TW201940683A - Touch improver for floor - Google Patents

Abstract

Provided are: a touch improver for floors, with which a floor surface having a denatured oil, e.g., a thermally denatured oil, adherent thereto can be made to feel non-tacky, smooth, and dry to the touch through a simple treatment in which the touch improver is applied to the floor surface and dried; a treatment agent composition for floors; and a method for treating a floor surface. The treatment agent composition for floors comprises (A) an alkylglycoside-type surfactant (hereinafter, referred to as (A) component) and water and optionally contains (B) a surfactant (hereinafter, referred to as (B) component) which is not (A) component, the mass ratio of the content of (A) component to the total content of (A) component and (B) component, (A)/[(A)+(B)], exceeding 0.55. The treatment agent composition for floors has a pH at 30 DEG C of 4 or higher but lower than 9.

Description

Touch improver for floor

The present invention relates to a touch improver for a floor, a treatment composition for a floor, and a method for treating a floor surface.

In countries or regions where barefoot lives in most cases, the floor surface is cleaned with a mop moistened with a mop. Although this daily cleaning is sufficient to remove mild dirt such as sweat or dust, but the modified oil such as the oil splashing from the cooking or the sweat from the feet is deteriorated by heat or light or oxygen in the air if it is attached to the floor Surface, the floor surface will become sticky, and this type of stickiness cannot be removed only by wet rubbing with previous washing water. Therefore, in order to remove such stickiness, formal floor washing is required.

Japanese Patent Laid-Open No. 2015-007220 discloses a hard surface cleaner composition for floors and the like, which contains a specific alkyl glycoside, a specific nonionic surfactant, an anionic surfactant, and a fragrance. After washing, the quick-drying property and playing performance are excellent. Japanese Patent Laid-Open No. 2000-297296 discloses a cleaning agent which contains an alkyl glycoside, a specific fungicide, and a fatty acid salt, and can simultaneously clean and clean the surfaces of plastics, tiles, and wood. Sterilization and excellent simplicity. In Japanese Patent Publication No. 2007-513215, a detergent composition is disclosed, which contains an alkyl glycoside and a specific polymer as a polishing component, and has a polishing effect on the surface of a wooden floor. Japanese Patent Laid-Open No. 2004-143251 discloses a resin wax film peeling agent composition containing an alkyl glycoside, an amine, and a water-soluble solvent.

However, the compositions disclosed in Japanese Patent Laid-Open Publication No. 2015-007220 and Japanese Patent Laid-Open Publication No. 2000-297296 are not for the purpose of cleaning modified oils, even if the moisturizing water containing the composition is used for mop cleaning. Wiping the floor surface can not improve the touch of the floor surface with denatured oil. In addition, the composition disclosed in Japanese Patent Publication No. 2007-513215 is a composition that uses a specific polymer as a polishing component to enhance the gloss of a wooden floor. It is not suggested that a floor treatment agent that does not contain such a component can only be borrowed. The daily wet rubbing treatment will improve the touch of the floor surface with denatured oil. The composition disclosed in Japanese Patent Laid-Open No. 2004-143251 is alkaline because it contains amines, and because it is a resin wax release agent, a rinsing step is required, so it cannot improve the feel of the floor surface to which denatured oil is attached. .

An object of the present invention is to provide a touch improver for a floor, a treatment composition for a floor, and a method for treating a floor surface. The touch improver for a floor is applied to a floor to which a modified oil such as a thermally modified oil is attached. The surface is simply coated and dried to improve the touch of the floor surface, making it non-sticky and dry. In the description of the present case, the modified oil means an oily component that is deteriorated by the action of heat, sunlight, and oxygen in the air. The thermally modified oil refers to an oil modified by heat and contains an oil component that is oxidized by heat.

The present invention relates to a touch improver for flooring comprising (A) an alkylglycoside-type surfactant.

The present invention also relates to a floor treatment composition containing (A) an alkyl glycoside surfactant [hereinafter, referred to as (A) component], and optionally (B) other than (A) component. Surfactant [hereinafter, referred to as (B) component], and water, the mass ratio of the content of (A) component to the total content of (A) component and (B) component (A) / [(A) + (B )] Exceeds 0.55, and the pH value of the floor treatment composition at 30 ° C. is 4 or more and less than 9.

The present invention also relates to a method for treating a floor surface, which comprises applying a composition containing (A) an alkyl glycoside surfactant at 5 ppm to 1,000 ppm, and water to the floor and drying it.

According to the present invention, there is provided a floor feel improver, a floor treatment composition, and a method for treating a floor surface. The floor feel improver is a floor surface to which a denatured oil such as a thermally modified oil is adhered. Only the simple treatment of coating and drying improves the touch of the floor surface, making it non-sticky and dry. Furthermore, according to the present invention, there is provided a method for treating a floor surface, which can improve the touch of the floor surface only by coating and drying the floor surface to which the denatured oil is attached, and making it non-sticky and dry. Therefore, cleaning can be completed without wet rubbing.

[Tactile improver for flooring]
This invention is a touch improvement agent for flooring containing (A) component.

Although the component (A) of the present invention can improve the feel of the floor surface and make it non-sticky and dry, although it cannot be fully explained, it is believed that the alkyl glycosides are compared with other nonionic surfactants. The crystals are easily precipitated, and the crystals of the alkyl glycosides deposited on the surface after drying can be left on the surface, so that a dry touch can be imparted.

From the viewpoint of improving the feel of the floor, the (A) component used in the present invention is preferably a straight chain or having a carbon number of 8 or more, more preferably 10 or more, and preferably 18 or less, and more preferably 16 or less. A branched alkyl group is preferably a linear alkyl group, and the average condensation degree of the sugar is preferably an alkyl glycoside of 1 or more and preferably 3 or less, more preferably 2 or less, and further preferably 1.5 or less. .

The component (A) is preferably a compound represented by the following general formula (A1).
R ^1a (OR ^2a ) _x G _y (A1)
[Wherein R ^1a represents a linear or branched alkyl group having 8 to 18 carbon atoms, R ^2a represents an alkylene group having 2 to 4 carbon atoms, and G represents a residue from a sugar having 5 or 6 carbon atoms , X represents a number whose average is 0 to 5 and y represents a number whose average is 1 to 3]

In the above general formula (A1), from the viewpoint of improving the feel of the floor, R ^{1a has} a carbon number of 8 or more, preferably 10 or more, and 18 or less, preferably 16 or less, and more preferably 14 or less. The linear or branched alkyl group is preferably a linear alkyl group. In addition, as the alkylene group represented by R ^2a , a carbon number of 2 is preferred from the viewpoint of improving the feel of the floor. In addition, the sugar-derived residue having a carbon number of 5 or 6 represented by G is determined by the sugars of monosaccharides or disaccharides used. As G, among monosaccharides, residues derived from glucose, galactose, xylose, mannose, lyxose, arabinose, fructose, or a mixture thereof may be mentioned. Among disaccharides or higher, maltose derived Residues of xyloose, isomaltose, cellobiose, gentiobiose, lactose, sucrose, aspergillose, sucrose, raffinose, gentiotriose, melezitose, or mixtures thereof . Among these, in terms of improving the feel of the floor and the availability and low cost of these, the preferred raw materials are glucose and fructose in monosaccharides, and maltose and sucrose in disaccharides and the like.

In addition, x in the general formula (A1) is an average addition mole number of OR ^2a , preferably 0 or more, and preferably 5 or less, more preferably 3 or less, and further preferably 1 or less. It is 0, and in order to improve crystallinity, it is 0. By the value of x, the water solubility and crystallinity of the component (A) can be adjusted. That is, the larger the value of x, the higher the water solubility of the component (A) and the lower the crystallinity.

In addition, when the average value of y in the general formula (A1) is greater than 1, that is, when the component (A) contains a sugar chain having a disaccharide or more as a hydrophilic group, a sugar chain bond may be included. The bonding method is any mixture of 1-2, 1-3, 1-4, 1-6 bonding or α-, β-pyranoside or furanoside bonding, and a combination of these bonding methods.

The average value of y in the general formula (A1) is 1 or more and 3 or less, preferably 2 or less, and more preferably 1.5 or less. The value of y (average degree of condensation of sugar) was measured by ¹ H-NMR. As a specific measurement method, refer to Japanese Patent Application Laid-Open No. 8-53696, page 6, column 10, column 26 to page 7, column 11, column 15.

If the touch-improving agent for flooring containing the component (A) of the present invention is dissolved in a solvent such as water and applied to a floor surface to which denatured oil is adhered and dried, the touch of the floor surface can be improved, and Sticky and dry.

[Floor treatment agent composition]
The present invention is a floor treatment agent composition containing: (A) component, arbitrary (B) component, and water; mass of (A) component content and total content of (A) component and (B) component The ratio (A) / [(A) + (B)] exceeds 0.55, and the pH value of the floor treatment composition at 30 ° C. is 4 or more and less than 9.

In the floor treatment composition of the present invention, it is necessary to limit the content of other components that inhibit the crystallization of the alkylglycoside (A) component, for example, the content of the (B) component as a surfactant other than the (A) component. The treatment agent composition for a floor of the present invention can suitably use the matters described above with respect to the touch-improving agent for a floor including the component (A) of the present invention. The component (A) in the floor treatment composition of the present invention is the same as the component (A) described in the floor texture improving agent of the present invention.

Regarding the floor treatment agent composition of the present invention, from the viewpoint of improving the feel of the floor, the component (A) preferably contains 0.01% by mass or more, more preferably 0.1% by mass or more, and even more preferably 1% by mass. Above, from the viewpoint that if the concentration of the component (A) is too high, the dry feeling of the floor tends to decrease, it is preferably 50% by mass or less, more preferably 15% by mass or less, and even more preferably 10%. Mass% or less, more preferably 5 mass% or less, still more preferably 2.5 mass% or less, and even more preferably 2 mass% or less.

The surface treating agent composition of the present invention may contain a surfactant other than the component (A) as the component (B), but from the viewpoint of improving the feel of the floor obtained from the component (A), (B) The content of ingredients is limited. In the floor treatment composition of the present invention, the mass ratio of the content of (A) component to the total content of (A) component and (B) component (A) / [(A) + (B)] From the viewpoint of improvement in touch, it is more than 0.55, preferably 0.6 or more, more preferably 0.65 or more, still more preferably 0.7 or more, still more preferably 0.8 or more, and 1 or less, and may also be 1. It is preferable that the processing agent composition for floors of this invention does not contain (B) component.

Since it is important to provide a bactericidal effect to the floor treatment agent composition as a demand of a living person, it is preferable to mix a bactericide in the floor treatment agent composition of the present invention. In order to impart a bactericidal effect, the floor treatment composition of the present invention preferably contains a cationic surfactant (hereinafter, referred to as (B1) component) as the component (B).

(B1) The component is not particularly limited as long as it can impart a bactericidal effect, and it may be a quaternary ammonium salt type cationic surfactant of a hydrochloride or a methyl or ethyl sulfate, which has one or two bonds An alkyl group having a carbon number of 8 or more and preferably 22 or less, more preferably 18 or less, and even more preferably 16 or less, and the remaining organic group bonded to the nitrogen atom is 1 or more carbon Short-chain alkyl or hydroxyalkyl group of 3 or less or at most 1 benzyl group.

(B1) The component is specifically preferably selected from the group consisting of a dialkyl group (carbon number of 1 alkyl group is 8 or more and 18 or less), a dimethyl ammonium salt, and a monoalkyl group (carbon number of 8 or more and 18 or less) trimethyl. One or more of an ammonium salt, an alkyl (carbon number of 8 to 18) dimethylbenzyl ammonium salt, and an ammonium salt of ammonium, and the salt is a hydrochloride or a methyl or ethyl sulfate. The (B1) component is more preferably an alkyl (carbon number: 12 or more and 16 or less) dimethylbenzyl ammonium salt from the viewpoints of bactericidal properties and touch of the floor.

When the floor treatment composition of the present invention contains (B1) component, the mass ratio of the content of (A) component to the total content of (A) component and (B1) component (A) / [(A) + (B1)] From the viewpoint of improving the feel of the floor, it is preferably more than 0.55, more preferably 0.6 or more, still more preferably 0.65 or more, and from the viewpoint of germicidal effect, it is preferably 0.9 or less, It is more preferably 0.8 or less, and still more preferably 0.7 or less. The content of the component (B1) is calculated based on the content converted when the counter ion of the cationic surfactant is a chloride ion.

Generally speaking, in order to clean the dirt existing on the floor, the floor treatment composition contains one selected from anionic surfactants and non-ionic surfactants other than the (A) component. More than one type of surfactant [hereinafter, also referred to as (B2) component]. However, in the floor treatment composition of the present invention, the crystallinity of the component (A) may be lowered. Therefore, it is preferable not to contain the component (B2).

When the floor treatment composition of the present invention contains the component (B2) for the purpose of cleaning and removing modified oil, the content of the component (A) and the total content of the components (A) and (B2) The mass ratio (A) / [(A) + (B2)] is preferably 0.7 or more, more preferably 0.8 or more, even more preferably 0.9 or more, and even more preferably 0.99 or more from the viewpoint of improving the feel of the floor. , And is preferably less than 1, can also be 1. When the component (B2) contains an anionic surfactant, the content of the anionic surfactant is calculated based on the content converted when the anionic surfactant is an acid type.

The floor treatment agent composition of this invention may also contain a fragrance | flavor as a (C) component from a viewpoint of taste. (C) A fragrance | flavor component may be used individually, and the fragrance | flavor composition containing a plurality of fragrance | flavor components in a specific ratio may be used. As a fragrance ingredient, "Chemistry of Perfume" (Akasaka Ryoichi, Industrial Chemistry Series of the Japanese Chemical Society, September 16, 1983) or "Synthetic Perfume Chemistry and Product Knowledge" (Into Fujimoto, Chemical Industry Daily) , Issued on March 6, 1996) or "Basics of Spices and Fragrances" (by Nakajima Kiyoshi, Industry Books (Stock), issued on June 21, 1995). The component (C) is preferably one excellent in the cleaning effect of dirt or the suppression effect of odors generated by bacteria.

As component (C), specifically, selected from the group consisting of a hydrocarbon-based perfume, an alcohol-based perfume, an ether-based perfume, an aldehyde-based perfume, a ketone-based perfume, an ester-based perfume, a lactone-based perfume, a cyclic ketone-based perfume, and a One or more kinds of nitrogen-based perfumes are preferably one or more kinds selected from hydrocarbon-based perfumes, alcohol-based perfumes, and aldehyde-based perfumes.

As the component (C), more specifically, as a preferred fragrance, it is preferably selected from the group consisting of tuna musk, oxetan-2-one, Jiale musk, hexyl salicylate, and α-hexylcinnamaldehyde. 1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-naphthylacetone, amyl salicylate, isocamphoryl cyclohexanol , Cyclohexyl salicylate, terpinolene, limonene, α-pentylcinnamaldehyde, benzyl salicylate, β-pinene, p-third butyl cyclohexyl acetate, or o-third butyl ring acetate Hexyl ester, isononyl acetate, methyl ionone-G, 1- (2-third butylhexyloxy) -2-butanol, allyl cyclohexyl propionate, 3,3,5 -Trimethylcyclohexylethyl ether, dimethyl benzyl hydrocarbon methyl ester, lyric aldehyde, γ-undecanolactone, β-ionone, terpineyl acetate, tetrahydro linalool, linal acetate , Allyl hexanoate, 3-methyl-5-phenylpentanol, dihydromyrcenol, phenethyl isobutyrate, tricyclodecenyl propionate, dimethyl benzyl hydrocarbon methyl ester , Geraniol, 1,8-eucalyptol, methyl β-naphthyl ketone, pinoresinol, borneol, linalool, guppen ester, methyl dihydrojasmonate, triacetate Decene ester, camphor, benzyl acetate, anisaldehyde, coumarin, the Japanese floral aldehyde, eucalyptus oil, and Brazil acid ethyl extension of one or more kinds of fragrances. Particularly preferred are fragrances with a logP (octanol / water partition coefficient) of greater than 1 for those fragrances, and more preferably greater than 2 for those fragrances.

In the present invention, it is preferable to contain a fragrance composition such as eucalyptus oil as the component (C) from the viewpoint of the cleaning effect of dirt or the suppressing effect of odor generated by bacteria.

With regard to the floor treatment agent composition of the present invention, from the standpoint of preference, the component (C) preferably contains 0.01% by mass or more, more preferably 0.05% by mass or more, and still more preferably 0.1% by mass or more, and From the viewpoint of the storage stability of the composition, it is preferably 1.5 mass% or less, more preferably 1 mass% or less, and still more preferably 0.8 mass% or less.

When the component (C) is used in the floor treatment composition of the present invention, the component (C) is insoluble in most cases. Therefore, when the component (C) is contained, the storage stability is considered. Need to pay attention. When the floor treatment composition of the present invention contains (C) component, the mass ratio of the content of (C) component to the total content of (A) component and (B) component (C) / [(A) + (B)] From the viewpoint of storage stability and taste, it is preferably 0.01 or more, more preferably 0.05 or more, still more preferably 0.1 or more, and preferably 1.0 or less, more preferably 0.8 or less, and more preferably It is preferably 0.4 or less.

The processing agent composition for floors of this invention may contain a solvent as a (D) component from a viewpoint of formulation stability of a composition. As the solvent, a water-soluble solvent having a solubility in water of 5 mass% or more at 20 ° C is preferred, and one or more solvents selected from alcohol-based solvents and glycol-based solvents having one or more hydroxyl groups are suitable. . Specific examples include ethers selected from the group consisting of ethanol, isopropanol, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, glycerol, isoamyl glycol, and ethylene glycol monoalkyl (4 to 8 carbon atoms) ethers. , Diethylene glycol monoalkyl (carbon number 4 to 8) ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monopropyl ether, propylene glycol monobutyl ether, dipropylene glycol alkyl (carbon number 1 to 4) ether One or more solvents of polyoxyethylene (an average addition mole number of ethylene oxide of 1 to 5) monophenyl ether and monoalkyl (carbon number of 3 to 8) glyceryl ether. In the floor treatment composition of the present invention, from the viewpoint of the storage stability of the composition, the (D) component is preferably polyoxyethylene (the average ethylene oxide addition mole number is 1 or more and 5 or less). Monophenyl ether, more preferably diethylene glycol monophenyl ether or phenoxyethanol. Since these solvents also have a bactericidal effect, anticorrosive effects are also expected.

Regarding the floor treatment composition of the present invention, from the viewpoint of the storage stability of the composition, the (D) component is preferably contained in an amount of 0.05% by mass or more, more preferably 0.1% by mass or more, and further preferably 0.5% by mass. % Or more, and preferably 10% by mass or less, more preferably 5% by mass or less, and even more preferably 2% by mass or less. Further, when the component (D) is a polyphenylene oxide (the average addition mole number of ethylene oxide is 1 or more and 5 or less) monophenyl ether, the floor treatment agent composition of the present invention is storage stability of the composition From the viewpoint of imparting antiseptic effect, the (D) component preferably contains 0.05% by mass or more, more preferably 0.1% by mass or more, still more preferably 0.5% by mass or more, and more preferably 10% by mass or less, more preferably The content is 5 mass% or less, and more preferably 2 mass% or less.

The floor treatment agent composition of the present invention may contain a germicidal agent (except (B1) component and (D) component) as the (E) component from the viewpoint of hygiene often required in washing operations. Here, the bactericidal agent of the present invention can be used in "The Science of Cosmetics, Pharmaceutical Preservatives, and Fungicides" by Takaichi Yoshimura, Hiroshi Takikawa, Fragrance Journal, April 10, 1990, p. 501 ~ Those listed on page 564. For example, it is selected from trichlorofloxacin, bis- (2-pyridylthio-1-oxide) zinc, 2,4,5,6-tetrachloroisophthalonitrile, trichlorosymmetric diphenylurea, 2- ( 4-thiocyanomethylthio) benzimidazole, polyhexamethylene biguanide hydrochloride, chlorhexidine glucuronide, 8-hydroxyquinoline, and polyionic acid. In addition, the triclosan itself described in Japanese Patent Laid-Open No. 11-189975 can be used, and specifically, dichlorohydroxydiphenyl ether and monochlorohydroxydiphenyl ether can be used.

Regarding the floor treatment agent composition of the present invention, from the viewpoint of sterilization, the (E) component preferably contains 0.001% by mass or more, more preferably 0.01% by mass or more, and still more preferably 0.1% by mass or more, and It is preferably 1% by mass or less, more preferably 0.5% by mass or less, and still more preferably 0.1% by mass or less. However, (B1) component and (D) component are excluded from the content of (E) component.

The floor treatment agent composition of the present invention is a liquid composition containing water. Any of the above-mentioned components can be dissolved, dispersed, and emulsified in water. As the water, ion-exchanged water or distilled water from which metal components have been removed, or hypochlorous acid sterilized water obtained by dissolving hypochlorous acid to a level of 0.5 ppm to 10 ppm can be used. The remainder of the water-based composition is contained in an amount of 100% by mass as a whole.

In the floor treatment composition of the present invention, the pH value at 30 ° C is 4 or more, preferably 5 or more, and less than 9, preferably 8 or less, from the viewpoint of improving the feel of the floor. It is preferably 7 or less, and more preferably 6.5 or less. As the pH adjusting agent adjusted to such a pH value, an inorganic acid selected from sulfuric acid, hydrochloric acid, and phosphoric acid is used, and selected from citric acid, malic acid, maleic acid, fumaric acid, succinic acid, lactic acid, and glycolic acid. The organic acid is carried out with inorganic alkali agents such as sodium hydroxide, potassium hydroxide, magnesium hydroxide, sodium carbonate, and potassium carbonate. In the present invention, it is preferable to provide the detergent composition with buffering capacity in terms of the sustainability of the cleaning power, and it is suitable to use the above-mentioned organic acid, preferably citric acid and an inorganic alkali agent in combination. The organic acid may also be formulated into the detergent composition in the form of a sodium salt or a potassium salt. The content of the organic acid in the floor treatment composition of the present invention is preferably 0.001% by mass or more in terms of the form of the acid. It is more preferably 0.01% by mass or more, more preferably 1% by mass or less, still more preferably 0.5% by mass or less, and still more preferably 0.1% by mass or less. The content of the inorganic alkali agent in the floor treatment composition of the present invention is preferably 0.001% by mass or more, more preferably 0.005% by mass or more, and preferably 0.1% by mass or less, and more preferably 0.05% by mass or less.

The floor treatment composition of the present invention can improve the touch of a floor surface to which a denatured oil such as a thermally modified oil is adhered, even if it does not contain polishing agents such as wax, resin wax, and silicon, making it non-sticky and dry. That is, in the floor treatment composition of the present invention, the ratio of the total content of (A) component and (B) component to (D) component as an optional component to all components except water is the feel of the floor. From the viewpoint of improvement, it is preferably 90% by mass or more, more preferably 93% by mass or more, still more preferably 95% by mass or more, still more preferably 99.5% by mass or less, still more preferably 99% by mass or less, and more preferably It is preferably 98.5 mass% or less. In the floor treatment composition of the present invention, the ratio of the content of the component (A) to all components except water may be from 20% by mass or more to 30% from the viewpoint of improving the feel of the floor. Mass% or more, further 40 mass% or more, further 50 mass% or more, and 95 mass% or less, further 80 mass% or less, further 70 mass% or less, and further 60 mass% or less are selected.

The floor treating agent composition of the present invention is suitably used as a wet wiping composition or a wet wiping article for a floor. That is, it is suitable for gentle washing of floors in living areas such as living rooms, rooms, kitchens, bathrooms, and toilets. Examples of the floor include a stone floor, a parquet floor, a tile, a linoleum, and a plastic floor, and are preferably suitable for a tile floor. The floor treatment agent composition of the present invention can improve the touch of the floor surface by simply coating and drying the floor surface to which the denatured oil such as thermally modified oil is adhered, so that it is not sticky and dry. Moreover, the effect of the present invention can be obtained even if wet wiping (secondary wiping) is not performed separately, so there is no need to perform wet wiping.

In the case where the floor treatment agent composition of the present invention is used on a floor with less dirt, it is preferably a treatment obtained by diluting it with water to 50 times or more, 80 times or more, 200 times or less, and 150 times or less. Apply as a liquid on the floor.

The floor treatment composition of the present invention or a treatment liquid (hereinafter, sometimes simply referred to as a treatment liquid) after diluting it as described above may be impregnated into a substrate and used as a cleaning article. The cleaning article impregnated with the floor treatment composition or the treatment liquid of the present invention in the substrate is preferred from the viewpoint of the operability of the cleaning operation.

As a substrate for a cleaning article impregnated with a floor treatment composition or a treatment liquid, the following substrate is used, which has flexibility and can be impregnated with the floor treatment composition or the treatment liquid, and has sufficient strength when used. , And no debris. It is particularly preferable to use a substrate capable of being impregnated with the following amount of a floor treatment composition or a treatment liquid under no load.

Examples of such a substrate include a fibrous structure including a fibrous material, such as various papers, nonwoven fabrics, woven fabrics, or knitted fabrics. Examples of the fibrous material constituting the fiber structure include cellulose-based fibers, modified cellulose-based fibers, synthetic fibers, and a mixture of two or more of these.

Moreover, a porous structure (for example, a sponge-like structure) obtained by dispersing air bubbles in a resin can also be used as the substrate.

In addition, the cleaning method for wiping the floor surface with a cleaning article impregnated with the floor treatment composition or the treatment liquid of the present invention is suitable for gentle cleaning of the floor surface from the viewpoint of the workability of the cleaning operation. The cleaning article impregnated with the floor treatment composition or the treatment liquid may be one in which the floor treatment composition or the treatment liquid is impregnated into the substrate in advance, or the floor treatment agent is sprayed or the like immediately before use. Either the composition or the treatment liquid is impregnated into a dried substrate. In addition, the surface to be cleaned may be cleaned with the sprayed cleaning article. The cleaning article impregnated with the floor treatment composition or the treatment liquid can be mounted on a mop-shaped cleaning tool, or it can be directly grasped by hand for cleaning.

When impregnated with the floor treatment agent composition or the treatment liquid in advance, the impregnation rate of the floor treatment agent composition or the treatment liquid is, from the viewpoint of the cleanability, relative to the mass of the substrate [that is, the non-impregnated state (dry state). The quality basis of the substrate] is preferably 100% by mass or more, more preferably 150% by mass or more, more preferably 1000% by mass or less, more preferably 400% by mass or less, and further preferably 350% by mass or less. When the impregnation rate is 100% by mass or more, sufficient cleaning performance against stains or dust can be obtained. If it is 1000% by mass or less, the release amount of the detergent composition on the surface to be cleaned becomes appropriate, dirt or dust does not remain on the surface to be cleaned, and it is possible to prevent the cleaning surface including various materials including wood materials from being affected. For use. In terms of further improving the cleaning performance, in the case where the substrate is a sheet, the base agent before the impregnation of the treating agent composition or the treating liquid for the floor is fixed and the holding ability of the treating agent required for the cleaning of a fixed area. From the viewpoint of material operability or cost, it is preferably 40 g / m ² or more, more preferably 50 g / m ² or more, and more preferably 200 g / m ² or less, and more preferably 150 g / m ² the following.

When a cleaning article impregnated with the floor treatment composition or the treatment liquid is used, the floor treatment composition or the treatment liquid of the present invention may be sprayed onto the object to be cleaned or the cleaning article. By using this method, a wider area can be cleaned.

[Handling method of floor surface]
The present invention is a method for treating a floor surface by applying a composition containing (A) component in an amount of 5 ppm to 1,000 ppm and water, and drying the floor. Furthermore, this invention is a processing method of the floor surface which apply | coats the composition containing (A) component 5 ppm or more and 1000 ppm or less, and water to a floor, and does not perform wet rubbing (secondary wiping), and makes it dry.

The method for treating the floor surface of the present invention is only required to make the content of the component (A) be 5 ppm or more, preferably 50 ppm or more, more preferably 100 ppm or more and 1000 ppm or less, preferably 500 ppm or less, more The composition prepared in a manner of preferably 200 ppm or less may be applied to the floor surface. The composition is preferably prepared by diluting the floor treatment composition of the present invention with water.

In the method for treating a floor surface of the present invention, a composition containing (A) component in an amount of 5 ppm to 1,000 ppm and water can also be prepared using the floor treatment composition of the present invention, (A) component and its comparison The preferred aspect and the optional components are the same as those described above with respect to the floor treatment composition of the present invention. The method for treating the floor surface of the present invention may suitably apply the matters described above with respect to the floor treatment composition of the present invention.

Regarding the embodiment described above, the present invention further discloses the following touch improving agent for flooring, a treating agent composition for flooring, and a method for treating a floor surface.

＜ 1 ＞
A touch-improving agent for flooring comprising (A) an alkylglycoside-type surfactant [hereinafter, referred to as (A) component].

＜ 2 ＞
The feel improving agent for flooring as described in the above <1>, wherein the (A) component is preferably a straight chain or a carbon number of 8 or more, more preferably 10 or more, and preferably 18 or less, and more preferably 16 or less. A branched alkyl group is preferably a linear alkyl group, and the average condensation degree of the sugar is preferably an alkyl glycoside of 1 or more and preferably 3 or less, more preferably 2 or less, and further preferably 1.5 or less. .

＜ 3 ＞
The touch improvement agent for floors as described in said <1> or <2> whose (A) component is a compound represented by the following general formula (A1).
R ^1a (OR ^2a ) _x G _y (A1)
[Wherein R ^1a represents a straight-chain or branched alkyl group having a carbon number of 8 or more, preferably 10 or more, and 18 or less, preferably 16 or less, and more preferably 14 or less, and is preferably a straight chain R ^2a represents an alkylene group having 2 to 4 carbon atoms, preferably an alkylene group having 2 carbon atoms, and G represents a residue from a sugar group having 5 or 6 carbon atoms, preferably a residue from glucose. Basis, x represents a number whose average value is 0 or more and preferably 5 or less, more preferably 3 or less, and further preferably 1 or less, and y represents an average value of 1 or more, and 3 or less, preferably 2 Below, more preferably below 1.5]

＜ 4 ＞
A floor treatment agent composition comprising (A) an alkyl glycoside-type surfactant [hereinafter, referred to as (A) component], and optionally (B) a surfactant other than (A) component [hereinafter, Called (B) component], and water, the mass ratio of the content of (A) component to the total content of (A) component and (B) component (A) / [(A) + (B)] exceeds 0.55, and The pH of this floor treatment composition at 30 ° C is 4 or more and less than 9.

＜ 5 ＞
The floor treatment agent composition according to the above <4>, in which the (A) component-based carbon number is preferably a straight chain or 8 or more, more preferably 10 or more, and preferably 18 or less, more preferably 16 or less A branched alkyl group is preferably a linear alkyl group, and the average condensation degree of the sugar is preferably an alkyl glycoside of 1 or more and preferably 3 or less, more preferably 2 or less, and further preferably 1.5 or less. .

＜ 6 ＞
The floor treatment agent composition as described in said <4> or <5> whose (A) component is a compound represented by the following general formula (A1).
R ^1a (OR ^2a ) _x G _y (A1)
[Wherein R ^1a represents a straight-chain or branched alkyl group having a carbon number of 8 or more, preferably 10 or more, and 18 or less, preferably 16 or less, and more preferably 14 or less, and is preferably a straight chain R ^2a represents an alkylene group having 2 to 4 carbon atoms, preferably an alkylene group having 2 carbon atoms, and G represents a residue from a sugar group having 5 or 6 carbon atoms, preferably a residue from glucose. Base, x represents a number whose average value is 0 or more and preferably 5 or less, more preferably 3 or less, and further preferably 1 or less, and y represents an average value of 1 or more and 3 or less, preferably 2 or less , More preferably 1.5 or less]

＜ 7 ＞
The floor treatment composition according to any one of the above <4> to <6>, the content of which is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, and even more preferably 1% by mass or more, It is preferably 50% by mass or less, more preferably 15% by mass or less, still more preferably 10% by mass or less, still more preferably 5% by mass or less, still more preferably 2.5% by mass or less, and even more preferably 2% by mass. (A) component of% or less.

＜ 8 ＞
The floor treatment agent composition according to any one of the above <4> to <7>, wherein the mass ratio (A) / (((A) component to the total content of (A) component and (B) component) A) + (B)] is preferably 0.6 or more, more preferably 0.65 or more, still more preferably 0.7 or more, and still more preferably 0.8 or more.

＜ 9 ＞
The floor treatment agent composition according to any one of the above <4> to <7>, wherein the mass ratio (A) / (((A) component to the total content of (A) component and (B) component) A) + (B)] is 1.

＜ 10 ＞
The floor treatment composition according to any one of the above <4> to <9>, wherein the component (B) contains a cationic surfactant [hereinafter, also referred to as (B1) component].

＜ 11 ＞
The floor treatment composition according to the above <10>, in which the component (B1) has one or two carbon atoms bonded to a nitrogen atom, preferably 8 or more and 22 or less, more preferably Alkyl group of 18 or less, and more preferably 16 or less, and the remaining organic group bonded to the nitrogen atom is a short-chain alkyl group or hydroxyalkyl group having 1 to 3 carbon atoms or a quaternary ammonium salt of at most 1 benzyl group Type cationic surfactant.

＜ 12 ＞
The floor treatment composition according to the above <10> or <11>, wherein the component (B1) is a dimethylammonium salt selected from a dialkyl group (the carbon number of one alkyl group is 8 or more and 18 or less), One or more of the monoalkyl (carbon number 8 to 18) trimethylammonium salt, alkyl (carbon number 8 to 18) dimethylbenzylammonium salt, and benzyl ammonium salt Preferred is an alkyl group (carbon number 12 to 16) dimethylbenzyl ammonium salt.

＜ 13 ＞
The floor treatment composition according to any one of the above <10> to <12>, wherein the mass ratio (A) / (((A) component to the total content of the (A) component and (B1) component) A) + (B1)] is preferably more than 0.55, more preferably 0.6 or more, still more preferably 0.65 or more, and more preferably 0.9 or less, more preferably 0.8 or less, and still more preferably 0.7 or less.

＜ 14 ＞
The floor treatment composition according to any one of the above <10> to <13>, wherein the content of (A) component, (A) component, and (B2) are selected from anionic surfactants and (A) The mass ratio (A) / [(A) + (B2)] of the total content of one or more surfactants [hereinafter, referred to as (B2) component] among non-ionic surfactants other than ingredients is preferably 0.7 Above, more preferably 0.8 or more, still more preferably 0.9 or more, even more preferably 0.99 or more, and preferably less than 1.

<15>
The floor treatment composition according to any one of the above <10> to <13>, wherein the content of (A) component, (A) component, and (B2) are selected from anionic surfactants and (A) The mass ratio (A) / [(A) + (B2)] of the total content of one or more kinds of non-ionic surfactants other than the ingredients [hereinafter, referred to as (B2) component] is 1.

<16>
The floor treatment agent composition as described in any one of said <4> to <15> which further contains a fragrance | flavor as (C) component.

＜ 17 ＞
The floor treatment composition according to the above <16>, the content thereof is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, still more preferably 0.1% by mass or more, and preferably 1.5% by mass or less. (C) component is more preferably 1% by mass or less, and still more preferably 0.8% by mass or less.

<18>
The floor treatment composition according to the above <16> or <17>, wherein the mass ratio of the content of the component (C) to the total content of the components (A) and (B) is (C) / [(A) + (B)] is preferably 0.01 or more, more preferably 0.05 or more, still more preferably 0.1 or more, and more preferably 1.0 or less, more preferably 0.8 or less, and even more preferably 0.4 or less.

＜ 19 ＞
The processing agent composition for floors as described in any one of said <4> to <18> which further contains a solvent as (D) component.

＜ 20 ＞
The floor treatment composition according to the above <19>, wherein the component (D) is a water-soluble solvent having a solubility in water at 20 ° C. of 5% by mass or more.

＜ 21 ＞
The floor treatment composition according to the above <19> or <20>, wherein the component (D) is selected from the group consisting of ethanol, isopropanol, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, glycerin, and isopropyl alcohol. Pentylene glycol, ethylene glycol monoalkyl (carbon number 4 to 8) ether, diethylene glycol monoalkyl (carbon number 4 to 8) ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monopropyl ether , Propylene glycol monobutyl ether, dipropylene glycol alkyl (carbon number 1 to 4) ether, polyoxyethylene (average ethylene oxide addition mole number 1 to 5) monophenyl ether and monoalkyl (carbon number 3 One or more solvents in glyceryl ether, preferably polyoxyethylene (average ethylene oxide addition mole number 1 to 5) monophenyl ether, more preferably diethylene glycol monophenyl ether Or phenoxyethanol.

＜ 22 ＞
The floor treatment composition according to any one of the above <19> to <21>, the content of which is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, and further preferably 0.5% by mass or more, The (D) component is preferably 10% by mass or less, more preferably 5% by mass or less, and even more preferably 2% by mass or less.

＜ 23 ＞
The floor treatment composition according to any one of the above <19> to <21>, wherein the component (D) is polyoxyethylene (the average ethylene oxide addition mole number is 1 or more and 5 or less) monobenzene Ether, and the content of the (D) component is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, still more preferably 0.5% by mass or more, and preferably 10% by mass or less, and more preferably 5% by mass or less It is more preferably 2% by mass or less.

＜ 24 ＞
The floor treatment composition as described in any one of the above <4> to <23>, further containing 0.001% by mass or more, more preferably 0.01% by mass or more in terms of acid, and more preferably It is preferably 1% by mass or less, more preferably 0.5% by mass or less, still more preferably 0.1% by mass or less of an organic acid, and more preferably citric acid.

＜ 25 ＞
The floor treatment composition according to any one of the above <4> to <24>, further containing preferably 0.001% by mass or more, more preferably 0.005% by mass or more, and more preferably 0.1% by mass or less The inorganic alkali agent is more preferably 0.05% by mass or less.

＜ 26 ＞
The floor treatment agent composition as described in any one of said <19> to <25>, wherein (A) component and the total of (B) component, (C) component, and (D) component which are arbitrary components The ratio of the content in all components except water is preferably 90% by mass or more, more preferably 93% by mass or more, still more preferably 95% by mass or more, and still more preferably 99.5% by mass or more, and more preferably 99% by mass. % Or less, and more preferably 98.5% by mass or less.

＜ 27 ＞
The floor treatment composition according to any one of the above <4> to <26>, wherein the ratio of the content of the component (A) to all components except water is 20% by mass or more, and further 30% by mass Above, further 40% by mass or more, further 50% by mass or more, and 95% by mass or less, further 80% by mass or less, further 70% by mass or less, and further 60% by mass or less.

＜ 28 ＞
A floor surface treatment method comprising diluting the floor treatment composition according to any one of the above <4> to <27> with water by 50 times or more, and further 80 times or more and 200 times or less. Further, the form of the treatment liquid obtained 150 times or less is applied to the floor surface and allowed to dry.

＜ 29 ＞
A floor surface treatment method comprising diluting the floor treatment composition according to any one of the above <4> to <27> with water by 50 times or more, and further 80 times or more, and 200 times or less, Furthermore, the form of the treatment liquid obtained 150 times or less was applied to the floor surface, and it was dried without wet rubbing.

＜ 30 ＞
A floor surface treatment method comprising applying a composition containing (A) an alkyl glycoside surfactant [hereinafter, referred to as (A) component] 5 ppm to 1000 ppm, and water to a floor dry.

＜ 31 ＞
A floor surface treatment method comprising applying a composition containing (A) an alkyl glycoside surfactant [hereinafter, referred to as (A) component] 5 ppm to 1,000 ppm, and water to the floor without Wipe to dry.

＜ 32 ＞
The method for treating a floor surface as described in the above <30> or <31> is such that the content of the component (A) is preferably 50 ppm or more, more preferably 100 ppm or more, and preferably 500 ppm or less The composition prepared in a manner of more preferably 200 ppm or less is coated on the floor surface.

<33>
The method for treating a floor surface as described in the above <30> or <31> is such that the content of the component (A) is 5 ppm or more, preferably 50 ppm or more, more preferably 100 ppm or more, and 1000 In a manner of not more than ppm, preferably not more than 500 ppm, and more preferably not more than 200 ppm, the treatment agent composition for flooring as described in any one of <4> to <27> above is diluted with water, and The obtained composition is applied on a floor surface.

In the examples, the following treatment ingredients were used to prepare the floor treatment composition shown in Tables 1 and 2, and the following items were evaluated. The results are shown in Tables 1 and 2. The floor treatment compositions of Tables 1 and 2 were prepared according to a conventional method. That is, components (A), (B), (C), and (D) are added to an appropriate amount of ion-exchanged water, and they are dissolved at room temperature (25 ° C), and sodium hydroxide or / And citric acid monohydrate to adjust the pH (30 ° C, glass electrode method) to the values shown in Tables 1 and 2. In addition, all the mass% of the blending ingredients in Tables 1 and 2 are numerical values based on active ingredients.

＜ Mixed ingredients ＞
(A) Component: AG: An alkyl glycoside. In the general formula (A1), R ^1a is a mixed alkyl group having 8 to 16 carbon atoms, G is a residue derived from glucose, x is 0, and y is 1.3.
(B) Component and cationic surfactant 1: Alkyl dimethyl benzyl ammonium chloride having an alkyl group of 12 to 16 carbon atoms
(C) Ingredients and fragrances a: 40% by mass of dihydromyrcenol, 25% by mass of eucalyptus oil, 15% by mass of linalool, 15% by mass of ethyl palmitate, and 5% by mass of methyl dihydrojasmonate Perfume composition
(D) Ingredients and phenoxyethanol: made by Japanese emulsifiers
pH adjuster ・ Citric acid: Citric acid monohydrate ・ Sodium hydroxide: 48% sodium hydroxide

＜ Evaluation method ＞
(1) Tactile evaluation 1
200 μl of rapeseed oil (Sangui Industrial Co., Ltd.) was evenly coated on a 10 cm × 10 cm tile, and heated in a constant temperature bath at 90 ° C. for 150 minutes as a model dirt with thermally modified oil attached. . The water-adjusted hardness of 5 ° dH was used to dilute the treatment composition for flooring of Table 1 to 100 times, and 3 ml of the obtained treatment solution was impregnated in Kimwipe (trade name). Wipe only 1 stroke on the tile. After the treatment liquid was dried, each of five skilled functional inspectors touched twice with their fingers, and evaluated the stickiness of the tiles based on the following evaluation criteria. The results are shown in Table 1. In Table 1, each of the five skilled functional inspectors judged twice based on the following criteria, and the average value was calculated and used.
3 points: Similar to the part wiped with the treatment liquid of Example 1, the floor is not sticky and dry.
2 points: Compared with the part wiped with the treatment liquid of Example 1, the floor has a sticky feeling.
1 point: Compared with the part wiped with the treatment liquid of Example 1, the floor is obviously sticky.

[Table 1]

(2) Tactile evaluation 2
Ordinary women who wet the floor with a mop mop using a commercially available floor cleaner usually use the floor treatment agent composition of each of the examples 3 to 5 in Table 2 instead of the usual floor cleaner, and use it for 1 month (relatively 10 treatment agents composition for each board). The method of use is to dilute the treatment agent composition for slabs of Examples 3 to 5 to 100 times with tap water, soak the obtained treatment liquid in the mop, and wet the floor. After 1 month of use, The touch of the floor after drying was counted as the number of people who answered, "Compared to usual cleaning, the floor is not sticky and dry after cleaning." The results are shown in Table 2.

[Table 2]

Table 3 shows preparation examples of the floor treatment composition of the present invention. Each of the formulation examples in Table 3 is 2.1 or more in the tactile evaluation 1. The floor surface can be improved by applying a simple treatment such as coating and drying to a floor surface to which a modified oil such as a thermally modified oil is attached. It feels non-sticky and dry.

[table 3]

In Table 3, the following were used for the cationic surfactant 2.
Cationic surfactant 2: Other fonts are used in the alkyl trimethylammonium chloride with 12 carbon atoms in the file. Please adjust the font (Chinese characters should be set to new detail style, English characters should be set to Times New Roman).

Claims (8)

A touch improvement agent for flooring, comprising (A) an alkylglycoside-type surfactant. A floor treatment agent composition comprising (A) an alkyl glycoside-type surfactant [hereinafter, referred to as (A) component], and optionally (B) a surfactant other than (A) component [hereinafter, Called (B) component], and water, the mass ratio of the content of (A) component to the total content of (A) component and (B) component (A) / [(A) + (B)] exceeds 0.55, and The pH of this floor treatment composition at 30 ° C is 4 or more and less than 9. The treatment agent composition for a floor according to claim 2, wherein the component (B) contains a cationic surfactant. The floor treatment composition according to claim 2 or 3, further comprising (C) a fragrance [hereinafter, referred to as (C) component]. The floor treatment composition according to any one of claims 2 to 4, further comprising (D) a solvent [hereinafter, referred to as (D) component]. The floor treatment composition according to any one of claims 2 to 5, wherein the ratio of the total content of the component (A) in all components except water is 90% by mass or more. In the case of the components B) to (D), their contents are also included in the total content. A method for treating a floor surface, which comprises applying a composition containing (A) an alkyl glycoside surfactant at 5 ppm to 1,000 ppm, and water, and drying the floor. A method for treating a floor surface is to apply a composition containing (A) an alkyl glycoside surfactant at 5 ppm to 1,000 ppm, and water to the floor, and dry it without wet rubbing.