TW201707675A - Aerosol cosmetic - Google Patents

Abstract

An aerosol cosmetic containing a liquid concentrate including the following components (A), (B), (C), (D), and (E), taking the entire liquid concentrate as 100 mass%: (A) 0.1-1.5 mass% of a silicone elastomer powder having an average particle size of 0.01-30 [mu]m, (B) 1-25 mass% of an oil solution having a viscosity of 1-100 mPa.s at 25 DEG C, (C) 0.05-6 mass% of a nonionic surfactant having an HLB of 3-20, (D) 0.1-1 mass% of a water-soluble thickener, and (E) water, and (F) a propellant including 90 mass% or more of carbon dioxide.

Description

Spray cosmetic

The present invention relates to a spray cosmetic.

In order to obtain blood flow, warming effect and massage effect, the industry has studied the use of carbon dioxide spray cosmetics. For example, Patent Document 1 describes a foam-like cosmetic formulated with carbon dioxide, and Patent Document 2 describes a foam cosmetic containing carbon dioxide and solid fat to have a warm feeling effect. Further, Patent Document 3 describes a cosmetic material which promotes transdermal absorption of carbon dioxide by using fine bubbles and which is not sticky after being applied, and Patent Document 4 describes that it is easy to massage and rinse after massage. A spray-type cosmetic with a good touch.

However, the cosmetic materials described in Patent Document 1 and Patent Document 2 have problems in the expansion of the bubble, and it has not been assumed that the bubble containing carbon dioxide is rapidly affinity with the skin. The cosmetic described in Patent Document 3 is insufficient in foaming and suppresses stickiness, but is insufficient in terms of swelling of the bubble or penetration into the skin. The massage agent described in Patent Document 4 is excellent in stretching for massage, but does not assume a feeling of penetration into the skin.

(Patent Document 1) Japanese Patent Laid-Open Publication No. 2005-506325

(Patent Document 2) Japanese Patent Laid-Open Publication No. 2010-30945

(Patent Document 3) Japanese Patent Laid-Open Publication No. 2014-129306

(Patent Document 4) Japanese Patent Laid-Open Publication No. 2011-93877

The present invention relates to a spray cosmetic comprising: The stock solution of the following components (A), (B), (C), (D), and (E) is contained in an amount of 100% by mass of the entire raw material, and (A) a polyfluorene oxide elastomer having an average particle diameter of 0.01 to 30 μm. The powder has a viscosity of 0.1 to 1.5% by mass and (B) a viscosity of 1 to 100 mPa at 25 ° C. s oil agent 1~25% by mass, (C) HLB3~20 nonionic surfactant 0.05~6 mass%, (D) water soluble tackifier 0.1~1% by mass, (E) water; and (F A propellant containing 90% by mass or more of carbon dioxide.

Fig. 1 is a graph showing the results of evaluating the uniform adhesion of the lotion to the skin in Test Example 4.

The present invention relates to a spray cosmetic which is excellent in the spread of foam and which can rapidly apply carbon dioxide to the skin and has excellent penetration into the skin.

The present inventors have found that a spray cosmetic which solves the above problems can be obtained by using a specific powder, an oil agent, a nonionic surfactant, a water-soluble tackifier, and carbon dioxide in combination.

In the spray cosmetic of the present invention, the carbon dioxide-containing foam is well spread, and carbon dioxide can be quickly applied to the skin, and the foam has excellent penetration into the skin, and the skin after application has a feeling of the film. Moreover, the penetration feeling of the cosmetics used after applying the spray cosmetic of the present invention to the skin is improved.

In addition, in this specification, a spray makeup may be described as a "composition."

The polysiloxane elastomer of the component (A) used in the present invention is preferably a polyfluorene oxide having a crosslinked structure obtained by polymerization of a monomer and a derivative thereof. For example, it is preferably selected from the group consisting of polydimethyl siloxane, vinyl polydimethyl siloxane, phenyl vinyl polydimethyl siloxane, The polyfluorene oxide and its derivative obtained by polymerizing or copolymerizing a monomer such as lauryl polydimethyl siloxane and lauryl polydimethyl decyloxyethyl dimethyl methoxy oxane From the viewpoint of combining the following component (C) to improve the penetration of the foam on the skin, it is more preferably a (polydimethylsiloxane/vinyl polydimethyloxane) crosslinked polymer, (poly) Dimethyl methoxy oxane / phenyl vinyl polydimethyl methoxy oxane) crosslinked polymer, (vinyl polydimethyl siloxane / lauryl polydimethyl siloxane) crosslinked polymer, (vinyl polydimethyl methoxy oxane / polymethyl oxa oxide sesquiterpene oxide) crosslinked polymer, (PEG-15 / lauryl polydimethyl siloxane) cross-linked polymer, and thus Cross-polymerization of (Polydimethylsiloxane/vinyl polydimethyloxane) cross-linked polymer (vinyl polydimethyloxane/Lauryl polydimethyloxane) And (PEG-15/lauryl polydimethyloxane) crosslinked polymer, and more preferably (polydimethylsiloxane/vinyl polydimethyloxane) crosslinked polymer.

Further, in the present invention, the skin and the skin have the same meaning.

The average particle diameter of the polyoxyxene elastomer of the component (A) is 0.01 to 30 μm, and the average particle diameter is preferably 0.1 from the viewpoint of combining the component (C) to improve the film feeling of the skin after application. ~20 μm, more preferably 1 to 10 μm.

In the present invention, the average particle diameter is measured by a laser diffraction scattering type particle size distribution measuring apparatus LA-920 (manufactured by HORIBA).

The polysiloxane elastomer of the component (A) may be used as it is as a solid, or may be uniformly mixed with water or a liquid oil. From the viewpoint of dispersibility in the cosmetic material, workability, and combination with the following component (C) to improve the penetration of the foam on the skin, it is preferably a dispersion liquid mixed with water or liquid oil. The form is used, and it is more preferably used in the form of a dispersion mixed with a liquid oil.

As a liquid oil, in combination with the following component (C), the viscosity of the foam to the skin is improved, and the viscosity at 25 ° C is preferably 100 mPa. s or less, more preferably 50mPa. s is below, and further preferably 30 mPa. s below, and more preferably 10mPa. s below.

Here, the viscosity is based on a B-type viscometer (VISCOMETER TVB-10, Dongji Industry) Manufactured by the company, measured by rotor No. 1, 60 rpm, 1 minute.

Moreover, as a liquid oil, it is preferable to combine with the following component (C), and it is preferable that it is at least one selected from the group consisting of a polyphthalic acid oil, a hydrocarbon oil, and an ester oil. Preferably, it is at least one selected from the group consisting of polyoxyl oil and hydrocarbon oil, and further preferably at least one selected from the group consisting of dimethyl polyoxyalkylene, decamethylcyclopentaoxane, liquid paraffin, and light isoparaffin. One, and more preferably at least one selected from the group consisting of dimethyl polyoxyalkylene and decamethylcyclopentaoxane.

As a (polydimethyl methoxy oxane / vinyl polydimethyl siloxane) crosslinked polymer, as a solid, Trefil E-506S (effective mass 100% by mass) (manufactured by Toray Dow Corning Co., Ltd.) In addition, as a mixture with a liquid oil, KSG-15 (effective fraction: 7 mass%) as a mixture with decamethylcyclopentaoxane (KF-995) can be cited as a low-viscosity dimethyl group. KSG-16 (effective fraction: 25 mass%) of a mixture of polyoxyalkylene (KF-96A-6cs) (above, Shin-Etsu Chemical Co., Ltd.), Trefil E-508 as a mixture with polydimethyl siloxane (Available as 70%), etc., as a mixture with water, commercially available products such as BY29-119 (effective fraction 63% by mass) and BY29-129 (effective fraction 63% by mass) can be used.

As a (polydimethyl methoxy oxane / phenyl vinyl polydimethyl siloxane) crosslinked polymer, it can be used as a mixture with a liquid oil to form a polyphenylene alkoxy phenyl group. Commercial product such as KSG-18A (effective fraction: 15% by mass) (manufactured by Shin-Etsu Chemical Co., Ltd.), a mixture of trimethyloxane (KF-56A).

Further, as a crosslinked polymer of (vinyl polydimethyl siloxane/lauryl polydimethyl siloxane), as a mixture with a liquid oil, KSG-which is a mixture with liquid paraffin can be used. 41 (effective fraction: 30% by mass), KSG-42 (effective fraction: 25 mass%) as a mixture with light isoparaffin wax, KSG-43 as a mixture with tri-2-ethylhexanoic acid glyceride (effective A commercial product such as KSG-44 (effective fraction: 30% by mass) (the above is manufactured by Shin-Etsu Chemical Co., Ltd.) which is a mixture with squalane.

As a (vinyl polydimethyl siloxane/polymethyl decane sesquioxane) cross-linked polymer, as a solid, KSP-100 (effective mass of 100% by mass) can be used (Shin-Etsu Chemicals) Commercial products such as those manufactured by the company.

As a (PEG-15/laurylpolydimethyloxane) cross-linked polymer, as a mixture with a liquid oil, KSG-310 (effective fraction of 30% by mass) which is a mixture with liquid paraffin can be used. KSG-320 (effective fraction: 25 mass%) as a mixture with light isoparaffin wax, KSG-330 (effective fraction: 20% by mass) as a mixture with tri-2-ethylhexanoic acid glyceride (above Commercial products such as Shin-Etsu Chemical Co., Ltd.).

The component (A) may be used in an amount of 0.1% by mass or more, preferably 0.2% by mass in terms of the amount of the sensation of the sensation of the blister to the skin and the expansion of the blister. The above is more preferably 0.4% by mass or more, and is 1.5% by mass or less, preferably 0.8% by mass or less, and more preferably 0.6% by mass or less from the viewpoint of improving the storage stability of the composition. Further, the content of the component (A) is 0.1 to 1.5% by mass, preferably 0.2 to 0.8% by mass, and more preferably 0.4 to 0.6% by mass in the stock solution.

In addition, the component (A) has a content of 0.1% by mass or more of the component other than the component (F) from the viewpoint of improving the sensation of the sensation of the blister on the skin, the sensation of the skin of the skin after application, and the expansion of the blister. The content is preferably 0.2% by mass or more, more preferably 0.4% by mass or more, and is 1.5% by mass or less, preferably 0.8% by mass or less, and more preferably 0.6% by mass, from the viewpoint of improving the storage stability of the composition. the following. Further, the content of the component (A) is 0.1 to 1.5% by mass, preferably 0.2 to 0.8% by mass, and more preferably 0.4 to 0.6% by mass, based on the component other than the component (F). The preferred content of the other components other than the component (F) is also the amount of the "stock solution" replaced by the "component other than the component (F)".

In the present invention, the term "bubble stretching" means that the foam is stretched on the skin while maintaining the foam. The soaking of the foam to the skin is excellent, and it is absorbed immediately after spreading in the form of a bubble, and no cosmetic remains. The touch on the skin. The so-called skin feeling of the coated skin means that the foamy cosmetic material is quickly absorbed, the stratum corneum of the skin is filled with the cosmetic material, and the stratum corneum is swollen, and there is no compression. Thereby, the affinity of the lotion or beauty liquid to be applied later becomes good. In the present invention, the so-called affinity system means that the lotion or beauty liquid should be When applied to the skin, the lotion or beauty lotion is retained on the skin and absorbed into the stratum corneum of the skin along with the already applied foamy cosmetic. Further, the affinity system means a feeling of penetration.

Moreover, the spray cosmetic of the present invention can also improve the affinity of other cosmetic materials such as lotion, lotion, and cream applied after applying the cosmetic.

In the present invention, the affinity means that when the spray cosmetic of the present invention is applied and other cosmetic materials are applied to the skin, the other cosmetic materials are retained on the skin and absorbed into the skin together with the spray cosmetic of the present invention which has been applied. The touch in the stratum corneum.

The viscosity of the oil agent of the component (B) used in the present invention at 25 ° C is 1 mPa from the viewpoint of improving the penetration of the foam on the skin. Above s, preferably 2 mPa. Above s, more preferably 3mPa. s or more, and further preferably 4 mPa. Above s, and is 100mPa. Below s, preferably 50 mPa. Below s, more preferably 30mPa. s below, and more preferably 20mPa. s below. Moreover, the oil of the component (B) is 1 to 100 mPa. s, preferably 2~50mPa. s, more preferably 3~30mPa. s, and further preferably 4 to 20 mPa. s.

Here, the viscosity was measured by a BM viscometer (manufactured by Toki Sangyo Co., Ltd.) (rotor No. 1, 60 rpm, 1 minute) at 25 °C.

The oil agent is not limited as long as it is a user of a usual cosmetic, and examples thereof include a hydrocarbon oil, a polyoxygenated oil, an ester oil, an ether oil, and a fluorine oil. More specifically, for example, a linear or branched hydrocarbon oil such as light isoparaffin, liquid paraffin, liquid isomerized paraffin, squalane or squalene; dimethyl polyoxane, cyclopolymer Methyl decane, polydimethyl siloxane, trioxane methyl polytrimethyl decane, ethyl trioxane, dimethylcyclopolyoxyalkylene, methyl phenyl fluorene Polyoxyphthalic acid such as oxane, methylhydrogenpolyoxane, higher alcohol modified organopolyoxyalkylene; isodecyl isononanoate, isotridecyl isononanoate, as benzoic acid and carbon number 12 Monoester oil such as alkyl benzoate (C12-15) of ester of aliphatic alcohol of ~15; diester oil such as neopentyl glycol dicaprate, glyceride of tris(octanoic acid/capric acid), 2-B Triester oil such as triglyceride, hexyl hexanoate; ether oil such as alkyl-1,3-dimethylbutyl ether, dioctyl ether, dioctyl ether; Polyether, perfluoroalkyl ether, polyfluorene and other fluorine oils.

The component (B) is preferably one or more selected from the group consisting of a hydrocarbon oil, an ester oil, and a polysiloxane oil, and is preferably a combination of the component (A) and the foam. The hydrocarbon oil, the monoester oil, the triester oil, and the polyoxygenated oil are preferably a monoester oil or a polyoxygenated oil. Further, from the viewpoint of improving the penetration feeling and stability of the foam on the skin, it is preferred to use a monoester oil and a polyoxyxylene oil in combination.

The component (B) may be used alone or in combination of two or more kinds, and the content of the foam on the skin and the skin feel of the skin after application are 1% by mass or more, preferably 2% by mass. % or more is more preferably 4% by mass or more, and is 25% by mass or less, preferably 15% by mass or less, and more preferably 12% by mass or less. Further, the content of the component (B) is 1 to 25% by mass, preferably 2 to 15% by mass, and more preferably 4 to 12% by mass in the stock solution.

The component (C) used in the present invention is a nonionic surfactant of HLB 3 to 20, and the HLB of the component (C) is preferably 7 from the viewpoint of improving the penetration of the foam on the skin and the storage stability of the composition. The above is more preferably 9 or more, and still more preferably 11 or more. From the viewpoint of improving the film feeling of the skin after application, it is preferably 18 or less, more preferably 16 or less, still more preferably 15 or less. Further, the HLB of the component (C) is preferably from 7 to 18, more preferably from 9 to 16, more preferably from 11 to 15. The nonionic surfactant of the component (C) is contained in view of the amount of carbon dioxide dissolved in the stock solution, the solubility and the foaming property at the time of coating.

Further, the component (C) does not contain the following component (G).

Here, HLB (Hydrophilic-Lypophilic Balance) refers to the molecular weight of the hydrophilic group portion occupied by the total molecular weight of the surfactant, and the nonionic surfactant is represented by Griffin ( The formula of Griffin).

The HLB system containing a mixed surfactant of two or more kinds of nonionic surfactants was obtained in the following manner. The HLB of the mixed surfactant is obtained by arithmetically averaging the HLB values of the respective nonionic surfactants based on their blending ratios.

Mixed HLB=Σ(HLBx×Wx)/ΣWx

HLBx represents the HLB value of the nonionic surfactant X.

Wx represents the mass (g) of the nonionic surfactant X having a value of HLBx.

Examples of the nonionic surfactant of the component (C) include sorbitan fatty acid ester, glycerin fatty acid ester, polyglycerin fatty acid ester, propylene glycol fatty acid ester, polyethylene glycol fatty acid ester, and sucrose fatty acid. Ester, polyoxyethylene fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene alkyl ether, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene propylene glycol fatty acid ester , polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil, polyoxyethylene hydrogenated castor oil fatty acid ester, polyoxyethylene plant stanol ether, polyoxyethylene plant sterol ether, polyoxyethylene dihydrocholesterol ether, polyoxygen Ethylene cholesteryl ether and the like.

Among these, sorbitan fatty acid ester, glycerin fatty acid ester, and polyoxyethylene sorbitan fat are preferred from the viewpoint of improving the osmotic feeling and stability of the vesicle to the skin in combination with the component (A). An acid ester, a polyoxyethylene alkyl ether, a polyoxyethylene hydrogenated castor oil, more preferably a glycerin fatty acid ester, a polyoxyethylene sorbitan fatty acid ester, a polyoxyethylene alkyl ether, a polyoxyethylene hydrogenated castor oil, and further Preferred are polyoxyethylene sorbitan fatty acid esters, polyoxyethylene hydrogenated castor oil, and more preferably polyoxyethylene hydrogenated castor oil.

Further, from the viewpoint of improving the feeling of penetration to the skin and the feeling of the skin of the skin after application, it is preferably a sorbitan fatty acid ester, a glycerin fatty acid ester, a polyoxyethylene fatty acid ester, or a polyoxyethylene sorbitol. Anhydride fatty acid ester, polyoxyethylene alkyl ether, polyoxyethylene hydrogenated castor oil, more preferably sorbitan fatty acid ester, glycerin fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene hydrogenated castor oil Further, it is preferably a sorbitan fatty acid ester, a polyoxyethylene hydrogenated castor oil, and more preferably a polyoxyethylene hydrogenated castor oil.

Further, from the viewpoint of improving the penetration feeling of the cosmetic material applied after application to the skin, it is preferably selected from the group consisting of sorbitan fatty acid ester, glycerin fatty acid ester, polyoxyethylene fatty acid ester, and polyoxyethylene sorbent. One or more of an alcoholic anhydride fatty acid ester, a polyoxyethylene alkyl ether, and a polyoxyethylene hydrogenated castor oil, more preferably selected from the group consisting of sorbitan fatty acid esters and polyoxyethylene esters One or more of a fatty acid ester, a polyoxyethylene alkyl ether, and a polyoxyethylene hydrogenated castor oil.

The polyoxyethylene hydrogenated castor oil preferably has an average addition molar number of 20 to 90 ethylene oxide in combination with the component (A) to improve the penetration and stability of the foam to the skin. It is 30 to 80, and more preferably 50 to 70.

The component (C) may be used in combination of one or more kinds selected from the above, and the content of the film is 0.05 mass in terms of the swelling of the foam, the feeling of penetration to the skin, and the feeling of the skin of the skin after application. % or more is preferably 0.1% by mass or more, more preferably 0.3% by mass or more, and is 6% by mass or less, preferably 2% by mass or less, and more preferably 1% by mass or less. Further, the content of the component (C) is 0.05 to 6% by mass, preferably 0.1 to 2% by mass, and more preferably 0.3 to 1% by mass in the stock solution.

In the present invention, the mass ratio [(A)/(C)] of the component (A) to the component (C) is preferably 0.05 or more, more preferably 0.2, from the viewpoint of improving the penetration of the foam on the skin. The above is more preferably 0.5 or more, and is preferably 3 or less, more preferably 2.2 or less, still more preferably 1.4 or less. Further, the mass ratio [(A)/(C)] of the component (A) to the component (C) is preferably 0.05 to 3, more preferably 0.2 to 2.2, still more preferably 0.5 to 1.4.

The water-soluble tackifier as the component (D) may be any user of a usual cosmetic, and examples thereof include carrageenan, dextrin, methylcellulose, ethylcellulose, and hydroxyethylcellulose. , hydroxypropyl cellulose, polyvinyl alcohol, polyacrylic acid, polymethacrylic acid, carboxyvinyl polymer, acrylic acid-alkyl methacrylate copolymer, santillac gum, carboxymethyl chitin, polyglucosamine Wait. These have the effect of increasing the viscosity of the stock solution and improving the stability.

Among these, a carboxyvinyl polymer and an acryl-methacrylic acid alkyl group are preferred from the viewpoint of improving the sensation of the blister to the skin and the sensation of the skin after application in combination with the component (A). The ester copolymer is more preferably an acrylic acid-alkyl methacrylate copolymer.

Here, the acrylic-alkyl methacrylate copolymer is a copolymer of C10-30 alkyl acrylate and acrylic acid, methacrylic acid or the lower alkyl ester, and is made of sugarcane. Commercially available products such as PEMULEN TR-1, PEMULEN TR-2, Carbopol ETD2020, Carbopol 1342, and Carbopol 1382 (above, Lubrizol Advanced Materials) can be used for the crosslinking of the allyl ether of sugar or the allyl ether of pentaerythritol.

Further, an acid-type water-soluble tackifier such as polyacrylic acid, a carboxyvinyl polymer or an acrylic acid-alkyl methacrylate copolymer preferably uses a base as a neutralizing agent and is a water-soluble or water-dispersible salt. Form use. Examples of the base include alkali metal hydroxides such as sodium and potassium; ammonium; ammonium salts derived from alkanolamines such as monoethanolamine, diethanolamine, triethanolamine and tromethamine; and alkalinity such as arginine and lysine. Amino acid; preferably an alkali metal hydroxide such as sodium or potassium, more preferably potassium hydroxide or sodium hydroxide.

The component (D) may be used in combination of one or more selected from the above, and in combination with other components, the content of the vesicle to the skin is improved, and the content is 0.1% by mass or more, preferably 0.15 in the stock solution. The mass% or more is more preferably 0.2% by mass or more, and is 1% by mass or less, preferably 0.8% by mass or less, and more preferably 0.5% by mass or less. Further, the content of the component (D) is 0.1 to 1% by mass, preferably 0.15 to 0.8% by mass, and more preferably 0.2 to 0.5% by mass in the stock solution.

In the present invention, the mass ratio [(A)/(D)] of the component (A) to the component (D) is preferably 0.2 or more, from the viewpoint of improving the penetration feeling and stability of the foam to the skin. It is preferably 0.6 or more, more preferably 1 or more, and is preferably 10 or less, more preferably 4 or less, still more preferably 2.5 or less. Further, the mass ratio [(A)/(D)] of the component (A) to the component (D) is preferably 0.2 to 10, more preferably 0.6 to 4, still more preferably 1 to 2.5.

The water of the component (E) used in the present invention acts as a solvent and becomes the remainder of the other components. The content of water in the component (E) is preferably 55 mass% or more, more preferably 65 mass% or more, further preferably 75 mass% or more, and more preferably 95 mass% or less, more preferably 93 mass% in the stock solution. % or less, further preferably 90% by mass or less. Further, the content of water is preferably 55 to 95% by mass, more preferably 65 to 93% by mass, still more preferably 75 to 90% by mass in the stock solution.

The cosmetic of the present invention may further contain (G) one or more selected from the group consisting of alkyl glyceryl ether modified polyfluorene oxide and polyalkylene oxide modified polyfluorene oxygen, and may be combined with component (A) to improve The swelling of the foam, the feeling of the skin of the skin after application, and the penetration of the cosmetic used after application to the skin.

As the component (G), in combination with the component (A), the expansion of the foam, the feeling of the skin after application, the feeling of penetration of the cosmetic after application to the skin, and the stability are improved. It is a polyalkylene oxide modified polyfluorene.

Examples of the alkyl glyceryl ether-modified polyfluorene oxide include those represented by the following formula (1).

[wherein, at least one of R ¹ to R ¹² is a group represented by the following formula (2);

(wherein Q represents a divalent hydrocarbon group having 3 to 20 carbon atoms, R ¹³ and R ¹⁴ each represent a hydrogen atom or a hydrocarbon group having 1 to 5 carbon atoms, at least one of which represents a hydrogen atom), and the balance represents a carbon number of 1 to 30. a linear, branched or cyclic hydrocarbon group or a group represented by the following formula (2-1); -YR ¹⁵ (2-1)

(wherein, Y represents a divalent hydrocarbon group having 1 to 10 carbon atoms and an ether bond or an ester bond, and R ¹⁵ represents a linear, branched or cyclic hydrocarbon group having 1 to 30 carbon atoms), and a, b and c represent 0 to 2000, when a+b+c=0, at least one of R ¹ to R ³ and R ¹⁰ to R ¹² represents a base (2)]

The alkyl glyceryl ether-modified polyfluorene is used in combination with the component (A) to improve the swelling of the foam, the feeling of the skin after application, and the feeling of penetration of the cosmetic used after application to the skin. Preferably, in the formula (1), one of R ¹ to R ¹² is a formula (2), and R ¹³ and R ¹⁴ of the formula (2) are a hydrogen atom, and the rest are methyl groups, and further In the following general formula (3), j=60 and k=4 can be produced by the method described in Japanese Laid-Open Patent Publication No. Hei-4-108795.

As the alkyl glyceryl ether-modified polyfluorene oxide, for example, a commercial product such as "Penetol SI-U" (glycerol undecyl polydimethyl siloxane) which is distributed by Kao Corporation can be used.

Further, examples of the polyalkylene oxide-modified polyfluorene oxide include a polyoxyethylene-methyl polyoxyalkylene copolymer and a poly(oxyethylene-oxypropylene)-methyl polyoxyalkylene copolymer as polyoxyethylene. The methyl polyoxyalkylene copolymer may, for example, be represented by the following formula (4).

Wherein R ¹⁷ to R ¹⁹ and R ²¹ to R ²² each represent a methyl group or a phenyl group, and R ¹⁶ , R ²⁰ and R ²³ each represent a methyl group, a phenyl group, or a group R ²⁴ (OC ₃ H ₆ ) _{f (OC 2 H 4) g O} (CH 2) h - (R 24 represents a hydrogen atom or an alkyl group having 1 to 12 carbon atoms of, f and g is an average value and each represents a number of 0 to 35, h represents 1 to 5 number). Wherein at least one of R ¹⁶ , R ²⁰ and R ²³ represents a group R ²⁴ (OC ₃ H ₆ ) _f (OC ₂ H ₄ ) _g O(CH ₂ ) _h −. d and e are average values, d is the number from 1 to 200, and e is the number from 0 to 50.

As the polyalkylene oxide-modified polyfluorene oxide, a polyoxyethylene-methyl polyoxyalkylene copolymer, a poly(oxyethylene-oxypropylene)-methyl polyoxyalkylene copolymer, and a component (A) are preferred. The polyoxyethylene represented by the general formula (4) is more preferably a combination of the foaming property of the skin, the feeling of the skin after application, and the feeling of penetration of the cosmetic material applied after application to the skin. Methyl polyoxyalkylene copolymer. As the polyoxyethylene-methyl polyoxyalkylene copolymer represented by the formula (4), "KF-6015" (PEG-3 polydimethylsiloxane) which is distributed by Shin-Etsu Chemical Co., Ltd., " KF-6019" (PEG-9 polydimethyl siloxane); "SH-3775M" (PEG-12 polydimethyl siloxane) and "SH-3771M" distributed by Toray Dow Corning/Aketone Company Commercial products such as (PEG-12 polydimethyloxane) and "SS-2804" (PEG-12 polydimethyloxane).

The component (G) may be used in combination with one or more of the above-mentioned ones, and the content of the skin of the skin after application and the feeling of penetration of the cosmetic material applied after application to the skin are The amount is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, further preferably 0.2% by mass or more, and more preferably 1.5% by mass or less, more preferably 1% by mass or less, still more preferably 0.7% by mass. the following. Further, the content of the component (G) is preferably 0.05 to 1.5% by mass, more preferably 0.1 to 1% by mass, still more preferably 0.2 to 0.7% by mass, based on the stock solution.

In the present invention, the stock solution may further contain (H) a binary polyol, and may be combined with the component (A) to improve the film feel of the skin after application.

The binary polyol as the component (H) may be a user of a usual cosmetic, and examples thereof include ethylene glycol, 1,2-propylene glycol, propylene glycol, and 1,3-butylene glycol. 3-propylene glycol, dipropylene glycol, polyethylene glycol, polypropylene glycol, etc., in combination with the component (A), improves the skin feel of the skin after application, and moisturizes the applied skin and obtains a tacky touch. From the viewpoint of sensation, preferred are 1,2-propylene glycol, propylene glycol, 1,3-butylene glycol, 1,3-propanediol, and dipropylene glycol, and more preferably 1,3-propanediol or dipropylene glycol. Further, it is preferred to use 1,3-propanediol and dipropylene glycol in combination.

The component (H) may be used in combination of one or more selected from the above, thereby increasing the delay of the bubble. From the viewpoint of exhibiting, the feeling of penetration of the foam on the skin, the feeling of the skin of the skin after application, and the feeling of penetration of the cosmetic material applied after application to the skin, the content is preferably 1% by mass or more, more preferably in the stock solution. It is 3% by mass or more, more preferably 5% by mass or more, and is preferably 20% by mass or less, more preferably 15% by mass or less, and still more preferably 10% by mass or less. Further, the content of the component (G) is preferably from 1 to 20% by mass, more preferably from 3 to 15% by mass, even more preferably from 5 to 10% by mass, based on the stock solution.

In the spray cosmetic of the present invention, the stock solution may further contain components used in usual cosmetics, for example, preservatives, oils other than the preservatives and components (B) at 25 ° C, in addition to preservatives. At 25 ° C outside the agent, it is an oil agent other than liquid, a surfactant other than the component (C), a powder other than the component (A), ethanol, a polyol other than the component (H), an antioxidant, a pigment, and a pH. Value adjusters, perfumes, humectants, blood flow promoters, cold sensitizers, antiperspirants, bactericides, whitening agents, anti-inflammatory agents, skin activators, and the like.

In the present invention, as the preservative, a paraben or a phenoxyethanol such as methyl p-hydroxybenzoate, ethyl p-hydroxybenzoate or butyl p-hydroxybenzoate may be used.

The content of the preservative in the stock solution is preferably from 0.05 to 1% by mass.

In the present invention, the content of the oil agent which is liquid at 25 ° C other than the preservative and the component (B) in the stock solution is preferably 1 mass in terms of improving the film feeling of the skin after application. % or more, and preferably 9% by mass or less, more preferably 7.5 mass% or less. Further, the liquid ultraviolet absorber other than the component (B) is also contained in an oil agent which is liquid at 25 ° C except for the preservative and the component (B).

The oil agent other than the preservative used in the stock solution, which is liquid at 25 ° C, means a wax, a paste or a solid fat or oil which is solid at 25 ° C, and examples thereof include a higher alcohol and a carbon number of 12 to 24 carbon atoms. 12~24 higher fatty acids, paraffin, etc. Further, the oil agent other than the preservative at 25 ° C in the form of a liquid also contains an ultraviolet absorber other than liquid at 25 ° C.

Further, from the viewpoint of improving the softness and elongation of the foam, the content of the oil agent other than the liquid at 25 ° C in addition to the preservative used in the stock solution is preferably 3 mass in the stock solution. % or less is more preferably 1% by mass or less, further preferably 0.5% by mass or less, further preferably 0.3% by mass or less, and more preferably 0.1% by mass or less.

The mass ratio of the oil agent other than the preservative in the stock solution to the liquid oil at 25 ° C other than the preservative and the component (B) in addition to the preservative (in addition to the preservative) The oil agent other than the liquid at 25 ° C) / (the liquid oil at 25 ° C other than the preservative and the component (B)) is preferably 0.1 or less, more preferably 0.07 or less, and further preferably It is 0.03 or less.

Furthermore, in the present invention, the content of the anionic surfactant contained in the stock solution is preferably 1% by mass or less, and more preferably 0.1% by mass or less, from the viewpoint of enhancing the elongation of the bubbles and the affinity of the bubbles.

Further, it may contain a powder other than the component (A), and may also contain any powder of a metal-containing powder or a metal-free powder, preferably a metal-free powder, more preferably a resin powder. . The average particle diameter of the powder other than the component (A) is preferably 30 μm or less, more preferably 10 μm or less, still more preferably 5 μm or less.

The content of the powder other than the component (A) is preferably 3% by mass or less, and more preferably 1% by mass or less, from the viewpoint of improving the film feeling of the skin after stretching and coating.

The content of the ethanol in the stock solution is preferably 3% by mass or less, more preferably 1% by mass or less, and is preferably substantially absent from the viewpoint of improving foaming.

In the spray cosmetic of the present invention, the stock solution is prepared by mixing the above components (A) to (E) and other components. The viscosity of the stock solution is preferably 500 mPa at 25 ° C from the viewpoint of improving stability, squirting of the bubble, and penetration of the blister to the skin. Above s, more preferably 1000mPa. s or more, and further preferably 1500 mPa. Above s, and preferably 20,000 mPa. Below s, more preferably 10000mPa. s is below, and further preferably 7000 mPa. s below. The stock solution preferably has a viscosity of 500 to 20000 mPa at 25 ° C. s, more preferably 1000~10000mPa. s, and further preferably 1500~7000 mPa. s.

Here, the viscosity is measured at 25 ° C using a BM viscometer (manufactured by Toki Sangyo Co., Ltd.) at a rotor No. 3, 12 rpm, 1 minute, and a viscosity of more than 10000 mPa. s feelings In the case of the shape, the values measured by the rotor No. 3, 6 rpm, and 1 minute were used.

The spray cosmetic of the present invention can be produced by filling the above-mentioned stock solution and (F) propellant into a pressure-resistant container (spray container). As a form of the ejection, it is preferably a foam type which is ejected in a bubble form.

The propellant of the component (F) contains 90% by mass or more of carbon dioxide, preferably 95% by mass or more, more preferably 98% by mass or more, and still more preferably 100% by mass.

The mass ratio of the stock solution to the (F) propellant is preferably from 94:6 to 99.5:0.5, more preferably from 95:5 to 99:1, and still more preferably from 96.5:3.5. 98.5: 1.5.

In the present invention, the mass ratio [(A)/(F)] of the component (A) to the component (F) is preferably 0.05 or more, more preferably 0.1, from the viewpoint of improving the penetration of the foam on the skin. The above is more preferably 0.12 or more, and is preferably 1 or less, more preferably 0.4 or less, still more preferably 0.3 or less. Further, the mass ratio [(A)/(F)] of the component (A) to the component (F) is preferably 0.05 to 1, more preferably 0.1 to 0.4, still more preferably 0.12 to 0.3.

The spray cosmetic of the present invention can be used as a cosmetic without any particular limitation, but in order to improve the skin color (brightness, dullness, etc.) in order to obtain a higher blood flow promoting effect than the former. ), a skin cosmetic that improves moisturizing feeling and the like is preferred. Moreover, the permeability of the cosmetic used after applying the spray cosmetic of the present invention can be improved.

Further, in the present invention, the cosmetic containing the components (A), (B), (C), (D), (E) and (F) can be filled in a spray container to prepare a cosmetic.

The spray cosmetic of the present invention can be applied to the skin, especially the skin other than the hair, preferably the face, the body, the hands and feet, etc., and is preferably used by coating.

Further, by applying or applying a cosmetic other than the present invention (referred to as another cosmetic) to the skin to which the spray cosmetic of the present invention is applied or applied, it is possible to improve the penetration of other cosmetic materials and to improve the feeling. The special effect of the extension of other cosmetic materials. The reason for the details is unknown, but it is considered that the reason is that the spray cosmetic of the present invention is applied or applied to The skin, which changes the surface state of the skin.

Therefore, the present invention further discloses a cosmetic material and a use method for use before other cosmetic materials.

That is, after applying or applying the spray cosmetic of the present invention to, for example, the skin, other cosmetic materials are applied or applied to the application method or the skin to which the spray cosmetic is applied.

As described above, if the spray cosmetic of the present invention is applied or applied to the skin before other cosmetic materials, the penetration and elongation of the other cosmetic materials applied or applied later can be improved.

In addition, the content of the carbon dioxide in the cosmetic (other cosmetic) other than the present invention is preferably 10% by mass or less, more preferably 5% by mass or less, and still more preferably 1% by mass in the cosmetic. Hereinafter, it is more preferably 0.1% by mass or less, and particularly preferably substantially 0% by mass.

The cosmetic preparation to which the spray cosmetic of the present invention is applied or applied to the skin and applied to the skin to which the spray cosmetic is applied or applied is not particularly limited, and may be used in the form of a lotion, an emulsion, a cream, or the like. From the viewpoint of evenly applying the cosmetic to the skin, it is preferably a lotion or an emulsion, more preferably a lotion.

Further, the other cosmetic material preferably contains water, and is preferably contained in the total composition of the other cosmetic materials in an amount of from 65 to 93% by mass, more preferably from 70 to 92% by mass.

Further, the other cosmetic material preferably contains a polyhydric alcohol such as glycerin or dipropylene glycol, and the content of the total composition of the other cosmetic is preferably from 3 to 40% by mass, more preferably from 5 to 30% by mass, still more preferably 7 ~25% by mass.

Further, the other cosmetic material preferably contains a polyalkylene oxide-modified polyfluorene oxide such as a polyoxyethylene-methyl polyoxyalkylene copolymer, and the content of the other components of the cosmetic is preferably 0.005 to 2% by mass. More preferably, it is 0.010 to 1.0% by mass, further preferably 0.015 to 0.5% by mass, and still more preferably 0.02 to 0.2% by mass.

Further, the other cosmetic material preferably contains a water-soluble tackifier such as a carboxyl group-modified carboxyvinyl polymer or polytriglucose, and the content of the other components of the cosmetic is preferably 0.001 to 1.0% by mass. More preferably, it is 0.01 to 0.5% by mass, and further preferably 0.05 to 0.3% by mass.

In the case where the spray cosmetic of the present invention is applied or applied to the skin and other cosmetic materials are applied to the skin to which the spray cosmetic is applied or applied, the affinity, extension, and skin of the other cosmetic materials are improved. From the viewpoint of uniform adhesion, the use ratio of the spray cosmetic to the amount of other cosmetic materials used [(the amount of the spray cosmetic used) / (the amount of other cosmetic materials used)] is preferably 0.2 to 6, more preferably Preferably, it is 0.3 to 5, and more preferably 0.4 to 4.

Moreover, from the viewpoint of improving the affinity and spread of other cosmetics, and the uniform adhesion to the skin, the spray cosmetic is applied or applied to the skin, and then the other cosmetic is applied to the application or coated. The time for spraying the skin of the cosmetic is preferably from 0 second to 5 minutes, more preferably from 3 seconds to 3 minutes, and still more preferably from 5 seconds to 1 minute.

The spray cosmetic of the present invention can improve the penetration into the skin by being applied to the skin.

Further, the spray cosmetic of the present invention can be applied to the skin to obtain a skin feel of the skin.

As described above, the spray cosmetic of the present invention can be applied to or applied to the skin of the spray cosmetic after the cosmetic is applied or applied to the skin, and thus can be made into a spray cosmetic and Make-up kits for other cosmetics.

Since the spray cosmetic of the present invention is applied to the skin for a fixed period of time, the effect of promoting blood flow can be enhanced, and the active ingredients in the cosmetic can be infiltrated together, which is considered to be very beneficial.

The spray cosmetic of the present invention can be applied to the skin and left to be intimate, wiped, or rinsed with the skin for a fixed period of time, and used depending on the use.

The spray cosmetic of the present invention can be produced by a usual method, for example, by In the following manner, the raw liquid component is mixed until uniform, and the obtained stock solution is filled in a pressure-resistant container and sealed, and then filled with the component (F) by pressurization.

Further, the present invention is improved in terms of improving the dispersibility of the component (A) in the cosmetic material, and the sensation of the foam of the obtained cosmetic material to the skin, the feeling of the skin of the skin after application, and the expansion of the foam. A preferred method of producing the stock solution of the spray cosmetic is a production method comprising the following steps 1 and 2.

Step 1: a step of preparing a solution containing a water-soluble tackifier by mixing part or all of the components (D) and (E),

Step 2: adding the components other than the component (F) to the solution containing the water-soluble tackifier obtained in the step 1, so that the components (A), (B), (C), (D) and (E) The step of preparing a stock solution by mixing.

Further, the component (A) may also be mixed in the step 1.

Step 1 preferably comprises the step of mixing in step 1 under heating to increase the dispersibility of the component (D) in the obtained solution containing the water-soluble tackifier, and the heating temperature is preferably 20 to 80 ° C. More preferably 40~60 °C.

Further, in the case where the component (D) is an acid type water-soluble tackifier, it is preferred to add a base in the step 1.

Further, from the same viewpoint, the step 2 preferably includes the step of mixing in the step 2 under heating to increase the dispersibility of the component (C), and the heating temperature is preferably 20 to 80 ° C, more preferably 40~60 °C. In the case where the mixing in the step 2 is carried out under heating, it is preferred to have a cooling step after the mixing, and specifically, the cooling temperature is cooled to a temperature of preferably 20 to 30 ° C, more preferably 20 to 25 ° C.

In the above embodiment, the present invention further discloses the following composition. Further, the present invention further discloses the following methods of use and the like.

<1> A spray cosmetic comprising: the following components (A), (B), (C), (D) and the like: (E) the stock solution, (A) 0.1~1.5% by mass of the polyfluorene oxide elastomer powder having an average particle diameter of 0.01 to 30 μm, and (B) the viscosity at 25 ° C is 1 to 100 mPa. s oil agent 1~25% by mass, (C) HLB3~20 nonionic surfactant 0.05~6 mass%, (D) water soluble tackifier 0.1~1% by mass, (E) water; and (F A propellant containing 90% by mass or more of carbon dioxide.

<2> The spray cosmetic according to the above <1>, wherein the polysiloxane elastomer of the component (A) is preferably selected from the group consisting of polydimethyl siloxane, vinyl polydimethyl siloxane, Obtained by polymerization or copolymerization of monomers in phenylvinylpolydimethyloxane, lauryl polydimethyloxane and lauryl polydimethylnonyloxyethylpolydimethyloxane Polyoxymethylene and its derivatives, more preferably (polydimethyl methoxy oxane / vinyl polydimethyl siloxane) cross-linked polymer, (polydimethyl siloxane / phenyl vinyl poly Methyl decane) crosslinked polymer, (vinyl polydimethyl methoxy oxane / lauryl polydimethyl siloxane) crosslinked polymer, (vinyl polydimethyl siloxane / polymethyl Crosslinked polymer, (PEG-15/Lauryl polydimethyloxane) crosslinked polymer, and more preferably (polydimethylsiloxane/vinyl) Polydimethylsiloxane (CDM) cross-linked polymer, (vinyl polydimethyl methoxy oxane / lauryl polydimethyl siloxane) cross-linked polymer, (PEG-15 / lauryl polydimethyl a siloxane (crosslinking polymer), and more preferably (polydimethyl methoxy oxane / Alkenyl polydimethylsiloxane) crosspolymer.

<3> The spray cosmetic according to the above <1> or <2>, wherein the polysiloxane elastomer of the component (A) preferably has an average particle diameter of 0.1 to 20 μm, more preferably 1 to 10 μm.

The spray cosmetic according to any one of the above-mentioned items, wherein the polyoxymethylene elastomer of the component (A) is preferably a dispersion obtained by mixing with water or a liquid oil. The form is used, and it is more preferably used in the form of a dispersion mixed with a liquid oil.

<5> The spray cosmetic according to the above <4>, wherein the liquid oil is preferably 25 ° C The viscosity is 100mPa. s or less, more preferably 50mPa. s is below, and further preferably 30 mPa. s below, and more preferably 10mPa. s below.

The spray cosmetic according to any one of the above-mentioned items, wherein the content of the component (A) is preferably 0.2% by mass or more, more preferably 0.4% by mass or more, based on the amount of the component (A). It is preferably 0.8% by mass or less, more preferably 0.6% by mass or less.

The spray cosmetic according to any one of the above items <1> to <6> wherein the oil of the component (B) preferably has a viscosity of 2 mPa at 25 ° C. Above s, more preferably 3mPa. s or more, and further preferably 4 mPa. Above s, and preferably 50 mPa. Below s, more preferably 30mPa. s below, and more preferably 20mPa. s below.

The spray cosmetic according to any one of the above-mentioned items, wherein the oil agent of the component (B) is preferably one selected from the group consisting of a hydrocarbon oil, an ester oil, and a polyoxygenated oil. Two or more kinds thereof are more preferably a hydrocarbon oil, a monoester oil, a triester oil or a polyoxygenated oil, further preferably a monoester oil or a polyoxyxane oil, and more preferably a monoester oil and a polyoxyxylene oil.

The spray cosmetic according to any one of the above-mentioned items, wherein the content of the component (B) is preferably 2% by mass or more, more preferably 4% by mass or more, and more preferably 4% by mass or more. It is preferably 15% by mass or less, and more preferably 12% by mass or less.

The spray cosmetic according to any one of the above-mentioned items, wherein the nonionic surfactant of the component (C) is preferably HLB7 or more, more preferably 9 or more, still more preferably 11 The above is preferably 18 or less, more preferably 16 or less, still more preferably 15 or less.

The spray cosmetic according to any one of the above-mentioned items, wherein the nonionic surfactant of the component (C) is preferably a sorbitan fatty acid ester, a glycerin fatty acid ester, or a polyoxygen. Ethylene sorbate fatty acid ester, polyoxyethylene alkyl ether, polyoxyethylene hydrogenated castor oil, more preferably glycerin fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene alkyl ether, polyoxyethylene The hydrogenated castor oil is further preferably a polyoxyethylene sorbitan fatty acid ester, a polyoxyethylene hydrogenated castor oil, and more preferably a polyoxyethylene hydrogenated castor oil.

<12> The spray cosmetic according to any one of the above <1> to <11> wherein The content of the component (C) is preferably 0.1% by mass or more, more preferably 0.3% by mass or more, and is preferably 2% by mass or less, and more preferably 1% by mass or less in the stock solution.

The spray cosmetic according to any one of the above-mentioned items, wherein the mass ratio [(A)/(C)] of the component (A) to the component (C) is preferably 0.05 or more. More preferably, it is 0.2 or more, further preferably 0.5 or more, and is preferably 3 or less, more preferably 2.2 or less, still more preferably 1.4 or less.

The spray cosmetic according to any one of the above items <1> to <13> wherein the water-soluble tackifier of the component (D) is preferably a carboxyvinyl polymer or an acrylic acid-alkyl methacrylate. The copolymer is more preferably an acrylic acid-alkyl methacrylate copolymer.

The spray cosmetic according to any one of the above-mentioned items, wherein the content of the component (D) is preferably 0.15% by mass or more, more preferably 0.2% by mass or more, based on the amount of the component (D). It is preferably 0.8% by mass or less, more preferably 0.5% by mass or less.

The spray cosmetic according to any one of the above-mentioned items, wherein the mass ratio [(A)/(D)] of the component (A) to the component (D) is preferably 0.2 or more. More preferably, it is 0.6 or more, More preferably, it is 1 or more, It is preferable that it is 10 or less, More preferably, it is 4 or less, More preferably, it is 2.5 or less.

The spray cosmetic according to any one of the above-mentioned items, wherein the content of water in the component (E) is preferably 55 mass% or more, more preferably 65 mass% or more in the stock solution. Further, it is preferably 75 mass% or more, more preferably 95 mass% or less, still more preferably 93 mass% or less, still more preferably 90 mass% or less.

The spray cosmetic according to any one of the items <1> to <17> further comprising (G) selected from the group consisting of alkyl glyceryl ether modified polyfluorene oxide and polyalkylene oxide modified polyfluorene oxide. One or two or more.

<19> The spray cosmetic according to the above <18>, wherein the component (G) is preferably a polyalkylene oxide-modified polyfluorene oxide, more preferably a polyoxyethylene-methyl polyoxyalkylene copolymer, or a poly (oxyethylene-oxypropylene)-methyl polyoxyalkylene copolymer, further preferably a polyoxyethylene-methyl polyoxyalkylene copolymer represented by the formula (4):

Wherein R ¹⁷ to R ¹⁹ and R ²¹ to R ²² each represent a methyl group or a phenyl group, and R ¹⁶ , R ²⁰ and R ²³ each represent a methyl group, a phenyl group, or a group R ²⁴ (OC ₃ H ₆ ) _f (OC ₂ H ₄ ) _g O(CH ₂ ) _h - (R ²⁴ represents a hydrogen atom or an alkyl group having 1 to 12 carbon atoms, f and g are average values, and represent 0 to 35, respectively, and h represents 1~ 5 number). Wherein at least one of R ¹⁶ , R ²⁰ and R ²³ represents a group R ²⁴ (OC ₃ H ₆ ) _f (OC ₂ H ₄ ) _g O(CH ₂ ) _h −. d and e are average values, and d represents the number from 1 to 200, and e represents the number from 0 to 50].

<20> The spray cosmetic according to the above <18> or <19>, wherein the content of the component (G) is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, more preferably 0.1% by mass or more. 0.2% by mass or more, and preferably 1.5% by mass or less, more preferably 1% by mass or less, still more preferably 0.7% by mass or less.

The spray cosmetic according to any one of <1> to <20> further comprising (H) a binary polyol.

<22> The spray cosmetic according to the above <21>, wherein the component (H) is preferably 1,2-propylene glycol, propylene glycol, 1,3-butylene glycol, 1,3-propanediol or dipropylene glycol, more preferably It is 1,3-propanediol and dipropylene glycol, and it is further preferred to use 1,3-propanediol and dipropylene glycol in combination.

<23> The spray cosmetic according to the above <21> or <22>, wherein the content of the component (H) is preferably 1% by mass or more, more preferably 3% by mass or more, more preferably 3% by mass or more, more preferably 5 mass% or more, and preferably 20 mass% or less, more preferably 15 mass% or less, further preferably 10 mass% or less.

The spray cosmetic according to any one of the above-mentioned items of the present invention, which further comprises a liquid agent in addition to the preservative and other components (B) at 25 ° C, in addition to the preservative. 25 At °C, it is an oil other than liquid.

<25> The spray cosmetic according to the above <24>, wherein the oil agent which is liquid at 25 ° C other than the component (B) other than the preservative is preferably a hydrocarbon oil, an ester oil or a polyoxygenated oil. More preferably, it is a hydrocarbon oil, a monoester oil, a triester oil, a polyoxyxane oil, further preferably a monoester oil, a polyoxyxane oil, and more preferably a monoester oil and a polyoxyxylene oil.

<26> The spray cosmetic according to the above <24> or <25>, wherein the content of the oil agent which is liquid at 25 ° C other than the preservative and the component (B) in the stock solution is preferably 1 mass. % or more, and preferably 9% by mass or less, more preferably 7.5 mass% or less.

The spray cosmetic according to any one of the above-mentioned items, wherein the content of the oil agent other than the preservative at 25 ° C is preferably 3% by mass in the stock solution. The amount is preferably 1% by mass or less, more preferably 0.5% by mass or less, still more preferably 0.3% by mass or less, and still more preferably 0.1% by mass or less.

The spray cosmetic according to any one of the above-mentioned <24>, wherein the oil agent other than the preservative at 25 ° C in addition to the preservative in the stock solution is relative to the component other than the preservative ( B) the mass ratio of the liquid oil at 25 ° C other than [the oil agent other than the preservative at 25 ° C in liquid form) / (at 25 ° C other than the preservative (B)) The liquid oil agent) is preferably 0.1 or less, more preferably 0.07 or less, still more preferably 0.03 or less.

The spray cosmetic according to any one of the above-mentioned items, wherein the content of the anionic surfactant contained in the stock solution is preferably 1% by mass or less, more preferably 0.1% by mass or less.

The content of the powder other than the component (A) is preferably 3% by mass or less, and more preferably 1% by mass or less, of the spray cosmetic according to any one of the above-mentioned items.

The spray cosmetic according to any one of the above-mentioned items, wherein the content of the ethanol in the stock solution is preferably 3% by mass or less, more preferably 1% by mass or less, and further preferably substantially Not included.

The spray cosmetic according to any one of the above items <1> to <31> wherein the stock solution The viscosity at 25 ° C is preferably 500 mPa. Above s, more preferably 1000mPa. s or more, and further preferably 1500 mPa. Above s, and preferably 20,000 mPa. Below s, more preferably 10000mPa. s is below, and further preferably 7000 mPa. s below.

The spray cosmetic according to any one of the above-mentioned items, wherein the spray agent of the component (F) preferably contains 95% by mass or more of carbon dioxide, more preferably 98% by mass or more, and further Good is 100% by mass.

The spray cosmetic according to any one of the above items <1> to <33> wherein the mass ratio of the stock solution to the (F) propellant is preferably 94:6 to 99.5:0.5, more preferably 95:5. ~99:1, and further preferably 96.5:3.5~98.5:1.5.

The spray cosmetic according to any one of the above-mentioned items, wherein the mass ratio [(A)/(F)] of the component (A) to the component (F) is preferably 0.05 or more. More preferably, it is 0.1 or more, further preferably 0.12 or more, and is preferably 1 or less, more preferably 0.4 or less, still more preferably 0.3 or less.

<36> A spray cosmetic comprising the following components (A), (B), (C), (D), (E), and (F): (A) an average particle diameter of 0.01 to 30 μm The 矽 oxygen elastomer powder, (B) viscosity at 25 ° C is 1 ~ 100mPa. s an oil agent, (C) a nonionic surfactant of HLB 3-20, (D) a water-soluble tackifier, (E) water, and (F) a propellant containing more than 90% by mass of carbon dioxide, and In the component other than F), the content of the component (A) is 0.1 to 1.5% by mass, the content of the component (B) is 1 to 25% by mass, and the content of the component (C) is 0.05 to 6% by mass, and The content of the above component (D) is from 0.1 to 1% by mass.

The spray cosmetic according to any one of the above-mentioned items, wherein the component (C) is preferably a sorbitan fatty acid ester, a glycerin fatty acid ester, a polyoxyethylene fatty acid ester, or a poly Oxyethylene sorbitan fatty acid ester, polyoxyethylene alkyl ether, polyoxyethylene hydrogenated castor oil, more preferably sorbitan fatty acid ester, glycerin fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxygen The ethylene hydrogenated castor oil is further preferably a sorbitan fatty acid ester, a polyoxyethylene hydrogenated castor oil, and more preferably a polyoxyethylene hydrogenated castor oil.

<38> A method of using a spray cosmetic according to any one of the items <1> to <37>, which is preferably applied to the skin, preferably a face, a body, a hand or a foot. Either.

The method for producing a stock solution of the spray cosmetic according to any one of the above items <1> to <37>, comprising the following steps 1 and 2.

Step 1: a step of preparing a solution containing a water-soluble tackifier by mixing part or all of the components (D) and (E); Step 2: adding a component to the solution containing the water-soluble tackifier obtained in the step 1 (F) The other components other than the components, the components (A), (B), (C), (D) and (E) are mixed to prepare a stock solution.

<40> The production method according to the above <39>, wherein the step 1 is preferably a step of mixing under heating, and the heating temperature is preferably from 20 to 80 ° C, more preferably from 40 to 60 ° C.

<41> The production method according to the above <39> or <40> wherein the component (D) is an acid-type water-soluble tackifier, and it is preferred to add a base in the step 1.

The method of any one of the above-mentioned <39> to <41>, wherein the step 2 is preferably a step of mixing under heating, and the heating temperature is preferably 20 to 80 ° C, more preferably It is 40~60 °C.

<43> The method for producing a cooling according to any one of the above-mentioned <39> to <42> wherein the step 2 includes a step of mixing under heating, and preferably has a cooling step after mixing. It is preferably cooled to 20 to 30 ° C, more preferably to 20 to 25 ° C.

<44> A method of improving the osmotic feeling to the skin, which is applied to the skin by the spray cosmetic according to any one of the above <1> to <37>.

<45> A method of obtaining a skin feel of the skin, which is applied to the skin by the spray cosmetic according to any one of the above <1> to <37>.

<46> A cosmetic kit according to any one of the above-mentioned items <1> to <37>, which preferably contains a lotion or an emulsion, and more preferably contains a cosmetic other than the spray cosmetic. Lotion.

<47> A method of using a spray cosmetic according to any one of the above <1> to <37>, which is applied to or applied to the skin, and the cosmetic other than the spray cosmetic (Other cosmetic materials) are applied or applied to the skin to which the application or the spray cosmetic is applied.

<48> The use method according to the above <47>, wherein the other cosmetic material preferably has a carbon dioxide content of 10% by mass or less, more preferably 5% by mass or less, and still more preferably 1% by mass or less in the cosmetic. Further, it is more preferably 0.1% by mass or less, and particularly preferably 0% by mass.

<49> The method of use according to the above <47> or <48>, wherein the other cosmetic is preferably a lotion, an emulsion, a cream, more preferably a lotion or an emulsion, and further preferably a lotion.

<50> The method according to any one of the above-mentioned <47> to <49> wherein the other cosmetic material is preferably water-containing, and the water content is preferably 65~ in the total composition of the other cosmetic materials. 93% by mass, more preferably 70 to 92% by mass.

The use method according to any one of the above <47> to <50>, wherein the other cosmetic is preferably a polyol, and the content is preferably from 3 to 40 in the total composition of the other cosmetic materials. The mass % is more preferably 5 to 30% by mass, still more preferably 7 to 25% by mass.

<52> The method of use according to any one of the above <47> to <51>, wherein The makeup material is preferably a polyalkylene oxide-modified polyfluorene, and the content is preferably 0.005 to 2% by mass, more preferably 0.01 to 1.0% by mass, based on the total composition of the other cosmetic materials, and further preferably 0.015 to 0.5% by mass, and more preferably 0.02 to 0.2% by mass.

<53> The method according to any one of the above <47> to <52> wherein the other cosmetic is preferably a water-soluble tackifier, and the content is preferably in the total composition of the other cosmetic materials. 0.001 to 1.0% by mass, more preferably 0.01 to 0.5% by mass, still more preferably 0.05 to 0.3% by mass.

<54> The use method according to any one of the above <47> to <53>, wherein the use ratio of the spray cosmetic to the use amount of the other cosmetic materials [(the amount of the spray cosmetic used) / (other cosmetic) The amount of use) is preferably from 0.2 to 6, more preferably from 0.3 to 5, still more preferably from 0.4 to 4.

<55> The method according to any one of the above-mentioned <47> to <54> wherein the spray cosmetic is applied or applied to the skin, and then the other cosmetic is applied to the application or coated with the spray. The skin time of the cosmetic is preferably from 0 seconds to 5 minutes, more preferably from 3 seconds to 3 minutes, and still more preferably from 5 seconds to 1 minute.

<56> Use of a cosmetic in a spray container, comprising: 100% by mass of the entire stock solution, and comprising the following components (A), (B), (C), (D), and (E) Stock solution: (A) 0.1~1.5% by mass of polyfluorene oxide elastomer powder with an average particle size of 0.01~30μm, and (B) viscosity of 1~100mPa at 25°C. s oil agent 1~25% by mass, (C) HLB3~20 nonionic surfactant 0.05~6 mass%, (D) water soluble tackifier 0.1~1% by mass, (E) water; and (F A propellant containing 90% by mass or more of carbon dioxide.

<57> use of a cosmetic in a spray container, the cosmetic containing the following Ingredients (A), (B), (C), (D), (E), and (F): (A) Polyxanthene oxide elastomer powder having an average particle diameter of 0.01 to 30 μm, (B) 25 ° C The viscosity is 1~100mPa. s an oil agent, (C) a nonionic surfactant of HLB 3 to 20, (D) a water-soluble tackifier, (E) water, and (F) a propellant containing 90% by mass or more of carbon dioxide, and In the component (F), the content of the component (A) is 0.1 to 1.5% by mass, the content of the component (B) is 1 to 25% by mass, and the content of the component (C) is 0.05 to 6% by mass. Further, the content of the above component (D) is from 0.1 to 1% by mass.

<58> A cosmetic in which a cosmetic is filled in a spray container, and the cosmetic contains 100% by mass of the entire raw material and contains the following components (A), (B), (C), and (D) And (E) the raw liquid: (A) the average particle diameter of 0.01 ~ 30μm poly-xyloxy elastomer powder 0.1 ~ 1.5% by mass, (B) viscosity at 25 ° C is 1 ~ 100mPa. s oil agent 1~25% by mass, (C) HLB3~20 nonionic surfactant 0.05~6 mass%, (D) water soluble tackifier 0.1~1% by mass, (E) water; and (F A propellant containing 90% by mass or more of carbon dioxide.

<59> A cosmetic in which a cosmetic is filled in a spray container, and the cosmetic contains the following components (A), (B), (C), (D), (E), and (F): (A) a polyfluorene oxide elastomer powder having an average particle diameter of 0.01 to 30 μm, (B) The viscosity at 25 ° C is 1 ~ 100mPa. s an oil agent, (C) a nonionic surfactant of HLB 3-20, (D) a water-soluble tackifier, (E) water, and (F) a propellant containing more than 90% by mass of carbon dioxide, and In the component other than F), the content of the component (A) is 0.1 to 1.5% by mass, the content of the component (B) is 1 to 25% by mass, and the content of the component (C) is 0.05 to 6% by mass, and The content of the above component (D) is from 0.1 to 1% by mass.

[Examples]

Production Example 1 (Production of Resin Powder A)

82 g of lauryl methacrylate, 3 g of methacrylic acid, 15 g of ethylene glycol dimethacrylate, and 2 g of lauric acid peroxide were added to the beaker, and the mixture was stirred and dissolved. 400 g of ion-exchanged water in which 0.75 g of N-stearylsulfonyl-N-methyltaurine sodium (SMT) was dissolved was added thereto, and the mixture was dispersed by a homogenizer until the average particle diameter was 2.2 μm. This dispersion liquid was poured into a four-necked flask, and nitrogen substitution was performed for 30 minutes while stirring. The temperature inside the flask was heated to 80 ° C by an oil bath, and after 80 ° C was reached, polymerization was carried out for 5 hours, followed by cooling to room temperature. After neutralizing 3.9 g of 1N NaOH to the dispersion of the polymerized particles, the dispersion was freeze-dried, and the particles were recovered, thereby obtaining a resin powder A (lauryl methacrylate, ethylene glycol II). Methacrylate, sodium methacrylate). The degree of neutralization of the carboxyl group of the resin powder A was 11.2%.

Examples 1 to 2 and Comparative Examples 1 to 4

The spray cosmetic having the composition shown in Table 1 was produced, and the viscosity of the original solution was measured at 25 ° C, and the elongation of the bubble, the feeling of penetration of the bubble on the skin, the feeling of the skin after application, and the affinity of the lotion were evaluated. The results are collectively shown in Table 1.

(Production method)

The components (A), (D) and (E) were stirred at 60 ° C, and the base was further mixed and stirred. Thereafter, the components (B) and (C) and the remaining components were further added, stirred uniformly, and cooled to 25 ° C to obtain a stock solution. The obtained stock solution was filled in a pressure-resistant container, and after sealing, the component (F) was filled, thereby obtaining a spray cosmetic.

(evaluation method)

(1) Expansion of the bubble:

0.2 g of each cosmetic was sprayed onto a black pad made of polypropylene on a flat A4, and the long axis of the pad was placed perpendicular to the ground, and left for 30 seconds to measure the dripping of the cosmetic. The length was evaluated on the basis of the following criteria. The results are shown in total of 5 times.

5; extension is longer than 20cm.

4; the extension is longer than 18cm to 20cm.

3; the extension is longer than 16cm to 18cm.

2; the extension is longer than 14cm to 16cm.

1; only extended to below 14cm.

(2) Penetration of the bubble on the skin (quantitative evaluation):

0.1 g of each cosmetic was sprayed to the skin on the inner side of the forearm, and massaged for 10 seconds at a speed of 1 second and 2 turns in a circular shape having a diameter of 3 cm.

The friction immediately after the measurement (a) and the friction (b) after 1 minute were measured, and the values of (b)-(a) were calculated. The friction was measured using a handy rub tester manufactured by Trilab, applying a load of 10 N.

In the case of the friction, if the cosmetic material remains on the skin, the resistance is small, so that it has a small value. If the cosmetic material is not left, the resistance is increased, so that it has a large value. Therefore, by calculating the values of (b)-(a), it is evaluated how much the cosmetic penetrates into the skin depending on the residual condition of the cosmetic. The greater the value of (b)-(a), the better the penetration.

(3) Penetration of the bubble on the skin (functional evaluation):

0.1 g of each cosmetic was sprayed to the skin on the inner side of the forearm, and massaged for 1 minute at a speed of 3 cm in a diameter of 3 cm, and then immediately touched the skin to evaluate the penetration of the bubble. In the standard, the "perceived sensation of blistering" is set to 5, and the "permeability of sensation of blistering" is set to 5 levels. Further, the sensation of penetration means that the solution of the cosmetic material does not remain on the coated skin. The results are shown as a total of 5 points.

(4) The feeling of the skin of the skin after application:

0.1 g of each cosmetic was sprayed to the skin on the inner side of the forearm, and massaged for 1 minute at a speed of 3 cm in a diameter of 3 cm, and then immediately touched the skin to evaluate the film feeling. The standard is set to 5 levels of "obvious film feeling" and 5 levels of "no feeling of film feeling at all". The results are shown as a total of 5 points.

(5) Affinity of lotion:

0.1 g of each cosmetic was sprayed to the skin on the inner side of the forearm, and massaged at a speed of 5 cm in diameter at a speed of 1 second and 2 laps for 1 minute. Thereafter, a commercially available lotion (applied as makeup) was applied. Water 1) 0.2 g, massaged for 20 seconds in the same manner, and immediately touched the skin to evaluate the ease of affinity. Easy to use means that the lotion does not remain on the skin after massage. The standard is set to 5 for "apparent disappearance of lotion" and 5 levels for "apparent residual makeup". The results are shown as a total of 5 points.

Example 3~24

Spraying compositions of the compositions shown in Tables 2 to 4 were produced in the same manner as in Examples 1 and 2, and the swelling of the bubbles, the feeling of penetration of the bubbles on the skin, and the feeling of the skin of the skin after application were evaluated. The results are collectively shown in Tables 2 to 4.

Test example 1

The viscosity of the stock solution used in Example 1 and Example 3 was measured.

Specifically, 50 g of the stock solution was placed in a 50 mL glass container, and the viscosity was measured at 25 ° C by a BM viscometer (manufactured by Toki Sangyo Co., Ltd.) (rotor No. 3, 12 rpm, 1 minute). The results are shown below.

‧Example 1: 2130 mPa. s

‧ Example 3: 3920 mPa. s

Test example 2

The spray cosmetics of Examples 4, 11, 12, and 24 were evaluated as "Affinity of lotion". The results are shown in Table 5.

(Evaluation method of the affinity of lotion)

0.1 g of each spray cosmetic was sprayed to the inside of the forearm by 5 professional inspectors The skin was massaged at a speed of 5 cm in diameter for 1 minute at a rate of 1 second and 2 laps, and then coated with 0.2 g of lotion (SOFINA beaute lotion (wet type), manufactured by Kao Corporation). The same massage was carried out for 20 seconds, and the skin was immediately touched to evaluate the ease of affinity. The easy affinity means that the lotion does not remain on the skin after the massage. The standard is set to 5 for "apparent disappearance of lotion" and 5 levels for "apparent residual makeup". The results are shown as a total of 5 points.

Test Example 3

In the same manner as in Test Example 2, the spray cosmetics of Examples 3, 5 to 10, and 13 to 23 were evaluated as "the affinity of the lotion". The results are shown in Tables 6 to 8.

*2 EMANON CH60K, manufactured by Kao Corporation: HLB14

*4 SH3775M, manufactured by Toray Dow Corning: HLB5

*5 manufactured by PEMULEN TR-1, Lubrizol Advanced Materials, Inc.

*7 KF-98A-6cs, manufactured by Shin-Etsu Chemical Co., Ltd.: viscosity 6mPa. s

*8 Finsolv-TN, manufactured by Innospec Active Chemicals LLC: viscosity 13mPa. s

*13 TSF405, Momentive High-tech Materials Japan Co., Ltd. Manufactured: Viscosity 5.9mPa. s

*14 KF56A, manufactured by Shin-Etsu Chemical Co., Ltd.: viscosity 15mPa. s

*15 PARLEAM EX, manufactured by Nippon Oil Co., Ltd.: viscosity 15mPa. s

*16 Marukazol R, manufactured by Maruzen Petrochemical Co., Ltd.: viscosity 5mPa. s

*17 Nikkol squalane, manufactured by Nikko Chemicals: viscosity 30mPa. s

*18 COCONARD MT, manufactured by Kao Corporation: viscosity 26mPa. s

*4 SH3775M, manufactured by Toray Dow Corning: HLB5

*5 PEMULEN TR-1, manufactured by Lubrizol Advanced Materials, Inc.

*7 KF-96A-6cs, manufactured by Shin-Etsu Chemical Co., Ltd.: viscosity 6mPa. s

*8 Finsolv-TN, manufactured by Innospec Active Chemicals LLC: viscosity 13mPa. s

*15 PARLEAM EX, manufactured by Nippon Oil Co., Ltd.: viscosity 15mPa. s

*16 Marukazol R, manufactured by Maruzen Petrochemical Co., Ltd.: viscosity 5mPa. s

*19 Effective score of KSG-320, manufactured by Shin-Etsu Chemical Co., Ltd.

KSG-320 series (PEG-15/Lauryl polydimethyl decane) cross-linked polymer / isododecane = 25/75

*20 Effective score of KSG-41A, manufactured by Shin-Etsu Chemical Co., Ltd.

KSG-41A series (vinyl polydimethyl methoxy oxane / lauryl polydimethyl decane) cross-linked polymer / mineral oil = 30 / 75

Test Example 4 (Examples 25 and 26, Comparative Examples 5 to 8)

A spray cosmetic having the composition shown in Table 9 was produced in the same manner as in Examples 1 and 2, and the swelling of the bubble, the feeling of penetration of the foam on the skin, and the feeling of the skin of the skin after application were evaluated. Further, in the same manner as in Test Example 2, "the affinity of the lotion" was evaluated. The results are collectively shown in Table 9.

Test Example 5

When the spray cosmetic of Example 1 is used in combination with a commercially available lotion (hereinafter referred to as lotion 2) (method 1), and only case 2 (method 2) is used, the spread of the lotion is easy. The degree, the uniform adhesion to the skin, and the affinity of the lotion were evaluated. The results are shown in Table 10.

(evaluation method)

(1) Easiness of stretching of lotion:

(method 1)

0.1 g of the spray cosmetic of Example 1 was sprayed to the skin on the inner side of the forearm by 5 professional inspectors, and massaged at a speed of 5 cm for 1 minute at a speed of 1 second, and then 0.2 g of the lotion 2 was applied. The massage was similarly performed for 20 seconds, at which time the ease of spreading of the applied lotion 2 was evaluated. The benchmark is set to 5 levels of "easy extension" and 1 level of "non-extendable". The results are shown as a total of 5 points.

(Method 2)

Evaluation was performed in the same manner as in Method 1 except that the spray cosmetic of Example 1 was not used.

(2) Uniform adhesion to the skin:

(method 1)

0.03 g of the spray cosmetic of Example 1 was sprayed to the skin of the inside of the forearm to a size of 3 × 7 cm ² , and uniformly applied. Thereafter, 0.01 g of a lotion 2 containing disodium stilbene-biphenyldisulfonate (Tinopal CBS-X, manufactured by Ciba Specialty Chemicals Co., Ltd.) as a water-soluble phosphor was mixed with 0.01 g of a black light lamp ( Photographs of the coating section were taken using a digital single-lens camera (model: EOS 60D, lens: EF100mm F2.8 micro USM, manufactured by Canon Inc.) under the blue and black light FPL27BLB 27 watts and manufactured by Sankyo Electric Co., Ltd. The distribution of the lotion 2 was visually evaluated by the five professional inspectors based on the photograph. The standard is set to 5 levels of "evenly attached" and 5 levels of "unevenly attached". The results are shown as a total of 5 points.

(Method 2)

Evaluation was performed in the same manner as in Method 1 except that the spray cosmetic of Example 1 was not used.

Furthermore, an image of the photograph taken is shown in Fig. 1.

(3) Affinity of lotion:

(method 1)

Evaluation was performed in the same manner as in Test Example 2 except that the lotion 2 was used as the lotion.

(Method 2)

Evaluation was performed in the same manner as in Method 1 except that the spray cosmetic of Example 1 was not used.

Examples 27 and 28

Spray cosmetics having the compositions shown in Tables 11 and 12 were produced in the same manner as in Examples 1 and 2.

The foam of the obtained spray cosmetic has a good spread, and the foam has excellent penetration into the skin, and the skin after application has a feeling of the film. Further, the penetration feeling of the other cosmetic materials used after applying the spray cosmetic of the present invention to the skin is improved.

Reference example 1

The spray cosmetic of the present invention is applied or applied to the skin applied or coated with the spray cosmetic by application or application to the skin, thereby improving the penetration of other cosmetic materials. And improve the extension of other cosmetics.

As described above, the other cosmetic materials used after the spray cosmetic of the present invention are not particularly limited, and examples thereof include lotions of the compositions shown in Table 13.

Claims (9)

A spray cosmetic comprising: a stock solution containing the following components (A), (B), (C), (D), and (E) in an amount of 100% by mass of the whole stock solution; (A) an average particle diameter of 0.01 ~30μm polyxene oxide elastomer powder 0.1~1.5% by mass, (B) viscosity at 25 °C is 1~100mPa. s oil agent 1~25% by mass, (C) HLB3~20 nonionic surfactant 0.05~6 mass%, (D) water soluble tackifier 0.1~1% by mass, (E) water; and (F A propellant containing 90% by mass or more of carbon dioxide. The spray cosmetic of claim 1, wherein the component (B) is one or more selected from the group consisting of a hydrocarbon oil, an ester oil, and a polysiloxane. The spray cosmetic of claim 1, wherein the mass ratio [(A)/(C)] of the component (A) to the component (C) is 0.05 to 3. The spray cosmetic of claim 1, wherein the mass ratio [(A)/(D)] of the component (A) to the component (D) is 0.2 to 10. The spray cosmetic of claim 1, wherein the mass ratio [(A)/(F)] of the component (A) to the component (F) is 0.05 to 1. The spray cosmetic of claim 1, wherein the component (D) is one or more selected from the group consisting of a carboxyvinyl polymer and an acrylic acid-alkyl methacrylate copolymer. The spray cosmetic according to any one of claims 1 to 6, which further comprises one or two selected from the group consisting of alkyl glyceryl ether modified polyfluorene oxide and polyalkylene oxide modified polyfluorene oxide. the above. The spray cosmetic according to any one of claims 1 to 6, which further comprises the component (H) selected from the group consisting of One or two or more of the binary polyols. A spray cosmetic comprising the following components (A), (B), (C), (D), (E) and (F): (A) Polyoxynoxyelastic having an average particle diameter of 0.01 to 30 μm Body powder, (B) viscosity at 25 ° C is 1 ~ 100mPa. s an oil agent, (C) a nonionic surfactant of HLB 3-20, (D) a water-soluble tackifier, (E) water, and (F) a propellant containing more than 90% by mass of carbon dioxide, and In the component other than F), the content of the component (A) is 0.1 to 1.5% by mass, the content of the component (B) is 1 to 25% by mass, and the content of the component (C) is 0.05 to 6% by mass, and The content of the above component (D) is from 0.1 to 1% by mass.