TW202036823A - Bonding structure for electronic packages and bonding wire - Google Patents
Bonding structure for electronic packages and bonding wire Download PDFInfo
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- TW202036823A TW202036823A TW108109032A TW108109032A TW202036823A TW 202036823 A TW202036823 A TW 202036823A TW 108109032 A TW108109032 A TW 108109032A TW 108109032 A TW108109032 A TW 108109032A TW 202036823 A TW202036823 A TW 202036823A
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/10—Bump connectors; Manufacturing methods related thereto
- H01L2224/12—Structure, shape, material or disposition of the bump connectors prior to the connecting process
- H01L2224/13—Structure, shape, material or disposition of the bump connectors prior to the connecting process of an individual bump connector
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/42—Wire connectors; Manufacturing methods related thereto
- H01L2224/47—Structure, shape, material or disposition of the wire connectors after the connecting process
- H01L2224/48—Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
- H01L2224/484—Connecting portions
- H01L2224/48463—Connecting portions the connecting portion on the bonding area of the semiconductor or solid-state body being a ball bond
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/42—Wire connectors; Manufacturing methods related thereto
- H01L2224/47—Structure, shape, material or disposition of the wire connectors after the connecting process
- H01L2224/48—Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
- H01L2224/485—Material
- H01L2224/48505—Material at the bonding interface
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Abstract
Description
本發明實施例係有關於一種接合結構,且特別有關於一種電子封裝接合結構。The embodiment of the present invention relates to a bonding structure, and particularly to an electronic package bonding structure.
打線接合(wire bonding)為積體電路(integrated circuit (IC))及發光二極體(light-emitting diode (LED))封裝的主要步驟之一。打線接合產品的可靠度主要取決於接合線與接合墊(例如:鋁墊)之間接合界面的品質。傳統封裝製程通常使用純金線、純銅線或銀合金線作為打線接合之接合線。Wire bonding is one of the main steps of integrated circuit (IC) and light-emitting diode (LED) packaging. The reliability of wire bonding products mainly depends on the quality of the bonding interface between the bonding wire and the bonding pad (such as aluminum pad). Traditional packaging processes usually use pure gold wires, pure copper wires or silver alloy wires as bonding wires for wire bonding.
根據文獻1(T.C. Wei and A.R. Daud, Mechanical and Electrical Properties of Au-Al and Cu-Al Intermetallics Layers at Wire Bonding Interface, Journal of Electronic Packaging, December 2003, Vol. 125, pp.617-620.)之報導,使用純金線與鋁墊進行打線接合並進行時效處理時,Au-Al介金屬相會快速成長,導致強度衰減及電阻率明顯上升。文獻1亦指出使用純銅線與鋁墊進行打線接合並進行時效處理時,Cu-Al介金屬相成長較緩慢,但仍會造成接合強度降低及電阻率上升。According to the report in Literature 1 (TC Wei and AR Daud, Mechanical and Electrical Properties of Au-Al and Cu-Al Intermetallics Layers at Wire Bonding Interface, Journal of Electronic Packaging, December 2003, Vol. 125, pp. 617-620.) , When using pure gold wire and aluminum pad for wire bonding and aging treatment, the Au-Al intermetallic phase will grow rapidly, resulting in strength attenuation and a significant increase in resistivity. Document 1 also pointed out that when pure copper wire and aluminum pad are used for wire bonding and aging treatment, the growth of the Cu-Al intermetallic phase is slower, but the bonding strength will still decrease and the resistivity will increase.
根據文獻2(C.L. Gan, C. Francis, B.L. Chan and U. Hashim, Gold Bull, 2013, Vol. 46, pp. 103-115.)之報導,使用純金線、純銅線與鋁墊進行打線接合並進行各種可靠度試驗之後,球焊點(或可稱為銲點)與鋁墊的界面發生嚴重之破裂,原因可能是Au-Al與Cu-Al介金屬相水解形成氧化鋁顆粒及氫氣而導致界面破裂之情形發生。According to literature 2 (CL Gan, C. Francis, BL Chan and U. Hashim, Gold Bull, 2013, Vol. 46, pp. 103-115.), pure gold wire, pure copper wire and aluminum pad are used for wire bonding and After various reliability tests, the interface between the ball solder joint (or solder joint) and the aluminum pad was severely cracked, which may be caused by the hydrolysis of Au-Al and Cu-Al intermetallic phase to form alumina particles and hydrogen. The interface rupture occurs.
根據文獻3(T.H. Chuang, C.C. Chang, C.H. Chuang, J.D. Lee and H.H. Tsai, Formation and Growth of Intermetallics in an Annealing-Twinned Ag-8Au-3Pd Wire Bonding Package During Reliability Tests, IEEE Transactions on Components, Packaging and Manufacturing Technology, January 2013, Vol. 3, No.1, pp.3-9.)之報導,使用Ag-8Au-3Pd銀合金線與鋁墊進行打線接合並進行各種可靠度試驗之後,球焊點與鋁墊的界面出現介金屬相Ag2 Al和AgAl2 。文獻3亦指出在使用純金線與鋁墊進行打線接合並進行可靠度試驗後,形成很厚的介金屬相Au8 Al3 、Au4 Al和AuAl2 。文獻3亦指出在使用純銅線與鋁墊進行打線接合並進行可靠度試驗後,形成介金屬相CuAl2 。According to literature 3 (TH Chuang, CC Chang, CH Chuang, JD Lee and HH Tsai, Formation and Growth of Intermetallics in an Annealing-Twinned Ag-8Au-3Pd Wire Bonding Package During Reliability Tests, IEEE Transactions on Components, Packaging and Manufacturing Technology , January 2013, Vol. 3, No.1, pp.3-9.) reported that using Ag-8Au-3Pd silver alloy wire and aluminum pad for wire bonding and various reliability tests, the ball solder joints and aluminum The intermetallic phases Ag 2 Al and AgAl 2 appear at the interface of the pad. Document 3 also pointed out that after the use of pure gold wire and aluminum pad for wire bonding and reliability test, thick intermetallic phases Au 8 Al 3 , Au 4 Al and AuAl 2 are formed . Document 3 also pointed out that after the use of pure copper wire and aluminum pad for wire bonding and reliability test, the intermetallic phase CuAl 2 is formed.
綜合上述,使用傳統的接合線進行打線接合製程所形成之介金屬相介面結構在封裝可靠度試驗及晶片運作的過程中可能會過度成長而導致電子產品性能劣化甚至失效。In summary, the intermetallic interface structure formed by the traditional bonding wire for wire bonding process may grow excessively during the package reliability test and chip operation process, which may cause the performance of electronic products to deteriorate or even fail.
由以上可知,雖然傳統的接合線大抵上滿足一般的使用需求,但並非在各方面都令人滿意。It can be seen from the above that although the traditional bonding wire meets the general use requirements, it is not satisfactory in all aspects.
本發明實施例包括一種電子封裝接合結構。上述電子封裝接合結構包括設置於半導體晶片上的球焊點部分。上述電子封裝接合結構亦包括設置於上述半導體晶片與上述球焊點部分之間的界面結構。上述界面結構包括一或多種尖晶石相MAl2 O4 。The embodiment of the present invention includes an electronic package bonding structure. The above-mentioned electronic package bonding structure includes a ball solder joint portion provided on a semiconductor chip. The electronic package bonding structure also includes an interface structure provided between the semiconductor chip and the ball solder joint portion. The aforementioned interface structure includes one or more spinel phase MAl 2 O 4 .
本發明實施例包括一種接合線。上述接合線包括金屬材料。上述金屬材料包括銀、銅、金、鋁、銀合金、銅合金、金合金、鋁合金或上述之組合。上述接合線亦包括Ce、Hf、La、Lu、Ta、Ti、Zn、Nb或上述之組合。The embodiment of the present invention includes a bonding wire. The aforementioned bonding wire includes a metal material. The aforementioned metal materials include silver, copper, gold, aluminum, silver alloys, copper alloys, gold alloys, aluminum alloys, or combinations thereof. The bonding wire also includes Ce, Hf, La, Lu, Ta, Ti, Zn, Nb or a combination of the above.
以下的揭露內容提供許多不同的實施例或範例以實施本案的不同特徵。以下的揭露內容敘述各個構件及其排列方式的特定範例,以簡化說明。當然,這些特定的範例並非用以限定。例如,若是本發明實施例敘述了一第一特徵部件形成於一第二特徵部件之上或上方,即表示其可能包含上述第一特徵部件與上述第二特徵部件是直接接觸的實施例,亦可能包含了有附加特徵部件形成於上述第一特徵部件與上述第二特徵部件之間,而使上述第一特徵部件與第二特徵部件可能未直接接觸的實施例。The following disclosure provides many different embodiments or examples to implement different features of this case. The following disclosure describes specific examples of each component and its arrangement to simplify the description. Of course, these specific examples are not meant to be limiting. For example, if the embodiment of the present invention describes that a first characteristic part is formed on or above a second characteristic part, it means that it may include an embodiment in which the first characteristic part and the second characteristic part are in direct contact. It may include an embodiment in which an additional characteristic part is formed between the first characteristic part and the second characteristic part, and the first characteristic part and the second characteristic part may not be in direct contact.
應理解的是,額外的操作步驟可實施於所述方法之前、之間或之後,且在所述方法的其他實施例中,部分的操作步驟可被取代或省略。It should be understood that additional operation steps may be implemented before, during or after the method, and in other embodiments of the method, part of the operation steps may be replaced or omitted.
此外,其中可能用到與空間相關用詞,例如「在…下方」、「下方」、「較低的」、「上方」、「較高的」及類似的用詞,這些空間相關用詞係為了便於描述圖示中一個(些)元件或特徵部件與另一個(些)元件或特徵部件之間的關係,這些空間相關用詞包括使用中或操作中的裝置之不同方位,以及圖式中所描述的方位。當裝置被轉向不同方位時(旋轉90度或其他方位),則其中所使用的空間相關形容詞也將依轉向後的方位來解釋。In addition, terms related to space may be used, such as "below", "below", "lower", "above", "higher" and similar terms. These space-related terms are In order to facilitate the description of the relationship between one element(s) or characteristic part and another element(s) or characteristic part in the illustration, these spatially related terms include the different orientations of the device in use or operation, and the The orientation described. When the device is turned in different directions (rotated by 90 degrees or other directions), the space-related adjectives used therein will also be interpreted according to the turned position.
除非另外定義,在此使用的全部用語(包括技術及科學用語)具有與此篇揭露所屬之一般技藝者所通常理解的相同涵義。能理解的是,這些用語,例如在通常使用的字典中定義的用語,應被解讀成具有與相關技術及本發明的背景或上下文一致的意思,而不應以一理想化或過度正式的方式解讀,除非在本發明實施例有特別定義。Unless otherwise defined, all terms (including technical and scientific terms) used herein have the same meanings commonly understood by the general artisans to whom the disclosure belongs. It is understandable that these terms, such as those defined in commonly used dictionaries, should be interpreted as having meanings consistent with the relevant technology and the background or context of the present invention, and should not be interpreted in an idealized or overly formal way. Interpretation, unless specifically defined in the embodiments of the present invention.
本揭露全文關於「純金屬」(例如:純銀、純銅、純金、純鋁)的敘述,係指在設計上期望為完全不含其他元素、化合物等雜質的純金屬,但在實際冶煉、精煉、鍍膜等過程中卻難以完全除去上述雜質而達成數學上或理論上含100%的純金屬,而當上述雜質含量的範圍落於對應的標準或規格所訂定的允收範圍內,就可視為「實質上的純金屬」。其他任何的實質上的純物質的意義亦同。本發明所屬技術領域中具有通常知識者應當瞭解依據不同的性質、條件、需求等等,上述對應的標準或規格會有所不同,故下文中並未列出特定的標準或規格。The description of “pure metal” (such as pure silver, pure copper, pure gold, pure aluminum) in the full text of this disclosure refers to a pure metal that is expected to be completely free of impurities such as other elements and compounds, but in actual smelting, refining, and It is difficult to completely remove the above-mentioned impurities during the process of coating and so on to achieve a mathematical or theoretical 100% pure metal. When the range of the above-mentioned impurity content falls within the allowable range set by the corresponding standard or specification, it can be regarded as "Substantially pure metal." The meaning of any other substantially pure matter is the same. Those with ordinary knowledge in the technical field to which the present invention pertains should understand that the corresponding standards or specifications mentioned above will be different according to different properties, conditions, requirements, etc., so no specific standards or specifications are listed below.
以下所揭露之不同實施例可能重複使用相同的參考符號及/或標記。這些重複係為了簡化與清晰的目的,並非用以限定所討論的不同實施例及/或結構之間有特定的關係。The different embodiments disclosed below may use the same reference symbols and/or marks repeatedly. These repetitions are for the purpose of simplification and clarity, and are not used to limit the specific relationship between the different embodiments and/or structures discussed.
在本發明實施例之電子封裝結構中,接合結構係包括與半導體晶片接合之界面結構,且上述界面結構係包括一或多種尖晶石相MAl2 O4 。相較於傳統之介金屬相,本發明實施例之包括一或多種尖晶石相MAl2 O4 的界面結構的機械性質較佳,因此可減少或避免破裂的情況發生而提高電子封裝結構的可靠度。In the electronic package structure of the embodiment of the present invention, the bonding structure includes an interface structure that is bonded to the semiconductor chip, and the interface structure includes one or more spinel phase MAl 2 O 4 . Compared with the traditional intermetallic phase, the mechanical properties of the interface structure including one or more spinel phases of MAl 2 O 4 in the embodiments of the present invention are better, so that the occurrence of cracking can be reduced or avoided and the electronic package structure is improved. Reliability.
本發明實施例之尖晶石相MAl2 O4 具有許多優點,例如:高強度、高熔點、優異的耐化學侵蝕性、耐熱衝擊性。舉例而言,本發明實施例之尖晶石相MAl2 O4 的熱傳導率可為1.0至 5.0 W/mK,熱膨脹係數可為6 x 10-6 K-1 至12 x 10-6 K-1 ,因此可以和大部分的金屬與陶瓷材料相容。此外,在一些實施例中,即使上述尖晶石相MAl2 O4 部分或全部轉化為反尖晶石相Al(MAl)2 O4 ,其物理與化學性質也不會有巨幅改變。The spinel phase MAl 2 O 4 of the embodiment of the present invention has many advantages, such as high strength, high melting point, excellent chemical resistance, and thermal shock resistance. For example, the thermal conductivity of the spinel phase MAl 2 O 4 of the embodiment of the present invention may be 1.0 to 5.0 W/mK, and the thermal expansion coefficient may be 6 x 10 -6 K -1 to 12 x 10 -6 K -1 , So it is compatible with most metal and ceramic materials. In addition, in some embodiments, even if the above-mentioned spinel phase MAl 2 O 4 is partially or completely converted into inverse spinel phase Al(MAl) 2 O 4 , its physical and chemical properties will not be greatly changed.
在一些實施例中,所形成之尖晶石相MAl2 O4 是良好的擴散阻障層(barrier layer),因此在接合製程(例如:打線接合製程)中可抑制對接合結構(例如:焊點結構)之可靠度不利之介金屬相之成長,藉此可避免或減少接合結構發生破裂及水解腐蝕等問題,亦可避免或減少接合結構中之Kirkendall孔洞的形成。In some embodiments, the formed spinel phase MAl 2 O 4 is a good diffusion barrier layer (barrier layer), so the bonding process (such as: wire bonding process) can inhibit the bonding structure (such as: welding The growth of the intermetallic phase that is unfavorable for the reliability of the dot structure can avoid or reduce the problems of cracking and hydrolytic corrosion of the bonding structure, and also avoid or reduce the formation of Kirkendall holes in the bonding structure.
在一些實施例中,由於所形成之接合結構之尖晶石相MAl2 O4 具有高強度、抗熱震、耐腐蝕等特性,因此可以有效提升電子產品(例如:電子封裝結構)的使用壽命。In some embodiments, since the spinel phase MAl 2 O 4 of the formed bonding structure has the characteristics of high strength, thermal shock resistance, corrosion resistance, etc., it can effectively improve the service life of electronic products (such as electronic packaging structures) .
此外,在傳統之接合製程中,接合線與半導體晶片上之接合墊反應所形成之界面介金屬相大多呈現貝殼狀成長,因此在焊點與半導體晶片之間(或者焊點與殘留之接合墊之間)會具有空隙而造成接合不完整。相較於傳統之介金屬相,在一些本發明的實施例中,所形成的尖晶石相MAl2 O4 較為連續,使得焊點與半導體晶片之間(或者焊點與殘留之接合墊之間)可較完整地接合。In addition, in the traditional bonding process, the intermetallic phase formed by the reaction between the bonding wire and the bonding pad on the semiconductor chip mostly exhibits a shell-like growth. Therefore, between the solder joint and the semiconductor chip (or between the solder joint and the remaining bonding pad) (Between) will have gaps and cause incomplete joints. Compared with the traditional intermetallic phase, in some embodiments of the present invention, the formed spinel phase MAl 2 O 4 is more continuous, so that between the solder joint and the semiconductor chip (or between the solder joint and the remaining bonding pad) Between) can be more completely joined.
另一方面,由於半導體晶片上之接合墊的尺寸持續縮小,在使用傳統之接合線進行打線接合製程後,小尺寸之接合墊可能會被完全轉化成傳統之介金屬相。由於傳統之介金屬相與半導體晶片(例如:矽晶片)之間的鍵結力很低,因此容易發生焊點脫落之問題而使封裝產品失效。相較之下,在本發明的一些實施例中,所形成之尖晶石相MAl2 O4 與半導體晶片(例如:矽晶片)之間的鍵結力較強,因此即使半導體晶片上的接合墊因尺寸小而於打線接合製程中被消耗殆盡,也不會發生焊點脫落之問題。On the other hand, as the size of the bonding pads on the semiconductor chip continues to shrink, after the wire bonding process is performed using traditional bonding wires, the small-sized bonding pads may be completely converted into the traditional intermetallic phase. Because the bonding force between the traditional intermetallic phase and the semiconductor chip (for example: silicon chip) is very low, it is prone to the problem of solder joints falling off and the packaged product failure. In contrast, in some embodiments of the present invention, the bonding force between the formed spinel phase MAl 2 O 4 and the semiconductor wafer (e.g., silicon wafer) is stronger, so even if the bonding on the semiconductor wafer Due to its small size, the pad is consumed during the wire bonding process, and there is no problem of solder joints falling off.
第1圖繪示出本發明一些實施例之電子封裝結構10的部分剖面圖。如第1圖所示,在一些實施例中,電子封裝結構10包括半導體晶片100(例如:矽晶片)以及接合結構102。FIG. 1 shows a partial cross-sectional view of an
在一些實施例中,接合結構102可連接半導體晶片100與電子封裝結構10之另一半導體晶片(未繪示於圖中)。在一些實施例中,接合結構102可連接半導體晶片100與電子封裝結構10之基板(未繪示於圖中)。舉例而言,上述基板可包括印刷電路板、其他適當之基板或上述之組合。In some embodiments, the
在一些實施例中,如第1圖所示,接合結構102包括界面層104、球焊點部分106(ball bonding portion)及/或線材部分(wire portion)108。In some embodiments, as shown in FIG. 1, the
在一些實施例中,界面層104包括界面結構,上述界面結構包括一或多種尖晶石相(spinel phase)MAl2
O4
。舉例而言,元素M可為Ce、Hf、La、Lu、Ta、Ti、Zn或Nb。在一些實施例中,可使用球型接合製程(ball bonding process)形成界面層104以及球焊點部分106。In some embodiments, the
在一些實施例中,可使用接合線進行打線接合製程以形成接合結構102之界面層104、球焊點部分106及線材部分108。在一些實施例中,於形成接合結構102的打線接合製程中,可經由火花放電(electronic flame-off, EFO)於上述接合線的末端形成熔融球體(free air ball,FAB),然後使上述熔融球體與半導體晶片100上的接合墊進行界面反應而形成界面層104。舉例而言,可使用熱壓接合、超音波接合、熱音波接合、其他適當之方式或上述之組合使上述熔融球體與半導體晶片100上的接合墊進行界面反應而形成界面層104。舉例而言,上述半導體晶片100上的接合墊可為單層結構(例如:鋁層或鋁矽層)或多層結構(例如:鋁層/鈦層/鋁層、鋁矽層/鈦層/鋁矽層)。在一些實施例中,上述半導體晶片100上的接合墊的表面上可形成有氧化物(例如:氧化鋁)。In some embodiments, a bonding wire may be used for a wire bonding process to form the
在一些實施例中,於形成接合結構102的打線接合製程中,在形成界面層104與球焊點部分106之後,可經由適當的路徑將上述接合線引導至電子封裝結構10之另一接合墊(例如:電子封裝結構10之另一半導體晶片上的接合墊、電子封裝結構10之基板上的接合墊),並使上述接合線與上述電子封裝結構10之另一接合墊進行接合(例如:楔型接合(wedge bonding))。在一些實施例中,上述接合線沿著上述路徑形成接合結構102的線材部分108。In some embodiments, in the wire bonding process for forming the
在一些實施例中,為了使界面層104之界面結構包括一或多種尖晶石相MAl2
O4
(例如:CeAl2
O4
、HfAl2
O4
、LaAl2
O4
、LuAl2
O4
、TaAl2
O4
、TiAl2
O4
、Zn Al2
O4
或NbAl2
O4
),於形成接合結構102的打線接合製程中所使用之接合線係包括一或多種元素M(例如:Ce、Hf、La、Lu、Ta、Ti、Zn或Nb)。因此,在此些實施例中,上述包括一或多種元素M的接合線於可於打線接合製程中與半導體晶片100上的接合墊進行界面反應而形成包括一或多種尖晶石相MAl2
O4
之界面層104之界面結構。In some embodiments, in order to make the interface structure of the
在一些實施例中,於形成接合結構102的打線接合製程中,上述尖晶石相MAl2
O4
可抑制接合線中的銀、銅、金、鋁或上述之組合經由擴散之方式與半導體晶片100上之接合墊發生反應,因此可避免或減少不利於可靠度之介金屬相形成於界面層104中。In some embodiments, during the wire bonding process for forming the
在一些實施例中,於形成接合結構102的打線接合製程中,接合線所包括的元素M對氧具有高親和力,因此可與半導體晶片100上之接合墊之表面上的氧化物反應而形成尖晶石相MAl2
O4
。In some embodiments, during the wire bonding process for forming the
在一些實施例中,如第1圖所示,在半導體晶片100上之接合墊較薄的情況下,上述接合墊可與接合線反應而完全轉化成界面層104。在一些實施例中,界面層104直接接觸半導體晶片100。在一些實施例中,界面層104之尖晶石相MAl2
O4
直接接觸半導體晶片100。相較於傳統的介金屬相,本發明實施例之界面層104之尖晶石相MAl2
O4
與半導體晶片100(例如:矽晶片)之間的鍵結力較高,因此即使半導體晶片100上之接合墊在打線接合製程中被完全消耗掉,界面層104從半導體晶片100脫落的情形仍不容易發生。舉例而言,界面層104的厚度可為0.1微米至4微米。In some embodiments, as shown in FIG. 1, when the bonding pads on the
在一些實施例中,界面層104之界面結構亦可包括一或多種含有元素M的反尖晶石相Al(MAl)2
O4
。在一些實施例中,界面層104之界面結構亦可包括一或多種含有元素M的氧化物(例如:MO)。在一些實施例中,界面層104之界面結構之含有元素M的氧化物摻雜於尖晶石相MAl2
O4
及/或反尖晶石相Al(MAl)2
O4
中。In some embodiments, the interface structure of the
舉例而言,可經由能量散射光譜儀(Energy Dispersive Spectrometer,EDS)、電子微探儀(Electron Probe X-ray MicroAnalyzer,EPMA)、穿透式電子顯微鏡之繞射(Transmission electron microscopy diffraction)、其他適當之方式或上述之組合來確認尖晶石相MAl2 O4 、反尖晶石相Al(MAl)2 O4 及/或含有元素M之氧化物之形成。For example, it can be achieved by Energy Dispersive Spectrometer (EDS), Electron Probe X-ray MicroAnalyzer (EPMA), Transmission electron microscopy diffraction (Transmission electron microscopy diffraction), and other appropriate Method or a combination of the above to confirm the formation of spinel phase MAl 2 O 4 , inverse spinel phase Al(MAl) 2 O 4 and/or oxide containing element M.
在一些實施例中,由於接合線中的元素M(例如: Ce、Hf、La、Lu、Ta、Ti、Zn或Nb)具有較高的表面偏析及界面偏析效應,因此接合線僅需包括低含量的元素M(例如:接合線中一或多種元素M的總含量小於等於10000 ppm且大於2 ppm),即可與半導體晶片100上之接合墊反應形成所欲之尖晶石相MAl2
O4
。在一些實施例中,由於接合線之一或多種元素M的總含量較低,因此接合結構102具有較佳的導電性與導熱性。在一些實施例中,接合線中一或多種元素M的總含量小於等於1000 ppm(例如:小於等於1000 ppm且大於2 ppm),而可使接合結構102具有較佳之效能。In some embodiments, since the element M in the bonding wire (for example: Ce, Hf, La, Lu, Ta, Ti, Zn or Nb) has high surface segregation and interface segregation effects, the bonding wire only needs to include low The content of element M (for example: the total content of one or more elements M in the bonding wire is less than or equal to 10000 ppm and greater than 2 ppm), it can react with the bonding pad on the
第2圖繪示出本發明一些實施例之電子封裝結構20的部分剖面圖。電子封裝結構20與電子封裝結構10之間的一個差異在於電子封裝結構20之半導體晶片100與界面層104之間殘留有接合墊101。換句話說,在一些實施例中,電子封裝結構20之接合結構102包括位於半導體晶片100與界面層104之間之接合墊101。在一些實施例中,接合墊101包括鋁。FIG. 2 illustrates a partial cross-sectional view of the
舉例而言,半導體晶片100上之接合墊101可具有較大之厚度,因此於形成接合結構102的打線接合製程後,仍有部分之接合墊101未被反應成界面層104而殘留於半導體晶片100之上。For example, the
第3圖繪示出本發明一些實施例之電子封裝結構30的部分剖面圖。電子封裝結構30與電子封裝結構10之間的一個差異在於電子封裝結構30的接合結構302為柱形凸塊(stud bump)。在一些實施例中,接合結構302包括球焊點部分306以及位於半導體晶片300與球焊點部分306之間的界面層304。在一些實施例中,接合結構302不包括如第1圖所示之線材部分108。FIG. 3 is a partial cross-sectional view of the
舉例而言,界面層304之材料與形成方法可相同或類似於前述實施例之界面層104,球焊點部分306之材料與形成方法可相同或類似於前述實施例之球焊點部分106,為了簡明起見,於此將不再詳細說明。在一些實施例中,界面層304包括界面結構,上述界面結構包括一或多種尖晶石相(spinel phase)MAl2
O4
。舉例而言,元素M可為Ce、Hf、La、Lu、Ta、Ti、Zn或Nb。For example, the material and forming method of the
在一些實施例中,可使用相同或類似於前述用於形成界面層104與球焊點部分106之打線接合製程形成界面層304與球焊點部分306,接著使接合線與球焊點部分306分離而形成接合結構302。In some embodiments, the same or similar wire bonding process used to form the
在一些實施例中,接合結構302可在覆晶接合(flip chip bonding)製程中被用來將半導體晶片300接合至其他半導體晶片(未繪示於圖中)或接合至電子封裝結構之基板(未繪示於圖中)。In some embodiments, the
在一些實施例中,界面層304之界面結構亦包括一或多種前述之尖晶石相MAl2
O4
(例如:CeAl2
O4
、HfAl2
O4
、LaAl2
O4
、LuAl2
O4
、TaAl2
O4
、TiAl2
O4
、Zn Al2
O4
或NbAl2
O4
),因此接合結構302之界面層304亦可具有相同或類似於前述接合結構102之界面層104之優點。In some embodiments, the interface structure of the
在一些實施例中,界面層304之界面結構亦可包括一或多種含有元素M的反尖晶石相Al(MAl)2
O4
。在一些實施例中,界面層304之界面結構亦可包括一或多種含有元素M的氧化物(例如:MO)。在一些實施例中,界面層304之界面結構之含有元素M的氧化物摻雜於尖晶石相MAl2
O4
及/或反尖晶石相Al(MAl)2
O4
中。In some embodiments, the interface structure of the
第4圖繪示出本發明一些實施例之電子封裝結構40的部分剖面圖。電子封裝結構40與電子封裝結構30的其中一個差異在於電子封裝結構40之半導體晶片300與接合結構302之界面層304之間殘留有接合墊301。舉例而言,接合墊301之材料與形成可相同或類似於前述實施例之接合墊101。FIG. 4 is a partial cross-sectional view of the
第5圖繪示出本發明一些實施例之接合線50。接合線50可被用來形成前述實施例之接合結構102與接合結構302。舉例而言,可使用接合線50進行打線接合製程形成接合結構102與接合結構302。Figure 5 illustrates the
如第5圖所示,在一些實施例中,接合線50係包括金屬材料50’。在一些實施例中,金屬材料50’為接合線50的主體。As shown in Figure 5, in some embodiments, the
在一些實施例中,金屬材料50’包括純銀、純銅、純金、純鋁、銀合金、銅合金、金合金、鋁合金或上述之組合。在一些實施例中,金屬材料50’包括鋁矽合金。In some embodiments, the
在一些實施例中,為了使接合線50可被用來形成前述實施例之含有一或多種尖晶石相MAl2
O4
(例如:CeAl2
O4
、HfAl2
O4
、LaAl2
O4
、LuAl2
O4
、TaAl2
O4
、TiAl2
O4
、Zn Al2
O4
或NbAl2
O4
)的接合結構(例如:接合結構102、302),接合線50需包括一或多種元素M(例如:Ce、Hf、La、Lu、Ta、Ti、Zn或Nb)。舉例而言,一或多種元素M可分布於金屬材料50’中。In some embodiments, in order to enable the
當接合線50所包括之一或多種元素M(例如:Ce、Hf、La、Lu、Ta、Ti、Zn或Nb)的總含量太大時,可能會使接合線50的電阻率增加而不利於電子封裝結構的效能。當接合線50所包括之一或多種元素M的總含量太小時,可能無法形成充足之尖晶石相MAl2
O4
。在一些實施例中,接合線50所包括之一或多種元素M的總含量大於2 ppm且小於等於10000 ppm。在一些實施例中,接合線50所包括之一或多種元素M的總含量小於等於1000 ppm(例如:小於等於1000 ppm且大於2 ppm),而可使所形成之接合結構具有較佳之效能。When the total content of one or more elements M (for example: Ce, Hf, La, Lu, Ta, Ti, Zn, or Nb) included in the
在一些實施例中,使用接合線50進行打線接合製程形成前述實施例之接合結構102。在此些實施例中,接合結構102之線材部分108係由未與接合墊反應的接合線50所形成。在一些實施例中,類似於接合線50,接合結構102之線材部分108亦包括一或多種元素M(例如:Ce、Hf、La、Lu、Ta、Ti、Zn或Nb),且接合結構102之線材部分108所包括之一或多種元素M的總含量亦大於2 ppm且小於等於10000 ppm。在一些實施例中,類似於接合線50,接合結構102之線材部分108所包括之一或多種元素M的總含量小於等於1000 ppm(例如:小於等於1000 ppm且大於2 ppm)而具有較佳的效能。In some embodiments, the
舉例而言,可使用感應耦合電漿(ICP)分析技術量測接合線50或線材部分108所包括之一或多種元素M的總含量。For example, inductively coupled plasma (ICP) analysis technology can be used to measure the total content of one or more elements M included in the
綜合上述,本發明實施例之接合結構之界面結構(例如:界面層104之界面結構、界面層304之界面結構)包括一或多種含有元素M的尖晶石相MAl2
O4
,上述尖晶石相MAl2
O4
具有良好的機械性質、較高之熔點、優異的耐化學侵蝕性與優異的耐熱衝擊性,此外其亦可抑制或減少性質不佳之傳統介金屬相之成長,因此可提高電子封裝結構(例如:電子封裝結構10、20、30、40)之可靠度。In summary, the interface structure of the bonding structure of the embodiment of the present invention (for example: the interface structure of the
前述內文概述了許多實施例的特徵部件,使本技術領域中具有通常知識者可以從各個方面更佳地了解本發明實施例。本技術領域中具有通常知識者應可理解,且可輕易地以本發明實施例為基礎來設計或修飾其他製程及結構,並以此達到相同的目的及/或達到與在此介紹的實施例相同之優點。本技術領域中具有通常知識者也應了解這些相等的結構並未背離本發明實施例的發明精神與範圍。在不背離本發明實施例的發明精神與範圍之前提下,可對本發明實施例進行各種改變、置換或修改,因此本發明之保護範圍當視後附之申請專利範圍所界定者為準。另外,雖然本發明已以數個較佳實施例揭露如上,然其並非用以限定本發明,且並非所有優點都已於此詳加說明。The foregoing text outlines the characteristic components of many embodiments, so that those skilled in the art can better understand the embodiments of the present invention from various aspects. Those skilled in the art should understand, and can easily design or modify other processes and structures based on the embodiments of the present invention, so as to achieve the same purpose and/or achieve the same purpose as the embodiments described herein. The same advantages. Those skilled in the art should also understand that these equivalent structures do not depart from the inventive spirit and scope of the embodiments of the present invention. Without departing from the spirit and scope of the embodiments of the present invention, various changes, substitutions or modifications can be made to the embodiments of the present invention. Therefore, the scope of protection of the present invention shall be subject to those defined by the appended patent scope. In addition, although the present invention has been disclosed as above in several preferred embodiments, they are not intended to limit the present invention, and not all advantages have been described in detail here.
本揭露之每一請求項可為個別的實施例,且本揭露之範圍包括本揭露之每一請求項及每一實施例彼此之結合。Each claim of the present disclosure may be a separate embodiment, and the scope of the present disclosure includes each claim of the present disclosure and the combination of each embodiment with each other.
10、20、30、40:電子封裝結構50:接合線100、300:半導體晶片101、301:接合墊102、302:接合結構104、304:界面層106、306:球焊點部分108:線材部分10, 20, 30, 40: Electronic package structure 50:
以下將配合所附圖式詳述本發明實施例。應注意的是,各種特徵部件並未按照比例繪製且僅用以說明例示。事實上,元件的尺寸可能經放大或縮小,以清楚地表現出本發明實施例的技術特徵。 第1圖繪示出本發明實施例之電子封裝結構10的部分剖面圖。 第2圖繪示出本發明實施例之電子封裝結構20的部分剖面圖。 第3圖繪示出本發明實施例之電子封裝結構30的部分剖面圖。 第4圖繪示出本發明實施例之電子封裝結構40的部分剖面圖。 第5圖繪示出本發明實施例之接合線50的部分立體圖。The embodiments of the present invention will be described in detail below in conjunction with the drawings. It should be noted that the various characteristic components are not drawn to scale and are only used for illustrative purposes. In fact, the size of the element may be enlarged or reduced to clearly show the technical features of the embodiment of the present invention. FIG. 1 shows a partial cross-sectional view of an
10:電子封裝結構 10: Electronic packaging structure
100:半導體晶片 100: semiconductor wafer
102:接合結構 102: Joint structure
104:界面層 104: Interface layer
106:球焊點部分 106: Ball solder joint part
108:線材部分 108: Wire part
Claims (11)
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GB2175009B (en) * | 1985-03-27 | 1990-02-07 | Mitsubishi Metal Corp | Wire for bonding a semiconductor device and process for producing the same |
US5202153A (en) * | 1991-08-23 | 1993-04-13 | E. I. Du Pont De Nemours And Company | Method for making thick film/solder joints |
US7214881B2 (en) * | 2004-04-01 | 2007-05-08 | Delphi Technologies, Inc. | High temperature electrical connection |
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