TW201840921A - Thermo-shapeable fabrics and articles made therefrom - Google Patents

Thermo-shapeable fabrics and articles made therefrom Download PDF

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Publication number
TW201840921A
TW201840921A TW107110493A TW107110493A TW201840921A TW 201840921 A TW201840921 A TW 201840921A TW 107110493 A TW107110493 A TW 107110493A TW 107110493 A TW107110493 A TW 107110493A TW 201840921 A TW201840921 A TW 201840921A
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Taiwan
Prior art keywords
melting point
point temperature
cloth
low
yarn
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TW107110493A
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Chinese (zh)
Inventor
黃謙智
劉子煒
張禕駿
翁翎翔
吉耶梅特.波琳.馬里昂 羅格朗
卡蜜兒.珍妮 特謝爾
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小智研發股份有限公司
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Publication of TW201840921A publication Critical patent/TW201840921A/en

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    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44Yarns or threads characterised by the purpose for which they are designed
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/14Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/567Shapes or effects upon shrinkage
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/62Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/04Heat-responsive characteristics
    • D10B2401/041Heat-responsive characteristics thermoplastic; thermosetting

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Woven Fabrics (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Knitting Of Fabric (AREA)

Abstract

Disclosed herein are fabrics having different thermo-properties. The fabric is characterized in its structure by having a high melting temperature zone and a low melting temperature zone, which are respectively made up by yarns having high and low melting temperatures By having yarns of high and low temperatures in the fabric, in which the respective melting temperatures in the high and low melting temperature zones differ by about 30 DEG C to 150 DEG C; and the low melting temperature zone melts and eventually becomes harden after heat-activation, while the high melting temperature zone remains un-melted and soft after heat-activation.

Description

熱塑性布及以此熱塑性布製成的物件Thermoplastic cloth and articles made from the same

本揭示內容係關於紡織技術,特別是關於具有不同熱性質之布及以該布製成的3D物件。This disclosure relates to textile technology, and more particularly to cloths with different thermal properties and 3D objects made from the cloth.

傳統上,在織品工業中,熱可塑纖維常被用來形成可塑型的多層結構,其是由多層、熱可塑纖維層壓而成的紡織層(例如,不織布(non-woven fabric))。然而,尚未有人嘗試透過針織(Knit)或梭織(Weave)熱可塑纖維成為布料,進而產生一種具有熱可塑性質的織品。Traditionally, in the textile industry, thermoplastic fibers have often been used to form moldable multilayer structures, which are textile layers (e.g., non-woven fabrics) laminated from multiple layers of thermoplastic fibers. However, no one has attempted to use Knit or Weave thermoplastic fibers to become fabrics, thereby producing a fabric with thermoplastic properties.

本揭示內容之發明人意外發明了一種智慧型織品,藉由針織、梭織、刺繡等技術,將具有高及低熔點之紗線織成一種布料,因而使得布料纖維具有熱可塑性質,當所述布料在熱活化後,即能直接在布料上形成3D物件。The inventor of the present disclosure accidentally invented a smart fabric. By knitting, weaving, embroidery and other technologies, weaving yarns with high and low melting points into a cloth, so that the cloth fibers have thermoplastic properties. After the fabric is thermally activated, it can form 3D objects directly on the fabric.

以下內容旨在提供本揭示內容的簡化重點,以使閱讀者對本揭示內容具備基本的理解。此簡化重點並非本揭示內容的完整描述,且其用意並非在指出本發明實施例的重要/關鍵元件或界定本發明的範圍。此簡化重點之目的在於提供本揭示的部分扼要概念,以作為進一步於下述說明之序幕。The following is intended to provide a simplified focus of this disclosure so that readers will have a basic understanding of this disclosure. This simplified emphasis is not a complete description of the disclosure, and it is not intended to point out important / critical elements of the embodiments of the invention or to define the scope of the invention. The purpose of this simplified focus is to provide some of the key concepts of this disclosure as a prelude to further description below.

一般而言,本揭示內容係有關於直接從熱可塑性布形成具有經濟效益的紡織物件(例如墊肩、日型環扣(triglide buckle)、口袋等)。Generally speaking, the present disclosure is related to the formation of economically beneficial textile articles (such as shoulder pads, triglide buckles, pockets, etc.) directly from thermoplastic fabrics.

基於上述,本揭示內容之一目的在於提供具有不同熱性質的布。所述布在結構上包括一高熔點溫度區及一低熔點溫度區,分別由具有高熔點及低熔點的紗線所組成 ,其中,於所述高熔點溫度區及所述低熔點溫度區的熔點相差約 30℃至150℃之間,且所述低熔點溫度區之布在熱活化後會硬化,所述高熔點區之布在熱活化後仍維持柔軟。Based on the foregoing, it is an object of the present disclosure to provide cloths having different thermal properties. The structure of the cloth includes a high melting point temperature region and a low melting point temperature region, which are respectively composed of yarns having a high melting point and a low melting point. Among the high melting point temperature region and the low melting point temperature region, The melting points differ between about 30 ° C. and 150 ° C., and the cloth in the low melting point temperature region will harden after thermal activation, and the cloth in the high melting point region will remain soft after thermal activation.

在本揭示內容的多個實施例中,每一紗線是由複數條纖維所組成,每一所述纖維是由聚酯(polyester, PES)組成,所述聚酯,包括,但不限於,聚對苯二甲酸乙二酯 (PET))、低熔點共聚酯及其之組合。In various embodiments of the present disclosure, each yarn is composed of a plurality of fibers, and each of the fibers is composed of polyester (PES). The polyester includes, but is not limited to, Polyethylene terephthalate (PET)), low melting point copolyester, and combinations thereof.

在本揭示內容的多個實施例中,所述低熔點共聚酯為一種由對苯二甲酸(terephthalic acid ,PTA)、乙二醇(ethylene glycol ,EG)以及一脂肪族單體組成的共聚物。所述脂肪族單體可為穀胺酸(glutamic acid)、己二酸(adipic acid)、庚二酸(pimelic acid)、辛二酸(suberic acid)、癸二酸(sebacic acid)、新戊二醇(neopentyl glycol)或丁二醇(butylene glycol)之任一種,且所述脂肪族單體在所述共聚物的總重量中,約佔1-20% (重量百分率)。較佳地,本揭示內容所述低熔點共聚酯是由對苯二甲酸(PTA)、乙二醇(ethylene glycol ,EG)以及癸二酸(sebacic acid)組成的共聚物。In various embodiments of the present disclosure, the low-melting copolyester is a copolymer composed of terephthalic acid (PTA), ethylene glycol (EG), and an aliphatic monomer. Thing. The aliphatic monomer may be glutamic acid, adipic acid, pimelic acid, suberic acid, sebacic acid, neopentyl Either neopentyl glycol or butylene glycol, and the aliphatic monomer accounts for about 1-20% (weight percentage) of the total weight of the copolymer. Preferably, the low-melting copolyester described in the present disclosure is a copolymer composed of terephthalic acid (PTA), ethylene glycol (EG), and sebacic acid.

在本揭示內容的多個實施例中,所述低熔點溫度區是藉由將具有低熔點的紗線繡於所述高熔點溫度區上的布而形成。In various embodiments of the present disclosure, the low melting point temperature region is formed by embroidering a yarn having a low melting point on a cloth on the high melting point temperature region.

在本揭示內容的多個實施例中,所述高及低熔點溫度區是分別藉由針織或梭織具有高熔點及低熔點的紗線而形成。In various embodiments of the present disclosure, the high and low melting temperature regions are formed by knitting or woven yarns having high melting points and low melting points, respectively.

在本揭示內容的多個實施例中,所述熱活化是透過對所述熱可塑性布加熱,直到溫度達到所述低熔點溫度區的熔點溫度,但未超過所述高熔點溫度區的熔點溫度而達成。In various embodiments of the present disclosure, the thermal activation is through heating the thermoplastic fabric until the temperature reaches the melting point temperature in the low melting point temperature region, but does not exceed the melting point temperature in the high melting point temperature region. And reach.

在本揭示內容的另一目的在於提供一種物件,其藉由熱活化所述之熱可塑性布使其形成特定形狀,進而在所述熱可塑性布上直接產生所述物件。Another object of the present disclosure is to provide an object that is formed into a specific shape by thermally activating the thermoplastic fabric, and then the object is directly generated on the thermoplastic fabric.

在本揭示內容的多個實施例中,所述物件的形狀是藉由對如前述之熱可塑性布加熱,直到溫度達到所述低熔點溫度區的熔點溫度,但未超過所述高熔點溫度區的熔點溫度,而形成。In various embodiments of the present disclosure, the shape of the object is by heating the thermoplastic fabric as described above until the temperature reaches the melting point temperature in the low melting point temperature region, but does not exceed the high melting point temperature region. The melting temperature is formed.

在本揭示內容的多個特定實施例中,所述物件的形狀是在所述熱活化過程中搭配使用模具而形成。In specific embodiments of the present disclosure, the shape of the object is formed by using a mold during the thermal activation process.

請搭配下述詳細說明並一併圖式,以利更能詳細理解本揭示內容的多個特徵與優點。Please accompany the following detailed description and drawings to better understand the multiple features and advantages of this disclosure.

以下說明是針對本申請所提具體例搭配圖式進行描述,不應被認定為單一實施態樣。此外,本說明為了建構及執行具體例,針對具體例的功效以及一系列步驟進行說明,但相同或相等功效或步驟亦可透過其他具體例所達成。The following description is described with reference to the specific examples provided in this application, and should not be considered as a single implementation. In addition, in order to construct and execute specific examples, the description describes the effects of specific examples and a series of steps, but the same or equivalent functions or steps can also be achieved through other specific examples.

本內容所述之「一」以及 「所述或該」,除非本內容有具體敘明,否則應認定為包含複數。The "a" and "said or" mentioned in this content shall be deemed to include plural unless specifically stated in this content.

一般而言,本揭示內容係關於,以具有經濟效益的方式,直接從一熱可塑性布上形成紡織物件(例如墊肩、鈕扣、口袋等)的方法。Generally speaking, the present disclosure relates to a method for forming textile items (such as shoulder pads, buttons, pockets, etc.) directly from a thermoplastic fabric in a cost-effective manner.

為達上述目的,將聚合纖維或絲線(例如: 低熔點共聚酯或聚對苯二甲酸乙二酯纖維)組合後形成紗線,所述紗線可再透過事先佈置安排,以刺繡 (embroider)、針織(knit)及/或梭織(woven)等方式製成布料,進而產生欲求的熱可塑性布,其上具有高、低熔點溫度區域。在接觸熱之後,一部分具有低熔點溫度區域的布將會熔化且最終將硬化,而一部分具有高熔點溫度的區域的布則會保持不熔化狀態且具有柔軟度,藉此,可直接於所述布上形成特定三維空間 (3D)型態的物件,此外,也可選擇性地將所述具有硬區與軟區的布凹折成所欲形成之3D物件的形狀。In order to achieve the above purpose, a polymer fiber or a silk thread (for example, a low melting point copolyester or polyethylene terephthalate fiber) is combined to form a yarn, and the yarn can be embroidered through an advance arrangement. ), Knit (knit) and / or woven (woven) and other methods to make cloth, and then produce the desired thermoplastic cloth, which has high and low melting temperature regions. After exposure to heat, a part of the cloth with a low melting temperature region will melt and eventually harden, while a part of the cloth with a high melting temperature region will remain unmelted and have softness, whereby it can be directly A specific three-dimensional space (3D) type of object is formed on the cloth. In addition, the cloth with the hard and soft regions can be selectively folded into the shape of the desired 3D object.

1.1. 絲線Silk thread

本申請所述之「絲線(filaments)」及「纖維」二名詞可互換使用,指某一連續的材料段。於本揭示內容中,所需的絲線或纖維是由聚酯(polyester, PES)所製得,其可以是聚對苯二甲酸乙二醇酯(PET)或低熔點聚酯;較佳地,其可由回收材料製得,以減少最終製成物件的碳足跡(carbon footage)。The terms "filaments" and "fibers" as used in this application are used interchangeably and refer to a continuous piece of material. In the present disclosure, the required threads or fibers are made of polyester (PES), which may be polyethylene terephthalate (PET) or a low melting point polyester; preferably, It can be made from recycled materials to reduce the carbon footage of the final article.

本文所述之「低熔點共聚酯」是指一種改質的聚酯,例如為對苯二甲酸(terephthalic acid ,PTA)、乙二醇(ethylene glycol,EG)以及一脂肪族單體所形成的共聚物。所述脂肪族單體可為穀胺酸(glutamic acid)、己二酸(adipic acid)、庚二酸(pimelic acid)、辛二酸(suberic acid)、癸二酸(sebacic acid)、新戊二醇(neopentyl glycol)及丁二醇(butylene glycol)中任一種。聚對苯二甲酸乙二醇酯的單體分別是對苯二甲酸(PTA)及乙二醇(EG)。在聚合期間,對苯二甲酸(PTA)及乙二醇(EG)會聚合形成聚對苯二甲酸乙二醇酯。然而,若有脂肪族單體存在,除了聚對苯二甲酸乙二醇酯鏈段之外,亦可能在脂肪族單體與對苯二甲酸(PTA)或乙二醇(EG)之間形成嵌段共聚物,基於前述,形成改質的聚對苯二甲酸乙二醇酯,其包含聚對苯二甲酸乙二醇酯/脂肪族單體形成的共聚物的嵌段結構。所述改質的聚對苯二甲酸乙二醇酯或共聚酯的結晶性質不同於未改質的聚對苯二甲酸乙二醇酯 (亦即,未添加脂肪族單體的聚對苯二甲酸乙二醇酯),改質的聚對苯二甲酸乙二醇酯的熔點遠低於未改質的聚對苯二甲酸乙二醇酯。聚對苯二甲酸乙二醇酯熔點的降低程度,與脂肪組單體於共聚物中的含量成反比,換言之,熔點越低,脂肪組單體於共聚物中的含量越高。較佳地,脂肪組單體於共聚酯中的重量百分率約為1-20% (wt%)。The "low melting point copolyester" described herein refers to a modified polyester, such as formed by terephthalic acid (PTA), ethylene glycol (EG), and an aliphatic monomer Copolymer. The aliphatic monomer may be glutamic acid, adipic acid, pimelic acid, suberic acid, sebacic acid, neopentyl Either neopentyl glycol or butylene glycol. The monomers of polyethylene terephthalate are terephthalic acid (PTA) and ethylene glycol (EG). During the polymerization, terephthalic acid (PTA) and ethylene glycol (EG) are polymerized to form polyethylene terephthalate. However, if there are aliphatic monomers, in addition to the polyethylene terephthalate segment, it may also form between the aliphatic monomer and terephthalic acid (PTA) or ethylene glycol (EG). Based on the foregoing, the block copolymer forms a modified polyethylene terephthalate, which includes a block structure of a copolymer formed of a polyethylene terephthalate / aliphatic monomer. The crystallinity of the modified polyethylene terephthalate or copolyester is different from that of unmodified polyethylene terephthalate (i.e., poly (p-phenylene) without added aliphatic monomer Diethylene glycol dicarboxylate), the melting point of modified polyethylene terephthalate is much lower than that of unmodified polyethylene terephthalate. The degree of decrease in the melting point of polyethylene terephthalate is inversely proportional to the content of the fatty monomer in the copolymer. In other words, the lower the melting point, the higher the content of the fatty monomer in the copolymer. Preferably, the weight percentage of the fatty group monomer in the copolyester is about 1-20% (wt%).

根據本揭示內容的較佳實施例,所述低熔點共聚酯為對苯二甲酸(PTA)、乙二醇(EG)以及癸二酸(sebacic acid)的共聚物。在本揭示內容中,低熔點共聚酯的熔點介於110-130℃之間,而聚對苯二甲酸乙二醇酯的熔點則約為250-260℃。基於前述,由聚對苯二甲酸乙二醇酯纖維所形成的紗線的熔點遠高於由低熔點共聚酯纖維所形成的紗線。適用於本揭示內容的低熔點共聚酯亦可為市售商品,例如SRPXTM絲線(小智研發,台北,台灣)。According to a preferred embodiment of the present disclosure, the low-melting copolyester is a copolymer of terephthalic acid (PTA), ethylene glycol (EG), and sebacic acid. In the present disclosure, the melting point of the low-melting copolyester is between 110-130 ° C, and the melting point of polyethylene terephthalate is about 250-260 ° C. Based on the foregoing, the melting point of yarns formed from polyethylene terephthalate fibers is much higher than that of yarns formed from low-melting copolyester fibers. Low-melting copolyesters suitable for the present disclosure may also be commercially available products, such as SRPXTM yarns (Xiaozhi R & D, Taipei, Taiwan).

適用於本揭示內容的聚合絲線可透過傳統技術(例如,紡織(spinning)) 製得。在一些實施例中,聚合絲線在結構上屬於芯-鞘複合纖維,包含一核芯及一外鞘,其中,所述外鞘配置於所述核芯的周圍。較佳地,所述核芯及所述外鞘是由不同熔點的聚合材料製成,藉此使纖維產生不同的熱性質。或者,聚合絲線可包含一內腔(或是其芯為中空的)。Polymeric threads suitable for the present disclosure can be made by conventional techniques (eg, spinning). In some embodiments, the polymeric filament belongs to a core-sheath composite fiber in structure, and includes a core and an outer sheath, wherein the outer sheath is arranged around the core. Preferably, the core and the sheath are made of polymer materials with different melting points, so that the fibers have different thermal properties. Alternatively, the polymeric filament may include a lumen (or its core may be hollow).

2.2. 紗線Yarn

在本揭示內容中製得且使用了幾種不同的紗線。一般而言,除了以含有回收材料及/或含有原生材料及回收材料之組合材料所形成的纖維製得的紗線外,可以習知技術製得前述該些紗線。根據不同生產技術,能夠形成具有多種結構與形狀的紗線。因此,紗線的橫切面形狀能夠具有圓形、三葉形、多葉形、橙片形等不同型態。Several different yarns were made and used in this disclosure. Generally speaking, in addition to yarns made from fibers containing recycled materials and / or a combination of virgin materials and recycled materials, the aforementioned yarns can be made by conventional techniques. According to different production technologies, yarns with various structures and shapes can be formed. Therefore, the cross-sectional shape of the yarn can have different shapes such as a circle, a trilobal shape, a multilobal shape, and an orange flake shape.

本揭示內容中所述之「高溫紗線」是指由具有高熔點溫度的絲線所組成的紗線,例如,由聚對苯二甲酸乙二醇酯絲線所組成的紗線。所述之「低溫紗線」是指由具有低熔點溫度的絲線所組成的紗線,例如,由低熔點聚酯絲線(例如,SRPXTM絲線)(小智研發,台北,台灣))所組成的紗線。The “high-temperature yarn” described in the present disclosure refers to a yarn composed of a yarn having a high melting point temperature, for example, a yarn composed of a polyethylene terephthalate yarn. The "low-temperature yarn" refers to a yarn composed of a yarn having a low melting point temperature, for example, a low-melting polyester yarn (e.g., SRPXTM yarn) (R & D, Taipei, Taiwan). Yarn.

2.12.1 由芯By core -- 鞘複合纖維Sheath composite fiber (core-sheath composite fibers)(core-sheath composite fibers) 所構成之紗線The yarn

請一併參照圖1A及圖1B,圖1A為一紗線10的示意圖,圖1B為紗線10沿1-1’線段的剖面圖。如圖1A所示,紗線10由複數條聚合絲線11所組成。沿1-1’線段的紗線10剖面圖顯示了每一條聚合絲線11都是芯-鞘複合纖維,其中,每條纖維包含一核芯11C 及一外鞘11S。核芯及外鞘可各自由低熔點共聚酯及聚對苯二甲酸乙二酯(PET)所製成,反之亦然。在本 揭示內容的一實施例中,核芯是由聚對苯二甲酸乙二酯(PET)所組成,而外鞘是由低熔點共聚酯所組成。在另一實施例中,核芯是由低熔點共聚酯所組成,而外鞘是由聚對苯二甲酸乙二酯(PET)所組成。Please refer to FIG. 1A and FIG. 1B together. FIG. 1A is a schematic view of a yarn 10, and FIG. 1B is a cross-sectional view of the yarn 10 along a line 1-1 '. As shown in FIG. 1A, the yarn 10 is composed of a plurality of polymer yarns 11. The cross-sectional view of the yarn 10 along the line 1-1 'shows that each of the polymer yarns 11 is a core-sheath composite fiber, wherein each fiber includes a core 11C and an outer sheath 11S. The core and the sheath can each be made of a low-melting copolyester and polyethylene terephthalate (PET), and vice versa. In one embodiment of the present disclosure, the core is composed of polyethylene terephthalate (PET), and the outer sheath is composed of a low-melting copolyester. In another embodiment, the core is composed of a low melting point copolyester, and the outer sheath is composed of polyethylene terephthalate (PET).

2.22.2 由複合纖維Composite fiber (comingled fibers)(comingled fibers) 所構成之紗線The yarn

請參照圖2A 及圖2B,其中,圖2A 為紗線20的立體示意圖; 圖2B 為紗線20沿2-2’線段的剖面圖。在本實施例中,紗線20是由複數條混雜的第一及第二聚合絲線21、22組成。第一及第二聚合絲線21、22分別是由低熔點共聚酯及聚對苯二甲酸乙二酯(PET)之單成分纖維所構成,反之亦然。在本揭示內容的一實施例中,第一聚合絲線21是由低熔點共聚酯製成,而第二聚合絲線22則由PET製成。Please refer to FIG. 2A and FIG. 2B, wherein FIG. 2A is a schematic perspective view of the yarn 20; FIG. 2B is a cross-sectional view of the yarn 20 along a line 2-2 '. In this embodiment, the yarn 20 is composed of a plurality of mixed first and second polymer yarns 21 and 22. The first and second polymeric yarns 21 and 22 are composed of single-component fibers of low-melting copolyester and polyethylene terephthalate (PET), and vice versa. In one embodiment of the present disclosure, the first polymeric yarn 21 is made of a low-melting copolyester, and the second polymeric yarn 22 is made of PET.

2.32.3 加捻紗線Twisted yarn (twisting yarns)(twisting yarns)

請一併參照圖3A及圖3B,其中,圖3A 為單包紗線30的示意圖。圖3B 為紗線30沿3-3’線段的剖面圖。在本實施例中,紗線30是由複數條第一及第二聚合絲線31、32所構成,其分別作為核芯纖維與加捻纖維,其中,在製造過程中,第二聚合絲線32(或加捻纖維)的方向是沿第一聚合絲線31加捻並轉向,使得兩聚合絲線得以緊密地靠攏,藉此讓紗線30的結構整體更加堅固。加捻是一紡織產業中常見技術,其能夠幫助纖維互相緊密貼附,進而增強紗線強度。紗線加捻的方向與次數有助於決定外觀、效果、紗線及隨後製得的物件及織品的耐用性。Please refer to FIG. 3A and FIG. 3B together, wherein FIG. 3A is a schematic diagram of a single package of yarn 30. Fig. 3B is a cross-sectional view of the yarn 30 along a line 3-3 '. In this embodiment, the yarn 30 is composed of a plurality of first and second polymeric yarns 31 and 32, which are respectively used as a core fiber and a twisted fiber. In the manufacturing process, the second polymeric yarn 32 ( (Or twisted fibers) is twisted and turned along the first polymeric yarn 31, so that the two polymeric yarns are brought closer together, thereby making the overall structure of the yarn 30 stronger. Twisting is a common technique in the textile industry, which can help fibers adhere closely to each other, thereby enhancing yarn strength. The direction and number of yarn twists help determine the appearance, effect, and durability of the yarn and subsequent articles and fabrics.

當製造加捻纖維時,核芯纖維可為具有高熔點的絲線(例如PET),而加捻纖維可為低熔點的絲線(例如低熔點共聚酯)。或是,核芯纖維及加捻纖維兩者都是芯-鞘複合纖維,其中,核芯為由相對高熔點的材料(例如,PET)製成,外鞘為由相對低熔點的材料(例如,低熔點共聚酯)製成。When making twisted fibers, the core fiber may be a thread having a high melting point (for example, PET), and the twisted fiber may be a thread having a low melting point (for example, a low melting point copolyester). Alternatively, both the core fiber and the twisted fiber are core-sheath composite fibers, in which the core is made of a relatively high melting point material (for example, PET) and the outer sheath is made of a relatively low melting point material (for example, PET). , Low melting point copolyester).

於本揭示內容的一些實施例中,單包紗線包含核芯纖維及加捻纖維,其分別由低熔點共聚酯製成。在其他實施例中,亦可製成雙包紗線,在此情況下,核芯纖維由聚對苯二甲酸乙二酯(PET)製成,加捻纖維由低熔點共聚酯製成。又,在其他實施例中,亦可製成由芯-鞘複合纖維所組成的電纜雙股紗線(cable double ply)或稱纜雙紗(cable double ply),其中,芯鞘複合纖維的核芯是由聚對苯二甲酸乙二酯(PET)製成,外鞘則是由低熔點共聚酯製成。In some embodiments of the present disclosure, the single-package yarn includes a core fiber and a twisted fiber, which are each made of a low-melting copolyester. In other embodiments, double-wrapped yarns can also be made. In this case, the core fibers are made of polyethylene terephthalate (PET), and the twisted fibers are made of low-melting copolyester. Also, in other embodiments, a cable double ply or cable double ply composed of a core-sheath composite fiber may be made, in which the core of the core-sheath composite fiber The core is made of polyethylene terephthalate (PET), and the outer sheath is made of a low-melting copolyester.

2.42.4 由空芯纖維Hollow fiber 所組成之紗線Composition of yarn

請一併參照圖4A及圖4B,其中,圖4A為紗線40的示意圖; 圖4B 為紗線40沿4-4’線段的剖面圖。在本實施例中,紗線40是由複數條聚合絲線41所組成,該些聚合絲線為空芯纖維,其中,每一纖維具有內腔或空芯。在本實施例中,空芯纖維由聚對苯二甲酸乙二酯(PET)製成,例如,回收的聚對苯二甲酸乙二酯(PET)。Please refer to FIG. 4A and FIG. 4B together, wherein FIG. 4A is a schematic view of the yarn 40; FIG. 4B is a cross-sectional view of the yarn 40 along a line 4-4 '. In this embodiment, the yarn 40 is composed of a plurality of polymer yarns 41, and the polymer yarns are hollow core fibers, wherein each fiber has an inner cavity or a hollow core. In this embodiment, the hollow fiber is made of polyethylene terephthalate (PET), for example, recycled polyethylene terephthalate (PET).

3.3. 熱可塑性布與其物件Thermoplastic cloth and its objects

為了產生具有熱可塑性質的布,有計畫地將由高熔點溫度或低熔點溫度絲線所組成的紗線以刺繡、針織或梭織方式形成布,使得布上具有欲求的溫度分佈面積或區域,藉此,使得布可透過加熱而被塑形。In order to produce a cloth with thermoplastic properties, it is planned to embroider, knit, or woven a yarn composed of high-melting temperature or low-melting temperature yarns, so that the cloth has a desired temperature distribution area or area. Thereby, the cloth can be shaped by heating.

較佳地,所述熱可塑性布應包含高及低溫度區,其中,高溫紗線的熔點溫度與低溫紗線的熔點溫度相差30℃至150℃,例如30、31、32、33、34、35、36、37、38、39、40、41、42、43、44、45、46、47、48、49、50、51、52、53、54、55、56、57、58、59、60、61、62、63、64、65、66、67、68、69、70、71、72、73、74、75、76、77、78、79、80、81、82、83、84、85、86、87、88、89、90、92、92、93、94、95、96、97、98、99、100、101、102、103、104、105、106、107、108、109、110、111、112、113、114、115、116、117、118、119、120、121、122、123、124、125、126、127、128、129、130、131、132、133、134、135、136、137、138、139、140、141、142、143、144、145、146、147、148、149、150℃。所屬領域具有通常知識者,可在不需過度實驗的情況下,選擇適當的高、低溫紗線,進而產生具有所需熱可塑性質的布。Preferably, the thermoplastic fabric should include high and low temperature regions, wherein the melting point temperature of the high temperature yarn and the melting point temperature of the low temperature yarn differ by 30 ° C to 150 ° C, such as 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 44, 45, 46, 47, 48, 49, 50, 51, 52, 53, 54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72, 73, 74, 75, 76, 77, 78, 79, 80, 81, 82, 83, 84, 85, 86, 87, 88, 89, 90, 92, 92, 93, 94, 95, 96, 97, 98, 99, 100, 101, 102, 103, 104, 105, 106, 107, 108, 109, 110, 111, 112, 113, 114, 115, 116, 117, 118, 119, 120, 121, 122, 123, 124, 125, 126, 127, 128, 129, 130, 131, 132, 133, 134, 135, 136, 137, 138, 139, 140, 141, 142, 143, 144, 145, 146, 147, 148, 149, 150 ° C. Those with ordinary knowledge in the field can choose appropriate high and low temperature yarns without undue experimentation, and then produce cloth with desired thermoplastic properties.

3.13.1 藉由刺繡技術而獲得熱可塑性布及其物件Thermoplastic cloth and objects obtained by embroidery technique

在一些較佳實施例中,將低溫紗線繡於一底布上,所述底布是由高溫紗線所製成,並且形成一特定圖案(如圖6所示)。或是,藉由將多層由低溫紗線形成的預設圖案繡於一底布上(如圖5所示),以強化意欲由該些紗線製成之物件的機械強度。在此情況下,被繡的圖案主要是由低溫紗線所組成(例如由低熔點共聚酯所製得的芯-鞘複合纖維),而底布則是由高溫紗線所組成(例如PET)。因此,當布的溫度上升至超過低溫紗線的熔點溫度時,在此些區域的紗線將會熔融,且在溫度下降後硬化; 於此同時,具有高溫紗線的區域仍維持柔軟,須知,在這些區域的紗線並未產生熔融。又請參見圖7,圖7為依據本揭示內容一具體實施例,為透過上述方式而製得的物件。所屬領域具有通常知識者能夠選擇混合高低溫紗線並透過任一種其認為適當的刺繡技術產生所需的圖案,使得刺繡的圖案最終能夠轉換成所需型狀的物件。In some preferred embodiments, the low-temperature yarn is embroidered on a base fabric, which is made of high-temperature yarn and forms a specific pattern (as shown in FIG. 6). Or, by embroidering a plurality of preset patterns formed of low-temperature yarns on a base fabric (as shown in FIG. 5), the mechanical strength of objects intended to be made of the yarns is enhanced. In this case, the embroidered pattern is mainly composed of low-temperature yarns (such as core-sheath composite fibers made of low-melting copolyester), while the base fabric is composed of high-temperature yarns (such as PET ). Therefore, when the temperature of the cloth rises above the melting point of the low-temperature yarns, the yarns in these areas will melt and harden after the temperature drops; at the same time, the areas with high-temperature yarns will remain soft. The yarns in these areas did not melt. Please also refer to FIG. 7, which is an object made in the foregoing manner according to a specific embodiment of the present disclosure. Those with ordinary knowledge in the art can choose to mix high and low temperature yarns and produce desired patterns through any embroidery technique they consider appropriate, so that the embroidered patterns can finally be converted into objects of the desired shape.

3.23.2 藉由針織技術而獲得熱可塑性布及其物件Thermoplastic cloth and objects obtained by knitting technique

在一些較佳實施例中,計畫性地將高低溫紗線針織成一塊布料,藉此,在所述布料上產生具有相異熱性質的區域。任何習知的針織技術均可用來針織本揭示內容的紗線,以形成布,針織方法的實例,包括但不限於,無縫(Seamless)、提花 (Jacquard)、雙面提花(Double Jacquard)、絎縫雙提花(Quilting double Jacquard)、鳥眼提花(Birdseye Jacquard)、單面提花針織(Single Jacquard)、經編(warp knit)、橫管(Cross Tubular)、平針(Jersey)、稜紋(Rib)、雙螺紋(Interlock)等。In some preferred embodiments, the high and low temperature yarns are knitted into a piece of cloth programmatically, whereby areas with different thermal properties are created on the cloth. Any conventional knitting technique can be used to knit the yarns of the present disclosure to form a cloth. Examples of knitting methods include, but are not limited to, Seamless, Jacquard, Double Jacquard, Quilting double Jacquard, Birdseye Jacquard, Single Jacquard, warp knit, Cross Tubular, Jersey, Rib ), Double thread (Interlock), etc.

請參照圖8A,其為依據本揭示內容一特定實施例,藉由提花針織高低溫紗線而製得的布。直線以界定出鑽石形狀的線條部分都是由高溫紗線所組成(例如PET),而其他區域則是由低溫紗線所組成(例如低熔點共聚酯),藉此,在布上產生具有不同熱性質區域。根據預設由所述布所製得的物件的大小及/或形狀,進而能夠對預設的區域充分地加熱,進而位於低溫度區的紗線(例如鑽石形狀區域)被熔融,而當溫度降低後,將會接續地硬化,於此同時,直線部分在加熱過程中仍維持軟度(如圖8B所示)。基於前述,所述布能夠被彎折形成所需的3D形狀而不需使用傳統的裁剪(Cutting)、刺縫(Quilting)、模壓 (Molding)技術。Please refer to FIG. 8A, which is a cloth made by jacquard knitting high and low temperature yarns according to a specific embodiment of the present disclosure. Straight lines to define the shape of the diamond are all composed of high-temperature yarns (such as PET), while other areas are composed of low-temperature yarns (such as low-melting copolyester). Areas of different thermal properties. According to the preset size and / or shape of the object made from the cloth, the preset area can be fully heated, and the yarn (such as a diamond-shaped area) located in a low temperature area is melted, and when the temperature is After lowering, it will continue to harden, and at the same time, the straight part will remain soft during heating (as shown in Figure 8B). Based on the foregoing, the cloth can be bent to form a desired 3D shape without using conventional cutting, quilting, and molding techniques.

再請參照圖9及圖10,圖9及圖10分別為藉由提花針織而製得的布所形成之二物件的實際相片圖。又,藉由類似的技術,圖11及圖12是分別藉由雙面提花針織法所製得之布的實際相片圖,且其類似於提花針織,這些布亦可透過加熱而塑形,其中,圖11描述了將雙面提花針織法所製得之熱可塑性布,透過熱活化形成一3D矩形形狀。Please refer to FIG. 9 and FIG. 10 again. FIG. 9 and FIG. 10 are actual photo diagrams of two objects formed by cloth made by jacquard knitting, respectively. In addition, with similar techniques, Figures 11 and 12 are actual photographs of cloths made by double-sided jacquard knitting, respectively, and they are similar to jacquard knitting. These cloths can also be shaped by heating. FIG. 11 illustrates that a thermoplastic fabric produced by a double-sided jacquard knitting method is formed into a 3D rectangular shape by thermal activation.

3.33.3 藉由梭織By weaving 技術所獲得之熱可塑性布及其物件Thermoplastic cloth and its objects obtained by technology

在其他實施例中,有計畫性地將高低溫紗線梭織成布,藉此,在布上形成具有不同熱性質的區域。可應用任何習知編織技術來梭織本揭示內容之紗線,以製成布料。適合用於梭織本揭示內容紗線的實例,包括但不限於,雙面梭織(double sided woven)、提花梭織(Jacquard)、剪線(Fil Coupé)等。In other embodiments, the high- and low-temperature yarns are woven into a cloth programmatically, thereby forming areas having different thermal properties on the cloth. Any conventional weaving technique can be applied to weave the yarns of this disclosure to make fabric. Examples of yarns suitable for weaving the present disclosure include, but are not limited to, double sided woven, Jacquard, Fil Coupé, and the like.

與藉由前述刺繡技術或針織技術所製得之布類似,藉由梭織技術製得的布,由於在梭織過程中編入了高低溫紗線,因此,亦具有熱可塑特性。Similar to the cloth made by the aforementioned embroidery technique or knitting technique, the cloth produced by the woven technique also has the characteristics of thermoplastic because the high and low temperature yarns are knitted in the woven process.

以下將透過下述數個實驗例以利更詳細描述本發明,所述實驗例用於描繪本發明之目的,但本發明之保護範圍不應限制於這些實驗例。In the following, the present invention will be described in more detail through the following experimental examples, which are used to describe the purpose of the present invention, but the protection scope of the present invention should not be limited to these experimental examples.

實驗例Experimental example

實驗例Experimental example 11 製造紗線Manufacturing yarn

在本實驗例中,透過一或多種由具有不同熔點溫度之一或兩種成分的絲線,製成能在兩種不同溫度下熔融的紗線。本實驗例所述絲線是透過習知紡織技術製成,能夠形成具有多種形狀的纖維,藉此,能產生圓形、三葉形、多葉形、圓形中空(由空芯纖維而來)或橙片形等不同剖面形狀。對芯-鞘複合纖維而言,每個纖維的核芯與外鞘分別為50/50或80/20。In this experimental example, yarns that can be melted at two different temperatures are made through one or more yarns having one or two components with different melting temperatures. The yarn described in this experimental example is made through conventional textile technology, and can form fibers with various shapes, thereby generating round, trilobal, multilobal, and circular hollow (from hollow core fibers) Or orange slices. For core-sheath composite fibers, the core and sheath of each fiber are 50/50 or 80/20, respectively.

1.11.1 由芯By core -- 鞘複合纖維所組成之紗線Yarn composed of sheath composite fibers

將總數介於16-192條之約30-450丹( Denier,D)的芯-鞘複合纖維聚集形成紗線。在本實驗例中,每條芯-鞘複合纖維包含核芯,其由聚對苯二甲酸乙二酯(PET) (約具有260℃熔點溫度)所組成,以及外鞘,其由低熔點共聚酯(約具有110-230℃之熔點溫度)所組成。接著,分別量取每條紗線的多個區塊而取得包括橙片形、圓形、三葉形、多葉形及橫切等多種形狀的切面,其分別顯示出每條紗線是由約5至80%的低熔點纖維組成。Core-sheath composite fibers with a total of about 30-450 deniers (Denier, D) ranging from 16 to 192 are aggregated to form a yarn. In this experimental example, each core-sheath composite fiber includes a core, which is composed of polyethylene terephthalate (PET) (having a melting point temperature of about 260 ° C), and an outer sheath, which is composed of Polyester (having a melting point of about 110-230 ° C). Then, the multiple sections of each yarn are measured separately to obtain various shapes including orange slices, circles, trilobes, multilobes, and cross-sections, which show that each yarn is composed of About 5 to 80% of low-melting fiber composition.

1.21.2 由芯By core -- 鞘複合纖維所組成之紗線Yarn composed of sheath composite fibers

在本實驗例的紗線是依據如實驗例1.1所述製程製造而成 , 差異在於核芯由低熔點共聚酯 (亦即,低溫度材料)所組成,以及外鞘由聚對苯二甲酸乙二酯(PET) (亦即,高溫度材料)所組成。The yarn in this experimental example is manufactured according to the process described in Experimental Example 1.1. The difference is that the core is composed of a low melting point copolyester (that is, a low temperature material) and the outer sheath is made of polyterephthalic acid. Composed of ethylene glycol (PET) (ie, high temperature material).

1.31.3 加捻紗線Twisted yarn

本實驗例包含三種型態的加捻紗線,其包括單包紗線(single covered yarns)、雙包紗線(double covered yarns)、纜雙紗(cable double pli)。 三種紗線分別透過習知紗線製程製得。單包紗線包含一束由300丹(D)的聚對苯二甲酸乙二酯(PET)所製得的核芯纖維以及一束由150D的低熔點共聚酯所製得的加捻型纖維。雙包紗線包含一束由聚對苯二甲酸乙二酯(PET)所製得的核芯纖維以及兩束加捻型纖維分別以相反方向圍繞核芯纖維加捻。在纜雙紗的實驗例中,核芯纖維及加捻纖維均為芯-鞘複合纖維,其中,每一複合纖維的核芯由聚對苯二甲酸乙二酯(PET)製得,外鞘由低熔點共聚酯製成。This experimental example includes three types of twisted yarns, including single covered yarns, double covered yarns, and cable double pli. The three kinds of yarns are respectively prepared through a conventional yarn manufacturing process. Single-package yarn contains a bundle of core fibers made of 300 denier (D) polyethylene terephthalate (PET) and a bundle of twisted types made of 150D low-melting copolyester fiber. The double-wrapped yarn includes a bundle of core fibers made of polyethylene terephthalate (PET) and two bundles of twisted fibers twisted around the core fibers in opposite directions, respectively. In the cable double yarn experimental example, the core fiber and the twisted fiber are core-sheath composite fibers, in which the core of each composite fiber is made of polyethylene terephthalate (PET) and the outer sheath Made of low melting point copolyester.

1.41.4 由空芯聚對苯二甲酸乙二酯Hollow core polyethylene terephthalate (PET)(PET) 纖維所組成之紗線Yarn made of fibers

在本實驗例中,將總數為16至192條之約30-450丹(D)之聚對苯二甲酸乙二酯(PET)絲線聚集形成紗線。In this experimental example, a total of 16 to 192 polyethylene terephthalate (PET) threads of about 30 to 450 deniers (D) were aggregated to form a yarn.

1.51.5 由低熔點共聚酯纖維所組成之紗線Yarn composed of low melting point copolyester fiber

在本實驗例中,將總數為16至192條之約30-450丹(D)之低熔點共聚酯絲線聚集形成紗線。In this experimental example, a total of 16 to 192 low melting point copolyester yarns of about 30 to 450 deniers (D) were aggregated to form a yarn.

實驗例Experimental example 22 藉由刺繡技術及熱活化而製得之熱可塑性布及物件Thermoplastic cloth and objects made by embroidery technology and thermal activation

在本實驗例中,計劃性地將一或多束紗線(如實驗例1的紗線)繡於習知底布上,以形成2D圖案(例如格狀圖案),接著施以熱活化,進而由所制定的2D圖案上形成熱可塑的3D物件。刺繡是以6-頭繡花機或具有綑綁裝置(cording device)的繡花機所執行。In this experimental example, one or more bundles of yarn (such as the yarn of Experimental Example 1) are embroidered on a conventional base fabric to form a 2D pattern (such as a grid pattern), and then thermally activated. Then, a thermoplastic 3D object is formed on the specified 2D pattern. Embroidery is performed with a 6-head embroidery machine or an embroidery machine with a cording device.

2.12.1 藉由By 6-6- 頭繡花機來製造熱可塑性布Head embroidery machine to make thermoplastic fabric

在本實驗例中,以榻榻米針法,以不同方向(例如0o、45o、 及 90o以增加紗線強度)將實驗例1之紗線所形成的多層結構,繡於一片底布上。詳細條件如下表1。又請參見圖5,圖5繪示了藉由6-頭繡花機而刺繡成具有2D格狀圖案的布。In this experimental example, the tatami needle method was used to embroider the multilayer structure formed by the yarn of Experimental Example 1 in different directions (for example, 0o, 45o, and 90o to increase yarn strength) on a base fabric. The detailed conditions are shown in Table 1 below. See also FIG. 5, which illustrates a cloth embroidered with a 2D grid pattern by a 6-head embroidery machine.

表1 6-頭繡花機之刺繡製程條件 Table 1 6-head embroidery machine embroidery process conditions

2.22.2 以具有綑綁裝置的繡花機製得之熱可塑性布Thermoplastic cloth obtained by embroidery mechanism with binding device

在本實驗例中,藉由具有綑綁裝置的繡花機將預製圖案繡於一塊由實驗例1之紗線所製成的底布上。詳細條件如下表2。請參見圖6,圖6繪示了一藉由具有綑綁裝置的繡花機所繡成之載有所繡圖案的布。In this experimental example, a pre-made pattern was embroidered on a base fabric made of the yarn of Experimental Example 1 by an embroidery machine with a binding device. The detailed conditions are shown in Table 2 below. Please refer to FIG. 6, which illustrates a cloth carrying an embroidery pattern embroidered by an embroidery machine with a binding device.

表2 具有綑綁裝置的繡花機之刺繡製程條件 Table 2 Embroidery process conditions of embroidery machine with binding device

2.3 由實驗例2.1及2.2之熱可塑性布所製得之物件2.3 Articles made from the thermoplastic fabrics of Experimental Examples 2.1 and 2.2

分別對實驗例2.1及2.2的布進行熱昇華轉印(sublimation printing)或熱壓(heat press),其中,在布上所形成的各別繡品在接觸熱後會逐漸軟化後再硬化,布料上其餘部分(例如未涵蓋繡品的部分)仍維持柔軟,藉此,可直接由布上的刺繡圖案直接產生熱可塑物件。在本實驗例的熱活化條件整理如表3及表4。又,請參見圖7,其繪示出透過熱壓刺繡於布上之如實驗例2.1之紗線,所形成的一熱可塑物件。Sublimation printing or heat press was performed on the cloths of Experimental Examples 2.1 and 2.2, respectively. The individual embroidery formed on the cloth will gradually soften and then harden after being exposed to heat. The rest of the upper part (for example, the part that does not cover the embroidery) is still soft, whereby the thermoplastic object can be directly generated from the embroidery pattern on the cloth. Table 3 and Table 4 summarize the thermal activation conditions in this experimental example. Also, please refer to FIG. 7, which shows a thermoplastic object formed by embroidering a cloth such as the yarn of Experimental Example 2.1 by hot pressing.

表3 6-頭繡花機之刺繡製程條件 Table 3 6-head embroidery machine embroidery process conditions

表4 用於熱壓之熱活化條件 Table 4 Thermal activation conditions for hot pressing

實驗例Experimental example 33 藉由針織及熱活化而製得之熱可塑性布及物件Thermoplastic cloth and articles made by knitting and thermal activation

在本實驗例中,計畫性地將如實驗例1之一或多束紗線針織成一習知布(例如由聚酯PES所製得之布),以在布上形成具有不同熔點溫度之區域,基於前述,由低熔點纖維組成之區域具熱可塑性質,會在熱活化後硬化,藉此,可直接由所述布形成熱可塑物件。適用本實驗例的針織方法,包括但不限於,無縫、提花及雙面提花。各種針織技術的條件及後續的熱活化條件整理於如表5、表6及表7。又請參見圖8至圖12,圖8至圖12描述了多個透過提花針織而製得之布以及由所述布製得之物件。In this experimental example, a conventional cloth (such as a cloth made of polyester PES) is knit into a conventional cloth such as one or more of Experimental Examples 1 to form a cloth having different melting temperatures on the cloth. Based on the foregoing, the region composed of low-melting-point fibers has thermoplastic properties, and will harden after thermal activation, whereby a thermoplastic article can be formed directly from the cloth. The knitting methods applicable to this experimental example include, but are not limited to, seamless, jacquard and double-sided jacquard. The conditions of various knitting techniques and subsequent thermal activation conditions are summarized in Table 5, Table 6 and Table 7. See also FIGS. 8 to 12, which illustrate a plurality of cloths made by jacquard knitting and articles made from the cloths.

請參見圖8A,圖8A繪示出藉由提花針織製得之布,又,位於布上之平行直線及透過線條定義出的鑽石形狀的部分是由具有相對高熔點溫度的紗線(如實驗例1之紗線)所組成,而其他區域則是由相對低熔點溫度紗線所組成(例如低熔點共聚酯)。在接觸熱之後,由具有低熔點溫度紗線所組成的布熔融並且最終硬化,而具有高熔點溫度之紗線所組成的布部分在熱活化後仍維持軟度,藉此,所述布能夠包括軟區及硬區,且能夠被彎折成預製備形狀(如圖8B)。Please refer to FIG. 8A. FIG. 8A shows a cloth made by jacquard knitting. Moreover, the parallel straight lines on the cloth and the diamond-shaped portion defined by the lines are made of yarns having a relatively high melting temperature (such as experiments The yarn of Example 1), and the other regions are made of yarns having a relatively low melting temperature (for example, a low-melting copolyester). After exposure to heat, the cloth composed of yarns having a low melting point temperature melts and eventually hardens, while the cloth portion consisting of yarns having a high melting point temperature remains soft after thermal activation, whereby the cloth can It includes soft and hard areas and can be bent into a pre-made shape (see Figure 8B).

將多層如圖8的布堆疊後,藉由矩形模具加熱形成一如圖9所示的硬化矩形物件。透過類似的方法,製得如圖10所示的日型環扣物件,其是藉由提花針織法所形成之布製得。如圖11所示的熱可塑矩形物件,其是藉由雙面提花針織法所形成之布製得。圖12為一實際相片圖,其繪示出具有如圖8A之類似圖案的熱可塑性布的兩面,其中所述布的正面為藍色,所述布的背面則是白色。After multiple layers of cloth as shown in FIG. 8 are stacked, a hardened rectangular object as shown in FIG. 9 is formed by heating with a rectangular mold. By a similar method, a Japanese-style ring-shaped buckle article as shown in FIG. 10 was prepared, which was made by a cloth formed by a jacquard knitting method. The thermoplastic rectangular object shown in FIG. 11 is made of a cloth formed by a double-sided jacquard knitting method. FIG. 12 is an actual photo drawing showing two sides of a thermoplastic cloth having a similar pattern as in FIG. 8A, wherein the front side of the cloth is blue and the back side of the cloth is white.

表5 無縫針織及熱活化條件 Table 5 Seamless knitting and thermal activation conditions

表6 提花針織及熱活化條件 Table 6 Jacquard knitting and thermal activation conditions

表7 雙面提花針織及熱活化條件 Table 7 Double-sided jacquard knitting and thermal activation conditions

實驗例Experimental example 44 藉由梭織及熱活化而製得之熱可塑性布及物件Thermoplastic cloth and articles made by weaving and thermal activation

本實驗例類似實驗例3之製程,差異在於本實驗例使用梭織技術來形成熱可塑性布。在本實驗例使用之梭織技術包括雙面梭織(double sided woven)、提花梭織(Jacquard)、多臂梭織(dobby woven) 及剪線梭織(Fil Coupé)。又表8、表9及表10整理了各種梭織技術的條件,而熱活化條件如表11所述。This experimental example is similar to the process of experimental example 3, except that the experimental example uses woven technology to form a thermoplastic fabric. The woven technology used in this experimental example includes double sided woven, Jacquard, dobby woven, and Fil Coupé. Table 8, Table 9 and Table 10 summarize the conditions of various weaving techniques, and the thermal activation conditions are as described in Table 11.

表8 雙面梭織條件 Table 8 Double-sided woven conditions

表9 提花梭織條件 Table 9 Jacquard weaving conditions

表10 剪線梭織條件 Table 10 Cutting and weaving conditions

表11 熱活化條件 Table 11 Thermal activation conditions

上文實施方式之描述僅為例示,所屬技術領域中具有通常知識者能夠進行多種修改。所述說明、實驗例及資料提供了完整的結構說明以及本發明具體實施例之用途。即使,本發明多個實施例以特定具體的方式描述或參照至一或多個個別實施例,然其並非用以限定本發明,本發明所屬技術領域中具有通常知識者,在不悖離本發明之原理與精神的情形下,當可對其進行各種更動與修飾。The descriptions of the above embodiments are merely examples, and those skilled in the art can make various modifications. The description, experimental examples, and data provide a complete structural description and uses of specific embodiments of the invention. Even though the multiple embodiments of the present invention are described or referred to one or more individual embodiments in a specific and specific manner, they are not intended to limit the present invention. Those with ordinary knowledge in the technical field to which the present invention pertains, without Under the circumstances of the principle and spirit of the invention, various changes and modifications can be made to it.

10、20、30、40‧‧‧紗線10, 20, 30, 40‧‧‧ yarn

11、41‧‧‧聚合絲線11, 41‧‧‧ polymer silk

11C‧‧‧核芯11C‧‧‧Core

11S‧‧‧外鞘11S‧‧‧ Outer Sheath

21、31‧‧‧第一聚合絲線21, 31‧‧‧ the first polymer yarn

22、32‧‧‧第二聚合絲線22, 32‧‧‧Second polymerized yarn

為讓本說明能更明顯易懂,所附圖式之說明如下:To make this description more obvious and easy to understand, the description of the drawings is as follows:

圖1A 為依據本揭示內容一實施例所繪示之一種由芯-鞘複合纖維所構成之紗線的示意圖 ;1A is a schematic diagram of a yarn composed of a core-sheath composite fiber according to an embodiment of the present disclosure;

圖1B 為如圖1A所描述之紗線沿1-1’線段的剖面圖 ;Figure 1B is a sectional view of the yarn along the line 1-1 'as described in Figure 1A;

圖2A 為依據本揭示內容另一實施例所繪示之一種由混合纖維(comingled fibers)所構成之紗線的示意圖 ;Figure 2A is a schematic diagram of a yarn composed of mixed fibers according to another embodiment of the present disclosure;

圖2B 為如圖2A所描述之紗線沿2-2’線段的剖面圖 ;Figure 2B is a cross-sectional view of the yarn along the line 2-2 'as described in Figure 2A;

圖3A 為依據本揭示內容一實施例所繪示之一種由加捻纖維(twisted fibers)所構成之紗線的示意圖 ;3A is a schematic diagram of a yarn composed of twisted fibers according to an embodiment of the present disclosure;

圖3B 為如圖3A所描述之紗線沿3-3’線段的剖面圖 ;Figure 3B is a sectional view of the yarn along the line 3-3 'as described in Figure 3A;

圖4A 為依據本揭示內容一實施例所繪示之一種由空芯纖維(hollow core fiber)所組成之紗線的示意圖 ;4A is a schematic diagram of a yarn composed of a hollow core fiber according to an embodiment of the present disclosure;

圖4B 為如圖4A所描述之紗線沿4-4’線段的剖面圖 ;Figure 4B is a sectional view of the yarn along the line 4-4 'as described in Figure 4A;

圖5 為依據本揭示內容一實施例所繪示之藉由6-頭繡花機而繡有2D格狀圖案之布的實際相片圖 ;Figure 5 is an actual photo drawing of a cloth embroidered with a 2D grid pattern by a 6-head embroidery machine according to an embodiment of the present disclosure;

圖6 為依據本揭示內容一實施例所繪示之藉由具有綑綁裝置的機械而繡有熱活化後圖案之布的實際相片圖 ;Figure 6 is an actual photo drawing of a cloth embroidered with a thermally activated pattern by a machine having a binding device according to an embodiment of the present disclosure;

圖7 為依據本揭示內容一實施例所繪示之藉由6-頭繡花機而繡有圖案之布所形成的一熱可塑物件的實際相片圖 ;FIG. 7 is an actual photo drawing of a thermoplastic object formed by a cloth embroidered with a pattern by a 6-head embroidery machine according to an embodiment of the present disclosure;

圖8A為依據本揭示內容一實施例所繪示之熱可塑性布的實際相片圖 ;FIG. 8A is an actual photo diagram of a thermoplastic cloth according to an embodiment of the present disclosure; FIG.

圖8B為依據本申請如圖8A所述的熱可塑性布經熱活化後的實際相片圖 ;Figure 8B is an actual photo of the thermoplastic cloth according to the present application as described in Figure 8A after thermal activation;

圖9為依據本揭示內容一實施例所繪示之由熱可塑性布製得的矩形物件的實際相片圖。FIG. 9 is an actual photo diagram of a rectangular object made of a thermoplastic cloth according to an embodiment of the present disclosure.

圖10為依據本申請一實施例所繪示之由熱可塑性布製得的日型環扣的實際相片圖。FIG. 10 is an actual photo diagram of a Japanese-style ring buckle made of a thermoplastic cloth according to an embodiment of the present application.

圖11為依據本揭示內容一實施例,藉由熱活化一透過雙面提花針織法所產生之熱可塑性布所形成的3D矩形形狀的實際相片圖。FIG. 11 is an actual photo diagram of a 3D rectangular shape formed by thermally activating a thermoplastic fabric produced by a double-sided jacquard knitting method according to an embodiment of the present disclosure.

圖12為依據本揭示內容一實施例,藉由雙面提花針織法所產生之熱可塑性布的兩面的實際相片圖,其中所述布的正面以藍色代表,所述布的背面則以白色代表。FIG. 12 is an actual photo view of two sides of a thermoplastic fabric produced by a double-sided jacquard knitting method according to an embodiment of the present disclosure, wherein the front of the cloth is represented by blue, and the back of the cloth is represented by white representative.

依據通常描述,多個被描述的特徵或元件並未用於定義範圍,而是用於描述與本發明有關之最佳具體特徵或元件。此外,不同圖式中的相同符號或名稱被用於描述相同元件或部位。According to the general description, a plurality of described features or elements are not used to define the scope, but are used to describe the best specific features or elements related to the present invention. In addition, the same symbols or names in different drawings are used to describe the same elements or parts.

no

Claims (10)

一種熱可塑性布包含 : 一高熔點溫度區及一低熔點溫度區,分別由具有高熔點及低熔點的紗線所構成 ,其中,於所述高熔點溫度區及所述低熔點溫度區的熔點彼此相差約 30℃至150℃,且所述低熔點溫度區之布在熱活化後會硬化,而所述高熔點溫度區之布在熱活化後仍維持柔軟。A thermoplastic fabric includes: a high melting point temperature zone and a low melting point temperature zone, which are respectively composed of yarns having a high melting point and a low melting point, wherein the melting points in the high melting point temperature zone and the low melting point temperature zone The difference between each other is about 30 ° C. to 150 ° C., and the cloth in the low melting point temperature region will harden after thermal activation, while the cloth in the high melting point temperature region remains soft after thermal activation. 如請求項1所述之熱可塑性布,其中,每一紗線是由複數條纖維所組成,每一纖維分別是由聚對苯二甲酸乙二酯 (PET)、低熔點共聚酯或其組合所製成。The thermoplastic cloth according to claim 1, wherein each yarn is composed of a plurality of fibers, and each fiber is respectively polyethylene terephthalate (PET), a low-melting copolyester, or Made by combination. 如請求項2所述之熱可塑性布,其中,所述低熔點共聚酯是一由對苯二甲酸(PTA)、乙二醇(EG)以及一脂肪族單體組成的共聚物,其中,所述脂肪族單體是選自由穀胺酸、己二酸、庚二酸、辛二酸、癸二酸、新戊二醇及丁二醇組成之群組中。The thermoplastic cloth according to claim 2, wherein the low-melting copolyester is a copolymer composed of terephthalic acid (PTA), ethylene glycol (EG), and an aliphatic monomer, wherein, The aliphatic monomer is selected from the group consisting of glutamic acid, adipic acid, pimelic acid, suberic acid, sebacic acid, neopentyl glycol, and butanediol. 如請求項3所述之熱可塑性布,其中,所述低熔點共聚酯是由對苯二甲酸(PTA)、乙二醇(EG)以及癸二酸組成共聚物。The thermoplastic cloth according to claim 3, wherein the low-melting copolyester is a copolymer composed of terephthalic acid (PTA), ethylene glycol (EG), and sebacic acid. 如請求項1所述之熱可塑性布,其中,所述低熔點溫度區是藉由將具有低熔點的紗線繡於所述高熔點溫度區之布上而形成。The thermoplastic fabric according to claim 1, wherein the low melting point temperature region is formed by embroidering a yarn having a low melting point on the cloth having the high melting point temperature region. 如請求項1所述之熱可塑性布,其中,所述高熔點溫度區及所述低熔點溫度區分別是藉由針織或梭織具有高熔點及低熔點的紗線而形成的。The thermoplastic fabric according to claim 1, wherein the high melting point temperature region and the low melting point temperature region are formed by knitting or woven yarns having a high melting point and a low melting point, respectively. 如請求項1所述之熱可塑性布,其中,所述熱活化包含對所述熱可塑性布加熱直到溫度達到所述低熔點溫度區的熔點溫度,但未超過所述高熔點溫度區的熔點溫度。The thermoplastic fabric according to claim 1, wherein the thermal activation comprises heating the thermoplastic fabric until the temperature reaches the melting point temperature in the low melting point temperature region, but does not exceed the melting point temperature in the high melting point temperature region. . 一種物件,其是藉由熱活化如請求項1所述之熱可塑性布,進而在所述熱可塑性布上直接形成所述物件的形狀。An article is obtained by thermally activating the thermoplastic cloth according to claim 1, and then directly forming the shape of the article on the thermoplastic cloth. 如請求項8所述之物件,其中,所述物件的形狀是藉由對如請求項1所述之熱可塑性布加熱直到溫度達到所述低熔點溫度區的熔點溫度,但未超過所述高熔點溫度區的熔點溫度,而形成的。The article according to claim 8, wherein the shape of the article is obtained by heating the thermoplastic fabric according to claim 1 until the temperature reaches the melting point temperature in the low melting point temperature range, but does not exceed the high melting point temperature. The melting point temperature is formed by the melting point temperature. 如請求項9所述之物件,其中,所述物件的形狀是在所述熱活化過程中搭配使用一模具而形成的。The article according to claim 9, wherein the shape of the article is formed by using a mold during the thermal activation process.
TW107110493A 2017-03-30 2018-03-27 Thermo-shapeable fabrics and articles made therefrom TW201840921A (en)

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US4155214A (en) * 1977-10-14 1979-05-22 E. I. Du Pont De Nemours And Company Yarn product and process
US5380477A (en) * 1993-05-25 1995-01-10 Basf Corporation Process of making fiber reinforced laminates
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