TW201806917A - Composition and novel compound - Google Patents

Abstract

A composition containing a compound having a substituent indicated by general formula (1). (In the formula, R1 and R2 each independently indicate a hydrogen atom, a halogen atom, a cyano group, a hydroxyl group, a nitro group, a carboxyl group, a C1-40 alkyl group that may have a substituent group, a C6-20 aryl group, a C7-20 arylalkyl group, a C2-20 heterocyclic ring-containing group, or a trialkylsilyl group. j indicates 1-3 and * indicates bonding with an adjacent group, at the * section).

Description

Compositions and novel compounds

The present invention relates to a composition containing a compound having a specific structure, which is inert at normal temperature and is activated by heating to a specific temperature to exhibit a function, and a novel compound. Furthermore, this invention relates to the coloring photosensitive composition which added the coloring agent to this composition, and the color filter which used the said coloring photosensitive composition.

In order to improve the weather resistance or heat resistance of a photosensitive composition, a method of adding an ultraviolet absorber or an antioxidant to stabilize the photosensitive composition is known (Patent Documents 1 to 4). Phenol-based antioxidants and UV absorbers have the function of capturing free radicals that have a large effect on the deterioration of polymers. Therefore, if these are added to the polymerization system, they generally function as so-called polymerization inhibitors, causing hardening inhibition Since the situation becomes a problem, the industry has developed a latent additive (Patent Document 5). However, since the composition using the conventional latent additive has a large amount of outgassing, there is a problem that the heating device is polluted or the physical properties of the composition are reduced. There is a problem that the device is contaminated or the physical properties are reduced. In addition, since the composition using the conventional latent additive has low solvent resistance of the cured product, there is also a problem that the cured product is dissolved out, for example, the brightness of the color filter is reduced. Prior Art Literature Patent Literature Patent Literature 1: Japanese Patent Laid-Open No. 2011-048382 Patent Literature 2: Japanese Patent Laid-Open No. 2014-194508 Patent Literature 3: Japanese Patent Laid-Open No. 2015-108649 Patent Literature 4: Japanese Patent Japanese Patent Application Laid-Open No. 2015-132791 Patent Document 5: International Publication No. 2014/021023

Therefore, an object of the present invention is to provide a compound which is inert at normal temperature and is activated by heating to a specific temperature to exhibit a function as an antioxidant or an ultraviolet absorber with less outgassing and a solvent-resistant hardened substance A composition having a high property, especially a photosensitive composition. It is another object of the present invention to provide a coloring composition to which a colorant is added to the above composition, and particularly a coloring photosensitive composition suitable for a color filter. The present inventors worked hard to find out that the composition using a compound having a specific protective group has less outgassing, and the hardened product has higher solvent resistance. Furthermore, it was found that coloring was added to the composition The coloring composition of the agent, especially the coloring photosensitive composition, does not reduce the brightness of the optical filter (especially the color filter), and is suitable for a color filter for an image display device such as a liquid crystal display panel, thereby achieving the invention. . This invention is completed based on the said knowledge, and provides the composition containing the compound which has a substituent represented by the following general formula (I). [Chemical 1] (In the formula, R ¹ and R ² each independently represent a hydrogen atom, a halogen atom, a cyano group, a hydroxy group, a nitro group, a carboxyl group, an alkyl group having 1 to 40 carbon atoms when having a substituent, and a substituent having a substituent. In the case of an aryl group having 6 to 20 carbon atoms, in the case of having an aryl alkyl group having 7 to 20 carbon atoms in the case of having a substituent, in a case of having a heterocyclic ring containing 2 to 20 carbon atoms in the case of having a substituent Group or trialkylsilyl group, the methylene group in the alkyl group or arylalkyl group represented by R ¹ and R ² is substituted with -O-, -S if the oxygen atoms are not adjacent -, -CO-, -O-CO-, -CO-O-, -O-CO-O-, -S-CO-, -CO-S-, -S-CO-O-, -O-CO In the case of a base formed by combining bases in -S-, -CO-NH-, -NH-CO-, -NH-CO-O-, -NR'-, -SS-, or -SO _2- , R ' Represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, j represents a number of 1 to 3, and ﹡ means that the ﹡ portion is bonded to an adjacent group)

Hereinafter, the present invention will be described in detail based on preferred embodiments. The composition of the present invention contains a compound having a substituent represented by the general formula (I). Among the compounds having a substituent represented by the general formula (I), those represented by the following general formula (IA) are particularly preferable because they have high heat resistance and low outgassing. [Chemical 2] (Where n is an integer from 1 to 10, X ¹ Represents an n-valent bond, R ¹ , R ² And j is the same as the general formula (I)) as R ¹ And R ² Examples of the halogen atom include fluorine, chlorine, bromine, and iodine. ¹ And R ² Examples of the alkyl group having 1 to 40 carbon atoms include methyl, ethyl, propyl, isopropyl, butyl, second butyl, third butyl, isobutyl, pentyl, and iso. Pentyl, third pentyl, cyclopentyl, hexyl, 2-hexyl, 3-hexyl, cyclohexyl, 4-methylcyclohexyl, heptyl, 2-heptyl, 3-heptyl, isoheptyl, Triheptyl, 1-octyl, isooctyl, third octyl, adamantyl, etc., as R ¹ And R ² Examples of the aryl group having 6 to 20 carbon atoms include phenyl, naphthyl, anthracenyl, phenanthryl, fluorenyl, indenyl, 2-methylphenyl, 3-methylphenyl, 4- Methylphenyl, 4-vinylphenyl, 3-isopropylphenyl, 4-isopropylphenyl, 4-butylphenyl, 4-isobutylphenyl, 4-tert-butylbenzene Base, 4-hexylphenyl, 4-cyclohexylphenyl, 4-octylphenyl, 4- (2-ethylhexyl) phenyl, 4-stearylphenyl, 2,3-dimethylbenzene Group, 2,4-dimethylphenyl, 2,5-dimethylphenyl, 2,6-dimethylphenyl, 3,4-dimethylphenyl, 3,5-dimethylbenzene Base, 2,4-di-third-butylphenyl, 2,5-di-third-butylphenyl, 2,6-di-third-butylphenyl, 2,4-di-third-pentylphenyl, 2,5-di-third pentylphenyl, 2,5-di-third octylphenyl, 2,4-diisopropylphenylphenyl, 4-cyclohexylphenyl, (1,1'-bi Phenyl) -4-yl, 2,4,5-trimethylphenyl, ferrocenyl, etc., as R ¹ And R ² Examples of the arylalkyl group having 7 to 20 carbon atoms include benzyl, 1-methyl-1-phenylethyl, 1-naphthylmethyl, 9-anthrylmethyl, and 9-fluorene. Group, 3-phenylpropyl, methyl-2-phenylpropane-2-yl, diphenylmethyl, triphenylmethyl, phenethyl, styryl, lauryl, etc., as R ¹ And R ² Examples of the heterocyclic group containing 2 to 20 carbon atoms include a pyridine ring, a pyrimidine ring, a da 𠯤 ring, a piperidine ring, a pyran ring, a pyrazoline ring, and a tri 𠯤 Ring, pyrroline ring, quinoline ring, isoquinoline ring, imidazoline ring, benzimidazoline ring, triazoline ring, furan ring, benzofuran ring, thiadiazoline ring, thiazoline ring, benzene Hexathiazoline ring, thiophene ring, oxazoline ring, benzoxazoline ring, isothiazoline ring, isoxazoline ring, indole ring, pyrrolidine ring, piperidone ring, dioxane ring, etc. A group consisting of a ring and a methylene chain, as R ¹ And R ² Examples of the trialkylsilyl group include trimethylsilane, triethylsilane, and ethyldimethylsilane, which are substituted with an alkyl group having 1 to 6 carbon atoms (three alkyl groups are the same or different). Silyl. Examples of the alkyl group having 1 to 8 carbon atoms represented by R ′ include R ¹ The above-mentioned alkyl group satisfies a specific number of carbon atoms. As a replacement for R ¹ And R ² Substituents of alkyl groups having 1 to 40 carbon atoms, aryl groups having 6 to 20 carbon atoms, arylalkyl groups having 7 to 20 carbon atoms or heterocyclic group containing 2 to 20 carbon atoms Examples include: ethylenically unsaturated groups such as vinyl, allyl, acrylic, and methacrylic groups; halogen atoms such as fluorine, chlorine, bromine, and iodine; ethenyl, 2-chloroethenyl, and propionyl , Octyl fluorenyl, acryl fluorenyl, methacryl fluorenyl, phenylcarbonyl (benzyl fluorenyl), phthalofluorenyl, 4-trifluoromethyl benzamyl, pentamyl, o-hydroxybenzyl, Acetyl, stearyl, methoxycarbonyl, ethoxycarbonyl, tert-butoxycarbonyl, n-octadecyloxycarbonyl, carbamoyl, and other fluorenyl groups; ethanyloxy, benzamidine Alkoxy, such as oxy; amine, ethylamino, dimethylamino, diethylamino, butylamino, cyclopentylamino, 2-ethylhexylamino, dodecyl Amine, aniline, chlorophenylamino, toluidine, methoxyaniline, N-methyl-aniline, diphenylamino, naphthylamino, 2-pyridylamine, methoxy Carbonylamino, phenoxycarbonylamino, acetamidine Methylamino, benzamidineamino, methylamidinoamino, pentamylamino, laurylamino, aminomethylamino, N, N-dimethylaminocarbonylamino, N, N-diethylaminocarbonylamino, morpholinylcarbonylamino, methoxycarbonylamino, ethoxycarbonylamino, tert-butoxycarbonylamino, n-octadecyloxycarbonyl Amine, N-methyl-methoxycarbonylamino, phenoxycarbonylamino, sulfamoylamino, N, N-dimethylaminosulfoamidoamine, methylsulfoamidoamine Substituted amine groups such as sulfonylamino, butylsulfonylamino, and phenylsulfonylamino; sulfonylamino, sulfonamido, carboxyl, cyano, sulfo, hydroxyl, nitro, mercapto, and iminoimino , Carbamoyl, sulfonamido, phosphonic acid, phosphate or carboxyl, sulfo, phosphonic acid, phosphate salts, etc. As R ¹ And R ² A hydrogen atom, an alkyl group having 1 to 8 carbon atoms, and an aryl group having 6 to 12 carbon atoms are preferred because they have less outgassing. R ¹ Is a branched alkyl group having 1 to 8 carbon atoms, especially a third butyl group, R ² When it is a hydrogen atom, outgassing is particularly small, so it is more preferable. In the general formula (IA), X ¹ An n-valent bonding group, specifically, a direct bond, a hydrogen atom, a nitrogen atom, an oxygen atom, a sulfur atom, a phosphorus atom, a group represented by the following (Ia) or (Ib), -CO-, -NH-CO-, -CO-NH-, -NR ^3- , -OR ³ , -SR ³ , -NR ³ R ⁴ Or an aliphatic hydrocarbon group having 1 to 120 carbon atoms when having a substituent having the same valence as n, an aromatic ring-containing hydrocarbon group having 6 to 35 carbon atoms having a substituent, or having In the case of a substituent, a heterocyclic group containing 2 to 35 carbon atoms, R ³ And R ⁴ A hydrogen atom, an aliphatic hydrocarbon group having 1 to 35 carbon atoms when having a substituent, an aromatic ring-containing hydrocarbon group having 6 to 35 carbon atoms when having a substituent, or a carbon atom having a substituent Heterocyclic groups containing 2 to 35, aliphatic hydrocarbon groups, aromatic ring-containing hydrocarbon groups, and heterocyclic-containing groups are substituted with -O-, -S-, -CO-, -O-CO-,- CO-O-, -O-CO-O-, -S-CO-, -CO-S-, -S-CO-O-, -O-CO-S-, -CO-NH-, -NH- CO-, -NH-CO-O-, -O-CO-NH-, -NR'-, -SS-, -SO ₂ -Or the case of a radical in a nitrogen atom. Where X ¹ When it is a nitrogen atom, a phosphorus atom, or a bonding group represented by the following (Ia) or (Ib), n is 3, and X is ¹ Is an oxygen atom or a sulfur atom, -CO-, -NH-CO-, -CO-NH-, or -NR ^3- In the case, n is 2 at X ¹ Hydrogen atom, -OR ³ , -SR ³ Or -NR ³ R ⁴ In this case, n is 1, X ¹ There may be a case where the benzene ring is integrated with the benzene ring. [Chemical 3] (﹡ Means bonding to the adjacent group in the ﹡ moiety) The compound represented by the above general formula (IA) has X ¹ The indicated n-valent bonding group has a structure in which n specific groups are bonded. The n groups are the same or different from each other. The value of n is 1 to 10, and in terms of ease of synthesis, 2 to 6 is preferred. In the general formula (IA), as X ¹ The aliphatic hydrocarbon group having 1 to 120 carbon atoms in the case of having a substituent having the same valence as n indicates that n is monovalent, and examples include methyl, ethyl, propyl, iso Propyl, cyclopropyl, butyl, second butyl, third butyl, isobutyl, pentyl, isopentyl, third pentyl, cyclopentyl, hexyl, 2-hexyl, 3-hexyl, Cyclohexyl, dicyclohexyl, 1-methylcyclohexyl, heptyl, 2-heptyl, 3-heptyl, isoheptyl, third heptyl, n-octyl, isooctyl, third octyl, 2- Alkyl groups such as ethylhexyl, nonyl, isononyl, decyl; methoxy, ethoxy, propoxy, isopropoxy, butoxy, second butoxy, third butoxy, Isobutoxy, pentyloxy, isopentyloxy, third pentyloxy, hexyloxy, cyclohexyloxy, heptyloxy, isoheptyloxy, third heptyloxy, n-octyloxy, iso Alkoxy groups such as octyloxy, third octyloxy, 2-ethylhexyloxy, nonyloxy, decyloxy; methylthio, ethylthio, propylthio, isopropylthio, butylthio , Second butylthio, third butylthio, isobutylthio, pentylthio, isopentyl Base, third pentylthio, hexylthio, cyclohexylthio, heptylthio, isoheptylthio, third heptylthio, n-octylthio, isooctylthio, third octylthio, 2- Alkylthio groups such as ethylhexylthio; vinyl, 1-methylvinyl, 2-methylvinyl, 2-propenyl, 1-methyl-3-propenyl, 3-butenyl, 1- Methyl-3-butenyl, isobutenyl, 3-pentenyl, 4-hexenyl, cyclohexenyl, dicyclohexenyl, heptenyl, octenyl, decenyl, pentaenyl Alkenyl, eicosenyl, docosenyl, etc .; and these groups are substituted with substituents described later; etc. As n is divalent, examples include methylene, ethylene, and propyl , Alkylene such as butylene, butyldiyl; the methylene chain of the above alkylene is replaced by -O-, -S-, -CO-O-, -O-CO-; ethylene glycol Residues of diols such as propylene glycol, butanediol, pentanediol, and hexanediol; of dithiols such as ethylenedithiol, propylenedithiol, butanedithiol, pentanethiol, and hexanedithiol Residues; and those substituted with substituents described later; etc. As n is trivalent, for example, propylidene, 1,1,3-butylene Other times alkyl; and after said group of such group substituted with a substituent of. As the aromatic ring-containing hydrocarbon group having 6 to 35 carbon atoms in the case of having a substituent having the same valence as that of n, examples of n having one valency include benzyl, phenethyl, and diphenylmethyl. , Arylalkyl such as triphenylmethyl, styryl, lauryl; aryl groups such as phenyl and naphthyl; aryloxy groups such as phenoxy and naphthyloxy; phenylthio and naphthylthio Arylthio groups; and those groups substituted with substituents to be described later; Examples of those in which n is divalent include: aryl groups such as phenylene and naphthyl; bisphenols such as catechol and bisphenol Residues of functional phenol; 2,4,8,10-tetraoxaspiro [5,5] undecane, etc .; and these groups are substituted by the substituents described later; As n is trivalent, enumerated : Phenyl-1,3,5-trimethylene and the like, and those groups substituted with a substituent described later. As a heterocyclic group having 2 to 35 carbon atoms in the case of having a substituent having the same valence as n, as n is a monovalent, there may be listed: pyridyl, pyrimidinyl, da 𠯤 Methyl, piperidinyl, pyranyl, pyrazolyl, trisyl, pyrrolyl, quinolinyl, isoquinolinyl, imidazolyl, benzimidazolyl, triazolyl, furyl , Furanyl, benzofuranyl, thienyl, phenylthio, benzophenylthio, thiadiazolyl, thiazolyl, benzothiazolyl, oxazolyl, benzoxazolyl, isothiazolyl Base, isoxazolyl, indolyl, 2-pyrrolidone-1-yl, 2-piperidone-1-yl, 2,4-dioxyimidazol-3-yl, 2,4-bis Oxyoxazolyl-3-yl, benzotriazolyl, etc .; and those groups substituted with a substituent described later; etc. As n is divalent, examples include pyridine ring, pyrimidine ring, piperidine Ring, pipe 𠯤 ring, tri 𠯤 ring, furan ring, thiophene ring, indole ring, etc .; and these groups are substituted with substituents described later; List: a group with isocyanuric acid ring, and three 𠯤 A cyclic group; and a group in which these groups are substituted with a substituent described later. As R ³ And R ⁴ Examples of the aliphatic hydrocarbon group having 1 to 35 carbon atoms in the case of having a substituent include the above-mentioned X ¹ As the represented aliphatic hydrocarbon group and a combination of the aliphatic hydrocarbon group and a substituent described later, a specific number of carbon atoms is satisfied as R ³ And R ⁴ Examples of the aromatic ring-containing hydrocarbon group having 6 to 35 carbon atoms in the case of having a substituent and the heterocyclic group containing 2 to 35 carbon atoms in the case of having a substituent include the above-mentioned X ¹ The aromatic ring-containing hydrocarbon group having 6 to 35 carbon atoms, the heterocyclic group containing 2 to 35 carbon atoms, and a group obtained by combining these groups with a substituent described later satisfy a specific number of carbon atoms. . Examples of the substituent include ethylenically unsaturated groups such as a vinyl group, an allyl group, an acrylic group, and a methacrylic group; halogen atoms such as fluorine, chlorine, bromine, and iodine; ethenyl, 2-chloroethenyl, Propionyl, octyl, propenyl, methacryl, phenylcarbonyl (benzyl), phthaloyl, 4-trifluoromethylbenzyl, pentamyl, o-hydroxybenzyl Fluorenyl, fluorenyl, stearyl fluorenyl, methoxycarbonyl, ethoxycarbonyl, tert-butoxycarbonyl, n-octadecyloxycarbonyl, and carbamoyl; ethenyl, Benzyloxy and other ethoxy; amine, ethylamino, dimethylamino, diethylamino, butylamino, cyclopentylamino, 2-ethylhexylamino, ten Dialkylamino, aniline, chlorophenylamino, toluidine, methoxyaniline, N-methyl-aniline, diphenylamino, naphthylamino, 2-pyridylamine, Methoxycarbonylamino, phenoxycarbonylamino, ethenylamino, benzamidineamino, formamidineamino, pentamidineamino, laurylamino, carbamoyl Amine, N, N-dimethylaminocarbonyl , N, N-diethylaminocarbonylamino, morpholinylcarbonylamino, methoxycarbonylamino, ethoxycarbonylamino, tert-butoxycarbonylamino, n-octadecyloxy Carbonylamino, N-methyl-methoxycarbonylamino, phenoxycarbonylamino, sulfamoylamino, N, N-dimethylaminosulfoamidoamine, methylsulfohydrazone Substituted amine groups such as aminoamino, butylsulfonylamino, phenylsulfonylamino; sulfonylamino, sulfonamido, carboxyl, cyano, sulfo, hydroxyl, nitro, thiol, sulfonyl Amino groups, carbamoyl groups, sulfonamido groups, phosphonic acid groups, phosphate groups or carboxyl groups, sulfo groups, phosphonic acid groups, salts of phosphate groups, etc., these groups may be substituted. In addition, a carboxyl group and a sulfo group may form a salt. In the general formula (IA), when n is 2 to 6, X ¹ They may also be represented by the following general formulae (1) to (5), respectively. [Chemical 4] (In the general formula (1), Y ¹ For single key, -CR ⁵ R ^6- , -NR ⁷ -, Divalent aliphatic hydrocarbon group having 1 to 35 carbon atoms, aromatic hydrocarbon group having 6 to 35 carbon atoms or heterocyclic group containing 2 to 35 carbon atoms, or the following (1-1) to ( Any of the groups represented by 1-3), wherein the aliphatic hydrocarbon group is substituted with -O-, -S-, -CO-, -COO-, -OCO-, -NH-, -SO ₂ In the case of-, -CONH- or -NHCO-, or a bonding group formed by combining these in a way that oxygen atoms are not adjacent, Z ¹ And Z ² Represents a direct bond, -O-, -S-, -CO-, -CO-O-, -O-CO-, -SO, each independently ₂ -, -SS-, -SO-, -NR ⁶ -Or-PR ⁶ -, R ⁵ , R ⁶ And R ⁷ Each independently represents a hydrogen atom, an aliphatic hydrocarbon group having 1 to 35 carbon atoms in the case of having a substituent, an aromatic hydrocarbon group having 6 to 35 carbon atoms in the case of having a substituent, or a case of having a substituent. A heterocyclic group containing 2 to 35 carbon atoms, ﹡ means that the ﹡ moiety is bonded to an adjacent group) [Chem. 5] (In the above formula, R ⁸ Represents a hydrogen atom, or a phenyl group or a cycloalkyl group having 3 to 10 carbon atoms in the case of having a substituent, R ⁹ Represents an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, and an alkenyl group or halogen atom having 2 to 10 carbon atoms. The alkyl group, alkoxy group, and alkenyl group each have a substituent. In this case, f is an integer from 0 to 5, ﹡ means that the ﹡ part is bonded to the adjacent base) [化 6] (﹡ Means bonding between the base and the adjacent base) [化 7] (In the above formula, R ¹⁰ And R ¹¹ Each independently represents an alkyl group having 1 to 10 carbon atoms in the case of having a substituent, an aryl group having 6 to 20 carbon atoms in the case of having a substituent, and 6 to 6 carbon atoms in the case of having a substituent. An aryloxy group of 20, an arylthio group having 6 to 20 carbon atoms when having a substituent, an arylalkenyl group having 6 to 20 carbon atoms when having a substituent, or an arylalkenyl group having a substituent In the case of an arylalkyl group having 7 to 20 carbon atoms, in a case of having a substituent, in a heterocyclic group containing 2 to 20 carbon atoms, or in a halogen atom, the alkyl group and the methylene group in the arylalkyl group When the group is substituted with an unsaturated bond, -O- or -S-, R ¹⁰ Adjacent R ¹⁰ In the case of forming a ring with each other, p represents the number of 0 to 4, q represents the number of 0 to 8, g represents the number of 0 to 4, h represents the number of 0 to 4, and the total number of g and h is 2 to 4, ﹡ Means bonding between the ﹡ part and the adjacent base) [化 8] (In the general formula (2), Y ¹¹ Represents a trivalent aliphatic hydrocarbon group having 1 to 35 carbon atoms, an alicyclic hydrocarbon group having 3 to 35 carbon atoms, an aromatic hydrocarbon group having 6 to 35 carbon atoms, or a heterocyclic group containing 2 to 35 carbon atoms , Z ¹ ,Z ² And Z ³ Represents a direct bond, -O-, -S-, -CO-, -CO-O-, -O-CO-, -SO, each independently ₂ -, -SS-, -SO-, -NR ¹² -Or-PR ¹² -, R ¹² Represents a hydrogen atom, an aliphatic hydrocarbon group having 1 to 35 carbon atoms in the case of having a substituent, an aromatic hydrocarbon group having 6 to 35 carbon atoms in the case of having a substituent, or a carbon atom in the case of having a substituent Heterocyclic groups containing 2 to 35, aliphatic hydrocarbon groups are substituted with -O-, -S-, -CO-, -COO-, -OCO-, -NH-, -SO ₂ -, -CONH- or -NHCO-, or a bonding group formed by combining these in a way that oxygen atoms are not adjacent, ﹡ means that the 指 part is bonded to the adjacent base) [化 9] (In the general formula (3), Y ¹² A carbon atom or a tetravalent aliphatic hydrocarbon group having 1 to 35 carbon atoms, an aromatic hydrocarbon group having 6 to 35 carbon atoms or a heterocyclic group containing 2 to 35 carbon atoms, and the aliphatic hydrocarbon group may be substituted -O-, -S-, -CO-, -COO-, -OCO-, -NH-, -SO ₂ In the case of-, -CONH- or -NHCO-, or a bonding group formed by combining these in a way that oxygen atoms are not adjacent, Z ¹ ~ Z ⁴ Are independently the same as Z in the general formula (2) ¹ ~ Z ³ A base of the same range as that indicated, ﹡ means that the ﹡ part is bonded to an adjacent base) [化 10] (In the general formula (4), Y ¹³ Represents a pentavalent aliphatic hydrocarbon group having 2 to 35 carbon atoms, an aromatic hydrocarbon group having 6 to 20 carbon atoms or a heterocyclic group containing 2 to 20 carbon atoms. The aliphatic hydrocarbon group is substituted with -O- , -S-, -CO-, -COO-, -OCO-, -NH-, -SO ₂ In the case of-, -CONH- or -NHCO-, or a bonding group formed by combining these in a way that oxygen atoms are not adjacent, Z ¹ ~ Z ⁵ Are independently the same as Z in the general formula (2) ¹ ~ Z ³ A base of the same range as that indicated, ﹡ means the bonding between the 与 part and the adjacent base) [化 11] (In the general formula (5), Y ¹⁴ It represents a hexavalent aliphatic hydrocarbon group having 2 to 35 carbon atoms, an aromatic hydrocarbon group having 6 to 35 carbon atoms or a heterocyclic group containing 2 to 35 carbon atoms. The aliphatic hydrocarbon group is substituted with -O- , -S-, -CO-, -COO-, -OCO-, -NH-, -SO ₂ In the case of-, -CONH- or -NHCO-, or a bonding group formed by combining these in a way that oxygen atoms are not adjacent, Z ¹ ~ Z ⁶ Are independently the same as Z in the general formula (2) ¹ ~ Z ³ A base in the same range as that represented by ﹡ means that the ﹡ moiety is bonded to an adjacent base) In the above general formula (1), as R ⁵ , R ⁶ And R ⁷ Examples of the aliphatic hydrocarbon group having 1 to 35 carbon atoms in the case of having a substituent include: X in the general formula (IA) ¹ The monovalent aliphatic hydrocarbon group represented by the represented n-valent bonding group, and these groups are represented as X in the general formula (IA). ¹ As the substituent of the n-valent bonding group represented by the exemplified group, the substituted group satisfies a specific number of carbon atoms, etc., as R ⁵ , R ⁶ And R ⁷ Examples of the aromatic ring-containing hydrocarbon group having 6 to 35 carbon atoms in the case of having a substituent include: X in the general formula (IA) ¹ The monovalent aromatic ring-containing hydrocarbon group represented by the represented n-valent bonding group, and these groups are represented as X in the general formula (IA). ¹ As the substituent of the n-valent bonding group represented by the exemplified group, the substituted group satisfies a specific number of carbon atoms, etc., as R ⁵ , R ⁶ And R ⁷ Examples of the heterocyclic-containing group having 2 to 35 carbon atoms in the case of having a substituent include: X in the general formula (IA) ¹ The n-valent bonding group shown is a monovalent heterocyclic group-containing group, and these groups are represented as X in the general formula (IA). ¹ Examples of the substituents of the n-valent bonded group shown above include those that satisfy a specific number of carbon atoms among the substituted groups. In addition, in the general formula (1), as Y ¹ Examples of the divalent aliphatic hydrocarbon group having 1 to 35 carbon atoms include X in the general formula (IA). ¹ The divalent aliphatic hydrocarbon group exemplified by the n-valent bonding group represented above, and these groups are represented as X in the general formula (IA). ¹ As the substituent of the n-valent bonding group represented by the examples, and those exemplified in the substituted group satisfying a specific number of carbon atoms, etc., as Y ¹ Examples of the divalent aromatic ring-containing hydrocarbon group having 6 to 35 carbon atoms include X in the general formula (IA). ¹ The divalent aromatic ring-containing hydrocarbon group exemplified by the n-valent bonding group represented by these, and these groups are represented as X in the general formula (IA). ¹ As the substituent of the n-valent bonding group represented by the examples, and those exemplified in the substituted group satisfying a specific number of carbon atoms, etc., as Y ¹ Examples of the divalent heterocyclic group containing 2 to 35 carbon atoms include: X in the general formula (IA) ¹ The divalent aromatic ring-containing hydrocarbon group exemplified by the n-valent bonding group represented by these, and these groups are represented as X in the general formula (IA). ¹ Examples of the substituent of the n-valent bonding group shown above include those that satisfy a specific number of carbon atoms among the substituted groups. Among the substituents represented by the above (1-1), as R ⁸ Examples of the cycloalkyl group having 3 to 10 carbon atoms include cyclopropyl, cyclobutyl, cyclopentyl, cycloheptyl, and cyclooctyl. ⁹ Examples of the alkyl group having 1 to 10 carbon atoms include R ¹ And R ² R is an alkyl group having 1 to 40 carbon atoms, and a group satisfying a specific number of carbon atoms among the exemplified groups is R ⁹ Examples of the alkoxy group having 1 to 10 carbon atoms include methoxy, ethoxy, propoxy, isopropoxy, butoxy, second butoxy, third butoxy, Isobutoxy, pentyloxy, isopentyloxy, third pentyloxy, hexyloxy, cyclohexyloxy, heptyloxy, isoheptyloxy, third heptyloxy, n-octyloxy, iso Octyloxy, third octyloxy, 2-ethylhexyloxy, nonyloxy, decoxy, etc., the substituents of phenyl, cycloalkyl, alkyl, alkoxy, and alkenyl are the same as those described above. X in Formula (IA) ¹ The substituents of the n-valent bonding group shown are the same as those exemplified. In the base represented by (1-3) above, as R ¹⁰ And R ¹¹ Examples of the alkyl group having 1 to 10 carbon atoms in the case of having a substituent include R ¹ And R ² R is an alkyl group having 1 to 40 carbon atoms, and a group satisfying a specific number of carbon atoms among the exemplified groups is R ¹⁰ And R ¹¹ Examples of the aryl group having 6 to 20 carbon atoms in the case of having a substituent include: R ¹ And R ² The exemplified aryl group having 6 to 20 carbon atoms, etc., is R ¹⁰ And R ¹¹ Examples of the aryloxy group having 6 to 20 carbon atoms in the case of having a substituent include phenoxy, naphthyloxy, 2-methylphenoxy, 3-methylphenoxy, 4 -Methylphenoxy, 4-vinylphenoxy, 3-isopropylphenoxy, 4-isopropylphenoxy, 4-butylphenoxy, 4-tert-butylphenoxy , 4-hexylphenoxy, 4-cyclohexylphenoxy, 4-octylphenoxy, 4- (2-ethylhexyl) phenoxy, 2,3-dimethylphenoxy, 2, 4-dimethylphenoxy, 2,5-dimethylphenoxy, 2,6-dimethylphenoxy, 3,4-dimethylphenoxy, 3,5-dimethylbenzene Oxygen, 2,4-di-tert-butylphenoxy, 2,5-di-tert-butylphenoxy, 2,6-di-tert-butylphenoxy, 2,4-di-tert-pentyl And other groups such as phenylphenoxy, 2,5-tertiarypentylphenoxy, 4-cyclohexylphenoxy, 2,4,5-trimethylphenoxy, and ferroceneoxy. ¹⁰ And R ¹¹ Examples of the arylthio group having 6 to 20 carbon atoms in the case of having a substituent include the substitution of the oxygen atom in the aryloxy group having 6 to 20 carbon atoms in the case of having the substituent as Base of sulfur atom, etc., as R ¹⁰ And R ¹¹ Examples of the arylalkenyl group having 8 to 20 carbon atoms in the case of having a substituent include the substitution of the oxygen atom in the aryloxy group having 6 to 20 carbon atoms in the case of having the substituent as Vinyl, allyl, 1-propenyl, isopropenyl, 2-butenyl, 1,3-butadienyl, 2-pentenyl, 2-octenyl and other alkenyl groups, etc., as R ¹⁰ And R ¹¹ Examples of the arylalkyl group having 7 to 20 carbon atoms in the case of having a substituent include: R ¹ And R ² The exemplified arylalkyl group having 7 to 20 carbon atoms, etc., is R ¹⁰ And R ¹¹ Examples of the heterocyclic group containing 2 to 20 carbon atoms in the case of having a substituent include: R ¹ And R ² Examples of the heterocyclic-containing group having 2 to 20 carbon atoms are exemplified. As Y in the general formula (2) ¹¹ Examples of the trivalent aliphatic hydrocarbon group having 1 to 35 carbon atoms include X in the general formula (IA). ¹ The trivalent aliphatic hydrocarbon group exemplified by the represented n-valent bonding group and these groups are referred to as X in the general formula (IA). ¹ As the Y of the general formula (2), the substituent of the n-valent bonding group represented by the exemplified group satisfies a specific number of carbon atoms, etc. ¹¹ Examples of the trivalent alicyclic hydrocarbon group having 3 to 35 carbon atoms include cyclopentyl, cyclohexyl, cycloheptyl, cyclooctyl, cyclodecyl, 1-adamantyl, and 2-adamantyl. Alkyl, noradamantyl, 2-methyladamantyl, noryl, isoryl, perhydronaphthyl, perhydroanthryl, bicyclo [1.1.0] butyl, Bicyclo [1.1.1] pentyl, bicyclo [2.1.0] pentyl, bicyclo [3.1.0] hexyl, bicyclo [2.1.1] hexyl, bicyclo [2.2.0] hexyl, bicyclo [4.1.0] heptyl , Bicyclic [3.2.0] heptyl, bicyclic [3.1.1] heptyl, bicyclic [2.2.1] heptyl, bicyclic [5.1.0] octyl, bicyclic [4.2.0] octyl, bicyclic [4.1. 1] octyl, bicyclic [3.3.0] octyl, bicyclic [3.2.1] octyl, bicyclic [2.2.2] octyl, spiro [4,4] nonyl, spiro [4,5] decyl, Trivalent groups derived from decahydronaphthalene, tricyclodecyl, tetracyclododecyl, cedarol, cyclododecyl, etc., as Y ¹¹ Examples of the trivalent aromatic ring-containing hydrocarbon group having 6 to 35 carbon atoms include: X in the general formula (IA) ¹ The trivalent aromatic ring-containing hydrocarbon group exemplified by the represented n-valent bonding group and these groups are referred to as X in the general formula (IA). ¹ As the substituent of the n-valent bonding group represented by the examples, the group substituted with a specific number of carbon atoms, etc., is Y ¹¹ Examples of the trivalent heterocyclic group containing 2 to 35 carbon atoms include: X in the general formula (IA) ¹ The exemplified trivalent heterocyclic ring-containing group represented by the n-valent bonding group and these groups are referred to as X in the general formula (IA). ¹ Examples of the substituents of the n-valent bonding group shown above satisfy the specific number of carbon atoms in the substituted groups. Again, as R ¹² The aliphatic hydrocarbon group having 1 to 35 carbon atoms in the case of having a substituent, the aromatic hydrocarbon group of 6 to 35 carbon atoms in the case of having a substituent, and the carbon number of 2 in the case of having a substituent Examples of the heterocyclic group containing ~ 35 include R in the general formula (1). ⁵ , R ⁶ And R ⁷ The aliphatic hydrocarbon group, aromatic ring-containing hydrocarbon group, and heterocyclic group-containing group exemplified in the description. In the general formula (3), as Y ¹² Examples of the tetravalent aliphatic hydrocarbon group having 1 to 35 carbon atoms include the following: X in the general formula (IA) ¹ The monovalent to trivalent aliphatic hydrocarbon groups represented by the n-valent bonding group shown and these groups are referred to as X in the general formula (IA). ¹ Y represents a substituent of an n-valent bonding group, and a quaternary group derived from a substituted group that satisfies a specific number of carbon atoms, etc., as Y ¹² Examples of the tetravalent aromatic ring-containing hydrocarbon group having 6 to 35 carbon atoms include: X in the general formula (IA) ¹ The monovalent to trivalent aromatic ring-containing hydrocarbon group represented by the n-valent bonding group shown and these groups are referred to as X in the general formula (IA). ¹ Y represents a substituent of an n-valent bonding group, and a quaternary group derived from a substituted group exemplified satisfies a specific number of carbon atoms, etc., as Y ¹² Examples of the tetravalent heterocyclic group containing 2 to 35 carbon atoms include: X in the general formula (IA) ¹ The n-valent bonding group represented is exemplified by the monovalent to trivalent heterocyclic group-containing groups and these groups as X in the general formula (IA). ¹ Among the substituents represented by the n-valent bonding group shown above, those exemplified by the substituted four-valent group satisfy a specific number of carbon atoms, and the like. As Y in the general formula (4) ¹³ Examples of the pentavalent aliphatic hydrocarbon group having 2 to 35 carbon atoms include: X in the general formula (IA) ¹ The monovalent to trivalent aliphatic hydrocarbon groups represented by the n-valent bonding group shown and these groups are referred to as X in the general formula (IA). ¹ Y represents a substituent of the n-valent bonding group and a pentad derived from a substituted group exemplifies a specific number of carbon atoms, etc., as Y ¹⁴ Examples of the pentavalent aromatic ring-containing hydrocarbon group having 6 to 35 carbon atoms include: X in the general formula (IA) ¹ The monovalent to trivalent aromatic ring-containing hydrocarbon group represented by the n-valent bonding group shown and these groups are referred to as X in the general formula (IA). ¹ Y represents a substituent of the n-valent bonding group and a pentad derived from a substituted group exemplifies a specific number of carbon atoms, etc., as Y ¹⁴ Examples of the pentavalent heterocyclic group containing 2 to 35 carbon atoms include: X in the general formula (IA) ¹ The n-valent bonding group represented is exemplified by the monovalent to trivalent heterocyclic group-containing groups and these groups as X in the general formula (IA). ¹ Among the pentavalent radicals derived from the substituents represented by the n-valent bonding groups shown above, those which satisfy a specific number of carbon atoms, and the like. As Y in the general formula (5) ¹⁴ Examples of the hexavalent aliphatic hydrocarbon group having 2 to 35 carbon atoms include the following: X in the general formula (IA) ¹ The monovalent to trivalent aliphatic hydrocarbon groups represented by the n-valent bonding group shown and these groups are referred to as X in the general formula (IA). ¹ Y which is a substituent of the n-valent bonding group represented by the exemplified substituted hexavalent group satisfies a specific number of carbon atoms, etc., is Y ¹⁴ Examples of the hexavalent aromatic ring-containing hydrocarbon group having 6 to 35 carbon atoms include: X in the general formula (IA) ¹ The monovalent to trivalent aromatic ring-containing hydrocarbon group represented by the n-valent bonding group shown and these groups are referred to as X in the general formula (IA). ¹ Y which is a substituent of the n-valent bonding group represented by the exemplified substituted hexavalent group satisfies a specific number of carbon atoms, etc., is Y ¹⁴ Examples of the hexavalent heterocyclic group containing 2 to 35 carbon atoms include: X in the general formula (IA) ¹ The n-valent bonding group represented is exemplified by the monovalent to trivalent heterocyclic group-containing groups and these groups as X in the general formula (IA). ¹ Among the hexavalent radicals derived from the substituents represented by the n-valent bonding group represented by the exemplified substituents, a specific number of carbon atoms is satisfied. Among the compounds represented by the general formula (IA), those represented by the following general formulae (II-1) to (II-3) are preferable because they are easy to synthesize and have high heat resistance. [Chemical 12] (Where, R ⁸² , R ⁸³ And R ⁸⁴ Each independently represents a hydrogen atom, a halogen atom, a cyano group, a hydroxy group, a nitro group, a carboxyl group, or an alkyl group having 1 to 40 carbon atoms, an aryl group having 6 to 20 carbon atoms, and a carbon atom in the case of having a substituent. Arylalkyl having 7 to 20 or heterocyclic containing group having 2 to 20 carbon atoms, R ¹ And R ² (Same as the above general formula (I)) (Where r = 2 ~ 6, X ² When r = 2, it is a base represented by the above general formula (1), when r = 3 is a base represented by the above general formula (2), when r = 4, it is a base represented by the above general formula (3), r When it is 5, it is the general formula (4). When r = 6, it is the general formula (5). R ⁹² And R ⁹³ Each independently represents a hydrogen atom, a halogen atom, a cyano group, a hydroxy group, a nitro group, a carboxyl group, or an alkyl group having 1 to 40 carbon atoms, an aryl group having 6 to 20 carbon atoms, and a carbon atom in the case of having a substituent. Arylalkyl having 7 to 20 or heterocyclic containing group having 2 to 20 carbon atoms, R ¹ And R ² (Same as the above general formula (I)) (Where, R ²⁰¹ , R ²⁰² , R ²⁰³ , R ²⁰⁴ , R ²⁰⁵ , R ²⁰⁶ , R ²⁰⁷ , R ²⁰⁸ Each independently represents a hydrogen atom, a halogen atom, a cyano group, a hydroxyl group, a nitro group, a carboxyl group, an alkyl group having 1 to 40 carbon atoms, an aryl group having 6 to 20 carbon atoms, and a carbon atom in the case of having a substituent Arylalkyl group of 7-20 or heterocyclic group containing 2-20 carbon atoms, Y ¹ ,Z ¹ And Z ² (Same as the general formula (1)) as R in the general formula (II-1) ⁸² , R ⁸³ And R ⁸⁴ The halogen atom represented is an alkyl group having 1 to 40 carbon atoms when having a substituent, an aryl group having 6 to 20 carbon atoms, an arylalkyl group having 7 to 20 carbon atoms, and 2 to carbon atoms. Examples of the heterocyclic group containing 20 include R in the general formula (I). ¹ And R ² Illustrated in the description. As R in the general formula (II-2) ⁹² And R ⁹³ The halogen atom represented is an alkyl group having 1 to 40 carbon atoms when having a substituent, an aryl group having 6 to 20 carbon atoms, an arylalkyl group having 7 to 20 carbon atoms, and 2 to carbon atoms. Examples of the heterocyclic group containing 20 include R in the general formula (I). ¹ And R ² Illustrated in the description. As R in the general formula (II-3) ²⁰¹ , R ²⁰² , R ²⁰³ , R ²⁰⁴ , R ²⁰⁵ , R ²⁰⁶ , R ²⁰⁷ , R ²⁰⁸ The halogen atom represented is an alkyl group having 1 to 40 carbon atoms when having a substituent, an aryl group having 6 to 20 carbon atoms, an arylalkyl group having 7 to 20 carbon atoms, and 2 to carbon atoms. Examples of the heterocyclic group containing 20 include R in the general formula (I). ¹ And R ² Illustrated in the description. Among the compounds represented by the general formula (II-1), R is preferred ¹ Is a branched alkyl group having 1 to 8 carbon atoms, especially a third butyl group, R ² For a hydrogen atom; R ⁸² , R ⁸³ And R ⁸⁴ They are independently a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 10 carbon atoms, an arylalkyl group having 7 to 12 carbon atoms, and a heterocyclic group containing 1 to 10 carbon atoms. , Especially R ⁸² , R ⁸³ And R ⁸⁴ Any of them is an alkyl group having 1 to 4 carbon atoms or a heterocyclic group containing 1 to 10 carbon atoms. Among the compounds represented by the general formula (II-2), R is preferred ¹ Is a branched alkyl group having 1 to 8 carbon atoms, especially a third butyl group, R ² For a hydrogen atom; R ⁹² And R ⁹³ They are independently a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 10 carbon atoms, an arylalkyl group having 7 to 12 carbon atoms, and a heterocyclic group containing 1 to 10 carbon atoms. , Especially R ⁹² Or R ⁹³ It is an alkyl group having 1 to 4 carbon atoms or a heterocyclic group containing 1 to 10 carbon atoms. In X ² In the case of the general formula (1), Y ¹ Preferred are a sulfur atom, an alkylene group having 1 to 20 carbon atoms, a bivalent aromatic ring-containing hydrocarbon group having 6 to 25 carbon atoms, and a bivalent heterocyclic group having 2 to 21 carbon atoms. 2,8,10-tetraoxaspiro [5,5] undecane-derived divalent group, particularly preferably an alkylene group having 1 to 15 carbon atoms, and a bivalent aromatic ring hydrocarbon group having 6 to 15 carbon atoms Divalent radical derived from 2,4,8,10-tetraoxaspiro [5,5] undecane, Z ¹ And Z ² Preferred are a direct bond, -CO-O-, -O-CO-, or an aliphatic hydrocarbon group having 1 to 20 carbon atoms and an aromatic hydrocarbon group having 6 to 10 carbon atoms which may have a substituent, particularly preferably The aliphatic hydrocarbon group having 1 to 8 carbon atoms having a substituent. In X ² In the case of the above general formula (2), Y ¹¹ It is preferably derived from an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 10 carbon atoms, an arylalkyl group having 7 to 12 carbon atoms, or a heterocyclic group containing group having 1 to 10 carbon atoms. The trivalent group is particularly preferably a trivalent group derived from an alkyl group having 1 to 8 carbon atoms, an aryl group having 6 to 9 carbon atoms or a heterocyclic group containing 1 to 6 carbon atoms, Z ¹ ,Z ² And Z ³ Preferably with Z ¹ And Z ² Same as X ² In the case of the general formula (3), Y ¹² Better as and better as Y ¹¹ The four-valent bases corresponding to the bases listed above, Z ¹ ~ Z ⁴ Preferably with Z ¹ And Z ² Same as X ² In the case of the general formula (4), Y ¹³ Better as and better as Y ¹¹ The pentavalent base corresponding to the bases listed above, Z ¹ ~ Z ⁵ Preferably with Z ¹ And Z ² Same as X ² In the case of the general formula (5), Y ¹⁴ Better as and better as Y ¹¹ The hexavalent base corresponding to the bases listed above, Z ¹ ~ Z ⁶ Preferably with Z ¹ And Z ² the same. The compound represented by the general formula (I) is preferably a compound represented by the following [Chem. 14] to [Chem. 15], but it is not limited to these compounds. [Chemical 15] [Chemical 16] The method for producing a compound having a substituent represented by the general formula (I) is not particularly limited. For example, Japanese Patent Laid-Open No. 57-111375, Japanese Patent Laid-Open No. 3-173843, and Japanese Patent Laid-Open No. No. 6-128195, Japanese Patent Laid-Open No. 7-206771, Japanese Patent Laid-Open No. 7-252191, Japanese Patent Laid-Open No. 2004-501128, and a phenolic compound produced by a method described in each of the gazettes and 1-chloro-3 -Methyl-2-butene is obtained by a reaction. The compound having a substituent represented by the general formula (I) can be used as a latent additive in various compositions. The above-mentioned latent additive means that it is inert in the pre-baking step at normal temperature or below 150 ° C, for example, below 150 ° C, because of heating at 100-250 ° C, or 80-200 in the presence of an acid / base catalyst Those who are heated at ℃, the protective group is detached and becomes active. The compound having a substituent represented by the general formula (I) can be used in a photosensitive composition, a photocurable composition, a thermosetting composition, or a polymerizable combination in addition to being a latent antioxidant or a latent ultraviolet absorber. It can also be used as a latent developer for heat sensitive materials. The composition of the present invention can be made into the same photosensitive composition, photocurable composition, thermosetting composition, and polymerization as before except that it contains a compound having a substituent represented by the general formula (I). Sex composition and so on. In the composition of the present invention, the content of the compound having a substituent represented by the general formula (I) as a latent additive is preferably 0.001 to 20% by mass in the solid component of the composition of the present invention, more preferably It is preferably 0.005 to 5 mass%. The composition of the present invention can be prepared as a latent antioxidant containing a compound having a substituent represented by the general formula (I), and further, a polymerizable compound having an ethylenically unsaturated bond having an acid value and photoradical polymerization. The photosensitive composition of the initiator (hereinafter also referred to as the photosensitive composition of the present invention). Examples of the polymerizable compound having an acidic unsaturated bond having an acid value include (meth) acrylic acid, α-chloroacrylic acid, itaconic acid, maleic acid, methyl maleic acid, Butenedioic acid, dicycloheptenedioic acid, butenoic acid, methacrylic acid, vinylacetic acid, allylacetic acid, cinnamic acid, sorbic acid, methyl fumaric acid, succinic acid mono [2- (methyl ) Acrylic ethoxyethyl] ester, phthalic acid mono [2- (meth) acrylic ethoxyethyl] ester, ω-carboxy polycaprolactone mono (meth) acrylate is equivalent to having carboxyl groups at both ends Mono (meth) acrylates with hydroxy polymers, hydroxyethyl (meth) acrylate-maleate, hydroxypropyl (meth) acrylate-maleate, dicyclopentane Unsaturated polybasic acids such as ene-maleic acid esters or polyfunctional (meth) acrylates having one carboxyl group and two or more (meth) acrylfluorenyl groups; phenol and / or cresol novolac epoxy Resin, novolac epoxy resin with biphenyl skeleton, naphthalene skeleton, bisphenol A novolac epoxy compound, dicyclopentadiene novolac epoxy compound Novolac-type epoxy compounds, polyphenylmethane-type epoxy resins having polyfunctional epoxy groups, epoxy compounds represented by the following general formula (III), etc., make unsaturated monobasic acids act on epoxy groups of epoxy resins Resins obtained by allowing unsaturated monoacids to act on epoxy groups of epoxy resins and further polybasic acid anhydrides acting on epoxy groups of epoxy resins, pentaerythritol triacrylate, dipentaerythritol pentaacrylate and other hydroxyl-containing resins The reactant of a polyfunctional acrylate with a dibasic acid anhydride such as succinic anhydride, phthalic anhydride, and tetrahydrophthalic anhydride is a polyfunctional acrylate having an acid value. [Chemical 17] (Where, X ⁴¹ A direct bond, an alkylene group having 1 to 4 carbon atoms when having a substituent, an alicyclic hydrocarbon group having 3 to 20 carbon atoms when having a substituent, -O-, -S-,- SO ₂ -, -SS-, -SO-, -CO-, -OCO- or the substituents represented by the above (1-1) to (1-3), R ⁴¹ , R ⁴² , R ⁴³ And R ⁴⁴ Each independently represents a hydrogen atom, an alkyl group having 1 to 5 carbon atoms when having a substituent, an alkoxy group having 1 to 8 carbon atoms when having a substituent, and a carbon having a substituent Alkenyl or halogen atom having 2 to 5 atoms, m is an integer of 0 to 10) These polymerizable compounds having an acidic ethylenically unsaturated bond having an acid value may be used alone or in combination of two or more kinds. It is used in combination with a polymerizable compound having an ethylenically unsaturated bond having no acid value. When two or more types are mixed and used, they may be copolymerized in advance and used as a copolymer. In the photosensitive composition of the present invention, the content of the polymerizable compound having an acidic ethylenically unsaturated bond having an acid value is preferably 20 to 80% by mass, and more preferably, the solid content of the composition of the present invention. 30 to 70% by mass of the solid component. Examples of the polymerizable compound having an ethylenically unsaturated bond that does not have an acid value include 2-hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate, and (meth) Glycidyl acrylate, the following compounds No.A1 to No.A4, methyl (meth) acrylate, butyl (meth) acrylate, isobutyl (meth) acrylate, third butyl (meth) acrylate , Cyclohexyl (meth) acrylate, n-octyl (meth) acrylate, isooctyl (meth) acrylate, isononyl (meth) acrylate, stearyl (meth) acrylate, (meth) Lauryl acrylate, methoxyethyl (meth) acrylate, dimethylaminomethyl (meth) acrylate, dimethylaminoethyl (meth) acrylate, aminopropyl (meth) acrylate , Dimethylaminopropyl (meth) acrylate, ethoxyethyl (meth) acrylate, poly (ethoxy) ethyl (meth) acrylate, butoxyethoxy (meth) acrylate Ethyl ester, ethylhexyl (meth) acrylate, phenoxyethyl (meth) acrylate, tetrahydrofuran (meth) acrylate, vinyl (meth) acrylate, allyl (meth) acrylate, ( methyl) Benzyl enoate, ethylene glycol di (meth) acrylate, diethylene glycol di (meth) acrylate, triethylene glycol di (meth) acrylate, polyethylene glycol di (meth) acrylic acid Ester, propylene glycol di (meth) acrylate, 1,4-butanediol di (meth) acrylate, 1,6-hexanediol di (meth) acrylate, trimethylolethane tris (methyl) Acrylate), trimethylolpropane tri (meth) acrylate, dipentaerythritol penta (meth) acrylate, dipentaerythritol hexa (meth) acrylate, pentaerythritol tetra (meth) acrylate, pentaerythritol tri ( (Meth) acrylate, tricyclodecane dimethylol di (meth) acrylate, tri [(meth) acrylmethylethyl] isocyanurate, polyester (meth) acrylate oligomer Unsaturated monobasic acids and esters of polybasic acids or polyphenols; metal salts of unsaturated polybasic acids such as zinc (meth) acrylate and magnesium (meth) acrylate; maleic anhydride, itaconic anhydride, methyl cis Butadiene anhydride, methyltetrahydrophthalic anhydride, tetrahydrophthalic anhydride, trialkyltetrahydrophthalic anhydride, 5- (2,5-dioxotetrahydrofuranyl) -3- Methyl-3-cyclohexyl -1,2-dicarboxylic anhydride, trialkyltetrahydrophthalic anhydride-maleic anhydride adduct, dodecenyl succinic anhydride, methyl bicycloheptene dicarboxylic anhydride and other unsaturated polybasic acids Acid anhydride; (meth) acrylamide, methylenebis- (meth) acrylamide, diethylene triamine tri (meth) acrylamide, xylylenebis (meth) acrylamide , Α-chloroacrylamide, N-2-hydroxyethyl (meth) acrylamide and other unsaturated monoacids and polyamines; ammonium and other unsaturated aldehydes; (meth) acrylonitrile, α- Unsaturated nitriles such as chloroacrylonitrile, vinylidene chloride, and allyl cyanide; styrene, 4-methylstyrene, 4-ethylstyrene, 4-methoxystyrene, 4-hydroxystyrene, 4-chlorostyrene, divinylbenzene, vinyltoluene, vinylbenzoic acid, vinylphenol, vinylsulfonic acid, 4-vinylbenzenesulfonic acid, vinylbenzyl methyl ether, vinylbenzyl glycidyl ether And other unsaturated aromatic compounds; unsaturated ketones such as methyl vinyl ketone; unsaturated amine compounds such as vinyl amine, allyl amine, N-vinyl pyrrolidone, and vinyl piperidine; vinyl methyl ether, ethyl Diethyl ether, n-butyl vinyl ether, isobutyl vinyl ether, allyl glycidyl ether and other vinyl ethers; cis-butylene diimide, N-phenyl cis-butyl diimide, N-cyclohexyl cis Unsaturated fluorenimines such as butenedifluorene; indenes such as indene, 1-methylindene; aliphatic conjugated diene such as 1,3-butadiene, isoprene, chloroprene ; Polystyrene, polymethyl (meth) acrylate, poly-n-butyl (meth) acrylate, and polysiloxane are equal to macromonomers with a mono (meth) acrylfluorene group at the end of the polymer molecular chain; (Methyl) acrylonitrile, ethylidene, propylidene, butylidene, vinyl chloride, vinyl acetate and other vinyl compounds, and polymethyl methacrylate macromonomers, polystyrene macromonomers, and other vinyl compounds Monomers, monomethacrylic esters with tricyclodecane skeleton, N-phenylcis butylene diimide, methacryloxymethyl-3-ethyloxetane, etc. (Meth) acrylic acid copolymers and copolymers of (meth) acrylic acid obtained by reacting these with isocyanate compounds having unsaturated bonds such as Karenz MOI and AOI manufactured by Showa Denko Corporation , Or vinyl chloride, vinylidene chloride, divinyl succinate, diallyl phthalate, triallyl phosphate, triallyl isocyanurate, vinyl sulfide, vinyl imidazole, vinyl Oxazoline, vinylcarbazole, vinylpyrrolidone, vinylpyridine, hydroxyl-containing vinyl monomer and polyisocyanate compound, vinyl carbamate compound, hydroxyl-containing vinyl monomer, and polycyclic ring Oxygen compounds such as vinyl epoxy compounds, pentaerythritol triacrylate, dipentaerythritol pentaacrylate and other functional groups containing polyfunctional acrylates such as toluene diisocyanate and hexamethylene diisocyanate. [Chemical 18] [Chemical 19] [Chemical 20] [Chemical 21] In order to improve the developability of the photosensitive composition of the present invention by adjusting the acid value, a monofunctional or polyfunctional epoxy compound may be used together with the polymerizable compound having an acidic unsaturated bond having an acid value. The polymerizable compound having an ethylenically unsaturated bond having an acid value is preferably in a range of 5 to 120 mgKOH / g of the solid content, and the amount of the monofunctional or polyfunctional epoxy compound is preferably to satisfy The way of the acid value is selected. Examples of the monofunctional epoxy compound include glycidyl methacrylate, methyl glycidyl ether, ethyl glycidyl ether, propyl glycidyl ether, isopropyl glycidyl ether, butyl glycidyl ether, and isopropyl ether. Butyl glycidyl ether, third butyl glycidyl ether, pentyl glycidyl ether, hexyl glycidyl ether, heptyl glycidyl ether, octyl glycidyl ether, nonyl glycidyl ether, decyl glycidyl ether, ten Monoalkyl glycidyl ether, dodecyl glycidyl ether, tridecyl glycidyl ether, tetradecyl glycidyl ether, pentadecyl glycidyl ether, cetyl glycidyl ether, 2-ethyl Hexyl glycidyl ether, allyl glycidyl ether, propargyl glycidyl ether, p-methoxyethyl glycidyl ether, phenyl glycidyl ether, p-methoxy glycidyl ether, p-butylphenol glycidyl ether Ether, tolyl glycidyl ether, 2-methyltolyl glycidyl ether, 4-nonylphenyl glycidyl ether, benzyl glycidyl ether, p-cumylphenyl glycidyl ether, trityl glycidyl ether Glyceryl ether, methacrylic acid 2 , 3-glycidyl ester, epoxidized soybean oil, epoxidized linseed oil, glycidyl butyrate, vinyl cyclohexane monoxide, 1,2-epoxy-4-vinyl cyclohexane, oxidation Styrene, pinene oxide, methylstyrene oxide, cyclohexane, propylene oxide, etc. As the polyfunctional epoxy compound, it is preferable to use one or more members selected from the group consisting of a bisphenol type epoxy compound and glycidyl ethers, since a photosensitive composition having better characteristics can be obtained. As the bisphenol-type epoxy compound, in addition to the epoxy compound represented by the general formula (III), a bisphenol-type epoxy compound such as a hydrogenated bisphenol-type epoxy compound can be used. Examples of the glycidyl ethers include ethylene glycol diglycidyl ether, propylene glycol diglycidyl ether, 1,4-butanediol diglycidyl ether, 1,6-hexanediol diglycidyl ether, 1, 8-octanediol diglycidyl ether, 1,10-decanediol diglycidyl ether, 2,2-dimethyl-1,3-propanediol diglycidyl ether, diethylene glycol diglycidyl ether, tris Ethylene glycol diglycidyl ether, tetraethylene glycol diglycidyl ether, hexaethylene glycol diglycidyl ether, 1,4-cyclohexanedimethanol diglycidyl ether, 1,1,1-tris (glycidyl Oxymethyl) propane, 1,1,1-tris (glycidyloxymethyl) ethane, 1,1,1-tris (glycidyloxymethyl) methane, 1,1,1,1- Tetrakis (glycidyloxymethyl) methane. In addition, phenol novolac epoxy compounds, biphenol novolac epoxy compounds, cresol novolac epoxy compounds, bisphenol A novolac epoxy compounds, and dicyclopentadiene novolac ring Novolac-type epoxy compounds such as oxygen compounds; 3,4-epoxy-6-methylcyclohexylmethyl-3,4-epoxy-6-methylcyclohexanecarboxylic acid esters, 3,4- Alicyclic epoxy compounds such as epoxycyclohexylmethyl-3,4-epoxycyclohexane carboxylate, 1-epoxyethyl-3,4-epoxycyclohexane; di-phthalate Glycidyl esters, diglycidyl tetrahydrophthalate, glycidyl dimer acid, and other glycidyl esters; tetraglycidyl diaminodiphenylmethane, triglycidyl p-aminophenol, N, N -Glycidylamines such as diglycidyl aniline; heterocyclic epoxy compounds such as 1,3-diglycidyl-5,5-dimethylhydantoin, triglycidyl isocyanurate, etc. Dioxide compounds such as dicyclopentadiene; naphthalene-type epoxy compounds, triphenylmethane-type epoxy compounds, dicyclopentadiene-type epoxy compounds, and the like. The photo-radical polymerization initiator may be a compound capable of starting radical polymerization upon exposure to light, and examples thereof include acetophenone-based compounds, benzophenone-based compounds, benzophenone-based compounds, 9 -Oxysulfur Ketone compounds, such as ketone compounds, oxime compounds, and the like are preferred. Examples of the acetophenone-based compound include diethoxyacetophenone, 2-hydroxy-2-methyl-1-phenylpropane-1-one, and 4'-isopropyl-2-hydroxy-2 -Methylphenylacetone, 2-hydroxymethyl-2-methylphenylacetone, 2,2-dimethoxy-1,2-diphenylethane-1-one, p-dimethylaminophenethyl Ketone, p-tert-butyldichloroacetophenone, p-tert-butyltrichloroacetophenone, p-azidebenzylidene, 1-hydroxycyclohexylphenylketone, 2-methyl-1 -[4- (methylthio) phenyl] -2-morpholinylacetone-1, 2-benzyl-2-dimethylamino-1- (4-morpholinylphenyl) -butanone- 1. Benzoin, benzoin methyl ether, benzoin ether, benzoin isopropyl ether, benzoin n-butyl ether, benzoin isobutyl ether, 1- [4- (2-hydroxyethoxy) -phenyl] -2-hydroxy-2- Methyl-1-propane-1-one and the like. Examples of the benzophenanthrene-based compound include benzophenanthrene and fennelpyrin. Examples of the benzophenone-based compound include benzophenone, methyl orthobenzoylbenzoate, Michelin, 4,4'-bisdiethylaminobenzophenone, 4, 4'-dichlorobenzophenone, 4-benzylidene-4'-methyldiphenyl sulfide and the like. As 9-oxysulfur Compounds, 9-oxysulfur , 2-methylthio 𠮿 ketone, 2-ethyl-9-oxothio 𠮿 , 2-chloro-9-oxysulfur 𠮿 , 2-isopropylthio 𠮿 ketone, 2,4-diethyl-9-oxothio 𠮿 Wait. As the oxime-based compound, a compound represented by the following general formula (IV) or (V) is particularly preferred in terms of sensitivity and heat resistance. [Chemical 22] (Where, R ⁵¹ And R ⁵² Each independently represents a hydrogen atom, a cyano group, an alkyl group having 1 to 20 carbon atoms when having a substituent, an aryl group having 6 to 30 carbon atoms when having a substituent, and a case having a substituent An arylalkyl group having 7 to 30 carbon atoms or a heterocyclic group containing 2 to 20 carbon atoms in the case of having a substituent, R ⁵³ And R ⁵⁴ Each independently represents a halogen atom, a nitro group, a cyano group, a hydroxyl group, a carboxyl group, and R ⁵⁵ , OR ⁵⁶ , SR ⁵⁷ , NR ⁵⁸ R ⁵⁹ COR ⁶⁰ SOR ⁶¹ , SO ₂ R ⁶² Or CONR ⁶³ R ⁶⁴ , R ⁵³ And R ⁵⁴ In the case of mutual bonding to form a ring, R ⁵⁵ , R ⁵⁶ , R ⁵⁷ , R ⁵⁸ , R ⁵⁹ , R ⁶⁰ , R ⁶¹ , R ⁶² , R ⁶³ And R ⁶⁴ Each independently represents an alkyl group having 1 to 20 carbon atoms in the case of having a substituent, an aryl group having 6 to 30 carbon atoms in the case of having a substituent, and 7 to 10 carbon atoms in the case of having a substituent. Arylalkyl group 30 or a heterocyclic group containing 2 to 20 carbon atoms in the case of having a substituent, X ³ Represents oxygen atom, sulfur atom, selenium atom, CR ⁷⁵ R ⁷⁶ , CO, NR ⁷⁷ Or PR ⁷⁸ , X ⁴ For single bond or CO, R ⁷⁵ ~ R ⁷⁸ Represents an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 30 carbon atoms or an aryl alkyl group having 7 to 30 carbon atoms, and the methylene group in the alkyl group or the arylalkyl group may be substituted. When it is a halogen atom, a nitro group, a cyano group, a hydroxyl group, a carboxyl group, or a heterocyclic group-containing group, it may be substituted with -O-, R ⁵³ And R ⁵⁴ In some cases, a ring is independently integrated with any adjacent benzene ring to form a ring, a represents an integer of 0 to 4 and b represents an integer of 0 to 5) [Chem. 23] (Where, R ¹⁰¹ And R ¹⁰² Represent R independently ¹¹¹ , OR ¹¹¹ COR ¹¹¹ , SR ¹¹¹ , CONR ¹¹² R ¹¹³ Or CN, R ¹¹¹ , R ¹¹² And R ¹¹³ Each independently represents a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 30 carbon atoms, an arylalkyl group having 7 to 30 carbon atoms, or a heterocyclic group containing 2 to 20 carbon atoms Base, R ¹¹¹ , R ¹¹² And R ¹¹³ The hydrogen atom of the indicated base has ¹²¹ , OR ¹²¹ COR ¹²¹ , SR ¹²¹ , NR ¹²² R ¹²³ , CONR ¹²² R ¹²³ , -NR ¹²² -OR ¹²³ , -NCOR ¹²² -OCOR ¹²³ , NR ¹²² COR ¹²¹ OCOR ¹²¹ COOR ¹²¹ SCOR ¹²¹ OCSR ¹²¹ COSR ¹²¹ CSOR ¹²¹ In the case of substitution with hydroxyl, hydroxy, nitro, CN or halogen atoms, R ¹²¹ , R ¹²² And R ¹²³ Each independently represents a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 30 carbon atoms, an arylalkyl group having 7 to 30 carbon atoms, or a heterocyclic group containing 2 to 20 carbon atoms Base, R ¹²¹ , R ¹²² And R ¹²³ The hydrogen atom of the indicated group may be further substituted by a hydroxyl group, a nitro group, a CN atom, a halogen atom, a hydroxyl group, or a carboxyl group. R ¹¹¹ , R ¹¹² , R ¹¹³ , R ¹²¹ , R ¹²² And R ¹²³ The alkylene moiety of the indicated group is substituted with -O-, -S-, -COO-, -OCO-, -NR under the condition that the oxygen atoms are not adjacent. ¹²⁴ -, -NR ¹²⁴ COO-, -OCONR ¹²⁴ -, -SCO-, -COS-, -OCS- or -CSO-, R ¹²⁴ Represents a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 30 carbon atoms, an arylalkyl group having 7 to 30 carbon atoms or a heterocyclic group containing 2 to 20 carbon atoms, R ¹¹¹ , R ¹¹² , R ¹¹³ , R ¹²¹ , R ¹²² , R ¹²³ And R ¹²⁴ The alkyl part of the indicated group may have a branched side chain or a cyclic alkyl group. R ¹⁰³ Represents a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 30 carbon atoms, an arylalkyl group having 7 to 30 carbon atoms or a heterocyclic group containing 2 to 20 carbon atoms, R ¹⁰³ The alkyl portion of the indicated group may have both a branched side chain and a cyclic alkyl group. In addition, R ¹⁰³ With R ¹⁰⁷ , R ¹⁰³ With R ¹⁰⁸ , R ¹⁰⁴ With R ¹⁰⁵ , R ¹⁰⁵ With R ¹⁰⁶ And R ¹⁰⁶ With R ¹⁰⁷ There may be cases when they become one and form a ring, R ¹⁰³ The hydrogen atom of the indicated base has ¹²¹ , OR ¹²¹ COR ¹²¹ , SR ¹²¹ , NR ¹²² R ¹²³ , CONR ¹²² R ¹²³ , -NR ¹²² -OR ¹²³ , -NCOR ¹²² -OCOR ¹²³ , NR ¹²² COR ¹²¹ OCOR ¹²¹ COOR ¹²¹ SCOR ¹²¹ OCSR ¹²¹ COSR ¹²¹ CSOR ¹²¹ In the case of substitution with hydroxyl, hydroxy, nitro, CN or halogen atoms, R ¹⁰⁴ , R ¹⁰⁵ , R ¹⁰⁶ And R ¹⁰⁷ Represent R independently ¹¹¹ , OR ¹¹¹ , SR ¹¹¹ COR ¹¹⁴ , CONR ¹⁵¹ R ¹¹⁶ , NR ¹¹² COR ¹¹¹ OCOR ¹¹¹ COOR ¹¹⁴ SCOR ¹¹¹ OCSR ¹¹¹ COSR ¹¹⁴ CSOR ¹¹¹ , Hydroxyl, CN or halogen atom, R ¹⁰⁴ With R ¹⁰⁵ , R ¹⁰⁵ With R ¹⁰⁶ And R ¹⁰⁶ With R ¹⁰⁷ There may be cases when they become one and form a ring, R ¹¹⁴ , R ¹¹⁵ And R ¹¹⁶ Represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms, R ¹⁰⁸ Represents R ¹¹¹ , OR ¹¹¹ , SR ¹¹¹ COR ¹¹¹ , CONR ¹¹² R ¹¹³ , NR ¹¹² COR ¹¹¹ OCOR ¹¹¹ COOR ¹¹¹ SCOR ¹¹¹ OCSR ¹¹¹ COSR ¹¹¹ CSOR ¹¹¹ , A hydroxyl group, a CN, or a halogen atom, z represents 0 or 1) As other photoradical polymerization initiators, there may be mentioned: 2,4,6-trimethylbenzylidene diphenylphosphine oxide, bis (cyclopentyl Dienyl) -bis [2,6-difluoro-3- (pyl-1-yl)] titanium and the like. These photo-radical polymerization initiators can be used by mixing one or two or more of them according to the required performance. The content of the photo-radical polymerization initiator as described above is preferably 0.1 to 30% by mass, and particularly preferably 0.5 to 10% by mass, in the solid content of the photosensitive composition of the present invention. If the content of the photo-radical polymerization initiator is less than 0.1% by mass, curing by exposure may become insufficient, and if it exceeds 30% by mass, the initiator may be precipitated in the photosensitive composition. The photosensitive composition of the present invention may be further added with a colorant to form a colored photosensitive composition. The hardened | cured material of this coloring photosensitive composition can be used suitably as a color filter. In the coloring photosensitive composition of the present invention, the content of the colorant in the solid matter component of the coloring photosensitive composition of the present invention is preferably 0.01 to 50% by mass, and more preferably 0.1 to 30% by mass. If the content of the colorant is less than 0.01% by mass, the desired chromaticity may not be obtained. If it is more than 50% by mass, the colorant may be precipitated in the coloring photosensitive composition. Examples of the colorant include dyes and pigments. The dye is not particularly limited as long as it is a compound having absorption at 380 to 1200 nm, and examples thereof include azo compounds, anthraquinone compounds, indigo compounds, triarylmethane compounds, 𠮿 Compounds, alizarin compounds, acridine compounds, fluorene compounds, thiazole compounds, naphthol compounds, quinoline compounds, nitro compounds, indamine compounds, hydrazone 𠯤 compounds, phthalocyanine compounds, cyanine compounds, diya Ammonium compound, cyanovinyl compound, dicyanostyrene compound, rose red compound, pyrene compound, polyene naphthylamine compound, coumarin compound, quaternary compound, ketonium compound, spiropyran compound , Spiro 𠯤 compound, merocyanine compound, oxo compound, styryl compound, pyranium compound, rhodanine compound, oxazolinone compound, phthalimide compound, oxoline Compounds, naphthoquinone compounds, azaanthraquinone compounds, porphyrin compounds, azaporphyrin compounds, pyrrole methylene compounds, quinacridone compounds, pyrrolopyrrole dione compounds, indigo compounds, acridine compounds, acrylates # 134116; Compounds, memine compounds, aniline compounds, quinacridone compounds, quinophthalone compounds, quinimine compounds, iridium complexes Was europium compound complexes dyes, plural kinds of these may be mixed and used. As the pigment, an inorganic pigment or an organic pigment can be used, for example, a nitroso compound, a nitro compound, an azo compound, a diazo compound, 𠮿 Compounds, quinoline compounds, anthraquinone compounds, coumarin compounds, phthalocyanine compounds, isoindolinone compounds, isoindolin compounds, quinacridone compounds, anthracene anthrone compounds, piperidone compounds, pyrene Compounds, pyrrolopyrrole dione compounds, thioindigo compounds, dihydrazone 𠯤 compounds, triphenylmethane compounds, quinophthalone compounds, naphthalenetetracarboxylic acids; metal complex compounds of azo dyes and cyanine dyes Lake pigments; carbon black obtained by furnace method, chimney method, heat flow method, or carbon black such as acetylene black, Ketjen black, or lamp black; those obtained by adjusting and coating the carbon black with epoxy resin, using resin The carbon black is obtained by dispersing the carbon black in a solvent in advance and adsorbing 20 to 200 mg / g of resin. The carbon black is obtained by performing acidic or alkaline surface treatment. The average particle diameter is 8 nm or more and DBP oil absorption. If the amount is 90 ml / 100 g or less, the CO and CO in the volatile components at 950 ° C ₂ Calculated total oxygen content per 100 m of carbon black per surface area ² Those above 9 mg; graphite, graphitized carbon black, activated carbon, carbon fiber, nanometer carbon tube, spiral carbon fiber, carbon nanohorn, carbon aerogel, fullerene; aniline black, pigment black 7, titanium black; Hydrophobic resin, chrome oxide green, milori blue, cobalt green, cobalt blue, manganese, ferrocyanide, phosphate ultramarine blue, iron blue, ultramarine blue, sky blue, strong green, emerald green, lead sulfate, lead yellow, Inorganic or organic pigments such as zinc yellow, iron dan (iron oxide red (III)), cadmium red, synthetic iron black, and brown earth. These pigments can be used alone or in combination. As the inorganic pigment or organic pigment, a commercially available pigment can also be used, and examples thereof include pigment red 1, 2, 3, 9, 10, 14, 17, 22, 23, 31, 38, 41, 48, 49, 88, 90, 97, 112, 119, 122, 123, 144, 149, 166, 168, 169, 170, 171, 177, 179, 180, 184, 185, 192, 200, 202, 209, 215, 216, 217, 220, 223, 224, 226, 227, 228, 240, 254; Pigment Orange 13, 31, 34, 36, 38, 43, 46, 48, 49, 51, 52, 55, 59, 60, 61, 62, 64, 65, 71; pigment yellow 1, 3, 12, 13, 14, 16, 17, 20, 24, 55, 60, 73, 81, 83, 86, 93, 95, 97, 98, 100, 109, 110, 113, 114, 117, 120, 125, 126, 127, 129, 137, 138, 139, 147, 148, 150, 151, 152, 153, 154, 166, 168, 175, 180, 185; Pigment Green 7, 10, 36; Pigment Blue 15, 15: 1, 15: 2, 15: 3, 15: 4, 15: 5, 15: 6, 22, 24, 56, 60, 61, 62, 64; Pigment Violet 1, 19, 23, 27, 29, 30, 32, 37, 40, 50, etc. A solvent may be further added to the photosensitive composition and the coloring photosensitive composition of the present invention. Examples of the solvent include solvents that can generally dissolve or disperse the above components as needed. Examples include methyl ethyl ketone, methyl amyl ketone, diethyl ketone, acetone, methyl isopropyl ketone, Ketones such as methyl isobutyl ketone, cyclohexanone, 2-heptanone; ether, dioxane, tetrahydrofuran, 1,2-dimethoxyethane, 1,2-diethoxyethane, di Ether solvents such as propylene glycol dimethyl ether; methyl acetate, ethyl acetate, n-propyl acetate, isopropyl acetate, n-butyl acetate, cyclohexyl acetate, ethyl lactate, dimethyl succinate, TEXANOL and other esters Solvent; solvent solvents such as ethylene glycol monomethyl ether and ethylene glycol monoethyl ether; methanol, ethanol, iso-or-n-propanol, iso-or-n-butanol, pentanol, diacetone alcohol and other alcohol-based solvents; B Glycol monomethyl acetate, ethylene glycol monoethyl acetate, propylene glycol-1-monomethyl ether-2-acetate (PGMEA), dipropylene glycol monomethyl ether acetate, 3-methoxy acetate Ether ester solvents such as butyl butyl, ethoxyethyl propionate, 1-third butoxy-2-propanol, 3-methoxybutyl acetate, cyclohexanol acetate; benzene, toluene, Xylene and other BTX Solvents; aliphatic hydrocarbon solvents such as hexane, heptane, octane, and cyclohexane; terpene hydrocarbon oils such as turpentine, D-limonene, and pinene; mineral spirits, Swazol # 310 (Cosmo Matsuyama Oil Co., Ltd. ), Solvesso # 100 (Exxon Chemical Co., Ltd.) and other paraffin-based solvents; carbon tetrachloride, chloroform, trichloroethylene, methylene chloride, 1,2-dichloroethane and other halogenated aliphatic hydrocarbon solvents; chlorine Halogenated aromatic hydrocarbon solvents such as benzene; carbitol solvents, aniline, triethylamine, pyridine, acetic acid, acetonitrile, carbon disulfide, N, N-dimethylformamide, N, N-dimethylacetamidine Amine, N-methylpyrrolidone, dimethylsulfinium, water, etc. These solvents can be used as one or more mixed solvents. Among these, ketones, ether ester solvents, etc., especially propylene glycol-1-monomethyl ether-2-acetate, and cyclohexanone are equal to the photosensitive composition, and the polymerization of the resist and photoradical is initiated The compatibility of the agent is good, so it is preferred. In the case of using a solvent, it is preferable to use the solid composition component of the photosensitive composition or colored photosensitive composition of the present invention in an amount of 25 to 35% by mass from the viewpoint of operability and the like. The photosensitive composition and the coloring photosensitive composition of the present invention may further contain an inorganic compound. Examples of the inorganic compound include metal oxides such as nickel oxide, iron oxide, iridium oxide, titanium oxide, zinc oxide, magnesium oxide, calcium oxide, potassium oxide, silicon dioxide, and aluminum oxide; layered clay minerals, and rice Lolita blue, calcium carbonate, magnesium carbonate, cobalt, manganese, glass powder, mica, talc, kaolin, ferrocyanide, various metal sulfates, sulfides, selenides, aluminum silicates, calcium silicates, hydrogen Alumina, platinum, gold, silver, copper, etc. When a coloring agent such as a pigment and / or an inorganic compound is used in the photosensitive composition and the coloring photosensitive composition of the present invention, a dispersant may be added. The dispersant is not particularly limited as long as it disperses and stabilizes colorants and inorganic compounds. Commercially available dispersants such as BYK series manufactured by BYK-Chemie can be used. Polymeric dispersants of polyesters, polyethers, and polyurethanes with basic functional groups; functional groups having nitrogen atoms as basic functional groups and functional groups having nitrogen atoms are amines and / or their quaternary salts and amine values It is 1 ～ 100 mgKOH / g. In addition, to the photosensitive composition and coloring photosensitive composition of the present invention, p-anisyl ether, hydroquinone, catechol, tertiary butylcatechol, phenanthrene, and # 134116 may be added as necessary. Isothermal polymerization inhibitors; plasticizers; then accelerators; fillers; defoamers; leveling agents; surface modifiers; phenolic antioxidants, phosphite antioxidants, thioether antioxidants and other antioxidants UV absorber; dispersing assistant; coacervation inhibitor; catalyst; effect promoter; cross-linking agent; tackifier and other commonly used additives. In addition, by using the polymerizable compound having an ethylenically unsaturated bond having an acid value and other organic polymers together, the characteristics of the cured composition of the photosensitive composition and the colored photosensitive composition of the present invention can also be improved. Examples of the organic polymer include polystyrene, polymethyl methacrylate, methyl methacrylate-ethyl acrylate copolymer, poly (meth) acrylic acid, and styrene- (meth) acrylic acid copolymer. , (Meth) acrylic acid-methyl methacrylate copolymer, ethylene-vinyl chloride copolymer, ethylene-vinyl copolymer, polyvinyl chloride resin, ABS resin, nylon 6, nylon 66, nylon 12, urethane Ester resin, polycarbonate polyvinyl butyral, cellulose ester, polypropylene ammonium, saturated polyester, phenol resin, phenoxy resin, polyamidamine imine resin, polyamino acid resin, epoxy resin, etc. Among these, polystyrene, (meth) acrylic acid-methyl methacrylate copolymer, and epoxy resin are also preferable. In the photosensitive composition and coloring photosensitive composition of the present invention, a chain transfer agent, a sensitizer, a surfactant, a silane coupling agent, a melamine compound, and the like may be used in combination. As the chain transfer agent and sensitizer, a sulfur atom-containing compound is generally used. Examples include: thioglycolic acid, thiomalic acid, thiosalicylic acid, 2-mercaptopropionic acid, 3-mercaptopropionic acid, 3-mercaptobutyric acid, N- (2-mercaptopropionyl) glycine Acid, 2-mercaptonicotinic acid, 3- [N- (2-mercaptoethyl) aminomethane] propionic acid, 3- [N- (2-mercaptoethyl) amino] propionic acid, N- ( 3-mercaptopropionyl) alanine, 2-mercaptoethanesulfonic acid, 3-mercaptopropanesulfonic acid, 4-mercaptobutanesulfonic acid, dodecyl (4-methylthio) phenyl ether, 2-mercaptoethanol, 3-mercapto-1,2-propanediol, 1-mercapto-2-propanol, 3-mercapto-2-butanol, mercaptophenol, 2-mercaptoethylamine, 2-mercaptoimidazole, 2-mercaptobenzimidazole, Thiol compounds such as 2-mercapto-3-pyridinol, 2-mercaptobenzothiazole, thioglycolic acid, trimethylolpropane tris (3-mercaptopropionate), pentaerythritol tetrakis (3-mercaptopropionate), etc. Disulfide compounds obtained by oxidation of mercapto compounds, iodoacetic acid, iodopropionic acid, 2-iodoethanol, 2-iodoethanesulfonic acid, 3-iodopropanesulfonic acid and other iodinated alkyl compounds, trimethylolpropanetriol (3-mercaptoisobutyrate), butanediol bis (3-mercaptoisobutyrate), hexamethylene dithiol, sebacyl mercaptan, 1,4-dimethylmercaptobenzene, Glycol Dimercaptopropionate, Butanediol Dimercaptoacetate, Glycol Dimercaptoacetate, Trimethylolpropane Trimercaptoacetate, Butanediol Dimercaptopropionate, Trimethylol Propane trimercaptopropionate, trimethylolpropane trimercaptoacetate, pentaerythritol tetramercaptopropionate, pentaerythritol tetramercaptoacetate, trihydroxyethyltrimercaptopropionate, the following compound No. C1, three Aliphatic polyfunctional thiol compounds such as mercaptopropionic tris (2-hydroxyethyl) isocyanurate, Karenz MT BD1, PE1, NR1, etc. manufactured by Showa Denko Corporation. [Chemical 24] As the surfactant, a fluorine surfactant such as a perfluoroalkyl phosphate, a perfluoroalkyl carboxylate, an anionic interface activity such as an alkali metal salt of a higher fatty acid, an alkyl sulfonate, or an alkyl sulfate can be used. Agents, higher amine hydrohalates, quaternary ammonium salts, and other cationic surfactants, polyethylene glycol alkyl ethers, polyethylene glycol fatty acid esters, sorbitan fatty acid esters, and fatty acid monoglycerides Surfactants such as surfactants, amphoteric surfactants, and polysiloxane surfactants can also be used in combination. As the silane coupling agent, for example, a silane coupling agent manufactured by Shin-Etsu Chemical Co., Ltd. can be used, and among them, KBE-9007, KBM-502, and KBE-403 having an isocyanate group, a methacryl group, and an epoxy group can be suitably used. Silane coupling agent. Examples of the melamine compound include active methylol groups among nitrogen compounds such as (poly) methylol melamine, (poly) methylol glycoluril, (poly) methylol benzoguanamine, and (poly) methylol urea. (CH ₂ Compounds in which all or a portion (at least 2) of the OH groups are alkyl etherified. Here, examples of the alkyl group constituting the alkyl ether include a methyl group, an ethyl group, and a butyl group. The alkyl group may be the same as or different from each other. In addition, the methylol group which has not been alkyl etherified may undergo self-condensation in one molecule, or may condense between two molecules to form an oligomer component. Specifically, hexamethoxymethylmelamine, hexabutoxymethylmelamine, tetramethoxymethylglycol urea, tetrabutoxymethylglycol urea, and the like can be used. Among these, alkyl melamine such as hexamethoxymethylmelamine and hexabutoxymethylmelamine is preferred. The photosensitive composition and colored photosensitive composition of the present invention can be applied by a spin coater, a roll coater, a bar coater, a die coater, a curtain coater, various printing, and dipping. Such well-known methods are applied to support substrates such as soda glass, quartz glass, semiconductor substrates, metals, paper, and plastics. In addition, it can also be transferred to other supporting substrates after being temporarily applied to a supporting substrate such as a film, and its application method is not limited. In addition, as the light source of the active light used for curing the photosensitive composition and the coloring photosensitive composition of the present invention, one that emits light with a wavelength of 300 to 450 nm can be used. For example, ultrahigh-pressure mercury, mercury vapor arc, Carbon arc, xenon arc, etc. Furthermore, the laser direct drawing method, which uses laser light as an exposure light source and directly forms an image from digital information such as a computer without using a mask, not only improves productivity, but also improves resolution and position accuracy. Therefore, it is more useful. As the laser light, it is suitable to use light with a wavelength of 340 to 430 nm, and also those that emit visible light to the infrared region such as argon ion laser, helium neon laser, YAG laser, and semiconductor laser. . When such lasers are used, a sensitizing pigment that absorbs visible light to infrared rays is added. The photosensitive composition and the colored photosensitive composition of the present invention can also be patterned through a double patterning process using two types of photosensitive compositions or colored photosensitive compositions divided into two patterns. The method for curing the photosensitive composition or colored photosensitive composition of the present invention includes the following steps: by the above-mentioned spin coater, roll coater, bar coater, die coater, curtain type A coating machine, various printing, dipping, and other known methods are applied to a support substrate such as soda glass, quartz glass, semiconductor substrate, metal, paper, plastic to form a coating film; and the coating film is exposed to the above-mentioned active light to make it hardening. The photosensitive composition and colored photosensitive composition (or a cured product thereof) of the present invention can be used for an adhesive such as a photocurable coating or varnish, a photocurable adhesive, a printed circuit board, a color television, a PC monitor, or a portable type. Information terminal, digital camera and other color display liquid crystal display panel color filter, CCD image sensor color filter, photosensitive spacer, black column spacer, electrode material for plasma display panel, touch Panel, touch sensor, powder coating, printing ink, printing plate, dental composition, photoforming resin, gel coating, photoresist for electronics, plating resist, etching resist, Both liquid and dry films, solder resists, resists used to make color filters for various display applications, or resists used to form structures in the manufacturing steps of plasma display panels, electroluminescent display devices, and LCDs, Compositions for sealing electrical and electronic parts, solder resists, magnetic recording materials, micro mechanical parts, waveguides, optical switches, plating masks, etching masks, color test systems, glass fiber cable coatings, screen plates Templates for printing, materials for manufacturing three-dimensional objects by stereolithography, materials for hologram recording, image recording materials, fine electronic circuits, decoloring materials, decoloring materials for image recording materials, microcapsules Decoloring materials for image recording materials, photoresist materials for printed wiring boards, photoresist materials for UV and visible light laser direct image systems, and photoresist for the formation of dielectric layers in successive buildups of printed circuit boards There are no particular restrictions on the applications of materials, photoresist materials for 3D mounting, or protective films. The photosensitive composition of the present invention can be used as a transparent structure by curing it. Examples of transparent structures include pillars called photosensitive spacers (PS) and column spacers (CS); fine patterns embossed with (nanometers); manufacturing of large-scale advertising signs or liquid crystals Inkjet receiving layers used in the manufacture of electronic devices such as color filters or alignment films for displays. The transparent structure of the present invention is suitable for a display device. The photosensitive composition of the present invention can be used for transparent conductive films, reflective films, polarizing plates, protective films, and the like, and can be used as a transparent laminated body laminated in the following manner, that is, the required layers are sequentially coated on a transparent substrate , Irradiate the active light through a mask having a specific pattern shape, use a developing solution to develop the exposed film, and heat the developed film. Examples of the transparent laminate include a transparent substrate in which a transparent thin film layer and a metal thin film layer containing a composite oxide of indium oxide and cerium oxide are alternately formed. The photosensitive composition of the present invention can be used for the photosensitive composition of the present invention containing a compound having a substituent represented by the general formula (I) in each of the layers as a latent additive, and the photosensitive composition can be used in any of the layers. Furthermore, this transparent laminated body is suitable for a display device. The colored photosensitive composition of the present invention is used for the purpose of forming pixels of a color filter, and is particularly useful as a photosensitive composition for forming a color filter for a display device for an image display device such as a liquid crystal display panel. . The above-mentioned color filter for a display device is preferably formed by the following steps: (1) forming a coating film of the colored photosensitive composition of the present invention on a substrate; (2) a mask having a specific pattern shape interposed therebetween The coating film is irradiated with active light; (3) the exposed film is developed using a developing solution; (4) the coated film is heated after development. Moreover, the coloring photosensitive composition of this invention is also useful as a coloring photosensitive composition of the inkjet system which does not have a developing process. As the mask, a multi-step mask such as a halftone mask or a grayscale mask may be used. Next, the thermosetting composition which is an example of the composition of this invention is demonstrated. The above thermosetting composition is one which is hardened by heating, and may be any one of a thermal cationic curable composition, a thermal anionic curable composition, or a thermal radical curable composition, and a thermal radical curable composition. When a compound having a substituent represented by the general formula (I), which is a latent antioxidant, is heated to activate it, it is preferable to capture radicals. This thermal radical-curable composition contains a compound having a substituent represented by the general formula (I) as a latent antioxidant, and contains a radical polymerizable organic substance and a thermal radical polymerization initiator as essential components. As said radically polymerizable organic substance, as said radically polymerizable organic substance, it is a polymerizable compound which has an ethylenically unsaturated bond, Specifically, the compound demonstrated by the said [0046], [0049] etc. are mentioned. Examples of the thermal radical polymerization initiator include 2,2'-azobisisobutyronitrile, 2,2'-azobis (methylisobutyrate), and 2,2'-azobis Azo-based initiators such as -2,4-dimethylvaleronitrile, 1,1'-azobis (1-acetamido-1-phenylethane); benzamidine peroxide, peroxide Peroxide-based initiators such as di-tert-butyl benzamidine, tert-butyl pervalerate, bis (4-tert-butylcyclohexyl) peroxydicarbonate, ammonium persulfate, persulfate Persulfates such as sodium and potassium persulfate. These can be used singly or in combination of two or more kinds. The above thermosetting composition can be dissolved or dispersed in an organic solvent as needed, and spin-coated, roll-coated, bar-coated, die-coated, curtain-coated, and various printing The obtained coating solution is applied to a supporting substrate such as soda glass, quartz glass, semiconductor substrate, metal, paper, plastic, and the like by known means such as immersion and dipping, and is heated to harden it. The above-mentioned organic solvent is not particularly limited, and known ones can be used. For example, ketones, ethers, amidines, alcohols, and the like can be preferably used. As specific examples, acetone, methyl ethyl ketone, methyl n-butyl Butyl ketone, methyl isobutyl ketone, ethyl isobutyl ketone, diethyl ether, tetrahydrofuran, dioxane, dimethylformamide, diethylformamide, dimethylacetamide, diethyl Known solvents such as acetofluoramine, N-methylpyrrolidone, methanol, ethanol, isopropanol, ethylene glycol, propylene glycol, 2-methoxy-2-propanol, tetraethylene glycol dimethyl ether, and the like. The heat curing is preferably performed at a temperature of about 60 ° C or higher, preferably about 100 to 300 ° C, for about 10 seconds to 3 hours. Next, the novel compounds of the present invention will be described. The novel compound of the present invention is represented by the following general formula (V), (VI) or (VII). The following general formulae (V), (VI), and (VII) correspond to the general formulae (II-1), (II-2), and (II-3), respectively, and the following general formula (V) For the variable groups in (VI), (VI) and (VII), the descriptions of the corresponding variable groups in the general formulae (II-1), (II-2), (II-3), and (I) can be appropriately applied. Also, the same applies to other aspects that are not specifically explained. [Chemical 25] (Where, R ³¹ , R ³² And R ³³ Each independently represents a hydrogen atom, a halogen atom, a cyano group, a hydroxy group, a nitro group, a carboxyl group, or an alkyl group having 1 to 40 carbon atoms, an aryl group having 6 to 20 carbon atoms, and a carbon atom in the case of having a substituent. Arylalkyl having 7 to 20 or heterocyclic containing group having 2 to 20 carbon atoms, R ³⁰ Represents a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, an arylalkyl group having 7 to 20 carbon atoms, a heterocyclic group containing 2 to 20 carbon atoms, or Trialkylsilyl, R ³⁰ The methylene group in the alkyl or arylalkyl group is substituted with -O-, -S-, -CO-, -O-CO-, -CO-O-, -O-CO-O- , -S-CO-, -CO-S-, -S-CO-O-, -O-CO-S-, -CO-NH-, -NH-CO-, -NH-CO-O-,- O-CO-NH-, -NR'-, -SS- or -SO ₂ -Or in the case where a group selected from these groups is combined under conditions where oxygen atoms are not adjacent, R 'represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms) [Chem. 26] (Where k = 2 ~ 6, X ^{twenty one} When k = 2, the base is represented by the following general formula (11), when k = 3 is the base represented by the following general formula (12), and when k = 4, it is represented by the following general formula (13) Group, when k = 5, the following general formula (14), when k = 6, the following general formula (15), R ³³ And R ³⁴ Each independently represents a hydrogen atom, a halogen atom, a cyano group, a hydroxy group, a nitro group, a carboxyl group, or an alkyl group having 1 to 40 carbon atoms, an aryl group having 6 to 20 carbon atoms, and a carbon atom in the case of having a substituent. Arylalkyl having 7 to 20 or heterocyclic containing group having 2 to 20 carbon atoms, R ³⁰ (Same as the above general formula (V)) (In the general formula (11), Y ²⁰ For single key, -CR ³⁵ R ³⁶ -, -NR ³⁷ -, Divalent aliphatic hydrocarbon group having 1 to 35 carbon atoms, aromatic hydrocarbon group having 6 to 35 carbon atoms or heterocyclic group containing 2 to 35 carbon atoms, or the following (11-1) to ( 11-3), the aliphatic hydrocarbon group is substituted with -O-, -S-, -CO-, -COO-, -OCO-, -NH-, -SO ₂ In the case of-, -CONH- or -NHCO-, or a bonding group formed by combining these in a way that oxygen atoms are not adjacent, Z ¹¹ And Z ¹² Represents a direct bond, -O-, -S-, -CO-, -CO-O-, -O-CO-, -SO, each independently ₂ -, -SS-, -SO-, -NR ³⁷ -Or-PR ³⁷ -, R ³⁵ , R ³⁶ And R ³⁷ Each independently represents a hydrogen atom, an aliphatic hydrocarbon group having 1 to 35 carbon atoms in the case of having a substituent, an aromatic hydrocarbon group having 6 to 35 carbon atoms in the case of having a substituent, or a case of having a substituent. A heterocyclic group containing 2 to 35 carbon atoms, ﹡ means that the ﹡ moiety is bonded to an adjacent group) [Chem 28] (In the above formula, R ¹¹⁷ Represents a hydrogen atom, or a phenyl group or a cycloalkyl group having 3 to 10 carbon atoms in the case of having a substituent, R ¹¹⁸ Represents an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, and an alkenyl group or halogen atom having 2 to 10 carbon atoms. The alkyl group, alkoxy group, and alkenyl group each have a substituent. In the case, j is an integer from 0 to 5, ﹡ means that the ﹡ part is bonded to the adjacent base) [化 29] (﹡ Means bonding between the base and the adjacent base) [化 30] (In the above formula, R ¹¹⁹ And R ¹²⁰ Each independently represents an alkyl group having 1 to 10 carbon atoms in the case of having a substituent, an aryl group having 6 to 20 carbon atoms in the case of having a substituent, and 6 to 6 carbon atoms in the case of having a substituent. An aryloxy group of 20, an arylthio group having 6 to 20 carbon atoms when having a substituent, an arylalkenyl group having 6 to 20 carbon atoms when having a substituent, or an arylalkenyl group having a substituent In the case of an arylalkyl group having 7 to 20 carbon atoms, and in a case of having a substituent, a heterocyclic group or halogen atom having 2 to 20 carbon atoms, and the methylene group in the alkyl group and the arylalkyl group In the case where it is substituted with an unsaturated bond, -O- or -S-, R ¹¹⁹ Adjacent R ¹¹⁹ In the case of forming a ring with each other, s represents a number from 0 to 4, t represents a number from 0 to 8, v represents a number from 0 to 4, w represents a number from 0 to 4, and the total number of v and w is 2 to 4, ﹡ Means bonding between the ﹡ part and the adjacent base) [化 31] (In the general formula (12), Y ^{twenty one} Represents a trivalent aliphatic hydrocarbon group having 3 to 35 carbon atoms, an alicyclic hydrocarbon group having 3 to 35 carbon atoms, an aromatic hydrocarbon group having 6 to 35 carbon atoms, or a heterocyclic group containing 2 to 35 carbon atoms , Z ¹¹ ,Z ¹² And Z ¹³ Represents a direct bond, -O-, -S-, -CO-, -CO-O-, -O-CO-, -SO, each independently ₂ -, -SS-, -SO-, -NR ¹¹¹ -Or-PR ¹¹¹ -, R ¹¹¹ Represents a hydrogen atom, an aliphatic hydrocarbon group having 1 to 35 carbon atoms in the case of having a substituent, an aromatic hydrocarbon group having 6 to 35 carbon atoms in the case of having a substituent, or a carbon atom in the case of having a substituent Heterocyclic groups containing 2 to 35, aliphatic hydrocarbon groups are substituted with -O-, -S-, -CO-, -COO-, -OCO-, -NH-, -SO ₂ -, -CONH- or -NHCO-, or a bonding group formed by combining these in a way that the oxygen atoms are not adjacent, ﹡ means that the ﹡ part is bonded to the adjacent base) [化 32] (In the general formula (13), Y ^{twenty two} A carbon atom or a tetravalent aliphatic hydrocarbon group having 1 to 35 carbon atoms, an aromatic hydrocarbon group having 6 to 35 carbon atoms or a heterocyclic group containing 2 to 35 carbon atoms, and the aliphatic hydrocarbon group may be substituted -O-, -S-, -CO-, -COO-, -OCO-, -NH-, -SO ₂ In the case of-, -CONH- or -NHCO-, or a bonding group formed by combining these in a way that oxygen atoms are not adjacent, Z ¹¹ ~ Z ¹⁴ Are independently the same as Z in the above general formula (12) ¹¹ ~ Z ¹³ A base of the same range as that indicated, ﹡ means bonding between the ﹡ part and the adjacent base) [化 33] (In the general formula (14), Y ^{twenty three} Represents a pentavalent aliphatic hydrocarbon group having 2 to 35 carbon atoms, an aromatic hydrocarbon group having 6 to 20 carbon atoms or a heterocyclic group containing 2 to 20 carbon atoms. The aliphatic hydrocarbon group is substituted with -O- , -S-, -CO-, -COO-, -OCO-, -NH-, -SO ₂ In the case of-, -CONH- or -NHCO-, or a bonding group formed by combining these in a way that oxygen atoms are not adjacent, Z ¹¹ ~ Z ¹⁵ Are independently the same as Z in the above general formula (12) ¹¹ ~ Z ¹³ A base of the same range as that indicated, ﹡ means the bonding between the 与 part and the adjacent base) [化 34] (In the general formula (15), Y ^{twenty four} It represents a hexavalent aliphatic hydrocarbon group having 2 to 35 carbon atoms, an aromatic hydrocarbon group having 6 to 35 carbon atoms or a heterocyclic group containing 2 to 35 carbon atoms. The aliphatic hydrocarbon group is substituted with -O- , -S-, -CO-, -COO-, -OCO-, -NH-, -SO ₂ In the case of-, -CONH- or -NHCO-, or a bonding group formed by combining these in a way that oxygen atoms are not adjacent, Z ¹¹ ~ Z ¹⁶ Are independently the same as Z in the above general formula (12) ¹¹ ~ Z ¹³ A base of the same range as that indicated, ﹡ means bonding between the ﹡ part and the adjacent base) [化 35] (Where, R ⁶¹ , R ⁶² , R ⁶³ , R ⁶⁴ , R ⁶⁵ , R ⁶⁶ , R ⁶⁷ , R ⁶⁸ Each independently represents a hydrogen atom, a halogen atom, a cyano group, a hydroxyl group, a nitro group, a carboxyl group, an alkyl group having 1 to 40 carbon atoms, an aryl group having 6 to 20 carbon atoms, and a carbon atom in the case of having a substituent Arylalkyl group of 7-20 or heterocyclic group containing 2-20 carbon atoms, Y ²⁰ ,Z ¹¹ And Z ¹² (Same as the general formula (11)) In the novel compounds of the present invention represented by the general formulae (V) and (VI), R ¹ An alkyl group having 1 to 8 carbon atoms having a branched chain, especially a third butyl group, is more preferable because it has less outgassing. The method for producing the novel compound of the present invention is not particularly limited. For example, it can be obtained by Japanese Patent Laid-Open No. 57-111375, Japanese Patent Laid-Open No. 3-173843, Japanese Patent Laid-Open No. 6-128195, and Japanese Patent Laid-Open No. 6-128195. No. 7-206771, Japanese Patent Laid-Open No. 7-252191, and Japanese Patent Laid-Open No. 2004-501128 are phenolic compounds produced by the methods described in the respective publications with 1-chloro-3-methyl-2-butene Obtained by reaction. The novel compounds of the present invention can be used in latent antioxidants, latent ultraviolet absorbers, dissolution regulators, and the like. [Examples] Hereinafter, the present invention will be described in more detail with examples and the like, but the present invention is not limited to these examples and the like. [Example 1-1] Synthesis of Compound No. 1 To a 0.9 equivalent dimethylacetamide solution (three times the theoretical yield) of a phenol compound of the following Compound No. 1 'was added potassium carbonate (relative to 1 Each phenol group was 2 equivalents), and it stirred at room temperature for 30 minutes. 1-chloro-3-methyl-2-butene (1.25 equivalents to one phenol group) was added, and the mixture was heated under reflux for 8 hours. Ethyl acetate was added for oil-water separation, and the organic layer was dried with anhydrous sodium sulfate. The solvent was then distilled off and purified by column chromatography (hexane: ethyl acetate = 98: 2). The obtained solid was dried under reduced pressure at 60 ° C for 3 hours to obtain a target substance. By ¹ H-NMR and IR confirmed that the obtained solid was a target. The results are shown in [Table 1] to [Table 2]. [Examples 1-2 to 1-6] Synthesis of compound Nos. 2 to 6 In Example 1-1, the following phenol compounds of compound Nos. 2 'to 6' were used instead of the following compound No. 1 ' Except for the phenol compound, Compound Nos. 2 to 6 were synthesized as the target compound in the same manner as in Example 1-1. By ¹ H-NMR and IR confirmed that the obtained solid was a target. The results are shown in [Table 1] to [Table 2]. [Chemical 36] [Chemical 37] [Table 1] [Table 2] [Example 2-1 and Comparative Examples 2-1 to 2-3] Preparation of Photosensitive Composition No. 1 and Comparative Photosensitive Composition No. 1 to No. 3 SPC-1000 (manufactured by Showa Denko Corporation, solid 29% of PGMEA solution) 50.0 g, ARONIX M-450 (manufactured by Toa Synthesis) 11.6 g, NCI-930 (manufactured by ADEKA) 0.3 g, PGMEA 34.7 g, FZ2122 (manufactured by Dow Corning Toray, solid matter 2.9 g of 1% PGMEA solution) and 0.81 g of the compound described in [Table 3] were mixed and stirred until the insoluble matter disappeared to obtain a photosensitive composition No. 1 and a comparative photosensitive composition No. 1 to No. 3 . [table 3] [Chemical 38] [Chemical 39] [Evaluation Example 1-1 and Comparative Evaluation Example 1-1] Evaluation of outgassing Compound No. 1 and Comparative Compound No. 2 were weighed 5 mg, respectively, and heated from room temperature to 230 ° C (20 ° C / 20 ° C) using a thermal mass measuring device. Min.), the weight reduction rate at the time of holding at 230 ° C for 30 minutes was measured and used as an outgassing evaluation of the photosensitive composition. The smaller the weight loss, the less outgassing. The results are shown in [Table 4]. [Table 4] From the above results, it is understood that the outgassing of the compound of the present invention is small, and the outgassing of the photosensitive composition of the present invention containing the compound of the present invention is small. [Evaluation Example 2-1 and Comparative Evaluation Examples 2-1 to 2-2] Evaluation of Solvent Resistance The photosensitive composition No. 1 obtained in the above Example 2-1 and Comparative Examples 2-1 to 2-2 were evaluated. The obtained comparative photosensitive compositions No. 1 to No. 2 were each applied to a glass substrate under the conditions of 410 rpm × 7 seconds, and dried with a hot plate (90 ° C. × 90 seconds). The obtained coating film was exposed using an ultra-high pressure mercury lamp (40 mJ / cm ² ). The exposed coating film was fired at 230 ° C for 30 minutes. After measuring the film thickness of the obtained coating film, it was immersed in PGMEA, cyclohexanone, N-methylpyrrolidone, and N-ethylpyrrolidone for 30 minutes at room temperature, and the film thickness after immersion was measured. The closer the film thickness ratio (film thickness after immersion × 100 / film thickness before immersion) to 100% before and after immersion, the higher the solvent resistance evaluation. [table 5] [Table 5] shows that the hardened product of the comparative photosensitive composition containing the antioxidant has low solvent resistance, and the photosensitive composition of the present invention using the compound of the present invention as a latent additive has a lower solvent resistance. high. From the above results, it is understood that the photosensitive composition of the present invention using a specific compound as a latent additive has less outgassing, and the cured product has excellent solvent resistance. [Industrial Applicability] According to the present invention, it is possible to provide a compound that is inert at normal temperature and is activated by heating to a specific temperature to exhibit less function as an antioxidant or ultraviolet absorber Moreover, the hardened | cured material has a high solvent resistance composition, especially a photosensitive composition.

no

Claims (10)

A composition containing a compound having a substituent represented by the following general formula (I), (In the formula, R ¹ and R ² each independently represent a hydrogen atom, a halogen atom, a cyano group, a hydroxy group, a nitro group, a carboxyl group, an alkyl group having 1 to 40 carbon atoms when having a substituent, and a substituent having In the case of aryl having 6 to 20 carbon atoms, in the case of having aryl alkyl having 7 to 20 carbon atoms in the case of having a substituent, in the case of having a heterocyclic ring containing 2 to 20 carbon atoms in the case of having the substituent Group or trialkylsilyl group, the methylene group in the alkyl group or arylalkyl group represented by R ¹ and R ² is substituted with -O-, -S if the oxygen atoms are not adjacent -, -CO-, -O-CO-, -CO-O-, -O-CO-O-, -S-CO-, -CO-S-, -S-CO-O-, -O-CO In the case of a base formed by combining bases in -S-, -CO-NH-, -NH-CO-, -NH-CO-O-, -NR'-, -SS-, or -SO _2- , R ' Represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, j represents a number of 1 to 3, and ﹡ means that the ﹡ moiety is bonded to an adjacent group). The composition of claim 1, wherein the compound having a substituent represented by the general formula (I) is a compound represented by the following general formula (IA), (In the formula, n represents an integer of 1 to 10, X ¹ represents an n-valent bonding group, and R ¹ , R ^2, and j are the same as the general formula (I)). The composition according to claim 1, which is a photosensitive composition further containing a polymerizable compound having an ethylenically unsaturated bond having an acid value and a photoradical polymerization initiator. A hardened material which is a hardened material of the composition of claim 3. A display device includes at least a part including a transparent laminated body or a transparent structure formed using a hardened material as claimed in claim 4. A coloring photosensitive composition obtained by further including a colorant in the composition according to claim 3. A cured product, which is a cured product of the colored photosensitive composition according to claim 6. A color filter formed using a hardened body as claimed in claim 7. A method for hardening a composition as claimed in claim 3 or a colored photosensitive composition as claimed in claim 6, comprising applying a composition as claimed in claim 3 or a colored photosensitive composition as claimed in claim 6 to a supporting substrate Forming a coating film on the substrate and exposing the coating film to active light to harden the coating film. A novel compound represented by the following general formula (V), (VI) or (VII), (Wherein R ³¹ , R ³² and R ³³ each independently represent a hydrogen atom, a halogen atom, a cyano group, a hydroxy group, a nitro group, a carboxyl group, or an alkyl group having 1 to 40 carbon atoms in the case of having a substituent, An aryl group having 6 to 20 carbon atoms, an arylalkyl group having 7 to 20 carbon atoms or a heterocyclic group containing 2 to 20 carbon atoms, R ³⁰ represents a hydrogen atom and an alkyl group having 1 to 20 carbon atoms Aryl group having 6 to 20 carbon atoms, arylalkyl group having 7 to 20 carbon atoms, heterocyclic group or trialkylsilyl group having 2 to 20 carbon atoms, alkyl group represented by R ³⁰ or The methylene group in the arylalkyl group is substituted with -O-, -S-, -CO-, -O-CO-, -CO-O-, -O-CO-O-, -S-CO- , -CO-S-, -S-CO-O-, -O-CO-S-, -CO-NH-, -NH-CO-, -NH-CO-O-, -O-CO-NH- , -NR'-, -SS-, or -SO _2- , or a base formed by combining bases selected from among these under the condition that oxygen atoms are not adjacent, R 'represents a hydrogen atom or the number of carbon atoms 1 to 8 alkyl) (In the formula, k = 2 to 6, X ²¹ is a base represented by the following general formula (11) when k = 2, and k = 3 is a base represented by the following general formula (12), and k = 4 Is the group represented by the following general formula (13), k = 5 is the following general formula (14), k = 6 is the following general formula (15), and R ³³ and R ³⁴ each independently represent hydrogen Atoms, halogen atoms, cyano, hydroxyl, nitro, carboxyl groups, or alkyl groups having 1 to 40 carbon atoms, aryl groups having 6 to 20 carbon atoms, and 7 to 20 carbon atoms having a substituent Arylalkyl or heterocyclic group containing 2 to 20 carbon atoms, R ³⁰ is the same as the general formula (V) above) (In the general formula (11), Y ²⁰ represents a single bond, -CR ³⁵ R ^36- , -NR ^37- , a divalent aliphatic hydrocarbon group having 1 to 35 carbon atoms, and an aromatic group having 6 to 35 carbon atoms. A hydrocarbon group or a heterocyclic group containing 2 to 35 carbon atoms, or any of the following groups (11-1) to (11-3), wherein the aliphatic hydrocarbon group is substituted with -O-, -S -, -CO-, -COO-, -OCO-, -NH-, -SO _2- , -CONH- or -NHCO-, or a bonding group formed by combining these in a way that oxygen atoms are not adjacent In the case, Z ¹¹ and Z ¹² each independently represent a direct bond, -O-, -S-, -CO-, -CO-O-, -O-CO-, -SO _2- , -SS-, -SO -, -NR ³⁷ -or -PR ^37- , R ³⁵ , R ³⁶ and R ³⁷ each independently represent a hydrogen atom, an aliphatic hydrocarbon group having 1 to 35 carbon atoms in the case of having a substituent, and an aliphatic hydrocarbon group having a substituent In the case of an aromatic hydrocarbon group having 6 to 35 carbon atoms or a heterocyclic group containing 2 to 35 carbon atoms in the case of having a substituent, ﹡ means that the ﹡ portion is bonded to an adjacent group) (In the above formula, R ¹¹⁷ represents a hydrogen atom or a phenyl group having a substituent or a cycloalkyl group having 3 to 10 carbon atoms, R ¹¹⁸ represents an alkyl group having 1 to 10 carbon atoms and 1 carbon atom When an alkoxy group of 10 to 10, an alkenyl group or a halogen atom having 2 to 10 carbon atoms has a substituent, j is an integer of 0 to 5, and ﹡ means ﹡ (Partially bonded to the adjacent base) (﹡ Means bonding between the ﹡ part and the adjacent base) (In the above formula, R ¹¹⁹ and R ¹²⁰ each independently represent an alkyl group having 1 to 10 carbon atoms when having a substituent, an aryl group having 6 to 20 carbon atoms when having a substituent, In the case of a substituent, an aryloxy group having 6 to 20 carbon atoms, in the case of having a substituent, an arylthio group of 6 to 20 in carbon, and in a case of having a substituent, an aryloxy group of 6 to 20 Aryl alkenyl, arylalkyl having 7 to 20 carbon atoms when having a substituent, heterocyclic containing group having 2 to 20 carbon atoms when having a substituent, or a halogen atom, the alkane The methylene group in the aryl group and the arylalkyl group may be substituted with an unsaturated bond, -O- or -S-, R ¹¹⁹ may be a ring formed by adjacent R ¹¹⁹ , and s represents a number of 0 to 4. , T is a number from 0 to 8, v is a number from 0 to 4, w is a number from 0 to 4, and the sum of the numbers of v and w is 2 to 4, 指 means the bond between the ﹡ part and the adjacent base ) (In the general formula (12), Y ²¹ represents a trivalent aliphatic hydrocarbon group having 1 to 35 carbon atoms, an alicyclic hydrocarbon group having 3 to 35 carbon atoms, an aromatic hydrocarbon group having 6 to 35 carbon atoms, or carbon. Heterocyclic group containing 2 to 35 atoms, Z ¹¹ , Z ¹² and Z ¹³ each independently represent a direct bond, -O-, -S-, -CO-, -CO-O-, -O-CO- _{, -SO 2 -, - SS -} , - SO -, - NR 111 - or -PR ¹¹¹ -, R ¹¹¹ represents a hydrogen atom, an aliphatic hydrocarbon group having a number of carbon atoms in the case of the substituent group of 1 to 35, having In the case of a substituent, an aromatic hydrocarbon group having 6 to 35 carbon atoms or in a case of having a substituent having a heterocyclic group containing 2 to 35 carbon atoms, the aliphatic hydrocarbon group may be substituted with -O-, -S- , -CO-, -COO-, -OCO-, -NH-, -SO _2- , -CONH-, or -NHCO-, or a bond formed by combining these in a way that the oxygen atoms are not adjacent In the case, ﹡ means bonding between the ﹡ part and the adjacent base) (In the general formula (13), Y ²² represents a carbon atom or a tetravalent aliphatic hydrocarbon group having 1 to 35 carbon atoms, an aromatic hydrocarbon group having 6 to 35 carbon atoms, or an impurity containing 2 to 35 carbon atoms. A cyclic group, the aliphatic hydrocarbon group is substituted with -O-, -S-, -CO-, -COO-, -OCO-, -NH-, -SO _2- , -CONH- or -NHCO-, or In the case of a bonded group formed by combining these atoms in such a manner that oxygen atoms are not adjacent, Z ¹¹ to Z ¹⁴ are each independently the same range as the group represented by Z ¹¹ to Z ¹³ in the general formula (12). Base, ﹡ means bonding between the base and the adjacent base) (In the general formula (14), Y ²³ represents a pentavalent aliphatic hydrocarbon group having 2 to 35 carbon atoms, an aromatic hydrocarbon group having 6 to 20 carbon atoms, or a heterocyclic group containing 2 to 20 carbon atoms, The aliphatic hydrocarbon group is substituted with -O-, -S-, -CO-, -COO-, -OCO-, -NH-, -SO _2- , -CONH- or -NHCO-, or not with an oxygen atom. In the case of a bonded group formed by combining these in an adjacent manner, Z ¹¹ to Z ¹⁵ are each independently a base in the same range as the base represented by Z ¹¹ to Z ¹³ in the general formula (12), ﹡ (Means that the ﹡ part is bonded to the adjacent base) (In the above general formula (15), Y ²⁴ represents a hexavalent aliphatic hydrocarbon group having 2 to 35 carbon atoms, an aromatic hydrocarbon group having 6 to 35 carbon atoms, or a heterocyclic group containing 2 to 35 carbon atoms, The aliphatic hydrocarbon group is substituted with -O-, -S-, -CO-, -COO-, -OCO-, -NH-, -SO _2- , -CONH- or -NHCO-, or not with an oxygen atom. In the case of a bonded group formed by combining these in an adjacent manner, Z ¹¹ to Z ¹⁶ are each independently a base in the same range as the base represented by Z ¹¹ to Z ¹³ in the general formula (12), ﹡ (Means that the ﹡ part is bonded to the adjacent base) (In the formula, R ⁶¹ , R ⁶² , R ⁶³ , R ⁶⁴ , R ⁶⁵ , R ⁶⁶ , R ⁶⁷ , and R ⁶⁸ each independently represent a hydrogen atom, a halogen atom, a cyano group, a hydroxy group, a nitro group, a carboxyl group, and a substituent. In the case of a radical, an alkyl group having 1 to 40 carbon atoms, an aryl group having 6 to 20 carbon atoms, an arylalkyl group having 7 to 20 carbon atoms or a heterocyclic group containing 2 to 20 carbon atoms, Y ²⁰ , Z ¹¹ and Z ¹² are the same as the above-mentioned general formula (11)).