TW202101647A - Carrier for back end of line processing - Google Patents
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- TW202101647A TW202101647A TW109120564A TW109120564A TW202101647A TW 202101647 A TW202101647 A TW 202101647A TW 109120564 A TW109120564 A TW 109120564A TW 109120564 A TW109120564 A TW 109120564A TW 202101647 A TW202101647 A TW 202101647A
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- H01L25/00—Assemblies consisting of a plurality of individual semiconductor or other solid state devices ; Multistep manufacturing processes thereof
- H01L25/50—Multistep manufacturing processes of assemblies consisting of devices, each device being of a type provided for in group H01L27/00 or H01L29/00
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- H—ELECTRICITY
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/683—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping
- H01L21/6835—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping using temporarily an auxiliary support
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C15/00—Surface treatment of glass, not in the form of fibres or filaments, by etching
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- H—ELECTRICITY
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- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/302—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
- H01L21/304—Mechanical treatment, e.g. grinding, polishing, cutting
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- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/77—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate
- H01L21/78—Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices
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- H01L24/00—Arrangements for connecting or disconnecting semiconductor or solid-state bodies; Methods or apparatus related thereto
- H01L24/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L24/26—Layer connectors, e.g. plate connectors, solder or adhesive layers; Manufacturing methods related thereto
- H01L24/28—Structure, shape, material or disposition of the layer connectors prior to the connecting process
- H01L24/29—Structure, shape, material or disposition of the layer connectors prior to the connecting process of an individual layer connector
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- H—ELECTRICITY
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- H01L24/80—Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected
- H01L24/83—Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected using a layer connector
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- H—ELECTRICITY
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L25/00—Assemblies consisting of a plurality of individual semiconductor or other solid state devices ; Multistep manufacturing processes thereof
- H01L25/16—Assemblies consisting of a plurality of individual semiconductor or other solid state devices ; Multistep manufacturing processes thereof the devices being of types provided for in two or more different main groups of groups H01L27/00 - H01L33/00, or in a single subclass of H10K, H10N, e.g. forming hybrid circuits
- H01L25/162—Assemblies consisting of a plurality of individual semiconductor or other solid state devices ; Multistep manufacturing processes thereof the devices being of types provided for in two or more different main groups of groups H01L27/00 - H01L33/00, or in a single subclass of H10K, H10N, e.g. forming hybrid circuits the devices being mounted on two or more different substrates
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- H—ELECTRICITY
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- H01L2221/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof covered by H01L21/00
- H01L2221/67—Apparatus for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components; Apparatus not specifically provided for elsewhere
- H01L2221/683—Apparatus for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components; Apparatus not specifically provided for elsewhere for supporting or gripping
- H01L2221/68304—Apparatus for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components; Apparatus not specifically provided for elsewhere for supporting or gripping using temporarily an auxiliary support
- H01L2221/68313—Auxiliary support including a cavity for storing a finished device, e.g. IC package, or a partly finished device, e.g. die, during manufacturing or mounting
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- H—ELECTRICITY
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2221/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof covered by H01L21/00
- H01L2221/67—Apparatus for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components; Apparatus not specifically provided for elsewhere
- H01L2221/683—Apparatus for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components; Apparatus not specifically provided for elsewhere for supporting or gripping
- H01L2221/68304—Apparatus for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components; Apparatus not specifically provided for elsewhere for supporting or gripping using temporarily an auxiliary support
- H01L2221/68327—Apparatus for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components; Apparatus not specifically provided for elsewhere for supporting or gripping using temporarily an auxiliary support used during dicing or grinding
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- H—ELECTRICITY
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- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/26—Layer connectors, e.g. plate connectors, solder or adhesive layers; Manufacturing methods related thereto
- H01L2224/28—Structure, shape, material or disposition of the layer connectors prior to the connecting process
- H01L2224/29—Structure, shape, material or disposition of the layer connectors prior to the connecting process of an individual layer connector
- H01L2224/29001—Core members of the layer connector
- H01L2224/2901—Shape
- H01L2224/29016—Shape in side view
- H01L2224/29018—Shape in side view comprising protrusions or indentations
- H01L2224/29019—Shape in side view comprising protrusions or indentations at the bonding interface of the layer connector, i.e. on the surface of the layer connector
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/80—Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected
- H01L2224/83—Methods for connecting semiconductor or other solid state bodies using means for bonding being attached to, or being formed on, the surface to be connected using a layer connector
- H01L2224/83009—Pre-treatment of the layer connector or the bonding area
Abstract
Description
本案主張以2019年6月20日提出申請之美國專利臨時申請案62/864,139號為優先權,該申請案全文皆以引用方式納入本說明書中以供參照。This case claims priority to the U.S. Provisional Application No. 62/864,139 filed on June 20, 2019. The full text of this application is incorporated into this specification by reference for reference.
本案大體上涉及積體電路製造。更具體而言,本案係涉及電子元件之互連。This case generally involves integrated circuit manufacturing. More specifically, this case relates to the interconnection of electronic components.
在諸如電晶體、電容器及電阻器等之個別元件形式的IC部件被製造出來之後,產線後段(BEOL)處理為積體電路(IC)製造之第二主要步驟。進行BEOL處理以在個別元件之間沉積金屬佈線,以透過金屬化使元件互連。BEOL包含許多步驟,包括將晶圓與支撐結構分離,該過程稱為剝離。After IC components in the form of individual components such as transistors, capacitors, and resistors are manufactured, the post-production (BEOL) process is the second major step in integrated circuit (IC) manufacturing. Perform BEOL processing to deposit metal wiring between individual components to interconnect the components through metallization. BEOL involves many steps, including separating the wafer from the support structure, a process called peeling.
本案涉及在保護晶圓免於損壞的同時簡化BEOL處理之技術。具體而言,如以下參考示例性非限制實施例所更詳細地描述,本案提出了簡化將晶圓傳送至切割平台之步驟以增加晶圓產量(亦即,無須因製造缺陷而被丟棄之晶圓比例)的裝置及方法。This case involves technologies that simplify BEOL processing while protecting the wafers from damage. Specifically, as described in more detail below with reference to exemplary non-limiting embodiments, this case proposes to simplify the step of transferring wafers to the dicing platform to increase wafer yield (that is, wafers that do not need to be discarded due to manufacturing defects) Circle ratio) device and method.
本案之至少一個實施例涉及一種用於支撐晶圓的載體組件,包括在BEOL處理期間。載體組件包括雙載體。第一載體包括階梯狀結構以便放置晶圓。晶圓之一側在無黏合劑的情況下結合至第一載體。第一載體係位於第二載體之頂部,從而被第二載體機械地支撐。每個載體皆由濕式蝕刻積層玻璃而製成,且未經機械拋光。At least one embodiment of this case relates to a carrier assembly for supporting wafers, including during BEOL processing. The carrier component includes a dual carrier. The first carrier includes a stepped structure for placing wafers. One side of the wafer is bonded to the first carrier without adhesive. The first carrier system is located on top of the second carrier so as to be mechanically supported by the second carrier. Each carrier is made of wet-etched laminated glass and is not mechanically polished.
本案之至少一個實施例涉及一種用於在處理期間支撐晶圓的方法。該方法包括將晶圓置於第一載體,並以至少部分地設置於第一載體下方之第二載體來支撐第一載體。第一載體與第二載體形成了供放置晶圓之雙載體。該方法進一步包括將晶圓原位傳送至切割平台,以在雙載體中對晶圓進行切割。At least one embodiment of this case relates to a method for supporting a wafer during processing. The method includes placing the wafer on a first carrier, and supporting the first carrier with a second carrier at least partially disposed under the first carrier. The first carrier and the second carrier form a dual carrier for placing wafers. The method further includes transferring the wafer in situ to a cutting platform to cut the wafer in the dual carrier.
另外,本案之至少一個實施例涉及一種製造載體組件的方法。該方法包括透過以下步驟來建構載體組件的第一載體:將第一載體之一第一覆層附接至一第一芯層;以及將第一載體之一第二覆層附接至該第一芯層,使得該第一芯層被夾在第一載體之該第一覆層與該第二覆層之間。該方法進一步包括:在第一載體上進行第一蝕刻製程以暴露該第一芯層的一部分;以及在第一載體上進行第二蝕刻製程以形成一通孔。該通孔之形成將第一載體分成第一區段及第二區段。In addition, at least one embodiment of this case relates to a method of manufacturing a carrier assembly. The method includes constructing a first carrier of a carrier assembly by the following steps: attaching a first cladding layer of the first carrier to a first core layer; and attaching a second cladding layer of the first carrier to the first core layer A core layer such that the first core layer is sandwiched between the first cladding layer and the second cladding layer of the first carrier. The method further includes: performing a first etching process on the first carrier to expose a portion of the first core layer; and performing a second etching process on the first carrier to form a through hole. The formation of the through hole divides the first carrier into a first section and a second section.
當配合附圖進行以下詳細描述時,該等與其他特徵併同其組織及操作方式將變得顯而易見,其中貫穿以下所描述的幾個附圖,相同的元件具有相同的元件符號。應當理解,前述概念及以下更詳細討論之附加概念的所有組合(當該等概念不相互矛盾時)皆被認為是本案所揭示標的之一部分。具體而言,於本案最後出現的請求標的之所有組合皆被認為是本案所揭示標的之一部分。When the following detailed descriptions are made in conjunction with the accompanying drawings, these and other features, as well as their organization and operation methods, will become apparent. Throughout the several drawings described below, the same elements have the same element symbols. It should be understood that all combinations of the aforementioned concepts and the additional concepts discussed in more detail below (when these concepts are not contradictory) are considered to be part of the subject matter disclosed in this case. Specifically, all combinations of the requested subject matter that appeared at the end of the case are considered to be part of the subject matter disclosed in the case.
各種示例實施例提供了雙載體,以便在BEOL處理期間支撐晶圓,例如矽(Si)晶圓。更具體而言,雙載體係由兩個載體片所形成,第一載體位於第二載體的頂部,如以下所述。在BEOL處理的多個階段期間,雙載體的至少一部分支撐晶圓。此外,雙載體的至少一部分在切割期間支撐晶圓,並且在切割之後支撐個別晶粒,因此不需要單獨的剝離過程。Various example embodiments provide dual carriers to support wafers, such as silicon (Si) wafers, during BEOL processing. More specifically, the dual carrier system is formed by two carrier sheets, with the first carrier on top of the second carrier, as described below. During multiple stages of BEOL processing, at least a portion of the dual carrier supports the wafer. In addition, at least a part of the dual carrier supports the wafer during dicing and supports individual dies after dicing, so a separate peeling process is not required.
在至少一個實施例中,雙載體100為玻璃製品。在至少一個實施例中,玻璃製品可為如2017年6月22日公開的美國專利申請公開號2017/0174564中所述之玻璃製品,其為2015年3月25日提出之美國專利申請號15/129,278的申請公開,其全部內容皆以引用方式併入本案,包括其中所闡述之組合物及方法。In at least one embodiment, the
第7圖描繪了根據至少一個實施例的玻璃製品。如本文所用,用語「平均熱膨脹係數」係指一給定材料或層在0℃至300℃之間的平均熱膨脹係數。如本文所用,用語「熱膨脹係數」係指平均熱膨脹係數,除非另有說明。Figure 7 depicts a glass product according to at least one embodiment. As used herein, the term "average thermal expansion coefficient" refers to the average thermal expansion coefficient of a given material or layer between 0°C and 300°C. As used herein, the term "coefficient of thermal expansion" refers to the average coefficient of thermal expansion, unless otherwise stated.
根據於ASTM C1499-08先進陶瓷在環境溫度下的單調等雙軸彎曲強度的標準測試方法中所述之測試方法,使用環對環負載來測定本文所述之至少一種玻璃製品的強度。通常,環對環負載測試方法係用於在單調單軸負載下透過同心環構型來測定環境溫度下先進脆性材料的雙軸強度,其已被廣泛地用作為評估玻璃製品表面強度的方法。本文所述之環對環負載結果是在2英寸的方形玻璃板上使用直徑為1英寸的支撐環及直徑為0.5英寸的負載環所測定的。環的接觸半徑為1.6毫米,頭速度為1.2毫米/分鐘。According to the test method described in ASTM C1499-08 Standard Test Method for Monotonic Biaxial Bending Strength of Advanced Ceramics at Ambient Temperature, ring-to-ring load is used to determine the strength of at least one glass product described herein. Generally, the ring-to-ring load test method is used to measure the biaxial strength of advanced brittle materials at ambient temperature through a concentric ring configuration under monotonic uniaxial load, and it has been widely used as a method to evaluate the surface strength of glass products. The ring-to-ring load results described in this article are measured on a 2-inch square glass plate using a 1-inch diameter support ring and a 0.5-inch diameter load ring. The contact radius of the ring is 1.6 mm, and the head speed is 1.2 mm/min.
如本文所用,用語「殘留強度」是指在將缺陷受控地引入玻璃製品的外表面之後所測定的玻璃製品強度。如本文所用,用語「努氏刮痕閾值」是指在漸增的負載下用努氏金剛石刮劃玻璃製品的表面時,首次在玻璃製品中觀察到橫向裂紋時的負載。該測試是在室溫於50%相對濕度下進行。As used herein, the term "residual strength" refers to the strength of a glass article measured after defects are introduced into the outer surface of the glass article in a controlled manner. As used herein, the term "Knoop Scratch Threshold" refers to the load when a transverse crack is first observed in the glass product when the surface of the glass product is scratched with Knoop diamond under increasing load. The test is carried out at room temperature and 50% relative humidity.
如本文所用,用語「壓痕閾值」是指在漸增的負載下用維氏壓頭對玻璃製品的表面施壓時,首次在玻璃製品中觀察到裂紋時的負載。使用維氏壓頭以0.2毫米/分鐘的速率將壓痕負載施加至玻璃製品的表面上,然後再從玻璃製品的表面上移開。維持最大壓痕負載10秒鐘。壓痕閾值定為一壓痕負載,在該負載下,10個壓痕中有50%會顯示出從壓痕角落發出的任意數量之徑向/中央裂紋。持續增加最大壓痕負載,直到達到給定玻璃製品的壓痕閾值為止。所有壓痕測量均在室溫於50%相對濕度下進行。As used herein, the term "indentation threshold" refers to the load at which a crack is first observed in the glass product when a Vickers indenter is used to press the surface of the glass product under increasing load. A Vickers indenter was used to apply the indentation load to the surface of the glass article at a rate of 0.2 mm/min, and then removed from the surface of the glass article. Maintain the maximum indentation load for 10 seconds. The indentation threshold is defined as an indentation load under which 50% of 10 indentations will show any number of radial/central cracks from the corners of the indentation. Continue to increase the maximum indentation load until the indentation threshold for a given glass article is reached. All indentation measurements are performed at room temperature and 50% relative humidity.
如本文所用,用語「維氏刮痕閾值」是指在漸增的負載下用維氏壓頭刮劃玻璃製品的表面時,首次在玻璃製品中觀察到橫向裂紋時的負載。測試程序類似於測定努氏刮痕閾值的程序,只是使用維氏壓頭來代替努氏金剛石。玻璃製品中的持續裂紋證實了橫向裂紋,該持續裂紋大於由維氏壓頭形成的原始刮痕或凹槽寬度的兩倍。As used herein, the term "Vickers Scratch Threshold" refers to the load when a Vickers indenter is used to scratch the surface of a glass product under increasing load when a transverse crack is first observed in the glass product. The test procedure is similar to the procedure for determining the Knoop scratch threshold, except that a Vickers indenter is used instead of Knoop diamond. Sustained cracks in the glass article confirmed transverse cracks that were greater than twice the width of the original scratch or groove formed by the Vickers indenter.
在多個實施例中,玻璃製品包括至少第一層及第二層。例如,第一層包括芯層,而第二層包括與該芯層相鄰之一或更多個覆層。第一層及/或第二層為包括玻璃、玻璃陶瓷、或其組合之玻璃層。在一些實施例中,第一層及/或第二層為透明玻璃層。In various embodiments, the glass article includes at least a first layer and a second layer. For example, the first layer includes a core layer, and the second layer includes one or more cladding layers adjacent to the core layer. The first layer and/or the second layer are glass layers including glass, glass ceramic, or a combination thereof. In some embodiments, the first layer and/or the second layer are transparent glass layers.
第7圖為玻璃製品200的一個示例性實施例之截面圖。在一些實施例中,玻璃製品200包括包含多個玻璃層的層壓板。層壓板可如第7圖所示為實質上平面的,或為非平面的。玻璃製品200包括設置於第一覆層104及第二覆層106之間的芯層102。在一些實施例中,第一覆層104及第二覆層106為如第7圖所示之外層。在其他實施例中,第一覆層及/或第二覆層為設置在芯層與外層之間的中間層。FIG. 7 is a cross-sectional view of an exemplary embodiment of the
芯層102包括第一主表面及與該第一主表面相對的第二主表面。在一些實施例中,第一覆層104係熔合至芯層102的第一主表面。另外,或可替代地,第二覆層106係熔合至芯層102的第二主表面。在這樣的實施例中,第一覆層104與芯層102之間及/或第二覆層106與芯層102之間的界面層沒有任何黏結材料,例如黏合劑、塗層、或任何添加或配置以黏結個別覆層至芯層之非玻璃材料。因此,第一覆層104及/或第二覆層106係直接熔合至芯層102或直接與芯層102相鄰。在一些實施例中,玻璃製品包括設置在芯層與第一覆層之間及/或芯層與第二覆層之間的一或更多個中間層。例如,中間層包括形成在芯層與覆層的界面處之中間玻璃層及/或擴散層。在一些實施例中,玻璃製品200係形成為玻璃-玻璃層壓板,其中直接相鄰的玻璃層之間的界面為玻璃-玻璃界面。The
在一些實施例中,芯層102包括第一玻璃組合物,且第一及/或第二覆層104及106包括與第一玻璃組合物不同的第二玻璃組合物。例如,在如第7圖所示的實施例中,芯層102包括第一玻璃組合物,且第一覆層104及第二覆層106均包括第二玻璃組合物。在其他實施例中,第一覆層包括第二玻璃組合物,且第二覆層包括與第一玻璃組合物及/或第二玻璃組合物不同的第三玻璃組合物。In some embodiments, the
玻璃製品可用適當的方法形成,例如熔融拉伸、向下拉伸、狹縫拉伸、向上拉伸或浮法。在一些實施例中,玻璃製品係使用熔融拉伸製程所形成。The glass product can be formed by a suitable method, such as melt stretching, downward stretching, slit stretching, upward stretching or float. In some embodiments, the glass product is formed using a melt stretching process.
第8圖為溢流分配器300的一個示例性實施例之剖視圖,溢流分配器300可用於形成玻璃製品,例如玻璃製品200。溢流分配器300可如美國專利4,214,886號中所述般配置,該專利全文皆以引用方式納入本說明書中。例如,溢流分配器300包括下部溢流分配器220、及位於該下部溢流分配器上方的上部溢流分配器240。下部溢流分配器220包括槽222。將第一玻璃組合物224熔化並以黏性狀態進料至槽222中。第一玻璃組合物224係形成玻璃製品200的芯層102,如以下所詳述。上部溢流分配器240包括槽242。將第二玻璃組合物244熔化並以黏性狀態進料至槽242中。第二玻璃組合物244係形成玻璃製品100的第一及第二覆層104及106,如以下所詳述。FIG. 8 is a cross-sectional view of an exemplary embodiment of the
第一玻璃組合物224溢出槽222,並向下流動至下部溢流分配器220的相對的外部成形表面226及228。外部成形表面226及228在牽引線230處會聚。個別的第一玻璃組合物224流係分別向下流動至下部溢流分配器220的外部形成表面226及228,並於外部形成表面226及228所會聚之牽引線230處融合在一起以形成玻璃製品100的芯層102。The
第二玻璃組合物244溢出槽242,並向下流動至上部溢流分配器240的相對的外部形成表面246及248。第二玻璃組合物244被上部溢流分配器240向外偏轉,使得第二玻璃組合物在下部溢流分配器220的周圍流動,並與流過下部溢流分配器的外部成形表面226及228之第一玻璃組合物224接觸。個別的第二玻璃組合物244流係分別與向下流動至下部溢流分配器220的外部成型表面226及228之第一玻璃組合物224流熔合。第一玻璃組合物224流在牽引線230處會聚之後,第二玻璃組合物244形成玻璃製品200的第一及第二覆層104及106。The
在一些實施例中,處於黏性狀態的芯層102的第一玻璃組合物224與處於黏性狀態的第一及第二覆層104及106的第二玻璃組合物244接觸以形成層壓板。在一些這樣的實施例中,層壓板為玻璃帶的一部分,該玻璃帶係自下部溢流分配器220的牽引線230處離去,如第8圖所示。可透過包括例如重力及/或牽引輥等之適當手段將玻璃帶自下部溢流分配器220拉離。玻璃帶於離開下部溢流分配器220後冷卻。將玻璃帶切斷以從中分離出層壓板。因此,層壓板係切割自玻璃帶。可用合適的技術例如刻痕、彎曲、熱衝擊及/或雷射切割來切斷玻璃帶。在一些實施例中,玻璃製品200包括如第7圖所示之層壓板。在其他實施例中,可對層壓板進一步處理(例如,透過切割或模製)以形成玻璃製品200。In some embodiments, the
雖然第7圖中所示之玻璃製品200具有三層,本案亦包括其他實施例。在其他實施例中,玻璃製品可具有預定數量的層,例如兩層、四層或更多層。可透過相應地改變溢流分配器來形成具有預定層數的玻璃製品。Although the
在一些實施例中,玻璃製品200的厚度為至少約0.05mm、至少約0.1mm、至少約0.2mm、或至少約0.3mm。另外地或可替代地,玻璃製品200包括至多約2mm、至多約1.5mm、至多約1mm、至多約0.7mm、或至多約0.5mm的厚度。在一些實施例中,芯層102的厚度與玻璃製品200的厚度的比率為至少約0.8、至少約0.85、至少約0.9、或至少約0.95。在一些實施例中,第二層(例如,第一覆層104及第二覆層106中的每一者)的厚度為約0.01mm至約0.3mm。In some embodiments, the thickness of the
在一些實施例中,第一玻璃組合物及/或第二玻璃組合物包括適合於使用如本文所述之熔融拉伸製程來形成玻璃製品200的液相線黏度。例如,第一層(例如,芯層102)的第一玻璃組合物的液相線黏度為至少約100kP、至少約200kP、或至少約300kP。另外地或可替代地,第一玻璃組合物的液相線黏度為至多約3000kP、至多約2500kP、至多約1000kP、或至多約800kP。另外地或可替代地,第二層(例如,第一及/或第二覆層104及106)的第二玻璃組合物的液相線黏度為至少約50kP、至少約100kP、或至少約200kP。另外地或可替代地,第二玻璃組合物的液相線黏度為至多約3000kP、至多約2500kP、至多約1000kP、或至多約800kP。第一玻璃組合物可有助於將第二玻璃組合物承載在溢流分配器上以形成第二層。因此,第二玻璃組合物的液相線黏度可低於通常認為適合於使用熔融拉伸法來形成單層板的液相線黏度。In some embodiments, the first glass composition and/or the second glass composition includes a liquidus viscosity suitable for forming the
在一些實施例中,玻璃製品200被配置為強化玻璃製品。例如,在一些實施例中,第二層(例如,第一及/或第二覆層104及106)的第二玻璃組合物包括與第一層(例如,芯層102)的第一玻璃組合物不同的平均熱膨脹係數(CTE)。例如,第一及第二覆層104及106係由具有比芯層102更低的平均CTE之玻璃組合物所形成。CTE失配(亦即,第一及第二覆層104及106的平均CTE與芯層102的平均CTE之差)會導致在冷卻玻璃製品200時在覆層中產生壓縮應力並在芯層中產生拉伸應力。在多個實施例中,第一及第二覆層中的每一者可獨立地具有較高的平均CTE、較低的平均CTE、或與芯層實質相同的平均CTE。In some embodiments, the
在一些實施例中,第一層(例如,芯層102)的平均CTE與第二層(例如,第一及/或第二覆層104及106)的平均CTE相差至少約5×10-7 ℃-1 、至少約15×10-7 ℃-1 、或至少約25×10-7 ℃-1 。另外地或可替代地,第一層的平均CTE與第二層的平均CTE相差至多約55×10-7 ℃-1 、至多約50×10-7 ℃-1 、至多約40×10-7 ℃-1 、至多約30×10-7 ℃-1 、至多約20×10-7 ℃-1 、或至多約10×10-7 ℃-1 。例如,在一些實施例中,第一層的平均CTE與第二層的平均CTE相差約5×10-7 ℃-1 至約30×10-7 ℃-1 或約5×10-7 ℃-1 至約20×10-7 ℃-1 。在一些實施例中,第二層的第二玻璃組合物包含至多約40×10-7 ℃-1 或至多約35×10-7 ℃-1 的平均CTE。另外地或可替代地,第二層的第二玻璃組合物包括至少約25×10-7 ℃-1 、或至少約30×10-7 ℃-1 的平均CTE。另外地或可替代地,第一層的第一玻璃組合物包括至少約40×10-7 ℃-1 、至少約50×10-7 ℃-1 、或至少約55×10-7 ℃-1 的平均CTE。另外地或可替代地,第一層的第一玻璃組合物包括至多約90×10-7 ℃-1 、至多約85×10-7 ℃-1 、至多約80×10-7 ℃-1 、至多約70×10-7 ℃-1 、或至多約60×10-7 ℃-1 的平均CTE。In some embodiments, the average CTE of the first layer (eg, core layer 102) differs from the average CTE of the second layer (eg, first and/or second cladding layers 104 and 106) by at least about 5×10 -7 ℃ -1 , at least about 15×10 -7 ℃ -1 , or at least about 25×10 -7 ℃ -1 . Additionally or alternatively, the average CTE of the first layer differs from the average CTE of the second layer by at most about 55×10 -7 ℃ -1 , at most about 50×10 -7 ℃ -1 , and at most about 40×10 -7 ℃ -1 , at most about 30×10 -7 ℃ -1 , at most about 20×10 -7 ℃ -1 , or at most about 10×10 -7 ℃ -1 . For example, in some embodiments, the average CTE of the first layer differs from the average CTE of the second layer by about 5×10 -7 ℃ -1 to about 30×10 -7 ℃ -1 or about 5×10 -7 ℃ - 1 to about 20×10 -7 ℃ -1 . In some embodiments, the second glass composition of the second layer includes an average CTE of at most about 40×10 -7 °C -1 or at most about 35×10 -7 °C -1 . Additionally or alternatively, the second glass composition of the second layer includes an average CTE of at least about 25×10 -7 °C -1 , or at least about 30×10 -7 °C -1 . Additionally or alternatively, the first glass composition of the first layer includes at least about 40×10 -7 ℃ -1 , at least about 50×10 -7 ℃ -1 , or at least about 55×10 -7 ℃ -1 The average CTE. Additionally or alternatively, the first glass composition of the first layer includes at most about 90×10 -7 ℃ -1 , at most about 85×10 -7 ℃ -1 , at most about 80×10 -7 ℃ -1 , An average CTE of at most about 70×10 -7 ℃ -1 , or at most about 60×10 -7 ℃ -1 .
在多個實施例中,可選擇玻璃組成及玻璃層的相對厚度以獲得具有所需強度特性的玻璃製品。例如,在一些實施例中,選擇第一層(例如,芯層102)的第一玻璃組合物及第二層(例如,第一及/或第二覆層104及106)的第二玻璃組合物以實現所需的CTE失配,並配合所需的CTE失配來選擇第一層及第二層的厚度,以獲得在第二層中所需的壓縮應力、在第一層中所需的拉伸應力、所需的殘留強度、及/或所需的掉落閾值。In various embodiments, the glass composition and the relative thickness of the glass layers can be selected to obtain glass products with desired strength characteristics. For example, in some embodiments, the first glass composition of the first layer (for example, the core layer 102) and the second glass composition of the second layer (for example, the first and/or second cladding layers 104 and 106) are selected In order to achieve the required CTE mismatch, the thickness of the first layer and the second layer can be selected to obtain the required compressive stress in the second layer and the required CTE mismatch in the first layer. Required tensile stress, required residual strength, and/or required drop threshold.
在多個實施例中,可選擇玻璃組成及玻璃層的相對厚度以獲得具有所需表面性質的玻璃製品。例如,在一些實施例中,選擇第一層(例如,芯層102)的第一玻璃組合物、第二層(例如,第一及/或第二覆層104及106)的第二玻璃組合物、以及第一層及第二層的厚度,以獲得具有所需努氏刮痕閾值及/或所需壓痕閾值的玻璃製品。In various embodiments, the glass composition and the relative thickness of the glass layers can be selected to obtain glass products with desired surface properties. For example, in some embodiments, the first glass composition of the first layer (for example, the core layer 102) and the second glass composition of the second layer (for example, the first and/or second cladding layers 104 and 106) are selected And the thickness of the first layer and the second layer to obtain a glass product having the required Knoop scratch threshold and/or the required indentation threshold.
在一些實施例中,玻璃製品的努氏刮痕閾值為至少約5N、至少約10N、或至少約15N。另外地或可替代地,玻璃製品的壓痕閾值為至少約20N、至少約30N、或至少約40N。另外地或可替代地,玻璃製品的維氏刮痕閾值為至少約2N、至少約3N、至少約5N、或至少約7N。另外地或可替代地,玻璃製品的掉落閾值為至少約100cm、至少約140cm、或至少約160cm。In some embodiments, the Knoop scratch threshold of the glass article is at least about 5N, at least about 10N, or at least about 15N. Additionally or alternatively, the indentation threshold of the glass article is at least about 20N, at least about 30N, or at least about 40N. Additionally or alternatively, the Vickers scratch threshold of the glass article is at least about 2N, at least about 3N, at least about 5N, or at least about 7N. Additionally or alternatively, the drop threshold of the glass article is at least about 100 cm, at least about 140 cm, or at least about 160 cm.
在一些實施例中,覆層的壓縮應力為至多約800MPa、至多約500MPa、至多約300MPa、至多約200MPa、至多約150MPa、至多約100MPa、至多約50MPa、或至多約40MPa。另外地或可替代地,覆層的壓縮應力為至少約10MPa、至少約20MPa、至少約30MPa、至少約50MPa、或至少約100MPa。In some embodiments, the compressive stress of the coating is at most about 800 MPa, at most about 500 MPa, at most about 300 MPa, at most about 200 MPa, at most about 150 MPa, at most about 100 MPa, at most about 50 MPa, or at most about 40 MPa. Additionally or alternatively, the compressive stress of the coating is at least about 10 MPa, at least about 20 MPa, at least about 30 MPa, at least about 50 MPa, or at least about 100 MPa.
第一層(例如,芯層102)的第一玻璃組合物及第二層(例如,第一覆層104及/或第二覆層106)的第二玻璃組合物可包含能夠形成具有如本文所述之所需性質的玻璃製品之適當玻璃組合物。The first glass composition of the first layer (for example, the core layer 102) and the second glass composition of the second layer (for example, the
在一些實施例中,第一玻璃組合物包含選自由SiO2 、Al2 O3 、B2 O3 及其組合所構成的群組之玻璃網絡形成劑。例如,第一玻璃組合物包含至少約50mol%的SiO2 、至少約55mol%的SiO2 、至少約60mol%的SiO2 、或至少約65mol%的SiO2 。另外地或可替代地,第一玻璃組合物包含至多約80mol%的SiO2 、至多約70mol%的SiO2 、至多約68mol%的SiO2 、或至多約60mol%的SiO2 。另外地或可替代地,第一玻璃組合物包含至少約5mol%的Al2 O3 、至少約9mol%的Al2 O3 、或至少約12mol%的Al2 O3 。另外地或可替代地,第一玻璃組合物包含至多約20mol%的Al2 O3 、至多約17mol%的Al2 O3 、或至多約11mol%的Al2 O3 。另外地或可替代地,第一玻璃組合物包含至少約3mol%的B2 O3 、至少約6mol%的B2 O3 、或至少約7mol%的B2 O3 。另外地或可替代地,第一玻璃組合物包含至多約11mol%的B2 O3 、至多約8mol%的B2 O3 、或至多約4mol%的B2 O3 。在一些實施例中,第一玻璃組合物實質上不含B2 O3 。例如,第一玻璃組合物包含至多約0.1mol%的B2 O3 。In some embodiments, the first glass composition includes a glass network former selected from the group consisting of SiO 2 , Al 2 O 3 , B 2 O 3 and combinations thereof. For example, the first glass composition includes at least about 50 mol% SiO 2 , at least about 55 mol% SiO 2 , at least about 60 mol% SiO 2 , or at least about 65 mol% SiO 2 . Additionally or alternatively, the first glass composition comprises up to about 80 mol% of SiO 2, up to about 70 mol% of SiO 2, up to about 68 mol% of SiO 2, or up to about 60mol% of SiO 2. Additionally or alternatively, the first glass composition includes at least about 5 mol% Al 2 O 3 , at least about 9 mol% Al 2 O 3 , or at least about 12 mol% Al 2 O 3 . Additionally or alternatively, the first glass composition includes at most about 20 mol% Al 2 O 3 , at most about 17 mol% Al 2 O 3 , or at most about 11 mol% Al 2 O 3 . Additionally or alternatively, the first glass composition includes at least about 3 mol% B 2 O 3 , at least about 6 mol% B 2 O 3 , or at least about 7 mol% B 2 O 3 . Additionally or alternatively, the first glass composition includes up to about 11 mol% B 2 O 3 , up to about 8 mol% B 2 O 3 , or up to about 4 mol% B 2 O 3 . In some embodiments, the first glass composition is substantially free of B 2 O 3 . For example, the first glass composition contains at most about 0.1 mol% B 2 O 3 .
在一些實施例中,第一玻璃組合物包含選自由Li2 O、Na2 O、K2 O及其組合所構成的群組之鹼金屬氧化物。例如,第一玻璃組合物包含至少約0.05mol%的Na2 O、至少約10mol%的Na2 O、或至少約13mol%的Na2 O。另外地或可替代地,第一玻璃組合物包含至多約16mol%的Na2 O、至多約14mol%的Na2 O、至多約2mol%的Na2 O、或至多約0.1mol%的Na2 O。另外地或可替代地,第一玻璃組合物包含至少約0.01mol%的K2 O、至少約2mol%的K2 O、或至少約8mol%的K2 O。另外地或可替代地,第一玻璃組合物包含至多約15mol%的K2 O、至多約9mol%的K2 O、至多約6mol%的K2 O、或至多約0.1mol%的K2 O。In some embodiments, the first glass composition includes an alkali metal oxide selected from the group consisting of Li 2 O, Na 2 O, K 2 O, and combinations thereof. For example, the first glass composition comprises at least about 0.05mol% of Na 2 O, at least about 10mol% of Na 2 O, or at least about 13mol% of Na 2 O. Additionally or alternatively, the first glass composition comprises up to about 16 mol% Na 2 O, up to about 14 mol% Na 2 O, up to about 2 mol% Na 2 O, or up to about 0.1 mol% Na 2 O . Additionally or alternatively, the first glass composition includes at least about 0.01 mol% K 2 O, at least about 2 mol% K 2 O, or at least about 8 mol% K 2 O. Additionally or alternatively, the first glass composition comprises up to about 15 mol% K 2 O, up to about 9 mol% K 2 O, up to about 6 mol% K 2 O, or up to about 0.1 mol% K 2 O .
在一些實施例中,第一玻璃組合物包含選自由MgO、CaO、SrO、BaO及其組合所構成的群組之鹼土金屬氧化物。例如,第一玻璃組合物包含至少約1mol%的MgO、至少約2mol%的MgO、至少約3mol%的MgO、或至少約4mol%的MgO。另外地或可替代地,第一玻璃組合物包含至多約8mol%的MgO、至多約4mol%的MgO、或至多約3mol%的MgO。另外地或可替代地,第一玻璃組合物包含至少約0.01mol%的CaO、至少約2mol%的CaO、至少約4mol%的CaO、至少約5mol%的CaO、或至少約6mol%的CaO。另外地或可替代地,第一玻璃組合物包含至多約8mol%的CaO、至多約7mol%的CaO、至多約0.1mol%的CaO、或至多約0.01mol%的CaO。另外地或可替代地,第一玻璃組合物包含至少約3mol%的SrO、至少約4mol%的SrO、至少約5mol%的SrO、或至少約6mol%的SrO。另外地或可替代地,第一玻璃組合物包含至多約7mol%的SrO、至多約6mol%的SrO、或至多約5mol%的SrO。另外地或可替代地,第一玻璃組合物包含至少約0.01mol%的BaO、至少約0.02mol%的BaO、或至少約0.07mol%的BaO。另外地或可替代地,第一玻璃組合物包含至多約0.1mol%的BaO、至多約0.09mol%的BaO、至多約0.05mol%的BaO、或至多約0.01mol%的BaO。在一些實施例中,第一玻璃組合物實質上不含SrO。例如,第一玻璃組合物包含至多約0.1mol%的SrO。In some embodiments, the first glass composition includes alkaline earth metal oxides selected from the group consisting of MgO, CaO, SrO, BaO, and combinations thereof. For example, the first glass composition includes at least about 1 mol% MgO, at least about 2 mol% MgO, at least about 3 mol% MgO, or at least about 4 mol% MgO. Additionally or alternatively, the first glass composition includes at most about 8 mol% MgO, at most about 4 mol% MgO, or at most about 3 mol% MgO. Additionally or alternatively, the first glass composition includes at least about 0.01 mol% CaO, at least about 2 mol% CaO, at least about 4 mol% CaO, at least about 5 mol% CaO, or at least about 6 mol% CaO. Additionally or alternatively, the first glass composition includes at most about 8 mol% CaO, at most about 7 mol% CaO, at most about 0.1 mol% CaO, or at most about 0.01 mol% CaO. Additionally or alternatively, the first glass composition includes at least about 3 mol% SrO, at least about 4 mol% SrO, at least about 5 mol% SrO, or at least about 6 mol% SrO. Additionally or alternatively, the first glass composition includes at most about 7 mol% SrO, at most about 6 mol% SrO, or at most about 5 mol% SrO. Additionally or alternatively, the first glass composition includes at least about 0.01 mol% BaO, at least about 0.02 mol% BaO, or at least about 0.07 mol% BaO. Additionally or alternatively, the first glass composition includes at most about 0.1 mol% BaO, at most about 0.09 mol% BaO, at most about 0.05 mol% BaO, or at most about 0.01 mol% BaO. In some embodiments, the first glass composition is substantially free of SrO. For example, the first glass composition includes up to about 0.1 mol% SrO.
在一些實施例中,第一玻璃組合物包含一或更多種另外的成分,包括例如SnO2 、Sb2 O3 、As2 O3 、Ce2 O3 、Cl(例如,衍生自KCl或NaCl)、ZrO2 或Fe2 O3 。In some embodiments, the first glass composition includes one or more additional ingredients, including, for example, SnO 2 , Sb 2 O 3 , As 2 O 3 , Ce 2 O 3 , Cl (eg, derived from KCl or NaCl ), ZrO 2 or Fe 2 O 3 .
在一些實施例中,第二玻璃組合物包含選自由SiO2 、Al2 O3 、B2 O3 及其組合所構成的群組之玻璃網絡形成劑。例如,第二玻璃組合物包含至少約60mol%的SiO2 、至少約62mol%的SiO2 、或至少約67mol%的SiO2 。另外地或可替代地,第二玻璃組合物包含至多約70mol%的SiO2 、至多約68mol%的SiO2 、至多約65mol%的SiO2 、或至多約63mol%的SiO2 。另外地或可替代地,第二玻璃組合物包含至少約6mol%的Al2 O3 、至少約10mol%的Al2 O3 、或至少約12mol%的Al2 O3 。另外地或可替代地,第二玻璃組合物包含至多約18mol%的Al2 O3 、至多約13mol%的Al2 O3 、或至多約8mol%的Al2 O3 。另外地或可替代地,第二玻璃組合物包含至少約4mol%的B2 O3 、至少約6mol%的B2 O3 、至少約9mol%的B2 O3 、或至少約16mol%的B2 O3 。另外地或可替代地,第二玻璃組合物包含至多約21mol%的B2 O3 、至多約18mol%的B2 O3 、或至多約11mol%的B2 O3 。In some embodiments, the second glass composition includes a glass network former selected from the group consisting of SiO 2 , Al 2 O 3 , B 2 O 3 and combinations thereof. For example, the second glass composition includes at least about 60 mol% SiO 2 , at least about 62 mol% SiO 2 , or at least about 67 mol% SiO 2 . Additionally or alternatively, the second glass composition includes at most about 70 mol% SiO 2 , at most about 68 mol% SiO 2 , at most about 65 mol% SiO 2 , or at most about 63 mol% SiO 2 . Additionally or alternatively, the second glass composition includes at least about 6 mol% Al 2 O 3 , at least about 10 mol% Al 2 O 3 , or at least about 12 mol% Al 2 O 3 . Additionally or alternatively, the second glass composition includes at most about 18 mol% Al 2 O 3 , at most about 13 mol% Al 2 O 3 , or at most about 8 mol% Al 2 O 3 . Additionally or alternatively, the second glass composition includes at least about 4 mol% B 2 O 3 , at least about 6 mol% B 2 O 3 , at least about 9 mol% B 2 O 3 , or at least about 16 mol% B 2 O 3 . Additionally or alternatively, the second glass composition includes at most about 21 mol% B 2 O 3 , at most about 18 mol% B 2 O 3 , or at most about 11 mol% B 2 O 3 .
在一些實施例中,第二玻璃組合物包含選自由Li2 O、Na2 O、K2 O及其組合所構成的群組之鹼金屬氧化物。例如,第二玻璃組合物包含約0mol%至約0.1mol%的Na2 O、或約0mol%至約0.06mol%的Na2 O。另外地或可替代地,第二玻璃組合物包含約0mol%至約0.05mol%的K2 O、或約0mol%至約0.03mol%的K2 O。在一些實施例中,第二玻璃組合物實質上不含鹼金屬。例如,第二玻璃組合物包含至多約0.1mol%的鹼金屬氧化物。在其他實施例中,第二玻璃組合物包含約5mol%至約10mol%的鹼金屬氧化物。In some embodiments, the second glass composition includes an alkali metal oxide selected from the group consisting of Li 2 O, Na 2 O, K 2 O, and combinations thereof. For example, the second glass composition includes about 0 mol% to about 0.1 mol% Na 2 O, or about 0 mol% to about 0.06 mol% Na 2 O. Additionally or alternatively, the second glass composition includes about 0 mol% to about 0.05 mol% K 2 O, or about 0 mol% to about 0.03 mol% K 2 O. In some embodiments, the second glass composition is substantially free of alkali metals. For example, the second glass composition contains at most about 0.1 mol% alkali metal oxide. In other embodiments, the second glass composition includes about 5 mol% to about 10 mol% of alkali metal oxide.
在一些實施例中,第二玻璃組合物包含選自由MgO、CaO、SrO、BaO及其組合所構成的群組之鹼土金屬氧化物。例如,第二玻璃組合物包含至少約0.2mol%的MgO、至少約1mol%的MgO、或至少約3mol%的MgO。另外地或可替代地,第二玻璃組合物包含至多約5mol%的MgO、至多約4mol%的MgO、至多約2mol%的MgO、或至多約0.5mol%的MgO。另外地或可替代地,第二玻璃組合物包含至少約3mol%的CaO、至少約4mol%的CaO、至少約5mol%的CaO、或至少約8mol%的CaO。另外地或可替代地,第二玻璃組合物包含至多約12mol%的CaO、至多約9mol%的CaO、至多約8mol%的CaO、或至多約5mol%的CaO。另外地或可替代地,第二玻璃組合物包含至少約0.2mol%的SrO、至少約1mol%的SrO、或至少約2mol%的SrO。另外地或可替代地,第二玻璃組合物包含至多約3mol%的SrO、至多約2mol%的SrO、或至多約1mol%的SrO。另外地或可替代地,第二玻璃組合物包含至少約0.01mol%的BaO、至少約0.02mol%的BaO、或至少約1mol%的BaO。另外地或可替代地,第二玻璃組合物包含至多約2mol%的BaO、至多約0.5mol%的BaO、至多約0.03mol%的BaO、至多約0.02mol%的BaO、或至多約0.01mol%的BaO。在一些實施例中,第二玻璃組合物包含約3mol%至約16mol%的鹼土金屬氧化物。此外,在一些實施例中,第二玻璃組合物包含一或更多種另外的成分,包括例如SnO2
、Sb2
O3
、As2
O3
、Ce2
O3
、Cl(例如,衍生自KCl或NaCl)、ZrO2
或Fe2
O3
。第1圖為根據至少一個實施例之放置有晶圓的雙載體之截面圖。如第1圖所示,晶圓(Si晶圓)101係位於雙載體100中。在至少一個實施例中,雙載體100可由例如上述玻璃製品200之至少一個玻璃製品所構成。在至少一個實施例中,雙載體100係由第一載體10、以及位於第一載體10下方以支撐第一載體10的第二載體20所形成之載體支撐結構或載體組件。以下描述根據至少一個示例性實施例的第一載體10及第二載體20之製造。In some embodiments, the second glass composition includes alkaline earth metal oxides selected from the group consisting of MgO, CaO, SrO, BaO, and combinations thereof. For example, the second glass composition includes at least about 0.2 mol% MgO, at least about 1 mol% MgO, or at least about 3 mol% MgO. Additionally or alternatively, the second glass composition includes at most about 5 mol% MgO, at most about 4 mol% MgO, at most about 2 mol% MgO, or at most about 0.5 mol% MgO. Additionally or alternatively, the second glass composition includes at least about 3 mol% CaO, at least about 4 mol% CaO, at least about 5 mol% CaO, or at least about 8 mol% CaO. Additionally or alternatively, the second glass composition includes at most about 12 mol% CaO, at most about 9 mol% CaO, at most about 8 mol% CaO, or at most about 5 mol% CaO. Additionally or alternatively, the second glass composition includes at least about 0.2 mol% SrO, at least about 1 mol% SrO, or at least about 2 mol% SrO. Additionally or alternatively, the second glass composition includes at most about 3 mol% SrO, at most about 2 mol% SrO, or at most about 1 mol% SrO. Additionally or alternatively, the second glass composition includes at least about 0.01 mol% BaO, at least about 0.02 mol% BaO, or at least about 1 mol% BaO. Additionally or alternatively, the second glass composition includes at most about 2 mol% BaO, at most about 0.5 mol% BaO, at most about 0.03 mol% BaO, at most about 0.02 mol% BaO, or at most about 0.01 mol% BaO. In some embodiments, the second glass composition includes about 3 mol% to about 16 mol% of alkaline earth metal oxide. Additionally, in some embodiments, the second glass composition includes one or more additional ingredients, including, for example, SnO 2 , Sb 2 O 3 , As 2 O 3 , Ce 2 O 3 , Cl (for example, derived from KCl Or NaCl), ZrO 2 or Fe 2 O 3 . Figure 1 is a cross-sectional view of a dual carrier on which wafers are placed according to at least one embodiment. As shown in Figure 1, the wafer (Si wafer) 101 is located in the
第2A-2E圖描繪了第一載體10的製備及形成。第2A圖為根據至少一個實施例之雙載體100的第一載體10於圖案化前之截面圖。如第2A圖所示,第一載體10包括夾在覆層的上層12及覆層的下層18之間的一層芯材料14。在一些實施例中,芯材料14(芯層)可為玻璃,且覆層的上(第一)層12及下(第二)層18可由層壓板製成。因此,可根據至少一個實施例,以玻璃製品200的方式建造第一載體10,其中芯材料14係由與芯層102相同或相似的組合物所製成,上層12係由與第一覆層104相同或相似的組合物所製成,且下層18係由與第二覆層106相同或相似的組合物所製成,其中各個部件係由與上述相同或相似的製程所製造。Figures 2A-2E depict the preparation and formation of the
在多個實施例中,芯材料14以及覆層的上層12及下層18可為具有不同組成且具有不同特性的玻璃。亦即,芯材料14可與覆層的上層12及下層18不同,且進一步地,在一些實施例中,上層12的覆層材料可與下層18的覆層材料相同或不同。更具體而言,在一些實施例中,芯材料14、上層12、或下層18中的一或更多者可包括積層玻璃。在一些實施例中,芯材料14的厚度與第一載體10的厚度的比率為至少約0.8、至少約0.85、至少約0.9、或至少約0.95。第2B圖為根據至少一個實施例之雙載體的第一載體於圖案化後之截面圖。如第2B圖所示,蝕刻防止層16係位於覆層的上層12之頂部。將蝕刻防止層16圖案化,以製備用於在其中形成一或更多個開口(孔)的第一載體10。如以下所述,蝕刻防止層16的圖案化形成至少一個開口,在該開口處上層12未被覆蓋。在一些實施例中,蝕刻防止層16可為光阻劑或遮罩。In various embodiments, the
在第2A至2C圖中,第一載體10被圖示為具有一個可在橫截面中看到的開口。應當理解到,這是為了便於說明,且第一載體10中的開口之尺寸及數量可根據某些實施例而變化。例如,第2A至2C圖中所圖示之第一載體10可為實際第一載體10的大約一半(亦即,載體10中包含有一個開口的一部分),而第一載體10的全長尺寸可為在載體10的長度方向上容納有兩個開口,且在寬度方向上亦容納有兩個開口。In Figures 2A to 2C, the
在一些實施例中,第一載體10的尺寸可容納2、4、6、8、10或12個開口,而在其他實施例中則可提供不同數量的開口。具體而言,開口的數量可依照第一載體10所欲裝載的晶圓尺寸而變化。例如,若使用直徑為約12英寸(約300mm)的矽晶圓,則第一載體10的尺寸可為約800mm×800mm,並設置有四個開口。若使用直徑為約8英寸(約200mm)的矽晶圓,則第一載體10的尺寸可為約550mm×550mm,並設置有四個開口。In some embodiments, the size of the
第2D圖為如第2B圖所示之第一載體之俯視圖,根據至少一個實施例。如第2D圖所示,當進行圖案化以形成孔時,蝕刻防止層16並非連續地設置於覆層的上層12之頂部。反而是,設置了開口17,而當從頂部觀察時,透過該等開口17可看到覆層的上層12。Figure 2D is a top view of the first carrier as shown in Figure 2B, according to at least one embodiment. As shown in FIG. 2D, when patterning is performed to form holes, the
第2C圖為根據至少一個實施例之雙載體的第一載體於蝕刻後之截面圖。在至少一個實施例中,在第一蝕刻製程中進行蝕刻以在第一載體10中形成孔。蝕刻製程去除了覆層的上層12的一部分,從而擴大了黏合劑16側面之間的開口。具體而言,藉由去除上層12因圖案化而暴露的部分,蝕刻至少擴大了開口17的深度。FIG. 2C is a cross-sectional view of the first carrier of the dual carrier after etching according to at least one embodiment. In at least one embodiment, etching is performed in the first etching process to form holes in the
第2E圖為如第2C圖所示之第一載體之俯視圖,根據至少一個實施例。如第2E圖所示,透過蝕刻以去除覆層的上層12的一部分,芯材料14係直接經由開口17暴露,且當從第一載體10的頂部觀察時可看見。Figure 2E is a top view of the first carrier as shown in Figure 2C, according to at least one embodiment. As shown in FIG. 2E, by etching to remove part of the
第3A圖為根據至少一個實施例之在圖案化以形成開口17作為通孔後的第一載體之截面圖。如第3A圖所示,可用這樣的方式進行圖案化,使得蝕刻防止層16不僅存在於覆層的上層12的上方,且亦存在於開口17的側面,特別是在與上層12的剩餘部分相鄰且位於芯材料14未被覆層的上層12覆蓋的部分的正上方之開口17外圍部分上。更具體而言,蝕刻防止層16被構造成使得階梯部分13以與開口17接壤的方式存在,蝕刻防止層16在橫向方向(沿著第一載體10的長軸方向)上延伸超過階梯部分13。FIG. 3A is a cross-sectional view of the first carrier after patterning to form the
第3C圖為如第3A圖所示之第一載體10之俯視圖,根據至少一個實施例。第3C圖所示之第一載體10的俯視圖係與第2E圖所示之第一載體10的俯視圖相當,儘管因開口17的側面上存在蝕刻防止層16而改變了蝕刻防止層16所覆蓋的表面積比例。Figure 3C is a top view of the
第3B圖為根據至少一個實施例之在蝕刻及通孔形成後的第一載體10之截面圖。如第3B圖所示,透過第二蝕刻製程去除覆層的上層12,以使其在第一載體10的橫向方向上的第一長度小於芯材料14下方的覆層的下層18的長度。根據一些實施例,芯材料14與覆層的下層18可具有大約相同的長度。FIG. 3B is a cross-sectional view of the
沿著比芯材料14及覆層的下層18更短的程度設置覆層的上層12,這樣的構造係用於形成階梯狀或交錯的開口17,該階梯狀或交錯的開口17在第一載體10的中心處具有邊緣或側壁15。階梯狀開口17係於未經機械拋光的情況下形成,其係透過該第一蝕刻製程及第二蝕刻製程形成。亦即,形成一T字形開口,其中T的桿部具有第一寬度,該第一寬度即為芯材料14及覆層的下層18被蝕刻去除部分的寬度,而垂直於該桿部之T的水平部分具有第二寬度,該第二寬度即為覆層的上層12被蝕刻去除部分的寬度,該第二寬度超過該第一寬度。The
在至少一個實施例中,側壁15與芯材料14的邊緣之間的階梯狀開口的寬度可在約2mm至約5mm的範圍內。亦即,第一載體10之第一區段A的覆層上層12與第二區段B的覆層上層12之間的距離,係超過第一區段A的覆層下層18與第二區段B的覆層下層18之間的距離。在晶圓處理期間,通常會排除晶圓鄰近側壁15的一部分,因為該部分無法使用。在至少一個實施例中,第一載體10所容納之晶圓的邊緣排除約為3mm。In at least one embodiment, the width of the stepped opening between the
第3D圖為如第3B圖所示之第一載體10之俯視圖,根據至少一個實施例。如第3D圖所示,至少由於覆層的上層12設置在整個芯材料14上,所以當開口17擴張以形成穿透芯材料14及覆層的下層18之通孔時,芯材料14的一部分是可看見的。因此,根據一些實施例,得到的第一載體10係由兩個不同的部件所形成,亦即,由開口17分開之載體區段A及載體區段B,如第3B圖所示。Figure 3D is a top view of the
第4A至4D圖描繪了第二載體20的製備及形成。第二載體20為當第一載體10位於第二載體20上時支撐第一載體10的載體部件,如第1圖所示。Figures 4A to 4D depict the preparation and formation of the
在一些實施例中,第一載體10與第二載體20的處理及構造彼此不同。例如,根據一些實施例之第一載體10是透過兩種不同的蝕刻製程所製造的,而在一些實施例中的第二載體20可由單一蝕刻製程所製造。作為另一示例,第一載體10與第二載體20的結構構造可在載體尺寸及輪廓方面有所不同。如上所述,第一載體10設置有階梯狀的開口17。相反地,第二載體20被設置為具有一突起之單一結構,如以下詳述。In some embodiments, the processing and configuration of the
第4A圖為根據至少一個實施例之雙載體100的第二載體20於圖案化後之截面圖。第二載體包括一層芯材料24,該層芯材料24夾在覆層材料的上層22與覆層材料的下層28之間。如第4A圖所示,蝕刻防止層26設置在覆層材料的上層22的一部分的頂部上。FIG. 4A is a cross-sectional view of the
應當理解到,這是為了便於說明,且第二載體20中的開口之尺寸及數量可根據某些實施例而變化。例如,於圖4C及圖4D中所圖示之第二載體20可為實際第二載體20的大約一半(亦即,載體10中包含有一個開口的一部分),而第二載體20的全長尺寸可為在第二載體20的長度方向上容納有兩個開口,且在寬度方向上亦容納有兩個開口。It should be understood that this is for ease of description, and the size and number of the openings in the
第4C圖為如第4A圖所示之第二載體20之俯視圖,根據至少一個實施例。如第4C圖所示,蝕刻防止層26係位於覆層材料的上層22的上方,當從載體20的未設置蝕刻防止層26的部分的頂部觀察時,覆層材料的下層28是可見的。Figure 4C is a top view of the
第4B圖為第二載體20為形成平台而經蝕刻後之截面圖,根據至少一個實施例。更具體而言,第4B圖描繪了已經使用酸進行濕蝕刻之後的第二載體20。於蝕刻之後,未被蝕刻防止層26所覆蓋之芯材料24及覆層的上層22被去除。剩餘結構包括覆層的下層28,其形成第二載體20的剩餘部分的平台或基底。FIG. 4B is a cross-sectional view of the
具體而言,覆層的下層28被配置為延伸之平面部分。未被蝕刻去除的芯材料24及覆層的上層22之剩餘部分形成凸部23。凸部23位於覆層的下層28上,使得覆層的下層28為凸部23提供支撐,並以由下層28及凸部23所形成的基底作為平台,從而為第二載體20提供結構穩定性。芯材料24與用於上層22及/或下層28的材料可為不同成分,以便為選擇性提供不同的濕蝕刻速率。當第二載體20與第一載體10組裝在一起時,下層28於凸部23的兩側沿橫向方向延伸,以將第一載體10的第一區段及第二區段支撐在凸部23的相對兩側上。Specifically, the
第4D圖為如第4B圖所示之第二載體20之俯視圖,根據至少一個實施例。如第4D圖所示,當在第二載體20上進行蝕刻時,蝕刻防止層26保護了位於芯材料24的一部分上方之覆層的上層22的一部分,而上層22及芯材料24的其他部分則被移除,僅留下位於凸部23下方的下層28。因此,如俯視圖中所示,僅覆層的上層22及覆層的下層28是可見的。Figure 4D is a top view of the
第5A圖為根據至少一個實施例之附接有晶圓101的雙載體100之截面圖。更具體而言,第5A圖描繪了由第一載體10與第二載體20組裝在一起所形成之雙載體100,其中晶圓101被設置為使得主體101的主軸由第二載體20的凸部23於下方支撐。當第一載體10與第二載體20組裝在一起時,第二載體20的上覆層22的至少一部分與第一載體10的芯材料層14的至少一部分齊平(嵌平),亦即上覆層22的至少一部分的高度與芯材料14層的至少一部分的高度相同。另外,如第5A圖所示,晶圓之大部分係直接由突起23所支撐。這種結構有助於將晶圓101定位。FIG. 5A is a cross-sectional view of the
另外,晶圓101在長度方向上突出超過凸部23的部分佔據了由第一載體10的交錯部分的開口17(階梯狀開口)所形成的空間。亦即,在一些實施例中,係將晶圓101放置為佔據跨越開口17的邊緣15之間的距離之空間。晶圓101係附接至第一載體10的邊緣15。例如,在一些實施例中,係使用黏合劑31(例如,熱塑性黏合劑)來將晶圓101附接至邊緣15。更具體而言,可將黏合劑31設置於第一載體10的邊緣15與芯材料24延伸超過第二載體22的覆層的上層22的部分之間,以使得當晶圓101被載體100所固持時,晶圓101接觸黏合劑31。以此方式,晶圓101係物理性地附接至第一載體10。In addition, the portion of the
晶圓101可被定向成使其第一表面121(例如,頂表面)為不與雙載體100接觸的自由表面。相反地,與其相對之第二表面111(例如底表面)係被定向成與凸部23的上表面(亦即第二載體20的覆層的上層22的上表面)抵接。根據一些實施例,第一表面121及第二表面111都沒有為了要將晶圓101附接至載體101而將黏合劑施加到它們上。具體而言,在至少一個實施例中,能夠以從未將黏合劑施加到晶圓101的頂表面或底表面的方式來進行整個BEOL處理。頂多是在用於定位晶圓之開口17的側壁15處可存在黏合劑。The
第5B圖為根據至少一個實施例之在晶圓薄化後的雙載體100之截面圖。如第5B圖所示,對晶圓101進行薄化以減小晶圓101的高度。具體而言,在一些實施例中,可對晶圓101進行薄化,以使得其高度從突出於第一載體10的覆層的上層12上方的原始高度降低至與覆層的上層12齊平。FIG. 5B is a cross-sectional view of the
在一些實施例中,晶圓101的薄化可以透過拋光來實現。如第5B圖所示,當進行薄化時,晶圓101係保持在其附接並連結至雙載體100時的原始取向。亦即,晶圓101的自由表面121為與覆層的上層12對準的最上方表面,而底表面111則被定位成抵接第二載體20的凸部23。如以下所述,第一載體10中的晶圓101之相同物理組裝可用於薄化晶圓及用於在切割平台上切割晶圓。In some embodiments, the thinning of the
第5C圖為晶圓101從雙載體100的第二載體20分離後的雙載體100之截面圖,根據至少一個實施例。更具體而言,第5C圖繪示了在薄化晶圓101後,從第二載體20分離時之第一載體10及晶圓101。固持晶圓101之第一載體10係從第二載體20分離以準備進行切割。經薄化後之晶圓101係相對於第一載體10保持其位置,從而被固持於覆層的上層12的邊緣15之間,並由芯材料14延伸超過上層12的邊緣15的部分所支撐。FIG. 5C is a cross-sectional view of the
第5D圖為晶圓101分離後的雙載體100的一部分之截面圖,根據至少一個實施例。更具體而言,第5D圖繪示了與固持經薄化後之晶圓101的第一載體10分離之第二載體20。第二載體20係與第一載體分離,使得凸部23不再支撐晶圓101,且晶圓101的底面111不再與凸部23抵接。相反地,除了那些與第一載體的上層12的邊緣15接觸的部分,底面111是自由且不受阻礙的。在至少一個實施例中,晶圓101與雙載體100的分離可藉由個別部件的分子的凡德瓦力作用來完成;替代地或另外地,亦可應用熱釋放黏合材料。FIG. 5D is a cross-sectional view of a part of the
第6A圖為位於平台上的雙載體100的一部分之截面圖,根據至少一個實施例。具體而言,第6A圖繪示了相對於例如第5C圖處於倒置方向的第一載體10。在至少一個實施例中,在晶圓101經薄化且第二載體20已從第一載體分離之後,固持晶圓101的第一載體10的組件被倒置。亦即,在不從第一載體10移除晶圓101的情況下倒置晶圓101。由晶圓101所製成之半導體元件50(例如,積體電路)被固持於載體100中。Figure 6A is a cross-sectional view of a portion of the
如第6A圖所示,當倒置時,晶圓101的表面111不再是晶圓101的底表面;相反地,它成為了頂表面,且表面111的大部分為暴露並且不受阻礙的。此外,當倒置時,晶圓101的表面121不再是自由的上表面,反而是成為晶圓101的底表面。在倒置狀態下,將第一載體10與晶圓101的組件置於切割平台40上,準備對晶圓101進行切割。當晶圓101被置於切割台平40上後,將切割工具置於晶圓101上方。As shown in FIG. 6A, when inverted, the
以此方式,即可在無需將晶圓101從第一載體10移出的情況下將晶圓101輸送至切割平台40,從而避免了需要另外的剝離製程來將晶圓從支撐件上分離的情況。具體而言,可完全省略掉雷射剝離製程。透過省略剝離製程,可降低對脆弱的薄化晶圓101造成損傷的風險。以此方式,可提高晶圓的產量,亦即減少晶圓的損壞率。In this way, the
第6B圖為在晶圓切割期間,位於平台上的雙載體的一部分之截面圖,根據至少一個實施例。使用切割工具將晶圓101切割為多個晶粒,例如,使得晶圓101在分界點60處被切割。在晶圓101仍處於載體10中的情況下,使用切割工具來進行切割。換言之,晶圓101不需要被輸送至另一位置,且切割可在原位進行。也就是說,不用將薄化後的晶圓101從進行薄化的位置輸送至另一個位置來進行切割。Figure 6B is a cross-sectional view of a part of the dual carrier on the platform during wafer dicing, according to at least one embodiment. The
第6C圖為晶圓101經切割後,位於平台40上的雙載體100的一部分之截面圖,根據至少一個實施例。更具體而言,在使用切割工具進行切割後,將晶圓101分為多個單獨的晶粒,包括兩個最外部晶粒103(矽邊緣)及內部晶粒105。基於與BEOL處理現象相關的各種製造原因,最外部晶粒103通常會劣於內部晶粒105,且通常會被丟棄(亦即,該等部分為被排除的邊緣)。剩餘的晶粒105被保留以進行進一步處理。由於晶粒105已被切割且可從載體10分離,因此不再需要剝離製程。FIG. 6C is a cross-sectional view of a part of the
根據一些實施例,在第一載體10從第二載體20分離後,第二載體20可被回收。在一些實施例中,在完成晶圓101的切割後,第一載體10及第二載體20皆可被回收。如第6C圖所示,最外部晶粒103在第一載體的覆層的上層12的邊緣15處與黏合劑31的位置相鄰。當第一載體10被回收時,最外部晶粒103及黏合劑31可被挑出。可透過對黏合劑施加熱及/或化學成分來去除黏合劑31。According to some embodiments, after the
應當理解到,前述實施例僅為說明性的。亦可採用其他的雙載體幾何形狀。此外,載體100不限於兩件式載體,且可由更少或更多的部件所形成。另外,在一些實施例中,可使用第一載體10及/或第二載體20或其他上述部件來進行進一步的處理。例如,除了晶圓101的切片之外,切割平台40亦可用於包括晶圓101的背面研磨等之製程及其他BEOL處理。第9圖繪示了根據至少一個實施例之用於製造雙載體的製程900的示例性製程圖。該製程包括根據上述技術建構第一載體10(901)。更具體而言,第一載體10係由芯層14、覆層的上層12、及覆層的下層18所製成,且該等部件可如以上結合第7、8圖所述般形成及組裝。亦即,芯層14、上層12及下層18可使用如第8圖所示之分配器製成。覆層的上層12及下層18可透過例如熔合的方式附接至芯層14。因此,芯層14被夾在上層12及下層18之間。第二載體20係以類似的方式製成。It should be understood that the foregoing embodiments are only illustrative. Other dual carrier geometries can also be used. In addition, the
在至少一個實施例中,於製造第一載體10後,對第一載體10進行圖案化及蝕刻之第一製程(902)。更具體而言,在覆層的上層12上提供蝕刻防止層16以進行圖案化,亦即,決定將透過蝕刻去除或保留哪些部分。然後,進行蝕刻(例如,濕蝕刻)以去除上覆層12的一部分,從而露出芯層14的一部分。以此方式,形成載體10的階梯狀部分,該階梯狀部分具有側壁15。接著,進行圖案化及蝕刻之第二製程(903)。在第二製程中,提供蝕刻防止層16,以使其沿著覆層的上層12的主表面延伸越過側壁15。進行蝕刻(例如,濕蝕刻)以形成開口17,開口17將第一載體10分成如圖3B所示之第一區段A及第二區段B,藉此得到分段的載體(904)。In at least one embodiment, after the
製程900進一步包括建構第二載體20(905)。形成芯層24、覆層的上層22、及覆層的下層28,並根據如以上結合第7、8圖所表示及敘述的技術,將芯層24附接至上層22及下層28。隨後,對第二載體20進行圖案化及蝕刻(906)。將蝕刻防止層26置於覆層的上層22上。進行蝕刻(例如濕蝕刻),以使得所得到之載體20包括由覆層的下層28所形成之基底、以及從該基底延伸並包括芯層24及上層22之突起23,以作為平台。然後將第一載體10與第二載體20組裝在一起(907)。The
具體而言,第一載體10的區段A係位於第二載體20的基底之第一側,亦即,在第一基底部分,而第一載體10的區段B則位於第二載體20的基底之第二側,亦即,在第二基底部分,該第二側係與該第一側相對,在區段A、B之間具有凸部23。如上所述,當第二載體20與第一載體10組裝在一起時,第二載體20的上覆層22與第一載體10的芯材料層14的高度齊平。應當理解到,可同時建構第一載體10及第二載體20,或於建構第二載體20前先建構第一載體10,或於建構第一載體10前先建構第二載體20。Specifically, the section A of the
如本文所用,用語「連接」或「偶接」等意指兩個構件彼此直接或間接地接合。這樣的接合可為固定的(例如,永久的)或可動的(例如,可移除或可釋放的)。可透過兩個構件或兩個構件及任何另外的中間構件彼此一體地形成為個別整體,或者透過兩個構件或兩個構件及任何另外的中間構件彼此附接而實現這種接合。As used herein, the terms “connected” or “coupled” and the like mean that two components are directly or indirectly joined to each other. Such engagement may be fixed (eg, permanent) or movable (eg, removable or releasable). This joining can be achieved by two members or two members and any other intermediate member being integrally formed with each other as an individual whole, or by attaching two members or two members and any other intermediate member to each other.
本文中對元件的位置(例如,「頂部」、「底部」、「上方」、「下方」等)的引用僅用於描述附圖中各個元件的方向。應當注意,根據其他示例性實施例,各種元件的位向可以不同,且本案意欲涵蓋此類變型。References to the positions of elements (for example, "top", "bottom", "above", "below", etc.) herein are only used to describe the orientation of each element in the drawings. It should be noted that according to other exemplary embodiments, the orientation of various elements may be different, and this case is intended to cover such variations.
應當注意,各種示例實施例的構造及佈置僅為說明性的。雖然在本案中僅詳述了一些實施例,但審閱本案之本領域技術人員將容易理解到,許多修改是可能的(例如,各種元件的大小、尺寸、結構、形狀及比例的變化、各種參數、安裝佈置、材料的使用、方向等),而不會實質地脫離本文所述標的之新穎教示及優勢。It should be noted that the configuration and arrangement of the various example embodiments are merely illustrative. Although only some embodiments are described in detail in this case, those skilled in the art who have reviewed this case will easily understand that many modifications are possible (for example, changes in the size, size, structure, shape and ratio of various elements, various parameters , Installation arrangement, material use, direction, etc.) without materially departing from the novel teachings and advantages of the subject matter described herein.
例如,表示為整體形成的元件可由多個部分或元件構成,元件的位置可顛倒或以其他方式改變,且離散元件的性質或數量或位置可以修改或變化。根據替代實施例,任何製程或方法步驟的順序可被改變或重新排序。在各種示例實施例的設計、操作條件及佈置中,亦可在不背離本文提出的概念的範圍內,進行其他替換、修改、改變及省略。For example, an element represented as integrally formed may be composed of multiple parts or elements, the position of the element may be reversed or changed in other ways, and the nature or number or position of discrete elements may be modified or changed. According to alternative embodiments, the order of any process or method steps may be changed or re-sequenced. In the design, operating conditions, and arrangement of various exemplary embodiments, other substitutions, modifications, changes, and omissions may also be made within the scope of not departing from the concepts presented herein.
雖然本說明書包含許多特定的實施細節,但這些不應被解釋為對任何實施例或可能請求保護的範圍之限制,而僅是對特定實施例的特定實施所特有的特徵之描述。在單獨的實現方式的上下文中,本說明書中所描述的某些特徵也可以在個別實現方式中組合實現。Although this specification contains many specific implementation details, these should not be construed as limiting any embodiment or the scope of protection that may be claimed, but only a description of the characteristics specific to the specific implementation of the specific embodiment. In the context of separate implementations, certain features described in this specification can also be implemented in combination in individual implementations.
相反地,在個別實施方式的上下文中所描述的各種特徵亦可分別在多個實施方式中或以任何合適的子組合來實施。此外,儘管以上可能將某些特徵描述為以某些組合來作用,且甚至最初如此聲稱,但在某些情況下可從組合中切除所請求保護的組合中之一或更多個特徵,且所請求保護的組合可針對子組合、或子組合之變體。Conversely, various features described in the context of individual embodiments can also be implemented in multiple embodiments separately or in any suitable subcombination. In addition, although the above may describe certain features as acting in certain combinations, and even initially claiming so, in some cases one or more of the claimed combinations may be removed from the combination, and The claimed combination may be for a sub-combination, or a variant of the sub-combination.
10:第一載體 12:覆層的上層 13:階梯部分 14:芯材料 15:側壁 16:蝕刻防止層 17:開口 18:覆層的下層 20:第二載體 22:覆層的上層 23:凸部 24:芯材料 26:蝕刻防止層 28:覆層的下層 31:黏合劑 40:切割台平 50:半導體元件 60:分界點 100:雙載體 101:晶圓 102:芯層 103:最外部晶粒 104:第一覆層 105:內部晶粒 106:第二覆層 111:第二表面 121:第一表面 200:玻璃製品 220:下部溢流分配器 222:槽 224:第一玻璃組合物 226:外部成形表面 228:外部成形表面 230:牽引線 240:上部溢流分配器 242:槽 244:第二玻璃組合物 246:外部形成表面 248:外部形成表面 300:溢流分配器 900:製程 901:步驟 902:步驟 903:步驟 904:步驟 905:步驟 906:步驟 907:步驟 A:區段 B:區段10: The first carrier 12: Upper layer of cladding 13: Stepped part 14: core material 15: side wall 16: Etching prevention layer 17: opening 18: Lower layer of cladding 20: second carrier 22: Upper layer of cladding 23: Convex 24: core material 26: Etching prevention layer 28: Lower layer of cladding 31: Adhesive 40: Cutting table level 50: Semiconductor components 60: Demarcation point 100: dual carrier 101: Wafer 102: core layer 103: Outermost Die 104: first cladding 105: internal grain 106: second cladding 111: second surface 121: first surface 200: glass products 220: Lower overflow distributor 222: Slot 224: The first glass composition 226: External forming surface 228: External forming surface 230: traction line 240: Upper overflow distributor 242: Slot 244: second glass composition 246: External forming surface 248: External forming surface 300: Overflow distributor 900: Process 901: step 902: step 903: step 904: step 905: step 906: step 907: step A: section B: section
透過結合附圖之以下敘述及所附申請專利範圍,本案之上述及其他特徵將變得更加清楚明顯。應當理解,該等附圖僅示出了根據本案之幾種實施方式,因此不應被認為是對其範圍之限制,將透過使用附圖以附加的特徵及細節來描述本案。The above and other features of this case will become clearer and more obvious through the following description in conjunction with the accompanying drawings and the scope of the attached patent application. It should be understood that the drawings only show a few implementations according to the case, and therefore should not be considered as a limitation of its scope. The case will be described with additional features and details by using the drawings.
第1圖為根據至少一個實施例之放置有晶圓的雙載體之截面圖。Figure 1 is a cross-sectional view of a dual carrier on which wafers are placed according to at least one embodiment.
第2A圖為雙載體的第一載體於圖案化前之截面圖,根據至少一個實施例。Figure 2A is a cross-sectional view of the first carrier of the dual carrier before patterning, according to at least one embodiment.
第2B圖為雙載體的第一載體於圖案化後之截面圖,根據至少一個實施例。Figure 2B is a cross-sectional view of the first carrier of the dual carrier after patterning, according to at least one embodiment.
第2C圖為雙載體的第一載體於蝕刻後之截面圖,根據至少一個實施例。Figure 2C is a cross-sectional view of the first carrier of the dual carrier after etching, according to at least one embodiment.
第2D圖為如第2B圖所示之第一載體之俯視圖,根據至少一個實施例。Figure 2D is a top view of the first carrier as shown in Figure 2B, according to at least one embodiment.
第2E圖為如第2C圖所示之第一載體之俯視圖,根據至少一個實施例。Figure 2E is a top view of the first carrier as shown in Figure 2C, according to at least one embodiment.
第3A圖為第一載體為形成通孔而經圖案化後之截面圖,根據至少一個實施例。FIG. 3A is a cross-sectional view of the first carrier after being patterned to form through holes, according to at least one embodiment.
第3B圖為第一載體經蝕刻及通孔形成後之截面圖,根據至少一個實施例。FIG. 3B is a cross-sectional view of the first carrier after etching and through-hole formation, according to at least one embodiment.
第3C圖為如第3A圖所示之第一載體之俯視圖,根據至少一個實施例。Figure 3C is a top view of the first carrier as shown in Figure 3A, according to at least one embodiment.
第3D圖為如第3B圖所示之第一載體之俯視圖,根據至少一個實施例。Figure 3D is a top view of the first carrier as shown in Figure 3B, according to at least one embodiment.
第4A圖為雙載體的第二載體於圖案化後之截面圖,根據至少一個實施例。Figure 4A is a cross-sectional view of the second carrier of the dual carrier after patterning, according to at least one embodiment.
第4B圖為第二載體為形成平台而經蝕刻後之截面圖,根據至少一個實施例。Figure 4B is a cross-sectional view of the second carrier after being etched to form a platform, according to at least one embodiment.
第4C圖為如第4A圖所示之第二載體之俯視圖,根據至少一個實施例。Figure 4C is a top view of the second carrier as shown in Figure 4A, according to at least one embodiment.
第4D圖為如第4B圖所示之第二載體之俯視圖,根據至少一個實施例。Figure 4D is a top view of the second carrier as shown in Figure 4B, according to at least one embodiment.
第5A圖為附接有晶圓的雙載體之截面圖,根據至少一個實施例。Figure 5A is a cross-sectional view of a dual carrier with wafer attached, according to at least one embodiment.
第5B圖為晶圓拋光後的雙載體之截面圖,根據至少一個實施例。Figure 5B is a cross-sectional view of the dual carrier after wafer polishing, according to at least one embodiment.
第5C圖為晶圓從雙載體的第二載體分離後的雙載體之截面圖,根據至少一個實施例。FIG. 5C is a cross-sectional view of the dual carrier after the wafer is separated from the second carrier of the dual carrier, according to at least one embodiment.
第5D圖為晶圓分離後的雙載體的一部分之截面圖,根據至少一個實施例。Figure 5D is a cross-sectional view of a part of the dual carrier after wafer separation, according to at least one embodiment.
第6A圖為位於平台上的雙載體的一部分之截面圖,根據至少一個實施例。Figure 6A is a cross-sectional view of a part of a dual carrier on a platform, according to at least one embodiment.
第6B圖為在晶圓切割期間,位於平台上的雙載體的一部分之截面圖,根據至少一個實施例。Figure 6B is a cross-sectional view of a part of the dual carrier on the platform during wafer dicing, according to at least one embodiment.
第6C圖為晶圓經切割後,位於平台上的雙載體的一部分之截面圖,根據至少一個實施例。Figure 6C is a cross-sectional view of a part of the dual carrier on the platform after the wafer has been diced, according to at least one embodiment.
第7圖為玻璃製品之截面圖,根據至少一個實施例。Figure 7 is a cross-sectional view of a glass product, according to at least one embodiment.
第8圖為可用於形成玻璃製品的溢流分配器之截面圖,根據至少一個實施例。Figure 8 is a cross-sectional view of an overflow distributor that can be used to form glass products, according to at least one embodiment.
第9圖示出製造雙載體之製程,根據至少一個實施例。Figure 9 shows a process for manufacturing a dual carrier, according to at least one embodiment.
於以下詳細描述中參考附圖。於附圖中,除非上下文另外指出,否則相似的符號通常表示相似的部件。於詳細描述、附圖、及申請專利範圍中所描述之說明性實施例並非限制性的。在不脫離本案所提出的標的之精神或範圍的情況下,可利用其他實施方式,且可以進行其他改變。可輕易地理解到,如本案一般描述及附圖所示,本案之各種態樣能夠以各種不同的配置來佈置、替換、組合及設計,這些都被明確地視為本案內容的一部分。Refer to the drawings in the following detailed description. In the drawings, similar symbols generally indicate similar components unless the context indicates otherwise. The illustrative embodiments described in the detailed description, drawings, and scope of patent application are not limitative. Without departing from the spirit or scope of the subject matter proposed in this case, other implementation manners can be used, and other changes can be made. It can be easily understood that, as shown in the general description of the case and the accompanying drawings, the various aspects of the case can be arranged, replaced, combined and designed in various configurations, which are clearly regarded as part of the content of the case.
國內寄存資訊(請依寄存機構、日期、號碼順序註記) 無 國外寄存資訊(請依寄存國家、機構、日期、號碼順序註記) 無Domestic deposit information (please note in the order of deposit institution, date and number) no Foreign hosting information (please note in the order of hosting country, institution, date and number) no
10:第一載體 10: The first carrier
20:第二載體 20: second carrier
100:雙載體 100: dual carrier
101:晶圓 101: Wafer
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US4214886A (en) | 1979-04-05 | 1980-07-29 | Corning Glass Works | Forming laminated sheet glass |
US6344105B1 (en) * | 1999-06-30 | 2002-02-05 | Lam Research Corporation | Techniques for improving etch rate uniformity |
US20080142946A1 (en) | 2006-12-13 | 2008-06-19 | Advanced Chip Engineering Technology Inc. | Wafer level package with good cte performance |
US20090221150A1 (en) * | 2008-02-29 | 2009-09-03 | Applied Materials, Inc. | Etch rate and critical dimension uniformity by selection of focus ring material |
US7960840B2 (en) | 2008-05-12 | 2011-06-14 | Texas Instruments Incorporated | Double wafer carrier process for creating integrated circuit die with through-silicon vias and micro-electro-mechanical systems protected by a hermetic cavity created at the wafer level |
KR20130000211A (en) | 2011-06-22 | 2013-01-02 | 삼성전자주식회사 | Methods for processing substrates |
US8629043B2 (en) | 2011-11-16 | 2014-01-14 | Taiwan Semiconductor Manufacturing Company, Ltd. | Methods for de-bonding carriers |
KR102421511B1 (en) | 2014-03-27 | 2022-07-15 | 코닝 인코포레이티드 | Glass Article |
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