TW201781B - - Google Patents

Download PDF

Info

Publication number
TW201781B
TW201781B TW080106587A TW80106587A TW201781B TW 201781 B TW201781 B TW 201781B TW 080106587 A TW080106587 A TW 080106587A TW 80106587 A TW80106587 A TW 80106587A TW 201781 B TW201781 B TW 201781B
Authority
TW
Taiwan
Prior art keywords
item
group
composition
patent application
pps
Prior art date
Application number
TW080106587A
Other languages
Chinese (zh)
Original Assignee
Toso Kk
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toso Kk filed Critical Toso Kk
Application granted granted Critical
Publication of TW201781B publication Critical patent/TW201781B/zh

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
    • C08L81/04—Polysulfides
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47C—CHAIRS; SOFAS; BEDS
    • A47C17/00—Sofas; Couches; Beds
    • A47C17/38—Wall beds

Landscapes

  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Nursing (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Epoxy Resins (AREA)
  • Mattresses And Other Support Structures For Chairs And Beds (AREA)
  • Invalid Beds And Related Equipment (AREA)

Description

經濟部中央標準局员工消资合作社印製 L01781 A 6 __B_6_ 五、發明説明（1) 本發明傈有關改良聚伸苯硫醚之耐衝性的樹脂組成物 Ο 聚伸苯硫醚（以下簡稱為PPS)僳可充分發揮其優 異之耐熱性、耐藥品性、做為電氣、電子機器零件、汽車 機器零件極受到瞩目者。又，可藉由射出成形、擠製成形 等成形為各種成形零件、薄膜、薄片、纖維等、被廣泛地 使用於要求耐熱性、耐藥品性之分野。 惟PPS卻具有展延性不佳、脆弱之極大缺點。 以往為改善P P S之耐衝擊性曾配合玻璃纖維等填充 材料，惟對要求柔軟性之用途、其改良仍不足。 又、曾有曹試與改性聚烯類共聚合物成為聚合物攙合 物者，例如特開昭58 — 1 54757號公報、特開昭 59 — 152953 號公報、特開昭 59 — 189166 號公報等。惟此等改性之聚烯類共聚物常常與PPS攙合 時會增加粘度，在射出成形時引起欠注（short shot)等 ,仍然無法獲得極佳之PPS成形品。 另一方面，其與聚伸烷二醇之聚合物混合髏（polymer alloy) 曾由本案申請人予以檢討已獲知對 PPS 之拉 伸伸長、成形加工性有所改良。惟此等混合體製品仍無法 成為耐衝擊性優之P P S成形品。 本發明僳為解決上述以往技術上之問題而為者，提供 對PPS之特徵不會有所影響，而成形加工性、耐衝擊性 、柔軟性被改良之PPS樹脂組成物者。 即，本發明僳有關對於100重量份（A) 70〜 太 /fiim + HKTiiismiCNS)甲 4 埒格（210x297公炒） -3 一 (請先閱讀背面之注意事項再填寫本頁) 裝< 訂 線- 〇176i Α6 Β6 五、發明説明（2 ) 99. 5重置％聚伸苯硫醚樹脂、（B) 30〜0. 5重 量％以一般式（I)及/或（I)所示聚伸烷二醇、 R 0 - R , -3~- X ] ( I ) 乂 X-〇-(- R 1—03~s~ER2—(0-R 1 ~m~3~— 0 - X ( Π ) (式中R係n=l時僳X、 η22時俗碩數2〜6之有機 基、Ri僳表示碩數2〜6之伸烷基、R2僳硪數1〜 24之有機基、X係表示含至少一個環氧基、酐基、羧基 、乙烯基之硪數1〜1◦的有機基或氫、m係5〜. 25000， η僳1〜10、 P僳2〜100之整數）之 A + Β合計量、 加入0. 5〜40重量份α -烯類與α, /3 —不飽和酸之 環氣丙酯所成烯条共聚物所成聚伸苯硫醚樹脂組成物者。 以下詳細說明本發明。 本發明中所用PPS傜含有70莫耳％以上，更佳僳 含9 0莫爾％以上之結合單位： (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局员工消费合作社印製Printed L01781 A 6 __B_6_ by the Employee Consumers Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention (1) The resin composition for improving the impact resistance of polyphenylene sulfide (polyphenylene sulfide) PPS) can make full use of its excellent heat resistance and chemical resistance, and it has attracted much attention as electrical, electronic equipment parts, and automobile equipment parts. In addition, it can be formed into various molded parts, films, sheets, fibers, etc. by injection molding, extrusion molding, etc., and is widely used in the division where heat resistance and chemical resistance are required. However, PPS has the great disadvantage of poor ductility and fragility. In the past, in order to improve the impact resistance of PPS, filler materials such as glass fiber have been used, but the application that requires flexibility is still insufficient for its improvement. Also, there have been those who had been Cao Shi and modified polyene copolymers into polymer admixtures, such as Japanese Patent Laid-Open No. 58-1 54757, Japanese Patent Laid-Open No. 59-152953, Japanese Patent Laid-Open No. 59-189166 Bulletin etc. However, these modified polyolefin copolymers often increase the viscosity when blended with PPS, causing short shots during injection molding, and still cannot obtain excellent PPS molded products. On the other hand, its polymer alloy with polyalkylene glycol has been reviewed by the applicant in this case and has been known to improve the tensile elongation and formability of PPS. However, these hybrid products still cannot be PPS molded products with excellent impact resistance. The present invention is intended to solve the above-mentioned problems in the prior art, and provides a PPS resin composition with improved moldability, impact resistance, and flexibility without affecting the characteristics of PPS. That is, the present invention relates to 100 parts by weight (A) 70 ~ Tai / fiim + HKTiiismiCNS) A 4 Si grid (210x297 male fried) -3 One (please read the precautions on the back before filling out this page) Line-〇176i Α6 Β6 V. Description of the invention (2) 99.5% reset polyphenylene sulfide resin, (B) 30 ~ 0.5% by weight as shown in general formula (I) and / or (I) Polyalkylene glycol, R 0-R, -3 ~-X] (I) XX-〇-(-R 1—03 ~ s ~ ER2— (0-R 1 ~ m ~ 3 ~ — 0-X (Π) (where R is n = l, when x = η22, it has an organic group of 2 ~ 6, Rix means an alkyl group with a master number of 2 ~ 6, and R2 has an organic group of 1 ~ 24. , X represents an organic group or hydrogen containing at least one epoxy group, anhydride group, carboxyl group, vinyl number 1 ~ 1◦, m system 5 ~. 25000, η 僳 1 ~ 10, P 僳 2 ~ 100 of Integer) The total amount of A + Β, adding 0.5 ~ 40 parts by weight of α-olefins and α, / 3-unsaturated acid of cyclic gas propyl ester to form a polystyrene sulfide resin The following is a detailed description of the present invention. The PPS used in the present invention contains 70 mol% or more, more preferably 90 mol% or more. Cooperative unit: (Please read the precautions on the back before filling out this page) Printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs

所示重覆單位之聚合物，還可以為以該重覆單位之30莫 爾％以下範圍含有具以下構造重覆單位之共聚物。 太Ziii »1 Η 宏拽谁（CNS)¥4規格（2】0乂297公分） -4 - ；01781 A 6 B 6 五、發明説明（3 )The polymer of the repeating unit shown may also be a copolymer containing repeating units having the following structure in the range of 30 mol% or less of the repeating unit. Too Ziii »1 Η Who pulls the macro (CNS) ¥ 4 specifications (2) 0 297 cm) -4-; 01781 A 6 B 6 V. Description of the invention (3)

(請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局员工消#合作社印製 上述P P S之製造方法可以採用使鹵素取代芳香族化 合物，例如使對二氣苯，在硫與碩酸鈉存在下聚合之方法 ,在極性溶劑中，於硫化納，硫化氫鈉及氫氧化鈉，或硫 化氫及氫氣化鈉、存在下，最好使用胺基烷羧酸鈉或有機 羧酸驗金屬鹽為聚合助劑，使對二氣苯聚合之方法，使對 氯化硫酚自已聚縮合之方法等，惟其中以在N—甲基吡咯 烷酮、二甲基乙醛胺等醯胺溶劑或二甲亞碩、四氫睡吩等 碩条熔劑中，使硫化銷與對二氣苯反應之方法為最適宜。 此等方法已為公知者，被掲示於美國專利25131 88號公報、特公昭44 一 2767 1號公報、特公昭4 5—3368號公報、特公昭52—1224◦號公報、 特開昭61—225217號公報，美國專利32741 65號公報、_國專利1 1 60660號公報、特公昭4 6 — 2 7 2 5 5號公報及比利時專利2 9 4 3 7號公報等 線. 太κ /ίϊΛ 用 Ψ a S i：；tsm(CNSVP4i0格（210x297公贷） -5 - 經濟部中央標準局貝工消费合作杜印製 A 6 _____B6_ 五、發明説明（4) Ο 另外，PPS傑直鍵狀，分岐狀之任一均可，又，此 等構造之混合物亦可。 又，此等之熔融粘度傜使用高化式流動測儀（模頭： 内徑0· 5咖、長度2. 0_;負荷：10kg)，於 3〇〇t!測定之值為1 ◦泊〜1 00000泊，較佳像 50泊〜50000泊範圍。 又，為提高與本發明中所用乙烯單體之互溶性，亦可 導入高反應性之官能基於PPS中。導入之官能基以硫代 羥基、胺基、羧基、羥基、酐基、環氧基為宜若考慮烯糸 共聚物及聚伸烷二醇之反應性時，導入PPS之官能基係 以胺基、氫矽烷基為最適宜。 其導入方法可以採用使含有此等官能基之含鹵素芳香 族化合物共聚合之方法，或使PPS與含有官能基之低分 子化合物予以高分子反應以導入之方法等。 另外，上述PPS還可以為進行脱離子處理（酸沖洗 或熱水沖洗）以減低鈉離子者。 本發明中所用之聚伸烷二醇係一般式（I)或（I) 所示聚伸烷二醇。本發明中所用較佳之聚伸烷乙二醇傜式 中之R為具有環氧基、羧基或酐基之碩數1〜9之有機基 、Ri為碩數2〜4之伸烷基、R2為磺數1〜15之有 機基、X為具有環氧基、羧基或酐基之磺數1〜9之有機 基、m為10〜1 5000, η為1〜5、p為3〜50 之聚伸烷二醇。在此式中、R:、、X僳均列有有機 (請先閲讀背面之注意事項再填寫本頁) 經濟部屮央標準局貝工消費合作社印製 01761 A 6 ____B6_ 五、發明説明（5 ) 基，惟此有機基並不限定為烴基、邇包含在R、、X 中具有含醚、酮、醯胺、砚等雜原子之官能基者。又，式 中m像表示聚伸烷二醇序列之聚合度者、m為5以下時耐 熱性不佳、成形加工時會發生大量之氣饑，所以不宜。另 一方面，m為25000以上時，則會降低聚伸烷二醇與 P P S之互溶性。 上述聚伸烷二醇可為例如以下若干例、卽、可為聚乙 二醇、聚丙二醇、聚丁二醇、丙三醇、異戊四酵、花楸醇 等多元醇與伸烷氣化物之加成聚合物。 又，可以利用上述聚伸烷二酵之末端羥基的反應性、 導入環氣基或酐基於聚伸烷二醇。例如使環氣氯丙烷與其 反應而可得環氣改性之聚伸烷二酵、使苯三甲酸酐醛氯與 其反應而可得酐改性之聚伸烷二醇。 本發明較適宜被使用之聚伸烷二醇的具體例僳分子量 為300〜1000000者，可為末端官能基為羥基、 環《基、羧基或酐基之聚乙二醇或琴JT三雙。 本發明中所用烯条共聚物傜由α—烯類與α,点一不 飽和酸環氣丙酯所成共聚物。在此α—烯類像有例如乙烯 、丙烯、丁烯一 1等，以乙烯最適於使用。又，α, 不飽和酸環氧丙酯有例如丙烯酸環氧丙酯、甲基丙烯酸環 氧丙酯、乙基丙烯酸環氧丙酯等，尤其以甲基丙烯酸環氣 丙酯為宜。烯糸共聚物中之α , /3 -不飽和酸之環氣丙酯 的共聚合量僳1〜50重量％，尤以3〜30重量％為宜 ,1重量％以下時無法改良勒性、50重量％以上則其效 (請先閲讀背面之注意事項再填寫本頁) 裝- 訂- 線. 太Κ疳诎用Φ因囷宏戏进（〇把）屮4®格（210x297公 -7 - A 6 B6 經濟部中央標準局貝工消費合作杜印製 五、發明説明（6 ) 果不變反而增加成本。 又、烯糸共聚物中邐可以在4 0重量％以下，且在不 損及本發明目的之範圍内、共聚合可以共聚合之其他不飽 和單體，例如乙烯基醚、醋酸乙烯酯丙酸乙烯酯、丙烯酸 甲酯、甲基丙烯酸甲酯、丙烯晡、苯乙烯等。 本發明中P P S含量若為7 0重量％以下時會降低 PPS之耐熱性、耐藥品性、聚伸烷二醇含置若為0. 5 重量％以下時，無法抑制混合體之增粘、降低成形加工性 。又，對於100重量份PPS與聚伸烷二醇之合計置， 若烯条共聚物之含量為0. 5重量份時，則無法改善攙合 物之耐衝擊性，又、40重量％以上時則會降低難燃性。 另外，在本發明之PPS樹脂組成物中添加少量之其 他聚合物，亦可賦予其他物性。添加之聚合物可為例如烯 糸、苯乙烯糸、胺基甲酸乙酯糸、酯糸、氰糸、醛胺条、 丙烯酸糸等熱塑性彈料、聚丁二烯、聚異戊二烯、聚氛丁 二烯、聚丁烯、苯乙烯丁二烯橡膠及其氫化物、丙烯腈丁 二烯橡膠、乙烯丙烯共聚物、乙烯丙烯亞乙烯原冰片烯共 聚物等之橡膠成份，尼龍6、尼龍66、尼龍6 10、尼 龍12、尼龍1 1、尼龍46等聚醯胺条樹脂、聚對苯二 甲酸伸乙酯、聚對苯二甲酸伸丁酯、聚芳酯等聚酯糸樹脂 、聚苯乙烯、聚α-甲基苯乙烯、聚醋酸乙烯、聚氣化乙 烯、聚丙烯酸酯、聚甲基丙烯酸酯、聚丙烯腈、聚烯、聚 胺基甲酸乙酯、聚縮醛、聚苯醚、聚碩酸酯、聚硯、聚醚 破、聚芳硯、聚伸苯硫醚碩、聚醚酮、聚醚♦醚酮、聚伸 /ίίΛΐίΐΦ因困宏搮迆（0胳）¥4規格（210x297公- 8 - (請先閲讀背面之注意事項再填寫本頁) 裝· 訂· 線. 經濟部中央標準局员工消#合作社印製 01761 A 6 _B6_ 五、發明説明（7 ) 苯硫醚酮、聚醯胺醯亞胺、聚矽氣樹脂、苯氣樹脂、氟樹 脂及可形成向異性熔融相之可熔融加工的樹脂等單獨聚合 物、無規或塊狀、接枝共聚物及彼等混合物或其改性物等 Ο 還可以視其需要配合玻璃纖維、碩纖維、鋁氧纖維等 陶瓷纖維、芳醯胺纖維、全芳香族聚酯纖維、金屬纖維、 鈦酸鉀晶鬚等補強用填充劑或碩酸鈣、雲母、滑石、矽石 、硫酸鋇、硫酸鈣、高嶺土、粘土、葉蟠石、膨土、絹雲 母、沸石、霞石正長巖、美國活性白土（attapulsite)、 矽灰石、肥粒鐵、矽酸鈣、磺酸鎂、白雲石、三氧化銻、 氧化鋅、氧化鈦、氧化鎂、氧化鐵、二硫化鉬、石墨、石 膏、玻璃珠、玻璃粉末、玻璃球、石英、石英玻璃等無機 填充劑及有機、無機顔料。 玻璃纖維可為例如纖維長1. 5〜12imn、纗維口徑 3〜24«m之短切原絲，缕維徑3〜8之軟纖維、 3 2 5篩孔以下之玻璃鱗片或玻璃粉末。 又，可視其需要添加芳香族羥基衍生物等之可塑劑或 脱模劑、矽烷条、鈦酸酯条偶合劑、滑劑、耐熱安定剤、 耐候性安定劑、晶核劑、發泡劑、防銹劑、離子截留劑、 難燃劑、難燃助劑等。 欲得本發明之PPS樹脂組成物的方法，可以採用： (1) 以混合機混合各成份後，使用擠製機熔融混練 後使其成為錠片之方法。 (2) 加入其他成份於（1)方法所得錠片中，再次 太《•谌K/fiA用ΦΚ Η玄找迆甲4規祺mo 乂 297公货） ~ 9 ~ (請先閲讀背面之注意事項再塡寫本頁) 裝· 訂- 緣- ^01781 A 6 B6 經濟部屮央標準局员工消f合作社印製 五、發明説明（8 ) 熔融混練，使其成為錠片之方法。 (3)溶解各成份於溶劑中，加熱攪拌之方法，等。 又，在上述方法中還可以單獨或組合密閉混合機，揑 揉機、熱壓器等公知之機器予以使用。 本發明之PPS樹脂組成物可以藉由射出成形，薄Η 成形、真空成形、異形成形、發泡成形等加工作為各種成 形品。 以下藉由實施例具體說明本發明，惟本發明並不被此 等實施例所限定者。 又，PPS之熔融粘度係使用高化式流動測儀（模頭 :内徑0. 5咖、長度2. 0咖；荷重：10kg),於 3 0 0 t：測定。 參考例1 在裝備有攪拌機之15{内容積熱壓器中加入 5000gN —甲基一 2—吡咯烷酮（以下簡稱為NMP ),及 1898g (14. 8 莫耳）硫化鈉（Na2S· 2. 9H2〇)、昇溫至205t：，餾去420g水與5g NMP。繼而加入2132g (14. 5莫爾）對二氣苯 、於2501C反應3小時。反應完後，冷卻反應物至室溫 ，以離心分離機分離聚合物，二氯苯之轉化率僳98. 5 %。以溫水重覆沖洗聚合物：減壓下於1〇〇它乾燥一軎 夜，得熔融粘度為300泊的PPS。再於250*0,空 氣中硬化處理PPS5小時，藉此得到熔融粘度2000 太Λϋ ffl ΨΗ ® 定找迆（〇^)¥4相格（21(1x297公分） -1〇 - (請先閱讀背面之注意事項再填寫本頁) 裝· 線- 017B1 A 6 B6 經濟部屮央標準局员工消费合作社印製 五、發明説明（9 ) 泊之PPS。以所得之PPS做為PPS — I。 參考例2 代替參考例1之對二氣苯（14. 5莫爾）使用對二 氣苯（14. 35莫爾）、3，5 -二氣苯胺（◦. 15 某爾）以外，其他均與參考例1 一樣操作。聚合物之轉化 率僳94%,硬化前及硬化後之熔融粘度係分別為2 8 0 泊、2800泊。以如此所得之pps做為PPS — I。 參考例3 代替參考例2之3, 5 —二氣苯胺（〇. 15荑爾） ，使用2, 4 —二氯苯甲酸（0. 15莫爾）以外，其他 均與參考例2—樣操作。聚合物之轉化率僳96%,硬化 前及硬化後之熔融粘度僳分別為2 8 0泊、2 6 0 〇泊。 以如此所得之PPS做為PPS —皿。 參考例4 代替參考例2之3, 5 —二氣苯胺（〇. i 5莫爾） ，使用3, 5 —二胺基氯苯（◦. 15莫爾）以外，其他 均與參考例2—樣操作。聚合物之轉化率像95%,硬化 前及硬化後之熔融粘度僳分別為110泊、2800泊。 以如此所得之PP S做為00S— IV。 參考例5 (請先閱讀背面之注意事項再填寫本頁) 裝. 線- -11 - 經濟部屮央標準局员工消费合作杜印製 ^01761 A 6 -------B6_ 五、發明説明（10) 在裝備有攪拌機之1 5 j?内容積的熱壓器中，加入 5〇〇〇gNMP,及 1898g (14. 8 莫爾）硫化 鈉（Na2S.2. 9H2〇) , l800g 苯甲酸鈉及 48g氫氣化鈉，昇溫至2〇5它，餾去418g水；與 SgNMP。趙而加入2l32g (14. 5莫爾）對二 氣苯，於220¾反應2小時，繼而於2501C反應3小 時。反應完後冷卻反應物至室溫，以離心分離機分離聚合 物。二氣苯之轉化率係9 6. 0%。以溫水重覆沖洗聚合 物，減壓下於1001C乾燥一畫夜，將熔融粘度3400 冶之PPS。以如此所得之pps為PPS — V。 參考例6 於氮氣流下，使用可分燒瓶，於2 0 〇1〇加熱攪拌 2〇〇ga, ω —聚乙二醇二環氧丙酯（Epolite 400 E :共榮社油脂公司製、平均分子量400)及107g 雙酚A、經2小時。冷卻至室溫後，滴下多量之二乙醚、 除去過量之雙酚A後，減壓下於室溫放置一夜，予以乾擧 ，得到平均分子量1 200之末端含環氣基之聚乙二醇〔 -般式（I)之型態者〕，以此為PEG - V。 實施例1〜6、比較例1〜2 分別混合參考例1〜5所得P P S與市販之聚乙二醇 (平均分子量40〇,稱為PEG— I) , α，ω —聚乙 二醇二環氧丙醋〔一般式（I)之型態者（Epolite 太蚯银/e磨iS用中囷κ :捃维听4採格公帑） ~ 12 ~ (請先閲讀背面之注意事項再填窝本頁) 裝< 訂' -線· mn(Please read the precautions on the back before filling this page.) The Ministry of Economic Affairs Central Standards Bureau employee Consumer # Cooperative prints the above PPS. The manufacturing method can use halogen to replace aromatic compounds, such as p-difluorobenzene, sulfur and acetic acid The polymerization method in the presence of sodium, in a polar solvent, in the presence of sodium sulfide, sodium hydrogen sulfide and sodium hydroxide, or hydrogen sulfide and sodium hydroxide, it is best to use sodium aminoalkanoate or organic carboxylic acid test metal Salt as a polymerization aid, a method for polymerizing p-dichlorobenzene, a method for self-polycondensing and condensing p-chlorothiophenol, etc., but in which N-methylpyrrolidone, dimethylacetaldehyde amine and other acetamide solvents or Among the master fluxes such as Jiayashuo and Tetrahydrobenzene, the method of reacting the sulfide pin with p-dichlorobenzene is the most suitable method. These methods are well known and are shown in US Patent No. 25131 88, Japanese Patent No. 44-2767 1, Japanese Patent No. 4-5368, Japanese Patent No. 52-1224, Japanese Patent No. 61-12 Gazette No. 225217, U.S. Patent No. 32741 65, Gazette Patent No. 1 1 60660 Gazette, Japanese Patent No. 4 6 — 2 7 2 5 5 Gazette and Belgian Patent No. 2 9 4 3 7 Gazette etc. for κ / ίϊΛ Ψ a S i :; tsm (CNSVP4i0 grid (210x297 public loan) -5-Printed A 6 _____B6_ by the Beigong Consumer Cooperation Bureau of the Central Standards Bureau of the Ministry of Economic Affairs V. Invention description (4) Ο In addition, PPS is straight-shaped and divided Any of the shapes can be used, and mixtures of these structures can also be used. Moreover, these melt viscosity 傜 use high-type flow tester (die head: inner diameter 0. 5 coffee, length 2. 0_; load: 10kg), the value measured at 30000t! Is 1 ◦ poise ~ 1 00000 poise, preferably like 50 poise ~ 50000 poise range. In addition, in order to improve the miscibility with the ethylene monomer used in the present invention, it can also be introduced Highly reactive functionalities are based on PPS. The introduced functional groups are thiol, amine, carboxyl, hydroxy, anhydride, ring In consideration of the reactivity of the ene copolymer and polyalkylene glycol, the functional group introduced into the PPS is most preferably an amine group or a hydrosilyl group. The introduction method can be such that the functional group contains these functional groups. The method of copolymerization of halogen aromatic compounds, or the method of introducing PPS with a low molecular compound containing functional groups by high molecular reaction for introduction, etc. In addition, the above PPS may also be subjected to deionization treatment (acid rinse or hot water rinse) to Sodium ions are reduced. The polyalkylene glycol used in the present invention is a polyalkylene glycol represented by general formula (I) or (I). The preferred polyalkylene glycol used in the present invention is R in the formula It is an organic group with an epoxy group, a carboxyl group or an anhydride group having a major number of 1 to 9, Ri is an alkylene group with a major number of 2 to 4, R2 is an organic group with a sulfonic number of 1 to 15, X is an epoxy group, Polyalkylene glycol having an sulfo number of 1 to 9 of the carboxyl group or anhydride group, m of 10 to 15,000, η of 1 to 5, and p of 3 to 50. In this formula, R :, X All are listed as organic (please read the precautions on the back before filling out this page) Printed by the Ministry of Economic Affairs, Bureau of Standards, Beigong Consumer Cooperative, 01762 A 6 ____B6_ Fifth, the description of the invention (5) group, but this organic group is not limited to a hydrocarbon group, a functional group containing heteroatoms such as ether, ketone, amide, ink, etc. contained in R, X. Also, the formula The medium m image indicates the degree of polymerization of the polyalkylene glycol sequence. When m is 5 or less, the heat resistance is not good, and a lot of gas will occur during molding, so it is not suitable. On the other hand, when m is 25000 or more, it will be Reduce the miscibility of polyalkylene glycol and PPS. The above polyalkylene glycol may be, for example, the following examples. It may be polyethylene glycol, polypropylene glycol, polytetramethylene glycol, glycerin, isopentaerythritol, sorbel, etc. Additive polymer. In addition, the reactivity of the terminal hydroxyl group of the polyalkylene diacid can be used to introduce a ring gas group or an anhydride based on polyalkylene glycol. For example, ring gas chloropropane can be reacted with it to obtain ring gas-modified polyalkylene diacid, and reaction with trimellitic anhydride aldehyde chloride can be used to obtain anhydride modified polyalkylene glycol. The specific examples of the polyalkylene glycol suitable for use in the present invention have a molecular weight of 300 to 1,000,000, and may be polyethylene glycol having a terminal functional group of a hydroxyl group, a cycloalkyl group, a carboxyl group or an anhydride group, or Qin JT tris. The olefin strip copolymer used in the present invention is composed of a copolymer of α-olefins and α, a point-unsaturated acid cyclic gas propyl ester. Here, α-olefins include, for example, ethylene, propylene, butene-1, etc., and ethylene is most suitable for use. The α, unsaturated acid glycidyl esters include, for example, glycidyl acrylate, epoxypropyl methacrylate, glycidyl ethacrylate, etc. Especially preferred is cyclopropyl methacrylate. The copolymerization amount of α, / 3 -unsaturated acid cyclic gas propyl ester in the eneshi copolymer is 1 to 50% by weight, especially 3 to 30% by weight. 50% by weight or more is effective (please read the precautions on the back before filling in this page). Packing-booking-line. 太 疳 薎 Equipped with Φ due to the great play (〇) 屮 4® grid (210x297 Gong-7 -A 6 B6 Printed by Beigong Consumer Cooperation of the Central Bureau of Standards of the Ministry of Economy V. Description of the invention (6) If it is not changed, it will increase the cost. In addition, the weight of the eneshi copolymer can be less than 40% by weight, without loss. Within the scope of the object of the present invention, other unsaturated monomers that can be copolymerized are copolymerized, such as vinyl ether, vinyl acetate, vinyl propionate, methyl acrylate, methyl methacrylate, propylene, styrene, etc. In the present invention, if the PPS content is 70% by weight or less, the heat resistance and chemical resistance of the PPS will be reduced, and if the polyalkylene glycol content is 0.5% by weight or less, the thickening and reduction of the mixture cannot be suppressed Moldability. For 100 parts by weight of PPS and polyalkylene glycol, the total When the content of the substance is 0.5 parts by weight, the impact resistance of the admixture cannot be improved, and when it is 40% by weight or more, the flame retardancy is reduced. In addition, a small amount of Other polymers can also be given other physical properties. The added polymers can be, for example, vinyl, styrene, urethane, ester, cyano, aldamine strip, acrylic, and other thermoplastic elastomers, polybutylene Copolymerization of diene, polyisoprene, polybutadiene, polybutene, styrene butadiene rubber and its hydride, acrylonitrile butadiene rubber, ethylene propylene copolymer, ethylene propylene vinylidene probornene Rubber components such as nylon 6, nylon 66, nylon 6 10, nylon 12, nylon 1 1, nylon 46 and other polyamide resins, polyethylene terephthalate, polybutylene terephthalate, Polyester resin such as polyarylate, polystyrene, polyα-methylstyrene, polyvinyl acetate, polygasified ethylene, polyacrylate, polymethacrylate, polyacrylonitrile, polyene, polyamine Ethyl formate, polyacetal, polyphenylene ether, polyester, poly Yan, Ether break, polyarylene ink, polyphenylene sulfide master, polyether ketone, polyether ether ketone, poly extrude / due to sleepy macro 搮 濤 (0) ¥ 4 specifications (210x297 public-8-(please read first (Notes on the back and then fill out this page) Installation · Order · Thread. Printed by the Central Bureau of Economic Affairs of the Ministry of Economic Affairs #Cooperative Co., Ltd. Printed 01761 A 6 _B6_ V. Description of the invention (7) Phenyl sulfide ketone, polyamidoamide imide, polyimide Silicone resins, benzene resins, fluororesins, melt-processable resins that can form an anisotropic melt phase, individual polymers, random or bulk, graft copolymers and their mixtures or their modifications, etc. According to their needs, it can be combined with ceramic fiber such as glass fiber, fiber, aluminum oxide fiber, aramid fiber, fully aromatic polyester fiber, metal fiber, potassium titanate whisker and other reinforcing fillers or calcium masterate, mica, Talc, silica, barium sulfate, calcium sulfate, kaolin, clay, cobblestone, bentonite, sericite, zeolite, nepheline syenite, attapulsite, wollastonite, ferrite, silicic acid Calcium, magnesium sulfonate, dolomite, antimony trioxide, zinc oxide, oxidation Inorganic fillers such as titanium, magnesium oxide, iron oxide, molybdenum disulfide, graphite, gypsum, glass beads, glass powder, glass balls, quartz, quartz glass, and organic and inorganic pigments. The glass fiber may be, for example, a fiber length of 1. 5 ~ 12imn, a chopped strand with a caliber of 3 ~ 24 «m, a soft fiber with a strand diameter of 3 ~ 8, a glass flake or glass powder with a mesh size of 325 or less. In addition, plasticizers or mold release agents such as aromatic hydroxy derivatives, silane strips, titanate strip coupling agents, slip agents, heat-resistant stabilizers, weather-resistant stabilizers, crystal nucleating agents, foaming agents, Rust inhibitor, ion trapping agent, flame retardant, flame retardant auxiliary, etc. To obtain the PPS resin composition of the present invention, the following methods can be used: (1) After mixing the components with a mixer, a method of melting and kneading with an extruder to make them into tablets. (2) Add other ingredients to the tablet obtained by (1), again too "• 谌 K / fiA for ΦΚ Η 玄 找 菤 甲 4 紀 琪 mo 係 297 public goods) ~ 9 ~ (please read the note on the back first Matters will be written on this page) Binding · Ordering-Fate-^ 01781 A 6 B6 Printed by the Employees' Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs V. Invention Instructions (8) Melting and mixing to make it a method of ingots. (3) The method of dissolving each component in the solvent, heating and stirring, etc. In addition, in the above method, well-known equipment such as a closed mixer, a kneader, and a hot press may be used alone or in combination. The PPS resin composition of the present invention can be used as various molded articles by injection molding, thin H molding, vacuum molding, deformed molding, foam molding, and the like. The present invention will be specifically described below by examples, but the present invention is not limited by these examples. In addition, the melt viscosity of PPS is measured using a high-flow meter (die: inner diameter 0.5 coffee, length 2.0 coffee; load: 10 kg) at 300 t. Reference Example 1 In a 15 {internal accumulator equipped with a stirrer, 5000gN-methyl-2-pyrrolidone (hereinafter abbreviated as NMP), and 1898g (14.8mol) sodium sulfide (Na2S · 2.9H2〇 ). Raise the temperature to 205t: Distill 420g of water and 5g of NMP. Then 2132g (14.5 mol) of p-difluorobenzene was added and reacted at 2501C for 3 hours. After the reaction was completed, the reaction was cooled to room temperature, and the polymer was separated by a centrifugal separator. The conversion rate of dichlorobenzene was 98.5%. The polymer was rinsed repeatedly with warm water: it was dried overnight at 100 under reduced pressure to obtain a PPS with a melt viscosity of 300 poises. Then harden the PPS in air at 250 * 0 for 5 hours, thereby obtaining a melt viscosity of 2000 Λϋ ffl ΨΗ ® fixed looking (〇 ^) ¥ 4 phase grid (21 (1x297 cm) -1〇- (please read the back Please pay attention to this page and then fill out this page) 装 · 线-017B1 A 6 B6 Printed by the Employee Consumer Cooperative of the Bureau of Standards of the Ministry of Economic Affairs V. Description of Invention (9) The PPS of the parking. Use the obtained PPS as the PPS — I. Reference example 2 Use p-difluorobenzene (14.35 mol) and 3,5-digas aniline (◦. 15 mol) instead of p-difluorobenzene (14. 5 mol) in Reference Example 1 for reference. The operation is the same as in Example 1. The conversion rate of the polymer is 94%. The melt viscosity before and after hardening is 2 800 poise and 2800 poise respectively. The pps thus obtained is used as PPS-I. Reference Example 3 replaces Reference Example 2 of 3, 5-difluoroaniline (0.15 mol), except for 2, 4-dichlorobenzoic acid (0.15 mol), the other operations are the same as in Reference Example 2. Conversion rate of polymer 96%, the melt viscosity before hardening and after hardening are 280 poise and 260 poise, respectively. The PPS thus obtained is used as a PPS plate. Reference Example 4 Generation Reference Example 2 No. 3, 5-difluoroaniline (〇. I 5 mol), except for using 3, 5-diaminochlorobenzene (◦. 15 mol), other operations are the same as in Reference Example 2. Polymerization The conversion rate of the material is like 95%. The melt viscosity before and after hardening is 110 poise and 2800 poise respectively. The PP S thus obtained is used as 00S- IV. Reference Example 5 (Please read the notes on the back before filling in This page) Installed. Line--11-Printed by the employee consumption cooperation of the Bureau of Standards of the Ministry of Economic Affairs ^ 01761 A 6 ------- B6_ V. Description of invention (10) 1 5 j equipped with a mixer? Into the internal volume of the autoclave, add 5000gNMP, and 1898g (14.8mol) sodium sulfide (Na2S.2. 9H2〇), 1800g sodium benzoate and 48g sodium hydride, warm it to 20.5 , 418g water was distilled off; and SgNMP. Zhao Er added 2l32g (14.5 mol) p-difluorobenzene, reacted at 220¾ for 2 hours, and then at 2501C for 3 hours. After the reaction was completed, the reaction was cooled to room temperature and centrifuged. The separator separates the polymer. The conversion rate of the two-gas benzene is 9 6.0%. The polymer is washed repeatedly with warm water, dried under reduced pressure at 1001C overnight, and the melt viscosity is 3400. PPS. The pps thus obtained is PPS-V. Reference Example 6 Under a nitrogen stream, a separable flask was used, and heated and stirred at 200 ° C in 200 ° C, ω—polyethylene glycol diglycidyl ester (Epolite 400 E: manufactured by Kyoeisha Oil & Fats Co., Ltd., with an average molecular weight of 400) and 107 g of bisphenol A for 2 hours. After cooling to room temperature, a large amount of diethyl ether was dropped, and excess bisphenol A was removed, and then left at room temperature under reduced pressure overnight, followed by dry lifting to obtain a polyethylene glycol having a ring gas group at the end with an average molecular weight of 1 200 [ -Those of general formula (I)], this is PEG-V. Examples 1 to 6 and Comparative Examples 1 to 2 The PPS obtained in Reference Examples 1 to 5 was mixed with commercially available polyethylene glycol (average molecular weight of 40 °, called PEG-1), α, ω-polyethylene glycol bicyclo Oxypropylene vinegar [General type (I) type (Epolite too earth silver / e-mill iS for the use of 囷: 揃 维 听 4 Caige public money) ~ 12 ~ (please read the precautions on the back before filling in Page) Install < Order '-Line · mn

丨17¾ 桃Ain年12月丨 17¾ Peach Ain December

告本Sue

五、發明説明（11 ) 10〇E :共榮社油脂製，平均分子量1〇〇,稱為 p E G ~ E ; Epolite 400E :共榮社油脂製，平均分 子量 4〇〇，簡稱 PEG— HI ; DENACOL EX- 8 6 1 長瀬 化成製，平均分子量1 000，簡稱PEG —IV)或 PEG — V之丙酮溶液，於1001C乾燥後，均勻地乾携 合市販之烯条共聚物（Bondfast住友化學公司製，如下式 )與第1表所示組成比。 (請先閲讀背面之注意事项再項寫t ch2Fifth, the description of the invention (11) 10〇E: Kyoeisha oil and fat, with an average molecular weight of 100, called p EG ~ E; Epolite 400E: Kyoyosha oil and fat, with an average molecular weight of 400, referred to as PEG-HI; DENACOL EX- 8 6 1 An acetone solution of Changsei Chemical Co., Ltd., with an average molecular weight of 1 000, referred to as PEG-IV) or PEG-V, dried at 1001C, and evenly carry and carry the commercially available olefin copolymer (manufactured by Bondfast Sumitomo Chemical Co., Ltd.) , The following formula) and the composition ratio shown in Table 1. (Please read the precautions on the back before writing t ch2

CH /a CH2 C ! ./b cooch2 ck - ch2 \〇/ 經 濟 部 中 央 標 準 貝 工 消 費 合 作 社 印 (式中R3表示氫或Ci 一 Ce之烷基，R4表示氫或 Cz —C：*之烷基，a : b之比例範圍為83 : 17至 9 9 . 8:0.2) 使用RAVOPLASTMILL (東洋精機公司製），於3〇〇 υ製錠試料後，用往復螺桿式注塑機（東芝公司製I S〜 50ΕΡ)，以料筒溫度2901C，模型溫度140¾得 到成形品。成形品之拉伸物性葆依ASTM D 6 3 8 , 懸臂樑式衝擊試驗傜依ASTM D256測定。試驗結 果示於第1表，另標示僅有PPS時之衝擊強度於第2表 訂- 蟓· it用中囿园家橒準（CNS)甲4规格（2]0 X 29T公兌） -13 - B •ο- ο t-iCH / a CH2 C! ./B cooch2 ck-ch2 \ 〇 / Printed by the Ministry of Economic Affairs Central Standard Beige Consumer Cooperative (where R3 represents hydrogen or Ci-Ce alkyl, R4 represents hydrogen or Cz —C: * alkane The ratio of a: b is 83:17 to 99.8: 0.2) Using RAVOPLASTMILL (manufactured by Toyo Seiki Co., Ltd.), after making an ingot sample at 300, a reciprocating screw injection molding machine (IS by Toshiba Corporation) ~ 50ΕΡ), with the barrel temperature 2901C, model temperature 140¾ to obtain molded products. The tensile properties of the molded product are determined in accordance with ASTM D 6 3 8 and the cantilever beam impact test in accordance with ASTM D256. The test results are shown in Table 1, and the impact strength when only PPS is marked is set in Table 2-貓 · it for Zhongyuanyuan Jiaju Standard (CNS) A 4 specifications (2) 0 X 29T public exchange -13 -B • ο- ο ti

66 AB 五、發明説明（1¾ 經濟部屮央標準局员工消費合作社印製 第1表 雛 PPS 議份） 勉份） (S*份） mmmmsi 附缺口 (kg * cm/cm) (泊） mm PPS — I 1900 A C·^ 600 PEG-IV 100 7 1900 mm2 PPS —I >r"' 1900 400 PEG-I 100 6 2200 PPS-I 1900 200 PEG - 皿 100 5 1900 smh V PPS — w ? · · 1900 » ； ·~·> 500 PEG-I 100 7 2300 SS&M5 PPS-V 1900 500 PEG-IV 100 14 2100 SSfe^l6 PPS-IV 1900 500 PEG-V 100 7 2400 t圆1 PPS-I 1900 600 — 7 (^»i) t，j2 PPS-I 1900 — PEG-IV 100 1> 1900 (請先閱讀背面之注意事項再塡寫本頁) 裝. 線· 14 -66 AB V. Description of the invention (1¾ The PPS proposal printed by the Consumer Cooperative of the Bureau of Standards and Economy of the Ministry of Economic Affairs, Table 1) Mian copy) (S * copy) mmmmsi with gap (kg * cm / cm) (poise) mm PPS — I 1900 AC · ^ 600 PEG-IV 100 7 1900 mm2 PPS —I > r " '1900 400 PEG-I 100 6 2200 PPS-I 1900 200 PEG-Dish 100 5 1900 smh V PPS — w? · 1900 »; ~ ≫ 500 PEG-I 100 7 2300 SS & M5 PPS-V 1900 500 PEG-IV 100 14 2100 SSfe ^ l6 PPS-IV 1900 500 PEG-V 100 7 2400 t round 1 PPS-I 1900 600 — 7 (^ »i) t, j2 PPS-I 1900 — PEG-IV 100 1 > 1900 (please read the precautions on the back before writing this page) Install. Line · 14-

OlVBi A# A6 B6 五、發明説明（13 ) 第2表 p p s 懸臂樑式衝擊強度 (kg ♦ cm /cm ) p p s - I 1 P P s - I 1 P p s - ® 1 P p s - IV 1 P P s - v 2 (請先閱讀背面之注意事項再填寫"K ) 裝· 訂· -泉. 經濟部中央標準局SK工消費合作社印製 〔發明之效果〕 如以上所述，藉由本發明可以得到在不降低PPS所 具有之其他物性之下、耐衝擊性、柔軟性被改良之PPS 樹脂組成物，其工業價值極高。 太紙張又度適用中31國家榫準（CNS)印4規格（210 X 297 i： ^ ) 15 81.9.25,000OlVBi A # A6 B6 5. Description of the invention (13) Table 2 pps Izod impact strength (kg ♦ cm / cm) pps-I 1 PP s-I 1 P ps-® 1 P ps-IV 1 PP s-v 2 (Please read the precautions on the back before filling in " K) Binding, Ordering,-Izumi. Printed by the SK Industrial and Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs [Effect of Invention] As described above, the invention can be used in The PPS resin composition with improved impact resistance and flexibility under the other physical properties of PPS has extremely high industrial value. Too much paper is also suitable for the 31 National Tenon Standard (CNS) printed 4 specifications (210 X 297 i: ^) 15 81.9.25,000

Claims (1)

A7 37 C7 D7 六、申請專利範園 (請先閲讀背面之注*事項再填寫. H丨午^第8〇1〇6578號專利申請案 中文申諳專利範圍修正本 民國81年12月修正 1 .—種聚伸苯硫醚樹脂組成物，其特歡為對於 100重量份由（A) 70〜99. 5重量％之溶融粘度 1 800 — 3600泊、且含有70莫爾％以上以下式 'TV〇}~s7 ， 所示重覆單位之聚伸苯硫醚樹脂、（B) 30〜0. 5重 量％以一般式（I)及/或（I)所示聚伸烷二醇、 •TI. R 0 - R【兮一^ -X ] η ·( I ) ίΠ π χ - ο-γ- r , — ο -v- [ r 2 ο - i?, -y m ] , ο - χ ( π ) 經濟部中央#準局tw工消费合作社印製 (式中R#n=l時僳X、η22時僳硪數2〜6之有機 基、Ri傈表示磺數2〜6之伸烷基、R2傜碩數1〜 1 5之有機基、X葆表示含至少一痼環氧基、、乙烯基之 碩數1〜6的有機基或氫、m僳5〜30、η镍1〜1.0 、Ρ^2〜5之整數）所成之Α+Β合計量、 加入◦. 5〜40重量份α-烯類與α,々一不飽和酸之 環氣丙酯所成烯条共聚物所成。 2·如申請專利範圍第1項之組成物，其中聚伸苯硫 本纸張尺茂適用中國國家橒準（CNS)甲4規格（210 X 297公笼） -1 - 81.9.10,000 ；0178i A7 B7 C7 D7 六、申請專利範团 _樹脂（A)為含有30莫爾％以下選自下示 Q rsT n〇r C Η 3 \ Γ' ' ·—» • 3 一 Γ-汉 r-' τ r U π C Η ί -靖先閱#背面之注意事喟再嶙寫夂 ) 經濟部中央標準48工消費合作社印製 所成群之其他重覆單位。 3. 如申請專利範圍第工 ，其中聚伸苯硫醚樹脂（Α) 1 000◦◦泊之熔融粘度者 4. 如申請專利範圍第1 聚伸苯硫醚樹脂（Α)為導入 改性為提高聚伸烷二醇（Β) 5. 如申請專利範圍第4 能基為硫醇基、胺基、羧基、 6. 如申請專利範圍第1 一種或一種以上R、R2及父 代者。 7. 如申請專利範圍第1 聚伸烷二醇（B)為伸烷基氧 8. 如申請專利範圍第7 項或第2項之任一項组成物 為包含在301C下為1〇〜 0 項或第2項之組成物，其中 高反應性官能基於其中，被 及烯条共聚物之互溶性者。 項之組成物，其中被導入官 羥基、酐基或環氣基。 項或第2項之組成物，其中 為以含雜原子之官能基所取 項或第2項之組成物，其中 化物與聚醇之加成聚合物。 項之組成物，其中聚醇為選 -—裝. 訂- .線. 本纸張尺茂通用t國國家櫺準（CNS)甲4规格（210 X 297公笼） ~ 2 - 81.9.10,000 A7 B7 C7 D7 六、申請專利範園 自聚乙二醇、聚丙二醇、聚丁二醇、丙三醇、異戊四醇及 花揪醇所成群者。 9. 如申請專利範圍第1項或第2項之組成物，其中 烯類共聚物為由乙烯、丙烯或丁烯一1所組成者。 10. 如申請專利範圍第1項或第2項之組成物，其 中烯類共聚物為與1〜5 0重量％選自丙烯酸環氣丙酯、 甲基丙烯酸環氧丙酯及乙基丙烯酸環氧丙酯之α, Θ_不 飽和酸環氣丙酯所共聚合之α —烯類所成。 1 1 .如申請專利範圍第1項或第2項之組成物，其 中烯類共聚物為含有選自乙烯基醚、醋酸乙烯、丙酸乙烯 、丙烯酸甲酯、甲基丙烯酸甲酯、丙烯睛或苯乙烯之可共 聚單體者。 (請先閲嘴背面之注意事項再填寫丸 -裝. .可 .線. 經濟部中央標準局®:工消費合作社印製 本紙張又度適用中國國家標準（CNS〉甲4規格（210 X 297公蹵） -3 — 81.9.10,000A7 37 C7 D7 VI. Applying for a patent fan garden (please read the notes on the back * and then fill in. H 丨 Wu ^ No. 8〇1〇6578 Patent application Chinese application of the patent scope amendments Dec. 81, Amendment 1 .- A polyphenylene sulfide resin composition, the special joy is for 100 parts by weight of (A) 70 ~ 99. 5 wt% melt viscosity 1 800-3600 poise, and contains 70 mol% or more of the following formula ' TV〇} ~ s7, the repeating unit of polyphenylene sulfide resin shown, (B) 30 ~ 0.5 wt% in the general formula (I) and / or (I) shown in the polyalkylene glycol, • TI. R 0-R 【兮 一 ^ -X] η · (I) ίΠ π χ-ο-γ- r, — ο -v- [r 2 ο-i ?, -ym], ο-χ (π ) Printed by the Central Bureau of the Ministry of Economic Affairs, quasi-bureau tw industrial and consumer cooperatives (where R # n = l when x is x, η 22 is when the organic group of 2 to 6 is ribbed, Ri is the alkyl group of 2 to 6 sulfide, R2, an organic group of 1 ~ 15, XBau means an organic group containing at least one epoxy group, a vinyl group of 1 ~ 6, or hydrogen, m5 ~ 30, η nickel 1 ~ 1.0, Ρ ^ 2 ~ 5 integer) the total amount of Α + Β, added ◦. 5 ~ 40 parts by weight α-enes α, 々Unsaturated acid cyclic gas propyl ester formed of olefin copolymer. 2 · As for the composition of item 1 of the patent application scope, the polyphenylene sulfide paper ruler is applicable to the Chinese national standard ( CNS) A4 specifications (210 X 297 male cage) -1-81.9.10,000; 0178i A7 B7 C7 D7 VI. Patent application model group_Resin (A) contains 30 mol% or less selected from the following Q rsT n〇 r C Η 3 \ Γ '' · — »• 3 一 Γ- 汉 r- 'τ r U π C Η ί-靖 先 读 # Remarks on the back Print other repeating units in groups. 3. If it is the first in the patent application scope, where the polyphenylene sulfide resin (Α) has a melt viscosity of 1 000 ◦. 4. If the patent application is the first polyphenylene sulfide resin (Α) is introduced into the modified Raise polyalkylene glycol (B) 5. If the fourth energy group in the patent scope is thiol group, amine group, carboxyl group, 6. If the first one or more R, R2 and parent in the patent scope. 7. If the patent application scope is the first polyalkylene glycol (B) is alkylene oxide 8. If the patent application scope item 7 or 2 of any one of the composition is included in 301C is 10 ~ 0 Item or the composition of item 2, wherein the highly reactive functional group is based on the miscibility of the olefin copolymer. Item of the composition, into which the official hydroxyl group, anhydride group or ring gas group is introduced. Item or the composition of Item 2, wherein the composition of Item or Item 2 is a functional group containing a hetero atom, and the addition polymer of the compound and the polyalcohol. The composition of the item, of which the polyalcohol is optional-binding. Binding-. Line. The size of the paper is General National Standard (CNS) A 4 specifications (210 X 297 male cage) ~ 2-81.9.10,000 A7 B7 C7 D7 VI. Patent application Fanyuan is a group of polyethylene glycol, polypropylene glycol, polybutylene glycol, glycerol, isopentaerythritol and rowanol. 9. The composition of item 1 or item 2 of the patent application scope, in which the vinyl copolymer is composed of ethylene, propylene or butene-1. 10. The composition as claimed in item 1 or 2 of the patent application, wherein the olefinic copolymer is selected from 1 to 50% by weight selected from cyclopropyl acrylate, glycidyl methacrylate and ethyl acrylate It is made of α-olefins copolymerized with α, Θ_ unsaturated acid ring gas propyl ester of oxypropyl ester. 1 1. The composition as claimed in item 1 or item 2 of the patent application, wherein the olefinic copolymer is selected from vinyl ether, vinyl acetate, vinyl propionate, methyl acrylate, methyl methacrylate, acrylonitrile Or copolymerizable monomer of styrene. (Please read the precautions on the back of the mouth first and then fill in the pill-pack .. OK. Line. Central Bureau of Economic Affairs of the Ministry of Economic Affairs: The paper printed by the Industrial and Consumer Cooperative Society is again applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 Gong Zhe) -3 — 81.9.10,000
TW080106587A 1990-08-22 1991-08-19 TW201781B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2219053A JP3034569B2 (en) 1990-08-22 1990-08-22 Polyphenylene sulfide resin composition

Publications (1)

Publication Number Publication Date
TW201781B true TW201781B (en) 1993-03-11

Family

ID=16729529

Family Applications (1)

Application Number Title Priority Date Filing Date
TW080106587A TW201781B (en) 1990-08-22 1991-08-19

Country Status (3)

Country Link
JP (1) JP3034569B2 (en)
KR (1) KR930006148B1 (en)
TW (1) TW201781B (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE602005024250D1 (en) * 2004-04-28 2010-12-02 Furukawa Electric Co Ltd MULTILAYER INSULATED LINE AND TRANSFORMER THEREWITH

Also Published As

Publication number Publication date
KR920004513A (en) 1992-03-27
JP3034569B2 (en) 2000-04-17
KR930006148B1 (en) 1993-07-08
JPH04103660A (en) 1992-04-06

Similar Documents

Publication Publication Date Title
JP4269198B2 (en) Polyarylene sulfide resin composition
WO2012108412A1 (en) Thermoplastic resin, resin composition, and molding of high thermal conductivity
TW201781B (en)
JPH05502055A (en) Blend of carboxy-functionalized polyphenylene resin and ethylene-glycidyl methacrylate copolymer
JPS62149753A (en) Thermoplastic resin composition
JPH11124476A (en) Thermoplastic resin composition
JPH0232143A (en) Thermoplastic resin composition
JP3019107B2 (en) Polyphenylene sulfide resin composition
JPS61204270A (en) Thermoplastic resin composition
US7601782B2 (en) Composition of polyarylenesulfide, bisphenol epoxy resin and oxazoline-containing amorphous polymer
JPS6281444A (en) Thermoplastic resin composition
JPH03265661A (en) Flame-retardant resin composition
JPH03153757A (en) Polyphenylene sulfide resin composition
JPS636042A (en) Thermoplastic resin composition
JP3432906B2 (en) ABS resin composition with excellent antistatic properties
JP3109215B2 (en) Polyphenylene sulfide resin composition
JP2975406B2 (en) Polyphenylene sulfide resin composition
JP3109223B2 (en) Polyphenylene sulfide resin composition
JPH04246461A (en) Polyphenylene ether resin composition of excellent antistatic properties
JP3109201B2 (en) Polyphenylene sulfide resin composition
JPH0286652A (en) Thermoplastic resin composition
JP3034570B2 (en) Polyphenylene sulfide resin composition
JP3044316B2 (en) Polyphenylene sulfide resin composition
JPH0129222B2 (en)
JPH0324142A (en) Styrene resin composition