TW201825842A - Ultrapure water manufacturing device - Google Patents

Ultrapure water manufacturing device Download PDF

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TW201825842A
TW201825842A TW106111921A TW106111921A TW201825842A TW 201825842 A TW201825842 A TW 201825842A TW 106111921 A TW106111921 A TW 106111921A TW 106111921 A TW106111921 A TW 106111921A TW 201825842 A TW201825842 A TW 201825842A
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water
heat exchanger
flow path
heat
medium
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TW106111921A
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TWI691687B (en
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堀井重希
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栗田工業股份有限公司
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24HFLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H1/00Water heaters, e.g. boilers, continuous-flow heaters or water-storage heaters
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24HFLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H1/00Water heaters, e.g. boilers, continuous-flow heaters or water-storage heaters
    • F24H1/10Continuous-flow heaters, i.e. heaters in which heat is generated only while the water is flowing, e.g. with direct contact of the water with the heating medium
    • F24H1/12Continuous-flow heaters, i.e. heaters in which heat is generated only while the water is flowing, e.g. with direct contact of the water with the heating medium in which the water is kept separate from the heating medium
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24HFLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H4/00Fluid heaters characterised by the use of heat pumps
    • F24H4/02Water heaters
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/02Non-contaminated water, e.g. for industrial water supply
    • C02F2103/04Non-contaminated water, e.g. for industrial water supply for obtaining ultra-pure water

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Hydrology & Water Resources (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Heat-Pump Type And Storage Water Heaters (AREA)
  • Instantaneous Water Boilers, Portable Hot-Water Supply Apparatuses, And Control Of Portable Hot-Water Supply Apparatuses (AREA)
  • Heat Treatment Of Water, Waste Water Or Sewage (AREA)

Abstract

Provided is an ultrapure water manufacturing device that can reduce the heat source cost of a heat exchanger, said heat exchanger being for heating ultrapure water to produce warm ultrapure water. Secondary pure water from a subsystem 4 is heated with a heat exchanger 6 and a heat exchanger 10, and is sent to a use point. A heat source of the heat exchanger 6 is returning warm ultrapure water from the use point. A heat source fluid of the heat exchanger 10 is warm water that has been heated with a heat pump 20 and a vapor-type heat exchanger 15. Heat sources of the heat pump 20 are warm discharge water from the use point and a retentate of a UF membrane separation device 11A.

Description

超純水製造裝置    Ultra-pure water manufacturing device   

本發明係關於超純水製造裝置,特別是關於將來自二次純水製造裝置的超純水以熱交換器進行加熱而作為溫超純水來供應至使用點的超純水製造裝置。 The present invention relates to an ultrapure water production device, and more particularly to an ultrapure water production device that heats ultrapure water from a secondary pure water production device with a heat exchanger and supplies it to the point of use as warm ultrapure water.

作為半導體洗淨用水來使用的超純水,係如圖7所示般使用由預處理系統50、一次純水製造裝置60、二次純水製造裝置(多稱為副系統)70所構成的超純水製造裝置來處理原水(工業用水、民生用水、井水等)來製造(專利文獻1)。圖7中各系統的功能係如以下所述。 As shown in FIG. 7, ultrapure water used as semiconductor washing water is composed of a pretreatment system 50, a primary pure water production device 60, and a secondary pure water production device (referred to as a sub-system) 70. An ultrapure water manufacturing apparatus is used to process raw water (industrial water, domestic water, well water, etc.) and manufacture it (Patent Document 1). The functions of each system in FIG. 7 are as follows.

在由凝集、加壓浮上(沈澱)、過濾(膜過濾)裝置等(該先前例為凝集過濾裝置)所成的預處理系統50中,進行原水中之懸浮物質或膠體物質的去除。且,在該過程中亦可去除高分子有機物、疏水性有機物等。 Removal of suspended matter or colloidal matter in raw water is performed in a pretreatment system 50 made up of an agglutination, pressure floating (precipitation), filtration (membrane filtration) device (the previous example is an agglutination filtration device). Moreover, polymer organic matter, hydrophobic organic matter, etc. can also be removed in this process.

在具備:預處理過之水的槽61、熱交換器65、逆滲透膜處理裝置(RO裝置)62、離子交換裝置(混合床式或4床5塔式等)63、槽63A、離子交換裝置63B、及脫氣裝置64的一次純水製造裝置60中,進行原水中之離子或有機成分的去除。又,水的溫度越高,則黏性越低,RO 膜的滲透性會提升。因此,如圖7所示,在逆滲透膜處理裝置62的前段設置有熱交換器65,將水加熱而使往逆滲透膜處理裝置62之供給水的溫度成為既定溫度以上。於熱交換器65的1次側,供給有作為熱源流體的蒸氣。在逆滲透膜處理裝置62中,去除鹽類並去除離子性、膠體性的TOC。在離子交換裝置63、63B中,去除鹽類、無機碳(IC)並藉由離子交換樹脂來進行吸附或離子交換之TOC成分的去除。在脫氣裝置64中進行無機碳(IC)、溶解氧的去除。 In the pre-treated water tank 61, heat exchanger 65, reverse osmosis membrane processing device (RO device) 62, ion exchange device (mixed bed type or 4 bed 5 tower type, etc.) 63, tank 63A, ion exchange The apparatus 63B and the primary pure water production apparatus 60 of the degassing apparatus 64 remove ions or organic components in raw water. In addition, the higher the temperature of water, the lower the viscosity, and the permeability of the RO membrane will increase. Therefore, as shown in FIG. 7, the heat exchanger 65 is provided in the front stage of the reverse osmosis membrane processing apparatus 62, and water is heated so that the temperature of the water supplied to the reverse osmosis membrane processing apparatus 62 may become more than predetermined temperature. On the primary side of the heat exchanger 65, steam as a heat source fluid is supplied. The reverse osmosis membrane processing apparatus 62 removes salts and removes ionic and colloidal TOC. In the ion exchange devices 63 and 63B, salts and inorganic carbon (IC) are removed, and TOC components for adsorption or ion exchange are removed by an ion exchange resin. The degassing device 64 removes inorganic carbon (IC) and dissolved oxygen.

在一次純水製造裝置60所製造的一次純水,係透過配管69而送水至溫超純水製造用的二次純水製造裝置70。該二次純水製造裝置70,係具備:副槽(亦有被稱之為純水槽)71、泵72、低壓紫外線氧化裝置(UV裝置)74、離子交換裝置75。低壓紫外線氧化裝置74,係藉由低壓紫外線燈所發出之185nm的紫外線來將TOC分解成有機酸、甚至是CO2。因分解而生成的有機物及CO2係藉由後段的離子交換裝置75來去除。 The primary pure water produced by the primary pure water producing device 60 is sent through a pipe 69 to a secondary pure water producing device 70 for producing ultra-pure water. The secondary pure water production device 70 includes a sub tank (also referred to as a pure water tank) 71, a pump 72, a low-pressure ultraviolet oxidation device (UV device) 74, and an ion exchange device 75. The low-pressure ultraviolet oxidizing device 74 decomposes TOC into organic acids and even CO 2 by ultraviolet rays of 185 nm emitted by a low-pressure ultraviolet lamp. Organic matter and CO 2 generated by the decomposition are removed by an ion exchange device 75 at a later stage.

將來自二次純水製造裝置70的超純水藉由前段側熱交換器85與後段側熱交換器86來加熱至70~80℃左右,並供給至使用點90。將來自該使用點90的溫回流水透過配管91來流通至前段側熱交換器85的熱源側。通過前段側熱交換器85之熱源側的回流水係降溫至40℃左右,並透過配管92回到副槽71。後段側熱交換器86係以蒸氣為熱源者。 The ultrapure water from the secondary pure water production device 70 is heated to about 70 to 80 ° C. by the front-stage heat exchanger 85 and the rear-stage heat exchanger 86 and supplied to a use point 90. The warm return water from the use point 90 is passed through the pipe 91 to flow to the heat source side of the front-stage-side heat exchanger 85. The temperature of the return water passing through the heat source side of the front-stage heat exchanger 85 is lowered to about 40 ° C., and returns to the sub tank 71 through the pipe 92. The rear-stage heat exchanger 86 uses steam as a heat source.

來自一次純水製造裝置60之一次純水的一部分,係送水至常溫超純水製造用的二次純水製造裝置70’。該二次純水製造裝置70’,係具備:副槽(亦有被稱之為純水槽)71’、泵72’、熱交換器73’、低壓紫外線氧化裝置(UV裝置)74’、離子交換裝置75’及超過濾膜(UF膜)分離裝置76’。從超過濾膜分離裝置76’透過配管88’來使常溫超純水被送到使用點90’。來自該使用點90’的回流水,係透過配管92’回到副槽71’。 A part of the primary pure water from the primary pure water production device 60 is a secondary pure water production device 70 'for supplying water to normal temperature ultrapure water production. The secondary pure water production device 70 'includes a sub tank (also referred to as a pure water tank) 71', a pump 72 ', a heat exchanger 73', a low-pressure ultraviolet oxidation device (UV device) 74 ', and ions. The exchange device 75 'and the ultrafiltration membrane (UF membrane) separation device 76'. From the ultrafiltration membrane separation device 76 ', a pipe 88' is passed to the room temperature ultrapure water to be used at the point of use 90 '. The return water from the use point 90 'is returned to the sub tank 71' through the pipe 92 '.

圖6係表示關於參考例之超純水製造裝置的系統圖。又,以下的說明中雖示例出水溫,但各水溫僅為一例,並沒有對本發明做出任何限定。 FIG. 6 is a system diagram showing an ultrapure water production apparatus according to a reference example. In addition, although the water temperature is illustrated in the following description, each water temperature is only an example, and does not limit the present invention at all.

約25℃的一次純水,係透過配管1、副槽2、配管3而導入至副系統4,從而製造有約30℃的超純水。所製造的超純水,係依序流過配管5、熱交換器6、配管9及熱交換器10,且藉由熱交換器6加熱至約42℃,並藉由熱交換器10加熱至約75℃,而作為溫超純水藉由配管11送水至使用點。於配管11,在即將抵達使用點之前設置有UF膜分離裝置11A。 The primary pure water at about 25 ° C is introduced into the secondary system 4 through the piping 1, the auxiliary tank 2, and the piping 3, thereby producing ultrapure water at about 30 ° C. The manufactured ultrapure water flows through the pipe 5, the heat exchanger 6, the pipe 9, and the heat exchanger 10 in this order, and is heated to about 42 ° C by the heat exchanger 6 and heated to The temperature is about 75 ° C, and water is sent to the point of use through the pipe 11 as warm ultrapure water. A UF membrane separation device 11A is installed on the pipe 11 immediately before the point of use.

在熱交換器6的熱源流體流路,透過配管7而導入有來自使用點之約75℃的回流溫超純水(回流水)。該回流溫超純水,係在熱交換器6與來自副系統4的超純水進行熱交換而降溫至約40℃之後,藉由配管8而送到副槽2。 Into the heat source fluid flow path of the heat exchanger 6, a return temperature ultrapure water (return water) of about 75 ° C. from the point of use is introduced through the pipe 7. The reflux temperature ultrapure water is cooled to about 40 ° C. by heat exchange between the heat exchanger 6 and ultrapure water from the sub-system 4, and then sent to the sub-tank 2 through a pipe 8.

於熱交換器10的熱源流體流路,循環流通有藉由熱交換器13、15加熱至約80℃的第1媒介水(作為傳熱 媒介的水)。亦即,從熱交換器10的熱源流體流路出口所流出之約47℃的第1媒介水,係從配管12通過熱交換器13被加熱至約49℃之後,流過配管14、熱交換器15、配管16而回到熱交換器10的熱源流體流路入口。 In the heat source fluid flow path of the heat exchanger 10, first medium water (water as a heat transfer medium) heated to about 80 ° C by the heat exchangers 13, 15 is circulated. That is, the first medium water at about 47 ° C. flowing out of the heat source fluid flow path outlet of the heat exchanger 10 is heated from the pipe 12 to about 49 ° C. through the heat exchanger 13, and then flows through the pipe 14 to exchange heat. The heater 15 and the piping 16 return to the heat source fluid flow path inlet of the heat exchanger 10.

於熱交換器13的熱源流體流路,透過配管17而導入有約56℃的溫排水。在熱交換器13降溫至約53℃的溫排水,係透過配管18而流出,且作為回收水而被回收。 The heat-source fluid flow path in the heat exchanger 13 is passed through the piping 17 to introduce warm water drainage at about 56 ° C. The warm drainage water cooled down to about 53 ° C. in the heat exchanger 13 flows out through the pipe 18 and is recovered as recovered water.

於熱交換器15的熱源流體流路,流通有來自鍋爐等的蒸氣(水蒸氣)。 Steam (water vapor) from a boiler or the like flows through the heat source fluid flow path of the heat exchanger 15.

圖示中雖省略,但在配管12、14或16設有循環用的泵。 Although not shown in the drawing, a circulating pump is provided in the piping 12, 14 or 16.

該圖6的超純水製造裝置中,在熱交換器13亦藉由溫排水所保有的熱來對第1媒介水加熱,故與僅藉由蒸氣式熱交換器來對來自熱交換器6的超純水進行加熱的情況相比之下,用來得到既定溫度之溫超純水的熱源成本會變便宜。但是,回流超純水之熱的回收不夠充分,期望有熱源成本之進一步的降低。 In the ultrapure water production apparatus of FIG. 6, the heat exchanger 13 also heats the first medium water by using the heat retained by the warm water drainage. In comparison to the case of heating ultrapure water, the cost of the heat source used to obtain the temperature of the ultrapure water at a given temperature becomes cheaper. However, the heat recovery of the returning ultrapure water is insufficient, and further reduction of the cost of the heat source is expected.

[專利文獻1]日本特開2013-202581 [Patent Document 1] Japanese Patent Laid-Open No. 2013-202581

本發明,其目的在於提供一種超純水製造裝置,可將對送水至使用點之超純水予以加溫來成為溫超純水用之熱交換器的熱源成本予以降低。 The purpose of the present invention is to provide an ultrapure water manufacturing device, which can reduce the cost of heat source for heating ultrapure water sent to the point of use to become a heat exchanger for warming ultrapure water.

本發明之一態樣的超純水製造裝置,係將被 加熱過的超純水供給至使用點,其具備:一次純水製造裝置、將來自該一次純水製造裝置的一次純水予以處理而製造超純水的二次純水製造裝置、用來將來自該二次純水製造裝置的超純水予以加熱並以來自使用點的回流水作為熱源的第1熱交換器、以及對在該第1熱交換器所加熱過的超純水進一步進行加熱的加熱手段,前述加熱手段,係具備:使在前述第1熱交換器被加熱過的超純水流通至被加熱流體流路的第2熱交換器、使作為傳熱媒介的第1媒介水在該第2熱交換器的熱源流體流路循環流通的第1循環流路、將流動於該第1循環流路的第1媒介水藉由溫排水的熱來加熱的第1媒介水加熱裝置、以及將以該第1媒介水加熱裝置所加熱過的第1媒介水藉由蒸氣來加熱的第3熱交換器。 One aspect of the present invention is an ultrapure water production device that supplies heated ultrapure water to a point of use, and includes: a primary pure water production device; and a method for treating primary pure water from the primary pure water production device. A secondary pure water production device for producing ultrapure water, a first heat exchanger for heating ultrapure water from the secondary pure water production device, and using return water from a point of use as a heat source; A heating means for further heating the ultrapure water heated by the first heat exchanger, the heating means includes means for circulating the ultrapure water heated in the first heat exchanger to a heated fluid flow path. A second heat exchanger, a first circulation flow path that circulates first medium water as a heat transfer medium in a heat source fluid flow path of the second heat exchanger, and a first medium that flows through the first circulation flow path A first medium water heating device in which water is heated by the heat of warm water drainage, and a third heat exchanger in which the first medium water heated by the first medium water heating device is heated by steam.

本發明的一態樣中,前述第1媒介水加熱裝置,係具有加熱泵,其具備凝縮器、蒸發器、泵及膨脹閥,該凝縮器,係設置在前述第1循環流路來加熱該第1媒介水,該蒸發器,係設置在循環有第2媒介水的第2循環流路,於該第2循環流路,設有第2媒介水加熱裝置,其用來以前述溫排水的熱來加熱第2媒介水。 In one aspect of the present invention, the first medium water heating device includes a heat pump including a condenser, an evaporator, a pump, and an expansion valve, and the condenser is installed in the first circulation flow path to heat the The first medium water and the evaporator are provided in a second circulation flow path in which the second medium water is circulated. A second medium water heating device is provided in the second circulation flow path, and is used to drain water at the aforementioned temperature. Heat to heat the second medium water.

本發明的一態樣中,前述第2媒介水加熱裝置,係使前述溫排水流通至熱源流體流路的第5熱交換器。 In one aspect of the present invention, the second medium water heating device is a fifth heat exchanger that passes the warm drain water to a heat source fluid flow path.

本發明的一態樣,係在前述第1熱交換器與第2熱交換器之間,設置有用來加熱前述超純水的第6熱交換 器,且設有溫排水流路,其用來將前述溫排水流通至第6熱交換器之後流通至第5熱交換器的熱源流體流路。 According to one aspect of the present invention, a sixth heat exchanger for heating the ultrapure water is provided between the first heat exchanger and the second heat exchanger, and a warm drainage flow path is provided. The warm drain water is passed to the sixth heat exchanger and then to the heat source fluid flow path of the fifth heat exchanger.

本發明的一態樣中,設有流路切換裝置,係用來切換:使前述溫排水經由前述第6熱交換器而流通至第5熱交換器的第1選擇流路、以及使溫排水繞過前述第6熱交換器而流通至第5熱交換器的第2選擇流路。 According to an aspect of the present invention, a flow path switching device is provided for switching between the first selected flow path in which the warm drain water flows to the fifth heat exchanger through the sixth heat exchanger, and the warm drain water. The second selected flow path that bypasses the sixth heat exchanger and flows to the fifth heat exchanger.

本發明的一態樣中,設有測量前述溫排水之水質的水質感測器,且具備控制裝置,其在該水質感測器的檢測水質比既定值還良好的情況,設成前述第1選擇流路,在檢測水質比該既定值還不良的情況,設成前述第2選擇流路。 In one aspect of the present invention, a water quality sensor for measuring the water quality of the warm drainage water is provided, and a control device is provided. When the detected water quality of the water quality sensor is better than a predetermined value, the water quality sensor is set to the first The selected flow path is set as the second selected flow path described above when the water quality is detected to be worse than the predetermined value.

本發明的一態樣中,前述第2媒介水加熱裝置,係使第3媒介水流通至熱源流體流路的第5熱交換器,於該第5熱交換器的熱源流體流路設有使第3媒介水循環流通用的第3循環流路,於該第3循環流路,設置有藉由前述溫排水來加熱第3媒介水的第7熱交換器。 In one aspect of the present invention, the second medium water heating device is a fifth heat exchanger that circulates the third medium water to the heat source fluid flow path, and a heat source fluid flow path is provided in the fifth heat exchanger. A third circulation flow path common to the third medium water circulation flow is provided in the third circulation flow path with a seventh heat exchanger that heats the third medium water by the warm water drainage.

本發明的一態樣中,在前述第1熱交換器與第2熱交換器之間,設置有用來加熱前述超純水的第6熱交換器,前述第3循環流路,係設置成使在前述第7熱交換器加熱過的第3媒介水經由該第6熱交換器的熱源流體流路而流通至第5熱交換器的熱源流體流路。 In one aspect of the present invention, a sixth heat exchanger for heating the ultrapure water is provided between the first heat exchanger and the second heat exchanger, and the third circulation flow path is provided so that The third medium water heated in the seventh heat exchanger flows through the heat source fluid flow path of the sixth heat exchanger to the heat source fluid flow path of the fifth heat exchanger.

在本發明的超純水製造裝置中,於第1熱交換 器,藉由使用點回流水所保有的熱來加熱超純水。且,藉由以溫排水的熱與蒸氣所加熱過的第1媒介水來作為熱源流體的第2熱交換器,來對該超純水進一步加熱。其結果,將送水至使用點的超純水加溫至既定溫度而成為溫超純水的熱源成本可以降低。 In the ultrapure water producing apparatus of the present invention, the ultrapure water is heated in the first heat exchanger by using the heat retained by the point-return water. Then, the ultrapure water is further heated by the second heat exchanger as the heat source fluid, using the first medium water heated by the heat and steam of the warm drainage water. As a result, it is possible to reduce the cost of heating the ultrapure water sent to the point of use to a predetermined temperature to become a heat source for the ultrapure water.

又,使用點回流水的水溫,通常為70~80℃例如約75℃。 The temperature of the point-of-use reflux water is usually 70 to 80 ° C, for example, about 75 ° C.

本發明中,所謂的溫排水,係指在使用點使用於洗淨的排水。在即將抵達使用點之前所設置的UF膜分離裝置,其濃縮水亦可包含在溫排水。溫排水的溫度,通常為50~60℃例如約56℃。 In the present invention, the so-called warm drainage means drainage used for washing at the point of use. Concentrated water of the UF membrane separation device installed immediately before the point of use can also be included in the warm drainage. The temperature of the warm drainage is usually 50 to 60 ° C, for example, about 56 ° C.

1‧‧‧一次純水 1‧‧‧ once pure water

2‧‧‧副槽 2‧‧‧ auxiliary tank

3‧‧‧配管 3‧‧‧Piping

4‧‧‧副系統 4‧‧‧ Subsystem

5‧‧‧配管 5‧‧‧Piping

6‧‧‧熱交換器 6‧‧‧ heat exchanger

7‧‧‧配管 7‧‧‧Piping

8‧‧‧配管 8‧‧‧Piping

9‧‧‧配管 9‧‧‧Piping

10‧‧‧熱交換器 10‧‧‧ heat exchanger

11‧‧‧配管 11‧‧‧Piping

11A‧‧‧UF膜分離裝置 11A‧‧‧UF membrane separation device

12‧‧‧配管 12‧‧‧Piping

13‧‧‧熱交換器 13‧‧‧Heat exchanger

14‧‧‧配管 14‧‧‧Piping

15‧‧‧熱交換器 15‧‧‧ heat exchanger

16‧‧‧配管 16‧‧‧Piping

17‧‧‧配管 17‧‧‧Piping

18‧‧‧配管 18‧‧‧Piping

圖1為關於實施形態之超純水製造裝置的系統圖。 FIG. 1 is a system diagram of an ultrapure water producing apparatus according to the embodiment.

圖2為關於實施形態之超純水製造裝置的系統圖。 FIG. 2 is a system diagram of an ultrapure water producing apparatus according to the embodiment.

圖3為關於實施形態之超純水製造裝置的系統圖。 Fig. 3 is a system diagram of an ultrapure water producing apparatus according to the embodiment.

圖4為關於實施形態之超純水製造裝置的系統圖。 Fig. 4 is a system diagram of an ultrapure water producing apparatus according to the embodiment.

圖5為關於實施形態之超純水製造裝置的系統圖。 Fig. 5 is a system diagram of an ultrapure water producing apparatus according to the embodiment.

圖6為關於參考例之超純水製造裝置的系統圖。 FIG. 6 is a system diagram of an ultrapure water manufacturing apparatus according to a reference example.

圖7為關於先前例之超純水製造裝置的系統圖。 FIG. 7 is a system diagram of the ultrapure water production apparatus of the previous example.

本發明的超純水製造裝置,具備一次純水製 造裝置及二次純水製造裝置以及加熱超純水的加熱手段。 An ultrapure water producing apparatus of the present invention includes a primary pure water producing apparatus, a secondary pure water producing apparatus, and a heating means for heating ultrapure water.

於該一次純水製造裝置的前段,通常設有預處理裝置。預處理裝置,係施以原水的過濾、凝集沈澱、精密過濾膜等所致的預處理,主要是去除懸浮物質。藉由該預處理,通常使水中的微粒子數量成為103個/mL以下。 A pretreatment device is usually provided at the front stage of the primary pure water production device. The pretreatment device is a pretreatment caused by filtering, agglomeration, and precision filtration membranes of raw water, mainly to remove suspended matter. By this pretreatment, the number of fine particles in water is usually set to 103 / mL or less.

一次純水製造裝置,係具備:逆滲透(RO)膜分離裝置、脫氣裝置、再生式離子交換裝置(混合床式或4床5塔式等)、電氣去離子裝置、紫外線(UV)照射氧化裝置等的氧化裝置等,其進行預處理水中之大半的電解質、微粒子、生菌等的去除。一次純水製造裝置,係例如由熱交換器、2台以上的RO膜分離裝置、混合床式離子交換裝置、及脫氣裝置所構成。 Primary pure water production equipment, including: reverse osmosis (RO) membrane separation device, degassing device, regenerative ion exchange device (mixed bed type or 4 bed 5 tower type, etc.), electrical deionization device, ultraviolet (UV) irradiation An oxidizing device, such as an oxidizing device, removes most of electrolytes, fine particles, germs, and the like in pretreated water. The primary pure water production device is composed of, for example, a heat exchanger, two or more RO membrane separation devices, a mixed-bed ion exchange device, and a degassing device.

二次純水製造裝置,係由副槽、供水泵、冷卻用熱交換器、低壓紫外線氧化裝置或殺菌裝置等紫外線照射裝置、非再生型混合床式離子交換裝置或電氣去離子裝置、超過濾(UF)膜分離裝置或精密過濾(MF)膜分離裝置等之膜過濾裝置所構成,但亦有進一步設置膜脫氣裝置、RO膜分離裝置、電氣去離子裝置等之去鹽裝置的情況。二次純水製造裝置中,適用低壓紫外線氧化裝置,並在其後段設置混合床式離子交換裝置,藉此以紫外線來氧化分解水中的TOC,並藉由離子交換來去除氧化分解生成物。本說明書中,以下,將二次純水製造裝置之中比副槽還後段側的部分稱之為副系統。 Secondary pure water production equipment is composed of auxiliary tanks, water supply pumps, cooling heat exchangers, low-pressure ultraviolet oxidizers, sterilizers and other ultraviolet irradiation devices, non-regenerating mixed bed ion exchange devices or electrical deionization devices, and ultrafiltration (UF) Membrane filtration devices such as membrane separation devices or precision filtration (MF) membrane separation devices. However, there may be cases in which desalting devices such as membrane degassing devices, RO membrane separation devices, and electric deionization devices are further provided. In the secondary pure water production device, a low-pressure ultraviolet oxidation device is applied, and a mixed bed type ion exchange device is provided at the latter stage, thereby oxidizing and decomposing TOC in water with ultraviolet rays, and removing oxidative decomposition products by ion exchange. In the present specification, a portion of the secondary pure water production apparatus that is on the rear side of the sub tank is referred to as a sub system.

又,亦可於二次純水製造裝置的後段設置三 次純水製造裝置,並對來自該三次純水製造裝置的超純水進行加熱。該三次純水製造裝置,係具備與二次純水製造裝置相同的構造,為製造更高純度的超純水者。 It is also possible to install a tertiary pure water production device at the rear stage of the secondary pure water production device and heat the ultrapure water from the tertiary pure water production device. The tertiary pure water production device has the same structure as the secondary pure water production device, and is a person producing ultra-pure water with higher purity.

以下,參照圖式,針對本發明的實施形態進行說明。圖2係表示關於第1實施形態之超純水製造裝置的系統圖。又,以下的說明中雖示例出水溫,但各水溫僅為一例,並沒有對本發明做出任何限定。 Hereinafter, embodiments of the present invention will be described with reference to the drawings. Fig. 2 is a system diagram showing an ultrapure water producing apparatus according to the first embodiment. In addition, although the water temperature is illustrated in the following description, each water temperature is only an example, and does not limit the present invention at all.

約25℃的一次純水,係透過配管1、副槽2、配管3而導入至副系統4,從而製造有約30℃的超純水。所製造的超純水,係依序流過配管5、熱交換器6、配管9及熱交換器10,且藉由熱交換器6加熱至約42℃,並藉由熱交換器10加熱至約75℃,而作為溫超純水藉由配管11送水至使用點。於配管11,在即將抵達使用點之前設置有UF膜分離裝置11A。 The primary pure water at about 25 ° C is introduced into the secondary system 4 through the piping 1, the auxiliary tank 2, and the piping 3, thereby producing ultrapure water at about 30 ° C. The manufactured ultrapure water flows through the pipe 5, the heat exchanger 6, the pipe 9, and the heat exchanger 10 in this order, and is heated to about 42 ° C by the heat exchanger 6 and heated to The temperature is about 75 ° C, and water is sent to the point of use through the pipe 11 as warm ultrapure water. A UF membrane separation device 11A is installed on the pipe 11 immediately before the point of use.

在熱交換器6的熱源流體流路,透過配管7而導入有來自使用點之約75℃的回流溫超純水(回流水)。該回流溫超純水,係在熱交換器6與來自副系統4的超純水進行熱交換而降溫至約40℃之後,藉由配管8而送到副槽2。 Into the heat source fluid flow path of the heat exchanger 6, a return temperature ultrapure water (return water) of about 75 ° C. from the point of use is introduced through the pipe 7. The reflux temperature ultrapure water is cooled to about 40 ° C. by heat exchange between the heat exchanger 6 and ultrapure water from the sub-system 4, and then sent to the sub-tank 2 through a pipe 8.

於熱交換器10的熱源流體流路,循環流通有藉由加熱泵20及蒸氣式熱交換器15所加熱過的第1媒介水(作為傳熱媒介的水)。亦即,將從熱交換器10流出之約60℃的第1媒介水以第1循環流路之加熱泵20的凝縮器23加熱至約70℃之後,以蒸氣式熱交換器15加熱至約85℃而流入熱交換器10。 A first medium water (water as a heat transfer medium) heated by the heat pump 20 and the steam heat exchanger 15 is circulated through the heat source fluid flow path of the heat exchanger 10. That is, the first medium water at about 60 ° C. flowing from the heat exchanger 10 is heated to about 70 ° C. by the condenser 23 of the heat pump 20 of the first circulation flow path, and then heated to about 60 ° C. by the steam heat exchanger 15. 85 ° C and flowed into the heat exchanger 10.

於熱交換器15的熱源流體流路,流通有來自鍋爐等的蒸氣(水蒸氣)。 Steam (water vapor) from a boiler or the like flows through the heat source fluid flow path of the heat exchanger 15.

加熱泵20係構成為:將來自蒸發器21之氯氟烴替代品等的熱媒介以泵22壓縮而導入凝縮器23,並將來自凝縮器23的熱媒介透過膨脹閥24而導入蒸發器21。 The heat pump 20 is configured such that a heat medium such as a chlorofluorocarbon substitute from the evaporator 21 is compressed by the pump 22 and introduced into the condenser 23, and the heat medium from the condenser 23 is introduced into the evaporator 21 through the expansion valve 24. .

使來自熱交換器10的第1媒介水透過配管12而導入至第1循環流路(高溫側流路)的凝縮器23,使在凝縮器23被加熱過的第1媒介水透過配管14而送水至熱交換器15。又,來自凝縮器23之第1媒介水的一部分,係透過旁通配管19而送回配管12。藉此,導入至凝縮器23之第1媒介水的水溫成為約65℃。於旁通配管19,設有流量調節閥(圖示省略)。 The first medium water from the heat exchanger 10 is introduced into the condenser 23 of the first circulation flow path (high-temperature-side flow path) through the pipe 12, and the first medium water heated in the condenser 23 is passed through the pipe 14 to Feed water to heat exchanger 15. A part of the first medium water from the condenser 23 is returned to the pipe 12 through the bypass pipe 19. As a result, the water temperature of the first medium water introduced into the condenser 23 becomes approximately 65 ° C. A flow regulating valve (not shown) is provided in the bypass pipe 19.

圖示中雖省略,但在配管12、14或16設有循環用的泵。後述之圖2~5的超純水製造裝置亦相同。 Although not shown in the drawing, a circulating pump is provided in the piping 12, 14 or 16. The same applies to the ultrapure water production apparatus of FIGS. 2 to 5 described later.

為了使第2媒介水在蒸發器21的熱源流體流路(低溫側流路)循環流通,設有由配管25、熱交換器26及配管27所成的循環流路。又,在配管25、27之間設有旁通配管28。 In order to circulate the second medium water through the heat source fluid flow path (low-temperature-side flow path) of the evaporator 21, a circulation flow path formed by a pipe 25, a heat exchanger 26, and a pipe 27 is provided. A bypass pipe 28 is provided between the pipes 25 and 27.

於熱交換器26的熱源流體流路,透過配管29而導入有約56℃的溫排水。與第2媒介水熱交換而降溫至約25℃的溫排水,係從配管30流出,而作為回收水被回收。 The heat source fluid flow path in the heat exchanger 26 is passed through the piping 29 to introduce warm water at about 56 ° C. The warm drainage water, which has been heat-exchanged with the second medium water and cooled down to about 25 ° C., flows out from the pipe 30 and is recovered as recovered water.

使在熱交換器26被加熱至約30℃的第2媒介水被導入至蒸發器21的熱源流體流路,與加熱泵20的熱媒介 進行熱交換而降溫至約20℃之後,透過配管25而送水至熱交換器26。一部分的第2媒介水,係透過旁通配管28而從配管25流往配管27。藉此,流入至蒸發器21之第2媒介水的水溫成為約25℃。於旁通配管28,設有流量調節閥(圖示省略)。 The second medium water heated to about 30 ° C. in the heat exchanger 26 is introduced into the heat source fluid flow path of the evaporator 21, exchanges heat with the heat medium of the heat pump 20 to reduce the temperature to about 20 ° C., and then passes through the pipe 25. And send water to the heat exchanger 26. A part of the second medium water flows from the pipe 25 to the pipe 27 through the bypass pipe 28. As a result, the water temperature of the second medium water flowing into the evaporator 21 becomes approximately 25 ° C. A flow regulating valve (not shown) is provided in the bypass pipe 28.

作為加熱泵20的運轉方法,例如,調整加熱泵壓縮機的輸入電力及循環水流量,來使第1媒介水及第2媒介水的出口溫度各自成為一定溫度。亦可使加熱泵成為複數系列,來因應熱負載進行台數控制。且,如圖示般,亦可於高溫側及(或)低溫側的循環系統設置有對熱交換器旁通的配管與流量控制閥,來進行能夠控制加熱泵入口溫度的運轉。 As a method of operating the heat pump 20, for example, the input power of the heat pump compressor and the circulating water flow rate are adjusted so that the outlet temperatures of the first medium water and the second medium water become constant temperatures, respectively. It is also possible to make the heat pump a plural series to control the number of units in accordance with the heat load. In addition, as shown in the figure, the high temperature side and / or low temperature side circulation system may be provided with a pipe bypassing the heat exchanger and a flow control valve to perform an operation capable of controlling the temperature of the inlet of the heat pump.

圖2係表示關於第2實施形態的超純水製造裝置。該超純水製造裝置,係在圖1的超純水製造裝置中,在連結熱交換器6、10之超純水配管9的途中設置熱交換器31,來使超純水流入熱交換器31的被加熱流路,並將約56℃的溫排水透過配管32導入至熱交換器31的熱源流體流路。 Fig. 2 shows an ultrapure water producing apparatus according to a second embodiment. This ultrapure water production device is an ultrapure water production device shown in FIG. 1. A heat exchanger 31 is provided in the middle of connecting ultrapure water pipes 9 of heat exchangers 6 and 10 to flow ultrapure water into the heat exchanger. 31 is heated, and hot water at about 56 ° C. is introduced into the heat source fluid flow path of the heat exchanger 31 through the pipe 32.

約56℃的溫排水,係在熱交換器31對配管9的超純水加熱而降溫至約47℃之後,藉由配管29供給至熱交換器26。 The warm water at about 56 ° C is supplied to the heat exchanger 26 through a pipe 29 after the ultra-pure water in the pipe 9 is heated to a temperature of about 47 ° C by the heat exchanger 31.

圖2的其他構造係與圖1相同。 The other structures of FIG. 2 are the same as those of FIG. 1.

根據圖2的超純水製造裝置,可比圖1的情況還要減少蒸氣使用量。但是,因溫排水的水質,會考慮到 追加之熱交換器31的傳熱面受污染,使傳熱性能降低的情況。溫超純水的製造製程中,為了維持溫超純水的品質而無法進行熱交換器31的分解洗淨,故圖2的流程,可適用於溫排水沒有污染(或是熱交換器的洗淨、污染去除為容易)的情況。作為熱交換器31,為了完全防止雜質的洩漏或溶解,以使用全焊接或單側焊接式的鈦製板熱型交換器為佳。 According to the ultrapure water production apparatus of FIG. 2, the amount of steam used can be reduced compared to the case of FIG. 1. However, due to the quality of the hot-drain water, the heat transfer surface of the additional heat exchanger 31 may be contaminated and the heat transfer performance may be reduced. In the manufacturing process of warm ultrapure water, in order to maintain the quality of warm ultrapure water, the decomposition and cleaning of the heat exchanger 31 cannot be performed. Therefore, the flow of FIG. 2 can be applied to the warm drainage without pollution (or the cleaning and pollution removal of the heat exchanger). For easy). As the heat exchanger 31, in order to completely prevent leakage or dissolution of impurities, it is preferable to use a full-welded or one-side welded titanium plate heat exchanger.

圖3係在圖2中,構成為可切換至將溫排水直接流通至熱交換器26的選擇流路、以及將溫排水透過熱交換器31流通至熱交換器26的選擇流路。 FIG. 3 is a configuration shown in FIG. 2, which can be switched to a selective flow path for directly passing warm water to the heat exchanger 26 and a selective flow path for passing warm water through the heat exchanger 31 to the heat exchanger 26.

亦即,溫排水用配管33,係透過閥34、配管35而連接於配管29。且,配管33,係透過從該配管33分歧的配管36、閥37及配管38而連接至熱交換器31。藉由打開閥34並關閉閥37,使來自配管33的溫排水直接流通至熱交換器26。 That is, the warm water drainage pipe 33 is connected to the pipe 29 through the valve 34 and the pipe 35. The piping 33 is connected to the heat exchanger 31 through a piping 36, a valve 37, and a piping 38 that branch from the piping 33. When the valve 34 is opened and the valve 37 is closed, the warm drain water from the pipe 33 is directly passed to the heat exchanger 26.

藉由關閉閥34並打開閥37,使來自配管33的溫排水,在流通至熱交換器31之後,流通至熱交換器26。 By closing the valve 34 and opening the valve 37, the warm water from the pipe 33 is allowed to flow to the heat exchanger 31 and then to the heat exchanger 26.

又,於配管33設置TOC計或電阻率計等之水質感測器39,並將該檢測值輸入至閥控制裝置(圖示省略),而將閥34、37控制成在溫排水的水質為良好(例如TOC比既定濃度還低)時,依序使溫排水流通至熱交換器31、26;在水質不良好(例如TOC濃度比既定值還高)時,直接使溫排水流通至熱交換器26為佳。 In addition, a water quality sensor 39 such as a TOC meter or a resistivity meter is installed in the piping 33, and the detection value is input to a valve control device (not shown), and the valves 34 and 37 are controlled so that the water quality of the water discharged at a temperature is When it is good (for example, the TOC is lower than the predetermined concentration), the warm water is allowed to flow to the heat exchangers 31 and 26 in sequence; when the water quality is not good (for example, when the TOC concentration is higher than the predetermined value), the warm water is directly passed to the heat exchange. The device 26 is preferable.

且,將洗淨水用配管40透過閥41來連接於配 管33,而因應必要以藥品或水來洗淨熱交換器31、26或配管亦可。 In addition, the piping 40 for washing water is connected to the piping 33 through the valve 41, and the heat exchangers 31 and 26 or piping may be washed with chemicals or water as necessary.

圖3的其他構造係與圖2相同。 The other structures of FIG. 3 are the same as those of FIG. 2.

根據圖3的超純水製造裝置,可謀求超純水之有效率地加熱、以及熱交換器的污染防止(抑制)。 According to the ultrapure water production apparatus of FIG. 3, efficient heating of ultrapure water and prevention (suppression) of contamination of a heat exchanger can be achieved.

圖4,係為了使第3媒介水循環流通至熱交換器26的熱源流體流路,而設置由熱交換器44、配管45、熱交換器31、配管29、熱交換器26、配管46所成的循環流路,透過配管47使約56℃的溫排水流通至熱交換器44的熱源流體流路,並將該約25℃的流出水藉由配管48而作為回收水來回收。 FIG. 4 is formed by a heat exchanger 44, a pipe 45, a heat exchanger 31, a pipe 29, a heat exchanger 26, and a pipe 46 in order to circulate the third medium water to the heat source fluid flow path of the heat exchanger 26. In the circulating flow path, warm water at about 56 ° C. is passed through the pipe 47 to the heat source fluid flow path of the heat exchanger 44, and the outflow water at about 25 ° C. is recovered as recycled water through the pipe 48.

藉由流動於熱交換器44的被加熱流體流路而被加熱至約51℃的第3媒介水,係透過配管45而流通至熱交換器31的熱源流體流路,來加熱流動於配管9的超純水。通過熱交換器31而降溫至約47℃的溫排水,係透過配管29而流通至熱交換器26的熱源流體流路,且降溫至約20℃,接著透過配管46回到熱交換器44的被加熱流體流路。在熱交換器26將約15℃的第2媒介水加熱至約25℃。 The third medium water heated to about 51 ° C. by the heated fluid flow path flowing through the heat exchanger 44 is a heat source fluid flow path flowing through the pipe 45 to the heat exchanger 31 to heat the flow through the pipe 9 Ultra pure water. The warm water that has been cooled to about 47 ° C by the heat exchanger 31 is a heat source fluid flow path that passes through the pipe 29 to the heat exchanger 26, and is cooled to about 20 ° C, and then returns to the heat exchanger 44 through the pipe 46. Heated fluid flow path. In the heat exchanger 26, the second medium water of about 15 ° C is heated to about 25 ° C.

該圖4的超純水製造裝置,其超純水的加熱效率良好,且於超純水用配管9的熱交換器31流通有清淨的第3媒介水,故能夠抑制在該熱交換器31附著污染的風險。 The ultrapure water producing apparatus of FIG. 4 has good heating efficiency for the ultrapure water, and clean third medium water flows through the heat exchanger 31 of the ultrapure water pipe 9. Therefore, it can be suppressed in the heat exchanger 31. Risk of contamination.

圖5係表示:在圖1中,構成為藉由複數台的加熱泵來加熱第1媒介水,並使設置在即將到達使用點之 前的UF膜分離裝置11A的濃縮水亦作為溫排水來利用之構造的實施形態。 FIG. 5 shows that in FIG. 1, the first medium water is heated by a plurality of heat pumps, and the concentrated water of the UF membrane separation device 11A installed immediately before the point of use is also used as warm water. The structure of the implementation.

該實施形態中,從熱交換器10的熱源流體流路出口所流出之約51℃的第1媒介水,係透過配管12而導入中繼槽12a。於中繼槽12a,亦導入有來自UF膜分離裝置11A的濃縮水。該濃縮水,其清淨度較高。中繼槽12a內的第1媒介水,係透過配管12b流通至第1加熱泵20A的凝縮器23而被加熱至約60℃之後,透過配管12c流通至第2加熱泵20B的凝縮器23而被加熱至約67℃,接著,透過配管14流通至蒸氣式熱交換器15而被加熱至約75~76℃之後,透過配管16循環至熱交換器10的熱源流體流路入口。 In this embodiment, the first medium water of about 51 ° C. flowing out of the heat source fluid flow path outlet of the heat exchanger 10 is introduced into the relay tank 12 a through the pipe 12. Concentrated water from the UF membrane separation device 11A is also introduced into the relay tank 12a. The concentrated water has high cleanliness. The first medium water in the relay tank 12a flows through the pipe 12b to the condenser 23 of the first heat pump 20A and is heated to about 60 ° C, and then flows through the pipe 12c to the condenser 23 of the second heat pump 20B. After being heated to about 67 ° C., it flows through the pipe 14 to the steam heat exchanger 15 and is heated to about 75 to 76 ° C., and then circulates through the pipe 16 to the heat source fluid flow path inlet of the heat exchanger 10.

加熱泵20A、20B的構造,係與加熱泵20相同。於各加熱泵20A、20B的蒸發器21,流通有在熱交換器26被加熱過的第2媒介水。通過熱交換器26的被加熱流體流路藉此被加熱至約40℃的第2媒介水,係藉由配管27及從此分歧的配管27a、27b來流通至各凝縮器21,而與加熱泵20A、20B的熱媒介進行熱交換來降溫。從各凝縮器21所流出之約30℃的第2媒介水,係透過配管25a、25b而導入合流槽25c。合流槽25c內的第2媒介水,係透過泵25d及配管25e而回到熱交換器26的被加熱流體流路。 The structures of the heat pumps 20A and 20B are the same as those of the heat pump 20. A second medium water heated in the heat exchanger 26 flows through the evaporator 21 of each of the heat pumps 20A and 20B. The heated medium flow path passing through the heat exchanger 26 is thereby heated to about 40 ° C. and the second medium water is circulated to the condensers 21 through the piping 27 and the piping 27 a and 27 b branching therefrom, and is connected to the heat pump. 20A, 20B heat exchange medium to cool down. The second medium water at about 30 ° C. flowing from each condenser 21 is introduced into the confluence tank 25 c through the pipes 25 a and 25 b. The second medium water in the combining tank 25c returns to the heated fluid flow path of the heat exchanger 26 through the pump 25d and the piping 25e.

來自溫排水槽95之約56℃的溫排水係透過配管29而導入至熱交換器26的熱源流體流路。在熱交換器26進行熱交換而降溫至約32℃的排水,係透過配管30而作為回收水被回收。 The warm water drainage of about 56 ° C. from the warm water drainage tank 95 is introduced into the heat source fluid flow path of the heat exchanger 26 through the pipe 29. The waste water which has been heat-exchanged in the heat exchanger 26 and cooled to about 32 ° C. is recovered as recovered water through the pipe 30.

從使用點90所排出的溫排水係被導入至溫排水槽95。且,該實施形態中,來自前述中繼槽12a的溢流水亦被導入至溫排水槽95。 The warm water drainage system discharged from the use point 90 is introduced into the warm water drainage tank 95. Further, in this embodiment, overflow water from the relay tank 12 a is also introduced into the warm water drainage tank 95.

圖5的其他構造係與圖1相同,相同的符號表示相同的部分。 Other structures in FIG. 5 are the same as those in FIG. 1, and the same reference numerals denote the same parts.

又,圖1~6的各超純水製造裝置中,係以一次純水溫度25℃、來自副系統4的超純水溫度30℃、溫超純水溫度60℃、溫排水溫度56℃、回收水溫度25℃、來自蒸氣式熱交換器15的第1媒介水溫度85℃之溫度條件,並以各種流量條件進行模擬。其結果,以圖6之超純水製造裝置的熱源成本為100的情況,圖1之超純水製造裝置的熱源成本為75%、圖2之超純水製造裝置的熱源成本為63%、圖4的熱源成本為65%。 In each of the ultrapure water production apparatuses of FIGS. 1 to 6, the primary pure water temperature is 25 ° C, the ultrapure water temperature from the sub-system 4 is 30 ° C, the temperature of the ultrapure water is 60 ° C, and the temperature of the drainage water is 56 ° C. The temperature conditions of the temperature of 25 ° C. and the temperature of the first medium water from the steam-type heat exchanger 15 were 85 ° C., and simulation was performed under various flow conditions. As a result, when the heat source cost of the ultrapure water production apparatus of FIG. 6 is 100, the heat source cost of the ultrapure water production apparatus of FIG. 1 is 75%, the heat source cost of the ultrapure water production apparatus of FIG. 2 is 63%, The heat source cost in Figure 4 is 65%.

上述實施形態為本發明的一例,本發明亦可為圖示以外的形態。例如,亦可在配管11設有蒸氣式熱交換器,來對在熱交換器10被加熱過的超純水進行加熱。 The embodiment described above is an example of the present invention, and the present invention may be in a form other than the one shown in the drawings. For example, a steam-type heat exchanger may be provided in the pipe 11 to heat the ultrapure water heated in the heat exchanger 10.

雖使用了特定的態樣來詳細說明了本發明,但本業業者明顯可在不超脫本發明之主旨的範圍內進行各種變更。 Although the present invention has been described in detail using specific aspects, it is apparent that various changes can be made by those skilled in the art without departing from the spirit of the present invention.

本申請案,係根據2016年9月14日所申請的日本專利申請案2016-179640,使其全體藉由引用來援用於此。 This application is based on Japanese Patent Application No. 2016-179640 filed on September 14, 2016, and is hereby incorporated by reference in its entirety.

Claims (8)

一種超純水製造裝置,係將被加熱過的超純水供給至使用點,其具有:一次純水製造裝置、將來自該一次純水製造裝置的一次純水予以處理而製造超純水的二次純水製造裝置、用來將來自該二次純水製造裝置的超純水予以加熱並以來自使用點的回流水作為熱源的第1熱交換器、以及對在該第1熱交換器被加熱過的超純水進一步進行加熱的加熱手段,其特徵為,前述加熱手段,係具備:使在前述第1熱交換器被加熱過的超純水流通至被加熱流體流路的第2熱交換器、使作為傳熱媒介的第1媒介水在該第2熱交換器的熱源流體流路循環流通的第1循環流路、將流動於該第1循環流路的第1媒介水藉由溫排水的熱來加熱的第1媒介水加熱裝置、以及將以該第1媒介水加熱裝置所加熱過的第1媒介水藉由蒸氣來加熱的第3熱交換器。     An ultrapure water production device is a device that supplies heated ultrapure water to a point of use. The device includes: a primary pure water production device; A secondary pure water production device, a first heat exchanger for heating ultrapure water from the secondary pure water production device, and using return water from a point of use as a heat source, and a first heat exchanger The heating means for further heating the heated ultrapure water is characterized in that the heating means is provided with a flow of the ultrapure water heated in the first heat exchanger to a second flow path of the heated fluid. A heat exchanger, a first circulation flow path that circulates first medium water as a heat transfer medium in a heat source fluid flow path of the second heat exchanger, and borrows first medium water that flows through the first circulation flow path. A first medium water heating device that is heated by the heat of warm water drainage, and a third heat exchanger that heats the first medium water heated by the first medium water heating device with steam.     如請求項1所述之超純水製造裝置,其中,前述第1媒介水加熱裝置,係具備加熱泵,其具有凝縮器、蒸發器、泵及膨脹閥,該凝縮器,係設置在前述第1循環流路來加熱該第1媒 介水,該蒸發器,係設置在循環有第2媒介水的第2循環流路,於該第2循環流路,設有第2媒介水加熱裝置,其用來以前述溫排水的熱來加熱第2媒介水。     The ultrapure water production device according to claim 1, wherein the first medium water heating device is provided with a heat pump having a condenser, an evaporator, a pump, and an expansion valve, and the condenser is provided in the first section. 1 circulation flow path is used to heat the first medium water, and the evaporator is provided in the second circulation flow path in which the second medium water is circulated, and in the second circulation flow path, a second medium water heating device is provided. The second medium water is heated by the heat of the warm water drainage.     如請求項2所述之超純水製造裝置,其中,前述第2媒介水加熱裝置,係使前述溫排水流通至熱源流體流路的第5熱交換器。     The ultrapure water production device according to claim 2, wherein the second medium water heating device is a fifth heat exchanger that circulates the warm water to the heat source fluid flow path.     如請求項3所述之超純水製造裝置,其中,在前述第1熱交換器與第2熱交換器之間,設置有用來加熱前述超純水的第6熱交換器,且設有溫排水流路,其用來將前述溫排水流通至第6熱交換器的熱源流體流路之後流通至第5熱交換器的熱源流體流路。     The ultrapure water production device according to claim 3, wherein a sixth heat exchanger for heating the ultrapure water is provided between the first heat exchanger and the second heat exchanger, and a temperature The drainage flow path is used to circulate the warm water to the heat source fluid flow path of the sixth heat exchanger and then to the heat source fluid flow path of the fifth heat exchanger.     如請求項4所述之超純水製造裝置,其中,設有流路切換裝置,係用來切換:使前述溫排水經由前述第6熱交換器而流通至第5熱交換器的第1選擇流路、以及使溫排水繞過前述第6熱交換器而流通至第5熱交換器的第2選擇流路。     The ultrapure water production device according to claim 4, further comprising a flow path switching device for switching: a first option for passing the warm water and drainage to the fifth heat exchanger through the sixth heat exchanger. A flow path and a second selected flow path that allows warm water to flow around the sixth heat exchanger and flow to the fifth heat exchanger.     如請求項5所述之超純水製造裝置,其中,設有測量 前述溫排水之水質的水質感測器,且具備控制裝置,其在該水質感測器的檢測水質比既定值還良好的情況,設成前述第1選擇流路,在檢測水質比該既定值還不良的情況,設成前述第2選擇流路。     The ultrapure water manufacturing device according to claim 5, further comprising a water quality sensor for measuring the temperature of the warm water drainage, and a control device for detecting that the water quality of the water quality sensor is better than a predetermined value. In this case, the first selected flow path is set, and when the detected water quality is worse than the predetermined value, the second selected flow path is set.     如請求項2所述之超純水製造裝置,其中,前述第2媒介水加熱裝置,係使第3媒介水流通至熱源流體流路的第5熱交換器,於該第5熱交換器的熱源流體流路設有使第3媒介水循環流通用的第3循環流路,於該第3循環流路,設置有藉由前述溫排水來加熱第3媒介水的第7熱交換器。     The ultrapure water production device according to claim 2, wherein the second medium water heating device is a fifth heat exchanger that circulates the third medium water to the heat source fluid flow path, and The heat source fluid flow path is provided with a third circulation flow path in which the third medium water circulation flow is common. The third circulation flow path is provided with a seventh heat exchanger for heating the third medium water by the above-mentioned warm drainage.     如請求項7所述之超純水製造裝置,其中,在前述第1熱交換器與第2熱交換器之間,設置有用來加熱前述超純水的第6熱交換器,前述第3循環流路,係設置成使在前述第7熱交換器加熱過的第3媒介水經由該第6熱交換器的熱源流體流路而流通至第5熱交換器的熱源流體流路。     The ultrapure water production device according to claim 7, wherein a sixth heat exchanger for heating the ultrapure water is provided between the first heat exchanger and the second heat exchanger, and the third cycle The flow path is a heat source fluid flow path provided so that the third medium water heated in the seventh heat exchanger flows through the heat source fluid flow path of the sixth heat exchanger to the fifth heat exchanger.    
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