TW201929807A - Absorbent article - Google Patents

Absorbent article Download PDF

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Publication number
TW201929807A
TW201929807A TW107142294A TW107142294A TW201929807A TW 201929807 A TW201929807 A TW 201929807A TW 107142294 A TW107142294 A TW 107142294A TW 107142294 A TW107142294 A TW 107142294A TW 201929807 A TW201929807 A TW 201929807A
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Taiwan
Prior art keywords
fiber
absorbent
absorbent article
fibers
article according
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TW107142294A
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Chinese (zh)
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TWI745639B (en
Inventor
金子将也
湯山暁
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日商花王股份有限公司
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Publication of TW201929807A publication Critical patent/TW201929807A/en
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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/53Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/53Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium
    • A61F13/534Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad
    • A61F13/535Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad inhomogeneous in the plane of the pad, e.g. core absorbent layers being of different sizes
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/53Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium
    • A61F13/534Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad
    • A61F13/537Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad characterised by a layer facilitating or inhibiting flow in one direction or plane, e.g. a wicking layer
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/53Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium
    • A61F13/538Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium characterised by specific fibre orientation or weave
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F5/00Orthopaedic methods or devices for non-surgical treatment of bones or joints; Nursing devices; Anti-rape devices
    • A61F5/44Devices worn by the patient for reception of urine, faeces, catamenial or other discharge; Portable urination aids; Colostomy devices

Abstract

This absorbent article (1) is provided with an absorbent body (4) and a surface sheet (2) arranged on the skin-facing surface side of the absorbent body (4). The absorbent body (4) is configured by including an absorbent core (40) that exhibits liquid absorbency, and a core wrapping sheet (41) that covers the skin-facing surface of the absorbent core (40). The absorbent core (40) includes a water-absorbing fiber (12F) and fiber lumps (11) including fibers (11F) that exhibits a weak water-absorbency which is weaker than that of the water-absorbing fiber (12F). The ratio between the liquid diffusion surface area of the absorbent core (40) and the liquid diffusion surface area of the core wrapping sheet (41), namely, the former over the latter, is at least 0.7.

Description

吸收性物品Absorbent article

本發明係關於一種經期衛生棉等吸收性物品。The present invention relates to an absorbent article such as menstrual sanitary napkin.

一般而言,拋棄式尿布、經期衛生棉等吸收性物品包含配置於相對接近穿著者之肌膚之位置之正面片材、配置於相對遠離穿著者之肌膚之位置之背面片材、及介介置於兩片材間之吸收體而構成。典型而言,該吸收體包含構成該吸收體之主體之吸收性芯體、及被覆該吸收性芯體之表面之包芯片材,該吸收性芯體多數情況下以木漿等吸水性纖維為主體,進而包含吸水性聚合物粒子而構成。關於用於吸收性物品之吸收體,柔軟性(緩衝性)、壓縮回覆性、保形性等各特性之提高為較大之課題。In general, absorbent articles such as disposable diapers and menstrual sanitary napkins include a front sheet disposed relatively close to the wearer's skin, a back sheet disposed relatively far from the wearer's skin, and an interposition It is composed of an absorber between two sheets. Typically, the absorbent body includes an absorbent core that constitutes the main body of the absorbent body, and a core-wrap material covering the surface of the absorbent core. In many cases, the absorbent core is made of water-absorbent fibers such as wood pulp. The main body is further composed of water-absorbing polymer particles. Regarding absorbers used for absorbent articles, improvement of various characteristics such as flexibility (buffering properties), compression responsiveness, and shape retention is a major issue.

作為吸收體之改良技術,例如,專利文獻1中記載有一種吸收體,其含有熱塑性樹脂纖維及纖維素系吸水性纖維,該熱塑性樹脂纖維於該吸收體之正面片材側之表面及該吸收體之背面片材側之表面之兩者露出。根據專利文獻1所記載之吸收體,熱塑性樹脂纖維作為用以保持纖維素系吸水性纖維等該吸收體之其他成分之骨架而發揮功能,故而較柔軟且不易褶皺。As an improved technique of the absorber, for example, Patent Document 1 describes an absorber containing thermoplastic resin fibers and cellulose-based water-absorbing fibers, the thermoplastic resin fibers on the surface of the absorber on the front sheet side and the absorber Both surfaces of the back sheet side of the body are exposed. According to the absorber described in Patent Document 1, the thermoplastic resin fibers function as a framework for holding other components of the absorber such as cellulose-based water-absorbing fibers, so they are relatively soft and are less likely to wrinkle.

又,專利文獻2中記載有一種吸收體,其含有包含熱熔纖維且預先使纖維間結合而賦予三維構造之不織布片、及吸水性纖維。該三維構造之不織布片使用切碎機粉碎方式等粉碎方法將不織布粉碎為碎片狀而製造,故而因該製造方法,而導致其如同一文獻之圖1及圖3中所記載般呈不定形狀,實質上不具有視為平面之部分。於專利文獻2中,作為同一文獻中記載之吸收體之較佳之形態,記載有使不織布片彼此熱熔而成者。根據專利文獻2所記載之吸收體,不織布片具有三維構造,故而於該吸收體內部形成有空隙,吸收水分時之恢復性提高,其結果為,吸水性能提高。In addition, Patent Document 2 describes an absorber including a non-woven fabric sheet including hot-melt fibers and previously bonded between fibers to give a three-dimensional structure, and water-absorbent fibers. The non-woven fabric piece of this three-dimensional structure is manufactured by pulverizing the non-woven fabric into pieces by a crushing method such as a shredder crushing method. Therefore, due to this manufacturing method, it has an indefinite shape as described in FIGS. Substantially does not have what is considered a plane. In Patent Document 2, as a preferred form of the absorber described in the same document, there is described a case where non-woven fabric sheets are thermally fused with each other. According to the absorber described in Patent Document 2, since the nonwoven fabric sheet has a three-dimensional structure, voids are formed inside the absorber, and the recovery when absorbing moisture is improved. As a result, the water absorption performance is improved.

又,專利文獻3中記載有具有相對較稠密之微細纖維核、及自該核向外側延出之纖維或纖維束之微細纖維網,又,記載有,將該微細纖維網與木漿或吸水性聚合物粒子混合而成之不織纖維網可用作吸收性物品用之吸收體。該微細纖維網係將不織布等原料片材揪下或撕下而製造,與專利文獻2所記載之不織布片同樣地呈不定形狀,實質上不具有視為平面之部分。In addition, Patent Document 3 describes a fine fiber web having a relatively dense fine fiber core and fibers or fiber bundles extending outward from the core, and further describes that the fine fiber core is combined with wood pulp or water absorption The nonwoven web made of mixed polymer particles can be used as an absorbent body for absorbent articles. This fine fiber web is produced by pulling or tearing a raw material sheet such as a nonwoven fabric, and has an indefinite shape like the nonwoven fabric sheet described in Patent Document 2, and does not substantially have a portion that is regarded as a plane.

又,專利文獻4中記載有,於吸收體含有吸水性聚合物之情形時,若該吸收體吸收液體而膨脹,則因配置於該吸收體之上下之正面片材及背面片材之密封而妨礙該吸水性聚合物之膨潤,為了解決該問題,使具有高壓縮/壓縮回覆性及液體透過性之緩衝層介置於正面片材與吸收體之間,又,記載有作為不織布之碎片之集合體而構成該緩衝層、及將緩衝層之厚度設為10~40 mm。於專利文獻4中,關於用於緩衝層之不織布之碎片之形狀等,並未具體記載。
[先前技術文獻]
[專利文獻]
In addition, Patent Document 4 describes that when the absorbent body contains a water-absorbing polymer, if the absorbent body absorbs liquid and swells, it is sealed by the front sheet and the back sheet disposed above and below the absorbent body To prevent swelling of the water-absorbing polymer, in order to solve this problem, a buffer layer with high compression / compression response and liquid permeability is interposed between the front sheet and the absorber, and it is described as fragments of non-woven fabric The aggregate constitutes the buffer layer, and the thickness of the buffer layer is 10 to 40 mm. In Patent Document 4, the shape and the like of the fragments of the non-woven fabric used for the buffer layer are not specifically described.
[Prior Technical Literature]
[Patent Literature]

[專利文獻1]日本專利特開2015-16296號公報
[專利文獻2]日本專利特開2002-301105號公報
[專利文獻3]日本專利特開平1-156560號公報
[專利文獻4]日本專利特開2003-52750號公報
[Patent Document 1] Japanese Patent Laid-Open No. 2015-16296
[Patent Document 2] Japanese Patent Laid-Open No. 2002-301105
[Patent Document 3] Japanese Patent Laid-Open No. 1-156560
[Patent Document 4] Japanese Patent Laid-Open No. 2003-52750

本發明係關於一種吸收性物品,其具有與穿著者之前後方向對應之縱向及與其正交之橫向,且具備吸收體、及配置於該吸收體之肌膚對向面側之正面片材。上述吸收體包含液體吸收性之吸收性芯體、及被覆該吸收性芯體之肌膚對向面之包芯片材而構成,該吸收性芯體包含:吸水性纖維;及纖維塊,其包含吸水性低於該吸水性纖維之弱吸水性之纖維。由下述方法測得之上述吸收性芯體之液體擴散面積與由下述方法測得之上述包芯片材之液體擴散面積之比率以前者/後者計為0.7以上。The present invention relates to an absorbent article having a longitudinal direction corresponding to the front-back direction of the wearer and a transverse direction orthogonal thereto, and having an absorber, and a front sheet disposed on the skin-facing side of the absorber. The above-mentioned absorbent body is composed of a liquid-absorbent absorbent core and a core-wrap material covering the skin opposite surface of the absorbent core, the absorbent core including: water-absorbent fibers; and a fiber block including water-absorbent core The fiber with weaker water absorption than the water absorbent fiber. The ratio of the liquid diffusion area of the above-mentioned absorbent core measured by the following method to the liquid diffusion area of the above-mentioned core-wrap material measured by the following method is 0.7 or more as the former / the latter.

<液體擴散面積之測定方法>
於相對於水平面具有45°之角度之斜面上,將測定對象以使其肌膚對向面朝向該斜面之方式固定,耗費23秒鐘將1.5 g脫纖維馬血注入至測定對象之肌膚對向面,放置3分鐘後,再次進行耗費相同時間將同量之脫纖維馬血注入至相同注入部位之操作。反覆進行6次該脫纖維馬血之注入、放置操作,將合計9 g之脫纖維馬血注入至測定對象。注入操作完成後,對測定對象之肌膚對向面中之脫纖維馬血之擴散面積進行測定,並將其作為該測定對象之液體擴散面積。
<Measurement method of liquid diffusion area>
On an inclined surface with an angle of 45 ° relative to the horizontal plane, fix the measurement object so that the opposite side of the skin faces the inclined surface, and it takes 23 seconds to inject 1.5 g of defibrinated horse blood into the opposite side of the measurement object After being left for 3 minutes, the same amount of defibrinated horse blood is injected into the same injection site in the same time. This defibrillation horse blood injection and placement operation was repeated 6 times, and a total of 9 g of defibrillation horse blood was injected into the measurement object. After the injection operation is completed, the diffusion area of the defibrillated horse blood in the skin facing surface of the measurement object is measured, and this is taken as the liquid diffusion area of the measurement object.

專利文獻1所記載之吸收體除了含有纖維素系吸水性纖維以外進而含有合成纖維(熱塑性樹脂纖維),故而與僅含有纖維素系吸水性纖維作為構成纖維之吸收體相比,剛性更高,因此可期待緩衝性、壓縮回覆性等各特性之提高,但所含有之複數條合成纖維各自獨立存在,並非形成聚集之1個塊,故而該等各特性之提高效果不充分,因此,在應用於吸收性物品之情形時,有易於發生褶皺而服貼性變得不充分之虞,尤其於尿、經血等體液之吸收後,此種不良狀況之發生較顯著。The absorber described in Patent Document 1 contains synthetic fibers (thermoplastic resin fibers) in addition to cellulose-based water-absorbent fibers, so it has higher rigidity than an absorber containing only cellulose-based water-absorbent fibers as constituent fibers. Therefore, the improvement of various characteristics such as cushioning properties and compression responsiveness can be expected, but the plurality of synthetic fibers contained are independent of each other and do not form an aggregate. Therefore, the improvement effect of these various characteristics is insufficient. In the case of absorbent articles, there is a possibility that wrinkles are likely to occur and the fit becomes insufficient, especially after the absorption of body fluids such as urine and menstrual blood.

另一方面,專利文獻2至4所記載之吸收體所含有之合成纖維均為被稱為不織布片或微細纖維網等之合成纖維集合體,故而可期待緩衝性之提高等。但是,根據本發明者之見解,若多個此種弱吸水性之合成纖維集合體包含於吸收體中,則吸收體之液體透過性降低,其結果為,透過正面片材而到達吸收體之肌膚對向面(包芯片材)之體液難以被引入至吸收體(吸收性芯體)內,體液大量殘留於吸收體之肌膚對向面,而成為不舒適之肌膚之黏膩或濕潤感之原因。於專利文獻2至4中未記載有起因於弱吸水性之合成纖維集合體之吸收體之問題,尚未提供一面活用合成纖維集合體之優點一面解決該問題之技術。On the other hand, the synthetic fibers contained in the absorbers described in Patent Documents 2 to 4 are all synthetic fiber aggregates called nonwoven fabric sheets, fine fiber webs, etc., so improvement in cushioning properties can be expected. However, according to the findings of the present inventors, if a plurality of such weakly absorbent synthetic fiber aggregates are included in the absorbent body, the liquid permeability of the absorbent body is reduced, and as a result, the absorbent sheet reaches the absorbent body through the front sheet Body fluids on the opposite side of the skin (chip-coated) are difficult to be introduced into the absorber (absorbent core), and a large amount of body fluid remains on the opposite side of the absorber's skin, which becomes sticky or moist in the uncomfortable skin the reason. Patent Documents 2 to 4 do not describe the problem caused by the absorbent body of the weakly absorbent synthetic fiber assembly, and there is no technology to solve the problem while utilizing the advantages of the synthetic fiber assembly.

因此,本發明係關於一種具備具有對吸收性芯體之較高之液體透過性且緩衝性優異之吸收體之吸收性物品。Therefore, the present invention relates to an absorbent article having an absorbent body having high liquid permeability to an absorbent core and excellent cushioning properties.

以下,針對本發明,一面參照圖式,一面基於其較佳之實施形態進行說明。圖1及圖2表示作為本發明之吸收性物品之一實施形態之經期衛生棉1。衛生棉1具備:吸收體4,其吸收保持體液;液體透過性之正面片材2,其配置於該吸收體4之肌膚對向面側,且可與穿著者之肌膚接觸;及液體難透過性之背面片材3,其配置於該吸收體4之非肌膚對向面側。如圖1所示,衛生棉1具有與穿著者之前後方向對應且自穿著者之腹側經由胯間部向背側延伸之縱向X、及與其正交之橫向Y,又,於縱向X上,分為如下3個區域:縱中央區域B,其包含與穿著者之陰道口等排泄部對向之排泄部對向部(排泄點);前方區域A,其配置於較該排泄部對向部更靠穿著者之腹側(前側);及後方區域C,其配置於較該排泄部對向部更靠穿著者之背側(後側)。Hereinafter, the present invention will be described based on its preferred embodiments while referring to the drawings. Figures 1 and 2 show a menstrual tampon 1 as an embodiment of the absorbent article of the present invention. The sanitary napkin 1 includes: an absorber 4, which absorbs and retains body fluids; a liquid-permeable front sheet 2, which is arranged on the skin-facing side of the absorber 4 and can be in contact with the wearer's skin; and the liquid is difficult to penetrate The back sheet 3 is arranged on the non-skin-facing side of the absorber 4. As shown in FIG. 1, the sanitary napkin 1 has a longitudinal direction X corresponding to the front and back directions of the wearer and extending from the ventral side of the wearer to the dorsal side through the crotch portion, and a transverse direction Y orthogonal thereto, and, in the longitudinal direction X, It is divided into the following three areas: the longitudinal central area B, which contains the excretory portion opposite portion (excretion point) opposite the wearer's vaginal opening and other excretory portions; the front area A, which is arranged opposite to the excretory portion It is closer to the ventral side (front side) of the wearer; and the rear area C is arranged closer to the wearer's back side (rear side) than the excretory facing portion.

於本說明書中,「肌膚對向面」係吸收性物品或其構成構件(例如,吸收體4)中之吸收性物品之穿著時朝向穿著者之肌膚側之面,即相對靠近穿著者之肌膚之側,「非肌膚對向面」係吸收性物品或其構成構件中之吸收性物品之穿著時朝向與肌膚側相反之側即相對遠離穿著者之肌膚之側之面。再者,此處所言之「穿著時」意指維持通常之適當之穿著位置即該吸收性物品之正確之穿著位置之狀態。In this specification, "skin-facing surface" refers to the surface of the absorbent article or its constituent members (for example, the absorbent body 4) that faces the wearer's skin when worn, that is, relatively close to the wearer's skin On the other hand, the "non-skin-facing surface" refers to the surface of the absorbent article or the absorbent article in its constituent members that faces the side opposite to the skin side, that is, the side relatively away from the wearer's skin. In addition, "when wearing" here means to maintain the state of the usual proper wearing position, that is, the correct wearing position of the absorbent article.

如圖1所示,衛生棉1具有:吸收性本體5,其為縱向X上較長之形狀;及一對翼(wing)部5W、5W,其等自吸收性本體5中之縱中央區域B之沿縱向X之兩側部各者向橫向Y之外側延出。吸收性本體5係構成衛生棉1之主體之部分,具備上述正面片材2、背面片材3及吸收體4,於縱向X上分為前方區域A、縱中央區域B及後方區域C之3個區域。As shown in FIG. 1, the sanitary napkin 1 has: an absorbent body 5 which is longer in the longitudinal direction X; and a pair of wings 5W, 5W, etc., which extend from the longitudinal central region of the absorbent body 5 Each of the two sides of B along the longitudinal direction X extends outward from the lateral direction Y. The absorbent body 5 constitutes the main part of the sanitary napkin 1, and includes the front sheet 2, the back sheet 3, and the absorber 4, and is divided into a front region A, a longitudinal center region B, and a rear region C in the longitudinal direction X Areas.

再者,於吸收性物品如衛生棉1般具有翼部之情形時,本發明之吸收性物品中之縱中央區域意指於該吸收性物品之縱向(長度方向,圖中之X方向)上具有翼部之區域,以衛生棉1為例,其係被一翼部5W之沿縱向X之根部與另一翼部5W之沿縱向X之根部所夾之區域。又,不具有翼部之吸收性物品中之縱中央區域意指將吸收性物品於縱向三等分時位於中間之區域。Furthermore, in the case where the absorbent article has wings like the sanitary napkin 1, the longitudinal central area in the absorbent article of the present invention means the longitudinal direction (length direction, X direction in the figure) of the absorbent article The region with wings, taking the sanitary napkin 1 as an example, is the region sandwiched by the root of one wing 5W in the longitudinal direction X and the root of the other wing 5W in the longitudinal direction X. In addition, the longitudinal center region in the absorbent article without wings means the region located in the middle when the absorbent article is divided into three in the longitudinal direction.

吸收體4係包含液體吸收性之吸收性芯體40、及被覆該吸收性芯體40之至少肌膚對向面之液體透過性之包芯片材41而構成。吸收性芯體40與吸收性本體5同樣地於如圖1所示之俯視下呈縱向X上較長之形狀,吸收性芯體40之長度方向與衛生棉1之縱向X一致,吸收性芯體40之寬度方向與衛生棉1之橫向Y一致。吸收性芯體40與包芯片材41之間亦可藉由熱熔型接著劑等接著劑接合。The absorber 4 is composed of a liquid-absorbent absorbent core 40 and a liquid-permeable chip covering 41 covering at least the skin-facing surface of the absorbent core 40. Like the absorbent body 5, the absorbent core 40 has a longer shape in the longitudinal direction X in plan view as shown in FIG. 1, and the longitudinal direction of the absorbent core 40 coincides with the longitudinal direction X of the sanitary napkin 1. The absorbent core The width direction of the body 40 coincides with the lateral direction Y of the sanitary napkin 1. The absorbent core 40 and the chip-wrapped material 41 may be joined by an adhesive such as a hot-melt adhesive.

於衛生棉1中,包芯片材41係具有吸收性芯體40之橫向Y之長度之2倍以上且3倍以下之寬度之1片連續之片材,如圖2所示,被覆吸收性芯體40之肌膚對向面之全域,且自吸收性芯體40之沿縱向X之兩側緣向橫向Y之外側延出,其延出部向吸收性芯體40之下方捲下,且被覆吸收性芯體40之非肌膚對向面之全域。再者,於本發明中,包芯片材亦可並非此種1片片材,例如,亦可包含被覆吸收性芯體40之肌膚對向面之1片肌膚側包芯片材、及與該肌膚側包芯片材不同體且被覆吸收性芯體40之非肌膚對向面之1片非肌膚側包芯片材之2片片材而構成。In the sanitary napkin 1, the core-wrap material 41 is a continuous sheet having a width of 2 times or more and 3 times or less of the width Y of the absorptive core 40, as shown in FIG. 2, the absorbent core is coated The whole area of the skin opposite to the body 40 extends from both sides of the absorbent core 40 in the longitudinal direction X to the outside of the lateral Y, and its extension is rolled down below the absorbent core 40 and covered The entire area of the non-skin-facing surface of the absorbent core 40. In addition, in the present invention, the chip-coated material may not be such a single sheet, for example, it may also include one skin-side chip-coated material covering the skin-facing side of the absorbent core 40 and the skin It is composed of two sheets of non-skin side wrapping chip material on the non-skin-facing side of the non-skin-facing side of the absorbent core 40 covered with different bodies on the side wrapping the sheet material.

如圖2所示,正面片材2被覆吸收體4之肌膚對向面之全域。另一方面,背面片材3被覆吸收體4之非肌膚對向面之全域,進而,自吸收體4之沿縱向X之兩側緣向橫向Y之外側延出,與下述側部片材6一併形成側翼(side flap)部(包含自吸收體4向橫向Y之外側延出之構件之部分)。背面片材3與側部片材6於自吸收體4之沿縱向X之兩側緣之延出部藉由接著劑、熱密封、超音波密封等公知之接合方法而相互接合。正面片材2及背面片材3各者與吸收體4之間亦可藉由接著劑接合。作為正面片材2、背面片材3,可無特別限制地使用先前用於經期衛生棉等吸收性物品之各種片材。例如,作為正面片材2,可使用單層或多層構造之不織布、或開孔膜等。作為背面片材3,可使用透濕性之樹脂膜等。As shown in FIG. 2, the front sheet 2 covers the entire area of the skin facing side of the absorber 4. On the other hand, the back sheet 3 covers the entire area of the non-skin-facing surface of the absorber 4 and further extends from the both edges of the absorber 4 in the longitudinal direction X to the outside in the lateral direction Y, and the following side sheet 6 A side flap portion (a portion including members extending outward from the absorber 4 to the lateral Y side) is formed together. The back sheet 3 and the side sheet 6 are bonded to each other at the extensions from the both edges of the absorber 4 along the longitudinal direction X by a known bonding method such as an adhesive, heat sealing, or ultrasonic sealing. Each of the front sheet 2 and the back sheet 3 and the absorber 4 may be joined by an adhesive. As the front sheet 2 and the back sheet 3, various sheets previously used for absorbent articles such as menstrual napkins can be used without particular limitation. For example, as the front sheet 2, a non-woven fabric of a single-layer or multi-layer structure, an apertured film, or the like can be used. As the back sheet 3, a moisture-permeable resin film or the like can be used.

如圖1所示,上述側翼部於縱中央區域B中向橫向Y之外側大幅突出,藉此,於吸收性本體5之沿縱向X之左右兩側延設有一對翼部5W、5W。翼部5W於如圖1所示之俯視下具有下底(長於上底之邊)位於吸收性本體5之側部側之大致梯形形狀,於其非肌膚對向面形成有將該翼部5W固定於短褲等衣物之翼部黏著部(未圖示)。翼部5W回折至短褲等衣物之褲襠部之非肌膚對向面(外表面)側而使用。上述翼部黏著部於其使用前被包含膜、不織布、紙等之剝離片材(未圖示)被覆。又,於吸收性本體5之肌膚對向面即正面片材2之肌膚對向面中之沿縱向X之兩側部,一對側部片材6、6以於俯視下與吸收體4之沿縱向X之左右兩側部重疊之方式遍及吸收性本體5之縱向X之大致全長而配置。一對側部片材6、6分別利用在縱向X上延伸之未圖示之接合線並藉由接著劑等公知之接合方法而接合於正面片材2等其他構件。As shown in FIG. 1, the side wing portion protrudes greatly outward in the lateral center Y in the longitudinal center region B, whereby a pair of wing portions 5W, 5W extend on the left and right sides of the absorbent body 5 along the longitudinal direction X. The wing portion 5W has a substantially trapezoidal shape with a lower bottom (longer than the upper bottom) on the side of the absorbent body 5 in a plan view as shown in FIG. 1, and the wing portion 5W is formed on the non-skin-facing surface It is fixed to the wing adhesion part (not shown) of clothing such as shorts. The wing part 5W is folded back to the non-skin-facing side (outer surface) side of the crotch part of shorts and other clothing. The wing part adhesive part is covered with a release sheet (not shown) containing film, non-woven fabric, paper, etc. before use. In addition, on the opposite side of the skin of the absorbent body 5 that is the opposite side of the skin of the front sheet 2 in the longitudinal direction X, a pair of side sheets 6 and 6 are connected to the absorbent body 4 in plan view. The left and right side portions along the longitudinal direction X are arranged over substantially the entire length of the longitudinal direction X of the absorbent body 5. The pair of side sheets 6 and 6 are respectively joined to other members such as the front sheet 2 by a known joining method such as an adhesive using a bonding wire (not shown) extending in the longitudinal direction X.

如圖1及圖2所示,於吸收體4之肌膚對向面,局部地形成有包芯片材41及吸收性芯體向該吸收體4之非肌膚對向面側一體地凹陷之凹陷部7。凹陷部7係藉由針對衛生棉1自其肌膚對向面即正面片材側實施壓擠加工而形成,就其形成方法而言,亦可稱為「壓擠部」。作為壓擠加工,可利用公知之方法,例如,可列舉伴有熱或不伴有熱之壓紋加工、或超音波壓紋等。凹陷部7因其形成方法而使得正面片材2、包芯片材41及吸收性芯體40向該吸收性芯體40之非肌膚對向面側(背面片材3側)一體地凹陷。又,凹陷部7因其形成方法而使得與其周邊部(凹陷部7之非形成部)相比密度更高。即,吸收性本體5具有與凹陷部7對應之高密度部、及與非凹陷部對應之低密度部。於凹陷部7之底部,存在正面片材2、包芯片材41及吸收性芯體40熱熔而一體化之情況。As shown in FIGS. 1 and 2, a concave portion integrally dented toward the non-skin-facing surface side of the absorber 4 is partially formed on the skin-facing surface of the absorber 4 7. The depressed portion 7 is formed by pressing the sanitary napkin 1 from the skin facing side, that is, the front sheet side, and may also be referred to as a "pressing portion" in terms of the forming method. As the extrusion processing, a known method can be used, and examples thereof include embossing with or without heat, ultrasonic embossing, and the like. Due to the method of forming the recessed portion 7, the front sheet 2, the core-wrap 41 and the absorbent core 40 are integrally recessed on the non-skin-facing side of the absorbent core 40 (back sheet 3 side). In addition, the recessed portion 7 has a higher density than its peripheral portion (non-formed portion of the recessed portion 7) due to the method of forming it. That is, the absorbent body 5 has a high-density portion corresponding to the recessed portion 7 and a low-density portion corresponding to the non-recessed portion. At the bottom of the concave portion 7, there may be a case where the front sheet 2, the chip wrapping 41 and the absorbent core 40 are melted and integrated.

如圖1所示,凹陷部7至少形成於縱中央區域B,更具體而言,自前方區域A之靠縱中央區域B之部分遍及至後方區域C之靠縱中央區域B之部分於縱向X上連續。於衛生棉1中,凹陷部7於如圖1所示之俯視下呈線狀,又,該線狀之凹陷部7於俯視下呈閉合之環狀。環狀之凹陷部7於俯視下呈縱向X上較長之形狀,其長度方向與縱向X一致。環狀之凹陷部7於前方區域A及後方區域C各者中形成為朝向縱向X之外側凸出之U字狀或弧狀,該U字狀或弧狀之頂部位於衛生棉1之橫向Y之中央。又,環狀之凹陷部7於縱中央區域B中形成為於縱向X上延伸之左右一對線狀。如此,凹陷部7以包圍縱中央區域B之橫向Y之中央部之方式形成。As shown in FIG. 1, the concave portion 7 is formed at least in the longitudinal central region B, more specifically, the portion of the front region A near the longitudinal central region B extends to the portion of the rear region C near the longitudinal central region B in the longitudinal direction X上 Continuous. In the sanitary napkin 1, the recessed portion 7 has a linear shape in plan view as shown in FIG. 1, and the linear recessed portion 7 has a closed ring shape in plan view. The annular recessed portion 7 has a shape that is longer in the longitudinal direction X in a plan view, and its longitudinal direction coincides with the longitudinal direction X. The annular concave portion 7 is formed in each of the front area A and the rear area C into a U-shape or an arc shape that protrudes toward the outside of the longitudinal direction X, and the top of the U-shape or arc shape is located in the lateral Y of the sanitary napkin 1 Of the center. In addition, the annular concave portion 7 is formed in the longitudinal center region B as a pair of left and right lines extending in the longitudinal direction X. In this way, the depressed portion 7 is formed so as to surround the central portion of the longitudinal central region B in the lateral direction Y.

於衛生棉1中,凹陷部7之深度(距正面片材2中之未凹陷之肌膚對向面之深度)遍及其長度方向之全長而成為固定。凹陷部7之深度可設定為與此種吸收性物品中之防漏槽之深度同樣之範圍,通常為1~10 mm左右。作為可藉由凹陷部7之形成而期待之效果,可列舉:抑制吸收體4之平面方向、尤其是橫向Y之液體之擴散,防止吸收體4之褶皺等。再者,線狀之凹陷部7之形狀、配置等並不限於圖示之形態,可與此種吸收性物品中被稱為防漏槽等者同樣地設定,俯視形狀包含直線及/或曲線而構成,各線可為連續線,亦可為虛線(深度不同之2種部分交替配置於線狀之凹陷部延伸之方向之形態)。In the sanitary napkin 1, the depth of the recessed portion 7 (the depth from the non-recessed skin facing surface in the front sheet 2) is fixed over its entire length in the longitudinal direction. The depth of the recess 7 can be set to the same range as the depth of the leak-proof groove in such an absorbent article, and is usually about 1 to 10 mm. Examples of effects that can be expected by the formation of the recessed portion 7 include the suppression of the diffusion of the liquid in the planar direction of the absorber 4, especially the lateral direction Y, and the prevention of wrinkles in the absorber 4. In addition, the shape and arrangement of the linear recesses 7 are not limited to those shown in the drawings, and can be set in the same manner as those of such absorbent articles called leak-proof grooves, etc. The shape in plan view includes straight lines and / or curves In terms of configuration, each line may be a continuous line or a dashed line (a form in which two parts with different depths are alternately arranged in the direction in which the linear recess extends).

作為衛生棉1之主要特徵部分之一,可列舉吸收性芯體40。圖3表示吸收性芯體40之一部分(凹陷部7之非形成部)。如圖2及圖3所示,吸收性芯體40包含含有複數條纖維(弱吸水性之合成纖維)11F之纖維塊11、及吸水性纖維12F。纖維塊11係纖維11F刻意地以塊狀集聚而一體化之纖維集合體,相對於此,吸水性纖維12F不刻意地一體化而以可各自獨立地存在之狀態存在於吸收性芯體40中。纖維塊11主要有助於吸收性芯體40之柔軟性、緩衝性、壓縮回覆性、保形性等之提高。另一方面,吸水性纖維12F主要有助於吸收性芯體40之液體吸收性及保形性等之提高。再者,吸收性芯體40係實質上亦可謂吸收體4其本身者,以下之關於吸收性芯體40之說明只要無特別說明,則作為吸收體4之說明而適當應用。即,本發明包含吸收體不含包芯片材而僅由吸收性芯體形成之情況,此時,於此情形時,吸收體與吸收性芯體為相同意義。As one of the main features of the sanitary napkin 1, an absorbent core 40 can be cited. FIG. 3 shows a part of the absorbent core 40 (non-formed part of the recess 7). As shown in FIGS. 2 and 3, the absorbent core 40 includes a fiber block 11 including a plurality of fibers (weak water-absorbing synthetic fibers) 11F, and a water-absorbing fiber 12F. The fiber block 11 is a fiber assembly in which fibers 11F are deliberately aggregated in a block shape. In contrast, the water-absorbent fibers 12F are not intentionally integrated but exist in the absorbent core 40 in a state where they can exist independently. . The fiber block 11 mainly contributes to the improvement of the flexibility, cushioning property, compression resilience, shape retention, etc. of the absorbent core 40. On the other hand, the water-absorbent fiber 12F mainly contributes to the improvement of the liquid absorption and shape retention properties of the absorbent core 40. In addition, the absorbent core 40 can also be said to be the absorber 4 itself substantially, and the following description about the absorbent core 40 is suitably applied as the description of the absorber 4 unless there is a special description. That is, the present invention includes the case where the absorber does not include the chip wrapping material and is formed only of the absorbent core. In this case, in this case, the absorber and the absorbent core have the same meaning.

於本說明書中,「纖維塊」係指複數條纖維聚集而成為一體之纖維集合體。作為纖維塊之形態,例如可列舉自具有固定大小之合成纖維片材分割成之薄片。作為纖維塊,尤其較佳為選擇不織布作為合成纖維片材並自該不織布剪切為特定之大小及形狀之不織布片。In this specification, "fiber block" refers to a fiber assembly in which a plurality of fibers are aggregated to become one. Examples of the form of the fiber block include a sheet divided from a synthetic fiber sheet having a fixed size. As the fiber block, it is particularly preferable to select a non-woven fabric as a synthetic fiber sheet and cut the non-woven fabric into a specific size and shape from the non-woven fabric sheet.

如此,作為本發明之纖維塊之較佳之一實施形態之薄片狀之纖維塊並非以使複數條纖維集聚而形成該薄片之方式構成,而藉由尺寸大於該薄片之纖維片材(較佳為不織布)之切斷而製造(參照圖6)。本發明之吸收體所含有之複數個纖維塊係與由如專利文獻1及2之先前技術製造者相比定形性更高之複數個薄片狀之纖維塊。In this way, the sheet-like fiber block, which is a preferred embodiment of the fiber block of the present invention, is not constituted by aggregating a plurality of fibers to form the sheet, but by a fiber sheet having a size larger than the sheet (preferably It is manufactured by cutting the nonwoven fabric (see FIG. 6). The plurality of fiber blocks contained in the absorbent body of the present invention are a plurality of lamella-shaped fiber blocks with higher setability than those manufactured by the prior arts such as Patent Documents 1 and 2.

然而,如專利文獻1~4所記載般之包含弱吸水性之合成纖維集合體之吸收性芯體如上所述般液體透過性較低,因此,關於使用其之吸收體,體液易於殘留於被覆該吸收性芯體之肌膚對向面之肌膚側包芯片材之肌膚對向面,其結果為,有導致不舒適之肌膚之黏膩或濕潤感之發生之虞。為了解決此種起因於弱吸水性之纖維之使用之問題,本發明者進行了各種研究,結果獲得了如下見解:有效方法為,將吸收體中通常最先與體液接觸之肌膚側包芯片材之面方向上之液體擴散性在同與該肌膚側包芯片材抵接之吸收性芯體之面方向上之液體擴散性之關係中設定為特定範圍。However, as described in Patent Documents 1 to 4, the absorbent core including the weakly absorbent synthetic fiber assembly has low liquid permeability as described above, and therefore, regarding the absorber using the same, body fluids tend to remain in the coating The skin-facing side of the skin-facing side of the absorbent core has the chip-facing skin-facing side. As a result, it may cause sticky or moist feeling of uncomfortable skin. In order to solve such a problem caused by the use of weakly absorbent fibers, the present inventors conducted various studies, and as a result obtained the following insights: An effective method is to wrap the skin side of the absorbent body, which is usually first contacted with body fluids, with a chip material The liquid diffusibility in the surface direction is set to a specific range in relation to the liquid diffusibility in the surface direction of the absorbent core that is in contact with the skin-side encapsulating core material.

基於上述見解,於衛生棉1中,將由上述<液體擴散面積之測定方法>測得之吸收性芯體40之液體擴散面積與由同一測定方法測得之肌膚側包芯片材41之液體擴散面積之比率(以下,亦稱為「液體擴散面積比率」)以前者/後者計設為0.7以上。若液體擴散面積比率為0.7以上,則易於順利地進行體液自肌膚側包芯片材41向吸收性芯體40之移動,體液不易殘留於肌膚側包芯片材41之肌膚對向面,可減少不舒適之肌膚之黏膩或濕潤感。就更順利地進行體液自肌膚側包芯片材41向吸收性芯體40之移動之觀點而言,液體擴散面積比率較佳為0.75以上,進而較佳為0.8以上,並且,較佳為1.5以下,進而較佳為2.0以下。Based on the above findings, in the sanitary napkin 1, the liquid diffusion area of the absorbent core 40 measured by the above <liquid diffusion area measurement method> and the liquid diffusion area of the skin-side cladding material 41 measured by the same measurement method The ratio (hereinafter, also referred to as "liquid diffusion area ratio") is set to 0.7 or more for the former / the latter. If the liquid diffusion area ratio is 0.7 or more, it is easy to smoothly move body fluids from the skin-side core wrapping material 41 to the absorbent core 40, and body fluids are less likely to remain on the skin-facing surface of the skin-side wrapping core material 41, which can reduce Sticky or moist feeling of comfortable skin. From the viewpoint of more smoothly moving body fluids from the skin-side core wrapping material 41 to the absorbent core 40, the liquid diffusion area ratio is preferably 0.75 or more, further preferably 0.8 or more, and preferably 1.5 or less , Further preferably 2.0 or less.

參照圖8,對上述<液體擴散面積之測定方法>進行補充,測定對象S(吸收性芯體、包芯片材)設為240 mm×75 mm之俯視四邊形形狀。用於測定之測定台100具有與水平面所成之角度θ為45°之斜面100a。將測定對象S以其肌膚對向面與斜面100a對向之方式載置於斜面100a之上,進而,於其測定對象S之上載置面積大於測定對象S之厚度3 mm之丙烯酸系樹脂板101。作為模擬血液注入至測定對象S之脫纖維馬血係使用B型黏度計(東機產業股份有限公司製造,型號TVB-10M,測定條件:轉子No.19、30 rpm、25℃、60秒鐘)測得之黏度為8 mPa・s者。作為此種脫纖維馬血,例如可使用股份有限公司NIPPON BIOTEST研究所製造之脫纖維馬血,可藉由視需要調整血球、血漿比率等而將黏度調整為上述特定之範圍。測定對象S中之脫纖維馬血之注入位置設為測定對象S之肌膚對向面之中心部(圖8中,箭頭所示之部分),使用未圖示之微型管泵(東京理化器械股份有限公司製造)注入。於該泵連結有未圖示之管,該管之同與該泵之連結側相反之側之端部連結於斜面100a上之測定對象S,脫纖維馬血通過該管而注入至測定對象S。測定對象S之肌膚對向面中之脫纖維馬血之擴散面積可藉由利用OHP(Overhead projector,高架式投影機)片材轉印測定對象S中之脫纖維馬血之分佈區域,並根據慣例使用圖像解析軟體NexusNewQube(Nexus公司製造)對該OHP片材進行處理而測定。With reference to FIG. 8, the above-mentioned <method for measuring the liquid diffusion area> is supplemented, and the measurement object S (absorbent core, chip-coated material) is set to a quadrangular shape in plan view of 240 mm × 75 mm. The measurement table 100 used for measurement has a slope 100a with an angle θ of 45 ° to the horizontal plane. The measurement object S is placed on the inclined surface 100a such that its skin-facing surface and the inclined surface 100a face each other, and further, an acrylic resin plate 101 with an area greater than the thickness of the measurement object S of 3 mm is placed on the measurement object S . As a defibrillated horse blood system that simulates blood injection into the measurement object S, a B-type viscometer (manufactured by Toki Industry Co., Ltd., model TVB-10M, measurement conditions: rotor No. 19, 30 rpm, 25 ° C, 60 seconds) is used ) The measured viscosity is 8 mPa · s. As such defibrillated horse blood, for example, defibrillated horse blood manufactured by NIPPON BIOTEST Co., Ltd. can be used, and the viscosity can be adjusted to the above-mentioned specific range by adjusting the blood cell, plasma ratio, etc. as necessary. The injection position of the defibrillated horse blood in the measurement object S is set to the center portion of the skin opposite to the measurement object S (the portion indicated by the arrow in FIG. 8), and a micro tube pump (Tokyo Ricoh Instruments Co., Ltd.) is used. Co., Ltd.) injection. A tube (not shown) is connected to the pump, and the end of the tube opposite to the connection side of the pump is connected to the measurement object S on the inclined surface 100a, and defibrillated horse blood is injected into the measurement object S through the tube . The diffusion area of the defibrillated horse blood in the surface opposite to the skin of the measurement object S can be transferred to the distribution area of the defibrillation horse blood in the measurement object S by using OHP (Overhead projector, overhead projector) sheet, and according to Conventionally, the image analysis software NexusNewQube (manufactured by Nexus) is used to process and measure the OHP sheet.

為了如上所述般將液體擴散面積比率設為0.7以上,需要對吸收性芯體40及肌膚側包芯片材41之兩者或一者之組成等想辦法。想辦法提高肌膚側包芯片材41之液體透過性效果尤其高。就該觀點而言,肌膚側包芯片材41較佳為以紙漿為主體之多孔性片材。再者,本說明書中之關於「肌膚側包芯片材」之說明只要無特別說明,則亦應用於1片連續片材即包芯片材41中之其他部分,例如,形成吸收體4之非肌膚對向面即介置配置於背面片材3與吸收性芯體40之間之非肌膚側包芯片材。In order to set the ratio of the liquid diffusion area to 0.7 or more as described above, it is necessary to think of a composition of two or one of the absorbent core 40 and the skin-side packaged core material 41. Finding a way to improve the liquid permeability of the skin-side wrapping chip 41 is particularly high. From this point of view, the skin-side core sheet 41 is preferably a porous sheet mainly composed of pulp. In addition, unless otherwise specified, the description of "skin-side wrapping material" in this specification also applies to one continuous sheet, that is, other parts of the wrapping material 41, for example, non-skin forming the absorber 4 The opposite surface is the non-skin-side chip wrapping material disposed between the back sheet 3 and the absorbent core 40.

作為較佳地作為肌膚側包芯片材41之上述多孔性片材,可例示以紙漿為主體之紙漿片材。作為該紙漿片材,藉由濕式造紙法製造之紙為典型者。作為上述多孔性片材之主成分即紙漿,可使用纖維素系纖維,例如,可列舉:針葉樹曬乾牛皮紙漿(NBKP)、闊葉樹曬乾牛皮紙漿(LBKP)、針葉樹曬乾亞硫酸鹽紙漿(NBSP)、熱機械紙漿(TMP)等木漿;構樹、結香、剪夏羅等韌皮纖維;槁、竹子、洋麻、麻等非木漿等,可單獨使用其等之1種或組合2種以上而使用。上述多孔性片材中之紙漿之含量較佳為10質量%以上,進而較佳為50質量%以上。上述多孔性片材亦可包含除紙漿以外之成分,亦可包含其他成分,作為該其他成分,例如,可列舉:滑石等填料、染料、著色顏料、紙力增強劑、抗菌劑、pH調整劑、良率提高劑、耐水化劑、消泡劑等一般用作造紙用原材料或添加物者,可單獨使用其等之1種或組合2種以上而使用。As the above-mentioned porous sheet preferably used as the skin-side wrapping sheet 41, a pulp sheet mainly composed of pulp can be exemplified. As the pulp sheet, paper produced by a wet papermaking method is typical. As the main component of the porous sheet, that is, pulp, cellulose-based fibers can be used. For example, conifer tree dried kraft pulp (NBKP), broad-leaved tree dried kraft pulp (LBKP), conifer dried sulfite pulp ( NBSP), thermo-mechanical pulp (TMP) and other wood pulps; bast fibers such as mulberry tree, knot incense, shear Charlotte, etc .; non-wood pulps such as chaga, bamboo, kenaf, hemp, etc., can be used alone or in combination Use 2 or more types. The content of the pulp in the porous sheet is preferably 10% by mass or more, and more preferably 50% by mass or more. The porous sheet may contain components other than pulp or other components. Examples of the other components include fillers such as talc, dyes, coloring pigments, paper strength enhancers, antibacterial agents, and pH adjusters. , Yield improvers, water resistance agents, defoamers, etc. are generally used as raw materials or additives for papermaking, and they can be used alone or in combination of two or more.

又,就提高肌膚側包芯片材41(上述多孔性片材)之液體透過性之觀點而言,肌膚側包芯片材41之密度較佳為設為0.1 g/m3 以下,尤其較佳為設為0.08 g/m3 以下。再者,較佳為,肌膚側包芯片材41之密度較佳為0.02 g/m3 以上,進而較佳為0.04 g/m3 以上,其原因在於,易於維持充分之片材強度。In addition, from the viewpoint of improving the liquid permeability of the skin-side chip wrapping 41 (the porous sheet), the density of the skin-side chip wrapping 41 is preferably 0.1 g / m 3 or less, and particularly preferably It is set to 0.08 g / m 3 or less. In addition, it is preferable that the density of the skin-side core sheet material 41 is preferably 0.02 g / m 3 or more, and more preferably 0.04 g / m 3 or more, because it is easy to maintain sufficient sheet strength.

又,就液體透過性與強度之平衡等觀點而言,肌膚側包芯片材41(上述多孔性片材)之基重較佳為5 g/m2 以上,進而較佳為10 g/m2 以上,並且,較佳為50 g/m2 以下,進而較佳為30 g/m2 以下。In addition, from the viewpoint of the balance between liquid permeability and strength, the basis weight of the skin-side core wrapping material 41 (the porous sheet) is preferably 5 g / m 2 or more, and more preferably 10 g / m 2 The above is preferably 50 g / m 2 or less, and more preferably 30 g / m 2 or less.

於衛生棉1中,如上所述,如圖1及圖2所示,於吸收體4之肌膚對向面形成有包芯片材41(更具體而言,為肌膚側包芯片材41)及吸收性芯體40向該吸收體4之非肌膚對向面側一體地凹陷之凹陷部7,此時,藉由該構成,對於衛生棉1之穿著者之體壓或動作,吸收體4之形狀進一步變穩定,可期待衛生棉1之服貼性等之進一步提高。又,僅吸收體4(吸收性芯體40)之一部分形成有凹陷部7,如下所述,占吸收性芯體40之大部分之凹陷部7之非形成部藉由構成纖維彼此交絡而具有保形性,起因於該情況等,其柔軟且具有緩衝性,故而衛生棉1實質上可直接顯現該凹陷部7之非形成部之特點。就吸收體4之形狀穩定性與緩衝性等之平衡之觀點而言,凹陷部7之總面積占吸收體4(吸收性芯體40)之肌膚對向面之總面積之比率(凹陷部佔有率)較佳為3%以上,進而較佳為5%以上,並且,較佳為97%以下,進而較佳為95%以下。In the sanitary napkin 1, as described above, as shown in FIGS. 1 and 2, a chip wrap 41 (more specifically, a skin-side chip wrap 41) and absorption are formed on the skin-facing surface of the absorber 4 The core part 40 of the absorbent core 4 is integrally recessed toward the non-skin-facing side of the absorbent body 4, at this time, with this configuration, the shape of the absorbent body 4 for the body pressure or movement of the wearer of the sanitary napkin 1 It is further stabilized, and it is expected that the suitability of the sanitary napkin 1 will be further improved. In addition, only a part of the absorbent body 4 (absorbent core 40) is formed with the recessed portion 7, as described below, the non-formed portion of the recessed portion 7 that accounts for most of the absorbent core 40 is formed by the fibers intersecting each other. The shape-retaining property is due to the fact that it is soft and has cushioning properties. Therefore, the sanitary napkin 1 can substantially directly show the characteristics of the non-forming portion of the recess 7. From the viewpoint of the balance between the shape stability and cushioning properties of the absorber 4, the ratio of the total area of the depressions 7 to the total area of the skin facing surface of the absorber 4 (absorbent core 40) (the depressions occupy Rate) is preferably 3% or more, more preferably 5% or more, and preferably 97% or less, and more preferably 95% or less.

又,於衛生棉1中,如圖1所示,凹陷部7以包圍縱中央區域B之橫向Y之中央部之方式形成,藉此,更進一步提高該縱中央區域B之中央部之形狀穩定性。被該凹陷部7包圍之縱中央區域B之中央部通常為包含上述排泄部對向部(排泄點)之部分,為最先承接衛生棉1之穿著者所排泄之體液並使其擴散之重要部分,此時,該重要部分之形狀穩定性較高,藉此,可期待液體吸收性(防漏性)、服貼性、穿著感等各特性之更進一步提高。In addition, in the sanitary napkin 1, as shown in FIG. 1, the concave portion 7 is formed so as to surround the central portion of the horizontal central region B in the lateral direction Y, thereby further improving the shape stability of the central portion of the vertical central region B Sex. The central portion of the longitudinal central area B surrounded by the recessed portion 7 is usually a portion including the above-mentioned excretory portion facing portion (drain point), which is the first to receive the body fluid discharged by the wearer of the sanitary napkin 1 and diffuse it. In this case, at this time, the shape stability of this important part is high, and thereby, it is expected that the characteristics of the liquid absorbability (leakage resistance), the fitability, and the feeling of wearing can be further improved.

以下,對吸收性芯體40進一步進行說明。
於吸收性芯體40中,複數個纖維塊11彼此或纖維塊11與吸水性纖維12F相互交絡。於本實施形態之吸收性芯體40中,複數個纖維塊11藉由與吸收性芯體40中之構成纖維(纖維11F、12F)之相互纏繞而結合,而形成1個纖維塊連續體。又,亦可複數個纖維塊11彼此交絡,並且纖維塊11與吸水性纖維12F交絡而結合。進而,通常,複數條吸水性纖維12F彼此亦相互交絡。吸收性芯體40中含有之複數個纖維塊11之至少一部分與其他纖維塊11或吸水性纖維12F交絡。於吸收性芯體40中,可能存在其中含有之複數個纖維塊11全部相互交絡而形成1個纖維塊連續體之情況,或者可能存在複數個纖維塊連續體相互以非結合之狀態混合存在之情況。纖維塊11之交絡性即與其他纖維塊11或吸水性纖維12F之交絡之容易度很大程度上取決於纖維塊11所具有之下述延出纖維部113之形態(數量、大小、分佈狀態等),藉由適當地控制延出纖維部113之形態,可提高纖維塊11之交絡性。
Hereinafter, the absorbent core 40 will be further described.
In the absorbent core 40, a plurality of fiber blocks 11 intersect with each other or the fiber blocks 11 and the water-absorbent fibers 12F. In the absorbent core 40 of the present embodiment, a plurality of fiber blocks 11 are combined by entanglement with constituent fibers (fibers 11F, 12F) in the absorbent core 40 to form a continuous fiber block. In addition, a plurality of fiber blocks 11 may be entangled with each other, and the fiber block 11 and the water-absorbent fibers 12F may be entangled and combined. Furthermore, in general, a plurality of water-absorbent fibers 12F also interlace with each other. At least a part of the plurality of fiber blocks 11 contained in the absorbent core 40 intersects the other fiber blocks 11 or the water-absorbent fibers 12F. In the absorbent core 40, there may be a case in which a plurality of fiber blocks 11 contained therein are all intertwined to form a fiber block continuous body, or there may be a plurality of fiber block continuous bodies mixed with each other in a non-bonded state Happening. The entanglement of the fiber block 11, that is, the ease of entanglement with other fiber blocks 11 or the water-absorbent fibers 12F largely depends on the shape (number, size, distribution state) of the fiber extended portion 113 that the fiber block 11 has Etc.), by appropriately controlling the shape of the extended fiber portion 113, the intertwinability of the fiber block 11 can be improved.

纖維塊11係柔軟性等優異者。於本實施形態中,關於吸收性芯體40,如上所述,其中含有之複數個纖維塊11彼此藉由相互交絡而結合,進而,纖維塊11與吸水性纖維12F之間亦藉由相互交絡而結合,故而保形性、柔軟性、緩衝性、壓縮回覆性等優異,於裝入至衛生棉1之情形時,對於承受自各種方向之外力(例如,吸收性物品穿著者之體壓)靈活地變形,可服貼性良好地使衛生棉1與穿著者之身體密接。The fiber block 11 is excellent in flexibility and the like. In the present embodiment, regarding the absorbent core 40, as described above, the plurality of fiber blocks 11 contained therein are combined by mutual interlacing, and further, the fiber blocks 11 and the water-absorbent fibers 12F are also interlaced by each other. In combination, it is excellent in shape retention, flexibility, cushioning, compression and resilience. When loaded into the sanitary napkin 1, it is resistant to external forces from various directions (for example, the body pressure of the wearer of the absorbent article) The flexible deformation makes the sanitary napkin 1 closely contact the wearer's body with good serviceability.

圖4模式性地表示吸收性芯體40受到外力F被壓縮時之變形狀態。於纖維集合體即纖維塊11與非纖維集合體即吸水性纖維12F混合存在之吸收性芯體40中,起因於兩構件11、12F之剛性差,於兩構件11、12F之邊界BL(圖4中之虛線)尤其容易彎曲,邊界BL作為吸收性芯體40之變形時之彎曲部而發揮功能,此時,由於作為該彎曲部之邊界BL通常遍及吸收性芯體40之全域而存在,故而吸收性芯體40對各種外力響應性較好地靈活變形,又,於解除該外力之情形時,可藉由纖維塊11所具備之壓縮回覆性而快速地恢復至原本之狀態。此種吸收性芯體40之變形-回覆特性不僅可於壓縮吸收性芯體40之情形時顯現,而且於扭曲之情形時亦可同樣地顯現。即,裝入至衛生棉1之吸收性芯體40於衛生棉1之穿著時以夾持於穿著者之兩大腿部間之狀態配置,故而其吸收體4存在因穿著者之步行動作時之兩大腿部之移動而繞於縱向X上延伸之假想之旋轉軸扭曲之情況,但由於吸收性芯體40具備較高之變形-回覆特性,故而即便於此種情形時,亦可針對促使來自兩大腿部之扭曲之外力而容易地變形、回覆,因此,不易褶皺,可對衛生棉1賦予對穿著者之身體之較高之服貼性。FIG. 4 schematically shows the deformed state of the absorbent core 40 when compressed by an external force F. FIG. In the absorbent core 40 in which the fiber aggregate 11 that is the fiber block 11 and the non-fiber aggregate that is the water-absorbent fiber 12F coexist, due to the difference in rigidity of the two members 11, 12F, at the boundary BL of the two members 11, 12F (Figure The broken line in 4) is particularly easy to bend, and the boundary BL functions as a bent portion when the absorbent core 40 is deformed. At this time, since the boundary BL as the bent portion usually exists throughout the entire area of the absorbent core 40, Therefore, the absorbent core 40 can be flexibly deformed in response to various external forces, and when the external force is released, it can be quickly restored to its original state by the compression and resilience of the fiber block 11. Such deformation-recovery characteristics of the absorbent core 40 can be manifested not only when the absorbent core 40 is compressed, but also when twisted. That is, the absorbent core 40 inserted into the sanitary napkin 1 is placed between the two thighs of the wearer when the sanitary napkin 1 is worn, so the absorber 4 is present when the wearer walks The movement of the two thighs is twisted around the imaginary axis of rotation extending in the longitudinal direction X, but because the absorbent core 40 has a high deformation-response characteristic, even in this case, it can be targeted The twisted external force from the two thighs is caused to easily deform and reply, so that it is not easily wrinkled, and the sanitary napkin 1 can be given a higher suitability to the wearer's body.

如上所述,於吸收性芯體40中,纖維塊11彼此或纖維塊11與吸水性纖維12F交絡,此時,此處所言之纖維塊11彼此等之「交絡」包含下述形態A及B。
形態A:纖維塊11彼此等藉由纖維塊11之構成纖維11F彼此之相互纏繞而結合,而非藉由熔合而結合之形態。
形態B:於吸收性芯體40之自然狀態(不施加外力之狀態)下,纖維塊11彼此等未結合,但於外力施加於吸收性芯體40之狀態下,纖維塊11彼此等可藉由構成纖維11F彼此之相互纏繞而結合之形態。此處所言之「外力施加於吸收性芯體40之狀態」係指例如於應用吸收性芯體40之吸收性物品之穿著中變形力施加於吸收性芯體40之狀態。
As described above, in the absorbent core 40, the fiber blocks 11 intersect each other or the fiber blocks 11 intersect with the water-absorbent fibers 12F. In this case, the "interlace" of the fiber blocks 11 and the like mentioned here includes the following forms A and B .
Form A: The fiber blocks 11 are combined with each other by the constituent fibers 11F of the fiber block 11 being intertwined with each other, rather than being combined by fusion.
Form B: In the natural state (the state where no external force is applied) of the absorbent core 40, the fiber blocks 11 are not combined with each other, but in the state where the external force is applied to the absorbent core 40, the fiber blocks 11 can be borrowed from each other The form in which the constituent fibers 11F are entangled with each other is combined. The "state in which external force is applied to the absorbent core 40" as used herein refers to, for example, the state in which the deforming force is applied to the absorbent core 40 during the wearing of the absorbent article to which the absorbent core 40 is applied.

如此,於吸收性芯體40中,纖維塊11除了如形態A般藉由纖維彼此之相互纏繞即「交絡」而與其他纖維塊11或吸水性纖維12F結合以外,亦可如形態B般,以可與其他纖維塊11或吸水性纖維12F交絡之狀態存在,該利用纖維之交絡之結合對進一步有效地顯現上述吸收性芯體40之作用效果而言,為重要方面之一。但是,就保形性之方面而言,吸收性芯體40更佳為具有形態A之「交絡」。無論為形態A或B,利用吸收性芯體40中之構成纖維之交絡之結合均不用接著成分而僅由纖維彼此之相互纏繞形成,故而與例如專利文獻2所記載般之利用「纖維之熔合」之結合相比,結合力本身更低,反過來說,交絡之各個要素(纖維塊11、吸水性纖維12F)之移動之自由度更高,因此,該各個要素可於能維持作為包含其等之集合體之一體性之範圍內移動。如此,吸收性芯體40藉由其中含有之複數個纖維塊11彼此或纖維塊11與吸水性纖維12F相對較鬆地結合,而具有受到外力時可變形之緩和之保形性,以高水準兼顧保形性與緩衝性及壓縮回覆性等。In this way, in the absorbent core 40, the fiber block 11 may be combined with other fiber blocks 11 or the water-absorbent fibers 12F by being entangled with each other, that is, "interlaced", as in the form A, but also in the form B, It exists in a state where it can be interlaced with other fiber blocks 11 or water-absorbent fibers 12F, and this combination of intersecting fibers is one of the important aspects for further effectively exhibiting the above-mentioned effect of the absorbent core 40. However, in terms of shape retention, the absorbent core 40 is more preferably a “interlace” with Form A. Regardless of the form A or B, the combination using the interlacing of the constituent fibers in the absorbent core 40 does not need to be followed by components but is only formed by the intertwining of the fibers, so it is similar to the use of "fiber fusion" as described in Patent Document 2 Compared with the combination, the binding force itself is lower. Conversely, the freedom of movement of the interlinked elements (fiber block 11, water-absorbent fiber 12F) is higher. Therefore, each element can be maintained as it contains Move within the physical range of the collective body. In this way, the absorbent core 40 is relatively loosely combined with the plurality of fiber blocks 11 contained therein, or the fiber block 11 and the water-absorbent fiber 12F, and has a shape-retaining shape-retaining property that can be deformed when subjected to an external force, at a high level Take into account both shape retention, cushioning and compression response.

再者,吸收性芯體40中之經由纖維塊11之結合態樣無需均為「交絡」,吸收性芯體40之一部分亦可包含除交絡以外之其他結合態樣,例如,利用接著劑之接合等。Furthermore, the binding state of the absorbent core 40 via the fiber block 11 need not be "interlaced", and a part of the absorbent core 40 may also include other binding forms besides intersecting, for example, using an adhesive Bonding etc.

但是,例如,與衛生棉1中之凹陷部7等吸收性物品之其他構件成為一體之結果為,於自吸收性芯體40排除形成於吸收性芯體40之「經由纖維塊11之熔合」而得之剩餘之部分,即,於吸收性芯體40其本身中,較理想為,纖維塊11彼此之結合、或纖維塊11與吸水性纖維12F之結合僅由「纖維之交絡」形成。However, for example, as a result of being integrated with other members of the absorbent article such as the recessed portion 7 in the sanitary napkin 1, the "fusion through the fiber block 11" formed on the absorbent core 40 is excluded from the absorbent core 40 The remaining part, that is, in the absorbent core 40 itself, ideally, the combination of the fiber blocks 11 or the combination of the fiber blocks 11 and the water-absorbent fibers 12F is formed only by "intersection of fibers".

就更進一步確實顯現上述吸收性芯體40之作用效果之觀點而言,形態A即「藉由交絡結合之纖維塊11」與形態B即「可交絡之狀態之纖維塊11」之合計數量相對於吸收性芯體40中之纖維塊11之總數,較佳為半數以上,進而較佳為70%以上,更佳為80%以上。
就同樣之觀點而言,具有形態A之「交絡」之纖維塊11之數量較佳為具有與其他纖維塊11或吸水性纖維12F之結合部之纖維塊11之總數之70%以上,尤佳為80%以上。
In terms of further demonstrating the effect of the above-mentioned absorbent core 40, the total number of the form A, that is, the "fiber block 11 combined by interlacing" and the form B, that is, the "fiber block 11 in the interlacable state" are relatively The total number of fiber blocks 11 in the absorbent core 40 is preferably more than half, more preferably 70% or more, and more preferably 80% or more.
From the same point of view, the number of fiber blocks 11 having “interlace” in form A is preferably 70% or more of the total number of fiber blocks 11 having a junction with other fiber blocks 11 or water-absorbing fibers 12F, particularly preferably More than 80%.

作為吸收性芯體40之主要特徵之一,可列舉纖維塊11之外形形狀。圖5表示2個纖維塊11之典型之外形形狀。圖5(a)所示之纖維塊11A呈四角柱形狀,更具體而言,呈長方體形狀,圖5(b)所示之纖維塊11B呈圓盤形狀。纖維塊11A、11B於具備相對向之2個基本面(base plane)111、及連結該2個基本面111之骨架面(bodyplane)112之方面有共通之處。基本面111及骨架面112均為在評價以此種纖維為主體之物品中之表面之凹凸程度時應用之等級下認為實質上無凹凸之部分。As one of the main characteristics of the absorbent core 40, the outer shape of the fiber block 11 can be mentioned. FIG. 5 shows a typical shape of two fiber blocks 11. The fiber block 11A shown in FIG. 5 (a) has a rectangular column shape, more specifically, a rectangular parallelepiped shape, and the fiber block 11B shown in FIG. 5 (b) has a disk shape. The fiber blocks 11A and 11B have in common that they have two base planes 111 facing each other and a body plane 112 connecting the two base planes 111. Both the basic surface 111 and the skeleton surface 112 are considered to be substantially free of unevenness at the level applied when evaluating the degree of unevenness of the surface in an article mainly composed of such fibers.

圖5(a)之長方體形狀之纖維塊11A具有6個平坦面,此時,該6個面之中具有最大面積之相對向之2個面分別為基本面111,剩餘之4個面分別為骨架面112。基本面111與骨架面112相互交叉,更具體而言,正交。
圖5(b)之圓盤形狀之纖維塊11B具有俯視圓形狀之相對向之2個平坦面、及連結兩平坦面之彎曲之周面,此時,該2個平坦面分別為基本面111,該周面為骨架面112。
纖維塊11A、11B在骨架面112於俯視下呈四邊形形狀,更具體而言,呈長方形形狀之方面亦有共通之處。
The rectangular parallelepiped fiber block 11A of FIG. 5 (a) has 6 flat surfaces. At this time, the opposite two surfaces having the largest area among the six surfaces are the basic surfaces 111, and the remaining four surfaces are respectively Skeleton surface 112. The basic surface 111 and the skeleton surface 112 cross each other, and more specifically, are orthogonal.
The disc-shaped fiber block 11B of FIG. 5 (b) has two flat surfaces facing the circular shape in a plan view, and a curved peripheral surface connecting the two flat surfaces. In this case, the two flat surfaces are the basic surfaces 111, respectively. , The peripheral surface is the skeleton surface 112.
The fiber blocks 11A and 11B have a quadrangular shape when the skeleton surface 112 is viewed from above, and more specifically, they have a common shape in a rectangular shape.

吸收性芯體40中含有之複數個纖維塊11在分別為如圖5所示之纖維塊11A、11B般之具備2個對向之基本面111及連結兩基本面111之骨架面112之「定形之纖維集合體」之方面,與作為不定形之纖維集合體之專利文獻2及3中記載之不織布片或微細纖維網不同。換言之,於透視吸收性芯體40中之任意1個纖維塊11之情形時(例如,於利用電子顯微鏡觀察之情形時),該纖維塊11之透視形狀根據其觀察角度而不同,每1個纖維塊11存在多個透視形狀,此時,吸收性芯體40中之複數個纖維塊11各者具有具備2個對向之基本面111及連結兩基本面111之骨架面112之特定透視形狀作為其多個透視形狀之一。專利文獻2及3中記載之吸收體中含有之複數個不織布片或微細纖維網實質上不具有如基本面111或骨架面112般之「面」即有擴展之部分,外形形狀相互不同,並非「定形」。The plurality of fiber blocks 11 contained in the absorbent core 40 are respectively fiber blocks 11A and 11B as shown in FIG. 5 and have two opposing basic surfaces 111 and a skeleton surface 112 connecting the two basic surfaces 111. The aspect of "fixed fiber assembly" is different from the non-woven fabric sheet or fine fiber web described in Patent Documents 2 and 3 as an indefinite fiber assembly. In other words, when seeing through any one fiber block 11 in the absorbent core 40 (for example, when observing with an electron microscope), the see-through shape of the fiber block 11 differs according to its viewing angle, and each The fiber block 11 has a plurality of perspective shapes. At this time, each of the plurality of fiber blocks 11 in the absorbent core 40 has a specific perspective shape having two opposed basic surfaces 111 and a skeleton surface 112 connecting the two basic surfaces 111 As one of its multiple perspective shapes. The plurality of nonwoven fabric sheets or microfiber webs contained in the absorbers described in Patent Documents 2 and 3 does not substantially have a "plane" like the basic plane 111 or the skeleton plane 112, that is, there is an expanded part, and the outer shapes are different from each other, not "Setting".

如此,若吸收性芯體40中包含之複數個纖維塊11為由基本面111及骨架面112劃分形成之「定形之纖維集合體」,則與其為如專利文獻2及3所記載般之不定形之纖維集合體之情況相比,吸收性芯體40中之纖維塊11之均勻分散性提高,故而藉由將如纖維塊11般之纖維集合體調配於吸收性芯體40而穩定地顯現期待之效果(吸收體之柔軟性、緩衝性、壓縮回覆性等之提高效果)。又,尤其於如圖5(a)所示之長方體形狀之纖維塊11之情形時,其外表面包含2個基本面111及4個骨架面112之6個面,故而與如圖5(b)所示之具有3個外表面之圓盤形狀之纖維塊11相比,可相對更多地具有與其他纖維塊11或吸水性纖維12F之接觸機會,交絡性提高,亦可提高保形性等。In this way, if the plurality of fiber blocks 11 included in the absorbent core 40 is a "fixed fiber assembly" formed by dividing the basic surface 111 and the skeleton surface 112, it is not as different as described in Patent Documents 2 and 3. Compared with the case of shaped fiber aggregates, the uniform dispersion of the fiber blocks 11 in the absorbent core 40 is improved, so that the fiber aggregates like the fiber blocks 11 are formulated in the absorbent core 40 to stably appear Expected effects (improvement effects such as flexibility, cushioning properties, and compression responsiveness of the absorber). Moreover, especially in the case of a rectangular parallelepiped fiber block 11 as shown in FIG. 5 (a), its outer surface includes 6 faces of 2 basic faces 111 and 4 skeleton faces 112, so it is different from FIG. 5 (b) ) Compared with the disc-shaped fiber block 11 with three outer surfaces, it can have relatively more contact opportunities with other fiber blocks 11 or water-absorbent fibers 12F, the cross-connectivity is improved, and the shape retention can also be improved Wait.

於纖維塊11中,2個基本面111之總面積大於骨架面112之總面積。即,於圖5(a)之長方體形狀之纖維塊11A中,2個基本面111各者之面積之總和大於4個骨架面112各者之面積之總和,又,於圖5(b)之圓盤形狀之纖維塊11B中,2個基本面111各者之面積之總和大於形成圓盤形狀之纖維塊11B之周面之骨架面112之面積。於纖維塊11A、11B任一者中,基本面111均為纖維塊11A、11B所具有之複數個面之中面積最大之面。In the fiber block 11, the total area of the two basic surfaces 111 is greater than the total area of the skeleton surface 112. That is, in the rectangular parallelepiped fiber block 11A of FIG. 5 (a), the sum of the areas of the two basic faces 111 is greater than the sum of the areas of the four skeleton faces 112. Also, in FIG. 5 (b) In the disc-shaped fiber block 11B, the sum of the areas of the two basic surfaces 111 is larger than the area of the skeleton surface 112 on the peripheral surface of the disc-shaped fiber block 11B. In any of the fiber blocks 11A and 11B, the basic surface 111 is the surface having the largest area among the plural surfaces of the fiber blocks 11A and 11B.

此種由2個基本面111及與兩基本面111交叉之骨架面112劃分形成之「定形之纖維集合體」即纖維塊11藉由使製造方法與先前技術不同而實現。如圖6所示,較佳之纖維塊11之製造方法係使用切割器等切斷器件將成為原料之原料纖維片材10bs(與纖維塊11為相同組成且尺寸大於纖維塊11之片材)切斷為定形。以此方式製造之複數個纖維塊11與利用如專利文獻2及3般之先前技術製造者相比,形狀及尺寸更定形地一致。圖6係說明圖5(a)之長方體形狀之纖維塊11A之製造方法之圖,圖6中之虛線表示切斷線。於吸收性芯體40中調配有以此方式將纖維片材切斷為定形而獲得之形狀及尺寸均勻之複數個纖維塊11。如上所述,作為原料纖維片材10bs,較佳為不織布。Such a "shaped fiber assembly", that is, a fiber block 11 formed by dividing two basic planes 111 and a skeleton plane 112 crossing the two basic planes 111, that is, the fiber block 11 is realized by making the manufacturing method different from the prior art. As shown in FIG. 6, a preferred method of manufacturing the fiber block 11 is to use a cutting device such as a cutter to cut the raw fiber sheet 10bs (a sheet having the same composition as the fiber block 11 and having a larger size than the fiber block 11). Broken to shape. The plurality of fiber blocks 11 manufactured in this way are more uniform in shape and size than those manufactured by the prior art as in Patent Documents 2 and 3. FIG. 6 is a diagram illustrating a method for manufacturing the rectangular parallelepiped fiber block 11A of FIG. 5 (a). The broken line in FIG. 6 indicates a cutting line. The absorbent core 40 is provided with a plurality of fiber blocks 11 having a uniform shape and size obtained by cutting the fiber sheet into a fixed shape in this way. As described above, the raw fiber sheet 10bs is preferably a non-woven fabric.

如圖6所示,圖5(a)之長方體形狀之纖維塊11A係藉由將原料纖維片材10bs於第1方向D1及與該第1方向D1交叉(更具體而言,為正交)之第2方向D2以特定之長度切斷而製造。兩方向D1、D2分別為片材10bs之面方向上之特定之一方向,片材10bs沿著與該面方向正交之厚度方向Z切斷。如此,於將原料纖維片材10bs切斷為所謂丁狀而獲得之複數個長方體形狀之纖維塊11A中,通常,其切斷面即片材10bs之切斷時與切割器等切斷器件接觸之面為骨架面112,非切斷面即不與該切斷器件接觸之面為基本面111。基本面111係片材10bs中之正面及背面(與厚度方向Z正交之面),又,如上所述,係纖維塊11A所具有之複數個面之中面積最大之面。As shown in FIG. 6, the rectangular parallelepiped fiber block 11A of FIG. 5 (a) is obtained by crossing the raw fiber sheet 10bs in the first direction D1 and crossing the first direction D1 (more specifically, orthogonally) The second direction D2 is cut with a specific length and manufactured. The two directions D1 and D2 are respectively a specific direction in the plane direction of the sheet 10bs, and the sheet 10bs is cut along the thickness direction Z orthogonal to the plane direction. In this manner, in the plurality of rectangular parallelepiped fiber blocks 11A obtained by cutting the raw fiber sheet 10bs into a so-called dicing shape, normally, the cut surface, that is, the cutting member, such as a cutter, comes into contact with the cutting device when cutting the sheet 10bs The surface is the skeleton surface 112, and the non-cut surface, that is, the surface that is not in contact with the cut device, is the basic surface 111. The basic surface 111 is the front surface and the back surface (the surface orthogonal to the thickness direction Z) of the sheet 10bs, and, as described above, is the surface having the largest area among the plural surfaces of the fiber block 11A.

再者,以上之關於纖維塊11A之說明亦基本上適用於圖5(b)之圓盤形狀之纖維塊11B。其與纖維塊11A之實質之不同僅為原料纖維片材10bs之切斷圖案,將片材10bs切斷為定形而獲得纖維塊11B時,只要與纖維塊11B之俯視形狀相應地將片材10bs切斷為圓形狀即可。Furthermore, the above description about the fiber block 11A is basically also applicable to the disk-shaped fiber block 11B of FIG. 5 (b). The essential difference from the fiber block 11A is only the cutting pattern of the raw fiber sheet 10bs. When the sheet 10bs is cut into a fixed shape to obtain the fiber block 11B, as long as the top view shape of the fiber block 11B corresponds to the sheet 10bs It can be cut into a round shape.

又,纖維塊11之外形形狀並不限定於圖5所示者,基本面111及骨架面112均可如圖5(a)之各面111、112般為不彎曲之平坦面,或者亦可如圖5(b)之骨架面112(圓盤形狀之纖維塊11B之周面)般為彎曲面。又,基本面111與骨架面112可為相互相同形狀相同尺寸,具體而言,例如,纖維塊11A之外形形狀可為立方體形狀。In addition, the outer shape of the fiber block 11 is not limited to that shown in FIG. 5, and the basic surface 111 and the skeleton surface 112 may be flat surfaces that are not curved like the surfaces 111, 112 of FIG. 5 (a), or may be As shown in FIG. 5 (b), the skeleton surface 112 (the peripheral surface of the disc-shaped fiber block 11B) is a curved surface. In addition, the basic surface 111 and the skeleton surface 112 may have the same shape and the same size. Specifically, for example, the outer shape of the fiber block 11A may be a cubic shape.

如上所述,纖維塊11(11A、11B)所具有之2種面(基本面111、骨架面112)分類為:切斷面(骨架面112),其於製造纖維塊11時由利用切割器等切斷器件之原料纖維片材10bs之切斷形成;及非切斷面(基本面111),其係片材10bs本來具有之面且不與該切斷器件接觸。並且,起因於是否為該切斷面之不同,切斷面即骨架面112具有與非切斷面即基本面111相比,纖維端部之每單位面積之數量更多之特徵。此處所言之「纖維端部」意指纖維塊11之構成纖維11F之長度方向端部。通常,纖維端部亦存在於非切斷面即基本面111,但骨架面112為由原料纖維片材10bs之切斷形成之切斷面,因此,包含由該切斷形成之構成纖維11F之切斷端部之纖維端部於骨架面112之整體存在多個,即,纖維端部之每單位面積之數量多於基本面111之每單位面積之數量。As described above, the two types of surfaces (basic surface 111, skeleton surface 112) of the fiber block 11 (11A, 11B) are classified as: the cut surface (skeletal surface 112), which is used by the cutter when manufacturing the fiber block 11 The raw fiber sheet 10bs of the cutting device is formed by cutting; and the non-cutting surface (basic surface 111), which is the surface that the sheet 10bs originally has and does not contact the cutting device. In addition, depending on whether the cut surface is different, the skeleton surface 112, which is a cut surface, has a feature that the number of fiber ends per unit area is larger than that of the basic surface 111, which is a non-cut surface. The "fiber end" mentioned here means the lengthwise end of the fiber 11F constituting the fiber 11F. Generally, the fiber end portion also exists on the non-cutting surface, that is, the basic surface 111, but the skeleton surface 112 is a cutting surface formed by cutting the raw fiber sheet 10bs, and therefore, includes the constituent fibers 11F formed by the cutting There are a plurality of fiber ends of the cut ends in the entire skeleton surface 112, that is, the number of fiber ends per unit area is greater than the number of base planes 111 per unit area.

存在於纖維塊11之各面(基本面111、骨架面112)之纖維端部對該纖維塊11與吸收性芯體40中包含之其他纖維塊11或吸水性纖維12F之間形成交絡有用。又,一般地,纖維端部之每單位面積之數量越多,越能提高交絡性,故而可提高吸收性芯體40之保形性等各特性。並且,如上所述,纖維塊11之各面中之纖維端部之每單位面積之數量並非均勻,關於該纖維端部之每單位面積之數量,「骨架面112>基本面111」之大小關係成立,故而經由纖維塊11之與其他纖維(其他纖維塊11、吸水性纖維12F)之交絡性根據該纖維塊11之面而不同,骨架面112與基本面111相比,交絡性更高。即,利用經由骨架面112之與其他纖維之交絡之結合與經由基本面111之結合相比結合力更強,於1個纖維塊11中,可利用基本面111及骨架面112使其與其他纖維之結合力產生差。一般地,該結合力越強,越限制其結合之纖維之移動之自由度,作為吸收性芯體40整體,強度(保形性)提高,反過來說,有柔軟度降低之傾向。The fiber ends present on each surface (basic surface 111, skeleton surface 112) of the fiber block 11 are useful for forming an intersection between the fiber block 11 and other fiber blocks 11 or the water-absorbent fibers 12F included in the absorbent core 40. In addition, generally, the greater the number of fiber end portions per unit area, the higher the cross-linkability, so that various characteristics such as shape retention of the absorbent core 40 can be improved. Also, as described above, the number of fiber ends per unit area in each face of the fiber block 11 is not uniform. Regarding the number of fiber ends per unit area, the size relationship of "skeletal plane 112> basic plane 111" Since it is established, the intertwinability between the fiber block 11 and other fibers (other fiber block 11 and water-absorbent fiber 12F) differs according to the surface of the fiber block 11, and the skeleton surface 112 has higher intertwinability than the basic surface 111. That is, the combination of the intersection with other fibers through the skeleton surface 112 is stronger than the combination through the basic surface 111. In one fiber block 11, the basic surface 111 and the skeleton surface 112 can be used to make it with other fibers The binding force of the fibers is poor. In general, the stronger the binding force, the more restrictive the freedom of movement of the fibers to be bonded. As the absorbent core 40 as a whole, the strength (shape retention) is improved, and conversely, the softness tends to decrease.

如此,於吸收性芯體40中,包含於其中之複數個纖維塊11各者對其周邊之其他纖維(其他纖維塊11、吸水性纖維12F)具有2種結合力而交絡,藉此,吸收性芯體40兼具適度之柔軟度與強度(保形性)。並且,於根據慣例將具有此種優異之特性之吸收性芯體40用作吸收性物品之吸收體之情形時,可對該吸收性物品之穿著者提供舒適之穿著感,並且有效地防止因穿著時之穿著者之體壓等外力而破壞吸收性芯體40之不良狀況。In this way, in the absorbent core 40, each of the plurality of fiber blocks 11 contained therein has two kinds of binding forces for other fibers (other fiber blocks 11, water-absorbent fibers 12F) around it to intersect, thereby absorbing The sexual core 40 has both moderate softness and strength (shape retention). Moreover, when the absorbent core 40 having such excellent characteristics is used as the absorbent body of an absorbent article according to the conventional practice, the wearer of the absorbent article can be provided with a comfortable wearing feeling, and effectively prevent When wearing, the wearer's body pressure and other external forces destroy the bad condition of the absorbent core 40.

尤其是,如上所述,圖5所示之纖維塊11(11A、11B)之2個基本面111之總面積大於骨架面112之總面積。因此,意味著,纖維端部之每單位面積之數量相對較少,因而與其他纖維之交絡性相對較低之基本面111與具有與其相反之性質之骨架面112相比,總面積更大。因此,圖5所示之纖維塊11(11A、11B)與纖維端部均勻地存在於表面整體之纖維塊相比,更易於抑制與周邊之其他纖維(其他纖維塊11、吸水性纖維12F)之交絡,又,即便與周邊之其他纖維交絡,亦易於以相對較弱之結合力交絡,因此,不易成為較大之團塊,可對吸收性芯體40賦予優異之柔軟性。In particular, as described above, the total area of the two basic surfaces 111 of the fiber block 11 (11A, 11B) shown in FIG. 5 is greater than the total area of the skeleton surface 112. Therefore, it means that the number of fiber ends per unit area is relatively small, so that the total area of the basic surface 111 with relatively low crosstalk with other fibers is larger than that of the skeleton surface 112 with the opposite properties. Therefore, the fiber block 11 (11A, 11B) shown in FIG. 5 is easier to suppress other fibers (other fiber block 11, water-absorbent fiber 12F) than the fiber block in which the fiber ends are uniformly present on the entire surface. The entanglement, even when entangled with other fibers in the periphery, is also apt to entangle with a relatively weak binding force. Therefore, it is not easy to become a large lump, and the absorbent core 40 can be provided with excellent flexibility.

相對於此,如上所述,專利文獻2及3中記載之不織布片或微細纖維網係利用如銑刀般之切斷機將原料纖維片材切斷為不定形等而製造,故而不會成為具有如基本面111或骨架面112般之「面」之定形之薄片狀之纖維塊,並且,於其製造時切斷處理之外力施加於纖維塊整體,故而構成纖維之纖維端部會隨機地形成於纖維塊整體,難以充分顯現由該纖維端部產生之上述作用效果。On the other hand, as described above, the non-woven fabric sheet or fine fiber web described in Patent Documents 2 and 3 is manufactured by cutting the raw fiber sheet into an indefinite shape using a cutter like a milling cutter, so it does not become A sheet-shaped fiber block having a "face" shaped like a basic surface 111 or a skeleton surface 112, and a force outside the cutting process is applied to the entire fiber block during its manufacture, so the fiber ends constituting the fiber are randomly It is formed in the entire fiber block, and it is difficult to sufficiently express the above-mentioned action effect produced by the fiber end.

就更確實地取得上述由纖維端部所產生之作用效果之觀點而言,基本面111(非切斷面)之纖維端部之每單位面積之數量N1 與骨架面112(切斷面)之纖維端部之每單位面積之數量N2 之比率在N1 <N2 之前提下,作為N1 /N2 ,較佳為0以上,進而較佳為0.05以上,並且,較佳為0.90以下,進而較佳為0.60以下。更具體而言,N1 /N2 較佳為0以上且0.90以下,進而較佳為0.05以上且0.60以上。
基本面111之纖維端部之每單位面積之數量N1 較佳為0個/mm2 以上,進而較佳為3個/mm2 以上,並且,較佳為8個/mm2 以下,進而較佳為6個/mm2 以下。
骨架面112之纖維端部之每單位面積之數量N2 較佳為5個/mm2 以上,進而較佳為8個/mm2 以上,並且,較佳為50個/mm2 以下,進而較佳為40個/mm2 以下。
基本面111、骨架面112之纖維端部之每單位面積之數量藉由以下之方法測定。
From the viewpoint of more surely obtaining the above-mentioned effect by the fiber end, the number N 1 per unit area of the fiber end of the basic surface 111 (non-cut surface) and the skeleton surface 112 (cut surface) The ratio of the number N 2 of the fiber end per unit area is raised before N 1 <N 2. As N 1 / N 2 , it is preferably 0 or more, more preferably 0.05 or more, and preferably 0.90 The following is more preferably 0.60 or less. More specifically, N 1 / N 2 is preferably 0 or more and 0.90 or less, and more preferably 0.05 or more and 0.60 or more.
The number N 1 per unit area of the fiber end of the basic surface 111 is preferably 0 pieces / mm 2 or more, and more preferably 3 pieces / mm 2 or more, and, preferably, 8 pieces / mm 2 or less, and further It is preferably 6 pieces / mm 2 or less.
The number N 2 per unit area of the fiber end of the skeleton surface 112 is preferably 5 pieces / mm 2 or more, more preferably 8 pieces / mm 2 or more, and, preferably, 50 pieces / mm 2 or less, and more It is preferably 40 pieces / mm 2 or less.
The number of fiber ends of the basic surface 111 and the skeleton surface 112 per unit area is measured by the following method.

<纖維塊之各面中之纖維端部之每單位面積之數量之測定方法>
針對包含測定對象之纖維之構件(纖維塊),使用雙面紙膠帶(米其邦股份有限公司製造之NICETACK NW-15),將測定片貼附於試樣台。繼而,對測定片塗佈鉑。塗佈係使用日立那珂精器股份有限公司製造之離子濺鍍裝置E-1030型(商品名),濺鍍時間設為120秒。針對測定片之切斷面,使用JEOL(股)製造之JCM-6000型之電子顯微鏡,以倍率100倍觀察基本面及骨架面。於該倍率100倍之觀察畫面中,於測定對象面(基本面或骨架面)之任意之位置設定縱1.2 mm、橫0.6 mm之長方形區域,且以該長方形區域之面積占該觀察畫面之面積之90%以上之方式調整觀察角度等之後,測定該長方形區域內包含之纖維端部之個數。其中,於倍率100倍之觀察畫面中,纖維塊之測定對象面小於1.2 mm×0.6 mm且上述長方形區域之面積占該觀察畫面整體之比率未達90%之情形時,使觀察倍率大於100倍之後,與上述同樣地測定該測定對象面中之上述長方形區域內包含之纖維端部之數量。此處,成為個數測定之對象之「纖維端部」係纖維塊之構成纖維之長度方向端部,即便該構成纖維之除長度方向端部以外之部分(長度方向中間部)自測定對象面延出,該長度方向中間部亦不設為個數測定之對象。然後,藉由下述式算出纖維塊之測定對象面(基本面或骨架面)中之纖維端部之每單位面積之數量。針對10個纖維塊各者,依據上述順序,測定基本面及骨架面各者中之纖維端部之每單位面積之數量,將該等複數個測定值之平均值設為該測定對象面中之纖維端部之每單位面積之數量。
纖維塊之測定對象面(基本面或骨架面)中之纖維端部之每單位面積之數量(個數/mm2 )=長方形區域(1.2×0.6 mm)中包含之纖維端部之個數/該長方形區域之面積(0.72 mm2 )
<Method for measuring the number of fiber ends per unit area on each face of the fiber block>
For the member (fiber block) containing the fiber to be measured, double-sided paper tape (NICETACK NW-15 manufactured by Mi Qibang Co., Ltd.) was used, and the measurement piece was attached to the sample stage. Then, platinum was coated on the measurement piece. For the coating system, an ion sputtering apparatus model E-1030 (trade name) manufactured by Hitachi Naka Seiki Co., Ltd. was used, and the sputtering time was set to 120 seconds. For the cut surface of the measuring piece, a JCM-6000 type electron microscope manufactured by JEOL Co., Ltd. was used to observe the basic surface and the skeleton surface at a magnification of 100 times. In the observation screen with a magnification of 100 times, set a rectangular area of 1.2 mm in length and 0.6 mm in width at any position of the measurement target surface (basic surface or skeleton surface), and the area of the rectangular area accounts for the area of the observation screen After adjusting the viewing angle by 90% or more, measure the number of fiber ends included in the rectangular area. In the case of an observation screen with a magnification of 100 times, when the measurement target surface of the fiber block is less than 1.2 mm × 0.6 mm and the area of the rectangular area accounts for less than 90% of the entire observation screen, the observation magnification is greater than 100 times Thereafter, the number of fiber ends included in the rectangular area in the measurement target surface is measured in the same manner as described above. Here, the “fiber end” which is the object of the number measurement is the longitudinal end of the constituent fibers of the fiber block, even if the portion of the constituent fiber other than the longitudinal end (the middle in the longitudinal direction) is from the measurement target surface Extending, the middle part in the longitudinal direction is not subject to the number measurement. Then, the number per unit area of the fiber end portion in the measurement target surface (basic surface or skeleton surface) of the fiber block is calculated by the following formula. For each of the 10 fiber blocks, the number of fiber ends per unit area in each of the basic surface and the skeleton surface is measured according to the above sequence, and the average value of the plurality of measurement values is set as the measurement target surface. The number of fiber ends per unit area.
The number of fiber ends per unit area (number / mm 2 ) in the measurement target surface (basic surface or skeleton surface) of the fiber block = the number of fiber ends included in the rectangular area (1.2 × 0.6 mm) / The area of the rectangular area (0.72 mm 2 )

於纖維塊11之基本面111如圖5(a)所示之纖維塊11A般於俯視下呈長方形形狀之情形時,就吸收體4中之纖維塊11之均勻分散性之提高之觀點而言,該長方形形狀之短邊111a較佳為與含有該纖維塊11(11A)之吸收性芯體40之厚度同等或與其相比更短。短邊111a之長度與吸收性芯體40之厚度之比率以前者/後者計較佳為0.03以上,進而較佳為0.08以上,並且,較佳為1以下,進而較佳為0.5以下。
吸收性芯體40之厚度較佳為1 mm以上,進而較佳為2 mm以上,並且,較佳為15 mm以下,進而較佳為10 mm以下。吸收性芯體40之厚度利用以下之方法測定。
In the case where the basic surface 111 of the fiber block 11 has a rectangular shape in plan view as the fiber block 11A shown in FIG. 5 (a), from the viewpoint of improving the uniform dispersion of the fiber block 11 in the absorber 4 The short side 111a of the rectangular shape is preferably equal to or shorter than the thickness of the absorbent core 40 containing the fiber block 11 (11A). The ratio of the length of the short side 111a to the thickness of the absorbent core 40 is preferably 0.03 or more, more preferably 0.08 or more, and preferably 1 or less, and more preferably 0.5 or less.
The thickness of the absorbent core 40 is preferably 1 mm or more, and more preferably 2 mm or more, and, preferably, 15 mm or less, and more preferably 10 mm or less. The thickness of the absorbent core 40 is measured by the following method.

<吸收體之厚度之測定方法>
將測定對象物(吸收性芯體40)以不發生皺褶或彎折之方式靜置於水平之位置,並測定5 cN/cm2 之負載下之測定對象物之厚度。具體而言,厚度之測定例如使用厚度計 PEACOCK DIAL UPRIGHT GAUGES R5-C(OZAKI MFG.CO.LTD.製造)。
此時,於厚度計之前端部與剪切之測定對象物之間配置以對測定對象物之負載成為5 cN/cm2 之方式調整了大小之俯視圓形狀或正方形狀之平板(厚度5 mm左右之丙烯酸系樹脂板),並測定厚度。厚度測定係測定10處,算出其等之平均值並將其作為測定對象物之厚度。
<Measurement method of thickness of absorber>
The object to be measured (absorbent core 40) was placed at a horizontal position without wrinkling or bending, and the thickness of the object to be measured under a load of 5 cN / cm 2 was measured. Specifically, for the thickness measurement, for example, a thickness gauge PEACOCK DIAL UPRIGHT GAUGES R5-C (manufactured by OZAKI MFG.CO. LTD.) Is used.
At this time, a flat plate (thickness 5 mm in thickness) with a round or square shape in plan view adjusted between the front end of the thickness gauge and the sheared measurement object so that the load on the measurement object becomes 5 cN / cm 2 Left and right acrylic resin plates), and measure the thickness. The thickness measurement system measures 10 locations, calculates the average value thereof, and uses it as the thickness of the object to be measured.

纖維塊11(11A、11B)之各部之尺寸等較佳為如下所示般設定。纖維塊11之各部之尺寸可基於下述纖維塊11之外形形狀之特定作業時之電子顯微鏡照片等進行測定。
於基本面111為如圖5(a)所示之俯視長方形形狀之情形時,其短邊111a之長度L1較佳為0.3 mm以上,進而較佳為0.5 mm以上,並且,較佳為10 mm以下,進而較佳為6 mm以下。俯視長方形形狀之基本面111之長邊111b之長度L2較佳為0.3 mm以上,進而較佳為2 mm以上,並且,較佳為30 mm以下,進而較佳為15 mm以下。
再者,如圖5所示,於基本面111為纖維塊11所具有之複數個面之中具有最大面積之面之情形時,長邊111b之長度L2與纖維塊11之最大兩端間距長度一致,該最大兩端間距長度與圓盤形狀之纖維塊11B中之俯視圓形狀之基本面111之直徑一致。
短邊111a之長度L1與長邊111b之長度L2之比率以L1/L2計較佳為0.003以上,進而較佳為0.025以上,並且,較佳為1以下,進而較佳為0.5以下。再者,於本發明中,基本面111之俯視形狀並不限定於如圖5(a)所示之長方形形狀,亦可為正方形形狀,即,相互正交之2邊之長度L1、L2之比率以L1/L2計亦可為1。
纖維塊11之厚度T,即,2個對向之基本面111間之長度T較佳為0.1 mm以上,進而較佳為0.3 mm以上,並且,較佳為10 mm以下,進而較佳為6 mm以下。
The size and the like of each part of the fiber block 11 (11A, 11B) are preferably set as shown below. The size of each part of the fiber block 11 can be measured based on the following electron microscope photographs of the specific operation of the outer shape of the fiber block 11.
When the basic surface 111 is a rectangular shape as shown in FIG. 5 (a) in plan view, the length L1 of the short side 111a is preferably 0.3 mm or more, further preferably 0.5 mm or more, and, preferably 10 mm Below, and further preferably 6 mm or less. The length L2 of the long side 111b of the basic surface 111 of the rectangular shape in plan view is preferably 0.3 mm or more, more preferably 2 mm or more, and, preferably, 30 mm or less, and more preferably 15 mm or less.
Furthermore, as shown in FIG. 5, when the basic surface 111 is the surface having the largest area among the plurality of surfaces of the fiber block 11, the length L2 of the long side 111 b and the maximum distance between the two ends of the fiber block 11 Consistently, the maximum length of the two ends is the same as the diameter of the base surface 111 of the circular-shaped fiber block 11B in the plan view.
The ratio of the length L1 of the short side 111a to the length L2 of the long side 111b in terms of L1 / L2 is preferably 0.003 or more, more preferably 0.025 or more, and preferably 1 or less, and more preferably 0.5 or less. Furthermore, in the present invention, the top view shape of the basic surface 111 is not limited to the rectangular shape as shown in FIG. 5 (a), but may also be a square shape, that is, the lengths L1 and L2 of the two orthogonal sides The ratio can also be 1 in terms of L1 / L2.
The thickness T of the fiber block 11, that is, the length T between the two opposed basic surfaces 111 is preferably 0.1 mm or more, and more preferably 0.3 mm or more, and, preferably, 10 mm or less, and more preferably 6 mm or less.

又,吸收性芯體40較佳為具有力學各向同性,以便於該吸收性芯體40之所有面易於取得起因於纖維塊11之存在之作用效果。因此,較佳為纖維塊11高密度且均勻地分佈於吸收性芯體40之整體。就該觀點而言,較佳為,於吸收性芯體40之相互正交之2個方向之投影觀察下,複數個纖維塊11之重疊部存在於任意之10 mm見方之單位區域中。圖3及圖4中之符號11Z表示複數個纖維塊11之重疊部。作為此處所言之「相互正交之2個方向之投影觀察」,典型而言,可列舉:吸收性芯體(吸收體)之厚度方向之投影觀察(即,針對吸收性芯體,自其肌膚對向面或非肌膚對向面觀察之情形)、及與該厚度方向正交之方向之投影觀察(即,針對吸收性芯體,自其側面觀察之情形)。In addition, the absorbent core 40 preferably has mechanical isotropy, so that all the surfaces of the absorbent core 40 can easily obtain the effect due to the presence of the fiber block 11. Therefore, it is preferable that the fiber blocks 11 are distributed at a high density and uniformly throughout the absorbent core 40. From this point of view, it is preferable that the overlapping portions of the plurality of fiber blocks 11 exist in an arbitrary unit area of 10 mm square when viewed in projections in two directions orthogonal to each other of the absorbent core 40. Symbols 11Z in FIGS. 3 and 4 indicate overlapping portions of the plurality of fiber blocks 11. As the "projection observation in two directions orthogonal to each other" mentioned here, typically, the projection observation in the thickness direction of the absorbent core (absorber) can be cited (that is, for the absorbent core, from Skin-facing surface or non-skin-facing surface), and projection observation in a direction orthogonal to the thickness direction (that is, when the absorbent core is viewed from its side).

圖7(a)表示本發明之纖維塊之一實例之電子顯微鏡照片,圖7(b)表示依照該電子顯微鏡照片模式性地表示纖維塊11之圖。如圖7所示,吸收性芯體40中包含之複數個纖維塊11中可包含具有本體部110、及包含自該本體部110向外側延出之纖維11F而構成且與該本體部110相比纖維密度更低(每單位面積之纖維之數量更少)之延出纖維部113者。再者,吸收性芯體40中亦可包含不具有延出纖維部113之纖維塊11,即僅包含本體部110之纖維塊11。延出纖維部113係上述存在於纖維塊11之各面(基本面111、骨架面112)之纖維端部之一種,係該纖維端部之中自纖維塊11之各面向外側延出之纖維端部。7 (a) shows an electron microscope photograph of an example of the fiber block of the present invention, and FIG. 7 (b) shows a diagram schematically showing the fiber block 11 according to the electron microscope photo. As shown in FIG. 7, the plurality of fiber blocks 11 included in the absorbent core 40 may include a body portion 110 and fibers 11F extending from the body portion 110 to the outside and formed with the body portion 110. Those with a lower fiber density (less number of fibers per unit area) extend out of the fiber portion 113. Furthermore, the absorbent core 40 may also include the fiber block 11 without the extended fiber portion 113, that is, the fiber block 11 including only the body portion 110. The extended fiber portion 113 is one of the fiber ends existing on each surface (basic surface 111, skeleton surface 112) of the fiber block 11 described above, and is a fiber extending out of each surface of the fiber block 11 among the fiber ends Ends.

本體部110係由上述2個對向之基本面111、及連結兩基本面111之骨架面112劃分形成之部分。本體部110係構成纖維塊11之主體且形成纖維塊11之定形之外形形狀之部分,纖維塊11所具有之較高之柔軟性、緩衝性、壓縮回覆性等各特性基本上很大程度上取決於本體部110。另一方面,延出纖維部113主要有助於吸收性芯體40中含有之複數個纖維塊11彼此或纖維塊11與吸水性纖維12F之交絡性之提高,與吸收性芯體40之保形性之提高直接相關,除此以外,亦影響纖維塊11之吸收性芯體40中之均勻分散性等,可間接地補強由本體部110產生之作用效果。The body portion 110 is a portion formed by dividing the two opposing basic surfaces 111 and the skeleton surface 112 connecting the two basic surfaces 111. The body portion 110 is the part that constitutes the main body of the fiber block 11 and forms the fixed shape of the fiber block 11. The various characteristics of the fiber block 11 such as high flexibility, cushioning, compression and resilience are largely largely Depends on the body part 110. On the other hand, the extended fiber portion 113 mainly contributes to the improvement of the intertwining property between the plurality of fiber blocks 11 contained in the absorbent core 40 or between the fiber blocks 11 and the water-absorbent fibers 12F, and the protection of the absorbent core 40 The improvement in formability is directly related, and in addition, it also affects the uniform dispersion in the absorbent core 40 of the fiber block 11, etc., and can indirectly reinforce the effect produced by the body portion 110.

本體部110與延出纖維部113相比,纖維密度更高,即,每單位面積之纖維之數量更多。又,通常,本體部110本身之纖維密度均勻。本體部110占纖維塊11之總質量之比率通常為至少40質量%以上,較佳為50質量%以上,進而較佳為60質量%以上,尤佳為85質量%以上。本體部110與延出纖維部113可藉由下述外形形狀之特定作業而區分。The body portion 110 has a higher fiber density than the extended fiber portion 113, that is, the number of fibers per unit area is greater. Also, generally, the fiber density of the body portion 110 itself is uniform. The ratio of the body portion 110 to the total mass of the fiber block 11 is usually at least 40% by mass or more, preferably 50% by mass or more, further preferably 60% by mass or more, and particularly preferably 85% by mass or more. The main body portion 110 and the extended fiber portion 113 can be distinguished by a specific operation of the outline shape described below.

特定出吸收性芯體40中包含之纖維塊11之本體部110之外形形狀之作業可藉由著眼於吸收性芯體40中之纖維密度之高低差(每單位面積之纖維數之多少)或纖維之種類、纖維直徑之不同等,並確認本體部110與除此以外之部分之「邊界」而進行。本體部110與存在於其周圍之延出纖維部113相比,纖維密度更高,又,通常,作為本體部110之構成纖維之合成纖維與吸水性纖維12F(典型而言,為纖維素系纖維)存在質量及/或尺寸之不同,故而即便為多個纖維塊11及吸水性纖維12F混合存在之吸收性芯體40,亦可藉由著眼於上述方面而容易地確認上述邊界。以此方式確認之邊界係基本面111或骨架面112之周緣(邊),藉由該邊界確認作業而特定出基本面111及骨架面112,進而特定出本體部110。該邊界確認作業可藉由使用電子顯微鏡,視需要以複數個觀察角度觀察對象物(吸收性芯體40)而實施。尤其於吸收性芯體40中包含之纖維塊11為如圖5所示之纖維塊11A、11B般之「2個基本面111之總面積大於骨架面112之總面積」者之情況下,尤其於基本面111成為該纖維塊11之具有最大面積之面之情形時,可相對較容易地特定出該較大面積之基本面111,故而可順利地進行本體部110之外形形狀之特定作業。The operation of specifying the outer shape of the body portion 110 of the fiber block 11 included in the absorbent core 40 can be achieved by focusing on the difference in the fiber density in the absorbent core 40 (the number of fibers per unit area) or The type of fiber, the difference in fiber diameter, etc. are confirmed by checking the "boundary" between the main body 110 and other parts. The body portion 110 has a higher fiber density than the extended fiber portion 113 existing around it. In general, the synthetic fibers and the water-absorbent fibers 12F (typically, cellulose-based fibers) constituting the fibers of the body portion 110 (Fibers) differ in quality and / or size, so even if the absorbent core 40 in which a plurality of fiber blocks 11 and water-absorbent fibers 12F are mixed, the above-mentioned boundary can be easily confirmed by focusing on the above aspects. The boundary confirmed in this way is the periphery (edge) of the basic surface 111 or the skeleton surface 112, and the basic surface 111 and the skeleton surface 112 are specified by the boundary confirmation operation, and then the body portion 110 is specified. This boundary confirmation operation can be performed by using an electron microscope to observe the object (absorbent core 40) at a plurality of observation angles as necessary. Especially in the case where the fiber block 11 included in the absorbent core 40 is like the fiber blocks 11A and 11B shown in FIG. 5, "the total area of the two basic surfaces 111 is greater than the total area of the skeleton surface 112", especially When the base surface 111 becomes the surface with the largest area of the fiber block 11, the base surface 111 with a larger area can be specified relatively easily, so that the outer shape of the body portion 110 can be smoothly specified.

如圖7所示,延出纖維部113包含自形成本體部110之外表面之基本面111及骨架面112之中之至少1個面向外側延出之本體部110之構成纖維11F。圖7係自基本面111(纖維塊11之複數個面之中具有最大面積之面)側俯視纖維塊11之圖,纖維11F自與該基本面111交叉之骨架面112延出多個而形成延出纖維部113。As shown in FIG. 7, the extended fiber portion 113 includes constituent fibers 11F of the main body portion 110 extending outward from at least one of the basic surface 111 and the skeleton surface 112 forming the outer surface of the main body portion 110. FIG. 7 is a plan view of the fiber block 11 from the side of the base surface 111 (the surface having the largest area among the plurality of surfaces of the fiber block 11), and the fibers 11F are formed by extending a plurality of skeleton surfaces 112 crossing the base surface 111.延 出 纤维 部 113.

延出纖維部113之形態並無特別限制。延出纖維部113既存在包含1條纖維11F之情況,又存在如下述延出纖維束部113S般包含複數條纖維11F之情況。又,延出纖維部113包含自本體部110延出之纖維11F之長度方向端部,但存在除了此種纖維端部以外亦可包含纖維11F之除長度方向兩端部以外之部分(長度方向中間部)之情況。即,於纖維塊11中,存在構成纖維11F之長度方向之兩端部存在於本體部110且除此以外之部分即長度方向中間部自本體部110向外側以環狀延出(突出)之情況,此時,此情形時之延出纖維部113包含該纖維11F之環狀之突出部而構成。The shape of the extended fiber portion 113 is not particularly limited. The extended fiber portion 113 may include one fiber 11F, and may include a plurality of fibers 11F as the extended fiber bundle portion 113S described below. Further, the extended fiber portion 113 includes the lengthwise end of the fiber 11F extending from the body portion 110, but there may be portions other than such fiber ends (excluding the both ends in the longitudinal direction) Middle section). That is, in the fiber block 11, there are both ends in the longitudinal direction constituting the fiber 11F in the body portion 110, and the other portion, that is, the middle portion in the longitudinal direction extends (protrudes) outward from the body portion 110 in a ring shape In this case, the extended fiber portion 113 in this case includes an annular protruding portion of the fiber 11F.

如上所述,延出纖維部113之主要作用之一係使吸收性芯體40中含有之複數個纖維塊11彼此、或纖維塊11與吸水性纖維12F相互交絡。一般地,若延出纖維部113自本體部110之延出長度變長,或延出纖維部113之粗細度變粗,或1個纖維塊11所具有之延出纖維部113之數量變多,則經由該延出纖維部113而交絡之物體彼此之連結變強而不易解除交絡,故而更進一步穩定地取得本發明之特定之效果。As described above, one of the main functions of the extended fiber portion 113 is to make the plural fiber blocks 11 contained in the absorbent core 40 intersect each other, or the fiber blocks 11 and the water-absorbent fibers 12F intersect each other. Generally, if the extension length of the extended fiber portion 113 from the main body portion 110 becomes longer, or the thickness of the extended fiber portion 113 becomes thicker, or the number of extended fiber portions 113 of one fiber block 11 increases , The connection between the objects interlaced through the extended fiber portion 113 becomes stronger and it is not easy to release the interlacing, so the specific effects of the present invention can be obtained more stably.

於纖維塊11係如圖6所示般將原料纖維片材10bs切斷為定形而獲得者之情形時,延出纖維部113相對較多地存在於其切斷面即骨架面112,相對於此,完全不存在於非切斷面即基本面111,或者即便存在,其數量亦少於骨架面112。如此,延出纖維部113偏集存在於作為切斷面之骨架面112之理由在於,延出纖維部113之多數係由原料纖維片材之切斷而產生之「細毛」。即,由原料纖維片材10bs之切斷形成之骨架面112於其切斷時藉由切割器等切斷器件而被整體地摩擦,故而易於形成包含片材10bs之構成纖維11F之細毛,易發生所謂的起毛。雖然亦根據原料纖維片材之種類而不同,但若縮短切斷線之間隔、或放慢切斷速度等,則易於形成延出纖維部113,其長度亦可調整。另一方面,非切斷面即基本面111並未發生此種與切斷器件之摩擦,故而不易形成細毛即延出纖維部113。In the case where the fiber block 11 is obtained by cutting the raw fiber sheet 10bs into a fixed shape as shown in FIG. 6, the extended fiber portion 113 is relatively present on the skeleton surface 112, which is the cut surface, relative to the Therefore, it does not exist at all on the non-cut surface, that is, the basic surface 111, or even if it exists, the number is less than the skeleton surface 112. In this way, the reason why the extended fiber portion 113 exists on the skeleton surface 112 as a cut surface is that most of the extended fiber portion 113 is "fine hair" generated by cutting the raw fiber sheet. That is, the skeleton surface 112 formed by the cutting of the raw fiber sheet 10bs is rubbed as a whole by a cutting device such as a cutter when it is cut, so it is easy to form fine hairs including the constituent fibers 11F of the sheet 10bs, and easy So-called fluff occurs. Although it also differs depending on the type of the raw fiber sheet, if the interval between the cutting lines is shortened or the cutting speed is slowed, the extended fiber portion 113 can be easily formed, and the length can be adjusted. On the other hand, the non-cutting surface, that is, the basic surface 111, does not have such friction with the cutting device, so it is not easy to form fine hairs and extend out of the fiber portion 113.

原料纖維片材10bs切斷時之切斷線之間隔L1a(第1方向之間隔,參照圖6)及間隔L2a(第2方向之間隔,參照圖6)就上述延出纖維部113之形成促進等觀點、及確保在纖維塊11顯現特定之效果之方面所必要之尺寸之觀點等而言,較佳為0.3 mm以上,進而較佳為0.5 mm以上,並且,較佳為30 mm以下,進而較佳為15 mm以下。The interval L1a (interval in the first direction, refer to FIG. 6) and the interval L2a (interval in the second direction, refer to FIG. 6) at the time of cutting of the raw fiber sheet 10bs facilitate the formation of the extended fiber portion 113 From the viewpoints such as and the viewpoint of ensuring the size necessary for the fiber block 11 to exhibit a specific effect, it is preferably 0.3 mm or more, more preferably 0.5 mm or more, and, preferably, 30 mm or less, and further It is preferably 15 mm or less.

如圖7所示,纖維塊11具有包含自本體部110、更具體而言自骨架面112向外側延伸之複數條纖維11F之延出纖維束部113S作為延出纖維部113之一種。纖維塊11所具有之延出纖維部113中之至少1個可為該延出纖維束部113S。延出纖維束部113S係自骨架面112延出之複數條纖維11F聚集而構成者,在與延出纖維部113相比自骨架面112之延出長度更長之方面被賦予了特徵。延出纖維束部113S亦可存在於基本面111,但典型而言,如圖7所示,存在於骨架面112,完全不存在於基本面111,或者即便存在,其數量亦少於骨架面112。其理由與延出纖維部113主要存在於切斷面即骨架面112之理由相同,如上所述。As shown in FIG. 7, the fiber block 11 has an extended fiber bundle portion 113S including a plurality of fibers 11F extending outward from the main body portion 110, more specifically, from the skeleton surface 112 as one of the extended fiber portions 113. At least one of the extended fiber portions 113 of the fiber block 11 may be the extended fiber bundle portion 113S. The extended fiber bundle portion 113S is composed of a plurality of fibers 11F extended from the skeleton surface 112, and is characterized by a longer extension length from the skeleton surface 112 than the extended fiber portion 113. The extended fiber bundle portion 113S may also exist on the base surface 111, but typically, as shown in FIG. 7, it exists on the skeleton surface 112, and does not exist on the base surface 111 at all, or even if it exists, the number is less than the skeleton surface 112. The reason is the same as the reason that the extended fiber portion 113 mainly exists on the skeleton surface 112 which is a cut surface, as described above.

纖維塊11具有此種亦可稱為長且粗之大型之延出纖維部113之延出纖維束部113S,藉此,纖維塊11彼此或纖維塊11與吸水性纖維12F之交絡更進一步增強,其結果為,更進一步穩定地取得起因於纖維塊11之存在的本發明之特定之效果。延出纖維束部113S易於藉由實施上述易於起毛之條件下之原料纖維片材10bs之切斷(參照圖6)而形成。The fiber block 11 has such an extended fiber bundle portion 113S, which can also be called a long and thick large extended fiber portion 113, whereby the intersection between the fiber blocks 11 or the fiber block 11 and the water-absorbent fiber 12F is further enhanced As a result, the specific effect of the present invention due to the presence of the fiber block 11 can be obtained more stably. The extended fiber bundle portion 113S is easily formed by performing the cutting of the raw fiber sheet 10bs under the above-described condition that is easy to fluff (see FIG. 6).

延出纖維束部113S自本體部110之延出長度即自骨架面112(切斷面)之延出長度較佳為0.05 mm以上,進而較佳為0.15 mm以上,並且,較佳為7 mm以下,進而較佳為4 mm以下。延出纖維束部113S之延出長度可於上述纖維塊11之外形形狀之特定作業(邊界確認作業)中測定。具體而言,例如,利用基恩士製造之顯微鏡(50倍率),將3M(股)製造之雙面膠帶貼在丙烯酸製之透明之樣本台之表面,於其上載置纖維塊11並進行固定,然後,根據上述外形形狀之特定作業,特定出該纖維塊11之外形形狀之後,測定自該外形形狀延出之纖維11F中之延出部分之長度,並將該測得之延出部分之長度設為延出纖維束部113S之延出長度。The extension length of the extended fiber bundle portion 113S from the body portion 110, that is, the extension length from the skeleton surface 112 (cut surface) is preferably 0.05 mm or more, and more preferably 0.15 mm or more, and, preferably, 7 mm Below, and further preferably 4 mm or less. The extended length of the extended fiber bundle portion 113S can be measured in the specific operation (boundary confirmation operation) of the outer shape of the fiber block 11 described above. Specifically, for example, using a microscope manufactured by Keyence (50 times magnification), a double-sided tape made of 3M (share) is attached to the surface of a transparent sample stage made of acrylic, and the fiber block 11 is placed thereon and fixed Then, after specifying the outer shape of the fiber block 11 according to the above-mentioned specific operation of the outer shape, the length of the extended portion of the fiber 11F extending from the outer shape is measured, and the measured extended portion The length is defined as the extended length of the extended fiber bundle portion 113S.

延出纖維束部113S較佳為其複數個構成纖維11F相互熱熔。該延出纖維束部113S之熱熔部通常與該延出纖維束部113S之其他部分(非熱熔部)相比,該延出纖維束部113S之與長度方向正交之方向之兩端間距長度(於該熱熔部之剖面為圓形之情形時,為直徑)更長。藉由使延出纖維束部113S具有此種亦可稱為大徑部之熱熔部,延出纖維束部113S本身之強度提高,藉此,經由延出纖維束部113S而交絡之纖維塊11彼此或纖維塊11與吸水性纖維12F之交絡更進一步增強。又,若延出纖維束部113S具有熱熔部,則具有如下優點:不僅於該延出纖維束部113S處於乾燥狀態之情形時,而且於吸收水分而成為濕潤狀態之情形時,該延出纖維束部113S本身之強度、保形性等亦得以提高。並且,藉由該優點,於將吸收性芯體40應用於吸收性物品之情形時,吸收性芯體40為乾燥狀態之情況自不待言,即便於吸收穿著者所排泄之尿或經血等體液而成為濕潤狀態之情形時,亦可穩定地取得上述起因於纖維塊11之存在之作用效果。此種具有熱熔部之延出纖維束部113S可藉由在如圖6所示之纖維塊11之製造步驟即纖維塊11之原料纖維片材10bs之切斷步驟中,使用上述「具有構成纖維彼此之熱熔部之纖維片材」作為原料纖維片材10bs而製造。The extended fiber bundle portion 113S is preferably such that a plurality of constituent fibers 11F are thermally fused with each other. The hot-melt portion of the extended fiber bundle portion 113S is usually compared with the other portion (non-hot-melt portion) of the extended fiber bundle portion 113S, and both ends of the extended fiber bundle portion 113S in the direction orthogonal to the longitudinal direction The pitch length (the diameter when the cross section of the hot-melt portion is circular) is longer. By making the extended fiber bundle portion 113S have such a hot-melt portion which can also be referred to as a large-diameter portion, the strength of the extended fiber bundle portion 113S itself is improved, and thereby, the fiber mass intertwined through the extended fiber bundle portion 113S 11 The intersection between each other or the fiber block 11 and the water-absorbing fiber 12F is further enhanced. In addition, if the extended fiber bundle portion 113S has a hot-melt portion, there is an advantage that the extended fiber bundle portion 113S is not only in a dry state but also in the case of absorbing moisture to become a wet state, the extended The strength and shape retention of the fiber bundle portion 113S itself are also improved. Moreover, with this advantage, when the absorbent core 40 is applied to an absorbent article, it is needless to say that the absorbent core 40 is in a dry state, even when absorbing body fluids such as urine or menstrual blood excreted by the wearer In the case of being in a wet state, the above-mentioned effect due to the presence of the fiber block 11 can also be stably obtained. Such an extended fiber bundle portion 113S having a hot-melt portion can be used in the cutting step of the raw fiber sheet 10bs of the fiber block 11 which is the manufacturing step of the fiber block 11 shown in FIG. The "fiber sheet of the hot-melt portion of the fibers" is manufactured as the raw fiber sheet 10bs.

纖維塊11之構成纖維11F包含吸水性低於吸水性纖維12F之「弱吸水性」之纖維。用作纖維11F之弱吸水性之纖維較佳為弱吸水性之合成纖維。藉由纖維塊11之構成纖維11F為弱吸水性之纖維,不僅於吸收性芯體40為乾燥狀態之情形時,而且於吸收水分(尿或經血等體液)而處於濕潤狀態之情形時,亦穩定地取得上述起因於纖維塊11之存在之作用效果(保形性、柔軟性、緩衝性、壓縮回覆性、不易褶皺性等之提高效果)。纖維塊11中之作為構成纖維11F之弱吸水性之纖維之含量相對於纖維塊11之總質量,較佳為90質量%以上,最佳為100質量%,即纖維塊11僅由弱吸水性之纖維形成。尤其於作為構成纖維11F之弱吸水性之纖維為非吸水性之纖維之情形時,進一步穩定地取得上述起因於纖維塊11之存在之作用效果。The constituent fibers 11F of the fiber block 11 include "weakly absorbent" fibers having lower water absorption than the water absorbent fibers 12F. The fiber used for the weak water absorption of the fiber 11F is preferably a weak water absorption synthetic fiber. The fibers 11F constituting the fiber block 11 are weakly absorbent fibers, not only when the absorbent core 40 is in a dry state, but also when it is in a wet state when absorbing moisture (body fluid such as urine or menstrual blood). The above-mentioned effects (increasing effects of shape retention, flexibility, cushioning properties, compression resilience, non-wrinkling properties, etc.) due to the presence of the fiber block 11 are stably obtained. The content of the weak water-absorbent fibers constituting the fiber 11F in the fiber block 11 is preferably 90% by mass or more, and most preferably 100% by mass relative to the total mass of the fiber block 11, that is, the fiber block 11 is only weakly water-absorbent Fiber formation. Especially when the weak water-absorbent fiber constituting the fiber 11F is a non-water-absorbent fiber, the above-mentioned effect due to the presence of the fiber block 11 can be obtained more stably.

於本說明書中,「吸水性」之用語係例如如認為紙漿有吸水性般,對業者而言可容易理解者。同樣地,熱塑性纖維亦可容易地理解為與紙漿相比為弱吸水性之纖維,並且為非吸水性纖維。另一方面,纖維之吸水性之程度可根據由下述方法測得之水分率之值而比較相對之吸水性之不同(吸水性纖維與吸水性弱於其之纖維之不同),並且亦可界定更佳之範圍。該水分率之值越大,纖維之吸水性越強。作為本發明之吸水性纖維,該水分率較佳為6%以上,進而較佳為10%以上。另一方面,本發明之弱親水性之纖維之該水分率較佳為未達6%,進而較佳為未達4%。再者,於水分率未達6%之情形時,該纖維可判定為非吸水性纖維。即,作為本發明之弱親水性之纖維,較佳為非吸水性纖維。In this specification, the term "water absorption" is, for example, assuming that the pulp has water absorption, which can be easily understood by the manufacturer. Similarly, thermoplastic fibers can be easily understood as fibers that are less water-absorbing than pulp, and are non-water-absorbing fibers. On the other hand, the degree of water absorption of the fiber can be compared with the difference in relative water absorption according to the value of the moisture content measured by the following method (the difference between the water-absorbing fiber and the fiber whose water absorption is weaker than it), and can also Define better scope. The greater the value of the moisture content, the stronger the water absorption of the fiber. As the water-absorbent fiber of the present invention, the moisture content is preferably 6% or more, and more preferably 10% or more. On the other hand, the moisture content of the weakly hydrophilic fiber of the present invention is preferably less than 6%, and more preferably less than 4%. Furthermore, when the moisture content is less than 6%, the fiber can be judged as non-absorbent fiber. That is, the weakly hydrophilic fiber of the present invention is preferably a non-absorbent fiber.

<水分率之測定方法>
水分率係採用JIS P8203之水分率試驗方法而算出。即,將纖維試樣靜置於溫度40℃、相對濕度80%RH之試驗室24小時之後,於該室內測定絕對乾燥處理前之纖維試樣之重量W(g)。其後,於溫度105±2℃之電乾燥機(例如,ISUZU製作所股份有限公司製造)內靜置1小時,進行纖維試樣之絕對乾燥處理。絕對乾燥處理後,於溫度20±2℃、相對溫度65±2%之標準狀態之試驗室中,在利用旭化成(股)製造之Saran Wrap(註冊商標)包覆纖維試樣之狀態下,將Si矽膠(例如,豐田化工(股))放入玻璃乾燥器內(例如,(股)Tech jam製造),將其靜置直至纖維試樣之溫度變為20±2℃為止。其後,稱量纖維試樣之恆量W'(g),由下式求出纖維試樣之水分率。水分率(%)=(W-W'/W')×100
<Measurement method of moisture content>
The moisture content is calculated using the moisture content test method of JIS P8203. That is, after leaving the fiber sample in a test room at a temperature of 40 ° C. and a relative humidity of 80% RH for 24 hours, the weight W (g) of the fiber sample before the absolute drying treatment was measured in the room. Thereafter, it was allowed to stand in an electric dryer (for example, manufactured by ISUZU Manufacturing Co., Ltd.) at a temperature of 105 ± 2 ° C for 1 hour to perform absolute drying of the fiber sample. After the absolute drying treatment, in a standard state laboratory with a temperature of 20 ± 2 ° C and a relative temperature of 65 ± 2%, with Saran Wrap (registered trademark) manufactured by Asahi Kasei Co., Ltd. covering the fiber sample, replace Si silicone rubber (for example, Toyota Chemical Co., Ltd.) is placed in a glass dryer (for example, manufactured by (Tech Co., Ltd.)), and it is left to stand until the temperature of the fiber sample becomes 20 ± 2 ° C. After that, the constant amount W '(g) of the fiber sample is weighed, and the moisture content of the fiber sample is obtained from the following formula. Moisture rate (%) = (W-W '/ W') × 100

又,同樣地,就吸收性芯體40在乾燥狀態及濕潤狀態之任一狀態下均可於保形性、柔軟性、緩衝性、壓縮回覆性、不易褶皺性等方面顯現優異之效果之觀點而言,纖維塊11較佳為具有複數個熱塑性纖維相互熱熔而成之三維構造。Also, from the viewpoint that the absorbent core 40 can exhibit excellent effects in terms of shape retention, flexibility, cushioning properties, compression responsiveness, and wrinkle resistance in any state of the dry state and the wet state, In other words, the fiber block 11 preferably has a three-dimensional structure formed by thermal fusion of a plurality of thermoplastic fibers.

又,為了獲得此種複數個熱熔部三維地分散而成之纖維塊11,用作纖維塊11之構成纖維11F之作為非吸水性纖維之合成纖維較佳為熱塑性纖維。又,如上所述,延出纖維束部113S較佳為具有熱熔部,此時,藉由纖維塊11之構成纖維11F為熱塑性纖維,亦可獲得該延出纖維束部113S之較佳之形態。Furthermore, in order to obtain such a fiber block 11 in which a plurality of hot-melt portions are dispersed three-dimensionally, the synthetic fiber as the non-absorbent fiber used as the constituent fiber 11F of the fiber block 11 is preferably a thermoplastic fiber. Also, as described above, the extended fiber bundle portion 113S preferably has a hot-melt portion. In this case, by forming the fiber 11F of the fiber block 11 as a thermoplastic fiber, a preferable form of the extended fiber bundle portion 113S can also be obtained. .

為了獲得複數個熱熔部三維地分散而成之纖維塊11,只要其原料纖維片材10bs(參照圖6)同樣地構成即可,又,如上所述,此種複數個熱熔部三維地分散而成之原料纖維片材10bs可藉由對以熱塑性纖維為主體之纖維網或不織布實施熱風處理等熱處理而製造。In order to obtain a fiber block 11 in which a plurality of hot-melt portions are three-dimensionally dispersed, it is sufficient if the raw fiber sheet 10bs (refer to FIG. 6) is constructed in the same manner, and, as described above, such a plurality of hot-melt portions is three-dimensionally The dispersed raw fiber sheet 10bs can be produced by subjecting a fibrous web or nonwoven fabric mainly composed of thermoplastic fibers to heat treatment such as hot air treatment.

作為較佳地作為纖維塊11之構成纖維11F之原材料之非吸水性之合成樹脂即熱塑性樹脂,例如,可列舉:聚乙烯、聚丙烯等聚烯烴;聚對苯二甲酸乙二酯等聚酯;尼龍6、尼龍66等聚醯胺;聚丙烯酸、聚甲基丙烯酸烷基酯、聚氯乙烯、聚偏二氯乙烯等,可單獨使用其等之1種或組合2種以上而使用。再者,纖維11F可為包括1種熱塑性樹脂或將包含熱塑性樹脂之2種以上之合成樹脂混合而成之摻合聚合物的單一纖維,或者亦可為複合纖維。此處所言之複合纖維係指利用紡絲頭將成分不同之2種以上之合成樹脂複合並同時進行紡絲而獲得之合成纖維(熱塑性纖維),且複數個成分以分別於纖維之長度方向上連續之構造於單纖維內相互接著而成者。複合纖維之形態有芯鞘型、並列型等,並無特別限制。The non-water-absorbent synthetic resin, which is preferably a raw material constituting the fiber 11F of the fiber block 11, is a thermoplastic resin, for example, polyolefins such as polyethylene and polypropylene; polyesters such as polyethylene terephthalate Polyamides such as nylon 6, nylon 66; polyacrylic acid, polyalkyl methacrylate, polyvinyl chloride, polyvinylidene chloride, etc., can be used alone or in combination of two or more. In addition, the fiber 11F may be a single fiber including a single thermoplastic resin or a blended polymer obtained by mixing two or more types of synthetic resins containing a thermoplastic resin, or may be a composite fiber. The composite fiber mentioned here refers to a synthetic fiber (thermoplastic fiber) obtained by compounding two or more kinds of synthetic resins with different compositions and spinning simultaneously using a spinning head, and a plurality of components are respectively in the longitudinal direction of the fiber The continuous structure is connected to each other in a single fiber. The shape of the composite fiber includes a core-sheath type and a side-by-side type, and is not particularly limited.

又,關於纖維塊11,就進一步提高初始排泄中之體液之引入性之觀點而言,由下述方法測得之與水之接觸角較佳為未達90度,尤其70度以下。作為此種纖維,藉由根據慣例利用親水化劑對上述弱吸水性之纖維、較佳為非吸水性纖維進行處理而獲得。作為親水化劑,可使用通常之界面活性劑。Further, regarding the fiber block 11, from the viewpoint of further improving the introduction of body fluids during initial excretion, the contact angle with water measured by the following method is preferably not more than 90 degrees, especially 70 degrees or less. Such fibers are obtained by treating the above-mentioned weakly water-absorbing fibers, preferably non-water-absorbing fibers, with a hydrophilizing agent in accordance with conventional practice. As the hydrophilizing agent, a common surfactant can be used.

<接觸角之測定方法>
自測定對象(吸收性芯體、纖維塊)取出纖維,測定水相對於該纖維之接觸角。作為測定裝置,使用協和界面科學股份有限公司製造之自動接觸角計MCA-J。接觸角之測定係使用去離子水。將自噴墨方式水滴噴出部(Cluster Technology公司製造,噴出部孔徑為25 μm之脈衝噴射器CTC-25)噴出之液量設定為20微微升,將水滴滴加至纖維之正上方。將滴加之情況錄影至連接於水平設置之相機之高速錄影裝置。就之後進行圖像解析之觀點而言,錄影裝置較理想為裝入有高速擷取裝置之個人電腦。於本測定中,每隔17 msec對圖像進行錄影。於所錄影之影像中,藉由附帶軟體FAMAS(軟體之版本設為2.6.2,解析手法設為液滴法,解析方法設為θ/2法,圖像處理演算法設為無反射,圖像處理影像模式設為圖框,臨限位準設為200,不進行曲率修正)對水滴滴落至纖維之最初之圖像進行圖像解析,算出水滴與空氣接觸之面和纖維所成之角,並將其設為接觸角。自測定對象取出之纖維被裁斷為纖維長1 mm,將該纖維載置於接觸角計之樣本台,並維持為水平。針對每1條纖維測定不同之2個部位之接觸角。測量N=5條之接觸角至小數點後1位,將合計10個部位之測定值之平均值(於小數點後第2位四捨五入)定義為該纖維與水之接觸角。測定環境係設為室溫22±2℃、濕度65±2%RH。
<Measurement method of contact angle>
The fiber was taken out from the measurement object (absorbent core, fiber block), and the contact angle of water relative to the fiber was measured. As a measuring device, an automatic contact angle meter MCA-J manufactured by Kyowa Interface Science Co., Ltd. was used. The contact angle is measured using deionized water. The amount of liquid ejected from the ink jet type water droplet ejection part (CTC-25 manufactured by Cluster Technology Co., Ltd., with an ejection part aperture of 25 μm) was set to 20 picoliters, and the water droplet was dropped directly above the fiber. Record the drip situation to a high-speed recording device connected to a horizontally set camera. From the viewpoint of image analysis later, the recording device is ideally a personal computer equipped with a high-speed capture device. In this measurement, the image is recorded every 17 msec. In the recorded images, by the accompanying software FAMAS (the software version is set to 2.6.2, the analysis method is set to the droplet method, the analysis method is set to the θ / 2 method, and the image processing algorithm is set to no reflection, Figure The image processing image mode is set to the frame, the limit level is set to 200, and no curvature correction is performed) image analysis is performed on the initial image of the water drop dripping to the fiber, and the surface of the water drop and the air and the fiber are calculated Angle and set it as the contact angle. The fiber removed from the measurement object is cut to a fiber length of 1 mm, and the fiber is placed on the sample table of the contact angle meter and maintained at a level. Measure the contact angle of two different parts for each fiber. Measure the contact angle of N = 5 to one decimal place, and define the average value of the measured values of 10 parts (rounded off to the second digit after the decimal point) as the contact angle of the fiber with water. The measurement environment was set at room temperature 22 ± 2 ° C and humidity 65 ± 2% RH.

再者,於測定對象之吸收體(吸收性芯體)用作吸收性物品等其他物品之構成構件並取出該吸收體進行評價測定之情況下,於該吸收體藉由接著劑、熔合等而固定於其他構成構件之情形時,在不對纖維之接觸角產生影響之範圍內,利用吹送冷噴霧之冷風等方法去除接著力之後將其固定部分取出。該順序於本案說明書中之所有測定中共通。In addition, when the absorber (absorbent core) to be measured is used as a constituent member of other articles such as absorbent articles and the absorber is taken out for evaluation and measurement, the absorber is subjected to adhesives, fusion, etc. In the case of fixing to other structural members, within the range that does not affect the contact angle of the fiber, remove the adhesive force after removing the adhesive force by using cold air such as blowing cold spray, etc. This sequence is common to all determinations in the specification of this case.

作為吸水性纖維12F,可使用先前用作此種吸收性物品之吸收體之形成材料之吸水性纖維,例如,可列舉:針葉樹紙漿或闊葉樹紙漿等木漿、棉紙漿或麻紙漿等非木漿等天然纖維;陽離子化紙漿、絲光化紙漿等改性紙漿等;可單獨使用其等之1種或將2種以上混合使用。吸水性纖維之中,尤佳為纖維素系之吸水性纖維。As the water-absorbent fiber 12F, water-absorbent fibers previously used as a material for forming the absorbent body of such absorbent articles can be used, for example, wood pulp such as conifer pulp or broad-leaf pulp, non-wood pulp such as cotton pulp or hemp pulp Natural fiber; modified pulp such as cationized pulp, mercerized pulp, etc .; one kind of these can be used alone or two or more kinds can be mixed and used. Among the water-absorbing fibers, particularly preferred are cellulose-based water-absorbing fibers.

於吸收性芯體40中,纖維塊11與吸水性纖維12F之含有質量比並無特別限定,根據纖維塊11之構成纖維(弱吸水性之合成纖維)11F及吸水性纖維12F之種類等適當調整即可。例如,於纖維塊11之構成纖維11F為非吸水性纖維即熱塑性纖維,吸水性纖維12F為纖維素系之吸水性纖維之情形時,就更確實地取得本發明之特定之效果之觀點而言,纖維塊11與吸水性纖維12F之含有質量比以前者(纖維塊11)/後者(吸水性纖維12F)計較佳為20/80~80/20,進而較佳為40/60~60/40。In the absorbent core 40, the content mass ratio of the fiber block 11 and the water-absorbent fiber 12F is not particularly limited, and it is appropriate according to the types of the constituent fibers (weak water-absorbing synthetic fiber) 11F and the water-absorbent fiber 12F of the fiber block 11 Just adjust. For example, when the constituent fibers 11F of the fiber block 11 are non-absorbent fibers, that is, thermoplastic fibers, and the water-absorbent fibers 12F are cellulose-based water-absorbent fibers, from the viewpoint of more surely obtaining the specific effect of the present invention The content of the fiber block 11 and the water-absorbent fiber 12F is preferably 20/80 to 80/20, more preferably 40/60 to 60/40 in terms of the former (fiber block 11) / the latter (water-absorbent fiber 12F) .

吸收性芯體40中之纖維塊11之含量相對於乾燥狀態之吸收性芯體40之總質量,較佳為20質量%以上,進而較佳為40質量%以上,並且,較佳為80質量%以下,進而較佳為60質量%以下。
吸收性芯體40中之吸水性纖維12F之含量相對於乾燥狀態之吸收性芯體40之總質量,較佳為20質量%以上,進而較佳為40質量%以上,並且,較佳為80質量%以下,進而較佳為60質量%以下。
The content of the fiber block 11 in the absorbent core 40 is preferably 20% by mass or more, more preferably 40% by mass or more, and preferably 80% by mass relative to the total mass of the absorbent core 40 in the dry state. % Or less, and more preferably 60% by mass or less.
The content of the water-absorbent fibers 12F in the absorbent core 40 is preferably 20% by mass or more, and more preferably 40% by mass or more, and preferably 80% with respect to the total mass of the absorbent core 40 in the dry state. The mass% or less is more preferably 60 mass% or less.

吸收性芯體40中之纖維塊11之基重較佳為32 g/m2 以上,進而較佳為80 g/m2 以上,並且,較佳為640 g/m2 以下,進而較佳為480 g/m2 以下。
吸收性芯體40中之吸水性纖維12F之基重較佳為32 g/m2 以上,進而較佳為80 g/m2 以上,並且,較佳為640 g/m2 以下,進而較佳為480 g/m2 以下。
The basis weight of the fiber block 11 in the absorbent core 40 is preferably 32 g / m 2 or more, more preferably 80 g / m 2 or more, and, preferably 640 g / m 2 or less, and more preferably 480 g / m 2 or less.
The basis weight of the water-absorbent fibers 12F in the absorbent core 40 is preferably 32 g / m 2 or more, more preferably 80 g / m 2 or more, and, preferably 640 g / m 2 or less, still more preferably 480 g / m 2 or less.

吸收性芯體40亦可含有除纖維塊11及吸水性纖維12F以外之其他成分,作為其他成分,可例示吸水性聚合物。作為吸水性聚合物,一般使用粒子狀者,但亦可為纖維狀者。於使用粒子狀之高吸水性聚合物之情形時,其形狀可為球狀、塊狀、袋狀或不定形之任一者。吸水性聚合物之平均粒徑較佳為10 μm以上,進而較佳為100 μm以上,並且,較佳為1000 μm以下,進而較佳為800 μm以下。作為吸水性聚合物,一般可使用丙烯酸或丙烯酸鹼金屬鹽之聚合物或共聚物。作為其例,可列舉聚丙烯酸及其鹽、以及聚甲基丙烯酸及其鹽。The absorbent core 40 may contain components other than the fiber block 11 and the water-absorbent fiber 12F. As other components, a water-absorbent polymer may be exemplified. As the water-absorbing polymer, particles are generally used, but fibers may also be used. When a particulate superabsorbent polymer is used, its shape can be any of spherical, block, bag or indefinite. The average particle diameter of the water-absorbing polymer is preferably 10 μm or more, more preferably 100 μm or more, and preferably 1000 μm or less, and more preferably 800 μm or less. As the water-absorbing polymer, polymers or copolymers of acrylic acid or alkali metal salts of acrylic acid can be generally used. Examples thereof include polyacrylic acid and its salts, and polymethacrylic acid and its salts.

吸收性芯體40中之吸水性聚合物之含量相對於乾燥狀態之吸收性芯體40之總質量,較佳為5質量%以上,進而較佳為10量%以上,並且,較佳為60質量%以下,進而較佳為40質量%以下。
吸收性芯體40中之吸水性聚合物之基重較佳為10 g/m2 以上,進而較佳為30 g/m2 以上,並且,較佳為100 g/m2 以下,進而較佳為70 g/m2 以下。
The content of the water-absorbent polymer in the absorbent core 40 is preferably 5% by mass or more, more preferably 10% by mass or more, and preferably 60% relative to the total mass of the absorbent core 40 in the dry state. The mass% or less is more preferably 40 mass% or less.
The basis weight of the water-absorbing polymer in the absorbent core 40 is preferably 10 g / m 2 or more, more preferably 30 g / m 2 or more, and, preferably 100 g / m 2 or less, still more preferably 70 g / m 2 or less.

吸收性芯體40之基重只要根據其用途等適當調整即可。例如,於吸收性芯體40之用途為拋棄式尿布或經期衛生棉等吸收性物品之吸收體之情形時,吸收性芯體40之基重較佳為100 g/m2 以上,進而較佳為200 g/m2 以上,並且,較佳為800 g/m2 以下,進而較佳為600 g/m2 以下。The basis weight of the absorbent core 40 should just be adjusted suitably according to the use etc. For example, when the use of the absorbent core 40 is an absorbent body for absorbent articles such as disposable diapers or menstrual sanitary napkins, the basis weight of the absorbent core 40 is preferably 100 g / m 2 or more, and more preferably It is 200 g / m 2 or more, and preferably 800 g / m 2 or less, and more preferably 600 g / m 2 or less.

具有如上所述之構成之吸收性芯體40及具備該吸收性芯體40之如衛生棉1般之吸收性物品柔軟且緩衝性優異,並且壓縮回覆性亦優異,對外力響應性良好地變形,若解除外力,則快速恢復至原本之狀態。具備此種吸收體(吸收性芯體)之吸收性物品之特性可將壓縮功量(WC)及回覆功量(WC')作為尺度而進行評價。壓縮功量係成為吸收性物品之緩衝性之尺度者,可評價為,WC值越大,緩衝性越高。回覆功量係表示將吸收性物品壓縮並解除壓縮狀態時之回覆之程度之尺度,可評價為,WC'值越大,壓縮回覆性越高。又,若考慮吸收保持液體之吸收性芯體40之作用,則不僅於乾燥狀態下,而且於吸收體液等成為濕潤狀態之情形時,吸收性物品亦較佳為WC值及WC'值較大。為了使吸收性物品於濕潤狀態下具有此種特性,如上所述,有效方法為使用如熱塑性纖維般之非吸水性之合成纖維作為纖維塊11之構成纖維11F。The absorbent core 40 having the above-mentioned structure and the absorbent article like the sanitary napkin 1 provided with the absorbent core 40 are soft and excellent in cushioning properties, and also have excellent compression and responsiveness, and deform well in response to external forces If the external force is released, it will quickly return to its original state. The characteristics of an absorbent article having such an absorber (absorbent core) can be evaluated using the compression work energy (WC) and the reply work energy (WC ') as a scale. Compression work is a measure of the cushioning properties of absorbent articles. It can be evaluated that the larger the WC value, the higher the cushioning properties. Response energy is a measure of the degree of response when an absorbent article is compressed and released from compression. It can be evaluated that the greater the WC 'value, the higher the compression response. In addition, considering the function of the absorbent core 40 that absorbs and retains the liquid, not only in the dry state, but also in the case where the absorbed body fluids and the like become wet, the absorbent article preferably has a larger WC value and WC 'value. . In order to make the absorbent article have such characteristics in a wet state, as described above, an effective method is to use non-absorbent synthetic fibers such as thermoplastic fibers as the constituent fibers 11F of the fiber block 11.

吸收性物品之乾燥狀態下之壓縮功量(d-WC)較佳為80 mN・cm/cm2 以上,進而較佳為90 mN・cm/cm2 以上,並且,較佳為150 mN・cm/cm2 以下,進而較佳為110 mN・cm/cm2 以下。
吸收性物品之濕潤狀態下之壓縮功量(w-WC)較佳為70 mN・cm/cm2 以上,進而較佳為80 mN・cm/cm2 以上,並且,較佳為150 mN・cm/cm2 以下,進而較佳為110 mN・cm/cm2 以下。
The compressive energy (d-WC) of the absorbent article in the dry state is preferably 80 mN · cm / cm 2 or more, and more preferably 90 mN · cm / cm 2 or more, and, preferably, 150 mN · cm / cm 2 or less, and more preferably 110 mN · cm / cm 2 or less.
The compressive energy (w-WC) of the absorbent article in the wet state is preferably 70 mN · cm / cm 2 or more, and more preferably 80 mN · cm / cm 2 or more, and, preferably, 150 mN · cm / cm 2 or less, and more preferably 110 mN · cm / cm 2 or less.

吸收性物品之乾燥狀態下之回覆功量(d-WC')較佳為34 mN・cm/cm2 以上,進而較佳為44 mN・cm/cm2 以上,並且,較佳為150 mN・cm/cm2 以下,進而較佳為60 mN・cm/cm2 以下。
吸收性物品之濕潤狀態下之回覆功量(w-WC')較佳為15 mN・cm/cm2 以上,進而較佳為25 mN・cm/cm2 以上,並且,較佳為150 mN・cm/cm2 以下,進而較佳為55 mN・cm/cm2 以下。
The dry work energy of the absorbent article (d-WC ') is preferably 34 mN · cm / cm 2 or more, and more preferably 44 mN · cm / cm 2 or more, and, preferably, 150 mN · cm / cm 2 or less, and more preferably 60 mN · cm / cm 2 or less.
The wet energy of the absorbent article (w-WC ') is preferably 15 mN · cm / cm 2 or more, more preferably 25 mN · cm / cm 2 or more, and preferably 150 mN · cm / cm 2 or less, and more preferably 55 mN · cm / cm 2 or less.

<壓縮功量(WC)及回覆功量(WC')之測定方法>
一般已知,吸收性物品之壓縮功量(WC)及回覆功量(WC')可由利用加多技術股份有限公司製造之KES(KAWABATA EVALUATION SYSTEM)之測定值表示(參考文獻:質感評價之標準化及解析(第2版),著者 川端季雄,昭和55年7月10日發行)。具體而言,可利用加多技術股份有限公司製造之自動化壓縮試驗裝置KES-G5測定壓縮功量及回覆功量。測定順序如下所述。
將作為試樣之「具備吸收體之吸收性物品(經期衛生棉)」安裝於壓縮試驗裝置之試驗台。其次,將該試樣於具有面積2 cm2 之圓形平面之鋼板間壓縮。壓縮速度係設為0.02 cm/sec,壓縮最大負載係設為490 mN/cm2 。回覆過程亦以同一速度進行測定。壓縮功量(WC)及回覆功量(WC')分別由下式表示。式中,Tm 、To 分別表示490 mN/cm2 負載時之厚度、4.9 mN/cm2 負載時之厚度。又,Pa 表示測定時(壓縮過程)之負載(mN/cm2 ),Pb 表示測定時(回覆過程)之負載(mN/cm2 )。
<Measurement method of compression work (WC) and reply work (WC ')>
It is generally known that the compressive energy (WC) and the reply energy (WC ') of absorbent articles can be expressed by measured values using KES (KAWABATA EVALUATION SYSTEM) manufactured by Kado Technology Co., Ltd. (reference: standardization of texture evaluation And analysis (2nd edition), author Kawabata Jixiong, published on July 10, 1985). Specifically, the automatic compression test device KES-G5 manufactured by Jiaduo Technology Co., Ltd. can be used to measure the compression work and the response work. The measurement sequence is as follows.
Install the "absorbent article with absorbent body (menstrual pad)" as a sample on the test stand of the compression test device. Next, the sample was compressed between steel plates having a circular plane with an area of 2 cm 2 . The compression speed is set to 0.02 cm / sec, and the maximum compression load is set to 490 mN / cm 2 . The response process is also measured at the same speed. Compression work (WC) and response work (WC ') are expressed by the following formulas. In the formula, T m and T o respectively represent the thickness under the load of 490 mN / cm 2 and the thickness under the load of 4.9 mN / cm 2 . In addition, P a represents the load (mN / cm 2 ) during the measurement (compression process), and P b represents the load (mN / cm 2 ) during the measurement (reply process).

[數1]
[Number 1]

[數2]
[Number 2]

再者,上述測定方法之測定對象即「具備乾燥狀態之吸收體之吸收性物品」係藉由將乾燥狀態之吸收性物品放置於氣溫23℃、相對濕度50%RH之環境下24小時而製備。又,上述測定方法之測定對象即「具備濕潤狀態之吸收體之吸收性物品」係將乾燥狀態之吸收性物品以正面片材側(肌膚對向面側)成為上側之方式水平放置,於該正面片材上放置橢圓形注入口(長徑50 mm、短徑23 m),自該注入口注入3.0 g脫纖維馬血,靜置1分鐘之後進而注入3.0 g脫纖維馬血,注入後1分鐘保持其狀態而製備。再者,注入至測定對象之脫纖維馬血係NIPPON BIOTEST(股)製造之脫纖維馬血且液溫25℃下之黏度調整為8 cp者,又,該黏度係於東機產業股份有限公司製造之TVB-10M形黏度計中,利用轉子名稱L/Adp(轉子編碼19)之轉子以旋轉速度12 rpm測定之情形之黏度。In addition, the measurement object of the above measurement method, namely, "absorbent article with an absorbent body in a dry state" is prepared by placing the absorbent article in a dry state in an environment with a temperature of 23 ° C and a relative humidity of 50% RH for 24 hours . In addition, the measurement object of the above-mentioned measurement method, that is, "absorbent article with an absorbent body in a wet state" is to place the absorbent article in a dry state horizontally with the front sheet side (skin-facing side) facing the upper side. Place an elliptical injection port (long diameter 50 mm, short diameter 23 m) on the front sheet. Inject 3.0 g defibrillated horse blood from the injection port. After standing for 1 minute, inject 3.0 g defibrillated horse blood. After injection 1 Prepared in minutes to keep it in its state. In addition, the defibrillated horse blood injected into the measurement object is made of defibrillated horse blood manufactured by NIPPON BIOTEST Co., Ltd. and the viscosity at a liquid temperature of 25 ° C. is adjusted to 8 cp. In the manufactured TVB-10M viscometer, the viscosity of the rotor with the rotor name L / Adp (rotor code 19) measured at a rotation speed of 12 rpm is used.

吸收性芯體40可與包含此種纖維材料之吸收性芯體(吸收體)同樣地製造。如上所述,如圖6所示,纖維塊11可藉由使用切割器等切斷器件,將成為原料之原料纖維片材(與纖維塊11相同組成且尺寸大於纖維塊11之片材)於相互交叉(正交)之2個方向切斷而製造,以此方式製造之複數個纖維塊11係形狀及尺寸均勻之「定形之纖維集合體」(例如,本體部110為長方體形狀)。包含纖維塊11及吸水性纖維12F之吸收性芯體40例如可根據慣例使用具備旋轉轉筒之公知之纖維堆積裝置而製造。典型而言,該纖維堆積裝置具備:旋轉轉筒,其於外周面形成有集聚用凹部;及導管,其於內部具有將吸收性芯體40之原材料(纖維塊11、吸水性纖維12F)搬送至該集聚用凹部之流路;一面使該旋轉轉筒沿其轉筒周向繞旋轉軸旋轉,一面使隨著藉由來自該旋轉轉筒之內部側之抽吸於該流路中產生之空氣流(真空空氣)而搬送之原材料纖維堆積於該集聚用凹部。The absorbent core 40 can be manufactured in the same manner as an absorbent core (absorber) containing such a fiber material. As described above, as shown in FIG. 6, the fiber block 11 can be cut by using a cutter or the like to make a raw fiber sheet (a sheet having the same composition as the fiber block 11 and having a larger size than the fiber block 11) in A plurality of fiber blocks 11 manufactured by cutting in two directions that cross each other (orthogonal directions) are made into a "fixed fiber assembly" having a uniform shape and size (for example, the body portion 110 has a rectangular parallelepiped shape). The absorbent core 40 including the fiber block 11 and the water-absorbent fibers 12F can be manufactured, for example, according to a conventional practice using a known fiber stacking device equipped with a rotating drum. Typically, the fiber stacking device includes: a rotating drum with a concave portion for accumulation formed on the outer peripheral surface; and a duct with materials for transferring the absorbent core 40 (fiber block 11, water-absorbent fiber 12F) inside The flow path to the recess for accumulation; while rotating the rotary drum around its axis of rotation along the circumference of the rotary drum, while causing it to be generated in the flow path by suction from the inner side of the rotary drum The raw material fiber conveyed by the air flow (vacuum air) accumulates in the recess for accumulation.

以上,針對本發明,基於其實施形態而進行了說明,但本發明並不限於上述實施形態,可適當進行變更。
例如,於本發明之吸收性芯體中,纖維塊亦可不均勻地分散存在於吸收性芯體整體,亦可偏集存在。作為纖維塊偏集存在之形態,可例示具有纖維塊構成主體之層與吸水性纖維構成主體之層之積層構造之吸收性芯體。
又,本發明之吸收性芯體亦可並非其中含有之所有纖維塊(弱吸水性之合成纖維集合體)均為如纖維塊11般之定形之纖維集合體,只要為不脫離本發明之主旨之範圍,則除了該定形之纖維集合體以外,亦可進而包含極少量不定形之纖維集合體。
本發明之吸收性物品廣泛包含用於自人體排出之體液(尿、軟便、經血、汗等)之吸收之物品,除了上述經期衛生棉以外,亦包含經期短褲(shorts)、具有固定帶之所謂展開型之拋棄式尿布、短褲(pants)型之拋棄式尿布、失禁護墊等。關於上述本發明之實施形態,進而揭示以下之附記。
In the above, the present invention has been described based on the embodiments, but the present invention is not limited to the above-mentioned embodiments, and can be modified as appropriate.
For example, in the absorbent core of the present invention, the fiber blocks may be unevenly dispersed throughout the absorbent core, or may be unevenly distributed. As a form in which the fiber blocks are present in a concentrated manner, an absorbent core having a laminated structure of a layer composed of a fiber block and a layer composed of a water-absorbent fiber can be exemplified.
In addition, the absorbent core of the present invention may not include all the fiber blocks (weakly absorbent synthetic fiber aggregates) contained therein as a fiber aggregate shaped like the fiber block 11, as long as it does not deviate from the gist of the present invention In addition to the shaped fiber assembly, it may further include a very small amount of unshaped fiber assembly.
The absorbent article of the present invention broadly includes articles for absorbing body fluids (urine, soft stools, menstrual blood, sweat, etc.) discharged from the human body. In addition to the above-mentioned menstrual sanitary pads, it also includes menstrual shorts (shorts) and so-called straps Expansion type disposable diapers, pants type disposable diapers, incontinence pads, etc. Regarding the embodiments of the present invention described above, the following supplementary notes will be disclosed.

<1>一種吸收性物品,其係具有與穿著者之前後方向對應之縱向及與其正交之橫向,且具備吸收體、及配置於該吸收體之肌膚對向面側之正面片材者,上述吸收體係包含液體吸收性之吸收性芯體、及被覆該吸收性芯體之肌膚對向面之包芯片材而構成,該吸收性芯體包含吸水性纖維、及含有吸水性低於該吸水性纖維之弱吸水性之纖維的纖維塊;由下述方法測得之上述吸收性芯體之液體擴散面積與由下述方法測得之上述包芯片材之液體擴散面積之比率以前者/後者計為0.7以上。
<液體擴散面積之測定方法>
於相對於水平面具有45°之角度之斜面上,將測定對象以使其肌膚對向面朝向該斜面之方式固定,耗費23秒鐘將1.5 g脫纖維馬血注入至測定對象之肌膚對向面,放置3分鐘後,再次進行耗費相同時間將同量之脫纖維馬血注入至相同注入部位之操作,反覆進行6次該脫纖維馬血之注入、放置操作,將合計9 g之脫纖維馬血注入至測定對象,注入操作完成後,對測定對象之肌膚對向面中之脫纖維馬血之擴散面積進行測定,並將其作為該測定對象之液體擴散面積。
<2>如上述<1>所記載之吸收性物品,其中上述包芯片材係以紙漿為主體之多孔性片材。
<3>如上述<1>或<2>所記載之吸收性物品,其中於上述吸收體之肌膚對向面,局部地形成有上述包芯片材及上述吸收性芯體向該吸收體之非肌膚對向面側一體地凹陷之凹陷部。
<4>如上述<3>所記載之吸收性物品,其中上述吸收性物品於縱向上分為:縱中央區域,其包含與穿著者之排泄部對向之排泄部對向部;前方區域,其配置於較該排泄部對向部更靠穿著者之腹側;及後方區域,其配置於較該排泄部對向部更靠穿著者之背側;上述凹陷部以包圍上述縱中央區域之橫向中央部之方式形成。
<5>如上述<1>至<4>中任一項所記載之吸收性物品,其中上述纖維塊之外形為長方體狀或圓盤狀。
<1> An absorbent article having a longitudinal direction corresponding to the front and back directions of the wearer and a transverse direction orthogonal thereto, and having an absorber and a front sheet disposed on the skin-facing side of the absorber, The above-mentioned absorption system includes a liquid-absorbent absorbent core and a core-clad material covering the skin-facing surface of the absorbent core, the absorbent core including water-absorbent fibers, and containing water-absorbent fibers less than the water-absorbent core The fiber block of weakly absorbent fiber of sexual fiber; the ratio of the liquid diffusion area of the above-mentioned absorbent core measured by the following method to the liquid diffusion area of the above-mentioned chip-coated sheet material measured by the following method Counted above 0.7.
<Measurement method of liquid diffusion area>
On an inclined surface with an angle of 45 ° relative to the horizontal plane, fix the measurement object so that the opposite side of the skin faces the inclined surface, and it takes 23 seconds to inject 1.5 g of defibrinated horse blood into the opposite side of the measurement object After leaving for 3 minutes, the same amount of defibrinated horse blood is injected into the same injection site again for the same time, and the defibrinated horse blood is injected and placed 6 times repeatedly to add a total of 9 g of defibrinated horse Blood is injected into the measurement object. After the injection operation is completed, the diffusion area of the defibrillated horse blood in the skin opposite to the measurement object is measured, and this is taken as the liquid diffusion area of the measurement object.
<2> The absorbent article according to the above <1>, wherein the chip-wrapped material is a porous sheet mainly composed of pulp.
<3> The absorbent article as described in the above <1> or <2>, wherein the non-contained core wrapping material and the absorbent core are partially formed on the skin-facing surface of the absorbent body toward the absorbent body A recessed part that is integrally recessed on the opposite side of the skin.
<4> The absorbent article as described in the above <3>, wherein the absorbent article is divided into: a longitudinal central region including a discharge part opposing part facing the wearer ’s discharge part; a front region, It is arranged on the ventral side of the wearer more than the opposite part of the excretory part; and the rear region is arranged on the back side of the wearer more than the opposite part of the excretion part; the recessed part surrounds the longitudinal central region Formed in the horizontal center.
<5> The absorbent article according to any one of the above <1> to <4>, wherein the shape of the fiber block is a rectangular parallelepiped or a disc.

<6>如上述<1>至<5>中任一項所記載之吸收性物品,其中上述纖維塊具有纖維密度相對較高之本體部、及存在於該本體部之周圍且與該本體部相比纖維密度更低之延出纖維部,複數個上述纖維塊彼此相互交絡,並且上述纖維塊與上述吸水性纖維相互交絡。
<7>如上述<6>所記載之吸收性物品,其中上述本體部具有2個對向之基本面、及連結該2個基本面之骨架面,該基本面於俯視下呈四邊形形狀。
<8>如上述<7>所記載之吸收性物品,其中上述2個基本面之總面積大於上述骨架面之總面積。
<9>如上述<7>或<8>所記載之吸收性物品,其中上述纖維塊具有延出纖維束部,該延出纖維束部包含自上述骨架面向外側延伸之複數條纖維。
<10>如上述<9>所記載之吸收性物品,其中上述延出纖維束部具有複數條纖維相互熱熔而成之部位。
<11>如上述<9>或<10>所記載之吸收性物品,其中上述延出纖維束部自上述本體部之延出長度、較佳為自上述骨架面之延出長度為0.05 mm以上且7 mm以下,較佳為0.15 mm以上且4 mm以下。
<12>如上述<7>至<11>中任一項所記載之吸收性物品,其中上述基本面於俯視下呈長方形形狀,該長方形形狀之短邊與上述吸收體之厚度相比更短。
<13>如上述<12>所記載之吸收性物品,其中上述基本面之短邊之長度與上述吸收體之厚度之比率以前者/後者計為0.03以上且1以下,較佳為0.08以上且0.5以下。
<14>如上述<12>或<13>所記載之吸收性物品,其中上述基本面之短邊之長度為0.3 mm以上且10 mm以下,較佳為0.5 mm以上且6 mm以下。
<15>如上述<12>至<14>中任一項所記載之吸收性物品,其中上述基本面之長邊之長度為0.3 mm以上且30 mm以下,較佳為2 mm以上且15 mm以下。
<16>如上述<7>至<15>中任一項所記載之吸收性物品,其中存在於上述基本面之纖維端部之每單位面積之數量N1 與存在於上述骨架面之纖維端部之每單位面積之數量N2 之比率N1 /N2 為0以上且0.90以下,較佳為0.05以上且0.60以上。
<17>如上述<7>至<16>中任一項所記載之吸收性物品,其中存在於上述基本面之纖維端部之每單位面積之數量為0個/mm2 以上且8個/mm2 以下,較佳為3個/mm2 以上且6個/mm2 以下。
<18>如上述<7>至<17>中任一項所記載之吸收性物品,其中存在於上述骨架面之纖維端部之每單位面積之數量為5個/mm2 以上且50個/mm2 以下,較佳為8個/mm2 以上且40個/mm2 以下。
<6> The absorbent article according to any one of the above <1> to <5>, wherein the fiber block has a body portion having a relatively high fiber density, and exists around the body portion and is in contact with the body portion Compared to the extended fiber portion having a lower fiber density, a plurality of the above-mentioned fiber blocks are interlaced with each other, and the above-mentioned fiber blocks and the water-absorbing fibers are interlaced with each other.
<7> The absorbent article according to the above <6>, wherein the main body portion has two opposing basic surfaces and a skeleton surface connecting the two basic surfaces, and the basic surface has a quadrangular shape in a plan view.
<8> The absorbent article as described in the above <7>, wherein the total area of the two basic surfaces is larger than the total area of the skeleton surface.
<9> The absorbent article according to the above <7> or <8>, wherein the fiber block has an extended fiber bundle portion including a plurality of fibers extending outward from the frame surface.
<10> The absorbent article according to the above <9>, wherein the extended fiber bundle portion has a portion where a plurality of fibers are thermally fused with each other.
<11> The absorbent article according to the above <9> or <10>, wherein the extended length of the extended fiber bundle portion from the main body portion, preferably the extended length from the skeleton surface is 0.05 mm or more And 7 mm or less, preferably 0.15 mm or more and 4 mm or less.
<12> The absorbent article according to any one of the above <7> to <11>, wherein the basic surface has a rectangular shape in plan view, and the short side of the rectangular shape is shorter than the thickness of the absorbent body .
<13> The absorbent article as described in the above <12>, wherein the ratio of the length of the short side of the basic surface to the thickness of the absorbent body is 0.03 or more and 1 or less, preferably 0.08 or more in the former / the latter. 0.5 or less.
<14> The absorbent article as described in the above <12> or <13>, wherein the length of the short side of the basic surface is 0.3 mm or more and 10 mm or less, preferably 0.5 mm or more and 6 mm or less.
<15> The absorbent article as described in any one of the above <12> to <14>, wherein the length of the long side of the basic surface is 0.3 mm or more and 30 mm or less, preferably 2 mm or more and 15 mm the following.
<16> The absorbent article as described in any one of the above <7> to <15>, wherein the number N 1 per unit area present at the fiber end of the basic surface and the fiber end present at the skeleton surface The ratio N 1 / N 2 of the number N 2 per unit area of the portion is 0 or more and 0.90 or less, preferably 0.05 or more and 0.60 or more.
<17> The absorbent article as described in any one of the above <7> to <16>, wherein the number per unit area of the fiber end portion present on the above basic surface is 0 pieces / mm 2 or more and 8 pieces / mm 2 or less, preferably 3 pieces / mm 2 or more and 6 pieces / mm 2 or less.
<18> The absorbent article as described in any one of the above <7> to <17>, wherein the number of fibers per unit area present at the fiber ends of the skeleton surface is 5 pieces / mm 2 or more and 50 pieces / mm 2 or less, preferably 8 pieces / mm 2 or more and 40 pieces / mm 2 or less.

<19>如上述<1>至<18>中任一項所記載之吸收性物品,其中上述纖維塊具有複數個熱塑性纖維相互熱熔而成之三維構造。
<20>如上述<1>至<19>中任一項所記載之吸收性物品,其中上述纖維塊與上述吸水性纖維之含有質量比以前者/後者計為20/80~80/20。
<21>如上述<1>至<20>中任一項所記載之吸收性物品,其中於上述吸收體中,上述纖維塊除了藉由交絡而與其他纖維塊或上述吸水性纖維結合以外,亦以可與其他纖維塊或上述吸水性纖維交絡之狀態存在。
<22>如上述<1>至<21>中任一項所記載之吸收性物品,其中具有與其他上述纖維塊或上述吸水性纖維之結合部之上述纖維塊之總數之70%以上、較佳為80%以上係該結合部藉由纖維之交絡而形成者。
<23>如上述<1>至<22>中任一項所記載之吸收性物品,其中上述纖維塊來源於不織布。
<24>如上述<1>至<23>中任一項所記載之吸收性物品,其中上述包芯片材之密度為0.1 g/m3 以下。
<25>如上述<1>至<24>中任一項所記載之吸收性物品,其中上述包芯片材之密度為0.1 g/m3 以下,較佳為0.08 g/m3 以下,又,為0.02 g/m3 以上,較佳為0.04 g/m3 以上。
<26>如上述<1>至<25>中任一項所記載之吸收性物品,其中上述包芯片材之基重為50 g/m2 以下,較佳為30 g/m2 以下,又,為5 g/m2 以上,較佳為10 g/m2 以上。
[實施例]
<19> The absorbent article according to any one of the above <1> to <18>, wherein the fiber block has a three-dimensional structure in which a plurality of thermoplastic fibers are heat-fused to each other.
<20> The absorbent article according to any one of the above <1> to <19>, wherein the content mass of the fiber block and the water-absorbing fiber is 20/80 to 80/20 in terms of the former / the latter.
<21> The absorbent article according to any one of the above <1> to <20>, wherein in the absorbent body, the fiber block is bound to other fiber blocks or the water-absorbing fiber by interlacing, It also exists in a state where it can interlace with other fiber blocks or the above-mentioned water-absorbing fibers.
<22> The absorbent article as described in any one of the above <1> to <21>, wherein 70% or more of the total number of the fiber blocks having a joint portion with other fiber blocks or the water-absorbent fibers, compared It is preferred that more than 80% of the joints are formed by interlacing fibers.
<23> The absorbent article according to any one of the above <1> to <22>, wherein the fiber block is derived from non-woven fabric.
<24> The absorbent article according to any one of the above <1> to <23>, wherein the density of the chip-wrapped material is 0.1 g / m 3 or less.
<25> The absorbent article according to any one of the above <1> to <24>, wherein the density of the above chip-wrapped material is 0.1 g / m 3 or less, preferably 0.08 g / m 3 or less, and, It is 0.02 g / m 3 or more, preferably 0.04 g / m 3 or more.
<26> The absorbent article according to any one of the above <1> to <25>, wherein the basis weight of the chip-wrapped material is 50 g / m 2 or less, preferably 30 g / m 2 or less, and , Is 5 g / m 2 or more, preferably 10 g / m 2 or more.
[Example]

以下,藉由實施例而對本發明進一步具體地進行說明,但本發明並不限定於該實施例。Hereinafter, the present invention will be further specifically described by examples, but the present invention is not limited to the examples.

[實施例1~2]
製作與圖1所示之衛生棉1同樣之構成之經期衛生棉。
作為正面片材,使用基重30 g/m2 之熱風不織布,作為背面片材,使用37 g/m2 之聚乙烯樹脂製膜。吸收體係將纖維塊及吸水性纖維用作吸收性芯體之纖維材料,進而使用另行準備之包芯片材,並使用公知之纖維堆積裝置,根據慣例而製造。纖維塊之製造係依據圖7,將原料纖維片材切斷為丁狀而製造。
作為纖維塊之原料纖維片材,使用以包含聚乙烯樹脂及聚對苯二甲酸乙二酯樹脂之熱塑性纖維(纖維直徑18 μm)為構成纖維之基重21 g/m2 之熱風不織布(具有構成纖維彼此之熱熔部之纖維片材)。作為吸水性纖維,使用纖維直徑22 μm之針葉樹曬乾牛皮紙漿(NBKP)。用於吸收體之纖維塊(定形之合成纖維集合體)具有如圖5(a)所示之長方體形狀之本體部,其基本面111之短邊111a為0.8 mm,長邊111b為3.9 mm,厚度T為0.6 mm。又,基本面111中之纖維端部之每單位面積之數量為3.2個/mm2 ,骨架面112中之纖維端部之每單位面積之數量為19.2個/mm2 。吸收體之基重為350 g/m2 ,厚度為5.7 mm。
[Examples 1-2]
A menstrual sanitary napkin having the same composition as the sanitary napkin 1 shown in FIG. 1 was produced.
As the front sheet, a hot air nonwoven fabric with a basis weight of 30 g / m 2 was used, and as the back sheet, a polyethylene resin film of 37 g / m 2 was used. In the absorption system, the fiber block and the water-absorbent fiber are used as the fiber material of the absorbent core, and the chip-wrapped material prepared separately is used, and it is manufactured in accordance with conventional practices using a known fiber stacking device. The production of the fiber block is produced by cutting the raw fiber sheet into D-shapes according to FIG. 7.
As the raw fiber sheet of the fiber block, a hot-air non-woven fabric (having a thermoplastic fiber containing polyethylene resin and polyethylene terephthalate resin (fiber diameter 18 μm) as the basis weight of the fiber 21 g / m 2 (with The fiber sheet constituting the hot-melt part of the fibers). As a water-absorbent fiber, conifer dried kraft pulp (NBKP) with a fiber diameter of 22 μm was used. The fiber block (fixed synthetic fiber assembly) used for the absorber has a rectangular parallelepiped body as shown in FIG. 5 (a). The short side 111a of the basic surface 111 is 0.8 mm and the long side 111b is 3.9 mm. The thickness T is 0.6 mm. In addition, the number of fiber ends in the basic surface 111 per unit area is 3.2 pieces / mm 2 , and the number of fiber ends in the skeleton surface 112 per unit area is 19.2 pieces / mm 2 . The basis weight of the absorber is 350 g / m 2 and the thickness is 5.7 mm.

實施例1及2中使用之包芯片材(上述多孔性片材)之詳細內容如下所述。(實施例1之包芯片材)
使用針葉樹曬乾牛皮紙漿(NBKP)製、基重13.5 g/m2 、密度0.092 g/cm3 之紙。
(實施例2之包芯片材)
使用實施了絲光化處理之真圓度為0.80之針葉樹曬乾牛皮紙漿(NBKP)且基重16.0 g/m2 、密度0.069 g/cm3 之紙。
The details of the core-wrap material (the porous sheet described above) used in Examples 1 and 2 are as follows. (The chip package of Example 1)
Paper made of conifer dried kraft pulp (NBKP), with a basis weight of 13.5 g / m 2 and a density of 0.092 g / cm 3 .
(The chip package of Example 2)
Paper with conifer sun-dried kraft pulp (NBKP) having a mercerizing treatment of 0.80 and a basis weight of 16.0 g / m 2 and a density of 0.069 g / cm 3 was used.

[比較例1]
將市售之經期衛生棉(Unicharm股份有限公司製造,商品名「Tanom Pew Slim 23cm」)直接作為比較例1。比較例1之經期衛生棉中之吸收體係混合有合成纖維(弱吸水性之纖維)及纖維素系纖維(吸水性纖維)者,故而不包含纖維塊。
[Comparative Example 1]
The commercially available menstrual sanitary napkin (manufactured by Unicharm Co., Ltd., trade name "Tanom Pew Slim 23cm") was directly used as Comparative Example 1. The absorption system in the menstrual sanitary napkin of Comparative Example 1 is a mixture of synthetic fibers (weakly absorbent fibers) and cellulose fibers (absorbent fibers), so it does not contain fiber blocks.

[比較例2]
將吸收體變更為下述者,除此以外,與實施例1同樣地製作經期衛生棉,並作為比較例2。
比較例2中使用之吸收體使用不定形之不織布片作為吸收性芯體中之纖維塊,且利用包芯片材將吸收性芯體被覆之後實施熱風處理加工,使該吸收性芯體中包含之該不織布片彼此相互熱熔,除此以外,與實施例1中使用之吸收體相同。於上述對吸收體實施之熱風處理加工中,將不織布片與紙漿纖維之混合集合體(長度240 mm×寬度75 mm)靜置於溫度150℃之電乾燥機(例如,ISUZU製作所股份有限公司製造)內10分鐘,而使不織布片彼此熱熔。所使用之不定形之不織布片係藉由將與實施例1中使用之熱風不織布相同者向任意之方向撕下而製造,其俯視下之兩端間距長度大概為25 mm左右。
[Comparative Example 2]
Except that the absorber was changed to the following, the menstrual sanitary napkin was prepared in the same manner as in Example 1 and used as Comparative Example 2.
The absorbent body used in Comparative Example 2 used an amorphous non-woven fabric sheet as the fiber block in the absorbent core, and after covering the absorbent core with a core wrapping material, it was subjected to hot air treatment to make the absorbent core contain The non-woven fabric sheets were the same as the absorber used in Example 1 except that the non-woven fabric sheets were heat-fused to each other. In the hot air treatment process performed on the absorber described above, the mixed aggregate (length 240 mm × width 75 mm) of the nonwoven fabric sheet and pulp fibers is placed in an electric dryer (for example, manufactured by ISUZU Manufacturing Co., Ltd.) at a temperature of 150 ° C. ) Within 10 minutes, and the non-woven fabric pieces are melted with each other. The amorphous nonwoven fabric sheet used was manufactured by tearing the same hot air nonwoven fabric as used in Example 1 in any direction, and the distance between the two ends in plan view was about 25 mm.

[比較例3]
將吸收體變更為下述者,除此以外,與實施例1同樣地製作經期衛生棉,並作為比較例3。關於比較例3中使用之吸收體,吸收性芯體中不包含纖維塊,僅包含上述吸水性纖維。作為包芯片材(上述多孔性片材),使用基重16.0 g/m2 、密度0.102 g/cm3 之針葉樹曬乾牛皮紙漿(NBKP)。
[Comparative Example 3]
Except that the absorber was changed to the following, a menstrual tampon was prepared in the same manner as in Example 1 and used as Comparative Example 3. With regard to the absorber used in Comparative Example 3, the absorbent core does not contain fiber blocks, and only contains the above-mentioned water-absorbent fibers. As the chip wrapping material (the porous sheet described above), conifer sun-dried kraft pulp (NBKP) having a basis weight of 16.0 g / m 2 and a density of 0.102 g / cm 3 was used.

[性能評價]
針對各實施例及比較例之經期衛生棉,藉由上述方法測定吸收性芯體及肌膚側包芯片材各者之液體擴散面積,基於其測定值而算出液體擴散面積比率(吸收性芯體之液體擴散面積/包芯片材之液體擴散面積)。又,藉由上述方法測定壓縮功量(WC)及回覆功量(WC'),並基於其等之測定值而對緩衝性及壓縮回覆性進行評價。將結果示於下述表1中。
[Performance evaluation]
For the menstrual pads of each example and comparative example, the liquid diffusion area of each of the absorbent core and the skin-side cladding material was measured by the above method, and the liquid diffusion area ratio (absorbent core body) was calculated based on the measured value. Liquid diffusion area / liquid diffusion area of chip package). In addition, the compression work (WC) and the response work (WC ') were measured by the above-mentioned method, and the cushioning property and the compression response were evaluated based on the measured values. The results are shown in Table 1 below.

[表1]
[Table 1]

如表1所示,各實施例之複數個纖維塊彼此相互交絡,且液體擴散面積比率(吸收性芯體之液體擴散面積/包芯片材之液體擴散面積)為0.7以上,因此,與不滿足其等之先前技術即比較例1~3相比,於乾燥狀態及濕潤狀態之任一狀態下,壓縮功量(WC)及回覆功量(WC')之值均更大,因此,於兩狀態下,緩衝性及壓縮回覆性優異。又,各實施例之液體擴散面積比率處於上述特定範圍,故而自正面片材經由肌膚側包芯片材向吸收性芯體之液體透過性優異。因此,各實施例係體液排泄後體液不易殘留於吸收體之肌膚對向面側者。
[產業上之可利用性]
As shown in Table 1, the plural fiber blocks of each example intersect each other, and the ratio of the liquid diffusion area (liquid diffusion area of the absorbent core / liquid diffusion area of the core-wrap material) is 0.7 or more. Compared with the prior arts, that is, Comparative Examples 1 to 3, in either the dry state or the wet state, the values of the compression work (WC) and the response work (WC ') are larger. In this state, the cushioning properties and compression response are excellent. In addition, since the liquid diffusion area ratio of each example is within the above-mentioned specific range, the liquid permeability from the front sheet to the absorbent core through the skin-side core-wrap is excellent. Therefore, in each of the embodiments, the body fluid is less likely to remain on the skin-facing side of the absorber after the body fluid is excreted.
[Industry availability]

本發明之吸收性物品具備具有較高之緩衝性及液體透過性之吸收體。因此,根據本發明之吸收性物品,體液排泄後體液不易殘留於吸收體之肌膚對向面側,降低不舒適之肌膚之黏膩或濕潤感,可期待優異之穿著感及服貼性。The absorbent article of the present invention has an absorber with high cushioning properties and liquid permeability. Therefore, according to the absorbent article of the present invention, after body fluid is excreted, body fluid is less likely to remain on the skin-facing side of the absorbent body, reducing sticky or moist feeling of uncomfortable skin, and can be expected to have excellent wearing feeling and suitability.

1‧‧‧衛生棉1‧‧‧ Sanitary napkin

2‧‧‧正面片材 2‧‧‧Front sheet

3‧‧‧背面片材 3‧‧‧Back sheet

4‧‧‧吸收體 4‧‧‧Absorber

5‧‧‧吸收性本體 5‧‧‧ Absorbent body

5W‧‧‧翼部 5W‧‧‧wing

6‧‧‧側部片材 6‧‧‧Side sheet

7‧‧‧凹陷部 7‧‧‧Depression

10bs‧‧‧原料纖維片材 10bs‧‧‧raw fiber sheet

11‧‧‧纖維塊 11‧‧‧ fiber block

11A‧‧‧纖維塊 11A‧‧‧Fiber block

11B‧‧‧纖維塊 11B‧‧‧ Fiber block

11F‧‧‧纖維 11F‧‧‧fiber

11Z‧‧‧重疊部 11Z‧‧‧Overlap

12F‧‧‧吸水性纖維 12F‧‧‧absorbent fiber

40‧‧‧吸收性芯體 40‧‧‧absorbent core

41‧‧‧包芯片材 41‧‧‧Package chips

100‧‧‧測定台 100‧‧‧ measuring table

100a‧‧‧斜面 100a‧‧‧Bevel

101‧‧‧丙烯酸系樹脂板 101‧‧‧Acrylic resin board

110‧‧‧本體部 110‧‧‧Body

111‧‧‧基本面 111‧‧‧ Fundamentals

111a‧‧‧短邊 111a‧‧‧short side

111b‧‧‧長邊 111b‧‧‧Long side

112‧‧‧骨架面 112‧‧‧Skeleton

113‧‧‧延出纖維部 113‧‧‧Extended from the fiber department

113S‧‧‧延出纖維束部 113S‧‧‧Extend the fiber bundle

A‧‧‧前方區域 A‧‧‧front area

B‧‧‧縱中央區域 B‧‧‧Vertical central area

BL‧‧‧邊界 BL‧‧‧Border

C‧‧‧後方區域 C‧‧‧ Rear area

D1‧‧‧第1方向 D1‧‧‧First direction

D2‧‧‧第2方向 D2‧‧‧ 2nd direction

F‧‧‧外力 F‧‧‧External force

L1‧‧‧長度 L1‧‧‧Length

L1a‧‧‧間隔 L1a‧‧‧Interval

L2‧‧‧長度 L2‧‧‧Length

L2a‧‧‧間隔 L2a‧‧‧Interval

S‧‧‧測定對象 S‧‧‧Measurement target

T‧‧‧厚度 T‧‧‧thickness

X‧‧‧縱向 X‧‧‧Portrait

Y‧‧‧橫向 Y‧‧‧horizontal

Z‧‧‧厚度方向 Z‧‧‧thickness direction

圖1係使作為本發明之吸收性物品之一實施形態之經期衛生棉之一例之肌膚對向面側(正面片材側)一部分斷裂並模式性地表示之俯視圖。Fig. 1 is a plan view schematically showing a part of the skin facing side (front sheet side) of an example of a menstrual sanitary napkin according to an embodiment of the absorbent article of the present invention.

圖2係模式性地表示圖1之I-I線剖面之橫截面圖。 FIG. 2 is a schematic cross-sectional view taken along the line I-I in FIG. 1.

圖3係圖1所示之吸收性物品所具備之吸收性芯體之一部分之模式性立體圖。 Fig. 3 is a schematic perspective view of a part of an absorbent core provided in the absorbent article shown in Fig. 1.

圖4係模式性地表示圖3所示之吸收性芯體之壓縮時之變形狀態之圖。 FIG. 4 is a diagram schematically showing the deformation state of the absorbent core shown in FIG. 3 when compressed.

圖5之圖5(a)係本發明之纖維塊之實例之電子顯微鏡照片(觀察倍率25倍),圖5(b)係模式性地表示該電子顯微鏡照片之纖維塊作為圖2所示之吸收體中包含之纖維塊之圖。 5 (a) of FIG. 5 is an electron microscope photograph of an example of the fiber block of the present invention (observation magnification is 25 times), and FIG. 5 (b) is a schematic representation of the fiber block of the electron microscope photo as shown in FIG. Picture of the fiber mass contained in the absorber.

圖6係本發明之纖維塊之製造方法之說明圖。 FIG. 6 is an explanatory diagram of the method of manufacturing the fiber block of the present invention.

圖7之圖7(a)及圖7(b)分別係本發明之纖維塊中之本體部之模式性立體圖。 7 (a) and 7 (b) of FIG. 7 are schematic perspective views of the body portion of the fiber block of the present invention, respectively.

圖8係液體擴散面積之測定方法之說明圖。 FIG. 8 is an explanatory diagram of the measurement method of the liquid diffusion area.

Claims (26)

一種吸收性物品,其係具有與穿著者之前後方向對應之縱向及與其正交之橫向,且具備吸收體、及配置於該吸收體之肌膚對向面側之正面片材者, 上述吸收體係包含液體吸收性之吸收性芯體、及被覆該吸收性芯體之肌膚對向面之包芯片材而構成,該吸收性芯體包含吸水性纖維、及含有吸水性低於該吸水性纖維之弱吸水性之纖維的纖維塊; 由下述方法測得之上述吸收性芯體之液體擴散面積與由下述方法測得之上述包芯片材之液體擴散面積之比率以前者/後者計為0.7以上, <液體擴散面積之測定方法> 於相對於水平面具有45°之角度之斜面上,將測定對象以使其肌膚對向面朝向該斜面之方式固定,耗費23秒鐘將1.5 g脫纖維馬血注入至測定對象之肌膚對向面,放置3分鐘後,再次進行耗費相同時間將同量之脫纖維馬血注入至相同注入部位之操作,反覆進行6次該脫纖維馬血之注入、放置操作,將合計9 g之脫纖維馬血注入至測定對象,注入操作完成後,對測定對象之肌膚對向面中之脫纖維馬血之擴散面積進行測定,並將其作為該測定對象之液體擴散面積。An absorbent article having a longitudinal direction corresponding to the front and back directions of the wearer and a transverse direction orthogonal to the wearer, and having an absorber and a front sheet disposed on the skin-facing side of the absorber, The above-mentioned absorption system includes a liquid-absorbent absorbent core and a core-clad material covering the skin-facing surface of the absorbent core, the absorbent core including water-absorbent fibers, and containing water-absorbent fibers less than the water-absorbent core Fiber blocks of weakly absorbent fibers of sexual fibers; The ratio of the liquid diffusion area of the above-mentioned absorbent core measured by the following method to the liquid diffusion area of the above-mentioned core-wrap material measured by the following method is 0.7 or more, <Measurement method of liquid diffusion area> On an inclined surface with an angle of 45 ° relative to the horizontal plane, fix the measurement object so that the opposite side of the skin faces the inclined surface, and it takes 23 seconds to inject 1.5 g of defibrinated horse blood into the opposite side of the measurement object After leaving for 3 minutes, the same amount of defibrinated horse blood is injected into the same injection site again for the same time, and the defibrinated horse blood is injected and placed 6 times repeatedly, a total of 9 g of defibrinated horse Blood is injected into the measurement object. After the injection operation is completed, the diffusion area of the defibrillated horse blood in the skin opposite to the measurement object is measured, and this is taken as the liquid diffusion area of the measurement object. 如請求項1之吸收性物品,其中上述包芯片材係以紙漿為主體之多孔性片材。The absorbent article according to claim 1, wherein the chip-wrapping material is a porous sheet mainly composed of pulp. 如請求項1之吸收性物品,其中於上述吸收體之肌膚對向面,局部地形成有上述包芯片材及上述吸收性芯體向該吸收體之非肌膚對向面側一體地凹陷之凹陷部。The absorbent article according to claim 1, wherein on the skin-facing surface of the absorbent body, a depression is integrally formed in which the chip-wrap and the absorbent core are integrally recessed toward the non-skin-facing surface side of the absorbent body unit. 如請求項3之吸收性物品,其中上述吸收性物品於縱向上分為:縱中央區域,其包含與穿著者之排泄部對向之排泄部對向部;前方區域,其配置於較該排泄部對向部更靠穿著者之腹側;及後方區域,其配置於較該排泄部對向部更靠穿著者之背側; 上述凹陷部以包圍上述縱中央區域之橫向中央部之方式形成。The absorbent article according to claim 3, wherein the above-mentioned absorbent article is longitudinally divided into: a longitudinal central area, which includes an excretory portion facing portion opposite to the wearer's excretory portion; a front area, which is disposed closer to the excretion The opposite part is closer to the ventral side of the wearer; and the rear area, which is arranged closer to the back side of the wearer than the opposite part of the excretory part; The concave portion is formed so as to surround the lateral central portion of the longitudinal central area. 如請求項1之吸收性物品,其中上述纖維塊之外形為長方體狀或圓盤狀。The absorbent article according to claim 1, wherein the fiber block is shaped like a rectangular parallelepiped or a disc. 如請求項1之吸收性物品,其中上述纖維塊具有纖維密度相對較高之本體部、及存在於該本體部之周圍且與該本體部相比纖維密度更低之延出纖維部, 複數個上述纖維塊彼此相互交絡,並且上述纖維塊與上述吸水性纖維相互交絡。The absorbent article according to claim 1, wherein the fiber block has a body portion having a relatively high fiber density, and an extended fiber portion existing around the body portion and having a lower fiber density than the body portion, A plurality of the fiber blocks are interlaced with each other, and the fiber block and the water-absorbent fibers are interlaced with each other. 如請求項6之吸收性物品,其中上述本體部具有2個對向之基本面、及連結該2個基本面之骨架面,該基本面於俯視下呈四邊形形狀。The absorbent article according to claim 6, wherein the body portion has two opposed basic surfaces and a skeleton surface connecting the two basic surfaces, and the basic surface has a quadrangular shape in plan view. 如請求項7之吸收性物品,其中上述2個基本面之總面積大於上述骨架面之總面積。The absorbent article according to claim 7, wherein the total area of the above two basic faces is greater than the total area of the above skeleton face. 如請求項7之吸收性物品,其中上述纖維塊具有延出纖維束部,該延出纖維束部包含自上述骨架面向外側延伸之複數條纖維。The absorbent article according to claim 7, wherein the fiber block has an extended fiber bundle portion including a plurality of fibers extending outward from the frame surface. 如請求項9之吸收性物品,其中上述延出纖維束部具有複數條纖維相互熱熔而成之部位。The absorbent article according to claim 9, wherein the extended fiber bundle portion has a portion where a plurality of fibers are thermally fused with each other. 如請求項9之吸收性物品,其中上述延出纖維束部自上述本體部之延出長度為0.05 mm以上且7 mm以下。The absorbent article according to claim 9, wherein the extended length of the extended fiber bundle portion from the main body portion is 0.05 mm or more and 7 mm or less. 如請求項7之吸收性物品,其中上述基本面於俯視下呈長方形形狀,該長方形形狀之短邊與上述吸收體之厚度相比更短。The absorbent article according to claim 7, wherein the basic surface has a rectangular shape in a plan view, and the short side of the rectangular shape is shorter than the thickness of the absorbent body. 如請求項12之吸收性物品,其中上述基本面之短邊之長度與上述吸收體之厚度之比率以前者/後者計為0.03以上且1以下。The absorbent article according to claim 12, wherein the ratio of the length of the short side of the basic surface to the thickness of the absorbent body is 0.03 or more and 1 or less as the former / the latter. 如請求項12之吸收性物品,其中上述基本面之短邊之長度為0.3 mm以上且10 mm以下。The absorbent article according to claim 12, wherein the length of the short side of the above basic surface is 0.3 mm or more and 10 mm or less. 如請求項12之吸收性物品,其中上述基本面之長邊之長度為0.3 mm以上且30 mm以下。The absorbent article according to claim 12, wherein the length of the long side of the above basic plane is 0.3 mm or more and 30 mm or less. 如請求項7之吸收性物品,其中存在於上述基本面之纖維端部之每單位面積之數量N1 與存在於上述骨架面之纖維端部之每單位面積之數量N2 之比率N1 /N2 為0以上且0.90以下。The requested item 7 of the absorbent article, which is present in the amount per unit area of the N-terminal portion of the fibers of the above-described fundamentals present in an amount per unit surface area of the fibrous skeleton of the end portion of the ratio N 1 N 2 / N 2 is 0 or more and 0.90 or less. 如請求項7之吸收性物品,其中存在於上述基本面之纖維端部之每單位面積之數量為0個/mm2 以上且8個/mm2 以下。The absorbent article according to claim 7, wherein the number per unit area present at the fiber end of the above-mentioned basic plane is 0 pieces / mm 2 or more and 8 pieces / mm 2 or less. 如請求項7之吸收性物品,其中存在於上述骨架面之纖維端部之每單位面積之數量為5個/mm2 以上且50個/mm2 以下。The absorbent article according to claim 7, wherein the number per unit area of the fiber end portion present on the skeleton surface is 5 pieces / mm 2 or more and 50 pieces / mm 2 or less. 如請求項1之吸收性物品,其中上述纖維塊具有複數個熱塑性纖維相互熱熔而成之三維構造。The absorbent article according to claim 1, wherein the fiber block has a three-dimensional structure formed by thermal fusion of a plurality of thermoplastic fibers. 如請求項1之吸收性物品,其中上述纖維塊與上述吸水性纖維之含有質量比以前者/後者計為20/80~80/20。The absorbent article according to claim 1, wherein the content mass of the fiber block and the water-absorbing fiber is 20/80 to 80/20 in terms of the former / the latter. 如請求項1之吸收性物品,其中於上述吸收體中,上述纖維塊除了藉由交絡而與其他纖維塊或上述吸水性纖維結合以外,亦以可與其他纖維塊或上述吸水性纖維交絡之狀態存在。The absorbent article according to claim 1, wherein in the above-mentioned absorbent body, the fiber block can be combined with other fiber blocks or the above-mentioned water-absorbent fibers by interlacing, and can also be entangled with other fiber blocks or the above-mentioned water-absorbent fibers. The state exists. 如請求項1之吸收性物品,其中具有與其他上述纖維塊或上述吸水性纖維之結合部之上述纖維塊之總數之70%以上係該結合部藉由纖維之交絡而形成者。The absorbent article according to claim 1, wherein more than 70% of the total number of the fiber blocks having a joint portion with other fiber blocks or the water-absorbent fibers is formed by intersecting fibers at the joint portion. 如請求項1之吸收性物品,其中上述纖維塊來源於不織布。The absorbent article according to claim 1, wherein the fiber block is derived from non-woven fabric. 如請求項1之吸收性物品,其中上述包芯片材之密度為0.1 g/m3 以下。The absorbent article according to claim 1, wherein the density of the above-mentioned chip wrapping material is 0.1 g / m 3 or less. 如請求項1之吸收性物品,其中上述包芯片材之密度為0.02 g/m3 以上且0.1 g/m3 以下。The absorbent article according to claim 1, wherein the density of the above-mentioned chip wrapping material is 0.02 g / m 3 or more and 0.1 g / m 3 or less. 如請求項1之吸收性物品,其中上述包芯片材之基重為5 g/m2 以上且50 g/m2 以下。The absorbent article according to claim 1, wherein the basis weight of the above chip-wrapped material is 5 g / m 2 or more and 50 g / m 2 or less.
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