TW201725256A - Liquid crystal composition - Google Patents

Abstract

The invention discloses a liquid crystal composition. The liquid crystal composition comprises one or more compounds shown in the formula I and one or more compounds shown in the formula II, and at least further comprises one or more compounds shown in the formula II-B contained in the formula II, wherein the formula I, the formula II and the formula II-B are shown in the description, and all substituent groups are defined. The liquid crystal composition has low viscosity gamma 1, moderate dielectric anisotropy delta epsilon and moderate optical anisotropism delta n, and quick response of liquid crystal displaying can be achieved.

Description

Liquid crystal composition and liquid crystal display element

The present invention relates to the field of liquid crystal display, and in particular to a liquid crystal composition and a liquid crystal display element or liquid crystal display comprising the liquid crystal composition.

At present, the application range of liquid crystal compounds is expanding wider and wider, and it can be applied to various types of displays, electro-optical elements, sensors, and the like. There are many kinds of liquid crystal compounds used in the above display field, and nematic liquid crystals are most widely used. Nematic liquid crystals have been used in passive TN, STN matrix displays and systems with TFT active matrices.

For the application of thin film transistor technology (TFT-LCD), although the market has been very large in recent years, and the technology has gradually matured, people's requirements for display technology are also constantly improving, especially in achieving rapid response and reducing the driving voltage. Reduce power consumption and other aspects. As one of the important optoelectronic materials for liquid crystal displays, liquid crystal materials play an important role in improving the performance of liquid crystal displays.

As a liquid crystal material, it is required to have good chemical and thermal stability as well as stability against electric fields and electromagnetic radiation. As a liquid crystal material for thin film transistor technology (TFT-LCD), it is not only required to have the above stability, but also has a wide nematic temperature range, a suitable birefringence anisotropy, a very high resistivity, Good UV resistance, high charge retention and low vapor pressure.

For the dynamic picture display application, eliminating the image sticking and smearing, the liquid crystal is required to have a fast response speed, so the liquid crystal is required to have a low rotational viscosity γ ₁ ; in addition, for the portable device, in order to reduce the energy consumption of the device, It is desirable that the driving voltage of the liquid crystal be as low as possible; and for a display such as a television, the driving voltage requirement for the liquid crystal is not so low.

The viscosity of the liquid crystal compound, especially the rotational viscosity γ ₁ directly affects the response time after the liquid crystal is powered on, whether it is the rise time (t _on ) or the fall time (t _off ), which is proportional to the rotational viscosity γ ₁ of the liquid crystal, and rises. The time (t _on ) is related to the liquid crystal cell and the driving voltage, and can be adjusted by increasing the driving voltage and reducing the thickness of the liquid crystal cell; and the falling time (t _off ) is independent of the driving voltage, mainly the elastic constant of the liquid crystal. the liquid crystal cell thickness is related decreased thickness will reduce the fall time (t _off), but different display modes, the motion of liquid crystal molecules is not the same, TN, IPS, VA three modes, respectively, the average spring constant K, torsional spring constant, The bending elastic constant is inversely proportional.

According to the theory of liquid crystal continuum, after different kinds of liquid crystals are deformed by external force (electric field, magnetic field), they will "rebound" back to the original shape by interaction between molecules; similarly, liquid crystal is also due to intermolecular The interaction forces form a "viscosity." Small changes in liquid crystal molecules can cause significant changes in the performance of liquid crystals. Some of these changes are regular, and some seem to be difficult to find. They also have a significant impact on the interaction between liquid crystal molecules. These effects are very Subtle, so far has not formed a perfect theoretical explanation.

The viscosity of liquid crystals is related to the molecular structure of liquid crystals. It is one of the important tasks of liquid crystal formulators to study the relationship between the viscosity of liquid crystal systems formed by different liquid crystal molecules and the molecular structure of liquid crystals.

An object of the present invention is to provide a liquid crystal composition and a liquid crystal display element or liquid crystal display comprising the liquid crystal composition, which has a low viscosity, can achieve a fast response, and has a moderate dielectric anisotropy Δ ε, Moderate optical anisotropy Δn, high stability to heat and light. A liquid crystal display element or liquid crystal display comprising the liquid crystal composition has a wide nematic temperature range, suitable birefringence anisotropy, very high resistivity, good ultraviolet resistance, high charge retention, and low steam Pressure and other properties.

In order to achieve the above technical effects, the present invention provides a liquid crystal composition comprising one or more compounds of the formula I and one or more compounds of the formula II, and the liquid crystal composition necessarily comprises one or two compounds of the formula II a compound represented by II-B, that is, when the liquid crystal composition contains only one compound of the formula II, the compound of the formula II is any one of the compounds of the formula II-B; when the liquid crystal composition comprises In the case of two compounds of the formula II, the two compounds of the formula II may be a compound of the formula II-B and a compound of the formula II-B, or a compound of the formula II-B. Any two compounds; when more than two compounds of formula II are included in the liquid crystal composition, the more than two compounds of formula II may be a compound of formula II-B and more than one of formula II a compound other than II-B, which may also be any two of the compounds of formula II-B and at least one compound of non-II-B of formula II I, II, II-B,

Wherein, X ₁ and X ₂ each independently represent H or F, but in the same molecular formula, they cannot be F at the same time, and cannot be H at the same time;

R ₀ , R ₁ , R ₂ and R ₃ each independently represent an alkyl group having 1 to 10 carbon atoms, a fluorine-substituted alkyl group having 1 to 10 carbon atoms, and an alkoxy group having 1 to 10 carbon atoms. a fluorine-substituted alkoxy group having 1 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms substituted by fluorine, and having 3 to 3 carbon atoms an alkenyloxy group having a carbon number of 8 or fluoro substituted with 3-8 alkenyloxy group, and _{R 0, R 1, R 2} , R 3 in any of a CH ₂ group may be a cyclopentyl, cyclobutyl or Cyclopropyl substitution; Y represents ethyl or vinyl.

, Each independently represents a 1,4-phenylene group, a 1,4-cyclohexylene group or a 1,4-cyclohexylene group.

The liquid crystal composition of the present invention preferably does not contain a liquid crystal compound containing -CN, and does not contain a compound containing a pyridine or a pyrimidine ring.

The present invention is further preferably a liquid crystal compound which does not contain a fused ring structure.

The liquid crystal composition provided by the present invention has Δn [589 nm, 25 ° C] > 0.08, Δ ε [1 KHz, 25 ° C] > 2 or Δ ε [1 KHz, 25 ° C] <-2, clear point Cp > 70.0 ° C, rotational viscosity γ ₁ [25 ° C] is between 40 and 120 mPa·s.

In the liquid crystal composition provided by the present invention, the liquid crystal composition preferably has a mass percentage of 2-25%, and one or both of the compounds of the formula II-B preferably have a mass percentage of 5-55. %, one or more compounds of the formula II are preferably present in an amount of from 0 to 30% by mass.

The liquid crystal composition of the present invention does not contain a liquid crystal component containing a -CN structure and a pyridine or pyrimidine ring compound. -CN has a large permanent dipole moment, the electron cloud is rich, easy to adsorb cations, resulting in ion solvation, resulting in decreased electrical properties of the liquid crystal, such as charge retention rate VHR, resistivity ρ, power consumption, etc.; pyridine, pyrimidine ring The compound is degraded in quality due to the electrons being easily excited under UV.

The formula I is specifically preferably a compound of the formula I1-I8 due to the difference in various substituents: I1 I2 I3, I4, I5, I6, I7, I8;

Wherein R ₁₁ represents an alkyl group having 1 to 10 carbon atoms; R ₁₂ represents an alkenyl group having 2 to 10 carbon atoms; R ₂₁ represents an alkyl group having 1 to 10 carbon atoms; and R ₂₂ represents a carbon atom; It is an alkoxy group of 1-10.

The compound of the formula I generally has good mutual solubility with other liquid crystals, in particular, the formula I wherein R ₁₂ represents an alkenyl group having 2 to 10 carbon atoms and R ₂₁ represents an alkyl group having 1 to 10 carbon atoms. Compound.

The optical anisotropy Δn of the I1-I8 compound is generally small, generally smaller than Δn of the mixed liquid crystal, and therefore can be used to adjust the Δn of the mixed liquid crystal in a low direction. When R ₂₂ represents an alkoxy group having 1 to 10 carbon atoms, Δn is slightly larger due to the conjugate of oxygen atoms.

The liquid crystal mixture of the invention contains one or both of the compounds of formula II-B II-B-1, II-B-2.

The liquid crystal mixture of the present invention may contain a compound of formula II II,

The compound of formula II is preferably a compound of formula II-1 to II-10: II-1, II-2, II-3, II-4, II-5, II-6, II-7, II-8, II-9, II-10.

The liquid crystal composition of the present invention may be a positive liquid crystal composition, and the liquid crystal composition may further comprise one or more compounds represented by formula III. III,

R ₄ represents an alkyl group having 1 to 10 carbon atoms, a fluorine-substituted alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, and a fluorine-substituted carbon number of 1 to 10 Alkoxy group, alkenyl group having 2 to 10 carbon atoms, alkenyl group having 2 to 10 carbon atoms substituted by fluorine, alkenyloxy group having 3 to 8 carbon atoms or fluorine-substituted carbon atom number 3-8 alkenyloxy group; and R _{4 is} any one or more CH ₂ groups may be cyclopentyl, cyclobutyl or cyclopropyl alternative.

, , Each independently represents: , , , , , , one of them;

m represents 1,2; Z ₁ and Z ₂ each independently represent a single bond, -CF ₂ O-, -CH ₂ CH ₂ -, -CH ₂ O-; Y represents F, and the fluorine-substituted carbon atom is 1- An alkyl group having 5, a fluorine-substituted alkoxy group having 1 to 5 carbon atoms, a fluorine-substituted alkenyl group having 2 to 5 carbon atoms, and a fluorine-substituted alkenyloxy group having 3 to 8 carbon atoms ;

One or more compounds of formula III are compounds of formula III1-III22 III1 III2 III3, III4, III5, III6, III7, III8, III9, III10, III11, III12, III13, III14, III15, III16, III17, III18, III19, III20, III21, III22;

Wherein, X ₁ and X ₂ each independently represent H or F, and in the same molecular formula, they cannot be F at the same time, and cannot be H at the same time;

R ₄ represents an alkyl group having 1 to 10 carbon atoms, a fluorine-substituted alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, and a fluorine-substituted carbon number of 1 to 10 Alkoxy group, alkenyl group having 2 to 10 carbon atoms, alkenyl group having 2 to 10 carbon atoms substituted by fluorine, alkenyloxy group having 3 to 8 carbon atoms or fluorine-substituted carbon atom a number 3-8 alkenyloxy group, and any one of R ₄ CH ₂ may be replaced by a cyclopentyl group, a cyclobutyl group or a cyclopropyl group;

(F) means H or F;

Y ₂ represents F, a fluorine-substituted alkyl group having 1 to 5 carbon atoms, a fluorine-substituted alkoxy group having 1 to 5 carbon atoms, a fluorine-substituted alkenyl group having 2 to 5 carbon atoms, and fluorine. The substituted alkenyloxy group having 3-8 carbon atoms.

The liquid crystal composition of the present invention may be a negative liquid crystal composition, and the liquid crystal composition may further comprise one or more compounds represented by Formula IV. IV;

Wherein R ₅ and R ₆ each independently represent an alkyl group having 1 to 10 carbon atoms, a fluorine-substituted alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, or a fluorine substitution. An alkoxy group having 1 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms substituted by fluorine, and an alkene having 3 to 8 carbon atoms group carbon atoms or fluorine-substituted 3-8 alkenyloxy group, and R _5, R ₆ in CH ₂ may be any one of cyclopentyl, cyclobutyl or cyclopropyl alternatively; Z _3, Z ₄ Each independently represents a single bond, -CH ₂ CH ₂ -, -CH ₂ O-; , Respectively , , , , , , One of them; m means 1, 2; n means 0, 1, 2.

One or more compounds of formula IV are IV1-IV11 compounds: IV1 IV2 IV3, IV4, IV5, IV6, IV7, IV8, IV9, IV10, IV11;

R ₅ and R ₆ each independently represent an alkyl group having 1 to 10 carbon atoms, a fluorine-substituted alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, or a fluorine-substituted carbon. An alkoxy group having an atomic number of 1 to 10, an alkenyl group having 2 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms substituted by fluorine, an alkenyloxy group having 3 to 8 carbon atoms carbon atoms or a fluorine-substituted 3-8 alkenyloxy group, and R _5, R ₆ in CH ₂ may be any one of cyclopentyl, cyclobutyl or cyclopropyl substitution;

The liquid crystal composition of the present invention may be a negative liquid crystal composition, and the liquid crystal composition may further comprise one or more compounds represented by Formula V. V;

R ₇ and R ₈ each independently represent an alkyl group having 1 to 10 carbon atoms, a fluorine-substituted alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, or a fluorine-substituted carbon. An alkoxy group having an atomic number of 1 to 10, an alkenyl group having 2 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms substituted by fluorine, an alkenyloxy group having 3 to 8 carbon atoms carbon atoms or a fluorine-substituted 3-8 alkenyloxy group, and R _5, R ₆ in CH ₂ may be any one of cyclopentyl, cyclobutyl or cyclopropyl alternative.

The compound of formula V is preferably: ;

R ₈₁ represents an alkoxy group having 1 to 10 carbon atoms.

The different ratios of the components of the liquid crystal composition may exhibit slightly different properties, such as dielectric anisotropy Δ ε, optical anisotropy Δn, transition temperature of the nematic type of liquid crystal into liquid, and stability at low temperature. It will vary and can be applied to different types of display elements, but the same feature is its low rotational viscosity γ ₁ . Applied to liquid crystal display elements for fast response.

Further, a dopant of various functions may be added to the liquid crystal compound provided by the present invention, and the dopant content is preferably between 0.01 and 1%. These dopants are mainly antioxidants, ultraviolet absorbers, and chiral agents.

The antioxidant and the ultraviolet absorber are preferably: , , , , , ,

S represents an integer of 1-10.

The chiral agent is preferably (left-handed or right-handed): , , , , .

The present invention also relates to a liquid crystal display element or liquid crystal display comprising any of the above liquid crystal compositions; the liquid crystal display element or liquid crystal display being an active matrix display element or display or a passive matrix display element or display.

The liquid crystal display element or liquid crystal display is preferably an active matrix addressed liquid crystal display element or a liquid crystal display.

The active matrix display element or display is specifically a TN-TFT or IPS-TFT liquid crystal display element or display.

The liquid crystal composition provided by the invention has a low viscosity, can achieve a fast response, and has moderate dielectric anisotropy Δ ε, moderate optical anisotropy Δn, high heat and light stability.

The liquid crystal material comprising the liquid crystal composition provided by the present invention not only has good chemical and thermal stability and stability against electric fields and electromagnetic radiation. Moreover, as a liquid crystal material for thin film transistor technology (TFT-LCD), it also has a wide nematic temperature range, suitable birefringence anisotropy, very high resistivity, good ultraviolet resistance, and high charge. Maintainability and low vapor pressure.

The invention is further illustrated by the following specific examples, but the invention is not limited to the following examples. The above methods are common methods unless otherwise specified. The raw materials can be obtained from an open commercial route unless otherwise specified. Percentages are percentages by mass unless otherwise stated.

In the following embodiments,

The CP indicates a sharp point and was directly measured using a WRX-1S micro-thermal analyzer, and the heating rate was set to 3 ° C / min.

Δn represents optical anisotropy (589 nm, 20oC),

Δε represents dielectric anisotropy (25 ° C, 1 KHz, HP 4284 A, 5.2 μm TN left-handed box),

γ ₁ represents rotational viscosity (mpas) at 20 ^o C, VHR (%) represents charge retention (5V, 60Hz, 20°C), and ρ (×1013Ω·cm) represents resistivity (20°C)

The tester with voltage holding ratio VHR(%) and resistivity ρ(×10 ¹³ Ω·cm) are both TOYO06254 and TOYO6517 liquid crystal physical property evaluation systems (test temperature 20 ° C, time 16 ms, test box 7.0 μm)

The liquid crystal monomer structure of the embodiment of the present invention is represented by a code, and the code representation methods of the liquid crystal ring structure, the terminal group and the linking group are shown in the following table (1) and Table (2).

Table (1): Corresponding code of the ring structure

Table (2): Corresponding code of end group and linking group

Example:

C(5)CCV1

3B B(3F) B(3F,5F) CF ₂ OB(3F,5F)F

Example 1

Example 2

Example 3

Example 4

Example 5

Example 6

Example 7

Example 8

Example 9

It can be seen from the above examples that the liquid crystal composition of the present invention has a low rotational viscosity γ1 for liquid crystal display, can achieve rapid response, and has moderate dielectric anisotropy Δ ε, moderate optical anisotropy Δn. High stability to heat. It is especially suitable for liquid crystal materials for TN, IPS, and VA modes.

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Claims (10)

A liquid crystal composition comprising one or more compounds of formula I and one or more compounds of formula II, and the liquid crystal composition further comprises at least one or two compounds of formula II-B of formula II, I, II, II-B; wherein one of X ₁ and X ₂ represents fluorine (F) and the other is hydrogen (H); R ₀ , R ₁ , R ₂ and R ₃ each independently represent a carbon number of 1 to 10 An alkyl group, a fluorine-substituted alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, a fluorine-substituted alkoxy group having 1 to 10 carbon atoms, and 2 carbon atoms An alkenyl group of 10, an alkenyl group having 2 to 10 carbon atoms substituted by fluorine, an alkenyloxy group having 3 to 8 carbon atoms or an alkenyloxy group having 3 to 8 carbon atoms substituted by fluorine. and _{R0, R1, R 2, R} 3 is not any one or more of the CH ₂ can be connected cyclopentyl, cyclobutyl, cyclopropyl, -O- alternative; the Y represents an ethyl or vinyl; , Each independently represents a 1,4-phenylene group, a 1,4-cyclohexylene group or a 1,4-cyclohexylene group. The liquid crystal composition according to claim 1, wherein the one or more compounds of the formula I are one or more compounds of the formula I1 to formula I8; the compound of the formula II comprises the formula II1 One or more compounds to the compound of II10; the one or more compounds of formula II-B are one or both of the compounds of formula II-B-1 to II-B-2, I1 I2 I3, I4, I5, I6, I7, I8, II-B-1, II-B-2, II-1, II-2, II-3, II-4, II-5, II-6, II-7, II-8, II-9, II-10; wherein R ₁₁ represents an alkyl group having 1 to 10 carbon atoms, R ₁₂ represents an alkenyl group having 2 to 10 carbon atoms, R ₂₁ represents an alkyl group having 1 to 10 carbon atoms, and R ₂₂ It represents an alkoxy group having a carbon number of 1-10. The liquid crystal composition according to claim 1 or 2, wherein the liquid crystal composition has a mass percentage of the compound of the formula I of 2-25%, and the formula II-B has a mass percentage of 5 -55%, the one or more compounds of the formula II have a mass percentage of 0-30%. The liquid crystal composition according to claim 1, which is a positive liquid crystal composition, the liquid crystal composition further comprising one or more compounds represented by formula III III; R ₄ represents an alkyl group having 1 to 10 carbon atoms, a fluorine-substituted alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, and 1 carbon atom substituted by fluorine. Alkoxy group of -10, alkenyl group having 2 to 10 carbon atoms, alkenyl group having 2 to 10 carbon atoms substituted by fluorine, alkenyloxy group having 3 to 8 carbon atoms or fluorine substituted An alkenyloxy group having 3 to 8 carbon atoms; and any one or more of CH _{2 in} R ₄ may be replaced by a cyclopentyl group, a cyclobutyl group or a cyclopropyl group; , , Each independently represents: , , , , , , One of them; m represents 1 or 2; Z ₁ and Z ₂ each independently represent a single bond, -CF ₂ O-, -CH ₂ CH ₂ - or -CH ₂ O-; Y ₂ represents F, a fluorine-substituted carbon atom An alkyl group having a number of 1 to 5, a fluorine-substituted alkoxy group having 1 to 5 carbon atoms, a fluorine-substituted alkenyl group having 2 to 5 carbon atoms, or a fluorine-substituted carbon number of 3 to 8 Alkenyloxy. The liquid crystal composition of claim 4, wherein the one or more compounds of formula III are compounds of formula III1 to formula III22. III1 III2 III3, III4, III5, III6, III7, III8, III9, III10, III11, III12, III13, III14, III15, III16, III17, III18, III19, III20, III21, III22; wherein X ₁ and X ₂ each independently represent H or F, but in the same molecular formula, they cannot be both F and H at the same time; R ₄ represents an alkyl group having 1 to 10 carbon atoms, and fluorine is substituted. An alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, a fluorine-substituted alkoxy group having 1 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms, a fluorine-substituted alkenyl group having 2 to 10 carbon atoms, an alkenyloxy group having 3 to 8 carbon atoms or an alkenyloxy group having 3 to 8 carbon atoms substituted by fluorine, and any one of R ₄ CH ₂ may be replaced by a cyclopentyl group, a cyclobutyl group or a cyclopropyl group; (F) represents H or F; Y ₂ represents F, a fluorine-substituted alkyl group having 1 to 5 carbon atoms, and a fluorine-substituted carbon number An alkoxy group of 1 to 5, a fluorine-substituted alkenyl group having 2 to 5 carbon atoms or a fluorine-substituted alkenyloxy group having 3 to 8 carbon atoms. The liquid crystal composition according to any one of claims 1 to 3, which is a negative liquid crystal composition further comprising one or more compounds represented by formula IV Wherein R ₅ and R ₆ each independently represent an alkyl group having 1 to 10 carbon atoms, a fluorine-substituted alkyl group having 1 to 10 carbon atoms, and an alkoxy group having 1 to 10 carbon atoms; Fluorine-substituted alkoxy group having 1 to 10 carbon atoms, alkenyl group having 2 to 10 carbon atoms, alkenyl group having 2 to 10 carbon atoms substituted by fluorine, and 3 to 8 carbon atoms carbon atoms, an alkenyloxy group or fluorine-substituted 3-8 alkenyloxy group, and R _5, R ₆ in CH ₂ may be any one of cyclopentyl, cyclobutyl or cyclopropyl alternatively; Z _3, Z ₄ each independently represents a single bond, -CH ₂ CH ₂ -, -CH ₂ O-; , Respectively , , , , , , One of them; m means 1 or 2; n means 0, 1, or 2. The liquid crystal composition according to claim 6, wherein the one or more compounds of the formula IV are compounds of the formula IV1 to IV11 IV1 IV2 IV3, IV4, IV5, IV6, IV7, IV8, IV9, IV10, IV11; R ₅ and R ₆ each independently represent an alkyl group having 1 to 10 carbon atoms, a fluorine-substituted alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, or a fluorine substitution. An alkoxy group having 1 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms substituted by fluorine, and an alkene having 3 to 8 carbon atoms group carbon atoms or fluorine-substituted 3-8 alkenyloxy group, and R _5, R ₆ in CH ₂ may be any one of cyclopentyl, cyclobutyl or cyclopropyl alternative. The liquid crystal composition according to any one of claims 1 to 3, which is a negative liquid crystal composition further comprising one or more compounds represented by formula V V; R ₇ and R ₈ each independently represent an alkyl group having 1 to 10 carbon atoms, a fluorine-substituted alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, or a fluorine substitution. An alkoxy group having 1 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms, an alkenyl group having 2 to 10 carbon atoms substituted by fluorine, and an alkene having 3 to 8 carbon atoms group carbon atoms or fluorine-substituted 3-8 alkenyloxy group, and R _5, R ₆ in CH ₂ may be any one of cyclopentyl, cyclobutyl or cyclopropyl alternative. A liquid crystal display element comprising the liquid crystal composition according to any one of claims 1 to 8, wherein the liquid crystal display element is an active matrix display element or a passive matrix display element. The liquid crystal display device of claim 9, wherein the active matrix display element is a TN-TFT, IPS-TFT or VA-TFT liquid crystal display element.