TW202237366A - Mold used for induction heating and compound formula material - Google Patents

Mold used for induction heating and compound formula material Download PDF

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TW202237366A
TW202237366A TW110110153A TW110110153A TW202237366A TW 202237366 A TW202237366 A TW 202237366A TW 110110153 A TW110110153 A TW 110110153A TW 110110153 A TW110110153 A TW 110110153A TW 202237366 A TW202237366 A TW 202237366A
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mold
induction heating
magnetic particle
magnetic
particles
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TW110110153A
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TWI768780B (en
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徐敏懷
楊申語
蔡曜陽
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國立臺灣大學
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  • Moulds For Moulding Plastics Or The Like (AREA)
  • General Induction Heating (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)

Abstract

A mold used for induction heating, a hot embossing method, and a compound formula material are provided. At least a surface of the mold forms a microstructure, and the mold is formed by a compound formula material. The compound formula material includes: a soft matrix material and a magnetic particle material mixed in the soft matrix material. The magnetic particle material is configured to assist in raising a shore hardness of the mold after baking, and the magnetic particle material is configured as an internal heat source of the mold to receive an induction heating frequency during a hot embossing process, thereby assisting in raising a mold temperature of the mold.

Description

可用於感應加熱的模具、熱壓印方法及複合配方材料Molds, hot embossing methods and composite formulations that can be used for induction heating

本發明涉及一種模具,特別是涉及一種可用於感應加熱的模具、利用該模具的熱壓印方法及形成該模具的複合配方材料。The invention relates to a mould, in particular to a mould, which can be used for induction heating, a hot embossing method utilizing the mould, and a composite formula material forming the mould.

相較於一般的硬式模具,軟性模具,諸如:PDMS模具、PFPE模具,具備形變能力,並且模具固化後具有可撓性。再者,軟性模具具有複製性優異、脫模容易、翻鑄時間短、可有效降低成本…等優點。因此,軟性模具的應用越來越受到重視。Compared with general hard molds, soft molds, such as PDMS molds and PFPE molds, have the ability to deform, and the molds are flexible after curing. Furthermore, flexible molds have the advantages of excellent reproducibility, easy demoulding, short casting time, and can effectively reduce costs...etc. Therefore, the application of flexible molds has attracted more and more attention.

高週波感應加熱技術具有加熱快速的優勢,其解決了傳統製程中升溫速率較慢的問題等。然而,現有軟性模具若要作為高週波感應加熱用模具,其主要面臨三項挑戰:1. 軟性模具的剛度及硬度低;2. 軟性模具的熱阻高且熱傳導效率差;以及3. 軟性模具無法直接感應加熱。High-frequency induction heating technology has the advantage of fast heating, which solves the problem of slow heating rate in traditional manufacturing processes. However, if the existing flexible mold is to be used as a mold for high-frequency induction heating, it mainly faces three challenges: 1. The rigidity and hardness of the flexible mold are low; 2. The thermal resistance of the flexible mold is high and the heat conduction efficiency is poor; and 3. The flexible mold Cannot be heated directly by induction.

本發明人有感於上述缺失之可以改善,乃特潛心研究並配合學理之運用,終於提出一種設計合理且有效改善上述缺失之本發明。The inventor of the present invention feels that the above defects can be improved, so he devoted himself to research and combined with the application of theories, and finally proposed an invention with reasonable design and effective improvement of the above defects.

本發明所要解決的技術問題在於,針對現有技術的不足提供一種可用於感應加熱的模具、熱壓印方法及複合配方材料。The technical problem to be solved by the present invention is to provide a mold that can be used for induction heating, a hot embossing method and a composite formula material in view of the deficiencies in the prior art.

為了解決上述的技術問題,本發明所採用的其中一技術方案是,提供一種可用於感應加熱的模具,其具有位於相反側的兩個表面,並且至少其中一個所述表面形成有一微結構,其特徵在於,所述模具是通過一複合配方材料所形成,所述複合配方材料包括有:一軟性基質材料;以及一磁性粒子材料,其混合於所述軟性基質材料之中;其中,所述磁性粒子材料經配置輔助地提升所述模具的一蕭氏硬度,並且所述磁性粒子材料經配置做為所述模具的一內部熱源,以於一熱壓印製程中、接收一感應加熱頻率、進而輔助地提升所述模具的一模具溫度。In order to solve the above technical problems, one of the technical solutions adopted by the present invention is to provide a mold that can be used for induction heating, which has two surfaces on opposite sides, and at least one of the surfaces is formed with a microstructure, which It is characterized in that the mold is formed by a composite formula material, and the composite formula material includes: a soft matrix material; and a magnetic particle material, which is mixed in the soft matrix material; wherein, the magnetic The particulate material is configured to assist in increasing a Shore hardness of the mold, and the magnetic particulate material is configured to act as an internal heat source for the mold to receive an induction heating frequency during a hot embossing process, thereby A mold temperature of the mold is auxiliary raised.

為了解決上述的技術問題,本發明所採用的另外一技術方案是,提供一種熱壓印方法,其包括:將一模具置放於一載台上;其中,所述模具的至少其中一個表面形成有一微結構,並且所述模具是通過一複合配方材料所形成,其包含一軟性基質材料及一磁性粒子材料;將一壓印板材置放於所述模具上、且使所述壓印板材貼合於所述模具的所述微結構;對所述模具施加一感應加熱頻率,以使得所述磁性粒子材料接收所述感應加熱頻率、進而輔助提升所述模具的一模具溫度,並且使得所述壓印板材能被所述模具溫度軟化;及利用一壓力單元對所述壓印板材施加一縱向壓力,以使得所述壓印板材局部地陷入所述模具的所述微結構,並且使所述壓印板材的表面形成有與所述模具的所述微結構在幾何形狀上互補的一轉印結構。In order to solve the above technical problems, another technical solution adopted by the present invention is to provide a hot embossing method, which includes: placing a mold on a stage; wherein at least one of the surfaces of the mold is formed There is a microstructure, and the mold is formed by a composite formula material, which includes a soft matrix material and a magnetic particle material; placing an embossing plate on the mold, and making the embossing plate stick Adapt to the microstructure of the mold; apply an induction heating frequency to the mold, so that the magnetic particle material receives the induction heating frequency, thereby assisting in raising a mold temperature of the mold, and making the the embossed sheet can be softened by the mold temperature; and applying a longitudinal pressure to the embossed sheet with a pressure unit so that the embossed sheet partially sinks into the microstructure of the mold and causes the The surface of the embossed sheet is formed with a transfer structure geometrically complementary to the microstructure of the mold.

為了解決上述的技術問題,本發明所採用的另外一技術方案是,提供一種複合配方材料,其適用於製作一模具,且所述複合配方材料包括:一軟性基質材料及混合於所述軟性基質材料中的一磁性粒子材料,所述磁性粒子材料經配置使得所述複合配方材料,先烘烤1小時再烘烤48小時後,具有不小於80 HD的一蕭氏硬度,並且所述磁性粒子材料經配置能於接收一感應加熱頻率後、產生一集膚效應。In order to solve the above-mentioned technical problems, another technical solution adopted by the present invention is to provide a composite formula material, which is suitable for making a mould, and the composite formula material includes: a soft matrix material and mixed in the soft matrix A magnetic particle material in the material, the magnetic particle material is configured so that the composite formula material has a Shore hardness not less than 80 HD after baking for 1 hour and then baking for 48 hours, and the magnetic particle The material is configured to generate a skin effect after receiving an induction heating frequency.

本發明的其中一有益效果在於,本發明所提供的可用於感應加熱的模具、熱壓印方法及複合配方材料,其能通過“在形成模具的軟性基質材料中混合具有特定規格的磁性粒子材料”,以使得所述模具能具有較高的硬度及較高的熱傳導效率、並且所述模具可以通過直接感應加熱的方式、而產生內部熱源,從而適用於高週波感應加熱。One of the beneficial effects of the present invention is that the mold, hot embossing method, and composite formula material that can be used for induction heating provided by the present invention can be obtained by "mixing magnetic particle materials with specific specifications in the soft matrix material forming the mould." ", so that the mold can have higher hardness and higher heat conduction efficiency, and the mold can generate an internal heat source through direct induction heating, which is suitable for high-frequency induction heating.

為使能更進一步瞭解本發明的特徵及技術內容,請參閱以下有關本發明的詳細說明與圖式,然而所提供的圖式僅用於提供參考與說明,並非用來對本發明加以限制。In order to further understand the features and technical content of the present invention, please refer to the following detailed description and drawings related to the present invention. However, the provided drawings are only for reference and description, and are not intended to limit the present invention.

以下是通過特定的具體實施例來說明本發明所公開的實施方式,本領域技術人員可由本說明書所公開的內容瞭解本發明的優點與效果。本發明可通過其他不同的具體實施例加以施行或應用,本說明書中的各項細節也可基於不同觀點與應用,在不悖離本發明的構思下進行各種修改與變更。另外,本發明的附圖僅為簡單示意說明,並非依實際尺寸的描繪,事先聲明。以下的實施方式將進一步詳細說明本發明的相關技術內容,但所公開的內容並非用以限制本發明的保護範圍。The following is an illustration of the disclosed embodiments of the present invention through specific specific examples, and those skilled in the art can understand the advantages and effects of the present invention from the content disclosed in this specification. The present invention can be implemented or applied through other different specific embodiments, and various modifications and changes can be made to the details in this specification based on different viewpoints and applications without departing from the concept of the present invention. In addition, the drawings of the present invention are only for simple illustration, and are not drawn according to the actual size, which is stated in advance. The following embodiments will further describe the relevant technical content of the present invention in detail, but the disclosed content is not intended to limit the protection scope of the present invention.

應當可以理解的是,雖然本文中可能會使用到“第一”、“第二”、“第三”等術語來描述各種元件或者信號,但這些元件或者信號不應受這些術語的限制。這些術語主要是用以區分一元件與另一元件,或者一信號與另一信號。另外,本文中所使用的術語“或”,應視實際情況可能包括相關聯的列出項目中的任一個或者多個的組合。It should be understood that although terms such as "first", "second", and "third" may be used herein to describe various elements or signals, these elements or signals should not be limited by these terms. These terms are mainly used to distinguish one element from another element, or one signal from another signal. In addition, the term "or" used herein may include any one or a combination of more of the associated listed items depending on the actual situation.

[可用於感應加熱的模具][Molds that can be used for induction heating]

請參閱圖1及圖2所示,本發明實施例提供一種模具M,其可用於感應加熱,特別是可用於高週波感應加熱(high-frequency induction heating)。Please refer to FIG. 1 and FIG. 2 , the embodiment of the present invention provides a mold M, which can be used for induction heating, especially for high-frequency induction heating (high-frequency induction heating).

所述模具M具有位於相反側的兩個表面101及102,至少其中一個所述表面101形成有一微結構M1,並且所述微結構M1可於一熱壓印製程中、對一壓印板材(如:PMMA)進行壓印,以使得所述壓印板材的表面形成有與微結構M1在形狀上互補的一轉印結構(如:凹透鏡結構或凸透鏡結構)。The mold M has two surfaces 101 and 102 on opposite sides, at least one of the surfaces 101 is formed with a microstructure M1, and the microstructure M1 can be used for an embossed plate ( Such as: PMMA) is embossed, so that a transfer structure (such as: a concave lens structure or a convex lens structure) complementary in shape to the microstructure M1 is formed on the surface of the embossed sheet.

在本發明的一實施例中,所述模具M的厚度可以例如是介於0.5公釐(mm)至5公釐之間,舉例而言,所述模具M的厚度為1.5公釐。再者,所述微結構M1可以例如是凹陷的微結構及凸出的微結構的至少其中之一。In an embodiment of the present invention, the thickness of the mold M may be, for example, between 0.5 millimeters (mm) to 5 millimeters, for example, the thickness of the mold M is 1.5 millimeters. Furthermore, the microstructure M1 may be, for example, at least one of a concave microstructure and a protruding microstructure.

其中,所述微結構M1的一縱向高度可以例如是介於5微米至10微米之間,並且所述微結構M1的一橫向寬度可以例如是介於40微米至60微米之間,但本發明不受限於此。Wherein, a longitudinal height of the microstructure M1 may be, for example, between 5 microns and 10 microns, and a lateral width of the microstructure M1 may, for example, be between 40 microns and 60 microns, but the present invention Not limited to this.

進一步地說,如圖2所示,所述模具M是通過一複合配方材料C所形成。所述複合配方材料C包含:一軟性基質材料C1(soft matrix material)及混合於軟性基質材料C1中的一磁性粒子材料C2(magnetic particle material)。Furthermore, as shown in FIG. 2 , the mold M is formed by a composite material C. The composite formulation material C includes: a soft matrix material C1 (soft matrix material) and a magnetic particle material C2 (magnetic particle material) mixed in the soft matrix material C1.

在材料種類方面,所述軟性基質材料C1可以例如是有機矽高分子材料、有機矽高分子材料的衍生物(derivative)、及有機矽高分子材料的共聚物(copolymer)的至少其中之一。In terms of material types, the soft matrix material C1 may be, for example, at least one of organosilicon polymer materials, derivatives of organosilicon polymer materials, and copolymers of organosilicon polymer materials.

需說明的是,本文中所提及的術語“有機矽高分子材料的衍生物”是指有機矽高分子材料經過官能基修飾或化學改質的材料。再者,本文中所提及的術語“有機矽高分子材料的共聚物”是指有機矽高分子材料與其它種類單體進行共聚合反應所形成的材料。It should be noted that the term "derivatives of organosilicon polymer materials" mentioned herein refers to materials in which organosilicon polymer materials have been modified with functional groups or chemically modified. Furthermore, the term "copolymer of organosilicon polymer material" mentioned in this article refers to the material formed by the copolymerization reaction of organosilicon polymer material and other types of monomers.

在本實施例中,所述有機矽高分子材料為聚二甲基矽氧烷(polydimethylsiloxane,PDMS),但本發明不受限於此。舉例來說,所述軟性基質材料C1也可以例如是全氟聚醚(perfluoropolyethers,PFPE)等適合用於製作軟性模具的材料。In this embodiment, the organosilicon polymer material is polydimethylsiloxane (PDMS), but the invention is not limited thereto. For example, the soft matrix material C1 may also be, for example, perfluoropolyethers (perfluoropolyethers, PFPE) and other materials suitable for making soft molds.

所述磁性粒子材料C2混合於軟性基質材料C1中,能輔助改善所述軟性基質材料C1的物理性質(如:硬度)。更具體地說,所述磁性粒子材料C2經配置輔助地提升模具M的一蕭氏硬度(shore-A-hardness)。The magnetic particle material C2 is mixed in the soft matrix material C1, which can assist in improving the physical properties (such as hardness) of the soft matrix material C1. More specifically, the magnetic particle material C2 is configured to assist in increasing the shore-A-hardness of the mold M.

再者,所述磁性粒子材料C2經配置做為模具M的一內部熱源,以於一熱壓印製程(hot embossing process)中、接收一感應加熱頻率(induction heating frequency)、進而輔助地提升所述模具的一模具溫度。Moreover, the magnetic particle material C2 is configured as an internal heat source of the mold M to receive an induction heating frequency during a hot embossing process, thereby assisting in enhancing the A mold temperature of the mould.

在材料種類方面,所述磁性粒子材料是選自由鐵粒子(iron particles)、鈷粒子(cobalt particles)、鎳粒子(nickel particles)、鐵-鈷合金粒子(Fe-Co alloy particles)、鐵-鎳合金粒子(Fe-Ni alloy particles)、鎳-鈷合金粒子(Ni-Co alloy particles)、鐵-鈷-鎳合金粒子(Fe-Co-Ni alloy particles)、及其衍生物,所組成的材料群組的至少其中之一。In terms of material types, the magnetic particle material is selected from iron particles, cobalt particles, nickel particles, iron-cobalt alloy particles (Fe-Co alloy particles), iron-nickel particles Material group consisting of Fe-Ni alloy particles, Ni-Co alloy particles, Fe-Co-Ni alloy particles, and their derivatives At least one of the groups.

進一步地說,本發明實施例所提供的磁性粒子材料C2具有特定的規格,以使得所述磁性粒子材料C2混合於軟性基質材料C1中,能提供所述模具M具有較高的硬度及較高的熱傳導效率、並且提供所述模具可以通過直接感應加熱的方式被加熱。Furthermore, the magnetic particle material C2 provided by the embodiment of the present invention has specific specifications, so that the magnetic particle material C2 is mixed in the soft matrix material C1, which can provide the mold M with higher hardness and higher The heat conduction efficiency is high, and the mold can be heated by direct induction heating.

請繼續參閱圖2所示,所述磁性粒子材料C2包含有彼此混合的複數個第一磁性粒子C21及複數個第二磁性粒子C22。其中,所述第一磁性粒子C21具有一第一平均粒徑。所述第一磁性粒子C21經配置於一熱壓印製程中、接收一感應加熱頻率。其中,所述感應加熱頻率對應於一集膚深度(skin depth,δ),並且所述第一磁性粒子C21的第一平均粒徑大於所述集膚深度。Please continue to refer to FIG. 2 , the magnetic particle material C2 includes a plurality of first magnetic particles C21 and a plurality of second magnetic particles C22 mixed with each other. Wherein, the first magnetic particles C21 have a first average particle size. The first magnetic particles C21 are configured in a thermal embossing process to receive an induction heating frequency. Wherein, the induction heating frequency corresponds to a skin depth (skin depth, δ), and the first average particle diameter of the first magnetic particles C21 is larger than the skin depth.

在本發明的多個實施例中,所述第一磁性粒子C21的第一平均粒徑為所述集膚深度的至少2倍以上、優選為4倍以上、且特優選為8倍以上,但本發明不受限於此。In many embodiments of the present invention, the first average particle size of the first magnetic particles C21 is at least 2 times or more, preferably 4 times or more, and particularly preferably 8 times or more, the skin depth, but The present invention is not limited thereto.

在本發明的多個實施例中,所述感應加熱頻率可以例如是介於1千赫茲(kHz)至2,000千赫茲之間,並且所述感應加熱頻率對應的所述集膚深度可以例如是介於5微米至80微米之間、且優選是介於10微米至80微米。In various embodiments of the present invention, the induction heating frequency may be, for example, between 1 kilohertz (kHz) and 2,000 kHz, and the skin depth corresponding to the induction heating frequency may be, for example, between between 5 microns and 80 microns, and preferably between 10 microns and 80 microns.

在本發明的多個實施例中,所述感應加熱頻率可以例如是介於30千赫茲至80千赫茲,並且所述集膚深度可以例如是介於15微米至80微米。再者,所述第一磁性粒子C21的第一平均粒徑可以例如是不小於10微米、且優選不小於30微米。特優選地,所述第一磁性粒子C21的第一平均粒徑為所述集膚深度的4倍以上、且不小於120微米。舉例而言,所述第一磁性粒子C21的第一平均粒徑可以例如是介於200微米至400微米之間,但本發明不受限於此。In various embodiments of the present invention, the induction heating frequency may be, for example, between 30 kHz and 80 kHz, and the skin depth may be, for example, between 15 microns and 80 microns. Furthermore, the first average particle diameter of the first magnetic particles C21 may be, for example, not less than 10 microns, and preferably not less than 30 microns. Particularly preferably, the first average particle diameter of the first magnetic particles C21 is more than 4 times the skin depth and not less than 120 microns. For example, the first average particle size of the first magnetic particles C21 may be, for example, between 200 microns and 400 microns, but the present invention is not limited thereto.

根據上述配置,所述第一磁性粒子C21能做為模具M的內部熱源(internal heat source),並且所述模具符合以下條件:當所述第一磁性粒子C21接收感應加熱頻率時,所述第一磁性粒子C21產生一集膚效應(skin effect),並且所述第一磁性粒子C21能使得模具M的一模具溫度由介於15 oC至30 oC的一常溫提升至介於100 oC至250 oC的一高溫,能在90秒內完成、且優選能在60秒內完成,但本發明不受限於此。也就是說,所述第一磁性粒子C21做為內部熱源,能使得模具M由常溫升溫至適合熱壓印的溫度在短的時間內完成。 According to the above configuration, the first magnetic particle C21 can be used as an internal heat source of the mold M, and the mold meets the following condition: when the first magnetic particle C21 receives induction heating frequency, the first magnetic particle C21 A magnetic particle C21 produces a skin effect (skin effect), and the first magnetic particle C21 can make a mold temperature of the mold M rise from a normal temperature between 15 ° C to 30 ° C to between 100 ° C to A high temperature of 250 o C can be completed within 90 seconds, and preferably within 60 seconds, but the present invention is not limited thereto. That is to say, the first magnetic particles C21 are used as an internal heat source, which can make the temperature of the mold M rise from normal temperature to a temperature suitable for hot embossing in a short time.

值得一提的是,在本實施例中,所述第一磁性粒子C21接收的感應加熱頻率是通過一高週波感應加熱設備(high-frequency induction heating apparatus)所產生的。也就是說,所述第一磁性粒子C21為高週波感應的熱源。It is worth mentioning that, in this embodiment, the induction heating frequency received by the first magnetic particles C21 is generated by a high-frequency induction heating apparatus. That is to say, the first magnetic particle C21 is a high-frequency induction heat source.

另外,值得一提的是,所述第一磁性粒子C21的第一平均粒徑必須限定大於所述集膚深度,其才可以達到高週波的感應加熱效率。若所述模具M中的磁性粒子的粒徑皆小於所述集膚深度,則高週波的感應加熱效率將會變得不佳,從而無法有效地通過感應加熱的方式提升模具的內部溫度。In addition, it is worth mentioning that the first average particle size of the first magnetic particles C21 must be limited to be larger than the skin depth, so as to achieve high-frequency induction heating efficiency. If the particle diameters of the magnetic particles in the mold M are all smaller than the skin depth, the high-frequency induction heating efficiency will become poor, so that the internal temperature of the mold cannot be effectively raised by induction heating.

本申請發明人經由實驗發現,PDMS模具中若只有加入3.5微米或粒徑更小的鎳粒子(用以提升軟性模具的硬度),則高週波的感應加熱效率不佳。80千赫茲的感應加熱頻率相對於鎳於常溫的集膚深度約為48微米。因此,模具中必需再加入第二種粒徑較大的磁性粒子,例如:200微米至400微米的鐵粒子或鎳-鈷合金粒子等。該磁性粒子的粒徑需遠大於鐵、鈷、鎳對應80千赫茲的集膚深度,藉此感應加熱效率才會有顯著的提升。The inventors of the present application have found through experiments that if only nickel particles with a particle size of 3.5 microns or smaller are added to the PDMS mold (to increase the hardness of the soft mold), the efficiency of high-frequency induction heating is not good. The induction heating frequency of 80 kHz is about 48 microns to the skin depth of nickel at room temperature. Therefore, it is necessary to add a second type of magnetic particles with a larger particle size into the mold, for example, iron particles or nickel-cobalt alloy particles with a size of 200 microns to 400 microns. The particle size of the magnetic particles needs to be much larger than the skin depth corresponding to 80 kHz of iron, cobalt, and nickel, so that the induction heating efficiency can be significantly improved.

本申請發明人另外經由實驗發現,加入粒徑200微米至400微米的鎳(75%)-鈷(25%)合金於PDMS模具中,其內部熱源感應加熱速率更快,60秒內即可由常溫升溫至220℃。反之,若模具中只有加入3.5微米的鎳粒子,則模具在相同的加熱條件下,於60秒內最高僅能升溫到82℃。The inventors of the present application have also found through experiments that adding a nickel (75%)-cobalt (25%) alloy with a particle size of 200 microns to 400 microns in the PDMS mold has a faster induction heating rate of the internal heat source, and can be heated from normal temperature within 60 seconds. The temperature was raised to 220°C. Conversely, if only nickel particles of 3.5 microns are added to the mold, the mold can only be heated up to 82° C. within 60 seconds under the same heating conditions.

進一步地說,請繼續參閱圖2所示,所述磁性粒子材料C2的第二磁性粒子C22具有一第二平均粒徑,並且所述第二磁性粒子C22的第二平均粒徑小於所述第一平均粒徑。在本發明的多個實施例中,所述第二磁性粒子C22的第二平均粒徑不大於10微米、且優選不大於5微米。Further, please continue to refer to FIG. 2, the second magnetic particle C22 of the magnetic particle material C2 has a second average particle size, and the second average particle size of the second magnetic particle C22 is smaller than the first an average particle size. In various embodiments of the present invention, the second average particle size of the second magnetic particles C22 is not greater than 10 microns, and preferably not greater than 5 microns.

所述第二磁性粒子C22相對於第一磁性粒子C21具有較小的平均粒徑。所述第二磁性粒子C22添加至模具M中,是用以提升所述模具M的硬度。更具體地說,所述第二磁性粒子C22用以輔助提升模具M的一蕭氏硬度(shore-A-hardness),並且使得所述模具M的蕭氏硬度優選是不小於38 HD、且不大於100 HD。其中,所述蕭氏硬度是通過一蕭氏硬度計的測量而得到。The second magnetic particles C22 have a smaller average particle diameter than the first magnetic particles C21. The second magnetic particles C22 are added to the mold M to increase the hardness of the mold M. More specifically, the second magnetic particles C22 are used to assist in increasing the Shore hardness (shore-A-hardness) of the mold M, and make the Shore hardness of the mold M preferably not less than 38 HD and not Greater than 100 HD. Wherein, the Shore hardness is obtained through the measurement of a Shore hardness tester.

在含量範圍方面,基於所述複合配方材料C為100重量百分濃度,所述軟性基質材料C1的含量範圍是介於5重量百分濃度至50重量百分濃度之間,並且所述磁性粒子材料C2(包含第一磁性粒子C21及第二磁性粒子C22)的含量範圍是介於50重量百分濃度至95重量百分濃度之間。其中,所述第一磁性粒子C21的含量範圍是介於20重量百分濃度至70重量百分濃度之間,並且所述第二磁性粒子C22的含量範圍是介於20重量百分濃度至70重量百分濃度之間。也就是說,所述磁性粒子材料C2的含量範圍優選是大於軟性基質材料C1的含量範圍,但本發明不受限於此。In terms of content range, based on 100% by weight of the composite formulation material C, the content range of the soft matrix material C1 is between 5% by weight and 50% by weight, and the magnetic particles The content range of the material C2 (including the first magnetic particle C21 and the second magnetic particle C22 ) is between 50% by weight and 95% by weight. Wherein, the content range of the first magnetic particle C21 is between 20 weight percent concentration and 70 weight percent concentration, and the content range of the second magnetic particle C22 is between 20 weight percent concentration and 70 weight percent concentration. between weight percent concentrations. That is to say, the content range of the magnetic particle material C2 is preferably greater than the content range of the soft matrix material C1, but the present invention is not limited thereto.

在本發明的多個實施例中,所述第二磁性粒子C22可以例如是粒徑介於2微米至4微米且鐵純度為99%以上的超細鐵粉、或粒徑介於3.5微米至4微米且鎳純度為99.8%以上的超細鎳粉、或粒徑為0.3微米且鎳純度為99%以上的的超細鎳粉,上述材料能作為提升軟性模具的硬度、剛度、及熱傳導效率的媒介。In various embodiments of the present invention, the second magnetic particles C22 can be, for example, ultrafine iron powder with a particle size ranging from 2 microns to 4 microns and an iron purity of more than 99%, or a particle size ranging from 3.5 microns to Ultrafine nickel powder with 4 microns and a nickel purity of 99.8% or more, or ultrafine nickel powder with a particle size of 0.3 microns and a nickel purity of 99% or more. The above materials can be used to improve the hardness, rigidity, and heat transfer efficiency of flexible molds medium.

整體而言,本發明實施例提供了軟性模具具有內部熱源、而能直接被感應加熱,其突破了傳統軟性模具(如:PDMS模具)本身無法自體發熱的限制。由於PDMS屬於絕緣體,高週波無法直接感應加熱,本發明實施例於PDMS內部加入磁性金屬粉末,以使高週波可以直接感應產生內部熱源,加熱PDMS模具本體,並減少外部熱源傳導之熱耗損及提升加熱效率。磁性金屬粉末也間接大幅提升PDMS之耐壓印硬度,以利後續大面積移動式滾輪感應加熱壓印的應用。Overall, the embodiments of the present invention provide a flexible mold with an internal heat source that can be directly heated by induction, which breaks through the limitation that traditional flexible molds (such as PDMS molds) cannot generate heat by themselves. Since PDMS is an insulator, high-frequency waves cannot be directly induced to heat. In the embodiment of the present invention, magnetic metal powder is added inside PDMS, so that high-frequency waves can directly induce internal heat sources, heat the PDMS mold body, and reduce heat loss and increase in external heat source conduction. Heating efficiency. The magnetic metal powder also indirectly greatly improves the embossing hardness of PDMS, which is convenient for the subsequent application of large-area mobile roller induction heating embossing.

值得一提的是,一般PDMS均採用AB劑10:1配方混合,但因PDMS屬於軟模,蕭氏A硬度量測只有38HD,不適合於大面積滾輪熱壓印。在本發明的多個實施例中,必須提高AB劑的配方比例至4~6:1,並於固化後再加上至少24小時以上之硬化烘烤,以提升PDMS本質硬度至60HD。也可以再添加鐵、鎳、鈷等磁性金屬材料於PDMS中,更進一步提升其硬度及熱傳導係數,以利較大面積之移動式滾輪熱壓印。It is worth mentioning that generally PDMS is mixed with AB agent 10:1, but because PDMS is a soft mold, the Shaw A hardness measurement is only 38HD, which is not suitable for large-area roller heat embossing. In many embodiments of the present invention, it is necessary to increase the formula ratio of AB agent to 4~6:1, and add hardening and baking for at least 24 hours after curing to increase the intrinsic hardness of PDMS to 60HD. It is also possible to add magnetic metal materials such as iron, nickel, and cobalt to PDMS to further increase its hardness and thermal conductivity, so as to facilitate thermal embossing of larger-area mobile rollers.

需說明的是,本文中所提及的術語“感應加熱”是利用電磁感應來加熱金屬,加熱時線圈周圍和導體內部會產生高頻電磁場。交變電流產生一個通過工件的時變磁場,該磁場由於集膚效應而激發導體內部的渦電流,並且集中在導體表面並產生焦耳熱。It should be noted that the term "induction heating" mentioned in this article refers to the use of electromagnetic induction to heat metal, and high-frequency electromagnetic fields will be generated around the coil and inside the conductor during heating. The alternating current produces a time-varying magnetic field passing through the workpiece, which excites eddy currents inside the conductor due to the skin effect, and concentrates on the surface of the conductor to generate Joule heat.

需說明的是,本文中所提及的術語“集膚效應” 是導體內部電流分布不均勻的一種現象,導體中的交流電流將電流集中在表面上並增加電流密度,從而減小了從表面到內部的密度分佈。集膚深度δ(m)是從表面到內部區域的距離,其中渦電流密度呈指數遞減可從100%降低到36.8%之深度,稱之為集膚深度。It should be noted that the term "skin effect" mentioned in this article is a phenomenon in which the current distribution inside the conductor is uneven. The alternating current in the conductor concentrates the current on the surface and increases the current density, thereby reducing the current from the surface to the internal density distribution. The skin depth δ (m) is the distance from the surface to the inner region, where the eddy current density decreases exponentially from 100% to 36.8%, which is called the skin depth.

集膚效應避免渦電流通過實心導體的中心,從而使其僅限於導體表面附近傳導。這將有效地限制了電子流經導體橫截面積,從而使該導體的電阻增加到比直流電更大的電阻,促使流經導體表面的高電阻的渦電流將電能轉化為熱能的焦耳效應(I 2R)。 The skin effect prevents eddy currents from passing through the center of a solid conductor, thereby confining it to conduction near the surface of the conductor. This will effectively limit the flow of electrons through the cross-sectional area of the conductor, thereby increasing the resistance of the conductor to a resistance greater than direct current, prompting the Joule effect (I 2 R).

[模具的製備方法][Mold preparation method]

請參閱圖7所示,本發明實施例的模具M可以例如是利用以下方式所製備得到,但本發明不受限於此。Referring to FIG. 7 , the mold M of the embodiment of the present invention can be prepared, for example, in the following manner, but the present invention is not limited thereto.

其中,PDMS的AB劑是選用道康寧公司Sylgard 184型號的PDMS,由於其黏滯係數低易於流動,適合精密微結構翻鑄。Among them, the AB agent of PDMS is the PDMS of Sylgard 184 type from Dow Corning Company. Because of its low viscosity coefficient and easy flow, it is suitable for precise microstructure casting.

所述模具M的翻模步驟依序包含步驟S1至步驟S7。步驟S1為將PDMS的AB劑及磁性粒子材料混合以形成複合配方材料C。步驟S2為對該複合配方材料C進行攪拌。步驟S3為對該複合配方材料C進行除氣。步驟S4為對該複合配方材料C進行澆鑄。步驟S5為對該複合配方材料C進行1小時85℃的固化烘烤。步驟S6為對該複合配方材料C進行脫模,以形成PDMS模具M。最後,步驟S7為對該模具M再經24至72小時85℃的硬化烘烤,從而提升該模具的硬度。The mold turning step of the mold M includes step S1 to step S7 in sequence. Step S1 is to mix the AB agent of PDMS and the magnetic particle material to form a composite formula material C. Step S2 is to stir the composite formula material C. Step S3 is to degas the composite formulation material C. Step S4 is casting the composite formula material C. Step S5 is curing and baking the composite formula material C at 85° C. for 1 hour. Step S6 is to demould the composite formula material C to form a PDMS mold M. Finally, in step S7, the mold M is hardened and baked at 85° C. for 24 to 72 hours, so as to increase the hardness of the mold.

[模具的熱壓印方法][Hot embossing method for molds]

請參閱圖3所示,本發明實施例另提供一種熱壓印方法,其包括步驟S110至步驟S140。所述熱壓印方法是利用上述實施例所提供的模具對壓印板材進行熱壓印。Please refer to FIG. 3 , an embodiment of the present invention further provides a thermal embossing method, which includes steps S110 to S140 . The hot embossing method is to use the mold provided in the above embodiment to hot emboss the embossed plate.

所述步驟S110包含:將一模具M置放於一載台P1上。其中,所述模具M的至少其中一個表面形成有一微結構M1。再者,所述模具M是通過如上述實施例的複合配方材料C所形成,並且所述複合配方材料C包含彼此混合的一軟性基質材料C1及一磁性粒子材料C2。The step S110 includes: placing a mold M on a stage P1. Wherein, at least one surface of the mold M is formed with a microstructure M1. Furthermore, the mold M is formed by the composite formula material C as in the above embodiment, and the composite formula material C includes a soft matrix material C1 and a magnetic particle material C2 mixed with each other.

所述步驟S120包含:將一壓印板材P2置放於所述模具M上,並且使所述壓印板材P2貼合於模具M表面上的微結構M1。其中,所述壓印板材P2可以例如是聚甲基丙烯酸甲酯板材(也就是,PMMA板材),但本發明不受限於此。The step S120 includes: placing an embossing plate P2 on the mold M, and attaching the embossing plate P2 to the microstructure M1 on the surface of the mold M. Wherein, the embossed sheet P2 may be, for example, a polymethyl methacrylate sheet (that is, a PMMA sheet), but the present invention is not limited thereto.

所述步驟S130包含:對所述模具M施加一感應加熱頻率(induction heating frequency),以使得所述磁性粒子材料C2接收所述感應加熱頻率、進而輔助提升所述模具M的一模具溫度,並且使得所述壓印板材P2被所述模具溫度加熱而軟化。The step S130 includes: applying an induction heating frequency to the mold M, so that the magnetic particle material C2 receives the induction heating frequency, thereby assisting in raising a mold temperature of the mold M, and The embossed sheet material P2 is heated and softened by the mold temperature.

所述步驟S140包含:利用一壓力單元P3對所述壓印板材P2施加一縱向壓力,以使所述壓印板材P2局部地陷入所述模具M的微結構中(圖未繪示),並且使所述壓印板材P2的表面形成有與所述微結構M1在幾何形狀上互補一轉印結構(圖未繪示)。The step S140 includes: using a pressure unit P3 to apply a longitudinal pressure to the embossed sheet P2, so that the embossed sheet P2 is partially trapped in the microstructure of the mold M (not shown in the figure), and A transfer structure (not shown) that is geometrically complementary to the microstructure M1 is formed on the surface of the embossed plate P2.

在本發明的一實施例中,所述磁性粒子材料C2所接收的感應加熱頻率是通過一高週波感應加熱設備(high-frequency induction heating apparatus)所產生的。In an embodiment of the present invention, the induction heating frequency received by the magnetic particle material C2 is generated by a high-frequency induction heating apparatus.

在本發明的一實施例中,所述壓力單元P3為一壓印滾輪,並且所述壓印板材P2表面所形成的所述轉印結構為凹陷的轉印結構(如:凹透鏡結構)及凸出的轉印結構(如:凸透鏡結構)的至少其中之一。In an embodiment of the present invention, the pressure unit P3 is an embossing roller, and the transfer structure formed on the surface of the embossed plate P2 is a concave transfer structure (such as a concave lens structure) and a convex At least one of the transfer structures (such as: convex lens structure).

在本發明的一實施例中,所述熱壓印方法進一步包括:將一緩衝軟墊P4置放於所述壓力單元P3與壓印板材P2間,以分散施加於所述壓印板材P2上的縱向壓力。其中,所述緩衝軟墊P4的一蕭氏硬度(shore-A-hardness)小於所述模具M的一蕭氏硬度,並且所述緩衝軟墊P4的蕭氏硬度不大於10 HD、優選不大於6 HD、且特優選不大於4 HD。舉例而言,所述緩衝軟墊P4可以例如是一耐高溫的發泡矽膠軟墊。In an embodiment of the present invention, the hot embossing method further includes: placing a cushioning pad P4 between the pressure unit P3 and the embossing plate P2, so as to spread and apply it on the embossing plate P2 the vertical pressure. Wherein, the Shore hardness (shore-A-hardness) of the buffer pad P4 is less than the Shore hardness of the mold M, and the Shore hardness of the buffer pad P4 is not greater than 10 HD, preferably not greater than 6 HD, and particularly preferably no more than 4 HD. For example, the cushioning pad P4 may be, for example, a high temperature resistant foamed silicone pad.

在本發明的一實施例中,如圖4所示,所述模具M的兩個表面皆形成有所述微結構M1,以使得所述熱壓印方法能於所述模具M的兩個表面上皆設置所述壓印板材P2,並且使得位於兩個所述表面上的所述壓印板材P2皆在施加所述縱向壓力後,分別局部地陷入所述模具M的兩個表面上的所述微結構中,從而完成轉印作業。值得一提的是,所述模具M的兩個表面上的所述微結構可以分別設計為相同或不同的微結構,例如:一表面設計凹陷的微結構,而另一表面設計凸出的微結構,本發明不予以限制。In one embodiment of the present invention, as shown in FIG. 4, the microstructure M1 is formed on both surfaces of the mold M, so that the hot embossing method can be applied on both surfaces of the mold M. The embossed sheet material P2 is arranged on the upper surface, and the embossed sheet material P2 located on the two surfaces is respectively partially sunk into all the two surfaces of the mold M after the longitudinal pressure is applied. In the above microstructure, the transfer printing operation is completed. It is worth mentioning that the microstructures on the two surfaces of the mold M can be respectively designed as the same or different microstructures, for example: a concave microstructure is designed on one surface, and a convex microstructure is designed on the other surface. structure, the present invention is not limited.

在本發明的一實施例中,如圖5所示,所述模具M的數量也可以例如是兩個以上,並且每個所述模具M的兩個表面上皆設置所述壓印板材P2,其實現四重堆疊壓印或多重堆疊壓印,從而提升生產的效率。In an embodiment of the present invention, as shown in FIG. 5 , the number of molds M may also be more than two, and the embossed sheet P2 is arranged on both surfaces of each mold M, It realizes quadruple stacked embossing or multi-stacked embossing, thereby improving production efficiency.

在本發明的一實施例中,如圖6所述,所述磁性粒子材料C2也可以例如加入一壓印滾輪P3內部之PDMS,且在所述壓印滾輪P3的表面上形成微結構M1。In an embodiment of the present invention, as shown in FIG. 6 , the magnetic particle material C2 can also be added to PDMS inside an embossing roller P3 , and form a microstructure M1 on the surface of the embossing roller P3 .

值得一提的是,本發明實施例所提供的軟性模具M相較於現有的硬式模具(如:鎳模具)具有較佳的形變能力。當所述壓印滾輪P3施加縱向壓力於軟性模具M上時,所述軟性模具M可以輕微形變,以使微結構M1凹陷中的氣體可以排出。再者,所述緩衝軟墊P4為耐高溫的發泡矽膠軟墊,其可以輕易地壓入凹陷中,從而有助於氣體的排出。It is worth mentioning that the soft mold M provided by the embodiment of the present invention has better deformability than the existing hard mold (such as nickel mold). When the embossing roller P3 exerts longitudinal pressure on the flexible mold M, the flexible mold M can be slightly deformed, so that the gas in the depression of the microstructure M1 can be discharged. Furthermore, the cushioning pad P4 is a heat-resistant foamed silicone pad, which can be easily pressed into the depression, thereby facilitating the discharge of gas.

在本發明的一實施例中,所述複合配方材料進一步包括:混合於所述軟性基質材料中的一金屬粒子材料或一非金屬粒子材料,並且所述複合配方材料的所述蕭氏硬度,能通過調整烘烤時間及調控所有粒子材料的濃度範圍,而進行調整。In an embodiment of the present invention, the composite formula material further includes: a metal particle material or a non-metal particle material mixed in the soft matrix material, and the Shore hardness of the composite formula material, Adjustments can be made by adjusting the baking time and controlling the concentration range of all particle materials.

在本發明的一實施例中,所述複合配方材料中的所述磁性粒子材料的分層分佈及局部濃度變化,能被調控,以形成一感應加熱目標區域,進而調控所述模具的局部轉印效果的高低差異。In an embodiment of the present invention, the layered distribution and local concentration change of the magnetic particle material in the composite formula material can be adjusted to form an induction heating target area, thereby adjusting the local rotation of the mold. The difference in the printing effect.

在本發明的一實施例中,所述複合配方材料進一步包括:混合於所述軟性基質材料中的一金屬粒子材料,並且所述複合配方材料的導電性及溫度分佈均勻性,能通過所述金屬粒子材料被調控。In an embodiment of the present invention, the composite formula material further includes: a metal particle material mixed in the soft matrix material, and the electrical conductivity and temperature distribution uniformity of the composite formula material can be passed through the The metal particle material is regulated.

[實施例的有益效果][Advantageous Effects of Embodiment]

本發明的其中一有益效果在於,本發明實施例所提供的可用於感應加熱的模具、熱壓印方法及複合配方材料,其能通過“在形成模具的軟性基質材料中混合具有特定規格的磁性粒子材料”,以使得所述模具能具有較高的硬度及較高的熱傳導效率、並且所述模具可以通過直接感應加熱的方式、而產生內部熱源,從而適用於高週波感應加熱。One of the beneficial effects of the present invention is that the molds, hot embossing methods and composite formula materials that can be used for induction heating provided by the embodiments of the present invention can be obtained by "mixing magnetic materials with specific specifications in the soft matrix material forming the mould." Particle material", so that the mold can have higher hardness and higher heat conduction efficiency, and the mold can generate an internal heat source through direct induction heating, which is suitable for high-frequency induction heating.

以上所公開的內容僅為本發明的優選可行實施例,並非因此侷限本發明的申請專利範圍,所以凡是運用本發明說明書及圖式內容所做的等效技術變化,均包含於本發明的申請專利範圍內。The content disclosed above is only a preferred feasible embodiment of the present invention, and does not therefore limit the scope of the patent application of the present invention. Therefore, all equivalent technical changes made by using the description and drawings of the present invention are included in the application of the present invention. within the scope of the patent.

M:模具 101、102:表面 M1:微結構 C:複合配方材料 C1:軟性基質材料 C2:磁性粒子材料 C21:第一磁性粒子 C22:第二磁性粒子 P1:載台 P2:壓印板材 P3:壓力單元 P4:緩衝軟墊 M: Mold 101, 102: surface M1: Microstructure C: Composite formula material C1: soft matrix material C2: Magnetic Particle Materials C21: The first magnetic particle C22: second magnetic particle P1: stage P2: Embossed sheet P3: Pressure unit P4: Buffer cushion

圖1為本發明實施例可用於感應加熱的模具的示意圖。FIG. 1 is a schematic diagram of a mold that can be used for induction heating according to an embodiment of the present invention.

圖2為圖1區域II的局部放大示意圖。FIG. 2 is a partially enlarged schematic diagram of area II in FIG. 1 .

圖3為本發明實施例熱壓印方法的示意圖。FIG. 3 is a schematic diagram of a thermal embossing method according to an embodiment of the present invention.

圖4為圖3熱壓印方法的變化態樣示意圖(一)。FIG. 4 is a schematic diagram (1) of the variation of the hot embossing method in FIG. 3 .

圖5為圖3熱壓印方法的變化態樣示意圖(二)。FIG. 5 is a schematic diagram (2) of the variation of the hot embossing method in FIG. 3 .

圖6為模具呈滾輪形狀的示意圖。Figure 6 is a schematic view of the mold in the shape of a roller.

圖7為模具的製造方法流程圖。Fig. 7 is a flow chart of the manufacturing method of the mould.

M:模具 M: Mold

M1:微結構 M1: Microstructure

P1:載台 P1: stage

P2:壓印板材 P2: Embossed sheet

P3:壓力單元 P3: Pressure unit

P4:緩衝軟墊 P4: Buffer cushion

Claims (18)

一種可用於感應加熱的模具,其具有位於相反側的兩個表面,並且至少其中一個所述表面形成有一微結構,其特徵在於,所述模具是通過一複合配方材料所形成,所述複合配方材料包括有: 一軟性基質材料;以及 一磁性粒子材料,其混合於所述軟性基質材料之中;其中,所述磁性粒子材料經配置輔助提升所述模具的一蕭氏硬度,並且所述磁性粒子材料經配置做為所述模具的一內部熱源,以於一熱壓印製程中、接收一感應加熱頻率、進而輔助地提升所述模具的一模具溫度。 A mold that can be used for induction heating has two surfaces on opposite sides, and at least one of the surfaces is formed with a microstructure, it is characterized in that the mold is formed by a compound formula material, and the compound formula Materials include: a soft matrix material; and A magnetic particle material, which is mixed in the soft matrix material; wherein, the magnetic particle material is configured to assist in raising a Shore hardness of the mold, and the magnetic particle material is configured as the mold An internal heat source is used to receive an induction heating frequency during a hot embossing process, thereby assisting in increasing a mold temperature of the mold. 如請求項1所述的可用於感應加熱的模具,其中,所述軟性基質材料為一有機矽高分子材料、其衍生物、及其共聚物的至少其中之一。The mold for induction heating according to claim 1, wherein the soft matrix material is at least one of an organosilicon polymer material, its derivatives, and its copolymers. 如請求項1所述的可用於感應加熱的模具,其中,所述磁性粒子材料是選自由鐵粒子、鈷粒子、鎳粒子、鐵-鈷合金粒子、鐵-鎳合金粒子、鎳-鈷合金粒子、鐵-鈷-鎳合金粒子、及其衍生物,所組成的材料群組的至少其中之一。The mold that can be used for induction heating as described in claim 1, wherein the magnetic particle material is selected from iron particles, cobalt particles, nickel particles, iron-cobalt alloy particles, iron-nickel alloy particles, nickel-cobalt alloy particles , iron-cobalt-nickel alloy particles, and derivatives thereof, at least one of the material group consisting of. 如請求項1所述的可用於感應加熱的模具,其中,所述磁性粒子材料包含有:複數個第一磁性粒子,並且所述第一磁性粒子具有一第一平均粒徑;其中,所述第一磁性粒子經配置於所述熱壓印製程中、接收所述感應加熱頻率,所述感應加熱頻率對應於一集膚深度(skin depth),並且所述第一磁性粒子的所述第一平均粒徑大於所述集膚深度。The mold that can be used for induction heating according to claim 1, wherein the magnetic particle material includes: a plurality of first magnetic particles, and the first magnetic particles have a first average particle size; wherein, the The first magnetic particle is configured in the thermal embossing process, receives the induction heating frequency, the induction heating frequency corresponds to a skin depth, and the first magnetic particle of the first magnetic particle The average particle size is larger than the skin depth. 如請求項4所述的可用於感應加熱的模具,其中,所述第一磁性粒子為所述模具的所述內部熱源;並且,所述模具符合以下條件:當所述第一磁性粒子接收所述感應加熱頻率時,所述第一磁性粒子產生一集膚效應、且使得所述模具的所述模具溫度由介於15 oC至30 oC的一常溫提升至介於100 oC至250 oC一的高溫,能在90秒內完成。 The mold that can be used for induction heating according to claim 4, wherein the first magnetic particles are the internal heat source of the mold; and the mold meets the following conditions: when the first magnetic particles receive the When the frequency of the induction heating is increased, the first magnetic particles produce a skin effect, and the mold temperature of the mold is increased from a normal temperature between 15 ° C to 30 ° C to a temperature between 100 ° C to 250 ° C The high temperature of C-1 can be completed within 90 seconds. 如請求項4所述的可用於感應加熱的模具,其中,所述磁性粒子材料進一步包含有:複數個第二磁性粒子,所述第二磁性粒子具有一第二平均粒徑,並且所述第二磁性粒子的所述第二平均粒徑小於所述第一平均粒徑、且不大於10微米。The mold that can be used for induction heating according to claim 4, wherein the magnetic particle material further includes: a plurality of second magnetic particles, the second magnetic particles have a second average particle size, and the first The second average particle diameter of the two magnetic particles is smaller than the first average particle diameter and not greater than 10 microns. 如請求項6所述的可用於感應加熱的模具,其中,所述第二磁性粒子輔助地提升所述模具的所述蕭氏硬度,並且所述模具的所述蕭氏硬度不小於38HD、且不大於100 HD。The mold that can be used for induction heating as claimed in claim 6, wherein the second magnetic particles assist in increasing the Shore hardness of the mold, and the Shore hardness of the mold is not less than 38HD, and No more than 100 HD. 如請求項6所述的可用於感應加熱的模具,其中,基於所述複合配方材料為100重量百分濃度,所述軟性基質材料的一含量範圍是介於5重量百分濃度至50重量百分濃度之間,並且所述磁性粒子材料的一含量範圍是介於50重量百分濃度至95重量百分濃度之間。The mold that can be used for induction heating as described in claim 6, wherein, based on the 100% by weight concentration of the composite formula material, a content range of the soft matrix material is between 5% by weight and 50% by weight Concentrations, and a content range of the magnetic particle material is between 50% by weight and 95% by weight. 一種熱壓印方法,其包括: 將一模具置放於一載台上;其中,所述模具的至少其中一個表面形成有一微結構,並且所述模具是通過一複合配方材料所形成,其包含一軟性基質材料及一磁性粒子材料; 將一壓印板材置放於所述模具上、且使所述壓印板材貼合於所述模具的所述微結構; 對所述模具施加一感應加熱頻率,以使得所述磁性粒子材料接收所述感應加熱頻率、進而輔助提升所述模具的一模具溫度,並且使得所述壓印板材被所述模具溫度軟化;以及 利用一壓力單元對所述壓印板材施加一縱向壓力,以使所述壓印板材局部地陷入所述模具的所述微結構,並且使所述壓印板材的表面形成有一轉印結構。 A method of hot embossing, comprising: A mold is placed on a stage; wherein at least one surface of the mold is formed with a microstructure, and the mold is formed by a composite formula material, which includes a soft matrix material and a magnetic particle material ; placing an embossed sheet on the mold, and attaching the embossed sheet to the microstructure of the mold; applying an induction heating frequency to the mold, such that the magnetic particle material receives the induction heating frequency, thereby assisting in raising a mold temperature of the mold, and causing the embossed sheet to be softened by the mold temperature; and A pressure unit is used to apply a longitudinal pressure to the embossed plate, so that the embossed plate is partially trapped in the microstructure of the mold, and a transfer structure is formed on the surface of the embossed plate. 如請求項9所述的熱壓印方法,其中,所述磁性粒子材料所接收的所述感應加熱頻率是通過一高週波感應加熱設備(high-frequency induction heating apparatus)所產生的。The thermal embossing method as claimed in claim 9, wherein the induction heating frequency received by the magnetic particle material is generated by a high-frequency induction heating apparatus. 如請求項9所述的熱壓印方法,其中,所述壓力單元為壓印滾輪,並且所述壓印板材的所述表面形成的所述轉印結構為凹陷的轉印結構及凸出的轉印結構的至少其中之一。The thermal embossing method according to claim 9, wherein the pressure unit is an embossing roller, and the transfer structure formed on the surface of the embossed sheet is a concave transfer structure and a protruding one. At least one of the transfer structures. 如請求項9所述的熱壓印方法,其中,當所述壓力單元對所述壓印板材施加所述縱向壓力時,所述壓力單元能使所述模具產生輕微形變,以使得存在於所述模具的所述微結構之凹陷中的氣體排出。The hot embossing method according to claim 9, wherein when the pressure unit applies the longitudinal pressure to the embossed sheet, the pressure unit can slightly deform the mold so that the The gas in the depressions of the microstructure of the mold is exhausted. 如請求項9所述的熱壓印方法,進一步包括:將一緩衝軟墊置放於所述壓力單元與所述壓印板材間,以分散施加於所述壓印板材上的所述縱向壓力;其中,所述緩衝軟墊的一蕭氏硬度小於所述模具的一蕭氏硬度,並且所述緩衝軟墊的所述蕭氏硬度不大於10 HD。The thermal embossing method according to claim 9, further comprising: placing a cushion cushion between the pressure unit and the embossing plate to distribute the longitudinal pressure applied to the embossing plate ; Wherein, a Shore hardness of the cushion cushion is less than a Shore hardness of the mold, and the Shore hardness of the cushion cushion is not greater than 10 HD. 如請求項9所述的熱壓印方法,其中,所述模具的兩個所述表面皆形成有所述微結構,以使得所述熱壓印方法能於所述模具的兩個所述表面上皆設置所述壓印板材,並且使得位於兩個所述表面上的所述壓印板材皆在施加所述縱向壓力後,分別局部地陷入所述模具的兩個所述表面上的所述微結構。The thermal embossing method according to claim 9, wherein the microstructures are formed on both the surfaces of the mold, so that the thermal embossing method can be applied on both the surfaces of the mold The embossed sheets are arranged on the upper surface, and the embossed sheets located on both the surfaces are respectively partially sunk into the said embossed sheets on the two surfaces of the mould, after the longitudinal pressure is applied. microstructure. 一種複合配方材料,其適用於製作一模具,且所述複合配方材料包括:一軟性基質材料及混合於所述軟性基質材料中的一磁性粒子材料,所述磁性粒子材料經配置使得所述複合配方材料具有不小於38HD的一蕭氏硬度,並且所述磁性粒子材料經配置於接收一感應加熱頻率後、產生一集膚效應。A composite formulation material, which is suitable for making a mold, and the composite formulation material includes: a soft matrix material and a magnetic particle material mixed in the soft matrix material, the magnetic particle material is configured so that the composite The formulation material has a Shore hardness not less than 38HD, and the magnetic particle material is configured to generate a skin effect after receiving an induction heating frequency. 如請求項15所述的複合配方材料,其進一步包括:混合於所述軟性基質材料中的一金屬粒子材料或一非金屬粒子材料,並且所述複合配方材料的所述蕭氏硬度,能通過調整烘烤時間及調控所有粒子材料的濃度範圍,而進行調整。The composite formula material as claimed in claim 15, which further includes: a metal particle material or a non-metal particle material mixed in the soft matrix material, and the Shore hardness of the composite formula material can be passed Adjustments are made by adjusting the baking time and adjusting the concentration range of all particle materials. 如請求項15所述的複合配方材料,其中,所述複合配方材料中的所述磁性粒子材料的分層分佈及局部濃度變化,能被調控,以形成一感應加熱目標區域,進而調控所述模具的局部轉印效果的高低差異。The composite formula material according to claim 15, wherein, the layered distribution and local concentration change of the magnetic particle material in the composite formula material can be adjusted to form an induction heating target area, and then regulate the The difference in the local transfer effect of the mold. 如請求項15所述的複合配方材料,其進一步包括:混合於所述軟性基質材料中的一金屬粒子材料,並且所述複合配方材料的導電性及溫度分佈均勻性,能通過所述金屬粒子材料被調控。The composite formula material as claimed in claim 15, which further includes: a metal particle material mixed in the soft matrix material, and the conductivity and temperature distribution uniformity of the composite formula material can pass through the metal particle Material is regulated.
TW110110153A 2021-03-22 2021-03-22 Mold used for induction heating and compound formula material TWI768780B (en)

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