TW201940683A - Touch improver for floor - Google Patents
Touch improver for floor Download PDFInfo
- Publication number
- TW201940683A TW201940683A TW108109512A TW108109512A TW201940683A TW 201940683 A TW201940683 A TW 201940683A TW 108109512 A TW108109512 A TW 108109512A TW 108109512 A TW108109512 A TW 108109512A TW 201940683 A TW201940683 A TW 201940683A
- Authority
- TW
- Taiwan
- Prior art keywords
- component
- floor
- less
- mass
- composition
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/12—Flooring or floor layers made of masses in situ, e.g. seamless magnesite floors, terrazzo gypsum floors
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Architecture (AREA)
- Structural Engineering (AREA)
- Civil Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Detergent Compositions (AREA)
- Floor Finish (AREA)
- Cleaning By Liquid Or Steam (AREA)
- Fats And Perfumes (AREA)
Abstract
Description
本發明係關於一種地板用觸感改善劑、地板用處理劑組合物、及地板面之處理方法。The present invention relates to a touch improver for a floor, a treatment composition for a floor, and a method for treating a floor surface.
於多數情況下赤腳生活之國家或地區,日常使用含有地板用洗淨劑組合物之洗淨水用拖把濕擦地板面來進行清潔。此種日常清潔雖足以除去汗污或塵土等輕度污垢,但由烹飪時飛濺之油污或來自腳汗之油等因熱或光或空氣中之氧等變質而來之變性油若附著於地板面,則地板面會變得黏膩,僅利用先前之洗淨水進行濕擦無法除去此種黏膩。因此,為了除去此種黏膩,需要進行正式之地板洗淨。In countries or regions where barefoot lives in most cases, the floor surface is cleaned with a mop moistened with a mop. Although this daily cleaning is sufficient to remove mild dirt such as sweat or dust, but the modified oil such as the oil splashing from the cooking or the sweat from the feet is deteriorated by heat or light or oxygen in the air if it is attached to the floor Surface, the floor surface will become sticky, and this type of stickiness cannot be removed only by wet rubbing with previous washing water. Therefore, in order to remove such stickiness, formal floor washing is required.
於日本專利特開2015-007220號公報中,揭示有一種地板等之硬質表面用洗淨劑組合物,其含有特定之烷基糖苷、特定之非離子界面活性劑、陰離子界面活性劑、及香料,且洗淨後之速乾性及打理性優異。於日本專利特開2000-297296號公報中,揭示有一種洗淨劑,其含有烷基糖苷、特定之殺菌劑、及脂肪酸鹽,且能夠同時進行塑膠、瓷磚、木材等之表面之洗淨與殺菌,簡便性優異。於日本專利特表2007-513215號公報中,揭示有一種洗淨劑組合物,其含有烷基糖苷及作為拋光成分之特定聚合物,且具有木質地板之表面之拋光效果。於日本專利特開2004-143251號公報中,揭示有一種樹脂蠟皮膜剝離劑組合物,其含有烷基糖苷、胺類、及水溶性溶劑。Japanese Patent Laid-Open No. 2015-007220 discloses a hard surface cleaner composition for floors and the like, which contains a specific alkyl glycoside, a specific nonionic surfactant, an anionic surfactant, and a fragrance. After washing, the quick-drying property and playing performance are excellent. Japanese Patent Laid-Open No. 2000-297296 discloses a cleaning agent which contains an alkyl glycoside, a specific fungicide, and a fatty acid salt, and can simultaneously clean and clean the surfaces of plastics, tiles, and wood. Sterilization and excellent simplicity. In Japanese Patent Publication No. 2007-513215, a detergent composition is disclosed, which contains an alkyl glycoside and a specific polymer as a polishing component, and has a polishing effect on the surface of a wooden floor. Japanese Patent Laid-Open No. 2004-143251 discloses a resin wax film peeling agent composition containing an alkyl glycoside, an amine, and a water-soluble solvent.
然而,日本專利特開2015-007220號公報及日本專利特開2000-297296號公報所揭示之組合物並非以改性油之洗淨為目的,即便使用含有該組合物之洗淨水用拖把濕擦地板面,亦無法改善附著有變性油之地板面之觸感。又,日本專利特表2007-513215號公報所揭示之組合物係利用作為拋光成分之特定聚合物而增強木質地板之光澤之組合物,並未提示不含此種成分之地板用處理劑僅藉由日常之濕擦處理會改善附著有變性油之地板面之觸感。日本專利特開2004-143251號公報所揭示之組合物因含有胺類而呈鹼性,並且,由於為樹脂蠟剝離劑而需要進行沖洗步驟,故而無法改善附著有變性油之地板面之觸感。However, the compositions disclosed in Japanese Patent Laid-Open Publication No. 2015-007220 and Japanese Patent Laid-Open Publication No. 2000-297296 are not for the purpose of cleaning modified oils, even if the moisturizing water containing the composition is used for mop cleaning. Wiping the floor surface can not improve the touch of the floor surface with denatured oil. In addition, the composition disclosed in Japanese Patent Publication No. 2007-513215 is a composition that uses a specific polymer as a polishing component to enhance the gloss of a wooden floor. It is not suggested that a floor treatment agent that does not contain such a component can only be borrowed. The daily wet rubbing treatment will improve the touch of the floor surface with denatured oil. The composition disclosed in Japanese Patent Laid-Open No. 2004-143251 is alkaline because it contains amines, and because it is a resin wax release agent, a rinsing step is required, so it cannot improve the feel of the floor surface to which denatured oil is attached. .
本發明之目的在於提供一種地板用觸感改善劑、地板用處理劑組合物、及地板面之處理方法,該地板用觸感改善劑係藉由對附著有熱改性油等變性油之地板面僅進行塗佈、乾燥之簡單之處理而改善地板面之觸感,使其不黏膩且乾爽。於本案說明書中,改性油係指包含因熱、日光、空氣中之氧等之作用而發生變質之油性成分者。又,熱改性油係指因熱而改性之油,且包含因熱而氧化之油成分。An object of the present invention is to provide a touch improver for a floor, a treatment composition for a floor, and a method for treating a floor surface. The touch improver for a floor is applied to a floor to which a modified oil such as a thermally modified oil is attached. The surface is simply coated and dried to improve the touch of the floor surface, making it non-sticky and dry. In the description of the present case, the modified oil means an oily component that is deteriorated by the action of heat, sunlight, and oxygen in the air. The thermally modified oil refers to an oil modified by heat and contains an oil component that is oxidized by heat.
本發明係關於一種包含(A)烷基糖苷型界面活性劑之地板用觸感改善劑。The present invention relates to a touch improver for flooring comprising (A) an alkylglycoside-type surfactant.
又,本發明係關於一種地板用處理劑組合物,其含有:(A)烷基糖苷型界面活性劑[以下,稱為(A)成分]、任意之(B)除(A)成分以外之界面活性劑[以下,稱為(B)成分]、及水,(A)成分之含量與(A)成分及(B)成分之合計含量之質量比(A)/[(A)+(B)]超過0.55,且該地板用處理劑組合物於30℃下之pH值為4以上且未達9。The present invention also relates to a floor treatment composition containing (A) an alkyl glycoside surfactant [hereinafter, referred to as (A) component], and optionally (B) other than (A) component. Surfactant [hereinafter, referred to as (B) component], and water, the mass ratio of the content of (A) component to the total content of (A) component and (B) component (A) / [(A) + (B )] Exceeds 0.55, and the pH value of the floor treatment composition at 30 ° C. is 4 or more and less than 9.
又,本發明係關於一種地板面之處理方法,其係將含有(A)烷基糖苷型界面活性劑5 ppm以上1000 ppm以下、及水之組合物塗佈於地板並使其乾燥。The present invention also relates to a method for treating a floor surface, which comprises applying a composition containing (A) an alkyl glycoside surfactant at 5 ppm to 1,000 ppm, and water to the floor and drying it.
根據本發明,提供一種地板用觸感改善劑、地板用處理劑組合物、及地板面之處理方法,該地板用觸感改善劑係藉由對附著有熱改性油等變性油之地板面僅進行塗佈、乾燥之簡單之處理而改善地板面之觸感,使其不黏膩且乾爽。進而,根據本發明,提供一種地板面之處理方法,其僅藉由對附著有變性油之地板面進行塗佈並使其乾燥便可改善地板面之觸感,使其不黏膩且乾爽,故而可不進行濕擦而完成洗淨。According to the present invention, there is provided a floor feel improver, a floor treatment composition, and a method for treating a floor surface. The floor feel improver is a floor surface to which a denatured oil such as a thermally modified oil is adhered. Only the simple treatment of coating and drying improves the touch of the floor surface, making it non-sticky and dry. Furthermore, according to the present invention, there is provided a method for treating a floor surface, which can improve the touch of the floor surface only by coating and drying the floor surface to which the denatured oil is attached, and making it non-sticky and dry. Therefore, cleaning can be completed without wet rubbing.
[地板用觸感改善劑]
本發明係一種包含(A)成分之地板用觸感改善劑。[Tactile improver for flooring]
This invention is a touch improvement agent for flooring containing (A) component.
對於本發明之(A)成分可改善地板面之觸感而使其不黏膩且乾爽之效果,雖無法充分地進行解釋說明,但認為,烷基糖苷相較於其他非離子界面活性劑,容易析出結晶,且於乾燥後之情形時析出之烷基糖苷之結晶會殘留於表面,從而能夠賦予乾爽之觸感。Although the component (A) of the present invention can improve the feel of the floor surface and make it non-sticky and dry, although it cannot be fully explained, it is believed that the alkyl glycosides are compared with other nonionic surfactants. The crystals are easily precipitated, and the crystals of the alkyl glycosides deposited on the surface after drying can be left on the surface, so that a dry touch can be imparted.
就地板之觸感改善之觀點而言,本發明中使用之(A)成分係碳數較佳為8以上、更佳為10以上且較佳為18以下、更佳為16以下之直鏈或支鏈之烷基,較佳為直鏈之烷基,且係糖之平均縮合度較佳為1以上且較佳為3以下、更佳為2以下、進而較佳為1.5以下之烷基糖苷。From the viewpoint of improving the feel of the floor, the (A) component used in the present invention is preferably a straight chain or having a carbon number of 8 or more, more preferably 10 or more, and preferably 18 or less, and more preferably 16 or less. A branched alkyl group is preferably a linear alkyl group, and the average condensation degree of the sugar is preferably an alkyl glycoside of 1 or more and preferably 3 or less, more preferably 2 or less, and further preferably 1.5 or less. .
作為(A)成分,宜為下述通式(A1)所表示之化合物。
R1a
(OR2a
)x
Gy
(A1)
[式中,R1a
表示碳數8以上18以下之直鏈或支鏈之烷基,R2a
表示碳數2以上4以下之伸烷基,G表示碳數5或6之來自糖之殘基,x表示其平均值為0以上5以下之數,y表示其平均值為1以上3以下之數]The component (A) is preferably a compound represented by the following general formula (A1).
R 1a (OR 2a ) x G y (A1)
[Wherein R 1a represents a linear or branched alkyl group having 8 to 18 carbon atoms, R 2a represents an alkylene group having 2 to 4 carbon atoms, and G represents a residue from a sugar having 5 or 6 carbon atoms , X represents a number whose average is 0 to 5 and y represents a number whose average is 1 to 3]
於上述通式(A1)中,就地板之觸感改善之觀點而言,R1a 為碳數8以上、較佳為10以上、且為18以下、較佳為16以下、更佳為14以下之直鏈或支鏈之烷基,較佳為直鏈之烷基。又,作為R2a 所表示之伸烷基,就地板之觸感改善之觀點而言,較佳為碳數為2者。又,G所表示之碳數5或6之來自糖之殘基係由所使用之單糖類或二糖類以上之糖決定其結構。作為G,於單糖類中,可列舉來自葡萄糖、半乳糖、木糖、甘露糖、來蘇糖、阿拉伯糖、果糖或該等之混合物等之殘基,於二糖類以上中,可列舉來自麥芽糖、木二糖、異麥芽糖、纖維雙糖、龍膽二糖、乳糖、蔗糖、黑麯黴糖、松二糖、棉子糖、龍膽三糖、松三糖或該等之混合物等之殘基。該等中,就地板之觸感改善之方面及該等之獲取性及低成本之方面而言,較佳之原料為單糖類中之葡萄糖及果糖、及二糖類以上中之麥芽糖及蔗糖。In the above general formula (A1), from the viewpoint of improving the feel of the floor, R 1a has a carbon number of 8 or more, preferably 10 or more, and 18 or less, preferably 16 or less, and more preferably 14 or less. The linear or branched alkyl group is preferably a linear alkyl group. In addition, as the alkylene group represented by R 2a , a carbon number of 2 is preferred from the viewpoint of improving the feel of the floor. In addition, the sugar-derived residue having a carbon number of 5 or 6 represented by G is determined by the sugars of monosaccharides or disaccharides used. As G, among monosaccharides, residues derived from glucose, galactose, xylose, mannose, lyxose, arabinose, fructose, or a mixture thereof may be mentioned. Among disaccharides or higher, maltose derived Residues of xyloose, isomaltose, cellobiose, gentiobiose, lactose, sucrose, aspergillose, sucrose, raffinose, gentiotriose, melezitose, or mixtures thereof . Among these, in terms of improving the feel of the floor and the availability and low cost of these, the preferred raw materials are glucose and fructose in monosaccharides, and maltose and sucrose in disaccharides and the like.
又,上述通式(A1)中之x為OR2a 之平均加成莫耳數,較佳為0以上,且較佳為5以下,更佳為3以下,進而較佳為1以下,亦可為0,為了提高結晶性,最佳為0。藉由該x之值,可調節(A)成分之水溶性及結晶性。即,有如下傾向:x之值越大,則(A)成分之水溶性越高且結晶性越低。In addition, x in the general formula (A1) is an average addition mole number of OR 2a , preferably 0 or more, and preferably 5 or less, more preferably 3 or less, and further preferably 1 or less. It is 0, and in order to improve crystallinity, it is 0. By the value of x, the water solubility and crystallinity of the component (A) can be adjusted. That is, the larger the value of x, the higher the water solubility of the component (A) and the lower the crystallinity.
又,於上述通式(A1)中之y之平均值大於1之情形時,亦即,於(A)成分以二糖類以上之糖鏈為親水性基之情形時,可包含糖鏈之鍵結方式為1-2、1-3、1-4、1-6鍵結或α-、β-吡喃糖苷鍵結或呋喃糖苷鍵結及將該等混合之鍵結方式的任意混合物。In addition, when the average value of y in the general formula (A1) is greater than 1, that is, when the component (A) contains a sugar chain having a disaccharide or more as a hydrophilic group, a sugar chain bond may be included. The bonding method is any mixture of 1-2, 1-3, 1-4, 1-6 bonding or α-, β-pyranoside or furanoside bonding, and a combination of these bonding methods.
上述通式(A1)中之y之平均值為1以上,且為3以下,較佳為2以下,更佳為1.5以下。該y之值(糖之平均縮合度)係藉由1 H-NMR進行測定。作為具體之測定方法,參照日本專利特開平8-53696號公報第6頁第10欄26列~第7頁第11欄15列。The average value of y in the general formula (A1) is 1 or more and 3 or less, preferably 2 or less, and more preferably 1.5 or less. The value of y (average degree of condensation of sugar) was measured by 1 H-NMR. As a specific measurement method, refer to Japanese Patent Application Laid-Open No. 8-53696, page 6, column 10, column 26 to page 7, column 11, column 15.
若將本發明之包含(A)成分之地板用觸感改善劑溶解於水等溶劑,塗佈於附著有變性油之地板面並使其乾燥,則能夠改善地板面之觸感,使其不黏膩且乾爽。If the touch-improving agent for flooring containing the component (A) of the present invention is dissolved in a solvent such as water and applied to a floor surface to which denatured oil is adhered and dried, the touch of the floor surface can be improved, and Sticky and dry.
[地板用處理劑組合物]
本發明係一種地板用處理劑組合物,其含有:(A)成分、任意之(B)成分、及水,(A)成分之含量與(A)成分及(B)成分之合計含量之質量比(A)/[(A)+(B)]超過0.55,且該地板用處理劑組合物於30℃下之pH值為4以上且未達9。[Floor treatment agent composition]
The present invention is a floor treatment agent composition containing: (A) component, arbitrary (B) component, and water; mass of (A) component content and total content of (A) component and (B) component The ratio (A) / [(A) + (B)] exceeds 0.55, and the pH value of the floor treatment composition at 30 ° C. is 4 or more and less than 9.
本發明之地板用處理劑組合物需要限制阻礙(A)成分即烷基糖苷之結晶化之其他成分、例如作為除(A)成分以外之界面活性劑之(B)成分的含量。本發明之地板用處理劑組合物可適當地使用上文關於本發明之包含(A)成分之地板用觸感改善劑所敍述之事項。又,本發明之地板用處理劑組合物中之(A)成分與本發明之地板用觸感改善劑中所記載之(A)成分相同。In the floor treatment composition of the present invention, it is necessary to limit the content of other components that inhibit the crystallization of the alkylglycoside (A) component, for example, the content of the (B) component as a surfactant other than the (A) component. The treatment agent composition for a floor of the present invention can suitably use the matters described above with respect to the touch-improving agent for a floor including the component (A) of the present invention. The component (A) in the floor treatment composition of the present invention is the same as the component (A) described in the floor texture improving agent of the present invention.
關於本發明之地板用處理劑組合物,就地板之觸感改善之觀點而言,(A)成分較佳為含有0.01質量%以上,更佳為0.1質量%以上,進而較佳為1質量%以上,並且,就若(A)成分之濃度過高則有地板之乾爽感降低之傾向之觀點而言,較佳為含有50質量%以下,更佳為15質量%以下,進而較佳為10質量%以下,進而更佳為5質量%以下,進而更佳為2.5質量%以下,進而更佳為2質量%以下。Regarding the floor treatment agent composition of the present invention, from the viewpoint of improving the feel of the floor, the component (A) preferably contains 0.01% by mass or more, more preferably 0.1% by mass or more, and even more preferably 1% by mass. Above, from the viewpoint that if the concentration of the component (A) is too high, the dry feeling of the floor tends to decrease, it is preferably 50% by mass or less, more preferably 15% by mass or less, and even more preferably 10%. Mass% or less, more preferably 5 mass% or less, still more preferably 2.5 mass% or less, and even more preferably 2 mass% or less.
本發明之地板用處理劑組合物亦可含有除(A)成分以外之界面活性劑作為(B)成分,但就由(A)成分獲得之地板之觸感改善之觀點而言,(B)成分之含量受到限制。於本發明之地板用處理劑組合物中,(A)成分之含量與(A)成分及(B)成分之合計含量之質量比(A)/[(A)+(B)]就地板之觸感改善之觀點而言,超過0.55,較佳為0.6以上,更佳為0.65以上,進而較佳為0.7以上,進而更佳為0.8以上,且為1以下,亦可為1。本發明之地板用處理劑組合物較佳為不含(B)成分。The surface treating agent composition of the present invention may contain a surfactant other than the component (A) as the component (B), but from the viewpoint of improving the feel of the floor obtained from the component (A), (B) The content of ingredients is limited. In the floor treatment composition of the present invention, the mass ratio of the content of (A) component to the total content of (A) component and (B) component (A) / [(A) + (B)] From the viewpoint of improvement in touch, it is more than 0.55, preferably 0.6 or more, more preferably 0.65 or more, still more preferably 0.7 or more, still more preferably 0.8 or more, and 1 or less, and may also be 1. It is preferable that the processing agent composition for floors of this invention does not contain (B) component.
基於對地板用處理劑組合物賦予殺菌效果亦作為生活者之需求變得重要,較佳為於本發明之地板用處理劑組合物中調配殺菌劑。為了賦予殺菌效果,本發明之地板用處理劑組合物較佳為(B)成分含有陽離子界面活性劑[以下,稱為(B1)成分]。Since it is important to provide a bactericidal effect to the floor treatment agent composition as a demand of a living person, it is preferable to mix a bactericide in the floor treatment agent composition of the present invention. In order to impart a bactericidal effect, the floor treatment composition of the present invention preferably contains a cationic surfactant (hereinafter, referred to as (B1) component) as the component (B).
(B1)成分只要為能夠賦予殺菌效果者,則無特別限制,可列舉作為鹽酸鹽或者甲基或乙基硫酸鹽之四級銨鹽型陽離子界面活性劑,其具有1個或2個鍵結於氮原子之碳數較佳為8以上且較佳為22以下、更佳為18以下、進而較佳為16以下之烷基,且鍵結於氮原子之剩餘有機基為碳數1以上3以下之短鏈烷基或羥烷基或至多1個苄基。(B1) The component is not particularly limited as long as it can impart a bactericidal effect, and it may be a quaternary ammonium salt type cationic surfactant of a hydrochloride or a methyl or ethyl sulfate, which has one or two bonds An alkyl group having a carbon number of 8 or more and preferably 22 or less, more preferably 18 or less, and even more preferably 16 or less, and the remaining organic group bonded to the nitrogen atom is 1 or more carbon Short-chain alkyl or hydroxyalkyl group of 3 or less or at most 1 benzyl group.
(B1)成分具體而言較佳為選自二烷基(1個烷基之碳數為8以上18以下)二甲基銨鹽、單烷基(碳數為8以上18以下)三甲基銨鹽、烷基(碳數為8以上18以下)二甲基苄基銨鹽、及苯銨松寧鹽中之1種以上,作為鹽,為鹽酸鹽或者甲基或乙基硫酸鹽。(B1)成分就殺菌性及地板之觸感之觀點而言,更佳為烷基(碳數12以上16以下)二甲基苄基銨鹽。(B1) The component is specifically preferably selected from the group consisting of a dialkyl group (carbon number of 1 alkyl group is 8 or more and 18 or less), a dimethyl ammonium salt, and a monoalkyl group (carbon number of 8 or more and 18 or less) trimethyl. One or more of an ammonium salt, an alkyl (carbon number of 8 to 18) dimethylbenzyl ammonium salt, and an ammonium salt of ammonium, and the salt is a hydrochloride or a methyl or ethyl sulfate. The (B1) component is more preferably an alkyl (carbon number: 12 or more and 16 or less) dimethylbenzyl ammonium salt from the viewpoints of bactericidal properties and touch of the floor.
於本發明之地板用處理劑組合物含有(B1)成分之情形時,(A)成分之含量與(A)成分及(B1)成分之合計含量之質量比(A)/[(A)+(B1)]就地板之觸感改善之觀點而言,較佳為超過0.55,更佳為0.6以上,進而較佳為0.65以上,並且,就殺菌效果之觀點而言,較佳為0.9以下,更佳為0.8以下,進而較佳為0.7以下。再者,(B1)成分之含量係根據於將陽離子界面活性劑之抗衡離子設為氯化物離子之情形時所換算之含量而算出。When the floor treatment composition of the present invention contains (B1) component, the mass ratio of the content of (A) component to the total content of (A) component and (B1) component (A) / [(A) + (B1)] From the viewpoint of improving the feel of the floor, it is preferably more than 0.55, more preferably 0.6 or more, still more preferably 0.65 or more, and from the viewpoint of germicidal effect, it is preferably 0.9 or less, It is more preferably 0.8 or less, and still more preferably 0.7 or less. The content of the component (B1) is calculated based on the content converted when the counter ion of the cationic surfactant is a chloride ion.
一般而言,多數情況下以將存在於地板之污垢洗淨為目的而於地板用處理劑組合物中含有選自陰離子界面活性劑及除(A)成分以外之非離子界面活性劑中之1種以上之界面活性劑[以下,亦稱為(B2)成分]。然而,於本發明之地板用處理劑組合物中,有降低(A)成分之結晶性之虞,故而較佳為不含有(B2)成分。Generally speaking, in order to clean the dirt existing on the floor, the floor treatment composition contains one selected from anionic surfactants and non-ionic surfactants other than the (A) component. More than one type of surfactant [hereinafter, also referred to as (B2) component]. However, in the floor treatment composition of the present invention, the crystallinity of the component (A) may be lowered. Therefore, it is preferable not to contain the component (B2).
於本發明之地板用處理劑組合物以洗淨、除去改性油為目的而含有(B2)成分之情形時,(A)成分之含量與(A)成分及(B2)成分之合計含量之質量比(A)/[(A)+(B2)]就地板之觸感改善之觀點而言,較佳為0.7以上,更佳為0.8以上,進而較佳為0.9以上,尤佳為0.99以上,且較佳為未達1,亦可為1。再者,於(B2)成分包含陰離子界面活性劑之情形時,陰離子界面活性劑之含量係根據於將陰離子界面活性劑設為酸型之情形時所換算之含量而算出。When the floor treatment composition of the present invention contains the component (B2) for the purpose of cleaning and removing modified oil, the content of the component (A) and the total content of the components (A) and (B2) The mass ratio (A) / [(A) + (B2)] is preferably 0.7 or more, more preferably 0.8 or more, even more preferably 0.9 or more, and even more preferably 0.99 or more from the viewpoint of improving the feel of the floor. , And is preferably less than 1, can also be 1. When the component (B2) contains an anionic surfactant, the content of the anionic surfactant is calculated based on the content converted when the anionic surfactant is an acid type.
本發明之地板用處理劑組合物就嗜好性之觀點而言,亦可含有香料作為(C)成分。(C)成分可使用單獨之香料成分,亦可使用以特定之比率含有複數種香料成分之香料組合物。作為香料成分,可使用「香料之化學」(赤星亮一著,日本化學會編產業化學系列1983年9月16日發行)或「合成香料化學與商品知識」(印藤元一著,化學工業日報社,1996年3月6日發行)或「香料與調香之基礎知識」(中島基貴著,產業圖書(股),1995年6月21日發行)中所記載者。作為(C)成分,較佳為污垢之洗淨效果或由細菌所產生之氣味之抑制效果優異者。The floor treatment agent composition of this invention may also contain a fragrance | flavor as a (C) component from a viewpoint of taste. (C) A fragrance | flavor component may be used individually, and the fragrance | flavor composition containing a plurality of fragrance | flavor components in a specific ratio may be used. As a fragrance ingredient, "Chemistry of Perfume" (Akasaka Ryoichi, Industrial Chemistry Series of the Japanese Chemical Society, September 16, 1983) or "Synthetic Perfume Chemistry and Product Knowledge" (Into Fujimoto, Chemical Industry Daily) , Issued on March 6, 1996) or "Basics of Spices and Fragrances" (by Nakajima Kiyoshi, Industry Books (Stock), issued on June 21, 1995). The component (C) is preferably one excellent in the cleaning effect of dirt or the suppression effect of odors generated by bacteria.
作為(C)成分,具體而言,可列舉選自烴系香料、醇系香料、醚系香料、醛系香料、酮系香料、酯系香料、內酯系香料、環狀酮系香料及含氮系香料中之1種以上,較佳為選自烴系香料、醇系香料及醛系香料中之1種以上。As component (C), specifically, selected from the group consisting of a hydrocarbon-based perfume, an alcohol-based perfume, an ether-based perfume, an aldehyde-based perfume, a ketone-based perfume, an ester-based perfume, a lactone-based perfume, a cyclic ketone-based perfume, and a One or more kinds of nitrogen-based perfumes are preferably one or more kinds selected from hydrocarbon-based perfumes, alcohol-based perfumes, and aldehyde-based perfumes.
作為(C)成分,更具體而言,作為較佳之香料,較佳為選自吐納麝香、氧雜環己烯-2-酮、佳樂麝香、水楊酸己酯、α-己基肉桂醛、1,2,3,4,5,6,7,8-八氫-2,3,8,8-四甲基-2-萘乙酮、水楊酸戊酯、異樟腦基環己醇、水楊酸環己酯、萜品油烯、檸檬烯、α-戊基肉桂醛、水楊酸苄酯、β-蒎烯、乙酸對第三丁基環己酯、乙酸鄰第三丁基環己酯、乙酸異壬酯、甲基紫羅蘭酮-G、1-(2-第三丁基己氧基)-2-丁醇、烯丙基環己基丙酸烯丙酯、3,3,5-三甲基環己基乙基醚、乙酸二甲基苄基烴甲基酯、鈴蘭醛、γ-十一酸內酯、β-紫羅蘭酮、乙酸松油酯、四氫沉香醇、乙酸沉香酯、己酸烯丙酯、3-甲基-5-苯基戊醇、二氫月桂烯醇、異丁酸苯乙酯、丙酸三環癸烯酯、乙酸二甲基苄基烴甲基酯、香葉草醇、1,8-桉樹腦、甲基β-萘基酮、松脂醇、冰片、沉香醇、格蓬酯、二氫茉莉酸甲酯、乙酸三環癸烯酯、樟腦、乙酸苄酯、茴香醛、香豆素、向日花香醛、桉葉油、及巴西酸伸乙酯中之1種以上之香料。尤佳為該等香料之logP(辛醇/水分配係數)大於1之香料,更佳為大於2之香料。As the component (C), more specifically, as a preferred fragrance, it is preferably selected from the group consisting of tuna musk, oxetan-2-one, Jiale musk, hexyl salicylate, and α-hexylcinnamaldehyde. 1,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-naphthylacetone, amyl salicylate, isocamphoryl cyclohexanol , Cyclohexyl salicylate, terpinolene, limonene, α-pentylcinnamaldehyde, benzyl salicylate, β-pinene, p-third butyl cyclohexyl acetate, or o-third butyl ring acetate Hexyl ester, isononyl acetate, methyl ionone-G, 1- (2-third butylhexyloxy) -2-butanol, allyl cyclohexyl propionate, 3,3,5 -Trimethylcyclohexylethyl ether, dimethyl benzyl hydrocarbon methyl ester, lyric aldehyde, γ-undecanolactone, β-ionone, terpineyl acetate, tetrahydro linalool, linal acetate , Allyl hexanoate, 3-methyl-5-phenylpentanol, dihydromyrcenol, phenethyl isobutyrate, tricyclodecenyl propionate, dimethyl benzyl hydrocarbon methyl ester , Geraniol, 1,8-eucalyptol, methyl β-naphthyl ketone, pinoresinol, borneol, linalool, guppen ester, methyl dihydrojasmonate, triacetate Decene ester, camphor, benzyl acetate, anisaldehyde, coumarin, the Japanese floral aldehyde, eucalyptus oil, and Brazil acid ethyl extension of one or more kinds of fragrances. Particularly preferred are fragrances with a logP (octanol / water partition coefficient) of greater than 1 for those fragrances, and more preferably greater than 2 for those fragrances.
於本發明中,就污垢之洗淨效果或由菌所產生之氣味之抑制效果之觀點而言,較佳為含有桉葉油等香料組合物作為(C)成分。In the present invention, it is preferable to contain a fragrance composition such as eucalyptus oil as the component (C) from the viewpoint of the cleaning effect of dirt or the suppressing effect of odor generated by bacteria.
關於本發明之地板用處理劑組合物,就嗜好性之觀點而言,(C)成分較佳為含有0.01質量%以上,更佳為0.05質量%以上,進而較佳為0.1質量%以上,並且,就組合物之儲存穩定性之觀點而言,較佳為含有1.5質量%以下,更佳為1質量%以下,進而較佳為0.8質量%以下。With regard to the floor treatment agent composition of the present invention, from the standpoint of preference, the component (C) preferably contains 0.01% by mass or more, more preferably 0.05% by mass or more, and still more preferably 0.1% by mass or more, and From the viewpoint of the storage stability of the composition, it is preferably 1.5 mass% or less, more preferably 1 mass% or less, and still more preferably 0.8 mass% or less.
於本發明之地板用處理劑組合物使用(C)成分之情形時,由於(C)成分於多數情況下為非水溶性,故而於含有(C)成分之情形時,就儲存穩定性之觀點而言需要注意。於本發明之地板用處理劑組合物含有(C)成分之情形時,(C)成分之含量與(A)成分及(B)成分之合計含量之質量比(C)/[(A)+(B)]就儲存穩定性及嗜好性之觀點而言,較佳為0.01以上,更佳為0.05以上,進而較佳為0.1以上,且較佳為1.0以下,更佳為0.8以下,進而較佳為0.4以下。When the component (C) is used in the floor treatment composition of the present invention, the component (C) is insoluble in most cases. Therefore, when the component (C) is contained, the storage stability is considered. Need to pay attention. When the floor treatment composition of the present invention contains (C) component, the mass ratio of the content of (C) component to the total content of (A) component and (B) component (C) / [(A) + (B)] From the viewpoint of storage stability and taste, it is preferably 0.01 or more, more preferably 0.05 or more, still more preferably 0.1 or more, and preferably 1.0 or less, more preferably 0.8 or less, and more preferably It is preferably 0.4 or less.
本發明之地板用處理劑組合物就組合物之調配穩定性之觀點而言,亦可含有溶劑作為(D)成分。作為溶劑,較佳為於20℃下對水之溶解度為5質量%以上之水溶性溶劑,且適宜為選自具有1個以上羥基之醇系溶劑及二醇系溶劑中之1種以上之溶劑。具體而言,可列舉選自乙醇、異丙醇、乙二醇、丙二醇、二乙二醇、二丙二醇、甘油、異戊二醇、乙二醇單烷基(碳數4以上8以下)醚、二乙二醇單烷基(碳數4以上8以下)醚、丙二醇單甲醚、丙二醇單乙醚、丙二醇單丙醚、丙二醇單丁醚、二丙二醇烷基(碳數1以上4以下)醚、聚氧乙烯(環氧乙烷平均加成莫耳數1以上5以下)單苯醚及單烷基(碳數3以上8以下)甘油醚中之1種以上之溶劑。於本發明之地板用處理劑組合物中,就組合物之儲存穩定性之觀點而言,(D)成分較佳為聚氧乙烯(環氧乙烷平均加成莫耳數1以上5以下)單苯醚,更佳為二乙二醇單苯醚或苯氧基乙醇。又,由於該等溶劑亦具有殺菌效果,故而亦期待防腐效果。The processing agent composition for floors of this invention may contain a solvent as a (D) component from a viewpoint of formulation stability of a composition. As the solvent, a water-soluble solvent having a solubility in water of 5 mass% or more at 20 ° C is preferred, and one or more solvents selected from alcohol-based solvents and glycol-based solvents having one or more hydroxyl groups are suitable. . Specific examples include ethers selected from the group consisting of ethanol, isopropanol, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, glycerol, isoamyl glycol, and ethylene glycol monoalkyl (4 to 8 carbon atoms) ethers. , Diethylene glycol monoalkyl (carbon number 4 to 8) ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monopropyl ether, propylene glycol monobutyl ether, dipropylene glycol alkyl (carbon number 1 to 4) ether One or more solvents of polyoxyethylene (an average addition mole number of ethylene oxide of 1 to 5) monophenyl ether and monoalkyl (carbon number of 3 to 8) glyceryl ether. In the floor treatment composition of the present invention, from the viewpoint of the storage stability of the composition, the (D) component is preferably polyoxyethylene (the average ethylene oxide addition mole number is 1 or more and 5 or less). Monophenyl ether, more preferably diethylene glycol monophenyl ether or phenoxyethanol. Since these solvents also have a bactericidal effect, anticorrosive effects are also expected.
關於本發明之地板用處理劑組合物,就組合物之儲存穩定性之觀點而言,(D)成分較佳為含有0.05質量%以上,更佳為0.1質量%以上,進而較佳為0.5質量%以上,且較佳為10質量%以下,更佳為5質量%以下,進而較佳為2質量%以下。進而,於(D)成分為聚氧乙烯(環氧乙烷平均加成莫耳數1以上5以下)單苯醚之情形時,本發明之地板用處理劑組合物就組合物之儲存穩定性及防腐效果賦予之觀點而言,(D)成分較佳為含有0.05質量%以上,更佳為0.1質量%以上,進而較佳為0.5質量%以上,且較佳為10質量%以下,更佳為5質量%以下,進而較佳為2質量%以下。Regarding the floor treatment composition of the present invention, from the viewpoint of the storage stability of the composition, the (D) component is preferably contained in an amount of 0.05% by mass or more, more preferably 0.1% by mass or more, and further preferably 0.5% by mass. % Or more, and preferably 10% by mass or less, more preferably 5% by mass or less, and even more preferably 2% by mass or less. Further, when the component (D) is a polyphenylene oxide (the average addition mole number of ethylene oxide is 1 or more and 5 or less) monophenyl ether, the floor treatment agent composition of the present invention is storage stability of the composition From the viewpoint of imparting antiseptic effect, the (D) component preferably contains 0.05% by mass or more, more preferably 0.1% by mass or more, still more preferably 0.5% by mass or more, and more preferably 10% by mass or less, more preferably The content is 5 mass% or less, and more preferably 2 mass% or less.
本發明之地板用處理劑組合物就洗淨操作中經常要求之衛生之觀點而言,亦可含有殺菌劑(但,(B1)成分及(D)成分除外)作為(E)成分。此處,本發明之殺菌劑可使用「香妝品、醫藥品防腐・殺菌劑之科學」吉村孝一、瀧川博文著、芳香雜誌(Fragrance Journal)社、1990年4月10日發行、第501頁~564頁所記載者。例如為選自三氯沙、雙-(2-吡啶硫基-1-氧化物)鋅、2,4,5,6-四氯間苯二甲腈、三氯對稱二苯脲、2-(4-硫氰基甲硫基)苯并咪唑、聚六亞甲基雙胍鹽酸鹽、葡萄糖醛酸洗必泰、8-羥基喹啉、及聚離胺酸中之1種以上。又,可使用日本專利特開平11-189975號中所記載之三氯沙類本身,具體而言,可使用二氯羥基二苯醚、及單氯羥基二苯醚。The floor treatment agent composition of the present invention may contain a germicidal agent (except (B1) component and (D) component) as the (E) component from the viewpoint of hygiene often required in washing operations. Here, the bactericidal agent of the present invention can be used in "The Science of Cosmetics, Pharmaceutical Preservatives, and Fungicides" by Takaichi Yoshimura, Hiroshi Takikawa, Fragrance Journal, April 10, 1990, p. 501 ~ Those listed on page 564. For example, it is selected from trichlorofloxacin, bis- (2-pyridylthio-1-oxide) zinc, 2,4,5,6-tetrachloroisophthalonitrile, trichlorosymmetric diphenylurea, 2- ( 4-thiocyanomethylthio) benzimidazole, polyhexamethylene biguanide hydrochloride, chlorhexidine glucuronide, 8-hydroxyquinoline, and polyionic acid. In addition, the triclosan itself described in Japanese Patent Laid-Open No. 11-189975 can be used, and specifically, dichlorohydroxydiphenyl ether and monochlorohydroxydiphenyl ether can be used.
關於本發明之地板用處理劑組合物,就殺菌性之觀點而言,(E)成分較佳為含有0.001質量%以上,更佳為0.01質量%以上,進而較佳為0.1質量%以上,且較佳為1質量%以下,更佳為0.5質量%以下,進而較佳為0.1質量%以下。但,於(E)成分之含量中,(B1)成分及(D)成分被排除在外。Regarding the floor treatment agent composition of the present invention, from the viewpoint of sterilization, the (E) component preferably contains 0.001% by mass or more, more preferably 0.01% by mass or more, and still more preferably 0.1% by mass or more, and It is preferably 1% by mass or less, more preferably 0.5% by mass or less, and still more preferably 0.1% by mass or less. However, (B1) component and (D) component are excluded from the content of (E) component.
本發明之地板用處理劑組合物係含有水之液體組合物。可為使上述成分於水中溶解、分散、乳化之形態中之任一者。水可使用已除去金屬成分之離子交換水或蒸餾水、或者將次亞氯酸溶解為0.5 ppm以上10 ppm以下程度所得之次亞氯酸滅菌水等。水係組合物之剩餘部分,且以整體設為100質量%之量含有。The floor treatment agent composition of the present invention is a liquid composition containing water. Any of the above-mentioned components can be dissolved, dispersed, and emulsified in water. As the water, ion-exchanged water or distilled water from which metal components have been removed, or hypochlorous acid sterilized water obtained by dissolving hypochlorous acid to a level of 0.5 ppm to 10 ppm can be used. The remainder of the water-based composition is contained in an amount of 100% by mass as a whole.
於本發明之地板用處理劑組合物中,30℃下之pH值就地板之觸感改善之觀點而言為4以上,較佳為5以上,且未達9,較佳為8以下,更佳為7以下,進而較佳為6.5以下。作為調整為此種pH值之pH值調整劑,使用選自硫酸、鹽酸、磷酸中之無機酸,選自檸檬酸、蘋果酸、馬來酸、富馬酸、琥珀酸、乳酸、乙醇酸中之有機酸,氫氧化鈉、氫氧化鉀、氫氧化鎂、碳酸鈉、碳酸鉀等無機鹼劑而進行。於本發明中,使洗淨劑組合物具備緩衝能力就洗淨力持續性之方面而言較佳,且適宜將上述有機酸、較佳為檸檬酸與無機鹼劑併用。有機酸亦可以鈉鹽或鉀鹽之形態調配於洗淨劑組合物中,以酸之形態計,該有機酸於本發明之地板用處理劑組合物中之含量較佳為0.001質量%以上,更佳為0.01質量%以上,且較佳為1質量%以下,更佳為0.5質量%以下,進而較佳為0.1質量%以下。無機鹼劑於本發明之地板用處理劑組合物中之含量較佳為0.001質量%以上,更佳為0.005質量%以上,且較佳為0.1質量%以下,更佳為0.05質量%以下。In the floor treatment composition of the present invention, the pH value at 30 ° C is 4 or more, preferably 5 or more, and less than 9, preferably 8 or less, from the viewpoint of improving the feel of the floor. It is preferably 7 or less, and more preferably 6.5 or less. As the pH adjusting agent adjusted to such a pH value, an inorganic acid selected from sulfuric acid, hydrochloric acid, and phosphoric acid is used, and selected from citric acid, malic acid, maleic acid, fumaric acid, succinic acid, lactic acid, and glycolic acid. The organic acid is carried out with inorganic alkali agents such as sodium hydroxide, potassium hydroxide, magnesium hydroxide, sodium carbonate, and potassium carbonate. In the present invention, it is preferable to provide the detergent composition with buffering capacity in terms of the sustainability of the cleaning power, and it is suitable to use the above-mentioned organic acid, preferably citric acid and an inorganic alkali agent in combination. The organic acid may also be formulated into the detergent composition in the form of a sodium salt or a potassium salt. The content of the organic acid in the floor treatment composition of the present invention is preferably 0.001% by mass or more in terms of the form of the acid. It is more preferably 0.01% by mass or more, more preferably 1% by mass or less, still more preferably 0.5% by mass or less, and still more preferably 0.1% by mass or less. The content of the inorganic alkali agent in the floor treatment composition of the present invention is preferably 0.001% by mass or more, more preferably 0.005% by mass or more, and preferably 0.1% by mass or less, and more preferably 0.05% by mass or less.
本發明之地板用處理劑組合物即便不含蠟、樹脂蠟、矽等拋光劑,亦能夠改善附著有熱改性油等變性油之地板面之觸感,使其不黏膩且乾爽。即,於本發明之地板用處理劑組合物中,(A)成分及作為任意成分之(B)成分~(D)成分之合計含量於除水以外之全部成分中之比率就地板之觸感改善之觀點而言,較佳為90質量%以上,更佳為93質量%以上,進而較佳為95質量%以上,且較佳為99.5質量%以下,更佳為99質量%以下,進而較佳為98.5質量%以下。又,於本發明之地板用處理劑組合物中,(A)成分之含量於除水以外之全部成分中之比率就地板之觸感改善之觀點而言,可自20質量%以上、進而30質量%以上、進而40質量%以上、進而50質量%以上,且95質量%以下、進而80質量%以下、進而70質量%以下、進而60質量%以下之中選擇。The floor treatment composition of the present invention can improve the touch of a floor surface to which a denatured oil such as a thermally modified oil is adhered, even if it does not contain polishing agents such as wax, resin wax, and silicon, making it non-sticky and dry. That is, in the floor treatment composition of the present invention, the ratio of the total content of (A) component and (B) component to (D) component as an optional component to all components except water is the feel of the floor. From the viewpoint of improvement, it is preferably 90% by mass or more, more preferably 93% by mass or more, still more preferably 95% by mass or more, still more preferably 99.5% by mass or less, still more preferably 99% by mass or less, and more preferably It is preferably 98.5 mass% or less. In the floor treatment composition of the present invention, the ratio of the content of the component (A) to all components except water may be from 20% by mass or more to 30% from the viewpoint of improving the feel of the floor. Mass% or more, further 40 mass% or more, further 50 mass% or more, and 95 mass% or less, further 80 mass% or less, further 70 mass% or less, and further 60 mass% or less are selected.
本發明之地板用處理劑組合物宜用作地板之濕擦用組合物或濕擦用物品。即,宜用於如起居室、房間、廚房、浴室、廁所之居住區等之地板之溫和洗淨。作為地板,可列舉石地板、拼花地板、瓷磚、油氈及塑膠地板,較佳為適合於瓷磚製地板。本發明之地板用處理劑組合物可藉由對附著有熱改性油等變性油之地板面僅進行塗佈、乾燥之簡單之處理而改善地板面之觸感,使其不黏膩且乾爽,又,即便不另外進行濕擦(二次擦拭),亦可獲得本發明之效果,故而無需進行濕擦。The floor treating agent composition of the present invention is suitably used as a wet wiping composition or a wet wiping article for a floor. That is, it is suitable for gentle washing of floors in living areas such as living rooms, rooms, kitchens, bathrooms, and toilets. Examples of the floor include a stone floor, a parquet floor, a tile, a linoleum, and a plastic floor, and are preferably suitable for a tile floor. The floor treatment agent composition of the present invention can improve the touch of the floor surface by simply coating and drying the floor surface to which the denatured oil such as thermally modified oil is adhered, so that it is not sticky and dry. Moreover, the effect of the present invention can be obtained even if wet wiping (secondary wiping) is not performed separately, so there is no need to perform wet wiping.
本發明之地板用處理劑組合物於對污垢較少之地板使用之情形時,較佳為以用水稀釋至50倍以上、進而80倍以上、且200倍以下、進而150倍以下所獲得之處理液之形式塗佈於地板面。In the case where the floor treatment agent composition of the present invention is used on a floor with less dirt, it is preferably a treatment obtained by diluting it with water to 50 times or more, 80 times or more, 200 times or less, and 150 times or less. Apply as a liquid on the floor.
又,本發明之地板用處理劑組合物或如上所述將其稀釋後之處理液(以下,有時亦簡稱為處理液)亦可含浸於基體中而用作清掃用物品。基體中含浸有本發明之地板用處理劑組合物或處理液之清掃用物品就清掃作業之作業性之觀點而言較佳。The floor treatment composition of the present invention or a treatment liquid (hereinafter, sometimes simply referred to as a treatment liquid) after diluting it as described above may be impregnated into a substrate and used as a cleaning article. The cleaning article impregnated with the floor treatment composition or the treatment liquid of the present invention in the substrate is preferred from the viewpoint of the operability of the cleaning operation.
作為用於含浸有地板用處理劑組合物或處理液之清掃用物品之基體,使用如下基體,其具有可撓性,可含浸地板用處理劑組合物或處理液,於使用時具有充分之強度,且不會產生碎屑等。尤佳為使用能夠於無負荷下含浸下述量之地板用處理劑組合物或處理液之基體。As a substrate for a cleaning article impregnated with a floor treatment composition or a treatment liquid, the following substrate is used, which has flexibility and can be impregnated with the floor treatment composition or the treatment liquid, and has sufficient strength when used. , And no debris. It is particularly preferable to use a substrate capable of being impregnated with the following amount of a floor treatment composition or a treatment liquid under no load.
作為此種基體,可列舉包含纖維狀材料之纖維結構體,例如各種紙、不織布、織布或針織布。作為構成該等纖維結構體之纖維狀材料,例如可列舉纖維素系纖維、改性纖維素系纖維、合成纖維及該等之兩種以上之混合物等。Examples of such a substrate include a fibrous structure including a fibrous material, such as various papers, nonwoven fabrics, woven fabrics, or knitted fabrics. Examples of the fibrous material constituting the fiber structure include cellulose-based fibers, modified cellulose-based fibers, synthetic fibers, and a mixture of two or more of these.
又,使氣泡分散於樹脂中而獲得之多孔質結構體(例如海綿狀結構體)亦可用作上述基體。Moreover, a porous structure (for example, a sponge-like structure) obtained by dispersing air bubbles in a resin can also be used as the substrate.
又,使用含浸有本發明之地板用處理劑組合物或處理液之清掃用物品擦拭地板面之洗淨方法就清掃作業之作業性之觀點而言適於地板面之溫和洗淨。含浸有地板用處理劑組合物或處理液之清掃用物品可為預先使地板用處理劑組合物或處理液含浸於基體中而成者,或於即將使用之前藉由噴霧等使地板用處理劑組合物或處理液含浸於乾燥之基體中而成者之任一者。又,亦可使用經噴霧之清掃用物品清掃被清掃面。含浸有地板用處理劑組合物或處理液之清掃用物品可安裝於拖把狀清潔工具上使用,亦可直接用手抓住而用於擦拭清潔。In addition, the cleaning method for wiping the floor surface with a cleaning article impregnated with the floor treatment composition or the treatment liquid of the present invention is suitable for gentle cleaning of the floor surface from the viewpoint of the workability of the cleaning operation. The cleaning article impregnated with the floor treatment composition or the treatment liquid may be one in which the floor treatment composition or the treatment liquid is impregnated into the substrate in advance, or the floor treatment agent is sprayed or the like immediately before use. Either the composition or the treatment liquid is impregnated into a dried substrate. In addition, the surface to be cleaned may be cleaned with the sprayed cleaning article. The cleaning article impregnated with the floor treatment composition or the treatment liquid can be mounted on a mop-shaped cleaning tool, or it can be directly grasped by hand for cleaning.
於預先含浸有地板用處理劑組合物或處理液之情形時,地板用處理劑組合物或處理液之含浸率就清掃性之觀點而言,相對於基體質量[即,未含浸狀態(乾燥狀態)之基體之質量基準],較佳為100質量%以上,更佳為150質量%以上,且較佳為1000質量%以下,更佳為400質量%以下,進而較佳為350質量%以下。若含浸率為100質量%以上,則可獲得對於污斑或塵土之充分之清掃性能。若為1000質量%以下,則洗淨劑組合物對被清掃面之釋出量變得適當,被清掃面上不會殘留污垢或塵土,又,能夠不影響包含木質材料等多種材料之清掃面而進行使用。就進一步提高清掃性之方面而言,於基體為片材之情形時,地板用處理劑組合物或處理液之含浸前之基重就固定面積之洗淨所需之處理劑之保持性及片材之操作性或成本之觀點而言,較佳為40 g/m2 以上,更佳為50 g/m2 以上,且較佳為200 g/m2 以下,更佳為150 g/m2 以下。When impregnated with the floor treatment agent composition or the treatment liquid in advance, the impregnation rate of the floor treatment agent composition or the treatment liquid is, from the viewpoint of the cleanability, relative to the mass of the substrate [that is, the non-impregnated state (dry state). The quality basis of the substrate] is preferably 100% by mass or more, more preferably 150% by mass or more, more preferably 1000% by mass or less, more preferably 400% by mass or less, and further preferably 350% by mass or less. When the impregnation rate is 100% by mass or more, sufficient cleaning performance against stains or dust can be obtained. If it is 1000% by mass or less, the release amount of the detergent composition on the surface to be cleaned becomes appropriate, dirt or dust does not remain on the surface to be cleaned, and it is possible to prevent the cleaning surface including various materials including wood materials from being affected. For use. In terms of further improving the cleaning performance, in the case where the substrate is a sheet, the base agent before the impregnation of the treating agent composition or the treating liquid for the floor is fixed and the holding ability of the treating agent required for the cleaning of a fixed area. From the viewpoint of material operability or cost, it is preferably 40 g / m 2 or more, more preferably 50 g / m 2 or more, and more preferably 200 g / m 2 or less, and more preferably 150 g / m 2 the following.
當使用含浸有地板用處理劑組合物或處理液之清掃用物品時,亦可一面另外將本發明之地板用處理劑組合物或處理液噴霧至被清掃物或上述清掃用物品一面使用。藉由該使用方法,可清掃更廣之面積。When a cleaning article impregnated with the floor treatment composition or the treatment liquid is used, the floor treatment composition or the treatment liquid of the present invention may be sprayed onto the object to be cleaned or the cleaning article. By using this method, a wider area can be cleaned.
[地板面之處理方法]
本發明係一種將含有(A)成分5 ppm以上1000 ppm以下、及水之組合物塗佈於地板並使其乾燥之地板面之處理方法。進而,本發明係一種將含有(A)成分5 ppm以上1000 ppm以下、及水之組合物塗佈於地板且不進行濕擦(二次擦拭)而使其乾燥之地板面之處理方法。[Handling method of floor surface]
The present invention is a method for treating a floor surface by applying a composition containing (A) component in an amount of 5 ppm to 1,000 ppm and water, and drying the floor. Furthermore, this invention is a processing method of the floor surface which apply | coats the composition containing (A) component 5 ppm or more and 1000 ppm or less, and water to a floor, and does not perform wet rubbing (secondary wiping), and makes it dry.
本發明之地板面之處理方法只要將以使(A)成分之含量成為5 ppm以上、較佳為50 ppm以上、更佳為100 ppm以上且為1000 ppm以下、較佳為500 ppm以下、更佳為200 ppm以下之方式製備之組合物塗佈於地板面即可。上述組合物較佳為使用利用水將本發明之地板用處理劑組合物進行稀釋而製備者。The method for treating the floor surface of the present invention is only required to make the content of the component (A) be 5 ppm or more, preferably 50 ppm or more, more preferably 100 ppm or more and 1000 ppm or less, preferably 500 ppm or less, more The composition prepared in a manner of preferably 200 ppm or less may be applied to the floor surface. The composition is preferably prepared by diluting the floor treatment composition of the present invention with water.
於本發明之地板面之處理方法中,含有(A)成分5 ppm以上1000 ppm以下、及水之組合物亦可使用本發明之地板用處理劑組合物進行製備,(A)成分及其較佳之態樣以及任意成分與上文關於本發明之地板用處理劑組合物所敍述之事項相同。本發明之地板面之處理方法可適當地應用上文關於本發明之地板用處理劑組合物所敍述之事項。In the method for treating a floor surface of the present invention, a composition containing (A) component in an amount of 5 ppm to 1,000 ppm and water can also be prepared using the floor treatment composition of the present invention, (A) component and its comparison The preferred aspect and the optional components are the same as those described above with respect to the floor treatment composition of the present invention. The method for treating the floor surface of the present invention may suitably apply the matters described above with respect to the floor treatment composition of the present invention.
關於上述實施形態,本發明進而揭示以下之地板用觸感改善劑、地板用處理劑組合物、及地板面之處理方法。Regarding the embodiment described above, the present invention further discloses the following touch improving agent for flooring, a treating agent composition for flooring, and a method for treating a floor surface.
<1>
一種地板用觸感改善劑,其包含(A)烷基糖苷型界面活性劑[以下,稱為(A)成分]。< 1 >
A touch-improving agent for flooring comprising (A) an alkylglycoside-type surfactant [hereinafter, referred to as (A) component].
<2>
如上述<1>所記載之地板用觸感改善劑,其中(A)成分係碳數較佳為8以上、更佳為10以上且較佳為18以下、更佳為16以下之直鏈或支鏈之烷基,較佳為直鏈之烷基,且係糖之平均縮合度較佳為1以上且較佳為3以下、更佳為2以下、進而較佳為1.5以下之烷基糖苷。< 2 >
The feel improving agent for flooring as described in the above <1>, wherein the (A) component is preferably a straight chain or a carbon number of 8 or more, more preferably 10 or more, and preferably 18 or less, and more preferably 16 or less. A branched alkyl group is preferably a linear alkyl group, and the average condensation degree of the sugar is preferably an alkyl glycoside of 1 or more and preferably 3 or less, more preferably 2 or less, and further preferably 1.5 or less. .
<3>
如上述<1>或<2>所記載之地板用觸感改善劑,其中(A)成分為下述通式(A1)所表示之化合物。
R1a
(OR2a
)x
Gy
(A1)
[式中,R1a
表示碳數為8以上、較佳為10以上、且為18以下、較佳為16以下、更佳為14以下之直鏈或支鏈之烷基,較佳為直鏈之烷基,R2a
表示碳數2以上4以下之伸烷基、較佳為碳數2之伸烷基,G表示碳數5或6之來自糖之殘基、較佳為來自葡萄糖之殘基,x表示其平均值為0以上且較佳為5以下、更佳為3以下、進而較佳為1以下之數,y表示其平均值為1以上、且為3以下、較佳為2以下、更佳為1.5以下之數]< 3 >
The touch improvement agent for floors as described in said <1> or <2> whose (A) component is a compound represented by the following general formula (A1).
R 1a (OR 2a ) x G y (A1)
[Wherein R 1a represents a straight-chain or branched alkyl group having a carbon number of 8 or more, preferably 10 or more, and 18 or less, preferably 16 or less, and more preferably 14 or less, and is preferably a straight chain R 2a represents an alkylene group having 2 to 4 carbon atoms, preferably an alkylene group having 2 carbon atoms, and G represents a residue from a sugar group having 5 or 6 carbon atoms, preferably a residue from glucose. Basis, x represents a number whose average value is 0 or more and preferably 5 or less, more preferably 3 or less, and further preferably 1 or less, and y represents an average value of 1 or more, and 3 or less, preferably 2 Below, more preferably below 1.5]
<4>
一種地板用處理劑組合物,其含有:(A)烷基糖苷型界面活性劑[以下,稱為(A)成分]、任意之(B)除(A)成分以外之界面活性劑[以下,稱為(B)成分]、及水,(A)成分之含量與(A)成分及(B)成分之合計含量之質量比(A)/[(A)+(B)]超過0.55,且該地板用處理劑組合物於30℃下之pH值為4以上且未達9。< 4 >
A floor treatment agent composition comprising (A) an alkyl glycoside-type surfactant [hereinafter, referred to as (A) component], and optionally (B) a surfactant other than (A) component [hereinafter, Called (B) component], and water, the mass ratio of the content of (A) component to the total content of (A) component and (B) component (A) / [(A) + (B)] exceeds 0.55, and The pH of this floor treatment composition at 30 ° C is 4 or more and less than 9.
<5>
如上述<4>所記載之地板用處理劑組合物,其中(A)成分係碳數較佳為8以上、更佳為10以上且較佳為18以下、更佳為16以下之直鏈或支鏈之烷基,較佳為直鏈之烷基,且係糖之平均縮合度較佳為1以上且較佳為3以下、更佳為2以下、進而較佳為1.5以下之烷基糖苷。< 5 >
The floor treatment agent composition according to the above <4>, in which the (A) component-based carbon number is preferably a straight chain or 8 or more, more preferably 10 or more, and preferably 18 or less, more preferably 16 or less A branched alkyl group is preferably a linear alkyl group, and the average condensation degree of the sugar is preferably an alkyl glycoside of 1 or more and preferably 3 or less, more preferably 2 or less, and further preferably 1.5 or less. .
<6>
如上述<4>或<5>所記載之地板用處理劑組合物,其中(A)成分為下述通式(A1)所表示之化合物。
R1a
(OR2a
)x
Gy
(A1)
[式中,R1a
表示碳數為8以上、較佳為10以上、且為18以下、較佳為16以下、更佳為14以下之直鏈或支鏈之烷基,較佳為直鏈之烷基,R2a
表示碳數2以上4以下之伸烷基、較佳為碳數2之伸烷基,G表示碳數5或6之來自糖之殘基、較佳為來自葡萄糖之殘基,x表示其平均值為0以上且較佳為5以下、更佳為3以下、進而較佳為1以下之數,y表示其平均值為1以上、且3以下、較佳為2以下、更佳為1.5以下之數]< 6 >
The floor treatment agent composition as described in said <4> or <5> whose (A) component is a compound represented by the following general formula (A1).
R 1a (OR 2a ) x G y (A1)
[Wherein R 1a represents a straight-chain or branched alkyl group having a carbon number of 8 or more, preferably 10 or more, and 18 or less, preferably 16 or less, and more preferably 14 or less, and is preferably a straight chain R 2a represents an alkylene group having 2 to 4 carbon atoms, preferably an alkylene group having 2 carbon atoms, and G represents a residue from a sugar group having 5 or 6 carbon atoms, preferably a residue from glucose. Base, x represents a number whose average value is 0 or more and preferably 5 or less, more preferably 3 or less, and further preferably 1 or less, and y represents an average value of 1 or more and 3 or less, preferably 2 or less , More preferably 1.5 or less]
<7>
如上述<4>至<6>中任一項所記載之地板用處理劑組合物,其含有較佳為0.01質量%以上,更佳為0.1質量%以上,進而較佳為1質量%以上,且較佳為50質量%以下,更佳為15質量%以下,進而較佳為10質量%以下,進而更佳為5質量%以下,進而更佳為2.5質量%以下,進而更佳為2質量%以下的(A)成分。< 7 >
The floor treatment composition according to any one of the above <4> to <6>, the content of which is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, and even more preferably 1% by mass or more, It is preferably 50% by mass or less, more preferably 15% by mass or less, still more preferably 10% by mass or less, still more preferably 5% by mass or less, still more preferably 2.5% by mass or less, and even more preferably 2% by mass. (A) component of% or less.
<8>
如上述<4>至<7>中任一項所記載之地板用處理劑組合物,其中(A)成分與(A)成分及(B)成分之合計含量之質量比(A)/[(A)+(B)]較佳為0.6以上,更佳為0.65以上,進而較佳為0.7以上,進而更佳為0.8以上。< 8 >
The floor treatment agent composition according to any one of the above <4> to <7>, wherein the mass ratio (A) / (((A) component to the total content of (A) component and (B) component) A) + (B)] is preferably 0.6 or more, more preferably 0.65 or more, still more preferably 0.7 or more, and still more preferably 0.8 or more.
<9>
如上述<4>至<7>中任一項所記載之地板用處理劑組合物,其中(A)成分與(A)成分及(B)成分之合計含量之質量比(A)/[(A)+(B)]為1。< 9 >
The floor treatment agent composition according to any one of the above <4> to <7>, wherein the mass ratio (A) / (((A) component to the total content of (A) component and (B) component) A) + (B)] is 1.
<10>
如上述<4>至<9>中任一項所記載之地板用處理劑組合物,其中(B)成分含有陽離子界面活性劑[以下,亦稱為(B1)成分]。< 10 >
The floor treatment composition according to any one of the above <4> to <9>, wherein the component (B) contains a cationic surfactant [hereinafter, also referred to as (B1) component].
<11>
如上述<10>所記載之地板用處理劑組合物,其中(B1)成分係具有1個或2個鍵結於氮原子之碳數較佳為8以上且較佳為22以下、更佳為18以下、進而較佳為16以下之烷基,且鍵結於氮原子之剩餘有機基為碳數1以上3以下之短鏈烷基或羥烷基或至多1個苄基的四級銨鹽型陽離子界面活性劑。< 11 >
The floor treatment composition according to the above <10>, in which the component (B1) has one or two carbon atoms bonded to a nitrogen atom, preferably 8 or more and 22 or less, more preferably Alkyl group of 18 or less, and more preferably 16 or less, and the remaining organic group bonded to the nitrogen atom is a short-chain alkyl group or hydroxyalkyl group having 1 to 3 carbon atoms or a quaternary ammonium salt of at most 1 benzyl group Type cationic surfactant.
<12>
如上述<10>或<11>所記載之地板用處理劑組合物,其中(B1)成分係選自二烷基(1個烷基之碳數為8以上18以下)二甲基銨鹽、單烷基(碳數為8以上18以下)三甲基銨鹽、烷基(碳數為8以上18以下)二甲基苄基銨鹽、及苯銨松寧鹽中之1種以上,較佳為烷基(碳數12以上16以下)二甲基苄基銨鹽。< 12 >
The floor treatment composition according to the above <10> or <11>, wherein the component (B1) is a dimethylammonium salt selected from a dialkyl group (the carbon number of one alkyl group is 8 or more and 18 or less), One or more of the monoalkyl (carbon number 8 to 18) trimethylammonium salt, alkyl (carbon number 8 to 18) dimethylbenzylammonium salt, and benzyl ammonium salt Preferred is an alkyl group (carbon number 12 to 16) dimethylbenzyl ammonium salt.
<13>
如上述<10>至<12>中任一項所記載之地板用處理劑組合物,其中(A)成分與(A)成分及(B1)成分之合計含量之質量比(A)/[(A)+(B1)]較佳為超過0.55,更佳為0.6以上,進而較佳為0.65以上,且較佳為0.9以下,更佳為0.8以下,進而較佳為0.7以下。< 13 >
The floor treatment composition according to any one of the above <10> to <12>, wherein the mass ratio (A) / (((A) component to the total content of the (A) component and (B1) component) A) + (B1)] is preferably more than 0.55, more preferably 0.6 or more, still more preferably 0.65 or more, and more preferably 0.9 or less, more preferably 0.8 or less, and still more preferably 0.7 or less.
<14>
如上述<10>至<13>中任一項所記載之地板用處理劑組合物,其中(A)成分之含量與(A)成分及(B2)選自陰離子界面活性劑及除(A)成分以外之非離子界面活性劑中之1種以上之界面活性劑[以下,稱為(B2)成分]之合計含量之質量比(A)/[(A)+(B2)]較佳為0.7以上,更佳為0.8以上,進而較佳為0.9以上,尤佳為0.99以上,且較佳為未達1。< 14 >
The floor treatment composition according to any one of the above <10> to <13>, wherein the content of (A) component, (A) component, and (B2) are selected from anionic surfactants and (A) The mass ratio (A) / [(A) + (B2)] of the total content of one or more surfactants [hereinafter, referred to as (B2) component] among non-ionic surfactants other than ingredients is preferably 0.7 Above, more preferably 0.8 or more, still more preferably 0.9 or more, even more preferably 0.99 or more, and preferably less than 1.
<15>
如上述<10>至<13>中任一項所記載之地板用處理劑組合物,其中(A)成分之含量與(A)成分及(B2)選自陰離子界面活性劑及除(A)成分以外之非離子界面活性劑中之1種以上之界面活性劑[以下,稱為(B2)成分]之合計含量之質量比(A)/[(A)+(B2)]為1。<15>
The floor treatment composition according to any one of the above <10> to <13>, wherein the content of (A) component, (A) component, and (B2) are selected from anionic surfactants and (A) The mass ratio (A) / [(A) + (B2)] of the total content of one or more kinds of non-ionic surfactants other than the ingredients [hereinafter, referred to as (B2) component] is 1.
<16>
如上述<4>至<15>中任一項所記載之地板用處理劑組合物,其進而含有香料作為(C)成分。<16>
The floor treatment agent composition as described in any one of said <4> to <15> which further contains a fragrance | flavor as (C) component.
<17>
如上述<16>所記載之地板用處理劑組合物,其含有較佳為0.01質量%以上,更佳為0.05質量%以上,進而較佳為0.1質量%以上,且較佳為1.5質量%以下,更佳為1質量%以下,進而較佳為0.8質量%以下的(C)成分。< 17 >
The floor treatment composition according to the above <16>, the content thereof is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, still more preferably 0.1% by mass or more, and preferably 1.5% by mass or less. (C) component is more preferably 1% by mass or less, and still more preferably 0.8% by mass or less.
<18>
如上述<16>或<17>所記載之地板用處理劑組合物,其中(C)成分之含量與(A)成分及(B)成分之合計含量之質量比(C)/[(A)+(B)]較佳為0.01以上,更佳為0.05以上,進而較佳為0.1以上,且較佳為1.0以下,更佳為0.8以下,進而較佳為0.4以下。<18>
The floor treatment composition according to the above <16> or <17>, wherein the mass ratio of the content of the component (C) to the total content of the components (A) and (B) is (C) / [(A) + (B)] is preferably 0.01 or more, more preferably 0.05 or more, still more preferably 0.1 or more, and more preferably 1.0 or less, more preferably 0.8 or less, and even more preferably 0.4 or less.
<19>
如上述<4>至<18>中任一項所記載之地板用處理劑組合物,其進而含有溶劑作為(D)成分。< 19 >
The processing agent composition for floors as described in any one of said <4> to <18> which further contains a solvent as (D) component.
<20>
如上述<19>所記載之地板用處理劑組合物,其中(D)成分係於20℃下對水之溶解度為5質量%以上之水溶性溶劑。< 20 >
The floor treatment composition according to the above <19>, wherein the component (D) is a water-soluble solvent having a solubility in water at 20 ° C. of 5% by mass or more.
<21>
如上述<19>或<20>所記載之地板用處理劑組合物,其中(D)成分係選自乙醇、異丙醇、乙二醇、丙二醇、二乙二醇、二丙二醇、甘油、異戊二醇、乙二醇單烷基(碳數4以上8以下)醚、二乙二醇單烷基(碳數4以上8以下)醚、丙二醇單甲醚、丙二醇單乙醚、丙二醇單丙醚、丙二醇單丁醚、二丙二醇烷基(碳數1以上4以下)醚、聚氧乙烯(環氧乙烷平均加成莫耳數1以上5以下)單苯醚及單烷基(碳數3以上8以下)甘油醚中之1種以上之溶劑,較佳為聚氧乙烯(環氧乙烷平均加成莫耳數1以上5以下)單苯醚,更佳為二乙二醇單苯醚或苯氧基乙醇。< 21 >
The floor treatment composition according to the above <19> or <20>, wherein the component (D) is selected from the group consisting of ethanol, isopropanol, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, glycerin, and isopropyl alcohol. Pentylene glycol, ethylene glycol monoalkyl (carbon number 4 to 8) ether, diethylene glycol monoalkyl (carbon number 4 to 8) ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monopropyl ether , Propylene glycol monobutyl ether, dipropylene glycol alkyl (carbon number 1 to 4) ether, polyoxyethylene (average ethylene oxide addition mole number 1 to 5) monophenyl ether and monoalkyl (carbon number 3 One or more solvents in glyceryl ether, preferably polyoxyethylene (average ethylene oxide addition mole number 1 to 5) monophenyl ether, more preferably diethylene glycol monophenyl ether Or phenoxyethanol.
<22>
如上述<19>至<21>中任一項所記載之地板用處理劑組合物,其含有較佳為0.05質量%以上,更佳為0.1質量%以上,進而較佳為0.5質量%以上,且較佳為10質量%以下,更佳為5質量%以下,進而較佳為2質量%以下的(D)成分。< 22 >
The floor treatment composition according to any one of the above <19> to <21>, the content of which is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, and further preferably 0.5% by mass or more, The (D) component is preferably 10% by mass or less, more preferably 5% by mass or less, and even more preferably 2% by mass or less.
<23>
如上述<19>至<21>中任一項所記載之地板用處理劑組合物,其中(D)成分為聚氧乙烯(環氧乙烷平均加成莫耳數1以上5以下)單苯醚,且(D)成分之含量較佳為0.05質量%以上,更佳為0.1質量%以上,進而較佳為0.5質量%以上,且較佳為10質量%以下,更佳為5質量%以下,進而較佳為2質量%以下。< 23 >
The floor treatment composition according to any one of the above <19> to <21>, wherein the component (D) is polyoxyethylene (the average ethylene oxide addition mole number is 1 or more and 5 or less) monobenzene Ether, and the content of the (D) component is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, still more preferably 0.5% by mass or more, and preferably 10% by mass or less, and more preferably 5% by mass or less It is more preferably 2% by mass or less.
<24>
如上述<4>至<23>中任一項所記載之地板用處理劑組合物,其進而含有以酸之形態計,較佳為0.001質量%以上,更佳為0.01質量%以上,且較佳為1質量%以下,更佳為0.5質量%以下,進而較佳為0.1質量%以下的有機酸,較佳為檸檬酸。< 24 >
The floor treatment composition as described in any one of the above <4> to <23>, further containing 0.001% by mass or more, more preferably 0.01% by mass or more in terms of acid, and more preferably It is preferably 1% by mass or less, more preferably 0.5% by mass or less, still more preferably 0.1% by mass or less of an organic acid, and more preferably citric acid.
<25>
如上述<4>至<24>中任一項所記載之地板用處理劑組合物,其進而含有較佳為0.001質量%以上,更佳為0.005質量%以上,且較佳為0.1質量%以下,更佳為0.05質量%以下的無機鹼劑。< 25 >
The floor treatment composition according to any one of the above <4> to <24>, further containing preferably 0.001% by mass or more, more preferably 0.005% by mass or more, and more preferably 0.1% by mass or less The inorganic alkali agent is more preferably 0.05% by mass or less.
<26>
如上述<19>至<25>中任一項所記載之地板用處理劑組合物,其中(A)成分及作為任意成分之(B)成分、(C)成分、及(D)成分之合計含量於除水以外之全部成分中之比率較佳為90質量%以上,更佳為93質量%以上,進而較佳為95質量%以上,且較佳為99.5質量%以下,更佳為99質量%以下,進而較佳為98.5質量%以下。< 26 >
The floor treatment agent composition as described in any one of said <19> to <25>, wherein (A) component and the total of (B) component, (C) component, and (D) component which are arbitrary components The ratio of the content in all components except water is preferably 90% by mass or more, more preferably 93% by mass or more, still more preferably 95% by mass or more, and still more preferably 99.5% by mass or more, and more preferably 99% by mass. % Or less, and more preferably 98.5% by mass or less.
<27>
如上述<4>至<26>中任一項所記載之地板用處理劑組合物,其中(A)成分之含量於除水以外之全部成分中之比率為20質量%以上,進而30質量%以上,進而40質量%以上,進而50質量%以上,且為95質量%以下,進而80質量%以下,進而70質量%以下,進而60質量%以下。< 27 >
The floor treatment composition according to any one of the above <4> to <26>, wherein the ratio of the content of the component (A) to all components except water is 20% by mass or more, and further 30% by mass Above, further 40% by mass or more, further 50% by mass or more, and 95% by mass or less, further 80% by mass or less, further 70% by mass or less, and further 60% by mass or less.
<28>
一種地板面之處理方法,其係將如上述<4>至<27>中任一項所記載之地板用處理劑組合物以利用水稀釋至50倍以上,進而80倍以上,且200倍以下,進而150倍以下所獲得之處理液之形式塗佈於地板面,且使其乾燥。< 28 >
A floor surface treatment method comprising diluting the floor treatment composition according to any one of the above <4> to <27> with water by 50 times or more, and further 80 times or more and 200 times or less. Further, the form of the treatment liquid obtained 150 times or less is applied to the floor surface and allowed to dry.
<29>
一種地板面之處理方法,其係將上述<4>至<27>中任一項所記載之地板用處理劑組合物以利用水稀釋至50倍以上,進而80倍以上,且200倍以下,進而150倍以下所獲得之處理液之形式塗佈於地板面,且不進行濕擦而使其乾燥。< 29 >
A floor surface treatment method comprising diluting the floor treatment composition according to any one of the above <4> to <27> with water by 50 times or more, and further 80 times or more, and 200 times or less, Furthermore, the form of the treatment liquid obtained 150 times or less was applied to the floor surface, and it was dried without wet rubbing.
<30>
一種地板面之處理方法,其係將含有(A)烷基糖苷型界面活性劑[以下,稱為(A)成分]5 ppm以上1000 ppm以下、及水之組合物塗佈於地板並使其乾燥。< 30 >
A floor surface treatment method comprising applying a composition containing (A) an alkyl glycoside surfactant [hereinafter, referred to as (A) component] 5 ppm to 1000 ppm, and water to a floor dry.
<31>
一種地板面之處理方法,其係將含有(A)烷基糖苷型界面活性劑[以下,稱為(A)成分]5 ppm以上1000 ppm以下、及水之組合物塗佈於地板,且不進行濕擦而使其乾燥。< 31 >
A floor surface treatment method comprising applying a composition containing (A) an alkyl glycoside surfactant [hereinafter, referred to as (A) component] 5 ppm to 1,000 ppm, and water to the floor without Wipe to dry.
<32>
如上述<30>或<31>所記載之地板面之處理方法,其係將以使(A)成分之含量成為較佳為50 ppm以上、更佳為100 ppm以上且較佳為500 ppm以下、更佳為200 ppm以下之方式製備之組合物塗佈於地板面。< 32 >
The method for treating a floor surface as described in the above <30> or <31> is such that the content of the component (A) is preferably 50 ppm or more, more preferably 100 ppm or more, and preferably 500 ppm or less The composition prepared in a manner of more preferably 200 ppm or less is coated on the floor surface.
<33>
如上述<30>或<31>所記載之地板面之處理方法,其係以使(A)成分之含量成為5 ppm以上、較佳為50 ppm以上、更佳為100 ppm以上、且為1000 ppm以下、較佳為500 ppm以下、更佳為200 ppm以下之含量之方式,利用水將如上述<4>至<27>中任一項所記載之地板用處理劑組合物進行稀釋,將所獲得之組合物塗佈於地板面。<33>
The method for treating a floor surface as described in the above <30> or <31> is such that the content of the component (A) is 5 ppm or more, preferably 50 ppm or more, more preferably 100 ppm or more, and 1000 In a manner of not more than ppm, preferably not more than 500 ppm, and more preferably not more than 200 ppm, the treatment agent composition for flooring as described in any one of <4> to <27> above is diluted with water, and The obtained composition is applied on a floor surface.
實施例
使用下述調配成分製備表1、2所示之地板用處理劑組合物,且對以下項目進行評估。將結果示於表1、2。表1、2之地板用處理劑組合物按照常規方法進行製備。即,於適量之離子交換水中添加(A)成分、(B)成分、(C)成分、及(D)成分,於室溫(25℃)下使其溶解,其後添加氫氧化鈉或/及檸檬酸一水合物而將pH值(30℃,玻璃電極法)調整為表1、2所示之值。再者,表1、2中之調配成分之質量%全部為基於有效成分之數值。In the examples, the following treatment ingredients were used to prepare the floor treatment composition shown in Tables 1 and 2, and the following items were evaluated. The results are shown in Tables 1 and 2. The floor treatment compositions of Tables 1 and 2 were prepared according to a conventional method. That is, components (A), (B), (C), and (D) are added to an appropriate amount of ion-exchanged water, and they are dissolved at room temperature (25 ° C), and sodium hydroxide or / And citric acid monohydrate to adjust the pH (30 ° C, glass electrode method) to the values shown in Tables 1 and 2. In addition, all the mass% of the blending ingredients in Tables 1 and 2 are numerical values based on active ingredients.
<調配成分>
(A)成分
・AG:烷基糖苷,於通式(A1)中,R1a
為碳數8以上16以下之混合烷基,G為來自葡萄糖之殘基,x為0,y為1.3之化合物
(B)成分
・陽離子界面活性劑1:烷基之碳數為12以上16以下之氯化烷基二甲基苄基銨
(C)成分
・香料a:含有二氫月桂烯醇40質量%、桉葉油25質量%、沉香醇15質量%、巴西酸伸乙酯15質量%、及二氫茉莉酸甲酯5質量%之香料組合物
(D)成分
・苯氧基乙醇:日本乳化劑(股)製造
pH值調整劑
・檸檬酸:檸檬酸一水合物
・氫氧化鈉:48%氫氧化鈉< Mixed ingredients >
(A) Component: AG: An alkyl glycoside. In the general formula (A1), R 1a is a mixed alkyl group having 8 to 16 carbon atoms, G is a residue derived from glucose, x is 0, and y is 1.3.
(B) Component and cationic surfactant 1: Alkyl dimethyl benzyl ammonium chloride having an alkyl group of 12 to 16 carbon atoms
(C) Ingredients and fragrances a: 40% by mass of dihydromyrcenol, 25% by mass of eucalyptus oil, 15% by mass of linalool, 15% by mass of ethyl palmitate, and 5% by mass of methyl dihydrojasmonate Perfume composition
(D) Ingredients and phenoxyethanol: made by Japanese emulsifiers
pH adjuster ・ Citric acid: Citric acid monohydrate ・ Sodium hydroxide: 48% sodium hydroxide
<評估方法>
(1)觸感評估1
於10 cm×10 cm之瓷磚上均勻地塗佈菜籽油(山桂產業股份有限公司)200 μl,於恆溫槽中以90℃加熱150分鐘,將其作為附著有熱改性油之模型污垢。使用硬度調整為5° dH之水將表1之地板用處理劑組合物稀釋至100倍,使所獲得之處理液3 ml含浸於Kimwipe(商品名)中,於附著有熱改性油污垢之瓷磚上僅擦拭1個行程。於處理液乾燥之後,5名熟練之官能檢查員每人用手指各觸摸2次,基於下述評估基準對瓷磚之黏膩感進行評估。將結果示於表1。於表1中,5名熟練之官能檢查員每人根據下述基準各判定2次,求出其平均值並採用。
3分:與利用實施例1之處理液擦拭之部分相同,地板不黏膩且乾爽。
2分:相較於利用實施例1之處理液擦拭之部分,地板有黏膩感。
1分:相較於利用實施例1之處理液擦拭之部分,地板明顯有黏膩感。< Evaluation method >
(1) Tactile evaluation 1
200 μl of rapeseed oil (Sangui Industrial Co., Ltd.) was evenly coated on a 10 cm × 10 cm tile, and heated in a constant temperature bath at 90 ° C. for 150 minutes as a model dirt with thermally modified oil attached. . The water-adjusted hardness of 5 ° dH was used to dilute the treatment composition for flooring of Table 1 to 100 times, and 3 ml of the obtained treatment solution was impregnated in Kimwipe (trade name). Wipe only 1 stroke on the tile. After the treatment liquid was dried, each of five skilled functional inspectors touched twice with their fingers, and evaluated the stickiness of the tiles based on the following evaluation criteria. The results are shown in Table 1. In Table 1, each of the five skilled functional inspectors judged twice based on the following criteria, and the average value was calculated and used.
3 points: Similar to the part wiped with the treatment liquid of Example 1, the floor is not sticky and dry.
2 points: Compared with the part wiped with the treatment liquid of Example 1, the floor has a sticky feeling.
1 point: Compared with the part wiped with the treatment liquid of Example 1, the floor is obviously sticky.
[表1]
(2)觸感評估2
使平時使用市售之地板洗淨劑用拖把濕擦地板之普通女性使用表2之實施例3~5之各地板用處理劑組合物代替平時之地板洗淨劑,並使用1個月(相對於各地板用處理劑組合物各10名)。使用方法係利用自來水將實施例3~5之各地板用處理劑組合物稀釋至100倍,使所獲得之處理液含浸於拖把中,而對地板進行濕擦,於使用1個月後,對於乾燥後之地板之觸感,對回答為「相較於平時之清掃,於清潔後地板不黏膩且乾爽」之人數進行計數。將結果示於表2。(2) Tactile evaluation 2
Ordinary women who wet the floor with a mop mop using a commercially available floor cleaner usually use the floor treatment agent composition of each of the examples 3 to 5 in Table 2 instead of the usual floor cleaner, and use it for 1 month (relatively 10 treatment agents composition for each board). The method of use is to dilute the treatment agent composition for slabs of Examples 3 to 5 to 100 times with tap water, soak the obtained treatment liquid in the mop, and wet the floor. After 1 month of use, The touch of the floor after drying was counted as the number of people who answered, "Compared to usual cleaning, the floor is not sticky and dry after cleaning." The results are shown in Table 2.
[表2]
於表3中,示出本發明之地板用處理劑組合物之調配例。表3中之各調配例於觸感評估1中為2.1分以上,藉由對附著有熱改性油等變性油之地板面僅進行塗佈、乾燥之簡單之處理便可改善地板面之觸感,使其不黏膩且乾爽。Table 3 shows preparation examples of the floor treatment composition of the present invention. Each of the formulation examples in Table 3 is 2.1 or more in the tactile evaluation 1. The floor surface can be improved by applying a simple treatment such as coating and drying to a floor surface to which a modified oil such as a thermally modified oil is attached. It feels non-sticky and dry.
[表3]
於表3中,陽離子界面活性劑2係使用以下者。
陽離子界面活性劑2:烷基之碳數為12之氯化烷基三甲基銨 文件中有使用其他字體,請調整字體(中文字請設定為新細明體、英文字請設定為Times New Roman)。In Table 3, the following were used for the cationic surfactant 2.
Cationic surfactant 2: Other fonts are used in the alkyl trimethylammonium chloride with 12 carbon atoms in the file. Please adjust the font (Chinese characters should be set to new detail style, English characters should be set to Times New Roman).
Claims (8)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2018052306A JP6749959B2 (en) | 2018-03-20 | 2018-03-20 | Floor feel improver |
JP2018-052306 | 2018-03-20 |
Publications (1)
Publication Number | Publication Date |
---|---|
TW201940683A true TW201940683A (en) | 2019-10-16 |
Family
ID=67987134
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW108109512A TW201940683A (en) | 2018-03-20 | 2019-03-20 | Touch improver for floor |
Country Status (6)
Country | Link |
---|---|
JP (1) | JP6749959B2 (en) |
CN (1) | CN111757921A (en) |
MY (1) | MY191105A (en) |
SG (1) | SG11202006584XA (en) |
TW (1) | TW201940683A (en) |
WO (1) | WO2019181601A1 (en) |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3711176B2 (en) * | 1996-06-21 | 2005-10-26 | 旭電化工業株式会社 | Cleaning composition for hard surface |
US7331355B2 (en) * | 2003-10-30 | 2008-02-19 | The Procter & Gamble Company | Floor cleaning and gloss enhancing compositions |
JP5552041B2 (en) * | 2009-12-28 | 2014-07-16 | 花王株式会社 | Cleaning composition for water wiping |
JP5897265B2 (en) * | 2010-04-12 | 2016-03-30 | 花王株式会社 | Disinfecting composition |
JP5666733B2 (en) * | 2013-05-27 | 2015-02-12 | 花王株式会社 | Cleaning composition for hard surface |
TR201809205T4 (en) * | 2013-09-20 | 2018-07-23 | Equator Global Ltd | Fermented fruit solutions for cleaning compositions. |
JP2018030955A (en) * | 2016-08-25 | 2018-03-01 | 株式会社Adeka | Detergent composition and method for cleaning product manufacturing facility |
-
2018
- 2018-03-20 JP JP2018052306A patent/JP6749959B2/en active Active
-
2019
- 2019-03-11 CN CN201980013874.1A patent/CN111757921A/en active Pending
- 2019-03-11 MY MYPI2020004800A patent/MY191105A/en unknown
- 2019-03-11 WO PCT/JP2019/009647 patent/WO2019181601A1/en active Application Filing
- 2019-03-11 SG SG11202006584XA patent/SG11202006584XA/en unknown
- 2019-03-20 TW TW108109512A patent/TW201940683A/en unknown
Also Published As
Publication number | Publication date |
---|---|
MY191105A (en) | 2022-05-30 |
JP2019163393A (en) | 2019-09-26 |
JP6749959B2 (en) | 2020-09-02 |
WO2019181601A1 (en) | 2019-09-26 |
SG11202006584XA (en) | 2020-10-29 |
CN111757921A (en) | 2020-10-09 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US10822576B2 (en) | Low-VOC cleaning substrates and compositions comprising a mixed ethoxy/propoxy alcohol or fatty acid | |
JP5419799B2 (en) | Liquid detergent composition for floors | |
JP5295548B2 (en) | Floor water wiping aid | |
US5156760A (en) | Surface cleaning compositions | |
BRPI0711505A2 (en) | neutral composition for cleaning, cleaning composition and method for cleaning a surface | |
JP5666733B2 (en) | Cleaning composition for hard surface | |
TW201940683A (en) | Touch improver for floor | |
JPH1161199A (en) | Cleansing composition | |
JP5769570B2 (en) | Biofilm remover, biofilm removal composition, and biofilm removal method | |
US11046912B2 (en) | Cleaning solution | |
JP2021088638A (en) | Clean wiping material | |
JP7264735B2 (en) | Hard surface treatment agent composition |