TW202129263A - Inspection method, inspection apparatus and inspection system - Google Patents

Inspection method, inspection apparatus and inspection system Download PDF

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TW202129263A
TW202129263A TW109137098A TW109137098A TW202129263A TW 202129263 A TW202129263 A TW 202129263A TW 109137098 A TW109137098 A TW 109137098A TW 109137098 A TW109137098 A TW 109137098A TW 202129263 A TW202129263 A TW 202129263A
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film
polarizing plate
retardation
inspection
linear polarizing
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小林信次
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日商住友化學股份有限公司
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/84Systems specially adapted for particular applications
    • G01N21/88Investigating the presence of flaws or contamination
    • G01N21/89Investigating the presence of flaws or contamination in moving material, e.g. running paper or textiles
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/84Systems specially adapted for particular applications
    • G01N21/88Investigating the presence of flaws or contamination
    • G01N21/89Investigating the presence of flaws or contamination in moving material, e.g. running paper or textiles
    • G01N21/892Investigating the presence of flaws or contamination in moving material, e.g. running paper or textiles characterised by the flaw, defect or object feature examined
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/30Polarising elements

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Abstract

An object of the present invention is to provide an inspection method which is capable of suppressing the influence of in-plane phase difference in a base film, and meanwhile conducting inspection of defects of a phase difference film comprising a cured article of a polymerizable liquid crystal compound. The inspection method makes light incident to an object to be inspected 10 so as to determine whether a phase difference film has a defect or not, the object to be inspected 10 comprising: a base film 8A having an in-plane phase difference value larger than 50 nm at wavelength of 550 nm, and the phase difference film 7A having a cured article of a polymerizable liquid crystal compound formed on one side of the base film. A first linear polarizing plate 3, the object to be inspected 10, a phase difference filter 4 and a second linear polarizing plate 5 are arranged in this order. The slow axis of the base film and the slow axis of the first or second linear polarizing plate are approximately orthogonal or parallel to each other. The slow axes of the phase difference film and the phase difference filter are approximately orthogonal to each other, and the in-plane phase differences of the phase difference film and the phase difference filter are approximately the same as each other. The inspection method makes light incident to one of the first linear polarizing plate side and second linear polarizing plate side, and observes the light from the other.

Description

檢查方法、檢查裝置及檢查系統 Inspection method, inspection device and inspection system

本發明係關於一種檢查方法、檢查裝置及檢查系統。 The present invention relates to an inspection method, inspection device and inspection system.

相位差膜係可將直線偏光轉換為圓偏光或橢圓偏光,或者反之將圓偏光或橢圓偏光轉換為直線偏光,故該相位差膜與直線偏光板組合而成的(橢)圓偏光板係應用於有機EL(Electroluminescence,電致發光)顯示裝置或反射型液晶顯示裝置。相位差膜之中又以藉由使聚合性液晶化合物配向及硬化所獲得的相位差膜為極度薄之膜,故在製造薄型的顯示裝置上受到矚目(例如參照專利文獻1)。 The retardation film system can convert linear polarization into circular polarization or elliptical polarization, or vice versa, convert circular polarization or elliptic polarization into linear polarization, so the phase difference film and linear polarization plate are combined to form (elliptical) circular polarization plate application Used in organic EL (Electroluminescence) display devices or reflective liquid crystal display devices. Among the retardation films, the retardation film obtained by aligning and curing a polymerizable liquid crystal compound is an extremely thin film, and therefore attracts attention in manufacturing thin display devices (for example, refer to Patent Document 1).

以製造此種相位差膜的方法而言,通常,係將包含聚合性液晶化合物的液狀組成物塗覆於長條狀的基材膜上以形成薄膜,且在使該薄膜中的聚合性液晶化合物朝所希望的方向配向之後,照射活性能量線。藉此,使配向後的聚合性液晶化合物硬化而成為相位差膜。另外,在使聚合性液晶化合物配向時,亦有在將液狀組成物塗覆於基材膜之前,於基材膜上形成配向膜的情形。 With regard to the method of manufacturing such retardation film, usually, a liquid composition containing a polymerizable liquid crystal compound is coated on a long substrate film to form a film, and the polymerizability of the film is After the liquid crystal compound is aligned in a desired direction, active energy rays are irradiated. Thereby, the polymerizable liquid crystal compound after alignment is cured to become a retardation film. In addition, when aligning the polymerizable liquid crystal compound, there are cases where an alignment film is formed on the base film before the liquid composition is applied to the base film.

[先前技術文獻] [Prior Technical Literature]

[專利文獻] [Patent Literature]

專利文獻1:日本特開2006-58546號公報 Patent Document 1: Japanese Patent Application Publication No. 2006-58546

在此製造方法中,當在基材膜上或配向膜上有塵埃等時,聚合性液晶化合物的配向會有在該塵埃的部分混亂而產生缺陷的情形。再者,當基材膜為具有面內相位差者時,將易於使藉由光學手段檢查形成於該基材膜上之相位差膜有無缺陷乙事變得困難。由於從市場上可廉價取得的基材膜一般以延展方式製造,故有廉價的基材膜難以使用在以上述方法所製造之相位差膜的檢查上之實際情形。 In this manufacturing method, when dust or the like is present on the base film or the alignment film, the alignment of the polymerizable liquid crystal compound may be disordered in the dust portion, which may cause defects. Furthermore, when the base film has an in-plane retardation, it is easy to make it difficult to optically inspect the retardation film formed on the base film for defects. Since base films available on the market at low prices are generally manufactured in a stretched manner, it is difficult to use inexpensive base films for inspections of retardation films manufactured by the above-mentioned methods.

因此,本發明之目的為提供一種抑制基材膜所具有之面內相位差的影響,同時可檢查由聚合性液晶化合物之硬化物所構成之相位差膜有無缺陷的檢查方法、檢查裝置及檢查系統。 Therefore, the object of the present invention is to provide an inspection method, inspection device, and inspection that suppresses the influence of the in-plane retardation of the base film while inspecting the retardation film composed of the cured product of the polymerizable liquid crystal compound for defects system.

本發明係提供一種檢查方法,該檢查方法係將光射入至膜狀的被檢查物以判斷相位差膜有無缺陷,該膜狀的被檢查物係具備在波長550nm時之面內相位差值為50nm以上的基材膜、及形成於基材膜之單面之由聚合性液晶化合物之硬化物所構成的相位差膜;其中,將第一直線偏光板、被檢查物、相位差過濾器(filter)、第二直線偏光板依序排列地配置,被檢查物之基材膜側的面係朝向第一直線偏光板側,基材膜的遲相軸、與第一直線偏光板或第二直線偏光板的偏光軸係彼此大致正交或大致平行,相位差膜的遲相軸、與相位差過濾器的遲相軸 係彼此大致正交,相位差膜之在波長550nm時之面內相位差值、與相位差過濾器之在波長550nm時之面內相位差值係彼此大致相同,第一直線偏光板與第二直線偏光板係構成正交偏光鏡(crossed nicol),從第一直線偏光板側或第二直線偏光板側的任一側,以光軸通過被檢查物上之預定之檢查區域之方式射入光,且從第一直線偏光板側或第二直線偏光板側的另一側觀察第二直線偏光板或第一直線偏光板。 The present invention provides an inspection method. The inspection method is to inject light into a film-like inspection object to determine whether the retardation film is defective, and the film-like inspection object has an in-plane retardation value at a wavelength of 550nm It is a base film of 50 nm or more, and a retardation film composed of a cured product of a polymerizable liquid crystal compound formed on one side of the base film; wherein, the first linear polarizing plate, the inspection object, and the retardation filter ( filter), the second linear polarizing plate is arranged in sequence, the substrate film side of the inspected object is facing the first linear polarizing plate side, and the slow axis of the substrate film is connected to the first linear polarizing plate or the second linear polarizing plate. The polarization axes of the plates are approximately orthogonal or approximately parallel to each other, the slow axis of the retardation film and the retardation axis of the retardation filter The in-plane retardation value of the retardation film at a wavelength of 550nm and the in-plane retardation value of the retardation filter at a wavelength of 550nm are approximately the same. The first linear polarizing plate and the second linear The polarizing plate constitutes a crossed nicol. From either the first linear polarizing plate side or the second linear polarizing plate side, the light is incident in such a way that the optical axis passes through a predetermined inspection area on the object to be inspected. And the second linear polarizing plate or the first linear polarizing plate is observed from the side of the first linear polarizing plate or the other side of the second linear polarizing plate side.

在此檢查方法中,係相對於具有相位差之基材膜的遲相軸將第一直線偏光板或第二直線偏光板之偏光軸配置成彼此大致正交或大致平行,因此通過直線偏光板後之光的偏光狀態不會因為基材膜而被攪亂。 In this inspection method, the polarization axes of the first linear polarizing plate or the second linear polarizing plate are arranged to be approximately orthogonal or approximately parallel to each other with respect to the slow axis of the base film with phase difference. Therefore, after passing through the linear polarizing plate The polarization state of the light will not be disturbed by the base film.

亦即,組成的光學系統如預期地發揮作用,且當相位差膜產生缺陷時在觀察視野上可適當地辨識該缺陷。因此,依據此檢查方法,可抑制基材膜所具有之面內相位差的影響,同時易於判斷相位差膜有無缺陷。 That is, the composed optical system functions as expected, and when a defect occurs in the retardation film, the defect can be appropriately recognized in the observation field of view. Therefore, according to this inspection method, the influence of the in-plane retardation of the base film can be suppressed, and it is easy to judge whether the retardation film has defects.

此外,在此檢查方法中,第一直線偏光板與第二直線偏光板係構成正交偏光鏡。此時,可將觀察視野整體設為最暗,故作為亮點被觀察到之相位差膜的缺陷部分在觀察視野之中最為顯著。因此,可更為容易地判斷相位差膜有無缺陷。 In addition, in this inspection method, the first linear polarizing plate and the second linear polarizing plate constitute an orthogonal polarizer. At this time, the entire observation field can be made the darkest, so the defect part of the retardation film observed as a bright spot is the most prominent in the observation field. Therefore, the presence or absence of defects in the retardation film can be judged more easily.

在此檢查方法中,亦可具有:以形成相位差膜之前之基材膜為對象,使用配向角測量器而預先求出基材膜之遲相軸之方向的步驟。當基材膜之遲相軸的方向不明確時,藉由預先求出基材膜之遲相軸的方向,從而可將第一直線偏光板或第二直線偏光板之偏光軸配置成與基材膜之遲相軸為彼此大致正交或大致平行。 In this inspection method, it is also possible to have a step of obtaining the direction of the retardation axis of the base film in advance by using an orientation angle measuring device for the base film before forming the retardation film. When the direction of the slow axis of the base film is not clear, by calculating the direction of the slow axis of the base film in advance, the polarization axis of the first linear polarizing plate or the second linear polarizing plate can be arranged with the base material The slow axis of the film is approximately orthogonal or approximately parallel to each other.

再者,此時,亦可具有:在藉由配向角測量器求出基材膜的遲相軸之後,在基材膜的單面,塗覆包含聚合性液晶化合物的液狀組成物而將包含聚合性液晶化合物的塗覆膜形成於基材膜的表面上,使塗覆膜中所含之聚合性液晶化合物配向及硬化而形成相位差膜的步驟。藉此,使相位差膜的製造效率化。 Furthermore, at this time, it is also possible to have: after obtaining the slow axis of the base film by an orientation angle measuring device, a liquid composition containing a polymerizable liquid crystal compound is applied to one side of the base film to remove The step of forming a coating film containing a polymerizable liquid crystal compound on the surface of a base film, and aligning and curing the polymerizable liquid crystal compound contained in the coating film to form a retardation film. Thereby, the production efficiency of the retardation film is improved.

此外,在本發明的檢查方法中,亦可使被檢查物在第一直線偏光板與相位差過濾器之間朝被檢查物的長邊方向搬運,同時朝長邊方向連續地進行檢查。藉此,即可使被檢查物的檢查效率化。 In addition, in the inspection method of the present invention, the inspection object may be conveyed in the longitudinal direction of the inspection object between the first linear polarizing plate and the retardation filter, and the inspection may be continuously performed in the longitudinal direction. In this way, the inspection efficiency of the inspection object can be improved.

此外,在本發明的檢查方法中,亦可在被檢查物的寬度方向上設置複數處檢測區域。由於基材膜一般係藉由至少朝一方向延展被製造,故遲相軸的方向大多在寬度方向上會有所不同。因此,藉由在被檢查物的整個寬度方向上區分檢查區域且在各個檢查區域進行該檢查,從而可在寬度方向的各部,進行抑制基材膜所具有之面內相位差之影響的檢查。 In addition, in the inspection method of the present invention, a plurality of detection areas may be provided in the width direction of the inspection object. Since the base film is generally manufactured by stretching in at least one direction, the direction of the slow axis is usually different in the width direction. Therefore, by dividing the inspection area in the entire width direction of the inspection object and performing the inspection in each inspection area, it is possible to perform an inspection that suppresses the influence of the in-plane retardation of the base film at each part in the width direction.

此外,本發明係提供一種檢查裝置,該檢查裝置係將光射入至膜狀的被檢查物以判斷相位差膜有無缺陷,該膜狀的被檢查物係具備在波長550nm時之面內相位差值為50nm以上的基材膜、及形成於基材膜之單面之由聚合性液晶化合物之硬化物所構成的相位差膜;該檢查裝置係具備:第一直線偏光板及相位差過濾器,係隔著供被檢查物配置之場所而配置;第二直線偏光板,係就相位差過濾器而言配置在與供被檢查物配置之場所為相反側的區域;及光源,係就第一直線偏光板或第二直線偏光板而言配置在與供被檢查物配置之場所為相反側的區域;第一直線偏光板或第二直線偏光板係配置成其偏光軸與基材膜的遲相軸為彼此大致正交或大致平行,第一直線偏光板與第二直線偏光板係構成正交偏光鏡,相位差過濾器係配置成其遲相軸與相位差膜的遲相軸為彼此大致正交, 相位差過濾器之在波長550nm時之面內相位差係被設為與相位差膜之在波長550nm時之面內相位差值大致相同,且光源係配置在於其光軸上排列有第一直線偏光板、被檢查物上之預定的檢測區域、相位差過濾器、及第二直線偏光板的位置上。 In addition, the present invention provides an inspection device that injects light into a film-like inspection object to determine whether the retardation film is defective, and the film-like inspection object has an in-plane phase at a wavelength of 550 nm. A base film with a difference of 50 nm or more, and a retardation film formed on one side of the base film made of a cured product of a polymerizable liquid crystal compound; the inspection device includes: a first linear polarizing plate and a retardation filter , Is arranged across the place where the inspected object is arranged; the second linear polarizer is arranged in the area on the opposite side of the place where the inspected object is arranged in terms of the phase difference filter; and the light source is arranged on the first The linear polarizing plate or the second linear polarizing plate is arranged in the area on the opposite side to the place where the inspection object is arranged; the first linear polarizing plate or the second linear polarizing plate is arranged so that the polarization axis and the base film are delayed The axes are approximately orthogonal or approximately parallel to each other. The first linear polarizer and the second linear polarizer constitute an orthogonal polarizer, and the retardation filter system is arranged so that its late axis and the retardation axis of the retardation film are approximately positive to each other pay, The in-plane retardation of the retardation filter at a wavelength of 550nm is set to be approximately the same as the in-plane retardation value of the retardation film at a wavelength of 550nm, and the light source is configured such that the first linearly polarized light is arranged on the optical axis On the board, the predetermined detection area on the inspected object, the phase difference filter, and the position of the second linear polarizing plate.

在此檢查裝置中,係相對於具有相位差之基材膜的遲相軸將第一直線偏光板或第二直線偏光板之偏光軸配置成彼此大致正交或大致平行,因此通過直線偏光板後之光的偏光狀態不會因為基材膜而被攪亂。亦即,組成的光學系統如預期地發揮作用,且當相位差膜產生缺陷時在觀察視野上可適當地辨識該缺陷。因此,依據此檢查裝置,可抑制基材膜所具有之面內相位差的影響,同時易於判斷相位差膜有無缺陷。 In this inspection device, the polarization axes of the first linear polarizer or the second linear polarizer are arranged to be substantially orthogonal or substantially parallel to each other with respect to the slow axis of the substrate film with phase difference. Therefore, after passing through the linear polarizer The polarization state of the light will not be disturbed by the base film. That is, the composed optical system functions as expected, and when a defect occurs in the retardation film, the defect can be appropriately recognized in the observation field of view. Therefore, according to this inspection device, the influence of the in-plane retardation of the base film can be suppressed, and at the same time, it is easy to determine whether the retardation film is defective.

此外,在此檢查裝置中,第一直線偏光板與第二直線偏光板係構成正交偏光鏡。此時,可將觀察視野整體設為最暗,故被作為亮點觀察到之相位差膜的缺陷部分會在觀察視野之中最為顯著。因此,可更容易地判斷相位差膜有無缺陷。 In addition, in this inspection device, the first linear polarizing plate and the second linear polarizing plate constitute an orthogonal polarizer. At this time, the entire observation field can be made the darkest, so the defect part of the retardation film that is observed as a bright spot will be the most prominent in the observation field. Therefore, the presence or absence of defects in the retardation film can be judged more easily.

此外,本發明係提供一種檢查系統,該檢查系統係具備:上述之檢查裝置;配向角測量器,係求出形成相位差膜之前之基材膜的遲相軸;及角度調整機構,係調整第一直線偏光板的角度,以使藉由配向角測量器所求出之基材膜的遲相軸與第一直線偏光板的偏光軸成為彼此大致正交或大致平行。當基材膜之遲相軸的方向不明確時,藉由預先求出基材膜之遲相軸的方向,從而可將第一直線偏光板或第二直線偏光板之偏光軸配置成與基材膜之遲相軸為彼此大致正交或大致平行。此外,藉由具備角度調整機構,即可使檢查系統的角度調整自動化。 In addition, the present invention provides an inspection system including: the above-mentioned inspection device; an alignment angle measuring device for obtaining the slow axis of the substrate film before the retardation film is formed; and an angle adjustment mechanism for adjusting The angle of the first linear polarizer is such that the slow axis of the base film obtained by the alignment angle measuring device and the polarization axis of the first linear polarizer become approximately orthogonal or approximately parallel to each other. When the direction of the slow axis of the base film is not clear, by calculating the direction of the slow axis of the base film in advance, the polarization axis of the first linear polarizing plate or the second linear polarizing plate can be arranged with the base material The slow axis of the film is approximately orthogonal or approximately parallel to each other. In addition, by having an angle adjustment mechanism, the angle adjustment of the inspection system can be automated.

依據本發明,即可提供一種檢查方法、檢查裝置及檢查系統,係可抑制基材膜所具有之面內相位差之影響,同時可檢查由聚合性液晶化合物之硬化物所構成之相位差膜有無缺陷。 According to the present invention, it is possible to provide an inspection method, inspection device and inspection system, which can suppress the influence of the in-plane retardation of the substrate film and at the same time inspect the retardation film composed of the cured product of the polymerizable liquid crystal compound Whether there are defects.

1A,1B:檢查裝置 1A, 1B: inspection device

2:光源 2: light source

3:第一直線偏光板 3: The first linear polarizer

4:相位差過濾器 4: Phase difference filter

5:第二直線偏光板 5: The second linear polarizer

6:攝像機(檢測手段) 6: Camera (detection means)

7A,7B:相位差膜 7A, 7B: retardation film

7a:塗覆膜 7a: Coating film

8A,8B:基材膜 8A, 8B: base film

9:光軸 9: Optical axis

10:被檢查物 10: Object to be inspected

12:配向角測量器 12: Orientation angle measurer

14:角度調整機構 14: Angle adjustment mechanism

16:塗覆機 16: Coating machine

18:乾燥器 18: Dryer

100:檢查系統 100: Check the system

A:檢測區域 A: Detection area

圖1係顯示第一實施型態之檢查裝置的圖。 FIG. 1 is a diagram showing the inspection device of the first embodiment.

圖2係顯示第一實施型態之檢查系統的圖。 Fig. 2 is a diagram showing the inspection system of the first embodiment.

圖3係顯示第一實施型態之檢查系統中之複數個檢查裝置之配置的部分立體圖。 3 is a partial perspective view showing the configuration of a plurality of inspection devices in the inspection system of the first embodiment.

圖4係顯示基材膜之遲相軸之情形的俯視圖。 Fig. 4 is a top view showing the state of the slow axis of the base film.

圖5係顯示第二實施型態之檢查裝置的圖。 Fig. 5 is a diagram showing the inspection device of the second embodiment.

以下參照圖式詳細地說明本發明之較佳實施型態。另外,對於各圖中相同部分或相等部分係附上相同符號,重複的說明則予以省略。 The preferred embodiments of the present invention will be described in detail below with reference to the drawings. In addition, the same symbols are attached to the same parts or equivalent parts in each figure, and repeated descriptions are omitted.

(用語及記號的定義) (Definition of terms and signs)

本說明書中的用語及記號的定義係如下所述。 The definitions of terms and symbols in this specification are as follows.

(1)折射率(nx、ny、nz) (1) Refractive index (nx, ny, nz)

「nx」係面內之折射率成為最大之方向(亦即遲相軸方向)的折射率,「ny」係在面內與遲相軸正交的方向,「nz」係厚度方向的折射率。 "Nx" is the refractive index in the direction in which the in-plane refractive index becomes the largest (that is, the slow axis direction), "ny" is in the direction orthogonal to the slow axis in the plane, and "nz" is the refractive index in the thickness direction .

(2)面內相位差值 (2) In-plane phase difference value

面內相位差值(Re(λ))係指23℃、波長λ(nm)下之膜之面內的相位差值。Re(λ)係膜的厚度設為d(nm)時,藉由Re(λ)=(nx-ny)×d而求出。 The in-plane retardation value (Re(λ)) refers to the in-plane retardation value of the film at 23°C and wavelength λ (nm). When the thickness of the Re(λ)-based film is d (nm), it is obtained by Re(λ)=(nx-ny)×d.

(3)厚度方向的相位差值 (3) Retardation value in the thickness direction

厚度方向的相位差值(Rth(λ))係指23℃、波長λ(nm)下之膜之厚度方向的相位差值。Rth(λ)係膜的厚度設為d(nm)時,藉由Rth(λ)=((nx+ny)/2-nz)×d而求出。 The thickness direction retardation value (Rth(λ)) refers to the thickness direction retardation value of the film at 23°C and wavelength λ (nm). When the thickness of the Rth(λ)-based film is d (nm), it is calculated by Rth(λ)=((nx+ny)/2-nz)×d.

<第一實施型態> <First Implementation Type>

(檢查裝置與被檢查物) (Inspection device and inspected object)

本實施型態之檢查裝置係檢查相位差膜有無光學缺陷者。如圖1所示,檢查裝置1A係依序配置光源2、第一直線偏光板3、相位差過濾器4、第二直線偏光板5、及攝像機(檢測手段)6所構成者。檢查裝置1A係在第一直線偏光板3與相位差過濾器4之間備有供配置屬於檢查對象之被檢查物10的場所,在圖1中,係描繪出在該場所配置有被檢查物10的情形。 The inspection device of this embodiment is to inspect the retardation film for optical defects. As shown in FIG. 1, the inspection apparatus 1A is composed of a light source 2, a first linear polarizing plate 3, a phase difference filter 4, a second linear polarizing plate 5, and a camera (detection means) 6 are arranged in this order. The inspection apparatus 1A is provided with a place where the inspection object 10 belonging to the inspection object is arranged between the first linear polarizing plate 3 and the retardation filter 4. In FIG. 1, the inspection object 10 is depicted in this place. Situation.

首先說明屬於檢查對象之膜狀的被檢查物10。被檢查物10係具備有:屬於檢查對象之本體的相位差膜7A、及於單面積層有相位差膜7A的基材膜8A。作為相位差膜7A之一例而言,係與直線偏光板組合而作為圓偏光板被使用於顯示裝置,例如液晶顯示裝置或有機EL顯示裝置者。另外,在本說明書中「圓偏光板」係包含圓偏光板及橢圓偏光板。此外,「圓偏光」係包含圓偏光與橢圓偏光。 First, the film-shaped inspection object 10 belonging to the inspection target will be described. The inspection object 10 includes a retardation film 7A belonging to the main body of the inspection target, and a base film 8A having a retardation film 7A in a single-area layer. As an example of the retardation film 7A, it is used in a display device such as a liquid crystal display device or an organic EL display device as a circular polarizing plate in combination with a linear polarizing plate. In addition, the "circular polarizing plate" in this specification includes a circular polarizing plate and an elliptical polarizing plate. In addition, "circularly polarized light" includes circularly polarized light and elliptical polarized light.

相位差膜7A之一例係將直線偏光轉換為圓偏光的膜。例如,相位差膜7A係λ/4板。在本實施型態中,相位差膜7A係由聚合性液晶化合物的硬化 物所構成。由聚合性液晶化合物之硬化物所構成的相位差膜7A,通常厚度薄至0.2μm至10μm左右,當含有異物等時,相位差值易於在該部分降低。 An example of the retardation film 7A is a film that converts linearly polarized light into circularly polarized light. For example, the retardation film 7A is a λ/4 plate. In this embodiment, the retardation film 7A is cured by a polymerizable liquid crystal compound Constituted by things. The retardation film 7A composed of a cured product of a polymerizable liquid crystal compound is usually as thin as about 0.2 μm to 10 μm in thickness, and when foreign matter or the like is contained, the retardation value tends to decrease in this part.

可供形成相位差膜7A的聚合性液晶化合物,係例如可列舉日本特開2009-173893號公報、日本特開2010-31223號公報、WO2012/147904號公報、WO2014/10325號公報及WO2017-43438號公報所揭示者。此些公報所記載的聚合性液晶化合物係可形成具有所謂逆波長分散性的相位差膜,其係可供在廣波長域進行均勻的偏光轉換。 Examples of polymerizable liquid crystal compounds that can be used to form the retardation film 7A include Japanese Patent Application Publication No. 2009-173893, Japanese Patent Application Publication No. 2010-31223, WO2012/147904, WO2014/10325, and WO2017-43438 No. Bulletin. The polymerizable liquid crystal compound systems described in these publications can form a retardation film having so-called reverse wavelength dispersion, which can allow uniform polarization conversion in a wide wavelength range.

作為相位差膜7A的形成方法而言,係將包含該聚合性液晶化合物的溶液(聚合性液晶化合物溶液:液狀組成物)塗布(塗覆)於基材膜8A上作成塗覆膜,且使之光聚合,從而如上所述可形成極薄者。在此基材膜8A上,為了使聚合性液晶化合物配向亦可設有配向膜。配向膜係可為藉由偏光照射使之光配向者、或藉由研磨處理使之機械性地配向者中的任一者。另外,作為此配向膜的具體例而言,係可使用上述公報所記載者。以此方式所形成的相位差膜7A係連同基材膜8A整個地貼合於其他膜,之後,將基材膜8A剝除,從而可將相位差膜7A轉印至該其他的膜上。 As a method of forming the retardation film 7A, a solution (polymerizable liquid crystal compound solution: liquid composition) containing the polymerizable liquid crystal compound is applied (coated) on the base film 8A to form a coating film, and It is photopolymerized to form an extremely thin one as described above. An alignment film may be provided on this base film 8A in order to align the polymerizable liquid crystal compound. The alignment film may be any one that is photo-aligned by polarized light irradiation or is mechanically aligned by polishing treatment. In addition, as a specific example of this alignment film, those described in the above-mentioned gazette can be used. The retardation film 7A formed in this way is completely bonded to another film together with the base film 8A, and after that, the base film 8A is peeled off, so that the retardation film 7A can be transferred to the other film.

在形成相位差膜7A時,當要塗布聚合性液晶化合物溶液的基材膜8A上存在有異物等,或基材膜8A本身產生了損傷等的情形下,會有塗布聚合性液晶化合物溶液所獲得的塗布膜本身產生缺陷的情形。此外,在將配向膜進行研磨處理的情形下,亦有研磨布的屑殘留於配向膜上,而此屑會使聚合性液晶化合物溶液(液晶硬化膜形成用組成物)的塗布膜產生缺陷的情形。如此,當從聚合性液晶化合物形成相位差膜時,雖可形成厚度極薄的相位差膜,但有以上所述的屑或損傷等成為使該相位差膜產生光學缺陷之要因的情形。 When forming the retardation film 7A, if there are foreign matters on the base film 8A to be coated with the polymerizable liquid crystal compound solution, or the base film 8A itself is damaged, there will be a problem of coating the polymerizable liquid crystal compound solution. The obtained coating film itself has defects. In addition, in the case where the alignment film is subjected to polishing treatment, there are also debris of the polishing cloth remaining on the alignment film, and this debris may cause defects in the coating film of the polymerizable liquid crystal compound solution (liquid crystal cured film formation composition) situation. In this way, when a retardation film is formed from a polymerizable liquid crystal compound, although an extremely thin retardation film can be formed, the above-mentioned dust or damage may cause optical defects in the retardation film.

要塗布聚合性液晶化合物溶液的基材膜8A,在進行相位差膜7A的缺陷檢查時處於與相位差膜7A為積層狀態者,故希望相位差值較小。然而,在本實施型態中,基材膜8A在波長550nm時之面內相位差值為50nm以上。該面內相位差值係可為100nm以上,亦可為500nm以上,亦可為1000nm以上,亦可為2000nm以上,亦可為5000nm以上,亦可為8000nm以上。即使基材膜8A具有此種相位差的情形下,依據本實施型態的檢查裝置,亦可不受到基材膜8A所具有之相位差的影響,而容易地進行相位差膜7A有無缺陷之判斷。 The base film 8A to which the polymerizable liquid crystal compound solution is to be applied is in a laminated state with the retardation film 7A during defect inspection of the retardation film 7A, so it is desirable that the retardation value is small. However, in this embodiment, the in-plane retardation value of the base film 8A at a wavelength of 550 nm is 50 nm or more. The in-plane retardation value may be 100 nm or greater, 500 nm or greater, 1000 nm or greater, 2000 nm or greater, 5000 nm or greater, or 8000 nm or greater. Even in the case where the base film 8A has such a retardation, according to the inspection device of this embodiment, it is not affected by the retardation of the base film 8A, and it is easy to judge whether the retardation film 7A is defective or not. .

以構成基材膜8A的材料而言,係可列舉上述之公報所記載者,其中尤以聚對酞酸乙二酯(Polyethylene Terephthalate,PET)為佳。基材膜8A的厚度係可為10至500μm,亦可為30至300μm,亦可為50至200μm,亦可為80至150μm。 As for the material constituting the base film 8A, those described in the above-mentioned publications can be cited, and among them, polyethylene terephthalate (PET) is particularly preferred. The thickness of the base film 8A may be 10 to 500 μm, 30 to 300 μm, 50 to 200 μm, or 80 to 150 μm.

在檢查裝置1A中,第一直線偏光板3係將從光源2射入的光轉換為直線偏光的膜,且於偏光膜的至少一面貼合有保護膜而成者。以偏光膜而言,係例如可列舉聚乙烯醇(polyvinyl alcohol)膜中吸附配向有碘或二色性色素者、或在配向聚合有聚合性液晶化合物者中吸附配向有二色性色素者。 In the inspection apparatus 1A, the first linear polarizing plate 3 is a film that converts light incident from the light source 2 into linearly polarized light, and a protective film is bonded to at least one surface of the polarizing film. As for the polarizing film, for example, a polyvinyl alcohol (polyvinyl alcohol) film has iodine or a dichroic dye adsorbed and aligned, or a polymerized liquid crystal compound has a polymerizable liquid crystal compound adsorbed and aligned with a dichroic dye.

在此,保護膜係用以保護偏光膜者。以保護膜而言,係以獲得具有適當機械性強度的偏光板為目的,而使用在偏光板的技術領域中所通用者。典型而言,係三醋酸纖維素(triacetyl cellulose)(TAC)膜等纖維素酯(cellulose ester)系膜、環狀烯烴(olefine)系膜、聚對酞酸乙二酯(PET)膜等聚酯(polyester)系膜、聚甲基丙烯酸甲酯(polymetylmethacry late)(PMMA)膜等甲基丙烯酸(methacrylic)系膜等。此外,在偏光板之技術領域所通用的添加劑係可包含在保護膜中。使用於直線偏光板中之保護膜的相位差係以較小為佳,例如,若Re(550)係以10nm以下為佳,且以5nm以下尤佳。 Here, the protective film is used to protect the polarizing film. In terms of the protective film, the purpose is to obtain a polarizing plate with appropriate mechanical strength, and those commonly used in the technical field of polarizing plates are used. Typically, triacetyl cellulose (TAC) film and other cellulose ester film, cyclic olefin (olefine) film, polyethylene terephthalate (PET) film and other poly Methacrylic film such as polyester film, polymetylmethacry late (PMMA) film, etc. In addition, additives commonly used in the technical field of polarizing plates may be included in the protective film. The retardation of the protective film used in the linear polarizing plate is preferably smaller. For example, if Re (550) is preferably 10 nm or less, and 5 nm or less is particularly preferred.

光源2雖可使用各種市售品,但以例如雷射光等直線光(亦包含近似於直線光者)為有利。光源2所發出的光為無偏光,通過第一直線偏光板3而成為預定方向的偏光,又通過相位差膜7A而成為圓偏光。亦即,無偏光的光通過第一直線偏光板3及相位差膜7A從而成為圓偏光。 Although various commercially available products can be used for the light source 2, it is advantageous to use linear light (including those similar to linear light) such as laser light. The light emitted by the light source 2 is unpolarized light, and becomes polarized light in a predetermined direction through the first linear polarizer 3, and becomes circularly polarized light through the retardation film 7A. That is, unpolarized light passes through the first linear polarizing plate 3 and the retardation film 7A to become circularly polarized light.

相位差過濾器4係具備相位差膜7B者。相位差過濾器4係使用在波長550nm時之面內相位差值與屬於檢查對象之相位差膜7A之在波長550nm時之面內相位差值大致相同者。當從亮度(明度)資訊△L*判定光學缺陷時,相位差過濾器4較佳為使用具有與被檢查物10相同之構成的膜。此外,當從色差資訊△E*判定光學缺陷時,相位差過濾器4較佳為使用具有與被檢查物10為相反之波長分散性的膜。以配置相位差過濾器4的方向而言,係設為相位差膜7A的遲相軸與相位差過濾器4的遲相軸為彼此大致正交。亦即,相位差過濾器4在檢查被檢查物10的情形中,總是將其方向調整成為與被檢查物10中的相位差膜7A構成正交偏光鏡。 The retardation filter 4 includes a retardation film 7B. For the retardation filter 4, the in-plane retardation value at the wavelength of 550 nm and the in-plane retardation value at the wavelength of 550 nm of the retardation film 7A belonging to the inspection object are used substantially the same. When determining an optical defect from the brightness (lightness) information ΔL*, the retardation filter 4 preferably uses a film having the same structure as the inspection object 10. In addition, when determining an optical defect from the color difference information ΔE*, the retardation filter 4 preferably uses a film having a wavelength dispersibility opposite to that of the inspection object 10. In terms of the direction in which the retardation filter 4 is arranged, it is assumed that the slow axis of the retardation film 7A and the slow axis of the retardation filter 4 are substantially orthogonal to each other. That is, in the case of inspecting the inspection object 10, the phase difference filter 4 always adjusts its direction so as to form a cross polarizer with the retardation film 7A in the inspection object 10.

此外,相位差過濾器4亦可更具備正C板(plate)。正C板係可設置在與相位差膜7A相向之側的面,亦可設置在其相反側的面。藉由使用正C板從而可擴大檢測區域。正C板之厚度方向的相位差值(Rth(550))係依據要檢查之相位差膜7A之厚度方向的相位差值適當選擇即可,例如當相位差膜7A為λ/4板時,藉由使用厚度方向之相位差值(Rth(550))為-50nm至-300nm者,從而易於獲得效果。 In addition, the phase difference filter 4 may be further equipped with a positive C plate. The positive C plate may be provided on the surface facing the retardation film 7A, or may be provided on the surface on the opposite side. The detection area can be enlarged by using a positive C plate. The thickness direction retardation value (Rth(550)) of the positive C plate can be appropriately selected according to the thickness direction retardation value of the retardation film 7A to be inspected. For example, when the retardation film 7A is a λ/4 plate, By using the thickness direction retardation value (Rth(550)) of -50nm to -300nm, the effect can be easily obtained.

相位差過濾器4亦可為具備相位差膜7B、及積層有相位差膜7B的基材膜8B者。基材膜8B係使用面內相位差值(Re(550))實質為零者,以不損害相位差膜7B的光學特性。在此,面內相位差值實質為零,係指面內相位差值(Re(550))為3nm以下。 The retardation filter 4 may be provided with a retardation film 7B and a base film 8B on which the retardation film 7B is laminated. For the base film 8B, the in-plane retardation value (Re(550)) is substantially zero so as not to impair the optical characteristics of the retardation film 7B. Here, the in-plane retardation value is substantially zero, which means that the in-plane retardation value (Re(550)) is 3 nm or less.

在此,顯示求出在波長550nm時之面內相位差值(Re(550))及厚度方向之相位差值(Rth(550))的方式。如上所述,從測量對象的膜分割例如40mm×40mm左右大小的片(從長條狀膜使用適當的切斷具進行分割等)。測量三次該片的Re(550),且求出Re(550)的平均值。片的Re(550)係使用相位差測量裝置KOBRA-WPR(王子測量機器股份有限公司製),且在測量溫度室溫(23℃)下進行測量。 Here, the method of obtaining the in-plane retardation value (Re(550)) and the thickness direction retardation value (Rth(550)) at a wavelength of 550 nm is shown. As described above, for example, a piece of about 40 mm×40 mm is divided from the film to be measured (divided from a long film using an appropriate cutting tool, etc.). The Re (550) of the piece was measured three times, and the average value of Re (550) was calculated. The Re (550) of the sheet was measured using a phase difference measuring device KOBRA-WPR (manufactured by Oji Measuring Instruments Co., Ltd.), and the measurement temperature was room temperature (23°C).

第二直線偏光板5係供通過相位差過濾器4後之光射入的膜,其構成或材料係與第一直線偏光板3相同。在檢查裝置1A中,第二直線偏光板5係配置成與第一直線偏光板3構成正交偏光鏡。 The second linear polarizing plate 5 is a film into which the light after passing through the phase difference filter 4 enters, and its composition or material is the same as that of the first linear polarizing plate 3. In the inspection apparatus 1A, the second linear polarizer 5 is arranged so as to form an orthogonal polarizer with the first linear polarizer 3.

再者,為了擴大檢測區域,亦可在第一直線偏光板3與基材膜8A之間配置正C板。正C板之厚度方向的相位差值(Rth(550))係依據基材膜8A之厚度方向的相位差值適當地選擇即可,例如藉由設為基材膜8A之厚度方向之相位差值(Rth(550))之1/3至2/3左右之厚度方向的相位差值,從而易於獲得效果。 Furthermore, in order to expand the detection area, a positive C plate may be arranged between the first linear polarizing plate 3 and the base film 8A. The retardation value (Rth(550)) in the thickness direction of the positive C plate can be appropriately selected according to the retardation value in the thickness direction of the base film 8A, for example, by setting the retardation in the thickness direction of the base film 8A The value (Rth(550)) is about 1/3 to 2/3 of the retardation value in the thickness direction, so that the effect is easy to obtain.

在本實施型態之檢查裝置1A中,為了觀察通過第一直線偏光板3、被檢查物10、相位差過濾器4、及第二直線偏光板5的光,在光軸9上,而且與相位差過濾器4之兩側中之具有光源2之側為相反側的位置上配置有攝像機(檢測手段)6。攝像機6係例如為CCD(Charge Coupled Device,電荷耦合元件)攝像機,此時,可藉由CCD攝像機與圖像處理裝置組合而成的圖像處理解析自動地檢測,且藉此進行被檢查物10的檢查。或者,以檢測手段而言,亦可由人取代攝像機6以目視方式觀察第二直線偏光板5。 In the inspection apparatus 1A of this embodiment, in order to observe the light passing through the first linear polarizing plate 3, the inspected object 10, the retardation filter 4, and the second linear polarizing plate 5, the light is on the optical axis 9 and is in phase A camera (detection means) 6 is arranged at a position where the side having the light source 2 among the two sides of the difference filter 4 is the opposite side. The camera 6 is, for example, a CCD (Charge Coupled Device) camera. In this case, it can be automatically detected by image processing analysis combined with a CCD camera and an image processing device, and the object to be inspected 10 can be performed thereby. Inspection. Alternatively, in terms of detection means, a human may replace the camera 6 to observe the second linear polarizing plate 5 visually.

(檢查方法) (Inspection Method)

使用檢查裝置1A的檢查方法係如下所述。首先,在檢查裝置1A之內部中之第一直線偏光板3與相位差過濾器4之間配置被檢查物10。此時,被檢查物10係配置成使其基材膜8A之側朝向第一直線偏光板3側,而且,使基材膜8A的遲相軸與第一直線偏光板3的偏光軸(穿透軸)為彼此大致正交或大致平行。再者,配置成相位差膜7A的遲相軸與相位差過濾器4的遲相軸為彼此大致正交,再者,使第一直線偏光板3與第二直線偏光板5構成正交偏光鏡。 The inspection method using the inspection device 1A is as follows. First, the inspection object 10 is arranged between the first linear polarizing plate 3 and the phase difference filter 4 in the interior of the inspection apparatus 1A. At this time, the inspection object 10 is arranged such that the side of the base film 8A faces the first linear polarizer 3 side, and the slow axis of the base film 8A is aligned with the polarization axis (transmission axis) of the first linear polarizer 3 ) Are approximately orthogonal or approximately parallel to each other. Furthermore, it is arranged such that the slow axis of the retardation film 7A and the slow axis of the retardation filter 4 are approximately orthogonal to each other, and further, the first linear polarizer 3 and the second linear polarizer 5 constitute an orthogonal polarizer. .

從光源2朝向第一直線偏光板3照射光。光源2所發出的光係射入第一直線偏光板3,在此,無偏光的光被轉換為直線偏光。再者,該直線偏光係從基材膜8A側射入至被檢查物10。通過基材膜8A後的直線偏光,係通過相位差膜7A而成為圓偏光。該圓偏光係從相位差膜7B之側射入至相位差過濾器4。在此,相位差膜7A的遲相軸、與相位差過濾器4的遲相軸係彼此大致正交,而且,相位差膜7A在波長550nm時之面內相位差值與相位差過濾器4在波長550nm時之面內相位差值係彼此大致相同,故通過相位差過濾器4後的光,係被轉換成原來的直線偏光。再者,通過相位差過濾器4後的光係接著射入至第二直線偏光板5。第二直線偏光板5係被作成與第一直線偏光板3為正交偏光鏡的配置,亦即第一直線偏光板3的穿透軸與第二直線偏光板5的吸收軸成為平行,故通過相位差過濾器4而恢復為直線偏光的光係被第二直線偏光板5阻斷。在此檢查中,當被檢查物10中的相位差膜7A不存在缺陷時,在藉由攝像機6的觀察中,第二直線偏光板5整面看起來為均勻的黑色。相對於此,當被檢查物10中的相位差膜7A存在缺陷時,通過此缺陷部分的光會以不完全變為所設想之圓偏光(橢圓偏光)的狀態射入相位差過濾器4。再者,該圓偏光(橢圓偏光)在通過相位差過濾器4時無法恢復為正 常的直線偏光,而成為橢圓偏光。因此,第二直線偏光板5無法進行正規的阻斷而使光洩漏,在藉由攝像機6的觀察上,該缺陷部分即會作為亮點被觀察到。 Light is irradiated from the light source 2 toward the first linear polarizing plate 3. The light emitted by the light source 2 is incident on the first linear polarizing plate 3, where the unpolarized light is converted into linearly polarized light. In addition, this linear polarization system is incident on the inspection object 10 from the base film 8A side. The linearly polarized light after passing through the base film 8A passes through the retardation film 7A to become circularly polarized light. This circularly polarized light enters the retardation filter 4 from the side of the retardation film 7B. Here, the retardation axis of the retardation film 7A and the retardation axis of the retardation filter 4 are approximately orthogonal to each other, and the in-plane retardation value of the retardation film 7A at a wavelength of 550 nm and the retardation filter 4 The in-plane retardation values at a wavelength of 550 nm are approximately the same as each other, so the light passing through the retardation filter 4 is converted into the original linearly polarized light. Furthermore, the light system that has passed through the phase difference filter 4 is then incident on the second linear polarizing plate 5. The second linear polarizer 5 is configured to be orthogonal to the first linear polarizer 3, that is, the penetration axis of the first linear polarizer 3 and the absorption axis of the second linear polarizer 5 become parallel, so it passes through the phase The optical system restored to the linearly polarized light by the difference filter 4 is blocked by the second linear polarizing plate 5. In this inspection, when there is no defect in the retardation film 7A in the inspected object 10, the entire surface of the second linear polarizing plate 5 appears uniformly black when viewed by the camera 6. On the other hand, when the retardation film 7A in the inspection object 10 has a defect, the light passing through the defect portion enters the retardation filter 4 in a state where it does not completely become the supposed circularly polarized light (elliptical polarized light). Furthermore, the circularly polarized light (elliptical polarized light) cannot be restored to positive when it passes through the phase difference filter 4. Normal linear polarized light becomes elliptical polarized light. Therefore, the second linear polarizing plate 5 cannot be properly blocked to allow light to leak, and the defective part is observed as a bright spot in the observation by the camera 6.

在此,基材膜8A係具有「在波長550nm時之面內相位差值為50nm以上」的相位差,故通過第一直線偏光板3後之光的偏光狀態可能會因為基材膜8A被攪亂。然而,在本實施型態的檢查方法中,係將第一直線偏光板3的偏光軸配置成相對於具有相位差之基材膜8A的遲相軸為彼此大致正交或大致平行,故通過第一直線偏光板3後之光的偏光狀態不會因為基材膜8A而被攪亂。亦即,組成的光學系統如預期地發揮作用,且當相位差膜7A產生缺陷時在觀察視野上可適當地辨識該缺陷。以往當基材膜8A的面內相位差值為50nm以上時,通過第一直線偏光板3後的光會因為基材膜8A所具有的相位差而成為圓偏光(橢圓偏光),結果,從第二直線偏光板5洩漏的光變多,而成為檢查的障礙。因此,依據本實施型態的檢查方法,可抑制基材膜8A所具有之面內相位差的影響,同時易於判斷相位差膜有無缺陷。 Here, the base film 8A has a retardation of "the in-plane retardation value at a wavelength of 550 nm is 50 nm or more." Therefore, the polarization state of the light after passing through the first linear polarizer 3 may be disturbed by the base film 8A. . However, in the inspection method of this embodiment, the polarization axis of the first linear polarizer 3 is arranged so that the slow axis of the base film 8A with phase difference is substantially orthogonal or substantially parallel to each other, so the first linear polarizer 3 The polarization state of the light behind the linear polarizing plate 3 will not be disturbed by the base film 8A. That is, the composed optical system functions as expected, and when a defect occurs in the retardation film 7A, the defect can be appropriately recognized in the observation field of view. Conventionally, when the in-plane retardation value of the base film 8A is 50 nm or more, the light after passing through the first linear polarizing plate 3 will become circularly polarized light (elliptical polarized light) due to the retardation of the base film 8A. The leakage of light from the two linear polarizers 5 increases, which becomes an obstacle to inspection. Therefore, according to the inspection method of this embodiment, the influence of the in-plane retardation of the base film 8A can be suppressed, and at the same time, it is easy to determine whether the retardation film has defects.

(連續檢查方法) (Continuous inspection method)

如圖2所示,本實施型態之檢查方法,係可併同在基材膜8A上連續形成相位差膜7A的步驟,而在與該步驟相同的製造生產線上連續地進行。圖2所示之檢查系統100除上述的檢查裝置1A外,還具備有下列元件而於生產線上進行被檢查物10的檢查:配向角測量器12,係求出形成相位差膜7A之前之基材膜8A之遲相軸(配向角)的方向;及角度調整機構14,係將第一直線偏光板3的角度調整成為使經由配向角測量器12所求出之基材膜8A的遲相軸與第一直線偏光板3之偏光軸成為彼此大致正交或大致平行。在此,被檢查物10係一面被搬運一面通過檢查裝 置1A之光軸9內,接受有無缺陷的檢查。再者,結束檢查後的被檢查物10被捲起。另外,在此,基材膜8A的寬度係可例如為0.5至2.0m,亦可為1.0至1.5m。 As shown in FIG. 2, the inspection method of this embodiment can be combined with the step of continuously forming the retardation film 7A on the base film 8A, and can be continuously performed on the same manufacturing line as this step. The inspection system 100 shown in FIG. 2 is equipped with the following components in addition to the inspection device 1A described above to inspect the inspection object 10 on the production line: the alignment angle measuring device 12 is used to determine the basis before the formation of the retardation film 7A The direction of the late axis (alignment angle) of the material film 8A; and the angle adjustment mechanism 14, which adjusts the angle of the first linear polarizer 3 to the late axis of the base film 8A obtained by the alignment angle measuring device 12 The polarization axes of the first linear polarizer 3 and the first linear polarizer 3 are substantially orthogonal or substantially parallel to each other. Here, the inspection object 10 is passed through the inspection equipment while being transported. Set in the optical axis 9 of 1A, and accept the inspection for defects. Furthermore, the inspection object 10 after the inspection is finished is rolled up. In addition, here, the width of the base film 8A may be, for example, 0.5 to 2.0 m, or 1.0 to 1.5 m.

如圖3所示,檢查系統100係在被檢查物10的整個寬度方向(垂直於搬運方向的方向)上配置有複數個檢查裝置1A。檢查裝置1A較佳為在被檢查物10的整個寬度方向上例如配置5至20處。在圖3中係配置有五個檢查裝置1A。 As shown in FIG. 3, in the inspection system 100, a plurality of inspection devices 1A are arranged in the entire width direction of the inspection object 10 (the direction perpendicular to the conveying direction). The inspection apparatus 1A is preferably arranged at 5 to 20 locations in the entire width direction of the inspection object 10, for example. In Fig. 3, five inspection devices 1A are arranged.

在圖2所示之製造生產線中,係搬運長條狀的基材膜8A,同時以配向角測量器12來測量基材膜8A之遲相軸的方向。此時,當基材膜8A為藉由延展所製造者時,如圖4所示,遲相軸的方向在其寬度方向上產生了變化。在圖4中,箭頭係表示在該部分中之遲相軸的方向。因此,藉由配向角測量器12所作的測量,係在基材膜8A之整個寬度方向上的複數個位置進行。配向角測量器12係將所測量之遲相軸的資訊提供給角度調整機構14。之後,一面搬運基材膜8A一面藉由塗覆機16將聚合性液晶化合物溶液塗布於基材膜8A上而作成塗覆膜7a,且藉由配置在塗覆機16之下游側的乾燥器18使塗覆膜7a乾燥。在此,所塗覆的聚合性液晶化合物係在基材膜8A上配向,且藉由乾燥、聚合進行硬化而成為相位差膜7A。乾燥後的膜即為被檢查物10,提供給配置於搬運之下游側之檢查裝置1A進行檢查。 In the manufacturing line shown in FIG. 2, the long substrate film 8A is conveyed, and the orientation angle measuring device 12 is used to measure the direction of the slow axis of the substrate film 8A. At this time, when the base film 8A is manufactured by stretching, as shown in FIG. 4, the direction of the slow axis changes in its width direction. In Fig. 4, the arrow indicates the direction of the slow axis in this part. Therefore, the measurement by the alignment angle measuring device 12 is performed at a plurality of positions in the entire width direction of the base film 8A. The alignment angle measuring device 12 provides the angle adjustment mechanism 14 with the information of the measured lag phase axis. After that, while conveying the base film 8A, the polymerizable liquid crystal compound solution was coated on the base film 8A by the coating machine 16 to form the coating film 7a, and the coating film 7a was formed by a dryer disposed on the downstream side of the coating machine 16. 18 The coating film 7a is dried. Here, the applied polymerizable liquid crystal compound is aligned on the base film 8A, and is cured by drying and polymerization to become the retardation film 7A. The dried film is the inspection object 10, and is provided to the inspection device 1A arranged on the downstream side of the conveyance for inspection.

角度調整機構14係根據從配向角測量器12所提供之基材膜8A之遲相軸方向的資訊,使第一直線偏光板3旋轉,且使第一直線偏光板3的偏光軸成為與基材膜8A的遲相軸大致正交或大致平行。同時,關於相位差過濾器4及第二直線偏光板5,亦使之旋轉以成為上述預定的關係。配置在被檢查物10之寬度方向上的複數個檢查裝置1A,係分別被分配有檢測區域A(參照圖3),被檢查物10係涵蓋寬度方向所有的區域而被檢查。在檢查中,係由角度調整機構14因應基材膜 8A的遲相軸在整個寬度方向上產生變化乙事,依每一檢測區域A使第一直線偏光板3的偏光軸所朝向的方向不同。另外,圖4所示之檢測區域A,係顯示基材膜8A上之圖3所示之檢測區域A所對應的部分。 The angle adjustment mechanism 14 rotates the first linear polarizer 3 based on the information of the slow axis direction of the substrate film 8A provided from the alignment angle measuring device 12, and makes the polarization axis of the first linear polarizer 3 coincide with the substrate film The slow axis of 8A is approximately orthogonal or approximately parallel. At the same time, regarding the phase difference filter 4 and the second linear polarizing plate 5, they are also rotated so as to become the above-mentioned predetermined relationship. The plurality of inspection devices 1A arranged in the width direction of the inspection object 10 are each assigned a detection area A (see FIG. 3), and the inspection object 10 covers all areas in the width direction and is inspected. During the inspection, the angle adjustment mechanism 14 responds to the base film The slow axis of 8A changes in the entire width direction. The direction in which the polarization axis of the first linear polarizer 3 faces is different for each detection area A. In addition, the detection area A shown in FIG. 4 shows the portion corresponding to the detection area A shown in FIG. 3 on the base film 8A.

藉由使用檢查系統100,可遍及基材膜8A的整個搬運方向連續地且效率良好地實施相位差膜7A的形成與檢查,因此可使被檢查物10的製造與檢查效率化。此外,在檢查系統100中係在被檢查物10的寬度方向上配置有複數個檢查裝置1A,故即使基材膜8A之遲相軸之方向在寬度方向上有所不同時,亦可將各個檢查裝置1A中之第一直線偏光板3的偏光軸與基材膜8A在該檢測區域A中之遲相軸的關係調整為預定的關係。亦即,在基材膜8A之寬度方向之所有的位置,可進行抑制基材膜8A所具有之面內相位差之影響的檢查。 By using the inspection system 100, the formation and inspection of the retardation film 7A can be performed continuously and efficiently throughout the entire conveyance direction of the base film 8A, and therefore, the production and inspection of the inspection object 10 can be made more efficient. In addition, in the inspection system 100, a plurality of inspection devices 1A are arranged in the width direction of the inspection object 10. Therefore, even if the direction of the slow axis of the base film 8A is different in the width direction, each The relationship between the polarization axis of the first linear polarizer 3 in the inspection device 1A and the slow axis of the base film 8A in the detection area A is adjusted to a predetermined relationship. That is, at all positions in the width direction of the base film 8A, inspections that suppress the influence of the in-plane retardation of the base film 8A can be performed.

<第二實施型態> <Second Implementation Type>

茲說明本發明的第二實施型態。作為第二實施型態,圖5所示的檢查裝置1B與第一實施型態之檢查裝置1A不同之點,係在於光源2與檢測手段的位置為相反之處。亦即,檢查裝置1B係依序配置攝像機(檢測手段)6、第一直線偏光板3、相位差過濾器4、第二直線偏光板5、及光源2而成者。在圖5中,係描繪出在第一直線偏光板3與相位差過濾器4之間配置有屬於檢查對象之被檢查物10的情形。在此,關於被檢查物10與第二直線偏光板5的配置,係配置成使基材膜8A的遲相軸與第二直線偏光板5的偏光軸為彼此大致正交或大致平行。 The second embodiment of the present invention is described here. As the second embodiment, the inspection device 1B shown in FIG. 5 is different from the inspection device 1A of the first embodiment in that the positions of the light source 2 and the detection means are opposite. In other words, the inspection device 1B is configured by sequentially arranging a camera (detection means) 6, a first linear polarizing plate 3, a phase difference filter 4, a second linear polarizing plate 5, and a light source 2 in this order. In FIG. 5, the state where the inspection object 10 belonging to the inspection target is arranged between the first linear polarizing plate 3 and the phase difference filter 4 is depicted. Here, regarding the arrangement of the inspection object 10 and the second linear polarizing plate 5, they are arranged so that the slow axis of the base film 8A and the polarization axis of the second linear polarizing plate 5 are substantially orthogonal or substantially parallel to each other.

在使用了此檢查裝置1B之被檢查物10的檢查中,亦可藉由與第一實施型態相同的原理而易於檢查相位差膜7A有無缺陷。 In the inspection of the inspection object 10 using this inspection apparatus 1B, it is also easy to inspect the retardation film 7A for defects by the same principle as in the first embodiment.

綜上雖已說明了本發明之較佳實施型態,但本發明不限定於上述實施型態。 In summary, although the preferred embodiments of the present invention have been described, the present invention is not limited to the above-mentioned embodiments.

[產業上之可利用性] [Industrial availability]

本發明係可利用於判斷相位差膜有無缺陷的檢查上。 The present invention can be used in inspections for judging the presence or absence of defects in the retardation film.

1A:檢查裝置 1A: Inspection device

2:光源 2: light source

3:第一直線偏光板 3: The first linear polarizer

4:相位差過濾器 4: Phase difference filter

5:第二直線偏光板 5: The second linear polarizer

6:攝像機(檢測手段) 6: Camera (detection means)

7A,7B:相位差膜 7A, 7B: retardation film

8A,8B:基材膜 8A, 8B: base film

9:光軸 9: Optical axis

10:被檢查物 10: Object to be inspected

Claims (7)

一種檢查方法,係將光射入至膜狀的被檢查物以判斷相位差膜有無缺陷,該膜狀的被檢查物係具備在波長550nm時之面內相位差值為50nm以上的基材膜、及形成於前述基材膜之單面之由聚合性液晶化合物之硬化物所構成的前述相位差膜;於前述檢查方法中, An inspection method in which light is injected into a film-like inspection object to determine whether the retardation film is defective. The film-like inspection object is equipped with a base film with an in-plane retardation value of 50nm or more at a wavelength of 550nm , And the aforementioned retardation film composed of a cured product of a polymerizable liquid crystal compound formed on one side of the aforementioned base film; in the aforementioned inspection method, 係將第一直線偏光板、前述被檢查物、相位差過濾器、第二直線偏光板依序排列地配置, The first linear polarizing plate, the aforementioned inspection object, the phase difference filter, and the second linear polarizing plate are arranged in order, 前述被檢查物之前述基材膜側的面係朝向前述第一直線偏光板側, The surface on the side of the substrate film of the inspection object faces the side of the first linear polarizing plate, 前述基材膜的遲相軸、與前述第一直線偏光板或前述第二直線偏光板的偏光軸係彼此大致正交或大致平行, The slow axis of the base film and the polarization axis of the first linear polarizer or the second linear polarizer are substantially orthogonal or substantially parallel to each other, 前述相位差膜的遲相軸、與前述相位差過濾器的遲相軸係彼此大致正交, The slow axis of the retardation film and the slow axis of the retardation filter are approximately orthogonal to each other, 前述相位差膜之在波長550nm時之面內相位差值、與前述相位差過濾器之在波長550nm時之面內相位差值係彼此大致相同, The in-plane retardation value of the aforementioned retardation film at a wavelength of 550nm and the in-plane retardation value of the aforementioned retardation filter at a wavelength of 550nm are approximately the same as each other, 前述第一直線偏光板與前述第二直線偏光板係構成正交偏光鏡,且 The first linear polarizer and the second linear polarizer constitute an orthogonal polarizer, and 從前述第一直線偏光板側或前述第二直線偏光板側的任一側,以光軸通過前述被檢查物上之預定之檢查區域之方式射入光,且從前述第一直線偏光板側或前述第二直線偏光板側的另一側觀察前述第二直線偏光板或前述第一直線偏光板。 Light is incident from either the first linear polarizing plate side or the second linear polarizing plate side so that the optical axis passes through the predetermined inspection area on the inspection object, and from the first linear polarizing plate side or the aforementioned Observe the second linear polarizing plate or the first linear polarizing plate on the other side of the second linear polarizing plate side. 如請求項1所述之檢查方法,係具有:以形成前述相位差膜之前之前述基材膜為對象,使用配向角測量器而預先求出前述基材膜之遲相軸之方向的步驟。 The inspection method according to claim 1 includes a step of obtaining the direction of the retardation axis of the base film in advance by using an orientation angle measuring device for the base film before forming the retardation film. 如請求項2所述之檢查方法,係具有:在藉由前述配向角測量器求出前述基材膜的遲相軸之後,在前述基材膜的單面,塗覆包含聚合性液晶化合物的液狀組成物而將包含前述聚合性液晶化合物的塗覆膜形成於前述基材膜的表面上,使前述塗覆膜中所含之前述聚合性液晶化合物配向及硬化而形成前述相位差膜的步驟。 The inspection method according to claim 2 includes: after the lag axis of the base film is obtained by the alignment angle measuring device, one side of the base film is coated with a polymerizable liquid crystal compound Liquid composition, a coating film containing the polymerizable liquid crystal compound is formed on the surface of the base film, and the polymerizable liquid crystal compound contained in the coating film is aligned and cured to form the retardation film step. 如請求項1至3中任一項所述之檢查方法,係使前述被檢查物在前述第一直線偏光板與前述相位差過濾器之間朝前述被檢查物的長邊方向搬運,同時朝前述長邊方向連續地進行檢查。 According to the inspection method described in any one of claims 1 to 3, the inspection object is conveyed between the first linear polarizing plate and the retardation filter in the longitudinal direction of the inspection object, and at the same time The inspection is carried out continuously in the longitudinal direction. 如請求項1至4中任一項所述之檢查方法,係在前述被檢查物的寬度方向上設置複數處前述檢測區域。 In the inspection method described in any one of claims 1 to 4, the inspection area is provided at a plurality of locations in the width direction of the inspection object. 一種檢查裝置,係將光射入至膜狀的被檢查物以判斷相位差膜有無缺陷,該膜狀的被檢查物係具備在波長550nm時之面內相位差值為50nm以上的基材膜、及形成於前述基材膜之單面之由聚合性液晶化合物之硬化物所構成的前述相位差膜,該檢查裝置係具備: An inspection device that injects light into a film-like inspection object to determine whether the retardation film is defective. The film-like inspection object is equipped with a base film with an in-plane retardation value of 50nm or more at a wavelength of 550nm , And the aforementioned retardation film composed of a cured product of a polymerizable liquid crystal compound formed on one side of the aforementioned base film, and the inspection device is provided with: 第一直線偏光板及相位差過濾器,係隔著供前述被檢查物配置之場所而配置; The first linear polarizer and the phase difference filter are arranged across the place where the inspection object is arranged; 第二直線偏光板,係就前述相位差過濾器而言配置在與供前述被檢查物配置之場所為相反側的區域;及 The second linear polarizing plate is arranged in an area on the opposite side of the place where the inspection object is arranged in terms of the phase difference filter; and 光源,係就前述第一直線偏光板或前述第二直線偏光板而言配置在與供前述被檢查物配置之場所為相反側的區域; The light source, in terms of the first linear polarizing plate or the second linear polarizing plate, is arranged in an area on the opposite side to the place where the inspection object is arranged; 前述第一直線偏光板或前述第二直線偏光板係配置成其偏光軸與前述基材膜的遲相軸為彼此大致正交或大致平行, The first linear polarizing plate or the second linear polarizing plate is arranged such that its polarization axis and the slow axis of the base film are substantially orthogonal or substantially parallel to each other, 前述相位差過濾器係配置成其遲相軸與前述相位差膜的遲相軸為彼此大致正交, The retardation filter is arranged such that its slow axis and the slow axis of the retardation film are substantially orthogonal to each other, 前述第一直線偏光板與前述第二直線偏光板係構成正交偏光鏡, The first linear polarizing plate and the second linear polarizing plate form an orthogonal polarizer, 前述相位差過濾器之在波長550nm時之面內相位差係被設為與前述相位差膜之在波長550nm時之面內相位差值大致相同,且 The in-plane retardation of the aforementioned retardation filter at a wavelength of 550nm is set to be approximately the same as the in-plane retardation value of the aforementioned retardation film at a wavelength of 550nm, and 前述光源係配置在於其光軸上排列有前述第一直線偏光板、前述被檢查物上之預定的檢測區域、前述相位差過濾器、及前述第二直線偏光板的位置。 The light source is arranged in positions where the first linear polarizing plate, the predetermined detection area on the inspection object, the phase difference filter, and the second linear polarizing plate are arranged on the optical axis. 一種檢查系統,係具備: An inspection system with: 請求項6所述之檢查裝置; The inspection device described in claim 6; 配向角測量器,係求出形成前述相位差膜之前之前述基材膜的遲相軸;及 An alignment angle measuring device to obtain the slow axis of the base film before the retardation film is formed; and 角度調整機構,係調整前述第一直線偏光板的角度,以使藉由前述配向角測量器所求出之前述基材膜的遲相軸與前述第一直線偏光板的偏光軸成為彼此大致正交或大致平行。 The angle adjustment mechanism adjusts the angle of the first linear polarizer so that the slow axis of the base film and the polarization axis of the first linear polarizer obtained by the alignment angle measuring device become approximately orthogonal to each other or Roughly parallel.
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