TW201732116A - Composition for fabric treatment - Google Patents

Abstract

The present invention relates to a composition for a fiber treatment and a method for producing the same and, more particularly, to a composition for a fiber treatment, comprising a cationic water-soluble polymer. The composition for a fiber treatment according to the present invention has excellent properties of suppressing laundry residue, preventing dye transfer and de-dyeing, or preventing dust adsorption.

Description

Fiber treatment composition

This application is based on Korean Patent Application No. 10-2016-0030913, which was filed on March 15, 2016, Korean Patent Application No. 10-2016-0030918, which was filed on March 15, 2016, and Korea, which was filed on December 21, 2015. Priority is claimed on Japanese Patent Application No. 10-2015-0182943, the entire disclosure of which is incorporated herein by reference.

The present invention relates to a fiber treatment composition, a method for producing a fiber treatment composition, and a fiber treatment product.

In general, fiber refers to an elongated linear structural unit constituting a living body tissue in the biological field, and is an elongated and soft object such as cotton or wool. There are dozens of types of fibers currently in use, classified according to chemical composition and physicochemical properties, and have different classifications depending on the times, countries, and scholars. For example, before the discovery of man-made fibers, they were classified into three types: plant fiber, animal fiber and mineral fiber, but after the man-made fiber was studied, it was classified into natural fiber and man-made fiber.

Natural fiber refers to a substance that can be directly used as a fiber in the form of fibers in nature, and a fiber obtained in a plant body such as flax is called a plant fiber. These fibers are all cellulose from the chemical point of view, so they are also called cellulose fibers.

Further, the fiber obtained from the animal body is called an animal fiber, and since the chemical component thereof is a protein, it is also called a protein fiber. Fibers can also be made from plant proteins. The properties of artificial protein fibers are closer to natural animal fibers than natural plant fibers because the properties of artificial protein fibers are not determined by the root cause of the plant or animal, but rather It is determined by whether the compound constituting the fiber is a cellulose system or a protein system.

In addition, regardless of whether the fibers are plant fibers or animal fibers, contamination may occur in human use, and washing is required at this time. When hand-washing or machine-washing, tens of thousands of washing residues remain on the fibers, that is, they remain on the clothes or bedding. In particular, the problem of residual white residue on the colored fibers is often found. When the lotion residue and fiber residue are intertwined on the clothes or bedding during the washing process, they will cause pilling, and the removal of the dye due to frequent repeated washing will accelerate the damage of the clothes or bedding. .

As a conventional anti-pilling technique, a quaternary ammonium type cationic surfactant, a polysiloxane, a starch or an acrylic polymer, a polyvinylpyrrolidone or the like is applied to clothes or bedding. A method of rubbing or inhibiting wear. However, this method has the concern of causing yellowing and does not achieve sufficient effects during the washing process. The conventional hair ball cleaning technique is a technique for hydrolyzing fibers by an enzyme. However, this technique is restricted by the temperature of the enzyme activity, and in addition to the inability to select a hydrolysis site, there is a problem that the fiber becomes thin. In addition, in the washing process, the technique of sufficiently dispersing the residue to prevent it from adhering again to the clothes or bedding articles and covering the clothes or bedding articles does not currently exist.

Therefore, in the current situation, it is necessary to develop a composition for fiber treatment which has an effect of removing the washing residue, an effect of preventing the removal of the dyeing, and an excellent effect of preventing the dust adsorption.

Problems to be solved by the invention

Therefore, an object of the present invention is to provide a fiber treatment composition which is excellent in the effect of suppressing the residue of washing residues, a method for producing the same, and a method for suppressing the residue of the washing residue by treating the composition.

Another object of the present invention is to provide a fiber treatment composition which is excellent in the effect of preventing the release of dyeing and a method for producing the same, or a method for preventing the fiber from being removed by treating the composition.

Another object of the present invention is to provide a fiber treatment composition excellent in the effect of preventing dust from adsorbing and a method for producing the same, or a method for preventing dust from adsorbing fibers by treating the above composition.

Technical solution to the problem

In order to achieve the above object, the present invention provides a fiber treating composition for suppressing the residue of a washing residue, wherein the water-soluble cationic polymer preferably contains water-soluble having a charge density of 0.1 to 25 meq/g. Cationic polymer.

Further, the fiber treatment composition according to the present invention may be a fiber treatment composition which suppresses the residue of the washing residue, prevents the dyeing, or prevents the dust from being adsorbed.

The "fiber treatment composition" of the present invention means a composition which is treated to contribute to improvement, relief, deterioration prevention, and the like of the fiber state, and the fiber includes natural fibers and/or rayon fibers.

Further, the present invention provides a product comprising the above fiber treatment composition, for example, a fiber lotion, a fiber softener, a fiber deodorant, a fiber fragrance, a fiber bleach, a fiber repair agent, a fiber pretreatment agent, a fiber. The post-treating agent, the fiber nutrient, the fiber serum, the fiber fixing agent, the fiber coloring agent or the fiber decoloring agent preferably provides a fiber softener or a fiber deodorant, and more preferably provides a fiber softener, but is not limited thereto.

An embodiment of the present invention utilizes a water-soluble cationic polymer to fundamentally solve the residual phenomenon of washing residue remaining on the laundry during washing or after washing, and to prevent the removal of dyeing and/or the prevention of dust adsorption. A fiber treatment composition excellent in effect.

In one embodiment of the present invention, the cationic polymer may be a polymer having a cationic quaternary ammonium, amine or imine group in the structure, or may be a polymerization of acrylamide and diallyldimethylammonium chloride. a quaternary ammonium product, dimethyldiallylammonium chloride alone or a polymer with acrylic acid, for example, selected from polydiallyldimethylammonium chloride (polyquaternium-6), Acrylamide-diallyldimethylammonium chloride (polyquaternium-7), polyvinylpyrrolidone (PVP)-dimethylaminoethyl methacrylate copolymer, polyvinylpyrrolidone (PVP)-methyl Dimethylaminoethyl acrylate (polyquaternium-11), acrylic acid-diallyldimethylammonium chloride (polyquaternium-22), acrylic acid-diallyldimethylammonium chloride-propylene Indoleamine polymer (polyquaternium-39), quaternized polyvinyl alcohol, cationic polyvinyl alcohol, cationic polyvinyl alcohol derivative, polyamine, polyethyleneimine, ethoxylated polyethyleneimine, poly Vinyl imidazole, polyquaternium-16 and polyquaternium-44 as copolymers of vinylpyrrolidone (VP) and vinylimidazole (QVI) (for example, Lu of BASF Corporation) Viquat Excellence, Luviquat UltraCare, SOKALAN HP 66K), chitosan, cationic cellulose derivatives, cationic starch derivatives, cationic guar derivatives, polyquaternium-51 (MPC constituent unit structure), acrylamide- Any one of a group consisting of dimethylaminoethyl methacrylate chloromethane polymer (polyquaternium-15) and a trimethylaminoethyl methacrylate polymer, or a mixture of two or more thereof or Copolymer. The above cationic guar gum derivative of the present invention may, for example, be a cationic guar derivative such as guar hydroxypropyltrimonium chloride or hydroxypropyl guar hydroxypropyltrimonium chloride. (eg, JAGUAR® C17). Further, the above cationic cellulose derivative of the present invention may, for example, be a polyquaternium-10, a polyquaternium-67 or a mixture thereof.

Preferably, the cationic polymer of the present invention may be selected from the group consisting of diallyldimethylammonium chloride and acrylamide, acrylic acid or poly-diallyldimethylammonium chloride polymerized separately (poly season) Ammonium salt-6), acrylamide-diallyldimethylammonium chloride (polyquaternium-7), polyquaternium-10, polyvinylpyrrolidone (PVP)-dimethylaminoethyl methacrylate Esters (polyquaternium-11), polyquaternium-16 and polyquaternium-44, polymers of vinylpyrrolidone (VP) and vinylimidazole (QVI), propylene-diallyldimethyl Ammonium chloride (polyquaternium-22), polyquaternium-39, polyquaternium-67, polyethyleneimine, ethoxylated polyethyleneimine, cationic polyvinyl alcohol, cationic starch derivatives, and Any one or a mixture or copolymer of two or more of the group consisting of cationic guar gum derivatives.

More preferably, the cationic polymer of the present invention may be selected from poly-diallyldimethylammonium chloride which is polymerized from diallyldimethylammonium chloride and acrylamide, acrylic acid, or separately. Polyquaternium-6), acrylamide-diallyldimethylammonium chloride (polyquaternium-7), polyvinylpyrrolidone (PVP)-dimethylaminoethyl methacrylate (polyquaternium) Salt-11), acrylate-diallyldimethylammonium chloride (polyquaternium-22), polyquaternium-16 as a polymer of vinylpyrrolidone (VP) and vinylimidazole (QVI) Any of the group consisting of polyquaternium-44, polyethyleneimine, ethoxylated polyethyleneimine, cationic cellulose derivative, cationic starch derivative, cationic guar derivative, and cationic polyvinyl alcohol One or two or more kinds of mixtures or copolymers.

In one embodiment of the present invention, the water-soluble cationic polymer has a charge density at pH 7 of about 0.1 to 25 meq/g, preferably about 0.5 to 20 meq/g, and more preferably about 1 to 10 meq/g. Most preferably it is about 5 to 8 meq/g. When the charge density is less than about 0.1 meq/g, the effect of suppressing the residue of the washing residue, preventing the removal of the dyeing or preventing the adsorption of dust, which is the object of the present invention, is lowered, and when the charge density is more than about 25 meq/g, There is a problem that stains are fixed on the fibers.

In one embodiment of the present invention, the content of the water-soluble cationic polymer may be from about 0.1 to 50% by weight, preferably from about 0.3 to 30% by weight, more preferably from about 0.5 to 20% by weight, based on the total weight of the composition. When the content of the water-soluble cationic polymer is less than 0.1% by weight, the effect of suppressing the residue of the washing residue, preventing the release of the dye or preventing the adsorption of dust, which is the object of the present experiment, is lowered, and if it exceeds 50% by weight, it is not economic.

Further, the fiber treatment composition according to an embodiment of the present invention may further contain a nonionic surfactant in addition to the cationic polymer.

The above nonionic surfactant may, for example, be hydrogenated castor oil, polyoxyethylene alkyl ether, cocodiethanolamine, fatty acid alkanolamine, amine oxide, alkyl polyglucoside, alkenyl group. Any one or more of the group consisting of alkenyl polyethylene alkyl ether and sugar ether, but is not limited thereto.

In one embodiment of the invention, the nonionic surfactant is present in an amount of from about 0.1% to about 80% by weight, based on the total weight of the composition, preferably from about 0.5% to about 40% by weight, more preferably from about 1% to about 20% by weight.

In the fiber treatment composition according to an embodiment of the present invention, the weight ratio of the water-soluble cationic polymer to the nonionic surfactant is from 0.1 to 20:1, preferably from 0.5 to 10:1, more preferably from 0.5 to 5:1. .

The use as the composition for fiber treatment of the present invention can be used for suppressing the residue of the washing residue, preventing the release of the dye or preventing the adsorption of dust. More specifically, it can be confirmed that the fiber treatment composition of the present invention has an excellent effect of suppressing the residue of the washing residue, preventing the release of the dye, or preventing the dust from being adsorbed, which is not contained in the conventional fiber treatment composition.

Therefore, the fiber treatment composition of the present invention can be provided as a fiber treatment composition for suppressing the residue of the washing residue, a fiber treatment composition for preventing the release of the dye, or a fiber treatment composition for preventing dust adsorption.

The above-mentioned washing residue is a general definition of the residue occurring in the washing water at the time of washing, and may include, for example, a detergent residue or a fiber residue generated from the laundry. In the case of the above-mentioned detergent, for example, a builder added to increase the detergency, an insoluble component of the lotion, a residue complexed with a lotion, a biofilm, a zeolite, and a carbonate may be contained. , phosphate, sulfate, etc.; the above-mentioned fibrous residue generated from the laundry, including all the residues of the fibers constituting the laundry. In addition, as the residue falling from the fiber, for example, it may include fiber dust, laundry dust, hair ball, dust, fine particles, dust in the air, pollen, fine dust, animal hair, fluff, hair, etc., but is not limited thereto. this. The fiber residue particles may have a diameter of about 1 to 50 μm, but are not limited thereto.

The above-mentioned prevention of transfer and dyeing is a term for preventing the transfer and decolorization of the dye of the laundry.

The dust includes all fine particles such as fine dust that can adhere to the laundry, but is not limited thereto. In the case of using the composition for fiber treatment of the present invention, it is possible to prevent dust from being adsorbed on the surface of the laundry.

In the present invention, the fiber treatment composition is not limited to the treatment form (treatment time, commonly used components, and the like, without impeding the effect of suppressing the residue of the washing residue, preventing the release of the dye or preventing the dust from being adsorbed. Dosage type, etc.). As an embodiment, the fiber treatment composition may be treated separately, sequentially or simultaneously with the common lotion, or separately, sequentially or simultaneously with the fiber softener after ordinary washing, or may be contained in a common lotion or fiber. Handling in a softener.

As confirmed by the examples of the present invention, the fiber treatment composition of the present invention has an intrinsic characteristic in addition to the effect of suppressing the residue of the washing residue, preventing the removal of the dye or preventing the adsorption of dust, for example, the case of the fiber softener. It is excellent in softness, fragrance and antistatic effect as a basic quality.

Further, in addition to the above-described components, other components may be added without affecting the object of the present invention.

Further, the fiber treatment composition of the present invention can be used as a liquid, a spray, a gel, a paste, a powder, a sheet, a film, a pellet, a granule or a granule. The method such as pastille is formulated, preferably by liquid or spray.

Further, the present invention provides a method for producing a composition for treating a fiber residue, preventing the removal of the residue or preventing the adsorption of dust, and comprising the step of adding a water-soluble cationic polymer.

The method for producing a fiber treatment composition of the present invention may further comprise the step of adding a nonionic surfactant.

The production of the above fiber treatment composition can be produced by a method generally used in the art.

Further, the present invention provides a method for suppressing residue of washing residue by treating the above composition with fibers; a method for preventing fiber removal by treating the above composition with fibers; or preventing dust by treating the above composition with fibers Adsorption method.

Effect of the invention

The fiber treatment composition of the present invention can exhibit an excellent effect of suppressing the residue of the washing residue, preventing the release of the dye, or preventing the adsorption of dust.

Hereinafter, in order to facilitate understanding of the present invention, examples and the like will be described in detail. However, the embodiments according to the present invention may be modified into other modes, and the scope of the present invention should not be construed as being limited to the following embodiments. The embodiments of the present invention are provided to more fully illustrate the present invention by those skilled in the art.

1. Manufacture of fiber treatment composition

In one embodiment of the present invention, a composition for fiber treatment was produced by the compositions shown in Tables 1 and 2 below.

More specifically, Comparative Example 1 is a general fiber softener composition, and as a main component of the cationic surfactant, a TEA Ester Quaternary (TEA Ester Quaternary) (TEA Ester quat, INCI name: dehydrogenated palm) was used. Dehydrogenated palmoylethyl hydroxyethylmonium methosulfate, active 90%). Comparative Example 2 is a fiber treatment composition containing citric acid and having a function of removing a detergent residue. Comparative Example 3 is a general fiber deodorant composition, Comparative Example 4 and Comparative Example 5 are deodorant, antistatic and anti-wrinkle spray compositions, TEA Ester quat and organic antimony are widely used in antistatic agents, and organic antimony is used. It is an emulsion type amino-modified organic hydrazine. As the deodorant, an extract containing polyphenols such as green tea or persimmon leaves, a cyclodextrin or the like is widely used, and a green tea extract is used here.

The water-soluble cationic high molecular compound used in the examples is as follows:

As a cationic polyvinyl alcohol (Cationic PVA), GOHSENX TM K of NIPPON GOHSEI was used; as an amphoteric modified starch, BASF Polyquart® Ecoclean was used; as a polyethylene Polyethyleneimine, using BASF's Sokalan HP20 (ethoxylated polyethyleneimine, ethoxylated polyethyleneimine); as a Cationic ampholytic acrylate polymer, using Lubrizol (Lubrizol) MerquatTM 295 (INCI name: Polyquaternium-22), Poly-DADMAC (polydiallyldimethylammonium chloride, INCI name: Polyquaternium-6) and Poly-DADMAC-acrylamide (Polydiallyldimethylammonium chloride acrylamide, INCI name: Polyquaternium-7), used under the trade name MerquatTM 100 Polymer, MerquatTM 550PR Polymer; as vinylpyrrolidone (VP)- Polyquaternary ammonium salt-16 of vinyl imidazole copolymer (QVI), using Luviquat Excellence of BASF (VP: QVI = 5: 95% by weight, high cationic charge density, phase In Luviquat UltraCare (Polyquaternium -44, VP: QVI = 80: 20 wt%) better).

Each raw material was converted based on a 5% activity standard. For example, in Comparative Example 1, it was added at 5.56 wt% based on the total amount of the composition.

Further, as the nonionic surfactant, low foaming type hydrogenated castor oil (HCO, Hydrogenated Castor Oil) is used, and polyoxyethylene alkyl ether or coconut oil which is solubilized by a usual fragrance or oil may be used. Ethanolamine, fatty acid alkanolamine, amine oxide, alkyl polyglucoside, and the like.

Table 1

Table 2

2. Experimental Example 1 - Residue residue confirmation experiment

In one embodiment of the present invention, the experimental conditions in the EL306 (fiber softener) in the environmental labeling certification standard of the Korea Environmental Industry and Technology Institute were used as washing test conditions, and the experiment was carried out using a sample amount of 0.67 ml/L.

In order to objectively confirm the residualness, the weight support of each laundry was removed, and the washing clothes used were: ordinary black 100% cotton T-shirt, black cotton/polyester blended T-shirt (66%/34%), and black blend. Fabric (acrylic/rayon/polyester/span), 47%/28%/19%/6%).

For objective evaluation, the artificially-derived residue was white zeolite (zeolite), calcium carbonate (CaCO3), cellulose (cellulose) particles, and pine pollen, each of which was charged 5 g. Zeolite and calcium carbonate are both a component of ordinary powder lotions and a component of soil ash. The cellulose particles are cotton fiber components having an average size of 30 μm and are components of general fiber dust or laundry dust. Pine pollen is one of the pollen dust.

The evaluation was carried out with the naked eye and was carried out based on the standard method of 5 points. The results are shown in Table 3.

(5 points: covering the entire surface of the test piece (very observed); 4 points: covering many areas of the surface of the test piece (many observed); 3 points: covering the surface of the test piece (partial observation); 2 points: Slightly covered the surface of the test piece (nearly observed); 1 point: not observed).

table 3

As a result, as shown in Table 3, in the case of the treatments of Examples 1 to 7, the residual residue observed by the naked eye was smaller than that of Comparative Example 1 and Comparative Example 2.

As a cationic surfactant (TEA Ester Quaternary) which is a main component in Comparative Example 1, the long-chain alkyl group has a lipophilic property which exhibits the property of capturing a residue. Although Comparative Example 2 shows good effects on zeolite and calcium carbonate, the main component is citric acid, which is a case where the washing rinse water is adjusted to (weak) acidic conditions to ionize the inorganic particles, and the (weak) acidic condition is based on The type of clothing and the state of dyeing may cause damage to the fibers. From Examples 1 to 7, it was confirmed that the residue can be sufficiently dispersed, and the residue and the surface of the laundry are repelled, thereby preventing the residue from remaining on the laundry. Further, it was confirmed that quaternized hydroxyethyl cellulose (INCI name: polyquaternium-10, 67) and quaternized guar gum (in addition to the water-soluble polymer used in the examples) Quaternized guar, JAGUAR C-17), polyquaternium-44 and the like were also more effective than Comparative Example 1.

3. Experimental Example 2 - Preventing the removal of dyeing experiments

As an experiment for preventing transfer dyeing, in one embodiment of the present invention, evaluation was carried out in accordance with the ASTM D5548 method. The de-dyed fabrics used were Direct Blue 90, Blue 1 Destained Fabric (TESTFABRICS, USA), and the transfer fabric used was a Bleached cotton print cloth (unstained (undyed)) (TESTFABRICS, USA). The change in color was measured using a spectrophotometer (SA 4000, NIPPON DENSHOKU), and the measurement results are shown in Table 4 below (sample usage: 0.67 ml/L).

Table 4

The smaller the ΔE(H) value, the smaller the color change, indicating that the effect of preventing the transfer is relatively better. As shown in the above Table 4, the effects of preventing the transfer removal of Examples 1 to 7 were superior to those of Comparative Example 1 and Comparative Example 2, and in the case of Comparative Example 2, it was considered that the transfer removal was severe due to the influence of citric acid. In particular, the anti-slipping effect of Example 3, Example 5, and Example 7 was very good, and it was judged that the cationic charge density was high.

4. Experimental Example 3 - Yellowing Experiment

As a yellowing experiment, in one embodiment of the present invention, an experiment was conducted in accordance with the test method in EL306 at a sample amount of 0.67 ml/L. In order to observe the color change, two sheets of bleached cotton print cloth (undyed) (TESTFABRICS, USA) were simultaneously introduced, and one rinse was performed. After drying in a constant temperature and humidity chamber for 12 hours, it was treated by a light fastness tester for 48 hours. The color change was measured using a spectrophotometer (SA 4000, NIPPON DENSHOKU) and the Δb value was measured. The higher the Δb value, the greater the degree of yellowing is judged.

table 5

As a result, as shown in the above Table 5, the yellowing of Comparative Example 1 was the most serious, and the color of the woven fabric was observed to be yellow when observed by the naked eye. It was confirmed that the change in color was small in the case of the treatment of Examples 1 to 7 with respect to Comparative Example 1 and Comparative Example 2.

5. Experimental Example 4 - Confirmation of Pollen Adsorption Experiment

In one embodiment of the present invention, in order to confirm the effect of the composition of the present invention on preventing pollen adsorption, 0.2 g of pine pollen is placed in a polyethylene bag (20 L), shaken up and down 30 times (1 time / 1 second), and then placed. 5 sheets of 6cm × 6cm black fabric (polyester / wool, 50% / 50%), shaken up and down 30 times (1 time / 1 second), immediately removed, visually evaluate the pine pollen adsorbed on the fiber surface, and use a microscope After magnifying 200 times the count, the average value is obtained. The experiment was carried out in a constant temperature and humidity chamber [20 ° C, 40% RH (relative humidity)].

As a treatment method, the surface contamination and organic matter are removed by using ethanol, and then naturally dried in a constant temperature and humidity chamber (20 ° C, 40% RH). Evaluation was carried out according to the EL3016 test method. The washing lotion used LG Life's TECH powder lotion (0.84g/L). At the end of rinsing, the amount of each sample used was 0.67ml/L. After washing, it was dried in a constant temperature and humidity chamber for more than 12 hours. Experimental tools such as pollen and bags are also stored in a constant temperature and humidity chamber for more than 12 hours.

As a control group, only the lotion was used, and it was evaluated by the naked eye by 10 professionals, and the average value was determined based on the 5-point standard method.

(5 points: much more than the control group; 4 points: more than the control group; 3 points: similar to the control group; 2 points: less compared with the control group; 1 point: very few compared to the control group)

The results are shown in the table below.

Table 6

As a result, as shown in the above Table 6, it was confirmed that more pine pollen was observed in Comparative Example 1 than in the control group, and in the case of the treatments of Examples 1 to 7, compared with the control group and Comparative Example 1 As in Comparative Example 2, the amount of adsorption of pine pollen was much reduced. Pollen dust such as pine pollen is composed of an organic component such as protein or fat. Therefore, in the case of Examples 1 to 7, it is possible to determine the antistatic property, the hydrophilic property, and the smoothness of the coating provided on the surface of the fabric. effect.

6. Experimental Example 5 - Confirmation of Pollen Adsorption Experiment - Spray Formulation

In an embodiment of the present invention, in order to confirm the effect of the composition of the present invention for preventing pollen adsorption, 0.2 g of pine pollen is placed in a polyethylene bag (20 L), shaken up and down 30 times (1 time / 1 second), and then placed in 5 A 6cm × 6cm black fabric (polyester / wool, 50% / 50%), shaken up and down 30 times (1 time / 1 second), immediately removed, visually evaluated the pine pollen adsorbed on the fiber surface and magnified with a microscope 200 Count the number and find the average value. The experiment was carried out in a constant temperature and humidity chamber [20 ° C, 40% RH (relative humidity)].

As a treatment method, the surface contamination and organic matter are removed by using ethanol, and then naturally dried in a constant temperature and humidity chamber (20 ° C, 40% RH). Each composition was spray-coated with 1 g of a spray, and then dried in a constant temperature and humidity chamber for 12 hours or more. The test tools such as pine powder and bags were also stored in a constant temperature and humidity chamber for 12 hours or more. The control group was untreated fabric. The evaluation was performed by 10 professionals through the naked eye, and the average value was determined based on the 5-point standard method, and the results are shown in the following table.

(5 points: much more than the control group; 4 points: more than the control group; 3 points: similar to the control group; 2 points: less compared with the control group; 1 point: very few compared to the control group).

Table 7

As a result, as shown in the above Table 7, it was confirmed that more pine pollen was observed in Comparative Examples 3, 4, and 5 than in the control group, and in the case of treatment in Examples 7 to 11, the amount was much reduced. The reason for this is that pollen dust such as pollen or pine pollen is composed of organic components such as protein and fat, and when treated with the compositions of Examples 7 to 11, the antistatic property, hydrophilic property, and smoothness imparted by the surface of the fabric are provided. The formation of a sexual film brings about the above effects. In particular, since it can be directly sprayed and applied, its effect is more effective than washing machine processing.

7. Experimental Example 6 - Prevention of Pet Villus Reattachment Experiment

In one embodiment of the invention, in order to practice the composition of the present invention to prevent pet fluff reattachment experiments, 30 dog hairs having substantially equal lengths and thicknesses are selected for attachment to black blended fabrics (acrylic/rayon/polyester) / Spandex, 47% / 28% / 19% / 6%), a washing machine rinsing program was performed, and the number of residual dog hair was measured. The above method was carried out three times, and the average amount of dog hair remaining in front of and behind the cloth was determined. The sample amount was 0.67 ml/L.

The results are shown in the table below.

Table 8

As a result, as shown in the above Table 8, it was confirmed that the number of remaining dog hairs was smaller when treated by Examples 1 to 7 as compared with Comparative Example 1 and Comparative Example 2.

8. Experimental Example 7 - Evaluation of Softness and Antistatic Force

In one embodiment of the invention, the softness and antistatic force of the compositions of the invention are determined.

After washing with each composition, the flexibility was evaluated according to the test method of EL306, and the laundry was three towels, and LG Life Healthy TECH powder lotion (0.84 g/L) was used as a washing lotion. At the end of the rinsing, the sample was used in an amount of 0.67 ml/L, and after washing, it was dried in a constant temperature and humidity chamber for 12 hours. In order to evaluate the antistatic force, it was dried under the same conditions as above except that the towel was placed in a test piece (polyester). The softness evaluation was performed by sensory evaluation by 10 professional monitors.

The judgment criterion is that the same judgment is 0 points as compared with the case where only the lotion is added and no addition is made at the time of the final rinse; the good judgment is 1 point compared with the lotion; and the judgment is excellent compared with the lotion It was 2 points; the judgment which was slightly worse than the lotion was -1 point; the difference from the lotion was judged to be -2 points.

The evaluation of the antistatic force was carried out by a friction band voltage measuring device (Rotary static tester, model: EC-3DN, INTEC. CO., LTD). It was measured according to the charging test method of the woven fabric and the knitted fabric (KS K 0555: 2010 B method, the friction band voltage measurement method), and the white cloth (cotton rubbing cloth) attached to the KS K 0905 dye fastness test was used.

The results are shown in the table below.

Table 9

As a result, as shown in the above Table 9, when the examples 1 to 7 were confirmed, the flexibility and the antistatic force similar to those of the comparative example 1 which is a general fiber softener composition were obtained.

9. Production Example of Fiber Treatment Composition

In one embodiment of the present invention, a powdery lotion, a liquid lotion, and a tablet lotion comprising the fiber treatment composition of the present invention were produced in the dosage form described in Table 10 below.

Table 10

Although the technical content of the present invention has been disclosed in the above preferred embodiments, it is not intended to limit the present invention, and any modifications and refinements made by those skilled in the art without departing from the spirit of the present invention are encompassed by the present invention. The scope of protection of the present invention is therefore defined by the scope of the appended claims.

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no

Claims (11)

A fiber treatment composition for suppressing residue of a washing residue, which comprises a water-soluble cationic polymer. A fiber treatment composition for preventing transfer dyeing, which comprises a water-soluble cationic polymer. A fiber treatment composition for preventing dust adsorption, comprising a water-soluble cationic polymer. The fiber treatment composition according to any one of claims 1 to 3, wherein the water-soluble cationic polymer is selected from the group consisting of polydiallyldimethylammonium chloride (poly season) Ammonium salt-6), acrylamide-diallyldimethylammonium chloride (polyquaternium-7), polyvinylpyrrolidone (PVP)-dimethylaminoethyl methacrylate copolymer, acrylic-second Allyldimethylammonium chloride (polyquaternium-22), acrylic acid-diallyldimethylammonium chloride-acrylamide polymer (polyquaternium-39), cationic polyvinyl alcohol derived , polyamine, polyethyleneimine, ethoxylated polyethyleneimine, polyvinylimidazole, vinylpyrrolidone (VP)-vinylimidazole (QVI) copolymer, chitosan, cationic cellulose derivative, cationic starch a group consisting of a derivative, a cationic guar derivative, a polyquaternium-51, a acrylamide-dimethylaminoethyl methacrylate chloromethane polymer, and a trimethylaminoethyl methacrylate polymer Any one of them, or a mixture or copolymer of two or more thereof. The fiber treatment composition according to any one of claims 1 to 3, wherein the water-soluble cationic polymer is selected from the group consisting of polydiallyldimethylammonium chloride (poly season) Ammonium salt-6), acrylamide-diallyldimethylammonium chloride (polyquaternium-7), polyvinylpyrrolidone (PVP)-dimethylaminoethyl methacrylate (polyquaternium- 11), acryl-diallyldimethylammonium chloride (polyquaternium-22), polyethyleneimine, ethoxylated polyethyleneimine, vinylpyrrolidone (VP)-vinylimidazole (QVI) Any one of a group consisting of a copolymer (polyquaternium-16), a cationic cellulose derivative, a cationic starch derivative, a cationic guar derivative, and a cationic polyvinyl alcohol, or a mixture of two or more thereof or Copolymer. The fiber treatment composition according to any one of claims 1 to 3, wherein the content of the water-soluble cationic polymer is from about 0.1 to 50 by weight based on the total weight of the fiber treatment composition. %. The fiber treatment composition according to any one of claims 1 to 3, further comprising a nonionic surfactant. The fiber treatment composition according to claim 7, wherein the content of the nonionic surfactant is from about 0.1 to 80% by weight based on the total weight of the fiber treatment composition. The fiber treatment composition according to claim 7, wherein the fiber treatment composition comprises a water-soluble cationic polymer and a nonionic surfactant in a weight ratio of 0.1 to 20:1. A method for producing a fiber treatment composition for suppressing residue of a washing residue, preventing migration or removal of dust, or preventing dust from adsorbing, and comprising the step of adding a water-soluble cationic polymer. A fiber treatment product comprising the fiber treatment composition according to any one of claims 1 to 9, wherein the fiber treatment product is selected from the group consisting of a fiber lotion, a fiber softener, and a fiber. Group of odorant, fiber fragrance, fiber bleach, fiber conditioner, fiber pretreatment agent, fiber post-treatment agent, fiber nutrient, fiber essence, fiber fixative, fiber colorant and fiber bleaching agent in.