TW201632469A - Electrolytic water generating apparatus - Google Patents

Electrolytic water generating apparatus Download PDF

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TW201632469A
TW201632469A TW105106131A TW105106131A TW201632469A TW 201632469 A TW201632469 A TW 201632469A TW 105106131 A TW105106131 A TW 105106131A TW 105106131 A TW105106131 A TW 105106131A TW 201632469 A TW201632469 A TW 201632469A
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power supply
supply body
anode
protrusion
outer casing
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TW105106131A
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TWI639562B (en
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Tachibana Takahito
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Nihon Trim Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods

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  • Chemical Kinetics & Catalysis (AREA)
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  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
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  • Water Treatment By Electricity Or Magnetism (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

In an electrolytic cell (4) of this electrolytic water generating apparatus, an electrolytic chamber is formed by fixing a first case piece (50) and a second case piece (60). A first protrusion section (53) contacting a positive electrode feeder (41) is disposed on the inner surface of the first case piece (50), and a second protrusion section (63) contacting a negative electrode feeder (42) is disposed on the inner surface of the second case piece (60). The first protrusion section (53) includes a first protrusion (56) contacting an end edge section (41e) of the positive electrode feeder (41), and the second protrusion section (63) includes a second protrusion 66 contacting an end edge section (42e) of the negative electrode feeder (42). Thus, the contact pressure between each of the end edge sections (41e, 42e) of the feeders (41, 42) and a separation membrane (43) is increased, and electrolytic current flowing through the end edge sections (41e, 42e) is increased, thereby accelerating electrolysis.

Description

電解水生成裝置Electrolyzed water generating device

本發明有關於一種透過對水進行電解而生成電解氫水的電解水生成裝置。The present invention relates to an electrolyzed water generating apparatus that generates electrolyzed hydrogen water by electrolyzing water.

一直以來,已知有如下的電解室生成裝置:其具備電解槽,電解槽具有透過隔膜分隔的陽極室和陰極室,透過對導入電解槽內的自來水等原水進行電解來生成電解氫水。Conventionally, there has been known an electrolysis chamber generating apparatus including an electrolytic cell having an anode chamber and a cathode chamber which are separated by a separator, and electrolyzed with raw water such as tap water introduced into the electrolytic cell to generate electrolytic hydrogen water.

期待溶解有生成在電解水生成裝置的陰極室中的氫氣的電解氫水在改善胃腸症狀方面發揮優異效果。另外,近年來,透過電解水生成裝置生成的電解氫水作為適於去除活性氧而受到關注。It is expected that electrolytic hydrogen water which dissolves hydrogen gas generated in the cathode chamber of the electrolyzed water generating apparatus exhibits an excellent effect in improving gastrointestinal symptoms. Further, in recent years, electrolytic hydrogen water generated by an electrolyzed water generating apparatus has been attracting attention as being suitable for removing active oxygen.

專利文獻1:日本專利第5639724號公報Patent Document 1: Japanese Patent No. 5,637,724

在電解水生成裝置中,由於為了使離子在陽極室與陰極室之間高效地通過而隔膜被形成為較薄,因此當例如產生在陽極室與陰極室之間的壓力差過大時,有可能隔膜受到損傷。因此,在上述專利文獻1的電解水生成裝置中,採用了如下的結構:透過構造電解槽的外殼片的凸狀部,夾住並支撐由陽極供電體、隔膜和陰極供電體構造的層壓體。In the electrolyzed water generating device, since the separator is formed to be thin in order to efficiently pass ions between the anode chamber and the cathode chamber, when, for example, a pressure difference between the anode chamber and the cathode chamber is excessively large, it is possible The diaphragm is damaged. Therefore, in the electrolyzed water generating apparatus of Patent Document 1, a configuration is adopted in which the convex portion of the outer shell piece of the electrolytic cell is sandwiched and supported to sandwich and support the structure of the anode power supply body, the separator, and the cathode power supply body. body.

在上述電解水生成裝置中,對層壓體被凸狀部按壓的部位來說,在各供電體與隔膜之間能夠得到足夠的接觸壓力,因此兩者間的接觸電阻降低,能夠充分確保供給到各供電體中的電解電流。In the above-mentioned electrolyzed water generating apparatus, since a sufficient contact pressure can be obtained between the respective power feeding bodies and the diaphragm in the portion where the laminated body is pressed by the convex portion, the contact resistance between the two can be reduced, and the supply can be sufficiently ensured. Electrolytic current to each power supply.

但是,如該文獻中的圖4所示,陽極供電體和陰極供電體的邊緣部並未被外殼片支撐而成為自由端。因此,難以充分確保陽極供電體和陰極供電體的邊緣部與隔膜之間的接觸壓力,兩者間的接觸電阻增大。其結果,供給到陽極供電體和陰極供電體的邊緣部的電解電流降低,有可能阻礙電解。However, as shown in Fig. 4 of this document, the edge portions of the anode power supply body and the cathode power supply body are not supported by the outer sheet piece and become free ends. Therefore, it is difficult to sufficiently ensure the contact pressure between the edge portion of the anode power supply body and the cathode power supply body and the separator, and the contact resistance between the two increases. As a result, the electrolysis current supplied to the edge portions of the anode power supply body and the cathode power supply body is lowered, which may hinder electrolysis.

本發明是鑒於上述實際情況而提出的,其主要目的在於提供一種電解水生成裝置,該裝置透過促進陽極供電體和陰極供電體的邊緣部的電解,從而能夠容易提高氫溶解濃度。The present invention has been made in view of the above circumstances, and a main object thereof is to provide an electrolyzed water generating apparatus which can easily increase the hydrogen dissolution concentration by promoting electrolysis of the edge portions of the anode power supply body and the cathode power supply body.

本發明的電解水生成裝置,具備:電解槽,形成有用於供給所電解的水的電解室;陽極供電體和陰極供電體,被彼此相對配置在電解室內;和隔膜,被配設在陽極供電體與陰極供電體之間,並且將電解室劃分為陽極供電體側的陽極室和陰極供電體側的陰極室,電解水生成裝置的隔膜被陽極供電體和陰極供電體夾持,電解槽透過固定接合陽極供電體側的第一外殼片和陰極供電體側的第二外殼片而形成電解室,在第一外殼片的朝向電解室側的內表面上配設有與陽極供電體抵接的第一凸部,在第二外殼片的朝向電解室側的內表面上配設有與陰極供電體抵接的第二凸部,第一凸部包括與陽極供電體的邊緣部抵接的第一突起,第二凸部包括與陰極供電體的邊緣部抵接的第二突起。An electrolyzed water generating apparatus according to the present invention includes an electrolytic cell in which an electrolysis chamber for supplying electrolyzed water is formed, an anode power supply body and a cathode power supply body are disposed to face each other in the electrolysis chamber, and a separator is disposed on the anode. Between the body and the cathode power supply body, and dividing the electrolysis chamber into an anode chamber on the anode power supply side and a cathode chamber on the cathode power supply side, the diaphragm of the electrolysis water generating device is sandwiched by the anode power supply body and the cathode power supply body, and the electrolytic cell is permeated The first outer casing piece on the anode power supply body side and the second outer casing piece on the cathode power supply body side are fixedly coupled to form an electrolysis chamber, and an inner surface of the first outer casing piece facing the electrolysis chamber side is disposed to abut against the anode power supply body. The first convex portion is provided with a second convex portion that abuts against the cathode power supply body on the inner surface of the second outer shell sheet facing the electrolytic chamber side, and the first convex portion includes a portion that abuts against the edge portion of the anode power supply body A protrusion, the second protrusion includes a second protrusion that abuts against an edge portion of the cathode power supply body.

較佳地,在電解水生成裝置中,沿陽極供電體的邊緣部設置有複數個第一突起,沿陰極供電體的邊緣部設置有複數個第二突起。Preferably, in the electrolyzed water generating apparatus, a plurality of first protrusions are provided along an edge portion of the anode power supply body, and a plurality of second protrusions are provided along an edge portion of the cathode power supply body.

較佳地,在電解水生成裝置中,第二突起被配設在相鄰的第一突起之間。Preferably, in the electrolyzed water generating device, the second protrusion is disposed between the adjacent first protrusions.

較佳地,在電解水生成裝置中,第一突起和第二突起包括有在順著電解室內的水的流動的縱向上長的縱長突起,縱長突起與陽極供電體或陰極供電體的垂直於縱向的橫向的橫邊緣部抵接。Preferably, in the electrolyzed water generating device, the first protrusion and the second protrusion include longitudinally elongated longitudinal projections along the flow of water along the electrolysis chamber, and the longitudinal projections are connected to the anode power supply body or the cathode power supply body. The lateral transverse edge portions perpendicular to the longitudinal direction abut.

較佳地,在電解水生成裝置中,第一突起和第二突起包括有在垂直於縱向的橫向上長的橫長突起,橫長突起與陽極供電體或陰極供電體的縱向的縱邊緣部抵接。Preferably, in the electrolyzed water generating device, the first protrusion and the second protrusion include a horizontally long protrusion that is long in a lateral direction perpendicular to the longitudinal direction, and a longitudinally long longitudinal portion of the horizontally long protrusion and the anode power supply body or the cathode power supply body Abut.

較佳地,在電解水生成裝置中,第一凸部的頂部包括有在第一外殼片側具有中心的曲面,第二凸部的頂部包括有在第二外殼片側具有中心的曲面。Preferably, in the electrolyzed water generating device, the top of the first convex portion includes a curved surface having a center on the side of the first outer shell sheet, and the top portion of the second convex portion includes a curved surface having a center on the side of the second outer shell sheet.

較佳地,在電解水生成裝置中,對於第一外殼片的朝向電解室側的內表面而言,在隔著隔膜、陽極供電體和陰極供電體與第二凸部相對的位置上,配設有高度小於第一凸部的第一小突起,對於第二外殼片的朝向電解室側的內表面而言,在隔著隔膜、陽極供電體和陰極供電體與第一凸部相對的位置上,配設有高度小於第二凸部的複數個第二小突起。Preferably, in the electrolyzed water generating device, the inner surface of the first outer shell sheet facing the electrolysis chamber side is disposed at a position opposed to the second convex portion via the separator, the anode power supply body, and the cathode power supply body. Providing a first small protrusion having a height smaller than the first convex portion, and an inner surface facing the electrolysis chamber side of the second outer shell sheet at a position opposite to the first convex portion via the diaphragm, the anode power supply body, and the cathode power supply body Upper, a plurality of second small protrusions having a height smaller than the second convex portion are disposed.

較佳地,在電解水生成裝置中,第一小突起與陽極供電體不抵接,第二小突起與陰極供電體不抵接。Preferably, in the electrolyzed water generating device, the first small protrusion does not abut the anode power supply body, and the second small protrusion does not abut the cathode power supply body.

關於本發明的電解水生成裝置,在第一外殼片的朝向電解室側的內表面上配設有與陽極供電體抵接的複數個第一凸部,第一凸部包括與陽極供電體的邊緣部抵接的第一突起。由此,陽極供電體的邊緣部被第一凸部向隔膜側按壓,從而陽極供電體的邊緣部與隔膜之間的接觸壓力提高。另一方面,在第二外殼片的朝向電解室側的內表面上配設有與陰極供電體抵接的複數個第二凸部,第二凸部包括與陰極供電體的邊緣部抵接的第二突起。由此,陰極供電體的邊緣部被第二凸部向隔膜側按壓,從而陰極供電體的邊緣部與隔膜之間的接觸壓力提高。因此,流過陽極供電體和陰極供電體的邊緣部的電解電流增大,能夠促進各邊緣部的電解。因此,能夠容易提高生成在陰極室中的電解氫水的氫溶解濃度。In the electrolyzed water generating apparatus of the present invention, a plurality of first convex portions abutting on the anode power feeding body are disposed on an inner surface of the first outer shell sheet facing the electrolysis chamber side, and the first convex portion includes an anode power supply body The first protrusion abutting the edge portion. Thereby, the edge portion of the anode power supply body is pressed toward the diaphragm side by the first convex portion, and the contact pressure between the edge portion of the anode power supply body and the diaphragm is improved. On the other hand, on the inner surface of the second outer casing sheet facing the electrolysis chamber side, a plurality of second convex portions abutting on the cathode power supply body are disposed, and the second convex portion includes abutting against the edge portion of the cathode power supply body. Second protrusion. Thereby, the edge portion of the cathode power supply body is pressed toward the diaphragm side by the second convex portion, and the contact pressure between the edge portion of the cathode power supply body and the diaphragm is improved. Therefore, the electrolysis current flowing through the edge portions of the anode power supply body and the cathode power supply body is increased, and electrolysis of each edge portion can be promoted. Therefore, the hydrogen dissolution concentration of the electrolytic hydrogen water generated in the cathode chamber can be easily increased.

下面,基於圖式對本發明的一實施方式進行說明。Hereinafter, an embodiment of the present invention will be described based on the drawings.

第1圖示出本實施方式的電解水生成裝置1的大致結構。電解水生成裝置1可用於家庭飲用和烹飪用水的生成以及血液透析用透析液的生成。Fig. 1 shows a schematic configuration of an electrolyzed water generating apparatus 1 of the present embodiment. The electrolyzed water generating apparatus 1 can be used for the generation of household drinking and cooking water and the generation of dialysate for hemodialysis.

電解水生成裝置1具備:電解槽4,形成有用於供給所電解的水的電解室40;陽極供電體41和陰極供電體42,被彼此相對配置在電解室40內;和隔膜43,被配設在陽極供電體41與陰極供電體42之間。在電解槽4的上游側或下游側也可以設置有其它電解槽。另外,還可以與電解槽4並列地設置有其它電解槽。對於另行設置的電解槽,也可適用與電解槽4相同的結構。The electrolyzed water generating apparatus 1 includes an electrolytic cell 4 in which an electrolysis chamber 40 for supplying electrolyzed water is formed, an anode electric power supply body 41 and a cathode electric power supply body 42 which are disposed to face each other in the electrolysis chamber 40, and a separator 43 which is equipped It is provided between the anode power supply body 41 and the cathode power supply body 42. Other electrolytic cells may be provided on the upstream side or the downstream side of the electrolytic cell 4. Further, other electrolytic cells may be provided in parallel with the electrolytic cell 4. The same structure as that of the electrolytic cell 4 can be applied to the electrolytic cell separately provided.

隔膜43將電解室40劃分為陽極供電體41側的陽極室40A和陰極供電體42側的陰極室40B。透過向電解室40的陽極室40A和陰極室40B這兩個室供給水,並對陽極供電體41和陰極供電體42施加直流電壓,從而在電解室40內發生水的電解。The separator 43 divides the electrolysis chamber 40 into an anode chamber 40A on the anode power supply body 41 side and a cathode chamber 40B on the cathode power supply body 42 side. Water is supplied to the two chambers of the anode chamber 40A and the cathode chamber 40B of the electrolysis chamber 40, and a DC voltage is applied to the anode power supply body 41 and the cathode power supply body 42, whereby electrolysis of water occurs in the electrolysis chamber 40.

隔膜43使透過電解產生的離子通過,並且陽極供電體41和陰極供電體42經由隔膜43電連接。隔膜43使用例如由具有磺酸基的氟系樹脂材料構成的固體高分子材料。The separator 43 passes ions generated by the electrolysis, and the anode power supply body 41 and the cathode power supply body 42 are electrically connected via the separator 43. As the separator 43, for example, a solid polymer material composed of a fluorine-based resin material having a sulfonic acid group is used.

在具有使用了固體高分子材料的隔膜43的電解槽4中,生成中性的電解氫水和電解氧水。透過水在電解室40內進行電解,從而在陰極室40B中獲得溶解有氫氣的電解氫水,在陽極室40A中獲得溶解有氧氣的電解氧水。Neutral electrolytic hydrogen water and electrolytic oxygen water are produced in the electrolytic cell 4 having the separator 43 using a solid polymer material. Electrolysis is performed in the electrolysis chamber 40 through the water, whereby electrolytic hydrogen water in which hydrogen gas is dissolved is obtained in the cathode chamber 40B, and electrolytic oxygen water in which oxygen is dissolved is obtained in the anode chamber 40A.

電解水生成裝置1進一步具備:控制單元6,用於控制電解槽4;進水部7,設置於電解槽4的上游側;和出水部8,設置於電解槽4的下游側。The electrolyzed water generating apparatus 1 further includes a control unit 6 for controlling the electrolytic cell 4, a water inlet portion 7 provided on the upstream side of the electrolytic cell 4, and a water discharge portion 8 provided on the downstream side of the electrolytic cell 4.

控制單元6例如具有CPU(Central Processing Unit:中央處理器)和記憶體等,其中,該CPU執行各種運算處理和資訊處理等,該記憶體存儲用於負責CPU操作的程式和各種資訊。The control unit 6 has, for example, a CPU (Central Processing Unit) that performs various arithmetic processing, information processing, and the like, and a memory or the like that stores programs and various information for the CPU operation.

在陽極供電體41與控制單元6之間的電流供給線路上設置有電流檢測單元44。電流檢測單元44也可以設置在陰極供電體42與控制單元6之間的電流供給線路上。電流檢測單元44檢測出供給到供電體41、42中的電解電流,並將相當於該值的信號輸出到控制單元6中。A current detecting unit 44 is provided on the current supply line between the anode power supply body 41 and the control unit 6. The current detecting unit 44 may also be disposed on the current supply line between the cathode power supply body 42 and the control unit 6. The current detecting unit 44 detects the electrolysis current supplied to the power supply bodies 41, 42 and outputs a signal corresponding to the value to the control unit 6.

控制單元6基於從電流檢測單元44輸入的信號,對施加到陽極供電體41與陰極供電體42之間的電壓進行回饋控制。例如,在電解電流過大的情況下,控制單元6使上述電壓減少,在電解電流過小的情況下,控制單元6使上述電壓增加。由此,能夠適當控制供給到供電體41、42中的電解電流。The control unit 6 performs feedback control of the voltage applied between the anode power supply body 41 and the cathode power supply body 42 based on the signal input from the current detecting unit 44. For example, when the electrolysis current is excessively large, the control unit 6 reduces the voltage, and when the electrolysis current is too small, the control unit 6 increases the voltage. Thereby, the electrolysis current supplied to the power supply bodies 41 and 42 can be appropriately controlled.

進水部7具有供水管71、流量感測器72、分支部73和流量調整閥74等。供水管71將供給到電解水生成裝置1中的水引導到電解室40中。流量感測器72設置于供水管71上。流量感測器72定期檢測供給到電解室40中的水的每單位時間的流量(以下,有時僅記載為“流量”)F,並將相當於該值的信號輸出到控制單元6中。The water inlet portion 7 has a water supply pipe 71, a flow rate sensor 72, a branch portion 73, a flow rate adjusting valve 74, and the like. The water supply pipe 71 guides the water supplied to the electrolyzed water generating device 1 into the electrolysis chamber 40. The flow sensor 72 is disposed on the water supply pipe 71. The flow rate sensor 72 periodically detects the flow rate per unit time (hereinafter, simply referred to as "flow rate") F of the water supplied to the electrolysis chamber 40, and outputs a signal corresponding to the value to the control unit 6.

分支部73將供水管71分支為供水管71a、71b這兩管。流量調整閥74將供水管71a、71b與陽極室40A或陰極室40B連接。在控制單元6的管理下,透過流量調整閥74對供給到陽極室40A和陰極室40B中的水的流量進行調整。為了提高水的利用效率,流量調整閥74對供給到陽極室40A和陰極室40B中的水的流量進行調整。由此,有時在陽極室40A與陰極室40B之間產生壓力差。The branch portion 73 branches the water supply pipe 71 into two pipes of the water supply pipes 71a and 71b. The flow rate adjustment valve 74 connects the water supply pipes 71a, 71b to the anode chamber 40A or the cathode chamber 40B. Under the management of the control unit 6, the flow rate of the water supplied to the anode chamber 40A and the cathode chamber 40B is adjusted by the flow rate adjusting valve 74. In order to improve the water use efficiency, the flow rate adjustment valve 74 adjusts the flow rate of the water supplied to the anode chamber 40A and the cathode chamber 40B. As a result, a pressure difference sometimes occurs between the anode chamber 40A and the cathode chamber 40B.

在本實施方式中,由於流量感測器72設置於分支部73的上游側,因此檢測出供給到陽極室40A中的水的流量和供給到陰極室40B中的水的流量的總和、即供給到電解室40中的水的流量F。In the present embodiment, since the flow rate sensor 72 is provided on the upstream side of the branch portion 73, the sum of the flow rate of the water supplied to the anode chamber 40A and the flow rate of the water supplied to the cathode chamber 40B, that is, the supply is detected. The flow rate F of water into the electrolysis chamber 40.

出水部8具有流路切換閥81、吐水管82和排水管83等。流路切換閥81將陽極室40A和陰極室40B與吐水管82或排水管83選擇性地連接。在電解水生成裝置1用於生成血液透析用透析液的情況下,生成在陰極室40B中的電解氫水經由吐水管82被供給到過濾處理用的反滲透膜模組和用於稀釋透析原液的稀釋裝置等中。The water discharge unit 8 has a flow path switching valve 81, a spout pipe 82, a drain pipe 83, and the like. The flow path switching valve 81 selectively connects the anode chamber 40A and the cathode chamber 40B with the spout pipe 82 or the drain pipe 83. When the electrolyzed water generating apparatus 1 is used to generate a dialysate for hemodialysis, the electrolyzed hydrogen water generated in the cathode chamber 40B is supplied to the reverse osmosis membrane module for filtration treatment via the spout pipe 82 and used to dilute the dialysis stock solution. Diluting device, etc.

控制單元6控制施加到陽極供電體41和陰極供電體42中的直流電壓的極性。例如,控制單元6基於從流量感測器72輸入的信號,對供給到電解室40中的水的流量F進行累計,若達到規定的流量,則切換施加到陽極供電體41和陰極供電體42的直流電壓的極性。伴隨此,陽極室40A和陰極室40B被相互交換。當切換直流電壓的極性時,控制單元6使流量調整閥74和流路切換閥81同步操作。由此,總是連接陰極室40B和吐水管82,從而生成在陰極室40B中的電解氫水從吐水管82排出。The control unit 6 controls the polarity of the direct current voltage applied to the anode power supply body 41 and the cathode power supply body 42. For example, the control unit 6 accumulates the flow rate F of the water supplied to the electrolysis chamber 40 based on the signal input from the flow rate sensor 72, and switches to the anode power supply body 41 and the cathode power supply body 42 if the predetermined flow rate is reached. The polarity of the DC voltage. Along with this, the anode chamber 40A and the cathode chamber 40B are exchanged with each other. When the polarity of the DC voltage is switched, the control unit 6 causes the flow regulating valve 74 and the flow path switching valve 81 to operate in synchronization. Thereby, the cathode chamber 40B and the spout pipe 82 are always connected, and the electrolyzed hydrogen water generated in the cathode chamber 40B is discharged from the spout pipe 82.

第2圖是電解槽4的裝配立體圖。電解槽4具有陽極供電體41側的第一外殼片50和陰極供電體42側的第二外殼片60。透過固定接合彼此相對配置的第一外殼片50和第二外殼片60,從而在其內部形成電解室40(參照第1圖)。Fig. 2 is an assembled perspective view of the electrolytic cell 4. The electrolytic cell 4 has a first outer casing piece 50 on the anode power supply body 41 side and a second outer casing piece 60 on the cathode power supply body 42 side. The first outer casing piece 50 and the second outer casing piece 60 which are disposed to face each other are fixedly joined to each other to form an electrolytic chamber 40 therein (refer to Fig. 1).

在電解槽4的電解室40內收容有透過疊放陽極供電體41、隔膜43和陰極供電體42而成的層壓體45。陽極供電體41、隔膜43和陰極供電體42分別被形成為矩形狀。A laminate 45 in which the anode power supply body 41, the separator 43, and the cathode power supply body 42 are stacked is housed in the electrolytic chamber 40 of the electrolytic cell 4. The anode power supply body 41, the diaphragm 43, and the cathode power supply body 42 are each formed in a rectangular shape.

陽極供電體41和陰極供電體42分別被構造為水能夠在其板厚方向上往返。對於陽極供電體41和陰極供電體42而言,可應用例如金屬網等網狀的金屬。這種網狀的陽極供電體41和陰極供電體42夾持隔膜43的同時,能夠使水遍及到隔膜43的表面,從而促進電解室40內的電解。在本實施方式中,作為陽極供電體41和陰極供電體42,可適用在鈦制金屬網的表面上形成有鍍鉑層的供電體。鍍鉑層防止鈦的氧化。The anode power supply body 41 and the cathode power supply body 42 are each configured such that water can reciprocate in the thickness direction thereof. For the anode power supply body 41 and the cathode power supply body 42, a mesh metal such as a metal mesh can be applied. The mesh-shaped anode power supply body 41 and the cathode power supply body 42 sandwich the separator 43 and allow water to flow over the surface of the separator 43, thereby promoting electrolysis in the electrolytic chamber 40. In the present embodiment, as the anode power supply body 41 and the cathode power supply body 42, a power supply body in which a platinum plating layer is formed on the surface of a titanium metal mesh can be applied. The platinized layer prevents oxidation of titanium.

在陽極供電體41設置有貫通第一外殼片50並向電解槽4的外部突出的端子41a。同樣,在陰極供電體42也設置有貫通第二外殼片60並向電解槽4的外部突出的端子42a。經由端子41a、42a,對陽極供電體41和陰極供電體42施加直流電壓。The anode power supply body 41 is provided with a terminal 41a that penetrates the first outer casing piece 50 and protrudes to the outside of the electrolytic cell 4. Similarly, the cathode power supply body 42 is also provided with a terminal 42a that penetrates the second outer casing piece 60 and protrudes to the outside of the electrolytic cell 4. A DC voltage is applied to the anode power supply body 41 and the cathode power supply body 42 via the terminals 41a and 42a.

在本實施方式中,對隔膜43使用例如由具有磺酸基的氟系樹脂材料構成的固體高分子材料。在具有使用了固體高分子材料的隔膜43的電解槽4中,生成中性的電解水。在隔膜43的兩表面形成有由鉑構成的鍍層43a。鍍層43a與陽極供電體41和陰極供電體42抵接並電連接。In the present embodiment, a solid polymer material composed of, for example, a fluorine-based resin material having a sulfonic acid group is used for the separator 43. Neutral electrolyzed water is produced in the electrolytic cell 4 having the separator 43 using a solid polymer material. A plating layer 43a made of platinum is formed on both surfaces of the separator 43. The plating layer 43a is in contact with and electrically connected to the anode power supply body 41 and the cathode power supply body 42.

隔膜43在電解室40內被陽極供電體41和陰極供電體42夾持。因此,隔膜43的形狀透過陽極供電體41和陰極供電體42來保持。根據這種隔膜43的保持結構,起因於陽極室40A與陰極室40B之間產生的壓力差的應力的大部分由陽極供電體41和陰極供電體42來承擔,從而減少施加到隔膜43的應力。由此,即使在陽極室40A與陰極室40B之間產生較大的壓力差的狀態下操作電解水生成裝置1,也不會在隔膜43中產生較大的應力。因此,能夠抑制隔膜43的損傷,並能夠容易提高水的利用效率。The separator 43 is sandwiched between the anode power supply body 41 and the cathode power supply body 42 in the electrolytic chamber 40. Therefore, the shape of the diaphragm 43 is maintained by the anode power supply body 41 and the cathode power supply body 42. According to the holding structure of the diaphragm 43, the majority of the stress resulting from the pressure difference generated between the anode chamber 40A and the cathode chamber 40B is borne by the anode power supply body 41 and the cathode power supply body 42, thereby reducing the stress applied to the diaphragm 43. . Thereby, even if the electrolyzed water generating apparatus 1 is operated in a state where a large pressure difference is generated between the anode chamber 40A and the cathode chamber 40B, a large stress is not generated in the diaphragm 43. Therefore, damage of the diaphragm 43 can be suppressed, and water use efficiency can be easily improved.

另外,由於隔膜43被陽極供電體41和陰極供電體42夾持,因此能夠減少隔膜43的鍍層43a與陽極供電體41之間以及鍍層43a與陰極供電體42之間的接觸電阻,抑制電壓下降。由此,能夠促進電解室40內的電解,生成較高的氫溶解濃度的電解氫水。Further, since the diaphragm 43 is sandwiched between the anode power supply body 41 and the cathode power supply body 42, the contact resistance between the plating layer 43a of the separator 43 and the anode power supply body 41 and between the plating layer 43a and the cathode power supply body 42 can be reduced, and voltage drop can be suppressed. . Thereby, electrolysis in the electrolysis chamber 40 can be promoted, and electrolytic hydrogen water having a high hydrogen solubility concentration can be generated.

在陽極供電體41和陰極供電體42的外周緣外側設置有用於防止水從第一外殼片50與第二外殼片60的接合面漏出的密封部件46。隔膜43的外周部被密封部件46夾持。A seal member 46 for preventing water from leaking from the joint surface of the first outer shell piece 50 and the second outer shell piece 60 is provided outside the outer peripheral edge of the anode power supply body 41 and the cathode power supply body 42. The outer peripheral portion of the diaphragm 43 is sandwiched by the sealing member 46.

各外殼片50和60被形成為在順著電解室40內的水的流動的縱向V上長的長方形狀。伴隨此,電解室40被形成為在縱向V上長的長方形狀。由於這種縱長形狀的電解室40,電解槽4內的流路變長。其結果,產生在陰極室40B中的氫氣能夠易於溶解於陰極室40B內的水中,提高氫溶解濃度。Each of the outer shell sheets 50 and 60 is formed in a rectangular shape elongated in the longitudinal direction V along the flow of water in the electrolytic chamber 40. Along with this, the electrolysis chamber 40 is formed in a rectangular shape elongated in the longitudinal direction V. Due to such an elongated electrolytic chamber 40, the flow path in the electrolytic cell 4 becomes long. As a result, the hydrogen gas generated in the cathode chamber 40B can be easily dissolved in the water in the cathode chamber 40B to increase the hydrogen dissolution concentration.

在電解槽4設置有L字狀的接頭91、92、93、94。接頭91、92被安裝在第一外殼片50、第二外殼片60的下部,並與上述流量調整閥74連接。接頭93、94被安裝在第一外殼片50、第二外殼片60的上部,並與上述流路切換閥81連接。透過開始向電解水生成裝置1內供水,從陽極室40A和陰極室40B的下部朝向上部產生水的整體流動。L-shaped joints 91, 92, 93, and 94 are provided in the electrolytic cell 4. The joints 91, 92 are attached to the lower portions of the first outer casing piece 50 and the second outer casing piece 60, and are connected to the flow rate adjusting valve 74. The joints 93, 94 are attached to the upper portions of the first outer casing piece 50 and the second outer casing piece 60, and are connected to the flow path switching valve 81. By starting to supply water into the electrolyzed water generating apparatus 1, the entire flow of water is generated from the lower portion of the anode chamber 40A and the cathode chamber 40B toward the upper portion.

產生在陰極室40B中的氫氣成為微小的氣泡並向陰極室40B的上方移動。在本實施方式中,由於氫氣的移動方向與水的整體流動方向一致,因此氫分子易於溶解于水中,提高氫溶解濃度。The hydrogen gas generated in the cathode chamber 40B becomes minute bubbles and moves above the cathode chamber 40B. In the present embodiment, since the moving direction of the hydrogen gas coincides with the entire flow direction of the water, the hydrogen molecules are easily dissolved in the water to increase the hydrogen dissolution concentration.

第3圖是從朝向電解室40側的內表面側觀察的、第一外殼片50和第二外殼片60的立體圖。第4圖的(a)是從內表面側觀察的第一外殼片50的主視圖,第4圖的(b)是從內表面側觀察的第二外殼片60的主視圖。第5圖是包括圖4的A-A剖面和B-B剖面的電解槽4的裝配立體圖。另外,第6圖是與第5圖相同的剖面中的電解槽4的剖視圖。Fig. 3 is a perspective view of the first outer casing piece 50 and the second outer casing piece 60 as viewed from the inner surface side toward the electrolysis chamber 40 side. Fig. 4(a) is a front view of the first outer casing piece 50 as seen from the inner surface side, and Fig. 4(b) is a front view of the second outer casing piece 60 as seen from the inner surface side. Fig. 5 is an assembled perspective view of the electrolytic cell 4 including the A-A section and the B-B section of Fig. 4. In addition, Fig. 6 is a cross-sectional view of the electrolytic cell 4 in the same cross section as Fig. 5.

在第一外殼片50和第二外殼片60的內表面的外緣部形成有用於固定接合第一外殼片50和第二外殼片60的接合面51、61。在接合面51、61的內側透過內壁從接合面51、61起沿第一外殼片50和第二外殼片60的厚度方向凹陷而設置有電解部52、62。電解部52構造陽極室40A,電解部62構造陰極室40B。Engagement faces 51, 61 for fixingly joining the first outer casing piece 50 and the second outer casing piece 60 are formed at outer edge portions of the inner surfaces of the first outer casing piece 50 and the second outer casing piece 60. Electrolytic portions 52 and 62 are provided in the thickness direction of the first outer shell piece 50 and the second outer shell piece 60 from the joint faces 51 and 61 through the inner wall through the inner wall of the joint faces 51 and 61. The electrolysis portion 52 constitutes an anode chamber 40A, and the electrolysis portion 62 constitutes a cathode chamber 40B.

在第一外殼片50的內表面上配設有多個第一凸部53。在本實施方式中,第一凸部53包括離散配置在電解部52的主要部52A上的突起53P。主要部52A為位於陽極供電體41的邊緣部41e和陰極供電體42的邊緣部42e的內側的、佔據電解部52的大部分的區域(以下,關於電解部62的主要部62A也相同)。各第一凸部53沿縱向V和垂直於縱向V的橫向H以矩陣狀(matrix狀)排列並配設。關於突起的配置,所謂“矩陣狀”是指沿縱向V排列有m個突起、且沿橫向H排列有n個突起的配置(如m行×n列矩陣的配置)(m、n為2以上的整數。以下相同)。A plurality of first convex portions 53 are disposed on the inner surface of the first outer casing piece 50. In the present embodiment, the first convex portion 53 includes protrusions 53P that are discretely disposed on the main portion 52A of the electrolysis portion 52. The main portion 52A is a region that occupies most of the electrolysis portion 52 on the inner side of the edge portion 41e of the anode power supply body 41 and the edge portion 42e of the cathode power supply body 42 (hereinafter, the main portion 62A of the electrolysis portion 62 is also the same). Each of the first convex portions 53 is arranged in a matrix (matrix shape) in the longitudinal direction V and the lateral direction H perpendicular to the longitudinal direction V. The arrangement of the protrusions refers to an arrangement in which m protrusions are arranged in the vertical direction V and n protrusions are arranged in the lateral direction H (for example, an arrangement of m rows × n columns of matrix) (m, n is 2 or more) The integer is the same as the following).

另一方面,在第二外殼片60的內表面上配設有多個第二凸部63。在本實施方式中,第二凸部63包括離散配置在電解部62的主要部62A上的突起63P。各第二凸部63沿縱向V和橫向H以矩陣狀排列並配設。On the other hand, a plurality of second convex portions 63 are disposed on the inner surface of the second outer casing sheet 60. In the present embodiment, the second convex portion 63 includes protrusions 63P that are discretely disposed on the main portion 62A of the electrolysis portion 62. Each of the second convex portions 63 is arranged in a matrix in the longitudinal direction V and the lateral direction H.

各第一凸部53在陽極室40A與陽極供電體41抵接,並將陽極供電體41向第二外殼片60側按壓。另一方面,各第二凸部63在陰極室40B與陰極供電體42抵接,並將陰極供電體42向第一外殼片50側按壓。因此,層壓體45從其兩表面被各第一凸部53和各第二凸部63夾持。Each of the first convex portions 53 abuts on the anode power supply body 41 in the anode chamber 40A, and presses the anode power supply body 41 toward the second outer casing sheet 60 side. On the other hand, each of the second convex portions 63 abuts on the cathode power supply body 42 in the cathode chamber 40B, and presses the cathode power supply body 42 toward the first outer casing sheet 50 side. Therefore, the laminate 45 is sandwiched by the respective first convex portions 53 and the respective second convex portions 63 from both surfaces thereof.

第一凸部53包括與陽極供電體41的邊緣部41e(參照第2圖、第6圖)抵接的第一突起56。第一突起56設置於第一凸部53中的、離散配置在電解部52的主要部上的突起的周邊。由此,陽極供電體41的邊緣部41e被第一突起56向隔膜43側按壓,從而陽極供電體41的邊緣部41e與隔膜43之間的接觸壓力提高,並且兩者間的接觸電阻降低。The first convex portion 53 includes a first protrusion 56 that abuts against the edge portion 41e (see FIGS. 2 and 6) of the anode power feeding body 41. The first protrusions 56 are provided in the periphery of the protrusions of the first convex portion 53 that are discretely disposed on the main portion of the electrolysis portion 52. Thereby, the edge portion 41e of the anode power supply body 41 is pressed toward the diaphragm 43 by the first projection 56, whereby the contact pressure between the edge portion 41e of the anode power supply body 41 and the diaphragm 43 is increased, and the contact resistance therebetween is lowered.

另一方面,第二凸部63包括與陰極供電體42的邊緣部42e(參照第2圖、第6圖)抵接的第二突起66。第二突起66設置於第二凸部63中的、離散配置在電解部62的主要部上的突起的周邊。由此,陰極供電體42的邊緣部42e被第二突起66向隔膜43側按壓,從而陰極供電體42的邊緣部42e與隔膜43之間的接觸壓力提高,並且兩者間的接觸電阻降低。On the other hand, the second convex portion 63 includes a second protrusion 66 that abuts against the edge portion 42e (see FIGS. 2 and 6) of the cathode power supply body 42. The second protrusions 66 are provided in the periphery of the protrusions of the second convex portion 63 that are discretely disposed on the main portion of the electrolysis portion 62. Thereby, the edge portion 42e of the cathode power supply body 42 is pressed toward the diaphragm 43 by the second protrusion 66, whereby the contact pressure between the edge portion 42e of the cathode power supply body 42 and the diaphragm 43 is increased, and the contact resistance therebetween is lowered.

因此,流過陽極供電體41的邊緣部41e和陰極供電體42的邊緣部42e的電解電流增大,能夠促進在各邊緣部41e、42e的電解。因此,能夠容易提高生成在陰極室40B中的電解氫水的氫溶解濃度。Therefore, the electrolysis current flowing through the edge portion 41e of the anode power supply body 41 and the edge portion 42e of the cathode power supply body 42 is increased, and electrolysis at each of the edge portions 41e and 42e can be promoted. Therefore, the hydrogen dissolution concentration of the electrolytic hydrogen water generated in the cathode chamber 40B can be easily increased.

在本實施方式中,沿陽極供電體41的邊緣部41e設置有多個第一突起56。同樣,沿陰極供電體42的邊緣部42e設置有多個第二突起66。In the present embodiment, a plurality of first protrusions 56 are provided along the edge portion 41e of the anode power supply body 41. Also, a plurality of second protrusions 66 are provided along the edge portion 42e of the cathode power supply body 42.

如第5圖、第6圖所示,當固定接合第一外殼片50和第二外殼片60時,密封部件46被配設在第一突起56和第二突起66的外側。也可以向密封部件46的內側、即陽極供電體41的邊緣部41e和陰極供電體42的邊緣部42e供給水。As shown in FIGS. 5 and 6, when the first outer casing piece 50 and the second outer casing piece 60 are fixedly joined, the sealing member 46 is disposed outside the first projection 56 and the second projection 66. Water may be supplied to the inner side of the sealing member 46, that is, the edge portion 41e of the anode power supply body 41 and the edge portion 42e of the cathode power supply body 42.

如第3圖至第6圖所示,各第二突起66被隔開間隔地設置在相鄰的第一突起56之間。換言之,各第一突起56被隔開間隔地設置在相鄰的第二突起66之間。由此,陽極供電體41的邊緣部41e和陰極供電體42的邊緣部42e從第一外殼片50側和第二外殼片60側被第一突起56和第二突起66交替按壓並支撐。另外,產生在邊緣部42e中的氫氣易於溶解於流入到相鄰的第二突起66之間的水中,從而氫溶解濃度進一步提高。As shown in FIGS. 3 to 6, each of the second projections 66 is disposed between the adjacent first projections 56 at intervals. In other words, each of the first protrusions 56 is disposed between the adjacent second protrusions 66 at intervals. Thereby, the edge portion 41e of the anode power supply body 41 and the edge portion 42e of the cathode power supply body 42 are alternately pressed and supported by the first protrusion 56 and the second protrusion 66 from the first outer shell piece 50 side and the second outer shell piece 60 side. Further, the hydrogen gas generated in the edge portion 42e is easily dissolved in the water flowing between the adjacent second protrusions 66, so that the hydrogen dissolution concentration is further increased.

如第6圖所示,較佳地,第一突起56和第二突起66的高度被設定為能夠將陽極供電體41的邊緣部41e和陰極供電體42的邊緣部42e矯正為波形的程度。由於這種波形的陽極供電體41的邊緣部41e和陰極供電體42的邊緣部42e具有較大的彎曲剛性,因此即使因電解室40內的壓力差而層壓體45受到較大的應力,也能夠抑制其變形,並且抑制隔膜43的損傷。As shown in Fig. 6, preferably, the heights of the first protrusions 56 and the second protrusions 66 are set to the extent that the edge portion 41e of the anode power supply body 41 and the edge portion 42e of the cathode power supply body 42 can be corrected to have a waveform. Since the edge portion 41e of the anode power supply body 41 of this waveform and the edge portion 42e of the cathode power supply body 42 have a large bending rigidity, even if the laminate 45 is subjected to a large stress due to a pressure difference in the electrolytic chamber 40, It is also possible to suppress the deformation thereof and suppress the damage of the diaphragm 43.

如第3圖至第6圖所示,第一突起56包括有在順著陽極室40A內的水的流動的縱向V上長的第一縱長突起57。第一縱長突起57與陽極供電體41的橫向H上的橫邊緣部41h抵接。橫邊緣部41h被第一縱長突起57向隔膜43側按壓,從而提高與隔膜43的接觸壓力。此外,所謂陽極供電體41的橫邊緣部41h是指例如從陽極供電體41的橫向H的邊緣至內側,為陽極供電體41的橫向H長度的2%以下的區域(以下,關於陰極供電體42的橫邊緣部42h也相同)。As shown in FIGS. 3 to 6, the first projection 56 includes a first elongated projection 57 that is long in the longitudinal direction V of the flow of water in the anode chamber 40A. The first vertical projection 57 abuts against the lateral edge portion 41h of the anode power supply body 41 in the lateral direction H. The lateral edge portion 41h is pressed toward the diaphragm 43 by the first longitudinal projection 57, thereby increasing the contact pressure with the diaphragm 43. In addition, the lateral edge portion 41h of the anode power supply body 41 is, for example, from the edge to the inner side of the lateral direction H of the anode power supply body 41, and is a region of 2% or less of the length H of the anode power supply body 41 (hereinafter, regarding the cathode power supply body) The lateral edge portion 42h of 42 is also the same).

第二突起66包括有在順著陰極室40B內的水的流動的縱向V上長的第二縱長突起67。在從橫向H觀察電解槽4的側視中,各第二縱長突起67被隔開間隔地設置在相鄰的第一縱長突起57之間。第二縱長突起67與陰極供電體42的橫向H上的橫邊緣部42h抵接。橫邊緣部42h被第二縱長突起67向隔膜43側按壓,從而提高與隔膜43的接觸壓力。此外,各第二縱長突起67在縱向V上與第一縱長突起57交替設置即可,也可以設置在當固定接合第一外殼片50和第二外殼片60時,在橫向H上與相鄰的第一縱長突起57錯開的位置上。The second projection 66 includes a second elongated projection 67 that is elongated in a longitudinal direction V along the flow of water within the cathode chamber 40B. In the side view of the electrolytic cell 4 viewed from the lateral direction H, each of the second longitudinal projections 67 is provided between the adjacent first longitudinal projections 57 at intervals. The second vertical projection 67 abuts against the lateral edge portion 42h of the cathode power supply body 42 in the lateral direction H. The lateral edge portion 42h is pressed toward the diaphragm 43 by the second longitudinal projection 67, thereby increasing the contact pressure with the diaphragm 43. Further, each of the second longitudinal projections 67 may be alternately disposed in the longitudinal direction V with the first longitudinal projections 57, or may be disposed in the lateral direction H when the first outer casing sheet 50 and the second outer casing sheet 60 are fixedly joined. The adjacent first longitudinal projections 57 are staggered.

第一凸部53的頂部53a被構造為包括有在第一外殼片50側具有中心的凸曲面53b。凸曲面53b包括被形成在第6圖所示的第一縱長突起57的頂部57a上的凸曲面57b。凸曲面53b可以是如圓柱側面的一部分的二次曲面,也可以是如球表面的一部分的三次曲面。由於頂部53a被構造為凸曲面53b,層壓體45以緩慢的曲率彎曲,因此向隔膜43的應力集中緩慢,能夠抑制隔膜43的損傷。The top portion 53a of the first convex portion 53 is configured to include a convex curved surface 53b having a center on the side of the first outer casing piece 50. The convex curved surface 53b includes a convex curved surface 57b formed on the top portion 57a of the first elongated projection 57 shown in Fig. 6. The convex curved surface 53b may be a quadric surface such as a part of the side surface of the cylinder, or may be a cubic curved surface such as a part of the surface of the sphere. Since the top portion 53a is configured as the convex curved surface 53b, the laminate 45 is curved with a slow curvature, so that the stress concentration to the diaphragm 43 is slow, and damage of the diaphragm 43 can be suppressed.

第二凸部63的頂部63a被構造為包括有在第二外殼片60側具有中心的凸曲面63b。凸曲面63b包括被形成在第6圖所示的第二縱長突起67的頂部67a上的凸曲面67b。關於凸曲面63b,也與上述凸曲面53b相同。The top portion 63a of the second convex portion 63 is configured to include a convex curved surface 63b having a center on the side of the second outer casing sheet 60. The convex curved surface 63b includes a convex curved surface 67b formed on the top portion 67a of the second longitudinal projection 67 shown in Fig. 6. The convex curved surface 63b is also the same as the above-described convex curved surface 53b.

在本實施方式中,當固定接合第一外殼片50和第二外殼片60時,第二凸部63被配置在以沿縱向V最近的距離相鄰的第一凸部53、53之間。伴隨此,第二凸部63被設置為與第一凸部53相比少一行。另外,第二凸部63被配置在以沿橫向H最近的距離相鄰的第一凸部53、53之間。In the present embodiment, when the first outer casing piece 50 and the second outer casing piece 60 are fixedly joined, the second convex portion 63 is disposed between the first convex portions 53, 53 adjacent to each other in the longitudinal direction V. Along with this, the second convex portion 63 is disposed to be one row smaller than the first convex portion 53. In addition, the second convex portion 63 is disposed between the first convex portions 53, 53 adjacent to each other in the lateral direction H.

透過相對配置這種各第一凸部53和各第二凸部63,在陰極室40B內各第二凸部63沿縱向V和橫向H離散且均等地分佈。由此,在陰極室40B內沿縱向V和橫向H分佈的第二凸部63之間流入流速較大的水,從而向陰極供電體42的表面供給足夠的水。因此,即使在例如透過加大供給到各供電體41、42中的電解電流,以在陰極供電體42的表面上產生大量的氫氣的情況下,也能夠抑制電解氫水的氫溶解濃度局部地接近飽和值,從而提高陰極室40B整體的氫溶解濃度。另外,即使在例如供給到陰極室40B中的水的流量較少的情況下,也能夠抑制電解氫水的氫溶解濃度局部地接近飽和值,從而提高陰極室40B整體的氫溶解濃度。The second convex portions 63 are discretely and uniformly distributed in the longitudinal direction V and the lateral direction H in the cathode chamber 40B by the relative arrangement of the first convex portions 53 and the second convex portions 63. Thereby, water having a large flow velocity flows between the second convex portions 63 distributed in the longitudinal direction V and the lateral direction H in the cathode chamber 40B, thereby supplying sufficient water to the surface of the cathode power supply body 42. Therefore, even if a large amount of hydrogen gas is generated on the surface of the cathode power supply body 42 by, for example, increasing the electrolysis current supplied to each of the power supply bodies 41 and 42, the hydrogen dissolution concentration of the electrolytic hydrogen water can be suppressed locally. The saturation value is approached, thereby increasing the hydrogen dissolution concentration of the cathode chamber 40B as a whole. Further, even when, for example, the flow rate of the water supplied to the cathode chamber 40B is small, it is possible to suppress the hydrogen dissolution concentration of the electrolytic hydrogen water from locally approaching the saturation value, thereby increasing the hydrogen dissolution concentration of the entire cathode chamber 40B.

另一方面,在陽極室40A內,各第一凸部53沿縱向V和橫向H離散且均等地分佈,在陽極室40A內沿縱向V和橫向H分佈的第一凸部53之間也流入流速較大的水,從而向陽極供電體41的表面供給足夠的水。因此,與上述的陰極室40B相同,陽極室40A整體的氫溶解濃度提高。由此,能夠使在陽極室40A中產生的氧氣容易溶解於陽極室40A內的水中並被排出。On the other hand, in the anode chamber 40A, each of the first convex portions 53 is discretely and equally distributed in the longitudinal direction V and the lateral direction H, and flows between the first convex portions 53 distributed in the longitudinal direction V and the lateral direction H in the anode chamber 40A. The water having a large flow rate supplies sufficient water to the surface of the anode power supply body 41. Therefore, similarly to the above-described cathode chamber 40B, the hydrogen dissolution concentration of the entire anode chamber 40A is improved. Thereby, the oxygen generated in the anode chamber 40A can be easily dissolved in the water in the anode chamber 40A and discharged.

第一凸部53和第二凸部63被形成為在縱向V上長的縱長形狀。利用這種縱長形狀的第一凸部53和第二凸部63,對陽極室40A和陰極室40B內的水進行整流,從而不會妨礙縱向V的整體水流,能夠以較寬的面積堅固地支撐層壓體45。因此,能夠降低各供電體41、42與隔膜43的鍍層43a之間的接觸電阻,能夠對電解室40內的水進行高效電解。在本實施方式中,作為縱長形狀的第一凸部53採用橢圓柱狀的突起,但也可以是長圓柱狀或長方體狀的突起。The first convex portion 53 and the second convex portion 63 are formed into a vertically long shape that is long in the longitudinal direction V. By using the first convex portion 53 and the second convex portion 63 of such an elongated shape, the water in the anode chamber 40A and the cathode chamber 40B is rectified so as not to hinder the entire water flow in the longitudinal direction V, and can be sturdy in a wide area. The laminate 45 is supported. Therefore, the contact resistance between the respective power supply bodies 41 and 42 and the plating layer 43a of the separator 43 can be reduced, and the water in the electrolytic chamber 40 can be efficiently electrolyzed. In the present embodiment, the first convex portion 53 having a vertically long shape is an elliptical columnar protrusion, but may be a long columnar or rectangular parallelepiped protrusion.

各第一凸部53在頂部53a與陽極供電體41抵接。頂部53a例如以與接合面51相同的高度突出。由此,陽極供電體41在與頂部53a抵接的部位向第二外殼片60側被按壓而突出。另一方面,各第二凸部63在頂部63a與陰極供電體42抵接。由此,陰極供電體42在與頂部63a抵接的部位向第一外殼片50側被按壓而突出。Each of the first convex portions 53 abuts on the anode power supply body 41 at the top portion 53a. The top portion 53a protrudes, for example, at the same height as the joint surface 51. Thereby, the anode power feeding body 41 is pressed toward the second outer casing piece 60 side at a portion abutting on the top portion 53a to protrude. On the other hand, each of the second convex portions 63 abuts on the cathode power supply body 42 at the top portion 63a. Thereby, the cathode power supply body 42 is pressed toward the first outer casing piece 50 side at a portion abutting on the top portion 63a to protrude.

在本發明中,由於在沿縱向V相鄰的第一凸部53、53之間配置有第二凸部63,因此層壓體45在沿縱向V的剖面上被矯正為波形。另一方面,由於在以沿橫向H最近的距離相鄰的第一凸部53、53之間配置有第二凸部63,因此層壓體45在沿橫向H的剖面上也被矯正為波形。由於這種波形的層壓體45具有較大的彎曲剛性,因此即使因電解室40內的壓力差而層壓體45受到較大的應力,也能夠抑制其變形,並且抑制隔膜43的損傷。In the present invention, since the second convex portion 63 is disposed between the first convex portions 53, 53 adjacent in the longitudinal direction V, the laminated body 45 is corrected to have a waveform in a cross section in the longitudinal direction V. On the other hand, since the second convex portion 63 is disposed between the first convex portions 53, 53 adjacent to each other in the lateral direction H, the laminated body 45 is also corrected to a waveform in the cross section along the lateral direction H. . Since the laminate 45 of such a waveform has a large bending rigidity, even if the laminate 45 is subjected to a large stress due to a pressure difference in the electrolytic chamber 40, deformation thereof can be suppressed, and damage of the separator 43 can be suppressed.

如第3圖、第4圖所示,較佳地,對於第一外殼片50的朝向電解室40側的內表面而言,在隔著層壓體45(參照第2圖)與第二外殼片60的第二凸部63(突起63P)相對的位置上,配設有多個第一小突起54。各第一小突起54堵住在沿橫向H相鄰的第一凸部53、53之間沿縱向V流動的水的一部分,並將其引導到第一小突起54的橫向H的兩端、即沿縱向V相鄰的第一凸部53、53之間。由此,陽極室40A內的水在第一小突起54的周邊被局部攪拌。因此,透過融合由第一凸部53引起的縱向V的整體水流和由第一小突起54引起的局部水流,從而供給到陽極供電體41的表面上的水的流動進一步均勻化,能夠提高氫溶解濃度。As shown in FIGS. 3 and 4, it is preferable that the inner surface of the first outer shell piece 50 facing the electrolysis chamber 40 side is interposed between the laminate 45 (see FIG. 2) and the second outer casing. A plurality of first small projections 54 are disposed at positions opposite to the second convex portions 63 (protrusions 63P) of the sheet 60. Each of the first small projections 54 blocks a portion of the water flowing in the longitudinal direction V between the first convex portions 53, 53 adjacent in the lateral direction H, and guides it to both ends of the lateral direction H of the first small projections 54, That is, between the first convex portions 53, 53 adjacent in the longitudinal direction V. Thereby, the water in the anode chamber 40A is partially stirred at the periphery of the first small protrusion 54. Therefore, by fusing the entire water flow in the longitudinal direction V caused by the first convex portion 53 and the local water flow caused by the first small projections 54, the flow of water supplied to the surface of the anode power supply body 41 is further uniformized, and hydrogen can be improved. Dissolved concentration.

較佳第一小突起54被形成為在橫向H上長的橫長形狀。這種第一小突起54將水引導到沿縱向V相鄰的第一凸部53、53之間的效果較高,並且供給到陽極供電體41的表面上的水的流動被進一步均勻化,從而能夠提高氫溶解濃度。在本實施方式中,作為橫長形狀的第一凸部53採用橢圓柱狀的突起,但也可以為長圓柱狀或長方體狀的突起。Preferably, the first small protrusions 54 are formed into a horizontally long shape that is long in the lateral direction H. Such a first small protrusion 54 has a higher effect of guiding water between the first convex portions 53, 53 adjacent in the longitudinal direction V, and the flow of water supplied to the surface of the anode power supply body 41 is further uniformed, Thereby, the hydrogen dissolution concentration can be increased. In the present embodiment, the first convex portion 53 having a horizontally long shape is an elliptical columnar projection, but may be a long cylindrical shape or a rectangular parallelepiped projection.

由於第一小突起54的高度小於第一凸部53,因此與陽極供電體41不抵接。因此,在第一小突起54與陽極供電體41之間形成流路,供給到陽極供電體41的表面上的水的流動進一步均勻化。Since the height of the first small protrusions 54 is smaller than that of the first convex portions 53, it does not abut against the anode power supply body 41. Therefore, a flow path is formed between the first small protrusions 54 and the anode power supply body 41, and the flow of water supplied to the surface of the anode power supply body 41 is further uniformized.

另一方面,較佳地,對於第二外殼片60的朝向電解室40側的內表面而言,在隔著層壓體45(參照第2圖)與第一外殼片50的第一凸部53(突起53P)相對的位置上,配設有多個第二小突起64。由於第二小突起64的形狀和作用效果與上述第一小突起54相同,因此省略其說明。On the other hand, preferably, the inner surface of the second outer shell piece 60 facing the electrolysis chamber 40 side is separated from the first convex portion of the first outer shell piece 50 via the laminate 45 (refer to FIG. 2). A plurality of second small protrusions 64 are disposed at positions opposite to each other at 53 (protrusions 53P). Since the shape and function of the second small projection 64 are the same as those of the first small projection 54, the description thereof will be omitted.

在本發明中,由於設置在第二突起66附近的第二小突起64朝向陰極供電體42的橫邊緣部42h引導陰極室40B內的水,因此也能夠向陰極供電體42的橫邊緣部42h的表面充分供給水。因此,透過由上述的第一突起56和第二突起66引起的邊緣部42e的電解促進作用而產生的氫氣易於溶解于水中,從而容易提高氫溶解濃度。In the present invention, since the second small projection 64 provided in the vicinity of the second projection 66 guides the water in the cathode chamber 40B toward the lateral edge portion 42h of the cathode power supply body 42, it is also possible to the lateral edge portion 42h of the cathode power supply body 42. The surface is fully supplied with water. Therefore, hydrogen gas generated by the electrolysis promoting action of the edge portion 42e by the first protrusions 56 and the second protrusions 66 described above is easily dissolved in water, and the hydrogen dissolution concentration is easily increased.

如第3圖和第6圖所示,較佳在第一小突起54形成有沿縱向V貫通第一小突起54的槽55。可適當設定相對於一個第一小突起54的槽55的條數、寬度和深度。例如,在本實施方式中,一條槽55被設置在第一小突起54的橫向H的中央部。另外,槽55的深度與第一小突起54的高度相同。槽55沿縱向V引導在沿橫向H相鄰的第一凸部53、53之間流動的水的一部分,並使其通過第一小突起54。透過槽55,供給到陽極供電體41的表面上的水的流動進一步均勻化。As shown in FIGS. 3 and 6, it is preferable that the first small projections 54 are formed with grooves 55 penetrating the first small projections 54 in the longitudinal direction V. The number, width and depth of the grooves 55 with respect to one first small projection 54 can be appropriately set. For example, in the present embodiment, one groove 55 is provided at the central portion of the lateral direction H of the first small protrusion 54. In addition, the depth of the groove 55 is the same as the height of the first small protrusion 54. The groove 55 guides a portion of the water flowing between the first convex portions 53, 53 adjacent in the lateral direction H in the longitudinal direction V and passes it through the first small protrusions 54. Through the groove 55, the flow of water supplied to the surface of the anode power supply body 41 is further uniformized.

同樣,較佳在第二小突起64形成有沿縱向V貫通第二小突起64的槽65。關於槽65的條數等,與上述槽55相同。槽65沿縱向V引導在沿橫向H相鄰的第二凸部63、63之間流動的水的一部分,並使其通過第二小突起64。透過槽65,供給到陰極供電體42的表面上的水的流動進一步均勻化。Also, it is preferable that the second small projection 64 is formed with a groove 65 penetrating the second small projection 64 in the longitudinal direction V. The number of the grooves 65 and the like are the same as those of the above-described grooves 55. The groove 65 guides a portion of the water flowing between the second convex portions 63, 63 adjacent in the lateral direction H in the longitudinal direction V and passes it through the second small protrusions 64. The flow of water supplied to the surface of the cathode power supply body 42 is further uniformized by the grooves 65.

此外,也有可能因上述第一小突起54和第二小突起64而阻礙陽極室40A內和陰極室40B內的水的流動。然而,在本實施方式中,第一小突起54的高度小於第一凸部53的高度,並且第一小突起54與陽極供電體41不抵接。因此,在第一小突起54與陽極供電體41之間形成流路,因第一小突起54而阻礙陽極室40A內的水的流動的可能性是有限的。同樣,因第二小突起64而阻礙陰極室40B內的水的流動的可能性是有限的。Further, there is a possibility that the flow of water in the anode chamber 40A and the cathode chamber 40B is hindered by the first small projections 54 and the second small projections 64 described above. However, in the present embodiment, the height of the first small protrusions 54 is smaller than the height of the first convex portions 53, and the first small protrusions 54 are not in contact with the anode power supply body 41. Therefore, a flow path is formed between the first small protrusions 54 and the anode power supply body 41, and the possibility that the first small protrusions 54 block the flow of water in the anode chamber 40A is limited. Also, the possibility of obstructing the flow of water in the cathode chamber 40B due to the second small protrusions 64 is limited.

如第3圖和第4圖所示,在第一外殼片50的內表面的下部形成有第一分水路58D。第一分水路58D沿第一外殼片50的橫向H延伸,並與電解部52連通。從接頭91流入的水經由第一分水路58D流入到電解部52,並向上方流過第一凸部53等的間隙。同樣,在第二外殼片60的內表面的下部形成有第二分水路68D。第二分水路68D沿第二外殼片60的橫向H延伸,並與電解部62連通。從接頭92流入的水經由第二分水路68D流入到電解部62,並向上方流過第二凸部63等的間隙。As shown in FIGS. 3 and 4, a first water dividing path 58D is formed at a lower portion of the inner surface of the first outer casing piece 50. The first water dividing passage 58D extends in the lateral direction H of the first outer casing piece 50 and communicates with the electrolysis portion 52. The water that has flowed in from the joint 91 flows into the electrolysis unit 52 through the first water dividing passage 58D, and flows upward through the gap of the first convex portion 53 or the like. Similarly, a second water dividing path 68D is formed at a lower portion of the inner surface of the second outer casing piece 60. The second water dividing passage 68D extends in the lateral direction H of the second outer casing piece 60 and communicates with the electrolysis portion 62. The water that has flowed in from the joint 92 flows into the electrolysis unit 62 through the second water dividing passage 68D, and flows upward through the gap of the second convex portion 63 or the like.

另一方面,在第一外殼片50的內表面的上部形成有第一集水路58C。第一集水路58C沿第一外殼片50的橫向H延伸,並與電解部52連通。移動至電解部52的上方的水被第一集水路58C收集,並從接頭93向電解槽4的外部流出。同樣,在第二外殼片60的內表面的上部形成有第二集水路68C。第二集水路68C沿第二外殼片60的橫向H延伸,並與電解部62連通。移動至電解部62的上方的水被第二集水路68C收集,並從接頭94向電解槽4的外部流出。On the other hand, a first water collecting passage 58C is formed in an upper portion of the inner surface of the first outer shell piece 50. The first water collection path 58C extends in the lateral direction H of the first outer casing piece 50 and communicates with the electrolysis portion 52. The water that has moved to the upper side of the electrolysis unit 52 is collected by the first water collection path 58C, and flows out from the joint 93 to the outside of the electrolytic cell 4. Similarly, a second water collection path 68C is formed on the upper portion of the inner surface of the second outer casing piece 60. The second water collecting path 68C extends in the lateral direction H of the second outer casing piece 60 and communicates with the electrolysis portion 62. The water moved to the upper side of the electrolysis section 62 is collected by the second water collection path 68C, and flows out from the joint 94 to the outside of the electrolytic cell 4.

若以接合面51為基準,則電解部52的深度小於第一分水路58D和第一集水路58C。透過這種電解部52,來提高在電解部52中流動的水的速度,從而易於溶解氧氣。而且,在電解部52與第一分水路58D和第一集水路58C之間的臺階部形成有斜面59。斜面59使陽極室40A內的水的流動順利,並抑制在電解部52中流動的水的速度的降低。When the joint surface 51 is used as a reference, the depth of the electrolysis portion 52 is smaller than the first water dividing passage 58D and the first water collecting passage 58C. The electrolysis unit 52 increases the speed of the water flowing through the electrolysis unit 52, thereby easily dissolving oxygen. Further, a slope 59 is formed in the step portion between the electrolysis portion 52 and the first water dividing passage 58D and the first water collecting passage 58C. The slope 59 smoothes the flow of water in the anode chamber 40A and suppresses a decrease in the speed of the water flowing in the electrolysis portion 52.

同樣,若以接合面61為基準,則電解部62的深度小於第二分水路68D和第二集水路68C。透過這種電解部62,來提高在電解部62中流動的水的速度,從而易於溶解氫氣。而且,在電解部62與第二分水路68D和第二集水路68C之間的臺階部形成有斜面69。斜面69使陰極室40B內的水的流動順利,並抑制在電解部62中流動的水的速度的降低。Similarly, the depth of the electrolysis portion 62 is smaller than the second water dividing passage 68D and the second water collecting passage 68C based on the joint surface 61. The electrolysis unit 62 increases the speed of the water flowing through the electrolysis unit 62, thereby easily dissolving hydrogen gas. Further, a slope 69 is formed in the step portion between the electrolysis portion 62 and the second water dividing passage 68D and the second water collecting passage 68C. The inclined surface 69 smoothes the flow of water in the cathode chamber 40B and suppresses a decrease in the speed of the water flowing in the electrolytic portion 62.

第7圖示出作為第一外殼片50的變形例的第一外殼片50A。另一方面,第8圖示出作為第二外殼片60的變形例的第二外殼片60A。Fig. 7 shows a first outer casing piece 50A as a modification of the first outer casing piece 50. On the other hand, Fig. 8 shows a second outer casing piece 60A as a modification of the second outer casing piece 60.

對於第一外殼片50A而言,在第一分水路58D(參照第3圖)和第一集水路58C的周圍設置有第一突起56,這一點與第一外殼片50不同。同樣,對於第二外殼片60A而言,在第二分水路68D(參照第3圖)和第二集水路68C的周圍設置有第二突起66,這一點與第二外殼片60不同。關於該第一外殼片50A和第二外殼片60A中的、以下未作說明的部分,可採用上述第一外殼片50和第二外殼片60的結構。In the first outer casing piece 50A, the first protrusion 56 is provided around the first water dividing passage 58D (see FIG. 3) and the first water collecting passage 58C, which is different from the first outer casing piece 50. Similarly, the second outer casing piece 60A is provided with a second projection 66 around the second water dividing passage 68D (see FIG. 3) and the second water collecting passage 68C, which is different from the second outer casing sheet 60. Regarding the portions of the first outer casing piece 50A and the second outer casing piece 60A which are not described below, the structures of the first outer casing piece 50 and the second outer casing piece 60 described above may be employed.

如第7圖所示,第一突起56包括有在橫向H上長的第一橫長突起57A。沿第3圖中的第一分水路58D的下端和第一集水路58C的上端設置有多個第一橫長突起57A,並且其與陽極供電體41的縱向V上的縱邊緣部41v(參照第2圖)抵接。由此,陽極供電體41的縱邊緣部41v被第一橫長突起57A支撐。因此,即使在陽極室40A與陰極室40B之間產生較大的壓力差的情況下,也能夠抑制層壓體45的變形,並且抑制隔膜43的損傷。此外,所謂陽極供電體41的縱邊緣部41v是指例如從陽極供電體41的縱向V的邊緣至內側,為陽極供電體41的縱向V長度的2%以下的區域(以下,關於陰極供電體42的縱邊緣部42v也相同)。As shown in Fig. 7, the first projection 56 includes a first lateral projection 57A that is long in the lateral direction H. A plurality of first laterally long projections 57A are provided along the lower end of the first water dividing passage 58D and the upper end of the first water collecting passage 58C in Fig. 3, and the longitudinal edge portion 41v in the longitudinal direction V of the anode power supply body 41 (refer to Figure 2) Abut. Thereby, the longitudinal edge portion 41v of the anode power supply body 41 is supported by the first laterally long projections 57A. Therefore, even when a large pressure difference is generated between the anode chamber 40A and the cathode chamber 40B, deformation of the laminate 45 can be suppressed, and damage of the diaphragm 43 can be suppressed. In addition, the longitudinal edge portion 41v of the anode power supply body 41 is, for example, an area from the edge of the longitudinal direction V of the anode power supply body 41 to the inner side, which is 2% or less of the longitudinal V length of the anode power supply body 41 (hereinafter, regarding the cathode power supply body) The longitudinal edge portion 42v of 42 is also the same).

同樣,如第8圖所示,第二突起66包括有在橫向H上長的第二橫長突起67A。在從縱向V觀察電解槽4的俯視中,第二橫長突起67A被隔開間隔地設置在相鄰的第一橫長突起57A之間。沿第3圖中的第二分水路68D的下端和第二集水路68C的上端設置有多個第二橫長突起67A,並且其與陰極供電體42的縱向V上的縱邊緣部42v(參照第2圖)抵接。由此,陰極供電體42的縱邊緣部42v被第二橫長突起67A支撐。因此,即使在陽極室40A與陰極室40B之間產生較大的壓力差的情況下,也能夠抑制層壓體45的變形,並且抑制隔膜43的損傷。此外,各第二橫長突起67A在橫向上與第一橫長突起57A交替設置即可,也可以設置在當固定接合第一外殼片50和第二外殼片60時,在縱向V上與相鄰的第一橫長突起57A錯開的位置上。Also, as shown in Fig. 8, the second projection 66 includes a second laterally elongated projection 67A that is long in the lateral direction H. In a plan view of the electrolytic cell 4 viewed from the longitudinal direction V, the second laterally long projections 67A are disposed between the adjacent first laterally long projections 57A with a space therebetween. A plurality of second laterally elongated projections 67A are provided along the lower end of the second water dividing passage 68D and the upper end of the second water collecting passage 68C in Fig. 3, and the longitudinal edge portion 42v in the longitudinal direction V of the cathode power supply body 42 (refer to Figure 2) Abut. Thereby, the longitudinal edge portion 42v of the cathode power supply body 42 is supported by the second horizontally long projection 67A. Therefore, even when a large pressure difference is generated between the anode chamber 40A and the cathode chamber 40B, deformation of the laminate 45 can be suppressed, and damage of the diaphragm 43 can be suppressed. Further, each of the second laterally elongated projections 67A may be alternately disposed in the lateral direction with the first laterally elongated projections 57A, or may be disposed in the longitudinal direction V when the first outer casing sheets 50 and the second outer casing sheets 60 are fixedly joined. The adjacent first horizontally long projections 57A are staggered.

以上,對本發明的電解水生成裝置1進行了詳細說明,但本發明並不限定於上述的具體實施方式,可以變更為多種方式來實施。即,電解水生成裝置1至少具備:電解槽4,形成有用於供給所電解的水的電解室40;陽極供電體41和陰極供電體42,被彼此相對配置在電解室40內;和隔膜43,被配置在陽極供電體41與陰極供電體42之間,並且將電解室40劃分為陽極室40A和陰極室40B,隔膜43被陽極供電體41和陰極供電體42夾持,電解槽4透過固定接合陽極供電體41側的第一外殼片50和陰極供電體42側的第二外殼片60而形成電解室40,在第一外殼片50的內表面上配設有與陽極供電體41抵接的第一凸部53,在第二外殼片60的內表面上配設有與陰極供電體42抵接的第二凸部63,第一凸部53包括與陽極供電體41的邊緣部41e抵接的第一突起56,第二凸部63包括與陰極供電體42的邊緣部42e抵接的第二突起66。Although the electrolyzed water generating apparatus 1 of the present invention has been described in detail above, the present invention is not limited to the specific embodiments described above, and can be modified in various forms. That is, the electrolyzed water generating apparatus 1 includes at least an electrolytic cell 4 in which an electrolysis chamber 40 for supplying electrolyzed water is formed, an anode power supply body 41 and a cathode power supply body 42 disposed opposite to each other in the electrolysis chamber 40, and a separator 43 Between the anode power supply body 41 and the cathode power supply body 42, the electrolytic chamber 40 is divided into an anode chamber 40A and a cathode chamber 40B, and the diaphragm 43 is sandwiched by the anode power supply body 41 and the cathode power supply body 42, and the electrolytic cell 4 is permeable. The first outer casing piece 50 on the side of the anode power supply body 41 and the second outer casing piece 60 on the side of the cathode power supply body 42 are fixedly coupled to form an electrolytic chamber 40, and the inner surface of the first outer casing piece 50 is disposed to be opposed to the anode power supply body 41. The first convex portion 53 is provided with a second convex portion 63 abutting on the inner surface of the second outer casing piece 60, and the first convex portion 53 includes an edge portion 41e with the anode power supply body 41. The second protrusion 63 that abuts, the second protrusion 63 includes a second protrusion 66 that abuts against the edge portion 42e of the cathode power supply body 42.

例如,設置在電解部52、62的主要部上的第一凸部53、第二凸部63並不限於沿第一外殼片50的縱向V離散分佈的形式的凸部,還可以是各種形式的凸部。For example, the first convex portion 53 and the second convex portion 63 provided on the main portion of the electrolysis portions 52, 62 are not limited to the convex portions in the form of discrete distribution in the longitudinal direction V of the first outer shell sheet 50, and may be various forms. The convex part.

第9圖示出作為第一外殼片50的另一變形例的第一外殼片50B和作為第二外殼片60的另一變形例的第二外殼片60B。第一外殼片50B應用與在上述專利文獻1的第6圖等中用符號32表示的凸狀部相同的第一凸部53B,來代替設置在電解部52的主要部52A(參照第3圖)上的第一凸部53,這一點與第一外殼片50不同。關於該第一外殼片50B中的、以下未作說明的部分,可採用上述第一外殼片50的結構。Fig. 9 shows a first outer casing piece 50B as another modification of the first outer casing piece 50 and a second outer casing piece 60B as another modification of the second outer casing piece 60. In the first outer casing piece 50B, the first convex portion 53B which is the same as the convex portion indicated by reference numeral 32 in the sixth drawing of the above-mentioned Patent Document 1 is used instead of the main portion 52A provided in the electrolysis portion 52 (refer to FIG. 3). The first convex portion 53 is different from the first outer casing piece 50. Regarding the portion of the first outer casing piece 50B which is not described below, the structure of the first outer casing piece 50 described above can be employed.

第一凸部53包括第一凸部53B和第一突起56。第一凸部53B從第一分水路58D的上端至第一集水路58C的下端,沿縱向V連續延伸。此時,在相鄰的第一凸部53B之間設置有第一槽部54B。The first convex portion 53 includes a first convex portion 53B and a first protrusion 56. The first convex portion 53B continuously extends in the longitudinal direction V from the upper end of the first water dividing passage 58D to the lower end of the first water collecting passage 58C. At this time, the first groove portion 54B is provided between the adjacent first convex portions 53B.

另一方面,第二外殼片60B應用與第一凸部53B相同的第二凸部63B,來代替設置在電解部62的主要部62A(參照第3圖)上的第二凸部63,這一點與第二外殼片60不同。關於該第二外殼片60B中的、以下未作說明的部分,可採用上述第二外殼片60的結構。On the other hand, the second outer casing piece 60B is applied with the second convex portion 63B which is the same as the first convex portion 53B instead of the second convex portion 63 provided on the main portion 62A (see FIG. 3) of the electrolysis portion 62, which One point is different from the second outer casing piece 60. Regarding the portion of the second outer casing piece 60B which is not described below, the structure of the second outer casing piece 60 described above can be employed.

第二凸部63包括第二凸部63B和第二突起66。第二凸部63B從第二分水路68D的上端至第二集水路68C的下端,沿縱向V連續延伸。此時,在相鄰的第二凸部63B之間設置有第二槽部64B。The second convex portion 63 includes a second convex portion 63B and a second protrusion 66. The second convex portion 63B continuously extends in the longitudinal direction V from the upper end of the second water dividing passage 68D to the lower end of the second water collecting passage 68C. At this time, the second groove portion 64B is provided between the adjacent second convex portions 63B.

第一凸部53B和第二凸部63B被設置為交替位於橫向V上。因此,當固定接合第一外殼片50B和第二外殼片60B時,第一凸部53B和第二槽部64B隔著層壓體45相對,並且第二凸部63B和第一槽部54B隔著層壓體45相對。例如,對於氫氣能夠充分溶解於流過第一槽部54B和第二槽部64B的水中的電解槽4而言,可較佳應用第一外殼片50B和第二外殼片60B。The first convex portion 53B and the second convex portion 63B are disposed alternately in the lateral direction V. Therefore, when the first outer casing piece 50B and the second outer casing piece 60B are fixedly joined, the first convex portion 53B and the second groove portion 64B are opposed to each other via the laminate 45, and the second convex portion 63B and the first groove portion 54B are separated The laminate 45 is opposed. For example, for the electrolytic cell 4 in which hydrogen gas can be sufficiently dissolved in the water flowing through the first groove portion 54B and the second groove portion 64B, the first outer shell piece 50B and the second outer shell piece 60B can be preferably applied.

對於第一外殼片50B和第二外殼片60B而言,還可以將第一凸部53和第二凸部63的一部分置換為第一凸部53B和第二凸部63B。例如,也可以在第一外殼片50B中混合設置有離散配置在電解部52的主要部上的第一凸部53和沿縱向V連續延伸的第一槽部54B。同樣,也可以在第二外殼片60B中混合設置有離散配置在電解部62的主要部上的第二凸部63和沿縱向V連續延伸的第二槽部64B。此外,第一外殼片50B和第二外殼片60B的特徵也可與第7圖、第8圖所示的第一外殼片50A和第二外殼片60A適當組合來應用。For the first outer casing piece 50B and the second outer casing piece 60B, a part of the first convex portion 53 and the second convex portion 63 may be replaced with the first convex portion 53B and the second convex portion 63B. For example, a first convex portion 53 discretely disposed on a main portion of the electrolytic portion 52 and a first groove portion 54B extending continuously in the longitudinal direction V may be mixed and mixed in the first outer shell piece 50B. Similarly, a second convex portion 63 discretely disposed on the main portion of the electrolytic portion 62 and a second groove portion 64B extending continuously in the longitudinal direction V may be mixed and mixed in the second outer casing piece 60B. Further, the features of the first outer casing piece 50B and the second outer casing piece 60B may be applied in appropriate combination with the first outer casing piece 50A and the second outer casing piece 60A shown in Figs. 7 and 8.

第10圖示出作為第一外殼片50的又一變形例的第一外殼片50C和作為第二外殼片60的又一變形例的第二外殼片60C。對於第一外殼片50C而言,在電解部52的主要部52A(參照第3圖)不存在第一凸部53,這一點與第一外殼片50不同。同樣,對於第二外殼片60C而言,在電解部62的主要部62A(參照第3圖)不存在第二凸部63,這一點與第二外殼片60不同。關於該第一外殼片50C和第二外殼片60C中的、以下未作說明的部分,可採用上述第一外殼片50和第二外殼片60的結構。Fig. 10 shows a first outer casing piece 50C as a further modification of the first outer casing piece 50 and a second outer casing piece 60C as a further modification of the second outer casing piece 60. In the first outer casing piece 50C, the first convex portion 53 is not present in the main portion 52A (see FIG. 3) of the electrolysis portion 52, which is different from the first outer casing piece 50. Similarly, in the second outer casing piece 60C, the second convex portion 63 is not present in the main portion 62A (see FIG. 3) of the electrolysis portion 62, which is different from the second outer casing sheet 60. Regarding the portions of the first outer casing piece 50C and the second outer casing piece 60C which are not described below, the structures of the first outer casing piece 50 and the second outer casing piece 60 described above may be employed.

第一凸部53包括第一突起56,第二凸部63包括第二突起66。例如,對於在隔膜43與陽極供電體41和陰極供電體42之間不要求較大的接觸壓力的電解槽4而言,可較佳應用第一外殼片50C和第二外殼片60C。此外,第一外殼片50C和第二外殼片60C的特徵也可與第7圖、第8圖所示的第一外殼片50A和第二外殼片60A適當組合來應用。The first convex portion 53 includes a first protrusion 56, and the second convex portion 63 includes a second protrusion 66. For example, for the electrolytic cell 4 which does not require a large contact pressure between the separator 43 and the anode power supply body 41 and the cathode power supply body 42, the first outer casing piece 50C and the second outer casing piece 60C can be preferably applied. Further, the features of the first outer casing piece 50C and the second outer casing piece 60C may be applied in appropriate combination with the first outer casing piece 50A and the second outer casing piece 60A shown in Figs. 7 and 8.

另外,還可以在第一外殼片50、50A、50B或50C中構造有透過一對凸狀部與橫邊緣部41h抵接的第一突起56,該一對凸狀部沿陽極供電體41的橫邊緣部41h,從第一分水路58D的外緣至第一集水路58C的外緣連續。這種第一突起56能夠代替多個離散化的第一縱長突起57來應用。同樣,還可以在第二外殼片60、60A、60B或60C中構造有透過一對凸狀部與橫邊緣部42h抵接的第二突起66,該一對凸狀部沿陰極供電體42的橫邊緣部42h,從第二分水路68D的外緣至第二集水路68C的外緣連續。這種第二突起66能代替多個離散化的第二縱長突起67來應用。In addition, a first protrusion 56 that abuts against the lateral edge portion 41h through a pair of convex portions along the anode power supply body 41 may be formed in the first outer casing piece 50, 50A, 50B or 50C. The lateral edge portion 41h is continuous from the outer edge of the first water dividing passage 58D to the outer edge of the first water collecting passage 58C. Such a first protrusion 56 can be applied instead of a plurality of discrete first lengthwise protrusions 57. Similarly, a second protrusion 66 that abuts against the lateral edge portion 42h through the pair of convex portions may be formed in the second outer casing piece 60, 60A, 60B or 60C, and the pair of convex portions are along the cathode power supply body 42. The lateral edge portion 42h is continuous from the outer edge of the second water dividing passage 68D to the outer edge of the second water collecting passage 68C. This second protrusion 66 can be applied instead of the plurality of discrete second lengthwise protrusions 67.

根據由上述凸狀部構造的第一突起56和第二突起66,能夠減少橫邊緣部41h和橫邊緣部42h附近的與隔膜43的接觸電阻,因此流過橫邊緣部41h和橫邊緣部42h的附近的電解電流增大,從而能夠進一步促進電解。此外,較佳地,由這種凸狀部構造的第一突起56和第二突起66的高度被設定為不會因隔膜43與陽極供電體41和陰極供電體42之間的接觸壓力而使隔膜43受到損傷的程度。According to the first protrusion 56 and the second protrusion 66 which are configured by the above-described convex portion, the contact resistance with the diaphragm 43 in the vicinity of the lateral edge portion 41h and the lateral edge portion 42h can be reduced, and thus flow through the lateral edge portion 41h and the lateral edge portion 42h The electrolysis current in the vicinity is increased to further promote electrolysis. Further, preferably, the heights of the first protrusions 56 and the second protrusions 66 constructed by such convex portions are set so as not to be caused by the contact pressure between the diaphragm 43 and the anode power supply body 41 and the cathode power supply body 42. The diaphragm 43 is damaged to the extent that it is damaged.

進一步,還可以在第一外殼片50A中構造有透過一對凸狀部與縱邊緣部41v抵接的第一突起56,該一對凸狀部沿陽極供電體41的縱邊緣部41v,從第一分水路58D的外緣至第一集水路58C的外緣連續。這種第一突起56能夠代替多個離散化的第一橫長突起57A來應用。同樣,也可以在第二外殼片60A中構造有透過一對凸狀部與縱邊緣部42v抵接的第二突起66,該一對凸狀部沿陰極供電體42的縱邊緣部42v連續。這種第二突起66能夠代替多個離散化的第一橫長突起67A來應用。Further, a first protrusion 56 that is in contact with the vertical edge portion 41v through a pair of convex portions may be formed in the first outer casing piece 50A, and the pair of convex portions are along the longitudinal edge portion 41v of the anode power supply body 41. The outer edge of the first water dividing passage 58D is continuous to the outer edge of the first water collecting passage 58C. Such a first protrusion 56 can be applied instead of the plurality of discretized first lateral length protrusions 57A. Similarly, a second protrusion 66 that is in contact with the vertical edge portion 42v through the pair of convex portions may be formed in the second outer casing piece 60A, and the pair of convex portions may be continuous along the longitudinal edge portion 42v of the cathode power supply body 42. This second protrusion 66 can be applied instead of the plurality of discretized first laterally elongated protrusions 67A.

根據上述第一突起56和第二突起66,在縱邊緣部41v和縱邊緣部42v的附近能夠堅固地支撐隔膜43,因此即使在陽極室40A與陰極室40B之間產生較大的壓力差的情況下,也能夠抑制層壓體45的變形,並且抑制隔膜43的損傷。此外,較佳地,由這種凸狀部構造的第一突起56和第二突起66的高度被設定為不會因隔膜43與陽極供電體41和陰極供電體42之間的接觸壓力而使隔膜43受到損傷的程度。According to the first protrusion 56 and the second protrusion 66 described above, the diaphragm 43 can be strongly supported in the vicinity of the longitudinal edge portion 41v and the longitudinal edge portion 42v, so that a large pressure difference is generated between the anode chamber 40A and the cathode chamber 40B. In this case, deformation of the laminate 45 can also be suppressed, and damage of the separator 43 can be suppressed. Further, preferably, the heights of the first protrusions 56 and the second protrusions 66 constructed by such convex portions are set so as not to be caused by the contact pressure between the diaphragm 43 and the anode power supply body 41 and the cathode power supply body 42. The diaphragm 43 is damaged to the extent that it is damaged.

1‧‧‧電解水生成裝置
4‧‧‧電解槽
40‧‧‧電解室
40A‧‧‧陽極室
40B‧‧‧陰極室
41‧‧‧陽極供電體
41a、42a‧‧‧端子
41e、42e‧‧‧邊緣部
41h、42h‧‧‧橫邊緣部
41v、42v‧‧‧縱邊緣部
42‧‧‧陰極供電體
43‧‧‧隔膜
43a‧‧‧鍍層
44‧‧‧電流檢測單元
45‧‧‧層壓體
46‧‧‧密封部件
50、50B、50C‧‧‧第一外殼片
51、61‧‧‧接合面
52、62‧‧‧電解部
53、53B‧‧‧第一凸部
53a、57a、63a、67a‧‧‧頂部
53b、57b、63b、67b‧‧‧凸曲面
53P、63P‧‧‧突起
54‧‧‧第一小突起
54B‧‧‧第一槽部
55、65‧‧‧槽
56‧‧‧第一突起
57、67‧‧‧縱長突起
57A‧‧‧第一橫長突起
58C‧‧‧第一集水路
58D‧‧‧第一分水路
59、69‧‧‧斜面
60、60B、60C‧‧‧第二外殼片
62A‧‧‧主要部
63、63B‧‧‧第二凸部
64‧‧‧第二小突起
64B‧‧‧第二槽部
66‧‧‧第二突起
68C‧‧‧第二集水路
68D‧‧‧第二分水路
7‧‧‧進水部
71、71a、71b‧‧‧供水管
72‧‧‧流量感測器
73‧‧‧分支部
74‧‧‧流量調整閥
8‧‧‧出水部
81‧‧‧流路切換閥
82‧‧‧吐水管
83‧‧‧排水管
91、92、93、94‧‧‧接頭
1‧‧‧ Electrolyzed water generating device
4‧‧‧electrolyzer
40‧‧‧Electrolytic chamber
40A‧‧‧Anode chamber
40B‧‧‧Cathode chamber
41‧‧‧Anode power supply
41a, 42a‧‧‧ terminals
41e, 42e‧‧‧ edge
41h, 42h‧‧‧ horizontal edge
41v, 42v‧‧‧ vertical edge
42‧‧‧Cathodic power supply
43‧‧‧Separator
43a‧‧‧ plating
44‧‧‧ Current detection unit
45‧‧‧Lamination
46‧‧‧ Sealing parts
50, 50B, 50C‧‧‧ first outer shell
51, 61‧‧‧ joint surface
52, 62‧‧‧Electrical Department
53, 53B‧‧‧ first convex
53a, 57a, 63a, 67a‧‧‧ top
53b, 57b, 63b, 67b‧‧‧ convex surface
53P, 63P‧‧‧ Protrusion
54‧‧‧First small protrusion
54B‧‧‧First groove
55, 65‧‧‧ slots
56‧‧‧First protrusion
57, 67‧‧‧ Longitudinal protrusion
57A‧‧‧First horizontal length
58C‧‧‧The first waterway
58D‧‧‧The first waterway
59, 69‧‧‧ Bevel
60, 60B, 60C‧‧‧ second outer shell
62A‧‧‧ Main Department
63, 63B‧‧‧second convex
64‧‧‧Second small protrusion
64B‧‧‧Second groove
66‧‧‧second protrusion
68C‧‧‧Second water channel
68D‧‧‧Second waterway
7‧‧‧Intake Department
71, 71a, 71b‧‧‧ water supply pipe
72‧‧‧Flow sensor
73‧‧‧ Branch
74‧‧‧Flow adjustment valve
8‧‧‧Water Department
81‧‧‧Flow path switching valve
82‧‧‧pipes
83‧‧‧Drainage pipe
91, 92, 93, 94‧‧‧ joints

第1圖是表示本發明的電解水生成裝置的一實施方式的大致結構的框圖。 第2圖是第1圖所示的電解槽的裝配立體圖。 第3圖是表示第2圖的第一外殼片和第二外殼片的立體圖。 第4圖是表示第2圖的第一外殼片和第二外殼片的主視圖。 第5圖是包括第4圖的A-A剖面和B-B剖面的電解槽的裝配剖視圖。 第6圖是與第5圖相同的剖面中的電解槽的剖視圖。 第7圖是表示第3圖的第一外殼片的變形例的立體圖。 第8圖是表示第3圖的第二外殼片的變形例的立體圖。 第9圖是表示第3圖的第一外殼片和第二外殼片的另一變形例的立體圖。 第10圖是表示第3圖的第一外殼片和第二外殼片的又一變形例的立體圖。Fig. 1 is a block diagram showing a schematic configuration of an embodiment of an electrolyzed water generating apparatus of the present invention. Fig. 2 is an assembled perspective view of the electrolytic cell shown in Fig. 1. Fig. 3 is a perspective view showing the first outer casing piece and the second outer casing piece of Fig. 2; Fig. 4 is a front elevational view showing the first outer casing piece and the second outer casing piece of Fig. 2; Fig. 5 is a cross-sectional view showing the assembly of the electrolytic cell including the A-A section and the B-B section of Fig. 4. Fig. 6 is a cross-sectional view of the electrolytic cell in the same cross section as Fig. 5. Fig. 7 is a perspective view showing a modification of the first outer casing piece of Fig. 3. Fig. 8 is a perspective view showing a modification of the second outer casing piece of Fig. 3. Fig. 9 is a perspective view showing another modification of the first outer casing piece and the second outer casing piece of Fig. 3. Fig. 10 is a perspective view showing still another modification of the first outer casing piece and the second outer casing piece of Fig. 3.

41‧‧‧陽極供電體 41‧‧‧Anode power supply

41e、42e‧‧‧邊緣部 41e, 42e‧‧‧ edge

41h、42h‧‧‧橫邊緣部 41h, 42h‧‧‧ horizontal edge

42‧‧‧陰極供電體 42‧‧‧Cathodic power supply

43‧‧‧隔膜 43‧‧‧Separator

45‧‧‧層壓體 45‧‧‧Lamination

46‧‧‧密封部件 46‧‧‧ Sealing parts

50‧‧‧第一外殼片 50‧‧‧First outer shell

57a、67a‧‧‧頂部 57a, 67a‧‧‧ top

57b、67b‧‧‧凸曲面 57b, 67b‧‧‧ convex surface

56‧‧‧第一突起 56‧‧‧First protrusion

57、67‧‧‧縱長突起 57, 67‧‧‧ Longitudinal protrusion

60‧‧‧第二外殼片 60‧‧‧Second outer shell

66‧‧‧第二突起 66‧‧‧second protrusion

Claims (8)

一種電解水生成裝置,其包含: 電解槽,形成有用於供給所電解的水的電解室; 陽極供電體和陰極供電體,被彼此相對配置在該電解室內;以及 隔膜,被配設在該陽極供電體與該陰極供電體之間,並且將該電解室劃分為該陽極供電體側的陽極室和該陰極供電體側的陰極室; 其中,該隔膜被該陽極供電體和該陰極供電體夾持,該電解槽透過固定接合該陽極供電體側的第一外殼片和該陰極供電體側的第二外殼片而形成該電解室,在該第一外殼片的朝向該電解室側的內表面上配設有與該陽極供電體抵接的第一凸部,在該第二外殼片的朝向該電解室側的內表面上配設有與該陰極供電體抵接的第二凸部,該第一凸部包括與該陽極供電體的邊緣部抵接的第一突起,該第二凸部包括與該陰極供電體的邊緣部抵接的第二突起。An electrolyzed water generating apparatus comprising: an electrolysis cell formed with an electrolysis chamber for supplying electrolyzed water; an anode supply body and a cathode supply body disposed opposite to each other in the electrolysis chamber; and a separator disposed at the anode Between the power supply body and the cathode power supply body, and dividing the electrolytic chamber into an anode chamber on the anode power supply body side and a cathode chamber on the cathode power supply body side; wherein the separator is sandwiched by the anode power supply body and the cathode power supply body Holding the electrolytic cell through the first outer casing piece fixed to the anode power supply body side and the second outer casing piece on the cathode power supply body side, the inner surface of the first outer casing piece facing the electrolytic chamber side a first convex portion that is in contact with the anode power supply body is disposed, and a second convex portion that is in contact with the cathode power supply body is disposed on an inner surface of the second outer casing sheet facing the electrolytic chamber side. The first convex portion includes a first protrusion that abuts against an edge portion of the anode power supply body, and the second convex portion includes a second protrusion that abuts against an edge portion of the cathode power supply body. 如申請專利範圍第1項所述之電解水生成裝置,其中沿該陽極供電體的邊緣部設置有複數個該第一突起,沿該陰極供電體的邊緣部設置有複數個該第二突起。The electrolyzed water generating apparatus according to claim 1, wherein a plurality of the first protrusions are provided along an edge portion of the anode power supply body, and a plurality of the second protrusions are provided along an edge portion of the cathode power supply body. 如申請專利範圍第2項所述之電解水生成裝置,其中該第二突起被配設在相鄰的該第一突起之間。The electrolyzed water generating device according to claim 2, wherein the second protrusion is disposed between the adjacent first protrusions. 如申請專利範圍第2項所述之電解水生成裝置,其中該第一突起和該第二突起包括有在順著該電解室內的水的流動的縱向上長的縱長突起,該縱長突起與該陽極供電體或該陰極供電體的垂直於縱向的橫向的橫邊緣部抵接。The electrolyzed water generating device according to claim 2, wherein the first protrusion and the second protrusion comprise longitudinally elongated protrusions extending in a flow along the electrolysis chamber, the longitudinal protrusions The anode power supply body or the lateral edge portion of the cathode power supply body that is perpendicular to the longitudinal direction is abutted. 如申請專利範圍第2項所述之電解水生成裝置,其中該第一突起和該第二突起包括有在垂直於縱向的橫向上長的橫長突起,該橫長突起與該陽極供電體或該陰極供電體的縱向的縱邊緣部抵接。The electrolyzed water generating device according to claim 2, wherein the first protrusion and the second protrusion comprise a horizontally long protrusion that is long in a lateral direction perpendicular to the longitudinal direction, the horizontally elongated protrusion and the anode power supply body or The longitudinal longitudinal edge portion of the cathode power supply body abuts. 如申請專利範圍第1項所述之電解水生成裝置,其中該第一凸部的頂部包括有在該第一外殼片側具有中心的曲面,該第二凸部的頂部包括有在該第二外殼片側具有中心的曲面。The electrolyzed water generating device of claim 1, wherein a top portion of the first convex portion includes a curved surface having a center on a side of the first outer shell sheet, and a top portion of the second convex portion includes a second outer shell The sheet side has a central curved surface. 如申請專利範圍第1至6項中之任一項所述之電解水生成裝置,其中對於該第一外殼片的朝向該電解室側的內表面而言,在隔著該隔膜、該陽極供電體和該陰極供電體與該第二凸部相對的位置上,配設有高度小於該第一凸部的第一小突起,對於該第二外殼片的朝向該電解室側的內表面而言,在隔著該隔膜、該陽極供電體和該陰極供電體與該第一凸部相對的位置上,配設有高度小於該第二凸部的複數個第二小突起。The electrolyzed water generating device according to any one of claims 1 to 6, wherein an inner surface of the first outer casing sheet facing the electrolysis chamber side is supplied with the anode via the diaphragm And a first small protrusion having a height smaller than the first convex portion at a position opposite to the cathode power supply body and the second convex portion, for the inner surface of the second outer casing sheet facing the electrolytic chamber side And a plurality of second small protrusions having a height smaller than the second convex portion are disposed at a position opposing the first convex portion via the diaphragm, the anode power supply body, and the cathode power supply body. 如申請專利範圍第7項所述之電解水生成裝置,其中該第一小突起與該陽極供電體不抵接,該第二小突起與該陰極供電體不抵接。The electrolyzed water generating device according to claim 7, wherein the first small protrusion does not abut the anode power supply body, and the second small protrusion does not abut the cathode power supply body.
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JP2016163865A (en) 2016-09-08
WO2016143540A1 (en) 2016-09-15

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