TW201828821A - Powdery plant extract for beverages and method for manufacturing same - Google Patents

Powdery plant extract for beverages and method for manufacturing same Download PDF

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TW201828821A
TW201828821A TW106134451A TW106134451A TW201828821A TW 201828821 A TW201828821 A TW 201828821A TW 106134451 A TW106134451 A TW 106134451A TW 106134451 A TW106134451 A TW 106134451A TW 201828821 A TW201828821 A TW 201828821A
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branched
plant extract
glucose
beverages
glucan
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TW106134451A
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Chinese (zh)
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TWI753025B (en
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井上紳一郎
渡邊光
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日商林原股份有限公司
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23FCOFFEE; TEA; THEIR SUBSTITUTES; MANUFACTURE, PREPARATION, OR INFUSION THEREOF
    • A23F3/00Tea; Tea substitutes; Preparations thereof
    • A23F3/16Tea extraction; Tea extracts; Treating tea extract; Making instant tea
    • A23F3/30Further treatment of dried tea extract; Preparations produced thereby, e.g. instant tea
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23FCOFFEE; TEA; THEIR SUBSTITUTES; MANUFACTURE, PREPARATION, OR INFUSION THEREOF
    • A23F3/00Tea; Tea substitutes; Preparations thereof
    • A23F3/16Tea extraction; Tea extracts; Treating tea extract; Making instant tea
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23FCOFFEE; TEA; THEIR SUBSTITUTES; MANUFACTURE, PREPARATION, OR INFUSION THEREOF
    • A23F5/00Coffee; Coffee substitutes; Preparations thereof
    • A23F5/24Extraction of coffee; Coffee extracts; Making instant coffee
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/385Concentrates of non-alcoholic beverages
    • A23L2/39Dry compositions
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/52Adding ingredients
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2250/00Food ingredients
    • A23V2250/60Sugars, e.g. mono-, di-, tri-, tetra-saccharides
    • A23V2250/61Glucose, Dextrose

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Non-Alcoholic Beverages (AREA)
  • Tea And Coffee (AREA)

Abstract

The present invention addresses the problem of providing a powdery plant extract for beverages having an excellent flavor-retention effect and high solubility. To solve this problem, provided is a powdery plant extract for beverages which comprises a drinkable plant extract and a branched [alpha]-glucan mixture, said branched [alpha]-glucan mixture having properties (A) to (C), at a ratio by mass in terms of solid of 1:0.1 to 1:20: (A) containing glucose as a constituting sugar; (B) having a branched structure with a glucose polymerization degree of 1 or greater that is connected, via a bond other than an [alpha]-1,4 bond, to a non-reducing terminal glucose residue positioned at an end of a linear glucan with a glucose polymerization degree of 3 or greater connected via an [alpha]-1,4 bond; and (C) when digested by isomaltodextranase, forming isomaltose in an amount of 5 mass% or more relative to solid digestion products.

Description

飲料用粉末植物萃取物及其製造方法Powdered plant extracts for beverages and method of manufacturing the same

[0001] 本發明係關於飲料用粉末植物萃取物,更詳細而言,係關於溶解性優異,若進行溶解則賦予與通常的植物萃取物飲料(綠茶、紅茶、咖啡等)同等的香氣、風味之飲料用粉末植物萃取物及其製造方法。[0001] The present invention relates to powdered plant extracts for beverages, more specifically, it is excellent in solubility, and when dissolved, imparts the same aroma and flavor as ordinary plant extract beverages (green tea, black tea, coffee, etc.) Powdered plant extracts for beverages and methods for making the same.

[0002] 由於粉末綠茶等所代表之將提取自植物之萃取物(飲用植物萃取物)進行粉末化而成之飲料用粉末植物萃取物係呈粉末形態,因而保存比較容易,再者,只要裝入茶杯等容器中並注入熱水等,即可簡便地調製植物萃取物飲料,故為有用。   [0003] 然而,此種飲料用粉末植物萃取物在其製造時及保存時,會有源自飲用植物萃取物之風味變質或者揮發而流失之問題。為了保持源自植物萃取物之風味,已提案出使用各種粉末化基材之多種方法,但仍未提案出就風味保持之方面而言可充分令人滿意者。除此以外,會發生因使用粉末化基材而使對水或熱水之溶解性降低之事態。   [0004] 舉例而言,在專利文獻1中,已揭示藉由將溶解並含有茶類萃取物及DE10~25的糊精而成之水溶液在二氧化碳溶存下進行噴霧乾燥而製造具有優異的風味及溶解性之即溶茶類之方法。然而,由於添加糊精,故會有因源自糊精之糊臭或黏性而損及茶原本的風味之課題。   [0005] 在專利文獻2中,已揭示藉由摻和具特定聚合度之麥芽寡醣而獲得之保持茶葉所持有之風味且保存安定性優異的即泡茶。然而,由於其大多使用麥芽四糖、麥芽五糖、麥芽六糖等麥芽寡醣,因而會有因源自此等麥芽寡醣之甜味而損及茶原本的風味之情形。   [0006] 在專利文獻3中,已揭示藉由使用環糊精而製造即便長期保存亦無香氣成分等的變質且具有與以通常的喝茶法所獲得之茶湯幾乎同樣的風味之保存安定性優異的即溶茶之方法。然而,由於此方法含有環糊精,故會有茶萃取物獨特的苦味被掩蓋,就結果而言損及茶原本的風味之疑慮。   [0007] 在專利文獻4中,已揭示藉由使用難消化性糊精作為粉末化基材,使二氧化碳溶解於含有茶萃取物及難消化性糊精之溶液中並進行噴霧乾燥而製造溶解時之香氣良好且適口性優異的即溶茶之方法。然而,此方法僅是將難消化性糊精混合於茶萃取物中而製成即溶茶,對水或熱水之溶解性較差,就需要使二氧化碳進一步溶解於添加並溶解有難消化性糊精之茶萃取物中並進行噴霧乾燥之步驟之方面而言,會有較費事之不便處。   [0008] 據申請人所知,調製步驟簡單並具有可充分令人滿意的溶解性且保持飲用植物萃取物原本的風味之飲料用粉末植物萃取物仍未被提供。該種狀況下,在該領域中,正殷切盼望不會損及飲用植物萃取物原本的風味、香氣等且溶解性優異的飲料用粉末植物萃取物及其製造方法。 [先前技術文獻] [專利文獻]   [0009]   [專利文獻1]日本專利特開昭60-210949號公報   [專利文獻2]日本專利特開2001-000108號公報   [專利文獻3]日本專利特開2000-253820號公報   [專利文獻4]日本專利特開2009-017867號公報[0002] Powdered plant extracts such as powdered green tea and the like are powdered plant extracts for beverages obtained by pulverizing plant extracts (drinking plant extracts) in powder form, so storage is relatively easy. It is useful because it can be easily prepared by pouring beverages such as tea cups and pouring hot water. [0003] However, such powdered plant extracts for beverages have a problem in that the flavor derived from drinking plant extracts deteriorates or volatilizes when they are manufactured and stored. In order to maintain the flavor derived from plant extracts, various methods using various powdered substrates have been proposed, but there has not yet been proposed a one that is sufficiently satisfactory in terms of flavor retention. In addition to this, the use of powdered base materials may reduce the solubility in water or hot water. [0004] For example, Patent Document 1 discloses that an aqueous solution prepared by dissolving and containing a tea extract and dextrins of DE10 to 25 is spray-dried under carbon dioxide dissolution to produce an excellent flavor and The method of dissolving instant tea. However, due to the addition of dextrin, there is a problem that the original flavor of the tea is impaired due to the paste smell or viscosity derived from dextrin. [0005] Patent Document 2 discloses a brewed tea that is obtained by blending malto-oligosaccharides with a specific degree of polymerization to maintain the flavor held by tea leaves and has excellent storage stability. However, since most of them use maltooligosaccharides such as maltotetraose, maltopentaose, maltohexaose, etc., the original flavor of tea may be impaired due to the sweet taste derived from these maltooligosaccharides. . [0006] Patent Document 3 discloses that the use of cyclodextrin to produce a long-term storage has no deterioration of aroma components and the like, and has a storage stability of almost the same flavor as the tea soup obtained by the usual tea drinking method Excellent method of instant tea. However, since this method contains cyclodextrin, the unique bitterness of the tea extract may be masked, and as a result, the original flavor of the tea may be compromised. [0007] Patent Document 4 discloses that when indigestible dextrin is used as a powdered base material, carbon dioxide is dissolved in a solution containing tea extract and indigestible dextrin and spray-dried to produce a solution A method of instant tea with good aroma and excellent palatability. However, this method only mixes indigestible dextrin with tea extract to make instant tea. The solubility in water or hot water is poor, so it is necessary to further dissolve carbon dioxide in the added and dissolved indigestible dextrin. In terms of the step of spray drying the tea extract, it is more inconvenient. [0008] As far as the applicant knows, powdered plant extracts for beverages that have simple preparation steps and have sufficiently satisfactory solubility and maintain the original flavor of drinking plant extracts have not yet been provided. Under such circumstances, in this field, it is earnestly looking forward to powdered plant extracts for beverages that are excellent in solubility, and a method for producing the same, without compromising the original flavor and aroma of the drinking plant extracts. [Prior Art Literature] [Patent Literature] [0009] [Patent Literature 1] Japanese Patent Laid-Open No. Sho 60-210949 [Patent Literature 2] Japanese Patent Laid-Open No. 2001-000108 [Patent Literature 3] Japanese Patent Laid-Open Gazette 2000-253820 [Patent Document 4] Japanese Patent Laid-Open No. 2009-017867

[發明所欲解決之課題]   [0010] 本發明係有鑑於上述習知技術的現狀而完成者,其課題為提供保持飲用植物萃取物原本的風味及香氣而且溶解性優異的飲料用粉末植物萃取物及其製造方法。 [解決課題之手段]   [0011] 本發明者等人在為了解決上述課題而致力進行研究之過程中,發現將本申請人於國際公開第WO2008/136331號小冊所揭示之分枝α-葡聚醣混合物對飲用植物萃取物以成為一定的質量比之方式進行摻和並粉末化而成之飲料用粉末植物萃取物相較於習知的飲料用粉末植物萃取物而言,令人意外地不僅飲用植物萃取物原本的風味、香氣優異,亦對水具有較高的溶解性,同時亦確立其製造方法,遂完成本發明。   [0012] 即,本發明係藉由提供包含飲用植物萃取物及具有下述(A)至(C)的特徵之分枝α-葡聚醣混合物之飲料用粉末植物萃取物而解決上述課題,該飲料用粉末植物萃取物中所包含之飲用植物萃取物與分枝α-葡聚醣混合物之按固形物換算之質量比為1:0.1~1:20;   (A)以葡萄糖作為構成糖,   (B)在位於經由α-1,4鍵結連結而成之葡萄糖聚合度3以上的直鏈狀葡聚醣的一端之非還原末端葡萄糖殘基具有經由α-1,4鍵結以外之鍵結連結而成之葡萄糖聚合度1以上的分枝結構,   (C)藉由異麥芽葡聚醣酶消化,而生成每消化物的固形物5質量%以上異麥芽糖。   [0013] 再者,本發明係藉由提供包含下列步驟之飲料用粉末植物萃取物之製造方法而解決上述課題:在水性溶媒的共存下,將具有下述(A)至(C)的特徵之分枝α-葡聚醣混合物對飲用植物萃取物以飲用植物萃取物與分枝α-葡聚醣混合物之按固形物換算之質量比成為1:0.1~1:20之方式進行混合,而獲得混合溶液之步驟;以及將所獲得之混合溶液進行粉末化之步驟。 [發明效果]   [0014] 本發明之飲料用粉末植物萃取物不會損及飲用植物萃取物原本的風味、香氣,使其溶解於水等液體中時,顯示出相較於習知的飲料用粉末植物萃取物而言更優異的溶解性。此外,根據本發明之製造方法,可僅以混合並粉末化之簡單的步驟調製前述飲料用粉末植物萃取物,故可在工業上容易且大量、價格低廉且安定地製造前述飲料用粉末植物萃取物。[Problems to be solved by the invention] [0010] The present invention was completed in view of the above-mentioned current state of the art, and its object is to provide powder plant extracts for beverages that maintain the original flavor and aroma of drinkable plant extracts and have excellent solubility Thing and its manufacturing method. [Means for Solving the Problem] [0011] In the course of their efforts to solve the above-mentioned problems, the inventors of the present invention found that the branch of the applicant disclosed in the International Publication No. WO2008 / 136331, branch α-Portuguese The glycan mixture is surprisingly surprising when compared to the conventional powdered plant extracts for beverages, the powdered plant extracts for beverages obtained by blending and pulverizing the drink plant extracts with a certain mass ratio are powdered. Not only the original flavor and aroma of drinking plant extracts are excellent, but also high solubility in water. At the same time, the manufacturing method is established to complete the present invention. [0012] That is, the present invention solves the above-mentioned problems by providing a powdered plant extract for beverages containing a drinkable plant extract and a branched α-glucan mixture having the following characteristics (A) to (C), The mass ratio in terms of solids of the mixture of drinking plant extracts and branched α-glucan contained in the powdered plant extracts for beverages is 1: 0.1 to 1:20; (A) uses glucose as a constituent sugar, (B) The non-reducing terminal glucose residue at one end of a linear glucan having a glucose polymerization degree of 3 or more linked by an α-1,4 bond has a bond other than the α-1,4 bond The branched structure of the glucose polymerization degree of 1 or more formed by the connection is digested by isomaltoglucanase to produce isomaltose of 5 mass% or more per solid of the digested matter. [0013] Furthermore, the present invention solves the above problem by providing a method for manufacturing a powdered plant extract for beverages including the following steps: in the coexistence of an aqueous solvent, it will have the following characteristics (A) to (C) The branched α-glucan mixture is mixed with the drinking plant extract in such a manner that the mass ratio of the drinking plant extract and the branched α-glucan mixture in terms of solids becomes 1: 0.1 to 1:20, and The step of obtaining a mixed solution; and the step of powdering the obtained mixed solution. [Effects of the invention] [0014] The powdered plant extract for beverages of the present invention does not impair the original flavor and aroma of drinking plant extracts, and when it is dissolved in liquids such as water, it shows that it is compared with conventional beverages. The powdered plant extract has better solubility. In addition, according to the manufacturing method of the present invention, the powdered plant extract for beverage can be prepared only in a simple step of mixing and pulverization, so the powdered plant extract for beverage can be manufactured industrially easily and in large quantities, at low cost, and stably Thing.

[0015] 本發明為涉及飲料用粉末植物萃取物及其製造方法之發明,前述飲料用粉末植物萃取物包含飲用植物萃取物及具有下述(A)至(C)的特徵之分枝α-葡聚醣混合物,該飲料用粉末植物萃取物中所包含之飲用植物萃取物與分枝α-葡聚醣混合物之按固形物換算之質量比為1:0.1~1:20;   (A)以葡萄糖作為構成糖,   (B)在位於經由α-1,4鍵結連結而成之葡萄糖聚合度3以上的直鏈狀葡聚醣的一端之非還原末端葡萄糖殘基具有經由α-1,4鍵結以外之鍵結連結而成之葡萄糖聚合度1以上的分枝結構,   (C)藉由異麥芽葡聚醣酶消化,而生成每消化物的固形物5質量%以上異麥芽糖。   [0016] 本說明書中所謂的飲料用粉末植物萃取物,係意味將藉由水性溶媒提取自植物之飲用植物萃取物進行乾燥、粉末化而成者。在此處,作為植物,具體而言,可列舉茶樹(Camellia sinensis)、阿薩姆紅茶(Assam)等茶樹類;洋甘菊、洛神花、薰衣草、薄荷、玫瑰果、胡椒薄荷、檸檬草、魚腥草、匙羹藤、大花紫薇、銀杏、黃麻菜、紫花苜蓿、魁蒿、巴拉圭冬青、佳葉龍茶、杜仲、南非茶、蘆薈、櫻葉、紫蘇等藥草(香草)類;麥、薏米、稻、大豆、蕎麥等穀物類;朝鮮人蔘、牛蒡等根菜類;咖啡樹等。   [0017] 本說明書中所謂的飲用植物萃取物,係意味將選自上述植物的葉、莖、花、萼、根、種子等之一種以上部位視需要施行乾燥、焙煎、發酵等加工,並進行提取而製作者。作為該種飲用植物萃取物之具體例,可列舉綠茶、烏龍茶、紅茶、焙茶、粗茶、香草茶、杜仲茶、南非茶、魚腥草茶、麥茶、薏米、玄米茶、蕎麥茶、牛蒡茶、咖啡生豆茶等。   [0018] 本說明書中所謂的分枝α-葡聚醣混合物,係意味例如與本案相同的申請人於國際公開第WO2008/136331號小冊等所揭示之分枝α-葡聚醣混合物(以下,僅稱為「分枝α-葡聚醣混合物」)。該分枝α-葡聚醣混合物係以澱粉作為原料,使各種酵素對其進行作用而獲得,通常呈以具有各式各樣的分枝結構及葡萄糖聚合度之複數種分枝α-葡聚醣作為主體之混合物的形態。作為該分枝α-葡聚醣混合物之製造方法,可例示使前述國際公開第WO2008/136331號小冊所揭示之α-葡萄糖苷基轉移酵素作用於澱粉質,或者除了前述α-葡萄糖苷基轉移酵素以外,復併用麥芽四糖生成澱粉酶(EC 3.2.1.60)等澱粉酶、支鏈澱粉酶(EC 3.2.1.41)、異澱粉酶(EC 3.2.1.68)等澱粉去支酵素,再者,環麥芽糊精葡聚醣轉移酶(EC 2.4.1.19)、澱粉分支酵素(EC 2.4.1.18)或日本專利特開2014-54221號公報等所揭示之具有將聚合度2以上的α-1,4葡聚醣進行α-1,6轉移至澱粉質內部的葡萄糖殘基之活性之酵素等之1或複數種並使其作用於澱粉質之方法。在現行的技術中,單離至構成本發明所使用之分枝α-葡聚醣混合物之各個分枝α-葡聚醣分子為止並進行定量或者決定其結構,即,屬於其構成單位之葡萄糖殘基的鍵結樣式及鍵結順序,實為不可能或極為困難,該分枝α-葡聚醣混合物可藉由該領域中一般所使用之各種物理手法、化學手法或酵素手法,就混合物整體而言賦予特徵。   [0019] 即,本發明所使用之分枝α-葡聚醣混合物的結構係就混合物整體而言藉由上述(A)至(C)的特徵而被賦予特徵。本分枝α-葡聚醣混合物為以葡萄糖作為構成糖之葡聚醣(特徵(A)),在位於經由α-1,4鍵結連結而成之葡萄糖聚合度3以上的直鏈狀葡聚醣的一端之非還原末端葡萄糖殘基具有經由α-1,4鍵結以外之鍵結連結而成之葡萄糖聚合度1以上的分枝結構(特徵(B))。另外,特徵(B)所謂的「非還原末端葡萄糖殘基」,係意味位於經由α-1,4鍵結連結而成之葡聚醣鏈中未顯示出還原性之末端之葡萄糖殘基,所謂的「α-1,4鍵結以外之鍵結」,如字義為「α-1,4鍵結以外之鍵結」,其係意味α-1,2鍵結、α-1,3鍵結、α-1,6鍵結等α-1,4鍵結以外之鍵結。   [0020] 再者,本發明所使用之分枝α-葡聚醣混合物具備下列特徵:藉由異麥芽葡聚醣酶消化,每消化物的固形物生成5質量%以上異麥芽糖(特徵(C))。   [0021] 如此,本發明所使用之分枝α-葡聚醣混合物為藉由前述特徵(A)至(C)而被賦予特徵之葡聚醣混合物。該等特徵之內,若針對特徵(C)進行補充,則如以下所述。   [0022] 關於對本發明所使用之分枝α-葡聚醣混合物賦予特徵之前述特徵(C),所謂的異麥芽葡聚醣酶消化,係意味使異麥芽葡聚醣酶作用於該分枝α-葡聚醣混合物,並進行水解。異麥芽葡聚醣酶為被賦予酵素編號(EC)3.2.1.94之酵素,其係具有無論是鄰接於α-葡聚醣中之異麥芽糖結構的還原末端側之α-1,2、α-1,3、α-1,4及α-1,6鍵結中之任何鍵結樣式皆會予以水解之特徵之酵素。在異麥芽葡聚醣酶消化中,較適當係使用源自球形節桿菌(Arthrobacter Globiformis)之異麥芽葡聚醣酶(參照例如Sawai等人,Agricultural and Biological Chemistry,第52卷,第2號,第495頁-501頁(1988))。   [0023] 藉由前述異麥芽葡聚醣酶消化所生成之每消化物的固形物之異麥芽糖的比例係表示構成分枝α-葡聚醣混合物之分枝α-葡聚醣的結構中之經異麥芽葡聚醣酶水解所獲得之異麥芽糖結構的比例,藉由特徵(C),可對本分枝α-葡聚醣混合物的結構就混合物整體而言藉由酵素手法賦予特徵。   [0024] 本發明所使用之分枝α-葡聚醣混合物係藉由異麥芽葡聚醣酶消化,而生成每消化物的固形物通常5質量%以上,較佳為10質量%以上,更佳為15質量%以上,再佳為20質量%以上且70質量%以下,再更佳為20質量%以上且60質量%以下異麥芽糖,使用此將飲用植物萃取物進行粉末化時之植物萃取物原本的風味之保持效果較強,可更適當地用在實施本發明上。   [0025] 即,如後述,一般認為構成分枝α-葡聚醣混合物之各個α-葡聚醣分子中之異麥芽糖結構係與本發明之飲料用粉末植物萃取物溶解時之風味保持深切相關。異麥芽葡聚醣酶消化中之異麥芽糖生成量未滿5質量%的分枝α-葡聚醣混合物會變得具有近似於分枝結構較少之麥芽糊精之結構,一般認為與飲料用粉末植物萃取物溶解時之風味保持相關之結構特徵變弱,故較不佳,對於利用異麥芽葡聚醣酶消化而得之異麥芽糖的量,係存在適當範圍。   [0026] 此外,作為本發明所使用之分枝α-葡聚醣混合物之一更適當的態樣,可列舉具有藉由高效液相層析(酵素-HPLC法)所求出之水溶性食物纖維含量為40質量%以上之特徵(D)者。   [0027] 關於對本發明所使用之分枝α-葡聚醣混合物賦予特徵之前述特徵(D),求出水溶性食物纖維含量之所謂的「高效液相層析法(酵素-HPLC法)」(以下,僅稱為「酵素-HPLC法」),係日本平成8年5月厚生省告示第146號之營養標示基準,「營養成分等之分析方法等(營養標示基準別表第1之第3欄所揭載之方法)」中之第8項,「食物纖維」所記載之方法,若說明其概略,則如下。即,藉由利用熱安定α-澱粉酶、蛋白酶及葡萄糖澱粉酶之一連串酵素處理對試料進行分解處理,藉由以離子交換樹脂自處理液中去除蛋白質、有機酸、無機鹽類而調製凝膠過濾層析用試料溶液。接著,供至凝膠過濾層析,求出層析圖中之未消化葡聚醣及葡萄糖的峰面積,使用各峰面積以及另行依常法藉由葡萄糖/氧化酶法所預先求出之試料溶液中之葡萄糖量,算出試料之水溶性食物纖維含量。另外,本說明書通篇所謂的「水溶性食物纖維含量」,在沒有特別說明之前提下,係意味以前述「酵素-HPLC法」所求出之水溶性食物纖維含量。   [0028] 水溶性食物纖維含量係表示未被α-澱粉酶及葡萄糖澱粉酶分解之α-葡聚醣的含量,特徵(D)為對本分枝α-葡聚醣混合物的結構就混合物整體而言藉由酵素手法賦予特徵之指標之一。   [0029] 具有上述特徵(A)~(C),同時水溶性食物纖維含量為40質量%以上且未滿100質量%,較佳為50質量%以上且未滿95質量%,更佳為60質量%以上且未滿90質量%,再佳為70質量%以上且未滿85質量%之分枝α-葡聚醣混合物,將飲料用粉末植物萃取物溶解於水等中時之風味保持效果較強,可更適當地用在實施本發明上。   [0030] 再者,作為本分枝α-葡聚醣混合物之一更適當的態樣,可列舉具有下述特徵(E)及(F)者,該特徵可藉由甲基化分析求出。   (E)經α-1,4鍵結之葡萄糖殘基與經α-1,6鍵結之葡萄糖殘基之比係在1:0.6至1:4的範圍,   (F)經α-1,4鍵結之葡萄糖殘基及經α-1,6鍵結之葡萄糖殘基之合計佔所有葡萄糖殘基的55%以上。   [0031] 所謂的甲基化分析,係如所週知,為一般所泛用作為在多醣或寡醣中,決定構成該等之單醣的鍵結樣式之方法之方法(Ciucanu等人,Carbohydrate Research,第131卷,第2號,第209-217頁(1984))。在將甲基化分析應用於葡聚醣中之葡萄糖的鍵結樣式的分析之情況,首先,將構成葡聚醣之葡萄糖殘基中之所有游離的羥基進行甲基化,接著,將經完全甲基化之葡聚醣進行水解。接著,將藉由水解所獲得之甲基化葡萄糖進行還原而製成經消去變旋異構物型之甲基化葡萄糖醇,再者,藉由將此甲基化葡萄糖醇中之游離的羥基進行乙醯化而獲得部分甲基化葡萄糖醇乙酸酯(另外,有時將「部分甲基化葡萄糖醇乙酸酯」僅總稱為「部分甲基化物」)。藉由將所獲得之部分甲基化物以氣相層析進行分析,可將源自葡聚醣中鍵結樣式各自不同的葡萄糖殘基之各種部分甲基化物以在氣相層析圖中之所有部分甲基化物的峰面積中所佔之峰面積的百分率(%)表示。又,可由此峰面積%決定該葡聚醣中之鍵結樣式不同的葡萄糖殘基之存在比,即,各葡萄糖苷鍵結的存在比率。針對部分甲基化物之「比」應意味甲基化分析之氣相層析圖中之峰面積之「比」,針對部分甲基化物之「%」應意味甲基化分析之氣相層析圖中之「面積%」。   [0032] 上述(E)及(F)中之所謂的「經α-1,4鍵結之葡萄糖殘基」,係僅經由鍵結至1位及4位碳原子之羥基鍵結至其他葡萄糖殘基而成之葡萄糖殘基,在甲基化分析中,係以2,3,6-三甲基-1,4,5-三乙醯基葡萄糖醇之形式被檢測出。此外,上述(E)及(F)中之所謂的「經α-1,6鍵結之葡萄糖殘基」,係僅經由鍵結至1位及6位碳原子之羥基鍵結至其他葡萄糖殘基而成之葡萄糖殘基,在甲基化分析中,係以2,3,4-三甲基-1,5,6-三乙醯基葡萄糖醇之形式被檢測出。   [0033] 藉由甲基化分析所獲得之經α-1,4鍵結之葡萄糖殘基與經α-1,6鍵結之葡萄糖殘基之比率,以及經α-1,4鍵結之葡萄糖殘基及經α-1,6鍵結之葡萄糖殘基相對於所有葡萄糖殘基之比例可用作對本分枝α-葡聚醣混合物的結構就混合物整體而言藉由化學手法賦予特徵之指標之一。   [0034] 上述(E)之「經α-1,4鍵結之葡萄糖殘基與經α-1,6鍵結之葡萄糖殘基之比係在1:0.6至1:4的範圍」之特徵係意味在將本分枝α-葡聚醣混合物供至甲基化分析時,所檢測出之2,3,6-三甲基-1,4,5-三乙醯基葡萄糖醇與2,3,4-三甲基-1,5,6-三乙醯基葡萄糖醇之比係在1:0.6至1:4的範圍。此外,上述(F)之「經α-1,4鍵結之葡萄糖殘基及經α-1,6鍵結之葡萄糖殘基之合計佔所有葡萄糖殘基的55%以上」之特徵係意味本分枝α-葡聚醣混合物在甲基化分析中,2,3,6-三甲基-1,4,5-三乙醯基葡萄糖醇及2,3,4-三甲基-1,5,6-三乙醯基葡萄糖醇之合計佔部分甲基化葡萄糖醇乙酸酯的55%以上。通常,澱粉不具有僅經以1位及6位鍵結之葡萄糖殘基,且經α-1,4鍵結之葡萄糖殘基佔所有葡萄糖殘基中之大半數,因而上述(E)及(F)之要件係意味本分枝α-葡聚醣混合物具有與澱粉完全不同的結構。   [0035] 如上述(E)及(F)的特徵所規定,本分枝α-葡聚醣混合物在一較佳態樣中,為相當程度具有通常在澱粉中不存在之「經α-1,6鍵結之葡萄糖殘基」者,在需要較高的風味保持效果之情況,具有更複雜的分枝結構者可期待更高的效果,故較佳係除了α-1,4鍵結及α-1,6鍵結以外,復具有α-1,3鍵結及α-1,3,6鍵結。具體而言,例如經α-1,3鍵結之葡萄糖殘基較佳為所有葡萄糖殘基的0.5%以上且未滿10%,經α-1,3,6鍵結之葡萄糖殘基較佳為所有葡萄糖殘基的0.5%以上。在此處,所謂的「α-1,3,6鍵結」,係意味「以1位、3位及6位羥基共3處與其他葡萄糖進行鍵結而成(經α-1,3,6鍵結)之葡萄糖殘基」。   [0036] 上述「經α-1,3鍵結之葡萄糖殘基為所有葡萄糖殘基的0.5%以上且未滿10%」可藉由下列方式確認:將本分枝α-葡聚醣混合物供至甲基化分析時,存在有部分甲基化葡萄糖醇乙酸酯的0.5%以上且未滿10%的2,4,6-三甲基-1,3,5-三乙醯基葡萄糖醇。此外,上述「經α-1,3,6鍵結之葡萄糖殘基為所有葡萄糖殘基的0.5%以上」可藉由下列方式確認:本分枝α-葡聚醣混合物在甲基化分析中,存在有部分甲基化葡萄糖醇乙酸酯的0.5%以上且未滿10%的2,4-二甲基-1,3,5,6-四乙醯基葡萄糖醇。   [0037] 本分枝α-葡聚醣混合物亦可藉由重量平均分子量(Mw)以及將重量平均分子量(Mw)除以數量平均分子量(Mn)而得之值(Mw/Mn)賦予特徵。重量平均分子量(Mw)及數量平均分子量(Mn)可使用例如尺寸排除層析等求出。此外,由於可基於重量平均分子量(Mw)算出構成本分枝α-葡聚醣混合物之分枝α-葡聚醣的平均葡萄糖聚合度,故本分枝α-葡聚醣混合物亦可藉由平均葡萄糖聚合度賦予特徵。平均葡萄糖聚合度可自重量平均分子量(Mw)減去18,並將該分子量除以葡萄糖殘基量162而求出。飲料用粉末植物萃取物中所使用之本分枝α-葡聚醣混合物較適當係其平均葡萄糖聚合度通常為8至500,較佳為15至400,更佳為20至300。另外,分枝α-葡聚醣混合物就平均葡萄糖聚合度越大則黏度增大,平均葡萄糖聚合度越小則黏度變小之方面而言,係顯示出與通常的葡聚醣同樣的性質。因此,可因應本發明之飲料用粉末植物萃取物之實施態樣,適宜選擇使用具有符合作為飲料所要求之黏度之平均葡萄糖聚合度之本分枝α-葡聚醣混合物。   [0038] 關於將重量平均分子量(Mw)除以數量平均分子量(Mn)而得之值Mw/Mn,越接近1係意味構成分枝α-葡聚醣混合物之分枝α-葡聚醣分子的葡萄糖聚合度的偏差越小。飲用植物萃取物中所使用之本分枝α-葡聚醣混合物較適當係只要Mw/Mn通常為20以下即無問題而可使用,但較佳為10以下,更佳為5以下。   [0039] 本發明所使用之分枝α-葡聚醣混合物係如以上所述,在本發明的實施中,可使用前述國際公開第WO2008/136331號小冊所揭示之各種分枝α-葡聚醣混合物。該等之中,可更適當地使用將源自環狀芽孢桿菌(Bacillus circulans)PP710(FERM BP-10771)及/或源自球形節桿菌(Arthrobacter Globiformis)PP349(FERM BP-10770)之α-葡萄糖苷基轉移酵素單獨地,或者將該α-葡萄糖苷基轉移酵素與支鏈澱粉酶(EC 3.2.1.41)、異澱粉酶(EC 3.2.1.68)等澱粉去支酵素及/或環麥芽糊精葡聚醣轉移酶(EC 2.4.1.19(CGTase)進行組合,使其作用於澱粉原料所獲得之分枝α-葡聚醣混合物。再者,可尤其適當地使用由本申請人林原股份有限公司以異麥芽糊精(註冊商標『Fibryxa』)之形式進行販售之分枝α-葡聚醣混合物。   [0040] 本發明之飲料用粉末植物萃取物中所含有之分枝α-葡聚醣混合物的量,相對於飲用植物萃取物而言按固形物換算之質量比為1:0.1至1:20,較適當係以1:0.33至1:5的比例含有。以前述數值範圍包含分枝α-葡聚醣混合物之飲料用粉末植物萃取物為溶解性優異,在溶解時保持與植物萃取物飲料(綠茶、紅茶、咖啡等)同等的風味、香氣之飲料用粉末植物萃取物。另外,在該質量比未滿0.1之情況,分枝α-葡聚醣混合物所引發之上述效果變得無法充分發揮,故較不佳。此外,相反地,在該質量比超過20之情況,會因多量的分枝α-葡聚醣混合物而有風味、溶解性等特性惡化之傾向。另外,本發明飲料用粉末植物萃取物中所含有之α-葡聚醣混合物通常係以粉末形態對植物萃取物進行添加,視需要亦可適宜以使其溶解於水等中而成之溶液形態進行添加,亦可以呈糖漿形態者進行添加。   [0041] 本發明所對象之飲料用粉末植物萃取物之特徵為藉由含有分枝α-葡聚醣混合物而在使飲料用粉末植物萃取物溶解於水等液體中時,充分保持植物萃取物飲料原本的風味、香氣。藉由含有分枝α-葡聚醣混合物而有效地維持飲料用粉末植物萃取物的風味及香氣之機制不明,可推定或許具有上述(A)至(C)的特徵之本分枝α-葡聚醣混合物會與屬於植物萃取物飲料(特定而言,茶類)的主要風味及香氣成分之萜烯類、醛類、吡嗪類、吡咯類、呋喃類進行某些相互作用而保持風味。   [0042] 如此,本發明之飲料用粉末植物萃取物係藉由含有所定量的分枝α-葡聚醣混合物而有效地保持風味,除此以外,變得溶解性優異。另外,在本發明之飲料用粉末植物萃取物中,亦隨意視需要適量摻和分枝α-葡聚醣混合物以外之其他成分。作為其他成分,可例示例如保存劑、著色劑、賦形劑、黏合劑、矯味劑、抗氧化劑、pH調整劑、甜味料、香料、酸味料、調味料等,可適宜組合使用該等之1種或2種以上的適量。前述其他成分的摻和量只要是依其種類及其所摻和之飲料用粉末植物萃取物的種類適宜設定即可,通常,針對各成分,可例示按固形物換算,相對於飲料用粉末植物萃取物而言,選自0.0001質量%以上,較適當為0.001至30質量%,更適當為0.01至20質量%,再適當為0.01至10質量%的範圍之量。此外,前述其他成分只要在直至本發明之飲料用粉末植物萃取物完成為止之1或複數個步驟中適宜摻和其必要量即可。   [0043] 作為前述保存劑,可例示例如醋酸、檸檬酸、蘋果酸、富馬酸、乳酸等可食性有機酸類;乙醇、丙二醇、甘油等醇類;甘胺酸、丙胺酸等胺基酸類;食鹽、醋酸鹽、檸檬酸鹽、碳酸鈉、碳酸鉀、氧化鈣、氫氧化鈣、碳酸鈣、磷酸二鈉、磷酸三鉀等鹽類等。   [0044] 作為前述著色劑,可例示例如紅麴、蟹殼粉末、蝦青素、蔬菜色素、紅麴色素、濃縮法夫酵母(Phaffia)色素油、梔子黃、抹茶色素、胭脂紅色素、梔子黃色素、梔子藍色素、類黃酮色素、焦糖色素、β-胡蘿蔔素、類胡蘿蔔素系色素、木炭等天然色素;以及紅色2號、紅色3號、紅色104號、紅色105號、紅色106號、黃色4號、黃色5號、藍色1號、二氧化鈦等合成著色料。   [0045] 作為前述甜味料,可例示例如砂糖、葡萄糖、果糖、高果糖漿、甘草素、甜菊、阿斯巴甜(aspartame)、果寡醣等。   [0046] 本發明之飲料用粉末植物萃取物可溶於水、溫水、牛乳等中飲用,此外,可摻和至曲奇餅、薄脆餅、餅乾等餅乾類或果凍、慕斯、巴伐利亞奶凍、布丁、冰品、蕨餅、糰子、蒸麵包、磅蛋糕、戚風蛋糕、蛋奶酥等中。此外,亦可摻和至錠劑、顆粒等補充劑中。藉由摻和本發明之飲料用粉末植物萃取物,可對各種飲食品、錠劑、顆粒等賦予植物萃取物原本的風味。此等食品中之飲料用粉末植物萃取物的含有量亦依食品的種類而有所不同,一般而言較適當為1~100質量%,特定而言5~80質量%。   [0047] <本發明所涉及之飲料用粉末植物萃取物之製造方法>   本發明為涉及飲料用粉末植物萃取物之製造方法之發明,該飲料用粉末植物萃取物之製造方法包含下列步驟:在水性溶媒的共存下,將上述之具有(A)至(C)的特徵之分枝α-葡聚醣混合物對飲用植物萃取物以飲用植物萃取物與分枝α-葡聚醣混合物之按固形物換算之質量比成為1:0.1~1:20之方式進行混合,而獲得混合溶液之步驟;以及將所獲得之混合溶液進行粉末化之步驟。   [0048] 針對該飲料用粉末植物萃取物之製造方法,若具體敘述其概要,係在植物原料中加入水性溶媒,進行提取、粗分離,獲得提取液(提取步驟),在該提取液(植物萃取物)中添加混合分枝α-葡聚醣混合物並使其溶解,進一步將提取液進行濃縮(濃縮步驟),然後,藉由使濃縮液乾燥(乾燥步驟)而去除水性溶媒,將所獲得之粉末組成物視需要進行粉碎、分級而製造飲料用粉末植物萃取物之方法。關於將分枝α-葡聚醣混合物摻和至提取液(植物萃取物)中之方法,無論是預先添加至水性溶媒中之方法、添加至提取液中之方法及添加至提取液的濃縮液中之方法中之任何方法皆可有利地實施。此外,亦可藉由此等複數種方法進行添加。   [0049] 所謂的提取步驟,係在植物原料中加入水性溶媒,進行浸漬、攪拌或加熱來施行提取,獲得提取液之步驟。作為水性溶媒,可使用自來水、去離子水、蒸餾水、去氧水等水或乙醇以及該等之混合溶媒。在水性溶媒中,亦可單獨地或併用地摻和抗氧化劑、乳化劑、pH調整劑等添加劑。此外,不使用水性溶媒,而使用將植物原料進行壓榨所獲得之榨汁液來代替提取液亦無妨。提取溫度並無特別限定,較佳為15℃以上且100℃以下。在提取溫度為未滿15℃時,提取效率明顯降低,此外,在其為超過100℃之溫度時,不需要的成分被過量地提取,且變得容易發生香氣成分的變性。   [0050] 所謂的濃縮步驟,係自植物提取液中選擇性地除去水性溶媒,提高提取液的濃度之步驟。濃縮步驟本身並非必要的步驟,藉由將提取液預先進行濃縮,可在乾燥步驟中效率良好地進行乾燥。濃縮可藉由減壓濃縮、凍結濃縮、逆滲透膜濃縮等公知的方法施行。該等之中,較佳為源自植物提取液之香氣成分的揮發、變性較少的逆滲透膜濃縮、凍結濃縮。   [0051] 所謂的乾燥步驟,係使已摻和分枝α-葡聚醣混合物之提取液(或濃縮液)之液中之水性溶媒蒸發而施行乾燥粉末化之步驟。乾燥粉末化可藉由熱風乾燥、真空乾燥、噴霧乾燥、凍結真空乾燥、滾筒乾燥、擠出造粒、流動造粒等適宜的方法施行。該等之中,較佳為源自乾燥中之植物提取液之風味成分的流失較少的凍結真空乾燥或噴霧乾燥。   [0052] 以下,基於實驗更詳細地說明本發明。   [0053] <實驗1:粉末化基材對植物萃取物飲料的風味所帶來之影響> (1)概要   藉由在飲用植物萃取物中摻和分枝α-葡聚醣混合物或難消化糊精作為粉末化基材而調製飲料用粉末植物萃取物,調查粉末化基材的差異對使各者溶解於溫水中時之植物萃取物飲料的風味所帶來之影響。 (2)實驗方法 (a)被驗試料的調製   在烏龍茶萃取物(商品名『烏龍茶萃取物M水性』,含有烏龍茶提取物固形物10質量%之溶液,丸善製藥股份有限公司販售)50g(固形物5g)中,添加與後述之實施例1所使用者相同的分枝α-葡聚醣混合物(以下,稱為「分枝α-葡聚醣混合物」)的粉末0.5、1.65、2.5、5.0、25.0、50.0、100.0、200.0g,進行混合,視需要適宜追加水,獲得分枝α-葡聚醣混合物的摻和比例不同的8種烏龍茶萃取物。然後,將所獲得之摻和有分枝α-葡聚醣混合物之烏龍茶萃取物各自進行凍結乾燥,製成飲料用粉末植物萃取物(粉末烏龍茶)(被驗試料1至8)。作為比較對象,除了摻和市售的難消化性糊精(商品名『Fibersol 2』,松谷化學工業股份有限公司販售)來代替分枝α-葡聚醣混合物以外,以與上述同樣的方法調製粉末烏龍茶(被驗試料9至16)。另外,所獲得之被驗試料1至8及9至16係相對於烏龍茶萃取物固形物1質量份而言,各自含有分枝α-葡聚醣混合物或難消化性糊精0.1、0.33、0.5、1、5、10、20或40質量份。   [0054] (b)官能試驗   針對以上述之方法所獲得之粉末烏龍茶的被驗試料1至16以及屬於原料之烏龍茶萃取物(對照),以源自烏龍茶萃取物之固形物各成為0.33g之方式裝入茶杯中,以70℃的溫水100ml進行溶解,針對其風味由5名評審員基於表1所示之評估基準施行官能評估。以評估評審員數最多的分數作為評估分數。在評估人數為同數之情況,採用該評估之中間分作為評估分數。將對照及被驗試料1至16各自的組成及官能評估之結果示於表2。   [0055][0056][0057] 如表2所示,可判明將使用分枝α-葡聚醣混合物作為粉末化基材並添加相對於烏龍茶萃取物中之固形物1質量份而言0.1至20質量份所調製而成之粉末烏龍茶(被驗試料1至7)溶解於溫水中所獲得之烏龍茶係與對照的烏龍茶相同地香氣或風味優異,添加0.33至5質量份所調製而成之粉末烏龍茶(被驗試料2至5)係特別優異。在此處,可判明在添加40質量份分枝α-葡聚醣混合物而成之粉末烏龍茶(被驗試料8)中,對於進行溶解所獲得之烏龍茶會感受到源自分枝α-葡聚醣混合物之甜味或異臭,損及烏龍茶原本的風味或香氣。另一方面,可判明在將使用難消化性糊精作為粉末化基材所調製而成之粉末烏龍茶(被驗試料9至16)溶解於溫水中所獲得之烏龍茶中,在所有的被驗試料中相較於對照的烏龍茶之情況而言皆會損及香氣或風味等,該影響係隨著難消化性糊精的添加量增加而變得顯著。   [0058] <實驗2:粉末化基材的種類差異對飲料用粉末植物萃取物的冷水溶解性所帶來之影響> (1)概要   在飲用植物萃取物中添加並摻和分枝α-葡聚醣混合物、難消化糊精或糊精作為粉末化基材,針對粉末化基材的種類差異對飲料用粉末植物萃取物的溶解性所帶來之影響進行調查。假定在冷水中利用植物萃取物飲料,在比較難以溶解之低溫條件下施行實驗。   [0059] (2)實驗方法 (a)被驗試料的調製   除了以相對於烏龍茶萃取物固形物1質量份而言按固形物換算成為5質量份之方式摻和一般的糊精(商品名『Pine Dex#1』,DE7.5的澱粉分解物,松谷化學工業股份有限公司販售)來代替分枝α-葡聚醣混合物或難消化性糊精以外,以與實驗1同樣的方法獲得摻和有糊精之粉末烏龍茶。 (b)溶解性試驗   將上述(a)所獲得之摻和有糊精之粉末烏龍茶、實驗1所獲得之被驗試料5及13(相對於源自烏龍茶萃取物之固形物1質量份而言包含5質量份的分枝α-葡聚醣混合物或難消化性糊精之粉末烏龍茶)各0.5g加至5℃的冷水50ml中,各自以轉數200rpm進行攪拌,以目視測定直至完全溶解為止之時間。實驗係施行2次,將基於2次的平均時間以4階段評估溶解性之結果示於表3。另外,將以5分鐘以上且未滿10分鐘溶解者評估為「4」,將以10分鐘以上且未滿15分鐘溶解者評估為「3」,將以15分鐘以上且未滿20分鐘溶解者評估為「2」,將以20分鐘以上溶解者評估為「1」。   [0060][0061] 如表3所示,以分枝α-葡聚醣混合物作為粉末化基材之本案發明之粉末烏龍茶係溶解性最優異,以5分鐘以上且未滿10分鐘完全溶解。相對於此,可確認以難消化性糊精作為粉末化基材之粉末烏龍茶在溶解時需要10分鐘以上且未滿15分鐘,溶解性稍差。再者,以糊精作為粉末化基材之粉末烏龍茶在加至冷水中時會結塊,直至完全溶解為止需要20分鐘以上,溶解性明顯較低。   [0062] 由以上所述之實驗1及2之結果,可判明本發明之分枝α-葡聚醣混合物相較於習知的粉末烏龍茶中所使用之糊精或目前市售作為水溶性食物纖維之難消化性糊精而言,粉末烏龍茶的溶解性以及使其溶解於熱水中時之香氣或風味之保持作用係較優異。一般認為該種分枝α-葡聚醣混合物所引發之較高的溶解性及溶解時之風味維持效果,不僅是在烏龍茶中,以將同樣的茶樹進行加工、提取而製作之茶類為首,在全部的具有香氣或風味之植物萃取物飲料中皆可同樣地發揮出來。   [0063] 本分枝α-葡聚醣混合物相較於以往公知的粉末化基材而言更有效地保持源自飲用植物萃取物之風味之理由的詳情不明。然而,一般認為具有上述(A)至(C)的結構特徵,特定而言,相較於難消化性糊精或糊精而言,具有藉由異麥芽葡聚醣酶消化而生成每消化物的固形物5質量%以上異麥芽糖之結構特徵,在發揮其機能上為必要的,可推定本分枝α-葡聚醣混合物之該結構特徵係作用於植物萃取物的風味及香氣成分。   [0064] 以下,藉由實施例進一步詳細說明本案發明,但本發明不受此等實施例所限定。 [實施例1]   [0065] <粉末綠茶>   在80℃的溫水10kg中加入綠茶葉0.5kg,於80℃提取15分鐘。進行粕分離,獲得布里糖度(Brix)2.5度的茶提取液8kg。將所獲得之提取液以離心分離機進行澄清化後,供至膜濃縮。在所獲得之濃縮液中添加並溶解按照國際公開第WO2008/136331號小冊之實施例5所揭示之方法所獲得之具有下述(a)至(j)的特性之分枝α-葡聚醣混合物的粉末150g,將該溶液進行凍結乾燥,獲得粉末綠茶。茶提取物與分枝α-葡聚醣混合物之按固形物換算之質量比為1:0.75。使所獲得之粉末綠茶溶解於70℃的溫水中,結果迅速地溶解,並感受到綠茶原本的清爽香氣以及風味。 <分枝α-葡聚醣混合物的特性>   (a)以葡萄糖作為構成糖。   (b)在位於經由α-1,4鍵結連結而成之葡萄糖聚合度3以上的直鏈狀葡聚醣的一端之非還原末端葡萄糖殘基具有經由α-1,4鍵結以外之鍵結連結而成之葡萄糖聚合度1以上的分枝結構。   (c)藉由異麥芽葡聚醣酶消化,而生成每消化物的固形物38.0質量%異麥芽糖。   (d)藉由高效液相層析法(酵素-HPLC法)所求出之水溶性食物纖維含量為81.2質量%。   (e)經α-1,4鍵結之葡萄糖殘基與經α-1,6鍵結之葡萄糖殘基之比為1:2.6。   (f)經α-1,4鍵結之葡萄糖殘基及經α-1,6鍵結之葡萄糖殘基之合計佔所有葡萄糖殘基的70.3%。   (g)經α-1,3鍵結之葡萄糖殘基為所有葡萄糖殘基的2.8%。   (h)經α-1,3,6鍵結之葡萄糖殘基為所有葡萄糖殘基的7.2%。   (i)重量平均分子量為4,600。   (j)Mw/Mn為2.3。 [實施例2]   [0066] <粉末紅茶>   在80℃的溫水10kg中加入紅茶葉0.75kg,於80℃提取15分鐘。進行粕分離,獲得布里糖度3.8度的提取液8kg。將所獲得之提取液以離心分離機進行澄清化後,供至膜濃縮。在所獲得之濃縮液中添加按照國際公開第WO2008/136331號小冊之實施例3所揭示之方法所獲得之具有下述(a)至(j)的特性之分枝α-葡聚醣混合物的粉末300g,將該溶液進行凍結乾燥,獲得粉末紅茶。紅茶提取液與分枝α-葡聚醣混合物之按固形物換算之質量比為1:1.5。使所獲得之粉末紅茶溶解於70℃的溫水中,結果迅速地溶解,並感受到紅茶原本的香氣以及風味。 <分枝α-葡聚醣混合物的特性>   (a)以葡萄糖作為構成糖。   (b)在位於經由α-1,4鍵結連結而成之葡萄糖聚合度3以上的直鏈狀葡聚醣的一端之非還原末端葡萄糖殘基具有經由α-1,4鍵結以外之鍵結連結而成之葡萄糖聚合度1以上的分枝結構。   (c)藉由異麥芽葡聚醣酶消化,而生成每消化物的固形物36.4質量%異麥芽糖。   (d)藉由高效液相層析法(酵素-HPLC法)所求出之水溶性食物纖維含量為75.2質量%。   (e)經α-1,4鍵結之葡萄糖殘基與經α-1,6鍵結之葡萄糖殘基之比為1:1.5。   (f)經α-1,4鍵結之葡萄糖殘基及經α-1,6鍵結之葡萄糖殘基之合計佔所有葡萄糖殘基的68.0%。   (g)經α-1,3鍵結之葡萄糖殘基為所有葡萄糖殘基的3.5%。   (h)經α-1,3,6鍵結之葡萄糖殘基為所有葡萄糖殘基的4.5%。   (i)重量平均分子量為6,300。   (j)Mw/Mn為2.2。 [實施例3]   [0067] <粉末洋甘菊茶>   在80℃的溫水10kg中加入洋甘菊茶葉1.5kg,於80℃提取15分鐘。進行粕分離,獲得布里糖度1.6度的提取液16kg。將所獲得之提取液以離心分離機進行澄清化後,供至膜濃縮。在所獲得之濃縮液中添加按照國際公開第WO2008/136331號小冊之實施例4所揭示之方法所獲得之具有下述(a)至(j)的特性之分枝α-葡聚醣混合物的粉末300g,將該溶液進行凍結乾燥,獲得粉末洋甘菊茶。洋甘菊茶提取液與分枝α-葡聚醣混合物之按固形物換算之質量比為1:0.8。使所獲得之粉末洋甘菊茶溶解於70℃的溫水中,結果迅速地溶解,並感受到洋甘菊茶原本的清爽香氣以及風味。 <分枝α-葡聚醣混合物的特性>   (a)以葡萄糖作為構成糖。   (b)在位於經由α-1,4鍵結連結而成之葡萄糖聚合度3以上的直鏈狀葡聚醣的一端之非還原末端葡萄糖殘基具有經由α-1,4鍵結以外之鍵結連結而成之葡萄糖聚合度1以上的分枝結構。   (c)藉由異麥芽葡聚醣酶消化,而生成每消化物的固形物41.8質量%異麥芽糖。   (d)藉由高效液相層析法(酵素-HPLC法)所求出之水溶性食物纖維含量為68.5質量%。   (e)經α-1,4鍵結之葡萄糖殘基與經α-1,6鍵結之葡萄糖殘基之比為1:1.9。   (f)經α-1,4鍵結之葡萄糖殘基及經α-1,6鍵結之葡萄糖殘基之合計佔所有葡萄糖殘基的78.9%。   (g)經α-1,3鍵結之葡萄糖殘基為所有葡萄糖殘基的1.7%。   (h)經α-1,3,6鍵結之葡萄糖殘基為所有葡萄糖殘基的2.2%。   (i)重量平均分子量為10,000。   (j)Mw/Mn為2.7。 [實施例4]   [0068] <粉末魚腥草茶>   在90℃的溫水10kg中加入魚腥草茶葉0.5kg,於90℃提取15分鐘。進行粕分離,獲得布里糖度1.9度的提取液8kg。將所獲得之提取液以離心分離機進行澄清化後,供至膜濃縮。在所獲得之濃縮液中添加按照國際公開第WO2008/136331號小冊之實施例6所揭示之方法所獲得之具有下述(a)至(j)的特性之分枝α-葡聚醣混合物的粉末250g,將該溶液進行凍結乾燥,獲得粉末魚腥草茶。魚腥草茶提取液與分枝α-葡聚醣混合物之按固形物換算之質量比為1:1.2。使所獲得之粉末魚腥草茶溶解於70℃的溫水中,結果迅速地溶解,並感受到魚腥草茶原本的香氣以及風味。 <分枝α-葡聚醣混合物的特性>   (a)以葡萄糖作為構成糖。   (b)在位於經由α-1,4鍵結連結而成之葡萄糖聚合度3以上的直鏈狀葡聚醣的一端之非還原末端葡萄糖殘基具有經由α-1,4鍵結以外之鍵結連結而成之葡萄糖聚合度1以上的分枝結構。   (c)藉由異麥芽葡聚醣酶消化,而生成每消化物的固形物40.1質量%異麥芽糖。   (d)藉由高效液相層析法(酵素-HPLC法)所求出之水溶性食物纖維含量為83.8質量%。   (e)經α-1,4鍵結之葡萄糖殘基與經α-1,6鍵結之葡萄糖殘基之比為1:3.8。   (f)經α-1,4鍵結之葡萄糖殘基及經α-1,6鍵結之葡萄糖殘基之合計佔所有葡萄糖殘基的66.6%。   (g)經α-1,3鍵結之葡萄糖殘基為所有葡萄糖殘基的2.6%。   (h)經α-1,3,6鍵結之葡萄糖殘基為所有葡萄糖殘基的5.6%。   (i)重量平均分子量為3,200。   (j)Mw/Mn為2.1。 [参考例]   [0069] <飲料用粉末植物萃取物>   除了使用屬於一般的糊精之DE25的糊精(商品名『Pine Dex#3』,松谷化學工業股份有限公司販售)、DE20的糊精(商品名『LDX35-20』,昭和產業股份有限公司販售)、DE15的糊精(商品名『Glister』,松谷化學工業股份有限公司販售)、DE14的糊精(商品名『液狀糊精』,松谷化學工業股份有限公司販售)、DE11的糊精(商品名『Pine Dex#2』,松谷化學工業股份有限公司販售)或DE4的糊精(商品名『Pine Dex#100』,松谷化學工業股份有限公司販售)來代替實施例1所使用之分枝α-葡聚醣混合物以外,與實施例1同樣地調製6種粉末綠茶。   [0070] 將本例所獲得之6種飲料用粉末植物萃取物(粉末綠茶)及實施例1所獲得之本發明之飲料用粉末植物萃取物(粉末綠茶)以源自綠茶提取液之固形物各成為0.33g之方式裝入茶杯中,以70℃的熱水100ml進行溶解,針對該等對風味進行比較,結果本例所獲得之6種飲料用粉末植物萃取物相較於實施例1所獲得之本發明之飲料用粉末植物萃取物而言,就風味、香氣、綠茶獨特的苦味、源自基材之味道等之方面而言皆明顯較差。 [產業上之可利用性]   [0071] 如以上所述,本發明係提供相較於習知的飲料用粉末植物萃取物而言,風味及溶解性獲得改善之飲料用粉末植物萃取物及其製造方法。本發明對該領域所帶來之影響如此甚大,本發明之產業上之可利用性極大。The present invention relates to a powder plant extract for beverages and a method for producing the same. The powder plant extract for beverages includes a drink plant extract and a branch α- having the following characteristics (A) to (C) The glucan mixture, the mass ratio of the drinking plant extract and the branched α-glucan mixture contained in the powdered plant extracts, in terms of solids, is 1: 0.1 ~ 1: 20; (A) Glucose as a constituent sugar, (B) at the non-reducing terminal glucose residue located at one end of a linear glucan having a glucose polymerization degree of 3 or more connected via an α-1,4 bond has a via α-1,4 The branched structure of glucose polymerization degree 1 or more formed by linkages other than the linkage, (C) is digested by isomalt glucanase to produce isomaltose of 5 mass% or more per solid of the digest. [0016] The so-called powdered plant extract for beverages in this specification means that the drinkable plant extract extracted from the plant by an aqueous solvent is dried and powdered. Here, as plants, specifically, tea trees such as Camellia sinensis and Assam tea; chamomile, roselle, lavender, mint, rose hip, peppermint, lemon grass, fish Herbs (vanilla) such as grass, Gymnema, Lagerstroemia indica, Ginkgo biloba, jute, alfalfa, cumin, winter holly, Jiayelong tea, eucommia, South African tea, aloe vera, cherry leaves, perilla, etc. , Rice, soybean, buckwheat and other cereals; Korean ginseng, burdock and other root vegetables; coffee trees, etc. [0017] The so-called drinkable plant extract in this specification means that one or more parts selected from the leaves, stems, flowers, calyx, roots, seeds, etc. of the above plants are subjected to processing such as drying, roasting, fermentation, etc. as needed, and Producer for extraction. Specific examples of the extract of this kind of drinking plant include green tea, oolong tea, black tea, roasted tea, crude tea, vanilla tea, eucommia tea, South African tea, houttuynia tea, barley tea, barley, black rice tea, buckwheat tea, burdock Tea, coffee beans, etc. [0018] The so-called branched α-glucan mixture in this specification means, for example, the branched α-glucan mixture disclosed by the same applicant as the present case in International Publication No. WO2008 / 136331, etc. (hereinafter , Only called "branched alpha-glucan mixture"). The branched α-glucan mixture is obtained by using starch as a raw material and various enzymes act on it, usually in the form of a plurality of branched α-glucans having various branching structures and glucose polymerization degrees The form of a mixture of sugar as the main body. As a method for producing the branched α-glucan mixture, it may be exemplified that the α-glucosidyl transferase disclosed in the aforementioned International Publication No. WO2008 / 136331 acts on starch, or other than the aforementioned α-glucosidyl group In addition to the transfer enzyme, amylases such as amylase (EC 3.2.1.60), amylase (EC 3.2.1.60), pullulanase (EC 3.2.1.41), isoamylase (EC 3.2.1.68) and other starch debranching enzymes are combined. In addition, cyclomaltodextrin glucan transferase (EC 2.4.1.19), starch branching enzyme (EC 2.4.1.18), or Japanese Patent Laid-Open No. 2014-54221, etc., have an α with a polymerization degree of 2 or more -1,4 Dextran is a method of performing one or more enzymes such as enzymes that transfer α-1,6 to glucose residues inside starch to act on starch. In the current technology, the individual branched α-glucan molecules constituting the branched α-glucan mixture used in the present invention are isolated and quantified or their structure is determined, that is, glucose belonging to its constituent unit The bonding pattern and bonding sequence of the residues is impossible or extremely difficult. The branched α-glucan mixture can be mixed by various physical, chemical or enzyme methods commonly used in the field. Give features as a whole. [0019] That is, the structure of the branched α-glucan mixture used in the present invention is characterized by the above-mentioned features (A) to (C) for the entire mixture. This branched α-glucan mixture is a glucan (characteristic (A)) that uses glucose as a constituent sugar, and is located in a linear glucose with a polymerization degree of glucose of 3 or more, which is connected via an α-1,4 bond. The non-reducing terminal glucose residue at one end of the glycan has a branched structure with a degree of glucose polymerization of 1 or more connected by a bond other than the α-1,4 bond (feature (B)). In addition, the so-called "non-reducing terminal glucose residue" in feature (B) means a glucose residue located at a terminal that does not show reducing properties in the glucan chain connected through the α-1,4 linkage. "A bond other than α-1,4 bond", if the word meaning is "a bond other than α-1,4 bond", it means α-1,2 bond, α-1,3 bond , Α-1,6 bonding, and other bonding other than α-1,4 bonding. [0020] Furthermore, the branched α-glucan mixture used in the present invention has the following characteristics: by isomalt glucanase digestion, each solid content of digestion produces 5 mass% or more isomaltose (characteristic ( C)). [0021] Thus, the branched α-glucan mixture used in the present invention is a glucan mixture characterized by the aforementioned characteristics (A) to (C). Among these characteristics, if the characteristics (C) are supplemented, they are as follows. [0022] With regard to the aforementioned feature (C) that characterizes the branched α-glucan mixture used in the present invention, so-called isomalt glucanase digestion means that isomalt glucanase acts on the The α-glucan mixture is branched and hydrolyzed. Isomalt glucanase is an enzyme given an enzyme number (EC) of 3.2.1.94, which is α-1,2, α with the reducing end side of the isomaltose structure adjacent to the α-glucan -1,3, α-1,4, and α-1,6, any of the bonding styles will be hydrolyzed with the characteristic enzyme. In isomalt glucanase digestion, it is more appropriate to use isomalt glucanase derived from Arthrobacter Globiformis (see, for example, Sawai et al., Agricultural and Biological Chemistry, Vol. 52, No. 2 No., pages 495-501 (1988)). [0023] The ratio of isomaltose per solid of the digested matter produced by the aforementioned isomalt glucanase digestion represents the structure of the branched α-glucan constituting the branched α-glucan mixture The ratio of the isomaltose structure obtained by the hydrolysis of isomalt glucanase can be characterized by the enzyme method in the structure of the branched α-glucan mixture by the feature (C). [0024] The branched α-glucan mixture used in the present invention is digested by isomaltoglucanase, and the solids produced per digest are usually 5 mass% or more, preferably 10 mass% or more, More preferably, it is 15% by mass or more, further preferably 20% by mass or more and 70% by mass or less, and still more preferably 20% by mass or more and 60% by mass or less isomaltose, the plant used to powder the drinkable plant extract The original flavor retention effect of the extract is stronger, and it can be more suitably used in the practice of the present invention. [0025] That is, as described later, it is generally considered that the isomaltose structure in each α-glucan molecule constituting the branched α-glucan mixture is closely related to the flavor retention of the powdered plant extract for beverage of the present invention when dissolved . The branched α-glucan mixture with an amount of isomaltose produced by the digestion of isomalt glucanase less than 5 mass% will have a structure similar to maltodextrin with less branched structure. When the powdered plant extracts for beverages are dissolved, the structural characteristics related to flavor retention are weakened, which is not good, and there is an appropriate range for the amount of isomaltose obtained by digestion with isomaltoglucanase. [0026] In addition, as one of the more suitable aspects of the branched α-glucan mixture used in the present invention, a water-soluble food obtained by high-performance liquid chromatography (enzyme-HPLC method) can be cited Characteristic (D) with a fiber content of 40% by mass or more. [0027] With regard to the aforementioned characteristic (D) that characterizes the branched α-glucan mixture used in the present invention, the so-called “high performance liquid chromatography (enzyme-HPLC method)” for obtaining the content of water-soluble dietary fiber (Hereinafter, just referred to as "enzyme-HPLC method"), it is the nutrition labeling standard of the Ministry of Health, Welfare and Welfare Notice No. 146, May, 2005, "Analysis method of nutritional components, etc. (Column 3, column 1 of nutrition labeling standard The method described in item 8), the method described in "food fiber", if it is outlined, is as follows. That is, the sample is decomposed by a series of enzyme treatments using heat-stabilizing α-amylase, protease, and glucoamylase, and the gel is prepared by removing proteins, organic acids, and inorganic salts from the treatment liquid with an ion exchange resin Filter the sample solution for chromatography. Next, it was subjected to gel filtration chromatography to obtain the peak areas of undigested glucan and glucose in the chromatogram, using each peak area and a sample previously determined by the glucose / oxidase method according to the usual method. The amount of glucose in the solution is used to calculate the water-soluble dietary fiber content of the sample. In addition, the so-called "water-soluble dietary fiber content" throughout this specification, unless otherwise specified, means the water-soluble dietary fiber content determined by the aforementioned "enzyme-HPLC method". [0028] The content of water-soluble dietary fiber means the content of α-glucan not decomposed by α-amylase and glucoamylase, and the characteristic (D) is that the structure of the branched α-glucan mixture is the whole of the mixture. It is one of the indicators that give features by enzyme technique. [0029] Having the above characteristics (A) to (C), while the content of water-soluble dietary fiber is 40% by mass or more and less than 100% by mass, preferably 50% by mass or more and less than 95% by mass, more preferably 60 More than 90% by mass and less than 90% by mass, preferably 70% by mass and less than 85% by mass branched α-glucan mixture, the flavor retention effect when the powdered plant extract for beverage is dissolved in water, etc. It is stronger and can be more appropriately used in the practice of the present invention. [0030] Furthermore, as one of the more suitable aspects of the present branched α-glucan mixture, those having the following characteristics (E) and (F) can be cited, and the characteristics can be obtained by methylation analysis . (E) The ratio of glucose residues bonded by α-1,4 to glucose residues bonded by α-1,6 is in the range of 1: 0.6 to 1: 4, (F) by α-1, The total of 4 linked glucose residues and α-1,6 linked glucose residues account for more than 55% of all glucose residues. [0031] The so-called methylation analysis, as is well known, is generally used as a method for determining the bonding pattern of monosaccharides constituting such polysaccharides or oligosaccharides (Ciucanu et al., Carbohydrate Research, Volume 131, No. 2, pages 209-217 (1984)). In the case of applying methylation analysis to the analysis of the bonding pattern of glucose in dextran, first, all free hydroxyl groups in the glucose residues constituting dextran are methylated, and then, after complete The methylated dextran is hydrolyzed. Next, the methylated glucose obtained by hydrolysis is reduced to produce a methylated glucose alcohol in the form of eliminated rotamers. Furthermore, by free hydroxyl groups in this methylated glucose alcohol Acetylation is performed to obtain partially methylated glucose alcohol acetate (in addition, "partially methylated glucose alcohol acetate" is sometimes simply referred to as "partial methylate"). By analyzing the obtained partial methylates by gas chromatography, various partial methylates derived from glucose residues with different bonding patterns in dextran can be The percentage (%) of the peak area occupied by the peak area of all partial methylates. In addition, the peak area% can determine the ratio of the presence of glucose residues having different bonding patterns in the glucan, that is, the ratio of the presence of each glucoside bond. The "ratio" for partial methylates should mean the "ratio" of the peak area in the gas chromatogram of the methylation analysis, and the "%" for partial methylation should mean the gas chromatography for the methylation analysis. "Area%" in the picture. [0032] The so-called "α-1,4 bonded glucose residues" in (E) and (F) above are bonded to other glucose only through hydroxyl groups bonded to the 1 and 4 carbon atoms Glucose residues derived from the residues were detected in the form of 2,3,6-trimethyl-1,4,5-triethoxyglucitol in methylation analysis. In addition, the so-called "α-1,6 bonded glucose residues" in (E) and (F) above are only bonded to other glucose residues through hydroxyl groups bonded to the 1 and 6 carbon atoms. In the methylation analysis, the glucose residue formed by the group was detected in the form of 2,3,4-trimethyl-1,5,6-triethoxyglucitol. [0033] The ratio of α-1,4 bonded glucose residues to α-1,6 bonded glucose residues obtained by methylation analysis, and α-1,4 bonded glucose residues The ratio of glucose residues and α-1,6-linked glucose residues to all glucose residues can be used to characterize the structure of the branched α-glucan mixture as a whole by chemical means. One of the indicators. [0034] The feature of "Equivalent ratio of glucose residues bonded through α-1,4 to glucose residues bonded through α-1,6" in (E) above is in the range of 1: 0.6 to 1: 4 It means that the 2,3,6-trimethyl-1,4,5-triethyl glucosyl alcohol and 2, were detected when the branched α-glucan mixture was submitted to methylation analysis. The ratio of 3,4-trimethyl-1,5,6-triethoxyglucitol is in the range of 1: 0.6 to 1: 4. In addition, the above (F) "Total glucose residues bonded by α-1,4 and glucose residues bonded by α-1,6 account for more than 55% of all glucose residues" means that this In the methylation analysis of the branched α-glucan mixture, 2,3,6-trimethyl-1,4,5-triethoxyglucitol and 2,3,4-trimethyl-1, The total amount of 5,6-triethyl glucosyl alcohol accounts for more than 55% of the partially methylated glucose alcohol acetate. In general, starch does not have glucose residues bonded only at positions 1 and 6, and α-1,4 bonded glucose residues account for the majority of all glucose residues, so (E) and ( The requirement of F) means that the branched α-glucan mixture has a completely different structure from starch. [0035] As specified in the characteristics of (E) and (F) above, in a preferred form, the branched α-glucan mixture has a considerable degree of , 6-linked glucose residues ", in cases where a higher flavor retention effect is required, those with a more complex branching structure can expect a higher effect, so it is better to exclude α-1,4 bonding and In addition to α-1,6 bonds, complexes have α-1,3 bonds and α-1,3,6 bonds. Specifically, for example, α-1,3-linked glucose residues are preferably 0.5% or more and less than 10% of all glucose residues, and α-1,3,6-linked glucose residues are preferred It is more than 0.5% of all glucose residues. Here, the so-called "α-1,3,6 bond" means "to bond with other glucose in 3 places at the 1st, 3rd and 6th hydroxyl groups (after α-1,3,6, 6) glucose residues). [0036] The above "α-1,3 bonded glucose residues are more than 0.5% and less than 10% of all glucose residues" can be confirmed by the following way: the present branched α-glucan mixture for At the time of methylation analysis, there was 2,4,6-trimethyl-1,3,5-triethyl glucosyl alcohol with more than 0.5% and less than 10% of partially methylated glucose alcohol acetate . In addition, the above "α-1,3,6 bonded glucose residues are more than 0.5% of all glucose residues" can be confirmed by the following way: This branched alpha-glucan mixture is in methylation analysis , There are 2,4-dimethyl-1,3,5,6-tetraethanoylglucitol with more than 0.5% and less than 10% of partially methylated glucose alcohol acetate. [0037] The present branched α-glucan mixture can also be characterized by a weight average molecular weight (Mw) and a value (Mw / Mn) obtained by dividing the weight average molecular weight (Mw) by the number average molecular weight (Mn). The weight average molecular weight (Mw) and the number average molecular weight (Mn) can be obtained using, for example, size exclusion chromatography. In addition, since the average degree of glucose polymerization of the branched α-glucans constituting the branched α-glucan mixture can be calculated based on the weight average molecular weight (Mw), the branched α-glucan mixture can also be calculated by The average degree of glucose polymerization is characteristic. The average glucose polymerization degree can be obtained by subtracting 18 from the weight average molecular weight (Mw) and dividing the molecular weight by the amount of glucose residues 162. The present branched α-glucan mixture used in powdered plant extracts for beverages is more suitably an average glucose polymerization degree of usually 8 to 500, preferably 15 to 400, more preferably 20 to 300. In addition, the branched α-glucan mixture exhibits the same properties as ordinary glucans in that the average glucose polymerization degree increases as the viscosity increases, and the average glucose polymerization degree decreases as the viscosity decreases. Therefore, according to the embodiment of the powdered plant extract for beverages of the present invention, it is suitable to select and use the present branched α-glucan mixture having an average degree of glucose polymerization that meets the viscosity required for the beverage. [0038] Regarding the value Mw / Mn obtained by dividing the weight average molecular weight (Mw) by the number average molecular weight (Mn), the closer to 1 it means the branched α-glucan molecules constituting the branched α-glucan mixture The smaller the deviation of the degree of glucose polymerization. The present branched α-glucan mixture used in the drinking plant extract is more suitably used as long as the Mw / Mn is usually 20 or less without problems, but it is preferably 10 or less, and more preferably 5 or less. [0039] The branched α-glucan mixture used in the present invention is as described above. In the practice of the present invention, various branched α-glucans disclosed in the aforementioned International Publication No. WO2008 / 136331 can be used Glycan mixture. Among these, α-derived from Bacillus circulans PP710 (FERM BP-10771) and / or Arthrobacter Globiformis PP349 (FERM BP-10770) may be used more appropriately. Glucosyltransferase alone, or the α-glucosyltransferase and pullulanase (EC 3.2.1.41), isoamylase (EC 3.2.1.68) and other starch debranching enzymes and / or cyclic malt The dextrin glucan transferase (EC 2.4.1.19 (CGTase) is combined to act on the branched α-glucan mixture obtained from the starch raw material. Furthermore, it can be particularly suitably used by the applicant Lin Yuan Co., Ltd. The branched alpha-glucan mixture sold by the company in the form of isomaltodextrin (registered trademark "Fibryxa"). [0040] The branched alpha-glucan contained in the powdered plant extract for beverages of the present invention The amount of the glycan mixture is 1: 0.1 to 1:20 in terms of solids relative to the drinking plant extract, and it is more appropriate to contain it in the ratio of 1: 0.33 to 1: 5. It is included in the aforementioned numerical range Powdered plant extracts for beverages containing branched α-glucan mixtures are excellent in solubility, and maintain the same flavor and aroma as plant extract beverages (green tea, black tea, coffee, etc.) when dissolved. In addition, in the case where the mass ratio is less than 0.1, the above-mentioned effects caused by the branched α-glucan mixture cannot be fully exerted, which is not good. In addition, on the contrary, when the mass ratio exceeds 20, Due to the large amount of branched α-glucan mixture, the characteristics such as flavor and solubility tend to deteriorate. In addition, the α-glucan mixture contained in the powdered plant extract for beverages of the present invention is usually in powder form. The plant extract is added, if necessary, in a form of a solution prepared by dissolving it in water, etc., or in the form of a syrup. [0041] Powdered plant extract for beverages targeted by the present invention It is characterized by containing a branched α-glucan mixture, and when the powdered plant extract for beverages is dissolved in a liquid such as water, the original flavor and aroma of the plant extract beverage are sufficiently maintained. The mechanism of the dextran mixture to effectively maintain the flavor and aroma of the powdered plant extracts for beverages is unknown. It can be presumed that this branched alpha-glucan mixture that may have the characteristics of (A) to (C) above may interact with plants. The main flavors and aroma components of extract beverages (specifically, teas) are terpenes, aldehydes, pyrazines, pyrroles, and furans that interact with each other to maintain flavor. [0042] Thus, the present invention The powdered plant extract for beverages is effective in maintaining flavor by containing a predetermined amount of branched α-glucan mixture, and besides, it becomes excellent in solubility. In addition, the powdered plant extract for beverages of the present invention in It also blends other ingredients other than the branched α-glucan mixture in appropriate amounts as needed. Examples of other ingredients include preservatives, colorants, excipients, binders, flavoring agents, antioxidants, pH adjusters, sweeteners, spices, sours, seasonings, etc., which can be used in appropriate combination Appropriate amount of 1 or 2 or more. The blending amount of the aforementioned other components may be appropriately set according to the type and the type of the powdered plant extract for beverages blended. Generally, for each component, it can be exemplified as a solid substance conversion, relative to the powdered plant for beverages. The extract is selected from 0.0001% by mass or more, more suitably from 0.001 to 30% by mass, more suitably from 0.01 to 20% by mass, and further suitably from 0.01 to 10% by mass. In addition, the aforementioned other components may be appropriately blended in the necessary amount in one or more steps until the powder plant extract for beverage of the present invention is completed. [0043] Examples of the preservatives include edible organic acids such as acetic acid, citric acid, malic acid, fumaric acid, and lactic acid; alcohols such as ethanol, propylene glycol, and glycerin; and amino acids such as glycine and alanine; Common salt, acetate, citrate, sodium carbonate, potassium carbonate, calcium oxide, calcium hydroxide, calcium carbonate, disodium phosphate, tripotassium phosphate and other salts. [0044] Examples of the aforementioned coloring agent include red yeast rice, crab shell powder, astaxanthin, vegetable pigment, red yeast rice pigment, concentrated Phaffia pigment oil, gardenia yellow, matcha pigment, carmine pigment, Gardenia yellow pigment, gardenia blue pigment, flavonoid pigment, caramel pigment, β-carotene, carotenoid pigment, charcoal and other natural pigments; and red No. 2, red No. 3, red No. 104, red No. 105 , Red No. 106, yellow No. 4, yellow No. 5, blue No. 1, titanium dioxide and other synthetic coloring materials. Examples of the aforementioned sweeteners include granulated sugar, glucose, fructose, high fructose syrup, glycyrrhizin, stevia, aspartame, and fructooligosaccharides. [0046] The powdered plant extracts for beverages of the present invention are soluble in water, warm water, milk, etc., and can be blended with cookies, crackers, biscuits and other biscuits or jelly, mousse, Bavarian milk Frozen, pudding, ice, fern cake, dumplings, steamed bread, pound cake, chiffon cake, souffle, etc. In addition, it can also be blended into supplements such as tablets and granules. By blending the powdered plant extract for beverages of the present invention, the original flavor of the plant extract can be imparted to various foods and drinks, lozenges, granules, and the like. The content of the powdered plant extracts for beverages in these foods also differs depending on the type of food, generally 1 to 100% by mass, and specifically 5 to 80% by mass. [0047] <The manufacturing method of the powder plant extract for beverages related to the present invention> The present invention is an invention related to the manufacturing method of the powder plant extract for beverages. The manufacturing method of the powder plant extract for beverages includes the following steps: Under the coexistence of an aqueous solvent, the above-mentioned branched α-glucan mixture having the characteristics of (A) to (C) is pressed against the drinking plant extract to the drinking plant extract and the branched α-glucan mixture in a solid The step of mixing the mass conversion ratio of 1: 0.1 to 1:20 to obtain a mixed solution; and the step of pulverizing the obtained mixed solution. [0048] For the production method of the powdered plant extract for beverages, if the outline is specifically described, an aqueous solvent is added to the plant raw material to perform extraction and rough separation to obtain an extraction solution (extraction step). Extract), add and mix the branched α-glucan mixture and dissolve it, further concentrate the extract (concentration step), and then remove the aqueous solvent by drying the concentrate (drying step) to obtain The powder composition is crushed and classified as needed to produce a powdered plant extract for beverages. Regarding the method of blending the branched α-glucan mixture into the extract (plant extract), whether it is added to the aqueous solvent in advance, added to the extract, and concentrated to the extract Any of the methods can be implemented advantageously. In addition, it can also be added by these plural methods. [0049] The so-called extraction step is a step of adding an aqueous solvent to the plant raw material, performing immersion, stirring, or heating to perform extraction to obtain an extraction solution. As the aqueous solvent, water such as tap water, deionized water, distilled water, deoxygenated water, or ethanol and mixed solvents of these can be used. In the aqueous solvent, additives such as antioxidants, emulsifiers, and pH adjusters may be blended alone or in combination. In addition, instead of using an aqueous medium, it is possible to use the juice obtained by pressing the plant raw material instead of the extract. The extraction temperature is not particularly limited, but is preferably 15 ° C or higher and 100 ° C or lower. When the extraction temperature is less than 15 ° C, the extraction efficiency is significantly reduced. In addition, when it is at a temperature exceeding 100 ° C, unnecessary components are excessively extracted, and denaturation of aroma components easily occurs. [0050] The so-called concentration step is a step of selectively removing the aqueous solvent from the plant extract to increase the concentration of the extract. The concentration step itself is not a necessary step. By concentrating the extract in advance, the drying step can be performed efficiently. Concentration can be performed by well-known methods, such as reduced pressure concentration, freeze concentration, and reverse osmosis membrane concentration. Among these, the reverse osmosis membrane concentration and freezing concentration of the volatile and less denatured aroma components derived from the plant extract are preferred. [0051] The so-called drying step is a step of evaporating the aqueous solvent in the liquid of the extraction liquid (or concentrated liquid) into which the branched α-glucan mixture has been blended to perform dry powdering. Dry powdering can be carried out by suitable methods such as hot air drying, vacuum drying, spray drying, freeze vacuum drying, drum drying, extrusion granulation, and flow granulation. Among these, freeze vacuum drying or spray drying with less loss of flavor components derived from the plant extract being dried is preferred. [0052] Hereinafter, the present invention will be described in more detail based on experiments. [0053] <Experiment 1: Effect of powdered base material on the flavor of plant extract beverages> (1) Summary By blending branched α-glucan mixture or indigestible paste in drinking plant extracts As a powdered base material, a powdered plant extract for beverage is prepared, and the influence of the difference in the powdered base material on the flavor of the plant extract beverage when each is dissolved in warm water is investigated. (2) Experimental method (a) The test sample was prepared in oolong tea extract (trade name "Oolong tea extract M aqueous", containing a solution of oolong tea extract solids 10% by mass, sold by Maruzen Pharmaceutical Co., Ltd.) 50g ( To the solids 5g), powders 0.5, 1.65, 2.5 of the same branched α-glucan mixture (hereinafter, referred to as "branched α-glucan mixture") added to the user of Example 1 described later are added. 5.0, 25.0, 50.0, 100.0, 200.0g, mix, add water as needed to obtain 8 kinds of oolong tea extracts with different blending ratio of branched α-glucan mixture. Then, each of the obtained oolong tea extracts blended with the branched α-glucan mixture was freeze-dried to prepare a powdered plant extract (powder oolong tea) for beverages (tested samples 1 to 8). As a comparison object, except that a commercially available indigestible dextrin (trade name "Fibersol 2", sold by Matsutani Chemical Industry Co., Ltd.) was added instead of the branched α-glucan mixture, the same method as above Prepare powdered oolong tea (tested samples 9 to 16). In addition, the obtained test samples 1 to 8 and 9 to 16 each contain a branched α-glucan mixture or indigestible dextrin 0.1, 0.33, 0.5 relative to 1 part by mass of oolong tea extract solids , 1, 5, 10, 20 or 40 parts by mass. [0054] (b) Functional test For the tested samples 1 to 16 of the powdered oolong tea obtained by the above method and the oolong tea extract (control) belonging to the raw material, the solids derived from the oolong tea extract became 0.33 g each It was filled into a teacup by a method, dissolved in 100 ml of warm water at 70 ° C, and its flavor was evaluated by five reviewers based on the evaluation criteria shown in Table 1. The score with the highest number of evaluation reviewers is used as the evaluation score. When the number of people evaluated is the same, the middle score of the evaluation is used as the evaluation score. Table 2 shows the composition and functional evaluation results of the control and tested samples 1 to 16, respectively. [0055] [0056] [0057] As shown in Table 2, it can be seen that the branched α-glucan mixture is used as a powdered base material and added to 0.1 to 20 parts by mass relative to 1 part by mass of solids in the oolong tea extract. The finished powdered oolong tea (test samples 1 to 7) is dissolved in warm water. The oolong tea is the same aroma or flavor as the control oolong tea. Add 0.33 to 5 parts by mass of powdered oolong tea (tested sample 2) The series to 5) are particularly excellent. Here, it can be seen that in the powdered oolong tea (tested sample 8) made by adding 40 parts by mass of branched α-glucan mixture, the branched α-glucan will be felt for the oolong tea obtained by dissolution The sweetness or odor of the mixture impairs the original flavor or aroma of oolong tea. On the other hand, it can be seen that in the oolong tea obtained by dissolving the powdered oolong tea (tested samples 9 to 16) prepared using indigestible dextrin as the powdered base material in warm water, all the tested samples Compared with the control of oolong tea, the medium will damage the aroma or flavor, etc. This effect becomes more significant as the amount of indigestible dextrin increases. [Experiment 2: The effect of differences in the types of powdered substrates on the cold water solubility of powdered plant extracts for beverages] (1) Summary Add and blend branched α-glucose in drinking plant extracts Glycan mixtures, indigestible dextrins or dextrins are used as powdered substrates, and the effects of differences in the types of powdered substrates on the solubility of powdered plant extracts for beverages are investigated. Assuming that the plant extract beverage is used in cold water, the experiment is carried out under low temperature conditions that are relatively difficult to dissolve. [0059] (2) Experimental method (a) The preparation of the tested sample is mixed with the general dextrin (trade name "commodity" in such a way that the solid content is converted into 5 parts by mass relative to 1 part by mass of the oolong tea extract solids) Pine Dex # 1 ", a starch decomposed product of DE7.5, sold by Matsutani Chemical Industry Co., Ltd.) instead of the branched α-glucan mixture or indigestible dextrin, the blend was obtained in the same manner as in Experiment 1. And powdered oolong tea with dextrin. (b) Solubility test: the powdered oolong tea mixed with dextrin obtained in (a) above, and the tested samples 5 and 13 obtained in experiment 1 (relative to 1 part by mass of solids derived from oolong tea extract) Powdered oolong tea containing 5 parts by mass of branched α-glucan mixture or indigestible dextrin) 0.5g each was added to 50ml of cold water at 5 ° C, and each was stirred at 200 rpm for visual determination until completely dissolved Time. The experiment system was performed twice, and the results of evaluating the solubility in four stages based on the average time of the two times are shown in Table 3. In addition, those who dissolve more than 5 minutes and less than 10 minutes are evaluated as "4", those who dissolve more than 10 minutes and less than 15 minutes are evaluated as "3", those who dissolve more than 15 minutes and less than 20 minutes It is evaluated as "2", and those who dissolve for more than 20 minutes are evaluated as "1". [0060] [0061] As shown in Table 3, the powdered oolong tea of the present invention using the branched α-glucan mixture as the powdered base material has the best solubility, and is completely dissolved in 5 minutes or more and less than 10 minutes. On the other hand, it was confirmed that the powdered oolong tea using indigestible dextrin as the powdered base material required 10 minutes or more and less than 15 minutes to dissolve, and the solubility was slightly poor. Furthermore, powdered oolong tea with dextrin as the powdered base material will agglomerate when added to cold water, and it will take more than 20 minutes until completely dissolved, and the solubility is significantly lower. [0062] From the results of Experiments 1 and 2 described above, it can be concluded that the branched α-glucan mixture of the present invention is compared to dextrin used in conventional powdered oolong tea or currently marketed as a water-soluble food For the indigestible dextrin of fiber, the solubility of powdered oolong tea and the retention of the aroma or flavor when dissolved in hot water are excellent. It is generally believed that the higher solubility and flavor maintenance effect caused by this branched α-glucan mixture is not only the tea produced by processing and extracting the same tea tree in oolong tea, It can be played in the same way in all the plant extract beverages with aroma or flavor. [0063] The reason for the present branched α-glucan mixture to retain the flavor derived from the drinking plant extract more effectively than the conventionally known powdered substrate is unknown. However, it is generally considered to have the above-mentioned structural characteristics of (A) to (C), in particular, compared to indigestible dextrin or dextrin, it has a digestion produced by isomalt glucanase digestion. The structural characteristics of isomaltose with a solid content of more than 5 mass% are necessary to exert its function, and it can be presumed that the structural characteristics of the branched α-glucan mixture act on the flavor and aroma components of plant extracts. [0064] Hereinafter, the present invention will be described in further detail by examples, but the present invention is not limited by these examples. [Example 1] [0065] <Powder Green Tea> 0.5 kg of green tea leaves was added to 10 kg of warm water at 80 ° C. and extracted at 80 ° C. for 15 minutes. Meal separation was performed to obtain 8 kg of tea extract with Brix 2.5 degree. After the obtained extract is clarified by a centrifuge, it is supplied to a membrane for concentration. A branched α-glucan having the following characteristics (a) to (j) obtained according to the method disclosed in Example 5 of International Publication No. WO2008 / 136331 was added and dissolved in the obtained concentrated liquid The sugar mixture powder was 150 g, and the solution was freeze-dried to obtain powdered green tea. The mass ratio of the tea extract and the branched α-glucan mixture in terms of solids is 1: 0.75. The obtained powdered green tea was dissolved in warm water at 70 ° C. As a result, it quickly dissolved and the original refreshing aroma and flavor of green tea were felt. <Characteristics of branched α-glucan mixture> (a) Glucose is used as a constituent sugar. (b) The non-reducing terminal glucose residue at one end of the linear glucan having a glucose polymerization degree of 3 or more connected by an α-1,4 bond has a bond other than the α-1,4 bond A branched structure of glucose with a polymerization degree of 1 or more. (c) Isomalt glucanase digestion produces 38.0% by mass of isomaltose solids per digest. (d) The water-soluble dietary fiber content determined by high-performance liquid chromatography (enzyme-HPLC method) was 81.2% by mass. (e) The ratio of α-1,4-linked glucose residues to α-1,6-linked glucose residues is 1: 2.6. (f) The total of α-1,4-linked glucose residues and α-1,6-linked glucose residues account for 70.3% of all glucose residues. (g) The α-1,3-linked glucose residue is 2.8% of all glucose residues. (h) The glucose residues bound by α-1,3,6 are 7.2% of all glucose residues. (i) The weight average molecular weight is 4,600. (j) Mw / Mn is 2.3. [Example 2] [0066] <Powder Black Tea> 0.75 kg of black tea leaves were added to 10 kg of warm water at 80 ° C. and extracted at 80 ° C. for 15 minutes. Meal separation was performed to obtain 8 kg of extract with a Brix degree of 3.8 degrees. After the obtained extract is clarified by a centrifuge, it is supplied to a membrane for concentration. To the obtained concentrated liquid, a branched α-glucan mixture having the following characteristics (a) to (j) obtained according to the method disclosed in Example 3 of International Publication No. WO2008 / 136331 is added. 300g of powder, freeze-dried the solution to obtain powdered black tea. The mass ratio of the mixture of black tea extract and branched α-glucan in terms of solids is 1: 1.5. The obtained powdered black tea was dissolved in warm water at 70 ° C. As a result, it quickly dissolved, and the original aroma and flavor of the black tea were felt. <Characteristics of branched α-glucan mixture> (a) Glucose is used as a constituent sugar. (b) The non-reducing terminal glucose residue at one end of the linear glucan having a glucose polymerization degree of 3 or more connected by an α-1,4 bond has a bond other than the α-1,4 bond A branched structure of glucose with a polymerization degree of 1 or more. (c) Isomaltose is digested by isomalt glucanase to produce 36.4% by mass of isomaltose per solid of digest. (d) The water-soluble dietary fiber content determined by high-performance liquid chromatography (enzyme-HPLC method) is 75.2% by mass. (e) The ratio of α-1,4-linked glucose residues to α-1,6-linked glucose residues is 1: 1.5. (f) The total of α-1,4-linked glucose residues and α-1,6-linked glucose residues account for 68.0% of all glucose residues. (g) The α-1,3-linked glucose residue is 3.5% of all glucose residues. (h) The glucose residues bound by α-1,3,6 are 4.5% of all glucose residues. (i) The weight average molecular weight is 6,300. (j) Mw / Mn is 2.2. [Example 3] [0067] <Powder Chamomile Tea> 1.5 kg of chamomile tea leaves was added to 10 kg of warm water at 80 ° C. and extracted at 80 ° C. for 15 minutes. Meal separation was performed to obtain 16 kg of extract with a Brix degree of 1.6 degrees. After the obtained extract is clarified by a centrifuge, it is supplied to a membrane for concentration. To the obtained concentrated liquid, a branched α-glucan mixture having the following characteristics (a) to (j) obtained according to the method disclosed in Example 4 of International Publication No. WO2008 / 136331 is added. 300g of powder, freeze-dried the solution to obtain powdered chamomile tea. The mass ratio of the mixture of chamomile tea extract and branched α-glucan in terms of solids is 1: 0.8. The obtained powdered chamomile tea was dissolved in warm water at 70 ° C. As a result, it quickly dissolved and the original refreshing aroma and flavor of the chamomile tea were felt. <Characteristics of branched α-glucan mixture> (a) Glucose is used as a constituent sugar. (b) The non-reducing terminal glucose residue at one end of the linear glucan having a glucose polymerization degree of 3 or more connected by an α-1,4 bond has a bond other than the α-1,4 bond A branched structure of glucose with a polymerization degree of 1 or more. (c) 41.8% by mass of isomaltose solids per digest is produced by isomalt glucanase digestion. (d) The content of water-soluble dietary fiber determined by high-performance liquid chromatography (enzyme-HPLC method) is 68.5% by mass. (e) The ratio of α-1,4-linked glucose residues to α-1,6-linked glucose residues is 1: 1.9. (f) The total of α-1,4-linked glucose residues and α-1,6-linked glucose residues account for 78.9% of all glucose residues. (g) The α-1,3-linked glucose residues are 1.7% of all glucose residues. (h) The glucose residues bound by α-1,3,6 are 2.2% of all glucose residues. (i) The weight average molecular weight is 10,000. (j) Mw / Mn is 2.7. [Example 4] [0068] <Powder Houttuynia cordata> 0.5kg of Houttuynia cordata leaf was added to 10 kg of warm water at 90 ° C. and extracted at 90 ° C. for 15 minutes. Meal separation was performed to obtain 8 kg of extract with a Brix degree of 1.9 degrees. After the obtained extract is clarified by a centrifuge, it is supplied to a membrane for concentration. To the obtained concentrated liquid, a branched α-glucan mixture having the following characteristics (a) to (j) obtained according to the method disclosed in Example 6 of International Publication No. WO2008 / 136331 is added. 250g of powder, freeze drying the solution to obtain powdered Houttuynia cordata tea. The mass ratio of the mixture of Houttuynia cordata extract and branched α-glucan in terms of solids is 1: 1.2. The obtained powdered Houttuynia cordata tea was dissolved in warm water at 70 ° C. As a result, it quickly dissolved and the original aroma and flavor of Houttuynia cordata tea were felt. <Characteristics of branched α-glucan mixture> (a) Glucose is used as a constituent sugar. (b) The non-reducing terminal glucose residue at one end of the linear glucan having a glucose polymerization degree of 3 or more connected by an α-1,4 bond has a bond other than the α-1,4 bond A branched structure of glucose with a polymerization degree of 1 or more. (c) 40.1% by mass of isomaltose per solid of digested matter is produced by isomalt glucanase digestion. (d) The water-soluble dietary fiber content determined by high-performance liquid chromatography (enzyme-HPLC method) was 83.8% by mass. (e) The ratio of α-1,4-linked glucose residues to α-1,6-linked glucose residues is 1: 3.8. (f) The total of α-1,4-linked glucose residues and α-1,6-linked glucose residues account for 66.6% of all glucose residues. (g) The α-1,3-linked glucose residue is 2.6% of all glucose residues. (h) The glucose residues bound by α-1,3,6 are 5.6% of all glucose residues. (i) The weight average molecular weight is 3,200. (j) Mw / Mn is 2.1. [Reference example] [0069] <Powder plant extract for beverages> In addition to using dextrin DE25 (trade name "Pine Dex # 3", sold by Matsutani Chemical Industry Co., Ltd.) which is a general dextrin, DE20 paste Jing (trade name "LDX35-20", sold by Showa Industries Co., Ltd.), DE15 dextrin (trade name "Glister", sold by Matsutani Chemical Industry Co., Ltd.), DE14 dextrin (trade name "liquid "Dextrin", sold by Matsutani Chemical Industries Co., Ltd., DE11 (trade name "Pine Dex # 2", sold by Matsutani Chemical Industries Co., Ltd.) or DE4 dextrin (trade name "Pine Dex # 100"", Sold by Matsutani Chemical Industry Co., Ltd.) Instead of the branched α-glucan mixture used in Example 1, six kinds of powdered green tea were prepared in the same manner as in Example 1. [0070] The 6 kinds of powdered plant extracts (powder green tea) obtained in this example and the powdered plant extracts (powder green tea) of the present invention obtained in example 1 were used as solids derived from green tea extract Each was put into a teacup in the form of 0.33 g and dissolved in 100 ml of hot water at 70 ° C. The flavors were compared for these. As a result, the 6 kinds of powdered plant extracts for beverage obtained in this example were compared with those in Example 1. The obtained powdered plant extract for beverages of the present invention is significantly inferior in terms of flavor, aroma, unique bitterness of green tea, and taste derived from the base material. [Industrial Applicability] [0071] As described above, the present invention provides powdered plant extracts for beverages having improved flavor and solubility compared to conventional powdered plant extracts for beverages and the like Manufacturing method. The impact of the present invention on this field is so great that the industrial applicability of the present invention is extremely great.

Claims (10)

一種飲料用粉末植物萃取物,其包含飲用植物萃取物及具有下述(A)至(C)的特徵之分枝α-葡聚醣混合物,前述飲料用粉末植物萃取物中所包含之飲用植物萃取物與分枝α-葡聚醣混合物之按固形物換算之質量比為1:0.1~1:20;   (A)以葡萄糖作為構成糖,   (B)在位於經由α-1,4鍵結連結而成之葡萄糖聚合度3以上的直鏈狀葡聚醣的一端之非還原末端葡萄糖殘基具有經由α-1,4鍵結以外之鍵結連結而成之葡萄糖聚合度1以上的分枝結構,   (C)藉由異麥芽葡聚醣酶消化,而生成每消化物的固形物5質量%以上異麥芽糖。A powdered plant extract for beverages comprising a drinkable plant extract and a branched α-glucan mixture having the following characteristics (A) to (C), the drinkable plant contained in the powdered plant extract for beverages The mass ratio of the extract and the branched α-glucan mixture in terms of solids is 1: 0.1 ~ 1: 20; (A) uses glucose as the constituent sugar, (B) is located via α-1,4 bonding The non-reducing terminal glucose residue at one end of the linear glucan having a glucose polymerization degree of 3 or more has a branch having a glucose polymerization degree of 1 or more connected by a bond other than the α-1,4 bond In the structure, (C) is digested with isomalt glucanase to produce 5% by mass or more of isomaltose per solid matter of digest. 如申請專利範圍第1項之飲料用粉末植物萃取物,其中,前述分枝α-葡聚醣混合物為具有下述(D)的特徵之分枝α-葡聚醣混合物;   (D)藉由高效液相層析法(酵素-HPLC法)所求出之水溶性食物纖維含量為40質量%以上。A powdered plant extract for beverages as claimed in item 1 of the patent application, wherein the aforementioned branched α-glucan mixture is a branched α-glucan mixture having the following characteristics (D); (D) The content of water-soluble dietary fiber determined by high-performance liquid chromatography (enzyme-HPLC method) is 40% by mass or more. 如申請專利範圍第1或2項之飲料用粉末植物萃取物,其中,前述分枝α-葡聚醣混合物為具有下述(E)及(F)的特性之分枝α-葡聚醣混合物;   (E)經α-1,4鍵結之葡萄糖殘基與經α-1,6鍵結之葡萄糖殘基之比係在1:0.6至1:4的範圍,以及   (F)經α-1,4鍵結之葡萄糖殘基及經α-1,6鍵結之葡萄糖殘基之合計佔所有葡萄糖殘基的55%以上。The powdered plant extract for beverages as claimed in item 1 or 2 of the patent application, wherein the aforementioned branched α-glucan mixture is a branched α-glucan mixture having the following characteristics (E) and (F) ; (E) The ratio of glucose residues bonded by α-1,4 to glucose residues bonded by α-1,6 is in the range of 1: 0.6 to 1: 4, and (F) by α- The total of 1,4-linked glucose residues and α-1,6-linked glucose residues accounts for more than 55% of all glucose residues. 如申請專利範圍第1至3項中任一項之飲料用粉末植物萃取物,其中,前述分枝α-葡聚醣混合物的平均葡萄糖聚合度為8至500。The powdered plant extract for beverages according to any one of claims 1 to 3, wherein the average degree of glucose polymerization of the aforementioned branched α-glucan mixture is 8 to 500. 如申請專利範圍第1至4項中任一項之飲料用粉末植物萃取物,其中,前述飲用植物萃取物與分枝α-葡聚醣混合物之按固形物換算之質量比為1:0.33~1:5。The powdered plant extract for beverages according to any one of the items 1 to 4 of the patent application range, wherein the mass ratio in terms of solids of the mixture of the drinkable plant extract and the branched α-glucan is 1: 0.33 ~ 1: 5. 如申請專利範圍第1至5項中任一項之飲料用粉末植物萃取物,其中,前述飲用植物萃取物之植物為選自茶樹、洋甘菊、洛神花、薰衣草、薄荷、玫瑰果、胡椒薄荷、檸檬草、魚腥草、匙羹藤、大花紫薇、銀杏、黃麻菜、紫花苜蓿、魁蒿、巴拉圭冬青、佳葉龍茶、杜仲、南非茶、蘆薈、櫻葉、紫蘇、麥、薏米、稻、大豆、蕎麥、朝鮮人蔘、牛蒡、咖啡樹之一種以上。The powdered plant extract for beverages according to any one of items 1 to 5 of the patent application range, wherein the plant of the drinkable plant extract is selected from the group consisting of tea tree, chamomile, roselle, lavender, mint, rose hip, peppermint, Lemongrass, Houttuynia cordata, Gymnema sylvestris, Lagerstroemia indica, Ginkgo biloba, Jute, alfalfa, cumin, hollywood Paraguay, hollyhock tea, eucommia, South African tea, aloe vera, cherry leaves, perilla, wheat, barley More than one of rice, soybean, buckwheat, Korean ginseng, burdock, coffee tree. 如申請專利範圍第1至6項中任一項之飲料用粉末植物萃取物,其中,前述飲用植物萃取物係將選自植物的葉、莖、花、萼、根、種子等之一種以上進行提取而成。The powdered plant extract for beverages according to any one of the items 1 to 6 of the patent application range, wherein the drinkable plant extract is carried out by more than one kind selected from leaves, stems, flowers, calyx, roots, seeds, etc. of plants Extracted. 如申請專利範圍第1至7項中任一項之飲料用粉末植物萃取物,其中,前述飲用植物萃取物之植物為茶樹。The powdered plant extract for beverages according to any one of claims 1 to 7 of the patent application, wherein the plant for drinking the plant extract is tea tree. 如申請專利範圍第1至8項中任一項之飲料用粉末植物萃取物,其中,前述飲用植物萃取物為綠茶、烏龍茶或紅茶。The powdered plant extract for beverages according to any one of items 1 to 8 of the patent application range, wherein the drinkable plant extract is green tea, oolong tea or black tea. 一種飲料用粉末植物萃取物之製造方法,其包含下列步驟:在水性溶媒的共存下,將具有下述(A)至(C)的特徵之分枝α-葡聚醣混合物對飲用植物萃取物以飲用植物萃取物與分枝α-葡聚醣混合物之按固形物換算之質量比成為1:0.1~1:20之方式進行混合,而獲得混合溶液之步驟;以及將所獲得之混合溶液進行粉末化之步驟;   (A)以葡萄糖作為構成糖,   (B)在位於經由α-1,4鍵結連結而成之葡萄糖聚合度3以上的直鏈狀葡聚醣的一端之非還原末端葡萄糖殘基具有經由α-1,4鍵結以外之鍵結連結而成之葡萄糖聚合度1以上的分枝結構,   (C)藉由異麥芽葡聚醣酶消化,而生成每消化物的固形物5質量%以上異麥芽糖。A method for manufacturing powder plant extracts for beverages, comprising the following steps: in the presence of an aqueous solvent, a branched α-glucan mixture having the following characteristics (A) to (C) to a drinking plant extract The step of obtaining the mixed solution by mixing the drinking plant extract and the branched α-glucan mixture in a mass conversion ratio of 1: 0.1 to 1:20 to obtain a mixed solution; and performing the obtained mixed solution The step of powdering; (A) uses glucose as a constituent sugar, and (B) is a non-reducing terminal glucose located at one end of a linear glucan having a glucose polymerization degree of 3 or more connected by α-1,4 linkage The residue has a branched structure with a glucose polymerization degree of 1 or more connected by a bond other than the α-1,4 bond, (C) is digested by isomalt glucanase to generate a solid form of each digest It is more than 5 mass% of isomaltose.
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