TW202239340A - Edible particles, manufacturing method thereof, and foods containing the same - Google Patents

Edible particles, manufacturing method thereof, and foods containing the same Download PDF

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TW202239340A
TW202239340A TW110111807A TW110111807A TW202239340A TW 202239340 A TW202239340 A TW 202239340A TW 110111807 A TW110111807 A TW 110111807A TW 110111807 A TW110111807 A TW 110111807A TW 202239340 A TW202239340 A TW 202239340A
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edible
granule
alginate
sterilization
particles
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TWI767639B (en
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陳愉婷
林淑莉
杜邦碩
楊炳輝
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財團法人食品工業發展研究所
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Abstract

The present invention provides an edible particle, which includes based on the total weight of the particle, 0.1% to 5% of alginate and 0.5% to 10% of microbial polysaccharide, and the balance is water. The present invention also provides a method for manufacturing the edible particle, and a food containing the edible particle.

Description

食用顆粒、其製造方法及包含彼之食品Edible particles, their production method and food containing them

本發明係關於一種食用顆粒,特別係關於一種具有耐熱與耐壓力之特性的食用顆粒、該食用顆粒之製造方法及包含該食用顆粒之食品。The present invention relates to an edible granule, in particular to an edible granule with properties of heat resistance and pressure resistance, a method for producing the edible granule and a food containing the edible granule.

近年來,全臺飲料店蓬勃發展,一年創造上千億元產值,且每年出口量年年倍增,堪稱另類臺灣之光。根據經濟部數據統計,飲料店營業額自2008年以來逐年攀升,至2018年已達962億元,平均每年成長8.9%,而2019年1至4月營業額續增4.8%,預期全年可望突破1,000億元。In recent years, Taiwan's beverage stores have flourished, creating an output value of over 100 billion yuan a year, and the annual export volume has doubled every year. It can be called the light of an alternative Taiwan. According to statistics from the Ministry of Economic Affairs, the turnover of beverage stores has increased year by year since 2008, reaching 96.2 billion yuan in 2018, with an average annual growth rate of 8.9%. The turnover from January to April 2019 continued to increase by 4.8%. Hope to exceed 100 billion yuan.

在臺灣的諸多飲品種類中,以含顆粒飲品最受歡迎。將粉圓(珍珠)加入奶茶中,由於口感特殊且變化多元,所以受到廣大的歡迎與回響,也成為臺灣最具代表性的飲食之一,並從臺灣流行至周邊國家地區甚至世界各地。珍珠奶茶不只國人愛喝,這股珍奶熱也跨出海外搶市,遠在東非都買得到。此外,粉圓(珍珠)更廣泛應用於其他飲料、冰棒、雪糕、糖果與蛋糕甜點等。近年來臺灣粉圓出口量年年倍增,根據行政院農委會資料,2019年1月至8月間臺灣粉圓對日出口值達2,679萬美元,相較於2018年同期237萬美元成長了10倍。臺灣珍珠奶茶乃全球珍珠奶茶產業的標竿,牽引產業脈動,於2019年上半年度已出口超過2.6萬公噸,出口值高達4,950萬美金,外銷比重美國佔第一,其次依序為日本、南韓、菲律賓與加拿大等國家,成為跨海最成功的臺灣餐飲。Among the many types of beverages in Taiwan, beverages containing particles are the most popular. Adding powder balls (pearls) to milk tea, because of its special taste and variety, has been widely welcomed and echoed. It has also become one of the most representative foods in Taiwan, and has become popular from Taiwan to neighboring countries and regions and even all over the world. Bubble milk tea is not only loved by Chinese people, but the craze for precious milk tea is also sold overseas, and it can be bought as far away as East Africa. In addition, powder balls (pearls) are more widely used in other beverages, popsicles, ice cream, candy and cake desserts, etc. In recent years, the export volume of Taiwan’s rice balls has doubled every year. According to the data from the Council of Agriculture of the Executive Yuan, the export value of Taiwan’s rice balls to Japan reached US$26.79 million from January to August 2019, an increase of 10% compared to US$2.37 million in the same period in 2018. times. Taiwan’s pearl milk tea is the benchmark of the global pearl milk tea industry, leading the pulse of the industry. In the first half of 2019, it has exported more than 26,000 metric tons, with an export value of up to 49.5 million US dollars. The United States accounts for the largest proportion of exports, followed by Japan and South Korea. , the Philippines, Canada and other countries, becoming the most successful Taiwanese restaurant across the sea.

一般粉圓(珍珠)由樹薯、地瓜或馬鈴薯澱粉再加水及糖製作而成。由於澱粉特性的關係,煮熟的珍珠自然而然就會有Q彈的口感。少數店家為了讓珍珠吃起來更有嚼勁,還會再加入小麥蛋白、玉米澱粉、食用化製澱粉等。然而這些受歡迎的含顆粒飲品,因其中之澱粉無法耐受高溫,當溫度達95℃以上時澱粉顆粒即會破裂崩解,造成許多產品無法進行殺菌處理。目前國內所販售的粉圓(珍珠)產品皆無法進行超高溫(Ultra-high-temperature processing, UHT)殺菌,故需添加防腐劑、糖液才可保存並應用於冷鏈飲品。再者,由於加工設備潔淨程度不足與環境衛生條件管理不易的問題,導致飲品衛生品質不佳且儲存時間短,僅能以手搖現做或是冷藏形式販售。國內食品產業雖已知曉含顆粒飲品為飲料產業新寵兒,但含顆粒流體食品在連續加工和無菌充填下如何確保穩定之品質和殺菌安全性,在製程上卻是相當大的挑戰。General vermicelli (pearls) are made from cassava, sweet potato or potato starch, water and sugar. Due to the characteristics of starch, cooked pearls will naturally have a Q-bomb taste. In order to make the pearls more chewy, a few stores will add wheat protein, corn starch, edible starch, etc. However, these popular beverages containing granules, because the starch in them cannot withstand high temperature, when the temperature reaches above 95°C, the starch granules will burst and disintegrate, resulting in many products that cannot be sterilized. At present, the powder ball (pearl) products sold in China cannot be sterilized by Ultra-high-temperature processing (UHT), so preservatives and sugar solution must be added before they can be stored and applied to cold chain drinks. Furthermore, due to insufficient cleanliness of processing equipment and difficult management of environmental sanitation conditions, the hygienic quality of beverages is poor and the storage time is short, so they can only be sold in the form of hand-cranked or refrigerated. Although the domestic food industry knows that particle-containing beverages are the new darling of the beverage industry, how to ensure stable quality and sterilization safety of particle-containing fluid food under continuous processing and aseptic filling is a considerable challenge in the manufacturing process.

同時,隨著台灣顆粒飲品的知名度日漸提升,當臺商欲將顆粒飲品外銷於世界時,受限於該國家龐大的國土面積,或交通建設的不完備,使粉圓(珍珠)中澱粉成分因不耐加熱、不耐高溫儲存的特性而更加暴露出飲品衛生品質不佳及儲存時間短的缺點。基於目前的粉圓(珍珠)販售品難以達到工業量產的需求,故難以於欲推廣的國家或地區獲取對應的經濟利益。At the same time, with the growing popularity of Taiwan’s granular beverages, when Taiwanese businessmen want to export granular beverages to the world, they are limited by the country’s huge land area or incomplete transportation. The shortcomings of poor hygienic quality and short storage time of beverages are more exposed due to the characteristics of not being resistant to heating and high temperature storage. Based on the fact that the current sales of powder balls (pearls) are difficult to meet the needs of industrial mass production, it is difficult to obtain corresponding economic benefits in the countries or regions to be promoted.

近年來有業者欲利用修飾澱粉,以期解決高溫使澱粉嚴重崩解影響口感,與維持顆粒構型之問題。但其粉圓(珍珠)則只能使用批式殺菌釜(高溫高壓蒸氣殺菌)進行殺菌,因殺菌釜是屬於長時間加熱殺菌之特性,局限珍珠載體飲品種類,限制了相關顆粒飲品的發展,且殺菌完之粉圓(珍珠)容易於儲藏過程中吸水膨大,使得其難以維持原本的構形且造成口感軟化等問題的發生。更甚者,為改善前述問題,竟有不肖業者將未經核准之順丁烯二酸酐化製澱粉添加於常用食品中,演變為重大食安事件,使民眾極為恐慌,導致部分消費者聽到修飾澱粉皆聞之色變,排斥購買相關產品。In recent years, some industry players want to use modified starch in order to solve the problem of severe disintegration of starch due to high temperature, affecting the taste and maintaining the granule configuration. However, its powder balls (pearls) can only be sterilized by using batch-type sterilizers (high temperature and high pressure steam sterilization), because the sterilizers are characterized by long-term heating and sterilization, which limits the types of pearl carrier drinks and limits the development of related particle drinks. And the sterilized powder balls (pearls) tend to absorb water and swell during storage, making it difficult to maintain the original configuration and causing problems such as softening of the mouthfeel. What's more, in order to improve the above-mentioned problems, some unscrupulous operators added unapproved maleic anhydride starch to common food, which turned into a major food safety incident, which caused great panic among the public and caused some consumers to hear that modified The discoloration of starch is discolored by hearing it, and I refuse to buy related products.

因此,於本產業中仍需要能夠耐熱及抗壓的粉圓(珍珠)來提升產業的升級。Therefore, heat-resistant and pressure-resistant powder balls (pearls) are still needed in this industry to upgrade the industry.

為解決上述問題,本發明提供一種食用顆粒,其具有耐熱與耐壓力之特性,而可經高溫高壓蒸氣殺菌或超高溫殺菌等商業殺菌製程處理。In order to solve the above problems, the present invention provides an edible granule, which has the characteristics of heat resistance and pressure resistance, and can be processed by commercial sterilization processes such as high temperature and high pressure steam sterilization or ultra-high temperature sterilization.

因此,本發明提供一種食用顆粒,其包含以總重量計0.1%至5%之海藻酸鹽及0.5%至10%之微生物多醣,餘量為水。Therefore, the present invention provides an edible granule, which comprises 0.1% to 5% alginate and 0.5% to 10% microbial polysaccharide by total weight, and the balance is water.

本發明另提供一種食用顆粒的製造方法,其包含: (a)    混合海藻酸鈉、微生物多醣及水以形成一膠體溶液,其中該膠體溶液包含以該膠體溶液總重量計0.1%至5%之海藻酸鈉及0.5%至10%之微生物多醣,餘量為水;及 (b)    將該膠體溶液滴入一固化液中,並靜置一段充分的時間來使該膠質溶液在該固化液中形成該食用顆粒,其中該固化液包含0.1 M至5 M之二價金屬離子及水。 The present invention also provides a method for producing edible granules, which comprises: (a) mixing sodium alginate, microbial polysaccharides and water to form a colloidal solution, wherein the colloidal solution contains 0.1% to 5% of sodium alginate and 0.5% to 10% of microbial polysaccharides based on the total weight of the colloidal solution, and the remaining the quantity is water; and (b) dropping the colloidal solution into a solidifying solution, and standing for a sufficient period of time to allow the colloidal solution to form the edible particles in the solidifying solution, wherein the solidifying solution contains 0.1 M to 5 M of divalent metal ions and water.

本發明又提供一種由前述方法所製得之食用顆粒,係。The present invention also provides an edible granule prepared by the aforementioned method, which is.

本發明另提供一種包含本發明食用顆粒之食品。The present invention further provides a food comprising the edible particles of the present invention.

本發明提供一種食用顆粒,其包含以總重量計0.1%至5%之海藻酸鹽及0.5%至10%之微生物多醣,餘量為水。The invention provides an edible granule, which comprises 0.1% to 5% alginate and 0.5% to 10% microbial polysaccharide by total weight, and the balance is water.

於本發明一實施例中,該食用顆粒可為例如粉圓(珍珠),亦即其可大致呈圓球體,且其粒徑可為約4 mm至約 10 mm之範圍。較佳地,該食用顆粒可為實心球體,且大致為均質之組成。然而,本發明不限制該食用顆粒之尺寸及形狀等。舉例而言,於其他實施例中,該食用顆粒可為非球體形狀,例如可為立方體、多面體,或具有特殊造型、圖案等。或者,該食用顆粒亦可為非均質結構,例如以前述海藻酸鹽及微生物多醣構成其外圍部分,而其中心部分為中空或包含任何其他可食用成分。In one embodiment of the present invention, the edible particles can be, for example, powder circles (pearls), that is, they can be roughly spherical, and their particle diameters can range from about 4 mm to about 10 mm. Preferably, the edible particles can be solid spheres with a substantially homogeneous composition. However, the present invention does not limit the size, shape, etc. of the edible particles. For example, in other embodiments, the edible particle may be in a non-spherical shape, such as a cube, a polyhedron, or have a special shape or pattern. Alternatively, the edible particle can also be of a heterogeneous structure, for example, the aforementioned alginate and microbial polysaccharides are used to form the peripheral part, while the central part is hollow or contains any other edible components.

本文所述「海藻酸(alginic acid)」又稱藻酸、褐藻酸、海藻素,是來自於褐藻細胞壁中的一種天然多糖,其可萃取自常見的褐藻,例如海帶、馬尾藻、泡葉藻及巨藻等。將前述藻類經氫氧化鈉處理後,再將抽提液與硫酸等強酸反應而製得海藻酸。此外,固氮菌和偽單胞菌也可以用於生物合成海藻酸。The "alginic acid" mentioned in this article, also known as alginic acid, alginic acid, and seaweed, is a natural polysaccharide from the cell wall of brown algae, which can be extracted from common brown algae, such as kelp, sargasso, and Ascophyllum nodosum and macroalgae etc. After the aforementioned algae are treated with sodium hydroxide, the extract is reacted with a strong acid such as sulfuric acid to obtain alginic acid. In addition, nitrogen-fixing bacteria and pseudomonads can also be used to biosynthesize alginic acid.

海藻酸為一種線性不分支的高分子聚合物,單體包含有D-甘露糖醛酸(D-mannuronic acid,下稱M單元)以β-(1→4)鍵結;和L-古羅糖醛酸(L-guluronic acid,下稱G單元)以α-(1→4)鍵結。M和G單元會以M-M、G-G或M-G的組合方式通過糖苷鍵相連成為嵌段共聚體。海藻酸的實驗式為(C 6H 8O 6) n,其分子量範圍則可為約1萬到60萬。 Alginic acid is a kind of linear unbranched polymer, the monomer contains D-mannuronic acid (D-mannuronic acid, hereinafter referred to as M unit) with β-(1→4) linkage; and L-guro Uronic acid (L-guluronic acid, hereinafter referred to as G unit) is bonded by α-(1→4). The M and G units will be connected by glycosidic bonds in a combination of MM, GG or MG to form a block copolymer. The experimental formula of alginic acid is (C 6 H 8 O 6 ) n , and its molecular weight ranges from about 10,000 to 600,000.

海藻酸易與一價陽離子形成具有較高溶解度之化合物,例如與碳酸鈉作用成海藻酸鈉等,其又被稱為海藻膠、褐藻膠或藻膠。海藻膠可與二價金屬離子(例如鈣離子、鋅離子、銅離子等)產生交聯作用(cross-linking),形成具有彈性之凝膠顆粒。舉例而言,將海藻酸鈉溶液滴入氯化鈣溶液中後,溶液中之鈣離子會取代海藻酸鈉羧基上的鈉離子,再結合另一醣醛酸分子上的羧基,形成離子架橋,使海藻酸鈉分子間的聯結性更強,形成一個三度空間的網狀組織結構,進而形成食用顆粒。於一實施例中,海藻酸鈉溶液中的鈉離子可部分或全部置換為鈣離子。Alginic acid is easy to form compounds with high solubility with monovalent cations, for example, it reacts with sodium carbonate to form sodium alginate, which is also known as alginate, alginate or alginate. Alginate can cross-link with divalent metal ions (such as calcium ions, zinc ions, copper ions, etc.) to form elastic gel particles. For example, after the sodium alginate solution is dropped into the calcium chloride solution, the calcium ions in the solution will replace the sodium ions on the carboxyl group of sodium alginate, and then combine with the carboxyl group on another uronic acid molecule to form an ion bridge. Make the connection between sodium alginate molecules stronger, form a three-dimensional network structure, and then form edible particles. In one embodiment, the sodium ions in the sodium alginate solution may be partially or completely replaced by calcium ions.

因此,本文所述「海藻酸鹽」即指前述海藻酸與陽離子所形成例如一或多種選自海藻酸鈉、海藻酸銨及海藻酸鉀之鹽類,及/或與二價金屬離子所形成例如一或多種選自海藻酸鈣、海藻酸鋅及海藻酸銅之鹽類。本文所述之「二價金屬離子」包含但不限於鈣離子、鋅離子及銅離子等。Therefore, the "alginate" mentioned herein refers to the formation of the aforementioned alginic acid and cations, such as one or more salts selected from sodium alginate, ammonium alginate and potassium alginate, and/or the formation of divalent metal ions For example, one or more salts selected from calcium alginate, zinc alginate and copper alginate. The "divalent metal ions" mentioned herein include but not limited to calcium ions, zinc ions and copper ions.

本文所述「微生物多醣」係指例如由細菌及/或真菌(包括黴菌和酵母菌)等所合成的細胞外多醣,其包含但不限於一或多種選自玉米糖膠、卡德蘭膠及結蘭膠之多醣,惟排除前述海藻酸及其鹽類。The "microbial polysaccharide" mentioned herein refers to, for example, extracellular polysaccharides synthesized by bacteria and/or fungi (including molds and yeasts), which include but are not limited to one or more selected from corn sugar gum, cardlan gum and Polysaccharides of gellan gum, except for the aforementioned alginic acid and its salts.

較佳地,海藻酸鹽佔該食用顆粒總重量的百分比為0.1%至5%,例如為0.5%至5%、1%至5%、2%至5%、3%至5%、0.5%至4%、0.5%至3%或1%至3%;且該微生物多醣佔該食用顆粒總重量的百分比為0.5%至10%,例如為1%至10%、3%至10%、5%至10%、0.5%至8%、0.5%至6%或3%至7%。於該等比例範圍下,本發明之食用顆粒不僅成型佳,其口感亦較佳,不會偏脆而無彈性。Preferably, the percentage of alginate in the total weight of the edible particles is 0.1% to 5%, such as 0.5% to 5%, 1% to 5%, 2% to 5%, 3% to 5%, 0.5% to 4%, 0.5% to 3% or 1% to 3%; and the percentage of the microbial polysaccharide in the total weight of the edible particle is 0.5% to 10%, such as 1% to 10%, 3% to 10%, 5% % to 10%, 0.5% to 8%, 0.5% to 6%, or 3% to 7%. Under these ratio ranges, the edible granules of the present invention not only have good shape, but also have good taste, and will not be brittle or inelastic.

藉由該等海藻酸鹽及該等微生物多醣之使用,且藉由前述之比例範圍,可使本發明之食用顆粒具有類似澱粉製粉圓(珍珠)之Q彈口感,並具有耐熱與耐壓力之特性。本發明之食用顆粒經高溫高壓蒸氣殺菌(殺菌釜)及/或超高溫殺菌等商業殺菌程序後,仍可維持口感及顆粒完整性。故本發明之食用顆粒不僅可藉由超高溫殺菌在最短時間內有效地殺死微生物,仍能保持食用顆粒之原有風味、品質與熱敏感營養成分,且具有保藏時間長、維持良好外型穩定性等優點。本發明之食用顆粒可於殺菌後,於常溫下長時間儲藏保存,仍能維持良好的品質及安定性。By the use of these alginates and these microbial polysaccharides, and by the above-mentioned ratio range, the edible granules of the present invention can have a Q-bouncing mouthfeel similar to starch flour balls (pearls), and have heat resistance and pressure resistance. characteristic. The edible granules of the present invention can still maintain the taste and the integrity of the granules after being sterilized by high-temperature and high-pressure steam (sterilizer) and/or ultra-high temperature sterilization and other commercial sterilization procedures. Therefore, the edible granules of the present invention can not only effectively kill microorganisms in the shortest time by ultra-high temperature sterilization, but also maintain the original flavor, quality and heat-sensitive nutrients of the edible granules, and have a long storage time and maintain a good appearance advantages of stability. The edible granules of the present invention can be stored at room temperature for a long time after sterilization, and can still maintain good quality and stability.

亦即,本發明之食用顆粒可用於連續或批式熱加工製程和無菌充填,提供穩定之產品品質和殺菌安全性,據此而達到更佳的商業實用價值。利於業界開創新型態的產品來擴展市場範圍及促進產業升級。此外,更可利於業者將產品銷售至世界各國,特別是該等具有龐大的國土面積的國家,且可解決交通建設及/或冷鏈設備不完備等問題,達到降低生產與運送成本,提升業者市場競爭力與增加產值的效果。That is to say, the edible granules of the present invention can be used in continuous or batch thermal processing and aseptic filling, providing stable product quality and sterilization safety, thereby achieving better commercial practical value. It is beneficial for the industry to create new types of products to expand the market scope and promote industrial upgrading. In addition, it can also help the industry to sell products to countries around the world, especially those countries with a large land area, and can solve the problems of transportation construction and/or incomplete cold chain equipment, so as to reduce production and transportation costs and improve the industry. Market competitiveness and the effect of increasing output value.

於本文中,所述Q彈口感之判定主要是依據Szczeniak et al (1963)全質構分析(Texture Profile Analysis, TPA)方法改良進行檢測,以彈性為主,脆性為輔的兩項口感指標作為判定依據。彈性是指探頭下壓兩次後回彈程度,當數值愈高,代表Q彈程度越高,口感越佳。此外,可進一步納入脆度做為Q彈程度的輔助判定數值,若Q彈程度越高,其脆度數值就會越低,反之若脆度數值偏高,代表Q彈程度較低,容易脆裂。In this paper, the determination of the texture of the Q bomb is mainly based on the improved method of Szczeniak et al (1963) Texture Profile Analysis (TPA). Judgment basis. Elasticity refers to the degree of rebound after the probe is pressed twice. The higher the value, the higher the degree of springiness and the better the taste. In addition, brittleness can be further included as an auxiliary judgment value for the degree of Q bomb. If the degree of Q bomb is higher, the value of brittleness will be lower. On the contrary, if the value of brittleness is higher, it means that the degree of Q bomb is lower and it is easy to be brittle. crack.

於本發明一實施例中,該食用顆粒之彈性係為約50%以上,例如可為約50%至約60%、約50%至約55%、約51%至約58%、約53%至約60%或約55%至約59%。此外,該食用顆粒之脆度係為約33%以下,例如可為約5%至約33%、約15%至約33%、約10%至約30%、約12%至約28%或約5%至約10%。In one embodiment of the present invention, the elasticity of the edible particles is above about 50%, such as about 50% to about 60%, about 50% to about 55%, about 51% to about 58%, about 53% to about 60% or about 55% to about 59%. In addition, the edible particles have a crispness of about 33% or less, such as about 5% to about 33%, about 15% to about 33%, about 10% to about 30%, about 12% to about 28%, or From about 5% to about 10%.

本發明更進一步以前述TPA方法檢測「硬度」,以表現該食用顆粒的質地耐受程度(亦即測試探頭下壓至顆粒變形70%之程度)。相較於其他口感指標(例如前述彈性、脆度等),硬度數值變化最能表現出食用顆粒的質地結構變化。當殺菌破壞程度愈大,則硬度下降程度越大。The present invention further uses the aforementioned TPA method to detect the "hardness" to show the texture tolerance of the edible granules (that is, the test probe is pressed down to the extent that the granules are deformed by 70%). Compared with other taste indicators (such as the aforementioned elasticity, crispness, etc.), the change in hardness value can best reflect the change in the texture and structure of edible particles. The greater the degree of bactericidal destruction, the greater the decrease in hardness.

於本發明一實施例中,該食用顆粒經殺菌處理後的硬度可為該食用顆粒殺菌處理前的硬度的50%以上。較佳地,該食用顆粒經殺菌處理後的硬度可大於或等於該食用顆粒殺菌處理前的硬度。亦即,於經高溫高壓蒸氣殺菌及/或超高溫殺菌後,本發明之食用顆粒之結構並不會被破壞而使硬度大幅下降。於某些實施例中,該食用顆粒經高溫高壓蒸氣殺菌及/或超高溫殺菌後,反而硬度會逐漸提升,顯示本發明具有特定組成比例之食用顆粒的質地結構在殺菌過程中反會更穩固,而使硬度增加。In one embodiment of the present invention, the hardness of the edible granules after the sterilization treatment may be more than 50% of the hardness of the edible granules before the sterilization treatment. Preferably, the hardness of the edible particles after the sterilization treatment may be greater than or equal to the hardness of the edible particles before the sterilization treatment. That is to say, after being sterilized by high-temperature, high-pressure steam and/or ultra-high temperature, the structure of the edible particles of the present invention will not be destroyed and the hardness will be greatly reduced. In some embodiments, after the edible particles are sterilized by high-temperature, high-pressure steam and/or ultra-high temperature sterilization, the hardness will gradually increase, which shows that the texture and structure of the edible particles with specific composition ratios in the present invention will be more stable during the sterilization process , so that the hardness increases.

於本發明一實施例中,該食用顆粒較佳不含澱粉及/或修飾澱粉。所述修飾澱粉包含但不限於糊精(Dextrin)、酸性改性澱粉(Acid-treated starch)、鹼性改性澱粉(Alkaline-treated starch)、漂白澱粉(Bleached starch)、氧化澱粉(Oxidized starch)、酵素改性澱粉(Starches, enzyme-treated)、磷酸澱粉(Monostarch phosphate)、磷酸二澱粉(Distarch phosphate)、磷酸化磷酸二澱粉(Phosphated distarch phosphate)、乙醯化磷酸二澱粉(Acetylated distarch phosphate)、醋酸澱粉(Starch acetate)、乙醯化己二酸澱粉(Acetylated distarch adipate)、羥丙基澱粉(Hydroxypropyl starch)、羥丙基磷酸二澱粉(Hydroxypropyl distarch phosphate)、羥丙基磷酸甘油二澱粉(Hydroxypropyl distarch glycerol)、辛烯基丁二酸酯澱粉(Starch sodium octenyl succinate)及乙醯化氧化澱粉(Acetylated oxidized starch)等。In one embodiment of the present invention, the edible granules preferably do not contain starch and/or modified starch. The modified starch includes but not limited to dextrin (Dextrin), acid-treated starch (Acid-treated starch), alkaline-modified starch (Alkaline-treated starch), bleached starch (Bleached starch), oxidized starch (Oxidized starch) , Starches, enzyme-treated, Monostarch phosphate, Distarch phosphate, Phosphated distarch phosphate, Acetylated distarch phosphate , Starch acetate, Acetylated distarch adipate, Hydroxypropyl starch, Hydroxypropyl distarch phosphate, Hydroxypropyl distarch phosphate ( Hydroxypropyl distarch glycerol), octenyl succinate starch (Starch sodium octenyl succinate) and acetylated oxidized starch (Acetylated oxidized starch), etc.

於一實施例中,該食用顆粒尚可包含一或多種食品添加劑。本文所述之「食品添加劑」係指可保持、調整或增進該食用顆粒之顏色、氣味、口感或營養價值之可食用添加物,例如防腐劑、殺菌劑、抗氧化劑、營養添加劑、著色劑、香料、調味劑、甜味劑等。其較佳須符合食品添加物使用範圍及限量暨規格標準。舉例而言,本發明食用顆粒可包含以食用顆粒總重量計0.01%至10%之食品添加劑。例如該食品添加劑的含量可為0.1%至10%、1%至10%、3%至10%、5%至10%、0.01%至8%、0.01%至6%、0.1%至8%、或1%至5%。於一實施例中,該食用顆粒包含調味劑、甜味劑、香料、色素及植物纖維。In one embodiment, the edible particles may further contain one or more food additives. The "food additive" mentioned herein refers to edible additives that can maintain, adjust or enhance the color, smell, taste or nutritional value of the edible particles, such as preservatives, bactericides, antioxidants, nutritional additives, colorants, Spices, flavorings, sweeteners, etc. It is better to meet the scope of use of food additives and the limit and specification standards. For example, the edible granules of the present invention may contain 0.01% to 10% of food additives based on the total weight of the edible granules. For example, the content of the food additive can be 0.1% to 10%, 1% to 10%, 3% to 10%, 5% to 10%, 0.01% to 8%, 0.01% to 6%, 0.1% to 8%, or 1% to 5%. In one embodiment, the edible granules contain flavoring agents, sweeteners, spices, pigments and plant fibers.

本發明另提供一種食用顆粒的製造方法,其包含: (a)    混合海藻酸鈉、微生物多醣及水以形成一膠體溶液,其中該膠體溶液包含以該膠體溶液總重量計0.1%至5%之海藻酸鈉及0.5%至10%之微生物多醣,餘量為水;及 (b)    將該膠體溶液滴入一固化液中,並靜置一段充分的時間來使該膠質溶液在該固化液中形成該食用顆粒,其中該固化液包含0.1 M至5 M之二價金屬離子及水。 The present invention also provides a method for producing edible granules, which comprises: (a) mixing sodium alginate, microbial polysaccharides and water to form a colloidal solution, wherein the colloidal solution contains 0.1% to 5% of sodium alginate and 0.5% to 10% of microbial polysaccharides based on the total weight of the colloidal solution, and the remaining the quantity is water; and (b) dropping the colloidal solution into a solidifying solution, and standing for a sufficient period of time to allow the colloidal solution to form the edible particles in the solidifying solution, wherein the solidifying solution contains 0.1 M to 5 M of divalent metal ions and water.

於本發明一實施例中,係將秤量後之海藻酸鈉、微生物多醣加入水中,並均勻混合以形成該膠體溶液。此外,可加溫以幫助溶解,另可於該膠體溶液中選擇性地添加一或多種食品添加劑。該膠體溶液中海藻酸鈉之重量百分比為0.1%至5%,例如為0.5%至5%、1%至5%、2%至5%、3%至5%、0.5%至4%、0.5%至3%或1%至3%;該微生物多醣之重量百分比為0.5%至10%,例如為1%至10%、3%至10%、5%至10%、0.1%至8%、0.1%至6%或3%至7%。In one embodiment of the present invention, the weighed sodium alginate and microbial polysaccharides are added into water and uniformly mixed to form the colloidal solution. In addition, heating can be used to help dissolve, and one or more food additives can be selectively added to the colloidal solution. The weight percentage of sodium alginate in the colloid solution is 0.1% to 5%, such as 0.5% to 5%, 1% to 5%, 2% to 5%, 3% to 5%, 0.5% to 4%, 0.5% % to 3% or 1% to 3%; the weight percentage of the microbial polysaccharide is 0.5% to 10%, such as 1% to 10%, 3% to 10%, 5% to 10%, 0.1% to 8%, 0.1% to 6% or 3% to 7%.

於本發明中,海藻酸鈉係以上述比例與具有上述比例的微生物多醣混合後,於固化液中形成之食用顆粒大致呈圓球體(圖1a),且於殺菌後仍呈現圓球體狀(圖1b)。反之,若海藻酸鈉及微生物多醣以較低的比例範圍進行混合,則所形成之膠體溶液會過稀;若海藻酸鈉及微生物多醣以較高之比例進行混合,則所形成之膠體溶液會過稠,二者皆無法於固化液中形成食用顆粒。此外,若海藻酸鈉及微生物多醣中任一者之比例以不同於本發明之比例範圍進行混合,則所獲得之食用顆粒容易變形。舉例而言,若海藻酸鈉使用本發明之比例範圍(例如為2%),而微生物多醣使用較低之比例範圍(例如低於0.5%),所獲得之食用顆粒易形成長條狀,難以形成圓球體(圖2a);抑或,若微生物多醣之比例調整至高於10%,所獲得之食用顆粒則會呈扁平拖尾狀(圖2b)。In the present invention, after the sodium alginate is mixed with the microbial polysaccharide having the above ratio in the above ratio, the edible particles formed in the solidification liquid are roughly spherical (Figure 1a), and still present spherical shape after sterilization (Figure 1a). 1b). Conversely, if sodium alginate and microbial polysaccharides are mixed at a lower ratio, the formed colloidal solution will be too dilute; if sodium alginate and microbial polysaccharides are mixed at a higher ratio, the formed colloidal solution will be too thin. Too thick, neither of them can form edible particles in the solidified liquid. In addition, if the ratio of any one of sodium alginate and microbial polysaccharide is mixed in a ratio range different from that of the present invention, the obtained edible particles are easily deformed. For example, if sodium alginate is used in the ratio range of the present invention (for example, 2%), and microbial polysaccharides are used in a lower ratio range (for example, less than 0.5%), the obtained edible particles are likely to form long strips, which are difficult to obtain. Form spherical spheres (Figure 2a); or, if the proportion of microbial polysaccharides is adjusted to be higher than 10%, the obtained edible particles will be flat and trailing (Figure 2b).

於本發明中,二價金屬離子可為鈣離子、鋅離子及銅離子等,故固化液中之二價金屬離子可以包含該二價金屬離子之可溶性鹽類的形式提供。舉例而言,可使用前述二價金屬離子之氯化物來製備固化液。In the present invention, the divalent metal ions can be calcium ions, zinc ions and copper ions, etc., so the divalent metal ions in the solidification solution can be provided in the form of soluble salts containing the divalent metal ions. For example, the chloride of the aforementioned divalent metal ions can be used to prepare the solidified solution.

於一實施例中,係採正向滴定法,亦即將該膠體溶液滴入該固化液中,並靜置以形成該食用顆粒。舉例而言,可使用單軸擠出器將該膠體溶液滴入該固化液。同時,藉由調整滴入量,來調整所形成之食用顆粒的粒徑。於本發明中,該靜置時間可為約10分鐘至約60分鐘、約15分鐘至約20分鐘、約16分鐘至約26分鐘、約17分鐘至約27分鐘或約20分鐘至約30分鐘。In one embodiment, a forward titration method is adopted, that is, the colloid solution is dropped into the solidification solution and left to form the edible particles. For example, the colloid solution can be dropped into the solidification liquid using a single-screw extruder. At the same time, the particle size of the formed edible granules is adjusted by adjusting the drop amount. In the present invention, the standing time can be from about 10 minutes to about 60 minutes, from about 15 minutes to about 20 minutes, from about 16 minutes to about 26 minutes, from about 17 minutes to about 27 minutes or from about 20 minutes to about 30 minutes .

於食用顆粒在固化液中形成後,可將該食用顆粒自該固化液中分離出,例如過濾該固化液,以獲得該食用顆粒。該食用顆粒可直接用於食品或飲品中,惟較佳可經殺菌處理,例如高溫高壓蒸氣殺菌(即,使用殺菌釜)或超高溫殺菌。該食用顆粒可單獨進行殺菌,亦可先加入食品或飲品中,再進行殺菌。After the edible particles are formed in the solidified liquid, the edible particles can be separated from the solidified liquid, such as filtered, to obtain the edible particles. The edible particles can be directly used in food or drink, but preferably can be sterilized, such as high-temperature and high-pressure steam sterilization (ie, using a sterilizer) or ultra-high temperature sterilization. The edible granule can be sterilized independently, or can be added to food or drink first, and then sterilized.

本發明又提供一種食用顆粒,係由前述方法所製得。The present invention also provides an edible granule prepared by the aforementioned method.

本發明另提供一種食品,其包含本發明之食用顆粒。舉例而言,所述食品可為飲料、冰棒、雪糕、糖果與蛋糕甜點等,且所述飲料更可為動植物乳品、咖啡、可可、蜂蜜水、果汁、茶飲、氣泡水、碳酸飲料或含酒精性飲品等,本發明不加以限制。如前所述,由於本發明之食用顆粒耐熱與耐壓力之特性,可通過連續式熱充填、超高溫殺菌或殺菌釜等殺菌製程後,製成PP盒(罐)、軟袋、罐頭、寶特瓶、紙盒包、鋁箔包之食品(飲料)成品或半成品,且可於常溫下保存,可拆封即食。The present invention further provides a food comprising the edible granules of the present invention. For example, the food can be beverages, popsicles, ice cream, candy and cake desserts, etc., and the beverages can be animal and plant milk products, coffee, cocoa, honey water, fruit juice, tea, sparkling water, carbonated beverages or beverages containing Alcoholic beverages and the like are not limited in the present invention. As mentioned above, due to the heat-resistant and pressure-resistant characteristics of the edible granules of the present invention, they can be made into PP boxes (cans), soft bags, cans, treasures, etc. Food (beverage) finished or semi-finished products in special bottles, carton packs, and aluminum foil packs, which can be stored at room temperature and can be opened and eaten immediately.

以下實施例係出於說明目的而提供,而並不意欲限制本發明範圍。 實施例 1 The following examples are provided for illustrative purposes and are not intended to limit the scope of the invention. Embodiment 1 :

(1) 膠體溶液之製備,係將0.5%海藻膠和5%微生物多醣混合均勻後,加入溫水攪拌溶解,之後再將調味粉(巧克力粉)、植物纖維(麥纖維)等成分加到上述溶液中製備成膠體溶液。(1) The preparation of the colloidal solution is to mix 0.5% seaweed gel and 5% microbial polysaccharide evenly, add warm water and stir to dissolve, and then add seasoning powder (chocolate powder), plant fiber (wheat fiber) and other ingredients to the above Prepare a colloidal solution from the solution.

(2) 固化液之製備,將含鈣成分(氯化鈣)溶解於水中,其濃度為0.5M。(2) For the preparation of the solidification solution, dissolve the calcium-containing component (calcium chloride) in water to a concentration of 0.5M.

(3) 採用正向滴定法,以單軸擠出器將前述膠體溶液滴入前述固化液,並靜置30分鐘,以形成顆粒大小約5 mm至約7 mm之食用顆粒。(3) Using the forward titration method, drop the aforementioned colloidal solution into the aforementioned solidification solution with a uniaxial extruder, and let it stand for 30 minutes to form edible granules with a particle size of about 5 mm to about 7 mm.

(4) 將該食用顆粒與固化液分離,收集該食用顆粒(圖1a)。(4) The edible particles are separated from the solidification liquid, and the edible particles are collected (Figure 1a).

(5) 將該食用顆粒單獨進行高溫高壓蒸氣殺菌(殺菌釜)121℃商業殺菌,獲得可即食食用顆粒(圖1b)。(5) The edible granules were commercially sterilized at 121°C by high-temperature and high-pressure steam sterilization (sterilizer) separately to obtain ready-to-eat granules (Figure 1b).

(6) 將前述經高溫高壓蒸氣殺菌之食用顆粒添加至相關飲品(奶茶)進行UHT商業殺菌,即可獲得一種含有該食用顆粒之飲品(珍珠奶茶)。 比較例 1 4 (6) Add the aforementioned edible granules sterilized by high-temperature and high-pressure steam to related drinks (milk tea) for UHT commercial sterilization, and a drink (bubble milk tea) containing the edible granules can be obtained. Comparative Examples 1 to 4 :

(1) 比較例1:以樹薯澱粉搓圓成團,經熱水煮熟(圖3a),而後進行121℃商業殺菌(圖3b),顆粒無法粒粒分明,也無法再添加至飲品進行UHT商業殺菌。(1) Comparative Example 1: Tapioca starch was used to form balls, boiled in hot water (Figure 3a), and then commercially sterilized at 121°C (Figure 3b). commercial sterilization.

(2) 比較例2:市售愛之味珍珠圓,以海藻酸鈉和修飾澱粉混製而成食用顆粒(圖4a)。經121℃商業殺菌後(圖4b),顆粒明顯吸水澎潤成原本的2倍,無法再添加至飲品進行UHT商業殺菌。(2) Comparative example 2: The commercially available Aizhiwei pearl balls are edible granules made of sodium alginate and modified starch (Figure 4a). After being commercially sterilized at 121°C (Figure 4b), the particles obviously absorbed water and became twice as moist as before, and could no longer be added to beverages for UHT commercial sterilization.

(3) 比較例3:市售承恩爆爆珠(芒果口味),係以反向滴定法將含鈣成分液體滴入膠體溶液中產生顆粒(圖5a),而後進行121℃商業殺菌(圖5b),殺菌後顆粒破裂,無法再添加至飲品進行UHT商業殺菌。(3) Comparative example 3: Commercially available Chengen popping pearls (mango flavor), the calcium-containing liquid was dropped into the colloidal solution by reverse titration to produce particles (Figure 5a), and then commercially sterilized at 121 °C (Figure 5a) 5b), the particles are broken after sterilization, and can no longer be added to beverages for UHT commercial sterilization.

(4) 比較例4:與本發明食用顆粒之製程相同,配方差異僅在於未添加微生物多醣及色料(圖6a),經121℃商業殺菌後顆粒明顯變小(圖6b)。(4) Comparative Example 4: The same manufacturing process as the edible granules of the present invention, the only difference in formula is that microbial polysaccharides and colorants are not added (Figure 6a), and the granules become significantly smaller after commercial sterilization at 121°C (Figure 6b).

比較實施例1與比較例1至4於121℃商業殺菌前後硬度變化,如下表1所示。如前所述,硬度數值變化最能表現出食用顆粒的質地結構變化,亦即當殺菌破壞程度愈大,其硬度下降程度越大。比較例1至4於殺菌後,硬度皆大幅下降。反之,實施例1之食用顆粒能通過商業殺菌測試且其硬度變化逐步遞增,顯示本發明中所使用之組成比例可使所獲得的食用顆粒在殺菌過程中更穩固其質地結構,而使硬度增加。 表一:實施例1與比較例1至4於121℃殺菌前後硬度變化 硬度 實施例1 比較例1 比較例2 比較例3 比較例4 殺菌前 2792.1 6291.5 2595.5 574.63 1152.9 殺菌後 3264.2 1029.3 769.3 破裂 556.6 The changes in hardness of Example 1 and Comparative Examples 1 to 4 before and after commercial sterilization at 121°C are shown in Table 1 below. As mentioned above, the change in hardness value can best reflect the change in the texture and structure of edible particles, that is, the greater the degree of sterilization damage, the greater the degree of decrease in hardness. In Comparative Examples 1 to 4, the hardness decreased significantly after sterilization. On the contrary, the edible granule of Example 1 can pass the commercial sterilization test and its hardness change gradually increases, showing that the composition ratio used in the present invention can make the obtained edible granule more stable in its texture and structure during the sterilization process, so that the hardness increases . Table 1: Changes in hardness of Example 1 and Comparative Examples 1 to 4 before and after sterilization at 121°C hardness Example 1 Comparative example 1 Comparative example 2 Comparative example 3 Comparative example 4 Before sterilization 2792.1 6291.5 2595.5 574.63 1152.9 After sterilization 3264.2 1029.3 769.3 rupture 556.6

另進行本案實施例1與比較例4於121℃殺菌後實施例1與比較例4之口感分析,如下表2所示。比較例4於殺菌後硬度下降,而實施例1之硬度上升,代表添加微生物多醣能有效提升殺菌耐受性及維持顆粒原有外觀。此外,相較於未添加微生物多醣之比較例4,實施例1之食用顆粒的脆裂感較低,而具有較佳的Q彈口感(脆度下降4.2%,彈性上升14.1%)。亦即,添加微生物多醣能改善海藻膠晶球原有的脆裂感,並增加顆粒的Q彈感。 表2:實施例1與比較例4於121℃殺菌後之口感分析 殺菌釜 硬度(g) 彈性(%) 脆度(%) 實施例1 3264.2 55.9 30.2 比較例4 556.6 41.8 34.4 In addition, the mouthfeel analysis of Example 1 and Comparative Example 4 after sterilization at 121° C. was carried out, as shown in Table 2 below. The hardness of Comparative Example 4 decreased after sterilization, while the hardness of Example 1 increased, indicating that the addition of microbial polysaccharides can effectively improve the sterilization tolerance and maintain the original appearance of the particles. In addition, compared with Comparative Example 4 in which no microbial polysaccharides were added, the edible granules of Example 1 had a lower brittleness and better Q-bomb texture (crispness decreased by 4.2%, and elasticity increased by 14.1%). That is to say, the addition of microbial polysaccharides can improve the original brittleness of alginate crystal balls and increase the Q-elasticity of the particles. Table 2: Mouthfeel analysis of Example 1 and Comparative Example 4 after sterilization at 121°C Retort Hardness (g) elasticity(%) Brittleness (%) Example 1 3264.2 55.9 30.2 Comparative example 4 556.6 41.8 34.4

進一步分析實施例1之食用顆粒經UHT商業殺菌後之口感,如下表3所示。本案之食用顆粒經135℃ UHT殺菌後,其彈性更增加19.7%,且脆度下降,顯示其具有更接近澱粉製粉圓(珍珠)的Q彈口感。此外,其硬度進一步上升,顯示本案之食用顆粒在殺菌過程中更穩固其質地結構。 表3:實施例1經135±2℃,40秒UHT商業殺菌後之口感分析 UHT殺菌 硬度(g) 彈性(%) 脆度(%) 殺菌前 3264.2 55.9 30.2 殺菌後 3330.6 75.6 28.4 The mouthfeel of the edible granules of Example 1 after UHT commercial sterilization was further analyzed, as shown in Table 3 below. After the edible granules in this case were sterilized by UHT at 135°C, their elasticity increased by 19.7%, and their brittleness decreased, indicating that they had a Q-bomb texture closer to starch-based flour balls (pearls). In addition, its hardness further increased, showing that the edible particles in this case have a more stable texture and structure during the sterilization process. Table 3: Mouthfeel analysis of Example 1 after UHT commercial sterilization at 135±2°C for 40 seconds UHT sterilization Hardness (g) elasticity(%) Brittleness (%) Before sterilization 3264.2 55.9 30.2 After sterilization 3330.6 75.6 28.4

上述實施例僅為說明本發明之原理及其功效,而非限制本發明。習於此技術之人士對上述實施例所做之修改及變化仍不違背本發明之精神。本發明之權利範圍應如後述之申請專利範圍所列。The above-mentioned embodiments are only to illustrate the principles and effects of the present invention, but not to limit the present invention. Modifications and changes made by those skilled in the art to the above embodiments still do not violate the spirit of the present invention. The scope of rights of the present invention should be listed in the scope of patent application described later.

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圖1a及1b分別顯示實施例1之食用顆粒於殺菌前及殺菌後之型態。Figures 1a and 1b show the shapes of the edible granules of Example 1 before and after sterilization, respectively.

圖2a顯示微生物多醣比例過低導致食用顆粒呈長條狀;圖2b顯示微生物多醣比例過高導致食用顆粒呈扁平拖尾狀。Figure 2a shows that the proportion of microbial polysaccharides is too low and the edible particles are long strips; Figure 2b shows that the proportion of microbial polysaccharides is too high and the edible particles are flat and trailing.

圖3a及3b分別顯示比較例1之食用顆粒於殺菌前、殺菌後之型態。Figures 3a and 3b show the shapes of the edible granules of Comparative Example 1 before and after sterilization, respectively.

圖4a及4b分別顯示比較例2之食用顆粒於殺菌前及殺菌後之型態。Figures 4a and 4b show the shapes of the edible particles of Comparative Example 2 before and after sterilization, respectively.

圖5a及5b分別顯示比較例3之食用顆粒於殺菌前及殺菌後之型態。Figures 5a and 5b show the shapes of the edible particles of Comparative Example 3 before and after sterilization, respectively.

圖6a及6b分別顯示比較例4之食用顆粒於殺菌前及殺菌後之型態。Figures 6a and 6b show the shapes of the edible particles of Comparative Example 4 before and after sterilization, respectively.

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Claims (18)

一種食用顆粒,其包含以總重量計0.1%至5%之海藻酸鹽及0.5%至10%之微生物多醣,餘量為水。An edible granule, which contains 0.1% to 5% of alginate and 0.5% to 10% of microbial polysaccharide by total weight, and the balance is water. 如請求項1之食用顆粒,其中該海藻酸鹽係選自海藻酸鈉、海藻酸銨、海藻酸鉀、海藻酸鈣、海藻酸鋅、海藻酸銅及其任意組合所組成之群。The edible granule according to claim 1, wherein the alginate is selected from the group consisting of sodium alginate, ammonium alginate, potassium alginate, calcium alginate, zinc alginate, copper alginate and any combination thereof. 如請求項1之食用顆粒,其中該微生物多醣係選自由玉米糖膠、卡德蘭膠、結蘭膠及其任意組合所組成之群。The edible granules as claimed in item 1, wherein the microbial polysaccharide is selected from the group consisting of corn sugar gum, cardlan gum, gellan gum and any combination thereof. 如請求項1之食用顆粒,其進一步包含一或多種食品添加劑。The edible granule according to claim 1, further comprising one or more food additives. 如請求項1之食用顆粒,其不包含澱粉及/或修飾澱粉。The edible granule according to claim 1, which does not contain starch and/or modified starch. 如請求項1之食用顆粒,其係為均質顆粒。As the edible granule of claim 1, it is a homogeneous granule. 如請求項1至6中任一項之食用顆粒,其中該食用顆粒之彈性係為50%以上。The edible granule according to any one of claims 1 to 6, wherein the elasticity of the edible granule is more than 50%. 如請求項1至6中任一項之食用顆粒,其中該食用顆粒之脆度係為33%以下。The edible granule according to any one of claims 1 to 6, wherein the brittleness of the edible granule is 33% or less. 如請求項1至6中任一項之食用顆粒,其中該食用顆粒經殺菌處理後之硬度為該食用顆粒經殺菌處理前之硬度的50%以上。The edible granule according to any one of claims 1 to 6, wherein the hardness of the edible granule after sterilization is more than 50% of the hardness of the edible granule before sterilization. 一種食用顆粒的製造方法,其包含: (a)    混合海藻酸鈉、微生物多醣及水以形成一膠體溶液,其中該膠體溶液包含以該膠體溶液總重量計0.1%至5%之海藻酸鈉及0.5%至10%之微生物多醣,餘量為水;及 (b)    將該膠體溶液滴入一固化液中,並靜置一段充分的時間來使該膠質溶液在該固化液中形成該食用顆粒,其中該固化液包含0.1 M至5 M之二價金屬離子及水。 A method for producing edible granules, comprising: (a) mixing sodium alginate, microbial polysaccharides and water to form a colloidal solution, wherein the colloidal solution contains 0.1% to 5% of sodium alginate and 0.5% to 10% of microbial polysaccharides based on the total weight of the colloidal solution, and the remaining the quantity is water; and (b) dropping the colloidal solution into a solidifying solution, and standing for a sufficient period of time to allow the colloidal solution to form the edible particles in the solidifying solution, wherein the solidifying solution contains 0.1 M to 5 M of divalent metal ions and water. 如請求項10之方法,其中於步驟(a)中,進一步添加一或多種食品添加劑。The method according to claim 10, wherein in step (a), one or more food additives are further added. 如請求項10之方法,其中於步驟(b)中,該靜置時間為約10分鐘至約60分鐘。The method according to claim 10, wherein in step (b), the standing time is about 10 minutes to about 60 minutes. 如請求項10之方法,其中於步驟(b)中,該二價金屬離子係為鈣離子、鋅離子或銅離子。The method according to claim 10, wherein in step (b), the divalent metal ion is calcium ion, zinc ion or copper ion. 如請求項10至13中任一項之方法,其進一步包含: (c)    將該固化液與該食用顆粒分離。 The method according to any one of claims 10 to 13, further comprising: (c) separating the solidified liquid from the edible particles. 如請求項14之方法,其進一步包含: (d)    對該食用顆粒進行殺菌處理。 The method of claim 14, further comprising: (d) Sterilize the edible particles. 如請求項15之方法,其中該殺菌處理係為高溫高壓蒸氣殺菌或超高溫殺菌。The method according to claim 15, wherein the sterilization treatment is high-temperature and high-pressure steam sterilization or ultra-high temperature sterilization. 一種食用顆粒,其係由如請求項10至16中任一項之方法所製得。An edible granule, which is prepared by the method according to any one of claims 10-16. 一種食品,其包含如請求項1或17之食用顆粒。A food comprising the edible granules according to claim 1 or 17.
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