TW201915594A - Semiconductor wafer processing method, semiconductor wafer processing system and method for cleaning semiconductor wafer processing system - Google Patents

Semiconductor wafer processing method, semiconductor wafer processing system and method for cleaning semiconductor wafer processing system Download PDF

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TW201915594A
TW201915594A TW106132232A TW106132232A TW201915594A TW 201915594 A TW201915594 A TW 201915594A TW 106132232 A TW106132232 A TW 106132232A TW 106132232 A TW106132232 A TW 106132232A TW 201915594 A TW201915594 A TW 201915594A
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cleaning device
electrostatic
semiconductor wafer
photomask
reticle
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TW106132232A
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Chinese (zh)
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TWI644164B (en
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李宗彥
盧玟銨
郭爵旗
許哲彰
周佳信
傅中其
陳立銳
鄭博中
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台灣積體電路製造股份有限公司
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Abstract

A semiconductor wafer processing method, a semiconductor wafer processing system and a method for cleaning a semiconductor wafer processing system are provided. The method for cleaning a semiconductor processing system includes placing a cleaning device over an electrostatic chuck for masks in a vacuum chamber. A polymer layer of the cleaning device is absorbed to the electrostatic chuck for masks. When the cleaning device has been absorbed to the electrostatic chuck for masks for a first time period, and the cleaning device is separated from the electrostatic chuck for masks.

Description

半導體晶圓加工方法、系統及系統之清潔方法  Semiconductor wafer processing method, system and system cleaning method  

本發明實施例是有關於一種半導體晶圓加工系統之清潔方法,特別是有關於光罩靜電座的清潔方法。 Embodiments of the present invention relate to a method of cleaning a semiconductor wafer processing system, and more particularly to a method of cleaning a photomask electrostatic mount.

半導體積體電路(IC)產業已快速成長一段時日。IC材料與設計的技術進步,使每一代的IC比前一代的IC更小且其電路更複雜。新一代的IC具有較大的功能密度(比如固定晶片面積中的內連線元件數目),與較小的尺寸(比如製程形成的最小構件或連線)。製程尺寸縮小往往有利於增加製程效率並降低相關成本。製程尺寸縮小會增加製程複雜度,但製程尺寸縮小的優點顯而易見,因此需要更小的IC製程。舉例來說,對高解析度微影製程的需求持續成長。 The semiconductor integrated circuit (IC) industry has grown rapidly for some time. Technological advances in IC materials and design have made each generation of ICs smaller and more complex than previous generation ICs. A new generation of ICs has a large functional density (such as the number of interconnect components in a fixed wafer area), and a smaller size (such as the smallest component or wiring formed by the process). Process size reduction is often beneficial to increase process efficiency and reduce associated costs. The reduced size of the process increases the complexity of the process, but the advantages of shrinking the process size are obvious, so a smaller IC process is required. For example, the demand for high-resolution lithography processes continues to grow.

微影技術之一為極紫外光(EUV)微影技術。極紫外光微影技術利用極紫外光曝光光罩,以於基板上形成圖案。一般而言,極紫外光微影技術所用之光罩稱作極紫外光(EUV)光罩,而極紫外光微影技術所用的光波長介於約1nm至約100nm之間。 One of the lithography technologies is extreme ultraviolet (EUV) lithography. Extreme ultraviolet lithography exposes the reticle with extreme ultraviolet light to form a pattern on the substrate. In general, the reticle used in extreme ultraviolet lithography is called an extreme ultraviolet (EUV) reticle, and the extreme ultraviolet lithography technique uses a wavelength of light between about 1 nm and about 100 nm.

現有的微影技術通常適用於特定目的,而無法用 於所有領域。舉例來說,重複使用極紫外光微影製程中的極紫外光光罩將產生一些問題。 Existing lithography techniques are generally suitable for a specific purpose and cannot be used in all areas. For example, repeated use of an extreme ultraviolet reticle in an extreme ultraviolet lithography process would create problems.

本發明實施例提供一種半導體晶圓加工系統之清潔方法。上述半導體晶圓加工系統之清潔方法包括在一真空腔室中,將一清潔裝置放置於一光罩靜電座上方。上述半導體晶圓加工系統之清潔方法還包括將上述清潔裝置之一聚合物材料層吸附於上述光罩靜電座。上述半導體晶圓加工系統之清潔方法更包括當上述清潔裝置吸附於上述光罩靜電座且經過一第一時間時,將上述清潔裝置與上述光罩靜電座分離。 Embodiments of the present invention provide a method of cleaning a semiconductor wafer processing system. The cleaning method of the above semiconductor wafer processing system includes placing a cleaning device over a photomask electrostatic mount in a vacuum chamber. The method of cleaning a semiconductor wafer processing system further includes adsorbing a layer of a polymer material of the cleaning device to the photomask electrostatic pad. The cleaning method of the semiconductor wafer processing system further includes separating the cleaning device from the photomask electrostatic pad when the cleaning device is adsorbed to the photomask electrostatic pad and passes a first time.

本發明實施例提供一種半導體晶圓加工方法。上述半導體晶圓加工方法包括在一真空腔室中,將一清潔裝置放置於一光罩靜電座上方。上述半導體晶圓加工方法還包括透過上述光罩靜電座將上述清潔裝置之一聚合物材料層吸附於上述光罩靜電座。上述半導體晶圓加工方法更包括當上述清潔裝置吸附於上述光罩靜電座後,將一半導體晶圓放置於一晶圓座上方。上述半導體晶圓加工方法又包括對上述半導體晶圓進行一第一半導體製程。上述半導體晶圓加工方法再包括進行上述第一半導體製程之後,將上述清潔裝置與上述光罩靜電座分離,且將上述半導體晶圓與上述晶圓座分離。 Embodiments of the present invention provide a semiconductor wafer processing method. The semiconductor wafer processing method includes placing a cleaning device over a photomask electrostatic mount in a vacuum chamber. The semiconductor wafer processing method further includes adsorbing a polymer material layer of one of the cleaning devices to the photomask electrostatic pad through the photomask electrostatic pad. The semiconductor wafer processing method further includes placing a semiconductor wafer over a wafer holder after the cleaning device is adsorbed to the photomask electrostatic pad. The semiconductor wafer processing method further includes performing a first semiconductor process on the semiconductor wafer. The semiconductor wafer processing method further includes separating the cleaning device from the photomask electrostatic pad and separating the semiconductor wafer from the wafer holder after performing the first semiconductor process.

本發明實施例提供一種半導體晶圓加工系統。上述半導體晶圓加工系統包括一真空腔室、一第一清潔裝置、一光罩靜電座、一傳送裝置和一控制器。上述第一清潔裝置設置於上述真空腔室內。上述第一清潔裝置包括一第一基板、一反 射結構、一保護層、一吸收層、一導電層和一第一聚合物材料層。上述第一基板的材質包括一低熱膨脹材料。上述反射結構設置於上述基板的一前側表面上方。上述保護層設置於上述反射結構上方。上述吸收層設置於上述保護層上方。上述導電層設置於上述基板的一後側表面上方。上述第一聚合物材料層,設置於上述導電層上方。上述光罩靜電座設置於上述真空腔室內。上述傳送裝置設置於上述真空腔室內以選擇性地將上述第一清潔裝置放置於上述光罩靜電座上方。上述控制器設置於上述真空腔室內以控制上述光罩靜電座與上述傳送裝置。上述光罩靜電座透過靜電吸附上述第一清潔裝置。 Embodiments of the present invention provide a semiconductor wafer processing system. The semiconductor wafer processing system includes a vacuum chamber, a first cleaning device, a photomask electrostatic mount, a transfer device, and a controller. The first cleaning device is disposed in the vacuum chamber. The first cleaning device comprises a first substrate, a reflective structure, a protective layer, an absorbing layer, a conductive layer and a first layer of polymeric material. The material of the first substrate comprises a low thermal expansion material. The reflective structure is disposed above a front side surface of the substrate. The protective layer is disposed above the reflective structure. The absorbing layer is disposed above the protective layer. The conductive layer is disposed above a rear side surface of the substrate. The first polymer material layer is disposed above the conductive layer. The photomask electrostatic mount is disposed in the vacuum chamber. The transfer device is disposed in the vacuum chamber to selectively place the first cleaning device above the photomask electrostatic seat. The controller is disposed in the vacuum chamber to control the reticle electrostatic mount and the transfer device. The photomask electrostatic seat is electrostatically attracted to the first cleaning device.

200A、200B、200C‧‧‧基板 200A, 200B, 200C‧‧‧ substrates

201‧‧‧前側表面 201‧‧‧ front side surface

202‧‧‧矽層 202‧‧‧矽

203‧‧‧後側表面 203‧‧‧Back surface

204‧‧‧鉬層 204‧‧‧ molybdenum layer

206‧‧‧反射結構 206‧‧‧Reflective structure

210‧‧‧保護層 210‧‧‧Protective layer

211‧‧‧不透明區 211‧‧‧Opacity zone

212‧‧‧氮化硼鉭層 212‧‧‧ boron nitride layer

213‧‧‧反射區 213‧‧‧Reflective zone

214‧‧‧氧化硼鉭層 214‧‧‧Boronium oxide layer

216‧‧‧吸收層 216‧‧‧absorbing layer

218‧‧‧導電層 218‧‧‧ Conductive layer

220‧‧‧聚合物材料層 220‧‧‧ polymer material layer

226A、226B‧‧‧圖案層 226A, 226B‧‧‧ pattern layer

228A、228B‧‧‧保護層 228A, 228B‧‧ ‧ protective layer

230、230A、230B‧‧‧光罩部分 230, 230A, 230B‧‧‧ mask parts

302‧‧‧真空腔室 302‧‧‧vacuum chamber

304‧‧‧射線源 304‧‧‧ray source

306‧‧‧光罩靜電座 306‧‧‧Photomask electrostatic seat

307‧‧‧吸附面 307‧‧‧Adsorption surface

308‧‧‧電極 308‧‧‧electrode

309‧‧‧污染物 309‧‧‧Contaminants

310‧‧‧傳送裝置 310‧‧‧Transport device

312‧‧‧控制器 312‧‧‧ Controller

314‧‧‧晶圓座 314‧‧‧ Wafer Block

316‧‧‧檢測裝置 316‧‧‧Detection device

320‧‧‧半導體晶圓 320‧‧‧Semiconductor wafer

322‧‧‧真空幫浦 322‧‧‧vacuum pump

500、500A、500B‧‧‧清潔裝置 500, 500A, 500B‧‧‧ cleaning devices

502、504、506、508、510、602、604、606、608、610、612、614、616、618、620、622‧‧‧操作 502, 504, 506, 508, 510, 602, 604, 606, 608, 610, 612, 614, 616, 618, 620, 622‧‧‧ operations

550‧‧‧半導體晶圓加工系統之清潔方法 550‧‧‧Methods for cleaning semiconductor wafer processing systems

600‧‧‧半導體晶圓加工系統 600‧‧‧Semiconductor Wafer Processing System

650‧‧‧半導體晶圓加工方法 650‧‧‧Semiconductor wafer processing method

700‧‧‧反射光罩 700‧‧‧Reflective mask

L‧‧‧極紫外光光線 L‧‧‧ Extreme ultraviolet light

TN‧‧‧時間 T N ‧‧‧Time

T‧‧‧間隔時間 T‧‧‧ interval

第1A、1B圖為依據一些實施例之半導體晶圓加工系統之清潔裝置的示意圖。 1A, 1B are schematic illustrations of a cleaning apparatus for a semiconductor wafer processing system in accordance with some embodiments.

第2圖為依據一些實施例之半導體晶圓加工系統的方塊圖。 2 is a block diagram of a semiconductor wafer processing system in accordance with some embodiments.

第3A圖為依據一些實施例之半導體晶圓加工系統之光罩靜電座的俯視示意圖。 3A is a top plan view of a photomask electrostatic mount of a semiconductor wafer processing system in accordance with some embodiments.

第3B圖為沿第3A圖的A-A’切線的剖面圖,其顯示依據一些實施例之半導體晶圓加工系統之光罩靜電座的剖面示意圖。 3B is a cross-sectional view taken along line A-A' of FIG. 3A, showing a cross-sectional view of a photomask electrostatic mount of a semiconductor wafer processing system in accordance with some embodiments.

第4圖為依據一些實施例之半導體晶圓加工系統之反射光罩的示意圖。 4 is a schematic illustration of a reflective reticle of a semiconductor wafer processing system in accordance with some embodiments.

第5圖為一些實施例之半導體晶圓加工系統的清潔方法的流程圖。 Figure 5 is a flow diagram of a method of cleaning a semiconductor wafer processing system of some embodiments.

第6A、6B圖為一些實施例之半導體晶圓加工方法的流程圖。 6A, 6B are flow diagrams of semiconductor wafer processing methods of some embodiments.

第7A、7B、7C、7D、7E圖顯示相應於第5圖所示之一些實施例之半導體晶圓加工系統之清潔方法和第6A、6B圖所示之一些實施例之半導體晶圓加工方法的不同操作階段的半導體晶圓加工系統的方塊示意圖。 7A, 7B, 7C, 7D, and 7E show a semiconductor wafer processing system cleaning method corresponding to some embodiments shown in FIG. 5 and a semiconductor wafer processing method according to some embodiments shown in FIGS. 6A and 6B. A block diagram of a semiconductor wafer processing system at different stages of operation.

第8A、8B、8C圖為依據一些實施例之半導體晶圓加工系統之清潔裝置與光罩靜電座在半導體晶圓加工系統之清潔方法和半導體晶圓加工方法的不同操作階段的示意圖。 8A, 8B, and 8C are schematic diagrams showing different stages of operation of the cleaning apparatus and the reticle electrostatic mount of the semiconductor wafer processing system in the semiconductor wafer processing system and the semiconductor wafer processing method according to some embodiments.

以下的揭露內容提供許多不同的實施例或範例,以實施本案的不同特徵。而本揭露書以下的揭露內容是敘述各個構件及其排列方式的特定範例,以求簡化說明。當然,這些特定的範例並非用以限定。例如,若是本揭露書以下的內容敘述了將一第一特徵形成於一第二特徵之上或上方,即表示其包括了所形成的上述第一特徵與上述第二特徵是直接接觸的實施例,亦包括了尚可將附加的特徵形成於上述第一特徵與上述第二特徵之間,而使上述第一特徵與上述第二特徵可能未直接接觸的實施例。另外,本揭露書中不同範例可能使用重複的參考符號及/或標記。這些重複係為了簡化與清晰的目的,並非用以限定各個實施例及/或所述外觀結構之間的關係。 The following disclosure provides many different embodiments or examples to implement various features of the present invention. The disclosure of the disclosure below is a specific example of the various components and their arrangement in order to simplify the description. Of course, these specific examples are not intended to be limiting. For example, if the following description of the present disclosure describes forming a first feature on or above a second feature, that is, it includes an embodiment in which the formed first feature is in direct contact with the second feature. Also included is an embodiment in which additional features may be formed between the first feature and the second feature described above, such that the first feature may not be in direct contact with the second feature. In addition, different examples in the disclosure may use repeated reference symbols and/or indicia. These repetitions are not intended to limit the relationship between the various embodiments and/or the appearance structures for the purpose of simplicity and clarity.

再者,為了方便描述圖式中一元件或特徵部件與另一(複數)元件或(複數)特徵部件的關係,可使用空間相關用語,例如“在...之下”、“下方”、“較下部”、“上方”、“較上部” 及類似的用語等。除了圖式所繪示的方位之外,空間相關用語用以涵蓋使用或操作中的裝置的不同方位。所述裝置也可被另外定位(例如,旋轉90度或者位於其他方位),並對應地解讀所使用的空間相關用語的描述。 Furthermore, for convenience of describing the relationship of one element or feature in the drawings to another (plural) element or (complex) feature, space-related terms such as "below", "below", "Lower", "above", "upper" and similar terms. Spatially relative terms are used to encompass different orientations of the device in use or operation, in addition to the orientation depicted in the drawings. The device may also be additionally positioned (eg, rotated 90 degrees or at other orientations) and the description of the spatially relevant terms used may be interpreted accordingly.

在下文中使用的第一以及第二等詞彙,僅作為清楚解釋之目的,並非用以對應以及限制專利範圍。此外,第一特徵以及第二特徵等詞彙,並非限定為相同或是不同的特徵。 The vocabulary of the first and second terms used hereinafter is for illustrative purposes only and is not intended to limit or limit the scope of the patent. In addition, the first feature and the second feature are not limited to the same or different features.

在圖式中,結構的形狀或厚度可能擴大,以簡化或便於標示。必須了解的是,未特別描述或圖示之元件可以本領域技術人士所熟知之各種形式存在。 In the drawings, the shape or thickness of the structure may be enlarged to simplify or facilitate the marking. It is to be understood that elements not specifically described or illustrated may be in various forms well known to those skilled in the art.

以下敘述了本揭露書的一些實施例。第1A圖為依據一些實施例之半導體晶圓加工系統之清潔裝置500A的示意圖。在一些實施例中,清潔裝置500A用以吸附於極紫外光(EUV)微影系統的光罩靜電座上以清潔光罩靜電座。在第1A圖所示的一些實施例中,清潔裝置500A包括基板200A、反射結構206、保護層210、吸收層216、導電層218和聚合物材料層220。 Some embodiments of the present disclosure are described below. FIG. 1A is a schematic illustration of a cleaning apparatus 500A of a semiconductor wafer processing system in accordance with some embodiments. In some embodiments, the cleaning device 500A is configured to be attached to a reticle electrostatic mount of an extreme ultraviolet (EUV) lithography system to clean the reticle electrostatic mount. In some embodiments shown in FIG. 1A, cleaning device 500A includes a substrate 200A, a reflective structure 206, a protective layer 210, an absorber layer 216, a conductive layer 218, and a layer of polymeric material 220.

如第1A圖所示,在一些實施例中,清潔裝置500A的基板200A具有一前側表面201和相對於上述前側表面201的一後側表面203。基板200A的材質可包括一低熱膨脹材料(low thermal expansion metal(LTEM))。上述低熱膨脹材料可包含掺雜氧化鈦(TiO2)之氧化矽(SiO2),及/或其他低熱膨脹材料。由低熱膨脹材料形成的基板200A可使加熱光罩所造成的影像扭曲問題最小化。在一些實施例中,在一些實施例中包含的材料具有低缺陷等級與平滑表面。 As shown in FIG. 1A, in some embodiments, the substrate 200A of the cleaning device 500A has a front side surface 201 and a rear side surface 203 with respect to the front side surface 201 described above. The material of the substrate 200A may include a low thermal expansion metal (LTEM). The aforementioned low thermal expansion material may comprise doped titanium oxide (TiO 2) of silicon oxide (SiO 2), and / or other low thermal expansion material. The substrate 200A formed of a low thermal expansion material minimizes image distortion problems caused by the heating mask. In some embodiments, the materials included in some embodiments have a low defect level and a smooth surface.

如第1A圖所示,清潔裝置500A的反射結構206設置於基板200A的前側表面201上方。在一些實施例中,反射結構206為多層結構(multi-layer structure)。依據Fresnel方程式,當光穿過不同折射率之兩種材料的界面時,會產生光反射的現象。當折射率差異越大,反射光越大。在一些實施例中,為了增加反射光強度,可增加交替的材料之多層界面數目,使光建設性干涉於每一不同界面處。在一些實施例中,反射結構206包括多個膜對,例如矽層202和鉬層204構成的鉬/矽(Mo/Si)膜對,即每一膜對中的鉬層204位於矽層202之上或之下。在一些實施例中,反射結構206包括鉬/鈹(Mo/Be)膜對,或對極紫外光(EUV)波長具有高反射率的任何合適材料。反射結構206的每一層厚度取決於EUV之波長及入射角。調整反射結構206的厚度(或膜對的厚度),可使每一界面反射之EUV光線具有最大的建設性干涉,且使反射結構206對EUV光具有最小吸收。反射結構206可選自對選定射線種類及/或波長具有高反射率。在一些實施例中,反射結構206中的膜對數目介於20至80之間,不過任何數目的膜對均有可能。在一些實施例中,反射結構206包含四十對的鉬層204/矽層202。 As shown in FIG. 1A, the reflective structure 206 of the cleaning device 500A is disposed above the front side surface 201 of the substrate 200A. In some embodiments, the reflective structure 206 is a multi-layer structure. According to the Fresnel equation, when light passes through the interface of two materials of different refractive indices, light reflection occurs. The greater the difference in refractive index, the larger the reflected light. In some embodiments, to increase the intensity of the reflected light, the number of multi-layer interfaces of alternating materials may be increased to allow light constructive interference at each of the different interfaces. In some embodiments, the reflective structure 206 includes a plurality of pairs of films, such as a molybdenum/germanium (Mo/Si) film pair composed of a tantalum layer 202 and a molybdenum layer 204, ie, the molybdenum layer 204 in each film pair is located in the tantalum layer 202. Above or below. In some embodiments, reflective structure 206 comprises a molybdenum/niobium (Mo/Be) film pair, or any suitable material having a high reflectivity for extreme ultraviolet (EUV) wavelengths. The thickness of each layer of reflective structure 206 depends on the wavelength of the EUV and the angle of incidence. Adjusting the thickness of the reflective structure 206 (or the thickness of the film pair) allows for maximum constructive interference of the EUV rays reflected by each interface and allows the reflective structure 206 to have minimal absorption of EUV light. Reflective structure 206 can be selected to have a high reflectivity for a selected ray species and/or wavelength. In some embodiments, the number of pairs of films in reflective structure 206 is between 20 and 80, although any number of film pairs are possible. In some embodiments, reflective structure 206 comprises forty pairs of molybdenum layer 204/germanium layer 202.

如第1A圖所示,清潔裝置500A的保護層210設置於反射結構206上方。在一些實施例中,設置於反射結構206上方的保護層210用以防止反射結構206氧化。在一些實施例中,保護層210可包括單一膜或多層膜以具有額外功能。在一些實施例中,保護層包括位於反射結構206上的蓋層(圖未顯示),以及位於蓋層上的緩衝層(圖未顯示)。蓋層可用以防止反射結構206 氧化。在一些實施例中,蓋層的材質包括矽,且其厚度約為4nm至7nm。在一些實施例中,可採用低溫沉積製程形成蓋層,以避免反射結構206之相互擴散。緩衝層係形成於蓋層上,以作為吸收層216之圖案化或修補製程中的蝕刻停止層。緩衝層與吸收層216具有不同的蝕刻特性。在一些實施例中,緩衝層的材質包括釕(Ru)、釕化合物如硼化釕(RuB)或釕矽(RuSi)、鉻(Cr)、氧化鉻(CrO)、或氮化鉻(CrN)。在一些實施例中,可採用低溫沉積製程形成緩衝層,以避免反射結構206的相互擴散。 As shown in FIG. 1A, the protective layer 210 of the cleaning device 500A is disposed above the reflective structure 206. In some embodiments, the protective layer 210 disposed over the reflective structure 206 serves to prevent oxidation of the reflective structure 206. In some embodiments, the protective layer 210 can include a single film or a multilayer film to have additional functionality. In some embodiments, the protective layer includes a cap layer (not shown) on the reflective structure 206, and a buffer layer (not shown) on the cap layer. A cap layer can be used to prevent oxidation of the reflective structure 206. In some embodiments, the material of the cap layer comprises tantalum and has a thickness of about 4 nm to 7 nm. In some embodiments, a cap layer may be formed using a low temperature deposition process to avoid interdiffusion of the reflective structures 206. A buffer layer is formed over the cap layer as an etch stop layer in the patterning or repair process of the absorber layer 216. The buffer layer and the absorber layer 216 have different etching characteristics. In some embodiments, the material of the buffer layer comprises ruthenium (Ru), a ruthenium compound such as ruthenium boride (RuB) or ruthenium (RuSi), chromium (Cr), chromium oxide (CrO), or chromium nitride (CrN). . In some embodiments, a buffer layer can be formed using a low temperature deposition process to avoid interdiffusion of the reflective structures 206.

如第1A圖所示,清潔裝置500A的吸收層216設置於保護層210上方。在一些實施例中,設置於反射結構206上方的吸收層216吸收照射至清潔裝置500A的基板200A的前側表面201上方的EUV波長範圍中的射線。吸收層216可包括多層膜層,且每一膜層的材質可包括鉻、氧化鉻、氮化鉻、鈦、氧化鈦、氮化鈦、鉭、氧化鉭、氮化鉭、氮氧化鉭、氮化硼鉭、氧化硼鉭、氮氧化硼鉭、鋁、鋁-銅、氧化鋁、銀、氧化銀、鈀、釕、鉬、其他合適材料或上述之組合。在如第1A圖所示的一些實施例中,吸收層216包括位於保護層210上方的氮化硼鉭(TaBN)層212和位於氮化硼鉭(TaBN)層212上方的氧化硼鉭(TaBO)層214。在一些實施例中,氮化硼鉭(TaBN)層212的厚度約為50nm至80nm,例如約為68nm。在一些實施例中,氧化硼鉭(TaBO)層214的厚度約為1nm至10nm,例如約為2nm。 As shown in FIG. 1A, the absorbing layer 216 of the cleaning device 500A is disposed above the protective layer 210. In some embodiments, the absorbing layer 216 disposed over the reflective structure 206 absorbs radiation in the EUV wavelength range that is illuminated above the front side surface 201 of the substrate 200A of the cleaning device 500A. The absorbing layer 216 may include a plurality of film layers, and the material of each film layer may include chromium, chromium oxide, chromium nitride, titanium, titanium oxide, titanium nitride, tantalum, hafnium oxide, tantalum nitride, niobium oxynitride, nitrogen. Boron bismuth, boron oxynitride, boron oxynitride, aluminum, aluminum-copper, aluminum oxide, silver, silver oxide, palladium, rhodium, molybdenum, other suitable materials or combinations thereof. In some embodiments as shown in FIG. 1A, the absorber layer 216 includes a boron nitride tantalum (TaBN) layer 212 over the protective layer 210 and a boron oxide tantalum (TaBO) over the boron nitride tantalum (TaBN) layer 212. ) Layer 214. In some embodiments, the boron nitride (TaBN) layer 212 has a thickness of between about 50 nm and 80 nm, such as about 68 nm. In some embodiments, the boron oxide lanthanum (TaBO) layer 214 has a thickness of between about 1 nm and 10 nm, such as about 2 nm.

在如第1A圖所示的一些實施例中,可依積體電路(IC)佈局圖案(或單純的IC圖案)圖案化吸收層216,以定義不透明區211與反射區213。在清潔裝置500A的不透明區211中保留 吸收層216,並在清潔裝置500A的反射區213中移除吸收層216。 In some embodiments as shown in FIG. 1A, the absorber layer 216 may be patterned in accordance with an integrated circuit (IC) layout pattern (or a simple IC pattern) to define an opaque region 211 and a reflective region 213. The absorbent layer 216 is retained in the opaque zone 211 of the cleaning device 500A and the absorbent layer 216 is removed in the reflective zone 213 of the cleaning device 500A.

如第1A圖所示,為了靜電固定的目的,可於清潔裝置500A的基板200A的後側表面203上形成導電層218。在一些實施例中,導電層218的材質包括氮化鉻(CrN)或其他合適導電材料。在一些實施例中,導電層218的厚度約為50nm至100nm,例如約為70nm。 As shown in FIG. 1A, a conductive layer 218 can be formed on the rear side surface 203 of the substrate 200A of the cleaning device 500A for the purpose of electrostatic fixing. In some embodiments, the material of the conductive layer 218 includes chromium nitride (CrN) or other suitable conductive material. In some embodiments, the conductive layer 218 has a thickness of about 50 nm to 100 nm, such as about 70 nm.

如第1A圖所示,清潔裝置500A的聚合物材料層220設置於基板200A的後側表面203上方,且位於導電層218上方。可將清潔裝置500A的聚合物材料層220靜電吸附至例如EUV微影系統的光罩靜電座(electrostatic chuck(e-chuck)),利用聚合物材料層220本身的黏著力將位於光罩靜電座的污染物黏附於其上,且將清潔裝置500A與上述光罩靜電座分離時,可同時將上述污染物帶離上述光罩靜電座的表面,進而達成清潔光罩靜電座的效果。聚合物材料層220可由彈性聚合物所組成或具有受控表面黏性且不會轉移至光罩靜電座的聚合物所組成。在一些實施例中,聚合物材料層220的材質包括聚醯亞胺(polyimide)、聚乙烯醇(polyvinyl alcohol(PVA))或其他合適的材料。在一些實施例中,聚合物材料層220包括金屬化合物以增強與光罩靜電座之間的靜電吸附力。在一些實施例中,聚合物材料層220的厚度大於或等於一既定厚度。在一些實施例中,聚合物材料層220的厚度約為5μm至10μm,例如約為8μm。 As shown in FIG. 1A, the polymer material layer 220 of the cleaning device 500A is disposed above the rear side surface 203 of the substrate 200A and above the conductive layer 218. The polymer material layer 220 of the cleaning device 500A can be electrostatically adsorbed to, for example, an electrostatic chuck (e-chuck) of the EUV lithography system, and the adhesion of the polymer material layer 220 itself will be located at the radome electrostatic seat. The contaminant adheres to the contaminant, and when the cleaning device 500A is separated from the photomask electrostatic seat, the contaminant can be simultaneously removed from the surface of the photomask electrostatic seat, thereby achieving the effect of cleaning the photomask electrostatic seat. The layer of polymeric material 220 may be comprised of a polymer of elastomeric polymer or a polymer having controlled surface tack and which is not transferred to the electrostatic mount of the reticle. In some embodiments, the material of the polymer material layer 220 includes polyimide, polyvinyl alcohol (PVA), or other suitable materials. In some embodiments, the polymeric material layer 220 includes a metal compound to enhance electrostatic attraction between the photomask and the photomask. In some embodiments, the thickness of the polymeric material layer 220 is greater than or equal to a predetermined thickness. In some embodiments, the polymeric material layer 220 has a thickness of between about 5 [mu]m and 10 [mu]m, such as about 8 [mu]m.

在一些實施例中,清潔裝置500A的基板200A、反射結構206、保護層210、吸收層216和導電層218視為清潔裝置500A的一光罩部分230A。清潔裝置500A的光罩部分230A可做 為EUV微影系統的反射光罩(reflective mask)。 In some embodiments, substrate 200A, reflective structure 206, protective layer 210, absorber layer 216, and conductive layer 218 of cleaning device 500A are considered a reticle portion 230A of cleaning device 500A. The reticle portion 230A of the cleaning device 500A can serve as a reflective mask for the EUV lithography system.

第1B圖為依據一些實施例之半導體晶圓加工系統之清潔裝置500B的示意圖。在一些實施例中,清潔裝置500B用以吸附於EUV微影系統的光罩靜電座上以清潔光罩靜電座。在第1B圖所示的一些實施例中,清潔裝置500A包括基板200B、金屬層226A和226B、保護層228A和228B和聚合物材料層220。 FIG. 1B is a schematic illustration of a cleaning apparatus 500B of a semiconductor wafer processing system in accordance with some embodiments. In some embodiments, the cleaning device 500B is used to adsorb to the reticle electrostatic mount of the EUV lithography system to clean the reticle electrostatic mount. In some embodiments illustrated in FIG. 1B, cleaning device 500A includes substrate 200B, metal layers 226A and 226B, protective layers 228A and 228B, and polymer material layer 220.

如第1B圖所示,在一些實施例中,清潔裝置500B的基板200B具有一前側表面201和相對於上述前側表面201的一後側表面203。基板200B的材質可包括矽。在一些實施例中,基板200B例如為石英玻璃(quartz)或鈉鈣玻璃(soda-lime glass)。 As shown in FIG. 1B, in some embodiments, the substrate 200B of the cleaning device 500B has a front side surface 201 and a rear side surface 203 with respect to the front side surface 201 described above. The material of the substrate 200B may include germanium. In some embodiments, the substrate 200B is, for example, quartz or soda-lime glass.

如第1B圖所示,清潔裝置500B的金屬層226A和226B分別設置於基板200B的前側表面201上方和後側表面203上方。在一些實施例中,金屬層226A和226B的材質包括鉻、鋁或其他適合的金屬材料。可利用濺鍍、化學氣相沉積法(CVD)、物理氣相沉積法(PVD)、雷射沉積法及/或原子層沉積法(ALD)形成金屬層226A和226B。在一些實施例中,金屬層226A和226B具有相同的厚度。在一些實施例中,金屬層226A和226B的厚度約為40nm至70nm,例如約為55nm。 As shown in FIG. 1B, the metal layers 226A and 226B of the cleaning device 500B are disposed above the front side surface 201 and the rear side surface 203 of the substrate 200B, respectively. In some embodiments, the materials of metal layers 226A and 226B include chromium, aluminum, or other suitable metallic materials. Metal layers 226A and 226B may be formed by sputtering, chemical vapor deposition (CVD), physical vapor deposition (PVD), laser deposition, and/or atomic layer deposition (ALD). In some embodiments, metal layers 226A and 226B have the same thickness. In some embodiments, metal layers 226A and 226B have a thickness of between about 40 nm and 70 nm, such as about 55 nm.

如第1B圖所示,清潔裝置500B的保護層228A和228B分別設置於金屬層226A和226B上方。在一些實施例中,保護層228A和228B用以防止其下的金屬層226A和226B氧化。在一些實施例中,保護層228A和228B的材質包括氮化鉻、氧 化鉻、或氮氧化鉻。可利用濺鍍法、化學氣相沉積法(CVD)、物理氣相沉積法(PVD)、雷射沉積法及/或原子層沉積法(ALD)形成保護層228A和228B。在一些實施例中,保護層228A和228B具有相同的厚度。在一些實施例中,保護層228A和228B的厚度約為10nm至30nm,例如約為18nm。 As shown in FIG. 1B, protective layers 228A and 228B of cleaning device 500B are disposed over metal layers 226A and 226B, respectively. In some embodiments, the protective layers 228A and 228B serve to prevent oxidation of the underlying metal layers 226A and 226B. In some embodiments, the materials of the protective layers 228A and 228B include chromium nitride, chromium oxide, or chromium oxynitride. The protective layers 228A and 228B may be formed by sputtering, chemical vapor deposition (CVD), physical vapor deposition (PVD), laser deposition, and/or atomic layer deposition (ALD). In some embodiments, the protective layers 228A and 228B have the same thickness. In some embodiments, the protective layers 228A and 228B have a thickness of about 10 nm to 30 nm, such as about 18 nm.

如第1B圖所示,清潔裝置500B的聚合物材料層220設置於基板200B的後側表面203上方,且位於保護層228B上方。可將清潔裝置500B的聚合物材料層220靜電吸附至例如極紫外光微影系統(EUV photolithography system)的光罩靜電座(electrostatic chuck(e-chuck)),利用聚合物材料層220本身的黏著力將位於光罩靜電座的污染物黏附於其上,且將清潔裝置500B與上述光罩靜電座分離時,可同時將上述污染物帶離上述光罩靜電座的表面,進而達成清潔光罩靜電座的效果。聚合物材料層220可由彈性聚合物所組成或具有受控表面黏性且不會轉移至光罩靜電座的聚合物所組成。在一些實施例中,聚合物材料層220的材質包括聚醯亞胺(polyimide)、聚乙烯醇(polyvinyl alcohol(PVA))或其他合適的材料。在一些實施例中,聚合物材料層220的厚度大於或等於一既定厚度。在一些實施例中,聚合物材料層220的厚度約為5μm至10μm,例如約為8μm。 As shown in FIG. 1B, the polymer material layer 220 of the cleaning device 500B is disposed above the rear side surface 203 of the substrate 200B and above the protective layer 228B. The polymer material layer 220 of the cleaning device 500B can be electrostatically adsorbed to an electrostatic chuck (e-chuck) such as an EUV photolithography system, using the adhesion of the polymer material layer 220 itself. The force adheres the contaminant located in the electrostatic seat of the photomask, and when the cleaning device 500B is separated from the electrostatic seat of the photomask, the contaminant can be simultaneously removed from the surface of the electrostatic seat of the photomask, thereby achieving a cleaning mask. The effect of the electrostatic seat. The layer of polymeric material 220 may be comprised of a polymer of elastomeric polymer or a polymer having controlled surface tack and which is not transferred to the electrostatic mount of the reticle. In some embodiments, the material of the polymer material layer 220 includes polyimide, polyvinyl alcohol (PVA), or other suitable materials. In some embodiments, the thickness of the polymeric material layer 220 is greater than or equal to a predetermined thickness. In some embodiments, the polymeric material layer 220 has a thickness of between about 5 [mu]m and 10 [mu]m, such as about 8 [mu]m.

在一些實施例中,清潔裝置500B的金屬層226A、金屬層226A和226B和保護層228A和228B視為清潔裝置500B的一光罩部分230B。清潔裝置500B的光罩部分230B可做為穿透光罩(transmission mask)。 In some embodiments, metal layer 226A, metal layers 226A and 226B, and protective layers 228A and 228B of cleaning device 500B are considered a reticle portion 230B of cleaning device 500B. The reticle portion 230B of the cleaning device 500B can function as a transmission mask.

第2圖是依據一些實施例之半導體晶圓加工系統600的方塊圖,其顯示將一些實施例之清潔裝置整合於其中的半導體晶圓加工系統。 2 is a block diagram of a semiconductor wafer processing system 600 in accordance with some embodiments showing a semiconductor wafer processing system incorporating the cleaning devices of some embodiments therein.

如第2圖所示,依據一些實施例之半導體晶圓加工系統600可為執行微影曝光製程的一掃描器(scanner),且此微影曝光製程具有個別的發光源以及曝光模式。在一些實施例中,半導體晶圓加工系統600為利用將光阻層暴露在來自射線源的極紫外光光線下之方式來進行極紫外光微影製程的極紫外光微影系統(EUV photolithography system),且上述光阻層為會對於極紫外光光線感光的材料。半導體晶圓加工系統600可包括真空腔室302、射線源304、光罩靜電座306、傳送裝置310、控制器312、晶圓座314、檢測裝置316、真空幫浦322、清潔裝置500和反射光罩700。 As shown in FIG. 2, semiconductor wafer processing system 600 in accordance with some embodiments may be a scanner that performs a lithography exposure process with individual illumination sources and exposure modes. In some embodiments, the semiconductor wafer processing system 600 is an EUV photolithography system that performs an extreme ultraviolet lithography process by exposing the photoresist layer to extreme ultraviolet light from a source. And the above photoresist layer is a material that is sensitive to extreme ultraviolet light. The semiconductor wafer processing system 600 can include a vacuum chamber 302, a radiation source 304, a reticle electrostatic mount 306, a transfer device 310, a controller 312, a wafer holder 314, a detection device 316, a vacuum pump 322, a cleaning device 500, and a reflection Photomask 700.

如第2圖所示,半導體晶圓加工系統600的真空腔室302可為一密閉腔室,射線源304、傳送裝置310、控制器312、晶圓座314、檢測裝置316和清潔裝置500設置於真空腔室302中。在一些實施例中,真空腔室302利用真空幫浦322使其維持在一個真空的環境下以避免來自射線源的極紫外光光線的強度損失。 As shown in FIG. 2, the vacuum chamber 302 of the semiconductor wafer processing system 600 can be a closed chamber, the radiation source 304, the transfer device 310, the controller 312, the wafer holder 314, the detecting device 316, and the cleaning device 500. In the vacuum chamber 302. In some embodiments, vacuum chamber 302 utilizes vacuum pump 322 to maintain it in a vacuum environment to avoid loss of intensity of extreme ultraviolet light from the source.

如第2圖所示,半導體晶圓加工系統600的光罩靜電座306可利用靜電吸附的方式承載固定清潔裝置500或反射光罩700。 As shown in FIG. 2, the reticle electrostatic mount 306 of the semiconductor wafer processing system 600 can carry the stationary cleaning device 500 or the reflective reticle 700 by electrostatic adsorption.

以下利用第3A、3B圖說明半導體晶圓加工系統600之光罩靜電座306的詳細構造。第3A圖為依據一些實施例之半 導體晶圓加工系統600之光罩靜電座306的吸附面307的俯視示意圖。第3B圖為沿第3A圖的A-A’切線的剖面圖,其顯示依據一些實施例之半導體晶圓加工系統600之光罩靜電座306的剖面示意圖。在一些實施例中,光罩靜電座306包括複數個電極308,以一陣列形式設置接近於光罩靜電座306的吸附面307。當清潔裝置500或反射光罩700放置於光罩靜電座306的吸附面307時,電極308可電性連接至一交流電源(圖未顯示)使其積聚正電荷(或負電荷),且吸附面307上的清潔裝置500或反射光罩700在相應於電極308的區域會感應出極性相反的負電荷(或正電荷),以於電極308和清潔裝置500(或反射光罩700)之間產生靜電場,且藉由靜電場的靜電引力而將清潔裝置500(或反射光罩700)牢固地吸附在光罩靜電座306的吸附面307。 The detailed structure of the photomask electrostatic pad 306 of the semiconductor wafer processing system 600 will be described below using FIGS. 3A and 3B. 3A is a top plan view of the adsorption face 307 of the reticle electrostatic mount 306 of the semiconductor wafer processing system 600 in accordance with some embodiments. 3B is a cross-sectional view taken along line A-A' of FIG. 3A, showing a cross-sectional view of the photomask electrostatic mount 306 of the semiconductor wafer processing system 600 in accordance with some embodiments. In some embodiments, the reticle electrostatic mount 306 includes a plurality of electrodes 308 that are disposed in an array proximate to the absorbing surface 307 of the reticle electrostatic mount 306. When the cleaning device 500 or the reflective mask 700 is placed on the adsorption surface 307 of the reticle electrostatic seat 306, the electrode 308 can be electrically connected to an AC power source (not shown) to accumulate a positive charge (or a negative charge) and adsorbed. The cleaning device 500 or the reflective mask 700 on the face 307 induces a negatively opposite negative charge (or positive charge) in the region corresponding to the electrode 308 for between the electrode 308 and the cleaning device 500 (or the reflective mask 700). An electrostatic field is generated, and the cleaning device 500 (or the reflective mask 700) is firmly adsorbed on the adsorption surface 307 of the photomask electrostatic pad 306 by electrostatic attraction of the electrostatic field.

在一些實施例中,半導體晶圓加工系統600的清潔裝置500用以清潔光罩靜電座306。另外,半導體晶圓加工系統600的清潔裝置500可用以進行一微影製程。清潔裝置500可包括聚合物材料層220和光罩部分230,且清潔裝置500的構造、功能和材質可相同或類似於第1A、1B圖所示的清潔裝置500A或500B。在一些實施例中,設置於半導體晶圓加工系統600中的清潔裝置500的數量並無限制。舉例來說,半導體晶圓加工系統600包括第1A圖所示的清潔裝置500A和第1B圖所示的清潔裝置500B。 In some embodiments, the cleaning device 500 of the semiconductor wafer processing system 600 is used to clean the reticle electrostatic mount 306. Additionally, the cleaning device 500 of the semiconductor wafer processing system 600 can be used to perform a lithography process. The cleaning device 500 can include a layer of polymeric material 220 and a reticle portion 230, and the configuration, function, and material of the cleaning device 500 can be the same or similar to the cleaning device 500A or 500B shown in Figures 1A, 1B. In some embodiments, the number of cleaning devices 500 disposed in the semiconductor wafer processing system 600 is not limited. For example, the semiconductor wafer processing system 600 includes the cleaning device 500A shown in FIG. 1A and the cleaning device 500B shown in FIG. 1B.

在一些實施例中,半導體晶圓加工系統600的反射光罩700用以對半導體晶圓進行微影製程。 In some embodiments, the reflective mask 700 of the semiconductor wafer processing system 600 is used to perform a lithography process on the semiconductor wafer.

以下利用第4圖說明半導體晶圓加工系統600之反 射光罩700的詳細構造。第4圖為依據一些實施例之半導體晶圓加工系統600之反射光罩700的示意圖。如第4圖所示的一些實施例中,反射光罩700包括基板200C、設置於基板200C的前側表面201上方的反射結構206、保護層210和吸收層216,以及設置於基板200C的後側表面203上方的導電層218。在一些實施例中,反射光罩700的基板200C、反射結構206、保護層210、吸收層216和導電層218的構造、功能和材質分別相同或類似於第1A圖所示的清潔裝置500A的基板200A、反射結構206、保護層210、吸收層216和導電層218,因而在此不再重複敘述。 The detailed construction of the reflective reticle 700 of the semiconductor wafer processing system 600 will now be described using FIG. 4 is a schematic illustration of a reflective mask 700 of a semiconductor wafer processing system 600 in accordance with some embodiments. In some embodiments as shown in FIG. 4, the reflective mask 700 includes a substrate 200C, a reflective structure 206 disposed over the front side surface 201 of the substrate 200C, a protective layer 210 and an absorbing layer 216, and a rear side disposed on the substrate 200C. Conductive layer 218 over surface 203. In some embodiments, the structure, function, and material of the substrate 200C, the reflective structure 206, the protective layer 210, the absorbing layer 216, and the conductive layer 218 of the reflective mask 700 are the same or similar to those of the cleaning device 500A shown in FIG. 1A. The substrate 200A, the reflective structure 206, the protective layer 210, the absorbing layer 216, and the conductive layer 218 are therefore not repeated herein.

如第2圖所示,半導體晶圓加工系統600的晶圓座314可用以承載半導體晶圓320,晶圓座314可透過靜電吸附的方式吸附半導體晶圓320。在一些實施例中,晶圓座314與光罩靜電座306為相對設置。在一些實施例中,半導體晶圓320包括例如將被圖案化的一矽晶圓或其他半導體晶圓,且其表面上塗有感光於極紫外光光線的一光阻層(圖未顯示)。在一些實施例中,半導體晶圓320包括空白晶圓(dummy wafer),且其表面上不具有上述光阻層。 As shown in FIG. 2, the wafer holder 314 of the semiconductor wafer processing system 600 can be used to carry the semiconductor wafer 320, and the wafer holder 314 can adsorb the semiconductor wafer 320 by electrostatic adsorption. In some embodiments, the wafer holder 314 is disposed opposite the reticle electrostatic mount 306. In some embodiments, the semiconductor wafer 320 includes, for example, a germanium wafer or other semiconductor wafer to be patterned, and the surface thereof is coated with a photoresist layer (not shown) that is sensitive to extreme ultraviolet light. In some embodiments, the semiconductor wafer 320 includes a dummy wafer and does not have the photoresist layer described above on its surface.

如第2圖所示,半導體晶圓加工系統600的射線源304用以產生波長範圍約在1nm與100nm之間的極紫外光光線。當清潔裝置500或反射光罩700吸附於光罩靜電座306上時,可藉由一反光器(illuminator)(圖未顯示)將射線源304產生的極紫外光光線(圖未顯示)導向清潔裝置500或反射光罩700。清潔裝置500或反射光罩700會部分吸收且部分反射上述極紫外光光線,藉由上述清潔裝置500或反射光罩700反射的極紫外 光光線會攜帶清潔裝置500或反射光罩700的圖案。可利用一投影光學模組(projection optics module)將清潔裝置500或反射光罩700的圖案映像(image)至吸附於晶圓座314上的半導體晶圓320以對半導體晶圓320曝光。在一些實施例中,射線源304產生一波長係集中在約13.5nm的極紫外光光線。因此,射線源304也可稱為極紫外光射線源。在一些實施例中,極紫外光射線源利用雙脈衝雷射產生電漿之機制來產生極紫外光射線。 As shown in FIG. 2, the radiation source 304 of the semiconductor wafer processing system 600 is used to generate extreme ultraviolet light having a wavelength range between about 1 nm and 100 nm. When the cleaning device 500 or the reflective mask 700 is adsorbed on the reticle electrostatic seat 306, the extreme ultraviolet light (not shown) generated by the radiation source 304 can be directed to the cleaning by an illuminator (not shown). Device 500 or reflective mask 700. The cleaning device 500 or the reflective mask 700 partially absorbs and partially reflects the extreme ultraviolet light, and the extreme ultraviolet light reflected by the cleaning device 500 or the reflective mask 700 carries the pattern of the cleaning device 500 or the reflective mask 700. The pattern of the cleaning device 500 or the reflective mask 700 can be imaged to the semiconductor wafer 320 adsorbed on the wafer holder 314 by a projection optics module to expose the semiconductor wafer 320. In some embodiments, the source 304 produces an extreme ultraviolet light having a wavelength centered at about 13.5 nm. Thus, source 304 can also be referred to as an extreme ultraviolet source. In some embodiments, an extreme ultraviolet light source utilizes a dual pulsed laser to generate a plasma mechanism to generate extreme ultraviolet light.

如第2圖所示,半導體晶圓加工系統600的傳送裝置310可用以選擇性地將清潔裝置500放置於光罩靜電座306、使清潔裝置500與光罩靜電座306分離、將反射光罩700放置於光罩靜電座306、使反射光罩700與光罩靜電座306分離、將半導體晶圓320放置於晶圓座314上或者使半導體晶圓320與晶圓座314分離。在一些實施例中,傳送裝置310包括機械手臂。 As shown in FIG. 2, the transfer device 310 of the semiconductor wafer processing system 600 can be used to selectively place the cleaning device 500 on the reticle electrostatic mount 306, separate the cleaning device 500 from the reticle electrostatic mount 306, and reflect the reticle. The 700 is placed on the mask electrostatic mount 306, the reflective mask 700 is separated from the mask electrostatic mount 306, the semiconductor wafer 320 is placed on the wafer holder 314, or the semiconductor wafer 320 is separated from the wafer holder 314. In some embodiments, the delivery device 310 includes a robotic arm.

如第2圖所示,半導體晶圓加工系統600的控制器312至少可配置以控制光罩靜電座306、晶圓座314、傳送裝置310與檢測裝置316。在一些實施例中,控制器312用以控制清潔裝置500與光罩靜電座306之間的靜電吸附力。在一些實施例中,控制器312可用於控制清潔裝置500吸附於光罩靜電座306的時間。 As shown in FIG. 2, the controller 312 of the semiconductor wafer processing system 600 can be configured to control at least the reticle electrostatic mount 306, the wafer holder 314, the transfer device 310, and the detection device 316. In some embodiments, the controller 312 is used to control the electrostatic adsorption force between the cleaning device 500 and the reticle electrostatic mount 306. In some embodiments, the controller 312 can be used to control when the cleaning device 500 is attracted to the reticle electrostatic mount 306.

如第2圖所示,半導體晶圓加工系統600的檢測裝置316可用以檢測光罩靜電座306表面是否需要被清潔(例如檢測光罩靜電座306表面是否具有污染物或光罩靜電座306表面是否不平坦)。在一些實施例中,檢測裝置205為光學檢測裝置,透過發射光線至光罩靜電座306且接收光罩靜電座306所產 生之反射光來判斷光罩靜電座306表面是否需要被清潔(例如透過反射光的角度或光線強度)。 As shown in FIG. 2, the detection device 316 of the semiconductor wafer processing system 600 can be used to detect whether the surface of the reticle electrostatic mount 306 needs to be cleaned (eg, to detect whether the surface of the reticle electrostatic mount 306 has contaminants or the surface of the reticle electrostatic mount 306). Is it not flat?) In some embodiments, the detecting device 205 is an optical detecting device that determines whether the surface of the reticle electrostatic seat 306 needs to be cleaned by transmitting light to the reticle electrostatic seat 306 and receiving the reflected light generated by the reticle electrostatic seat 306 (eg, through The angle of the reflected light or the intensity of the light).

第5圖為一些實施例之半導體晶圓加工系統之清潔方法550的流程圖。在一些實施例中,半導體晶圓加工系統之清潔方法550可應用於第2圖之半導體晶圓加工系統600。第2、7A、7B、7C圖顯示相應於第5圖所示之一些實施例之半導體晶圓加工系統之清潔方法550的不同操作時的半導體晶圓加工系統600的方塊示意圖。並且,第8A、8B、8C圖為依據一些實施例之半導體晶圓加工系統之清潔裝置500與光罩靜電座306在半導體晶圓加工系統之清潔方法550的不同操作階段的示意圖。後續的說明係同時利用第5圖搭配第2、7A~7C圖以及第8A、8B、8C圖說明依據一些實施例之半導體晶圓加工系統之清潔方法550。可以在半導體晶圓加工系統之清潔方法550的流程的前面、中間或者後面提供額外的操作,且所描述的某些操作可以被替換、消除或者移動以作為此方法的附加實施例。 FIG. 5 is a flow diagram of a cleaning method 550 of a semiconductor wafer processing system of some embodiments. In some embodiments, the semiconductor wafer processing system cleaning method 550 can be applied to the semiconductor wafer processing system 600 of FIG. 2, 7A, 7B, and 7C are block diagrams showing the semiconductor wafer processing system 600 in a different operation of the cleaning method 550 of the semiconductor wafer processing system corresponding to some of the embodiments shown in FIG. Moreover, FIGS. 8A, 8B, and 8C are schematic views of different stages of operation of the cleaning method 500 of the semiconductor wafer processing system and the mask electrostatic mount 306 in the semiconductor wafer processing system cleaning method 550, in accordance with some embodiments. The subsequent description utilizes FIG. 5 in conjunction with FIGS. 2, 7A-7C, and 8A, 8B, and 8C to illustrate a cleaning method 550 of a semiconductor wafer processing system in accordance with some embodiments. Additional operations may be provided in front of, in the middle or after the flow of the cleaning method 550 of the semiconductor wafer processing system, and some of the operations described may be replaced, eliminated or moved as an additional embodiment of the method.

請同時參考第2、5、7A、8A圖,一些實施例之半導體晶圓加工系統之清潔方法550可包括操作502,在一真空腔室中,將一清潔裝置500放置於半導體晶圓加工系統600的一光罩靜電座306上。可利用傳送裝置310將清潔裝置500放置於光罩靜電座306上方。如第3B圖所示,在一些實施例中,接近光罩靜電座306的吸附面307的電極308的表面上會因為重複承載光罩進行微影製程而吸附累積污染物309,如第8A圖所示。累積的污染物309可能會造成光罩靜電座306損傷或使光罩無法平坦放置於光罩靜電座306。因此,清潔裝置500可用於將上述 污染物帶離光罩靜電座306的表面(吸附面307),進而達成清潔光罩靜電座的效果306。在一些實施例中,清潔裝置500包括聚合物材料層220和光罩部分230。清潔裝置500的構造、功能和材質可相同或類似於第1A、1B圖所示的清潔裝置500A、500B。聚合物材料層220的構造、功能和材質可相同或類似於第1A、1B圖所示的聚合物材料層220,且光罩部分230的構造、功能和材質可相同或類似於第1A、1B圖所示的光罩部分230A、230B。 Referring to FIGS. 2, 5, 7A, and 8A, the cleaning method 550 of the semiconductor wafer processing system of some embodiments may include an operation 502 of placing a cleaning device 500 in a semiconductor wafer processing system in a vacuum chamber. A reticle electrostatic seat 306 of 600. The cleaning device 500 can be placed over the reticle electrostatic mount 306 using the transfer device 310. As shown in FIG. 3B, in some embodiments, the surface of the electrode 308 adjacent to the adsorption surface 307 of the reticle electrostatic mount 306 is adsorbed and accumulated by the lithography process by repeating the photomask, as shown in FIG. 8A. Shown. The accumulated contaminants 309 may cause damage to the reticle electrostatic mount 306 or render the reticle unflattenable to the reticle electrostatic mount 306. Accordingly, the cleaning device 500 can be used to carry the above-described contaminants away from the surface of the photomask mount 306 (adsorption surface 307), thereby achieving the effect 306 of cleaning the photomask electrostatic mount. In some embodiments, the cleaning device 500 includes a layer of polymeric material 220 and a reticle portion 230. The configuration, function, and material of the cleaning device 500 may be the same or similar to the cleaning devices 500A, 500B shown in Figures 1A, 1B. The structure, function and material of the polymer material layer 220 may be the same or similar to the polymer material layer 220 shown in FIGS. 1A and 1B, and the configuration, function and material of the reticle portion 230 may be the same or similar to the 1A, 1B. The mask portions 230A, 230B are shown.

請同時參考第5、7A、8B圖,接著,半導體晶圓加工系統之清潔方法550可包括操作504,透過光罩靜電座306將清潔裝置500之聚合物材料層220吸附於光罩靜電座306,並使清潔裝置500之聚合物材料層220接觸光罩靜電座306的吸附面307。在一些實施例中,光罩靜電座306可利用靜電吸附的方式將清潔裝置500吸附於其上。如第3C圖所示,進行操作504期間,光罩靜電座306的吸附面307可被聚合物材料層220完全覆蓋,聚合物材料層220可因清潔裝置500與光罩靜電座306之間的靜電吸附力而被壓縮,進而與光罩靜電座306的污染物309接觸,使上述污染物309附著(或黏附)於清潔裝置500的聚合物材料層220上。 Referring to FIGS. 5, 7A, and 8B simultaneously, the semiconductor wafer processing system cleaning method 550 can include an operation 504 of adsorbing the polymer material layer 220 of the cleaning device 500 through the mask electrostatic mount 306 to the mask electrostatic mount 306. And the polymeric material layer 220 of the cleaning device 500 contacts the adsorption surface 307 of the reticle electrostatic mount 306. In some embodiments, the reticle electrostatic mount 306 can electrostatically adsorb the cleaning device 500 thereto. As shown in FIG. 3C, during operation 504, the adsorption surface 307 of the reticle electrostatic mount 306 can be completely covered by the polymeric material layer 220, which can be between the cleaning device 500 and the reticle electrostatic mount 306. The electrostatic adsorption force is compressed to contact the contaminant 309 of the photomask electrostatic seat 306, so that the contaminant 309 adheres (or adheres) to the polymer material layer 220 of the cleaning device 500.

在一些實施例中,控制器312用以控制清潔裝置500與光罩靜電座306之間的靜電吸附力,藉此增加聚合物材料層220被擠壓的程度,使光罩靜電座306的電極308上的污染物309更容易被黏附或嵌入於清潔裝置500的聚合物材料層220。 In some embodiments, the controller 312 is configured to control the electrostatic adsorption force between the cleaning device 500 and the reticle electrostatic mount 306, thereby increasing the extent to which the polymer material layer 220 is squeezed to the electrodes of the reticle electrostatic mount 306. The contaminants 309 on the 308 are more likely to be adhered or embedded in the layer of polymeric material 220 of the cleaning device 500.

請參考第7A圖,在一些實施例中,當清潔裝置500吸附於光罩靜電座306之後,將半導體晶圓320放置且吸附於晶 圓座314上。接著,利用射線源304進行一微影製程(例如極紫外光extreme ultra-violet(EUV)微影製程)。在一些實施例中,射線源304包括一極紫外光(EUV)光源,射線源304在進行微影製程期間用以產生極紫外光光線L對半導體晶圓320曝光。並且,在進行微影製程期間,可藉由一反光器(圖未顯示)將射線源304產生的極紫外光光線L導向清潔裝置500的光罩部分230,清潔裝置500的光罩部分230會將極紫外光光線L反射至半導體晶圓320,且可利用一投影光學模組(圖未顯示)將清潔裝置500的光罩部分230的圖案映像(image)至吸附於晶圓座314上的半導體晶圓320以對半導體晶圓320曝光。進行上述微影製程之後,射線源304停止產生極紫外光光線L。 Referring to FIG. 7A, in some embodiments, after the cleaning device 500 is attracted to the reticle electrostatic mount 306, the semiconductor wafer 320 is placed and adsorbed onto the wafer holder 314. Next, a lithography process (eg, an extreme ultra-violet (EUV) lithography process) is performed using the radiation source 304. In some embodiments, the source 304 includes an extreme ultraviolet (EUV) light source that is used to generate the extreme ultraviolet light L to expose the semiconductor wafer 320 during the lithography process. Moreover, during the lithography process, the extreme ultraviolet light L generated by the radiation source 304 can be directed to the reticle portion 230 of the cleaning device 500 by a reflector (not shown), and the reticle portion 230 of the cleaning device 500 The extreme ultraviolet light L is reflected to the semiconductor wafer 320, and the pattern of the mask portion 230 of the cleaning device 500 can be imaged onto the wafer holder 314 by a projection optical module (not shown). The semiconductor wafer 320 is exposed to the semiconductor wafer 320. After the above lithography process, the source 304 stops generating the extreme ultraviolet light L.

在本實施例中,清潔裝置500的構造、功能和材質可相同或類似於第1A圖所示的清潔裝置500A。清潔裝置500的聚合物材料層220的構造、功能和材質可相同或類似於第1A圖所示的聚合物材料層220,且清潔裝置500的光罩部分230的構造、功能和材質可相同或類似於第1A圖所示的光罩部分230A。 In the present embodiment, the configuration, function and material of the cleaning device 500 may be the same or similar to the cleaning device 500A shown in FIG. 1A. The configuration, function and material of the polymer material layer 220 of the cleaning device 500 may be the same or similar to the polymer material layer 220 shown in FIG. 1A, and the configuration, function and material of the reticle portion 230 of the cleaning device 500 may be the same or Similar to the mask portion 230A shown in FIG. 1A.

在本實施例中,半導體晶圓320可為一工作晶圓,且其表面上塗有對極紫外光光線感光的一光阻層(圖未顯示)。或者,半導體晶圓320可包括空白晶圓(dummy wafer),且其表面上不具有上述光阻層。 In this embodiment, the semiconductor wafer 320 can be a working wafer, and its surface is coated with a photoresist layer (not shown) that is sensitive to extreme ultraviolet light. Alternatively, the semiconductor wafer 320 may include a dummy wafer and has no photoresist layer on its surface.

如第7A圖所示,當清潔裝置500吸附於光罩靜電座306之後,半導體晶圓加工系統600可利用清潔裝置500對半導體晶圓320進行微影製程,並且在進行微影製程期間同時清潔光罩靜電座306,藉此減少進行微影製程與清潔光罩靜電座306 的整體時間。 As shown in FIG. 7A, after the cleaning device 500 is adsorbed to the photomask electrostatic mount 306, the semiconductor wafer processing system 600 can perform a lithography process on the semiconductor wafer 320 by using the cleaning device 500, and simultaneously clean during the lithography process. The mask electrostatic mount 306 thereby reduces the overall time required to perform the lithography process and clean the reticle electrostatic mount 306.

請同時參考第5、7B、8C圖,接著,半導體晶圓加工系統之清潔方法550可包括操作506,當清潔裝置500吸附於光罩靜電座306且經過時間TN時,將清潔裝置500與光罩靜電座306分離。如第8C圖所示,清潔裝置500與光罩靜電座306分離時,光罩靜電座306的電極308上的污染物309附著(或黏附)於清潔裝置500的聚合物材料層220上。在一些實施例中,指標N的預設值為0,亦即時間TN的預設值為時間T0。舉例來說,時間T0約為30分鐘。然而,也可根據進行微影製程的時間及/或次數等條件來調整時間TN的預設值為時間T0Please refer to FIGS. 5, 7B, and 8C at the same time. Next, the cleaning method 550 of the semiconductor wafer processing system may include an operation 506. When the cleaning device 500 is attracted to the reticle electrostatic mount 306 and the time T N elapses, the cleaning device 500 is The mask electrostatic mount 306 is separated. As shown in FIG. 8C, when the cleaning device 500 is separated from the photomask electrostatic mount 306, the contaminants 309 on the electrodes 308 of the photomask electrostatic mount 306 are attached (or adhered) to the polymeric material layer 220 of the cleaning device 500. In some embodiments, the preset value of the indicator N is 0, that is, the preset value of the time T N is the time T 0 . For example, time T 0 is approximately 30 minutes. However, it is also possible to adjust the preset value of the time T N to the time T 0 according to conditions such as the time and/or the number of times the lithography process is performed.

在一些實施例中,清潔裝置500被光罩靜電座306吸附的時間TN可大於一既定時間(例如約為30分鐘),藉此增加聚合物材料層101被擠壓的程度,使上述污染物更容易被黏附或嵌入於聚合物材料層220。然而,也可根據進行微影製程的時間及/或次數等條件來調整時間TN。在一些實施例中,控制器312可用於控制清潔裝置500被光罩靜電座306吸附的時間(即時間TN)。 In some embodiments, the time TN at which the cleaning device 500 is attracted by the photomask electrostatic mount 306 can be greater than a predetermined time (eg, about 30 minutes), thereby increasing the extent to which the layer of polymeric material 101 is squeezed, causing the contamination. The material is more easily adhered or embedded in the layer of polymeric material 220. However, the time T N may also be adjusted according to conditions such as the time and/or the number of times the lithography process is performed. In some embodiments, the controller 312 can be used to control the time (ie, time TN ) at which the cleaning device 500 is attracted by the reticle electrostatic mount 306.

在半導體晶圓加工系統600利用吸附於光罩靜電座306的清潔裝置500對半導體晶圓320進行微影製程的實施例中,上述微影製程的製程時間設計小於或等於時間TN。並且,執行完操作506後,將半導體晶圓320與晶圓座314分離,如第7B圖所示。 In an embodiment in which the semiconductor wafer processing system 600 performs a lithography process on the semiconductor wafer 320 by the cleaning device 500 adsorbed to the photomask electrostatic pad 306, the process time design of the lithography process is less than or equal to the time T N . And, after operation 506 is performed, the semiconductor wafer 320 is separated from the wafer holder 314 as shown in FIG. 7B.

在一些實施例中,半導體晶圓加工系統之清潔方法550至少經過操作502、操作504和操作506而完成。 In some embodiments, the cleaning method 550 of the semiconductor wafer processing system is completed at least via operation 502, operation 504, and operation 506.

在一些實施例中,已清潔過的光罩靜電座306的電極308上的污染物309仍可能隨著時間而累積。累積的污染物309可能會造成光罩靜電座306損壞或使光罩無法平坦放置於光罩靜電座306。 In some embodiments, the contaminants 309 on the electrodes 308 of the cleaned photomask electrostatic mount 306 may still accumulate over time. The accumulated contaminants 309 may cause damage to the reticle electrostatic mount 306 or render the reticle unflattenable to the reticle electrostatic mount 306.

在一些實施例中,在操作506完成後,半導體晶圓加工系統之清潔方法550還包括操作508,利用檢測裝置316偵測且判斷光罩靜電座306表面是否需要清潔。若檢測裝置316判斷光罩靜電座306表面需要被清潔(如第5圖所示的”是”),則控制器312將操作506中的時間TN改為時間TN+1(亦即將指標N的數值加1)並且再次執行操作502、操作504和操作506。並且,在操作506中,當清潔裝置500吸附於光罩靜電座306且經過時間T1(亦即指標N的數值加1)時,將清潔裝置500與光罩靜電座306分離,以此類推。 In some embodiments, after operation 506 is completed, the semiconductor wafer processing system cleaning method 550 further includes an operation 508 of detecting and determining whether the surface of the photomask electrostatic mount 306 requires cleaning. If the detecting means 316 determines that the surface of the reticle electrostatic seat 306 needs to be cleaned ("Y" as shown in Fig. 5), the controller 312 changes the time TN in operation 506 to time TN+1 (i.e., the index) The value of N is incremented by 1) and operation 502, operation 504, and operation 506 are performed again. Then, in operation 506, and 306 (i.e., the numerical index N plus 1), the cleaning device 500 when the cleaning device 500 is separated from the reticle electrostatic adsorption seat 1 and the elapsed time T electrostatic reticle base 306, and so on .

在一些實施例中,時間TN中的指標N的數值越大,代表TN的時間越長。在此狀況下,清潔方法550在執行完操作502、操作504和操作506後,若在執行完操作508判斷光罩靜電座306表面需要被清潔(仍有污染物)(如第5圖所示的”是”),則清潔方法550會再次操作502、操作504和操作506,並且在操作506中以更長的時間(例如使用大於時間T0的時間T1),將清潔裝置500吸附於光罩靜電座306,藉此增加清潔裝置500之聚合物材料層220被擠壓的程度,使污染物更容易被黏附或嵌入於清潔裝置500之聚合物材料層220中,藉此進一步清除尚未從光罩靜電座306移除的污染物309。在一些實施例中,時間T0為一第一時間(長度),而時間T1為一第二時間(長度)。 In some embodiments, the greater the value of the time index N T N, T N longer representative of the. In this case, after performing operation 502, operation 504, and operation 506, the cleaning method 550 determines that the surface of the photomask electrostatic seat 306 needs to be cleaned (and still has contaminants) after performing operation 508 (as shown in FIG. 5). "yES"), the cleaning method 550 will again operation 502, operation 504 and operation 506, and a longer period of time (for example, greater than time T 0 T 1 of time in operation 506), the cleaning device 500 is adsorbed on The mask electrostatic mount 306, thereby increasing the extent to which the polymeric material layer 220 of the cleaning device 500 is squeezed, allowing contaminants to be more easily adhered or embedded in the polymeric material layer 220 of the cleaning device 500, thereby further eliminating Contaminants 309 removed from the reticle electrostatic mount 306. In some embodiments, time T 0 is a first time (length) and time T 1 is a second time (length).

另一方面,若執行完半導體晶圓加工系統之清潔方法550的操作508,判斷光罩靜電座306表面不需要被清潔(如第5圖所示的”否”),則執行清潔方法550的操作510,利用控制器312將操作506中的時間TN恢復為預設值(例如時間T0)。在操作510中,在清潔裝置500與光罩靜電座306分離且經過間隔時間T時,再次執行操作502、操作504和操作506。舉例來說,若光罩靜電座306表面不需要被清潔,則在清潔裝置500與光罩靜電座306分離且經過間隔時間T時,再將清潔裝置500放置於光罩靜電座306上方,透過光罩靜電座306將清潔裝置500之聚合物材料層220吸附於光罩靜電座306,以及當清潔裝置500吸附於光罩靜電座306且經過時間T0時,將清潔裝置500與光罩靜電座306分離。 On the other hand, if the operation 508 of the cleaning method 550 of the semiconductor wafer processing system is performed, it is judged that the surface of the photomask electrostatic pad 306 does not need to be cleaned ("NO" as shown in FIG. 5), then the cleaning method 550 is performed. Operation 510, using controller 312 to restore time T N in operation 506 to a preset value (eg, time T 0 ). In operation 510, when the cleaning device 500 is separated from the reticle electrostatic mount 306 and the interval time T elapses, operation 502, operation 504, and operation 506 are performed again. For example, if the surface of the photomask electrostatic seat 306 does not need to be cleaned, when the cleaning device 500 is separated from the photomask electrostatic seat 306 and the interval time T is passed, the cleaning device 500 is placed over the photomask electrostatic seat 306. The mask electrostatic mount 306 adsorbs the polymer material layer 220 of the cleaning device 500 to the photomask electrostatic mount 306, and when the cleaning device 500 is attracted to the photomask electrostatic mount 306 and passes the time T 0 , the cleaning device 500 and the photomask are electrostatically charged. Block 306 is separated.

在一些實施例中,利用控制器312決定間隔時間T,可達到避免過度頻繁地清潔光罩靜電座的效果,或者可達到避免半導體晶圓加工系統之清潔方法550的操作的時間間隔太長造成在光罩靜電座上累積過多污染物的效果。在一些實施例中,間隔時間T可大於操作506中清潔裝置500被光罩靜電座306吸附的時間TN。舉例來說,間隔時間T範圍可約在20小時與30小時之間,例如約為24小時。然而,也可根據進行微影製程的時間及/或次數等條件來調整間隔時間T。 In some embodiments, using the controller 312 to determine the interval time T, the effect of avoiding excessively frequent cleaning of the reticle mount can be achieved, or the time interval to avoid operation of the cleaning method 550 of the semiconductor wafer processing system can be too long. The effect of accumulating excessive contaminants on the reticle mount. In some embodiments, the interval time T can be greater than the time T N at which the cleaning device 500 is adsorbed by the mask electrostatic mount 306 in operation 506. For example, the interval time T can range between about 20 hours and 30 hours, such as about 24 hours. However, the interval time T may be adjusted according to conditions such as the time and/or the number of times the lithography process is performed.

依據一些實施例之半導體晶圓加工系統之清潔方法550具有以下優點。在清潔半導體晶圓加工系統600的光罩靜電座306時,不需要將半導體晶圓加工系統600離線(off-line)停機,破壞真空腔室302的真空環境以進行清潔。因此,不需 要耗費恢復真空環境的作業時間,使清潔光罩靜電座306的時間可被縮短,另一方面,由於進行半導體晶圓加工系統之清潔方法550時不會破壞真空腔室302的真空環境,進而改善整體半導體製程的效率。 The cleaning method 550 of a semiconductor wafer processing system in accordance with some embodiments has the following advantages. When cleaning the reticle electrostatic mount 306 of the semiconductor wafer processing system 600, there is no need to off-line the semiconductor wafer processing system 600, damaging the vacuum environment of the vacuum chamber 302 for cleaning. Therefore, it is not necessary to consume the working time for restoring the vacuum environment, so that the time for cleaning the photomask electrostatic pad 306 can be shortened, and on the other hand, the vacuum of the vacuum chamber 302 is not broken when the cleaning method 550 of the semiconductor wafer processing system is performed. The environment, which in turn improves the efficiency of the overall semiconductor process.

第6A、6B圖為一些實施例之半導體晶圓加工方法650的流程圖。在一些實施例中,半導體晶圓加工方法650可應用於第4圖之半導體晶圓加工系統600。第2、7A、7B、7C、7D、7E圖也可用於顯示相應於第6A、6B圖所示之一些實施例之半導體晶圓加工方法650的不同操作時的半導體晶圓加工系統600的方塊示意圖。並且,第8A、8B、8C圖為也可用於顯示依據一些實施例之半導體晶圓加工系統600之清潔裝置500與光罩靜電座306在半導體晶圓加工方法650的不同操作階段的示意圖。後續的說明係同時利用第6A、6B圖搭配第2、7A~7E圖以及第8A、8B、8C圖說明依據一些實施例之半導體晶圓加工方法650。可以在半導體晶圓加工方法650的流程的前面、中間或者後面提供額外的操作,且所描述的某些操作可以被替換、消除或者移動以作為此方法的附加實施例。 6A, 6B are flow diagrams of a semiconductor wafer processing method 650 of some embodiments. In some embodiments, semiconductor wafer processing method 650 can be applied to semiconductor wafer processing system 600 of FIG. The 2, 7A, 7B, 7C, 7D, 7E diagrams can also be used to display the blocks of the semiconductor wafer processing system 600 in the different operations of the semiconductor wafer processing method 650 corresponding to some of the embodiments shown in FIGS. 6A, 6B. schematic diagram. Moreover, FIGS. 8A, 8B, and 8C are schematic diagrams that may also be used to display the cleaning apparatus 500 and the photomask static mount 306 of the semiconductor wafer processing system 600 in accordance with some embodiments at different stages of operation of the semiconductor wafer processing method 650. Subsequent descriptions of the semiconductor wafer processing method 650 in accordance with some embodiments are illustrated by using FIGS. 6A and 6B in conjunction with FIGS. 2, 7A-7E, and 8A, 8B, and 8C. Additional operations may be provided in front of, in the middle, or behind the flow of semiconductor wafer processing method 650, and some of the operations described may be replaced, eliminated, or moved as an additional embodiment of the method.

請同時參考第2、6A、6B、7A、8A圖,一些實施例之半導體晶圓加工方法650可包括操作602,在一真空腔室中,將一清潔裝置500放置於半導體晶圓加工系統600的一光罩靜電座306上。在一些實施例中,半導體晶圓加工方法650的操作602的執行方式相同或類似於第5圖所示之半導體晶圓加工系統之清潔方法的操作502,因而在此不再重複敘述。在本實施例中,清潔裝置500的構造、功能和材質可相同或類似於第 1A圖所示的清潔裝置500A。清潔裝置500的聚合物材料層220的構造、功能和材質可相同或類似於第1A圖所示的聚合物材料層220,且清潔裝置500的光罩部分230的構造、功能和材質可相同或類似於第1A圖所示的光罩部分230A。 Referring to FIGS. 2, 6A, 6B, 7A, and 8A, the semiconductor wafer processing method 650 of some embodiments may include an operation 602 of placing a cleaning device 500 in a semiconductor wafer processing system 600 in a vacuum chamber. A photomask is placed on the electrostatic mount 306. In some embodiments, operation 602 of semiconductor wafer processing method 650 is performed in the same manner or similar to operation 502 of the cleaning method of the semiconductor wafer processing system illustrated in FIG. 5, and thus will not be repeated herein. In the present embodiment, the configuration, function and material of the cleaning device 500 may be the same or similar to the cleaning device 500A shown in Fig. 1A. The configuration, function and material of the polymer material layer 220 of the cleaning device 500 may be the same or similar to the polymer material layer 220 shown in FIG. 1A, and the configuration, function and material of the reticle portion 230 of the cleaning device 500 may be the same or Similar to the mask portion 230A shown in FIG. 1A.

請同時參考第6A、6B、7A、8B圖,接著,半導體晶圓加工方法650可包括操作604,透過光罩靜電座306將清潔裝置500之聚合物材料層220吸附於光罩靜電座306,並使清潔裝置500之聚合物材料層220接觸光罩靜電座306的吸附面307。在一些實施例中,半導體晶圓加工方法650的操作604的執行方式相同或類似於第5圖所示之半導體晶圓加工系統之清潔方法的操作504,因而在此不再重複敘述。 Referring to FIGS. 6A, 6B, 7A, and 8B, the semiconductor wafer processing method 650 may include an operation 604 of adsorbing the polymer material layer 220 of the cleaning device 500 to the photomask electrostatic pad 306 through the photomask electrostatic pad 306. The polymeric material layer 220 of the cleaning device 500 is brought into contact with the adsorption surface 307 of the reticle electrostatic mount 306. In some embodiments, operation 604 of semiconductor wafer processing method 650 is performed in the same manner or similar to operation 504 of the cleaning method of the semiconductor wafer processing system illustrated in FIG. 5, and thus will not be repeated herein.

請同時參考第6A、6B、7A圖,接著,半導體晶圓加工方法650可包括操作606,將半導體晶圓320放置且吸附於晶圓座314上。晶圓座314可透過靜電吸附的方式吸附半導體晶圓320。在一些實施例中,半導體晶圓320可為一工作晶圓,且其表面上塗有感光於極紫外光光線的一光阻層(圖未顯示)。或者,半導體晶圓320可包括空白晶圓(dummy wafer),且其表面上不具有上述光阻層。 Referring to FIGS. 6A, 6B, and 7A simultaneously, the semiconductor wafer processing method 650 can include an operation 606 of placing and adsorbing the semiconductor wafer 320 on the wafer holder 314. The wafer holder 314 can adsorb the semiconductor wafer 320 by electrostatic adsorption. In some embodiments, the semiconductor wafer 320 can be a working wafer and its surface is coated with a photoresist layer (not shown) that is sensitive to extreme ultraviolet light. Alternatively, the semiconductor wafer 320 may include a dummy wafer and has no photoresist layer on its surface.

請同時參考第6A、6B、7A圖,接著,半導體晶圓加工方法650可包括操作608,對半導體晶圓320進行一第一半導體製程。在一些實施例中,第一半導體製程為一微影製程(例如EUV微影製程),可利用射線源304進行上述第一半導體製程。在一些實施例中,射線源304包括一極紫外光(EUV)光源,射線源304在進行第一半導體製程(微影製程)期間用以產生極 紫外光光線L對半導體晶圓320曝光。並且,在進行第一半導體製程期間,可藉由一反光器(圖未顯示)將射線源304產生的極紫外光光線L導向清潔裝置500的光罩部分230,清潔裝置500的光罩部分230會將極紫外光光線L反射至半導體晶圓320,且可利用一投影光學模組(圖未顯示)將清潔裝置500的光罩部分230的圖案映像(image)至吸附於晶圓座314上的半導體晶圓320以對半導體晶圓320曝光。進行上述第一半導體製程之後,射線源304停止產生極紫外光光線L。 Please refer to FIGS. 6A, 6B, and 7A at the same time. Next, the semiconductor wafer processing method 650 can include an operation 608 of performing a first semiconductor process on the semiconductor wafer 320. In some embodiments, the first semiconductor process is a lithography process (eg, an EUV lithography process), and the first semiconductor process can be performed using the ray source 304. In some embodiments, the source 304 includes an extreme ultraviolet (EUV) source that is used to generate the extreme ultraviolet light L to expose the semiconductor wafer 320 during the first semiconductor process (lithography process). Moreover, during the first semiconductor process, the extreme ultraviolet light L generated by the radiation source 304 can be directed to the reticle portion 230 of the cleaning device 500 by a reflector (not shown), and the reticle portion 230 of the cleaning device 500 The extreme ultraviolet light L is reflected to the semiconductor wafer 320, and the pattern of the mask portion 230 of the cleaning device 500 can be imaged onto the wafer holder 314 by a projection optical module (not shown). The semiconductor wafer 320 is exposed to the semiconductor wafer 320. After the first semiconductor process described above, the source 304 stops generating the extreme ultraviolet light L.

如第7A、8B圖所示,執行操作608期間,半導體晶圓加工系統600可利用清潔裝置500對半導體晶圓320進行半導體製程(微影製程),並且在進行微影製程期間同時清潔光罩靜電座306,藉此減少進行半導體製程與清潔光罩靜電座306的整體時間。 As shown in FIGS. 7A and 8B, during operation 608, the semiconductor wafer processing system 600 can perform a semiconductor process (lithography process) on the semiconductor wafer 320 using the cleaning device 500, and simultaneously clean the mask during the lithography process. The electrostatic mount 306 thereby reduces the overall time required to perform the semiconductor process and clean the photomask electrostatic mount 306.

請同時參考第6A、6B、7B、8C圖,接著,半導體晶圓加工方法650可包括操作610,進行上述半導體製程之後,將清潔裝置500與光罩靜電座306分離,且將半導體晶圓320與晶圓座314分離。如第8C圖所示,清潔裝置500與光罩靜電座306分離時,光罩靜電座306的電極308上的污染物309附著(或黏附)於清潔裝置500的聚合物材料層220上。 Referring to FIGS. 6A, 6B, 7B, and 8C, the semiconductor wafer processing method 650 may further include an operation 610 of separating the cleaning device 500 from the photomask electrostatic pad 306 and performing the semiconductor wafer 320 after performing the semiconductor process. Separated from wafer holder 314. As shown in FIG. 8C, when the cleaning device 500 is separated from the photomask electrostatic mount 306, the contaminants 309 on the electrodes 308 of the photomask electrostatic mount 306 are attached (or adhered) to the polymeric material layer 220 of the cleaning device 500.

在一些實施例中,半導體晶圓加工方法650至少經過操作602、604、606、608和610而完成。 In some embodiments, semiconductor wafer processing method 650 is accomplished at least via operations 602, 604, 606, 608, and 610.

在一些實施例中,進行微影製程期間同時已清潔過的光罩靜電座306的電極308上的污染物309仍可能隨著時間而累積。累積的污染物309可能會造成光罩靜電座306損壞或使 光罩無法平坦放置於光罩靜電座306。 In some embodiments, contaminants 309 on the electrodes 308 of the reticle electrostatic mount 306 that have been cleaned during the lithography process may still accumulate over time. The accumulated contaminants 309 may cause damage to the reticle electrostatic mount 306 or prevent the reticle from being placed flat on the reticle electrostatic mount 306.

請同時參考第6A、6B、7C圖,接著,半導體晶圓加工方法650還包括操作612,利用檢測裝置316偵測且判斷光罩靜電座306表面是否需要清潔。若檢測裝置316判斷光罩靜電座306表面需要被清潔(如第6A、6B圖所示的”是”),則依序執行操作614、616、618。在操作614中,將清潔裝置500放置於光罩靜電座306。在操作616中,透過光罩靜電座306將清潔裝置500之聚合物材料層220吸附於光罩靜電座306。在操作616中,當清潔裝置500吸附於光罩靜電座306且經過時間TN時,將清潔裝置500與光罩靜電座306分離。 Referring to FIGS. 6A, 6B, and 7C, the semiconductor wafer processing method 650 further includes an operation 612 of detecting and determining whether the surface of the photomask electrostatic pad 306 needs cleaning. If the detecting means 316 judges that the surface of the photomask electrostatic pad 306 needs to be cleaned ("Ye" as shown in Figs. 6A, 6B), operations 614, 616, 618 are sequentially performed. In operation 614, the cleaning device 500 is placed in the reticle electrostatic mount 306. In operation 616, the polymeric material layer 220 of the cleaning device 500 is adsorbed to the reticle electrostatic mount 306 through the reticle electrostatic mount 306. In operation 616, when the cleaning device 500 is attracted to the reticle electrostatic mount 306 and the time TN elapses, the cleaning device 500 is separated from the reticle electrostatic mount 306.

在一些實施例中,半導體晶圓加工方法650的操作614、616、618的執行方式分別相同或類似於第5圖所示之半導體晶圓加工系統之清潔方法的操作502、504、508,因而在此不再重複敘述。 In some embodiments, operations 614, 616, 618 of semiconductor wafer processing method 650 are performed the same or similar to operations 502, 504, 508 of the semiconductor wafer processing system cleaning method illustrated in FIG. 5, respectively. The description will not be repeated here.

在一些實施例中,在操作508完成後,再次執行半導體晶圓加工方法650的操作612,利用檢測裝置316偵測且判斷光罩靜電座306表面是否需要清潔。若檢測裝置316判斷光罩靜電座306表面需要被清潔(如第6A、6B圖所示的”是”),則控制器312將操作506中的時間TN改為時間TN+1(亦即將指標N的數值加1)並且再次執行操作614、616、618。並且,在操作618中,當清潔裝置500吸附於光罩靜電座306且經過時間T1(亦即指標N的數值加1)時,將清潔裝置500與光罩靜電座306分離,以此類推。在一些實施例中,時間T0為一第一時間(長度),而時間T1為一第二時間(長度),且時間T1的長度大於時間T0。半 導體晶圓加工方法650可藉由再次執行操作614、616、618且延長清潔裝置500吸附於光罩靜電座306的時間,增加清潔裝置500之聚合物材料層220被擠壓的程度,使污染物更容易被黏附或嵌入於清潔裝置500之聚合物材料層220中,藉此進一步清除尚未從光罩靜電座306移除的污染物309。 In some embodiments, after operation 508 is completed, operation 612 of semiconductor wafer processing method 650 is performed again, with detection device 316 detecting and determining whether the surface of reticle electrostatic mount 306 requires cleaning. If the detecting means 316 determines that the surface of the reticle electrostatic seat 306 needs to be cleaned ("Ye" as shown in Figs. 6A, 6B), the controller 312 changes the time T N in operation 506 to time T N+1 (also That is, the value of the index N is incremented by 1) and operations 614, 616, 618 are performed again. And, at operation 618, when the cleaning apparatus 500 and the reticle electrostatic adsorption seat 306 the elapsed time T 1 (i.e., the numerical index N plus 1), the cleaning means 500 is separated from the electrostatic reticle base 306, and so on . In some embodiments, time T 0 is a first time (length), and time T 1 is a second time (length), and the length of time T 1 is greater than time T 0 . The semiconductor wafer processing method 650 can increase the extent to which the polymer material layer 220 of the cleaning device 500 is squeezed by performing operations 614, 616, 618 again and extending the time that the cleaning device 500 is attracted to the reticle electrostatic mount 306. The material is more easily adhered or embedded in the layer of polymeric material 220 of the cleaning device 500, thereby further removing contaminants 309 that have not been removed from the photomask electrostatic mount 306.

請同時參考第6A、6B、7D、7E圖,若執行半導體晶圓加工方法650的操作612,判斷光罩靜電座306表面不需要被清潔(如第6A、6B圖所示的”否”),則執行半導體晶圓加工方法650的操作620,將一反射光罩700吸附於光罩靜電座306,且當反射光罩700吸附於光罩靜電座306後,將另一半導體晶圓230放置於晶圓座314上方,且對另一半導體晶圓230進行第二半導體製程,以及進行上述第二半導體製程之後,將反射光罩700與光罩靜電座306分離,且將另一半導體晶圓230與晶圓座314分離。 Referring to FIGS. 6A, 6B, 7D, and 7E, if the operation 612 of the semiconductor wafer processing method 650 is performed, it is determined that the surface of the photomask electrostatic pad 306 does not need to be cleaned (as shown in FIGS. 6A and 6B). Then, the operation 620 of the semiconductor wafer processing method 650 is performed, a reflective mask 700 is adsorbed to the photomask electrostatic mount 306, and after the reflective mask 700 is adsorbed to the photomask electrostatic mount 306, another semiconductor wafer 230 is placed. After the second semiconductor process is performed on the other semiconductor wafer 230 and after the second semiconductor process is performed, the reflective mask 700 is separated from the photomask electrostatic pad 306, and another semiconductor wafer is separated. 230 is separated from wafer holder 314.

在一些實施例中,第二半導體製程為一微影製程(例如EUV微影製程),可利用射線源304進行上述第二半導體製程。在一些實施例中,射線源304包括一極紫外光(EUV)光源,射線源304在進行第二半導體製程(微影製程)期間用以產生極紫外光光線L對另一半導體晶圓320曝光。並且,在進行第二半導體製程(微影製程)期間,可藉由一反光器(圖未顯示)將射線源304產生的極紫外光光線L導向反射光罩700,反射光罩700會將極紫外光光線L反射至半導體晶圓320,且可利用一投影光學模組(圖未顯示)將反射光罩700的圖案映像(image)至吸附於晶圓座314上的半導體晶圓320以對半導體晶圓320曝光。進行 上述微影製程之後,射線源304停止產生極紫外光光線L。在一些實施例中,反射光罩700的構造、功能和材質相同或類似於如第2圖所示的反射光罩700,因而在此不再重複敘述。 In some embodiments, the second semiconductor process is a lithography process (eg, an EUV lithography process), and the second semiconductor process can be performed using the radiation source 304. In some embodiments, the source 304 includes an extreme ultraviolet (EUV) source that is used to generate extreme ultraviolet light L to expose another semiconductor wafer 320 during a second semiconductor process (lithography process). . Moreover, during the second semiconductor process (lithography process), the extreme ultraviolet light L generated by the radiation source 304 can be directed to the reflective mask 700 by a reflector (not shown), and the reflective mask 700 will be extremely The ultraviolet light L is reflected to the semiconductor wafer 320, and a projection optical module (not shown) can be used to image the pattern of the reflective mask 700 to the semiconductor wafer 320 adsorbed on the wafer holder 314. The semiconductor wafer 320 is exposed. After the above lithography process, the source 304 stops generating the extreme ultraviolet light L. In some embodiments, the configuration, function, and material of the reflective mask 700 are the same or similar to the reflective mask 700 as shown in FIG. 2, and thus will not be repeated here.

請參考第6A、6B、7E圖,將反射光罩700與光罩靜電座306分離,且將另一半導體晶圓230與晶圓座314分離後,執行操作622,利用控制器312將操作618中的時間TN恢復為預設值(指標N的預設值為0,亦即時間TN的預設值為時間T0)。在操作510中,在將反射光罩700和另一半導體晶圓230分別與光罩靜電座306分離,且經過間隔時間T時,再次執行操作602、604、606、608、610和612。若執行操作612後,檢測裝置316判斷光罩靜電座306表面需要被清潔(如第6A、6B圖所示的”是”),則再次依序執行操作614、616、618,且在操作616中,當清潔裝置500吸附於光罩靜電座306且經過時間TN(例如為時間T0)時,將清潔裝置500與光罩靜電座306分離。 Referring to FIGS. 6A, 6B, and 7E, the reflective mask 700 is separated from the mask electrostatic mount 306, and after the other semiconductor wafer 230 is separated from the wafer holder 314, operation 622 is performed, and operation 618 is performed by controller 312. The time T N in the recovery is restored to a preset value (the preset value of the indicator N is 0, that is, the preset value of the time T N is the time T 0 ). In operation 510, when the reflective mask 700 and the other semiconductor wafer 230 are separated from the photomask electrostatic mount 306, respectively, and the interval time T elapses, operations 602, 604, 606, 608, 610, and 612 are performed again. If the detecting device 316 determines that the surface of the photomask electrostatic pad 306 needs to be cleaned (as shown in FIGS. 6A, 6B) after performing operation 612, operations 614, 616, 618 are performed sequentially, and at operation 616. In the meantime, when the cleaning device 500 is attracted to the reticle electrostatic mount 306 and the time T N (for example, time T 0 ) elapses, the cleaning device 500 is separated from the reticle electrostatic mount 306.

在一些實施例中,在執行半導體晶圓加工方法650的操作622後及再次執行操作602之前,可再次執行半導體晶圓加工方法650的操作612,利用檢測裝置316偵測且判斷光罩靜電座306表面是否需要清潔。若檢測裝置316判斷光罩靜電座306表面需要被清潔(如第6A、6B圖所示的”是”),則控制器312將操作506中的時間TN改為時間TN+1(亦即將指標N的數值加1)並且再次執行操作614、616、618。若執行半導體晶圓加工方法650的操作612,判斷光罩靜電座306表面不需要被清潔(如第6A、6B圖所示的”否”),則執行操作602。 In some embodiments, after operation 622 of semiconductor wafer processing method 650 is performed and operation 602 is performed again, operation 612 of semiconductor wafer processing method 650 can be performed again, with detection device 316 detecting and determining the mask electrostatic mount. 306 Whether the surface needs cleaning. If the detecting means 316 determines that the surface of the reticle electrostatic seat 306 needs to be cleaned ("Ye" as shown in Figs. 6A, 6B), the controller 312 changes the time T N in operation 506 to time T N+1 (also That is, the value of the index N is incremented by 1) and operations 614, 616, 618 are performed again. If the operation 612 of the semiconductor wafer processing method 650 is performed, it is determined that the surface of the photomask electrostatic pad 306 does not need to be cleaned ("NO" as shown in FIGS. 6A, 6B), then operation 602 is performed.

依據一些實施例之半導體晶圓加工方法650具有 以下優點。半導體晶圓加工系統600可利用包括聚合物材料層220和光罩部分230的清潔裝置500,在光罩靜電座306吸附清潔裝置500時,利用清潔裝置500的聚合物材料層220黏附光罩靜電座306的電極308上的污染物309,且同時利用清潔裝置500的光罩部分230對半導體晶圓進行微影製程。上述半導體晶圓加工方法650在清潔半導體晶圓加工系統600的光罩靜電座306時不需將半導體晶圓加工系統600離線(off-line)停機且破壞真空腔室302的真空環境以清潔光罩靜電座306,因此不需耗費恢復真空環境的作業時間,可大為提升半導體製程的效率。 The semiconductor wafer processing method 650 in accordance with some embodiments has the following advantages. The semiconductor wafer processing system 600 can utilize a cleaning device 500 including a layer of polymer material 220 and a reticle portion 230. When the reticle electrostatic holder 306 is attracted to the cleaning device 500, the reticle mount is adhered by the polymer material layer 220 of the cleaning device 500. The contaminants 309 on the electrodes 308 of 306, and simultaneously lithographically processing the semiconductor wafer using the mask portion 230 of the cleaning device 500. The semiconductor wafer processing method 650 described above eliminates the need to off-line the semiconductor wafer processing system 600 and destroy the vacuum environment of the vacuum chamber 302 to clean the light when cleaning the mask electrostatic mount 306 of the semiconductor wafer processing system 600. The electrostatic seat 306 is covered, so that it is not necessary to recover the working time of the vacuum environment, and the efficiency of the semiconductor process can be greatly improved.

本揭露書之實施例提供一種半導體晶圓加工系統之清潔方法550、一種半導體晶圓加工方法650與一種半導體晶圓加工系統600。在一些實施例中,上述半導體晶圓加工系統之清潔方法550包括在一真空腔室302中,將一清潔裝置500(包括第1A、1B圖所示的清潔裝置500A、500B)放置於一光罩靜電座306上方。上述半導體晶圓加工系統之清潔方法550包括透過上述光罩靜電座306將上述清潔裝置500之一聚合物材料層220吸附於上述光罩靜電座306。上述半導體晶圓加工系統之清潔方法550包括當上述清潔裝置500吸附於上述光罩靜電座306且經過一第一時間TN時,將上述清潔裝置500與上述光罩靜電座306分離。上述半導體晶圓加工系統之清潔方法550可應用於半導體晶圓加工系統600(第2圖),例如為極紫外光(EUV)微影系統。在一些實施例中,其可將與極紫外光(EUV)光罩(光罩部分230)整合的清潔裝置500吸附於半導體晶圓加工系統600的光罩靜電座306上,清潔裝置500的聚合物材料層220可黏附位於 光罩靜電座306的電極308上的污染物309(例如CrN、TaB等光罩基材微粒)。因此,當清潔裝置500與光罩靜電座306分離時,可同時將上述污染物309帶離上述光罩靜電座306的吸附面307,進而達成清潔光罩靜電座306的效果。上述半導體晶圓加工系統之清潔方法550在清潔半導體晶圓加工系統600的光罩靜電座306時不需將半導體晶圓加工系統600離線(off-line)停機且破壞真空腔室302的真空環境以清潔光罩靜電座306,因此可大為節省清潔光罩靜電座306的時間,且可大為提升半導體製程的效率。 Embodiments of the present disclosure provide a method 550 of cleaning a semiconductor wafer processing system, a semiconductor wafer processing method 650, and a semiconductor wafer processing system 600. In some embodiments, the cleaning method 550 of the semiconductor wafer processing system described above includes placing a cleaning device 500 (including the cleaning devices 500A, 500B shown in FIGS. 1A, 1B) in a vacuum chamber 302. The cover is over the electrostatic seat 306. The cleaning method 550 of the semiconductor wafer processing system includes adsorbing a polymer material layer 220 of the cleaning device 500 to the mask electrostatic mount 306 through the mask electrostatic mount 306. The cleaning method 550 of the semiconductor wafer processing system includes separating the cleaning device 500 from the mask electrostatic mount 306 when the cleaning device 500 is attracted to the mask electrostatic mount 306 and passes a first time TN . The above described semiconductor wafer processing system cleaning method 550 can be applied to a semiconductor wafer processing system 600 (Fig. 2), such as an extreme ultraviolet (EUV) lithography system. In some embodiments, the cleaning device 500 integrated with an extreme ultraviolet (EUV) reticle (mask portion 230) can be adsorbed onto the reticle electrostatic mount 306 of the semiconductor wafer processing system 600, the polymerization of the cleaning device 500. The material layer 220 can adhere to contaminants 309 (eg, mask base particles such as CrN, TaB, etc.) located on the electrodes 308 of the reticle electrostatic mount 306. Therefore, when the cleaning device 500 is separated from the photomask electrostatic pad 306, the contaminant 309 can be simultaneously removed from the adsorption surface 307 of the photomask electrostatic pad 306, thereby achieving the effect of cleaning the photomask electrostatic pad 306. The cleaning method 550 of the semiconductor wafer processing system described above eliminates the need to off-line the semiconductor wafer processing system 600 and destroy the vacuum environment of the vacuum chamber 302 when cleaning the mask electrostatic mount 306 of the semiconductor wafer processing system 600. In order to clean the reticle electrostatic seat 306, the time for cleaning the reticle electrostatic seat 306 can be greatly saved, and the efficiency of the semiconductor process can be greatly improved.

本揭露書之實施例提供一種半導體晶圓加工系統之清潔方法、一種半導體晶圓加工方法與一種半導體晶圓加工系統。上述半導體晶圓加工系統之清潔方法包括在一真空腔室中,將一清潔裝置放置於一光罩靜電座上方。透過上述光罩靜電座將上述清潔裝置之一聚合物材料層吸附於上述光罩靜電座。當上述清潔裝置吸附於上述光罩靜電座且經過一第一時間時,將上述清潔裝置與上述光罩靜電座分離。上述半導體晶圓加工系統之清潔方法可應用於極紫外光微影系統。上述半導體晶圓加工系統之清潔方法使用與極紫外光光罩整合的清潔裝置,在維持微影製程的真空環境下,利用光罩靜電座吸附清潔裝置。上述半導體晶圓加工系統之清潔方法可使用清潔裝置的聚合物材料層黏附光罩靜電座電極上的污染物,且同時利用清潔裝置的光罩部分對半導體晶圓進行微影製程。可大為節省清潔光罩靜電座的時間,且可大為提升半導體製程的效率。 Embodiments of the present disclosure provide a method of cleaning a semiconductor wafer processing system, a semiconductor wafer processing method, and a semiconductor wafer processing system. The cleaning method of the above semiconductor wafer processing system includes placing a cleaning device over a photomask electrostatic mount in a vacuum chamber. A polymer material layer of one of the cleaning devices is adsorbed to the photomask electrostatic pad through the photomask electrostatic pad. The cleaning device is separated from the photomask electrostatic seat when the cleaning device is adsorbed to the photomask electrostatic seat for a first time. The cleaning method of the above semiconductor wafer processing system can be applied to an extreme ultraviolet lithography system. The cleaning method of the above semiconductor wafer processing system uses a cleaning device integrated with an extreme ultraviolet ray mask to adsorb the cleaning device by using a reticle electrostatic seat in a vacuum environment that maintains the lithography process. The cleaning method of the above semiconductor wafer processing system can use the polymer material layer of the cleaning device to adhere the contaminants on the reticle electrostatic seat electrode, and at the same time, lithographically process the semiconductor wafer by using the reticle portion of the cleaning device. It can greatly save the time of cleaning the reticle electrostatic seat, and can greatly improve the efficiency of the semiconductor process.

根據一些實施例,提供一種半導體晶圓加工系統 之清潔方法。上述半導體晶圓加工系統之清潔方法包括在一真空腔室中,將一清潔裝置放置於一光罩靜電座上方。上述半導體晶圓加工系統之清潔方法還包括透過上述光罩靜電座將上述清潔裝置之一聚合物材料層吸附於上述光罩靜電座。上述半導體晶圓加工系統之清潔方法更包括當上述清潔裝置吸附於上述光罩靜電座且經過一第一時間時,將上述清潔裝置與上述光罩靜電座分離。 In accordance with some embodiments, a method of cleaning a semiconductor wafer processing system is provided. The cleaning method of the above semiconductor wafer processing system includes placing a cleaning device over a photomask electrostatic mount in a vacuum chamber. The method of cleaning a semiconductor wafer processing system further includes adsorbing a polymer material layer of the cleaning device to the photomask electrostatic pad through the photomask electrostatic pad. The cleaning method of the semiconductor wafer processing system further includes separating the cleaning device from the photomask electrostatic pad when the cleaning device is adsorbed to the photomask electrostatic pad and passes a first time.

在一些實施例中,上述半導體晶圓加工系統之清潔方法包括當上述清潔裝置吸附於上述光罩靜電座之後,將一半導體晶圓放置於一晶圓座上方。上述半導體晶圓加工系統之清潔方法還包括利用一射線源進行一微影製程,在進行上述微影製程期間上述射線源用以產生極紫外光線,以對上述半導體晶圓曝光。 In some embodiments, the cleaning method of the semiconductor wafer processing system includes placing a semiconductor wafer over a wafer holder after the cleaning device is adsorbed to the photomask electrostatic mount. The method for cleaning a semiconductor wafer processing system further includes performing a lithography process using a ray source for generating extreme ultraviolet light during exposure of the lithography process to expose the semiconductor wafer.

在一些實施例中,上述半導體晶圓加工系統之清潔方法包括在將上述清潔裝置與上述光罩靜電座分離後,判斷上述光罩靜電座表面是否需要被清潔。上述半導體晶圓加工系統之清潔方法還包括若上述光罩靜電座表面需要被清潔,則將上述清潔裝置放置於上述光罩靜電座上方,透過上述光罩靜電座將上述清潔裝置之上述聚合物材料層吸附於上述光罩靜電座,以及當上述清潔裝置吸附於上述光罩靜電座且經過一第二時間時,將上述清潔裝置與上述光罩靜電座分離。上述半導體晶圓加工系統之清潔方法更包括上述第二時間大於上述第一時間。 In some embodiments, the cleaning method of the semiconductor wafer processing system includes determining whether the surface of the reticle electrostatic seat needs to be cleaned after separating the cleaning device from the reticle electrostatic mount. The cleaning method of the semiconductor wafer processing system further includes: if the surface of the photomask electrostatic seat needs to be cleaned, placing the cleaning device above the photomask electrostatic seat, and passing the polymer of the cleaning device through the photomask electrostatic seat The material layer is adsorbed to the photomask electrostatic mount, and the cleaning device is separated from the photomask electrostatic mount when the cleaning device is adsorbed to the photomask electrostatic mount for a second time. The cleaning method of the semiconductor wafer processing system further includes the second time being greater than the first time.

在一些實施例中,上述半導體晶圓加工系統之清 潔方法包括若上述光罩靜電座表面不需要被清潔,則在上述清潔裝置與上述光罩靜電座分離且經過一間隔時間時,將上述清潔裝置放置於上述光罩靜電座上方,透過上述光罩靜電座將上述清潔裝置之上述聚合物材料層吸附於上述光罩靜電座,以及當上述清潔裝置吸附於上述光罩靜電座且經過上述第一時間時,將上述清潔裝置與上述光罩靜電座分離。 In some embodiments, the cleaning method of the semiconductor wafer processing system includes: if the reticle electrostatic seat surface does not need to be cleaned, the cleaning is performed when the cleaning device is separated from the reticle electrostatic seat and passes an interval time. The device is placed above the photomask electrostatic seat, and the polymer material layer of the cleaning device is adsorbed to the photomask electrostatic seat through the photomask electrostatic seat, and the cleaning device is adsorbed to the photomask electrostatic seat and passes through the above For a time, the cleaning device is separated from the photomask electrostatic seat.

根據一些實施例,提供一種半導體晶圓加工方法。上述半導體晶圓加工方法包括在一真空腔室中,將一清潔裝置放置於一光罩靜電座上方。上述半導體晶圓加工方法還包括透過上述光罩靜電座將上述清潔裝置之一聚合物材料層吸附於上述光罩靜電座。上述半導體晶圓加工方法更包括當上述清潔裝置吸附於上述光罩靜電座後,將一半導體晶圓放置於一晶圓座上方。上述半導體晶圓加工方法又包括對上述半導體晶圓進行一第一半導體製程。上述半導體晶圓加工方法再包括進行上述第一半導體製程之後,將上述清潔裝置與上述光罩靜電座分離,且將上述半導體晶圓與上述晶圓座分離。 In accordance with some embodiments, a semiconductor wafer processing method is provided. The semiconductor wafer processing method includes placing a cleaning device over a photomask electrostatic mount in a vacuum chamber. The semiconductor wafer processing method further includes adsorbing a polymer material layer of one of the cleaning devices to the photomask electrostatic pad through the photomask electrostatic pad. The semiconductor wafer processing method further includes placing a semiconductor wafer over a wafer holder after the cleaning device is adsorbed to the photomask electrostatic pad. The semiconductor wafer processing method further includes performing a first semiconductor process on the semiconductor wafer. The semiconductor wafer processing method further includes separating the cleaning device from the photomask electrostatic pad and separating the semiconductor wafer from the wafer holder after performing the first semiconductor process.

在一些實施例中,上述半導體晶圓加工方法包括在將上述清潔裝置與上述光罩靜電座分離後,判斷上述光罩靜電座表面是否需要被清潔。上述半導體晶圓加工方法還包括若上述光罩靜電座表面需要被清潔,則將上述清潔裝置放置於上述光罩靜電座上方,透過上述光罩靜電座將上述清潔裝置之上述聚合物材料層吸附於上述光罩靜電座,以及當上述清潔裝置吸附於上述光罩靜電座且經過一第一時間時,將上述清潔裝置與上述光罩靜電座分離。上述半導體晶圓加工方法更包括若上 述光罩靜電座表面不需要被清潔,則將一反射光罩吸附於上述光罩靜電座,且當上述反射光罩吸附於上述光罩靜電座後,將另一半導體晶圓放置於上述晶圓座,且對上述另一半導體晶圓進行一第二半導體製程,以及進行上述第二半導體製程之後,將上述反射光罩與上述光罩靜電座分離,且將上述另一半導體晶圓與上述晶圓座分離。 In some embodiments, the semiconductor wafer processing method includes determining whether the surface of the photomask electrostatic pad needs to be cleaned after separating the cleaning device from the photomask electrostatic pad. The semiconductor wafer processing method further includes: if the surface of the photomask electrostatic seat needs to be cleaned, placing the cleaning device above the photomask electrostatic seat, and adsorbing the polymer material layer of the cleaning device through the photomask electrostatic seat And the cleaning device is separated from the photomask electrostatic seat when the cleaning device is adsorbed to the photomask electrostatic seat and a first time passes. The semiconductor wafer processing method further includes: if the surface of the photomask electrostatic seat does not need to be cleaned, adsorbing a reflective mask to the photomask electrostatic seat, and when the reflective mask is adsorbed to the photomask electrostatic seat, And placing another semiconductor wafer on the wafer holder, performing a second semiconductor process on the another semiconductor wafer, and performing the second semiconductor process, separating the reflective mask from the photomask electrostatic mount, and The other semiconductor wafer is separated from the wafer holder.

在一些實施例中,上述半導體晶圓加工方法包括在將上述清潔裝置與上述光罩靜電座分離後,判斷上述光罩靜電座表面是否需要被清潔。上述半導體晶圓加工方法還包括若上述光罩靜電座表面需要被清潔,則將上述清潔裝置放置於上述光罩靜電座上方,透過上述光罩靜電座將上述清潔裝置之上述聚合物材料層吸附於上述光罩靜電座,以及當上述清潔裝置吸附於上述光罩靜電座且經過一第二時間時,將上述清潔裝置與上述光罩靜電座分離。上述半導體晶圓加工方法更包括上述第二時間大於上述第一時間。 In some embodiments, the semiconductor wafer processing method includes determining whether the surface of the photomask electrostatic pad needs to be cleaned after separating the cleaning device from the photomask electrostatic pad. The semiconductor wafer processing method further includes: if the surface of the photomask electrostatic seat needs to be cleaned, placing the cleaning device above the photomask electrostatic seat, and adsorbing the polymer material layer of the cleaning device through the photomask electrostatic seat And the cleaning device is separated from the photomask electrostatic seat when the cleaning device is adsorbed to the photomask electrostatic seat for a second time. The semiconductor wafer processing method further includes the second time being greater than the first time.

根據一些實施例,提供一種半導體晶圓加工系統。上述半導體晶圓加工系統包括一真空腔室、一第一清潔裝置、一光罩靜電座、一傳送裝置和一控制器。上述第一清潔裝置設置於上述真空腔室內。上述第一清潔裝置包括一第一基板、一反射結構、一保護層、一吸收層、一導電層和一第一聚合物材料層。上述第一基板的材質包括一低熱膨脹材料。上述反射結構設置於上述基板的一前側表面上方。上述保護層設置於上述反射結構上方。上述吸收層設置於上述保護層上方。上述導電層設置於上述基板的一後側表面上方。上述第一聚合物 材料層,設置於上述導電層上方。上述光罩靜電座設置於上述真空腔室內。上述傳送裝置設置於上述真空腔室內以選擇性地將上述第一清潔裝置放置於上述光罩靜電座上方。上述控制器設置於上述真空腔室內以控制上述光罩靜電座與上述傳送裝置。上述光罩靜電座透過靜電吸附上述第一清潔裝置。 In accordance with some embodiments, a semiconductor wafer processing system is provided. The semiconductor wafer processing system includes a vacuum chamber, a first cleaning device, a photomask electrostatic mount, a transfer device, and a controller. The first cleaning device is disposed in the vacuum chamber. The first cleaning device includes a first substrate, a reflective structure, a protective layer, an absorbing layer, a conductive layer and a first polymer material layer. The material of the first substrate comprises a low thermal expansion material. The reflective structure is disposed above a front side surface of the substrate. The protective layer is disposed above the reflective structure. The absorbing layer is disposed above the protective layer. The conductive layer is disposed above a rear side surface of the substrate. The first polymer material layer is disposed above the conductive layer. The photomask electrostatic mount is disposed in the vacuum chamber. The transfer device is disposed in the vacuum chamber to selectively place the first cleaning device above the photomask electrostatic seat. The controller is disposed in the vacuum chamber to control the reticle electrostatic mount and the transfer device. The photomask electrostatic seat is electrostatically attracted to the first cleaning device.

在一些實施例中,上述半導體晶圓加工系統包括一極紫外光光源,設置於上述真空腔室內且用於進行一微影製程,在進行上述微影製程期間上述射線源用以產生極紫外光線,以對一半導體晶圓曝光。 In some embodiments, the semiconductor wafer processing system includes an extreme ultraviolet light source disposed in the vacuum chamber for performing a lithography process, wherein the radiation source is used to generate extreme ultraviolet light during the lithography process. To expose a semiconductor wafer.

在一些實施例中,上述半導體晶圓加工系統包括一第二清潔裝置,設置於上述真空腔室內。上述第二清潔裝置包括一第二基板、一第一金屬層、一第二金屬層、一第一金屬層、一第二金屬層和一第二聚合物材料層。上述第二基板的材質包括矽。上述第一金屬層和上述第二金屬層分別設置於上述第二基板的一前側表面上方和一後側表面上方。上述第一金屬層和上述第二金屬層分別設置於上述第一金屬層上方和上述第二金屬層上方。上述第二聚合物材料層,設置於上述基板的上述後側表面上方,且位於上述第二保護層上方。上述光罩靜電座透過靜電吸附上述第二清潔裝置。 In some embodiments, the semiconductor wafer processing system includes a second cleaning device disposed within the vacuum chamber. The second cleaning device includes a second substrate, a first metal layer, a second metal layer, a first metal layer, a second metal layer and a second polymer material layer. The material of the second substrate includes ruthenium. The first metal layer and the second metal layer are respectively disposed above a front side surface and a rear side surface of the second substrate. The first metal layer and the second metal layer are respectively disposed above the first metal layer and above the second metal layer. The second polymer material layer is disposed above the rear side surface of the substrate and above the second protective layer. The photomask electrostatic seat is electrostatically attracted to the second cleaning device.

前述內文概述了許多實施例的特徵,使本技術領域中具有通常知識者可以從各個方面更佳地了解本揭露。本技術領域中具有通常知識者應可理解,且可輕易地以本揭露為基礎來設計或修飾其他製程及結構,並以此達到相同的目的及/或達到與在此介紹的實施例等相同之優點。本技術領域中具有 通常知識者也應了解這些相等的結構並未背離本揭露的發明精神與範圍。在不背離本揭露的發明精神與範圍之前提下,可對本揭露進行各種改變、置換或修改。 The foregoing summary of the invention is inferred by the claims It will be understood by those of ordinary skill in the art, and other processes and structures may be readily designed or modified on the basis of the present disclosure, and thus achieve the same objectives and/or achieve the same embodiments as those described herein. The advantages. Those of ordinary skill in the art should also understand that such equivalent structures do not depart from the spirit and scope of the invention. Various changes, permutations, or alterations may be made in the present disclosure without departing from the spirit and scope of the invention.

Claims (10)

一種半導體晶圓加工系統之清潔方法,包括下列步驟:在一真空腔室中,將一清潔裝置放置於一光罩靜電座上方;將該清潔裝置之一聚合物材料層吸附於該光罩靜電座;以及當該清潔裝置吸附於該光罩靜電座且經過一第一時間時,將該清潔裝置與該光罩靜電座分離。  A cleaning method for a semiconductor wafer processing system, comprising the steps of: placing a cleaning device over a photomask electrostatic seat in a vacuum chamber; adsorbing a polymer material layer of the cleaning device to the photomask static electricity And the cleaning device is separated from the reticle electrostatic seat when the cleaning device is attracted to the reticle electrostatic seat and passes a first time.   如申請專利範圍第1項所述之半導體晶圓加工系統之清潔方法,更包括:當該清潔裝置吸附於該光罩靜電座之後,將一半導體晶圓放置於一晶圓座上方;以及利用一射線源進行一微影製程,在進行該微影製程期間該射線源用以產生極紫外光線,以對該半導體晶圓曝光。  The method for cleaning a semiconductor wafer processing system according to claim 1, further comprising: placing a semiconductor wafer over a wafer holder after the cleaning device is adsorbed to the photomask electrostatic seat; and utilizing A ray source performs a lithography process for generating extreme ultraviolet light during exposure of the lithography process to expose the semiconductor wafer.   如申請專利範圍第2項所述之半導體晶圓加工系統之清潔方法,更包括:在將該清潔裝置與該光罩靜電座分離後,判斷該光罩靜電座表面是否需要被清潔;以及若該光罩靜電座表面需要被清潔,則將該清潔裝置放置於該光罩靜電座上方,透過該光罩靜電座將該清潔裝置之該聚合物材料層吸附於該光罩靜電座,以及當該清潔裝置吸附於該光罩靜電座且經過一第二時間時,將該清潔裝置與該光罩靜電座分離;其中,該第二時間大於該第一時間。  The cleaning method of the semiconductor wafer processing system of claim 2, further comprising: after separating the cleaning device from the photomask electrostatic seat, determining whether the surface of the photomask electrostatic seat needs to be cleaned; The surface of the reticle electrostatic seat needs to be cleaned, and the cleaning device is placed above the reticle electrostatic seat, and the polymer material layer of the cleaning device is adsorbed to the reticle electrostatic seat through the reticle electrostatic seat, and when The cleaning device is detached from the reticle electrostatic seat and separated from the reticle electrostatic seat by a second time; wherein the second time is greater than the first time.   如申請專利範圍第3項所述之半導體晶圓加工系統之清潔 方法,更包括:若該光罩靜電座表面不需要被清潔,則在該清潔裝置與該光罩靜電座分離且經過一間隔時間時,將該清潔裝置放置於該光罩靜電座上方,透過該光罩靜電座將該清潔裝置之該聚合物材料層吸附於該光罩靜電座,以及當該清潔裝置吸附於該光罩靜電座且經過該第一時間時,將該清潔裝置與該光罩靜電座分離。  The cleaning method of the semiconductor wafer processing system of claim 3, further comprising: if the surface of the photomask electrostatic seat does not need to be cleaned, the cleaning device is separated from the photomask electrostatic seat and passes through an interval. When the time is up, the cleaning device is placed above the photomask electrostatic seat, and the polymer material layer of the cleaning device is adsorbed to the photomask electrostatic seat through the photomask electrostatic seat, and when the cleaning device is adsorbed to the photomask When the electrostatic seat passes the first time, the cleaning device is separated from the photomask electrostatic seat.   一種半導體晶圓加工方法,包括下列步驟:在一真空腔室中,將一清潔裝置放置於一光罩靜電座上方;透過該光罩靜電座將該清潔裝置之一聚合物材料層吸附於該光罩靜電座;當該清潔裝置吸附於該光罩靜電座後,將一半導體晶圓放置於一晶圓座上方;對該半導體晶圓進行一第一半導體製程;以及進行該第一半導體製程之後,將該清潔裝置與該光罩靜電座分離,且將該半導體晶圓與該晶圓座分離。  A semiconductor wafer processing method comprising the steps of: placing a cleaning device over a photomask electrostatic mount in a vacuum chamber; and adsorbing a polymer material layer of the cleaning device through the photomask electrostatic mount a photomask electrostatic seat; after the cleaning device is adsorbed to the photomask electrostatic mount, placing a semiconductor wafer over a wafer holder; performing a first semiconductor process on the semiconductor wafer; and performing the first semiconductor process Thereafter, the cleaning device is separated from the photomask electrostatic mount, and the semiconductor wafer is separated from the wafer holder.   如申請專利範圍第5項所述之半導體晶圓加工方法,更包括:在將該清潔裝置與該光罩靜電座分離後,判斷該光罩靜電座表面是否需要被清潔;若該光罩靜電座表面需要被清潔,則將該清潔裝置放置於該光罩靜電座上方,透過該光罩靜電座將該清潔裝置之該聚合物材料層吸附於該光罩靜電座,以及當該清潔裝置吸附於該光罩靜電座且經過一第一時間時,將該清潔裝置與 該光罩靜電座分離;以及若該光罩靜電座表面不需要被清潔,則將一反射光罩吸附於該光罩靜電座,且當該反射光罩吸附於該光罩靜電座後,將另一半導體晶圓放置於該晶圓座,且對該另一半導體晶圓進行一第二半導體製程,以及進行該第二半導體製程之後,將該反射光罩與該光罩靜電座分離,且將該另一半導體晶圓與該晶圓座分離。  The semiconductor wafer processing method of claim 5, further comprising: after separating the cleaning device from the photomask electrostatic seat, determining whether the surface of the photomask electrostatic seat needs to be cleaned; if the photomask is electrostatically The surface of the seat needs to be cleaned, and the cleaning device is placed above the reticle electrostatic seat, and the polymer material layer of the cleaning device is adsorbed to the reticle electrostatic seat through the reticle electrostatic seat, and when the cleaning device is adsorbed Separating the cleaning device from the reticle electrostatic seat when the reticle electrostatic seat passes a first time; and if the reticle electrostatic seat surface does not need to be cleaned, attaching a reflective reticle to the reticle An electrostatic holder, and after the reflective mask is adsorbed to the photomask electrostatic mount, another semiconductor wafer is placed on the wafer holder, and a second semiconductor process is performed on the other semiconductor wafer, and the After the semiconductor process, the reflective mask is separated from the photomask electrostatic mount, and the other semiconductor wafer is separated from the wafer holder.   如申請專利範圍第6項所述之半導體晶圓加工方法,更包括:在將該清潔裝置與該光罩靜電座分離後,判斷該光罩靜電座表面是否需要被清潔;以及若該光罩靜電座表面需要被清潔,則將該清潔裝置放置於該光罩靜電座上方,透過該光罩靜電座將該清潔裝置之該聚合物材料層吸附於該光罩靜電座,以及當該清潔裝置吸附於該光罩靜電座且經過一第二時間時,將該清潔裝置與該光罩靜電座分離;其中,該第二時間大於該第一時間。  The semiconductor wafer processing method of claim 6, further comprising: after separating the cleaning device from the reticle electrostatic seat, determining whether the reticle surface of the reticle needs to be cleaned; and if the reticle The electrostatic seat surface needs to be cleaned, and the cleaning device is placed above the photomask electrostatic seat, and the polymer material layer of the cleaning device is adsorbed to the photomask electrostatic seat through the photomask electrostatic seat, and when the cleaning device is The cleaning device is separated from the photomask electrostatic seat when adsorbed to the photomask electrostatic seat and passes through a second time; wherein the second time is greater than the first time.   一種半導體晶圓加工系統,包括:一真空腔室;以及一第一清潔裝置,設置於該真空腔室內,且該第一清潔裝置包括:一第一基板,其中該第一基板的材質包括一低熱膨脹材料;一反射結構,設置於該基板的一前側表面上方;一保護層,設置於該反射結構上方; 一吸收層,設置於該保護層上方;一導電層,設置於該基板的一後側表面上方;一第一聚合物材料層,設置於該導電層上方;一光罩靜電座,設置於該真空腔室內;一傳送裝置,設置於該真空腔室內以選擇性地將該第一清潔裝置放置於該光罩靜電座上方;以及一控制器,設置於該真空腔室內以控制該光罩靜電座與該傳送裝置;其中該光罩靜電座透過靜電吸附該第一清潔裝置。  A semiconductor wafer processing system includes: a vacuum chamber; and a first cleaning device disposed in the vacuum chamber, and the first cleaning device includes: a first substrate, wherein the material of the first substrate comprises a a low thermal expansion material; a reflective structure disposed over a front side surface of the substrate; a protective layer disposed over the reflective structure; an absorbing layer disposed over the protective layer; a conductive layer disposed on the substrate a first polymer material layer disposed above the conductive layer; a photomask electrostatic seat disposed in the vacuum chamber; a transfer device disposed in the vacuum chamber to selectively apply the first A cleaning device is disposed above the reticle electrostatic seat; and a controller is disposed in the vacuum chamber to control the reticle electrostatic seat and the conveying device; wherein the reticle electrostatic seat electrostatically adsorbs the first cleaning device.   如申請專利範圍第8項所述之半導體晶圓加工系統,更包括:一極紫外光光源,設置於該真空腔室內且用於進行一微影製程,在進行該微影製程期間該射線源用以產生極紫外光線,以對一半導體晶圓曝光。  The semiconductor wafer processing system of claim 8, further comprising: a monopolar ultraviolet light source disposed in the vacuum chamber and configured to perform a lithography process, the ray source during the lithography process Used to generate extreme ultraviolet light to expose a semiconductor wafer.   如申請專利範圍第8項所述之半導體晶圓加工系統,更包括:一第二清潔裝置,設置於該真空腔室內,且該第二清潔裝置包括:一第二基板,其中該第二基板的材質包括矽;一第一金屬層和一第二金屬層,分別設置於該第二基板的一前側表面上方和一後側表面上方;一第一保護層和一第二保護層,分別設置於該第一金屬層和該第二金屬層上方;以及一第二聚合物材料層,設置於該基板的該後側表面上方, 且位於該第二保護層上方;其中該光罩靜電座透過靜電吸附該第二清潔裝置。  The semiconductor wafer processing system of claim 8, further comprising: a second cleaning device disposed in the vacuum chamber, and the second cleaning device comprises: a second substrate, wherein the second substrate The material includes a crucible; a first metal layer and a second metal layer are respectively disposed above a front side surface and a rear side surface of the second substrate; a first protective layer and a second protective layer are respectively disposed Above the first metal layer and the second metal layer; and a second polymer material layer disposed above the rear side surface of the substrate and above the second protective layer; wherein the photomask electrostatic block passes through Electrostatically adsorbing the second cleaning device.  
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