TW201929696A - Smoking article with filter - Google Patents

Smoking article with filter Download PDF

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TW201929696A
TW201929696A TW106146257A TW106146257A TW201929696A TW 201929696 A TW201929696 A TW 201929696A TW 106146257 A TW106146257 A TW 106146257A TW 106146257 A TW106146257 A TW 106146257A TW 201929696 A TW201929696 A TW 201929696A
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Taiwan
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filter
pulp
tipping paper
paper
smoking article
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TW106146257A
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Chinese (zh)
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TWI741119B (en
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櫻井亨
日出島拓
黒宮悠祐
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日商日本煙草產業股份有限公司
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Abstract

The present invention provides a smoking article with filter having an aerosol generating rod, a filter disposed at the downstream end of the aerosol generating rod, a tipping paper wound on the downstream end of the aerosol generating rod and the outer circumferential surface of the filter to connect the aerosol generating rod and the filter, wherein the tipping paper is a paper containing bleached pulp and unbleached pulp, and the fibers of the unbleached pulp have a length of 1 mm to 4 mm and a thickness of 20 [mu]m to 70 [mu]m.

Description

附濾嘴之吸煙物品 Smoking article with filter

本發明係關於附濾嘴之吸煙物品。 The present invention relates to a smoking article with a filter.

附濾嘴之吸煙物品,例如,一般之附濾嘴之香煙係如下所述:將含有乙酸纖維素纖維或紙漿之不織布予以綁束或折疊而成型為濾嘴材,且將該濾嘴材以濾嘴包覆材(filter wrapper)包起而成型為棒狀之濾嘴,另將乾燥煙草葉以香煙紙包起而成型為棒狀之香煙棒(cigarette rod),而且將該濾嘴與該香煙棒在端與端鄰接之狀態下以接裝紙(tipping paper,又稱外層紙)捲包全周而將濾嘴與香煙棒兩者予以接著並一體化者。此時,接裝紙係捲在香煙棒之濾嘴側端部及濾嘴,且連接香煙棒與濾嘴。 A smoking article with a filter, for example, a general cigarette with a filter is as follows: a non-woven fabric containing cellulose acetate fibers or pulp is tied or folded to form a filter material, and the filter material is a filter wrapper is packaged to form a rod-shaped filter, and the dried tobacco leaf is wrapped with cigarette paper to form a rod-shaped cigarette rod, and the filter is The cigarette rod is wrapped around the end and the end with a tipping paper (also referred to as an outer layer paper) and the filter and the cigarette rod are both joined and integrated. At this time, the tipping paper is wound around the filter side end of the cigarette rod and the filter, and the cigarette rod and the filter are connected.

接裝紙為嘴吸部位,係與附濾嘴之香煙的嗜好性有關之部位之一,故一般係重視能營造出清潔感之白度。因此,檢討對於白色接裝紙原紙進行加飾而製造接裝紙之技術。如此之對於白色接裝紙原紙之加飾,係有凹板印刷、全像圖印刷、箔印刷等,藉由採用發揮該原紙的白度之設計,而可對於附濾嘴之香煙賦予嗜好性並追求製品之差別化(例如專利文獻1、2)。 The tipping paper is one of the parts related to the taste of the cigarette with the filter, so it is generally attached to the whiteness that can create a clean feeling. Therefore, the technique of manufacturing the tipping paper for the white tipping paper base paper is reviewed. Such a decoration for the white tipping paper base paper is concave printing, full-image printing, foil printing, etc., and by using the design of the whiteness of the base paper, it is possible to impart preference to the cigarette with the filter. In addition, product differentiation is pursued (for example, Patent Documents 1 and 2).

另一方面,亦存在有以白色原紙為基底而訴求天然感之設計,較易理解的例子可舉出軟木印刷(例如專利文獻3)。 On the other hand, there is a design that appeals to the natural feeling based on the white base paper, and an example that can be easily understood is cork printing (for example, Patent Document 3).

[先前技術文獻] [Previous Technical Literature] [專利文獻] [Patent Literature]

專利文獻1:國際公開第2015/177907號。 Patent Document 1: International Publication No. 2015/177907.

專利文獻2:日本特表2016-508377號公報。 Patent Document 2: Japanese Laid-Open Patent Publication No. 2016-508377.

專利文獻3:日本專利第4191273號公報。 Patent Document 3: Japanese Patent No. 4121273.

除了白色接裝紙以外,對於附濾嘴之香煙能有效地賦予嗜好性之接裝紙,係例如具有清潔感、天然感之外觀之接裝紙。雖然軟木印刷現在是一般廣為使用之設計,但終究只是仿製而還是有人工感。即使欲使質感變更好而追求軟木印刷以外之設計,然而終究只是以「刻在凹板圓筒上之乍看下為不規則但實際上為規則之圖案」重複而製作之圖案,若以至今為止之白色原紙與印刷的組合,實難以營造出天然感及自然感。 In addition to the white tipping paper, the tipping paper which can effectively impart a preference to the cigarette with a filter is, for example, a tipping paper having a clean feeling and a natural appearance. Although cork printing is now widely used, it is only imitation and artificial. Even if you want to make the texture better, and pursue the design other than cork printing, after all, it is only a pattern created by repeating the pattern that is “irregular but actually a regular pattern on the concave cylinder”. The combination of white base paper and printing has made it difficult to create a natural and natural feeling.

本發明之課題為提供一種附濾嘴之吸煙物品,係含有具質感之接裝紙,而可營造出以印刷係無法實現之自然感。 An object of the present invention is to provide a smoking article with a filter, which comprises a textured tipping paper, and which can create a natural feeling that cannot be achieved by a printing system.

根據本發明可提供一種附濾嘴之吸煙物 品,係具備:霧氣(aerosol,亦可稱為氣溶膠)生成棒;濾嘴,係配置於霧氣生成棒之下游端;以及接裝紙,係捲在霧氣生成棒之下游端部及濾嘴之外周面,而連接霧氣生成棒及濾嘴;其中,接裝紙係含有漂白紙漿及未漂白紙漿之紙,未漂白紙漿之纖維具有1mm至4mm之長度、20μm至70μm之粗度。 According to the present invention, a smoking article with a filter can be provided The product has a: aerosol (also known as an aerosol) generating rod; the filter is disposed at the downstream end of the mist generating rod; and the tipping paper is wound at the downstream end of the mist generating rod and the filter The outer peripheral surface is connected to the mist generating rod and the filter; wherein the tipping paper contains paper of bleached pulp and unbleached pulp, and the fibers of the unbleached pulp have a length of from 1 mm to 4 mm and a thickness of from 20 μm to 70 μm.

就吸煙物品而言,除了香煙以外,亦有使包含香煙棒之霧氣生成棒的前端燃燒而生成煙之雪茄(cigar)或小雪茄(cigarillo)等吸煙物品。此外,吸煙物品亦包括「將包含香煙棒之霧氣生成棒在不伴隨燃燒之情形下進行加熱而生成香味成分的型態」。在不伴隨燃燒之情形下進行加熱之方式,係有藉由電阻、IH、化學變化或相變化而加熱之方式等。 In the case of smoking articles, in addition to cigarettes, there are also smoking articles such as cigars or cigarillos that burn the front end of a mist-generating rod containing a cigarette rod to generate smoke. In addition, the smoking article also includes "a type in which a mist-generating rod containing a cigarette rod is heated to generate a flavor component without being burned." The method of heating without being accompanied by combustion is a method of heating by resistance, IH, chemical change, or phase change.

如上所述,霧氣生成棒係包含將乾燥煙草葉以香煙紙包起而成型為棒狀之香煙棒。此外,亦包含:將乾燥煙草葉以煙草薄片包起者;以及於煙草葉以外之基材含浸甘油等霧氣源與香味成分,並將該基材以紙包起而製成棒狀者等。不論在任一形態中,霧氣生成棒皆為略圓柱狀,在一方之端部對接濾嘴,並以接裝紙捲裝而連接。 As described above, the mist generating rods include cigarette rods in which dried tobacco leaves are wrapped in cigarette paper to form a rod shape. Further, the present invention also includes a method in which a dry tobacco leaf is wrapped with a tobacco sheet, and a substrate other than the tobacco leaf is impregnated with a mist source such as glycerin and a flavor component, and the substrate is wrapped in paper to form a rod. In either form, the mist generating rods are slightly cylindrical, and the filters are butted at one end and connected by a tipping paper roll.

根據本發明,可對於附濾嘴之吸煙物品賦予天然感及嗜好性。 According to the present invention, it is possible to impart a natural feeling and a preference to a smoking article with a filter.

1‧‧‧第1實施形態的附濾嘴之香煙 1‧‧‧The filter cigarette with the first embodiment

2‧‧‧第2實施形態的附濾嘴之香煙 2‧‧‧A cigarette with a filter of the second embodiment

11‧‧‧霧氣生成棒 11‧‧‧Fog gas generation rod

12‧‧‧濾嘴 12‧‧‧ filter

13‧‧‧接裝紙 13‧‧‧Tipping paper

14‧‧‧清漆 14‧‧‧ varnish

111‧‧‧煙草細絲 111‧‧‧Tobacco filament

112‧‧‧香煙紙 112‧‧‧ cigarette paper

121‧‧‧濾嘴材 121‧‧‧Filter material

122‧‧‧濾嘴包覆材 122‧‧‧Filter cover material

第1圖係第1實施形態的附濾嘴之香煙之概略斜視圖。 Fig. 1 is a schematic perspective view of a cigarette with a filter according to a first embodiment.

第2圖係將沿著第1圖之II-II線之剖面予以放大表示的概略剖面圖。 Fig. 2 is a schematic cross-sectional view showing an enlarged cross section taken along line II-II of Fig. 1 .

第3圖係將第2實施形態的附濾嘴之香煙之一部分予以放大表示的剖面圖。 Fig. 3 is a cross-sectional view showing an enlarged portion of a cigarette with a filter according to a second embodiment.

以下一邊參照圖面一邊說明數個實施形態。實施形態中之相同構成係附以相同符號並省略重複說明。此外,各圖係用以理解實施形態之示意圖,其形狀、尺寸、比例等有與實際情形相異之處。本說明書中適宜使用「上游」及「下游」之用語,該等係以將附濾嘴之吸煙物品進行吸煙時之主流煙之流動方向為基準。 Hereinafter, several embodiments will be described with reference to the drawings. The same components in the embodiments are denoted by the same reference numerals and the description thereof will not be repeated. In addition, the drawings are used to understand the schematic diagram of the embodiment, and the shape, size, proportion, and the like are different from the actual situation. It is appropriate to use the terms "upstream" and "downstream" in this specification, which is based on the flow direction of the mainstream smoke when the smoking article with the filter is smoked.

以下之實施形態中,係說明以附濾嘴之香煙作為附濾嘴之吸煙物品之一例。 In the following embodiments, a cigarette with a filter is used as an example of a smoking article with a filter.

(第1實施形態) (First embodiment)

第1圖係第1實施形態的附濾嘴之香煙1之概略斜視圖。第2圖係將沿著第1圖之II-II線之剖面予以放大表示的概略剖面圖。附濾嘴之香煙1係具備霧氣生成棒11、濾嘴12、及接裝紙13。 Fig. 1 is a schematic perspective view of the cigarette 1 with a filter according to the first embodiment. Fig. 2 is a schematic cross-sectional view showing an enlarged cross section taken along line II-II of Fig. 1 . The cigarette 1 with a filter includes a mist generating rod 11, a filter 12, and a tipping paper 13.

霧氣生成棒11係例如由「包含乾燥煙草葉之煙草細絲111」及「捲裝煙草細絲111周圍之香煙紙112」所構成,為略圓柱狀。香煙紙112為例如具有通氣性的紙。 The mist generating rod 11 is composed of, for example, "tobacco filaments 111 containing dried tobacco leaves" and "cigarette paper 112 around the bundle of tobacco filaments 111", and has a substantially cylindrical shape. The cigarette paper 112 is, for example, paper having air permeability.

濾嘴12係配置於霧氣生成棒11之下游端。濾嘴12係具有與霧氣生成棒11相同或略同之直徑。濾嘴12係由「濾嘴材121」及「捲裝濾嘴材121周圍之濾嘴包覆材122」所構成。濾嘴12係由單一濾嘴材所構成,亦即具有簡樸濾嘴(plain filter)構造。 The filter 12 is disposed at the downstream end of the mist generating rod 11. The filter 12 has the same or slightly the same diameter as the mist generating rod 11. The filter 12 is composed of "filter material 121" and "filter cover material 122 around the package filter material 121". The filter 12 is composed of a single filter material, that is, has a plain filter structure.

濾嘴材121係例如由「將纖維素乙酸酯纖維或紙漿之不織布予以綁束或折疊而成型者」所構成。 The filter material 121 is composed of, for example, "a pair of cellulose acetate fibers or a non-woven fabric of pulp to be bundled or folded."

濾嘴包覆材122係例如基量15gsm至100gsm、厚度30μm至100μm之紙。此種紙的通氣度為0C.U.至30000C.U.。通氣度係根據ISO 2965:2009所測定之值,其係以在紙兩面之壓差為1kPa時每1分鐘通過面積1cm2之氣體流量(cm3)來表示。1Coresta單位(1C.U.)係在1kPa下的cm3/(min.cm2)。 The filter covering member 122 is, for example, a paper having a basis weight of 15 gsm to 100 gsm and a thickness of 30 μm to 100 μm. The air permeability of such paper is from 0 C. U. to 30000 C. U. The air permeability is a value measured according to ISO 2965:2009, which is expressed by a gas flow rate (cm 3 ) per 1 minute passing through an area of 1 cm 2 when the pressure difference between the two sides of the paper is 1 kPa. The 1 Coresta unit (1 C. U.) is cm 3 /(min.cm 2 ) at 1 kPa.

接裝紙13係捲在霧氣生成棒11之下游端部及濾嘴12之外周面,且連接霧氣生成棒11與濾嘴12。接裝紙13係藉由糊等接著劑而將霧氣生成棒11與濾嘴12予以接著。此外,接裝紙13係含有漂白紙漿與未漂白紙漿之紙。 The tipping paper 13 is wound around the downstream end of the mist generating rod 11 and the outer peripheral surface of the filter 12, and the mist generating rod 11 and the filter 12 are connected. The tipping paper 13 is followed by the mist generating rod 11 and the filter 12 by an adhesive such as a paste. Further, the tipping paper 13 is a paper containing bleached pulp and unbleached pulp.

未漂白紙漿係未經漂白之有色紙漿。未漂白紙漿之纖維係具有1mm至4mm之長度、20μm至70μm之粗度,較佳為具有2mm至4mm之長度、30μm至70μm之粗度。當接裝紙13中所含之未漂白紙漿之纖維具有1mm至4mm之長度、20μm至70μm之粗度時,吸煙者可在接裝紙13外周側表面目視確認到未漂白紙漿之存在。因此, 當接裝紙13含有「具有1mm至4mm之長度、20μm至70μm之粗度的未漂白紙漿之纖維」時,具備該接裝紙13的附濾嘴之香煙1可使吸煙者目視確認到天然感。 Unbleached pulp is unbleached colored pulp. The fiber of the unbleached pulp has a length of from 1 mm to 4 mm, a thickness of from 20 μm to 70 μm, preferably a length of from 2 mm to 4 mm, and a thickness of from 30 μm to 70 μm. When the fibers of the unbleached pulp contained in the tipping paper 13 have a length of from 1 mm to 4 mm and a thickness of from 20 μm to 70 μm, the smoker can visually confirm the presence of the unbleached pulp on the outer peripheral side surface of the tipping paper 13. therefore, When the tipping paper 13 contains "fibers of unbleached pulp having a length of 1 mm to 4 mm and a thickness of 20 μm to 70 μm", the cigarette 1 with the tipping paper 13 allows the smoker to visually confirm the natural sense.

接裝紙13所含之未漂白紙漿之纖維之長度及粗度係使用顯微鏡以100倍以下倍率觀察接裝紙13之表面,並以附屬之尺規來測定50條左右之可目視之有色纖維的粗度及長度。 The length and the thickness of the fibers of the unbleached pulp contained in the tipping paper 13 are observed on the surface of the tipping paper 13 at a magnification of 100 times or less using a microscope, and 50 or so visible colored fibers are measured by an attached ruler. Thickness and length.

接裝紙13所含之未漂白紙漿之比例係例如較佳為1重量%以上且90重量%以下,更佳為5重量%以上且未達86重量%,又更佳為5重量%以上且60重量%以下。實施形態所使用之接裝紙13係含有漂白紙漿及未漂白紙漿,故相較於僅由漂白紙漿所構成之接裝紙,在製造時可減少使用漂白劑而可減輕環境負荷。 The ratio of the unbleached pulp contained in the tipping paper 13 is, for example, preferably 1% by weight or more and 90% by weight or less, more preferably 5% by weight or more and less than 86% by weight, and still more preferably 5% by weight or more. 60% by weight or less. Since the tipping paper 13 used in the embodiment contains the bleached pulp and the unbleached pulp, the use of the bleaching agent can reduce the use of the bleaching agent and reduce the environmental load.

漂白紙漿係藉由使用氧化劑、還原劑等漂白劑而經漂白之紙漿。漂白紙漿之纖維之長度及粗度,係可與未漂白紙漿之長度及粗度相同或相異,並無特別限定。 The bleached pulp is a bleached pulp by using a bleaching agent such as an oxidizing agent or a reducing agent. The length and thickness of the fibers of the bleached pulp may be the same or different from the length and thickness of the unbleached pulp, and are not particularly limited.

此外,接裝紙13較佳為CIELab表色系中的明度L*為78至93、色度a*為0.6至2.8、色度b*為7至18。接裝紙13之CIELab表色系中的明度L*、色度a*、色度b*可使用分光光度計(X-Rite公司製,品名SpectroEye)計測。更佳為接裝紙13之CIELab表色系為明度L*為80至92.5、色度a*為0.7至1.6、色度b*為8至13。接裝紙13之CIELab表色系之明度L*、色度a*、色度b*可藉由調節漂白紙漿與未漂白紙漿之種類、未漂白紙漿之含量而 控制。另外,即使接裝紙之CIELab表色系中的明度L*為78至93、色度a*為0.6至2.8、色度b*為7至18之範圍內,當該接裝紙不含有「具有1mm至4mm之長度、20μm至70μm之粗度的未漂白紙漿之纖維」時,該接裝紙會僅為有色紙。因此,含有該接裝紙的附濾嘴之香煙,會難以使吸煙者目視確認到天然感。 Further, the tipping paper 13 preferably has a lightness L* of 78 to 93, a chromaticity a* of 0.6 to 2.8, and a chromaticity b* of 7 to 18 in the CIELab color system. The brightness L*, the chromaticity a*, and the chromaticity b* in the CIELab color system of the tipping paper 13 can be measured using a spectrophotometer (manufactured by X-Rite Co., Ltd., product name SpectroEye). More preferably, the CIELab color of the tipping paper 13 has a lightness L* of 80 to 92.5, a chromaticity a* of 0.7 to 1.6, and a chromaticity b* of 8 to 13. The brightness L*, chromaticity a*, and chromaticity b* of the CIELab color of the tipping paper 13 can be adjusted by adjusting the type of bleached pulp and unbleached pulp, and the content of unbleached pulp. control. In addition, even if the brightness L* of the CIELab color system of the tipping paper is 78 to 93, the chromaticity a* is 0.6 to 2.8, and the chromaticity b* is in the range of 7 to 18, when the tipping paper does not contain " When the fiber of unbleached pulp having a length of from 1 mm to 4 mm and a thickness of from 20 μm to 70 μm is used, the tipping paper is only colored paper. Therefore, it is difficult for a cigarette with a filter containing the tipping paper to visually confirm the natural feeling of the smoker.

漂白紙漿可使用木材紙漿。未漂白紙漿可使用木材紙漿或非木材紙漿。 Wood pulp can be used for bleached pulp. Wood pulp or non-wood pulp can be used for unbleached pulp.

成為木材紙漿原料之木材種類並無特別限定,較佳為:日本柳杉、日本扁柏、松樹、日本冷杉、唐檜等針葉樹;桉樹、山毛櫸、櫟樹、楊樹等闊葉樹。 The type of wood to be used as a raw material for wood pulp is not particularly limited, and is preferably: Japanese cedar, Japanese cypress, pine, Japanese fir, and Tang dynasty; coniferous trees such as eucalyptus, beech, eucalyptus, and poplar.

就木材紙漿而言,例如可使用上述木材,以牛皮紙漿法(Kraft process)等化學處理之蒸解步驟而從原料木材去除雜質或木質素,然後進行漂白步驟、洗淨步驟,藉此而製造木材紙漿。如此之以牛皮紙漿法製造之木材紙漿,亦稱為牛皮紙漿或化學紙漿,具有高柔軟性且雜質少,故以作為漂白紙漿來使用為佳。 In the case of wood pulp, for example, the above-mentioned wood can be used, and impurities or lignin can be removed from the raw material wood by a chemical treatment distillation step such as a Kraft process, followed by a bleaching step and a washing step, thereby producing wood. pulp. The wood pulp produced by the kraft pulp process, also known as kraft pulp or chemical pulp, has high flexibility and less impurities, so it is preferably used as a bleached pulp.

此外,就木材紙漿而言,例如可使用上述木材,以蒸解步驟而從原料木材去除雜質或木質素,然後以短時間進行或完全不進行漂白步驟,並且進行洗淨步驟,藉此而製造木材紙漿。如此製造之木材紙漿係因具有上述長度及粗度之纖維,故可作為未漂白紙漿來使用。 Further, in the case of wood pulp, for example, the above-mentioned wood can be used to remove impurities or lignin from the raw material wood in a steaming step, and then the bleaching step is carried out in a short time or not at all, and a washing step is carried out, thereby producing wood. pulp. The wood pulp thus produced is used as an unbleached pulp because it has fibers of the above length and thickness.

未漂白紙漿可含有例如非木材紙漿。成為非木材紙漿原料之非木材之種類並無特別限定,較佳為大 麻屬、洋麻、亞麻、稻桿、麥桿等。 Unbleached pulp may contain, for example, non-wood pulp. The type of non-wood which is a non-wood pulp raw material is not particularly limited, and is preferably large. Hemp, kenaf, flax, rice straw, wheat straw, etc.

非木材紙漿中,除了上述具有較佳長度及粗度之纖維以外,有時會含有超過較佳長度及粗度之纖維、斑點狀的塊等。含有此等不佳之纖維及塊之接裝紙中,該纖維或塊會在外觀上被視為異物,具備該接裝紙的附濾嘴之香煙會有損及高嗜好性之虞。因此,未漂白紙漿雖亦可含有非木材紙漿,但較佳為含有較多之木材紙漿,又更佳為僅有木材紙漿。 In the non-wood pulp, in addition to the above-mentioned fibers having a preferred length and thickness, fibers having more than a preferred length and thickness, and a patch-like block may be contained. In the tipping paper containing such poor fibers and blocks, the fibers or blocks are regarded as foreign matter in appearance, and the filter-attached cigarette having the tipping paper may be detrimental to high taste. Therefore, the unbleached pulp may contain non-wood pulp, but preferably contains more wood pulp, and more preferably only wood pulp.

接裝紙13可更含有屬於填料之碳酸鈣或氧化鈦,且可為不透明度76%以上之紙。不透明度76%以上之接裝紙13,係例如可藉由含有20重量%以上碳酸鈣而得之。不透明度76%以上之接裝紙13中,表面印刷之文字及圖形難以透至內面,故為較佳。 The tipping paper 13 may further contain calcium carbonate or titanium oxide belonging to the filler, and may be paper having an opacity of 76% or more. The tipping paper 13 having an opacity of 76% or more can be obtained, for example, by containing 20% by weight or more of calcium carbonate. In the tipping paper 13 having an opacity of 76% or more, it is preferable that the characters and graphics printed on the surface are difficult to penetrate to the inner surface.

填料係例如為於紙中所調配之礦物質粉末,係包括無機或有機之合成物。就填料而言,除了碳酸鈣以外,亦包括氧化鈦、燒成高嶺土、高嶺土、滑石、酸性白土、氫氧化鋁或合成二氧化矽等。接裝紙13中,除了碳酸鈣、氧化鈦以外,可含有1種以上之其他填料。藉由在接裝紙13中若含有上述填料,即可在不損及能目視確認接裝紙之未漂白紙漿之纖維的外觀性下,對該接裝紙賦予阻燃性。例如,藉由在接裝紙13中含有高嶺土、氫氧化鋁,而可對該接裝紙賦予阻燃性。 The filler is, for example, a mineral powder formulated in paper, and includes an inorganic or organic composition. In terms of the filler, in addition to calcium carbonate, titanium oxide, calcined kaolin, kaolin, talc, acid white clay, aluminum hydroxide or synthetic cerium oxide are also included. The tipping paper 13 may contain one or more other fillers in addition to calcium carbonate and titanium oxide. By including the filler in the tipping paper 13, the flame retardancy can be imparted to the tipping paper without impairing the appearance of the fiber of the unbleached pulp which can visually confirm the tipping paper. For example, by including kaolin and aluminum hydroxide in the tipping paper 13, the tipping paper can be imparted with flame retardancy.

此外,在含有「木材紙漿、屬於填料之碳酸鈣、以及濕潤紙力增強劑」的基網表面形成有疏水性塗 佈劑層之接裝紙,係可賦予優異耐水性。 In addition, a hydrophobic coating is formed on the surface of the base web containing "wood pulp, calcium carbonate belonging to the filler, and wet paper strength enhancer" The tipping paper of the cloth layer imparts excellent water resistance.

濕潤紙力增強劑可舉出聚醯胺環氧氯丙烷(polyamideepichlorohydrin,即PAE)、聚乙烯亞胺(polyethyleneimine)、環氧化聚醯胺、聚丙烯醯胺等。 Examples of the moist paper strength enhancer include polyamideepichlorohydrin (PAE), polyethyleneimine, epoxidized polyamine, and polypropylene decylamine.

疏水性塗佈劑可舉出硝基纖維素(NC)、含有適於凹板印刷之顏料的有色疏水性印墨等。 Examples of the hydrophobic coating agent include nitrocellulose (NC), a colored hydrophobic ink containing a pigment suitable for intaglio printing, and the like.

接裝紙13較佳為更具有例如26.0N/15mm以上之拉伸強度。具有26.0N/15mm以上之拉伸強度之接裝紙13,可確保在高速製造香煙時所要求之充分強度。因此,在高速製造香煙時,在各裝置移動之間可防止或降低接裝紙受傷或破裂。 The tipping paper 13 preferably has a tensile strength of, for example, 26.0 N/15 mm or more. The tipping paper 13 having a tensile strength of 26.0 N/15 mm or more ensures sufficient strength required for high-speed manufacture of cigarettes. Therefore, when the cigarette is manufactured at a high speed, the tipping paper can be prevented or reduced from being injured or broken between the movements of the respective devices.

就接裝紙13而言,在其表面粗糙時,於其表面上印刷之文字或圖案雖容易缺白,但因缺白之文字或圖案而可增加天然感。另一方面,表面平滑之接裝紙,可在不損及天然感下,於其表面上印刷明瞭之文字或圖案。因此,接裝紙13可具有5sec以上且300sec以下之廣範圍之平滑度。此外,於接裝紙13印刷時,可使用環境對應型印墨,例如植物油印墨。 In the case of the tipping paper 13, when the surface thereof is rough, the characters or patterns printed on the surface thereof are easily whitened, but the natural feeling is increased by the lack of white characters or patterns. On the other hand, the tipping paper with a smooth surface can print a clear text or pattern on the surface without damaging the natural feeling. Therefore, the tipping paper 13 can have a wide range of smoothness of 5 sec or more and 300 sec or less. Further, when the tipping paper 13 is printed, an environment-compatible ink such as a vegetable oil ink can be used.

例如,可藉由如以下之方法來製造上述接裝紙。 For example, the above tipping paper can be manufactured by the following method.

首先,準備屬於針葉樹之唐檜及屬於闊葉樹之楊樹作為漂白紙漿,並準備松樹作為未漂白紙漿。將所期望之比例之漂白紙漿與未漂白紙漿投入打漿機(pulper),使該等紙漿離解。然後,將離解之紙漿移至精製 機(refiner),並以精製機進行叩解。另外準備作為填料之碳酸鈣、以及作為製造助劑之凝集劑,將該等與經叩解之紙漿混合。此外,可使用複數個打漿機分別單獨離解漂白紙漿及未漂白紙漿,以精製機進行叩解,於混合箱中將分別經叩解之漂白紙漿及未漂白紙漿、填料、製造助劑予以混合。 First, the Tang dynasty belonging to the conifer and the poplar belonging to the broad-leaved tree are prepared as bleached pulp, and the pine is prepared as the unbleached pulp. The desired ratio of bleached pulp and unbleached pulp is placed in a pulper to dissociate the pulp. Then, the disintegrated pulp is moved to the refined Refiner and resolve with a refiner. Further, calcium carbonate as a filler and an aggregating agent as a manufacturing aid are prepared, and these are mixed with the decomposed pulp. In addition, a plurality of beaters can be used to separate the bleached pulp and the unbleached pulp separately, and the product is decomposed by a refiner, and the separately decomposed bleached pulp and unbleached pulp, filler, and manufacturing aid are mixed in a mixing tank.

其次,使用該混合紙漿,在以長網抄紙機、圓網抄紙機、圓短複合抄紙機等所進行之抄紙步驟中,整理質地並予以均一化而製造接裝紙。此外,在抄紙步驟時,可添加烷基烯酮二聚物(alkyl ketene dimer,即AKD)之類之滲透防止劑而調整接裝紙之印刷情況、或可添加濕潤紙力劑而對接裝紙賦予耐水性。 Next, using the mixed pulp, the texture is finished and homogenized in a papermaking step by a long-wire paper machine, a cylinder paper machine, a round-short paper machine, or the like to produce a tipping paper. In addition, in the papermaking step, a penetration preventive agent such as an alkyl ketene dimer (AKD) may be added to adjust the printing of the tipping paper, or a wet paper force agent may be added to the butt paper. Give water resistance.

(第2實施形態) (Second embodiment)

第3圖係將第2實施形態的附濾嘴之香煙2之一部分予以放大表示之概略剖面圖。第2實施形態的附濾嘴之香煙2,除了在接裝紙13外周側存在有清漆(varnish)14以外,具有與第1實施形態的附濾嘴之香煙1相同之構成。 Fig. 3 is a schematic cross-sectional view showing a part of the cigarette 2 with a filter according to the second embodiment in an enlarged manner. In addition to the varnish 14 on the outer peripheral side of the tipping paper 13, the cigarette 2 with a filter of the second embodiment has the same configuration as the cigarette 1 with a filter according to the first embodiment.

清漆14係滲入接裝紙13並亦存在於接裝紙13內部。清漆係例如可使用硝基纖維素、乙基纖維素、羧甲基纖維素等。 The varnish 14 is infiltrated into the tipping paper 13 and is also present inside the tipping paper 13. As the varnish, for example, nitrocellulose, ethylcellulose, carboxymethylcellulose or the like can be used.

因附濾嘴之香煙2係在接裝紙13外周側存在有清漆14,故除了第1實施形態所述效果以外,亦可抑制或防止由源自於接裝紙13所含之未漂白紙漿的木質素 或其他雜質所造成之風味降低。此外,因附濾嘴之香煙2係於接裝紙13外周側存在有清漆14,故可提高在將附濾嘴之香煙2進行吸煙時之接裝紙13之離脣性。 Since the cigarette 2 with the filter has the varnish 14 on the outer peripheral side of the tipping paper 13, the unbleached pulp derived from the tipping paper 13 can be suppressed or prevented in addition to the effects described in the first embodiment. Lignin Or the flavor caused by other impurities is reduced. Further, since the cigarette 2 with the filter is provided with the varnish 14 on the outer peripheral side of the tipping paper 13, the lip-off property of the tipping paper 13 when the cigarette 2 with the filter is smoked can be improved.

此外,以上所說明之各實施形態的附濾嘴之香煙亦可具備其他構成。例如,亦可具備貫通接裝紙並到濾嘴為止之複數個孔(通氣孔)。如此之通氣孔係具有從外部往濾嘴內供給空氣的功能。 Further, the cigarette with a filter according to each of the embodiments described above may have other configurations. For example, a plurality of holes (vent holes) may be provided through the tipping paper and up to the filter. Such a vent hole has a function of supplying air from the outside into the filter.

此外,濾嘴形狀可為雙重濾嘴(dual filter)、三重濾嘴(triple filter)等。 Further, the filter shape may be a dual filter, a triple filter, or the like.

(實施例) (Example)

以下詳細說明本發明之實施例。 The embodiments of the present invention are described in detail below.

(實施例1至8及比較例1、2) (Examples 1 to 8 and Comparative Examples 1, 2)

依下述表1所示比例調配漂白紙漿及未漂白紙漿,於實施例1至8準備接裝紙。此外,未漂白紙漿具有1mm至4mm之長度、20μm至70μm之粗度之纖維。 The bleached pulp and the unbleached pulp were blended in the proportions shown in Table 1 below, and the tipping paper was prepared in Examples 1 to 8. Further, the unbleached pulp has a fiber having a length of from 1 mm to 4 mm and a thickness of from 20 μm to 70 μm.

另外,準備不含有未漂白紙漿而僅由漂白紙漿所構成之白色接裝紙,作為比較例1之接裝紙。 Further, a white tipping paper composed of only bleached pulp which did not contain unbleached pulp was prepared as the tipping paper of Comparative Example 1.

再者,準備在比較例1之白色接裝紙之表面上施予軟木印刷而得之比較例2之接裝紙。並且,軟木印刷係以模仿天然軟木圖案之圖案進行凹板印刷者,其係普遍廣泛使用於香煙。 Further, a tipping paper of Comparative Example 2 obtained by applying cork printing to the surface of the white tipping paper of Comparative Example 1 was prepared. Moreover, cork printing is a gravure printing machine that mimics the pattern of a natural cork pattern, which is widely used in cigarettes.

使用分光光度計(X-Rite公司製,品名SpectroEye)計測實施例1至8及比較例1、2之接裝紙之 CIELab表色系之明度L*、色度a*、色度b*。計測係在光源D65、無光源過濾器、視角2°之條件下,於ISO白色度92%之紙上放置1片試料,於其上按壓分光光度計而實施。此外,每1次都變更接裝紙之計測處共計測5點,計算5點之平均值。其結果示於下述表1。 The tipping papers of Examples 1 to 8 and Comparative Examples 1 and 2 were measured using a spectrophotometer (manufactured by X-Rite Co., Ltd., SpectroEye). The brightness of the CIELab color system is L*, chromaticity a*, and chromaticity b*. The measurement was carried out by placing a sample on a paper having an ISO whiteness of 92% under the conditions of a light source D65, a light sourceless filter, and a viewing angle of 2°, and pressing the spectrophotometer thereon. In addition, the measurement area of the tipping paper is changed every 5 times to measure 5 points, and the average value of 5 points is calculated. The results are shown in Table 1 below.

其次,使用實施例1至5及比較例1之接裝紙,製造第2圖所示構成的附濾嘴之香煙。 Next, using the tipping sheets of Examples 1 to 5 and Comparative Example 1, the filter-attached cigarette having the configuration shown in Fig. 2 was produced.

另外,於實施例6至8及比較例2之接裝紙之外周面,將由硝基纖維素所構成之清漆進行凹版印刷後,使用該等接裝紙,製造如第3圖所示構成的附濾嘴之香煙。 Further, in the outer peripheral surfaces of the tipping sheets of Examples 6 to 8 and Comparative Example 2, the varnish composed of nitrocellulose was subjected to gravure printing, and then the tipping paper was used to fabricate the varnish as shown in Fig. 3. A cigarette with a filter.

分別製造20支具備實施例1至8及比較例1、2之接裝紙的附濾嘴之香煙,在溫度22℃、相對濕度60%之環境下藏置10天。 Twenty cigarettes with filters attached to the tipping sheets of Examples 1 to 8 and Comparative Examples 1 and 2 were separately produced and stored for 10 days in an environment of a temperature of 22 ° C and a relative humidity of 60%.

對於實施例1至8及比較例1、2的附濾嘴之香煙,進行以下所說明之評價(1)至(4)。 The cigarettes attached to the filters of Examples 1 to 8 and Comparative Examples 1 and 2 were evaluated (1) to (4) described below.

<評價(1):關於外觀(未漂白紙漿之纖維之目視確認性)之官能評價> <Evaluation (1): Functional evaluation of appearance (visual confirmation of fibers of unbleached pulp) >

關於「未漂白紙漿之纖維之目視確認性」之官能評價,係將具備實施例1至8及比較例1、2之接裝紙的附濾嘴之香煙置於舖有白紙之桌上,由20名測試員以目視實施評價。20名測試員全員一眼即可目視到未漂白紙漿之纖維時為「A」,即使僅有1名測試員無法一眼目視到未漂白紙 漿之纖維時亦為「B」。 The sensory evaluation of the "visual confirmation of the fibers of the unbleached pulp" was carried out by placing the cigarettes with the tipping papers of Examples 1 to 8 and Comparative Examples 1 and 2 on a table covered with white paper. Twenty testers performed the evaluation visually. 20 testers can see the fiber of unbleached pulp at a glance, even if only one tester can't see the unbleached paper at a glance. The fiber of the pulp is also "B".

<評價(2):關於外觀(天然感)之官能評價> <Evaluation (2): Functional evaluation about appearance (natural feeling)>

關於「天然感」之官能評價,係將具備實施例1至8及比較例1、2之接裝紙的附濾嘴之香煙與評價(1)之官能評價同樣地置於舖有白紙之桌上,由20名測試員以目視實施評價。明顯感到天然、自然時為3分,稍微感到天然、自然時為2分,少許感到天然、自然時為1分,完全未感到天然、自然感時為0分,當20名之平均分數大於2分(具有高天然感)時為「A」,1至2分(具有比較性上為較高之天然感)時為「B」,未達1分(具有低天然感)時為「C」。 The sensory evaluation of the "natural feeling" was carried out on the table covered with white paper in the same manner as the sensory evaluation of the evaluation (1) of the cigarettes provided with the tipping sheets of Examples 1 to 8 and Comparative Examples 1 and 2. The evaluation was carried out visually by 20 testers. It is obvious that it is natural and natural for 3 points, and it is natural and natural for 2 points, a little natural and natural for 1 point, and no natural and natural feeling for 0 points. When 20 people have an average score of more than 2 "A" when the score (has a high natural feeling), "B" when it is 1 to 2 points (a comparatively high natural feeling), and "C" when it is less than 1 point (has a low natural feeling) .

<評價(3):關於外觀(嗜好性)之官能評價> <Evaluation (3): Functional evaluation on appearance (hobby)>

關於「嗜好性」之官能評價,係將具備實施例1至8及比較例1、2之接裝紙的附濾嘴之香煙與評價(1)及(2)之官能評價同樣地置於舖有白紙之桌上,由20名測試員以目視實施評價。令人明顯想吸煙時為3分,令人稍微想吸煙時為2分,令人少許想吸煙時為1分,令人完全不想吸煙時為0分,當20名之平均分數大於2分(具有高嗜好性)時為「A」,1至2分(具有比較性上為較高之嗜好性)時為「B」,未達1分(具有低嗜好性)時為「C」。 The sensory evaluation of the "favorability" was carried out in the same manner as the sensory evaluations of the evaluations (1) and (2) of the cigarettes provided with the tipping sheets of Examples 1 to 8 and Comparative Examples 1 and 2. On the table with white paper, evaluation was performed visually by 20 testers. It is obvious that when you want to smoke, you will get 3 points. If you want to smoke a little, you will get 2 points. If you want to smoke a little, you will get 1 point. If you don't want to smoke, you will get 0 points. When you have 20 points, the average score is more than 2 points. When there is a high preference, it is "A", and when it is 1 to 2 points (higher preference), it is "B", and when it is less than 1 point (having low preference), it is "C".

<評價(4):關於風味之官能評價> <Evaluation (4): Functional evaluation about flavor>

關於「風味」之官能評價,係由5名測試員實際將具 備實施例1至8及比較例1、2之接裝紙的附濾嘴之香煙進行吸煙而實施。以具備比較例1之接裝紙的附濾嘴之香煙為基準,相較於比較例1而為風味無差別時為0分,相較於比較例1而為風味微差時為1分,相較於比較例1而為風味稍差時為2分,相較於比較例1而為風味明顯較差時為3分,5名之平均分數未達1分(與比較例1之風味差異少)時為「A」,1至2分(與比較例1之風味稍微有差異)時為「B」,大於2分(與比較例1之風味差異大)時為「C」。 The functional evaluation of "flavor" was actually carried out by 5 testers. The filter-attached cigarettes of the tipping sheets of Examples 1 to 8 and Comparative Examples 1 and 2 were subjected to smoking. The cigarette with the filter having the tipping paper of Comparative Example 1 was 0 in comparison with Comparative Example 1 when the flavor was not different, and was 1 minute when the flavor was inferior to Comparative Example 1. Compared with Comparative Example 1, it was 2 points when the flavor was slightly inferior, 3 points when the flavor was significantly worse than Comparative Example 1, and the average score of 5 was less than 1 point (the difference from the flavor of Comparative Example 1 was small). When it is "A", it is "B" when it is 1 to 2 points (slightly different from the flavor of Comparative Example 1), and is "C" when it is more than 2 points (large difference in flavor from Comparative Example 1).

前述評價結果係示於下述表1。 The above evaluation results are shown in Table 1 below.

由前述表1之評價(1)之結果可知,實施例1至8之接裝紙係含有1重量%以上之具有「1mm至4mm之長度、20μm至70μm之粗度的纖維」之未漂白紙漿,具備該「實施例1至8之接裝紙」的附濾嘴之香煙係可一眼目視確認到未漂白紙漿之纖維。 From the results of the evaluation (1) of the above Table 1, it is understood that the tipping papers of Examples 1 to 8 contain 1% by weight or more of unbleached pulp having "fibers having a length of 1 mm to 4 mm and a thickness of 20 μm to 70 μm". The filter-attached cigarette having the "the tipping paper of the first to eighth embodiments" can visually recognize the fibers of the unbleached pulp at a glance.

由表1之評價(2)之結果可知,實施例1至8之接裝紙係含有具有「1mm至4mm之長度、20μm至70μm之粗度的纖維」之未漂白紙漿,相較於具備「不含有未漂白紙漿之比較例1、2之接裝紙」的附濾嘴之香煙,具備「實施例1至8之接裝紙」的附濾嘴之香煙係可使測試員(例如吸煙者)感到天然、自然。 From the results of the evaluation (2) of Table 1, it is understood that the tipping papers of Examples 1 to 8 contain unbleached pulp having "fibers having a length of 1 mm to 4 mm and a thickness of 20 μm to 70 μm", as compared with having " A cigarette with a filter attached to the tipping paper of Comparative Examples 1 and 2 which does not contain unbleached pulp, and a cigarette with a filter attached to "the tipping paper of Examples 1 to 8" can be used by a tester (for example, a smoker) I feel natural and natural.

由表1之評價(3)之結果可知,具備「含有86重量%之未漂白紙漿的實施例5、8之接裝紙」的附濾嘴之香煙係具有比較性上為較高之嗜好性,具備「實施例1至4、6、7及比較例1、2之接裝紙」的附濾嘴之香煙係具有更高之嗜好性。此外,具備「含有超過86重量%之未漂白紙漿的接裝紙」的附濾嘴之香煙雖保有天然感,但因較濃之色調,故使測試員聯想到老舊感及廉價感,有降低嗜好性之虞。 As a result of the evaluation (3) of Table 1, it is understood that the filter-attached cigarette having "the tipping paper of Examples 5 and 8 containing 86% by weight of unbleached pulp" has a comparatively high preference. The filter-attached cigarettes having the "the tipping sheets of Examples 1 to 4, 6, and 7 and Comparative Examples 1 and 2" have higher preference. In addition, the filter-attached cigarette with "the tipping paper containing more than 86% by weight of unbleached pulp" has a natural feeling, but because of the thicker color, the tester thinks of the old feeling and the cheap feeling. Reduce the hobby of hobbies.

由表1之評價(4)之結果可知,相較於具備實施例3至5之接裝紙的附濾嘴之香煙,具備「在外周面被覆有清漆之接裝紙」之實施例6至8的附濾嘴之香煙係分別提高風味。 As a result of the evaluation (4) of Table 1, it is understood that the cigarettes with the filter having the tipping papers of Examples 3 to 5 are provided with the "attachment paper coated with the varnish on the outer peripheral surface" to the sixth embodiment. The cigarettes with a filter of 8 respectively enhance the flavor.

如上所述,具備「實施例1至8之接裝紙」的附濾嘴之香煙係在官能評價中具有天然感及嗜好性,此為具備「比較例1之白色接裝紙、比較例2之經施予軟木印刷之接裝紙」的附濾嘴之香煙所無法獲得者。 As described above, the filter-attached cigarettes having the "the tipping sheets of the first to eighth embodiments" have a natural feeling and a preference for the sensory evaluation. This is the "white tipping paper of Comparative Example 1, Comparative Example 2". A cigarette with a filter attached to a tipping paper for cork printing is not available.

上述實施形態中,雖然是以附濾嘴之香煙作為附濾嘴之吸煙物品之一例來進行說明,但不限於此, 附濾嘴之吸煙物品可為連接有濾嘴之其他吸煙物品,例如雪茄、小雪茄、利用電加熱/化學反應熱之非燃燒型吸煙物品、非加熱型吸煙物品等。 In the above embodiment, the cigarette with a filter is used as an example of a smoking article with a filter, but the invention is not limited thereto. The smoking article with the filter may be other smoking articles connected with a filter, such as cigars, small cigars, non-combustible smoking articles using electric heating/chemical reaction heat, non-heating smoking articles, and the like.

此外,雖說明了數個實施形態,但該等實施形態僅為例示而非限定發明範圍者。該等實施形態可以其他各種形態來實施,在不超出發明主旨之範圍內可進行各種變更。該等實施形態及其變形係包括於發明之範圍或主旨,且包括於申請專利範圍所記載之發明及其均等範圍。 In addition, although several embodiments are described, these embodiments are merely illustrative and not limiting. The embodiments can be implemented in various other forms, and various modifications can be made without departing from the spirit and scope of the invention. The invention and its modifications are intended to be included within the scope and spirit of the invention and are intended to

Claims (7)

一種附濾嘴之吸煙物品,係具備:霧氣生成棒;濾嘴,係配置於前述霧氣生成棒之下游端;以及接裝紙,係捲在前述霧氣生成棒之下游端部及前述濾嘴之外周面,而連接前述霧氣生成棒及前述濾嘴;其中,前述接裝紙係含有漂白紙漿及未漂白紙漿的紙,前述未漂白紙漿之纖維具有1mm至4mm之長度、20μm至70μm之粗度。 A smoking article with a filter includes: a mist generating rod; a filter disposed at a downstream end of the mist generating rod; and a tipping paper wound at a downstream end of the mist generating rod and the filter The outer peripheral surface is connected to the mist generating rod and the filter; wherein the tipping paper is a paper containing bleached pulp and unbleached pulp, and the fibers of the unbleached pulp have a length of 1 mm to 4 mm and a thickness of 20 μm to 70 μm. . 如申請專利範圍第1項所述之附濾嘴之吸煙物品,其中,前述接裝紙係在CIELab表色系中的明度L*為78至93、色度a*為0.6至2.8、色度b*為7至18。 The smoking article with a filter according to claim 1, wherein the tipping paper has a brightness L* of 78 to 93 and a chromaticity a* of 0.6 to 2.8 in the CIELab color system. b* is 7 to 18. 如申請專利範圍第1或2項所述之附濾嘴之吸煙物品,其中,前述漂白紙漿為木材紙漿,前述未漂白紙漿為木材紙漿或非木材紙漿。 The smoking article with a filter according to claim 1 or 2, wherein the bleached pulp is wood pulp, and the unbleached pulp is wood pulp or non-wood pulp. 如申請專利範圍第1或2項所述之附濾嘴之吸煙物品,其中,前述漂白紙漿及前述未漂白紙漿為木材紙漿。 The smoking article with a filter according to claim 1 or 2, wherein the bleached pulp and the unbleached pulp are wood pulp. 如申請專利範圍第1至4項中任一項所述之附濾嘴之吸煙物品,其中,前述接裝紙係更含有屬於填料之碳酸鈣或氧化鈦,且為不透明度76%以上之紙。 The smoking article with a filter according to any one of claims 1 to 4, wherein the tipping paper further contains calcium carbonate or titanium oxide belonging to a filler, and is a paper having an opacity of 76% or more. . 如申請專利範圍第1至5項中任一項所述之附濾嘴之吸煙物品,其中,前述接裝紙係在外周側存在有清漆。 The smoking article with a filter according to any one of claims 1 to 5, wherein the tipping paper has a varnish on the outer peripheral side. 如申請專利範圍第1至6項中任一項所述之附濾嘴之吸 煙物品,其中,前述接裝紙具有26.0N/15mm以上之拉伸強度。 The suction of the filter as described in any one of claims 1 to 6 The smoking article, wherein the tipping paper has a tensile strength of 26.0 N/15 mm or more.
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RU2765149C2 (en) * 2020-01-03 2022-01-26 Кейтиэндджи Корпорейшн Smoking material wrapper containing grain husks, smoking article containing such wrapper, and method for manufacturing a smoking article

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ES463499A1 (en) * 1977-10-25 1978-08-01 Glatz Julius Gmbh Mouthpiece paper for cigar
JP2003328299A (en) * 2002-04-30 2003-11-19 Oji Paper Co Ltd Liner of corrugated cardboard for exterior
JP2005171411A (en) * 2003-12-10 2005-06-30 Seiko Pmc Corp Filler-containing paper, and method for producing filler-containing paper
JP5912033B2 (en) * 2011-11-22 2016-04-27 大王製紙株式会社 Paper towel manufacturing method
JP6755942B2 (en) * 2016-04-28 2020-09-16 日本たばこ産業株式会社 Cigarette with filter

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RU2765149C2 (en) * 2020-01-03 2022-01-26 Кейтиэндджи Корпорейшн Smoking material wrapper containing grain husks, smoking article containing such wrapper, and method for manufacturing a smoking article

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