TW202133836A - Hair cosmetic composition - Google Patents

Abstract

A hair cosmetic composition and a hair cosmetic using said hair cosmetic composition which are packed into a non-gas type foam dispensing container for use, wherein: said composition contains the following component (A), component (B), and component (C), and component (A) is a cationic surfactant, component (B) is an amphoteric surfactant, and component (C) is at least one component selected from the group consisting of nonionic surfactants (C1), modified silicones having a cationic group (C2), and sugar alcohols having a carbon number of at least 4 (C3); the mass ratio of [(B)/(A)] is 0.4-5, inclusive; and the higher alcohol content is no more than 0.1 mass%.

Description

Hair cosmetic composition

The present invention relates to a hair cosmetic composition.

Hair is damaged due to living environment (ultraviolet rays or heat generated by sunlight), daily hair care activities (friction caused by shampooing or combing), chemical treatment (hair dyeing, perming, etc.). Therefore, hair cosmetics that inhibit hair damage are more important, and a hair cosmetic that can realize efficient and stress-free hair care behaviors is desired. In response to this expectation, a hair cosmetic that does not use a propellant but uses an airless bubble spray container is proposed.

Patent Document 1 (Japanese Patent Laid-Open No. 2017-128618) discloses that it contains a predetermined amount of stearyl trimethylammonium chloride, polyoxyethylene-polyoxypropylene butyl ether, dipropylene glycol, and ethanol. The gas-type foam-like hair cosmetics have higher foam elasticity, have a moderate foam lasting feeling without dripping, and can impart a higher repair feeling to the hair. Patent Document 2 (Japanese Patent Laid-Open No. 2018-158901) discloses a polyglycerol fat containing a cationic surfactant and an HLB (Hydrophile Lipophile Balance, hydrophilic/oil ratio) of 12-18 carbon numbers 8-18 Hair cosmetics containing acid esters, polyoxyethylene alkyl glucosides, and one or more polyols selected from di- or tripropylene glycol, 1,2-propylene glycol, and 1,3-propylene glycol when applied to the hair Excellent feeling in use, and the finished hair has excellent softness, smoothness, and neatness without stickiness. Patent Document 3 (Japanese Patent Laid-Open No. 2018-2637) states that a composition containing an amphoteric surfactant and a nonionic surfactant is contained in a composition having 3 or more sheets as a mesh thickness within a prescribed range The porous body of the sieve and the spray volume of the above composition each time is an airless foaming container of 3 ml or more. Hair cosmetics selected from hair cleansers and rinse-off hair protectors can prevent friction between hairs Or hair damage caused by rinsing after use. Patent Document 4 (Japanese Patent Laid-Open No. 2006-104149) discloses that it is possible to provide an amphoteric surfactant, a cationic surfactant, and a higher alcohol, and the compounding amount of the amphoteric surfactant is within a prescribed range, and The conditioner composition for non-aerosol bubble spray container with the mass ratio of amphoteric surfactant, cationic surfactant and higher alcohol within the specified range, and the conditioner product using the same as a stable sprayable bubble, The conditioner composition and the conditioner products that use it smoothly during rinsing. Patent Document 5 (Japanese Patent Laid-Open No. 2001-10930) discloses that a compound containing an IOB (Inorganic Organic Balance) value within a predetermined range and having an OH group, silicone oil, and The non-aerosol foamed hair cosmetic obtained by filling the foam spray container with the surfactant composition has excellent foaming properties, the foam is fine and creamy, and the smoothness after being applied to the hair is also good.

The present invention relates to the following [1] and [2]. [1] A hair cosmetic composition containing or blending the following ingredients (A), ingredient (B), and ingredient (C): Ingredient (A): cationic surfactant; Ingredient (B): Amphoteric surfactant; Ingredient (C): one selected from the group consisting of nonionic surfactants (C1), modified silicones with cationic groups (C2), and sugar alcohols with 4 or more carbons (C3) above; The mass ratio [(B)/(A)] of the content or blended amount of the component (B) to the content or blended amount of the component (A) is 0.4 to 5, The content or blending amount of higher alcohol is 0.1% by mass or less, The hair cosmetic composition is filled in an airless bubble spray container for use. [2] A hair cosmetic, which is formed by filling the hair cosmetic composition of the above-mentioned [1] in an airless bubble ejection container.

When a gas-free bubble spray container is applied to hair, the hair cosmetic composition is mixed with air in the bubble spray container and extruded through a screen to spray out in a bubble shape. However, if the hair cosmetic composition is ejected from the bubble ejection container in a low temperature environment such as -5°C, there is a problem that ejection failure occurs. The cause of the poor ejection was found to be that the hair cosmetic composition had low stability when stored in a low-temperature environment, and the screen was clogged due to the precipitation of the components of the composition. Therefore, it is required to improve the storage stability of the hair cosmetic composition in a low temperature environment. On the other hand, if it is desired to improve the storage stability in a low-temperature environment, the composition of the hair cosmetic composition is restricted. In the technology of Patent Documents 1 to 5, the storage stability under low temperature environment, the texture of the foam, the characteristics of preventing hair from being damaged by friction between the hairs during application, and the smoothness during rinsing are imparted and The suppression of hair tangles has not been fully satisfied, so improvement is sought. The present invention relates to a hair cosmetic composition and a hair cosmetic using the hair cosmetic composition. The hair cosmetic composition has excellent storage stability in a low temperature environment, and the texture of bubbles ejected from a bubble ejection container is excellent It also has excellent properties in preventing hair from being damaged by friction between hairs during application, and can give hair good smoothness during rinsing, and can prevent hair from getting tangled.

The inventors of the present invention found that the following hair cosmetic composition can solve the above-mentioned problems. The hair cosmetic composition contains or is formulated with a cationic surfactant, an amphoteric surfactant, and a nonionic surfactant with cationic surfactants. One or more of the group consisting of modified silicones and carbon number 4 or more sugar alcohols, the content or blending amount of the amphoteric surfactant is relative to the content or blending amount of the cationic surfactant The content or blending amount of higher alcohol is 0.1% by mass or less than within the specified range. That is, the present invention relates to the following [1] and [2]. [1] A hair cosmetic composition containing or blending the following ingredients (A), ingredient (B), and ingredient (C): Ingredient (A): cationic surfactant; Ingredient (B): Amphoteric surfactant; Ingredient (C): one selected from the group consisting of nonionic surfactants (C1), modified silicones with cationic groups (C2), and sugar alcohols with 4 or more carbons (C3) above; The mass ratio [(B)/(A)] of the content or blended amount of the component (B) to the content or blended amount of the component (A) is 0.4 to 5, The content or blending amount of higher alcohol is 0.1% by mass or less, The hair cosmetic composition is filled in an airless bubble spray container for use. [2] A hair cosmetic, which is formed by filling the hair cosmetic composition of the above-mentioned [1] in an airless bubble ejection container.

According to the present invention, it is possible to provide a hair cosmetic composition and a hair cosmetic using the hair cosmetic composition. The hair cosmetic composition has excellent storage stability in a low-temperature environment and is excellent in the foam ejected from the foam ejection container. It has excellent texture and has excellent properties in preventing hair from being damaged by friction between hairs during application. Furthermore, it can impart good smoothness to hair during rinsing, and can inhibit hair tangling.

[Hair cosmetic composition] The hair cosmetic composition of the present invention (hereinafter also simply referred to as "hair cosmetic composition") contains or is formulated with the following ingredients (A), ingredient (B), and ingredient (C): Ingredient (A): cationic surfactant; Ingredient (B): Amphoteric surfactant; Ingredient (C): one selected from the group consisting of nonionic surfactants (C1), modified silicones with cationic groups (C2), and sugar alcohols with 4 or more carbons (C3) above; The mass ratio [(B)/(A)] of the content or blended amount of component (B) to the content or blended amount of component (A) is 0.4 to 5, The content or blending amount of higher alcohol is 0.1% by mass or less, The hair cosmetic composition is filled in an airless bubble spray container for use. Furthermore, in the present invention, the storage stability at -5°C is used as the index of "storage stability in a low temperature environment". If the storage stability at -5°C is excellent, the hair cosmetic composition of the present invention can be filled in a gas-free bubble spray container even in a cold area. The shape of the hair cosmetic composition for use is sufficient use. Hereinafter, the "storage stability under low temperature environment" is simply referred to as "low temperature stability".

The reason why the hair cosmetic composition of the present invention has the above-mentioned structure to exert the effects of the present invention is not clear, but it is estimated as follows. The hair cosmetic composition of the present invention contains or blends a cationic surfactant as the component (A), an amphoteric surfactant as the component (B), and a nonionic surfactant selected from the group consisting of the component (C) (C1) One or more of the group consisting of modified silicone with cationic group (C2) and sugar alcohol (C3) with 4 or more carbons. By the mass ratio [(B)/(A)] of the content or blended amount of the component (B) in the hair cosmetic composition to the content or blended amount of the component (A) within the specified range, the component (A) ) Improve the solubility of component (B), thereby improving low-temperature stability. In addition, with the above-mentioned mass ratio [(B)/(A)] within the specified range, the texture of the bubble ejected from the bubble ejection container is improved, and the property that the bubble is easy to fuse with the hair during application is improved, and the hair can be prevented from being damaged. Damage caused by friction between hairs. In addition, since the content or blending amount of the higher alcohol in the hair cosmetic composition of the present invention is less than a specific value, the components of the composition do not precipitate even in a low temperature environment, and the low temperature stability is further improved. In addition, component (C) can prevent hair from being damaged by friction between hairs during application, can impart good smoothness to hair during rinsing, and can prevent hair from becoming tangled.

<Component (A): Cationic surfactant> The hair cosmetic composition contains or blends a cationic surfactant as a component (A) (hereinafter simply referred to as "(A)"). As the cationic surfactant, (i) alkyl trimethyl ammonium salt, (ii) alkoxy alkyl trimethyl ammonium salt, (iii) dialkyl dimethyl ammonium salt, (iv) Alkylamido alkyl trimethyl ammonium salt, (v) alkyl dimethyl amine and its salt, (vi) alkoxy alkyl dimethyl amine and its salt, and (vii) alkyl amine Alkyl dimethyl amine and its salts, etc.

As the (i) alkyl trimethyl ammonium salt, an alkyl trimethyl ammonium salt having an alkyl group having preferably a carbon number of 12 or more and 22 or less, and more preferably a carbon number of 16 or more and 20 or less can be exemplified. For example, cetyl trimethyl ammonium chloride (cetyl trimethyl ammonium chloride), stearyl trimethyl ammonium chloride (stearyl trimethyl ammonium chloride), chlorinated Behenyl trimethyl ammonium and so on. As the (ii) alkoxyalkyl trimethylammonium salt, an alkoxyalkyl group having an alkoxy group having preferably a carbon number of 12 or more and 22 or less, more preferably a carbon number of 16 or more and 20 or less can be mentioned. Trimethylammonium salt, specifically, stearyloxypropyltrimethylammonium chloride, stearyloxyethyltrimethylammonium chloride, stearyloxyhydroxypropyltrimethylchloride Base ammonium and so on. The (iii) dialkyl dimethyl ammonium salt may, for example, be a dialkyl dimethyl ammonium salt having an alkyl group having a carbon number of 12 or more and 22 or less, and more preferably a carbon number of 16 or more and 20 or less. Specifically, distearyl dimethyl ammonium chloride etc. may be mentioned. As (iv) alkylamidoalkyltrimethylammonium salt, an alkylamine having an alkyl group having preferably a carbon number of 11 or more and 21 or less, more preferably a carbon number of 13 or more and 19 or less can be exemplified The base alkyl trimethyl ammonium salt, specifically, palmitoylamino propyl trimethyl ammonium chloride (palmitamido propyl trimethyl ammonium chloride) etc. can be mentioned.

(v) Alkyl dimethyl amine, (vi) alkoxy alkyl dimethyl amine, and (vii) alkyl amido alkyl dimethyl amine react with acid to form tertiary amine salt, which becomes cationic Surfactant. (v) Alkyl dimethyl amine and its salt and (vi) Alkoxy alkyl dimethyl amine and its salt preferably have a carbon number of 12 or more and 22 or less, more preferably a carbon number of 16. Above 20 alkyl groups. (vii) Alkylaminoalkyldimethylamine and its salt The alkyl group is preferably an alkyl group having a carbon number of 11 or more and 21 or less, and more preferably a carbon number of 15 or more and 19 or less.

The amines of (v) to (vii) can be preliminarily reacted with an acid to form a salt and be formulated in the hair cosmetic composition, and can also be directly formulated as an amine in the hair cosmetic composition, and then in the hair cosmetic composition The acid is formulated in the medium, thereby forming a salt in the composition. Therefore, here, the above-mentioned amines and their salts are defined as cationic surfactants. In addition, the content or blending amount is converted into the mass of the above-mentioned amine. As the salt of the amine of (v) to (vii), a salt obtained with an organic acid or an inorganic acid can be mentioned. Examples of organic acids include monocarboxylic acids such as acetic acid and propionic acid; dicarboxylic acids such as malonic acid, succinic acid, glutaric acid, adipic acid, maleic acid, fumaric acid, and phthalic acid; Polycarboxylic acids such as polyglutamic acid; hydroxycarboxylic acids such as glycolic acid, lactic acid, hydroxyacrylic acid, glyceric acid, malic acid, tartaric acid, and citric acid; acidic amino acids such as glutamic acid and aspartic acid. As an inorganic acid, hydrochloric acid, sulfuric acid, phosphoric acid, etc. are mentioned, for example. Among these, organic acids are preferred, and one or more selected from the group consisting of dicarboxylic acids, hydroxycarboxylic acids, and acidic amino acids are more preferred. The dicarboxylic acid is more preferably one or more selected from the group consisting of maleic acid and succinic acid. The hydroxycarboxylic acid is more preferably at least one selected from the group consisting of glycolic acid, lactic acid, and malic acid. As the acidic amino acid, glutamic acid is more preferred.

(V) Alkyldimethylamine and its salts include N,N-dimethylbehenylamine, N,N-dimethylstearylamine, and organic acid salts thereof, preferably The lactate of N,N-dimethylbehenamine, the glycolate of N,N-dimethylstearylamine, etc.

(Vi) Alkoxyalkyldimethylamine and its salts include N,N-dimethyl-3-hexadecyloxypropylamine, N,N-dimethyl-3-dec Octaalkoxypropylamine, and its organic acid salt, preferably N,N-dimethyl-3-hexadecyloxypropylamine or its salt, N,N-dimethyl-3 -Stearyloxypropylamine (stearyloxypropyldimethylamine) or a salt thereof.

Examples of (vii) alkylamidoalkyldimethylamine and its salts include N-[3-(dimethylamino)propyl]erucamide and N-[3-(dimethylamine) Base) propyl] stearylamine, and its organic acid salts, preferably N-[3-(dimethylamino)propyl] erucamide lactate, N-[3-(di (Methylamino)propyl]stearylamine glycolate.

Component (A) can use 1 type or 2 or more types. Among the above, from the viewpoints of improving low-temperature stability, improving hair protection during coating, imparting smoothness during rinsing, and suppressing tangling, as component (A), it is preferably selected from the group consisting of (i) alkyl Trimethylammonium salt, (ii) alkoxyalkyltrimethylammonium salt, (iii) dialkyldimethylammonium salt, (iv) alkylamidoalkyltrimethylammonium salt, (v ) Alkyl dimethyl amine and its salt, (vi) alkoxy alkyl dimethyl amine and its salt, and (vii) alkyl amido alkyl dimethyl amine and its salt One or more of them are more preferably one or more selected from the group consisting of (i) alkyl trimethyl ammonium salt and (iv) alkyl amidoalkyl trimethyl ammonium salt.

From the viewpoints of improving low-temperature stability, improving hair protection during application, and imparting smoothness and inhibiting tangling during washing, the content or blending amount of component (A) in the hair cosmetic composition is preferably 0.08 Mass% or more, more preferably 0.10 mass% or more, still more preferably 0.50 mass% or more, and preferably 5 mass% or less, more preferably 4 mass% or less, and still more preferably 3 mass% or less. More specifically, the content or blending amount of the component (A) in the hair cosmetic composition is preferably 0.08 to 5% by mass, more preferably 0.08 to 4% by mass, still more preferably 0.08 to 3% by mass, and further It is more preferably 0.10 to 3% by mass, and still more preferably 0.50 to 3% by mass.

<Component (B): Amphoteric surfactant> The hair cosmetic composition contains or blends an amphoteric surfactant as the component (B) (hereinafter simply referred to as "(B)"). As an amphoteric surfactant, a betaine type surfactant, an amine oxide type surfactant, an amino acid type surfactant, etc. are mentioned. Among these, from the viewpoints of improving low-temperature stability, improving foam quality, improving hair protection during application, and imparting smoothness during rinsing and suppressing tangles, betaine-type surfactants are preferred.

Examples of betaine-type surfactants include: alkyl dimethylamino acetic acid betaine, fatty amine propyl betaine, and other carboxy betaine types; alkyl sultaines, alkyl hydroxy sultaines And other sulfobetaine type; imidazoline betaine type; phosphate betaine type, etc.

As the alkyl dimethylamino acetic acid betaine, one having an alkyl group having preferably a carbon number of 8 or more and 22 or less, and more preferably a carbon number of 10 or more and 20 or less can be mentioned. As a specific example, a lauryl group can be mentioned. Betaine dimethylaminoacetate, betaine stearyl dimethylaminoacetate, etc. As the fatty amidopropyl betaine, those having an acyl group having preferably a carbon number of 8 or more and 18 or less, and more preferably a carbon number of 10 or more and 16 or less can be mentioned. As a specific example, lauramidopropyl betaine (lauramidopropyl betaine), palm kernel oil fatty acid amidopropyl betaine, coconut oil fatty acid amidopropyl betaine (coco amidopropyl betaine) can be mentioned as specific examples. Betaine) and so on.

As the alkyl sultaine, an alkyl sultaine having an alkyl group having preferably a carbon number of 8 or more and 22 or less, and more preferably a carbon number of 10 or more and 18 or less can be mentioned. Specific examples of alkyl sulfobetaine include lauryl dimethyl sulfoethyl betaine, lauryl dimethyl sulfopropyl betaine, myristyl dimethyl sulfoethyl betaine, and myristyl sulfoethyl betaine. Dimethyl sulfopropyl betaine, stearyl dimethyl sulfoethyl betaine, stearyl dimethyl sulfopropyl betaine, coco fatty acid dimethyl sulfopropyl betaine, etc.

The alkylhydroxysulfobetaine may, for example, be an alkylhydroxysulfo group having an alkyl group having preferably a carbon number of 8 or more and 22 or less, more preferably a carbon number of 10 or more and 18 or less, and having at least one hydroxyl group. Betaine. As specific examples of alkyl hydroxy sulfobetaines, lauryl dimethyl sulfo (hydroxyethyl) betaine, lauryl dimethyl sulfo (hydroxypropyl) betaine [lauryl hydroxy sulfo Betaine], myristyl dimethyl sulfo (hydroxyethyl) betaine, myristyl dimethyl sulfo (hydroxypropyl) betaine, stearyl dimethyl sulfo (hydroxypropyl) betaine Alkali, bis-(2-hydroxy-ethyl)sulfoethyl betaine, lauryl bis-(2-hydroxy-ethyl)sulfopropyl betaine, etc. Among these, lauryl dimethyl sulfo (hydroxypropyl) betaine [lauryl hydroxy sultaine] represented by the following formula is preferred. [化1]

As the imidazoline betaine type, 2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine may be mentioned, and as a specific example, coco amphoteric sodium acetate etc. may be mentioned. The phosphate betaine type may, for example, be lauryl hydroxy phosphate betaine.

Component (B) can use 1 type or 2 or more types. Among the above, from the viewpoints of improving low-temperature stability, improving foam quality, improving hair protection during application, and imparting smoothness during rinsing and suppressing tangling, the component (B) is more preferably selected from the group consisting of carboxyl groups. One or more of the group consisting of betaine type, sultaine type and imidazoline type betaine type, and more preferably selected from the group consisting of alkyl dimethylamino acetate betaine and fatty amide propyl betaine , Alkyl sultaines, alkyl hydroxy sultaines, and 2-alkyl-N-carboxymethyl-N-hydroxyethyl imidazolinium betaines, and more It is preferably 1 selected from the group consisting of fatty amidopropyl betaine, alkyl hydroxy sultaine, and 2-alkyl-N-carboxymethyl-N-hydroxyethyl imidazolinium betaine More than species.

From the viewpoints of improving low temperature stability, improving foam quality, improving hair protection during application, and imparting smoothness and inhibiting tangling during washing, the content or blending amount of component (B) in the hair cosmetic composition It is preferably 0.08% by mass or more, more preferably 0.10% by mass or more, still more preferably 0.50% by mass or more, still more preferably 1% by mass or more, and preferably 15% by mass or less, more preferably 12% by mass or less It is more preferably 10% by mass or less, still more preferably 8% by mass or less, and still more preferably 5% by mass or less. More specifically, the content or blending amount of the component (B) in the hair cosmetic composition is preferably 0.08-15% by mass, more preferably 0.08-12% by mass, still more preferably 0.08-10% by mass, and further It is more preferably 0.10 to 10% by mass, still more preferably 0.50 to 8% by mass, still more preferably 0.50 to 5% by mass, and still more preferably 1 to 5% by mass.

From the viewpoint of improving low-temperature stability, improving foam quality, improving the protection of hair by foam during application, and imparting smoothness and inhibiting tangling during washing, the ingredients in the hair cosmetic composition ( The mass ratio [(B)/(A)] of the content or blended amount of B) relative to the content or blended amount of component (A) is 0.4 or more, preferably 0.7 or more, more preferably 1.0 or more, and still more preferably 1.5 or more, more preferably 1.7 or more, and 5 or less, preferably 4.5 or less, more preferably 4.0 or less, still more preferably 3.5 or less, and still more preferably 3.0 or less. More specifically, the range of the above-mentioned mass ratio [(A)/(B)] is preferably 0.7 to 4.5, more preferably 1.0 to 4.0, still more preferably 1.5 to 3.5, and still more preferably 1.7 to 3.0.

＜(C) Ingredient＞ The hair cosmetic composition contains or blends selected from the group consisting of nonionic surfactants (C1), modified silicones with cationic groups (C2), and sugar alcohols with 4 or more carbons (C3) One or more of them are used as ingredient (C). By using ingredient (C) in addition to ingredient (A) and ingredient (B), the protection of the hair during application can be improved, the hair can be given good smoothness during washing, and the tangling of the hair can be suppressed.

[(C1) Ingredient: Non-ionic surfactant] As the (C1) component, that is, the nonionic surfactant (hereinafter simply referred to as "component (C1)" or "(C1)"), polyoxyalkylene alkyl ether and polyoxyalkylene alkenyl can be mentioned Ether, polyoxyalkylene sorbitan fatty acid ester, polyoxyalkylene fatty acid ester, alkyl glucoside, alkyl alkanolamide, alkyl glycerol ether, higher fatty acid sucrose ester, polyglycerin fatty acid ester , Polyoxyethylene hydrogenated castor oil, alkyl sugar, etc.

Among the above, from the viewpoints of improving hair protection during application, imparting smoothness during washing, and inhibiting tangling, as component (C1), it is preferably selected from polyoxyalkylene alkyl ethers and polyoxyalkylene ethers. The group consisting of oxyalkylene ether, polyoxyalkylene sorbitan fatty acid ester, polyoxyalkylene fatty acid ester, alkyl glucoside, alkyl alkanol amide, and alkyl glycerol ether One or more of these, more preferably one or more selected from the group consisting of polyoxyalkylene alkyl ethers, alkyl glucosides, alkyl alkanol amides, and alkyl glyceryl ethers. Polyoxyalkylene alkyl ether, alkyl glucoside, alkyl alkanol amide, alkyl glycerol ether, and alkyl in alkyl sugar, alkenyl in polyoxyalkylene ether, and poly The fatty acid in the oxyalkylene sorbitan fatty acid ester, polyoxyalkylene fatty acid ester, sucrose higher fatty acid ester, and polyglycerin fatty acid ester preferably has a carbon number of 8 or more and 22 or less, more preferably a carbon number of 8 or more and 18 or less.

As the polyoxyalkylene alkyl ether, an alkyl group having preferably a carbon number of 8 or more and 22 or less, more preferably a carbon number of 8 or more and 18 or less, and still more preferably a carbon number of 8 or more and 12 or less , Polyoxyethylene alkyl ether or polyoxypropylene alkyl ether. As specific examples thereof, "Emulgen 103" (Laureth-3: PEG (Polyethylene Glycol, polyethylene glycol)-3 lauryl ether) manufactured by Kao Co., Ltd., and "Emulgen 116" (Polyethylene Glycol) can be mentioned. Ether-16: PEG-16 lauryl ether), "Emulgen 306P" (steareth-6: polyoxyethylene (6) stearyl ether), "KAO SOFCARE GP-1" (PPG-3 octyl ether), etc. . As the alkyl glucoside, an alkyl glucose having an alkyl group having preferably a carbon number of 8 or more and 22 or less, more preferably a carbon number of 8 or more and 18 or less, and still more preferably a carbon number of 8 or more and 12 or less As specific examples of glycosides, "Mydol 10" (decyl glucoside) manufactured by Kao Co., Ltd., "AG-124" (lauryl glucoside), and the like can be mentioned. As the alkyl alkanol amine, a fatty acid having an acyl group having preferably a carbon number of 8 or more and 22 or less, more preferably a carbon number of 8 or more and 18 or less, and still more preferably a carbon number of 8 or more and 12 or less Ethanolamide or fatty acid diethanolamide, as specific examples thereof, "AMINON PK-02S" (palm kernel oil fatty acid diethanolamide) manufactured by Kao Co., Ltd., and "AMINON L-02" (lauric acid Diethanolamide), "AMINON C-11S" (coconut oil fatty acid N-methylethanolamide), etc. As the alkyl glycerol ether, an alkyl glycerol having an alkyl group having preferably a carbon number of 8 or more and 22 or less, more preferably a carbon number of 8 or more and 18 or less, and still more preferably a carbon number of 8 or more and 12 or less As a specific example of the ether, "PENETOL GE-ID" (isodecyl glyceryl ether) manufactured by Kao Co., Ltd. can be cited. Component (C1) can use 1 type or 2 or more types.

From the viewpoints of improving hair protection during application, imparting smoothness during rinsing, and suppressing tangles, the content or blending amount of the component (C1) in the hair cosmetic composition is preferably 0.08% by mass or more, and more It is preferably 0.10% by mass or more, more preferably 0.30% by mass or more, more preferably 6% by mass or less, more preferably 4% by mass or less, and still more preferably 2% by mass or less. More specifically, the content or blending amount of the component (C1) in the hair cosmetic composition is preferably 0.08-6 mass%, more preferably 0.10-4 mass%, and still more preferably 0.30-2 mass%.

From the viewpoints of improving hair protection during application, imparting smoothness and suppressing tangling during washing, the total content or total blending amount of the component (A) and component (B) in the hair cosmetic composition is relative to The content of component (C1) or the mass ratio of the blended amount [[(A)+(B)]/(C1)] (hereinafter referred to as "mass ratio [[(A)+(B)]/(C1)] ") is preferably 0.1 or more, more preferably 0.5 or more, still more preferably 1 or more, still more preferably 3 or more, and preferably 25 or less, more preferably 20 or less, still more preferably 15 or less, and still more Preferably, it is 10 or less. More specifically, the range of the mass ratio [[(A)+(B)]/(C1)] is preferably 0.1-25, more preferably 0.5-20, still more preferably 1-15, and still more preferably 3～10.

[Component (C2): Modified silicone with cationic group] Component (C2) is a modified silicone with a cationic group (hereinafter referred to as "component (C2)" or "(C2)") is a modified silicone with a cationic group introduced, preferably in polysilicon Modified silicone with cationic group on the side chain or end of the oxane skeleton. Here, the cationic group refers to a cationic group, or a group that can be ionized to become a cationic group. Specifically, a primary amino group, a secondary amino group, a tertiary amino group, and a quaternary ammonium group can be mentioned. From the viewpoints of improving hair protection during application, imparting smoothness during rinsing, and suppressing tangles, the nitrogen content of component (C2) is preferably 0.1% by mass or more, more preferably 0.2% by mass or more, and further It is preferably 0.5% by mass or more, still more preferably 0.8% by mass or more, and more preferably 2.5% by mass or less, more preferably 2.0% by mass or less, still more preferably 1.8% by mass or less, and still more preferably 1.5% by mass the following. More specifically, the range of the nitrogen content of the component (C2) is preferably 0.1 to 2.5% by mass, more preferably 0.2 to 2.0% by mass, still more preferably 0.5 to 1.8% by mass, and still more preferably 0.8 to 1.5 quality%. The nitrogen content of component (C2) is a value measured in accordance with the potentiometric titration method specified in JIS K0113:2005.

[式(1-1)中，R¹¹ 表示碳數為1以上6以下之一價烴基。R¹² 表示R¹¹ 或E。E表示藉由-R¹³ -Z(R¹³ 表示單鍵、或碳數為1以上20以下之二價烴基，Z表示含有一級～三級胺基之基)所表示之一價基。Y表示碳數為1以上6以下之伸烷基。a表示2以上之數，b表示1以上之數，c表示4以上100以下之數，d表示1以上之數。n表示2以上10以下之數。括號內之結構單元彼此之鍵結順序不限，鍵結形態可為嵌段狀或無規狀。c個C_n H_2n O可相同亦可不同。又，複數個R¹¹ 、R¹² 、及E可相同亦可不同]From the viewpoints of improving hair protection during coating, imparting smoothness and inhibiting tangling during washing, component (C2) is preferably selected from the group consisting of amino polyether modified silicone and quaternary ammonium cation modified One or more of the group consisting of sex silicones. More specifically, the amino polyether modified silicone is preferably an amino polyether modified silicone having a structure represented by the following general formula (1-1). [化2]

[In the formula (1-1), R ¹¹ represents a monovalent hydrocarbon group having a carbon number of 1 or more and 6 or less. R ¹² represents R ¹¹ or E. E represents a ^{monovalent group represented by -R 13} -Z (R ¹³ represents a single bond or a divalent hydrocarbon group with a carbon number of 1 or more and 20 or less, and Z represents a group containing primary to tertiary amino groups). Y represents an alkylene group having a carbon number of 1 or more and 6 or less. a represents a number of 2 or more, b represents a number of 1 or more, c represents a number of 4 or more and 100 or less, and d represents a number of 1 or more. n represents the number of 2 or more and 10 or less. The bonding sequence of the structural units in the brackets is not limited, and the bonding form can be block or random. The c C _n H _2n O may be the same or different. Also, a plurality of R ¹¹ , R ¹² , and E may be the same or different]

In the general formula (1-1), R ^{11 is} preferably each independently an alkyl group having a carbon number of 1 to 6 or a phenyl group, more preferably a methyl group or an ethyl group, and still more preferably a methyl group. In the general formula (1-1), R ¹² represents R ¹¹ or E. E represents a ^{monovalent group represented by -R 13} -Z (R ¹³ represents a single bond or a divalent hydrocarbon group having 1 or more and 20 or less carbon atoms). R ^{13 is} preferably a divalent hydrocarbon group having a carbon number of 1 or more and 20 or less, more preferably an alkylene group having a carbon number of 1 or more and 20 or less, and more preferably a linear or branched chain having a carbon number of 1 or more and 6 or less The alkylene group is more preferably a methylene group, an ethylene group, a trimethylene group, a propylene group, a tetramethylene group, or a hexamethylene group, and even more preferably a trimethylene group or a propylene group.

Z is a group containing primary to tertiary amino groups, preferably by -N(R ¹⁴ ) ₂ , -NR ¹⁴ (CH ₂ ) _m N(R ¹⁴ ) ₂ , or -NR ¹⁴ (CH ₂ ) _m N (R ¹⁵ ) An amino group-containing group represented by CO-R ^16. Among them, R ¹⁴ and R ¹⁵ each independently represent a hydrogen atom or an alkyl group having a carbon number of 1 or more and 3 or less, preferably a hydrogen atom or a methyl group. R ¹⁶ represents an alkyl group having 1 or more and 3 or less carbon atoms. m represents a number of 1 or more and 6 or less, preferably a number of 2 or more and 4 or less.

In the general formula (1-1), E is preferably -(CH ₂ ) ₃ -NH ₂ , -(CH ₂ ) ₃ -N(CH ₃ ) ₂ , -(CH ₂ ) ₃ -NH-(CH ₂ ) ₂ -NH ₂ , or -(CH ₂ ) ₂ -NH-(CH ₂ ) ₂ -N(CH ₃ ) ₂ , more preferably -(CH ₂ ) ₃ -NH-(CH ₂ ) ₂ -NH ₂ .

In the general formula (1-1), Y is preferably ethylene, propylene, trimethylene, n-butylene (tetramethylene) or isobutylene, more preferably n-butylene or isobutylene Butyl. The isobutylene group referred to here includes -CH(CH ₃ )CH ₂ CH ₂ -, -CH ₂ CH(CH ₃ )CH ₂ -, and -CH ₂ CH ₂ CH(CH ₃ )-.

In the general formula (1-1), a represents a number of 2 or more, b represents a number of 1 or more, c represents a number of 4 or more and 100 or less, and d represents a number of 1 or more. a is preferably a number of 2 or more and 1000 or less, and more preferably a number of 2 or more and 100 or less. b is preferably 1 or more and 50 or less, c is preferably 4 or more and 50 or less, more preferably 10 or more and 18 or less, and d is preferably 2 or more and 100 or less.

In the general formula (1-1), n represents a number of 2 or more and 10 or less, preferably 2 or more and 6 or less, more preferably 2 or more and 4 or less.

[式(1-2)中，a～d與上述相同]The amino polyether modified silicone is more preferably an amino polyether modified silicone having a structure represented by the following general formula (1-2). [化3]

[In formula (1-2), a to d are the same as above]

The amino polyether-modified silicone can be used singly or in combination of two or more kinds. As the amino polyether modified silicone, commercially available amino polyether modified silicone can also be used. For example, as an amino polyether-modified silicone having a repeating unit represented by the general formula (1-2), "SILSTYLE 104" manufactured by Dow Toray (stock) ((bis-isobutyl PEG-14/ Amino-terminated dimethylpolysiloxane copolymer, nitrogen content: 1.2% by mass), "DOWSIL SS-3588" ((bisisobutyl PEG-15/amino-terminated dimethylpolysiloxane) Alkyl) copolymer, nitrogen content rate: 1.0% by mass), "SILSTYLE 401" ((bisisobutyl PEG/PPG-20/35/amino-terminated dimethyl polysiloxane) copolymer, nitrogen content rate : 0.2% by mass), "SILSTYLE 201" ((bis-isobutyl PEG-14/amino-terminated dimethyl polysiloxane) copolymer, nitrogen content: 1.2% by mass), etc.

[式(2-1)中，R²¹ 表示碳數為1以上6以下之一價烴基。R²² 表示氫原子、碳數為1以上20以下之烴基、或碳數為1以上20以下之包含醯胺鍵之烴基。L表示二價有機基。Q^- 係四級銨離子之抗衡離子。r表示2以上之數，s表示1以上之數。括號內之結構單元彼此之鍵結順序不限，鍵結形態可為嵌段狀或無規狀。又，複數個R²¹ 及R²² 可相同亦可不同] [化5]

[式(2-2)中，R²¹ 、R²² 、L、Q^- 及r與上述相同]More specifically, the quaternary ammonium cation-modified silicone is preferably a side chain type quaternary ammonium cation-modified silicone having a structure represented by the following general formula (2-1), or having the following general formula ( 2-2) The end-capped quaternary ammonium cation modified silicone of the structure shown. [化4]

[In formula (2-1), R ²¹ represents a monovalent hydrocarbon group having a carbon number of 1 or more and 6 or less. R ²² represents a hydrogen atom, a hydrocarbon group having a carbon number of 1 or more and 20 or less, or a hydrocarbon group having a carbon number of 1 or more and 20 or less including an amide bond. L represents a divalent organic group. Q ^- is the counter ion of the quaternary ammonium ion. r represents a number of 2 or more, and s represents a number of 1 or more. The bonding sequence of the structural units in the brackets is not limited, and the bonding form can be block or random. Also, a plurality of R ²¹ and R ²² may be the same or different] [化5]

[In formula (2-2), R ²¹ , R ²² , L, Q ^- and r are the same as above]

In the general formulas (2-1) and (2-2), R ^{21 is} preferably each independently an alkyl group having 1 to 6 carbon atoms, or a phenyl group, more preferably a methyl group or an ethyl group, and further Preferably it is methyl. In the general formulae (2-1) and (2-2), R ^{22 is} preferably a hydrocarbon group with a carbon number of 1 or more and 20 or less, or a hydrocarbon group with a carbon number of 1 or more and 20 or less containing an amide bond, and there are plural At least one of R ²² is more preferably a hydrocarbon group containing an amide bond with a carbon number of 1 or more and 20 or less.

In the general formulas (2-1) and (2-2), L is preferably * ¹ -R ²³ -CH ₂ -CHOH-CH ₂ -* ² . Among them, R ²³ is a divalent organic group, preferably an alkylene group having 1 to 20 carbon atoms, or an oxyalkylene group having 1 to 20 carbon atoms. * ¹ indicates the bonding site with silicon atom, and * ² indicates the bonding site with nitrogen atom.

In the general formula (2-1), r is preferably a number of 2 or more and 200 or less, and more preferably a number of 2 or more and 50 or less. s is preferably a number of 1 or more and 50 or less, more preferably a number of 2 or more and 20 or less, and still more preferably a number of 2 or more and 10 or less. In the general formula (2-2), r is preferably a number of 2 or more and 200 or less, and more preferably a number of 2 or more and 100 or less.

In the general formulas (2-1) and (2-2), Q- means: chloride ions, bromide ions, and other halide ions; alkyl sulfate ions, acetate ions, and lactic acid ions with a carbon number of 1 to 3 , Benzoic acid ion, adipic acid ion, formate ion, malate ion, glycolic acid ion and other organic acid ions; and other anions. Among them, lactic acid ion is preferred.

[式(2-3)中，R²¹ 、R²² 、L、Q^- 及r與上述相同。R²⁴ 表示碳數為1以上6以下之烷基、或苯基。R²⁵ 表示碳數為1以上20以下之烴基、或碳數為1以上20以下之包含醯胺鍵之烴基]The blocked quaternary ammonium cation modified silicone is more preferably a quaternary ammonium cation modified silicone having a structure represented by the following general formula (2-3). [化6]

[In formula (2-3), R ²¹ , R ²² , L, Q ^- and r are the same as above. R ²⁴ represents an alkyl group having a carbon number of 1 to 6 or a phenyl group. R ²⁵ represents a hydrocarbon group with a carbon number of 1 or more and 20 or less, or a hydrocarbon group with a carbon number of 1 or more and 20 or less containing an amide bond]

In the general formula (2-3), R ^{21 is} preferably each independently an alkyl group having a carbon number of 1 to 6 or a phenyl group, more preferably a methyl group or an ethyl group, and still more preferably a methyl group. In the general formula (2-3), R ^{22 is} preferably a hydrocarbon group having a carbon number of 1 or more and 20 or less, and more preferably a methyl group. In the general formula (2-3), R ²⁴ is an alkyl group having a carbon number of 1 to 6 or a phenyl group, preferably a phenyl group. In the general formula (2-3), Q ^-is preferably a lactic acid ion, and r is preferably a number of 2 or more and 200 or less, and more preferably a number of 2 or more and 100 or less.

In the general formula (2-3), R ^{25 is} preferably a hydrocarbon group having a carbon number of 1 or more and 20 or less, or a hydrocarbon group having a carbon number of 1 or more and 20 or less including an amide bond, more preferably a carbon number of 1 or more and 20 The following hydrocarbon groups containing amide bonds are more preferably -R ²⁶ -NHCO-R ²⁷ . Among them, R ²⁶ is an alkylene or oxyalkylene having 1 to 18 carbon atoms, preferably an alkylene having 1 to 18 ^{carbon atoms, and R 27} is an alkylene having 1 to 18 carbon atoms. . In the general formula (2-3), L is preferably * ¹ -R ²³ -CH ₂ -CHOH-CH ₂ -* ² . Among them, R ^{23 is} preferably an alkylene group having a carbon number of 1 to 20, or an oxyalkylene group having a carbon number of 1 to 20, and more preferably an oxyalkylene group having a carbon number of 1 to 20. * ¹ and * ² are the same as above.

As the quaternary ammonium cation modified silicone, quaternary ammonium silicone-1, quaternary ammonium silicone-2, quaternary ammonium silicone-3, quaternary ammonium silicone-4, silicone Ketone quaternary ammonium salt-5, silicone quaternary ammonium salt-6, silicone quaternary ammonium salt-7, silicone quaternary ammonium salt-8, silicone quaternary ammonium salt-9, silicone quaternary ammonium salt -10, silicone quaternary ammonium salt-11, silicone quaternary ammonium salt-12, silicone quaternary ammonium salt-15, silicone quaternary ammonium salt-16, silicone quaternary ammonium salt-17, silicone Quaternary ammonium salt-18, silicone quaternary ammonium salt-20, silicone quaternary ammonium salt-21, silicone quaternary ammonium salt-22, quaternary ammonium salt-80, silicone quaternary ammonium salt-2 pan Alcohol succinate, silicone quaternary ammonium salt-16/glycidyl dimethyl polysiloxane cross-linked polymer, etc.

From the viewpoints of improving hair protection during coating, imparting smoothness during rinsing, and inhibiting tangling, component (C2) preferably contains amino polyether-modified silicone. In this case, amino polyether modified silicone and quaternary ammonium cation modified silicone can be used together as component (C2). When the component (C2) contains an amino polyether modified silicone, the content of the amino polyether modified silicone in the component (C2) is preferably 50% by mass or more, more preferably 70% by mass or more, More preferably, it is 90% by mass or more.

From the viewpoints of improving hair protection during application, imparting smoothness during rinsing, and suppressing tangles, the content or blending amount of the component (C2) in the hair cosmetic composition is preferably 0.08% by mass or more, and more It is preferably 0.10% by mass or more, more preferably 0.15% by mass or more, and more preferably 3% by mass or less, more preferably 2% by mass or less, and still more preferably 1% by mass or less. More specifically, the content or blending amount of the component (C2) in the hair cosmetic composition is preferably 0.08 to 3% by mass, more preferably 0.10 to 2% by mass, and still more preferably 0.15 to 1% by mass.

[Component (C3): Sugar alcohol with 4 or more carbons] As the sugar alcohol of the component (C3), a sugar alcohol having a carbon number of 4 or more, erythritol, xylitol, sorbitol, mannitol, maltitol, lactitol, etc. may be mentioned. Among them, from the viewpoints of improving hair protection during application, imparting smoothness during rinsing, and suppressing tangling, it is preferably one selected from the group consisting of erythritol and mannitol above. From the viewpoints of improving hair protection during application, imparting smoothness and suppressing tangling during rinsing, the content or blending amount of the component (C3) in the hair cosmetic composition is preferably 0.05% by mass or more, and more Preferably it is 0.10% by mass or more, more preferably 0.50% by mass or more, and more preferably 3.0% by mass or less, more preferably 2.5% by mass or less, still more preferably 2.0% by mass or less, still more preferably 1.5% by mass or less . More specifically, the content or blending amount of the component (C3) in the hair cosmetic composition is preferably 0.05 to 3.0% by mass, more preferably 0.10 to 2.5% by mass, still more preferably 0.50 to 2.0% by mass, and further More preferably, it is 0.50 to 1.5% by mass.

In the present invention, the component (C) is not particularly limited, and includes a nonionic surfactant (C1), a modified silicone having a cationic group (C2), and a sugar alcohol with a carbon number of 4 or more ( C3) At least one of the group consisting of is sufficient. From the viewpoints of improving low-temperature stability, improving foam quality, improving hair protection during application, and imparting smoothness during rinsing and suppressing tangles, it is more Preferably, the component (C) contains a nonionic surfactant (C1) (hereinafter referred to as the "first aspect"), or the component (C) contains a modified silicone with a cationic group (C2). ) And one or more aspects of the group consisting of sugar alcohols (C3) with 4 or more carbon atoms (hereinafter referred to as "the second aspect"). The first aspect of the present invention is a hair cosmetic composition containing or blending the following ingredients (A), ingredient (B), and ingredient (C): Ingredient (A): cationic surfactant; Ingredient (B): Amphoteric surfactant; Ingredient (C): Contains non-ionic surfactant (C1); The mass ratio [(B)/(A)] of the content or blended amount of component (B) to the content or blended amount of component (A) is 0.4 to 5, The content or blending amount of higher alcohol is 0.1% by mass or less, The hair cosmetic composition is filled in an airless bubble spray container for use.

In the first aspect, the content or blending amount of the component (C1) in the hair cosmetic composition is as described above. In the first aspect, from the viewpoints of improving low-temperature stability, improving hair protection during application, and imparting good smoothness and inhibiting tangling during washing, the component (A) in the hair cosmetic composition The mass ratio [[(A)+(B)]/(C1)] of the total content or total blended amount of component (B) to the content or blended amount of component (C1) is preferably 0.1 or more, more preferably 0.5 or more, more preferably 1 or more, still more preferably 3 or more, and preferably 25 or less, more preferably 20 or less, still more preferably 15 or less, and still more preferably 10 or less. More specifically, the mass ratio [[(A)+(B)]/(C1)] is preferably 0.1 to 25, more preferably 0.5 to 20, still more preferably 1 to 15, and still more preferably 3 to 10.

In the first aspect, from the viewpoints of improving hair protection during application, imparting smoothness during rinsing, and suppressing tangling, it is preferable that component (C) contains component (C2) in addition to component (C1). ). When component (C) contains component (C1) and component (C2), from the viewpoints of improving hair protection during application, imparting smoothness during rinsing, and suppressing tangles, the hair cosmetic composition The mass ratio of the content or blended amount of the component (C2) to the content or blended amount of the component (C1) [(C2)/(C1)] (hereinafter referred to as "mass ratio [(C2)/(C1)] ") is preferably 0.08 or more, more preferably 0.1 or more, still more preferably 0.2 or more, and preferably 10 or less, more preferably 5 or less, still more preferably 3 or less, and still more preferably 2 or less. More specifically, the mass ratio [(C2)/(C1)] is preferably 0.08-10, more preferably 0.1-5, still more preferably 0.1-3, and still more preferably 0.2-2.

The second aspect of the present invention is a hair cosmetic composition containing or blending the following ingredients (A), ingredient (B), and ingredient (C): Ingredient (A): cationic surfactant; Ingredient (B): Amphoteric surfactant; Component (C): Contains one or more selected from the group consisting of a modified silicone (C2) with a cationic group and a sugar alcohol (C3) with a carbon number of 4 or more; The mass ratio [(B)/(A)] of the content or blended amount of component (B) to the content or blended amount of component (A) is 0.4 to 5, The content or blending amount of higher alcohol is 0.1% by mass or less, The hair cosmetic composition is filled in an airless bubble spray container for use.

In the second aspect, from the viewpoints of improving low-temperature stability, improving hair protection during application, imparting good smoothness during washing, and suppressing tangles, the ingredients in the hair cosmetic composition (C2) The total content or total blending amount of component (C3) is preferably 0.1% by mass or more, more preferably 0.3% by mass or more, still more preferably 0.5% by mass or more, and preferably 5% by mass or less, more preferably 3 % By mass or less, more preferably 2% by mass or less. More specifically, the total content or total blending amount of the component (C2) and the component (C3) in the hair cosmetic composition is preferably 0.1-5 mass%, more preferably 0.3-3 mass%, and still more preferably 0.5-2% by mass. In the second aspect, from the viewpoints of improving low-temperature stability, improving hair protection during application, imparting smoothness during rinsing, and suppressing tangles, the ingredients (A) and ingredients in the hair cosmetic composition The mass ratio of the total content or total blended amount of (B) to the total content or total blended amount of component (C2) and component (C3) [[(A)+(B)]/[(C2)+(C3) ]] (hereinafter simply referred to as "mass ratio [[(A)+(B)]/[(C2)+(C3)]]") is preferably 0.1 or more, more preferably 0.3 or more, and even more preferably 1 Above, and preferably 40 or less, more preferably 35 or less, still more preferably 30 or less, still more preferably 20 or less, and still more preferably 15 or less. More specifically, the mass ratio [[(A)+(B)]/[(C2)+(C3)]] is preferably 0.1-40, more preferably 0.3-35, and still more preferably 1-30, It is still more preferably 1-20, and still more preferably 1-15.

In the second aspect, from the viewpoints of improving low-temperature stability, improving hair protection during application, imparting smoothness during rinsing, and suppressing tangles, component (C) can be used in combination with component (C2) and component ( C3). That is, when the component (C) contains the component (C2) and the component (C3), from the viewpoints of improving low-temperature stability, improving hair protection during application, and imparting smoothness during rinsing and suppressing tangling , The mass ratio [(C3)/(C2)] of the content or blending amount of the component (C3) in the hair cosmetic composition relative to the content or blending amount of the component (C2) (hereinafter simply referred to as "mass ratio [( C3)/(C2)]") is preferably 0.08 or more, more preferably 0.5 or more, still more preferably 1 or more, and preferably 10 or less, more preferably 5 or less, and still more preferably 3 or less. More specifically, the mass ratio [(C3)/(C2)] is preferably 0.08-10, more preferably 0.5-5, and still more preferably 1-3.

The total content or total blending amount of component (A), component (B), and component (C) in the hair cosmetic composition is preferably 0.2% by mass or more, more preferably 0.3% by mass or more, and still more preferably 0.5 Mass% or more, more preferably 1 mass% or more, and preferably 20 mass% or less, more preferably 15 mass% or less, and still more preferably 10 mass% or less. More specifically, the total content or total blending amount of component (A), component (B), and component (C) in the hair cosmetic composition is preferably 0.2-20% by mass, more preferably 0.3-15% by mass %, more preferably 0.5-10% by mass, still more preferably 1-10% by mass.

＜Higher alcohols＞ In the hair cosmetic composition of the present invention, the content or blending amount of the higher alcohol is 0.1% by mass or less. This improves low-temperature stability and foam quality. From this viewpoint, the content or blending amount of the higher alcohol in the hair cosmetic composition is preferably 0.06% by mass or less, more preferably 0.03% by mass or less, and even more preferably 0% by mass. The carbon number of the higher alcohol is preferably 12 or more and 22 or less. As this higher alcohol, cetyl alcohol, oleyl alcohol, stearyl alcohol, isostearyl alcohol, 2-octyldodecanol, myristyl alcohol, behenyl alcohol, cetearyl alcohol, etc. are mentioned. These higher alcohols may contain one type or two or more types in an amount that satisfies the range of the above-mentioned content or blended amount. Furthermore, when two or more higher alcohols are used in combination as the higher alcohols, the content or blending amount of the higher alcohols in the hair cosmetic composition is the total content or blending amount of the higher alcohols.

<Component (D): Anionic surfactant> The hair cosmetic composition may further contain or blend an anionic surfactant (hereinafter simply referred to as "component (D)" or "(D)") as a component (D). As component (D), for example, alkylbenzene sulfonate, alkyl or alkenyl ether sulfate, alkyl or alkenyl sulfate, alkyl sulfonate, saturated or unsaturated fatty acid salt, alkyl Or alkenyl ether carboxylate, α-sulfo fatty acid salt, N-amino acid, phosphoric acid mono- or diester, sulfosuccinate, etc. Among them, one or two or more can be used. As the counter ion of the anionic group of component (D), for example, alkali metal ions such as sodium ion and potassium ion; alkaline earth metal ions such as calcium ion and magnesium ion; ammonium ion; Or 3 alkanol ammonium (for example, monoethanolammonium, diethanolammonium, triethanolammonium, triisopropoxide, etc.). Component (D) is preferably one or more selected from the group consisting of alkyl sulfate, alkyl ether sulfate, and alkyl ether carboxylate. Examples of the alkyl ether sulfates include polyoxyethylene alkyl ether sulfates such as sodium laureth sulfate, and the alkyl ether carboxylates include polyoxyethylene such as sodium laureth acetate. Alkyl ether acetate. Component (D) is more preferably one or more selected from the group consisting of alkyl ether sulfates and alkyl ether carboxylates, and more preferably selected from polyoxyethylene alkyl ether sulfates and polyoxyethylene alkyls One or more of the group consisting of base ether acetate.

When the hair cosmetic composition contains or blends the ingredient (D), the content or blending amount of the ingredient (D) in the hair cosmetic composition is preferably 0.005% by mass or more, more preferably 0.01% by mass or more , More preferably 0.02% by mass or more, more preferably 3% by mass or less, more preferably 1% by mass or less, still more preferably 0.5% by mass or less, and still more preferably 0.1% by mass or less. More specifically, the content or blending amount of the component (D) in the hair cosmetic composition is preferably 0.005 to 3% by mass, more preferably 0.01 to 1% by mass, and still more preferably 0.01 to 0.5% by mass, and further It is more preferably 0.01 to 0.1% by mass, and still more preferably 0.02 to 0.1% by mass.

＜Cationic polymer＞ From the viewpoints of hair protection at the time of application, smoothness imparting at the time of rinsing, and reduction of tangles, the hair cosmetic composition may further contain or be formulated with a cationic polymer. In the present invention, "cationic polymer" refers to a water-soluble polymer having a cationic group and cationic charge as a whole, and the cationic group is as described above.

Examples of the cationic polymer include: cationized guar gum, cationized tara gum, cationized locust bean gum, etc., cationized galactomannan; cationized cellulose; cationized hydroxyethyl Cellulose, cationized hydroxypropyl cellulose, etc., cationized hydroxyalkyl cellulose; cationic starch; cationized polyvinyl alcohol; Vinylpyrrolidone/N,N-dimethylaminoethylmethacrylate diethylsulfate copolymer, N,N-dimethylaminoethylmethacrylate diethylsulfate/N,N- Dimethacrylamide/polyethylene glycol dimethacrylate copolymer, etc., quaternized dialkylaminoalkyl (meth)acrylate polymer; Polydiallyldimethylammonium chloride, diallyldimethylammonium chloride/acrylic acid copolymer, diallyldimethylammonium chloride/acrylamide copolymer, diallyl chloride Dimethylammonium/acrylic acid/acrylamide copolymer, etc., diallyl quaternary ammonium salt polymer; Vinyl imidazolium trichloride/vinyl pyrrolidone copolymer; vinyl pyrrolidone/(meth)acrylic acid alkylamino alkyl ester copolymer; vinyl pyrrolidone/(meth)acrylic acid alkyl amino group Alkyl ester/vinyl caprolactam copolymer; vinyl pyrrolidone/(meth)acrylamidopropyl trimethylammonium chloride copolymer; alkyl acrylamide/(meth)acrylate /Alkylaminoalkylacrylamide/polyethylene glycol (meth)acrylate copolymer; adipic acid/dimethylaminohydroxypropyl ethylenetriamine copolymer; and, Cationic polymers and the like described in Japanese Patent Laid-Open No. 53-139734 and Japanese Patent Laid-Open No. 60-36407. One type or two or more types of these can be used for the cationic polymer. Among them, it is preferably selected from the group consisting of cationized galactomannan, cationized hydroxyalkyl cellulose, quaternized dialkylaminoalkyl (meth)acrylate polymer, and diallyl tetra One or more of the group consisting of graded ammonium salt polymers, more preferably selected from the group consisting of cationized guar gum, cationized hydroxyalkyl cellulose, and quaternized dialkylaminoalkyl (meth)acrylic acid One or more of the group consisting of salt polymers.

From the viewpoints of hair protection during coating, smoothness imparting during rinsing, and reduction of tangles, the weight average molecular weight of the cationic polymer is preferably 10,000 or more, more preferably 50,000 or more, and further It is preferably 100,000 or more, and usually 8 million or less. Among them, the weight average molecular weight can be measured, for example, by gel permeation chromatography (GPC) under the following conditions. Moving bed: 50 mM LiBr, 1% CH ₃ COOH/ethanol: water = 3: 7 Column: TSK gel α-M (2 units in series) Standard material: polyethylene glycol

Commercially available cationic polymers can be used for the cationic polymer. For example, the following cationic polymers can be mentioned. (Cationized guar gum) JAGUAR Excel (Solvay (Novecare) company), JAGUAR C-14-S (Solvay-Rhodia company), etc. (Cationized Tara Gum) CATINAL CTR-100 (Toho Chemical Industry Co., Ltd.), etc. (Cationized Locust Bean Gum) CATINAL CLB-100 (Toho Chemical Industry Co., Ltd.), etc. (Cationized hydroxyethyl cellulose) Polyquaternary ammonium salt-10 (o-[2-hydroxy-3-(trimethylammonium)propyl] hydroxyethyl cellulose chloride): such as Ucare Polymer JR-400 (The Dow Chemical Company), POIZ C -60H (Kao (share)), POIZ C-150L (Kao (share)), etc. Polyquaternary ammonium salt-67: SoftCAT (The Dow Chemical Company), etc. (Cationized hydroxypropyl cellulose) SOFCARE C-HP2W (Kao (Stock)) etc. (Cationized polyvinyl alcohol) GOHSENX K-434 (Nippon Synthetic Chemical Industry Co., Ltd.), CM318 (Kuraray Co., Ltd.), etc. (Vinylpyrrolidone/N,N-Dimethylaminoethyl Methacrylate Diethyl Sulfate Copolymer) Polyquaternary ammonium salt-11: Gafquat 734 (ISP JAPAN company), Gafquat 755N (ISP JAPAN company), etc. (N,N-Dimethylaminoethyl Methacrylate Diethyl Sulfate/N,N-Dimethacrylamide/Polyethylene Glycol Dimethacrylate Copolymer) Polyquaternary ammonium salt-52: SOFCARE KG-101W-E (Kao (stock)), etc. (Polydiallyldimethylammonium chloride) Polyquaternary ammonium salt-6: MERQUAT100 (Lubrizol Advanced Materials), etc. (Diallyldimethylammonium chloride/acrylic acid copolymer) Polyquaternary ammonium salt-22: MERQUAT280, MERQUAT295 (above, Lubrizol Advanced Materials), etc. (Diallyldimethylammonium chloride/acrylamide copolymer) Polyquaternary ammonium salt-7: MERQUAT550 (Lubrizol Advanced Materials), etc. (Diallyldimethylammonium chloride/acrylic acid/acrylamide polymer) Polyquaternary ammonium salt-39: MERQUAT3331PR (Lubrizol Advanced Materials), etc.

When the hair cosmetic composition contains or is formulated with the above cationic polymer, the content or blending amount of the cationic polymer in the hair cosmetic composition depends on the hair protection at the time of application and the effect at the time of rinsing. From the viewpoint of imparting smoothness and reducing entanglement, it is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, and even more preferably 0.1% by mass or more, and from the viewpoint of ease of blending, it is more It is preferably 3% by mass or less, more preferably 1% by mass or less, and still more preferably 0.5% by mass or less. More specifically, the range of the content or blending amount of the cationic polymer in the hair cosmetic composition is preferably 0.01-3% by mass, more preferably 0.05-1% by mass, and still more preferably 0.1-0.5% by mass %.

＜Organic acid or inorganic acid＞ From the viewpoint of dissolving ingredients (A), (B), and (C), and the use of alkyl dimethyl amine, alkoxy alkyl dimethyl amine, and alkyl amide in cationic surfactants When amines such as alkyl dimethyl amine are used as the component (A), from the viewpoint of neutralizing these to form a salt, the hair cosmetic composition preferably further contains or blends an organic acid or an inorganic acid. As an organic acid or an inorganic acid, the above-mentioned organic acid or an inorganic acid can be mentioned, Preferably it is an organic acid. The organic acid is preferably at least one selected from the group consisting of dicarboxylic acids, hydroxycarboxylic acids, and acidic amino acids, and more preferably hydroxycarboxylic acids. The dicarboxylic acid is more preferably one or more selected from the group consisting of maleic acid and succinic acid. The hydroxycarboxylic acid is more preferably at least one selected from the group consisting of glycolic acid, lactic acid, and malic acid. As the acidic amino acid, glutamic acid is more preferred.

In the case of using organic acid or inorganic acid, the content or blending amount of the organic acid and inorganic acid in the hair cosmetic composition is preferable from the viewpoint of dissolving the ingredients (A), (B) and (C) It is 0.005% by mass or more, more preferably 0.01% by mass or more, and still more preferably 0.02% by mass or more. From the viewpoint of the stability of the product, it is preferably 10% by mass or less, more preferably 8% by mass or less, and further It is preferably 5% by mass or less, still more preferably 1% by mass or less, and still more preferably 0.5% by mass or less. More specifically, the range of the content or blending amount of the organic acid or inorganic acid in the hair cosmetic composition is preferably 0.005-10% by mass, more preferably 0.01-8% by mass, and still more preferably 0.02-5% by mass %, more preferably 0.02 to 1% by mass, and still more preferably 0.02 to 0.5% by mass. Furthermore, when using amines such as alkyl dimethyl amine, alkoxy alkyl dimethyl amine, and alkyl amido alkyl dimethyl amine as the cationic surfactant of component (A) In order to neutralize these and form a salt, a suitable amount of organic acid or inorganic acid can be appropriately contained or blended.

＜Aqueous medium＞ The hair cosmetic composition usually contains or is formulated with an aqueous medium. The aqueous medium may, for example, be water or an organic solvent. Examples of the organic solvent include lower alcohols such as ethanol and isopropanol; 1,3-butanediol, glycerin, ethylene glycol, propylene glycol, dipropylene glycol, etc., low molecular weight diols with a carbon number of 6 or less, and triglycerides. alcohol. Among them, water is preferred. From the viewpoint of foam quality improvement and foam ejection properties, the content or blending amount of the aqueous medium in the hair cosmetic composition is preferably 60 to 99% by mass, more preferably 70 to 99% by mass.

＜Other ingredients＞ The hair cosmetic composition may appropriately contain or blend other ingredients within a range that does not impair the purpose of the present invention. As the component, for example, antioxidants, oils, anti-dandruff agents, vitamins, bactericides, anti-inflammatory agents, preservatives, chelating agents, and moisturizers, which are normally formulated in hair cosmetics, can be mentioned. , Pearlescent agents, brain amines, fragrances, ultraviolet absorbers, etc.

＜pH value＞ Regarding the pH value of the hair cosmetic composition, from the viewpoint of improving the foam quality, it is preferably 3.0 or more, more preferably 3.1 or more, and still more preferably 3.2 or more in terms of the pH value of a 5% aqueous dispersion. From the viewpoint of hair smoothness and tangling suppression, in terms of the pH value of a 5% aqueous dispersion, it is preferably 7.0 or less, more preferably 6.0 or less, and still more preferably 5.0 or less. More specifically, the pH value of the 5% aqueous dispersion of the hair cosmetic composition is preferably in the range of 3.0 to 7.0, more preferably 3.1 to 6.0, and still more preferably 3.2 to 5.0. The above-mentioned pH value is a measured value at 25°C, and can be specifically measured by the method described in the examples.

＜Viscosity at 30℃＞ Regarding the viscosity of the hair cosmetic composition at 30°C, from the viewpoint of improving foam quality, it is preferably 0.8 mPa·s or more, more preferably 1 mPa·s or more, and still more preferably 2 mPa·s or more It is still more preferably 3 mPa·s or more, and from the viewpoint of bubble ejectability, it is preferably 20 mPa·s or less, more preferably 15 mPa·s or less, and still more preferably 10 mPa·s or less. More specifically, the range of the viscosity of the hair cosmetic composition at 30°C is preferably 0.8-20 mPa·s, more preferably 1-15 mPa·s, and still more preferably 2-10 mPa·s, and further More preferably, it is 3～10 mPa·s. The viscosity at 30°C can be specifically measured by the method described in the examples.

＜Viscosity at 5℃＞ Regarding the viscosity of the hair cosmetic composition at 5°C, from the viewpoint of improving foam quality, it is preferably 1.5 mPa·s or more, more preferably 2 mPa·s or more, and still more preferably 4 mPa·s or more , And more preferably 6 mPa·s or more. From the viewpoint of bubble ejectability, it is preferably 50 mPa·s or less, more preferably 30 mPa·s or less, and still more preferably 20 mPa·s or less, and further More preferably, it is 15 mPa·s or less. More specifically, the range of the viscosity of the hair cosmetic composition at 5°C is preferably 1.5-50 mPa·s, more preferably 2-30 mPa·s, and still more preferably 4-20 mPa·s, and further More preferably, it is 6～15 mPa·s. The above-mentioned viscosity at 5°C can be specifically measured by the method described in the examples.

(Method for manufacturing hair cosmetic composition) The manufacturing method of the hair cosmetic composition is not specifically limited. For example, by mixing ingredients (A) to (C) and other ingredients as necessary by the method described in the examples, and mixing them with a known stirring device, etc., hair cosmetics can be produced combination.

[Hair cosmetics] The hair cosmetic composition of the present invention is preferably used as a hair cosmetic filled in an airless bubble ejection container. Examples of the hair cosmetics include hair cleansers such as shampoos, conditioners, conditioners, care agents (including no-rinse type), styling agents, hair dyes, hair growth agents, and the like. Among them, a conditioner, a conditioning agent, a care agent, or a styling agent is preferred, and a conditioning agent is more preferred. As a gas-free bubble spray container, it can be used as long as it can mix the filled hair cosmetic composition with air in the spray container to spray out in a bubble shape. For example, by pressing the pump head, the cylinder of the air chamber and the cylinder of the hair cosmetic composition are pressurized, and the air is mixed with the hair cosmetic composition to spray the hair cosmetic composition in a bubble shape. Foaming container; squeezing the container body part of the squeezable and deformable container, the container deforms to spray out the hair cosmetic composition squeeze foaming container. From the viewpoint of adjusting the foam quality, it is preferable that the spray flow path of the hair cosmetic composition of the foam spray container is provided with a porous membrane filter such as a mesh. As a specific example of a gas-free bubble ejection container, a foam container manufactured by Yoshino Kogyo Co., Ltd. and Yamato Can Co., Ltd. can be cited. Moreover, the bubble ejection container described in Japanese Patent Laid-Open No. 7-315463, Japanese Patent Laid-Open No. 8-230961, Japanese Patent Laid-Open No. 2005-193972, etc. can also be used.

(How to use hair cosmetics) The method of using the hair cosmetic is not particularly limited as long as it is a method of applying the hair cosmetic in a bubble form to the hair using a bubble spray container. In the method of applying to the hair, the foamed hair cosmetic sprayed from the foaming spray container can be applied to wet hair or dry hair, preferably to wet hair. When the hair cosmetics are conditioners, conditioners, or conditioners, for example, apply the foamed hair cosmetics sprayed from the foaming spray container to the washed hair and fuse the hair after washing as necessary. The method and so on. In the case where the hair cosmetic is a hair cleanser, a method of washing the hair with a foamed hair cosmetic sprayed from a foam spray container can be mentioned. The washing method includes, for example, applying a foam-like hair cosmetic sprayed from a foam spraying container to the hair and rinsing it. The washing method preferably includes applying the foamed hair cosmetic material sprayed from the foam spraying container to the hair and rinsing it, and more preferably includes applying the foamed hair cosmetic material sprayed from the foam spraying container to the hair , To make the applied hair cosmetics foam and rinse. By applying the hair cosmetics to the hair in the form of bubbles, it is easy to cover all the hair during application and can be fully fused with the hair. By using the hair cosmetic of the present invention in the above-mentioned method, the container will not be clogged even when the bubble is sprayed out in a low temperature environment. In addition, the foam with good texture during application can prevent the hair from being caused by contact between the hairs. The damage, and the smoothness of hair can be given to the hair when rinsed, and the tangling of the hair can be suppressed.

The amount of the hair cosmetic applied to the hair is calculated as the mass ratio relative to the quality of the hair (quality of the hair cosmetic/quality of the hair), preferably 0.02 or more, more preferably 0.03 or more, and still more preferably 0.05 or more , And preferably 0.6 or less, more preferably 0.5 or less. The hair to be treated may be at least a part of the hair.

Regarding the above-mentioned embodiment, the present invention discloses the following hair cosmetic composition and hair cosmetic. ＜1＞ A hair cosmetic composition containing or blending the following ingredients (A), ingredient (B), and ingredient (C): Component (A): one or more cationic surfactants selected from the group consisting of alkyl trimethyl ammonium salts and alkyl amide alkyl trimethyl ammonium salts; Ingredient (B): Betaine type surfactant; Component (C): one or more selected from the group consisting of (C1), (C2) and (C3), (C1) is selected from polyoxyalkylene alkyl ether, alkyl glucoside, alkyl One or more nonionic surfactants in the group consisting of alkanolamides and alkyl glycerol ethers, (C2) is selected from amino polyether modified silicones and quaternary ammonium cationic modified silicones One or more modified silicones with cationic groups in the group, (C3) is a sugar alcohol with 4 or more carbons; The mass ratio [(B)/(A)] of the content or blended amount of component (B) to the content or blended amount of component (A) is 0.4 to 5, The content or blending amount of higher alcohol is 0.1% by mass or less, The hair cosmetic composition is filled in an airless bubble spray container for use.

[式(1-2)中，a表示2以上之數，b表示1以上之數，c表示4以上100以下之數，d表示1以上之數。括號內之結構單元彼此之鍵結順序不限，鍵結形態可為嵌段狀或無規狀。c個C₂ H₄ O可相同亦可不同]。 ＜3＞ 如＜1＞或＜2＞之毛髮化妝料組合物，其中上述四級銨陽離子改性矽酮具有下述通式(2-3)所表示之結構， [化8]

[式(2-3)中，R²¹ 表示碳數為1以上6以下之一價烴基。R²² 表示氫原子、碳數為1以上20以下之烴基、或碳數為1以上20以下之包含醯胺鍵之烴基。L表示二價有機基。Q^- 係四級銨離子之抗衡離子。r表示2以上之數。括號內之結構單元彼此之鍵結順序不限，鍵結形態可為嵌段狀或無規狀。又，複數個R²¹ 及R²² 可相同亦可不同。R²⁴ 表示碳數為1以上6以下之烷基、或苯基。R²⁵ 表示碳數為1以上20以下之烴基、或碳數為1以上20以下之包含醯胺鍵之烴基]。 ＜4＞ 如＜1＞至＜3＞中任一項之毛髮化妝料組合物，其中上述成分(C3)係選自由赤藻糖醇及甘露醇所組成之群中之1種以上。 ＜5＞ 如＜1＞至＜4＞中任一項之毛髮化妝料組合物，其中上述成分(C)包含上述成分(C1)，上述成分(A)及上述成分(B)之合計含量或合計調配量相對於該成分(C1)之含量或調配量之質量比[[(A)+(B)]/(C1)]為0.1以上25以下。 ＜6＞ 如＜1＞至＜5＞中任一項之毛髮化妝料組合物，其中上述成分(C)包含上述成分(C1)，上述成分(A)及上述成分(B)之合計含量或合計調配量相對於該成分(C1)之含量或調配量之質量比[[(A)+(B)]/(C1)]為3以上10以下。 ＜7＞ 如＜5＞或＜6＞之毛髮化妝料組合物，其中上述成分(C)進而包含成分(C2)。 ＜8＞ 如＜7＞之毛髮化妝料組合物，其中上述成分(C2)之含量或調配量相對於上述成分(C1)之含量或調配量之質量比[(C2)/(C1)]為0.08以上10以下。 ＜9＞ 如＜5＞至＜8＞中任一項之毛髮化妝料組合物，其中上述成分(C1)之含量或調配量為0.08質量%以上6質量%以下。 ＜10＞ 如＜5＞至＜9＞中任一項之毛髮化妝料組合物，其中上述成分(C1)之含量或調配量為0.30質量%以上2質量%以下。 ＜11＞ 如＜1＞至＜4＞中任一項之毛髮化妝料組合物，其中上述成分(C)包含選自由上述成分(C2)及上述成分(C3)所組成之群中之1種以上。 ＜12＞ 如＜11＞之毛髮化妝料組合物，其中上述成分(A)及上述成分(B)之合計含量或合計調配量相對於上述成分(C2)及上述成分(C3)之合計含量或合計調配量之質量比[[(A)+(B)]/[(C2)+(C3)]]為0.1以上40以下。 ＜13＞ 如＜11＞或＜12＞之毛髮化妝料組合物，其中上述成分(A)及上述成分(B)之合計含量或合計調配量相對於上述成分(C2)及上述成分(C3)之合計含量或合計調配量之質量比[[(A)+(B)]/[(C2)+(C3)]]為1以上15以下。 ＜14＞ 如＜11＞至＜13＞中任一項之毛髮化妝料組合物，其中上述成分(C2)及上述成分(C3)之合計含量或合計調配量為0.1質量%以上5質量%以下。 ＜15＞ 如＜11＞至＜14＞中任一項之毛髮化妝料組合物，其中上述成分(C2)及上述成分(C3)之合計含量或合計調配量為0.5質量%以上2質量%以下。<2> The hair cosmetic composition according to <1>, wherein the amino polyether-modified silicone has a structure represented by the following general formula (1-2), [化7]

[In formula (1-2), a represents a number of 2 or more, b represents a number of 1 or more, c represents a number of 4 or more and 100 or less, and d represents a number of 1 or more. The bonding sequence of the structural units in the brackets is not limited, and the bonding form can be block or random. The c C ₂ H ₄ O may be the same or different]. <3> The hair cosmetic composition of <1> or <2>, wherein the quaternary ammonium cation-modified silicone has a structure represented by the following general formula (2-3), [化8]

[In the formula (2-3), R ²¹ represents a monovalent hydrocarbon group having a carbon number of 1 or more and 6 or less. R ²² represents a hydrogen atom, a hydrocarbon group having a carbon number of 1 or more and 20 or less, or a hydrocarbon group having a carbon number of 1 or more and 20 or less including an amide bond. L represents a divalent organic group. Q ^- is the counter ion of the quaternary ammonium ion. r represents a number of 2 or more. The bonding sequence of the structural units in the brackets is not limited, and the bonding form can be block or random. In addition, a plurality of R ²¹ and R ²² may be the same or different. R ²⁴ represents an alkyl group having a carbon number of 1 to 6 or a phenyl group. R ²⁵ represents a hydrocarbon group having a carbon number of 1 or more and 20 or less, or a hydrocarbon group having a carbon number of 1 or more and 20 or less including an amide bond]. <4> The hair cosmetic composition according to any one of <1> to <3>, wherein the above-mentioned component (C3) is one or more selected from the group consisting of erythritol and mannitol. <5> The hair cosmetic composition of any one of <1> to <4>, wherein the above-mentioned component (C) includes the above-mentioned component (C1), the total content of the above-mentioned component (A) and the above-mentioned component (B), or The mass ratio [[(A)+(B)]/(C1)] of the total blended amount with respect to the content of the component (C1) or blended amount is 0.1 or more and 25 or less. <6> The hair cosmetic composition of any one of <1> to <5>, wherein the above-mentioned component (C) includes the above-mentioned component (C1), the total content of the above-mentioned component (A) and the above-mentioned component (B), or The mass ratio [[(A)+(B)]/(C1)] of the total blended amount with respect to the content of the component (C1) or blended amount is 3 or more and 10 or less. <7> The hair cosmetic composition as in <5> or <6>, wherein the above-mentioned component (C) further contains a component (C2). <8> The hair cosmetic composition of <7>, wherein the mass ratio [(C2)/(C1)] of the content or blended amount of the above-mentioned component (C2) relative to the content or blended amount of the above-mentioned component (C1) is Above 0.08 and below 10. <9> The hair cosmetic composition according to any one of <5> to <8>, wherein the content or blending amount of the above-mentioned component (C1) is 0.08% by mass or more and 6% by mass or less. <10> The hair cosmetic composition according to any one of <5> to <9>, wherein the content or blending amount of the above-mentioned component (C1) is 0.30% by mass or more and 2% by mass or less. <11> The hair cosmetic composition according to any one of <1> to <4>, wherein the above-mentioned component (C) includes one selected from the group consisting of the above-mentioned component (C2) and the above-mentioned component (C3) above. <12> The hair cosmetic composition as in <11>, wherein the total content or total blending amount of the above-mentioned component (A) and the above-mentioned component (B) is relative to the total content of the above-mentioned component (C2) and the above-mentioned component (C3) or The mass ratio [[(A)+(B)]/[(C2)+(C3)]] of the total blending amount is 0.1 or more and 40 or less. <13> The hair cosmetic composition of <11> or <12>, wherein the total content or total blending amount of the above-mentioned component (A) and the above-mentioned component (B) is relative to the above-mentioned component (C2) and the above-mentioned component (C3) The total content or the mass ratio of the total blending amount [[(A)+(B)]/[(C2)+(C3)]] is 1 to 15 or less. <14> The hair cosmetic composition of any one of <11> to <13>, in which the total content or total blending amount of the above-mentioned component (C2) and the above-mentioned component (C3) is 0.1% by mass to 5% by mass . <15> The hair cosmetic composition of any one of <11> to <14>, wherein the total content or total blending amount of the above-mentioned component (C2) and the above-mentioned component (C3) is 0.5% by mass to 2% by mass .

＜16＞ The hair cosmetic composition according to any one of <1> to <15>, wherein the content or blending amount of the above-mentioned component (A) is 0.08% by mass to 5% by mass. ＜17＞ The hair cosmetic composition according to any one of <1> to <16>, wherein the content or blending amount of the above-mentioned component (A) is 0.50% by mass or more and 3% by mass or less. ＜18＞ The hair cosmetic composition according to any one of <1> to <17>, wherein the content or blending amount of the above-mentioned component (B) is 0.08% by mass or more and 15% by mass or less. ＜19＞ The hair cosmetic composition according to any one of <1> to <18>, wherein the content or blending amount of the above-mentioned component (B) is 1% by mass to 5% by mass. ＜20＞ The hair cosmetic composition of any one of <1> to <19>, wherein the total content or total blending amount of the above-mentioned component (A), the above-mentioned component (B), and the above-mentioned component (C) is 0.2% by mass or more 20% by mass or less. ＜21＞ The hair cosmetic composition of any one of <1> to <20>, wherein the total content or total blending amount of the above-mentioned component (A), the above-mentioned component (B), and the above-mentioned component (C) is 1% by mass or more 10% by mass or less.

＜22＞ Such as the hair cosmetic composition of any one of <1> to <21>, which further contains or is blended with the following ingredients (D): Ingredient (D): Anionic surfactant. ＜23＞ Such as the hair cosmetic composition of <22>, wherein the content or blending amount of the above-mentioned component (D) is 0.02% by mass or more and 0.1% by mass or less. ＜24＞ Such as the hair cosmetic composition of any one of <1> to <23>, which further contains or is formulated with a cationic polymer. ＜25＞ Such as the hair cosmetic composition of <24>, wherein the cationic polymer is selected from the group consisting of cationized guar gum, cationized hydroxyalkyl cellulose, and quaternary dialkylaminoalkyl (meth)acrylate One or more of the group consisting of polymers. ＜26＞ Such as the hair cosmetic composition of <24> or <25>, wherein the content or blending amount of the cationic polymer is 0.1% by mass or more and 0.5% by mass or less. ＜27＞ Such as the hair cosmetic composition of any one of <1> to <26>, which further contains or blends an organic acid or an inorganic acid. ＜28＞ For example, in the hair cosmetic composition of <27>, the content or blending amount of organic acid and inorganic acid is 0.02% by mass or more and 0.5% by mass or less. ＜29＞ The hair cosmetic composition according to any one of <1> to <28>, which further contains or is blended with an organic acid, which is a hydroxycarboxylic acid. ＜30＞ For example, the hair cosmetic composition of any one of <1> to <29> has a viscosity at 30°C of 0.8 mPa·s or more and 20 mPa·s or less. ＜31＞ For example, the hair cosmetic composition of any one of <1> to <30> has a viscosity of 3 mPa·s or more and 10 mPa·s or less at 30°C. ＜32＞ For example, the hair cosmetic composition of any one of <1> to <31> has a viscosity at 5°C of 1.5 mPa·s or more and 50 mPa·s or less. ＜33＞ For example, the hair cosmetic composition of any one of <1> to <32> has a viscosity of 6 mPa·s or more and 15 mPa·s or less at 5°C. ＜34＞ A hair cosmetic material, which is formed by filling a hair cosmetic composition according to any one of <1> to <33> in an airless bubble spray container. [Example]

Hereinafter, the present invention will be described through examples, but the present invention is not limited to the scope of the examples. Furthermore, in this example, various measurements were performed by the following methods.

(pH measurement) The pH value of the hair cosmetic composition at 25°C was measured using a pH meter (F-51, manufactured by Horiba Manufacturing Co., Ltd.). The pH value was measured using an aqueous dispersion obtained by diluting the hair cosmetic composition to 5% with purified water.

(Viscosity measurement: 5℃) After filling about 100 mL of the hair cosmetic composition obtained in each example into a 110 mL glass bottle, seal it and let it stand in a constant temperature and constant temperature room at 5°C for more than 24 hours. After that, the No. 1 rotor was used to measure the viscosity with a BM type viscometer (TV-10, manufactured by Toki Sangyo Co., Ltd.). Furthermore, the rotation speed was set to 60 rpm, and the viscosity 60 seconds after the start of rotation was taken as the viscosity of the hair cosmetic composition at 5°C.

(Viscosity measurement: 30℃) After filling about 100 mL of the hair cosmetic composition obtained in each example into a 110 mL glass bottle, it is sealed and placed in a constant temperature thermostat at 30°C for more than 1 hour. After that, the No. 1 rotor was used to measure the viscosity with a BM type viscometer (TV-10, manufactured by Toki Sangyo Co., Ltd.). Furthermore, the rotation speed was set to 60 rpm, and the viscosity 60 seconds after the start of rotation was taken as the viscosity of the hair cosmetic composition at 30°C.

Examples 1-29, Comparative Examples 1-10 (Preparation and Evaluation of Hair Cosmetic Composition) The hair cosmetic composition of each example was prepared according to the formulating composition shown in Tables 2 to 6 as a conditioner, and the hair cosmetic composition or the hair cosmetic composition was filled in the following bubble ejection container Hair cosmetics were evaluated by the methods shown below. The results are shown in Tables 2-6. In addition, the compounding amount described in Tables 2 to 6 is the effective ingredient amount (mass %) of each component. Among them, the blending amount of the organic solvent described in Tables 2 to 6 is the blending amount obtained by adding dipropylene glycol to the organic solvent derived from the raw material of the hair cosmetic composition. The components used in Tables 2 to 6 are shown in Table 1.

[Table 1] Table 1 Raw material trade name Manufacturer name Contains the indication name or contains the ingredient name VARISOFT PATC Made by Evonik Japan Co., Ltd. Palmitoyl Ammonium Propyl Trimethyl Ammonium Chloride (Palmamido Propyl Trimethyl Ammonium Chloride) Quartamin 60W Kao Co., Ltd. manufacturing Cetyl Trimethyl Ammonium Chloride (Cetyl Trimethyl Ammonium Chloride) water Quartamin 86P Conc Kao Co., Ltd. manufacturing Stearyl Trimethyl Ammonium Chloride (Stearyl Trimethyl Ammonium Chloride) Isopropanol water Amphitol 20HD Kao Co., Ltd. manufacturing Lauryl hydroxysultaine water Amphitol 20AB Kao Co., Ltd. manufacturing Lauramidopropyl betaine water Amphitol 20Y-B Kao Co., Ltd. manufacturing Coco amphoteric sodium acetate (2-alkyl-N-carboxymethyl-N-hydroxyethyl imidazolinium betaine) Ethanol water KAO SOFCARE GP-1 Kao Co., Ltd. manufacturing PPG-3 octyl ether PENETOL GE-ID Kao Co., Ltd. manufacturing Isodecyl glyceryl ether AMINON C-11S Kao Co., Ltd. manufacturing Coconut Oil Amino Methyl MEA (Coconut Oil Fatty Acid N-Methyl Ethanol Amine) Emulgen 116 Kao Co., Ltd. manufacturing Laureth-16 (PEG-16 Laureth) AG-124 Kao Co., Ltd. manufacturing Lauryl Glucoside DOWSIL SS-3588 Manufactured by Dow Toray Co., Ltd. (Bis-isobutyl PEG-15/amino-terminated dimethyl polysiloxane) copolymer Ethanol ABIL ME45 Made by Evonik Japan Co., Ltd. Silicone quaternary ammonium salt-22 Polyglycerol-3 Caprate Dipropylene glycol Coco Aminopropyl Betaine (Coconut Fatty Aminopropyl Dimethylamino Acetate Betaine) Palmitoyl Ammonium Propyl Trimethyl Ammonium Chloride (Palmamido Propyl Trimethyl Ammonium Chloride) Propylene Glycol water Zerose Erythritol STD GRAN Made in Cargill Corporation Erythritol Marine Crystal Mitsubishi Corporation Life Sciences Co., Ltd. Mannitol Kalcol 8098 Kao Co., Ltd. manufacturing Stearyl alcohol Kalcol 4098 Kao Co., Ltd. manufacturing Myristyl alcohol EMAL 227-PH11 Kao Co., Ltd. manufacturing Sodium Laureth Sulfate (Polyoxyethylene Laureth Sodium Sulfate) CATICELO H-60 Kao Co., Ltd. manufacturing Polyquaternary ammonium salt-10 (cationized cellulose)

(Storage stability under low temperature (-5℃) environment (low temperature stability)) Fill about 100 mL of the hair cosmetic composition obtained in each example in a 110 mL glass bottle, seal it and let it stand for 3 days in a constant temperature and constant temperature room at -5°C, observe the appearance visually, according to the following 3 levels Evaluation based on the evaluation criteria. [Evaluation criteria] A: Transparent. B: Translucent. C: White turbidity, or precipitation, separation, or precipitation is confirmed.

(Evaluation of foam quality when sprayed from a foam spray container: room temperature) Fill about 100 mL of the hair cosmetic composition obtained in each example in a foam spray container that sprays bubbles by pressing the pump head [Pump Foamer, Yoshino The screen size of the porous membrane filter installed in the bubble ejection flow path is #200, which is manufactured by the Industrial Institute (Stock). The number of screens is two. The amount of liquid ejected per press is about 1 g. Each press The air ejection volume (bubble ejection volume) is about 13 cm ³ , and the volume of the container is about 300 mL], then seal it and let it stand still. After that, the bubble ejection container is placed on a horizontal platform, and the pump head is vertically pressed to the end to eject the bubble. A professional sensory inspector visually evaluates the state of bubbles ejected by this operation based on the evaluation criteria of the following three levels. Fig. 1 is a photograph showing the state of bubbles in the following evaluation criteria. [Evaluation Criteria] A: Stiff bubbles. B: Soft collapsed bubbles. C: Large bubbles are mixed.

(Evaluation of the protection of the hair during application) After fully moistening the 30 cm long, 6 cm wide, and 20 g weight Japanese female hair bundle with warm water at 35 to 40°C, wash it off with the following ordinary shampoo. After wringing out the water, the hair cosmetics prepared in the following amounts were applied to the hair bundles, and the touch of the hair when fused with the hair was evaluated by 7 panelists, and the protective feeling of the hair was evaluated. The touch of the hair is from "A: It blends well with all the hair, giving a very smooth touch and feeling the protection of the hair" / "B: Neither" / "C: It is not easy to blend with all the hair, There is no smooth touch, and the protection of hair is not felt." Choose one. In Tables 2 to 6, the number of people evaluated as A, B, and C is shown in order from the left.

[Composition of ordinary shampoo]Element ( quality %) Polyoxyethylene (2.0) lauryl ether sulfate Na 15.5 Diethanolamine lauric acid 2.2 Disodium ethylenediaminetetraacetic acid 0.15 Sodium benzoate 0.18 Oxyphenone 0.03 Phosphoric acid 0.07 Sodium chloride 0.8 Spices 0.4purified water margin 100.0

(Evaluation of the smoothness and resistance to tangling of the hair during rinsing) After fully moistening the 30 cm length, 6 cm width, and 20 g weight Japanese female hair bundle with warm water at 35-40°C, wash it off with the above-mentioned ordinary shampoo. After wringing out the water, apply the hair cosmetics prepared in the following amounts to the hair bundles, and after they blend well with the hair, rinse them with warm water at 35-40°C, and check by 7 panelists The staff evaluates the touch of the hair during rinsing, and evaluates the smoothness and resistance to tangling of the hair. The touch of the hair is selected from "A: Very smooth touch, and the tangles of the hair are fully suppressed" / "B: Neither" / "C: No smooth touch, but tangled hair" One choice. In Tables 2 to 6, the number of people evaluated as A, B, and C is shown in order from the left.

[Table 2] Table 2 Example 1 2 3 4 5 6 7 Composition of hair cosmetic composition (mass%) (A) Palmitoylamino propyl trimethyl ammonium chloride 1.00 0.30 Cetyl Trimethyl Ammonium Chloride 1.00 0.70 1.00 1.00 1.00 1.00 Stearyl Trimethyl Ammonium Chloride (B) Lauryl hydroxy sultaine 2.70 2.70 2.70 2.00 2.70 2.70 Lauryl Aminopropyl Betaine 2.70 0.70 Coco Aminopropyl Betaine Coco Amphoteric Sodium Acetate (C) (C1) PPG-3 octyl ether 0.50 0.50 0.50 0.50 0.50 0.25 Isodecyl glyceryl ether 0.50 0.25 Polyglycerol-3 Caprate Coconut Aminomethyl MEA Laureth-16 Lauryl Glucoside (C2) (Bis-isobutyl PEG-15/amino-terminated dimethyl polysiloxane) copolymer 0.60 0.60 0.60 0.60 0.60 0.60 0.60 Silicone quaternary ammonium salt-22 (C3) Erythritol Mannitol Higher alcohol Stearyl alcohol Myristyl alcohol (D) Sodium Laureth Sulfate Cationic polymer Polyquaternary Ammonium-10 0.10 0.10 0.10 0.10 0.10 0.10 0.10 Lactic acid 0.36 0.36 0.36 0.36 0.36 0.36 0.36 Aqueous medium Organic solvents 7.00 7.00 7.00 7.00 7.00 7.00 7.00 water margin margin margin margin margin margin margin Mass ratio [(B)/(A)] 2.7 2.7 2.7 2.7 2.7 2.7 2.7 Mass ratio [[(A)+(B)]/(C1)] 7.4 7.4 7.4 7.4 7.4 7.4 7.4 Mass ratio [[(A)+(B)]/[(C2)+(C3)]] 6.2 6.2 6.2 6.2 6.2 6.2 6.2 Total content [(A)+(B)+(C)] (mass%) 4.80 4.80 4.80 4.80 4.80 4.80 4.80 (A) Content of ingredients (mass%) 1.00 1.00 1.00 1.00 1.00 1.00 1.00 (B) Content of ingredients (mass%) 2.70 2.70 2.70 2.70 2.70 2.70 2.70 (C1) Ingredient content (mass%) 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Total content [(C2)+(C3)] (mass%) 0.60 0.60 0.60 0.60 0.60 0.60 0.60 pH value 3.51 3.48 3.46 3.73 3.55 3.43 3.44 Viscosity at 30℃ (mPa·s) 4.6 4.4 4.6 4.7 4.5 4.8 4.9 Viscosity at 5℃ (mPa·s) 7.6 7.6 7.5 7.6 7.4 7.5 7.8 Evaluation results Low temperature stability A A A A A A A Foam quality A A A A A A A Protective feeling of hair during application (A/B/C) 6/1/0 6/1/0 6/1/0 6/1/0 6/1/0 6/1/0 5/2/0 Smoothness and resistance to tangling of hair during rinsing (A/B/C) 6/1/0 6/1/0 6/1/0 6/1/0 6/1/0 4/3/0 4/3/0

[table 3] table 3 Example 8 9 10 11 12 13 14 15 Composition of hair cosmetic composition (mass%) (A) Palmitoylamino propyl trimethyl ammonium chloride 0.01 Cetyl Trimethyl Ammonium Chloride 1.00 1.00 1.00 1.00 2.00 2.00 2.00 0.50 Stearyl Trimethyl Ammonium Chloride (B) Lauryl hydroxy sultaine 2.70 2.70 2.70 1.00 1.00 10.00 8.00 0.50 Lauryl Aminopropyl Betaine Coco Aminopropyl Betaine 0.04 Coco Amphoteric Sodium Acetate (C) (C1) PPG-3 octyl ether 0.50 0.50 0.50 0.50 0.50 0.50 0.70 0.80 Isodecyl glyceryl ether 0.70 Polyglycerol-3 Caprate 0.10 Coconut Aminomethyl MEA Laureth-16 3.50 Lauryl Glucoside (C2) (Bis-isobutyl PEG-15/amino-terminated dimethyl polysiloxane) copolymer 0.30 0.60 0.60 0.60 0.60 0.60 Silicone quaternary ammonium salt-22 0.30 (C3) Erythritol 0.60 0.30 Mannitol 0.30 Higher alcohol Stearyl alcohol Myristyl alcohol (D) Sodium Laureth Sulfate Cationic polymer Polyquaternary Ammonium-10 0.10 0.10 0.10 0.10 0.10 0.10 0.10 0.10 Lactic acid 0.36 0.36 0.36 0.36 0.36 0.36 0.36 0.36 Aqueous medium Organic solvents 7.00 7.00 7.00 7.00 7.00 7.00 7.00 7.00 water margin margin margin margin margin margin margin margin Mass ratio [(B)/(A)] 2.7 2.7 2.7 1.0 0.5 5.0 4.0 1.0 Mass ratio [[(A)+(B)]/(C1)] 6.3 7.4 7.4 4.0 6.0 24.0 14.3 0.2 Mass ratio [[(A)+(B)]/[(C2)+(C3)]] 6.3 6.2 6.2 3.3 5.0 20.0 16.7 1.7 Total content [(A)+(B)+(C)] (mass%) 4.95 4.80 4.80 3.10 4.10 13.10 11.30 6.60 (A) Content of ingredients (mass%) 1.01 1.00 1.00 1.00 2.00 2.00 2.00 0.50 (B) Content of ingredients (mass%) 2.74 2.70 2.70 1.00 1.00 10.00 8.00 0.50 (C1) Ingredient content (mass%) 0.60 0.50 0.50 0.50 0.50 0.50 0.70 5.00 Total content [(C2)+(C3)] (mass%) 0.60 0.60 0.60 0.60 0.60 0.60 0.60 0.60 pH value 3.43 3.30 3.29 3.43 3.45 3.45 3.45 3.55 Viscosity at 30℃ (mPa·s) 4.6 4.6 4.7 5.8 5.8 5.2 5.0 7.6 Viscosity at 5℃ (mPa·s) 7.4 7.6 7.4 9.3 9.3 8.4 7.8 12.5 Evaluation results Low temperature stability A A A A A A A A Foam quality A A A A A A A A Protective feeling of hair during application (A/B/C) 6/1/0 5/2/0 5/2/0 3/4/0 5/2/0 4/3/0 5/2/0 4/3/0 Smoothness and resistance to tangling of hair during rinsing (A/B/C) 6/1/0 4/3/0 4/3/0 5/2/0 6/1/0 3/4/0 5/2/0 5/2/0

[Table 4] Table 4 Example 16 17 18 19 20 twenty one Composition of hair cosmetic composition (mass%) (A) Palmitoylamino propyl trimethyl ammonium chloride 0.30 0.30 0.30 Cetyl Trimethyl Ammonium Chloride 2.40 0.70 0.70 0.70 0.10 2.00 Stearyl Trimethyl Ammonium Chloride (B) Lauryl hydroxy sultaine 3.60 2.00 2.00 2.00 0.10 6.00 Lauryl Aminopropyl Betaine 0.70 0.70 0.70 Coco Aminopropyl Betaine Coco Amphoteric Sodium Acetate (C) (C1) PPG-3 octyl ether 0.50 0.50 0.10 0.50 Isodecyl glyceryl ether 0.50 Polyglycerol-3 Caprate Coconut Aminomethyl MEA Laureth-16 3.00 Lauryl Glucoside 0.20 (C2) (Bis-isobutyl PEG-15/amino-terminated dimethyl polysiloxane) copolymer 0.60 0.60 0.60 0.60 Silicone quaternary ammonium salt-22 (C3) Erythritol 0.60 Mannitol 0.60 Higher alcohol Stearyl alcohol Myristyl alcohol (D) Sodium Laureth Sulfate Cationic polymer Polyquaternary Ammonium-10 0.10 0.10 0.10 0.10 0.10 0.10 Lactic acid 0.36 0.36 0.36 0.36 0.36 0.36 Aqueous medium Organic solvents 7.00 7.00 7.00 7.00 7.00 7.00 water margin margin margin margin margin margin Mass ratio [(B)/(A)] 1.5 2.7 2.7 2.7 1.0 3.0 Mass ratio [[(A)+(B)]/(C1)] 12.0 5.3 - - 2.0 2.0 Mass ratio [[(A)+(B)]/[(C2)+(C3)]] 10.0 - 3.1 6.2 0.3 13.3 Total content [(A)+(B)+(C)] (mass%) 7.10 4.40 4.90 4.30 0.90 12.60 (A) Content of ingredients (mass%) 2.40 1.00 1.00 1.00 0.10 2.00 (B) Content of ingredients (mass%) 3.60 2.70 2.70 2.70 0.10 6.00 (C1) Ingredient content (mass%) 0.50 0.70 0.00 0.00 0.10 4.00 Total content [(C2)+(C3)] (mass%) 0.60 0.00 1.20 0.60 0.60 0.60 pH value 3.46 3.40 3.40 3.62 3.82 3.47 Viscosity at 30℃ (mPa·s) 5.2 4.6 4.6 4.8 5.3 7.3 Viscosity at 5℃ (mPa·s) 7.9 8.0 8.0 7.7 7.8 11.4 Evaluation results Low temperature stability A A A A A A Foam quality A A A A B A Protective feeling of hair during application (A/B/C) 5/2/0 3/4/0 5/2/0 5/2/0 4/3/0 5/2/0 Smoothness and resistance to tangling of hair during rinsing (A/B/C) 5/2/0 4/3/0 4/3/0 5/2/0 5/2/0 5/2/0

[table 5] table 5 Example twenty two twenty three twenty four 25 26 27 28 29 Composition of hair cosmetic composition (mass%) (A) Palmitoylamino propyl trimethyl ammonium chloride 0.30 0.50 0.31 Cetyl Trimethyl Ammonium Chloride 0.70 0.90 0.70 2.00 1.00 2.40 2.00 2.00 Stearyl Trimethyl Ammonium Chloride 1.00 (B) Lauryl hydroxy sultaine 2.00 2.00 2.00 1.50 1.50 8.00 6.00 1.50 Lauryl Aminopropyl Betaine 0.70 1.00 0.70 2.00 2.00 2.00 Coco Aminopropyl Betaine 0.04 Coco Amphoteric Sodium Acetate 0.50 0.50 0.50 (C) (C1) PPG-3 octyl ether 0.50 0.50 0.25 0.50 0.70 0.50 0.50 Isodecyl glyceryl ether 0.50 0.25 0.50 Polyglycerol-3 Caprate 0.10 Coconut Aminomethyl MEA 0.25 Laureth-16 0.75 1.00 3.00 1.00 Lauryl Glucoside (C2) (Bis-isobutyl PEG-15/amino-terminated dimethyl polysiloxane) copolymer 0.60 0.60 0.30 0.60 0.18 0.60 0.60 0.18 Silicone quaternary ammonium salt-22 0.30 (C3) Erythritol 0.60 Mannitol 0.60 Higher alcohol Stearyl alcohol Myristyl alcohol 0.10 (D) Sodium Laureth Sulfate 0.05 0.03 Cationic polymer Polyquaternary Ammonium-10 0.10 0.10 0.10 0.10 0.10 0.10 0.10 0.10 Lactic acid 0.36 0.36 0.36 0.36 0.36 0.36 0.36 0.36 Aqueous medium Organic solvents 7.00 7.00 7.00 7.00 7.00 7.00 7.00 7.00 water margin margin margin margin margin margin margin margin Mass ratio [(B)/(A)] 2.7 2.1 2.7 2.0 2.0 3.3 3.0 2.0 Mass ratio [[(A)+(B)]/(C1)] 7.4 8.8 6.3 4.0 4.0 14.9 2.0 4.0 Mass ratio [[(A)+(B)]/[(C2)+(C3)]] 6.2 7.3 2.1 10.0 33.3 17.3 13.3 33.3 Total content [(A)+(B)+(C)] (mass%) 4.80 5.50 6.15 8.10 7.68 11.70 12.60 7.68 (A) Content of ingredients (mass%) 1.00 1.40 1.01 2.00 2.00 2.40 2.00 2.00 (B) Content of ingredients (mass%) 2.70 3.00 2.74 4.00 4.00 8.00 6.00 4.00 (C1) Ingredient content (mass%) 0.50 0.50 0.60 1.50 1.50 0.70 4.00 1.50 Total content [(C2)+(C3)] (mass%) 0.60 0.60 1.80 0.60 0.18 0.60 0.60 0.18 pH value 3.54 3.50 3.48 4.10 3.98 3.43 3.62 3.78 Viscosity at 30℃ (mPa·s) 5.4 5.0 4.5 6.8 5.0 5.6 6.8 5.0 Viscosity at 5℃ (mPa·s) 7.4 7.4 7.4 13.1 7.6 8.9 11.5 8.4 Evaluation results Low temperature stability A A A A A A A A Foam quality A A A A A A A A Protective feeling of hair during application (A/B/C) 7/0/0 7/0/0 7/0/0 7/0/0 6/1/0 6/1/0 6/1/0 7/0/0 Smoothness and resistance to tangling of hair during rinsing (A/B/C) 7/0/0 6/1/0 7/0/0 7/0/0 6/1/0 4/3/0 6/1/0 6/1/0

[Table 6] Table 6 Comparative example 1 2 3 4 5 6 7 8 9 10 Composition of hair cosmetic composition (mass%) (A) Palmitoylamino propyl trimethyl ammonium chloride 0.40 Cetyl Trimethyl Ammonium Chloride 0.001 0.01 0.10 1.00 1.00 1.00 8.00 2.00 Stearyl Trimethyl Ammonium Chloride (B) Lauryl hydroxy sultaine 2.70 2.70 2.70 2.70 2.70 2.70 2.70 Lauryl Aminopropyl Betaine 2.00 8.00 Coco Aminopropyl Betaine Coco Amphoteric Sodium Acetate (C) (C1) PPG-3 octyl ether 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Isodecyl glyceryl ether Polyglycerol-3 Caprate Coconut Aminomethyl MEA Laureth-16 0.10 0.10 Lauryl Glucoside (C2) (Bis-isobutyl PEG-15/amino-terminated dimethyl polysiloxane) copolymer 0.60 0.60 0.60 0.60 0.60 0.60 0.60 0.60 0.60 Silicone quaternary ammonium salt-22 (C3) Erythritol Mannitol Higher alcohol Stearyl alcohol 0.80 0.30 Myristyl alcohol (D) Sodium Laureth Sulfate Cationic polymer Polyquaternary Ammonium-10 0.10 0.10 0.10 0.10 0.10 0.10 0.10 0.10 0.10 0.10 Lactic acid 0.36 0.36 0.36 0.36 0.36 0.36 0.36 0.36 0.36 0.36 Aqueous medium Organic solvents 7.00 7.00 7.00 7.00 7.00 7.00 7.00 7.00 7.00 7.00 water margin margin margin margin margin margin margin margin margin margin Mass ratio [(B)/(A)] - 2700 270.0 27.0 0.0 2.7 2.7 0.3 4.0 6.8 Mass ratio [[(A)+(B)]/(C1)] 5.4 5.4 5.4 5.6 2.0 - 7.4 100.0 100.0 6.2 Mass ratio [[(A)+(B)]/[(C2)+(C3)]] 4.5 4.5 4.5 4.7 1.7 - 6.2 16.7 16.7 5.2 Total content [(A)+(B)+(C)] (mass%) 3.80 3.80 3.81 3.90 2.10 3.70 4.80 10.70 10.70 4.20 (A) Content of ingredients (mass%) 0.000 0.001 0.010 0.100 1.00 1.00 1.00 8.00 2.00 0.40 (B) Content of ingredients (mass%) 2.70 2.70 2.70 2.70 0.00 2.70 2.70 2.00 8.00 2.70 (C1) Ingredient content (mass%) 0.50 0.50 0.50 0.50 0.50 0.00 0.50 0.10 0.10 0.50 Total content [(C2)+(C3)] (mass%) 0.60 0.60 0.60 0.60 0.60 0.00 0.60 0.60 0.60 0.60 pH value 3.46 3.46 3.50 3.46 3.40 3.34 3.47 3.58 4.17 3.50 Viscosity at 30℃ (mPa·s) 5.1 5.1 4.8 5.1 5.3 4.5 - 6.3 5.6 4.5 Viscosity at 5℃ (mPa·s) 7.3 7.3 7.5 7.3 7.6 7.3 - 13.8 11 7.3 Evaluation results Low temperature stability C C C C A A C C C A Foam quality A A A A C A *1 A A A Protective feeling of hair during application (A/B/C) 3/1/3 4/1/2 3/1/3 2/2/3 0/3/4 2/1/4 0/1/6 2/4/1 1/4/2 2/3/2 Smoothness and resistance to tangling of hair during rinsing (A/B/C) 0/2/5 0/2/5 1/2/4 1/2/4 1/2/4 0/0/7 0/0/7 4/2/1 1/2/4 1/3/3 *1: The foam quality cannot be evaluated due to clogging during spraying.

As shown in Tables 2 to 6, it can be seen that compared with Comparative Examples 1 to 10, the hair cosmetic compositions of Examples 1 to 29 have excellent storage stability in a low temperature environment, and the texture of the bubbles ejected from the bubble ejection container is excellent. And it can prevent the hair from being damaged by the friction between the hairs during the application, and can give the hair good smoothness during washing, and can inhibit the tangling of the hair. [Industrial availability]

According to the hair cosmetic composition of the present invention, the container will not be clogged even when the bubble is sprayed out in a low-temperature environment. In addition, due to the foam with good texture during application, the hair can be prevented from being damaged, and smoothness can be imparted to the hair during rinsing. , It can inhibit the tangled hair and make the hair care behavior more comfortable.

Fig. 1 is a photograph showing the state of the foam quality as an evaluation criterion used when the foam quality is evaluated.

Claims (14)

A hair cosmetic composition comprising the following ingredients (A), ingredient (B), and ingredient (C): Ingredient (A): cationic surfactant; Ingredient (B): Amphoteric surfactant; Ingredient (C): one selected from the group consisting of nonionic surfactants (C1), modified silicones with cationic groups (C2), and sugar alcohols with 4 or more carbons (C3) above; The mass ratio [(B)/(A)] of the content of the component (B) to the content of the component (A) is 0.4 or more and 5 or less, The content of higher alcohol is 0.1% by mass or less, The hair cosmetic composition is filled in an airless bubble spray container for use. The hair cosmetic composition of claim 1, wherein the above-mentioned component (C) comprises the above-mentioned component (C1), and the mass ratio of the total content of the above-mentioned component (A) and the above-mentioned component (B) to the content of the component (C1) [[(A)+(B)]/(C1)] is 0.1 or more and 25 or less. The hair cosmetic composition of claim 2, wherein the above-mentioned component (C) further comprises the above-mentioned component (C2). The hair cosmetic composition of claim 2 or 3, wherein the content of the above-mentioned component (C1) is 0.08% by mass or more and 6% by mass or less. The hair cosmetic composition of claim 1, wherein the component (C) includes one or more selected from the group consisting of the component (C2) and the component (C3). The hair cosmetic composition of claim 5, wherein the mass ratio of the total content of the above-mentioned component (A) and the above-mentioned component (B) to the total content of the above-mentioned component (C2) and the above-mentioned component (C3) [[(A) +(B)]/[(C2)+(C3)]] is 0.1 or more and 40 or less. The hair cosmetic composition of claim 5 or 6, wherein the total content of the above-mentioned component (C2) and the above-mentioned component (C3) is 0.1% by mass to 5% by mass. The hair cosmetic composition according to any one of claims 1 to 7, wherein the total content of the above-mentioned component (A), the above-mentioned component (B), and the above-mentioned component (C) is 0.2% by mass or more and 20% by mass or less. For example, the hair cosmetic composition of any one of claims 1 to 8 has a viscosity at 30°C of 0.8 mPa·s or more and 20 mPa·s or less. For example, the hair cosmetic composition of any one of claims 1 to 9 has a viscosity at 5°C of 1.5 mPa·s or more and 50 mPa·s or less. The hair cosmetic composition according to any one of claims 1 to 10, wherein the content of the above-mentioned component (A) is from 0.08% by mass to 5% by mass. The hair cosmetic composition according to any one of claims 1 to 11, wherein the content of the above-mentioned component (B) is 0.08% by mass or more and 15% by mass or less. The hair cosmetic composition according to any one of claims 1 to 12, which further contains the following ingredient (D): Ingredient (D): Anionic surfactant. A hair cosmetic material, which is formed by filling the hair cosmetic composition according to any one of claims 1 to 13 in an airless bubble spray container.

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