TW201704462A - Hop pellets - Google Patents

Hop pellets Download PDF

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TW201704462A
TW201704462A TW105114951A TW105114951A TW201704462A TW 201704462 A TW201704462 A TW 201704462A TW 105114951 A TW105114951 A TW 105114951A TW 105114951 A TW105114951 A TW 105114951A TW 201704462 A TW201704462 A TW 201704462A
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hops
hop
beer
group
value
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TWI641681B (en
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Takako Inui
Hiroo Matsui
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Suntory Holdings Ltd
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    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12CBEER; PREPARATION OF BEER BY FERMENTATION; PREPARATION OF MALT FOR MAKING BEER; PREPARATION OF HOPS FOR MAKING BEER
    • C12C3/00Treatment of hops
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/38Other non-alcoholic beverages
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/52Adding ingredients
    • A23L2/56Flavouring or bittering agents
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12CBEER; PREPARATION OF BEER BY FERMENTATION; PREPARATION OF MALT FOR MAKING BEER; PREPARATION OF HOPS FOR MAKING BEER
    • C12C3/00Treatment of hops
    • C12C3/04Conserving; Storing; Packing
    • C12C3/06Powder or pellets from hops
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12CBEER; PREPARATION OF BEER BY FERMENTATION; PREPARATION OF MALT FOR MAKING BEER; PREPARATION OF HOPS FOR MAKING BEER
    • C12C5/00Other raw materials for the preparation of beer
    • C12C5/02Additives for beer
    • C12C5/026Beer flavouring preparations
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Food Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Genetics & Genomics (AREA)
  • Biochemistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Nutrition Science (AREA)
  • Polymers & Plastics (AREA)
  • Distillation Of Fermentation Liquor, Processing Of Alcohols, Vinegar And Beer (AREA)
  • Non-Alcoholic Beverages (AREA)

Abstract

Hop pellets obtained by using, as a starting material, 10 wt% or more of Saaz hop strobilus (L.SL) exhibiting a color hue that satisfies the requirements of a* ≥ -0.5 and b* ≥ 25 in the CIE Lab Color Model. The hop pellets according to the present invention have different characteristics from hops commonly employed. By selectively using the hop pellets according to the present invention and the hops commonly used or using the same in combination, therefore, more diversified beers can be manufactured and a new palatable taste can be provided.

Description

啤酒花顆粒 Hops granules

本發明係有關於啤酒花顆粒。更詳而言之,係有關於用於啤酒等的啤酒風味飲料的製造之啤酒花顆粒、該啤酒花顆粒的製造方法、及以該啤酒花顆粒為原料之啤酒風味飲料或含有啤酒花之組成物的製造方法。 The present invention relates to hops particles. More specifically, the present invention relates to hop granules for producing beer-flavored beverages such as beer, a method for producing the hop granules, and a method for producing a beer-flavored beverage or a hop-containing composition using the hop granules as a raw material .

對啤酒風味飲料而言,麥芽、啤酒花等原料會大幅影響其品質。舉例來說,啤酒花不僅會對啤酒風味飲料賦予苦味,還會賦予其爽口的啤酒花香或濃厚感。苦味係由啤酒花中的α酸等,啤酒花香係由萜烯類等,濃厚感則由多酚等,分別由各種的成分所賦予。然而,由於啤酒花為農作物,可掌握因種植因素或收成後的保存條件等而產生品質差異者。 For beer-flavored beverages, raw materials such as malt and hops will greatly affect their quality. For example, hops not only impart a bitter taste to beer-flavored beverages, but also give them a refreshing hop or a rich scent. The bitterness is derived from alpha acids in hops, the hops are from terpenes, and the thickness is imparted by various components such as polyphenols. However, since hops are crops, it is possible to grasp the difference in quality due to planting factors or storage conditions after harvesting.

舉例而言,在非專利文獻1中,係針對薩茲(Saaz)啤酒花,解析各栽培年度的天候與屬苦味成分之α酸的關係。由數據確認,屬苦味成分之α酸的值,會隨著溫度或濕度、照射日數等的天候因素大幅變動。 For example, in Non-Patent Document 1, the relationship between the weather of each cultivation year and the alpha acid of the bitterness component is analyzed for Saaz hops. It is confirmed by the data that the value of the alpha acid which is a bitter component varies greatly with weather conditions such as temperature, humidity, and number of days of irradiation.

另外,非專利文獻2係調查啤酒花的熟度或 收成時期會對啤酒花的品質造成何種影響者,係針對Cascade與Willamette揭示其結果。具體而言,針對在比標準收成日早10~14日的時期(Early)、標準收成日(Typical)、比標準收成日晚5~10日的時期(Late)共計3點收成的啤酒花測定其構成成分,其記載α酸、β酸、副酒花酮幾乎未有因收成時期所致之差異,而是大幅受到各年之種植條件等的影響。另一方面,就芳香油成分,收成時期為Early者係比Typical與Late來得少。 In addition, Non-Patent Document 2 investigates the familiarity of hops or The impact of the harvest period on the quality of hops is revealed by Cascade and Willamette. Specifically, the hops are measured at a total of 3 points in a period of 10 to 14 days (Early), a standard harvest day (Typical), and a period of 5 to 10 days later than the standard harvest day (Late). In the constituent components, it is described that the α acid, the β acid, and the hop ketone are hardly affected by the planting conditions of each year due to the difference in the harvest period. On the other hand, in the aromatic oil component, the harvest period is earlier than the Typical and Late.

再者,非專利文獻3指出啤酒花之精油成分的最高值係在其苦味質達最高後出現,並針對Hallertaua中早與Fuggle與薩茲(Saaz)揭示其結果。具體而言,就Hallertaua與Fuggle,於8月18日、8月31日、9月9日收成者,其中屬芳香油成分的沉香醇(Linalool)會隨時間經過而增加,但就薩茲而言,於8月18日、8月31日、9月9日收成者,其中的沉香醇則會緩緩減少,隨品種而異,沉香醇含量與啤酒花收成日早晚的關係也不一致。 Further, Non-Patent Document 3 indicates that the highest value of the essential oil component of hops occurs after the highest bitterness is reached, and the results are revealed for Hallertaua and Fuggle and Saaz. Specifically, in Hallertaua and Fuggle, on August 18th, August 31st, September 9th, the aromatic oil component of Linalool will increase over time, but in terms of Saz In the words, on August 18th, August 31st, and September 9th, the linalool will gradually decrease, depending on the variety, and the relationship between the content of linalool and the hop harvest day will be inconsistent.

另一方面,專利文獻1中揭示,藉由將收成後未經乾燥而冷凍的生啤酒花或者其粉碎物作為啤酒花原料使用,可製成大量含有屬新鮮生啤酒花之香氣成分的沉香醇等,且可將因啤酒花的氧化而生成的HDE(Humulene Diepoxide)等壓低至極少量之具有花香般、青草般的新鮮的香氣之芳香性高的發酵麥芽飲料。 On the other hand, in Patent Document 1, it is disclosed that a raw hop or a pulverized product which has been frozen without being dried after being harvested is used as a raw material of hops, and a large amount of linalool containing aroma components of fresh raw hops can be obtained, and A fermented malt beverage having a high aromaticity with a floral aroma and a fresh aroma of flowers, which is produced by oxidation of hops, such as HDE (Humulene Diepoxide), can be reduced to a very small amount.

專利文獻2中揭示,藉由將收成後經乾燥的 啤酒花毬果,在10~20℃的中低溫下進行3個月以上的熟成,可顯著促進供生成啤酒花毬果中之香氣成分的氧化反應,使啤酒花所含之香味成分增加,而且可顯著抑制汗臭或其他不佳之氧化臭成分及樹脂般的臭味等,而能夠製造富含啤酒花香氣成分的發酵酒精飲料。又,專利文獻3中揭示,在調製所述熟成啤酒花之際,透過將啤酒花中之特定的苦味成分及/或香氣成分的比例作為指標予以調整,可製造可賦予苦味與鮮味經調和之沉穩的苦味的後熟啤酒花(參照專利文獻3)。 Patent Document 2 discloses that by drying after harvesting The hops, which are cooked at a medium and low temperature of 10 to 20 ° C for more than 3 months, can significantly promote the oxidation reaction of the aroma components in the hops, and increase the aroma components contained in the hops, and can significantly inhibit A fermented alcoholic beverage rich in hop aroma components can be produced by sweaty odor or other undesirable oxidizing odor components and resin-like odors. Further, Patent Document 3 discloses that, when the cooked hops are prepared, by adjusting the ratio of the specific bitterness component and/or the aroma component in the hop as an index, it is possible to produce a calming taste which can impart a blend of bitterness and flavor. Post-ripe hops of bitterness (see Patent Document 3).

更者,專利文獻4中揭示,藉由對植物散布處理來自醯基環己二酮化合物群的生長調節性化合物等,可增加植物中之類黃酮及酚系成分的含量。 Further, Patent Document 4 discloses that the content of flavonoids and phenolic components in plants can be increased by treating plant growth-regulating compounds derived from the fluorenylcyclohexanedione compound group.

〔先前技術文獻〕 [Previous Technical Literature] 〔專利文獻〕 [Patent Document]

[專利文獻1]日本特開2004-81113號公報 [Patent Document 1] Japanese Patent Laid-Open Publication No. 2004-81113

[專利文獻2]日本特開2007-89439號公報 [Patent Document 2] Japanese Patent Laid-Open Publication No. 2007-89439

[專利文獻3]日本特開2008-228634號公報 [Patent Document 3] Japanese Patent Laid-Open Publication No. 2008-228634

[專利文獻4]日本特開2006-52217號公報 [Patent Document 4] Japanese Patent Laid-Open Publication No. 2006-52217

〔非專利文獻〕 [Non-patent literature]

[非專利文獻1]Krofta et al., Mathematical Model for Prediction of Alpha Acid Contents from Meteorological Data for ‘Saaz’ Aroma Variety, Proceedings of the Second International Humulus Symposium (ISBN:978 90 6605 722 7) 2009, p.131-139 [Non-Patent Document 1] Krofta et al., Mathematical Model for Prediction of Alpha Acid Contents from Meteorological Data for ‘Saaz’ Aroma Variety, Proceedings of the Second International Humulus Symposium (ISBN:978 90 6605 722 7) 2009, p.131-139

[非專利文獻2]Daniel C.Charp et al., Effect of Harvest Maturity on the Chemical Composition of Cascade and Willamette Hops, J. Am. Soc. Brew. Chem., 72 (4):231-238, 2014 [Non-Patent Document 2] Daniel C. Charp et al., Effect of Harvest Maturity on the Chemical Composition of Cascade and Willamette Hops, J. Am. Soc. Brew. Chem., 72 (4): 231-238, 2014

[非專利文獻3]啤酒釀造技術‧1998年12月28日初版發行(宮地秀夫)p48 [Non-Patent Document 3] Brewing Technology ‧Debut on December 28, 1998 (Miyaji Hideo) p48

然而,非專利文獻1中並未有香氣成分或濃厚感成分相關之報導,亦未詳細明述對啤酒風味飲料的品質造成影響之啤酒花原料品質的參差不齊及其原因(種植因素)。又,非專利文獻2中雖記載收成時期較晚收成的啤酒花其芳香成分較豐富,但該啤酒花一般而言並未上市,而且也有因啤酒花品質的劣化,使得使用其所得之啤酒風味飲料的香味品質無法獲得滿足之虞。再者,由非專利文獻3可明瞭,隨啤酒花的品種而異,收成日與芳香成分的含量之傾向也不同,可知收成日與啤酒花品質的關係並非一致。 However, Non-Patent Document 1 does not report on the aroma component or the thick component, and does not describe in detail the unevenness of the quality of the hop material and the cause (planting factor) which affect the quality of the beer flavored beverage. Further, in Non-Patent Document 2, it is described that the hops which are harvested later in the harvest period are rich in fragrant components, but the hops are generally not marketed, and the hops of the beer-flavored beverages obtained therefrom are also deteriorated due to deterioration of hop quality. Quality cannot be met. Further, from Non-Patent Document 3, it is understood that the tendency of the content of the harvest day and the content of the aroma component differs depending on the type of hop, and it is understood that the relationship between the harvest date and the quality of the hop does not match.

又,在生長中或收成後實施某些處理的情況下,需額外準備用於該處理的裝置或設備,而有作業繁雜或較不經濟的課題。 Further, in the case where some treatment is carried out during or after the harvest, it is necessary to additionally prepare a device or equipment for the treatment, and there is a problem that the operation is complicated or less economical.

本發明之課題在於,作為調整啤酒花之品質的因素之一,係著眼於啤酒花「外觀」,闡明其對啤酒風味飲料之品質所造成的影響,而提供一種可穩定地精製所期望之啤酒品質的啤酒花顆粒、該啤酒花顆粒的製造方法、及以該啤酒花顆粒為原料之啤酒風味飲料或含有啤酒花之組成物的製造方法。 An object of the present invention is to provide a stable appearance of the desired quality of beer by focusing on the "appearance" of hops and clarifying the effect on the quality of the beer-flavored beverage. Hop granules, a method for producing the hop granules, and a method for producing a beer-flavored beverage or a hop-containing composition using the hop granules as a raw material.

一般啤酒花顆粒係於一產地,在不同的農場中由啤酒花生產者收集多種在各種收成時期收成的啤酒花予以摻合後製造而成。本案發明人為了解決前述課題,而由收集之薩茲種啤酒花當中,僅選擇性地收集通常作為外觀劣化品而被啤酒花生產者棄之不用的略呈金黃色的啤酒花來調製啤酒花顆粒,並嘗試作成啤酒風味飲料,偶然獲得香味品質優良之耐人尋味的見地。因此,本案發明人對包含呈金黃色之啤酒花的使用比率等,進一步重複多次研究的結果發現,使用一定量以上之呈現特定的色相的啤酒花毬果調製顆粒,使用該顆粒所得之啤酒風味飲料在大量含有被視為有助於華麗的香氣(花香般等)之單萜烯類,尤為沉香醇方面屬優良者,終至完成本發明。 Generally, hops granules are produced in a place where hops are collected from different hops in various farms and mixed with hops harvested in various harvest periods. In order to solve the above-mentioned problems, the inventors of the present invention have only selectively collected hops of hops which are usually used as fascinating products and are discarded by hop producers, and try to prepare hop granules from among the collected sage hops, and try Create a beer-flavored drink and occasionally get an intriguing insight into the quality of the fragrance. Therefore, the inventors of the present invention have further repeated studies on the use ratio of hops containing golden yellow, etc., and found that a certain amount or more of hops berry granules exhibiting a specific hue is used, and the beer-flavored beverage obtained by using the granules is used. It is excellent in the case of a large amount of monoterpenes which are regarded as contributing to a gorgeous aroma (flowery, etc.), particularly in the form of linalool, and the present invention has finally been completed.

本發明係有關於下述〔1〕~〔4〕。 The present invention relates to the following [1] to [4].

〔1〕一種啤酒花顆粒,其係使用10重量%以上的呈現CIE Lab表色系統之a*的值滿足-0.5以上、b*的值滿足25以上的色相之薩茲種的啤酒花毬果(L‧SL)作為 原料而得到。 [1] A hop granule which uses 10% by weight or more of hops (A) having a value of - * of a CIE Lab color system that satisfies -0.5 or more and a value of b * of 25 or more. ‧SL) is obtained as a raw material.

〔2〕一種如前述〔1〕之啤酒花顆粒的製造方法,其特徵為使用啤酒花毬果的10重量%以上,該啤酒花毬果係使用呈現CIE Lab表色系統之a*的值滿足-0.5以上、b*的值滿足25以上的色相之薩茲種的啤酒花毬果(L‧SL)作為原料。 [2] A method for producing hop granules according to the above [1], characterized in that 10% by weight or more of the hops are used, and the hops are a value of -0.5 or more using a value of a * which exhibits a CIE Lab color system. The hops (L.SL) of the Saaz species having a h * value of 25 or more are used as raw materials.

〔3〕一種啤酒風味飲料的製造方法,其特徵為使用如前述〔1〕之啤酒花顆粒。 [3] A method for producing a beer flavored beverage, characterized in that the hop pellets according to the above [1] are used.

〔4〕一種含有啤酒花之組成物的製造方法,其特徵為使用如前述〔1〕之啤酒花顆粒。 [4] A method for producing a composition containing hops, which comprises using the hop pellets of the above [1].

使用本發明之啤酒花顆粒而得到的啤酒風味飲料,在大量含有被視為有助於華麗的香氣(花香般等)之單萜烯類,尤為沉香醇、香葉烯等方面屬優良者。 The beer-flavored beverage obtained by using the hop granules of the present invention is excellent in a large amount of monoterpenes which are considered to contribute to a gorgeous aroma (flowery, etc.), particularly linalool, geranene and the like.

第1圖為表示按各啤酒花的收成時期之CIE Lab及CIE Lch表色系統之各座標軸的數值的圖。 Fig. 1 is a view showing numerical values of respective coordinate axes of the CIE Lab and CIE Lch color system for each hop harvesting period.

第2圖為表示使用收成時期相異之啤酒花毬果所得之啤酒的官能評定結果(甜味)的圖。 Fig. 2 is a graph showing the results of functional evaluation (sweetness) of beer obtained by using hops with different harvest periods.

第3圖為表示使用收成時期相異之啤酒花毬果所得之啤酒的官能評定結果(啤酒之啤酒花香)的圖。 Fig. 3 is a view showing the results of the functional evaluation of beer obtained from the use of hops with different harvest periods (beer hops of beer).

〔實施發明之形態〕 [Formation of the Invention]

本發明之啤酒花顆粒係以使用10重量%以上的呈現CIE Lab表色系統之a*的值滿足-0.5以上、b*的值滿足25以上的色相之薩茲種的啤酒花毬果(表記為「啤酒花毬果(L‧SL)」)作為原料為特徵。以下,於本說明書中,亦有將啤酒花毬果單純記載為「啤酒花」。此外,在本說明書中使用「~」表示範圍時,係包含其兩端的數字。 Hop value based particles of the present invention to use 10 wt% or more exhibits the CIE Lab colorimetric system satisfies -0.5 a *, b * values satisfying the above 25 kinds of the hue of Saaz hops cones (denoted as " Hop hazel (L.SL)" is characterized as a raw material. Hereinafter, in the present specification, the hops are also simply described as "hops". In addition, when "~" is used in this specification to indicate a range, the number of both ends is included.

一般而言,啤酒花係以啤酒花中的α酸量達最高含量的當日作為收成開始日而開始收成,通常在25天左右即結束收成。又,啤酒花的外觀會隨時間經過而變黃,一般所知外觀較差的啤酒花,比起外觀良好者在市場上的交易價格會降低。從而,縱使在一般的收成期間內,啤酒花生產者若想要盡可能地收成更多的外觀更良好者,也會將日程提早,例如大多在收成開始日起15日以內收成,在期間的最後階段收成之外觀較差等的啤酒花在市場上流通的量極少。然而,本案發明人等藉由將這類被視為外觀較差的啤酒花與一般外觀良好的啤酒花摻混,提高其使用比率作成啤酒花顆粒,意外發現使用所得啤酒花顆粒作為原料的啤酒風味飲料可發揮優良的呈味。亦即,本發明係基於由作為外觀較差的啤酒花,比一般的收成時期晚,較佳為從收成開始日起15~50日左右後收成的啤酒 花當中,以CIE Lab表色系統之a*的值與b*的值為特定之數值的色相作為指標,選擇使用薩茲種的啤酒花毬果(L‧SL)者。此外,於本說明書中,啤酒花毬果的色相係指將啤酒花毬果乾燥並粉碎後的色相,例如可藉由後述之實施例所記載的方法來評定。 In general, hops are harvested on the day when the amount of alpha acid in the hops reaches the highest level, and the harvest is usually completed in about 25 days. Moreover, the appearance of hops will turn yellow over time, and hops, which are generally known to have a poor appearance, will be reduced in the market price compared to those with good appearance. Therefore, even if the hop producer wants to harvest as much as possible in the general harvest period, the schedule will be earlier, for example, the harvest will be completed within 15 days from the start of the harvest, at the end of the period. The amount of hops that are poor in appearance and the like in the market is extremely small. However, the inventors of the present invention have made such a hops which are regarded as having a poor appearance and blended with hops having a good general appearance, and increased the use ratio thereof to form hop granules, and unexpectedly found that the beer-flavored beverage using the obtained hop granules as a raw material can be excellent. Taste. That is, the present invention is based on the hops which are poor in appearance, which are later than the general harvesting period, preferably from 15 to 50 days after the start of the harvest, and which are a * of the CIE Lab color system. The hue with a value of b * and a specific value is used as an indicator, and the hops (L.SL) of the Saz species are selected. Further, in the present specification, the hue of the hops is a hue obtained by drying and pulverizing the hops, and can be evaluated, for example, by the method described in the examples below.

於本說明書中,薩茲種的啤酒花係指捷克產薩茲種,可包含苞或葉,只要至少包含毬花的忽布素部分則不特別限定。 In the present specification, the hops of the Saaz species are referred to as the Saz species of the Czech Republic, and may include sputum or leaves, and are not particularly limited as long as at least the sputum component of the sassafras is included.

被視為外觀良好之薩茲種的啤酒花毬果其CIE Lab表色系統之a*的值為0或負數,例如未達-0.5,收成時期愈早愈呈現接近綠色的色相。又,市售品之薩茲種啤酒花顆粒其a*的值亦為負數,通常為-0.8~-1.2左右。另一方面,本發明所使用之啤酒花毬果(L‧SL)其a*的值為-0.5以上,較佳為-0.2以上,呈現接近紅色的色相。 Is regarded as a good appearance of Saaz hops cones that kind of CIE Lab color system of a * value of 0 or negative, such as less than -0.5, the sooner the better harvest period for near-green hue. Further, the value of a * of the Saz hops granules of the commercial product is also a negative number, and is usually about -0.8 to -1.2. On the other hand, the hops (L‧SL) used in the present invention has a value of a * of -0.5 or more, preferably -0.2 or more, and exhibits a hue close to red.

又,薩茲種的啤酒花毬果,無論其外觀是否良好,其CIE Lab表色系統之b*的值均顯示正數,收成時期愈晚,數值雖會隨之變動,但無法看出一定的傾向。縱使如此,其均呈現接近黃色的色相。本發明所使用之啤酒花毬果(L‧SL)其b*的值為25以上,較佳為29以上。此外,市售品之薩茲種啤酒花顆粒其b*的值為正數,通常為29~35左右。 Moreover, the hops of the Saz species, regardless of their appearance, the value of b * of the CIE Lab color system shows a positive number. The later the harvest period, the value will change, but the certain tendency cannot be seen. . Even so, they all exhibit a hue close to yellow. The hops (L.SL) used in the present invention has a value of b * of 25 or more, preferably 29 or more. Further, the commercially available Saaz hop granules have a positive value of b * , usually about 29 to 35.

本發明所使用之啤酒花毬果(L‧SL)其CIE Lab表色系統之a*的值與b*的值係為前述數值,而 薩茲種的啤酒花毬果其CIE Lab表色系統之L*的值為正數,收成時期愈晚,數值雖會隨之變動,但無法看出一定的傾向。縱使如此,其明度均較高。本發明所使用之啤酒花毬果(L‧SL)之L*的值較佳為55以上。此外,市售品之薩茲種啤酒花顆粒其L*的值為正數,通常為50~65左右。 The hops (L.SL) used in the present invention has the values of a * and b * of the CIE Lab color system as the aforementioned values, and the hops of the saz species have its L of the CIE Lab color system. The value of * is a positive number. The later the harvest period, the value will change, but there is no certain tendency. Even so, its brightness is high. The value of L * of the hops (L.SL) used in the present invention is preferably 55 or more. In addition, the commercial sax hop granules have a positive L * value of usually about 50 to 65.

又,以與CIE Lab表色系統不同的CIE Lch表色系統表示薩茲種的啤酒花毬果時,CIE Lch表色系統之c*的值為正數,收成時期愈晚,數值雖會隨之變動,但無法看出一定的傾向。縱使如此,其彩度均較高。本發明所使用之啤酒花毬果(L‧SL)之c*的值較佳為30以上。此外,市售品之薩茲種啤酒花顆粒其c*的值為正數,通常為29~35左右。 Moreover, when the CIE Lch color system different from the CIE Lab color system indicates the hops of the Saz species, the C * value of the CIE Lch color system is a positive number, and the later the harvest period, the value will change accordingly. But can't see a certain tendency. Even so, the chroma is high. The value of c * of the hops (L.SL) used in the present invention is preferably 30 or more. Further, the commercially available Saaz hop granules have a positive value of c * , usually about 29 to 35.

薩茲種的啤酒花毬果之CIE Lch表色系統之h的值若為正數時,會隨著收成時期愈晚而愈小,到了收成期間的後半段會急遽降低。本發明所使用之啤酒花毬果(L‧SL)之h的值較佳為75°以上,更佳為78°以上;較佳為90.5°以下,更佳為88°以下。此外,CIE Lch表色系統之h的值係指色相角度,市售品之啤酒花顆粒之h的值通常為91°~95°左右。 If the value of h in the CIE Lch color system of the sage hops is positive, it will be smaller as the harvest period becomes later, and will fall sharply in the second half of the harvest period. The value of h of the hops (L.SL) used in the present invention is preferably 75 or more, more preferably 78 or more; preferably 90.5 or less, more preferably 88 or less. Further, the value of h of the CIE Lch color system refers to the hue angle, and the value of h of the commercially available hop particle is usually about 91 to 95.

本發明之啤酒花顆粒,只要使用具有如前述所規定之色相的啤酒花毬果(L‧SL)作為原料,則其他的原料不特別限定。原料全體中的前述色相之啤酒花毬果(L‧SL)的用量,基於使啤酒風味飲料大量含有被視為 有助於華麗的香氣(花香般等)之單萜烯類,尤為沉香醇、香葉烯等的觀點,係為10重量%以上,較佳為20重量%以上,更佳為50重量%以上;基於可穩定且大量地供應本發明之啤酒花顆粒的觀點,較佳為100重量%以下,更佳為90重量%以下,再更佳為80重量%以下。此外,一般啤酒花顆粒係於一產地,在不同的農場中由啤酒花生產者收集多種在各種收成時期收成的啤酒花予以摻合後製造而成。前述色相之啤酒花毬果(L‧SL)係呈現接近紅色,且略帶黃色的啤酒花外觀,已失去啤酒花之鮮豔的綠色,屬外觀劣化品被啤酒花生產者棄之不用。因此,若非選擇性地收集前述色相之啤酒花毬果(L‧SL)來調製,原料全體中的前述色相之啤酒花毬果(L‧SL)的用量便達不到10重量%以上。 The hop particles of the present invention are not particularly limited as long as the hops (L.SL) having the hue as defined above are used as the raw material. The amount of the hops (L‧SL) of the aforementioned hue in the whole raw material is based on making the beer-flavored beverage contain a large amount The monoterpene which contributes to a rich aroma (flowery, etc.), especially a linalyl alcohol, a geranene, etc., is 10 weight% or more, Preferably it is 20 weight% or more, More preferably, it is 50 weight% or more. The viewpoint of supplying the hop particles of the present invention stably and in a large amount is preferably 100% by weight or less, more preferably 90% by weight or less, still more preferably 80% by weight or less. In addition, the general hop granules are produced in a place where the hop producers collect a variety of hops collected in various harvest periods in different farms and blend them. The aforementioned hops of hops (L.SL) are nearly red, and have a yellowish hop appearance, which has lost the vivid green color of hops, and the appearance deterioration products are discarded by the hop producers. Therefore, if the hops (L‧SL) of the above-described hue are not selectively collected and prepared, the amount of the hops (L·SL) of the aforementioned hue in the entire raw material is less than 10% by weight.

又,本發明之啤酒花顆粒,只要使用特定量的具有如前述所規定之色相的啤酒花毬果(L‧SL)作為原料,則其調製方法不予限定。例如,只要將含有具有如前述所規定之色相的啤酒花毬果(L‧SL)的原料,利用打錠機進行造粒即可。 Further, the hop particle of the present invention is not limited as long as a specific amount of hops (L.SL) having a hue as defined above is used as a raw material. For example, a raw material containing hops (L.SL) having a hue as defined above may be granulated by a tablet machine.

一般而言,啤酒花在收成後,為了防止腐壞而加以乾燥去除水分。將收成時有約80%左右的水分降低至15%以下,較佳為11%以下後予以儲存。乾燥係於65℃以下,較佳為60℃以下進行。於本發明中,基於不使富含之沉香醇氧化的觀點,宜使用將水分降低至較佳為15%以下,更佳為11%以下的啤酒花毬果(L‧SL)。另 一方面,基於防止乾燥之啤酒花裂開等的破損之觀點,宜使用水分較佳為9%以上,更佳為10%以上的啤酒花毬果(L‧SL)。 In general, after the harvest, the hops are dried to remove moisture in order to prevent spoilage. When about 80% of the water is reduced to 15% or less, preferably 11% or less, it is stored. The drying is carried out at 65 ° C or lower, preferably 60 ° C or lower. In the present invention, it is preferred to use hops (L.SL) which lowers the water content to preferably 15% or less, more preferably 11% or less, based on the viewpoint of not oxidizing the rich linalool. another On the other hand, it is preferable to use hops (L.SL) having a water content of preferably 9% or more, more preferably 10% or more, from the viewpoint of preventing breakage of dry hopping or the like.

如此所得之本發明之啤酒花顆粒其CIE Lab表色系統之a*的值較佳為-0.5以上,更佳為-0.2以上;較佳為4以下,更佳為3.5以下。CIE Lab表色系統之b*的值較佳為25以上,更佳為29以上;較佳為40以下,更佳為36以下。又,CIE Lch表色系統之h的值較佳為75°以上,更佳為78°以上;較佳為90°以下,更佳為87°以下。此外,前述的值係依據啤酒花毬果(L‧SL)的用量而變動,惟較佳處於前述範圍內。 The hop particle of the present invention thus obtained preferably has a value of a * of the CIE Lab color system of -0.5 or more, more preferably -0.2 or more, more preferably 4 or less, still more preferably 3.5 or less. The value of b * of the CIE Lab color system is preferably 25 or more, more preferably 29 or more; preferably 40 or less, more preferably 36 or less. Further, the value of h of the CIE Lch color system is preferably 75 or more, more preferably 78 or more; preferably 90 or less, more preferably 87 or less. Further, the aforementioned values vary depending on the amount of hops (L‧SL), but are preferably within the above range.

本發明又提供一種啤酒花顆粒的製造方法,其特徵為使用啤酒花毬果中的10重量%以上,該啤酒花毬果係使用呈現CIE Lab表色系統之a*的值滿足-0.5以上、b*的值滿足25以上的色相之薩茲種的啤酒花毬果(L‧SL)作為原料。於此,作為原料使用之啤酒花毬果係指作為原料使用之啤酒花毬果的總用量。 The present invention further provides a method for producing hop granules, characterized in that 10% by weight or more of hops are used, and the hops using a value of a * exhibiting a CIE Lab color system satisfy -0.5 or more, b * The hops (L.SL) of the Saaz species having a hue of 25 or more are used as raw materials. Here, the hops used as a raw material means the total amount of hops used as a raw material.

在本發明之啤酒花顆粒的製造方法中,只要使用特定量的前述之色相的啤酒花毬果(L‧SL)作為原料,則對於原料的種類、量、使用比例、及造粒之方法等,可參照本發明之啤酒花顆粒之項目使用。 In the method for producing hop granules of the present invention, as long as a specific amount of hops (L·SL) of the above-described hue is used as a raw material, the type, amount, use ratio, and granulation method of the raw material may be used. Reference is made to the item of hop pellets of the present invention.

又,本發明亦提供一種啤酒風味飲料的製造方法,其特徵為使用本發明之啤酒花顆粒。 Further, the present invention also provides a method of producing a beer flavored beverage, characterized in that the hop pellet of the present invention is used.

本說明書中的「啤酒風味飲料」係指具有啤 酒般的風味的碳酸飲料。換言之,本說明書之啤酒風味飲料,若未特別合先敘明,則不拘使用酵母之發酵步驟的有無,包含所有啤酒風味之碳酸飲料。具體而言,可舉出啤酒、發泡酒、其他雜酒、利口酒類、非酒精飲料等。 “Beer flavored drink” in this manual means beer A carbonated drink with a wine-like flavor. In other words, the beer-flavored beverage of the present specification includes all beer-flavored carbonated beverages without using the yeast fermentation step, unless otherwise specified. Specific examples thereof include beer, sparkling wine, other miscellaneous wines, liqueurs, and non-alcoholic beverages.

就本發明之啤酒風味飲料的製造方法,除了包含使用本發明之啤酒花顆粒的步驟以外,亦可依循本領域具有通常知識者所熟知的一般方法來進行。例如,除選自由麥芽等的麥、其他的穀物、澱粉、及糖類所成之群中的至少1種之外,還可視需求將苦味料、色素等原料饋入至裝置釜或裝置槽中,並視需求添加澱粉酶等的酵素使其進行糊化、糖化後,藉由過濾去除穀皮等而得到麥汁,接著對所得麥汁添加本發明之啤酒花顆粒予以煮沸,在澄清槽中去除凝固蛋白質等的固體成分,而得到澄清麥汁。此等糖化步驟、煮沸‧澄清化步驟、固體成分除去步驟等中的條件只要採用周知之條件即可。 The method for producing the beer-flavored beverage of the present invention may be carried out in accordance with a general method well known to those skilled in the art, in addition to the step of using the hop particles of the present invention. For example, in addition to at least one selected from the group consisting of wheat, other grains, starch, and sugars such as malt, raw materials such as bitter, pigment, and the like may be fed into the apparatus tank or the device tank as needed. And adding an enzyme such as amylase to gelatinize and saccharify as needed, and then removing the hull by filtration to obtain wort, and then adding the hop granule of the present invention to the obtained wort, boiling it, and removing it in the clarification tank A solid component such as a protein is coagulated to obtain a clarified wort. The conditions in the saccharification step, the boiling, the clarification step, the solid component removal step, and the like may be as long as known conditions are employed.

其次,若為酒精飲料時,可對前述所得之澄清麥汁添加酵母使其進行發酵,並視需求以過濾機等去除酵母而製造(亦稱發酵步驟)。發酵條件只要採用周知之條件即可。又,亦可於發酵開始後添加前述中經篩選之本發明中的啤酒花毬果(L‧SL)或包含彼等的啤酒花顆粒。或者,亦可添加蒸餾酒等具有酒精分的原料,來替代經過發酵步驟。進而,經過儲酒步驟,視需求添加二氧化碳,再經過過濾‧容器填裝步驟,並視需求經過殺菌步驟,可製得酒精啤酒風味飲料。 Next, in the case of an alcoholic beverage, yeast may be added to the clarified wort obtained as described above to be fermented, and the yeast may be removed by a filter or the like as needed (also referred to as a fermentation step). The fermentation conditions may be as long as known conditions are employed. Further, the hops (L.SL) of the present invention screened in the above-mentioned medium may be added or the hop particles containing the same may be added after the start of the fermentation. Alternatively, a raw material having an alcohol content such as distilled wine may be added instead of the fermentation step. Further, after the wine storage step, carbon dioxide is added according to the demand, and then the filtration and container filling steps are carried out, and the sterilization step is performed according to the demand, thereby preparing an alcoholic beer flavored beverage.

另一方面,若為非酒精飲料時,則可例如未經過前述發酵步驟,在上述固體成分除去步驟後,直接儲存前述中所得的澄清麥汁,添加二氧化碳,經過過濾‧容器填裝步驟,並視需求經過殺菌步驟而製造。或者,在前述酒精飲料的發酵步驟之後,藉由啤酒膜處理或稀釋等的周知之方法降低酒精濃度,由此亦可得到非酒精啤酒風味飲料。 On the other hand, in the case of a non-alcoholic beverage, for example, after the solid component removal step, the clarified wort obtained as described above may be directly stored, the carbon dioxide is added, and the filtration and container filling steps are performed, without the above-described fermentation step. Manufactured according to the requirements of the sterilization step. Alternatively, after the fermentation step of the alcoholic beverage described above, the alcohol concentration is lowered by a well-known method such as beer film treatment or dilution, whereby a non-alcohol beer-flavored beverage can also be obtained.

如此,透過使用本發明之啤酒花顆粒,可發揮以下優良的效果:可有效地精製在大量含有被視為有助於華麗的香氣(花香般等)之單萜烯類,尤為沉香醇、香葉烯等方面屬優良的啤酒風味飲料。 In this way, by using the hop granules of the present invention, the following excellent effects can be exhibited: it can be efficiently purified and contains a large amount of monoterpenes which are regarded as contributing to a gorgeous aroma (floral-like, etc.), especially linalool and geranium. It is an excellent beer flavored beverage in terms of olefins and the like.

又,本發明亦提供一種含有啤酒花之組成物的製造方法,其特徵為使用本發明之啤酒花顆粒。 Further, the present invention also provides a method for producing a composition containing hops, which is characterized in that the hop particles of the present invention are used.

本說明書中的「含有啤酒花之組成物」係指萃取自本發明之啤酒花顆粒的組成物,進一步包含其組成物的二次加工品。作為其一例,可舉出以乙醇為溶劑的啤酒花萃取物、或以二氧化碳為溶劑的啤酒花萃取物(亦包含將乾燥之次臨界狀態或超臨界狀態之二氧化碳用於溶劑而得到的啤酒花萃取物(日本專利第3155003號、日本專利第3513877))、或異構化啤酒花、還原啤酒花、生啤酒花、六氫異構化啤酒花、四氫異構化啤酒花等的啤酒花加工品。 The "composition containing hop" in the present specification means a composition extracted from the hop particles of the present invention, and further includes a secondary processed product of the composition. Examples thereof include a hop extract using ethanol as a solvent or a hop extract using carbon dioxide as a solvent (including a hop extract obtained by using a dry subcritical state or a supercritical carbon dioxide as a solvent). Japanese Patent No. 3155003, Japanese Patent No. 3513877), or processed hops of isomerized hops, reduced hops, raw hops, hexahydroisomerized hops, tetrahydroisomerized hops, and the like.

〔實施例〕 [Examples]

以下示出實施例對本發明具體地加以說明,惟本發明非限於下述實施例。 The invention is specifically illustrated by the following examples, but the invention is not limited to the following examples.

試驗例1(啤酒花毬果的色相) Test Example 1 (hue of hops hazelnut)

針對2012年、2013年、及2014年產之啤酒花原料(品種:Saaz,產地:捷克),按收成時期之順序,將在收成開始日收成者分為「E群」,將收成開始日起10日後收成者分為「M群」,將收成開始日起25日後收成者分為「L群」,將收成開始日起50日後收成者分為「SL群」,依循以下條件測定色相。此外,對前述分群以併記收成年度之下二位的方式來表記收成年度與收成時期。例如,2013年產之「L群」係如「13L」所示。又,作為試樣的前處理,係將各群之乾燥毬花以咖啡磨粉機磨碎,將其粉碎物直接供予測定。將測定結果示於表1及第1圖。另外,對於混合作為市售之薩茲種啤酒花顆粒之於2013年收成的各種農場的啤酒花後再經過顆粒加工者亦同樣地進行評定。 For the hops raw materials (variety: Saaz, origin: Czech Republic) produced in 2012, 2013, and 2014, the harvesters will be divided into "E groups" on the harvest start date in the order of the harvest period, starting from the start date of the harvest. In the future, the harvester is divided into "M group", and the harvester is divided into "L group" after 25 days from the start of the harvest, and the harvester is divided into "SL group" 50 days after the start of the harvest, and the hue is measured according to the following conditions. In addition, the harvest year and the harvest period are expressed in the manner in which the above-mentioned grouping is recorded in the lower two places. For example, the "L group" produced in 2013 is as shown in "13L". Further, as a pretreatment of the sample, the dried squid of each group was ground by a coffee grinder, and the pulverized product was directly supplied for measurement. The measurement results are shown in Table 1 and Figure 1. In addition, the granules of various farms which were collected in 2013 as the commercially available Saz hop granules were similarly evaluated by the granule processor.

<色相測定條件> <Hue measurement conditions>

表色系統:CIE Lab表色系統 Color system: CIE Lab color system

測定儀器:分光測色系統CM-2002(MINOLTA公司製) Measuring instrument: Spectrophotometric system CM-2002 (manufactured by MINOLTA)

視角:10°視野 Viewing angle: 10° field of view

光源:D65 Light source: D65

解析軟體:SpectraMagic NX(MINOLTA公司製) Analysis software: SpectraMagic NX (manufactured by MINOLTA)

根據表1及第1圖,「12L群」、「12SL群」、「13L群」、「13SL群」、「14L群」及「14SL群」其CIE Lab表色系統之a*的值為-0.5以上,與其他的群大幅相異。又,「12L群」、「12SL群」、「13L群」、「13SL群」、「14L群」及「14SL群」其CIE Lch表色系統之h的值為77.74°至90.27°,由在年度內的對比,分別與「E群」及「M群」大幅相異。從而,「12L群」、「12SL群」、「13L群」、「13SL群」、「14L群」及「14SL群」,比起其他的群均可看出數值 上的差異,可看出與其他時期收成者外觀上相異。 According to Table 1 and Figure 1, the values of a * of the CIE Lab color system of "12L Group", "12SL Group", "13L Group", "13SL Group", "14L Group" and "14SL Group" are - 0.5 or more, which is significantly different from other groups. In addition, the values of h in the CIE Lch color system of "12L group", "12SL group", "13L group", "13SL group", "14L group" and "14SL group" are 77.74° to 90.27°. The comparisons during the year are significantly different from the "E Group" and the "M Group" respectively. Therefore, the "12L group", "12SL group", "13L group", "13SL group", "14L group" and "14SL group" can be seen as numerical differences compared with other groups. In other periods, the harvesters look different.

此外,非專利文獻2中既已述及,其記載針對啤酒花的收成時期在比標準收成日早10~14日的時期(Early)、標準收成日(Typical)、比標準收成日晚5~10日的時期(Late)共計3點收成的啤酒花測定其構成成分,屬苦味成分的α酸、β酸、副酒花酮幾乎未有因收成時期所致之差異,而是大幅受到各年之栽培條件等的影響;就芳香油成分,收成時期為Early者係比Typical與Late來得少。然而,收成時期較晚的啤酒花,由此結果色相呈紅色,呈現金黃色的外觀,但由非專利文獻2並無法獲知色相與啤酒風味飲料之香味的相關性。 Further, in Non-Patent Document 2, it is described that the harvesting period for hops is 10 to 14 days earlier than the standard harvest day (Early), standard harvest day (Typical), and 5 to 10 times later than the standard harvest day. In the day of the day (Late), the hops of the three-point harvest are measured, and the alpha-acid, the beta-acid, and the hop-based hops, which are bitter components, are hardly affected by the harvest period, but are greatly affected by the cultivation conditions of each year. The influence of the other; as for the aromatic oil component, the harvest period is earlier than the Typical and Late. However, the hops which are later in the harvest period have a reddish hue and a golden appearance, but the correlation between the hue and the flavor of the beer-flavored beverage is not known from Non-Patent Document 2.

試驗例2(啤酒花毬果的苦味成分與芳香成分) Test Example 2 (bitter and aroma components of hops)

針對以與試驗例1同樣的方式分群的啤酒花毬果,與試驗例1同樣地進行前處理後依循以下條件測定苦味成分與芳香成分的含量。此外,前述經分群之啤酒花的表記係與試驗例1相同。又,對作為市售之薩茲種啤酒花顆粒之與試驗例1同樣地經過顆粒加工者亦同樣地進行評定。將測定結果示於表2。 The hops that were grouped in the same manner as in Test Example 1 were pretreated in the same manner as in Test Example 1, and the contents of the bitterness component and the aroma component were measured according to the following conditions. Further, the above-described grouped hops were the same as in Test Example 1. Moreover, the same as the test example 1 of the commercially available Saz hop granules was similarly evaluated by the granule processor. The measurement results are shown in Table 2.

<苦味成分的測定條件> <Measurement conditions of bitter component>

啤酒花原料中之α酸、β酸、副酒花酮的定量分析係依循EBC(European Brewery Convention)所發行之分析法的規定「Analytica-EBC」之Method 7.7所記載的方法 來進行。 Quantitative analysis of alpha acids, beta acids, and hops in hops is based on the method described in Method 7.7 of "Analytica-EBC", which is defined by the EBC (European Brewery Convention). Come on.

<芳香成分的測定條件> <Measurement conditions of aromatic ingredients>

作為啤酒花原料中之芳香(精油)成分的定量分析,精油成分的合計含量係根據ASBC(The American Society of Brewing Chemists)所發行之分析法的規定「ASBC Methods of Analysis」所記載的水蒸氣蒸餾法定量,並進一步對所得精油以GC-MS(TIC模式),依以下條件進行芳香各成分的定量分析。 As a quantitative analysis of the aromatic (essential oil) component in the hop raw material, the total content of the essential oil component is the steam distillation method described in the "ASBC Methods of Analysis" according to the analysis method issued by ASBC (The American Society of Brewing Chemists). Quantitatively, and further quantitative analysis of the aromatic components was carried out by GC-MS (TIC mode) on the obtained essential oil under the following conditions.

〔GC-MS條件〕 [GC-MS conditions]

毛細管柱:J&W公司製DB-WAX(長度60m,內徑0.25mm,膜壓0.5μm) Capillary column: DB-WAX manufactured by J&W Co., Ltd. (length 60 m, inner diameter 0.25 mm, membrane pressure 0.5 μm)

烘箱溫度:自40℃起以6℃/分昇溫至240℃,保持20分 Oven temperature: from 40 ° C to 6 ° C / min to 240 ° C, keep 20 minutes

載送氣體:He Carrier gas: He

氣體流量:1.5mL/min Gas flow rate: 1.5mL/min

傳輸線路溫度:240℃ Transmission line temperature: 240 ° C

MS離子源溫度:230℃ MS ion source temperature: 230 ° C

MS四極溫度:150℃ MS quadrupole temperature: 150 ° C

前側注入口溫度:240℃ Front side inlet temperature: 240 ° C

根據表2,對於苦味成分(α酸、β酸、副酒花酮),由在年度內的對比,未看出收成時期的差異所致之含量的變動。另一方面,對於芳香成分(沉香醇、香葉烯),「12L群」、「12SL群」、「13L群」、「13SL群」、「14L群」及「14SL群」,由在年度內的對比,分別與「E群」及「M群」大幅相異,且為高含量。從而,可知顯示出與非專利文獻2同樣的傾向。 According to Table 2, for the bitterness component (alpha acid, beta acid, and hop ketone), the change in the content due to the difference in the harvest period was not observed by comparison within the year. On the other hand, for the aromatic components (salt alcohol, geraniene), "12L group", "12SL group", "13L group", "13SL group", "14L group" and "14SL group" are included in the year. The comparisons are significantly different from the "E group" and the "M group" respectively, and are high in content. Therefore, it is understood that the same tendency as Non-Patent Document 2 is exhibited.

試驗例3(啤酒的官能評定) Test Example 3 (Functional Evaluation of Beer) <啤酒的製造> <Manufacture of beer>

分別調製由試驗例1中所使用之「13E群」、「13M 群」或「13L群」之啤酒花毬果的粉碎物構成的啤酒花顆粒後,添加於以一般方法所得到的過濾麥汁100L。攪拌1分鐘後,取出旋渦槽殘餘物,予以急速冷卻,調製成冷麥汁。添加酵母使其發酵,經過濾後,調整二氧化碳壓力而製成啤酒。 The "13E group" and "13M" used in the test example 1 were separately modulated. After the hop pellets composed of the pulverized material of the hops of the "Group" or "13L group", 100 g of the filtered wort obtained by the general method was added. After stirring for 1 minute, the residue of the vortex tank was taken out and rapidly cooled to prepare a cold wort. Yeast is added to ferment, and after filtration, the pressure of carbon dioxide is adjusted to produce beer.

<官能評定> <Functional assessment>

茲根據採評分法的官能試驗來評定所得之啤酒的香味。請5位經過充分訓練的官能評定者,就「甜味」及「啤酒之啤酒花香」的有無,針對製成的啤酒進行有關啤酒花之香氣特徵與味道的官能比較評定。茲就各香氣特徵,將其強度以0至3分,以0.1分為級距進行評分比較評定。隨官能檢查員的不同,官能評分範圍也不同,因此,係以一位官能檢查員對全部試樣之評分的平均為50、標準差為10的方式予以標準化,進行試樣間的比較。將「甜味」的評定結果示於第2圖,將「啤酒之啤酒花香」的評定結果示於第3圖。 The aroma of the resulting beer was evaluated according to the functional test of the scoring method. For the five well-trained functional assessors, the "sweet flavor" and the "beer hops" of the beer were evaluated for the beer's aroma characteristics and taste. For each aroma characteristic, the intensity is scored from 0 to 3 points and scored in 0.1 steps. The functional scoring range differs depending on the functional inspector. Therefore, a single functional inspector normalizes the scores of all the samples to 50 and the standard deviation is 10, and compares between the samples. The evaluation result of "sweet taste" is shown in Fig. 2, and the evaluation result of "beer hops of beer" is shown in Fig. 3.

由第2圖可明瞭,「13L群」比起「13E群」及「13M群」,「甜味」較少。又,由第3圖可知,「13L群」比起「13E群」及「13M群」較富「啤酒之啤酒花香」。亦即,本發明實施形態之「13L群」,其苦味成分係與一般啤酒花同等,富含芳香油成分(沉香醇),且極富「啤酒之啤酒花香」,甚而,賦予「甜味」之味道的因子較少。「甜味」係對於啤酒的香味具有正面作用的 因子,但與例如來自麥芽的甜味等共同作用而成為過度的甜味時,有時對於啤酒全體的香味會有負面作用。藉由具備與一般啤酒花不同的特性,透過與一般啤酒花分開使用、及併用,可拓展啤酒製造的寬裕度。 As can be seen from Figure 2, the "13L Group" is less "sweet" than the "13E Group" and "13M Group". In addition, as can be seen from the third figure, "13L Group" is richer than "13E Group" and "13M Group". In other words, the "13L group" according to the embodiment of the present invention has the same bitter taste component as the general hops, is rich in aromatic oil component (salted alcohol), and is rich in "beer hops", and even imparts "sweetness". There are fewer factors for taste. "Sweet" has a positive effect on the aroma of beer. The factor may be a negative effect on the flavor of the whole beer when it is combined with sweetness such as malt to cause excessive sweetness. By having characteristics different from those of ordinary hops, it can be expanded and used in combination with general hops to expand the breadth of beer manufacturing.

〔產業上可利用性〕 [Industrial Applicability]

本發明之啤酒花顆粒由於具備與一般啤酒花相異之特性,透過與一般啤酒花分開使用、及併用,可拓展啤酒製造的寬裕度,而能夠提供作為喜好品之新穎的風味。 Since the hop granules of the present invention have characteristics different from those of ordinary hops, they can be used separately from ordinary hops and used in combination, thereby expanding the breadth of beer production and providing a novel flavor as a favorite.

Claims (5)

一種啤酒花顆粒,其係使用10重量%以上的呈現CIE Lab表色系統之a*的值滿足-0.5以上、b*的值滿足25以上的色相之薩茲種的啤酒花毬果(L‧SL)作為原料而得到。 A hop granule which uses 10% by weight or more of hops (L.SL) which exhibits a color of a * of the CIE Lab color system and satisfies -0.5 or more, and a value of b * satisfies a hue of 25 or more. It is obtained as a raw material. 如請求項1之啤酒花顆粒,其中啤酒花毬果(L‧SL)之CIE Lch表色系統之h的值係滿足75°~90.5°。 The hop particle of claim 1, wherein the value of h of the CIE Lch color system of hops (L‧SL) satisfies 75° to 90.5°. 一種如請求項1或2之啤酒花顆粒的製造方法,其特徵為使用啤酒花毬果的10重量%以上,該啤酒花毬果係使用呈現CIE Lab表色系統之a*的值滿足-0.5以上、b*的值滿足25以上的色相之薩茲種的啤酒花毬果(L‧SL)作為原料。 A method of manufacturing a hop value particle requested item 1 or 2, characterized by the use of more than 10% by weight of hops cones of the hop cones lines exhibiting the CIE Lab colorimetric system satisfies a * -0.5, b * The hops (L‧SL) of the Saz species, which satisfies the hue of 25 or more, are used as raw materials. 一種啤酒風味飲料的製造方法,其特徵為使用如請求項1或2之啤酒花顆粒。 A method of producing a beer flavored beverage characterized by using the hop pellets of claim 1 or 2. 一種含有啤酒花之組成物的製造方法,其特徵為使用如請求項1或2之啤酒花顆粒。 A method of producing a composition comprising hops, characterized in that hop granules according to claim 1 or 2 are used.
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