色性和整體加工性能。若選用高丹尼的聚酯原絲(Polyester Fully Oriented Yarn,FOY),雖然高丹尼強度大,且聚酯原絲具有金屬光澤感,但聚酯原絲之間無抱合力,易產生相對滑移的物理特性,而在織造過程中單絲易產生分纖、滑脫、崩紗、磨斷和毛羽織造困難等問題。 To solve the above problems, the traditional manufacturing process includes tissue design, weaving, dyeing, calendering, gluing, and stitching testing. As shown in the first figure, it is a flow chart of traditional fabric processing. In the part of structure design and weaving, the traditional method is to use Air Textured Yarn (ATY) or sizing to improve cohesion, but the length of blown twist The physical properties of silk 91 decrease, which directly affects the tensile force and tear strength, and even has problems such as many loops, non-wear resistance, and dullness. The sizing process is complicated and costly, and it will also affect the dyeability and overall processing performance. If high denier polyester yarn (Polyester Fully Oriented Yarn, FOY) is used, although the high denier yarn has high strength and the polyester yarn has a metallic luster, there is no cohesion between the polyester yarns, and relative The physical characteristics of slippage, and in the weaving process, monofilaments are prone to problems such as fiber separation, slippage, yarn collapse, abrasion and hairiness weaving difficulties.

再者重磅聚酯布屬高丹尼織物,組織密度低、纖維滲透性差,如以傳統的高溫高壓溢流方式進行染色,因織物呈繩狀環形在染色機92中運轉,容易造成布面勾毛、裂紗水傷、有雞爪痕、方格不正、折皺等平整性不佳之瑕疵,造成良率下降、製程縮率損耗變大。若以經軸染色使其染色過程中保持平整狀態,雖可獲得布面平整、及手感滑爽等優點,但實際生產過程中因重磅 高織密織物捲在經軸上有捲繞密度的差異,若密度小,織物容易滑移,外層易出現左中右色差、色花,若織物捲在經軸密度大,染料分子不易擴散造成染液穿透不均勻,使內外層色差大,容易產生內外層色花等現象。即使透過傳統二輥熱壓機93進行壓光,因僅進行一次壓合,仍有壓縮不足易起毛、紗線間間隙較大、表面不平整等問題。 In addition, the heavy polyester cloth is a high-denier fabric with low tissue density and poor fiber permeability. If the traditional high-temperature and high-pressure overflow method is used for dyeing, the fabric is run in the dyeing machine 92 in the shape of a rope, which is easy to cause damage to the cloth surface. Poor flatness defects such as hooking, cracked yarn, water damage, chicken claw marks, irregular squares, and wrinkles will cause a decrease in yield and increase loss in process shrinkage. If warp beam dyeing is used to keep it in a flat state during the dyeing process, although the advantages of smooth cloth surface and smooth hand feeling can be obtained, the actual production process is heavy due to heavy There is a difference in the winding density of the high-density fabric roll on the warp beam. If the density is small, the fabric is easy to slip, and the outer layer is prone to color difference and color flower. The uneven penetration of the dye solution will cause a large color difference between the inner and outer layers, and it is easy to produce color flowers on the inner and outer layers. Even though the calendering is carried out by the traditional two-roll heat press machine 93, because only one pressing is performed, there are still problems such as insufficient compression, easy fluffing, large gaps between yarns, and uneven surface.

另外,袋材塗層大量使用溶劑型膠黏劑造成環境污染嚴重,而隨著環保意識的日益增強、及相關環保法規日趨嚴厲,導致織物塗層的加工用化學品對適應低碳經濟需要之要求越來越高。由於織物的表面都是凹凸不平非常粗糙,使得多數的溶劑型膠黏劑和多孔性織物都需要塗膠2~4次,故重磅高織密織物也需進行多次塗布,目前製程設備94則以流延成膜和塗層製程為主,而流延成膜法需以溶劑型PU膠料在袋材正反兩面打底,且要在黏膠烘乾、溶劑揮發之後再進行下次塗膠加工,讓背面底塗提高塗層與基布的附著力,使塗層在織物表面形成一層連續的薄膜,提高耐水性,但袋材正面塗層為得到良好的機械強度和耐磨等特性,會再透過擠壓機與淋膜塗層複合,複合過程需控制黏結力、外觀及複合膜厚度等因素,故對袋材的尺寸安定性、手感、成本及機械性能都有很大的影響,製程非常繁瑣。 In addition, the extensive use of solvent-based adhesives in the coating of bag materials has caused serious environmental pollution. With the increasing awareness of environmental protection and the increasingly stringent environmental protection regulations, the processing chemicals used in fabric coating are not suitable for meeting the needs of low-carbon economy. Increasingly demanding. Because the surface of the fabric is uneven and very rough, most solvent-based adhesives and porous fabrics need to be coated 2 to 4 times, so heavy and high-density fabrics also need to be coated multiple times. The current process equipment is 94 The film-casting and coating process is the main method, and the film-casting method needs to use solvent-based PU glue on the front and back sides of the bag as a primer, and the next step should be done after the adhesive is dried and the solvent evaporates. Glue processing, let the back primer improve the adhesion between the coating and the base fabric, so that the coating forms a continuous film on the surface of the fabric to improve water resistance, but the front coating of the bag material is not good for obtaining good mechanical strength and wear resistance, etc. properties, it will be compounded with the film coating through the extruder. During the compounding process, factors such as cohesion, appearance and thickness of the compound film need to be controlled, so it has a great impact on the dimensional stability, hand feeling, cost and mechanical properties of the bag material. Affected, the manufacturing process is very cumbersome.

是以,要如何解決上述習用之問題與缺失,即為本發明之發明人與從事此行業之相關廠商所亟欲研究改善之方向所在者。 Therefore, how to solve the above-mentioned conventional problems and deficiencies is the direction that the inventor of the present invention and related manufacturers engaged in this industry want to research and improve urgently.

故,本發明之發明人有鑑於上述缺失,乃蒐集相關資料,經由多方評估及考量,並以從事於此行業累積之多年經驗,經由不斷試作及修改,始設計出此種複合塗層牢固度佳、經緯組織強度高、布面立體飽滿、染色均勻飽和、表面平整光滑、製程環保無溶劑、及可降低製造成本的環保無溶劑重磅織物之結構及其製程的發明專利者。 Therefore, in view of the above shortcomings, the inventor of the present invention collected relevant information, evaluated and considered in many ways, and based on years of experience accumulated in this industry, through continuous trials and modifications, he designed this composite coating. Excellent, high warp and weft weave strength, full three-dimensional cloth surface, uniform and saturated dyeing, smooth surface, environmentally friendly solvent-free manufacturing process, and an invention patenter for the structure and manufacturing process of environmentally friendly solvent-free heavyweight fabrics that can reduce manufacturing costs.

本發明之主要目的在於:以緯重平組織織造高丹尼聚酯原絲,並控制捲布密度及染色壓差進行經軸染色,再以無溶劑型單組分接著劑,進行雙塗頭轉移重貼塗布,藉此提升織機效能、降低紗線成本、提升重磅織物染色良率、降低織物製程損耗、滿足環保要求、提高操作效率、開發高值化袋包用布。 The main purpose of the present invention is to weave high-denier polyester raw yarn with weft-heavy flat weave, and carry out warp beam dyeing by controlling the cloth density and dyeing pressure difference, and then use solvent-free single-component adhesive to carry out double coating head Transfer and re-coating can improve the efficiency of looms, reduce yarn costs, increase the dyeing yield of heavy fabrics, reduce fabric process losses, meet environmental protection requirements, improve operating efficiency, and develop high-value bag fabrics.

為達成上述目的,本發明之主要結構包括:一聚酯原絲基材、複數立體凸出部、一經軸染色部、一仿淋膜層、及一濕氣硬化型聚氨酯熱熔膠。該聚酯原絲基材係以緯重平組織(Weft Rib Weave)成型,且其總丹尼數為600D以上,該立體凸出部係網狀排列於聚酯原絲基材表面,該經軸染色部係藉由控制捲布密度及染色壓差值形成於聚酯原絲基材上,該仿淋膜層係由無溶劑反應型聚氨酯(Thermoplastic polyurethanes,TPU)加熱成型,而該濕氣硬化型聚氨酯熱熔膠(Polyurethane Reactive,PUR)係利用全面式移轉塗布貼合方式,使該聚酯原絲基材與該仿淋膜層複合成型。 To achieve the above purpose, the main structure of the present invention includes: a polyester raw silk base material, multiple three-dimensional protrusions, a warp beam dyeing part, an imitation coating layer, and a moisture-curing polyurethane hot-melt adhesive. The polyester raw silk substrate is formed by Weft Rib Weave, and its total denier number is above 600D. The three-dimensional protrusions are arranged in a network on the surface of the polyester raw silk substrate. The axial dyeing part is formed on the polyester raw silk substrate by controlling the cloth density and the dyeing pressure difference. The imitation coating layer is formed by heat-forming of solvent-free reactive polyurethane (Thermoplastic polyurethanes, TPU), and the moisture The hardening polyurethane hot melt adhesive (Polyurethane Reactive, PUR) adopts a full-scale transfer coating lamination method to make the polyester raw silk base material and the imitation coating layer compositely formed.

製作時,係將聚酯原絲以平紋組織製成緯重平組織態樣且總丹尼數600D以上之聚酯原絲基材,以提供高強力、表面光滑、有光澤感之優點,並利用立體凸出部產生立體感飽滿粗曠的自然風格,再改良經軸染色技術,以藉由捲繞聚酯原絲基材於空心捲軸上,使其捲布密度從內至外漸高,同時配合控制其染色壓差值,以於聚酯原絲基材上形成經軸染色部,再配合三軸熱壓機將染色後的聚酯原絲基材進行兩次壓光,而提升重磅織物染色良率及布面平整性,並降低織物製程損耗,最後利用第一塗布模組及第二塗布模組(雙塗頭塗布系統),分別導入一由TPU加熱成型之仿淋膜層及該聚酯原絲基材,並塗布濕氣硬化型聚氨酯熱熔膠(PUR),以藉由一次性的全面貼合,使該聚酯原絲基材與該仿淋膜層複合成型,而具有複合塗層牢固度佳、可降低成本、提高良率、布面平整及製程環保無溶劑等進步性。 During production, the polyester raw silk is made into a polyester raw silk substrate with a weft-heavy flat weave pattern and a total denier number of more than 600D in a plain weave to provide the advantages of high strength, smooth surface, and luster. Using the three-dimensional protrusions to produce a three-dimensional, full and rough natural style, and then improving the warp beam dyeing technology, by winding the polyester raw silk base material on the hollow reel, the density of the cloth is gradually increased from the inside to the outside. At the same time, cooperate with the control of the dyeing pressure difference to form the warp beam dyeing part on the polyester raw silk base material, and then cooperate with the three-axis hot press to carry out the calendering of the dyed polyester raw silk base material twice to increase the weight. lb fabric dyeing yield and fabric smoothness, and reduce fabric process loss, and finally use the first coating module and the second coating module (double coating head coating system) to introduce an imitation coating layer heated and formed by TPU And the polyester raw silk substrate, and coated with moisture-curing polyurethane hot melt adhesive (PUR), so that the polyester raw silk substrate and the imitation coating layer can be compounded by one-time full lamination, However, it has the advantages of good composite coating firmness, cost reduction, yield improvement, smooth cloth surface, and environmentally friendly and solvent-free manufacturing process.

藉由上述技術,可針對習用袋包材所存在之基材強度不足導致織造困難、纖維滲透性差造成染色性不佳、製程多使用溶劑型黏劑、需進行多次塗布、製程複雜成本高等的問題點加以突破,達到上述優點之實用進步性。 With the above-mentioned technology, we can solve the difficulties in weaving due to insufficient base material strength in conventional bag packaging materials, poor dyeability due to poor fiber permeability, solvent-based adhesives are often used in the process, multiple coatings are required, and the process is complicated and costly. Break through the problems to achieve the practical progress of the above advantages.

1:聚酯原絲基材 1: Polyester raw silk substrate

11:立體凸出部 11: three-dimensional protrusion

2:經軸染色部 2: Warp axis dyeing department

3:仿淋膜層 3: imitation coating layer

4:濕氣硬化型聚氨酯熱熔膠 4: Moisture hardening polyurethane hot melt adhesive

5:空心捲軸 5: Hollow Scroll

51:開孔 51: opening

6:染色槽 6: dye tank

7:三軸熱壓機 7: Three-axis heat press machine

8:雙塗頭轉移塗布系統 8: Double coating head transfer coating system

81:第一塗布模組 81: The first coating module

811:刀軸部 811: Cutter shaft

812:入料軸 812: Feed shaft

813:轉移軸 813: transfer axis

82:第二塗布模組 82: The second coating module

821:刀軸部 821: Cutter shaft

822:入料軸 822: Feed shaft

823:轉移軸 823: transfer axis

83:第一調節間隙 83: The first adjustment gap

84:第二調節間隙 84: Second adjustment gap

91:長絲 91: Filament

92:染色機 92: dyeing machine

93:二輥熱壓機 93: Two-roll heat press

94:製程設備 94: Process equipment

第一圖 係為傳統織物加工流程圖。 The first figure is the flow chart of traditional fabric processing.

第二圖 係為本發明較佳實施例之立體透視圖。 The second figure is a three-dimensional perspective view of a preferred embodiment of the present invention.

第三圖 係為本發明較佳實施例之方塊流程圖。 The third figure is a block flow diagram of a preferred embodiment of the present invention.

第四圖 係為本發明較佳實施例之經軸染色示意圖。 Figure 4 is a schematic diagram of warp beam dyeing in a preferred embodiment of the present invention.

第五圖 係為本發明較佳實施例之三軸壓光示意圖。 Figure 5 is a schematic diagram of triaxial calendering in a preferred embodiment of the present invention.

第六圖 係為本發明較佳實施例之全面貼合示意圖。 Figure 6 is a schematic diagram of the overall lamination of the preferred embodiment of the present invention.

為達成上述目的及功效,本發明所採用之技術手段及構造,茲繪圖就本發明較佳實施例詳加說明其特徵與功能如下,俾利完全了解。 In order to achieve the above-mentioned purpose and effect, the technical means and structure adopted by the present invention are hereby illustrated in detail with respect to the preferred embodiments of the present invention. Its features and functions are as follows, so that it can be fully understood.

請參閱第二圖至第六圖所示,係為本發明較佳實施例之立體透視圖至全面貼合示意圖,由圖中可清楚看出本發明係包括: Please refer to the second figure to the sixth figure, which are stereoscopic perspective views of the preferred embodiment of the present invention to a full bonding schematic diagram. It can be clearly seen from the figures that the present invention includes:

一聚酯原絲基材1,係以緯重平組織(Weft Rib Weave)成型,且其總丹尼數為600D以上,並於該聚酯原絲基材1表面形成複數網狀排列之立體凸出部11; A polyester raw silk base material 1 is molded with a weft-rib weave (Weft Rib Weave), and its total denier number is more than 600D, and a plurality of three-dimensional net-like arrangements are formed on the surface of the polyester raw silk base material 1. protrusion 11;

一經軸染色部2,係藉由控制捲布密度及染色壓差值形成於該聚酯原絲基材1上; A warp beam dyeing part 2 is formed on the polyester raw silk substrate 1 by controlling the cloth density and the dyeing pressure difference;

一仿淋膜層3,係由無溶劑反應型聚氨酯(Thermoplastic polyurethanes,TPU)加熱成型;及 An imitation coating layer 3 is heat-molded by solvent-free reactive polyurethane (Thermoplastic polyurethanes, TPU); and

一濕氣硬化型聚氨酯熱熔膠4(Polyurethane Reactive,PUR),係利用全面式移轉塗布貼合方式,使該聚酯原絲基材1與該仿淋膜層3複合成型。 A moisture-curing polyurethane hot-melt adhesive 4 (Polyurethane Reactive, PUR) is formed by compounding the polyester raw silk base material 1 and the imitation coating layer 3 by using a full-scale transfer coating lamination method.

而本發明之一種環保無溶劑重磅織物之製程,其中主要包括: And the manufacturing process of a kind of environment-friendly solvent-free heavy fabric of the present invention, wherein mainly comprises:

(a)織物設計:將聚酯原絲以平紋組織製成緯重平組織(Weft Rib Weave)態樣之聚酯原絲基材1,且其總丹尼數為600D以上; (a) Fabric design: the polyester raw silk base material 1 is made into a weft rib weave (Weft Rib Weave) pattern with a plain weave, and its total denier number is more than 600D;

(b)織造:於該聚酯原絲基材1表面形成複數網狀排列之立體凸出部11; (b) Weaving: forming a plurality of three-dimensional protrusions 11 arranged in a network on the surface of the polyester raw silk substrate 1;

(c)基材捲繞:將該聚酯原絲基材1捲繞於空心捲軸5上,該空心捲軸5上具有複數開孔51,且該聚酯原絲基材1從內至外的捲繞密度漸高; (c) Substrate winding: the polyester precursor substrate 1 is wound on the hollow reel 5, which has a plurality of openings 51, and the polyester precursor substrate 1 from the inside to the outside The winding density is getting higher;

(d)經軸染色:將該聚酯原絲基材1及該空心捲軸5置於染色槽6中,並控制其染色壓差值以於該聚酯原絲基材1上形成一經軸染色部2; (d) Beam dyeing: place the polyester precursor base material 1 and the hollow reel 5 in the dyeing tank 6, and control the dyeing pressure difference to form a beam dyeing process on the polyester precursor base material 1. part 2;

(e)壓光:利用一三軸熱壓機7將染色後的聚酯原絲基材1進行兩次壓光; (e) calendering: using a three-axis hot press 7 to carry out calendering twice on the dyed polyester raw silk substrate 1;

(f)第一塗頭膜層上膠:利用一第一塗布模組81導入一仿淋膜層3,並於該仿淋膜層3上塗布濕氣硬化型聚氨酯熱熔膠4(Polyurethane Reactive ,PUR),該仿淋膜層3係由無溶劑反應型聚氨酯(Thermoplastic polyurethanes,TPU)加熱成型; (f) Gluing on the first coating head film layer: Utilize a first coating module 81 to import an imitation coating layer 3, and apply moisture-curing polyurethane hot melt adhesive 4 (Polyurethane Reactive) on the imitation coating layer 3 , PUR), the imitation coating layer 3 is heat-molded by solvent-free reactive polyurethane (Thermoplastic polyurethanes, TPU);

(g)第二塗頭基材上膠:利用一第二塗布模組82導入壓光後之聚酯原絲基材1,並於其上塗布濕氣硬化型聚氨酯熱熔膠4(Polyurethane Reactive,PUR);及 (g) Glue on the substrate of the second coating head: Utilize a second coating module 82 to introduce the calendered polyester precursor substrate 1, and apply moisture-curing polyurethane hot melt adhesive 4 (Polyurethane Reactive , PUR); and

(h)塗層複合:將塗布濕氣硬化型聚氨酯熱熔膠4後的仿淋膜層3及聚酯原絲基材1,進行一次性的全面貼合,使該聚酯原絲基材1與該仿淋膜層3複合成型。 (h) Coating composite: the imitation coating layer 3 and the polyester raw silk base material 1 after coating the moisture-hardening type polyurethane hot melt adhesive 4 are carried out in a one-time comprehensive lamination, so that the polyester raw silk base material 1 and the imitation coating layer 3 are compositely formed.

其中,該聚酯原絲基材1之經向密度為每吋40根至46根,且該緯向密度為每吋22根至28根,該聚酯原絲基材1之捲布密度平均硬度為邵氏硬度55A至66A,該聚酯原絲基材1之染色壓差值為每平方公分3公斤至5公斤,該聚酯原絲基材1之張力控制在幅寬縮率25毫米(mm)至40毫米(mm),且其中該第一塗布模組81係分別具有一刀軸部811、一入料軸812、及一設於該刀軸部811與該入料軸812間之轉移軸813,且該刀軸部811與該轉移軸813間形成有一第一調節間隙83,該轉移軸813與該入料軸812間形成有一第二調節間隙84,同樣的該第二塗布模組81也具有對應的刀軸部821、入料軸822、及轉移軸823。 Wherein, the warp direction density of the polyester precursor base material 1 is 40 to 46 strands per inch, and the weft density is 22 to 28 strands per inch, and the cloth density of the polyester strand base material 1 is average The hardness is Shore hardness 55A to 66A, the dyeing pressure difference of the polyester raw silk base material 1 is 3 kg to 5 kg per square centimeter, and the tension of the polyester raw silk base material 1 is controlled at a width shrinkage rate of 25 mm (mm) to 40 millimeters (mm), and wherein the first coating module 81 has a knife shaft portion 811, a material feed shaft 812, and a blade between the knife shaft portion 811 and the material feed shaft 812. Transfer shaft 813, and a first adjustment gap 83 is formed between the cutter shaft portion 811 and the transfer shaft 813, a second adjustment gap 84 is formed between the transfer shaft 813 and the feeding shaft 812, and the same second coating mold The set 81 also has a corresponding cutter shaft portion 821 , feeding shaft 822 , and transfer shaft 823 .

藉由上述之說明,已可了解本技術之結構,而依據這個結構之對應配合,更可達到複合塗層牢固度佳、經緯組織強度高、布面立體飽滿、染色均勻飽和、表面平整光滑、製程環保無溶劑、及可降低製造成本等優勢,而詳細之解說將於下述說明。 Through the above description, the structure of this technology can be understood, and according to the corresponding cooperation of this structure, the composite coating can be achieved with good firmness, high warp and weft weave strength, three-dimensional and full cloth surface, uniform and saturated dyeing, smooth and smooth surface, The process is environmentally friendly, solvent-free, and can reduce manufacturing costs. The detailed explanation will be explained below.

由第二圖及第三圖中可清楚看出,首先以織物設計與織造而言,本實施例之織物係以開發為袋材作為舉例,而纖維的選擇及組織設計是袋材開發的重要關鍵之一,故原料的選擇以高丹尼聚酯原絲纖維(Polyester Fully Oriented Yarn,FOY)作為主材料,並搭配高質感之織物外觀結構設計,產出聚酯原絲基材1,以大幅提升面料基本抗撕裂與拉伸強度,達到織物緊實耐磨耗,同時具有光澤金屬感。所以本發明必須選擇合適的織物組織結構,與抓住原料特殊性之間相互關係的重要性,因此,為了營造飽滿粗曠的自然風格,以設計出布身經緯的組織突出於布面而產生立體凸出部11,即所謂的突出針點,然而,普通一上一下的平紋組織雖然可形成突出針點,但不夠突出不夠豐滿,因此,本 發明以平紋變化設計緯重平組織結構,產生符合需求的立體凸出部11,並具有最佳結構穩定性和最大的織物強度。 It can be clearly seen from the second and third figures that, first of all, in terms of fabric design and weaving, the fabric in this embodiment is developed as a bag material as an example, and fiber selection and tissue design are important in the development of bag materials. One of the key points, so the selection of raw materials is made of high-denier polyester fiber (Polyester Fully Oriented Yarn, FOY) as the main material, and with the high-quality fabric appearance structure design, the polyester fiber substrate 1 is produced, with The basic tear resistance and tensile strength of the fabric are greatly improved, so that the fabric is firm and wear-resistant, and at the same time has a lustrous metallic feel. Therefore, in the present invention, it is necessary to select a suitable fabric structure and grasp the importance of the relationship between the particularity of the raw material. Therefore, in order to create a full and rough natural style, the warp and weft of the cloth body is designed to protrude from the cloth surface. The three-dimensional protruding part 11 is the so-called protruding pin point. However, although the ordinary plain weave with one up and one down can form a protruding pin point, it is not protruding enough and full. Therefore, this The invention uses plain weave variation to design the weft-heavy flat weave structure to produce a three-dimensional protrusion 11 that meets the requirements, and has the best structural stability and maximum fabric strength.

其中,聚酯原絲的丹尼數以600D以上為佳,具體而言,因經緯丹尼數的設計對針點的突出非常密切,故本發明係以經向250D合股為500D後,再雙根合併配製成1000D,使織物組織呈現立體粗曠感,而經緯密度的設計適當與否,則是決定織物外觀的主要因素,過大的經緯密度會使織物手感變硬、彈性差、成本高,經緯密度過小則影響織物豐滿度且易造成位移,因此本發明以經向密度為40根/吋~46根/吋,緯向密度22根/吋~28根/吋進行。 Among them, the denier number of the polyester raw yarn is better than 600D. Specifically, because the design of the warp and weft denier numbers is very close to the protrusion of the pin point, so the present invention is based on warp direction 250D plying to 500D, and double The roots are combined and formulated into 1000D, which makes the fabric texture present a three-dimensional rough feeling, and whether the design of the warp and weft density is appropriate or not is the main factor determining the appearance of the fabric. Excessive warp and weft density will make the fabric feel hard, poor in elasticity, and high in cost If the warp and weft density is too small, it will affect the fullness of the fabric and easily cause displacement. Therefore, the present invention is carried out with a warp density of 40 threads/inch to 46 threads/inch and a weft density of 22 threads/inch to 28 threads/inch.

如第三圖及第四圖所示,針對重磅布匹的經軸染色技術,為了克服傳統高壓溢流染色機染色易造成布面勾毛、裂紗水傷、雞爪痕、方格不正等缺點,本發明以技術層次較高的高溫高壓布匹經軸染色方法進行,並開發高均染性、飽和度佳、平整性佳之重磅織物。然而,在實際重磅布匹經軸染色中,若捲布密度、染色壓差或染色載布量參數設計不佳,容易出現織物在染色過程中移位、經軸內外層顏色差異、或織物面產生水波紋等問題。因此,本發明針對捲布密度的設計,係使聚酯原絲基材1從內至外的捲繞密度漸高,且經軸平均硬度為55A~65A,其中,若捲布時張力大或張力不均會造成染液穿透不均勻,產生色差等瑕疵,故利用聚酯原絲基材1在空心捲軸5上的內、中、外各層捲布密度之不同,使聚酯原絲基材1在空心捲軸5上平整不易滑移,同時利用空心捲軸5上的開孔51,使液流在染色槽6中能充分穿透外層,讓聚酯原絲基材1上色均勻,另外,一般經軸染色時,靠高壓將染液強行穿透織物,會因壓差過大易產生移位左右異色,或因壓差過小使染液無法穿透聚酯原絲基材1布面而產生嚴重色花現象。因此,本發明依據重磅織物密度及最適捲布量制定最適合的染色壓差值為3kg/cm2~5kg/cm2,而藉上述操作產生本發明期望之經軸染色部2。 As shown in the third and fourth pictures, the warp beam dyeing technology for heavy-weight cloth is aimed at overcoming the shortcomings of the traditional high-pressure overflow dyeing machine, which may easily cause the cloth surface to be scratched, water damage, chicken claw marks, and irregular squares. , the present invention is carried out by the high-temperature and high-pressure cloth warp beam dyeing method with higher technical level, and develops heavy fabrics with high level dyeing property, good saturation and good flatness. However, in the actual warp beam dyeing of heavy cloth, if the parameters of the cloth density, dyeing pressure difference or dyeing load are not well designed, it is easy to cause the fabric to shift during the dyeing process, the color difference between the inner and outer layers of the warp beam, or the surface of the fabric to be damaged. Problems such as water ripples occur. Therefore, the design of the present invention for the cloth rolling density is to make the winding density of the polyester raw silk substrate 1 gradually increase from the inside to the outside, and the average hardness of the warp beam is 55A~65A. Uneven tension will cause uneven penetration of the dyeing solution, resulting in color difference and other defects. Therefore, the difference in the density of the inner, middle and outer layers of the polyester raw silk substrate 1 on the hollow reel 5 is used to make the polyester raw silk substrate The material 1 is flat on the hollow reel 5 and is not easy to slip. At the same time, the opening 51 on the hollow reel 5 is used to make the liquid flow in the dyeing tank 6 fully penetrate the outer layer, so that the polyester raw silk substrate 1 is evenly colored. Generally, when warp beam dyeing, the dye solution is forced to penetrate the fabric by high pressure, which will easily cause shifting and left-right color difference due to excessive pressure difference, or the dye solution cannot penetrate the polyester raw silk substrate 1 fabric surface due to too small pressure difference. Severe discoloration occurs. Therefore, the present invention formulates the most suitable dyeing pressure difference value of 3kg/cm 2 ~5kg/cm 2 according to the heavy fabric density and the optimum cloth volume, and the desired warp beam dyeing part 2 of the present invention is produced by the above operation.

如第三圖及第五圖所示,就重磅織物表面處理而言,重磅聚酯織物丹尼數高,交織點間有一定的空隙,且織物表面具有凹凸的交織點,為使重磅織物表面毛羽平整、紗線間空隙減少、且結構緊密,以確保在塗層複合加工時的布面平整性,須對織物進行壓光處理,以達到理想的密度、厚度及手感,確保複合面平整,達到接著強度之要求。具體而言,本發明係以三軸熱壓機7進行壓光處理,相較於傳統二輥熱壓機,三軸壓光可以一回進行兩次壓光,使 聚酯原絲基材1產生壓縮、讓表面單絲的毛羽變得扁平化、紗線間的間隙變小、且表面平整緻密。而壓光參數設定部分,因壓光製程中張力及溫度之控制對重磅織物成形物性影響極大,張力太小會產生壓折,張力太大則幅寬會縮減,故本發明將張力控制在幅寬縮率25mm~40mm。 As shown in Figure 3 and Figure 5, in terms of the surface treatment of heavyweight polyester fabrics, heavyweight polyester fabrics have a high denier number, there are certain gaps between interweaving points, and the surface of the fabric has concave and convex interweaving points. The surface hairiness of the pound fabric is smooth, the gaps between the yarns are reduced, and the structure is tight, so as to ensure the flatness of the cloth surface during the coating composite processing. The fabric must be calendered to achieve the ideal density, thickness and feel to ensure the composite The surface is flat and meets the requirements of bonding strength. Specifically, the present invention uses a three-axis heat press 7 to perform calendering treatment. Compared with a traditional two-roll heat press, the three-axis calender can be calendered twice at one time, so that The polyester raw silk base material 1 is compressed, so that the hairiness of the surface monofilaments becomes flattened, the gaps between the yarns become smaller, and the surface is smooth and compact. As for the setting of calendering parameters, the control of tension and temperature in the calendering process has a great influence on the forming properties of heavy fabrics. If the tension is too small, creasing will occur, and if the tension is too high, the width will be reduced. Therefore, the present invention controls the tension at Width shrinkage rate 25mm~40mm.

如第三圖及第六圖所示,至於環保問題及塗層複合問題,本發明之仿淋膜層3為無溶劑單組份反應型聚氨酯組成份,並以異氰酸酯與多元醇為主要原料,其在一定條件下合成預聚物,使反應型聚氨酯材料成膜後具有結構堅韌、繞曲性佳、接著強度高等特性,並為了降低熔融黏度及熔融溫度、提高熔融時的黏度穩定性、降低成本、簡化生產製程,以及提高成膜性初始黏著性、耐水解性、柔軟性等機械性能,更以濕氣硬化型聚氨酯熱熔膠4(Polyurethane Reactive,PUR)作為黏著劑,以符合環保需求、突破重磅織物的膜複合接著強度。 As shown in Figure 3 and Figure 6, as for environmental protection and coating compounding issues, the imitation coating layer 3 of the present invention is a solvent-free one-component reactive polyurethane component, and isocyanate and polyol are used as main raw materials. It synthesizes a prepolymer under certain conditions, so that the reactive polyurethane material has the characteristics of tough structure, good flexibility, and high bonding strength after forming a film. In order to reduce the melt viscosity and melting temperature, improve the viscosity stability during melting, and reduce cost, simplify the production process, and improve mechanical properties such as film-forming initial adhesion, hydrolysis resistance, and flexibility, and use moisture-curing polyurethane hot-melt adhesive 4 (Polyurethane Reactive, PUR) as the adhesive to meet environmental protection requirements , Breaking through the film composite bonding strength of heavy fabrics.

具體而言,本發明係利用雙塗頭轉移塗布系統8進行塗布,由於傳統刮刀塗布是將不平整的織物表面和剛性金屬刀之間的空隙(擠壓)填滿,膠料將充滿織物紗線的頂部和底部,透過較厚的膠料填充織物的間隙,過多膠料會滲透到織物內部而造成黏合量變少,影響材料複合時的黏接強度。本發明之雙塗頭轉移塗布系統8為多軸系統,第一塗布模組81由左而右具有刀軸部811、轉移軸813及入料軸812,用以傳送仿淋膜層3,並於仿淋膜層3上塗布濕氣硬化型聚氨酯熱熔膠4,第二塗布模組82由右而左具有刀軸部821、轉移軸823及入料軸822,用以傳送聚酯原絲基材1,並於聚酯原絲基材1上塗布濕氣硬化型聚氨酯熱熔膠4,且刀軸部811(或821)與轉移軸813(或823)間形成有可調整寬度的第一調節間隙83,該轉移軸813(或823)與該入料軸812(或822)間也形成有可調整的第二調節間隙84,藉以控制濕氣硬化型聚氨酯熱熔膠4的滲透量,因此,本發明得以相同厚度的膠料在轉移軸813、823上形成,再轉移到聚酯原絲基材1與仿淋膜層3,這時剪切力比刮刀要小,使聚酯原絲基材1上各個點(即紗的峰與谷)的塗布效果一致,當紗的突出部具較多膠料時,參與黏合的量足夠,將獲得顯著的機械性能提升,而藉由濕氣硬化型聚氨酯熱熔膠4滲透量的控制,可克服許多塗層容易出現的瑕疵,且轉移塗布複合後的織物手感變得較柔軟。此外,雙塗頭轉移塗布系統8可以不做機械改變而適用於開放式塗布結構和全 覆蓋式塗布結構,塗布液滲入聚酯原絲基材1或仿淋膜層3的深度,可以透過增加或減小第一調節間隙83,及轉移軸813、823與基材之間的第二調節間隙84大小與速度差異來調節,進行半滲透加工或全塗碎紋加工。 Specifically, the present invention utilizes a double-coating head transfer coating system 8 for coating. Since the traditional knife coating is to fill up the gap (extrusion) between the uneven fabric surface and the rigid metal knife, the sizing material will be filled with the fabric yarn The top and bottom of the thread fill the gaps in the fabric with thicker glue. Too much glue will penetrate into the fabric and cause less bonding, which will affect the bonding strength of the material when it is compounded. The double-coating head transfer coating system 8 of the present invention is a multi-axis system, and the first coating module 81 has a cutter shaft portion 811, a transfer shaft 813, and a feeding shaft 812 from left to right, for conveying the imitation coating layer 3, and Apply moisture-curing polyurethane hot-melt adhesive 4 on the imitation coating layer 3. The second coating module 82 has a knife shaft part 821, a transfer shaft 823, and a feeding shaft 822 from right to left for conveying polyester raw silk base material 1, and apply moisture-curing polyurethane hot melt adhesive 4 on the polyester raw silk base material 1, and a first adjustable width is formed between the knife shaft part 811 (or 821) and the transfer shaft 813 (or 823). An adjustment gap 83, an adjustable second adjustment gap 84 is also formed between the transfer shaft 813 (or 823) and the feed shaft 812 (or 822), so as to control the penetration amount of the moisture-curing polyurethane hot melt adhesive 4 Therefore, the present invention can form the sizing material of the same thickness on the transfer shafts 813, 823, and then transfer to the polyester raw silk base material 1 and the imitation coating layer 3. At this time, the shearing force is smaller than that of the scraper, so that the polyester raw silk The coating effect of each point on the silk substrate 1 (that is, the peaks and valleys of the yarn) is consistent. When the protruding part of the yarn has more glue, the amount involved in bonding is sufficient, and a significant improvement in mechanical properties will be obtained. The control of the penetration of air-curing polyurethane hot melt adhesive 4 can overcome the defects that are prone to appear in many coatings, and the fabric feels softer after transfer coating and compounding. In addition, the dual-head transfer coating system 8 can be adapted to open coating structures and full coating without mechanical changes. Covering coating structure, the depth of the coating liquid penetrating into the polyester raw silk substrate 1 or the imitation coating layer 3 can be adjusted by increasing or decreasing the first gap 83, and the second gap between the transfer shafts 813, 823 and the substrate. Adjust the size of the gap 84 and the speed difference to adjust, and carry out semi-permeable processing or full-coating grain processing.

惟,以上所述僅為本發明之較佳實施例而已,非因此即侷限本發明之專利範圍,故舉凡運用本發明說明書及圖式內容所為之簡易修飾及等效結構變化,均應同理包含於本發明之專利範圍內,合予陳明。 However, the above description is only a preferred embodiment of the present invention, and does not limit the patent scope of the present invention. Therefore, all simple modifications and equivalent structural changes made by using the description and drawings of the present invention should be treated in the same way. Included in the scope of the patent of the present invention, it is jointly stated.

綜上所述,本發明之環保無溶劑重磅織物之結構及其製程於使用時,為確實能達到其功效及目的,故本發明誠為一實用性優異之發明,為符合發明專利之申請要件,爰依法提出申請,盼 審委早日賜准本發明,以保障發明人之辛苦發明,倘若 鈞局審委有任何稽疑,請不吝來函指示,發明人定當竭力配合,實感德便。 To sum up, the structure and manufacturing process of the environmentally friendly solvent-free heavyweight fabric of the present invention can indeed achieve its effect and purpose when used, so the present invention is an invention with excellent practicability, and it is in line with the application for an invention patent The essential requirement is to file an application in accordance with the law. I hope that the review committee will approve the invention as soon as possible to protect the hard work of the inventor. If the review committee has any doubts, please feel free to send a letter to instruct the inventor. I will do my best to cooperate, and I really appreciate it.

1:聚酯原絲基材 1: Polyester raw silk substrate

11:立體凸出部 11: three-dimensional protrusion

2:經軸染色部 2: Warp axis dyeing department

3:仿淋膜層 3: imitation coating layer

4:濕氣硬化型聚氨酯熱熔膠 4: Moisture hardening polyurethane hot melt adhesive

Claims (10)

一種環保無溶劑重磅織物之結構,其主要包括: An environment-friendly solvent-free heavy fabric structure, which mainly includes: 一聚酯原絲基材,係以緯重平組織(Weft Rib Weave)成型,且其總丹尼數為600D以上,並於該聚酯原絲基材表面形成複數網狀排列之立體凸出部; A polyester raw silk base material, which is formed by Weft Rib Weave (Weft Rib Weave), and its total denier number is more than 600D, and forms a plurality of three-dimensional protrusions arranged in a network on the surface of the polyester raw silk base material department; 一經軸染色部,係藉由控制捲布密度及染色壓差值形成於該聚酯原絲基材上; A warp beam dyeing section is formed on the polyester raw silk substrate by controlling the cloth density and the dyeing pressure difference; 一仿淋膜層,係由無溶劑反應型聚氨酯(Thermoplastic polyurethanes,TPU)加熱成型;及 An imitation coating layer, which is thermoformed by solvent-free reactive polyurethane (Thermoplastic polyurethanes, TPU); and 一濕氣硬化型聚氨酯熱熔膠(Polyurethane Reactive,PUR),係利用全面式移轉塗布貼合方式,使該聚酯原絲基材與該仿淋膜層複合成型。 A moisture-curing polyurethane hot-melt adhesive (Polyurethane Reactive, PUR), which uses a full-scale transfer coating lamination method to make the polyester raw silk base material and the imitation coating layer compositely formed. 如申請專利範圍第1項所述之環保無溶劑重磅織物之結構,其中該聚酯原絲基材之經向密度為每吋40根至46根,且該緯向密度為每吋22根至28根。 The structure of the environmentally friendly solvent-free heavyweight fabric as described in item 1 of the patent application, wherein the warp density of the polyester raw silk substrate is 40 to 46 threads per inch, and the weft density is 22 threads per inch to 28. 如申請專利範圍第1項所述之環保無溶劑重磅織物之結構,其中該聚酯原絲基材之捲布密度平均硬度為邵氏硬度55A至66A。 The structure of the environment-friendly solvent-free heavyweight fabric as described in item 1 of the scope of the patent application, wherein the average hardness of the cloth density of the polyester raw silk base material is Shore hardness 55A to 66A. 如申請專利範圍第1項所述之環保無溶劑重磅織物之結構,其中該聚酯原絲基材之染色壓差值為每平方公分3公斤至5公斤。 The structure of the environment-friendly solvent-free heavyweight fabric described in item 1 of the patent application, wherein the dyeing pressure difference of the polyester raw silk base material is 3 kg to 5 kg per square centimeter. 如申請專利範圍第1項所述之環保無溶劑重磅織物之結構,其中該聚酯原絲基材之張力控制在幅寬縮率25毫米(mm)至40毫米(mm)。 The structure of the environment-friendly solvent-free heavyweight fabric as described in item 1 of the scope of the patent application, wherein the tension of the polyester raw silk substrate is controlled at a width shrinkage rate of 25 millimeters (mm) to 40 millimeters (mm). 一種環保無溶劑重磅織物之製程,其中主要包括: A process for the production of environmentally friendly solvent-free heavyweight fabrics, which mainly includes: (a)將聚酯原絲以平紋組織製成緯重平組織(Weft Rib Weave)態樣之聚酯原絲基材,且其總丹尼數為600D以上; (a) The polyester raw silk substrate is made into a weft rib weave (Weft Rib Weave) pattern with a plain weave, and its total denier number is more than 600D; (b)於該聚酯原絲基材表面形成複數網狀排列之立體凸出部; (b) forming a plurality of three-dimensional protrusions arranged in a network on the surface of the polyester raw silk substrate; (c)將該聚酯原絲基材捲繞於空心捲軸上,該空心捲軸上具有複數開孔,且該聚酯原絲基材從內至外的捲繞密度漸高; (c) winding the polyester precursor base material on a hollow reel, the hollow reel has a plurality of openings, and the winding density of the polyester precursor base material is gradually higher from the inside to the outside; (d)將該聚酯原絲基材及該空心捲軸置於染色槽中,並控制其染色壓差值以於該聚酯原絲基材上形成一經軸染色部; (d) placing the polyester raw silk substrate and the hollow reel in a dyeing tank, and controlling the dyeing pressure difference to form a warp beam dyeing portion on the polyester raw silk substrate; (e)利用一三軸熱壓機將染色後的聚酯原絲基材進行兩次壓光; (e) Carrying out calendering twice to the dyed polyester raw silk base material by a three-axis hot press; (f)利用一第一塗布模組導入一仿淋膜層,並於該仿淋膜層上塗布濕氣 硬化型聚氨酯熱熔膠(Polyurethane Reactive,PUR),該仿淋膜層係由無溶劑反應型聚氨酯(Thermoplastic polyurethanes,TPU)加熱成型; (f) Utilize a first coating module to introduce an imitation coating layer, and apply moisture on the imitation coating layer Hardened polyurethane hot melt adhesive (Polyurethane Reactive, PUR), the imitation coating layer is formed by heating of solvent-free reactive polyurethane (Thermoplastic polyurethanes, TPU); (g)利用一第二塗布模組導入壓光後之聚酯原絲基材,並於其上塗布濕氣硬化型聚氨酯熱熔膠(Polyurethane Reactive,PUR);及 (g) using a second coating module to introduce the calendered polyester precursor substrate, and apply moisture-curing polyurethane hot-melt adhesive (Polyurethane Reactive, PUR) thereon; and (h)將塗布濕氣硬化型聚氨酯熱熔膠後的仿淋膜層及聚酯原絲基材,進行一次性的全面貼合,使該聚酯原絲基材與該仿淋膜層複合成型。 (h) Carry out one-time comprehensive lamination of the imitation coating layer and the polyester raw silk base material after the moisture-curing polyurethane hot melt adhesive is applied, so that the polyester precursor base material and the imitation coating layer are compounded forming. 如申請專利範圍第6項所述之環保無溶劑重磅織物之製程,其中該聚酯原絲基材之經向密度為每吋40根至46根,且該緯向密度為每吋22根至28根。 The manufacturing process of the environmentally friendly solvent-free heavyweight fabric as described in item 6 of the patent application, wherein the warp density of the polyester raw silk substrate is 40 to 46 threads per inch, and the weft density is 22 threads per inch to 28. 如申請專利範圍第6項所述之環保無溶劑重磅織物之製程,其中該聚酯原絲基材之染色壓差值為每平方公分3公斤至5公斤。 The manufacturing process of the environment-friendly solvent-free heavyweight fabric as described in item 6 of the scope of the patent application, wherein the dyeing pressure difference of the polyester raw silk base material is 3 kg to 5 kg per square centimeter. 如申請專利範圍第6項所述之環保無溶劑重磅織物之製程,其中該聚酯原絲基材之張力控制在幅寬縮率25毫米(mm)至40毫米(mm)。 The manufacturing process of the environmentally friendly solvent-free heavyweight fabric as described in item 6 of the patent application, wherein the tension of the polyester raw silk base material is controlled at a width shrinkage rate of 25 millimeters (mm) to 40 millimeters (mm). 如申請專利範圍第6項所述之環保無溶劑重磅織物之製程,其中該第一塗布模組及該第二塗布模組係分別具有一刀軸部、一入料軸、及一設於該刀軸部與該入料軸間之轉移軸,且該刀軸部與該轉移軸間形成有一第一調節間隙,該轉移軸與該入料軸間形成有一第二調節間隙。 The manufacturing process of the environmentally friendly solvent-free heavy fabric as described in item 6 of the scope of the patent application, wherein the first coating module and the second coating module have a cutter shaft, a feeding shaft, and a The transfer shaft between the cutter shaft part and the feeding shaft, and a first adjustment gap is formed between the cutter shaft part and the transfer shaft, and a second adjustment gap is formed between the transfer shaft and the feeding shaft.
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