TW202220206A - semiconductor device - Google Patents
semiconductor device Download PDFInfo
- Publication number
- TW202220206A TW202220206A TW110137652A TW110137652A TW202220206A TW 202220206 A TW202220206 A TW 202220206A TW 110137652 A TW110137652 A TW 110137652A TW 110137652 A TW110137652 A TW 110137652A TW 202220206 A TW202220206 A TW 202220206A
- Authority
- TW
- Taiwan
- Prior art keywords
- semiconductor device
- crystalline oxide
- oxide semiconductor
- semiconductor layer
- heat dissipation
- Prior art date
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- 239000004065 semiconductor Substances 0.000 title claims abstract description 297
- 230000017525 heat dissipation Effects 0.000 claims abstract description 79
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- 239000002184 metal Substances 0.000 claims description 49
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Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/20—Deposition of semiconductor materials on a substrate, e.g. epitaxial growth solid phase epitaxy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/02—Semiconductor bodies ; Multistep manufacturing processes therefor
- H01L29/12—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/66007—Multistep manufacturing processes
- H01L29/66075—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
- H01L29/66227—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
- H01L29/66409—Unipolar field-effect transistors
- H01L29/66477—Unipolar field-effect transistors with an insulated gate, i.e. MISFET
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
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Abstract
Description
本發明係關於包含結晶性氧化物半導體層的半導體裝置。The present invention relates to a semiconductor device including a crystalline oxide semiconductor layer.
作為可實現高耐壓、低損失及高耐熱的次世代結晶性氧化物半導體材料,使用大能隙之氧化鎵(Ga 2O 3)的半導體裝置受到矚目。包含結晶性氧化物半導體的半導體裝置,作為開關元件而被期待應用於反向器等電力用半導體裝置。又,因為寬能隙而亦被期待應用作為LED或感測器等的受發光裝置。 As a next-generation crystalline oxide semiconductor material capable of achieving high withstand voltage, low loss, and high heat resistance, semiconductor devices using gallium oxide (Ga 2 O 3 ) with a large energy gap have been attracting attention. A semiconductor device including a crystalline oxide semiconductor is expected to be applied to a power semiconductor device such as an inverter as a switching element. Also, due to its wide energy gap, it is expected to be used as a light receiving and light receiving device such as an LED or a sensor.
已知氧化鎵中存在α、β、γ、δ、ε的5種結晶結構(非專利文獻1)。其中,具有剛玉結構的氧化鎵其能隙高,作為適用於次世代功率元件傾向的半導體材料而受到矚目。然而仍具有下述的課題:氧化鎵中,最穩定相為β-gallia結構,若不使用特殊的成膜方法則難以形成包含具有屬於準穩定相之剛玉結構的氧化鎵的結晶膜這樣的課題、以及該結晶膜在半導體裝置中的熱行為尚不明確這樣的課題。對此,目前包含具有剛玉結構之結晶性半導體的成膜在內,針對包含氧化鎵及/或其混晶的結晶性氧化物半導體膜已有些許研究。例如,專利文獻1中記載將氧化鎵分別與銦或鋁或其組合進行混晶,藉此可控制能隙,而作為InAlGaO系半導體。此處InAlGaO系半導體表示In
XAl
YGa
ZO
3(0≤X≤2,0≤Y≤2,0≤Z≤2,X+Y+Z=1.5~2.5),可將其視為內含氧化鎵的相同材料系統。
It is known that there are five crystal structures of α, β, γ, δ, and ε in gallium oxide (Non-Patent Document 1). Among them, gallium oxide having a corundum structure has a high energy gap and is attracting attention as a semiconductor material that tends to be suitable for next-generation power devices. However, there is still the following problem: in gallium oxide, the most stable phase is the β-gallia structure, and it is difficult to form a crystal film containing gallium oxide having a corundum structure belonging to the quasi-stable phase without using a special film formation method. , and the problem that the thermal behavior of the crystalline film in a semiconductor device has not been clarified. In this regard, some studies have been conducted on crystalline oxide semiconductor films containing gallium oxide and/or mixed crystals thereof, including film formation of crystalline semiconductors having a corundum structure. For example,
此外,以往具有在對半導體元件施加電流時所產生的熱會影響半導體元件特性及壽命的問題,已有人研究例如透過散熱板進行散熱的結構。
專利文獻2中記載一種半導體裝置,其具有與半導體元件連接的一對金屬板,而金屬板則發揮了電極與散熱板兩者的功能。
然而,即使具有這樣的散熱結構,亦未必滿足氧化鎵的散熱性,仍可望一種更有效率地提升散熱性的氧化鎵之半導體裝置。
[先前技術文獻]
[專利文獻]
In addition, conventionally, there is a problem that the heat generated when a current is applied to the semiconductor element affects the characteristics and life of the semiconductor element. For example, a structure for dissipating heat through a heat dissipation plate has been studied.
[專利文獻1]國際公開WO2014-050793A1 [專利文獻2]日本特開2007-73743號公報 [非專利文獻] [Patent Document 1] International Publication WO2014-050793A1 [Patent Document 2] Japanese Patent Laid-Open No. 2007-73743 [Non-patent literature]
[非專利文獻1】R. Roy V.G. Hill, and E. F. Osborn: J. Am. Chem. Soc. 74 (1952) 719[Non-Patent Document 1] R. Roy V.G. Hill, and E. F. Osborn: J. Am. Chem. Soc. 74 (1952) 719
[發明所欲解決之課題][The problem to be solved by the invention]
本發明之目的在於提供一種半導體裝置,其對於結晶性氧化物半導體層具有效率良好的散熱性。 [解決課題之手段] An object of the present invention is to provide a semiconductor device having an efficient heat dissipation property for a crystalline oxide semiconductor layer. [Means of Solving Problems]
本案發明人為了達成上述目的而詳細研究的結果發現,在具備包含氧化鎵或其混晶之結晶性氧化物半導體層、及至少一部分埋設於前述結晶性氧化物半導體層中的閘電極的半導體裝置中,配置至少一部分位於比前述閘電極的埋設端部更深之位置的散熱部,藉此可得到具有對於前述結晶性氧化物半導體層之散熱效率良好的結構的半導體裝置。 又,本案發明人在得到上述見解後,進一步反覆研究進而完成本發明。 As a result of detailed studies to achieve the above object, the inventors of the present invention found that a semiconductor device including a crystalline oxide semiconductor layer containing gallium oxide or a mixed crystal thereof and a gate electrode at least partially embedded in the crystalline oxide semiconductor layer Among them, by arranging at least a part of the heat dissipation portion located deeper than the buried end portion of the gate electrode, a semiconductor device having a structure with good heat dissipation efficiency with respect to the crystalline oxide semiconductor layer can be obtained. In addition, the inventors of the present invention completed the present invention after further research after obtaining the above-mentioned findings.
亦即,本發明係關於以下的發明。 [1]一種半導體裝置,包含至少一部分埋設於結晶性氧化物半導體層的閘電極、及導熱率高於前述結晶性氧化物半導體層之導熱率的散熱部,其中前述散熱部的至少一部分位於前述結晶性氧化物半導體層內之前述閘電極的埋設端部附近及/或比前述埋設端部更深的位置。 [2]如[1]之半導體裝置,其中前述閘電極的埋設端部為埋設下端部。 [3]如[2]之半導體裝置,其中前述散熱部的至少一部分位於比前述埋設下端部更深的位置。 [4]如[2]或[3]之半導體裝置,其更包含深p層,該深p層的至少一部分在前述結晶性氧化物半導體層中埋設至與前述埋設下端部相同的深度或是比前述埋設下端部更深的位置。 [5]如[1]至[4]中任一項之半導體裝置,其中前述散熱部包含導電性材料。 [6]如[5]之半導體裝置,其中前述導電性材料為p型半導體。 [7]如[6]之半導體裝置,其中前述p型半導體具有載子濃度的濃度梯度。 [8]如[6]之半導體裝置,其中前述p型半導體中,載子濃度朝向深度方向變高。 [9]如[1]至[8]中任一項之半導體裝置,其中前述結晶性氧化物半導體層包含選自鎵、銦及鋁中的1種或2種以上的金屬。 [10]如[1]至[9]中任一項之半導體裝置,其中前述結晶性氧化物半導體層含鎵。 [11]如[1]至[10]中任一項之半導體裝置,其為常閉型。 [12]如[1]至[11]中任一項之半導體裝置,其為功率元件。 [13]如[1]至[11]中任一項之半導體裝置,其為功率模組、反向器或轉換器。 [14]如[1]至[11]中任一項之半導體裝置,其為功率卡。 [15]一種半導體系統,具備半導體裝置,其中前述半導體裝置為如[1]至[14]中任一項之半導體裝置。 [發明之效果] That is, the present invention relates to the following inventions. [1] A semiconductor device comprising a gate electrode at least partially embedded in a crystalline oxide semiconductor layer, and a heat dissipation portion having a thermal conductivity higher than that of the crystalline oxide semiconductor layer, wherein at least a portion of the heat dissipation portion is located in the In the crystalline oxide semiconductor layer, the gate electrode is in the vicinity of the buried end portion and/or at a position deeper than the buried end portion. [2] The semiconductor device according to [1], wherein the buried end portion of the gate electrode is a buried lower end portion. [3] The semiconductor device according to [2], wherein at least a part of the heat dissipation portion is located deeper than the buried lower end portion. [4] The semiconductor device according to [2] or [3], further comprising a deep p layer, at least a part of which is buried in the crystalline oxide semiconductor layer to the same depth as the buried lower end portion or A position deeper than the aforementioned buried lower end. [5] The semiconductor device according to any one of [1] to [4], wherein the heat dissipation portion includes a conductive material. [6] The semiconductor device according to [5], wherein the conductive material is a p-type semiconductor. [7] The semiconductor device according to [6], wherein the p-type semiconductor has a concentration gradient of carrier concentration. [8] The semiconductor device according to [6], wherein in the p-type semiconductor, the carrier concentration increases toward the depth direction. [9] The semiconductor device according to any one of [1] to [8], wherein the crystalline oxide semiconductor layer contains one or more metals selected from the group consisting of gallium, indium, and aluminum. [10] The semiconductor device according to any one of [1] to [9], wherein the crystalline oxide semiconductor layer contains gallium. [11] The semiconductor device according to any one of [1] to [10], which is a normally closed type. [12] The semiconductor device according to any one of [1] to [11], which is a power element. [13] The semiconductor device according to any one of [1] to [11], which is a power module, an inverter, or a converter. [14] The semiconductor device according to any one of [1] to [11], which is a power card. [15] A semiconductor system including a semiconductor device, wherein the semiconductor device is the semiconductor device according to any one of [1] to [14]. [Effect of invention]
本發明之半導體裝置,對於結晶性氧化物半導體層散熱性優良,而發揮良好的半導體特性。The semiconductor device of the present invention is excellent in heat dissipation with respect to the crystalline oxide semiconductor layer, and exhibits favorable semiconductor characteristics.
本發明的半導體裝置包含至少一部分埋設於結晶性氧化物半導體層的閘電極、及導熱率高於前述結晶性氧化物半導體層之導熱率的散熱部,其特徵為:前述散熱部的至少一部分位於前述結晶性氧化物半導體層內之前述閘電極的埋設端部附近及/或比前述埋設端部更深的位置。The semiconductor device of the present invention includes a gate electrode at least partially embedded in a crystalline oxide semiconductor layer, and a heat dissipation portion having a thermal conductivity higher than that of the crystalline oxide semiconductor layer, wherein at least a portion of the heat dissipation portion is located in In the crystalline oxide semiconductor layer, the gate electrode is in the vicinity of the buried end portion and/or at a position deeper than the buried end portion.
「閘電極的埋設端部附近」係表示位於接近至「可防止或抑制由至少一部分被埋設之閘電極而來的電場集中所造成的局部高溫化」之程度的距離,亦包含閘電極周邊。另外,可不與閘電極相接,亦可隔著閘極絕緣膜而位於閘電極的整個周圍或部分周圍。「埋設端部」係指前述閘電極的整個埋設面或部分埋設面,不僅是前述閘電極的整個底部或部分底部,亦包含前述閘電極被埋設的整個側面或部分側面。"Near the buried end of the gate electrode" means a distance close to "the local high temperature caused by electric field concentration from at least a part of the buried gate electrode can be prevented or suppressed", and the periphery of the gate electrode is also included. In addition, it may not be in contact with the gate electrode, or may be located on the entire circumference or part of the circumference of the gate electrode via the gate insulating film. "Buried end" refers to the entire or part of the buried surface of the gate electrode, not only the entire bottom or part of the bottom of the gate electrode, but also the entire or part of the side surface where the gate electrode is buried.
「比埋設端部更深的位置」係指位於「可防止或抑制由至少一部分被埋設之閘電極而來的電場集中所造成之局部高溫化」之程度的深度,亦可不位於閘電極的正下方,但本發明中前述埋設端部較佳為埋設下端部。"Position deeper than the buried end" refers to a depth that "can prevent or suppress local high temperature caused by electric field concentration from at least a part of the buried gate electrode", and may not be located directly under the gate electrode However, in the present invention, the buried end portion is preferably the buried lower end portion.
「埋設下端部」係指前述閘電極的整個底部或部分底部。另外,前述埋設端部為埋設下端部時,更包含至少一部分在前述結晶性氧化物半導體層中埋設至與前述埋設下端部相同深度或比前述埋設下端部更深之位置的深p層,可更良好地緩和前述結晶性氧化物半導體層的電場集中等,因而較佳。"Buried lower end" refers to the entire bottom or part of the bottom of the aforementioned gate electrode. In addition, when the buried end portion is a buried lower end portion, at least a part of the deep p-layer is buried in the crystalline oxide semiconductor layer to the same depth as the buried lower end portion or a position deeper than the buried lower end portion. It is preferable because the electric field concentration of the crystalline oxide semiconductor layer and the like are moderated well.
前述閘電極,只要是可控制主電流之流動的電極,則未特別限定,包含半導體區域、擴散區域、電極等。The gate electrode is not particularly limited as long as it is an electrode that can control the flow of the main current, and includes a semiconductor region, a diffusion region, an electrode, and the like.
「散熱部」,只要是可釋放前述結晶性氧化物半導體層內的熱,則未特別限定,可為層狀,亦可為一部分,亦可為一部分在固定方向上相連者。前述散熱部包含例如由散熱構件所構成之散熱部或是散熱層或具有冷卻功能的冷卻部等。前述散熱構件,只要導熱性高於前述結晶性半導體層,則未特別限定。本發明中,前述散熱構件的導熱率較佳為30W/m・K以上,更佳為50W/m・K以上,最佳為100W/m・K以上。又,本發明中,前述散熱構件包含導電性材料亦較佳。前述導電性材料並未特別限定,較佳為導電率高於前述結晶性氧化物半導體層者,作為這種較佳的導電性材料,可列舉例如:p型半導體等。前述p型半導體並未特別限定,本發明中,較佳為p型的結晶性氧化物半導體,更佳為載子濃度具有濃度梯度,最佳為載子濃度朝向深度方向變高。藉由使用這種較佳的散熱構件,可發揮更優良的半導體特性。The "heat dissipation portion" is not particularly limited as long as it can release the heat in the crystalline oxide semiconductor layer, and may be layered, partially, or partially connected in a fixed direction. The aforementioned heat dissipation portion includes, for example, a heat dissipation portion composed of a heat dissipation member, a heat dissipation layer, or a cooling portion having a cooling function. The heat dissipation member is not particularly limited as long as the thermal conductivity is higher than that of the crystalline semiconductor layer. In the present invention, the thermal conductivity of the heat dissipating member is preferably 30 W/m·K or more, more preferably 50 W/m·K or more, and most preferably 100 W/m·K or more. Moreover, in this invention, it is also preferable that the said heat dissipation member contains a conductive material. The above-mentioned conductive material is not particularly limited, and it is preferably one whose electrical conductivity is higher than that of the above-mentioned crystalline oxide semiconductor layer. Examples of such a preferred conductive material include a p-type semiconductor and the like. The p-type semiconductor is not particularly limited, but in the present invention, it is preferably a p-type crystalline oxide semiconductor, more preferably, the carrier concentration has a concentration gradient, and it is more preferable that the carrier concentration increases toward the depth direction. By using such a preferable heat dissipating member, more excellent semiconductor characteristics can be exhibited.
前述結晶性氧化物半導體層,通常包含結晶性氧化物半導體作為主成分。前述結晶性氧化物半導體較佳為含鎵,更佳為含氧化鎵及其混晶作為主成分。又,前述結晶性氧化物半導體的結晶結構等並未特別限定。作為前述結晶性氧化物半導體的結晶結構,可列舉例如:剛玉結構、β-gallia結構、六方晶結構(例如ε型結構)等。本發明中,前述結晶性氧化物半導體較佳為具有剛玉結構或β-gallia結構,更佳為具有剛玉結構。前述具有剛玉結構的結晶性氧化物半導體並未特別限定,較佳係至少包含週期表第3週期~第6週期中的1種或2種以上的金屬,更佳係包含選自鎵、銦、銠、銥及鋁之中的至少一者。關於n型結晶性氧化物半導體,較佳為至少含鎵。關於p型結晶性氧化物半導體,較佳為含有選自銥、銠之中的至少一者,更佳為含銥。作為含鎵之前述結晶性氧化物半導體,可列舉例如:α-Ga 2O 3或其混晶等。作為含銥之前述金屬氧化物,可列舉例如:α-Ir 2O 3或其混晶(例如氧化銥與氧化鎵的混晶)。包含這種較佳的結晶性氧化物半導體作為主成分的結晶性氧化物半導體層,其結晶性及散熱性更為優良,亦可使半導體特性更加優良。另外,前述「主成分」係指以結晶性氧化物半導體層中的組成比計,包含50%以上的前述結晶性氧化物,較佳為包含70%以上,更佳為包含90%以上。例如,前述結晶性氧化物半導體為α-Ga 2O 3的情況,只要以前述結晶性氧化物半導體層之金屬元素中鎵的原子比為0.5以上的比例含有α-Ga 2O 3即可。本發明中,前述結晶性氧化物半導體層之金屬元素中鎵的原子比較佳為0.7以上,更佳為0.8以上。另外,前述結晶性氧化物半導體可為單晶,亦可為多晶。又,前述結晶性氧化物半導體通常為膜狀,只要不阻礙本發明之目的則未特別限定,可為板狀,亦可為片狀,亦可為層狀,亦可為包含多層的積層體。 The crystalline oxide semiconductor layer usually contains a crystalline oxide semiconductor as a main component. The aforementioned crystalline oxide semiconductor preferably contains gallium, more preferably contains gallium oxide and a mixed crystal thereof as a main component. In addition, the crystal structure and the like of the aforementioned crystalline oxide semiconductor are not particularly limited. As a crystal structure of the said crystalline oxide semiconductor, a corundum structure, a β-gallia structure, a hexagonal structure (for example, an ε-type structure), etc. are mentioned, for example. In the present invention, the crystalline oxide semiconductor preferably has a corundum structure or a β-gallia structure, and more preferably has a corundum structure. The above-mentioned crystalline oxide semiconductor having a corundum structure is not particularly limited, but preferably contains at least one or two or more metals in the third to sixth period of the periodic table, and more preferably contains a metal selected from the group consisting of gallium, indium, At least one of rhodium, iridium and aluminum. The n-type crystalline oxide semiconductor preferably contains at least gallium. The p-type crystalline oxide semiconductor preferably contains at least one selected from iridium and rhodium, and more preferably contains iridium. Examples of the crystalline oxide semiconductor containing gallium include α-Ga 2 O 3 or a mixed crystal thereof. Examples of the iridium-containing metal oxide include α-Ir 2 O 3 or a mixed crystal thereof (eg, a mixed crystal of iridium oxide and gallium oxide). A crystalline oxide semiconductor layer containing such a preferred crystalline oxide semiconductor as a main component has more excellent crystallinity and heat dissipation properties, and can also improve semiconductor characteristics. In addition, the above-mentioned "main component" means that the crystalline oxide is contained by 50% or more, preferably 70% or more, and more preferably 90% or more, based on the composition ratio in the crystalline oxide semiconductor layer. For example, when the crystalline oxide semiconductor is α-Ga 2 O 3 , α-Ga 2 O 3 may be contained in such a ratio that the atomic ratio of gallium in the metal element of the crystalline oxide semiconductor layer is 0.5 or more. In the present invention, the atomic ratio of gallium in the metal element of the crystalline oxide semiconductor layer is preferably 0.7 or more, more preferably 0.8 or more. In addition, the aforementioned crystalline oxide semiconductor may be a single crystal or a polycrystal. The crystalline oxide semiconductor is usually in the form of a film, and is not particularly limited as long as the object of the present invention is not inhibited, and may be in the form of a plate, a sheet, a layer, or a laminate including a plurality of layers. .
前述結晶性氧化物半導體亦可含摻雜物。前述摻雜物,只要不阻礙本發明之目的則未特別限定。可為n型摻雜物,亦可為p型摻雜物。作為前述n型摻雜物,可列舉例如:錫、鍺、矽、鈦、鋯、釩或鈮等。作為前述p型摻雜物,可列舉例如:鎂、鈣等。摻雜物的濃度可適當設定,具體而言,例如可為約1×10 16/cm 3~1×10 22/cm 3,又,亦可使摻雜物的濃度為例如約1×10 17/cm 3以下的低濃度。又,再者,根據本發明,亦可以約1×10 20/cm 3以上的高濃度含有摻雜物。 The aforementioned crystalline oxide semiconductor may contain a dopant. The aforementioned dopant is not particularly limited as long as it does not inhibit the purpose of the present invention. It can be an n-type dopant or a p-type dopant. Examples of the n-type dopant include tin, germanium, silicon, titanium, zirconium, vanadium, or niobium. As said p-type dopant, magnesium, calcium, etc. are mentioned, for example. The concentration of the dopant can be appropriately set, and specifically, for example, it may be about 1×10 16 /cm 3 to 1×10 22 /cm 3 , and the concentration of the dopant may be, for example, about 1×10 17 . Low concentration below /cm 3 . Furthermore, according to the present invention, the dopant may be contained in a high concentration of about 1×10 20 /cm 3 or more.
例如以霧化CVD法或霧化/磊晶法進行磊晶結晶成長,可更適當地得到前述結晶性氧化物半導體。For example, the above-mentioned crystalline oxide semiconductor can be obtained more appropriately by performing epitaxial crystal growth by the atomization CVD method or the atomization/epitaxy method.
<結晶基板> 前述結晶基板,只要不阻礙本發明之目的則未特別限定,則亦可為習知的基板。其可為絕緣體基板,亦可為導電性基板,亦可為半導體基板。其可為單晶基板,亦可為多晶基板。作為前述結晶基板,可列舉例如:包含具有剛玉結構之結晶物作為主成分的基板。另外,前述「主成分」係指以基板中的組成比計,包含50%以上之前述結晶物者,較佳為包含70%以上者,更佳為包含90%以上者。作為前述具有剛玉結構之結晶基板,可列舉例如:藍寶石基板、α型氧化鎵基板等。 <Crystalline substrate> The aforementioned crystal substrate is not particularly limited as long as it does not inhibit the purpose of the present invention, and may be a known substrate. It may be an insulator substrate, a conductive substrate, or a semiconductor substrate. It can be a single crystal substrate or a polycrystalline substrate. As the crystal substrate, for example, a substrate containing, as a main component, a crystal product having a corundum structure is exemplified. In addition, the above-mentioned "main component" refers to what contains 50% or more of the above-mentioned crystallized product in terms of the composition ratio in the substrate, preferably 70% or more, and more preferably 90% or more. Examples of the crystal substrate having the corundum structure include a sapphire substrate, an α-type gallium oxide substrate, and the like.
本發明中,前述結晶基板較佳為藍寶石基板。作為前述藍寶石基板,可列舉例如:c面藍寶石基板、m面藍寶石基板、a面藍寶石基板、r面藍寶石基板等。又,前述藍寶石基板亦可具有偏離角。前述偏離角並未特別限定,例如可為0.01°以上,較佳為0.2°以上,更佳為0.2°~12°。前述藍寶石基板中,結晶成長面較佳為a面、m面或r面,具有0.2°以上之偏離角的c面藍寶石基板亦較佳。 另外,前述結晶基板的厚度並未特別限定,通常較佳為10μm~20mm,更佳為10~1000μm。 In the present invention, the aforementioned crystal substrate is preferably a sapphire substrate. As said sapphire substrate, a c-plane sapphire substrate, an m-plane sapphire substrate, an a-plane sapphire substrate, an r-plane sapphire substrate, etc. are mentioned, for example. In addition, the aforementioned sapphire substrate may have an off-angle. The aforementioned off angle is not particularly limited, but may be, for example, 0.01° or more, preferably 0.2° or more, and more preferably 0.2° to 12°. In the aforementioned sapphire substrate, the crystal growth plane is preferably a-plane, m-plane or r-plane, and a c-plane sapphire substrate having an off angle of 0.2° or more is also preferred. In addition, the thickness of the said crystal substrate is not specifically limited, Usually, 10-20 mm is preferable, and 10-1000 micrometers is more preferable.
又,前述結晶基板可為至少含有第1結晶軸與第2結晶軸的形狀,或是亦可形成與第1結晶軸及第2結晶軸對應的溝。 作為前述結晶基板的適當形狀,可列舉例如:圓形、三角形、四角形(例如長方形或梯形等)、五角形或六角形等多角形、扇型等。 Further, the crystal substrate may have a shape including at least a first crystal axis and a second crystal axis, or may form grooves corresponding to the first crystal axis and the second crystal axis. As a suitable shape of the said crystal substrate, a circle, a triangle, a quadrangle (for example, a rectangle, a trapezoid, etc.), a polygon, such as a pentagon or a hexagon, a fan shape, etc. are mentioned, for example.
另外,本發明中,亦可在前述結晶基板上設置緩衝層或應力緩和層等其他層。作為緩衝層,可列舉由具有與前述結晶基板或前述結晶性氧化物半導體之結晶結構相同結晶結構的金屬氧化物所構成之層等。又,作為應力緩和層,可列舉ELO遮罩層等。In addition, in the present invention, other layers such as a buffer layer and a stress relaxation layer may be provided on the crystal substrate. As the buffer layer, a layer composed of a metal oxide having the same crystal structure as the crystal structure of the aforementioned crystalline substrate or the aforementioned crystalline oxide semiconductor can be mentioned. Moreover, as a stress relaxation layer, an ELO mask layer etc. are mentioned.
前述磊晶結晶成長的方法,只要不阻礙本發明之目的則未特別限定,亦可為習知的方法。作為前述磊晶結晶成長方法,可列舉例如:CVD法、MOCVD法、MOVPE法、霧化CVD法、霧化/磊晶法、MBE法、HVPE法、脈衝成長法或ALD法等。本發明中,前述磊晶結晶成長較佳係使用霧化CVD法或霧化/磊晶法進行。The method for growing the epitaxial crystal is not particularly limited as long as the object of the present invention is not inhibited, and a known method may be used. As the epitaxial crystal growth method, for example, CVD method, MOCVD method, MOVPE method, atomization CVD method, atomization/epitaxy method, MBE method, HVPE method, pulse growth method, ALD method, etc. are mentioned. In the present invention, the above-mentioned epitaxial crystal growth is preferably performed by the atomized CVD method or the atomized/epitaxial method.
前述霧化CVD法或霧化/磊晶法係以下述方式進行:使包含金屬的原料溶液霧化(霧化步驟),使液滴飄浮而以載氣載持所得之霧化液滴並將其運送至前述結晶基板附近(運送步驟),然後使前述霧化液滴進行熱反應(成膜步驟)。The aforementioned atomized CVD method or atomization/epitaxy method is carried out by atomizing a raw material solution containing a metal (atomizing step), floating the droplets and supporting the obtained atomized droplets with a carrier gas It is transported to the vicinity of the aforementioned crystalline substrate (transportation step), and then the aforementioned atomized droplets are subjected to thermal reaction (film formation step).
(原料溶液) 原料溶液只要包含作為成膜原料的金屬且可霧化則未特別限定,可包含無機材料,亦可包含有機材料。前述金屬可為金屬單質,亦可為金屬化合物,只要不阻礙本發明之目的則未特別限定,可列舉:選自鎵(Ga)、銥(Ir)、銦(In)、銠(Rh)、鋁(Al)、金(Au)、銀(Ag)、鉑(Pt)、銅(Cu)、鐵(Fe)、錳(Mn)、鎳(Ni)、鈀(Pd)、鈷(Co)、釕(Ru)、鉻(Cr)、鉬(Mo)、鎢(W)、鉭(Ta)、鋅(Zn)、鉛(Pb)、錸(Re)、鈦(Ti)、錫(Sn)、鎂(Mg)、鈣(Ca)及鋯(Zr)之中的1種或2種以上的金屬等,但本發明中,前述金屬較佳為至少包含週期表第3週期~第6週期的1種或2種以上的金屬,更佳為包含選自鎵、銦、銠、銥及鋁之中的至少一者,最佳為至少含鎵。又,本發明中,前述金屬包含鎵、銦及/或鋁亦較佳。藉由使用這種較佳的金屬,能夠形成更適用於半導體裝置等的前述結晶性氧化物半導體膜。 (raw material solution) The raw material solution is not particularly limited as long as it contains a metal as a film-forming raw material and can be atomized, and may contain an inorganic material or an organic material. The aforementioned metal may be a metal element or a metal compound, and is not particularly limited as long as it does not hinder the purpose of the present invention, and may be selected from the group consisting of gallium (Ga), iridium (Ir), indium (In), rhodium (Rh), Aluminum (Al), Gold (Au), Silver (Ag), Platinum (Pt), Copper (Cu), Iron (Fe), Manganese (Mn), Nickel (Ni), Palladium (Pd), Cobalt (Co), Ruthenium (Ru), Chromium (Cr), Molybdenum (Mo), Tungsten (W), Tantalum (Ta), Zinc (Zn), Lead (Pb), Rhenium (Re), Titanium (Ti), Tin (Sn), One or more metals among magnesium (Mg), calcium (Ca), and zirconium (Zr), etc., but in the present invention, it is preferable that the above-mentioned metals include at least one of the third to sixth periods of the periodic table. One or more metals, more preferably at least one selected from the group consisting of gallium, indium, rhodium, iridium and aluminum, and most preferably at least gallium. In addition, in the present invention, the aforementioned metals preferably include gallium, indium and/or aluminum. By using such a preferable metal, the aforementioned crystalline oxide semiconductor film which is more suitable for use in semiconductor devices and the like can be formed.
本發明中,作為前述原料溶液,可適當地使用使前述金屬以錯合物或鹽的型態溶解或分散於有機溶劑或水者。作為錯合物的型態,可列舉例如:乙醯丙酮錯合物、羰基錯合物、氨錯合物、氫化物錯合物等。作為鹽的型態,可列舉例如:有機金屬鹽(例如乙酸金屬鹽、乙二酸金屬鹽、檸檬酸金屬鹽等)、硫化金屬鹽、硝化金屬鹽、磷酸化金屬鹽、鹵化金屬鹽(例如氯化金屬鹽、溴化金屬鹽、碘化金屬鹽等)等。In the present invention, as the raw material solution, one obtained by dissolving or dispersing the metal in the form of a complex or a salt in an organic solvent or water can be suitably used. As a form of a complex, an acetylacetone complex, a carbonyl complex, an ammonia complex, a hydride complex, etc. are mentioned, for example. Examples of the salt form include organic metal salts (eg, metal acetate, metal oxalate, metal citrate, etc.), metal sulfide, metal nitrate, metal phosphate, metal halide (eg, metal halide). chloride metal salt, bromide metal salt, iodide metal salt, etc.) and the like.
前述原料溶液的溶劑,只要不阻礙本發明之目的則未特別限定,可為水等無機溶劑,亦可為醇等有機溶劑,亦可為無機溶劑與有機溶劑的混合溶劑。本發明中,前述溶劑較佳為含水。The solvent of the raw material solution is not particularly limited as long as it does not hinder the object of the present invention, and may be an inorganic solvent such as water, an organic solvent such as alcohol, or a mixed solvent of an inorganic solvent and an organic solvent. In the present invention, the aforementioned solvent is preferably water-containing.
又,前述原料溶液中,亦可混合氫鹵酸或氧化劑等添加劑。作為前述氫鹵酸,可列舉例如:氫溴酸、鹽酸、氫碘酸等。作為前述氧化劑,可列舉例如:過氧化氫(H 2O 2)、過氧化鈉(Na 2O 2)、過氧化鋇(BaO 2)、過氧化苯甲醯(C 6H 5CO) 2O 2等過氧化物、次氯酸(HClO)、過氯酸、硝酸、臭氧水、過乙酸或硝基苯等有機過氧化物等。 Moreover, additives, such as a hydrohalic acid and an oxidizing agent, may be mixed with the said raw material solution. As said hydrohalic acid, hydrobromic acid, hydrochloric acid, hydroiodic acid, etc. are mentioned, for example. Examples of the oxidizing agent include hydrogen peroxide (H 2 O 2 ), sodium peroxide (Na 2 O 2 ), barium peroxide (BaO 2 ), and benzyl peroxide (C 6 H 5 CO) 2 O 2nd class peroxide, hypochlorous acid (HClO), perchloric acid, nitric acid, ozone water, peracetic acid or nitrobenzene and other organic peroxides, etc.
前述原料溶液中亦可含有摻雜物。前述摻雜物只要不阻礙本發明之目的則未特別限定。作為前述摻雜物,可列舉例如:錫、鍺、矽、鈦、鋯、釩或鈮等n型摻雜物、或鎂或鈣等p型摻雜物等。摻雜物的濃度通常為約1×10 16/cm 3~1×10 22/cm 3,又,亦可使摻雜物的濃度為例如約1×10 17/cm 3以下的低濃度。又,再者,根據本發明,亦可以約1×10 20/cm 3以上的高濃度使其含有摻雜物。 The aforementioned raw material solution may also contain a dopant. The aforementioned dopant is not particularly limited as long as it does not inhibit the purpose of the present invention. Examples of the dopant include n-type dopants such as tin, germanium, silicon, titanium, zirconium, vanadium, and niobium, and p-type dopants such as magnesium and calcium. The concentration of the dopant is usually about 1×10 16 /cm 3 to 1×10 22 /cm 3 , and the concentration of the dopant may be as low as about 1×10 17 /cm 3 or less, for example. Furthermore, according to the present invention, the dopant may be contained at a high concentration of about 1×10 20 /cm 3 or more.
(霧化步驟) 前述霧化步驟,係製備調整含金屬之原料溶液,將前述原料溶液霧化以使液滴飄浮而產生霧化液滴。前述金屬的混合比例並未特別限定,相對於原料溶液整體,較佳為0.0001mol/L~20mol/L。霧化方法只要可使前述原料溶液霧化則未特別限定,可為習知的霧化方法,但本發明中較佳係使用超音波振動的霧化方法。本發明中所使用的霧氣係飄浮在空中,例如更佳係不以噴霧的方式吹附,而是初速度為零可作為飄浮於空間中的氣體運送的霧氣。霧氣的液滴尺寸並未特別限定,可為數mm左右的液滴,較佳為50μm以下,更佳為1~10μm。 (Atomization step) The aforementioned atomization step is to prepare and adjust the metal-containing raw material solution, and atomize the aforementioned raw material solution to float the droplets to generate atomized droplets. The mixing ratio of the aforementioned metals is not particularly limited, but is preferably 0.0001 mol/L to 20 mol/L relative to the entire raw material solution. The atomization method is not particularly limited as long as the raw material solution can be atomized, and may be a conventional atomization method, but in the present invention, an atomization method using ultrasonic vibration is preferred. The mist used in the present invention floats in the air. For example, it is more preferable that the mist is not blown in the form of a spray, but has an initial velocity of zero and can be transported as a gas floating in space. The droplet size of the mist is not particularly limited, and may be droplets of about several mm, preferably 50 μm or less, and more preferably 1 to 10 μm.
(運送步驟) 前述運送步驟中,藉由前述載氣將前述霧化液滴運送至前述基體。作為載氣的種類,只要不阻礙本發明之目的則未特別限定,可列舉例如:氧、臭氧、非活性氣體(例如氮或氬等)或還原氣體(氫氣或合成氣體等)等作為適當的例子。又,載氣的種類可為1種,亦可為2種以上,亦可進一步使用使載氣濃度變化的稀釋氣體(例如10倍稀釋氣體等)等作為第2載氣。又,載氣的供給處可不只1處而為2處以上。載氣的流量並未特別限定,較佳為1LPM以下,更佳為0.1~1LPM。 (shipping step) In the aforementioned transporting step, the aforementioned atomized droplets are transported to the aforementioned substrate by the aforementioned carrier gas. The type of carrier gas is not particularly limited as long as the object of the present invention is not inhibited, and examples thereof include oxygen, ozone, inert gas (for example, nitrogen, argon, etc.), reducing gas (hydrogen gas, synthesis gas, etc.) and the like. example. In addition, one type of carrier gas may be used, or two or more types may be used, and a dilution gas (for example, a 10-fold dilution gas, etc.) which changes the carrier gas concentration may be further used as the second carrier gas. In addition, the supply location of the carrier gas may be not only one location but two or more locations. The flow rate of the carrier gas is not particularly limited, but is preferably 1 LPM or less, and more preferably 0.1 to 1 LPM.
(成膜步驟) 成膜步驟中,使前述霧化液滴反應而在前述結晶基板上成膜。前述反應,只要是從前述霧化液滴形成膜的反應則未特別限定,本發明中較佳為熱反應。前述熱反應,只要是以熱能使前述霧化液滴反應即可,反應條件等只要不阻礙本發明之目的亦未特別限定。本步驟中,通常係以原料溶液之溶劑的蒸發溫度以上的溫度進行前述熱反應,較佳為不過高的溫度以下,更佳為650℃以下。又,熱反應只要不阻礙本發明之目的,則可在真空下、非氧環境下、還原氣體環境下及氧氣環境下的任一環境下進行,又可在大氣壓下、加壓下及減壓下的任一條件下進行,本發明中,從蒸發溫度的計算更簡單且亦可使設備等簡化等的觀點來看,較佳係在大氣壓下進行。又,可藉由調整成膜時間來設定膜厚。 (film formation step) In the film formation step, the atomized droplets are reacted to form a film on the crystal substrate. The above-mentioned reaction is not particularly limited as long as it is a reaction of forming a film from the above-mentioned atomized liquid droplets, but in the present invention, a thermal reaction is preferred. The thermal reaction is not particularly limited as long as the atomized liquid droplets are reacted with thermal energy, and the reaction conditions and the like are not particularly limited as long as the object of the present invention is not inhibited. In this step, the thermal reaction is usually carried out at a temperature higher than or equal to the evaporation temperature of the solvent of the raw material solution, preferably not higher than the temperature, more preferably 650°C or lower. In addition, the thermal reaction can be carried out in any environment of vacuum, non-oxygen environment, reducing gas environment and oxygen environment, as long as the object of the present invention is not hindered, and it can be carried out under atmospheric pressure, under pressure and under reduced pressure. In the present invention, it is preferably carried out under atmospheric pressure from the viewpoints that the calculation of the evaporation temperature is simpler and the equipment and the like can be simplified. In addition, the film thickness can be set by adjusting the film-forming time.
以下使用圖式說明適用於本發明的成膜裝置601。圖14的成膜裝置601具備:載氣裝置622a,供給載氣;流量調節閥623a,調節從載氣裝置622a送出之載氣的流量;載氣(稀釋)裝置622b,供給載氣(稀釋);流量調節閥623b,用以調節從載氣(稀釋)裝置622b送出之載氣(稀釋)的流量;霧氣產生源624,收納有原料溶液624a;容器625,放入有水625a;超音波振動子626,安裝於容器625的底面;成膜室630;石英製的供給管627,從霧氣產生源624連接至成膜室630;及加熱板(加熱器)628,設於成膜室630內。加熱板628上設有基板603。The
然後如圖14所示,將原料溶液624a收納於霧氣產生源624內。接著使用基板603,設於加熱板628上,使加熱板628運作而提高成膜室630內的溫度。接著開啟流量調節閥623(623a、623b),從載氣源(載氣裝置622a及載氣(稀釋)裝置622b)將載氣供給至成膜室630內,以載氣充分取代成膜室630的環境後,分別調節載氣的流量、載氣(稀釋)的流量。接著使超音波振動子626振動,透過水625a將其振動傳遞至原料溶液624a,藉此使原料溶液624a微粒子化,而產生霧化液滴624b。此霧化液滴624b由載氣導入成膜室630內,被運送至基板603,然後在大氣壓下,於成膜室630內使霧化液滴624b進行熱反應,而在基板603上形成膜。Then, as shown in FIG. 14, the
又,使用圖15所示的霧化CVD裝置(成膜裝置)602亦較佳。圖15的霧化CVD裝置602具備:載置台621,載置基板603;載氣供給裝置622a,供給載氣;流量調節閥623a,用以調節從載氣供給裝置622a送出的載氣之流量;載氣(稀釋)供給裝置622b,供給載氣(稀釋);流量調節閥623b,用以調節從載氣(稀釋)供給裝置622b送出之載氣的流量;霧氣產生源624,收納有原料溶液624a;容器625,放入有水625a;超音波振動子626,安裝於容器625的底面;供給管627,由內徑40mm的石英管所構成;加熱器628,設於供給管627的周邊部;及排氣口629,將熱反應後的霧氣、液滴及排出氣體排出。載置台621係由石英所構成,載置基板603的面相對於水平面傾斜。作為成膜室的供給管627與載置台621皆由石英所製作,藉此抑制來自裝置之雜質混入形成於基板603上的膜內。此霧化CVD裝置602可與前述成膜裝置601相同地進行操作。In addition, it is also preferable to use the atomizing CVD apparatus (film forming apparatus) 602 shown in FIG. 15 . The
若使用前述較佳的成膜裝置,則可在前述結晶基板的結晶成長面上更輕易地形成前述結晶氧化物半導體。另外,前述結晶氧化物半導體通常係由磊晶結晶成長所形成。If the above-mentioned preferable film forming apparatus is used, the above-mentioned crystalline oxide semiconductor can be more easily formed on the crystal growth surface of the above-mentioned crystal substrate. In addition, the aforementioned crystalline oxide semiconductor is usually formed by epitaxial growth.
前述結晶性氧化物半導體可用於半導體裝置,尤其可用於功率元件。作為使用前述結晶性氧化物半導體所形成之半導體裝置,可列舉:金屬半導體場效電晶體(MESFET)、高電子移動率電晶體(HEMT)、金屬氧化膜半導體場效電晶體(MOSFET)、靜電感應電晶體(SIT)、接面場效電晶體(JFET)、絕緣閘雙極電晶體(IGBT)等。本發明中,可因應預期將前述結晶性氧化物半導體與前述結晶基板剝離等,而用於半導體裝置。The aforementioned crystalline oxide semiconductor can be used for a semiconductor device, especially a power element. Examples of semiconductor devices formed using the aforementioned crystalline oxide semiconductor include metal semiconductor field effect transistor (MESFET), high electron mobility transistor (HEMT), metal oxide semiconductor field effect transistor (MOSFET), electrostatic induction Transistor (SIT), Junction Field Effect Transistor (JFET), Insulated Gate Bipolar Transistor (IGBT), etc. In the present invention, the crystalline oxide semiconductor can be used in a semiconductor device according to expectations such as peeling off the crystalline oxide semiconductor from the crystalline substrate.
又,前述半導體裝置可適用於在半導體層的單面側形成有電極的橫型的元件(橫型元件)及在半導體層的表面與背面兩側分別具有電極的縱型的元件(縱型元件)的任一種,其中,本發明較佳係用於縱型元件。作為前述半導體裝置的較佳例,可列舉例如:金屬半導體場效電晶體(MESFET)、高電子移動率電晶體(HEMT)、金屬氧化膜半導體場效電晶體(MOSFET)、靜電感應電晶體(SIT)、接面場效電晶體(JFET)、絕緣閘雙極電晶體(IGBT)等。In addition, the aforementioned semiconductor device can be applied to a horizontal element (horizontal element) in which electrodes are formed on one side of a semiconductor layer, and a vertical element (vertical element) having electrodes on both sides of the front and rear sides of the semiconductor layer, respectively. ), wherein the present invention is preferably used for vertical elements. Preferred examples of the aforementioned semiconductor devices include, for example, metal semiconductor field effect transistors (MESFETs), high electron mobility transistors (HEMTs), metal oxide semiconductor field effect transistors (MOSFETs), and electrostatic induction transistors (SITs). ), Junction Field Effect Transistor (JFET), Insulated Gate Bipolar Transistor (IGBT), etc.
以下使用圖式說明將本發明的結晶性氧化物半導體應用於n型半導體層(n+型半導體或n型半導體層等)及p型半導體層時前述半導體裝置的較佳例,但本發明不限於此等的例子。Preferred examples of the aforementioned semiconductor device when the crystalline oxide semiconductor of the present invention is applied to an n-type semiconductor layer (n+-type semiconductor layer, n-type semiconductor layer, etc.) and p-type semiconductor layer will be described below using drawings, but the present invention is not limited to Examples of such.
圖1中顯示具備含有結晶性氧化物半導體層之積層體50及至少一部分埋設於積層體50中的閘電極13的半導體裝置100之立體剖面圖。另外,為了方便觀看閘電極周圍的結構,省略表示剖面圖的斜線。圖1的半導體裝置100,至少具有第1導電型的第1結晶性氧化物半導體層1、配置於第1結晶性氧化物半導體層1上的第2結晶性氧化物半導體層2、形成於第2結晶性氧化物半導體層2上的第2導電型的第3結晶性氧化物半導體層3,亦更具備絕緣膜(層間絕緣膜)25與汲電極26等。又,半導體裝置100中,為了防止絕緣膜12的破壞而具有外側位置的深p層6,其具有與第3結晶性氧化物半導體層3的第2面3b相接的面,部分埋設於第2結晶性氧化物半導體層2中,並且位於閘電極13的外側。如圖1所示,2個外側位置的深p層6配置成夾住閘電極的態樣。FIG. 1 shows a perspective cross-sectional view of a
電極的材料亦可為習知的電極材料,作為前述電極材料,可列舉例如:Al、Mo、Co、Zr、Sn、Nb、Fe、Cr、Ta、Ti、Au、Pt、V、Mn、Ni、Cu、Hf、W、Ir、Zn、In、Pd、Nd或Ag等金屬或此等的合金、氧化錫、氧化鋅、氧化錸、氧化銦、氧化銦錫(ITO)、氧化鋅銦(IZO)等金屬氧化物導電膜、聚苯胺、聚噻吩或聚吡咯等有機導電性化合物、或此等的混合物以及積層體等。電極的形成法並未特別限定,可考量與前述材料的適性而藉由適當選自印刷方式、噴霧法、塗布方式等濕式方式、真空蒸鍍法、濺鍍法、離子植入法等物理方式、CVD、電漿CVD法等化學方式等之中的方法形成於前述基板上。The material of the electrode can also be a known electrode material. Examples of the aforementioned electrode material include Al, Mo, Co, Zr, Sn, Nb, Fe, Cr, Ta, Ti, Au, Pt, V, Mn, Ni , Cu, Hf, W, Ir, Zn, In, Pd, Nd or Ag and other metals or their alloys, tin oxide, zinc oxide, rhenium oxide, indium oxide, indium tin oxide (ITO), zinc indium oxide (IZO ) and other metal oxide conductive films, organic conductive compounds such as polyaniline, polythiophene, and polypyrrole, or mixtures and laminates of these. The formation method of the electrodes is not particularly limited, and may be appropriately selected from wet methods such as printing methods, spray methods, and coating methods, vacuum evaporation methods, sputtering methods, ion implantation methods, and other physical methods in consideration of suitability with the aforementioned materials. A method among chemical methods such as CVD method, plasma CVD method, etc. is formed on the aforementioned substrate.
半導體裝置100具備:第1電極26(汲電極),與第1結晶性氧化物半導體層1電連接;絕緣膜12,配置於溝槽11的內側面;作為閘電極的第2電極13(閘電極),配置於溝槽11的內側面,且配置於絕緣膜12上;及第3電極24(源電極),與第3結晶性氧化物半導體層3電連接。The
圖2係針對將電流施加於含有結晶性氧化物半導體層之半導體裝置100時於閘電極13周圍產生的熱分布,進行模擬的評價結果,可知在比閘電極13的埋設端部13b更深的位置且含有結晶性氧化物半導體層之積層體50的內部成為高溫。詳細而言,如圖2所示,在作為結晶性氧化物半導體層的第2結晶性氧化物半導體層2(n-型半導體層)內,閘電極13的下方特別高溫。FIG. 2 is an evaluation result of simulating the heat distribution generated around the
圖3係顯示具有散熱結構之半導體裝置的示意圖。圖3的半導體裝置具有散熱部21,此點與圖1不同。半導體裝置200具有:積層體50,包含結晶性氧化物半導體層1;閘電極13,至少一部分埋設於積層體50;及散熱部21,至少一部分位於比前述閘電極13的埋設端部13b更深的位置。散熱部21位於閘電極13的埋設端部13b的下方。散熱部21埋設於第2結晶性氧化物半導體層2(n-型半導體層)的內部。散熱部21在俯視下位於比外側位置的深p層6更靠近閘電極的位置。亦即,散熱部21在俯視下至少一部分與閘電極重疊。FIG. 3 is a schematic diagram showing a semiconductor device having a heat dissipation structure. The semiconductor device of FIG. 3 is different from FIG. 1 in that it has a
再者,半導體裝置200亦可具有:第1半導體區域4(源區域),配置於第3結晶性氧化物半導體層3(p型半導體層)上,其載子密度高於第2結晶性氧化物半導體層2(n-型半導體層)的載子密度;第2半導體區域5(接觸區域),配置於第3結晶性氧化物半導體層3(p型半導體層)上,其載子密度高於第3結晶性氧化物半導體層3(p型半導體層)的載子密度。閘電極13在第1方向(深度方向)以及相對第1方向具有角度的第2方向上延伸,該第1方向係從第1半導體區域4(源區域)的第1面4a貫通至相反側的第2面4b,再從第3結晶性氧化物半導體層3(p型半導體層)的第1面3a貫通至相反側的第2面3b。根據半導體裝置的設計,第2方向可為斜向,亦可相對第1方向垂直。散熱部21之中心配置於前述閘電極的第1方向(深度方向)與深p層6之埋設下端部6b的虛擬延長線交叉的位置時,可更有效率地將結晶性氧化物半導體層內部的熱擴散。又,作為另一實施例,散熱部21亦可具有與深p層6接觸的面。散熱部21與深p層6熱性連接的情況中,可將封閉在結晶性氧化物半導體層內部的熱更有效率地釋放至半導體裝置之外。另外,「熱性連接」係指例如前述深p層與前述散熱部直接或間接(透過導熱率高於空氣的媒介)相接而使前述深p層的熱傳遞至前述散熱部的構成。圖3中顯示閘電極在第1方向及相對第1方向垂直之方向(圖3中半導體裝置的長邊方向)上延伸。閘電極13的埋設端部13b作為埋設端面而在第2方向上延伸,位於閘電極13之埋設端面下方的散熱部21,亦可沿著閘電極13的埋設端面在第2方向上延伸配置。又,如圖4的剖面圖所示,散熱部21亦可設置為一體,如圖8所示,亦可將2個以上的多個散熱部21鄰接設置或互相分開配置。另外,圖4係示意顯示了在包含IV-IV線且與半導體裝置200之長邊方向平行的面將圖3的半導體裝置截斷所得到之剖面的圖。又,圖8係示意顯示在包含VIII-VIII線且與半導體裝置400之長邊方向平行的面將圖7的半導體裝置截斷所得到之剖面的圖。另外,半導體裝置200為金屬氧化膜半導體場效電晶體(MOSFET)的情況,結晶性氧化物半導體層1為n型半導體層。半導體裝置為絕緣閘雙極電晶體(IGBT)的情況,結晶性氧化物半導體層1為p+型半導體層。Furthermore, the
散熱部21的材料可為習知的材料,但散熱部21的導熱性必須高於散熱部所埋設的結晶性氧化物半導體層的導熱性。例如,第1結晶性氧化物半導體層2的主成分為氧化鎵的情況,散熱部21包含導熱性高於氧化鎵的材料。例如,散熱部21亦可包含高導熱性的金屬(例如鋁或銅等)、金屬化合物及/或金屬氧化物,亦可包含矽化物、多晶矽、石墨等高導熱性材料。散熱部21亦可具有導電性。The material of the
散熱部21亦可含有第2導電型(p型)的雜質。第2導電型雜質的濃度,在更靠近閘電極的散熱部21之第1面21a附近的位置與和第1面21a相反側之第2面21b附近的位置亦可不同。散熱部21中,濃度亦可朝向第1方向(深度方向)變高。散熱部21的第2面21b較佳係位於比外側位置的深p層6的第2面6b更深的位置。The
圖5係顯示具有散熱結構之半導體裝置的另一示意圖。圖5的半導體裝置中,散熱部21具有第1濃度區域23及第2濃度區域22,此點與圖3的半導體裝置不同。半導體裝置300中,配置於閘電極之埋設端部13b下方的散熱部21亦可具有第1濃度區域23(p-)、及第2導電型雜質濃度高於第1濃度區域23的第2濃度區域22(p)。圖6係示意顯示了在包含VI-VI線且與半導體裝置300之長邊方向上平行的面將圖5的半導體裝置截斷所得之剖面的圖。如圖6的剖面圖所示,散熱部21可設置為一體,如圖8的剖面圖所示,亦可將2個以上的多個散熱部21沿著閘電極13的埋設端部13b(第2方向上)鄰接或分開配置,但如圖2的模擬評價結果所示,藉由將散熱部21配置於比閘電極13的埋設端部13b更深的位置且在含有結晶性氧化物半導體層之積層體50的內部,可有效率地使氧化物半導體層內部的熱擴散。FIG. 5 is another schematic diagram showing a semiconductor device having a heat dissipation structure. The semiconductor device of FIG. 5 differs from the semiconductor device of FIG. 3 in that the
圖7係顯示具有散熱結構之半導體裝置的另一示意圖。半導體裝置400具有包含閘電極之埋設端部13b的至少兩面、及隔著絕緣膜12熱性連接的散熱部21。散熱部21中,於上表面具有在第2方向上延伸的凹部,散熱部21的凹部亦可構成溝槽11的一部分,包含閘電極之埋設端部13b的下部隔著絕緣膜12與散熱部21連結。散熱部21其寬度亦可朝向底面變窄。又,第2結晶性氧化物半導體層2亦可具有2個以上配置於第2導電型的前述散熱部之間的電流擴散區域。
另外,圖7中,閘電極的上端部13a未埋設於溝槽內,但本發明中更佳係閘電極的上端部13a埋設於溝槽內。
FIG. 7 is another schematic diagram showing a semiconductor device having a heat dissipation structure. The
圖9係顯示具有散熱結構之半導體裝置的另一示意圖。半導體裝置500具有包含閘電極之埋設端部13b的至少兩面、及隔著絕緣膜12熱性連接的散熱部21。散熱部21於上表面具有在第2方向上延伸的凹部,散熱部21的凹部亦可構成溝槽11的一部分,包含閘電極之埋設端部13b的下部隔著絕緣膜12與散熱部21連結。散熱部21亦可包含第2導電型(p型)的雜質,第2導電型的雜質濃度在具有凹部的散熱部21之上表面與散熱部21的底面亦可不同。散熱部21中,濃度亦可朝向第1方向(深度方向)變高。圖10係示意顯示了在包含X-X線且與半導體裝置500之長邊方向平行的面將圖9的半導體裝置截斷所得之剖面的圖。如圖10的剖面圖所示,散熱部21亦可設置為一體,如圖8所示,亦可將2個以上的多個散熱部21鄰接設置或互相分開配置。散熱部21的第1濃度區域23,位於比第2濃度區域22更靠近溝槽側面的位置。在對於第2電極13施加電壓時,第1濃度區域在靠近溝槽之該側面的位置形成反轉層。FIG. 9 is another schematic diagram showing a semiconductor device having a heat dissipation structure. The
又,針對結晶性氧化物半導體層使用α-Ga 2O 3、散熱部使用p型氧化物半導體(α-Ir 2O 3或摻雜了Mg的α-Ga 2O 3)之情況的圖3、圖5、圖7及圖9所示之半導體裝置的各閘電極周圍的熱分布進行研究,結果並未產生如圖2所示的高溫部。由此亦可知,根據本發明,可防止或抑制由至少一部分被埋設之閘電極而來的電場集中造成局部高溫化,其半導體特性優良。 3 shows the case where α-Ga 2 O 3 is used for the crystalline oxide semiconductor layer and p-type oxide semiconductor (α-Ir 2 O 3 or Mg-doped α-Ga 2 O 3 ) is used for the heat dissipation portion , FIG. 5, FIG. 7 and FIG. 9 of the semiconductor device shown in FIG. 9 heat distribution around each gate electrode, the results did not produce a high temperature portion shown in FIG. 2 . From this, it can be seen that according to the present invention, local temperature increase due to electric field concentration from at least a part of the buried gate electrode can be prevented or suppressed, and the semiconductor characteristics are excellent.
半導體裝置各層的形成手段,只要不阻礙本發明之目的則未特別限定,亦可為習知手段。例如,在藉由真空蒸鍍法、CVD法、濺鍍法或各種塗布技術等成膜後藉由光微影法圖案化的手段、或是使用印刷技術等直接進行圖案化的手段等。The formation means of each layer of the semiconductor device is not particularly limited as long as the object of the present invention is not inhibited, and conventional means may be used. For example, a method of patterning by a photolithography method after forming a film by a vacuum deposition method, a CVD method, a sputtering method, or various coating techniques, or a method of directly patterning using a printing technique or the like.
前述半導體裝置對於功率元件特別有用,尤其適合用作常閉型半導體裝置。本發明中,因應預期使用習知的手段將前述結晶性氧化物半導體與前述結晶基板剝離等,可用於半導體裝置,可適當地用作縱型元件。另外,前述半導體裝置適用於半導體層的單面側形成有電極的橫型的元件(橫型元件)與半導體層表面與背面的兩面側分別具有電極的縱型的元件(縱型元件)之任一者,其中本發明較佳係用於縱型元件。作為前述半導體裝置的較佳例,可列舉例如:金屬半導體場效電晶體(MESFET)、高電子移動率電晶體(HEMT)、金屬氧化膜半導體場效電晶體(MOSFET)、靜電感應電晶體(SIT)、接面場效電晶體(JFET)、絕緣閘雙極電晶體(IGBT)等。本發明中,其中較佳為絕緣閘極型半導體裝置(例如MOSFET或IGBT等)或具有肖特基閘極的半導體裝置(例如MESFET等),更佳為MOSFET或IGBT。The aforementioned semiconductor device is particularly useful for power elements, and is particularly suitable for use as a normally-off semiconductor device. In the present invention, it is expected that the crystalline oxide semiconductor can be used for a semiconductor device by peeling off the crystalline oxide semiconductor from the crystalline substrate by a conventional means, and can be suitably used as a vertical element. In addition, the aforementioned semiconductor device is suitable for any of a horizontal element (horizontal element) in which an electrode is formed on one side of a semiconductor layer, and a vertical element (vertical element) having electrodes on both sides of the front and rear sides of the semiconductor layer, respectively. One, wherein the present invention is preferably used for vertical elements. Preferred examples of the aforementioned semiconductor devices include, for example, metal semiconductor field effect transistors (MESFETs), high electron mobility transistors (HEMTs), metal oxide semiconductor field effect transistors (MOSFETs), and electrostatic induction transistors (SITs). ), Junction Field Effect Transistor (JFET), Insulated Gate Bipolar Transistor (IGBT), etc. In the present invention, an insulated gate type semiconductor device (eg, MOSFET or IGBT, etc.) or a semiconductor device with a Schottky gate (eg, MESFET, etc.) is preferable, and MOSFET or IGBT is more preferable.
本發明的半導體裝置,除了上述事項以外,亦可進一步使用習知的方法而適當地用作功率模組、反向器或轉換器,可再佳地用於例如使用了電源裝置的半導體系統等。前述電源裝置可使用習知的方法,藉由連接於配線圖案等,而由前述半導體裝置所製作,或是製作為前述半導體裝置。圖11係使用複數的前述電源裝置171、172與控制電路173構成電源系統170。前述電源系統,如圖12所示,可將電子電路181與電源系統182組合而用於系統裝置180。另外,電源裝置的電源電路圖之一例顯示於圖13。圖13係顯示功率電路與控制電路所構成之電源裝置的電源電路,藉由反向器192(由MOSFET A~D所構成)以高頻切換DC電壓而轉換成AC後,以變壓器193實施絕緣及變壓,並藉由整流MOSFET194(A~B’)整流後,以DCL195(平滑用線圈L1、L2)與電容器進行平滑,輸出直流電壓。此時以電壓比較器197將輸出電壓與基準電壓比較,以PWM控制電路196控制反向器192及整流MOSFET194而成為預期的輸出電壓。In addition to the above-mentioned matters, the semiconductor device of the present invention can be appropriately used as a power module, an inverter, or a converter using a conventional method, and can be preferably used, for example, in a semiconductor system using a power supply device. . The aforementioned power supply device can be fabricated from the aforementioned semiconductor device by connecting to a wiring pattern or the like using a conventional method, or can be fabricated as the aforementioned semiconductor device. In FIG. 11 , a
本發明中,前述半導體裝置較佳為功率卡,更佳為包含冷卻器及絕緣構件且前述冷卻器分別至少隔著前述絕緣構件設於前述半導體層的兩側,最佳為前述半導體層的兩側分別設有散熱層且前述冷卻器至少隔著前述絕緣構件分別設於散熱層的外側。圖16係顯示本發明之較佳實施態樣之一的功率卡。圖16的功率卡為雙面冷卻型功率卡201,其具備冷媒管202、間隔器203、絕緣板(絕緣間隔器)208、密封樹脂部209、半導體晶片301a、金屬導熱板(突出端子部)302b、熱匯(heat sink)及電極303、金屬導熱板(突出端子部)303b、焊接層304、控制電極端子305以及接合線308。冷媒管202的厚度方向剖面,具有多個以互相隔著既定間隔在流路方向上延伸的多個分隔壁221所劃分出來的流路222。根據這種較佳的功率卡,可實現更高的散熱性,可滿足更高的可靠度。In the present invention, the semiconductor device is preferably a power card, and more preferably includes a cooler and an insulating member, and the cooler is disposed on both sides of the semiconductor layer at least across the insulating member, preferably two of the semiconductor layer. A heat dissipation layer is respectively provided on the sides, and the coolers are respectively provided on the outer side of the heat dissipation layer through at least the insulating member. FIG. 16 shows a power card of one of the preferred embodiments of the present invention. The power card shown in FIG. 16 is a double-sided cooling
半導體晶片301a以焊接層304接合於金屬導熱板(突出端子部)302b內側的主面上,金屬導熱板(突出端子部)303b以焊接層304接合於半導體晶片301a的剩餘主面,藉此在IGBT的集電極面及發射電極面上,續流二極體的陽極電極面及陰極電極面進行所謂的反向並聯連接。作為金屬導熱板(突出端子部)302b及303b的材料,可列舉例如Mo或W等。金屬導熱板(突出端子部)302b及303b具有厚度差以吸收半導體晶片301a之厚度差,藉此使金屬導熱板302b及303b的外表面成為平面。The
樹脂密封部209由例如環氧樹脂所構成,其覆蓋該等金屬導熱板302b及303b的側面而進行密封,半導體晶片301a由樹脂密封部209所密封。然而,金屬導熱板302b及303b的外主面、亦即接觸受熱面完全露出。金屬導熱板(突出端子部)302b及303b從樹脂密封部209往圖16中的右邊突出,作為所謂引線框架端子的控制電極端子305,將例如形成有IGBT的半導體晶片301a之閘極(控制)電極面與控制電極端子305連接。The
作為絕緣間隔器的絕緣板208,例如係由氮化鋁膜所構成,但亦可為其他絕緣膜。絕緣板208完全被覆金屬導熱板302b及303b而與其密合,但絕緣板208亦可僅與金屬導熱板302b及303b接觸,亦可塗布矽滑脂等優良導熱材,亦可以各種方法將此等接合。又,亦可以陶瓷噴塗等形成絕緣層,亦可將絕緣板208接合於金屬導熱板上,亦可與冷媒管接合或形成於其上。The insulating
冷媒管202係將以拉擠成形法或擠製成形法使鋁合金成形而成的板材裁切成必要長度而製作。冷媒管202的厚度方向剖面具有多個以互相隔著既定間隔在流路方向上延伸的多個分隔壁221所劃分而成的流路222。間隔器203可為例如焊料合金等軟質的金屬板,亦可作為以塗布等而形成於金屬導熱板302b及303b之接觸面的膜(film)。此軟質之間隔器203的表面容易變形而配合絕緣板208的微小凹凸或翹曲、冷媒管202的微小凹凸或翹曲以降低熱阻抗。另外,可在間隔器203的表面等塗布習知導熱性優良的油脂等,亦可省略間隔器203。
[產業上的可利用性]
The
本發明的半導體裝置可用於例如化合物半導體電子元件、電子零件/電器設備零件、光學/電子影像相關裝置、工業構件等所有領域,尤其可用於包含氧化物半導體層的功率元件。The semiconductor device of the present invention can be used in all fields, such as compound semiconductor electronic elements, electronic parts/electrical equipment parts, optical/electronic imaging related devices, and industrial components, and is especially applicable to power elements including oxide semiconductor layers.
1:第1結晶性氧化物半導體層 2:第2結晶性氧化物半導體層 3:第3結晶性氧化物半導體層 3a:第3結晶性氧化物半導體層的第1面 3b:第3結晶性氧化物半導體層的第2面 4:第1半導體區域 4a:第1半導體區域的第1面 4b:第1半導體區域的第2面 5:第2半導體區域 6:外側位置的深p層 6b:深p層的埋設下端部 11:溝槽 12:絕緣膜 13:閘電極 13a:閘電極的上端部 13b:閘電極的埋設下端部 21:散熱部 21a:第1面 21b:第2面 22:第2濃度區域 23:第1濃度區域 24:源電極 25:絕緣膜(層間絕緣膜) 26:汲電極 50:積層體 100:半導體裝置 170:電源系統 171:電源裝置 172:電源裝置 173:控制電路 180:系統裝置 181:電子電路 182:電源系統 192:反向器 193:變壓器 194:整流MOSFET 195:DCL 196:PWM控制電路 197:電壓比較器 200:半導體裝置 201:兩面冷卻型功率卡 202:冷媒管 203:間隔器 208:絕緣板(絕緣間隔器) 209:密封樹脂部 221:分隔壁 222:流路 300:半導體裝置 301a:半導體晶片 302b:金屬導熱板(突出端子部) 303:熱匯及電極 303b:金屬導熱板(突出端子部) 304:焊接層 305:控制電極端子 308:接合線 400:半導體裝置 500:半導體裝置 601:霧化裝置(成膜裝置) 602:霧化裝置(成膜裝置) 603:基板 621:載置台 622a:載氣供給裝置 622b:載氣(稀釋)供給裝置 623a:流量調節閥 623b:流量調節閥 624:霧氣產生源 624a:原料溶液 625:容器 625a:水 626:超音波振動子 627:供給管 628:加熱器 629:排氣口 630:成膜室 D:深度 W:間隔 1: First crystalline oxide semiconductor layer 2: Second crystalline oxide semiconductor layer 3: Third crystalline oxide semiconductor layer 3a: the first surface of the third crystalline oxide semiconductor layer 3b: the second surface of the third crystalline oxide semiconductor layer 4: 1st semiconductor region 4a: The first surface of the first semiconductor region 4b: The second side of the first semiconductor region 5: Second semiconductor region 6: Deep p-layer at outer position 6b: Buried lower end of deep p-layer 11: Groove 12: Insulating film 13: Gate electrode 13a: Upper end of gate electrode 13b: Buried lower end of gate electrode 21: heat dissipation department 21a: Side 1 21b: Side 2 22: The second concentration area 23: The first concentration area 24: Source electrode 25: Insulating film (interlayer insulating film) 26: drain electrode 50: Laminate 100: Semiconductor Devices 170: Power System 171: Power supply unit 172: Power supply unit 173: Control circuit 180: System installation 181: Electronic Circuits 182: Power System 192: reverser 193: Transformer 194: Rectifier MOSFET 195: DCL 196: PWM control circuit 197: Voltage Comparator 200: Semiconductor Devices 201: Two-sided cooling power card 202: Refrigerant pipe 203: Spacer 208: Insulation board (insulation spacer) 209: Sealing Resin Department 221: Dividing Wall 222: flow path 300: Semiconductor Devices 301a: Semiconductor wafers 302b: Metal thermal conductive plate (protruding terminal part) 303: Heat sinks and electrodes 303b: Metal thermal conductive plate (protruding terminal part) 304: Welding layer 305: Control electrode terminal 308: Bonding Wire 400: Semiconductor Devices 500: Semiconductor Devices 601: Atomization device (film forming device) 602: Atomization device (film forming device) 603: Substrate 621: Mounting Table 622a: Carrier gas supply 622b: Carrier gas (dilution) supply device 623a: Flow control valve 623b: Flow regulating valve 624: Mist generation source 624a: raw material solution 625: Container 625a: Water 626: Ultrasonic Vibrator 627: Supply Tube 628: Heater 629: exhaust port 630: Film forming chamber D: depth W: interval
【圖1】係顯示具有含結晶性氧化物半導體層之積層體的半導體裝置的概略立體剖面圖。 【圖2】係顯示針對將電流施加於圖1之半導體裝置時在閘電極周圍產生之熱分布進行模擬的評價結果。 【圖3】係示意顯示具有散熱結構之半導體裝置的較佳之一例的立體剖面圖。 【圖4】係示意顯示圖3的半導體裝置之剖面的圖。 【圖5】係示意顯示具有散熱結構之半導體裝置的較佳之一例的立體剖面圖。 【圖6】係示意顯示圖5的半導體裝置之剖面的圖。 【圖7】係示意顯示具有散熱結構之半導體裝置的較佳之一例的立體剖面圖。 【圖8】係示意顯示圖7的半導體裝置之剖面的圖。 【圖9】係示意顯示具有散熱結構之半導體裝置的較佳之一例的立體剖面圖。 【圖10】係示意顯示圖9的半導體裝置之剖面的圖。 【圖11】係示意顯示電源系統的較佳之一例的圖。 【圖12】係示意顯示電源裝置的電源電路圖的較佳之一例的圖。 【圖13】係示意顯示電源裝置的電源電路圖的較佳之一例的圖。 【圖14】係顯示結晶性氧化物半導體層的形成中所使用的成膜裝置(霧化CVD裝置)的概略圖。 【圖15】係顯示結晶性氧化物半導體層的形成中所使用的成膜裝置(霧化CVD裝置)的概略圖。 【圖16】係示意顯示功率卡的較佳之一例的圖。 FIG. 1 is a schematic perspective cross-sectional view showing a semiconductor device having a laminate including a crystalline oxide semiconductor layer. [ Fig. 2] Fig. 2 shows an evaluation result obtained by simulating the heat distribution generated around the gate electrode when a current is applied to the semiconductor device of Fig. 1 . 3 is a perspective cross-sectional view schematically showing a preferred example of a semiconductor device having a heat dissipation structure. FIG. 4 is a diagram schematically showing a cross section of the semiconductor device of FIG. 3 . 5 is a perspective cross-sectional view schematically showing a preferred example of a semiconductor device having a heat dissipation structure. FIG. 6 is a diagram schematically showing a cross section of the semiconductor device of FIG. 5 . 7 is a perspective cross-sectional view schematically showing a preferred example of a semiconductor device having a heat dissipation structure. FIG. 8 is a diagram schematically showing a cross section of the semiconductor device of FIG. 7 . 9 is a perspective cross-sectional view schematically showing a preferred example of a semiconductor device having a heat dissipation structure. FIG. 10 is a diagram schematically showing a cross section of the semiconductor device of FIG. 9 . [ Fig. 11 ] A diagram schematically showing a preferred example of a power supply system. [ Fig. 12 ] A diagram schematically showing a preferred example of a power supply circuit diagram of a power supply device. [ Fig. 13 ] A diagram schematically showing a preferred example of a power supply circuit diagram of a power supply device. FIG. 14 is a schematic diagram showing a film formation apparatus (atomized CVD apparatus) used for formation of a crystalline oxide semiconductor layer. FIG. 15 is a schematic diagram showing a film formation apparatus (atomized CVD apparatus) used for formation of a crystalline oxide semiconductor layer. [ Fig. 16 ] A diagram schematically showing a preferred example of a power card.
1:第1結晶性氧化物半導體層 1: First crystalline oxide semiconductor layer
2:第2結晶性氧化物半導體層 2: Second crystalline oxide semiconductor layer
3:第3結晶性氧化物半導體層 3: Third crystalline oxide semiconductor layer
3a:第3結晶性氧化物半導體層的第1面 3a: the first surface of the third crystalline oxide semiconductor layer
6:外側位置的深p層 6: Deep p-layer at outer position
7:p-型半導體層(通道層) 7: p-type semiconductor layer (channel layer)
11:溝槽 11: Groove
16:p+型半導體層 16: p+ type semiconductor layer
24:源電極 24: Source electrode
25:絕緣膜(層間絕緣膜) 25: Insulating film (interlayer insulating film)
26:汲電極 26: drain electrode
D:深度 D: depth
W:間隔 W: interval
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