TW201713223A - Lump formation-preventing agent - Google Patents

Lump formation-preventing agent Download PDF

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TW201713223A
TW201713223A TW105120781A TW105120781A TW201713223A TW 201713223 A TW201713223 A TW 201713223A TW 105120781 A TW105120781 A TW 105120781A TW 105120781 A TW105120781 A TW 105120781A TW 201713223 A TW201713223 A TW 201713223A
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Taiwan
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tackifier
polysaccharide
food
viscosity
weight
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TW105120781A
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Chinese (zh)
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Nobuko Jinno
Miki Konno
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Meiji Co Ltd
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/20Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L33/00Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
    • A23L33/10Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
    • A23L33/17Amino acids, peptides or proteins
    • A23L33/175Amino acids

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Proteomics, Peptides & Aminoacids (AREA)
  • Mycology (AREA)
  • Dispersion Chemistry (AREA)
  • Jellies, Jams, And Syrups (AREA)
  • Non-Alcoholic Beverages (AREA)

Abstract

Provided is a novel lump formation-preventing agent. An agent for preventing the formation of lumps from a thickening polysaccharide, said agent comprising at least one component selected from the group consisting of lysine, aspartic acid and salts thereof.

Description

粉塊形成抑制劑 Powder formation inhibitor

本發明係揭示關於增黏多醣類的粉塊形成抑制劑及增黏劑等之技術。 The present invention discloses techniques for a powder block forming inhibitor, a tackifier, and the like of a polysaccharide-promoting polysaccharide.

增黏多醣類已在各種技術領域中使用,在食品領域中,已使用作為例如用於對飲食品賦予黏稠度之增黏劑。此種增黏劑係不僅配合一般消費者的嗜好來調整飲食品的黏度而使口感有所變化,亦可在防止飲食品受到高齡者等所誤吞之目的下使用。在此種目的下所使用之增黏劑亦已知為黏稠度調整食品。 Tackified polysaccharides have been used in various technical fields, and have been used as a tackifier for imparting viscosity to foods and drinks, for example, in the food field. Such a tackifier not only adjusts the viscosity of the food and beverage to the taste of the general consumer, but also changes the taste, and can also be used for the purpose of preventing the food and beverage from being swallowed by elderly people. Adhesives used for such purposes are also known as viscosity-adjusting foods.

在食品領域中利用作為增黏劑之增黏多醣類中,係已知包含黃原膠及瓜爾膠在內之許多種類。黃原膠等具有黏稠度的表現迅速、黏膩感低之優異的特性。另一方面,黃原膠等具有分散性低,以粉末之狀態添加至水中時,僅其表面會溶解,其內部容易形成以粉狀殘留之所謂的「團塊(粉塊、疙瘩)」,此外,在水中無法均勻地分散,於一部分會形成膠狀的塊體之一面。 Among the polysaccharide-promoting polysaccharides used as a tackifier in the food field, many types including xanthan gum and guar gum are known. Xanthan gum has excellent properties such as quickness of viscosity and low stickiness. On the other hand, when xanthan gum or the like has a low dispersibility and is added to water in the form of a powder, only the surface thereof is dissolved, and a so-called "cluster (powder, crucible)" which remains in a powder form is easily formed inside. In addition, it is not uniformly dispersed in water, and a part of the gel-like block is formed in part.

作為改善起因於黃原膠等的分散性低之問題 之手段,在專利文獻1中,已揭示使鉀鹽黏結於粉末狀的黃原膠等之表面之技術。此外,在專利文獻2中,已揭示添加聚-γ-麩胺酸或其鹽之技術。 As a problem of improving the dispersibility of xanthan gum or the like In the method of Patent Document 1, a technique of bonding a potassium salt to a surface of a powdery xanthan gum or the like has been disclosed. Further, in Patent Document 2, a technique of adding poly-?-glutamic acid or a salt thereof has been disclosed.

[先前技術文獻] [Previous Technical Literature] [專利文獻] [Patent Literature]

[專利文獻1]WO2006/095756 [Patent Document 1] WO2006/095756

[專利文獻2]日本專利特開2009-95341 [Patent Document 2] Japanese Patent Laid-Open No. 2009-95341

在如上述之習知的使黃原膠等對水之分散性提升之技術中,尚有改善的餘地。舉例而言,在專利文獻1所揭示之手段中,儘管藉由使用鉀鹽,黃原膠對水之分散性係提升,但在經賦予黏稠度之飲食品,特定而言,水及其他飲料中,係伴隨著起因於鉀鹽之特有的不愉快風味(例如苦味),難以維持飲食品本來的風味。此外,在專利文獻2所揭示之手段中,儘管藉由聚-γ-麩胺酸抑制增黏多醣類溶解時疙瘩(粉塊)的形成,但在經賦予黏稠度之飲食品中,會強烈表現出獨特的沾黏(牽絲),而損及飲食品本來的鮮嫩口感。 There is still room for improvement in the technique for improving the dispersibility of water such as xanthan gum as described above. For example, in the means disclosed in Patent Document 1, although the dispersibility of water by xanthan gum is improved by using a potassium salt, in the case of a food and drink which is given a viscosity, specifically, water and other beverages Among them, the unpleasant flavor (for example, bitterness) which is caused by the potassium salt is difficult to maintain, and it is difficult to maintain the original flavor of the food and beverage. Further, in the means disclosed in Patent Document 2, although the formation of bismuth (powder) during the dissolution of the polysaccharide-promoting polysaccharide is inhibited by poly-γ-glutamic acid, in the foods and beverages to which the viscosity is imparted, Strongly showing a unique adhesion (drawing), and hurting the original taste of food and beverage.

為了解決上述所代表之課題,反覆致力研究之結果,發現藉由使用離胺酸或天冬胺酸或者該等之鹽,可與鉀鹽同等以上地改善增黏多醣類的分散性。此外,發現藉由使用前述胺基酸或其鹽來代替鉀鹽,能夠在不會對飲食品賦予起因於鉀鹽之獨特的風味之情形下,對飲食品賦予黏稠度。基於該種見解,在進一步研究及檢討之後,遂提供下述所代表之發明。 In order to solve the above-mentioned problems, it has been found that by using the lysine or aspartic acid or the salts, the dispersibility of the polysaccharides can be improved in the same manner as the potassium salts. In addition, it has been found that by using the amino acid or a salt thereof instead of the potassium salt, it is possible to impart a viscosity to a food or drink without giving a flavor to the food or beverage which is caused by the unique flavor of the potassium salt. Based on this insight, after further research and review, the following representative inventions are provided.

1.粉塊形成抑制劑 Powder block inhibitor 1-1. 1-1.

一種增黏多醣類的粉塊形成抑制劑,其係包含選自離胺酸及天冬胺酸以及該等之鹽所組成群組之至少一種。 A powder block forming inhibitor of a viscosity-promoting polysaccharide, which comprises at least one selected from the group consisting of lysine and aspartic acid and a salt thereof.

1-2. 1-2.

如1-1所記載之粉塊形成抑制劑,其中,增黏多醣類為選自黃原膠及瓜爾膠所組成群組之至少一種。 The powder formation inhibitor according to the item 1-1, wherein the polysaccharide-promoting polysaccharide is at least one selected from the group consisting of xanthan gum and guar gum.

1-3. 1-3.

如1-1或1-2所記載之粉塊形成抑制劑,其中,增黏多醣類為黃原膠。 The powder block forming inhibitor according to 1-1 or 1-2, wherein the polysaccharide-promoting polysaccharide is xanthan gum.

1-4. 1-4.

如1-1~1-3中任一項所記載之粉塊形成抑制劑,其係進一步包含糊精。 The powder formation inhibitor according to any one of items 1 to 3, which further comprises a dextrin.

2.增黏劑 2. Adhesive 2-1. 2-1.

一種增黏劑,其係包含選自離胺酸及天冬胺酸以及該等之鹽所組成群組之至少一種、以及增黏多醣類。 A tackifier comprising at least one selected from the group consisting of aminic acid and aspartic acid and salts thereof, and a polysaccharide-promoting polysaccharide.

2-2. 2-2.

如2-1所記載之增黏劑,其中,增黏多醣類為選自黃原膠及瓜爾膠所組成群組之至少一種。 The tackifier according to the item 2-1, wherein the polysaccharide-promoting polysaccharide is at least one selected from the group consisting of xanthan gum and guar gum.

2-3. 2-3.

如2-1或2-2所記載之增黏劑,其中,選自離胺酸及天冬胺酸以及該等之鹽所組成群組之至少一種的含量以乾燥重量換算,係相對於增黏劑100份而言,為1~20份。 The tackifier according to 2-1 or 2-2, wherein the content of at least one selected from the group consisting of amino acid and aspartic acid and the salt thereof is converted in dry weight, relative to increase For 100 parts of the adhesive, it is 1 to 20 parts.

2-4. 2-4.

如2-1~2-3中任一項所記載之增黏劑,其中,增黏多醣類為黃原膠。 The tackifier according to any one of 2-1 to 2-3, wherein the polysaccharide of the viscosity is xanthan gum.

2-5. 2-5.

如2-1~2-4中任一項所記載之增黏劑,其中,增黏多醣類的含量以乾燥重量換算,係相對於增黏劑100份而言,為20~80份。 The tackifier according to any one of the items 2-1 to 2-4, wherein the content of the polysaccharide-promoting polysaccharide is 20 to 80 parts by weight based on 100 parts by weight of the tackifier.

2-6. 2-6.

如2-1~2-5所記載之增黏劑,其係進一步包含糊精。 The tackifier as described in 2-1 to 2-5 further comprises dextrin.

2-7. 2-7.

如2-6所記載之增黏劑,其中,糊精的含量以乾燥重量換算,係相對於增黏劑100份而言,為20~80份。 The tackifier according to 2-6, wherein the content of the dextrin is 20 to 80 parts by weight based on 100 parts of the tackifier.

2-8. 2-8.

如2-1~2-7中任一項所記載之增黏劑,其中,選自 離胺酸及天冬胺酸以及該等之鹽所組成群組之至少一種係黏結至增黏多醣類。 The tackifier according to any one of items 2 to 2-7, wherein At least one of the group consisting of lysine and aspartic acid and the salts thereof is bonded to the viscosifying polysaccharide.

2-9. 2-9.

如2-1~2-8中任一項所記載之增黏劑,其係吞嚥輔助劑。 The viscosity-increasing agent as described in any one of 2-1 to 2-8, which is a swallowing adjuvant.

2-10. 2-10.

一種容器填裝增黏劑,其係在容器中填充2-1~2-9中任一項所記載之增黏劑。 A container is filled with a tackifier which is filled with a tackifier as described in any one of 2-1 to 2-9.

3.飲食品 3. Food and drink 3-1. 3-1.

一種飲食品,其係摻合有2-1~2-10中任一項所記載之增黏劑。 A food or drink comprising a tackifier as described in any one of 2-1 to 2-10.

3-2. 3-2.

如3-1所記載之飲食品,其係吞嚥輔助飲食品。 A food or drink as described in 3-1, which is a swallowing-assisted food or drink.

3-3. 3-3.

如3-1或3-2所記載之飲食品,其中,飲食品為液狀。 The food or drink according to 3-1 or 3-2, wherein the food or drink is in a liquid form.

4.用途 4. Use 4-1. 4-1.

一種選自離胺酸及天冬胺酸以及該等之鹽所組成群組之一種以上之用途,其係用於抑制增黏多醣類的粉塊形成。 A use of one or more selected from the group consisting of aminic acid and aspartic acid, and a salt thereof, for inhibiting the formation of agglomerates of a polysaccharide-promoting polysaccharide.

4-2. 4-2.

如4-1所記載之用途,其中,增黏多醣類為選自黃原膠及瓜爾膠所組成群組之至少一種。 The use according to any one of the items 4-1, wherein the polysaccharide-promoting polysaccharide is at least one selected from the group consisting of xanthan gum and guar gum.

4-3. 4-3.

如4-1或4-2所記載之用途,其中,增黏多醣類為黃原膠。 The use as described in 4-1 or 4-2, wherein the polysaccharide-promoting polysaccharide is xanthan gum.

4-4. 4-4.

如2-1~2-10中任一項所記載之增黏劑之用途,其係用於對飲食品賦予黏稠度。 The use of the tackifier according to any one of 2-1 to 2-10, which is for imparting viscosity to foods and drinks.

4-5. 4-5.

如4-4所記載之用途,其中,飲食品為液狀。 The use according to 4-4, wherein the food or drink is in a liquid form.

5.增黏劑之製法 5. Method for making tackifier 5-1. 5-1.

一種增黏劑之製造方法,其係包含調製溶解有選自離胺酸及天冬胺酸以及該等之鹽所組成群組之至少一種之水溶液、以及將該水溶液噴佈於增黏多醣類。 A method for producing a tackifier, comprising: preparing an aqueous solution in which at least one selected from the group consisting of lysine and aspartic acid and a salt thereof is dissolved, and spraying the aqueous solution on the polysaccharide class.

5-2. 5-2.

如5-1所記載之方法,其係包含使經噴佈該水溶液之增黏多醣類進行乾燥。 The method according to 5-1, which comprises drying the polysaccharide-promoting polysaccharide sprayed with the aqueous solution.

5-3. 5-3.

如5-1或5-2所記載之方法,其係包含在進行該噴佈之前,將該至少一種增黏多醣類與糊精進行混合。 The method of 5-1 or 5-2, wherein the at least one adhesion-promoting polysaccharide is mixed with the dextrin before the spraying.

5-4. 5-4.

如5-1~5-3中任一項所記載之方法,其中,該水溶液包含糊精。 The method of any one of 5-1 to 5-3, wherein the aqueous solution comprises dextrin.

5-5. 5-5.

如5-1~5-4中任一項所記載之方法,其中,增黏多醣類為選自黃原膠及瓜爾膠所組成群組之至少一種。 The method according to any one of 5-1 to 5, wherein the polysaccharide-promoting polysaccharide is at least one selected from the group consisting of xanthan gum and guar gum.

6.飲食品之製造方法 6. Method of manufacturing food and beverage products 6-1. 6-1.

一種具有黏稠度之飲食品之製造方法,其係包含將2-1~2-10中任一項所記載之增黏劑摻合至飲食品中。 A method for producing a food or drink having a viscosity, which comprises blending a tackifier according to any one of 2-1 to 2-10 into a food or beverage.

6-2. 6-2.

如6-1所記載之製造方法,其中,飲食品為液狀的飲食品。 The production method according to 6-1, wherein the food or drink is a liquid food or drink.

6-3. 6-3.

如6-1或6-2所記載之製造方法,其中,飲食品為吞嚥輔助飲食品。 The production method according to 6-1 or 6-2, wherein the food or drink is a swallowing-assisted food or drink.

6-4. 6-4.

如6-1~6-3中任一項所記載之製造方法,其係進一步包含將摻合有該增黏劑之飲食品進行攪拌。 The production method according to any one of 6-1 to 6-3, further comprising stirring the food or beverage to which the thickener is blended.

7.黏稠度之賦予方法 7. Method of imparting viscosity 7-1. 7-1.

一種對飲食品賦予黏稠度之方法,其係包含將2-1~ 2-10中任一項所記載之增黏劑摻合至飲食品中。 A method for imparting viscosity to foods and beverages, which comprises 2-1~ The tackifier described in any one of 2 to 10 is incorporated into a food or drink.

7-2. 7-2.

如7-1所記載之方法,其中,飲食品為液狀的飲食品。 The method according to 7-1, wherein the food or drink is a liquid food or drink.

7-3. 7-3.

如7-1或7-2所記載之方法,其中,飲食品為吞嚥輔助飲食品。 The method according to 7-1 or 7-2, wherein the food or drink is a swallowing auxiliary food or drink.

7-4. 7-4.

如7-1~7-3中任一項所記載之方法,其係進一步包含將摻合有該增黏劑之飲食品進行攪拌。 The method according to any one of items 7-1 to 7-3, further comprising stirring the food or beverage to which the tackifier is blended.

藉由本說明書所揭示之發明,可有效地抑制增黏多醣類的粉塊形成。此外,藉由本說明書所揭示之發明,可在不會對飲食品賦予起因於鉀鹽(例如氯化鉀)之獨特的風味(例如苦味及澀味)之情形下,調整飲食品的黏稠度。 According to the invention disclosed in the present specification, the formation of a powdery mass of the polysaccharide-promoting polysaccharide can be effectively suppressed. Further, according to the invention disclosed in the present specification, the viscosity of the food or drink can be adjusted without imparting a unique flavor (for example, bitterness and astringency) due to a potassium salt (for example, potassium chloride) to foods and drinks.

[圖1]從上側拍攝分散有製造例1所獲得之增黏劑(配方1)之溶液而得之照片。 Fig. 1 is a photograph obtained by photographing a solution in which the tackifier (Formulation 1) obtained in Production Example 1 was dispersed from the upper side.

[圖2]從上側拍攝分散有製造例1所獲得之增黏劑(配方2)之溶液而得之照片。 2] A photograph obtained by photographing a solution in which the tackifier obtained in Production Example 1 (Formulation 2) was dispersed from the upper side.

[圖3]從上側拍攝分散有製造例1所獲得之增黏劑(配方3)之溶液而得之照片。 3] A photograph obtained by photographing a solution in which the tackifier obtained in Production Example 1 (Formulation 3) was dispersed from the upper side.

1.粉塊形成抑制劑 Powder block inhibitor

針對包含選自離胺酸及天冬胺酸以及該等之鹽所組成群組之至少一種之增黏多醣類的粉塊形成抑制劑進行說明。 The powder block formation inhibitor containing a viscosity-increasing polysaccharide selected from at least one selected from the group consisting of amino acid and aspartic acid and such a salt is described.

離胺酸、天冬胺酸、以及該等之鹽只要是能夠在食品的領域中使用者即可,其來源及種類等並無限制。舉例而言,此等可為源自於微生物、動物、或植物之天然物,亦可為藉由化學合成法、或基因重組法所獲得者。離胺酸及麩胺酸係L體、D體、以及此等之混合物(例如消旋體)皆可,較佳為L體。離胺酸、天冬胺酸、以及該等之鹽亦可為水合物。 The lysine, the aspartic acid, and the salt thereof are not limited as long as they can be used in the food field, and the source and type thereof are not limited. For example, these may be natural products derived from microorganisms, animals, or plants, or may be obtained by chemical synthesis or genetic recombination. The lysine and glutamic acid L bodies, D bodies, and mixtures thereof (e.g., racemates) may be used, and L bodies are preferred. The lysine, aspartic acid, and salts thereof may also be hydrates.

作為離胺酸或天冬胺酸之「鹽」,只要是在食品的領域中可容許之鹽,即無特別限制。作為此種鹽,可列舉例如與無機鹼之鹽、與無機酸之鹽、以及與有機酸之鹽等。作為與無機鹼之鹽,可列舉鈉、鉀、及鋰等鹼金屬鹽、鈣、及鎂等鹼土金屬鹽、以及銨鹽等。作為與無機酸之鹽,可列舉與氫鹵酸(鹽酸、氫溴酸、及氫碘酸等)、硫酸、硝酸、及磷酸等之鹽。作為與有機酸之鹽,可列舉與蟻酸、醋酸、丙酸、草酸、琥珀酸、馬來酸、富 馬酸、及檸檬酸等之鹽。在一實施形態中,較佳的鹽為鈉鹽、鉀鹽、及鹽酸鹽等。 The "salt" of the acid or the aspartic acid is not particularly limited as long as it is a salt which is acceptable in the field of foods. Examples of such a salt include a salt with an inorganic base, a salt with an inorganic acid, and a salt with an organic acid. Examples of the salt with the inorganic base include alkali metal salts such as sodium, potassium, and lithium, alkaline earth metal salts such as calcium and magnesium, and ammonium salts. Examples of the salt with the inorganic acid include salts with hydrohalic acids (hydrochloric acid, hydrobromic acid, and hydroiodic acid), sulfuric acid, nitric acid, and phosphoric acid. Examples of the salt with an organic acid include formic acid, acetic acid, propionic acid, oxalic acid, succinic acid, maleic acid, and rich. A salt of horse acid, citric acid or the like. In one embodiment, preferred salts are sodium salts, potassium salts, and hydrochloride salts.

增黏多醣類只要是可在食品的領域中使用者即可,其種類及來源等並無限制。作為增黏多醣類,可列舉例如琥珀醯聚醣、結蘭膠、天然結蘭膠、天然型結蘭膠、脫醯型結蘭膠、鹿角菜膠(κ、、λ、μ、ν、θ、ζ、或π)、紅藻膠、黃原膠、葡甘露聚糖、刺槐豆膠、塔拉膠、車前子膠、海藻酸及其鹽、果膠、甲基纖維素、羧甲基纖維素及其鹽、羅望子膠、棕色固氮菌(Azotobacter vinelandii)膠、硫酸軟骨素及其鹽、瓜爾膠、瓜爾膠酵素分解物、阿拉伯膠、阿拉伯木聚醣、阿拉伯半乳聚醣、刺梧桐膠、肉桂膠、水溶性或水不溶性大豆多醣類、沙蒿籽膠、大莖點黴膠、黃蓍膠、羥丙基纖維素(HPC)、羥乙基纖維素(HEC)、澱粉、明膠、鼠李聚醣膠、瓊脂、卡特蘭多醣、威蘭膠、普魯蘭多醣、黃蓍膠、甘地膠、PGA、化工或加工澱粉、澱粉水解物、環糊精、幾丁質、幾丁聚醣、卵白、乳清蛋白、乳白蛋白、乳球蛋白、牛血清白蛋白、以及大豆蛋白等。在一實施形態中,從分散性之觀點而言,增黏多醣類較佳為黃原膠及瓜爾膠,更佳為黃原膠。 The polysaccharide of the polysaccharide can be used as long as it can be used in the field of foods, and the type and source thereof are not limited. Examples of the polysaccharide-promoting polysaccharides include amber sulphate, sulphate, natural sulphate, natural sulphate, deodorized sulphate, carrageenan (κ, , λ, μ, ν, θ, ζ, or π), red algae, xanthan gum, glucomannan, locust bean gum, tara gum, psyllium gum, alginic acid and its salts, pectin, Methylcellulose, carboxymethylcellulose and its salts, tamarind gum, Azotobacter vinelandii gum, chondroitin sulfate and its salts, guar gum, guar enzyme decomposition products, gum arabic, arabian wood Glycan, arabinogalactan, karaya gum, cassia gum, water-soluble or water-insoluble soybean polysaccharide, artemisia seed gum, big stem mold, gum tragacanth, hydroxypropyl cellulose (HPC), Hydroxyethyl cellulose (HEC), starch, gelatin, rhamnose gel, agar, carterin, welan gum, pullulan, tragacanth, glycyrrhizin, PGA, chemical or processed starch, starch hydrolysis , cyclodextrin, chitin, chitosan, egg white, whey protein, lactalbumin, lactoglobulin, bovine serum albumin, and soy protein. In one embodiment, from the viewpoint of dispersibility, the polysaccharide-promoting polysaccharide is preferably xanthan gum or guar gum, more preferably xanthan gum.

粉塊形成抑制劑可為僅由選自離胺酸及天冬胺酸以及該等之鹽所組成群組之至少一種所構成之構造,亦可視需要包含任意的其他成分(例如pH調整劑及礦物質類等)。在一實施形態中,從更有效地發揮粉塊形成的 抑制效果之觀點而言,粉塊形成抑制劑較佳係進一步包含糊精。糊精只要是可在食品的領域中使用者即可,其種類及來源等並無限制。在一實施形態中,從更有效地發揮分散性的提升效果之觀點而言,糊精較佳係右旋糖當量(DE)為6~30,更佳為6~25。 The powder formation inhibitor may be a structure composed only of at least one selected from the group consisting of lysine and aspartic acid, and the salt thereof, and may optionally contain any other components (for example, a pH adjuster and Minerals, etc.). In one embodiment, the powder formation is more effectively utilized. From the viewpoint of the inhibitory effect, the powder formation inhibitor preferably further contains dextrin. As long as it is a user who can be used in the field of food, the type of dextrin is not limited. In one embodiment, the dextrin preferably has a dextrose equivalent (DE) of from 6 to 30, more preferably from 6 to 25, from the viewpoint of more effectively exhibiting the effect of improving the dispersibility.

在粉塊形成抑制劑包含糊精之情況,(a)選自離胺酸及天冬胺酸以及該等之鹽所組成群組之至少一種與(b)糊精之(摻合)比率,只要可發揮粉塊抑制效果,即無特別限制。舉例而言,該比率以乾燥重量換算,係(a):(b)=30:1~200:1。 In the case where the powder formation inhibitor contains dextrin, (a) a ratio of at least one selected from the group consisting of amino acid and aspartic acid and the salts thereof, and (b) dextrin (blending) ratio, There is no particular limitation as long as the powder block suppression effect can be exerted. For example, the ratio is expressed as dry weight, which is (a): (b) = 30:1 to 200:1.

在一實施形態中,從風味或口感之觀點而言,粉塊形成抑制劑較佳係不含氯化鉀及/或聚-γ-麩胺酸。 In one embodiment, the powder formation inhibitor is preferably free of potassium chloride and/or poly-gamma-glutamic acid from the viewpoint of flavor or texture.

粉塊形成抑制劑可藉由摻合至增黏多醣類(或包含該等之組成物)中而使用。 The powder formation inhibitor can be used by blending into the (or containing) the adhesion-promoting polysaccharide.

2.增黏劑 2. Adhesive

本發明係提供包含選自離胺酸及天冬胺酸以及該等之鹽所組成群組之至少一種、以及增黏多醣類之增黏劑(即,包含上述1.之粉塊形成抑制劑以及增黏多醣類之增黏劑)。在一實施形態中,增黏劑係指對液體的飲食品賦予黏性之食品(或食品添加物),其係與「黏稠度調整劑」、或「膠化劑」同義。 The present invention provides a viscosity-increasing agent comprising at least one selected from the group consisting of lysine and aspartic acid, and a salt of the same, and a viscosity-increasing agent (i.e., the formation of the powder comprising the above 1.) Agents and tackifiers for polysaccharides) In one embodiment, the tackifier refers to a food (or food additive) that imparts viscosity to a liquid food or drink, and is synonymous with a "stickiness adjuster" or a "gelling agent".

增黏劑中可包含之離胺酸、天冬胺酸、及該 等之鹽、以及增黏多醣類係如上述1.之粉塊形成抑制劑之項目中所說明。 An amine acid, aspartic acid, and the like which may be included in the tackifier The salt and the polysaccharide-promoting polysaccharide are as described in the item of the above-mentioned powder forming inhibitor.

增黏劑中所包含之選自離胺酸及天冬胺酸以及該等之鹽所組成群組之至少一種的含量為任意,可視賦予黏性之飲食品或種類以及應達成之飲食品的黏度等而適宜設定。舉例而言,增黏劑中所包含之選自離胺酸及天冬胺酸以及該等之鹽所組成群組之至少一種的含量以乾燥重量換算,係相對於增黏劑100份而言,為1~20份,較佳為3~15份,更佳為7~15份。此等數值範圍係包含下限為1份且上限為20份、或15份之情況、下限為3份且上限為20份或15份之情況、下限為7份且上限為20份或15份之情況。 The content of at least one selected from the group consisting of lysine and aspartic acid and a salt thereof is included in the viscosity-increasing agent, and may be visibly imparted to the viscous food or drink and the food and drink to be achieved. It is suitable for setting such as viscosity. For example, the content of at least one selected from the group consisting of amino acid and aspartic acid and the salt thereof contained in the tackifier is in dry weight, relative to 100 parts of the tackifier. It is 1 to 20 parts, preferably 3 to 15 parts, more preferably 7 to 15 parts. These numerical ranges are those in which the lower limit is 1 part and the upper limit is 20 parts, or 15 parts, the lower limit is 3 parts, the upper limit is 20 parts or 15 parts, the lower limit is 7 parts, and the upper limit is 20 parts or 15 parts. Happening.

增黏劑中所包含之增黏多醣類的含量可視賦予黏性之飲食品或種類以及所達成之飲食品的黏度等而適宜設定。舉例而言,增黏劑中所包含之增黏多醣類的含量以乾燥重量換算,係相對於增黏劑100份而言,為20~80份,較佳為25~70份,更佳為30~70份。此等數值範圍係包含下限為10份且上限為80份、或70份之情況、下限為25份且上限為80份、或70份之情況、下限為30份且上限為80份、或70份之情況。 The content of the polysaccharide-promoting polysaccharide contained in the tackifier can be appropriately set depending on the food or drink to which the viscosity is applied, the viscosity of the food or drink to be obtained, and the like. For example, the content of the polysaccharide-promoting polysaccharide contained in the tackifier is 20 to 80 parts, preferably 25 to 70 parts, more preferably 100 parts by weight based on the dry weight. It is 30~70 copies. These numerical ranges include the case where the lower limit is 10 parts and the upper limit is 80 parts or 70 parts, the lower limit is 25 parts, the upper limit is 80 parts, or 70 parts, the lower limit is 30 parts, and the upper limit is 80 parts, or 70. The situation.

在一實施形態中,增黏劑較佳係含有糊精。在增黏劑含有糊精之情況,糊精的含量係例如以乾燥重量換算,相對於增黏劑100份而言,為20~80份,較佳為25~80份,更佳為30~75份。此等數值範圍係包含下限 為20份且上限為80份、或75份之情況、下限為25份且上限為80份、或75份之情況、下限為30份且上限為80份或75份之情況。 In one embodiment, the tackifier preferably contains dextrin. In the case where the tackifier contains dextrin, the content of the dextrin is, for example, in terms of dry weight, and is 20 to 80 parts, preferably 25 to 80 parts, more preferably 30 parts, per 100 parts of the tackifier. 75 copies. These numerical ranges contain the lower limit In the case of 20 parts and the upper limit is 80 parts or 75 parts, the lower limit is 25 parts, the upper limit is 80 parts, or 75 parts, the lower limit is 30 parts, and the upper limit is 80 parts or 75 parts.

增黏劑的構造為任意,只要可發揮所期望的黏性附加效果,即無特別限制。從更有效地抑制增黏多醣類所引發之粉塊形成之觀點而言,增黏劑較佳係具有選自離胺酸及天冬胺酸以及該等之鹽所組成群組之至少一種黏結至增黏多醣類之構造。 The structure of the tackifier is arbitrary, and is not particularly limited as long as the desired viscous additional effect can be exerted. The tackifier preferably has at least one selected from the group consisting of lysine and aspartic acid and a salt thereof, from the viewpoint of more effectively inhibiting the formation of agglomerates caused by the polysaccharide-promoting polysaccharide. Bonded to the structure of the viscosifying polysaccharide.

增黏劑的形狀並無特別限制。舉例而言,增黏劑可為粉末狀或液狀。從更有效地發揮保存性的提升效果之觀點而言,增黏劑較佳為粉末狀。增黏劑的粒徑係越細小,越容易表現黏度,但容易形成粉塊(疙瘩)。增黏劑的粒徑較佳係250μm以下的顆粒為10%以下。增黏劑的粒徑為250μm以下可藉由將粉末狀的增黏劑通過孔徑為250μm之篩(60網目)而進行測定。 The shape of the tackifier is not particularly limited. For example, the tackifier can be in the form of a powder or a liquid. The tackifier is preferably in the form of a powder from the viewpoint of more effectively exerting the effect of preservability. The finer the particle size of the tackifier, the easier it is to express the viscosity, but it is easy to form a powder. The particle size of the tackifier is preferably 10% or less of particles of 250 μm or less. The particle size of the tackifier is 250 μm or less, which can be measured by passing a powdery tackifier through a sieve having a pore size of 250 μm (60 mesh).

在一實施形態中,增黏劑較佳為不僅會抑制粉塊形成,在水中黏稠度的表現亦迅速者。在一實施形態中,增黏劑係以3g添加至100g(100ml)的離子交換水中,以塑膠製的藥匙攪拌20秒,並靜置5分鐘後緊接之水黏度為5000mPa‧s以上。較佳為5400mPa‧s以上,更佳為5800mPa‧s以上。此外,在一實施形態中,增黏劑較佳為不僅會抑制粉塊形成,在鹽水中黏稠度的表現亦迅速者。在一實施形態中,增黏劑係以3g添加至100g(100ml)的食鹽水(2重量%)中,以塑膠製的藥匙攪 拌20秒,並靜置5分鐘後緊接之鹽水黏度為1500mPa‧s以上。較佳為1800mPa‧s以上,更佳為2200mPa‧s以上。水黏度及鹽水黏度可使用例如B型黏度計(旋轉速度:12rpm,旋轉時間:30秒,轉子:M3,東機產業公司製)予以測定。 In one embodiment, the tackifier preferably not only inhibits the formation of the powder, but also exhibits a rapid viscosity in water. In one embodiment, the tackifier is added to 100 g (100 ml) of ion-exchanged water in an amount of 3 g, stirred with a plastic spatula for 20 seconds, and allowed to stand for 5 minutes, and the water viscosity immediately after it is 5000 mPa·s or more. It is preferably 5400 mPa ‧ or more, more preferably 5800 mPa ‧ s or more. Further, in one embodiment, it is preferred that the tackifier not only inhibits the formation of the powder, but also exhibits a rapid increase in the viscosity in the brine. In one embodiment, the tackifier is added to 100 g (100 ml) of saline (2% by weight) in 3 g, and stirred with a plastic spoon. Mix for 20 seconds, and let stand for 5 minutes, then the salt water viscosity is above 1500mPa‧s. It is preferably 1800 mPa ‧ or more, more preferably 2200 mPa ‧ s or more. The water viscosity and the viscosity of the salt water can be measured using, for example, a B-type viscometer (rotation speed: 12 rpm, rotation time: 30 seconds, rotor: M3, manufactured by Toki Sangyo Co., Ltd.).

增黏劑可添加至液體的飲食品中而使用。藉由將增黏劑添加至液體的飲食品中,可對食品附加黏性。對液體的飲食品附加黏性係有助於吞嚥輔助。因此,在一實施形態中,增黏劑係使用作為吞嚥輔助劑。 The tackifier can be added to a liquid food or drink. Viscosity can be added to foods by adding a tackifier to the liquid food or beverage. Adding a viscous line to liquid foods and beverages helps with swallowing. Therefore, in one embodiment, the tackifier is used as a swallowing aid.

摻合至飲食品中之增黏劑的量為任意,可視作為目的之黏度的強度等而適宜設定。舉例而言,增黏劑可在飲料中以每100ml為0.5~5重量%,較佳為1~3重量%進行摻合。此等數值範圍係包含下限為0.5重量%且上限為5重量%或3重量%之情況、以及下限為1重量%且上限為5重量%或3重量%之情況。 The amount of the tackifier blended into the food or drink is arbitrary, and can be appropriately set depending on the strength of the viscosity to be used. For example, the tackifier may be blended in the beverage at 0.5 to 5% by weight, preferably 1 to 3% by weight, per 100 ml. These numerical ranges include the case where the lower limit is 0.5% by weight and the upper limit is 5% by weight or 3% by weight, and the lower limit is 1% by weight and the upper limit is 5% by weight or 3% by weight.

增黏劑所摻合之飲食品為任意,只要是液狀的飲食品,即無特別限制。作為飲食品,可列舉例如水、茶飲料、果汁、清涼飲料水、牛乳、發酵乳飲料、及乳酸菌飲料等飲料、湯汁、味噌湯、沙拉醬、拉麵、烏龍麵、湯意麵、流質食物、及混合食品等食品。在一實施形態中,增黏劑亦可使用於對液狀的醫藥品、及化妝品賦予黏性。 The food or drink to which the tackifier is blended is arbitrary, and is not particularly limited as long as it is a liquid food or drink. Examples of foods and drinks include beverages such as water, tea beverages, fruit juices, refreshing beverage water, milk, fermented milk beverages, and lactic acid bacteria beverages, soups, miso soups, salad dressings, ramen noodles, oolong noodles, soup noodles, and liquids. Food, and mixed foods. In one embodiment, the tackifier may be used to impart viscosity to liquid pharmaceuticals and cosmetics.

可將增黏劑填充於任意的容器中,而製成容器填裝增黏劑。用於填充增黏劑之容器只要適於食品的保 存,即無特別限制。舉例而言,在增黏劑為粉末狀之情況,作為用於填充增黏劑之容器,可列舉例如合成樹脂製之袋、包含阻隔性層(例如鋁等金屬箔、乙烯-乙烯醇共聚物、或二氯亞乙烯系聚合物等)及熱封性樹脂層之積層材袋、PET瓶、金屬罐、紙容器等。從填充的效率及保存性之觀點而言,用於填充增黏劑之容器較佳為包含阻隔性層(鋁等金屬箔)及熱封性樹脂層之積層材袋,更佳為可進行再包裝之形態及/或可包裝1次份之形態的積層袋。在此種容器中,可僅填充增黏劑,亦可視需要加入任意的其他成分(例如乾燥劑)進行填充。 The tackifier can be filled in any container and the container is filled with a tackifier. The container used to fill the tackifier is suitable for food protection. There is no special restriction. For example, in the case where the tackifier is in the form of a powder, the container for filling the tackifier may, for example, be a bag made of a synthetic resin, or include a barrier layer (for example, a metal foil such as aluminum or an ethylene-vinyl alcohol copolymer). Or a vinyl chloride polymer or the like, and a laminate bag of a heat sealable resin layer, a PET bottle, a metal can, a paper container, or the like. The container for filling the tackifier is preferably a laminated material bag including a barrier layer (a metal foil such as aluminum) and a heat-sealable resin layer, from the viewpoint of the efficiency of the filling and the preservability, and more preferably A laminated bag in the form of a package and/or in a form that can be packaged in one portion. In such a container, only the tackifier may be filled, and any other ingredients (such as a desiccant) may be added for filling as needed.

在增黏劑為液體狀(液狀)之情況,作為用於填充增黏劑之容器,可列舉例如合成樹脂製之袋、包含阻隔性層(鋁等金屬箔、乙烯-乙烯醇共聚物、或二氯亞乙烯系聚合物等)及熱封性樹脂層之積層材袋、附遮光性薄膜之管材、附遮光性薄膜之PET瓶、金屬罐、以及紙容器等。從保存性之觀點而言,用於填充增黏劑之容器較佳為包含阻隔性層(鋁等金屬箔)及熱封性樹脂層之積層材袋、管材、以及金屬罐,在使用PET瓶等之情況,較佳係以不會透光或氧之薄膜進行覆蓋。 In the case where the tackifier is in the form of a liquid (liquid), the container for filling the tackifier may, for example, be a synthetic resin bag or a barrier layer (a metal foil such as aluminum or an ethylene-vinyl alcohol copolymer, Or a laminate of a heat-sealable resin layer, a tube with a light-shielding film, a PET bottle with a light-shielding film, a metal can, and a paper container. From the viewpoint of preservability, the container for filling the tackifier is preferably a laminate bag, a tube, and a metal can including a barrier layer (a metal foil such as aluminum) and a heat-sealable resin layer, and a PET bottle is used. In other cases, it is preferred to cover with a film that does not transmit light or oxygen.

如上述般經容器填裝之增黏劑可視需要製成組合有任意的其他食品之飲食品。 The tackifier filled in the container as described above may be prepared into a food or beverage combination of any other food as needed.

3.飲食品 3. Food and drink

本發明係提供摻合有上述2.所說明之增黏劑之飲食 品。在此處,針對摻合至飲食品中之成分,係如上述1~2.中所說明。摻合有增黏劑之飲食品並不限於上述飲料及食品,亦包含凍狀或膠狀的飲食品。由於摻合有增黏劑之飲食品係經附加黏性,因而可利用作為吞嚥輔助食品。 The present invention provides a diet incorporating the tackifier described in 2. above. Product. Here, the ingredients blended into the food or beverage are as described in the above 1 to 2. Foods and beverages incorporating a tackifier are not limited to the above beverages and foods, and include frozen or gelled foods and drinks. Since the dietary supplement blended with the tackifier is additionally viscous, it can be utilized as a swallowing auxiliary food.

4.用途 4. Use

如上述,可藉由離胺酸、天冬胺酸、或該等之鹽抑制增黏多醣類所引發之粉塊形成。從而,本發明係提供離胺酸、天冬胺酸、或該等之鹽用於抑制增黏多醣類所引發之粉塊形成之用途(或使用方法)。 As described above, the formation of agglomerates caused by the adhesion-promoting polysaccharide can be inhibited by the removal of the amine acid, aspartic acid, or the like. Accordingly, the present invention provides the use (or method of use) of the amine acid, aspartic acid, or the like for inhibiting the formation of a powder mass caused by a polysaccharide-promoting polysaccharide.

藉由將上述之增黏劑摻合至飲食品中,可一面抑制粉塊形成,一面對飲食品賦予黏性(或黏稠度)。因此,本發明係提供增黏劑用於對飲食品賦予黏稠度之用途(或黏稠度賦予方法)。增黏劑對飲食品之摻合比例等係如上述。 By blending the above-mentioned tackifier into foods and drinks, it is possible to suppress the formation of powders and to impart viscosity (or consistency) to foods and drinks. Accordingly, the present invention provides a use of a tackifier for imparting a viscosity to a food or drink (or a method for imparting a viscosity). The blending ratio of the tackifier to the food or drink is as described above.

5.增黏劑之製法 5. Method for making tackifier

包含選自離胺酸及天冬胺酸以及該等之鹽所組成群組之至少一種、以及增黏多醣類之增黏劑之製造方法為任意。舉例而言,可將選自離胺酸及天冬胺酸以及該等之鹽所組成群組之至少一種、以及增黏多醣類、以及視需要糊精進行混合而獲得增黏劑。此混合係以粉末狀施行、在水溶液(液體)中施行皆可。各成分之混合順序為任意。 The method for producing a tackifier comprising at least one selected from the group consisting of amino acid and aspartic acid and such salts, and a viscosity-increasing polysaccharide is optional. For example, at least one selected from the group consisting of amino acid and aspartic acid and the salts thereof, and a polysaccharide-promoting polysaccharide, and optionally a dextrin may be mixed to obtain a tackifier. This mixing is carried out in the form of a powder and can be carried out in an aqueous solution (liquid). The mixing order of each component is arbitrary.

在一實施形態中,從有效地抑制增黏劑所引 發之粉塊形成之觀點而言,增黏劑較佳係以包含(1)調製溶解有選自離胺酸及天冬胺酸以及該等之鹽所組成群組之至少一種之水溶液、以及(2)將該水溶液噴佈於增黏多醣類之方法予以製造。 In one embodiment, the effective introduction of the tackifier is From the viewpoint of the formation of the powder block, the tackifier preferably comprises (1) an aqueous solution prepared by dissolving at least one selected from the group consisting of lysine and aspartic acid and salts thereof; (2) A method in which the aqueous solution is sprayed on a polysaccharide-promoting polysaccharide.

溶解有選自離胺酸及天冬胺酸以及該等之鹽所組成群組之至少一種之水溶液可藉由將選自離胺酸及天冬胺酸以及該等之鹽所組成群組之至少一種添加至水中,視需要進行攪拌而獲得。此水溶液有時亦稱為黏合劑液。水溶液中之選自離胺酸及天冬胺酸以及該等之鹽所組成群組之至少一種的濃度並無特別限制,舉例而言,水溶液(液體)中之離胺酸、天冬胺酸、或該等之鹽的濃度為0.5~15重量%,較佳為1~13重量%,更佳為1~11重量%。此等數值範圍係包含下限為0.5重量%且上限為15重量%、13重量%、或11重量%之情況、以及下限為1重量%且上限為15重量%、13重量%、或11重量%之情況。 An aqueous solution in which at least one selected from the group consisting of amino acid and aspartic acid, and a salt thereof, is dissolved by a group selected from the group consisting of lysine and aspartic acid and salts thereof At least one is added to water and obtained by stirring as needed. This aqueous solution is sometimes also referred to as a binder liquid. The concentration of at least one selected from the group consisting of amino acid and aspartic acid and the salt of the salt in the aqueous solution is not particularly limited. For example, the lyophilic acid and aspartic acid in the aqueous solution (liquid) Or the concentration of the salt is from 0.5 to 15% by weight, preferably from 1 to 13% by weight, more preferably from 1 to 11% by weight. These numerical ranges include a lower limit of 0.5% by weight and an upper limit of 15% by weight, 13% by weight, or 11% by weight, and a lower limit of 1% by weight and an upper limit of 15% by weight, 13% by weight, or 11% by weight. The situation.

在一實施形態中,上述水溶液較佳係含有糊精。水溶液中之糊精的濃度並無特別限制,舉例而言,為20~40重量%,較佳為25~35重量%。此等數值範圍係包含下限為20重量%且上限為40重量%或35重量%之情況、以及下限為25重量%且上限為40重量%或35重量%之情況。藉由在水溶液中摻合糊精,可使離胺酸、天冬胺酸、或該等之鹽容易黏結至增黏多醣類。 In one embodiment, the aqueous solution preferably contains dextrin. The concentration of the dextrin in the aqueous solution is not particularly limited, and is, for example, 20 to 40% by weight, preferably 25 to 35% by weight. These numerical ranges include the case where the lower limit is 20% by weight and the upper limit is 40% by weight or 35% by weight, and the lower limit is 25% by weight and the upper limit is 40% by weight or 35% by weight. By blending dextrin in an aqueous solution, the lysine, aspartic acid, or such salts can be readily bonded to the viscosifying polysaccharide.

調製上述水溶液之條件並無特別限制,舉例而言,可在常壓常溫下進行調整。上述水溶液的pH值並 無特別限制,舉例而言,為3~8。從上述水溶液與離胺酸、天冬胺酸、或該等之鹽之風味的相性之觀點而言,較佳為4~7.5。 The conditions for preparing the above aqueous solution are not particularly limited, and for example, it can be adjusted at normal temperature and normal temperature. The pH of the above aqueous solution is There is no particular limitation, for example, 3 to 8. From the viewpoint of the affinity of the above aqueous solution with the acidity of the amine acid, aspartic acid or the salt, it is preferably from 4 to 7.5.

可將上述水溶液以任意的手段對增黏多醣類進行噴佈,較佳係將上述水溶液均勻地噴佈於增黏多醣類。接著,經噴佈水溶液之增黏多醣類係視需要進行乾燥。此噴佈可例如以可一面噴佈液體,一面將粉體進行造粒之裝置(例如SFC-LABO,Freund產業(股)製)施行。從更有效地發揮分散性或保存性的提升效果之觀點而言,經乾燥之增黏多醣類的水分含量係例如為8%重量以下。較佳為7%重量以下,更佳為6%重量以下。 The above aqueous solution may be sprayed on the polysaccharide-promoting polysaccharide by any means, and it is preferred to spray the aqueous solution uniformly on the polysaccharide-promoting polysaccharide. Next, the polysaccharide-promoting polysaccharide which is sprayed with the aqueous solution is dried as needed. This spray can be applied, for example, to a device that granulates a powder while spraying a liquid (for example, SFC-LABO, manufactured by Freund Industries Co., Ltd.). The moisture content of the dried polysaccharide-promoting polysaccharide is, for example, 8% by weight or less from the viewpoint of more effectively exhibiting the effect of improving dispersibility or preservability. It is preferably 7% by weight or less, more preferably 6% by weight or less.

可將上述水溶液僅噴佈於增黏多醣類,較佳係將上述水溶液噴佈於增黏多醣類及糊精之混合物。此外,只要不會阻礙增黏劑的特性及粉塊形成抑制效果(作用),在此混合物中亦可包含任意的其他成分。在此混合物中,增黏多醣類與糊精之(摻合)比率只要不會阻礙增黏劑的特性及粉塊抑制效果,即無特別限制。舉例而言,該比率以乾燥重量換算,係增黏多醣類:糊精=1~3:1~5。從分散性之觀點而言,該比率較佳為1~2:1~5。 The aqueous solution may be sprayed only on the polysaccharide-promoting polysaccharide, and it is preferred to spray the aqueous solution onto a mixture of the polysaccharide-promoting polysaccharide and the dextrin. Further, any other components may be contained in the mixture as long as the properties of the tackifier and the powder formation inhibiting effect (action) are not inhibited. In this mixture, the ratio of the polysaccharide-adhering polysaccharide to the dextrin is not particularly limited as long as it does not hinder the characteristics of the tackifier and the powder suppressing effect. For example, the ratio is in terms of dry weight, which is a viscosity-promoting polysaccharide: dextrin = 1 to 3: 1 to 5. From the viewpoint of dispersibility, the ratio is preferably from 1 to 2:1 to 5.

噴佈於增黏多醣類或上述混合物之上述水溶液的量只要可獲得所期望的粉塊形成抑制效果(作用),即無特別限制。舉例而言,增黏多醣類或上述混合物與上述水溶液之比例係相對於80~90重量份(增黏多醣類或混合物)而言為20~30重量份(水溶液)。 The amount of the above aqueous solution sprayed on the polysaccharide-promoting polysaccharide or the above mixture is not particularly limited as long as the desired powder formation inhibiting effect (action) can be obtained. For example, the ratio of the adhesion-promoting polysaccharide or the above mixture to the above aqueous solution is 20 to 30 parts by weight (aqueous solution) with respect to 80 to 90 parts by weight (tackifying polysaccharide or mixture).

[實施例] [Examples]

以下,藉由實施例,針對本發明進一步詳細地進行說明,但本發明並不限制於此等。 Hereinafter, the present invention will be described in further detail by way of examples, but the invention is not limited thereto.

<製造例1:增黏劑的調製(氯化鉀、離胺酸、甘胺酸)> <Manufacturing Example 1: Preparation of tackifier (potassium chloride, lysine, glycine)>

如表1所示,將58重量份的糊精及33重量份的黃原膠進行混合,而獲得混合粉末。此外,將8重量份的糊精溶解於15重量份的水中之後,添加1重量份的氯化鉀並使其溶解,而獲得黏合劑液。使用造粒裝置(SFC-LABO,Freund產業(股)製)),一面對糊精及黃原膠之混合粉末噴佈黏合劑液(全量),一面將糊精及黃原膠之混合粉末進行造粒,獲得增黏劑(配方1)。 As shown in Table 1, 58 parts by weight of dextrin and 33 parts by weight of xanthan gum were mixed to obtain a mixed powder. Further, after dissolving 8 parts by weight of dextrin in 15 parts by weight of water, 1 part by weight of potassium chloride was added and dissolved to obtain a binder liquid. A granulation device (SFC-LABO, manufactured by Freund Industries Co., Ltd.), a mixed powder of dextrin and xanthan gum, and a mixture of dextrin and xanthan gum Granulation was carried out to obtain a tackifier (Formulation 1).

如表1所示,除了將混合粉末中所包含之糊精的摻合量變更為56重量份,並將黏合劑液中所摻合之氯化鉀變更為3重量份的離胺酸鹽酸鹽以外,係依與配方1同樣之方式,獲得增黏劑(配方2)。 As shown in Table 1, except that the blending amount of the dextrin contained in the mixed powder was changed to 56 parts by weight, and the potassium chloride blended in the binder liquid was changed to 3 parts by weight of the peri-acid acid. In addition to the salt, a tackifier (Formulation 2) was obtained in the same manner as in Formulation 1.

如表1所示,除了將黏合劑液中所摻合之氯化鉀變更為1重量份的甘胺酸以外,係依與配方1同樣之方式,獲得增黏劑(配方3)。 As shown in Table 1, a tackifier (Formulation 3) was obtained in the same manner as in Formulation 1, except that potassium chloride blended in the binder liquid was changed to 1 part by weight of glycine.

<試驗例1:黏稠度的表現及分散性之評估> <Test Example 1: Evaluation of Viscosity and Dispersibility>

使用下列評估方法,針對製造例1所獲得之各增黏劑,評估黏稠度(黏度)的表現性、及分散性(粉塊形成的抑制效果)。增黏劑較理想為在所定的水、或鹽水中,黏稠度的表現迅速、不會形成團塊、及團塊(在形成之情況)細小。 The viscosity (viscosity) expression and dispersibility (inhibition effect of powder formation) were evaluated for each of the tackifiers obtained in Production Example 1 using the following evaluation methods. Preferably, the tackifier is in a given water or brine, and the viscosity is expressed rapidly, does not form agglomerates, and the agglomerates (in the case of formation) are fine.

<黏稠度(黏度)的表現之評估方法> <Evaluation method of the performance of viscosity (viscosity)>

在玻璃製的燒杯(100ml容積)中準備100g的離子交換水,於室溫加入3g的增黏劑,以塑膠製的藥匙攪拌20秒,並靜置5分鐘後,測定水黏度。在水黏度為5000mPa‧s以上之情況,評估為黏稠度的表現良好。 100 g of ion-exchanged water was prepared in a glass beaker (100 ml volume), 3 g of a tackifier was added at room temperature, and the mixture was stirred for 20 seconds with a plastic spoon and allowed to stand for 5 minutes, and then the water viscosity was measured. In the case where the water viscosity was 5000 mPa ‧ or more, it was evaluated that the viscosity was good.

在玻璃製的燒杯(100ml容積)中準備100g的食鹽水(2重量%),加入3g的增黏劑,以塑膠製的藥匙攪拌20秒,並靜置5分鐘後,測定鹽水黏度。在鹽水 黏度為1500mPa‧s以上之情況,評估為在鹽水中之黏稠度的表現良好。 100 g of saline (2% by weight) was prepared in a glass beaker (100 ml volume), 3 g of a tackifier was added, and the mixture was stirred for 20 seconds with a plastic spoon, and allowed to stand for 5 minutes, and then the viscosity of the salt was measured. In brine When the viscosity was 1500 mPa ‧ or more, it was evaluated that the viscosity in the saline was good.

使用B型黏度計(旋轉速度:12rpm,旋轉時間:30秒,轉子:M3,東機產業公司製),測定水黏度及鹽水黏度。 Water viscosity and salt water viscosity were measured using a B-type viscometer (rotation speed: 12 rpm, rotation time: 30 seconds, rotor: M3, manufactured by Toki Sangyo Co., Ltd.).

<分散性之評估方法> <Evaluation method of dispersibility>

在玻璃製的燒杯(100ml容積)中,準備100g的食鹽水(0.025重量%),加入2g的增黏劑,靜置2秒,以磁力式攪拌器(攪拌棒的長度:4cm)攪拌10秒後,確認團塊的狀態。接著,以表2所示之4個階段,評估增黏劑的分散性。各增黏劑的分散性係以各3次進行評估。 In a glass beaker (100 ml volume), 100 g of saline solution (0.025% by weight) was prepared, 2 g of a tackifier was added, and the mixture was allowed to stand for 2 seconds, and stirred for 10 seconds with a magnetic stirrer (length of the stirring bar: 4 cm). After that, confirm the status of the bunk. Next, the dispersibility of the tackifier was evaluated in four stages shown in Table 2. The dispersibility of each tackifier was evaluated three times each.

針對配方1~3,將關於黏稠度的表現性之評估結果示於表3,將關於分散性之評估結果示於表4。此外,針對配方1~3,將從上側拍攝分散有各增黏劑之溶液而得之照片示於圖1。 The results of the evaluation of the expression of the viscosity for the formulations 1 to 3 are shown in Table 3, and the results of the evaluation regarding the dispersibility are shown in Table 4. Further, for the formulations 1 to 3, a photograph obtained by photographing a solution in which the respective tackifiers were dispersed from the upper side is shown in Fig. 1.

如表3及表4以及圖1所示,可確認在摻合有離胺酸之配方2的增黏劑中,係與摻合有氯化鉀之配方1的增黏劑同等地,黏稠度的表現性及分散性良好。另一方面,可確認在摻合有甘胺酸來代替氯化鉀之配方3的增黏劑中,儘管黏稠度的表現性良好,但會形成直徑為10mm以上的團塊,分散性未充分地獲得改善。由此等結果,可確認藉由在增黏劑中使用離胺酸來代替氯化鉀,可獲得與氯化鉀同等的黏稠度調整(賦予)作用、以及粉塊形成抑制作用。 As shown in Tables 3 and 4 and Figure 1, it was confirmed that the tackifier of Formulation 2 blended with lysine was equivalent to the tackifier of Formulation 1 in which potassium chloride was blended, and the viscosity was the same. Expressive and dispersive. On the other hand, it has been confirmed that in the tackifier of Formulation 3 in which glycine acid is blended instead of potassium chloride, although the consistency of the viscosity is good, agglomerates having a diameter of 10 mm or more are formed, and the dispersibility is insufficient. The ground is improved. As a result of the above, it was confirmed that the use of tartaric acid in place of potassium chloride in the tackifier can achieve the same viscosity-adjusting (giving) action and suppressing powder formation as potassium chloride.

<製造例2:增黏劑的調製(天冬胺酸)> <Manufacturing Example 2: Preparation of tackifier (aspartic acid)>

如表5所示,將54重量份的糊精及33重量份的黃原膠進行混合,而獲得混合粉末。此外,將8重量份的糊精溶解於15重量份的水中之後,添加5重量份的天冬胺酸 鈉一水合物並使其溶解,而獲得黏合劑液。與製造例1同樣地,一面對糊精及黃原膠之混合粉末噴佈黏合劑液(全量),一面將糊精及黃原膠之混合粉末進行造粒,獲得增黏劑(配方4)。 As shown in Table 5, 54 parts by weight of dextrin and 33 parts by weight of xanthan gum were mixed to obtain a mixed powder. Further, after dissolving 8 parts by weight of dextrin in 15 parts by weight of water, adding 5 parts by weight of aspartic acid The sodium monohydrate is dissolved and dissolved to obtain a binder liquid. In the same manner as in Production Example 1, a mixed powder of dextrin and xanthan gum was sprayed with a mixed powder of dextrin and xanthan gum, and a mixed powder of dextrin and xanthan gum was granulated to obtain a tackifier (Formulation 4). ).

如表5所示,將57重量份的糊精及33重量份的黃原膠進行混合,而獲得混合粉末。此外,將8重量份的糊精溶解於15重量份的水中之後,添加2重量份的天冬胺酸鈉一水合物並使其溶解,而獲得黏合劑液。與製造例1同樣地,對糊精及黃原膠之混合粉末噴佈黏合劑液(全量),獲得增黏劑(配方5)。 As shown in Table 5, 57 parts by weight of dextrin and 33 parts by weight of xanthan gum were mixed to obtain a mixed powder. Further, after dissolving 8 parts by weight of dextrin in 15 parts by weight of water, 2 parts by weight of sodium asparagate monohydrate was added and dissolved to obtain a binder liquid. In the same manner as in Production Example 1, a binder liquid (total amount) was sprayed on a mixed powder of dextrin and xanthan gum to obtain a tackifier (Formulation 5).

如表5所示,除了將混合粉末中所包含之糊精的摻合量變更為58重量份,並將黏合劑液中所摻合之天冬胺酸鈉一水合物的摻合量變更為1重量份以外,係依與配方4同樣之方式,獲得增黏劑(配方6)。 As shown in Table 5, the blending amount of the dextrin contained in the mixed powder was changed to 58 parts by weight, and the blending amount of the sodium asparagate monohydrate blended in the binder liquid was changed to A tackifier (Formulation 6) was obtained in the same manner as in Formulation 4 except for 1 part by weight.

如表5所示,除了將混合粉末中所包含之糊精的摻合量變更為59重量份以及將黃原膠的摻合量變更為32.5重量份,並將黏合劑液中所摻合之天冬胺酸鈉一水合物的摻合量變更為0.5重量份以外,係依與配方4同樣之方式,獲得增黏劑(配方7)。 As shown in Table 5, the blending amount of the dextrin contained in the mixed powder was changed to 59 parts by weight, and the blending amount of xanthan gum was changed to 32.5 parts by weight, and the binder liquid was blended. A tackifier (Formulation 7) was obtained in the same manner as in Formulation 4 except that the blending amount of sodium aspartate monohydrate was changed to 0.5 part by weight.

<試驗例2:黏稠度的表現及分散性之評估> <Test Example 2: Evaluation of Viscosity and Dispersibility>

使用與試驗例1相同的評估方法,針對製造例2所獲得之各增黏劑,評估黏稠度(黏度)的表現性、及分散性(粉塊形成的抑制效果)。將此結果示於表6及表7。 Using the same evaluation method as in Test Example 1, the tackiness (viscosity) expression and dispersibility (inhibition effect of powder formation) were evaluated for each tackifier obtained in Production Example 2. The results are shown in Tables 6 and 7.

如表6及表7所示,可確認與天冬胺酸的摻合量無關,黏稠度的表現良好。另一方面,可確認伴隨著 天冬胺酸的摻合量增加,分散性係獲得改善。 As shown in Tables 6 and 7, it was confirmed that the viscosity was excellent regardless of the amount of aspartic acid blended. On the other hand, it can be confirmed that The blending amount of aspartic acid is increased, and the dispersibility is improved.

<試驗例3:風味評估> <Test Example 3: Flavor Evaluation>

針對配方4的增黏劑、以及除了將配方4之天冬胺酸一水合物變更為氯化鉀以外係依與配方4同樣之方式所製造之增黏劑(配方8),依照下列次序,評估對風味之影響。 The tackifier prepared for Formulation 4 and the tackifier (Formulation 8) manufactured in the same manner as Formulation 4 except that the aspartic acid monohydrate of Formulation 4 was changed to potassium chloride, in the following order, Assess the impact on flavor.

將配方4、或配方8的增黏劑以3重量%添加至離子交換水中之後進行攪拌,對離子交換水賦予黏稠度,而獲得黏稠的水。使7名專門的專業評判攝取黏稠的水,依照以下評估系統,評估其餘味及鹹味。 The tackifier of Formulation 4 or Formulation 8 was added to ion-exchanged water at 3% by weight, and then stirred to impart viscosity to the ion-exchanged water to obtain viscous water. Seven specialized specialists were judged to take in the thick water, and the rest of the taste and salty taste were evaluated according to the following evaluation system.

餘味評估:以使用配方4的增黏劑之情況之餘味為基準,針對配方8的增黏劑,以下列5個階段進行評估(5;明顯減輕、4;稍微減輕、3;相同、2;稍微較強、1;明顯較強)。 Evaluation of Aftertaste: Based on the aftertaste of the tackifier of Formulation 4, the tackifier for Formulation 8 was evaluated in the following five stages (5; significant reduction, 4; slightly reduced, 3; identical, 2; Slightly stronger, 1; significantly stronger).

鹹味評估:以使用配方4的增黏劑之情況之鹹味為基準,針對配方8的增黏劑,以下列5個階段進行評估(5:明顯較強、4:稍微較強、3:相同、2:稍微減輕、1:明顯減輕)。 Saline evaluation: Based on the salty taste of the tackifier of Formulation 4, the tackifier for Formulation 8 was evaluated in the following five stages (5: significantly stronger, 4: slightly stronger, 3: identical, 2: slightly relieved, 1: significantly reduced).

使用配方8的增黏劑之情況之餘味的評估,平均為1.3,可確認相較於使用氯化鉀之配方8而言,在配方4的增黏劑中,餘味係顯著(P<0.05)地獲得改善。此外,使用配方8的增黏劑之情況之鹹味的評估,平均為3.9,可確認相較於使用氯化鉀之配方8而言,在配方4的增黏劑中,鹹味係顯著(P<0.05)地獲得改善。 The evaluation of the aftertaste of the tackifier of Formulation 8 was 1.3 on average, and it was confirmed that the aftertaste was significantly higher in Formula 4 tackifier than in Formulation 8 using potassium chloride (P<0.05). The ground is improved. Further, the evaluation of the salty taste in the case of using the tackifier of Formulation 8 was 3.9 on average, and it was confirmed that the salty taste was remarkable in the tackifier of Formula 4 as compared with Formulation 8 using potassium chloride (P< 0.05) improved.

Claims (13)

一種增黏多醣類的粉塊形成抑制劑,其係包含選自離胺酸及天冬胺酸以及該等之鹽所組成群組之至少一種。 A powder block forming inhibitor of a viscosity-promoting polysaccharide, which comprises at least one selected from the group consisting of lysine and aspartic acid and a salt thereof. 如請求項1之粉塊形成抑制劑,其中,增黏多醣類為選自黃原膠及瓜爾膠所組成群組之至少一種。 The powder forming inhibitor of claim 1, wherein the polysaccharide-promoting polysaccharide is at least one selected from the group consisting of xanthan gum and guar gum. 一種增黏劑,其係包含選自離胺酸及天冬胺酸以及該等之鹽所組成群組之至少一種、以及增黏多醣類。 A tackifier comprising at least one selected from the group consisting of aminic acid and aspartic acid and salts thereof, and a polysaccharide-promoting polysaccharide. 如請求項3之增黏劑,其中,增黏多醣類為選自黃原膠及瓜爾膠所組成群組之至少一種。 The tackifier of claim 3, wherein the polysaccharide-promoting polysaccharide is at least one selected from the group consisting of xanthan gum and guar gum. 如請求項3或4之增黏劑,其係進一步包含糊精。 The tackifier of claim 3 or 4 further comprising dextrin. 如請求項3至5中任一項之增黏劑,其中,選自離胺酸及天冬胺酸以及該等之鹽所組成群組之至少一種係黏結至增黏多醣類。 The tackifier according to any one of claims 3 to 5, wherein at least one selected from the group consisting of amino acid and aspartic acid and the salts thereof is bonded to the polysaccharide. 一種容器填裝增黏劑,其係在容器中填充請求項3至6中任一項之增黏劑。 A container is filled with a tackifier which is filled in the container with the tackifier of any one of claims 3 to 6. 一種飲食品,其係摻合有請求項3至6中任一項之增黏劑。 A food or drink which is blended with the tackifier of any one of claims 3 to 6. 如請求項8之飲食品,其係吞嚥輔助食品。 The food or drink of claim 8, which is a swallowing supplementary food. 一種選自離胺酸及天冬胺酸以及該等之鹽所組成群組之一種以上之用途,其係用於抑制增黏多醣類的粉塊形成。 A use of one or more selected from the group consisting of aminic acid and aspartic acid, and a salt thereof, for inhibiting the formation of agglomerates of a polysaccharide-promoting polysaccharide. 如請求項10之用途,其中,增黏多醣類為選自黃原膠及瓜爾膠所組成群組之至少一種。 The use of claim 10, wherein the polysaccharide-promoting polysaccharide is at least one selected from the group consisting of xanthan gum and guar gum. 一種具有黏稠度之飲食品之製造方法,其係包含 將請求項3至6中任一項之增黏劑摻合至飲食品中。 Method for manufacturing a food or drink having a viscosity, which comprises The tackifier of any one of claims 3 to 6 is blended into a food or beverage. 一種對飲食品賦予黏稠度之方法,其係包含將請求項3至6中任一項之增黏劑摻合至飲食品中。 A method of imparting a viscosity to a food or drink comprising blending the tackifier of any one of claims 3 to 6 into a food or drink.
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