TW201938094A - Cooking apparatus and cooling method that includes a transformer that generates a secondary-side output that is supplied to an antenna immersed in oil/fat to emit an electric field to the oil/fat - Google Patents

Cooking apparatus and cooling method that includes a transformer that generates a secondary-side output that is supplied to an antenna immersed in oil/fat to emit an electric field to the oil/fat Download PDF

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TW201938094A
TW201938094A TW107106983A TW107106983A TW201938094A TW 201938094 A TW201938094 A TW 201938094A TW 107106983 A TW107106983 A TW 107106983A TW 107106983 A TW107106983 A TW 107106983A TW 201938094 A TW201938094 A TW 201938094A
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oil
fat
antenna
transformer
cooking
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TW107106983A
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TWI754014B (en
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木内正人
宮川和夫
川井貴幸
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宮川和夫
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Abstract

An object of the present invention is to provide a cooking apparatus and a cooking method that help prevent deterioration of oil and fat for cooking. [Solution] A cooking apparatus 1 includes an antenna 2 that is arranged in an oil bath 12 in which cooking oil/fat 10 is received to be immersed in the oil/fat, and a transformer 31 that is input with an alternate-current power source at a primary side and supplies an alternate-current power source at a secondary side, with a frequency component of a basic frequency superimposed with a harmonic component. When oil/fat is heated and food is immersed in the oil/fat for cooking, the antenna 2 is immersed in the oil/fat 10 and the secondary side output of the transformer 31 is supplied to the antenna 2 so that an alternate-current electric field emitted from the antenna 2 is applied to the oil/fat 10. As such, oxidation of the oil/fat is suppressed and various matters generated through chemical reactions of glycerin fatty acid ester are reduced to dramatically extend the life time of the oil/fat by more than three times.

Description

調理器具及調理方法Conditioning device and method

本發明係關於將食材浸漬在加溫料理用油脂中進行料理時防止油脂劣化的調理器具及調理方法。The present invention relates to a conditioning device and a conditioning method for preventing the deterioration of fats and oils when the food is immersed in heated cooking fats and oils.

一直以來,利用料理用油脂進行料理的方法係將油脂加熱至120℃到180℃左右,把食材浸漬到油脂中,以進行料理。例如沙拉油等料理用油脂係為以不飽和脂肪酸為主的甘油脂肪酸酯的混合物。就由將其加熱,浸漬食材,並進行料理,可提供天婦羅、炸物等等食品。 隨著料理的持續進行,油脂會慢慢氧化劣化,因而有損風味,最後把劣化的油脂換掉廢棄。具體來說,透過從食材出來的氧、水等等會產生活性氧,經由甘油脂肪酸酯進行化學反應,生成種種物質。例如,產生2-庚炔-1-醇、反,反-2,4-庚二烯-1-醛、9- 癸炔-1-醇、反,反-2,4-壬二烯-1-醛、 反,反-2,4-癸二烯-1-醛、10-十一烯-1-醛、十五酸甲酯、脂肪酸酯等等。這些非所欲的物質會使食品的風味等品質下降。蓄積這些的油脂必須替換掉,並不經濟。因此,為了降低替換油脂的頻率,需要進行種種步驟以抑制上述反應,延長油脂的壽命。例如,已知有把電極插入放油脂的油槽內,試加高頻率(4kHz~25kHz)交流電場給油脂(例如參照專利文獻1)、試加靜電場給油脂(例如參照專利文獻2)。 [習知技術文獻] [專利文獻]Conventionally, the method of cooking with cooking oil is to heat the oil to about 120 ° C to 180 ° C, and immerse the ingredients in the oil to cook. For example, cooking oils such as salad oil are a mixture of glycerin fatty acid esters mainly composed of unsaturated fatty acids. It is heated, dipped in ingredients, and cooked to provide food such as tempura and fried food. As the cooking continues, the fat will gradually oxidize and deteriorate, which will damage the flavor. Finally, the deteriorated fat will be replaced and discarded. Specifically, active oxygen is generated through oxygen, water, and the like coming out of food materials, and chemical reactions are performed through glycerol fatty acid esters to generate various substances. For example, 2-heptyne-1-ol, trans, trans-2,4-heptadiene-1-aldehyde, 9-decyne-1-ol, trans, trans-2,4-nonadiene-1 -Aldehydes, trans, trans-2,4-decadiene-1-aldehyde, 10-undecen-1-aldehyde, methyl pentarate, fatty acid esters and the like. These undesired substances can reduce the quality of food such as flavor. It is not economical to accumulate these greases. Therefore, in order to reduce the frequency of replacing fats and oils, various steps need to be performed to suppress the above reactions and extend the life of the fats and oils. For example, it is known to insert an electrode into an oil tank where grease is put, and try to apply a high-frequency (4 kHz to 25 kHz) AC electric field to the grease (for example, refer to Patent Document 1), and to apply an electrostatic field to the grease (for example, refer to Patent Document 2). [Habitual technical literature] [patent literature]

[專利文獻1] WO2010/073572A1 [專利文獻2] 特開2000-116535號公報[Patent Document 1] WO2010 / 0737352A1 [Patent Document 2] Japanese Patent Laid-Open No. 2000-116355

[發明概要] [發明欲解決的課題][Summary of the Invention] [Problems to be Solved by the Invention]

雖然上述專利文獻1與2所記載的方法就實驗結果而言可以稍微延長油脂的壽命,但無法延長到三倍以上。Although the methods described in the aforementioned Patent Documents 1 and 2 can slightly extend the life of fats and oils in terms of experimental results, they cannot be extended more than three times.

本發明旨在解決上述課題,提供可大幅延長料理用油脂的壽命的調理器具及調理方法。 [解決課題的手段]The present invention aims to solve the above-mentioned problems, and provides a conditioning device and a conditioning method that can significantly extend the life of cooking fats. [Means for solving problems]

為達成上述目的,本發明的調理器具係將食材浸漬在加溫料理用油脂中加熱進行料理的調理器具,其具備浸漬在油脂中的天線、以及一次側輸入交流電源、二次側得到交流電源的基本頻率的頻率成分與其諧波成分的重疊交流輸出的變壓器。變壓器的二次側輸出提供給天線,由天線放射交流電場給油脂。In order to achieve the above object, the conditioning device of the present invention is a conditioning device in which food is immersed in heated cooking fat, and includes an antenna immersed in the fat, an input AC power source on the primary side, and an AC power source on the secondary side. An AC output transformer with a frequency component of the fundamental frequency and its harmonic component overlapping. The secondary output of the transformer is provided to the antenna, and the antenna radiates an AC electric field to the grease.

在上述調理器具中的變壓器較佳在其二次側的交流輸出中,諧波成分的強度隨著更高階次而強度漸減,超過1kHz的頻率成分的強度為第二諧波的1/100以下。In the transformer of the conditioning device, it is preferable that the intensity of the harmonic component gradually decreases with higher order in the AC output of the secondary side. The intensity of the frequency component exceeding 1 kHz is less than 1/100 of the second harmonic. .

此外,在上述調理器具中的變壓器較佳在其一次側和二次側透過電阻相連。In addition, the transformer in the conditioning appliance is preferably connected via a resistor on its primary side and secondary side.

又,在上述調理器具中的天線較佳由導電金屬片所形成,該片的全表面形成絕緣塗層。天線的形狀不特別限定,但可考慮為長方形或正方形的板狀。又,也可以用金屬製的調理容器來做為天線。設置天線的配置不特別限定,但為了從天線放射電磁波的方向可以是金屬表面的法線方向,較佳此方向為油脂存在的配置。The antenna in the conditioning device is preferably formed of a conductive metal sheet, and an insulating coating is formed on the entire surface of the sheet. The shape of the antenna is not particularly limited, but may be a rectangular or square plate shape. Alternatively, a metal conditioning container may be used as the antenna. The arrangement for setting the antenna is not particularly limited, but in order to radiate the electromagnetic wave from the antenna in a direction normal to the metal surface, it is preferable that this direction be a configuration in which grease exists.

又,本發明的調理方法係將食材浸漬在加溫料理用油脂中加熱進行料理的調理方法,使天線浸漬在油脂中,將交流電源的基本頻率的頻率成分與其諧波成分的重疊交流輸出的變壓器的輸出供給至天線,由天線放射交流電場給油脂進行食材的料理。 [發明效果]In addition, the conditioning method of the present invention is a conditioning method in which food is immersed in heated cooking fat, the antenna is immersed in fat, and the frequency component of the basic frequency of the AC power source and its harmonic component are superimposed on the AC output. The output of the transformer is supplied to the antenna, and the antenna radiates an AC electric field to the oil to cook the food. [Inventive effect]

根據本發明,加熱料理用油脂並將食材浸漬到油脂中進行調理時,將100 Hz以下的基本頻率的諧波重疊,將保持在1 kHz以下的頻率的交流電場供應至油脂中。藉此,可抑制油脂的氧化,抑制因甘油脂肪酸酯的化學反應生成種種物質,可跳躍性地(根據實驗結果達3倍以上)延長油脂的壽命。According to the present invention, when cooking cooking oil and fat and immersing ingredients in the oil and conditioning, harmonics of a fundamental frequency of 100 Hz or less are superimposed, and an AC electric field maintained at a frequency of 1 kHz or less is supplied to the oil and fat. Thereby, the oxidation of fats and oils can be suppressed, and various substances generated by the chemical reaction of glycerin fatty acid esters can be suppressed, and the life of fats and oils can be extended (up to three times according to the experimental results).

以下,透過具體化實施型態,參照圖式針對調理器具以及調理方法進行說明。圖1顯示調理器具1的外觀構成。調理器具1係將食材浸漬在加溫料理用油脂中加熱進行料理的物品,透過對料理用油脂10施加交流電場,防止油脂10劣化。此調理器具1於油脂10中施加基本頻率成分與其諧波成分重疊的交流電場,防止油脂10劣化。Hereinafter, a conditioning device and a conditioning method will be described with reference to the drawings through specific implementation forms. FIG. 1 shows the external configuration of the conditioning device 1. The conditioning device 1 is an article in which a food is immersed in warming cooking fat, and an AC electric field is applied to the cooking fat 10 to prevent deterioration of the fat 10. This conditioning device 1 applies an alternating-current electric field in which the fundamental frequency component and its harmonic component overlap in the grease 10 to prevent the grease 10 from deteriorating.

調理器具1具有做為誘發交流電場的電極用的天線2,以及產生使天線2誘發交流電場的交流輸出的驅動源3。驅動源3 具有一次側輸入交流電源32、二次側得到交流電源的基本頻率的頻率成分與其諧波成分的重疊交流輸出的變壓器31。天線2浸漬在油脂10中。調理器具中,驅動源3的輸出,也就是變壓器31的二次側輸出,供給天線2,以施加交流電場至油脂10。變壓器31為二次側主要成分,100 Hz以下的基本頻率成分和其諧波成分重疊的交流輸出中,較佳可得到大多為1kHz以下頻率的交流輸出,若包含超過 1kHz的諧波成分亦無妨。The conditioning device 1 includes an antenna 2 as an electrode for inducing an AC electric field, and a drive source 3 for generating an AC output that causes the antenna 2 to induce an AC electric field. The drive source 3 includes a transformer 31 having an input AC power source 32 on the primary side and an AC output having a frequency component of the basic frequency of the AC power source and a harmonic component on the secondary side. The antenna 2 is immersed in the grease 10. In the conditioning appliance, the output of the driving source 3, that is, the secondary-side output of the transformer 31, is supplied to the antenna 2 to apply an AC electric field to the grease 10. Transformer 31 is the main component of the secondary side. Of the AC output whose basic frequency component below 100 Hz and its harmonic component overlap, it is preferable to obtain an AC output mostly with a frequency below 1 kHz, and it may not matter if it contains harmonic components exceeding 1 kHz. .

根據本實施型態的調理器具1具備具有放入料理用油脂10的油槽12的炸台 11。天線2由導電金屬板所形成,此板的全表面形成絕緣塗層。天線2具有U型彎曲引掛部21,例如在炸台11的側壁11a上緣引掛上引掛部21,使天線2浸漬在油槽12內的油脂10中。天線2透過引掛部21的背面所接合的電性配線線路4電性連接至驅動源3,而連接至變壓器31的二次側。The conditioning apparatus 1 according to this embodiment includes a fryer 11 having an oil tank 12 into which cooking oil 10 is placed. The antenna 2 is formed of a conductive metal plate, and an insulating coating is formed on the entire surface of the plate. The antenna 2 has a U-shaped bent hanging portion 21. For example, the hanging portion 21 is hung on the upper edge of the side wall 11 a of the fryer 11, and the antenna 2 is immersed in the grease 10 in the oil tank 12. The antenna 2 is electrically connected to the driving source 3 through the electric wiring line 4 bonded to the back surface of the hanging portion 21 and is connected to the secondary side of the transformer 31.

變壓器31於一次側輸入交流電源32,其二次側的兩端透過電阻33互相連接,二次側透過線圈34與電性配線線路4以及天線2連接。此外,變壓器31的一次側和二次側透過電阻35互相連接。交流電源32為頻率100Hz以下的交流電源。變壓器31的一次側輸入頻率為交流電源32的100Hz以下的頻率,因此,二次側的交流輸出的頻率為和交流電源32一樣的100Hz以下的頻率。二次側的輸出電壓因應一次側和二次側線圈捲數升壓。The transformer 31 receives an AC power source 32 on the primary side, and both ends of the secondary side are connected to each other through a resistor 33, and the secondary side is connected to the electrical wiring line 4 and the antenna 2 through a coil 34. The primary and secondary sides of the transformer 31 are connected to each other through a resistance 35. The AC power source 32 is an AC power source having a frequency of 100 Hz or less. The input frequency of the primary side of the transformer 31 is a frequency of 100 Hz or less of the AC power source 32. Therefore, the frequency of the AC output of the secondary side is the same frequency of 100 Hz or less as the AC power source 32. The output voltage of the secondary side is boosted according to the number of windings of the primary and secondary coils.

由於變壓器31的一次側和二次側透過電阻35互相連接,兩極間為非對稱構成,二次側的輸出波型會產生歪斜,因此,二次側的交流輸出會得到100Hz以下的基本頻率(交流電源的基本頻率)再疊加上此基本頻率的諧波的交流輸出。此諧波係頻率為基本頻率的整數倍的波,從靠近基本頻率起算順序稱為一次諧波(第一諧波)、二次諧波(第二諧波)、三次諧波(第三諧波)…。這樣的變壓器31的二次側輸出供給至天線2,透過天線2,因變壓器31的二次側輸出誘發出交流電場,因變壓器31的二次側輸出施加交流電場至油脂10。換言之,天線2係以100Hz以下的頻率(交流電源的基本頻率)做為基本頻率的電場,誘發出疊加上此基本頻率的諧波的交流電場,施加此交流電場至油脂10。Because the primary and secondary sides of the transformer 31 are connected to each other through a resistance 35, the two poles are asymmetrically formed, and the output waveform of the secondary side will be skewed. Therefore, the AC output on the secondary side will get a basic frequency of 100 Hz ( The basic frequency of the AC power supply) is superimposed on the harmonic output of the basic frequency. This harmonic is a wave whose frequency is an integer multiple of the fundamental frequency. It is called the first harmonic (the first harmonic), the second harmonic (the second harmonic), and the third harmonic (the third harmonic). wave)…. Such a secondary output of the transformer 31 is supplied to the antenna 2, and an AC electric field is induced by the secondary output of the transformer 31 through the antenna 2, and an AC electric field is applied to the grease 10 by the secondary output of the transformer 31. In other words, the antenna 2 uses a frequency below 100 Hz (the basic frequency of the AC power source) as the electric field of the basic frequency, and induces an AC electric field superimposed with a harmonic of the basic frequency, and applies the AC electric field to the grease 10.

圖3顯示驅動源3的變化例。圖3所顯示的此驅動源3為圖2所示驅動源3之外、在變壓器31的一次側另具備變壓器39。變壓器39於一次側輸入交流電源32,二次側與變壓器31的一次側相連接。變壓器31的一次側輸入為變壓器39的二次側輸出。變壓器39的二次側輸出的頻率也就是變壓器31的一次側輸入的頻率,和交流電源32相同頻率,因此,變壓器31的二次側輸出的頻率和交流電源32一樣是100Hz以下的頻率。變壓器31的二次側輸出電壓因應變壓器39的一次側和二次側的線圈捲數比,以及變壓器31的一次側和二次側的線圈捲數比而升壓。根據此種構成,藉由採用不同的變壓器39的線圈捲數比,調整變壓器31的一次側輸入電壓,可以調整誘發天線2的交流電場的強度。FIG. 3 shows a modified example of the drive source 3. This drive source 3 shown in FIG. 3 is provided with a transformer 39 on the primary side of the transformer 31 in addition to the drive source 3 shown in FIG. 2. The transformer 39 receives an AC power source 32 on the primary side, and the secondary side is connected to the primary side of the transformer 31. The primary input of the transformer 31 is the secondary output of the transformer 39. The frequency of the secondary-side output of the transformer 39 is the frequency of the primary-side input of the transformer 31, which is the same frequency as the AC power source 32. Therefore, the frequency of the secondary-side output of the transformer 31 is the same as the AC power source 32 at a frequency below 100 Hz. The secondary-side output voltage of the transformer 31 is boosted in accordance with the ratio of the number of windings of the primary and secondary sides of the transformer 39 and the ratio of the number of windings of the primary and secondary sides of the transformer 31. According to such a configuration, by adjusting the primary winding input voltage of the transformer 31 by using different coil winding ratios of the transformer 39, the intensity of the AC electric field of the induced antenna 2 can be adjusted.

圖4顯示交流電源32的頻率為60Hz的情況下,變壓器31的二次側交流輸出的頻率特性。交流電源32的頻率為60Hz的情況下,變壓器31的二次側交流輸出包含基本頻率60Hz的頻率成分和60Hz的諧波120Hz, 180Hz, 240Hz等的頻率成分。愈高層的諧波強度漸減,超過1kHz的諧波成分的強度為第二諧波(180Hz)的百分之一以下。視情況而定,第二諧波(180Hz)也可能比第一諧波(120Hz)的強度大,第二諧波強度為第一諧波強度的兩倍以上也有可能。此外,偶數次諧波比奇數次諧波強度大的情況也可存在。此種情況亦屬於技術範圍內。交流電源32的頻率為60Hz的情況,天線2的誘發交流電場為以頻率60Hz做為基本頻率,重疊60Hz的諧波120Hz, 180Hz, 240Hz…的電場,超過1kHz的諧波成分的強度為第二諧波(180Hz)的百分之一以下。FIG. 4 shows the frequency characteristics of the secondary-side AC output of the transformer 31 when the frequency of the AC power source 32 is 60 Hz. When the frequency of the AC power source 32 is 60 Hz, the secondary-side AC output of the transformer 31 includes a frequency component of a basic frequency of 60 Hz and a frequency component of 60 Hz harmonics of 120 Hz, 180 Hz, 240 Hz, and the like. The harmonic intensity of higher layers gradually decreases, and the intensity of harmonic components exceeding 1 kHz is less than one percent of the second harmonic (180 Hz). Depending on the situation, the intensity of the second harmonic (180 Hz) may also be greater than the intensity of the first harmonic (120 Hz), and it is also possible that the intensity of the second harmonic is more than twice the intensity of the first harmonic. In addition, even-order harmonics may be stronger than odd-order harmonics. This situation is also within the technical scope. When the frequency of the AC power source 32 is 60 Hz, the induced AC electric field of the antenna 2 is an electric field with the frequency of 60 Hz as the basic frequency and the harmonics of the 60 Hz harmonics 120 Hz, 180 Hz, 240 Hz ... The intensity of the harmonic component exceeding 1 kHz is the second Harmonic (180Hz) is less than one percent.

又,交流電源32的頻率不限於60Hz,亦可為100Hz以下的任意頻率。例如流電源32的頻率為50Hz的情況時,變壓器31的二次側交流輸出包含基本頻率50Hz的頻率成分和50Hz的諧波100Hz, 150Hz, 200Hz等的頻率成分。愈高層的諧波強度漸減,超過1kHz的諧波成分的強度為第二諧波(150Hz)的百分之一以下。視情況而定,第二諧波(150Hz)也可能比第一諧波(100Hz)的強度大,第二諧波強度為第一諧波強度的兩倍以上也有可能。此外,偶數次諧波比奇數次諧波強度大的情況也可存在。此種情況亦屬於技術範圍內。交流電源32的頻率為50Hz的情況,天線2的誘發交流電場為以頻率50Hz做為基本頻率,重疊50Hz的諧波100Hz, 150Hz, 200Hz…的電場,超過1kHz的諧波成分的強度為第二諧波(150Hz)的百分之一以下。The frequency of the AC power source 32 is not limited to 60 Hz, and may be any frequency below 100 Hz. For example, when the frequency of the current source 32 is 50 Hz, the secondary-side AC output of the transformer 31 includes a frequency component of a basic frequency of 50 Hz and a frequency component of a 50 Hz harmonic such as 100 Hz, 150 Hz, and 200 Hz. The harmonic intensity of higher layers gradually decreases, and the intensity of harmonic components exceeding 1 kHz is less than one percent of the second harmonic (150 Hz). Depending on the situation, the intensity of the second harmonic (150 Hz) may also be greater than the intensity of the first harmonic (100 Hz), and it is also possible that the intensity of the second harmonic is more than twice the intensity of the first harmonic. In addition, even-order harmonics may be stronger than odd-order harmonics. This situation is also within the technical scope. When the frequency of the AC power source 32 is 50Hz, the induced AC electric field of the antenna 2 is an electric field with the frequency of 50Hz as the basic frequency and the harmonics of 50Hz, 100Hz, 150Hz, 200Hz, etc., and the intensity of harmonic components exceeding 1kHz is the second. Harmonics (150Hz) are less than one percent.

針對利用本實施例型態的調理器具1進行料理的實施例,以及以無施加交流電場至油脂10的調理器具進行料理的比較例,調查油脂10的劣化情形。其結果如下所示。 [實施例 1]Regarding the example of cooking using the conditioning device 1 of this embodiment and the comparative example of cooking using a conditioning device without applying an AC electric field to the grease 10, the deterioration of the grease 10 was investigated. The results are shown below. [Example 1]

將圖1所示的天線2設置在如圖2所示的可投入4L(公升)料理用油脂10的炸台11的油槽12內,投入60Hz交流電力至交流電源32,使來自天線2的交流電場呈現放射狀。天線的主要部分為15cm×20cm的大小,厚度為1mm。從天線2放射狀分布的交流電場所誘發的磁場,1kHz以下為15微特斯拉,1kHz以上為0.3微特斯拉。將3.5L油脂10 (本實施例中為沙拉油)投入油槽12中,加熱油脂10至180℃。將天線2浸漬在油脂10中,從天線2放射交流電場至油脂10中。換言之,油脂10中施加有60Hz的基本頻率上疊加此基本頻率的諧波,且超過1kHz的諧波成分的強度為第二諧波的百分之一以下的交流電場。在180℃加熱油脂10中,依照以下方式依序投入冷凍食品進行料理。對春捲(1Kg)、一口豬排 (500g)、紫蘇梅雞 (1Kg)、馬鈴薯條(1Kg)、洋蔥圈(500g) 、 脆皮雞(1Kg)、炸蝦(300g) 、炸沙丁魚(600g)進行炸物料理。針對料理後的油脂10中所生成的物質及其生成量,以氣相層析分析裝置以及氣相層析質量分析裝置進行測定。其測定結果如表1 (施加交流電場進行料理的油脂中所生成的物質及其量) 所示。The antenna 2 shown in FIG. 1 is installed in the oil tank 12 of the fryer 11 that can be filled with 4 L (liters) of cooking oil 10 as shown in FIG. 2, and 60 Hz AC power is input to the AC power source 32 so that the AC from the antenna 2 is AC. The electric field is radial. The main part of the antenna is 15cm × 20cm, and the thickness is 1mm. The magnetic field induced from the alternating current field distributed radially by the antenna 2 is 15 microtesla below 1 kHz and 0.3 microtesla above 1 kHz. 3.5 L of grease 10 (salad oil in this example) is put into the oil tank 12 and the grease is heated to 10 to 180 ° C. The antenna 2 is immersed in the grease 10, and an AC electric field is radiated from the antenna 2 into the grease 10. In other words, an alternating-current electric field with a harmonic of this fundamental frequency superimposed on a fundamental frequency of 60 Hz is applied to the grease 10, and the intensity of the harmonic component exceeding 1 kHz is less than one percent of the second harmonic. The heated fats and oils 10 were heated at 180 ° C., and the frozen food was sequentially prepared in the following manner for cooking. Spring rolls (1Kg), bite pork chops (500g), shimeji chicken (1Kg), potato strips (1Kg), onion rings (500g), crispy chicken (1Kg), fried shrimp (300g), fried sardines (600g) Fried dishes. The substances produced in the fat 10 after cooking and the amounts of the substances produced were measured by a gas chromatography analysis device and a gas chromatography mass analysis device. The measurement results are shown in Table 1 (substances and amounts produced in fats and oils cooked by applying an AC electric field).

表 1 Table 1

測定的結果檢出2-庚炔-1-醇、反,反-2,4-庚二烯-1-醛、9- 癸炔-1-醇、反,反-2,4-壬二烯-1-醛、 反,反-2,4-癸二烯-1-醛、10-十一烯-1-醛、十五酸甲酯、兩種脂肪酸酯,這些物質的生成量如表1所示。這些物質為非包含在原本油脂10中的物質,是因為油脂10劣化所生成的劣化物質。 [比較例 1]As a result of the measurement, 2-heptyn-1-ol, trans, trans-2,4-heptadiene-1-aldehyde, 9-decyn-1-ol, trans, trans-2,4-nonadiene were detected -1-aldehyde, trans, trans-2,4-decadiene-1-aldehyde, 10-undecene-1-aldehyde, methyl pentadecanoate, two fatty acid esters, the production amounts of these substances are shown in the table 1 is shown. These substances are substances which are not contained in the original fats and oils 10 and are degraded substances generated by the deterioration of the fats and oils 10. [Comparative Example 1]

和實施例1相同,在油槽12內設置如圖2所示的調理器具1的天線2。不在交流電源32中投入電力,沒有交流電場從天線2放射出的情形。此外,和實施例1一樣,將3.5L油脂10投入油槽12中,加熱油脂10至180℃。因為沒有在交流電源32中投入電力,沒有電場施加至油脂10中。和實施例1一樣,在180℃加熱油脂10中依序投入冷凍食品進行料理。對料理後的油脂10中所生成的物質及其生成量進行測定。其測定結果如表2 (無施加交流電場進行料理的油脂中所生成的物質及其量) 所示。As in Embodiment 1, an antenna 2 of the conditioning instrument 1 shown in FIG. 2 is provided in the oil tank 12. No power is input to the AC power source 32 and no AC electric field is emitted from the antenna 2. In addition, as in Example 1, 3.5 L of grease 10 was put into the oil tank 12 and the grease 10 was heated to 180 ° C. Since no power is input to the AC power source 32, no electric field is applied to the grease 10. In the same manner as in Example 1, frozen food was sequentially put into the fat and oil 10 heated at 180 ° C. for cooking. The substances produced in the fats and oils 10 after cooking and the amounts thereof were measured. The measurement results are shown in Table 2 (Substances and amounts produced in fats and oils cooked without applying an AC electric field).

表 2 Table 2

測定的結果檢出2-庚炔-1-醇、反,反-2,4-庚二烯-1-醛、9- 癸炔-1-醇、反,反-2,4-壬二烯-1-醛、 反,反-2,4-癸二烯-1-醛、10-十一烯-1-醛、十五酸甲酯、兩種脂肪酸酯,這些物質的生成量如表2所示。As a result of the measurement, 2-heptyn-1-ol, trans, trans-2,4-heptadiene-1-aldehyde, 9-decyn-1-ol, trans, trans-2,4-nonadiene were detected -1-aldehyde, trans, trans-2,4-decadiene-1-aldehyde, 10-undecene-1-aldehyde, methyl pentadecanoate, two fatty acid esters, the production amounts of these substances are shown in the table 2 shown.

圖5顯示實施例1(表1,交流電場on)和比較例1(表2,交流電場off)中,油脂10中所生成各劣化物質的生成量的比較結果。實施例1和比較例1相較之下,對於全部的劣化物質而言,實施例1中的生成量都不到比較例1中生成量的三分之一。因此,根據實施例1,抑制了料理用油脂10的劣化,油脂10的壽命可延長三倍以上。 [實施例 2]FIG. 5 shows a comparison result of the amount of each degraded substance generated in the grease 10 in Example 1 (Table 1, AC electric field on) and Comparative Example 1 (Table 2, AC electric field off). In comparison with Example 1 and Comparative Example 1, the production amount in Example 1 is less than one-third of the production amount in Comparative Example 1 for all the degraded substances. Therefore, according to Example 1, the deterioration of the cooking fat 10 is suppressed, and the life of the fat 10 can be extended three times or more. [Example 2]

將圖1所示的天線2設置在如圖3所示的可投入4L料理用油脂10的炸台11的油槽12內,投入50Hz交流電力至交流電源32,使來自天線2的交流電場呈現放射狀。天線的主要部分為15cm×20cm的大小,厚度為1mm。從天線2放射狀分布的交流電場所誘發的磁場,1kHz以下為13微特斯拉,1kHz以上為0.2微特斯拉。將3L油脂10 (本實施例中為沙拉油)投入油槽12中,加熱油脂10至170℃。將天線2浸漬在油脂10中,從天線2放射交流電場至油脂10中。換言之,油脂10中施加有50Hz的基本頻率上疊加此基本頻率的諧波,且超過1kHz的諧波成分的強度為第二諧波的百分之一以下的交流電場。在170℃加熱油脂10中不投入食品,以0.8L/分的比例進行空氣打氣。每30分鐘採取微量油脂10,對油脂10中的劣化物質2,4-癸二烯-1-醛 的生成量,以氣相層析分析裝置進行測定。其測定結果如圖6 (施加交流電場加熱沙拉油與進行空氣打氣時的2,4-癸二烯-1-醛 的生成量) 所示。測定結果顯示2,4-癸二烯-1-醛 的生成量隨時間經過上升,12小時後達到最大濃度。The antenna 2 shown in FIG. 1 is installed in the oil tank 12 of the fryer 11 that can be filled with 4 L of cooking oil 10 as shown in FIG. shape. The main part of the antenna is 15cm × 20cm, and the thickness is 1mm. The magnetic field induced from the alternating current field distributed radially by the antenna 2 is 13 micro Tesla below 1 kHz and 0.2 micro Tesla above 1 kHz. 3 L of grease 10 (salad oil in this example) is put into the oil tank 12 and the fat is heated to 10 to 170 ° C. The antenna 2 is immersed in the grease 10, and an AC electric field is radiated from the antenna 2 into the grease 10. In other words, an AC electric field with a harmonic of this fundamental frequency superimposed on a basic frequency of 50 Hz is applied to the grease 10, and the intensity of the harmonic component exceeding 1 kHz is less than one percent of the second harmonic. The food was not heated in the oil and fat 10 heated at 170 ° C., and air was inflated at a rate of 0.8 L / min. A trace amount of oil and fat 10 was taken every 30 minutes, and the amount of 2,4-decadiene-1-aldehyde produced as a degraded substance in the oil and fat 10 was measured with a gas chromatography analysis device. The measurement results are shown in Fig. 6 (the amount of 2,4-decadien-1-aldehyde produced when an electric field is applied to heat salad oil and air is inflated). The measurement results showed that the amount of 2,4-decadiene-1-aldehyde increased with time, and reached the maximum concentration after 12 hours.

和實施例2相同,在油槽12內設置如圖3所示的調理器具1的天線2。不在交流電源32中投入電力,沒有交流電場從天線2放射出的情形。此外,和實施例2一樣,將3L油脂10投入油槽12中,加熱油脂10至170℃。因為沒有在交流電源32中投入電力,沒有電場施加至油脂10中。和實施例2一樣,在170℃加熱油脂10中不投入食品,以0.8L/分的比例進行空氣打氣。每30分鐘採取微量油脂10,對油脂10中的2,4-癸二烯-1-醛 的生成量,以氣相層析分析裝置進行測定。其測定結果如圖7(無施加交流電場加熱沙拉油與進行空氣打氣時的2,4-癸二烯-1-醛 的生成量) 所示。測定結果顯示2,4-癸二烯-1-醛 的生成量隨時間經過上升,4小時後達到最大濃度。As in the second embodiment, the antenna 2 of the conditioning instrument 1 shown in FIG. 3 is provided in the oil tank 12. No power is input to the AC power source 32 and no AC electric field is emitted from the antenna 2. In addition, as in Example 2, 3 L of grease 10 was put into the oil tank 12 and the grease was heated to 10 to 170 ° C. Since no power is input to the AC power source 32, no electric field is applied to the grease 10. As in Example 2, food was not heated in the oil and fat 10 heated at 170 ° C, and air was inflated at a rate of 0.8 L / min. A trace amount of oil and fat 10 was collected every 30 minutes, and the amount of 2,4-decadiene-1-aldehyde produced in the oil and fat 10 was measured with a gas chromatography analyzer. The measurement results are shown in Fig. 7 (the amount of 2,4-decadiene-1-aldehyde produced when the salad oil is heated without applying an AC electric field and air is inflated). The measurement results showed that the amount of 2,4-decadiene-1-aldehyde increased with time, and reached the maximum concentration after 4 hours.

實施例2(圖6,交流電場on)和比較例2(圖7,交流電場off)比較,油脂10中所生成2,4-癸二烯-1-醛的生成量達到最大濃度的時間,實施例2為12小時後,而相較之下,比較例2為4小時後,實施例2一方比比較例2慢三倍。因此,根據實施例2,抑制了料理用油脂10的劣化,油脂10的壽命可延長三倍以上。Compared with Example 2 (Fig. 6, AC electric field on) and Comparative Example 2 (Fig. 7, AC electric field off), the time when the amount of 2,4-decadiene-1-aldehyde produced in the fat 10 reaches the maximum concentration, Example 2 was 12 hours later, and Comparative Example 2 was 4 hours later, and Example 2 was three times slower than Comparative Example 2. Therefore, according to Example 2, the deterioration of the cooking fat 10 is suppressed, and the life of the fat 10 can be extended three times or more.

在實施例1與實施例2中,抑制料理用油脂10劣化的作用機制不明,但實驗結果可判別此效果的再現性。認為透過施加100Hz以下基本頻率並疊加此基本頻率的諧波,且超過1kHz的諧波成分的強度為第二諧波的百分之一以下的交流電場,會有抑制高溫的油脂10中的氧自由基的生成以及反應的效果。In Examples 1 and 2, the action mechanism for suppressing the deterioration of the cooking fat 10 is unknown, but experimental results can determine the reproducibility of this effect. It is thought that by applying a basic frequency below 100 Hz and superimposing a harmonic of this basic frequency, and an alternating-current electric field having an intensity of harmonic components exceeding 1 kHz to be less than one percent of the second harmonic, there will be suppression of oxygen in the high-temperature grease 10 The generation of free radicals and the effects of reactions.

根據本實施例,加熱油脂10,將食材浸漬在油脂10中進行料理時,施加100Hz以下基本頻率並疊加此基本頻率的諧波,且超過1kHz的諧波成分的強度為第二諧波的百分之一以下的交流電場,可抑制甘油脂肪酸酯的化學反應所致種種物質(例如2-庚炔-1-醇、反,反-2,4-庚二烯-1-醛、9- 癸炔-1-醇、反,反-2,4-壬二烯-1-醛、 反,反-2,4-癸二烯-1-醛、10-十一烯-1-醛、十五酸甲酯、脂肪酸酯等)的生成。藉此,油脂10的壽命可跳躍式地大幅延長三倍以上。According to this embodiment, when heating the fat 10 and immersing the ingredients in the fat 10 for cooking, a fundamental frequency below 100 Hz is applied and the harmonics of the fundamental frequency are superimposed, and the intensity of the harmonic components exceeding 1 kHz is 100% of the second harmonic. An AC electric field of less than one part can inhibit various substances caused by the chemical reaction of glycerol fatty acid esters (such as 2-heptyn-1-ol, trans, trans-2,4-heptadiene-1-aldehyde, 9- Decyne-1-ol, trans, trans-2,4-nonadien-1-aldehyde, trans, trans-2,4-decadiene-1-aldehyde, 10-undecene-1-aldehyde, ten Methyl pentanoate, fatty acid ester, etc.). As a result, the life of the grease 10 can be significantly extended by three times or more.

又,本發明不限於上述實施型態,可以有種種變形。例如,天線2可以全體浸漬在油脂10中,也可以例如水平配置在油槽12的底面。又,油脂10不限於沙拉油,其它料理用油脂也可適用。In addition, the present invention is not limited to the above-mentioned embodiments, and can be variously modified. For example, the entire antenna 2 may be immersed in the grease 10 or may be horizontally arranged on the bottom surface of the oil tank 12, for example. The fats and oils 10 are not limited to salad oil, and other cooking fats and oils can also be applied.

1‧‧‧調理器具‧‧‧ conditioning equipment

2‧‧‧天線2‧‧‧ antenna

3‧‧‧驅動源‧‧‧Drive source

4‧‧‧電性配線線路4‧‧‧ electric wiring

10‧‧‧油脂10‧‧‧ grease

12‧‧‧油槽12‧‧‧ oil tank

31‧‧‧變壓器31‧‧‧Transformer

【圖1】(a)為顯示本發明一實施型態的調理器具的大致構成的立體圖;(b)為同一調理器具的天線的立體圖;(c)為(a)的A-A線剖面圖。 【圖2】為同一調理器具的電子電路圖。 【圖3】為顯示同一調理器具的變形例的電子電路圖。 【圖4】為顯示同一調理器具的變壓器的二次側輸出的頻率特性圖。 【圖5】顯示利用同一調理器具進行料理的實施例和利用不對油脂施加交流電場的調理器具進行料理的比較例中,油脂中生成各種劣化物質的生成量的比較結果。 【圖6】顯示利用同一調理器具進行料理的實施例的油脂中,2,4-癸二烯-1-醛的生成量思維時間的變化。 【圖7】顯示不對油脂施加交流電場的調理器具進行料理的比較例中,2,4-癸二烯-1-醛的生成量思維時間的變化。[Fig. 1] (a) is a perspective view showing a schematic configuration of a conditioning device according to an embodiment of the present invention; (b) is a perspective view of an antenna of the same conditioning device; (c) is a sectional view taken along the line AA of (a) . [Figure 2] Electronic circuit diagram of the same conditioning appliance. [Fig. 3] An electronic circuit diagram showing a modification of the same conditioning device. [Fig. 4] is a frequency characteristic diagram showing the secondary output of a transformer of the same conditioning appliance. [Fig. 5] Comparison results of examples of cooking using the same conditioning device and comparative examples of cooking using a conditioning device that does not apply an AC electric field to fats and oils are shown. [Fig. 6] Fig. 6 shows the change in thinking time of the amount of 2,4-decadien-1-aldehyde produced in the oil and fat of the example in which the same conditioning apparatus was used for cooking. [Fig. 7] In a comparative example in which a conditioning device that does not apply an AC electric field to oils and fats is shown, the amount of 2,4-decadiene-1-aldehyde produced is thought to change over time.

Claims (5)

一種將食材浸漬在加溫料理用油脂中加熱進行料理的調理器具,包括: 浸漬在油脂中的天線,以及 一次側輸入交流電源、二次側得到交流電源的基本頻率的頻率成分與其諧波成分的重疊交流輸出的變壓器; 上述變壓器的二次側輸出提供給天線,由天線放射交流電場給油脂。A conditioner for immersing food ingredients in heated cooking oil for cooking, including: an antenna immersed in oil and fat, and a frequency component and a harmonic component of a basic frequency of an input AC power source on a primary side and an AC power source on a secondary side. A transformer with overlapping AC output; the secondary side output of the transformer is provided to an antenna, and the antenna radiates an AC electric field to the grease. 如請求項1所記載的調理器具,在變壓器的二次側的交流輸出中,諧波成分的強度隨著更高階次而強度漸減,超過1kHz的頻率成分的強度為第二諧波的1/100以下。The conditioning device according to claim 1, in the AC output of the secondary side of the transformer, the intensity of the harmonic component gradually decreases with a higher order, and the intensity of the frequency component exceeding 1 kHz is 1 / of the second harmonic. 100 or less. 如請求項1或請求項2所記載的調理器具,上述變壓器的一次側和二次側透過電阻相連。In the conditioning device according to claim 1 or claim 2, the primary side and the secondary side of the transformer are connected through a resistor. 如請求項1至請求項3中任一項所記載的調理器具,上述天線由導電金屬片所形成,該片的全表面形成絕緣塗層。In the conditioning appliance according to any one of claim 1 to claim 3, the antenna is formed of a conductive metal sheet, and an insulating coating is formed on the entire surface of the sheet. 一種將食材浸漬在加溫料理用油脂中加熱進行料理的調理方法,包括: 使天線浸漬在油脂中; 將交流電源的基本頻率的頻率成分與其諧波成分的重疊交流輸出的變壓器的輸出供給至天線;以及 由上述天線放射交流電場給油脂,以進行食材的料理。A conditioning method for immersing food ingredients in heated cooking oil for cooking, comprising: immersing an antenna in the oil; and supplying an output of a transformer in which an AC output of a frequency component of a basic frequency of an AC power source and a harmonic component overlap with each other to an AC output. An antenna; and an AC electric field radiated from the antenna to the grease for cooking ingredients.
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