TW201605316A - Manufacturing method of multi-layer printed wiring board - Google Patents

Manufacturing method of multi-layer printed wiring board Download PDF

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Publication number
TW201605316A
TW201605316A TW104108179A TW104108179A TW201605316A TW 201605316 A TW201605316 A TW 201605316A TW 104108179 A TW104108179 A TW 104108179A TW 104108179 A TW104108179 A TW 104108179A TW 201605316 A TW201605316 A TW 201605316A
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Taiwan
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circuit substrate
printed wiring
wiring board
manufacturing
multilayer printed
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TW104108179A
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Chinese (zh)
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TWI608778B (en
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Yoshihiko Narisawa
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Nippon Mektron Kk
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    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/46Manufacturing multilayer circuits

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Production Of Multi-Layered Print Wiring Board (AREA)
  • Manufacturing Of Printed Wiring (AREA)
  • Screen Printers (AREA)
  • Printing Elements For Providing Electric Connections Between Printed Circuits (AREA)

Abstract

The purpose of the present invention is to provide a manufacturing method of multi-layer printed wiring board for inexpensively and efficiently manufacturing multi-layer printed wiring boards. In the manufacturing method of multi-layer printed wiring board, a printed board 100 includes: a frame part 110 having a large opening part 110a larger than a circuit substrate 10 when viewed from the top; and a resin-made edging part 120 having a small opening 120a smaller than the circuit substrate 10 when viewed from the top, which is arranged on the periphery of a lower part of the large opening part 110a. The printing method using the printed board 100 includes: a step of enabling the frame part 110 to be positioned and mounted on the circuit substrate 10 in a manner of using the small opening 120a to cover the periphery of the circuit substrate 10; a step of uniformly coating conductive paste P on the circuit substrate 10 through the small opening part 120a so as to fill up a conduction hole 15 with the conductive paste P; and a step of mounting the remaining conductive paste P in the large opening part 110a onto the edging part 120.

Description

多層印刷配線板之製造方法 Multilayer printed wiring board manufacturing method

本發明係有關一種多層印刷配線板之製造方法,特別是有關包含將電路基材的周緣以印刷版覆蓋,以印刷橡皮輥(squeegee)在電路基材的導通用孔填充導電糊的印刷工程之多層印刷配線板之製造方法。 The present invention relates to a method of manufacturing a multilayer printed wiring board, and more particularly to a printing process comprising covering a periphery of a circuit substrate with a printing plate and filling a conductive paste with a conductive squeegee on a conductive hole of the circuit substrate. A method of manufacturing a multilayer printed wiring board.

近年來,逐漸促進電子機器的小型化及高機能化,因此針對印刷配線板之高密度化的要求越來越高。於是,透過將印刷配線板從單面設為雙面、三層以上的多層印刷配線板以謀求印刷配線板的高密度化。 In recent years, the miniaturization and high performance of electronic devices have been gradually promoted. Therefore, there is an increasing demand for higher density of printed wiring boards. Then, the printed wiring board is made of a multilayer printed wiring board having two or more layers on one side, thereby achieving a higher density of the printed wiring board.

就採用多層印刷配線板的筆記型電腦、智慧手機等之電子機器而言,近年資訊量大增,對於多層印刷配線板也要求能因應於高速、大容量通信。例如,在筆記型電腦的情況,從2010年到2011年,傳送速度移行到6Gbps的傳送標準,在多層印刷配線板內的高速信號之低傳送損失化變得重要。 In the case of electronic devices such as notebook computers and smart phones that use multi-layer printed wiring boards, the amount of information has increased in recent years, and multi-layer printed wiring boards are also required to be able to respond to high-speed and large-capacity communication. For example, in the case of a notebook computer, from 2010 to 2011, the transmission speed shifts to a transmission standard of 6 Gbps, and low transmission loss of a high-speed signal in a multilayer printed wiring board becomes important.

於是,液晶聚合物(Liquid Crystal Polymer:LCP)開始被適用作為多層印刷配線板的層間絕緣材料。液晶聚合物係因為於介電係數及消耗因子低,故介電體損失小,能減低傳送損失。又因為具有高折曲性,故 亦可因應在朝機器內裝入之際的彎曲。 Thus, liquid crystal polymer (LCP) is beginning to be applied as an interlayer insulating material for a multilayer printed wiring board. Since the liquid crystal polymer has a low dielectric constant and a low consumption factor, the dielectric loss is small and the transmission loss can be reduced. Because of its high flexibility, It can also be bent when it is loaded into the machine.

然而,液晶聚合物的厚度方向的熱膨脹係數是比習知的撓性印刷配線板所使用之聚醯亞胺等的絕緣材料來得大。因此,在為了層間連接而使用一般所採用之鍍銅通孔的情況,認為液晶聚合物與銅的熱膨脹係數之差大,可能無法充分確保有關溫度循環試驗等之層間連接可靠性。 However, the coefficient of thermal expansion in the thickness direction of the liquid crystal polymer is larger than that of a polyimide or the like which is used in a conventional flexible printed wiring board. Therefore, in the case of using a copper-plated through hole which is generally used for interlayer connection, it is considered that the difference in thermal expansion coefficient between the liquid crystal polymer and copper is large, and the interlayer connection reliability such as the temperature cycle test may not be sufficiently ensured.

於是,對於將液晶聚合物作為絕緣層的印刷配線板,有提案取代鍍銅通孔,改為將使用了導電糊的導通用孔適用於層間連接上(例如,參照專利文獻1)。 Then, in the printed wiring board in which the liquid crystal polymer is used as the insulating layer, it is proposed to replace the copper-plated through hole, and the conductive hole using the conductive paste is applied to the interlayer connection (see, for example, Patent Document 1).

在將導電糊填充於導通用孔的印刷工程中,為在印刷後將剩餘的導電糊回收再利用,通常如圖7(a)所示,使用將版框210與具有對應於電路基材300的大小之開口部220a的金屬板220組合而成的金屬製印刷版200。此處,例如,在電路基材300的尺寸設為寬度250mm、長度300mm的情況,金屬板220的開口部220a設定成從電路基材300的四邊朝內側小5mm程度的寬度240mm、長度290mm。 In the printing process of filling the conductive paste into the conductive hole, in order to recycle and reuse the remaining conductive paste after printing, generally, as shown in FIG. 7(a), the frame 210 is used and has a corresponding circuit substrate 300. The metal printing plate 200 in which the metal plates 220 of the openings 220a of the size are combined. Here, for example, when the size of the circuit board 300 is 250 mm and the length is 300 mm, the opening 220a of the metal plate 220 is set to have a width of 240 mm and a length of 290 mm which are smaller by 5 mm from the four sides of the circuit substrate 300.

〔先行技術文獻〕 [prior technical literature] 〔專利文獻〕 [Patent Document]

〔專利文獻1〕特開2011-66293號公報。 [Patent Document 1] JP-A-2011-66293.

然而,在金屬板220是形成比既定量(例 如,1mm)厚之情況,因未圖示的印刷橡皮輥與電路基材300疏離,故如圖7(b)所示,印刷橡皮輥到不了開口部220a端易使導電糊P殘留於電路基材300上,具有所謂導電糊P無法有效率地回收,製品成本上昇之問題。 However, in the metal plate 220, the formation ratio is both quantitative (example) For example, when the thickness is 1 mm), since the printing squeegee (not shown) is separated from the circuit substrate 300, as shown in FIG. 7(b), the printing squeegee does not reach the end of the opening 220a, and the conductive paste P remains in the circuit. On the substrate 300, there is a problem that the conductive paste P cannot be efficiently recovered, and the cost of the product increases.

再者,因為電路基材300與印刷橡皮輥疏離會降低在印刷橡皮輥進行將電路基材300上的導電糊P塗勻之際的印刷壓力,如圖7(c)所示,具有所謂在導通用孔310內產生空隙v,生產率惡化之問題。 Furthermore, since the circuit substrate 300 is separated from the printing squeegee, the printing pressure at the time when the printing squeegee performs the coating of the conductive paste P on the circuit substrate 300 is reduced, as shown in FIG. 7(c), A gap v is generated in the general-purpose hole 310, and the productivity is deteriorated.

另一方面,如圖8(a)、(b)所示,在金屬板220形成比既定量(例如,0.1mm)薄而剛性低的情況,當開口部220a形成較大時,在開口部220a的周邊容易產生彎曲w,金屬製印刷版200對於反覆印刷之耐久性降低且有印刷穩定性降低之虞。 On the other hand, as shown in FIGS. 8(a) and 8(b), when the metal plate 220 is formed to be thinner than a predetermined amount (for example, 0.1 mm) and the rigidity is low, when the opening portion 220a is formed large, the opening portion is formed in the opening portion. The periphery of 220a is likely to be bent w, and the durability of the metal printing plate 200 for reverse printing is lowered and the printing stability is lowered.

於是,衍生出為了廉價且有效率地製造多層印刷配線板而應解決之技術的課題,本發明之目的即為解決此課題。 Therefore, a problem to be solved by manufacturing a multilayer printed wiring board at a low cost and efficiently has been derived, and an object of the present invention is to solve the problem.

本發明係為達成上述目的而提案者,請求項1所記載之發明提供一種多層印刷配線板之製造方法,該多層印刷配線板之製造方法係包含將電路基材的周緣以印刷版覆蓋,以印刷橡皮輥在前述電路基材上塗勻導電糊而在前述電路基材的導通孔填充前述導電糊之印刷工程的多層印刷配線板之製造方法,其特徵為:前述印刷版係具備在俯視觀之具有比前述電路基材大的大開口部之框體部、及在俯視觀之具有比前述電路基材小的小開口部 且配置在前述大開口部的下方周緣之樹脂製的鑲邊部,前述印刷工程係包含:以前述小開口部覆蓋前述電路基材的周緣之方式將前述框體部定位並載置前述電路基材上之工程;透過前述小開口部將前述導電糊塗勻於前述電路基材上而在前述導通用孔填充前述導電糊之工程;及在前述大開口部內將剩餘的前述導電糊匯集在前述鑲邊部上之工程。 The present invention provides a method for producing a multilayer printed wiring board, which comprises covering a periphery of a circuit substrate with a printing plate, and the present invention provides a method for producing a multilayer printed wiring board. A method for producing a multilayer printed wiring board in which a printing blanket is coated with a conductive paste on the circuit substrate and filled with a conductive paste in a conductive via of the circuit substrate, wherein the printing plate has a plan view. a frame portion having a large opening portion larger than the circuit substrate, and a small opening portion having a smaller opening than the circuit substrate in plan view And a resin edging portion disposed on a lower peripheral edge of the large opening portion, wherein the printing process includes positioning the frame portion and placing the circuit base such that the small opening portion covers a periphery of the circuit substrate Engineering of the material; coating the conductive paste on the circuit substrate through the small opening portion to fill the conductive paste in the conductive hole; and collecting the remaining conductive paste in the large opening portion Engineering on the side.

依據本構成,因為藉由以印刷橡皮輥接近於電路基材的狀態將導電糊塗勻俾得以使導電糊以高的印刷壓力填充於導通用孔,故抑制空隙的產生,可生產率佳地進行印刷工程。又,因印刷橡皮輥將小開口部內的導電糊誘導至鑲邊部,故導電性橡皮輥在電路基材上局部地殘留的情形受到抑制,可有效率地回收導電糊。再者,因接於電路基材的樹脂製鑲邊部無彎曲下平坦地與電路基材抵接而增大印刷版的耐久性,可穩定地進行印刷。 According to this configuration, since the conductive paste is uniformly applied in a state in which the printing rubber roller is close to the circuit substrate, the conductive paste is filled in the conductive hole with a high printing pressure, so that generation of voids is suppressed, and printing can be performed with high productivity. engineering. Further, since the conductive paste in the small opening portion is induced to the edging portion by the printing rubber roller, the conductive rubber roller is partially left on the circuit substrate, and the conductive paste can be efficiently recovered. Further, since the resin edging portion attached to the circuit substrate is flatly brought into contact with the circuit substrate without bending, the durability of the printing plate is increased, and printing can be stably performed.

請求項2所記載之發明提供如請求項1之多層印刷配線板之製造方法,其中前述框體部與前述鑲邊部係隔著黏貼部而被黏貼。 The invention of claim 2, wherein the frame portion and the rim portion are adhered to each other via the adhesive portion.

依據本構成,即使因鑲邊部隔著黏貼部被黏貼於框體部使鑲邊部損傷的情況,藉由將鑲邊部自框體部剝下作交換仍可沿用框體部,故而可減低印刷工程所需的成本。 According to this configuration, even if the rim portion is adhered to the frame portion via the adhesive portion via the adhesive portion, the rim portion can be removed by being peeled off from the frame portion, so that the frame portion can be used. Reduce the cost of printing engineering.

請求項3所記載之發明提供如請求項2之多層印刷配線板之製造方法,其中前述黏貼部係遍及全面將前述框體部與前述鑲邊部黏貼之雙面膠帶。 The invention of claim 3, wherein the adhesive portion is a double-sided tape in which the frame portion and the edging portion are adhered to each other in a comprehensive manner.

依據本構成,因依雙面膠帶的大小來確保框體部與鑲邊部之黏貼面積,故鑲邊部被強固地黏貼於框體部,故增大印刷版的耐久性,可穩定地進行印刷。 According to this configuration, since the adhesion area between the frame portion and the rim portion is ensured by the size of the double-sided tape, the edging portion is strongly adhered to the frame portion, so that the durability of the printing plate is increased, and the printing plate can be stably performed. print.

請求項4所記載之發明係提供如請求項2之多層印刷配線板之製造方法,其中前述黏貼部係用以黏貼前述鑲邊部的周緣與前述框體部的單面膠帶。 The invention of claim 4 is the method of manufacturing the multilayer printed wiring board according to claim 2, wherein the adhesive portion is a single-sided tape for adhering the peripheral edge of the edging portion to the frame portion.

依據本構成,因鑲邊部的周緣是隔著單面膠帶被黏貼於框體部,在交換鑲邊部之際鑲邊部容易被剝下,故可容易地交換鑲邊部。 According to this configuration, since the peripheral edge of the edging portion is adhered to the frame portion via the single-sided tape, the edging portion is easily peeled off when the edging portion is exchanged, so that the edging portion can be easily exchanged.

請求項5所記載之發明係提供如請求項1至4中任一項之多層印刷配線板之製造方法,其中前述框體部的厚度設定成0.5mm以上。 The invention according to claim 5, wherein the thickness of the frame portion is set to 0.5 mm or more.

依據本構成,藉由確保框體部的剛性,抑制在框體部的大開口部周邊產生彎曲,印刷版的耐久性增大,可穩定地進行印刷。 According to this configuration, by ensuring the rigidity of the frame portion, it is possible to suppress the occurrence of bending around the large opening portion of the frame portion, and the durability of the printing plate is increased, so that printing can be performed stably.

請求項6所記載之發明係提供如請求項1至5中任一項之多層印刷配線板之製造方法,其中前述鑲邊部的厚度被設定成0.1mm以下。 The invention of claim 6 is the method of manufacturing the multilayer printed wiring board according to any one of claims 1 to 5, wherein the thickness of the edging portion is set to be 0.1 mm or less.

依據本構成,因印刷橡皮輥與電路基材是因應鑲邊部的厚度而接近,故抑制在導通用孔內產生空隙,使印刷工程的生產率提升,並可有效率地回收剩餘的導電糊。 According to this configuration, since the printing rubber roller and the circuit substrate are close to each other in accordance with the thickness of the edging portion, it is possible to suppress the occurrence of voids in the conductive hole, improve the productivity of the printing process, and efficiently collect the remaining conductive paste.

請求項7所記載之發明係提供如請求項1至6中任一項之多層印刷配線板之製造方法,其中前述框 體為不鏽鋼或鋁製。 The invention of claim 7 is the method of manufacturing the multilayer printed wiring board according to any one of claims 1 to 6, wherein the aforementioned frame The body is made of stainless steel or aluminum.

依據本構成,藉由確保框體部的剛性,抑制在框體部的大開口部周邊產生彎曲,增大印刷版的耐久性,可穩定地進行印刷。 According to this configuration, by ensuring the rigidity of the frame portion, it is possible to suppress the occurrence of bending around the large opening portion of the frame portion, thereby increasing the durability of the printing plate, and printing can be stably performed.

請求項8所記載之發明係提供如請求項1至7中任一項之多層印刷配線板之製造方法,其中前述鑲邊部係由PET、PEN、聚醯亞胺或LCP構成。 The invention of claim 8, wherein the edging portion is made of PET, PEN, polyimide or LCP.

依據本構成,因可廉價地獲得鑲邊部,加工性優異且破損時的交換變容易,故可減低交換鑲邊部所需的成本。 According to this configuration, since the edging portion can be obtained at low cost, the workability is excellent and the exchange at the time of breakage is facilitated, so that the cost required to exchange the edging portion can be reduced.

請求項9所記載之發明係提供如請求項1至7中任一項之多層印刷配線板之製造方法,其中前述鑲邊部係將PET、PEN、聚醯亞胺或LCP疊層所構成。 The invention of claim 9, wherein the edging portion is formed by laminating PET, PEN, polyimide or LCP.

依據本構成,因可廉價地獲得鑲邊部,加工性優異且破損時的交換變容易,故可減低交換鑲邊部所需的成本。 According to this configuration, since the edging portion can be obtained at low cost, the workability is excellent and the exchange at the time of breakage is facilitated, so that the cost required to exchange the edging portion can be reduced.

〔發明效果〕 [effect of the invention]

本發明係導電糊被以高的印刷壓力填充於導通用孔,剩餘的導電糊被有效率地回收,印刷版可反覆利用,故而可廉價且有效率地製造多層印刷配線板。 In the present invention, the conductive paste is filled in the conductive hole with a high printing pressure, and the remaining conductive paste is efficiently recovered, and the printing plate can be reused, so that the multilayer printed wiring board can be manufactured inexpensively and efficiently.

10‧‧‧電路基材 10‧‧‧ circuit substrate

11‧‧‧可撓性絕緣基材 11‧‧‧Flexible insulating substrate

12‧‧‧銅箔 12‧‧‧ copper foil

13‧‧‧疊層用接著材 13‧‧‧Laminated laminate

14‧‧‧遮罩膜 14‧‧‧ Mask film

15‧‧‧導通用孔 15‧‧‧General purpose hole

20‧‧‧電路基材 20‧‧‧ circuit substrate

21‧‧‧可撓性絕緣基材 21‧‧‧Flexible insulating substrate

22‧‧‧銅箔 22‧‧‧ copper foil

23‧‧‧遮罩膜 23‧‧‧ Mask film

24‧‧‧導通用孔 24‧‧‧General purpose hole

30‧‧‧多層電路基材 30‧‧‧Multilayer circuit substrate

100‧‧‧印刷版 100‧‧‧Printed version

110‧‧‧框體部 110‧‧‧ Frame Department

110a‧‧‧大開口部 110a‧‧‧ Large opening

111‧‧‧版框 111‧‧‧ frame

112‧‧‧金屬板 112‧‧‧Metal plates

120‧‧‧鑲邊部 120‧‧‧Flange

120a‧‧‧小開口部 120a‧‧‧Small opening

130‧‧‧雙面膠帶(黏貼部) 130‧‧‧Double-sided tape (adhesive part)

131‧‧‧單面膠帶(黏貼部) 131‧‧‧Single-sided tape (adhesive part)

P‧‧‧導電糊 P‧‧‧Electric paste

S‧‧‧印刷橡皮輥 S‧‧‧Printing rubber roller

200‧‧‧金屬製印刷版 200‧‧‧Metal printing plate

210‧‧‧版框 210‧‧‧ frame

220‧‧‧金屬板 220‧‧‧Metal plates

220a‧‧‧開口部 220a‧‧‧ openings

300‧‧‧電路基材 300‧‧‧ circuit substrate

310‧‧‧導通用孔 310‧‧‧General purpose hole

w‧‧‧彎曲 W‧‧‧Bend

v‧‧‧空隙 V‧‧‧ gap

pa‧‧‧圖案 Pa‧‧‧ pattern

[圖1]係顯示本發明一實施例的多層印刷配線板之製造方法的程序之一部份的示意圖,(a)係顯示電路基材,(b)係顯示在電路基材形成導通用孔之狀態,(c)係顯示在導 通用孔內填充了導電糊之狀態。 1 is a schematic view showing a part of a procedure of a method of manufacturing a multilayer printed wiring board according to an embodiment of the present invention, wherein (a) shows a circuit substrate, and (b) shows a conductive hole formed on a circuit substrate. State, (c) is shown in the guide The general hole is filled with the state of the conductive paste.

[圖2]係顯示本發明一實施例的多層印刷配線板之製造方法的程序之一部份的示意圖,(a)係顯示電路基材,(b)係顯示在電路基材形成導通用孔之狀態,(c)係顯示在導通用孔內填充了導電糊之狀態。 2] FIG. 2 is a schematic view showing a part of a procedure of a method of manufacturing a multilayer printed wiring board according to an embodiment of the present invention, wherein (a) is a display circuit substrate, and (b) is a conductive hole formed on a circuit substrate. In the state, (c) shows a state in which the conductive paste is filled in the conductive hole.

[圖3]係顯示本發明一實施例的多層印刷配線板之製造方法的程序之一部份,(a)係顯示將圖1(c)所獲得之電路基材與圖2(c)所獲得之電路基材進行接著前之狀態,(b)係顯示已將電路基材疊層之狀態,(c)係顯示在電路基材的雙面形成圖案之狀態。 3 is a part showing a procedure of a method of manufacturing a multilayer printed wiring board according to an embodiment of the present invention, and (a) shows a circuit substrate obtained in FIG. 1(c) and FIG. 2(c). The obtained circuit substrate is in a state before the next step, (b) shows a state in which the circuit substrate has been laminated, and (c) shows a state in which a pattern is formed on both surfaces of the circuit substrate.

[圖4]係顯示在本發明的多層印刷配線板之製造方法所用的印刷版,(a)係印刷版的平面圖,(b)係圖4(a)的IV-IV線端面圖。 Fig. 4 is a plan view showing a printing plate used in the method for producing a multilayer printed wiring board of the present invention, (a) is a plan view of the printing plate, and (b) is a line end view taken along line IV-IV of Fig. 4(a).

[圖5]係顯示在本發明的多層印刷配線板之製造方法所用的印刷版的變形例,(a)係印刷版的平面圖,(b)係圖5(a)的V-V線端面圖。 Fig. 5 is a view showing a modification of the printing plate used in the method for producing a multilayer printed wiring board of the present invention, wherein (a) is a plan view of the printing plate, and (b) is a V-V line end view of Fig. 5 (a).

[圖6]係顯示印刷工程之示意圖,(a)係顯示在電路基材載放印刷版之狀態,(b)係顯示以印刷橡皮輥將導電糊塗勻前之狀態,(c)係顯示以印刷橡皮輥將導電糊塗勻的狀態,(d)係顯示匯集剩餘的導電糊之狀態。 [Fig. 6] is a schematic view showing a printing process, (a) showing a state in which a printed board is placed on a circuit substrate, (b) showing a state in which a conductive paste is applied by a printing rubber roller, and (c) showing The printing rubber roller is in a state where the conductive paste is evenly coated, and (d) is a state in which the remaining conductive paste is collected.

[圖7]係顯示在習知的多層印刷配線板之製造方法所用的印刷版,(a)係印刷版的平面圖,(b)係圖7(a)中的VIIB-VIIB線端面圖,(c)係圖7(b)中的VIIC部放大圖。 Fig. 7 is a plan view showing a printing plate used in a conventional method for manufacturing a multilayer printed wiring board, (a) a plan view of a printing plate, and (b) a line view of line VIIB-VIIB in Fig. 7(a), ( c) is an enlarged view of the VIIC portion in Fig. 7(b).

[圖8]係顯示在習知的多層印刷配線板之製造方法所用的印刷版,(a)係印刷版的平面圖,(b)係圖8(a)的 VIIIB-VIIIB線端面圖,(c)係圖8(a)中的VIIIC-VIIIC線端面圖。 8 is a plan view showing a printing plate used in a conventional method for manufacturing a multilayer printed wiring board, (a) a plan view of a printing plate, and (b) a drawing of FIG. 8(a). VIIIB-VIIIB line end view, (c) is the end view of line VIIIC-VIIIC in Fig. 8(a).

本發明的多層印刷配線板之製造方法為達成廉價且有效率地製造多層印刷配線板之目的,係按以下方式來實現,即一種多層印刷配線板之製造方法,係包含將電路基材的周緣以印刷版覆蓋,以印刷橡皮輥在前述電路基材上塗勻導電糊而在前述電路基材的導通孔填充前述導電糊之印刷工程的多層印刷配線板之製造方法,其特徵為:前述印刷版係具備在俯視觀之具有比前述電路基材大的大開口部之框體部、及在俯視觀之具有比前述電路基材小的小開口部且配置在前述大開口部的下方周緣之樹脂製的鑲邊部,前述印刷工程係包含:以前述小開口部覆蓋前述電路基材的周緣之方式將前述框體部定位並載置前述電路基材上之工程;透過前述小開口部將前述導電糊塗勻於前述電路基材上而在前述導通用孔填充前述導電糊之工程;及在前述大開口部內將剩餘的前述導電糊匯集在前述鑲邊部上之工程。 The method for producing a multilayer printed wiring board of the present invention is achieved in order to achieve a low-cost and efficient production of a multilayer printed wiring board, which is achieved in a method of manufacturing a multilayer printed wiring board including a peripheral edge of a circuit substrate. A method for manufacturing a multilayer printed wiring board in which a conductive paste is coated on a printed circuit board and a conductive paste is coated on the circuit substrate to fill a conductive hole of the conductive substrate with a printing blanket, and the printing plate is coated with a printing plate. A frame body having a large opening portion larger than the circuit substrate in plan view, and a resin having a small opening portion smaller than the circuit substrate in a plan view and disposed on a lower peripheral edge of the large opening portion In the edging portion, the printing system includes a process of positioning and placing the frame portion on the circuit substrate so that the small opening portion covers the periphery of the circuit substrate; and transmitting the a conductive paste is applied to the circuit substrate to fill the conductive paste in the conductive hole; and the remaining front portion is in the large opening portion Pooling the works in the conductive paste portions of the trim.

〔實施例〕 [Examples]

以下,針對本發明一實施例的多層印刷配線板之製造方法,依據圖面作說明。 Hereinafter, a method of manufacturing a multilayer printed wiring board according to an embodiment of the present invention will be described with reference to the drawings.

首先,準備一對電路基材10、20。如圖1(a)所示,一方的電路基材10具備:可撓性絕緣基材11;被覆可撓性絕緣基材11的一側面之銅箔12;及被覆可撓性絕緣基材11的另一側面之疊層用接著材13及遮罩膜14。 First, a pair of circuit substrates 10, 20 are prepared. As shown in FIG. 1(a), one of the circuit substrates 10 includes a flexible insulating substrate 11; a copper foil 12 covering one side of the flexible insulating substrate 11; and a coated flexible insulating substrate 11 The laminate 13 and the mask film 14 are laminated on the other side.

可撓性絕緣基材11係厚度50μm的LCP製。又,銅箔12的厚度係設定成12μm。又,疊層用接著材13係厚度15μm的環氧系接著材。遮罩膜14係厚度20μm的PET(polyethylene terephthalate;聚對苯二甲酸乙二酯)製。遮罩膜14係於形成後述的導通用孔15之際在導通用孔15的上部形成透過導電糊的孔,被用作為印刷工程中的印刷遮罩。 The flexible insulating base material 11 is made of LCP having a thickness of 50 μm. Further, the thickness of the copper foil 12 was set to 12 μm. Moreover, the laminated adhesive material 13 is an epoxy-based adhesive material having a thickness of 15 μm. The mask film 14 is made of PET (polyethylene terephthalate) having a thickness of 20 μm. The mask film 14 is formed as a printing mask in a printing process by forming a hole through which the conductive paste is formed in the upper portion of the conductive hole 15 when forming the conductive hole 15 to be described later.

其次,如圖1(b)所示,在電路基材10進行雷射加工、去膠渣處理以形成導通用孔15。雷射加工係例如使用生產性高的碳酸氣雷射較佳。 Next, as shown in FIG. 1(b), the circuit substrate 10 is subjected to laser processing and desmearing to form a conductive hole 15. Laser processing is preferably performed using, for example, a highly productive carbon dioxide laser.

其次,如圖1(c)所示,經過使用了後述的印刷版之印刷工程,將導電糊P填充於導通用孔15內。此處,導電糊P係於環氧等之樹脂黏著劑混合了銅粒子或銀粒子等之金屬粒子而成者。藉由遮罩膜14被覆電路基材10的表面,避免成為短路不良的要因之導電糊P附著於疊層用接著材13的表面,可將導電糊P填充於導通用孔15。 Next, as shown in FIG. 1(c), the conductive paste P is filled in the conductive hole 15 through a printing process using a printing plate to be described later. Here, the conductive paste P is obtained by mixing metal particles such as copper particles or silver particles with a resin adhesive such as epoxy. The surface of the circuit substrate 10 is covered with the mask film 14 to prevent the conductive paste P from adhering to the surface of the laminate material 13 for the short-circuit defect, and the conductive paste P can be filled in the conductive hole 15.

如圖2(a)所示,另一電路基材20具備:可撓性絕緣基材21;被覆可撓性絕緣基材21的一側面之銅箔22;及被覆可撓性絕緣基材21的另一側面之遮罩膜23。可撓性絕緣基材21係與上述的可撓性絕緣基材11相同,銅箔22係與上述的銅箔12相同。 As shown in FIG. 2(a), the other circuit substrate 20 includes a flexible insulating substrate 21, a copper foil 22 covering one side of the flexible insulating substrate 21, and a coated flexible insulating substrate 21. The mask film 23 on the other side. The flexible insulating base material 21 is the same as the above-described flexible insulating base material 11, and the copper foil 22 is the same as the above-described copper foil 12.

遮罩膜23係18μm的PET製,隔著厚度7μm的未圖示的易剝離性接著材被接著於可撓性絕緣基材21。遮罩膜23係於形成後述的導通用孔24之際在導通 用孔24的上部形成透過導電糊的孔而被用作為印刷工程中的印刷遮罩。 The mask film 23 is made of PET of 18 μm, and is adhered to the flexible insulating base material 21 via a non-peelable adhesive material (not shown) having a thickness of 7 μm. The mask film 23 is turned on when forming the conductive hole 24 to be described later. The upper portion of the hole 24 is formed to pass through the hole of the conductive paste and is used as a printing mask in a printing process.

其次,如圖2(b)所示,在電路基材20進行雷射加工、去膠渣處理以形成導通用孔24。雷射加工係例如使用生產性高的碳酸氣雷射較佳。 Next, as shown in FIG. 2(b), the circuit substrate 20 is subjected to laser processing and desmearing to form a conductive hole 24. Laser processing is preferably performed using, for example, a highly productive carbon dioxide laser.

其次,圖2(c)所示,經過使用了後述的印刷版之印刷工程,將導電糊P填充於導通用孔24內。 Next, as shown in FIG. 2(c), the conductive paste P is filled in the conductive hole 24 through a printing process using a printing plate to be described later.

此外,上述的可撓性絕緣基材11、21可因應用途而適宜變更厚度、材料。例如,薄型基板所用的可撓性基材可考慮選擇厚度12μm的聚醯亞胺製。又,銅箔12、22的厚度不受限於上述的厚度,亦可因應於銅配線的圖案寬度而選擇例如9μm等之較薄尺寸者。又,疊層用接著材13的厚度係可因應用途作變更,例如,薄型基板所用的疊層用接著材可選擇厚度10μm等之薄尺寸者。再者,遮罩膜14、23的厚度可因應用途作變更,由於會影響印刷後所形成之傳導性糊高度,故在欲抑制疊層後的導電糊P流出的情況,為降低傳導性糊高度,可選擇厚度16μm等之薄尺寸者。 Further, the above-described flexible insulating base materials 11 and 21 can be appropriately changed in thickness and material depending on the application. For example, a flexible substrate for a thin substrate can be selected from a polyimide having a thickness of 12 μm. Further, the thickness of the copper foils 12 and 22 is not limited to the above-described thickness, and a thinner size such as 9 μm may be selected depending on the pattern width of the copper wiring. In addition, the thickness of the laminated material for lamination 13 can be changed depending on the application. For example, the laminate for lamination of a thin substrate can be selected to have a thickness of 10 μm or the like. Further, the thickness of the mask films 14 and 23 can be changed depending on the application, and the conductive paste height formed after printing is affected. Therefore, in order to suppress the outflow of the conductive paste P after lamination, the conductive paste is lowered. The height can be selected from thinner thicknesses such as 16 μm.

在將一對電路基材10、20疊層之際,首先,除去遮罩膜14、23。藉此,殘存於遮罩膜14、23上的導電糊P被剝離,以抑制導電糊P附著於疊層用接著材13。 When the pair of circuit substrates 10 and 20 are laminated, first, the mask films 14 and 23 are removed. Thereby, the conductive paste P remaining on the mask films 14 and 23 is peeled off, and the adhesion of the conductive paste P to the laminated adhesive 13 is suppressed.

而且,如圖3(a)所示,以導電糊P、P呈對向之方式定位電路基材10、20。其次,如圖3(b)所示,藉由一對電路基材10、20以隔著疊層用接著材13被真空壓機等進行黏貼而能獲得多層電路基材30。然後,如圖3(c) 所示,透過一般的感光蝕刻加工手法將圖案pa形成在多層電路基材30的雙面。之後,視需要在基板表面上施予銲料鍍敷、鍍鎳、鍍金等之表面處理,透過進行阻焊劑(photo solder resist)層之形成、外形加工而可獲得多層印刷配線板。 Further, as shown in FIG. 3(a), the circuit substrates 10 and 20 are positioned such that the conductive pastes P and P face each other. Then, as shown in FIG. 3(b), the multilayer circuit substrate 30 can be obtained by adhering a pair of circuit substrates 10 and 20 with a vacuum press or the like via the laminate 13 for lamination. Then, as shown in Figure 3(c) As shown, the pattern pa is formed on both sides of the multilayer circuit substrate 30 by a general photosensitive etching process. Thereafter, a surface treatment such as solder plating, nickel plating, or gold plating is applied to the surface of the substrate as needed, and a multilayer solder printed wiring board is obtained by performing formation of a photo solder resist layer and external shape processing.

其次,針對在印刷工程使用的印刷版作說明。此外,以下,雖以電路基材10為例作說明,但當然針對電路基材20亦是同樣。 Next, the printing plate used in the printing project will be described. In the following description, the circuit substrate 10 will be described as an example, but of course, the same applies to the circuit substrate 20.

如圖4(a)、(b)所示,印刷版100係具備具有大開口部110a的框體部110、及配置在開口部110a的下方周緣之鑲邊部120。 As shown in FIGS. 4(a) and 4(b), the printing plate 100 includes a frame portion 110 having a large opening portion 110a and a rim portion 120 disposed on a lower peripheral edge of the opening portion 110a.

框體部110係具備版框111、及形成有大開口部110a的金屬板112。大開口部110a在俯視觀之係形成比電路基材10大。本實施例中,大開口部110a設定成寬度340mm、長度390mm。 The frame portion 110 includes a frame 111 and a metal plate 112 on which the large opening portion 110a is formed. The large opening portion 110a is formed larger than the circuit substrate 10 in a plan view. In the present embodiment, the large opening portion 110a is set to have a width of 340 mm and a length of 390 mm.

金屬板112的厚度係以設定成0.5mm以上較佳,本實施例中設定成2mm。藉此,可一邊確保大開口部110a的大小一邊抑制金屬板112的彎曲。金屬板112的材質只要具有在形成有大開口部110a的狀態不產生彎曲的程度之剛性即可,例如,以不鏽鋼、鋁等較佳。本實施例中,金屬板112為不鏽鋼製。此外,金屬板112的厚度、材質分別不受限於2mm、不鏽鋼,係在可抑制金屬板112的彎曲之範圍內因應版框111、開口部110a的大小作適宜選擇者。 The thickness of the metal plate 112 is preferably set to 0.5 mm or more, and is set to 2 mm in this embodiment. Thereby, it is possible to suppress the bending of the metal plate 112 while securing the size of the large opening portion 110a. The material of the metal plate 112 may have rigidity such that it does not bend in a state in which the large opening portion 110a is formed. For example, stainless steel, aluminum, or the like is preferable. In the present embodiment, the metal plate 112 is made of stainless steel. Further, the thickness and material of the metal plate 112 are not limited to 2 mm and stainless steel, respectively, and the size of the frame 111 and the opening 110a can be appropriately selected within a range in which the bending of the metal plate 112 can be suppressed.

在俯視觀之,鑲邊部120係具備比電路基 材10小的小開口部120a。小開口部120a係藉由雷射加工等而被形成為寬度240mm、長度290mm。 In a plan view, the edging portion 120 has a specific circuit base The small opening portion 120a of the material 10 is small. The small opening portion 120a is formed to have a width of 240 mm and a length of 290 mm by laser processing or the like.

鑲邊部120的厚度係以設定在0.1mm以下較佳,本實施例中設定成0.1mm。因此,印刷橡皮輥被以與電路基材10接近的狀態配置。鑲邊部120的材質係以對導電糊P具有耐溶劑性且比要使用的橡皮輥還柔軟的材料較佳,本實施例中為PET製。例如,在使用聚氨基甲酸酯橡皮輥作為印刷橡皮輥的情況,單獨使用0.1mm厚的PET、PEN(聚萘二甲酸乙二醇酯;polyethylene naphthalate)、聚醯亞胺、LCP等,或使用該等當中至少2個以上的樹脂疊層者亦無妨。這樣的鑲邊部120與金屬板112相較下因廉價且加工性優異,故在破損時可容易進行交換。 The thickness of the edging portion 120 is preferably set to 0.1 mm or less, and is set to 0.1 mm in this embodiment. Therefore, the printing blanket roller is disposed in a state close to the circuit substrate 10. The material of the edging portion 120 is preferably a material which is solvent-resistant to the conductive paste P and softer than the rubber roller to be used, and is made of PET in this embodiment. For example, in the case of using a polyurethane rubber roller as a printing rubber roller, 0.1 mm thick PET, PEN (polyethylene naphthalate), polyimine, LCP, etc., or It is also possible to use at least two or more resin laminates among these. Such a rim portion 120 is inexpensive and has excellent workability as compared with the metal plate 112, so that it can be easily exchanged at the time of breakage.

鑲邊部120係藉由雙面膠帶130被黏貼於框體110。鑲邊部120係因應於鑲邊部120與雙面膠帶130之黏貼面積而被強固地黏貼。因此,即使是鑲邊部120損傷的情況,透過僅交換鑲邊部120,可反覆使用印刷版100。 The edging portion 120 is adhered to the frame body 110 by the double-sided tape 130. The edging portion 120 is strongly adhered to the affixing area of the edging portion 120 and the double-sided tape 130. Therefore, even if the edging portion 120 is damaged, the printing plate 100 can be used repeatedly by exchanging only the edging portion 120.

此外,如圖5(a)、(b)所示,黏貼部亦可為將鑲邊部120的周緣黏貼於框體部110之單面膠帶131。因此,在交換鑲邊部120時,可容易將鑲邊部120從框體部110卸下。此外,單面膠帶131係以選擇比電路基材薄者較佳。本實施例中,單面膠帶係厚度60μm的聚醯亞胺製。 Further, as shown in FIGS. 5( a ) and 5 ( b ), the adhesive portion may be a single-sided tape 131 that adheres the peripheral edge of the edging portion 120 to the frame portion 110 . Therefore, when the edging portion 120 is exchanged, the edging portion 120 can be easily detached from the frame portion 110. Further, the single-sided tape 131 is preferably selected to be thinner than the circuit substrate. In the present embodiment, the single-sided tape was made of polyimide having a thickness of 60 μm.

其次,針對使用印刷版100的印刷工程作說明。首先,電路基材10係以導通用孔15在上方開口的 方式載置於未圖示的夾盤上,被真空吸附於該夾盤而固定。之後,如圖6(a)所示,使印刷版100被載於電路基材10上。當印刷版100被定位於電路基材10上的既定位置時,大開口部110a被配置成圍繞電路基材10,小開口部120a被配置成覆蓋電路基材10的周緣。藉此,電路基材10的導通用孔15係透過開口部110a、開口部120a而露出於外部。 Next, a description will be given of a printing process using the printing plate 100. First, the circuit substrate 10 is opened above the conductive hole 15 The method is placed on a chuck (not shown) and is vacuum-adsorbed to the chuck to be fixed. Thereafter, as shown in FIG. 6(a), the printing plate 100 is placed on the circuit substrate 10. When the printing plate 100 is positioned at a predetermined position on the circuit substrate 10, the large opening portion 110a is disposed to surround the circuit substrate 10, and the small opening portion 120a is configured to cover the periphery of the circuit substrate 10. Thereby, the conductive hole 15 of the circuit substrate 10 is exposed to the outside through the opening 110a and the opening 120a.

藉由導電糊P被投入開口部110a內,印刷橡皮輥S一邊將導電糊P塗勻於電路基材10上一邊從大開口部110a的一端朝另一端移動,使導電糊P被填充於印刷版100的導通用孔15。藉由將鑲邊部120形成較薄且使印刷橡皮輥S與電路基材10接近,俾讓導電糊P以適切的印刷壓力填充於導通用孔15。 The conductive paste P is placed in the opening 110a, and the printing blanket S is moved from the one end of the large opening portion 110a toward the other end while the conductive paste P is applied to the circuit substrate 10, so that the conductive paste P is filled in the printing. The guide hole 15 of the plate 100. By forming the edging portion 120 thin and bringing the printing squeegee S into contact with the circuit substrate 10, the conductive paste P is filled in the conductive hole 15 with an appropriate printing pressure.

如圖6(d)所示,當印刷橡皮輥S移動到大開口部110a的另一端時,剩餘的導電糊P被匯集於鑲邊部120上。此時,在鑲邊部120形成較薄且印刷橡皮輥S與電路基材10接近的狀態將導電糊P塗勻,俾抑制剩餘的導電糊P在電路基材10上局部地囤積。 As shown in FIG. 6(d), when the printing blanket roller S moves to the other end of the large opening portion 110a, the remaining conductive paste P is collected on the edging portion 120. At this time, the conductive paste P is evenly coated in a state where the edging portion 120 is formed thin and the printing blanket roller S is close to the circuit substrate 10, and the remaining conductive paste P is locally accumulated on the circuit substrate 10.

又,在將導電糊P填充於導通用孔15後,可透過使用比橡皮輥硬的未圖示之刮刀進一步除去殘留於電路基材10上的導電糊P。具體言之,使刮刀從開口部110a的另一端朝一端移動,將殘留於電路基材10的遮罩膜14的表面之導電糊P削去,能確實地回收剩餘的導電糊P。 Further, after the conductive paste P is filled in the conductive hole 15, the conductive paste P remaining on the circuit substrate 10 can be further removed by using a doctor blade (not shown) which is harder than the rubber roller. Specifically, the blade is moved from the other end of the opening 110a toward the one end, and the conductive paste P remaining on the surface of the mask film 14 of the circuit substrate 10 is scraped off, whereby the remaining conductive paste P can be reliably recovered.

如此,本發明的多層印刷配線板之製造方 法係透過在印刷橡皮輥接近於電路基材10的狀態下塗勻導電糊P,俾使導電糊P被以高的印刷壓力填充於導通用孔15,故抑制空隙的產生,可生產率佳地進行印刷工程。又,由於導電糊P在電路基材10上局部地殘留的情形受到抑制,故可有效率地回收導電糊P。而且,藉由與電路基材10接觸的樹脂製之鑲邊部120無彎曲地維持平坦抵接於電路基材10,可穩定地進行印刷。因此,可廉價且有效率地製造多層印刷配線板。 Thus, the manufacturer of the multilayer printed wiring board of the present invention By coating the conductive paste P in a state where the printing rubber roller is close to the circuit substrate 10, the conductive paste P is filled in the conductive hole 15 with a high printing pressure, so that generation of voids is suppressed, and productivity can be performed with good productivity. Printing engineering. Further, since the conductive paste P is partially left on the circuit substrate 10, the conductive paste P can be efficiently recovered. In addition, the resin-made edging portion 120 that is in contact with the circuit substrate 10 is maintained in a flat manner against the circuit substrate 10 without bending, so that printing can be stably performed. Therefore, the multilayer printed wiring board can be manufactured inexpensively and efficiently.

此外,本發明係可在不悖離本發明的精神下作各種改變,且本發明當然可及於該改變者 Further, the present invention can be variously changed without departing from the spirit of the invention, and the invention can of course be adapted to the changer.

10‧‧‧電路基材 10‧‧‧ circuit substrate

100‧‧‧印刷版 100‧‧‧Printed version

110‧‧‧框體部 110‧‧‧ Frame Department

110a‧‧‧大開口部 110a‧‧‧ Large opening

111‧‧‧版框 111‧‧‧ frame

112‧‧‧金屬板 112‧‧‧Metal plates

120‧‧‧鑲邊部 120‧‧‧Flange

120a‧‧‧小開口部 120a‧‧‧Small opening

130‧‧‧雙面膠帶(黏貼部) 130‧‧‧Double-sided tape (adhesive part)

Claims (9)

一種多層印刷配線板之製造方法,係包含將電路基材的周緣以印刷版覆蓋,以印刷橡皮輥在前述電路基材上塗勻導電糊而在前述電路基材的導通孔填充前述導電糊之印刷工程的多層印刷配線板之製造方法,其特徵為:前述印刷版係具備在俯視觀之具有比前述電路基材大的大開口部之框體部、及在俯視觀之具有比前述電路基材小的小開口部且配置在前述大開口部的下方周緣之樹脂製的鑲邊部,前述印刷工程係包含:以前述小開口部覆蓋前述電路基材的周緣之方式將前述框體部定位並載置前述電路基材上之工程;透過前述小開口部將前述導電糊塗勻於前述電路基材上而在前述導通用孔填充前述導電糊之工程;及在前述大開口部內將剩餘的前述導電糊匯集在前述鑲邊部上之工程。 A method for manufacturing a multilayer printed wiring board comprises covering a periphery of a circuit substrate with a printing plate, coating a conductive paste on the circuit substrate with a printing rubber roller, and filling the conductive paste with a conductive hole of the circuit substrate. In the method of manufacturing a multilayer printed wiring board according to the aspect of the invention, the printing plate includes a frame portion having a large opening portion larger than the circuit substrate in a plan view, and a circuit substrate in a plan view. a small small opening portion is disposed in a resin edging portion on a lower peripheral edge of the large opening portion, and the printing process includes positioning the frame portion so that the small opening portion covers a periphery of the circuit substrate a process of mounting the circuit substrate; applying the conductive paste to the circuit substrate through the small opening portion to fill the conductive paste in the conductive hole; and leaving the conductive portion in the large opening portion The paste is collected on the aforementioned edging section. 如請求項1之多層印刷配線板之製造方法,其中前述框體部與前述鑲邊部係隔著黏貼部而被黏貼。 The method of manufacturing a multilayer printed wiring board according to claim 1, wherein the frame portion and the rim portion are adhered via an adhesive portion. 如請求項2之多層印刷配線板之製造方法,其中前述黏貼部係遍及全面用以將前述框體部與前述鑲邊部黏貼之雙面膠帶。 The method of manufacturing a multilayer printed wiring board according to claim 2, wherein the adhesive portion is a double-sided tape that is used to adhere the frame portion to the flange portion. 如請求項2之多層印刷配線板之製造方法,其中前述黏貼部係用以黏貼前述鑲邊部的周緣與前述框體部的單面膠帶。 The method of manufacturing a multilayer printed wiring board according to claim 2, wherein the adhesive portion is a single-sided tape for adhering the peripheral edge of the edging portion to the frame portion. 如請求項1之多層印刷配線板之製造方法,其中前述框體部的厚度係設定成0.5mm以上。 The method of manufacturing a multilayer printed wiring board according to claim 1, wherein the thickness of the frame portion is set to 0.5 mm or more. 如請求項1之多層印刷配線板之製造方法,其中前述鑲邊部的厚度係設定成0.1mm以下。 The method of manufacturing a multilayer printed wiring board according to claim 1, wherein the thickness of the edging portion is set to be 0.1 mm or less. 如請求項1之多層印刷配線板之製造方法,其中前述框體部係不鏽鋼或鋁製。 The method of manufacturing a multilayer printed wiring board according to claim 1, wherein the frame portion is made of stainless steel or aluminum. 如請求項1之多層印刷配線板之製造方法,其中前述鑲邊部係由PET、PEN、聚醯亞胺或LCP所構成。 The method of producing a multilayer printed wiring board according to claim 1, wherein the edging portion is composed of PET, PEN, polyimine or LCP. 如請求項1之多層印刷配線板之製造方法,其中前述鑲邊部係由PET、PEN、聚醯亞胺或LCP疊層所構成。 The method of manufacturing a multilayer printed wiring board according to claim 1, wherein the edging portion is composed of a PET, a PEN, a polyimide or an LCP laminate.
TW104108179A 2014-07-23 2015-03-13 Multilayer printed wiring board manufacturing method TWI608778B (en)

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