TW201802864A - Method and apparatus for cleaning and drying integrated circuit substrate comprising a chuck, a driving unit, a solid plate, a first nozzle, a second nozzle, and a movable arm - Google Patents

Method and apparatus for cleaning and drying integrated circuit substrate comprising a chuck, a driving unit, a solid plate, a first nozzle, a second nozzle, and a movable arm

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TW201802864A
TW201802864A TW105121963A TW105121963A TW201802864A TW 201802864 A TW201802864 A TW 201802864A TW 105121963 A TW105121963 A TW 105121963A TW 105121963 A TW105121963 A TW 105121963A TW 201802864 A TW201802864 A TW 201802864A
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substrate
solid plate
nozzle
cleaning
liquid
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TW105121963A
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Chinese (zh)
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TWI706433B (en
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王暉
陳福平
張曉燕
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盛美半導體設備(上海)有限公司
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Abstract

This invention discloses a method and an apparatus for cleaning and drying an integrated circuit substrate. The apparatus comprises a chuck for placing and supporting the substrate; a driving unit connected with the chuck for driving the chuck to rotate; a solid plate positioned above the substrate; a first nozzle disposed on the solid plate for spraying a cleaning fluid onto the surface of the substrate; a second nozzle disposed on the solid plate for spraying low-tension fluid onto the surface of the substrate; and a movable arm disposed above the substrate for supplying dry gas to the surface of the substrate.

Description

用於清洗和乾燥積體電路基板的方法和裝置 Method and device for cleaning and drying integrated circuit substrate

本發明關於半導體器件製造領域,尤其關於一種化學液清洗基板後,積體電路基板清洗和乾燥的方法和裝置。 The present invention relates to the field of semiconductor device manufacturing, and in particular, to a method and device for cleaning and drying integrated circuit substrates after cleaning the substrate with a chemical liquid.

在半導體基板的加工過程中,避免細小顆粒和其他污染物接觸基板表面是非常重要的,因為顆粒和污染物會造成器件的產量低和壽命短,因此在產生顆粒或污染物的工藝步驟後執行清洗工藝是至關重要的。如今,清洗方法主要是濕法清洗,一組基板同時清洗(槽式清洗)或者每個基板單獨清洗(單片清洗)。由於多種原因,例如製程靈活性、成本效益和廢液管理,近幾年單片濕法清洗機在積體電路製造領域受到極大的歡迎。在單片濕法清洗機中,基板會用不同的工藝化學液進行一系列的處理,工藝的最終步驟是清洗和乾燥。由於乾燥是清洗工序的最後一步,它對整個清洗工藝而言是非常重要的。 During the processing of semiconductor substrates, it is very important to avoid fine particles and other pollutants from contacting the substrate surface, because particles and pollutants will cause low yield and short life of the device, so it is performed after the process steps that generate particles or pollutants The cleaning process is crucial. Today, the cleaning method is mainly wet cleaning, a group of substrates are cleaned simultaneously (tank cleaning) or each substrate is cleaned separately (single-chip cleaning). Due to various reasons, such as process flexibility, cost-effectiveness, and waste liquid management, single-chip wet cleaning machines have been greatly welcomed in the field of integrated circuit manufacturing in recent years. In a single-chip wet cleaning machine, the substrate is subjected to a series of treatments with different process chemicals. The final steps of the process are cleaning and drying. Since drying is the last step in the cleaning process, it is very important for the entire cleaning process.

旋轉-清洗-乾燥對於單片濕法清洗機來說是常見的清洗方法。在該方法中,化學液處理後,大多數的清洗液在離心力的作用下從基板上甩掉,然而,由於清洗 液膜變薄,且達到一個點,在該點由於清洗液膜的粘性阻力比離心力大,離心力不再對清洗液的去除有效,最終,清洗液靠自然或強制蒸發而去除。微量的不易揮發的污染物和細小顆粒存在於變薄的清洗液中,清洗工藝結束後,這些污染物和細小顆粒結合在一起殘留在基板上。根據基板的化學同質性,這些不易揮發的污染物和細小顆粒會造成基板上的諸多瑕疵,衆所周知的例子就是基板疏水區域的浮水印。 Spin-wash-dry is a common cleaning method for single-chip wet cleaning machines. In this method, after the chemical liquid treatment, most of the cleaning liquid is thrown off the substrate by the centrifugal force. However, due to the cleaning The liquid film becomes thinner and reaches a point where the viscous resistance of the cleaning liquid film is greater than the centrifugal force, and the centrifugal force is no longer effective in removing the cleaning liquid. Finally, the cleaning liquid is removed by natural or forced evaporation. A small amount of non-volatile pollutants and fine particles exist in the thinned cleaning solution. After the cleaning process is completed, these pollutants and fine particles are combined and left on the substrate. According to the chemical homogeneity of the substrate, these non-volatile pollutants and fine particles can cause many defects on the substrate. A well-known example is the watermark in the hydrophobic region of the substrate.

Maragoni乾燥機的開發解決了上述的部分問題,Maragoni乾燥機主要使用表面張力梯度力將清洗液膜拉離基板,在乾燥過程中,在基板表面留下微小殘留清洗液膜。參考美國專利No.6,405,452公開了一種乾燥基板的方法,在該方法中,首先將基板浸沒在容器內的去離子水中,然後將乙醇蒸汽和惰性氣體的混合物通入沒有裝滿去離子水的容器的上部,接著,基板離開去離子水進入到容器的上部,從而去除基板表面的去離子水分子。Maragoni乾燥法引入的液體運動只在存在表面張力梯度的情況下起作用,並不保證其他地方沒有顆粒和污染物重新附著到基板表面,一旦重新附著,顆粒和污染物將很難去除。為了更好的去除顆粒和污染物,需要一種有效的方法來阻止顆粒和污染物重新附著在基板表面。 The development of the Maragoni dryer solves some of the above problems. The Maragoni dryer mainly uses the surface tension gradient force to pull the cleaning liquid film away from the substrate. During the drying process, a small residual cleaning liquid film is left on the substrate surface. A method for drying a substrate is disclosed with reference to U.S. Patent No. 6,405,452. In this method, a substrate is first immersed in deionized water in a container, and then a mixture of ethanol vapor and an inert gas is passed into a container not filled with deionized water. Then, the substrate leaves the deionized water and enters the upper part of the container, thereby removing the deionized water molecules on the surface of the substrate. The liquid movement introduced by the Maragoni drying method works only in the presence of surface tension gradients, and does not guarantee that no particles and contaminants will reattach to the substrate surface elsewhere. Once reattached, the particles and contaminants will be difficult to remove. In order to better remove particles and contaminants, an effective method is needed to prevent particles and contaminants from re-adhering to the substrate surface.

根據本發明的一個方面,提出一種用於清洗和 乾燥積體電路基板的方法,包括:以第一轉速旋轉基板並移動固體板使固體板靠近基板,固體板的底面與基板的上表面之間具有間隙;向基板的上表面噴灑清洗液以形成清洗液膜,清洗液膜覆蓋基板的整個上表面;降低固體板並使固體板大體上平行於基板的上表面,固體板上至少有一個區域覆蓋基板的中心區域,液橋被限制在固體板的底面和基板的上表面之間;以第二轉速旋轉基板並向基板的上表面噴灑低張力液體;將固體板從基板的中心區域移動到基板的邊緣,在移動過程中,固體板大體上平行於基板的上表面,將活動臂移動到基板上方的位置以向基板上表面供應乾燥氣體。 According to one aspect of the present invention, a method for cleaning and A method for drying an integrated circuit substrate includes: rotating the substrate at a first speed and moving the solid plate to bring the solid plate closer to the substrate, with a gap between the bottom surface of the solid plate and the upper surface of the substrate; and spraying a cleaning solution on the upper surface of the substrate to form The cleaning liquid film covers the entire upper surface of the substrate; lower the solid plate and make the solid plate substantially parallel to the upper surface of the substrate. At least one area of the solid plate covers the center area of the substrate, and the liquid bridge is limited to the solid plate Between the bottom surface of the substrate and the upper surface of the substrate; rotating the substrate at a second speed and spraying a low tension liquid onto the upper surface of the substrate; moving the solid plate from the center region of the substrate to the edge of the substrate. During the movement, the solid plate was roughly Parallel to the upper surface of the substrate, the movable arm is moved to a position above the substrate to supply a dry gas to the upper surface of the substrate.

根據本發明的另一個方面,提出一種用於清洗和乾燥積體電路基板的裝置,包括:放置並支撐基板的卡盤;與卡盤相連用於驅動卡盤旋轉的驅動單元;位於基板上方的固體板;設置在固體板上用於向基板表面噴灑清洗液的第一噴嘴;設置在固體板上用於向基板表面噴灑低張力液體的第二噴嘴;位於基板上方用於向基板表面供應乾燥氣體的活動臂。 According to another aspect of the present invention, a device for cleaning and drying an integrated circuit substrate is provided, including: a chuck for placing and supporting the substrate; a driving unit connected to the chuck for driving the rotation of the chuck; A solid plate; a first nozzle provided on the solid plate for spraying a cleaning liquid onto the surface of the substrate; a second nozzle provided on the solid plate for spraying a low tension liquid on the substrate surface; located above the substrate for supplying drying to the substrate surface Gas movable arm.

101‧‧‧固體板 101‧‧‧Solid board

102‧‧‧活動臂 102‧‧‧ Mobile arm

103‧‧‧卡盤 103‧‧‧chuck

104‧‧‧基板 104‧‧‧ substrate

105‧‧‧驅動單元 105‧‧‧Drive unit

106‧‧‧第二噴嘴 106‧‧‧Second Nozzle

107‧‧‧第一噴嘴 107‧‧‧first nozzle

108‧‧‧水膜 108‧‧‧ water film

201‧‧‧固體板 201‧‧‧Solid board

204‧‧‧基板 204‧‧‧ substrate

301‧‧‧固體板 301‧‧‧Solid board

304‧‧‧基板 304‧‧‧ substrate

309‧‧‧層流 309‧‧‧ laminar

401‧‧‧固體板 401‧‧‧Solid board

404‧‧‧基板 404‧‧‧ substrate

410‧‧‧顆粒 410‧‧‧ particles

501‧‧‧固體板 501‧‧‧Solid board

502‧‧‧活動臂 502‧‧‧ movable arm

503‧‧‧卡盤 503‧‧‧chuck

504‧‧‧基板 504‧‧‧ substrate

505‧‧‧驅動單元 505‧‧‧Drive unit

506‧‧‧第二噴嘴 506‧‧‧Second Nozzle

507‧‧‧第一噴嘴 507‧‧‧first nozzle

511‧‧‧溫度控制裝置 511‧‧‧Temperature control device

601‧‧‧固體板 601‧‧‧Solid board

602‧‧‧活動臂 602‧‧‧ movable arm

603‧‧‧卡盤 603‧‧‧chuck

604‧‧‧基板 604‧‧‧ substrate

605‧‧‧驅動單元 605‧‧‧Drive unit

606‧‧‧第二噴嘴 606‧‧‧second nozzle

607‧‧‧第一噴嘴 607‧‧‧first nozzle

701‧‧‧固體板 701‧‧‧Solid board

704‧‧‧基板 704‧‧‧ substrate

706‧‧‧第二噴嘴 706‧‧‧Second Nozzle

707‧‧‧第一噴嘴 707‧‧‧first nozzle

為使本領域的技術人員對本發明更加明顯易懂,下面結合附圖對本發明的具體實施方式做詳細的說明,其中: 圖1A描述了用於清洗和乾燥積體電路基板的裝置的具體實施方式;圖1B是圖1A所示裝置的俯視圖;圖2A-2G描述了積體電路基板的清洗和乾燥工藝的具體實施方式;圖3A-3C描述了積體電路基板的清洗和乾燥原理;圖4描述了積體電路基板的清洗和乾燥原理;圖5A-5B描述了積體電路基板的清洗和乾燥原理;圖6A-6D描述了積體電路基板的清洗和乾燥原理;圖7A-7C描述了積體電路基板的清洗和乾燥原理;圖8描述了積體電路基板的清洗和乾燥原理;圖9描述了用於清洗和乾燥積體電路基板的裝置的另一個具體實施方式;圖10A描述了用於清洗和乾燥積體電路基板的裝置的又一個具體實施方式;圖10B是圖10A的俯視圖;圖11A-11B描述了用於清洗和乾燥積體電路基板的裝置的又一個具體實施方式;圖12A-12F描述了固體板的各種形狀。 In order to make the present invention more comprehensible to those skilled in the art, specific embodiments of the present invention are described in detail below with reference to the accompanying drawings, in which: 1A illustrates a specific embodiment of a device for cleaning and drying integrated circuit substrates; FIG. 1B is a top view of the device shown in FIG. 1A; and FIGS. 2A-2G describe a specific embodiment of a cleaning and drying process of the integrated circuit substrate Figures 3A-3C describe the principle of cleaning and drying of integrated circuit substrates; Figure 4 describes the principle of cleaning and drying of integrated circuit substrates; Figures 5A-5B describe the principle of cleaning and drying of integrated circuit substrates; Figures 6A- 6D describes the principle of cleaning and drying the integrated circuit substrate; Figs. 7A-7C describe the principle of cleaning and drying the integrated circuit substrate; Fig. 8 describes the principle of cleaning and drying of the integrated circuit substrate; FIG. 10A depicts another embodiment of the device for cleaning and drying an integrated circuit substrate; FIG. 10B is a top view of FIG. 10A; FIG. 11A-11B describes Another specific embodiment of the apparatus for cleaning and drying integrated circuit substrates is shown; FIGS. 12A-12F illustrate various shapes of a solid board.

下面將結合附圖詳細的描述本發明的多個實施例。 Hereinafter, various embodiments of the present invention will be described in detail with reference to the accompanying drawings.

如圖1A-1B所示為本發明提出的一種用於清洗 和乾燥積體電路基板的裝置的具體實施方式。裝置包括用於放置並支撐基板104的卡盤103,卡盤103與驅動單元105連接,驅動單元105可以是,例如馬達,驅動單元105驅動卡盤103旋轉,基板104隨卡盤103一起旋轉。驅動單元105可以驅動卡盤103以順時針方向、逆時針方向或順時針和逆時針交替旋轉。固體板101位於基板104的上方。固體板101的底面可以由以下任意一種材料製成:藍寶石玻璃、石英、不銹鋼或陽極氧化鋁。固體板101的底面還可以由以下任意一種可濕性陶瓷材料製成:三氧化二鋁或二氧化矽。固體板101的底面還可以由以下任意一種惰性金屬或金屬合金塗層製成:鉑金、黃金、鈦或碳化鈦。固體板101的底面還可以由以下任意一種可濕性改性塑膠製成:PTFE、PVDF或PEEK。 As shown in Figures 1A-1B A specific embodiment of a device for drying and drying an integrated circuit board. The device includes a chuck 103 for placing and supporting the substrate 104. The chuck 103 is connected to a driving unit 105. The driving unit 105 may be, for example, a motor. The driving unit 105 drives the chuck 103 to rotate, and the substrate 104 rotates with the chuck 103. The driving unit 105 can drive the chuck 103 to rotate in a clockwise direction, a counterclockwise direction, or clockwise and counterclockwise alternately. The solid plate 101 is located above the substrate 104. The bottom surface of the solid plate 101 may be made of any one of the following materials: sapphire glass, quartz, stainless steel, or anodized aluminum. The bottom surface of the solid plate 101 may also be made of any one of the following wettable ceramic materials: aluminum oxide or silicon dioxide. The bottom surface of the solid plate 101 can also be made of any one of the following inert metal or metal alloy coatings: platinum, gold, titanium, or titanium carbide. The bottom surface of the solid plate 101 may also be made of any of the following wettable modified plastics: PTFE, PVDF, or PEEK.

第一噴嘴107設置在固體板101的端部以向基板104的表面噴灑清洗液。清洗液為去離子水或含臭氧的去離子水。第二噴嘴106設置在固體板101的端部並鄰近第一噴嘴107,且第二噴嘴106比第一噴嘴107更靠近固體板101的末端,第二噴嘴106用於向基板104的表面噴灑低張力液體。低張力液體可以是以下任意一種:乙醇、IPA、丙酮、乙酸乙酯或者是乙醇、IPA、丙酮、乙酸乙酯的蒸汽形態,較佳的,低張力液體選用IPA液體或IPA蒸汽。活動臂102位於基板104的上方且與固體板101的末端相對以向基板104的表面供應乾燥氣體,乾燥氣體可以是以下任意一種:空氣、氮氣或氬氣,較佳者為氮氣。 The first nozzle 107 is provided at an end of the solid plate 101 to spray a cleaning liquid onto the surface of the substrate 104. The cleaning solution is deionized water or deionized water containing ozone. The second nozzle 106 is disposed at the end of the solid plate 101 and is adjacent to the first nozzle 107. The second nozzle 106 is closer to the end of the solid plate 101 than the first nozzle 107. The second nozzle 106 is used to spray the surface of the substrate 104 low. Tension liquid. The low-tension liquid can be any of the following: ethanol, IPA, acetone, ethyl acetate, or the vapor form of ethanol, IPA, acetone, and ethyl acetate. Preferably, the low-tension liquid is IPA liquid or IPA vapor. The movable arm 102 is located above the substrate 104 and is opposite to the end of the solid plate 101 to supply a dry gas to the surface of the substrate 104. The dry gas may be any of the following: air, nitrogen, or argon, preferably nitrogen.

根據該實施例,本發明還提供了清洗和乾燥工藝步驟,其中,去離子水、IPA和氮氣被噴到基板104的表面並結合固體板101的應用,顆粒和其他污染物將被有效的去除,並能阻止引入顆粒到基板104表面和裝置自身上。使用固體板101的操作步驟可以設置如下: According to this embodiment, the present invention also provides cleaning and drying process steps, in which deionized water, IPA, and nitrogen are sprayed onto the surface of the substrate 104 and combined with the application of the solid plate 101, particles and other pollutants will be effectively removed And can prevent the introduction of particles to the surface of the substrate 104 and the device itself. The operation steps using the solid plate 101 can be set as follows:

步驟1:以第一轉速ω旋轉基板104,ω的範圍在10-50rpm,移動固體板101,使固體板101靠近基板104,固體板101的底面與基板104的上表面之間具有間隙。 Step 1: Rotate the substrate 104 at a first rotation speed ω, the range of ω is 10-50 rpm, move the solid plate 101 so that the solid plate 101 is close to the substrate 104, and there is a gap between the bottom surface of the solid plate 101 and the upper surface of the substrate 104.

步驟2:使用第一噴嘴107向基板104的上表面噴灑去離子水以形成水膜108,水膜108覆蓋基板104的整個上表面,水膜108的厚度大約3mm,圖2A所示為步驟2的示例。 Step 2: Use the first nozzle 107 to spray deionized water on the upper surface of the substrate 104 to form a water film 108. The water film 108 covers the entire upper surface of the substrate 104. The thickness of the water film 108 is about 3 mm. FIG. 2A shows step 2 Example.

步驟2是去離子水清洗步驟,在這一步驟中,由於基板104以一個相對低的轉速旋轉,水膜108為連續的水膜並覆蓋了基板104的整個上表面。 Step 2 is a deionized water cleaning step. In this step, since the substrate 104 is rotated at a relatively low speed, the water film 108 is a continuous water film and covers the entire upper surface of the substrate 104.

步驟3:降低固體板101,固體板101的底面大體上平行於基板104的上表面,此處的“大體上平行”意思是固體板101的底面平行或近似於平行基板104的上表面。固體板101緊挨著基板104以便在固體板101的底面和基板104的上表面之間形成液橋,由於毛細現象,液橋被限制在固體板101的底面和基板104的上表面之間。固體板101上至少有一個區域覆蓋基板104的中心區域,中心區域包括基板104的中心和靠近中心的區域。 Step 3: The solid plate 101 is lowered. The bottom surface of the solid plate 101 is substantially parallel to the upper surface of the substrate 104. “Substantially parallel” here means that the bottom surface of the solid plate 101 is parallel to or approximately parallel to the upper surface of the substrate 104. The solid plate 101 is next to the substrate 104 so as to form a liquid bridge between the bottom surface of the solid plate 101 and the upper surface of the substrate 104. Due to the capillary phenomenon, the liquid bridge is restricted between the bottom surface of the solid plate 101 and the upper surface of the substrate 104. At least one region on the solid plate 101 covers the central region of the substrate 104, and the central region includes the center of the substrate 104 and a region near the center.

步驟4:以大約300rpm的第二轉速旋轉基板104並向 基板104的上表面噴灑IPA一秒鐘,IPA透過第二噴嘴106噴灑到基板104的上表面,圖2B所示為步驟4的示例。由於基板104持續旋轉,噴灑到基板104上表面的IPA的路徑為螺旋狀,如圖2C所示。在這一步驟中,當IPA噴灑到基板104的上表面時,可以停止噴灑去離子水。 Step 4: Rotate the substrate 104 at a second rotation speed of about 300 rpm and The upper surface of the substrate 104 is sprayed with IPA for one second, and the IPA is sprayed onto the upper surface of the substrate 104 through the second nozzle 106. FIG. 2B shows an example of step 4. As the substrate 104 continues to rotate, the path of the IPA sprayed onto the upper surface of the substrate 104 is spiral, as shown in FIG. 2C. In this step, when the IPA is sprayed on the upper surface of the substrate 104, the spraying of deionized water may be stopped.

步驟5:以程式預設的速度將固體板101從基板104的中心區域移動到基板104的邊緣,在移動過程中,固體板101大體上平行於基板104的上表面。同時,將活動臂102移動到基板104上方的特定位置以向基板104上表面供應氮氣,然後開始在該特定位置和基板104的邊緣之間做往復運動,活動臂102的運動終點為基板104的邊緣,此過程有利於去除顆粒。以大約300rpm的第二轉速持續旋轉基板104並持續向基板104的上表面噴灑IPA。圖2D所示為步驟5的示例。圖2E所示為在基板104上表面的IPA的螺旋運動軌迹。 Step 5: The solid plate 101 is moved from the central area of the substrate 104 to the edge of the substrate 104 at a preset speed. During the movement, the solid plate 101 is substantially parallel to the upper surface of the substrate 104. At the same time, move the movable arm 102 to a specific position above the substrate 104 to supply nitrogen to the upper surface of the substrate 104, and then start reciprocating movement between the specific position and the edge of the substrate 104. The end point of the movable arm 102 is the Edge, this process facilitates the removal of particles. The substrate 104 is continuously rotated at a second rotation speed of about 300 rpm and the upper surface of the substrate 104 is continuously sprayed with IPA. Figure 2D shows an example of step 5. FIG. 2E shows the spiral motion trajectory of the IPA on the upper surface of the substrate 104.

如圖2F所示,在步驟5中,較佳的,當固體板101即將離開基板104時,將活動臂102移動到基板104的中心,然後開始基板104中心到邊緣的往復運動,活動臂102的運動終點在基板104的邊緣。 As shown in FIG. 2F, in step 5, preferably, when the solid plate 101 is about to leave the substrate 104, the movable arm 102 is moved to the center of the substrate 104, and then the center-to-edge reciprocating motion of the substrate 104 is started, and the movable arm 102 The end of the movement is at the edge of the substrate 104.

如圖2G所示,在步驟5中,較佳的,當固體板101離開基板104後,將活動臂102移動到基板104的中心以供應氮氣,然後開始基板104中心到邊緣的往復運動,活動臂102的運動終點在基板104的邊緣。 As shown in FIG. 2G, in step 5, preferably, when the solid plate 101 leaves the substrate 104, the movable arm 102 is moved to the center of the substrate 104 to supply nitrogen, and then the center-to-edge reciprocating motion of the substrate 104 is started to move. The end of the movement of the arm 102 is at the edge of the substrate 104.

由於液橋被限制在固體板101的底面和基板 104的上表面之間,表面張力低於去離子水的低張力液體被引入到靠近固體板101末端邊緣的水膜108的自由液面上,且位於基板104的中心區域,在基板104的中心或靠近中心處形成一個表面張力梯度區域。移動固體板101往外推動水膜108,從而打破基板104中心區域水膜108的連續性。由於固體板101向外移動,拖拽下方的水膜108同軌迹移動,固體板101底面下方的水膜108持續與固體板101噴灑的低張力液體接觸,可維持固體板101末端邊緣表面張力梯度的存在,以推動水膜108向外流動。因此基板104可達成無水痕乾燥,且顆粒和污染物隨著水膜108一起被去除,並不會再吸附到基板104的表面。水膜108的縮減速度直接取決於固體板101的移動速度和基板104的轉速。在水膜108去除工藝的最後,氮氣可以由單獨的輸送裝置供應到基板104上,以幫助殘留在基板104表面的揮發性成分蒸發。 Because the liquid bridge is confined to the bottom surface and the base plate of the solid plate 101 Between the upper surfaces of 104, a low-tension liquid with a surface tension lower than that of deionized water is introduced to the free liquid surface of the water film 108 near the end edge of the solid plate 101, and is located in the center region of the substrate 104, in the center of the substrate 104 Or form a surface tension gradient area near the center. Moving the solid plate 101 pushes the water film 108 outward, thereby breaking the continuity of the water film 108 in the central area of the substrate 104. As the solid plate 101 moves outward, drag the water film 108 below it to follow the trajectory. The water film 108 below the bottom surface of the solid plate 101 continuously contacts the low tension liquid sprayed by the solid plate 101, which can maintain the surface tension gradient at the end edge of the solid plate 101. Presence to push the water film 108 outward. Therefore, the substrate 104 can be dried without water marks, and particles and pollutants are removed together with the water film 108, and will not be adsorbed on the surface of the substrate 104 again. The reduction speed of the water film 108 directly depends on the moving speed of the solid plate 101 and the rotation speed of the substrate 104. At the end of the water film 108 removal process, nitrogen can be supplied to the substrate 104 by a separate transport device to help the volatile components remaining on the surface of the substrate 104 evaporate.

根據圖3A-3C所示的清洗和乾燥原理,表面張力對於乾燥性能來說是最重要的。在常用的Maragoni乾燥機中,顆粒和水膜的去除是透過從覆蓋有IPA層的水中拉基板。20℃,IPA的表面張力為21.3mN/m,去離子水的表面張力為72.7mN/m。由於高表面張力的液體比低表面張力的液體對周圍液體的拉力更強烈,表面張力梯度的存在將自然而然的使液體從低表面張力的區域流向高表面張力區域。水面上IPA的量、腔內溫度和向外拉基板的速度都需要精確控制。由於低粘度和低表面張力,IPA乾燥在單片清 洗機中也具有市場。IPA透過噴嘴噴到基板的表面,然後高速旋轉基板,透過離心力乾燥基板。這種方法非常方便,但對於疏水性和親水性的混合矽基板表面來說,在乾燥過程中,表面可能會存在浮水印的問題。所有現有的Maragoni乾燥技術在乾燥過程中具有自由液面,而本發明所揭示的方法將水膜108限制在固體板101的底面和基板104的上表面之間,透過這個方法,無論基板104是否具有可濕性表面,透過固體板101的移動和基板104的轉動,以及移動固體板101附加的液體噴灑裝置,可維持移動水膜108的連續性不被打破,透過固體板101的拖曳力與兩種液體間的表面張力梯度驅動力,使得水膜108徹底從基板104表面拉走。被限制的水膜108的連續性沒有被打破,因此從基板104的表面去除時有效避免了滴液的乾燥印記,這些乾燥印記,通常呈環形形成在疏水面,就是所謂的“浮水印”,它們因在半導體製造中會降低器件產量而聞名。 According to the cleaning and drying principles shown in Figures 3A-3C, surface tension is most important for drying performance. In a commonly used Maragoni dryer, particles and water films are removed by pulling the substrate from water covered with an IPA layer. At 20 ° C, the surface tension of IPA was 21.3 mN / m, and the surface tension of deionized water was 72.7 mN / m. Because a liquid with a high surface tension has a stronger pulling force on the surrounding liquid than a liquid with a low surface tension, the existence of a surface tension gradient will naturally cause the liquid to flow from a region with a low surface tension to a region with a high surface tension. The amount of IPA on the water surface, the temperature in the cavity, and the speed of pulling the substrate outwards all need to be precisely controlled. Due to low viscosity and low surface tension, IPA is dried There is also a market in washing machines. IPA is sprayed onto the surface of the substrate through a nozzle, then the substrate is rotated at a high speed, and the substrate is dried by centrifugal force. This method is very convenient, but for hydrophobic and hydrophilic mixed silicon substrate surfaces, during the drying process, there may be watermark problems on the surface. All existing Maragoni drying technologies have a free liquid surface during the drying process, and the method disclosed in the present invention confines the water film 108 between the bottom surface of the solid plate 101 and the upper surface of the substrate 104. Through this method, regardless of whether the substrate 104 is With a wettable surface, through the movement of the solid plate 101 and the rotation of the substrate 104, and the liquid spraying device attached to the moving solid plate 101, the continuity of the moving water film 108 can be maintained. The drag force of the solid plate 101 and the The driving force of the surface tension gradient between the two liquids causes the water film 108 to be completely pulled away from the surface of the substrate 104. The continuity of the confined water film 108 is not broken, so the dry marks of the drip are effectively avoided when removing from the surface of the substrate 104. These dry marks are usually formed in a ring shape on the hydrophobic surface, which is called a "watermark". They are known for reducing device yield in semiconductor manufacturing.

當固體板101向外移動,拖動固體板101下方被限制的水膜108同軌跡移動,固體板101底面下方的水膜108持續與固體板101噴灑的低張力液體接觸,以維持固體板101末端邊緣處的表面張力梯度區域,從而驅動水膜108向外流動。水膜108的縮減速度直接取決於固體板101的移動速度和基板104的轉速。圖3C所示為固體板101底面下方的水膜108與固體板101噴灑的低張力液體接觸的實施例。γc是基板104表面上方和固體板101下方的水膜108的毛細長度,可以由以下計算:

Figure TW201802864AD00001
When the solid board 101 moves outward, drag the restricted water film 108 below the solid board 101 to follow the trajectory, and the water film 108 under the bottom of the solid board 101 continues to contact the low tension liquid sprayed by the solid board 101 to maintain the solid board 101 The area of the surface tension gradient at the tip edge drives the water film 108 to flow outward. The reduction speed of the water film 108 directly depends on the moving speed of the solid plate 101 and the rotation speed of the substrate 104. FIG. 3C shows an embodiment where the water film 108 under the bottom surface of the solid plate 101 is in contact with the low-tension liquid sprayed from the solid plate 101. γc is the capillary length of the water film 108 above the surface of the substrate 104 and below the solid plate 101, and can be calculated as follows:
Figure TW201802864AD00001

其中,γ是表面張力,ρ是液體密度,g是重力加速度。在本發明所揭示的乾燥過程中,γ由於噴灑低張力液體而逐漸減小,當固體板101離開基板104時,γc越來越小。 Where γ is the surface tension, ρ is the density of the liquid, and g is the acceleration of gravity. In the drying process disclosed by the present invention, γ gradually decreases due to spraying of a low-tension liquid. When the solid plate 101 leaves the substrate 104, γc becomes smaller and smaller.

參考圖4所示,圖4示意了基板的兩種屬性。接觸角φ大於90°,基板顯示疏水性。接觸角φ小於90°,基板顯示親水性。很難從疏水性的基板上去除表面顆粒,在半導體工業中,常用的去除顆粒的方法是將基板的疏水性改變為親水性,但在工藝過程中,將在基板上生長輕微氧化層,這對於器件的電氣特性是有害的,特別是臨界尺寸減小到65nm及以下。開發一種化學氧化層可控的集成性乾燥方法和設備是很有必要且急迫的。 Referring to FIG. 4, FIG. 4 illustrates two attributes of the substrate. The contact angle φ is larger than 90 °, and the substrate exhibits hydrophobicity. The contact angle φ is less than 90 °, and the substrate exhibits hydrophilicity. It is difficult to remove surface particles from a hydrophobic substrate. In the semiconductor industry, the commonly used method of removing particles is to change the hydrophobicity of the substrate to hydrophilic, but during the process, a slight oxide layer will grow on the substrate. It is harmful to the electrical characteristics of the device, especially the critical dimension is reduced to 65nm and below. It is necessary and urgent to develop an integrated drying method and equipment with a controlled chemical oxide layer.

如圖5A-5B所示為使用固體板101的基板104清洗和乾燥的基本原理的一個實施例。如圖5A所示,透過旋轉基板104,去離子水膜可以保持在基板104的表面和邊緣,去離子水膜對於接下來的工藝步驟是非常重要的,例如,防止局部區域的化學濃度高,由於基板104邊緣液膜的分離壓力,圖5A示意了一個不穩定的狀態。噴灑IPA且IPA擴散至去離子水膜後,混合液體中將產生表面張力梯度,表面張力和基板104邊緣處的分離壓力之間的相互作用使得整個液膜分成兩部分,如圖5B。由於離心力和重力,位於基板104邊緣處的部分將從基板104上滴落,圖5B中 所示的液膜可以解決基板104邊緣的浮水印問題。 An embodiment of the basic principle of cleaning and drying the substrate 104 using the solid plate 101 is shown in FIGS. 5A-5B. As shown in FIG. 5A, through rotating the substrate 104, the deionized water film can be maintained on the surface and edges of the substrate 104. The deionized water film is very important for the next process steps, for example, to prevent high chemical concentrations in local areas, Due to the separation pressure of the liquid film at the edge of the substrate 104, FIG. 5A illustrates an unstable state. After the IPA is sprayed and the IPA diffuses to the deionized water film, a surface tension gradient will be generated in the mixed liquid. The interaction between the surface tension and the separation pressure at the edge of the substrate 104 causes the entire liquid film to be divided into two parts, as shown in FIG. 5B. Due to centrifugal force and gravity, the portion located at the edge of the substrate 104 will drip from the substrate 104, as shown in FIG. 5B The illustrated liquid film can solve the watermark problem at the edge of the substrate 104.

如圖6A-6D所示為使用固體板201的基板204清洗和乾燥的基本原理的另一個實施例。圖6A所示為基板204上液相的接觸角φ,φ和基板的表面特性之間的關係已經在圖4中呈現。圖6B所示為毛細作用力,發生在液體填滿兩個活動部件之間的微小空間時。當兩個活動部件之間液體接觸角φ小於90°時,由於“液橋”的形成使得兩個表面之間存在引力,根據理論得到的表面張力為:γ=Fmax/2πr 6A-6D show another embodiment of the basic principle of cleaning and drying the substrate 204 using the solid plate 201. FIG. 6A shows that the relationship between the contact angles φ, φ of the liquid phase on the substrate 204 and the surface characteristics of the substrate has been presented in FIG. 4. Figure 6B shows capillary forces that occur when liquid fills a tiny space between two moving parts. When the liquid contact angle φ between two moving parts is less than 90 °, there is a gravitational force between the two surfaces due to the formation of a "liquid bridge". According to the theory, the surface tension is: γ = Fmax / 2πr

其中,Fmax是最大過剩力,r是液體的半徑。 Among them, Fmax is the maximum excess force, and r is the radius of the liquid.

圖6C所示為在低張力液體噴灑到基板204表面的過程中可能發生的現象,該現象由表面張力引起,並對基板204的乾燥工藝有害。幸運的是,這種現象可以透過固體板201的應用而避免。如圖6D所示,可以看出均勻的液膜覆蓋固體板201下方的基板204,固體板201的底面和基板204的上表面之間的間隙d應該被控制在小於r。 FIG. 6C illustrates a phenomenon that may occur during the spraying of a low tension liquid on the surface of the substrate 204, which is caused by surface tension and is harmful to the drying process of the substrate 204. Fortunately, this phenomenon can be avoided by the application of the solid plate 201. As shown in FIG. 6D, it can be seen that the uniform liquid film covers the substrate 204 under the solid plate 201, and the gap d between the bottom surface of the solid plate 201 and the upper surface of the substrate 204 should be controlled to be less than r.

如圖7A-7C所示為關於固體板301和基板304之間的均勻液膜的正式理論的一個實施例。圖7A所示,往基板304表面噴灑低張力液體的過程中理論上會形成島狀液膜。圖7B所示為固體板301作用於基板304表面。固體板301以特定的速度離開基板304,移動過程中固體板301大體上與基板304的表面平行,同時,基板304旋轉且轉速由乾燥性能決定。當固體板301離開基板304時,固體板301的下方有層流309。圖7C所示為固體板301作用於 基板304的表面。離心力和表面張力之間的相互作用使均勻液膜覆蓋固體板301下方的基板304。 An embodiment of a formal theory regarding a uniform liquid film between a solid plate 301 and a substrate 304 is shown in FIGS. 7A-7C. As shown in FIG. 7A, in the process of spraying a low tension liquid on the surface of the substrate 304, an island-like liquid film is theoretically formed. FIG. 7B shows that the solid plate 301 acts on the surface of the substrate 304. The solid plate 301 leaves the substrate 304 at a specific speed. During the movement, the solid plate 301 is substantially parallel to the surface of the substrate 304. At the same time, the substrate 304 rotates and the rotation speed is determined by the drying performance. When the solid plate 301 leaves the substrate 304, there is a laminar flow 309 below the solid plate 301. Figure 7C shows the solid plate 301 acting on The surface of the substrate 304. The interaction between centrifugal force and surface tension causes a uniform liquid film to cover the substrate 304 below the solid plate 301.

如圖8所示為使用固體板401的基板清洗和乾燥原理的又一個實施例。布朗運動表面上看是液體內懸浮顆粒410的隨機運動,尤其是在液膜中。如果液膜的溫度升高,布朗運動加劇,如果液體的粘度降低,布朗運動依然加劇。因此,透過帶有低張力液體輸送系統的固體板401對液膜進行加熱處理,加劇顆粒410和污染物的布朗運動,阻止更多顆粒410和污染物附著到基板404的表面。此外,透過在固體板401上安裝兆聲波換能器對液膜施加兆聲波能量,聲波能量引起的微觀高速流場去除可能重新依附到基板404表面的顆粒410和污染物。 As shown in FIG. 8, another embodiment of the substrate cleaning and drying principle using the solid plate 401 is shown. The Brownian motion surface appears to be the random movement of suspended particles 410 in a liquid, especially in a liquid film. If the temperature of the liquid film increases, Brownian motion intensifies, and if the viscosity of the liquid decreases, Brownian motion still intensifies. Therefore, the liquid film is heated through the solid plate 401 with the low-tension liquid conveying system, which intensifies the Brownian motion of the particles 410 and pollutants, and prevents more particles 410 and pollutants from attaching to the surface of the substrate 404. In addition, by installing a megasonic wave transducer on the solid plate 401 to apply megasonic wave energy to the liquid film, the removal of microscopic high-speed flow fields caused by the sonic wave energy may reattach particles 410 and contaminants to the surface of the substrate 404.

如圖9所示為用於清洗和乾燥積體電路基板的裝置的另一個具體實施方式。裝置包括放置並支撐基板504的卡盤503,卡盤503與驅動單元505連接,驅動單元505可以是,例如馬達,驅動單元505驅動卡盤503旋轉,基板504隨卡盤503一起旋轉。固體板501位於基板504的上方。第一噴嘴507設置在固體板501的端部以向基板504的表面噴灑去離子水。第二噴嘴506設置在固體板501的端部並靠近第一噴嘴507,且第二噴嘴506比第一噴嘴507更靠近固體板501的末端,第二噴嘴506向基板504的表面噴灑低張力液體。活動臂502位於基板504的上方並與固體板501的端部相對以供應氮氣。此外,裝置還包括設置在固體板501上的溫度控制裝置511,溫度控制裝置511 上塗有PEEK,溫度控制裝置511為多個電阻加熱塊或多個輻射加熱燈。在清洗和乾燥基板504的工藝過程中,透過固體板501提供熱能,加劇小顆粒和污染物的布朗運動,阻止更多顆粒和污染物附著到基板504的表面。透過使用溫度控制裝置511,基板504表面的低張力液體的溫度根據工藝要求被保持在一個特定的範圍。裝置在不降低工藝性能的情況下能夠提高加工能力。裝置還包括設置在固體板501上的兆聲波換能器,兆聲波換能器向液膜提供兆聲波能量,在被限制的液膜中產生空化微流,阻止小顆粒和污染物在清洗和乾燥過程中重新吸附到基板504的表面。 As shown in FIG. 9, another embodiment of an apparatus for cleaning and drying an integrated circuit substrate is shown. The device includes a chuck 503 on which the substrate 504 is placed and supported. The chuck 503 is connected to a driving unit 505. The driving unit 505 may be, for example, a motor. The driving unit 505 drives the chuck 503 to rotate, and the substrate 504 rotates with the chuck 503. The solid plate 501 is located above the substrate 504. The first nozzle 507 is provided at an end of the solid plate 501 to spray deionized water on the surface of the substrate 504. The second nozzle 506 is disposed at the end of the solid plate 501 and is close to the first nozzle 507. The second nozzle 506 is closer to the end of the solid plate 501 than the first nozzle 507. The second nozzle 506 sprays a low-tension liquid onto the surface of the substrate . The movable arm 502 is located above the base plate 504 and is opposed to the end of the solid plate 501 to supply nitrogen. In addition, the device also includes a temperature control device 511, a temperature control device 511 provided on the solid plate 501 It is coated with PEEK, and the temperature control device 511 is a plurality of resistance heating blocks or a plurality of radiant heating lamps. During the process of cleaning and drying the substrate 504, thermal energy is provided through the solid plate 501, intensifying the Brownian motion of small particles and contaminants, preventing more particles and contaminants from attaching to the surface of the substrate 504. By using the temperature control device 511, the temperature of the low-tension liquid on the surface of the substrate 504 is maintained in a specific range according to process requirements. The device can improve the processing capacity without reducing the process performance. The device also includes a megasonic transducer provided on the solid plate 501. The megasonic transducer provides megasonic energy to the liquid film, generates cavitation microflow in the confined liquid film, and prevents small particles and pollutants from cleaning. And re-adsorbed to the surface of the substrate 504 during the drying process.

如圖10A-10B所示為用於清洗和乾燥積體電路基板的裝置的另一個具體實施方式的示意圖和俯視圖。裝置包括放置並支撐基板604的卡盤603,卡盤603與驅動單元605連接,驅動單元605可以是,例如馬達,驅動單元605驅動卡盤603旋轉,基板604隨卡盤603一起旋轉。裝置還包括固體板601,固體板601為矩形並覆蓋大部分基板604。第一噴嘴607和第二噴嘴606分別固定在固體板601的中心。活動臂602位於基板604的上方用來供應氮氣。與圖1A所示的裝置相比,固體板601的水平移動速度增大。 10A-10B are schematic diagrams and top views of another embodiment of a device for cleaning and drying an integrated circuit substrate. The device includes a chuck 603 on which the substrate 604 is placed and supported. The chuck 603 is connected to a driving unit 605. The driving unit 605 may be, for example, a motor. The driving unit 605 drives the chuck 603 to rotate, and the substrate 604 rotates with the chuck 603. The device also includes a solid plate 601 which is rectangular and covers most of the substrate 604. The first nozzle 607 and the second nozzle 606 are fixed at the center of the solid plate 601, respectively. The movable arm 602 is located above the substrate 604 for supplying nitrogen. Compared with the device shown in FIG. 1A, the horizontal moving speed of the solid plate 601 is increased.

如圖11A-11B所示為用於清洗和乾燥積體電路基板的裝置的又一個具體實施方式,與圖1A所示的裝置相比,其區別在於本實施例中的裝置的第一噴嘴707設置在固體板701的端部,第二噴嘴706設置在固體板701的斜邊上,且第二噴嘴706可以沿著固體板701的斜邊移動。 去離子水清洗工藝完成後,不論固體板701是否向基板704外側移動,第二噴嘴706向基板704噴灑低張力液體並沿著固體板701的斜邊移動。第二噴嘴706可以沿著固體板701的斜邊往復運動。在噴灑低張力液體的過程中,當基板704旋轉時,移動第二噴嘴706可以保持低張力液膜連續覆蓋在基板704上。圖11B所示為乾燥過程中固體板701向基板704外側移動的狀態。在這一工藝期間,當第二噴嘴706噴灑低張力液體時,第二噴嘴706可以沿著固體板701的斜邊往復運動,低張力液體連續覆蓋基板704,以避免浮水印和污染物的問題。 11A-11B show another specific embodiment of a device for cleaning and drying an integrated circuit substrate. Compared with the device shown in FIG. 1A, the difference lies in the first nozzle 707 of the device in this embodiment. The second nozzle 706 is disposed on an oblique side of the solid plate 701, and the second nozzle 706 can be moved along the oblique side of the solid plate 701. After the deionized water cleaning process is completed, regardless of whether the solid plate 701 moves outside the substrate 704, the second nozzle 706 sprays a low tension liquid on the substrate 704 and moves along the oblique side of the solid plate 701. The second nozzle 706 can reciprocate along the hypotenuse of the solid plate 701. During the process of spraying the low tension liquid, when the substrate 704 is rotated, moving the second nozzle 706 can keep the low tension liquid film continuously covering the substrate 704. FIG. 11B shows a state where the solid plate 701 is moved outside the substrate 704 during the drying process. During this process, when the second nozzle 706 sprays a low tension liquid, the second nozzle 706 can reciprocate along the hypotenuse of the solid plate 701, and the low tension liquid continuously covers the substrate 704 to avoid problems with watermarks and contaminants. .

圖12A-12F是本發明的固體板的各種形狀。固體板的形狀可以從以下選擇:如圖12A所示的六邊形、如圖12B所示的覆蓋整個基板的圓形、如圖12C所示的覆蓋部分基板的四分之三圓形、如圖12D所示的同心圓、三角形、如圖12E所示的覆蓋一半基板的半圓形、如圖12F所示的橢圓形等。 12A-12F are various shapes of the solid plate of the present invention. The shape of the solid board can be selected from the following: a hexagon as shown in FIG. 12A, a circle covering the entire substrate as shown in FIG. 12B, a three-quarter circle as shown in FIG. 12C covering a part of the substrate, such as Concentric circles, triangles shown in FIG. 12D, semicircles covering half of the substrate as shown in FIG. 12E, oval shapes as shown in FIG. 12F, and the like.

本發明不僅可以應用於半導體工業,還可以應用於其他需要被處理的物件,如太陽能電池基板和LCD基板等。 The invention can be applied not only to the semiconductor industry, but also to other objects that need to be processed, such as solar cell substrates and LCD substrates.

以上描述是為了說明和描述本發明,並沒有詳盡的揭露或限制本發明,儘管本發明以特定的實施方式、舉例、應用來說明,本領域內顯而易見的改動和替換將依舊落入本發明的保護範圍。 The above description is intended to illustrate and describe the present invention, and does not disclose or limit the present invention in detail. Although the present invention is described with specific embodiments, examples, and applications, obvious modifications and substitutions in the art will still fall into the present invention. protected range.

101‧‧‧固體板 101‧‧‧Solid board

102‧‧‧活動臂 102‧‧‧ Mobile arm

103‧‧‧卡盤 103‧‧‧chuck

104‧‧‧基板 104‧‧‧ substrate

105‧‧‧驅動單元 105‧‧‧Drive unit

106‧‧‧第二噴嘴 106‧‧‧Second Nozzle

107‧‧‧第一噴嘴 107‧‧‧first nozzle

Claims (26)

一種用於清洗和乾燥積體電路基板的方法,其特徵在於,包括:以第一轉速旋轉基板並移動固體板使固體板靠近基板,固體板的底面與基板的上表面之間具有間隙;向基板的上表面噴灑清洗液以形成清洗液膜,清洗液膜覆蓋基板的整個上表面;降低固體板並使固體板大體上平行於基板的上表面,固體板上至少有一個區域覆蓋基板的中心區域,液橋被限制在固體板的底面和基板的上表面之間;以第二轉速旋轉基板並向基板的上表面噴灑低張力液體;將固體板從基板的中心區域移動到基板的邊緣,在移動過程中,固體板大體上平行於基板的上表面,將活動臂移動到基板上方的位置以向基板上表面供應乾燥氣體。 A method for cleaning and drying an integrated circuit substrate, comprising: rotating the substrate at a first rotation speed and moving the solid plate to bring the solid plate closer to the substrate, with a gap between the bottom surface of the solid plate and the upper surface of the substrate; The upper surface of the substrate is sprayed with a cleaning solution to form a cleaning liquid film, which covers the entire upper surface of the substrate; lower the solid plate and make the solid plate substantially parallel to the upper surface of the substrate. At least one area of the solid plate covers the center of the substrate Area, the liquid bridge is confined between the bottom surface of the solid plate and the upper surface of the substrate; the substrate is rotated at a second speed and a low tension liquid is sprayed on the upper surface of the substrate; the solid plate is moved from the center area of the substrate to the edge of the substrate, During the moving process, the solid plate is substantially parallel to the upper surface of the substrate, and the movable arm is moved to a position above the substrate to supply dry gas to the upper surface of the substrate. 根據請求項1所述的方法,其特徵在於,清洗液為去離子水或含臭氧的去離子水。 The method according to claim 1, wherein the cleaning liquid is deionized water or ozone-containing deionized water. 根據請求項1所述的方法,其特徵在於,低張力液體的表面張力低於清洗液的表面張力。 The method according to claim 1, wherein the surface tension of the low-tension liquid is lower than the surface tension of the cleaning liquid. 根據請求項3所述的方法,其特徵在於,低張力液體是以下任意一種:乙醇、IPA、丙酮、乙酸乙酯或者是乙醇、IPA、丙酮、乙酸乙酯的蒸汽形態。 The method according to claim 3, wherein the low-tension liquid is any one of the following: ethanol, IPA, acetone, ethyl acetate, or a vapor form of ethanol, IPA, acetone, or ethyl acetate. 根據請求項1所述的方法,其特徵在於,第一轉速低於第二轉速。 The method according to claim 1, wherein the first rotation speed is lower than the second rotation speed. 根據請求項1所述的方法,其特徵在於,當固體板即將離開基板時,將活動臂移動到基板的中心,然後開始做基板中心到基板邊緣的往復運動。 The method according to claim 1, characterized in that when the solid plate is about to leave the substrate, the movable arm is moved to the center of the substrate, and then the reciprocating motion of the center of the substrate to the edge of the substrate is started. 根據請求項1所述的方法,其特徵在於,當固體板離開基板後,將活動臂移動到基板的中心,然後開始做基板中心到基板邊緣的往復運動。 The method according to claim 1, characterized in that when the solid plate leaves the substrate, the movable arm is moved to the center of the substrate, and then the reciprocating motion of the center of the substrate to the edge of the substrate is started. 根據請求項1所述的方法,其特徵在於,進一步包括加熱限制在固體板的底面和基板的上表面之間的液橋。 The method according to claim 1, further comprising heating a liquid bridge confined between a bottom surface of the solid plate and an upper surface of the substrate. 根據請求項1所述的方法,其特徵在於,進一步包括向限制在固體板的底面和基板的上表面之間的液橋提供聲能。 The method according to claim 1, further comprising providing acoustic energy to a liquid bridge confined between a bottom surface of the solid plate and an upper surface of the substrate. 根據請求項1所述的方法,其特徵在於,當向基板的上表面噴灑低張力液體時,停止噴灑清洗液。 The method according to claim 1, wherein when the low tension liquid is sprayed onto the upper surface of the substrate, the spraying of the cleaning liquid is stopped. 根據請求項1所述的方法,其特徵在於,乾燥氣體為以下任意一種:空氣、氮氣或氬氣。 The method according to claim 1, wherein the dry gas is any one of the following: air, nitrogen, or argon. 一種用於清洗和乾燥積體電路基板的裝置,其特徵在於,包括:放置並支撐基板的卡盤; 與卡盤相連的驅動單元,該驅動單元驅動卡盤旋轉;位於基板上方的固體板;設置在固體板上的第一噴嘴,該第一噴嘴向基板表面噴灑清洗液;設置在固體板上的第二噴嘴,該第二噴嘴向基板表面噴灑低張力液體;位於基板上方的活動臂,該活動臂向基板表面供應乾燥氣體。 A device for cleaning and drying an integrated circuit substrate, comprising: a chuck for placing and supporting the substrate; A drive unit connected to the chuck, the drive unit drives the chuck to rotate; a solid plate located above the substrate; a first nozzle provided on the solid plate, the first nozzle sprays a cleaning liquid on the surface of the substrate; A second nozzle that sprays a low tension liquid onto the surface of the substrate; a movable arm located above the substrate, the movable arm supplying dry gas to the surface of the substrate. 根據請求項12所述的裝置,其特徵在於,進一步包括設置在固體板上的溫度控制裝置。 The device according to claim 12, further comprising a temperature control device provided on the solid plate. 根據請求項13所述的裝置,其特徵在於,溫度控制裝置包括多個電阻加熱塊。 The device according to claim 13, wherein the temperature control device includes a plurality of resistance heating blocks. 根據請求項13所述的裝置,其特徵在於,溫度控制裝置包括多個輻射加熱燈。 The device according to claim 13, wherein the temperature control device includes a plurality of radiant heating lamps. 根據請求項12所述的裝置,其特徵在於,進一步包括設置在固體板上的聲換能器。 The device according to claim 12, further comprising an acoustic transducer provided on a solid plate. 根據請求項12所述的裝置,其特徵在於,第二噴嘴設置在固體板的斜邊上,且第二噴嘴可以沿著固體板的斜邊移動。 The device according to claim 12, wherein the second nozzle is disposed on a hypotenuse of the solid plate, and the second nozzle is movable along the hypotenuse of the solid plate. 根據請求項17所述的裝置,其特徵在於,第二噴嘴可以沿固體板的斜邊往復運動。 The device according to claim 17, wherein the second nozzle can reciprocate along a beveled edge of the solid plate. 根據請求項12所述的裝置,其特徵在於,固體板的形狀可以是以下任意一種:三角形、矩形、六邊形、圓形、四分之三圓形、同心圓、半圓形和橢圓形。 The device according to claim 12, wherein the shape of the solid plate can be any of the following: triangle, rectangle, hexagon, circle, three-quarters circle, concentric circle, semicircle, and oval . 根據請求項12所述的裝置,其特徵在於,驅動單元驅動卡盤朝順時針方向旋轉、逆時針方向旋轉或順時針、逆時針方向交替旋轉。 The device according to claim 12, wherein the drive unit drives the chuck to rotate in a clockwise direction, a counterclockwise direction, or an alternate rotation in a clockwise or counterclockwise direction. 根據請求項12所述的裝置,其特徵在於,固體板的底面由以下任意一種材料製成:藍寶石玻璃、石英、不銹鋼或陽極氧化鋁。 The device according to claim 12, wherein the bottom surface of the solid plate is made of any one of the following materials: sapphire glass, quartz, stainless steel, or anodized aluminum. 根據請求項12所述的裝置,其特徵在於,固體板的底面由以下任意一種可濕性陶瓷材料製成:三氧化二鋁或二氧化矽。 The device according to claim 12, characterized in that the bottom surface of the solid plate is made of any one of the following wettable ceramic materials: aluminum oxide or silicon dioxide. 根據請求項12所述的裝置,其特徵在於,固體板的底面由以下任意一種惰性金屬或金屬合金塗層製成:鉑金、黃金、鈦或碳化鈦。 The device according to claim 12, characterized in that the bottom surface of the solid plate is made of any one of the following inert metal or metal alloy coatings: platinum, gold, titanium or titanium carbide. 根據請求項12所述的裝置,其特徵在於,固體板的底面由以下任意一種可濕性改性塑膠製成:PTFE、PVDF或PEEK。 The device according to claim 12, characterized in that the bottom surface of the solid plate is made of any one of the following wettable modified plastics: PTFE, PVDF or PEEK. 根據請求項12所述的裝置,其特徵在於,清洗液是去離子水或含臭氧的去離子水。 The device according to claim 12, wherein the cleaning liquid is deionized water or ozone-containing deionized water. 根據請求項12所述的裝置,其特徵在於,低張力液體為以下任意一種:乙醇、IPA、丙酮、乙酸乙酯或者是乙醇、IPA、丙酮、乙酸乙酯的蒸汽形態。 The device according to claim 12, wherein the low-tension liquid is any one of the following: ethanol, IPA, acetone, ethyl acetate, or a vapor form of ethanol, IPA, acetone, or ethyl acetate.
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CN108296204A (en) * 2018-01-29 2018-07-20 马奔腾 A kind of production of crude drugs processing Alternative pretreatment system
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CN108296204A (en) * 2018-01-29 2018-07-20 马奔腾 A kind of production of crude drugs processing Alternative pretreatment system
CN112397414A (en) * 2019-08-12 2021-02-23 南亚科技股份有限公司 Wafer cleaning device and operation method thereof
US11227778B2 (en) 2019-08-12 2022-01-18 Nanya Technology Corporation Wafer cleaning apparatus and operation method of the same
TWI756570B (en) * 2019-08-12 2022-03-01 南亞科技股份有限公司 Wafer cleaning apparatus and operation method of the same

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