TW201600541A - Method of converting waste into slag forming agent and flux - Google Patents

Method of converting waste into slag forming agent and flux Download PDF

Info

Publication number
TW201600541A
TW201600541A TW103122541A TW103122541A TW201600541A TW 201600541 A TW201600541 A TW 201600541A TW 103122541 A TW103122541 A TW 103122541A TW 103122541 A TW103122541 A TW 103122541A TW 201600541 A TW201600541 A TW 201600541A
Authority
TW
Taiwan
Prior art keywords
waste
carbon black
agent
flux
forming agent
Prior art date
Application number
TW103122541A
Other languages
Chinese (zh)
Other versions
TWI504644B (en
Inventor
zhong-he Li
Original Assignee
Jinzan Environmental Prot Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jinzan Environmental Prot Technology Co Ltd filed Critical Jinzan Environmental Prot Technology Co Ltd
Priority to TW103122541A priority Critical patent/TW201600541A/en
Application granted granted Critical
Publication of TWI504644B publication Critical patent/TWI504644B/zh
Publication of TW201600541A publication Critical patent/TW201600541A/en

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Landscapes

  • Processing Of Solid Wastes (AREA)

Abstract

A method of converting waste into slag forming agent and flux comprises: a cracking step for burning waste in a vacuum environment to crack the waste into carbon blacks; a screening step for using a screen to screen the particle size of the carbon blacks; a magnetic selection step for magnetically adsorbing partial metal slag in the carbon blacks; and an analysis step for confirming that the percentage of fixed carbon in the carbon blacks is above 70% and useful as slag forming agent and flux. Wastes such as waste wheels, plastics, rubbers and the like can be cracked to produce carbon blacks, which may be subjected to the above-described process to allow regeneration and reuse for replacing slag forming agent and flux used in the steelmaking process, thereby thoroughly fulfilling the ideals of environment protection.

Description

將廢棄物製成造渣劑及助熔劑之方法 Method for making waste into slag forming agent and fluxing agent

本發明是有關於一種製成造渣劑及助熔劑之方法,特別是指一種將廢棄物製成造渣劑及助熔劑之方法。 The invention relates to a method for preparing a slagging agent and a fluxing agent, in particular to a method for preparing waste into a slagging agent and a fluxing agent.

人類在日常生活中會產生相當多種類的廢棄物,為了避免讓廢棄物大量堆放而佔據土地,通常會將廢棄物進行焚化、掩埋的處理,或者是經過其他處理而使廢棄物轉換為可再生利用的物質,藉此落實環保的理念,也能促進經濟發展。 Humans produce a wide variety of wastes in their daily lives. In order to avoid occupying large amounts of waste and occupying land, wastes are usually incinerated, buried, or otherwise processed to convert waste into renewable. The use of substances to implement the concept of environmental protection can also promote economic development.

其中,在廢輪胎、塑膠、橡膠的處理上,通常是以裂解方式處理,提煉生產生質油料。在裂解製程中,會伴隨產生碳黑,由於目前並無將所述碳黑妥善利用的途徑,必須將產生的碳黑另行處理而排放或者丟棄,不但對廠商增加多餘負擔,也使原本回收廢棄物而處理再利用的環保概念無法徹底落實,排放或者丟棄的碳黑也難免會對環境造成不良影響。因此,相關領域從事者無不費心研究將所述碳黑妥善處理或者再生利用的方法。 Among them, in the treatment of waste tires, plastics and rubber, it is usually treated by cracking to refine the raw oil. In the cracking process, carbon black is produced. Since there is no way to properly use the carbon black, the carbon black produced must be disposed of separately or discharged, which not only adds unnecessary burden to the manufacturer, but also wastes the original waste. The environmental concept of recycling and recycling of materials cannot be completely implemented, and carbon black emitted or discarded will inevitably have adverse effects on the environment. Therefore, practitioners in related fields have no trouble to study the method of properly treating or recycling the carbon black.

因此,本發明之目的,即在提供一種能妥善利用廢棄物裂解所產生之碳黑的將廢棄物製成造渣劑及助熔 劑之方法。 Therefore, the object of the present invention is to provide a slag forming agent and a fluxing agent which can properly utilize the carbon black generated by waste cracking. Method of the agent.

於是,本發明將廢棄物製成造渣劑及助熔劑之方法,包含一裂解步驟、一過篩步驟、一磁選步驟,及一分析步驟。 Thus, the method of the invention for making waste into a slagging agent and a flux comprises a cracking step, a screening step, a magnetic separation step, and an analysis step.

該裂解步驟是將廢棄物在真空環境下燃燒,使廢棄物裂解產生碳黑。 The cracking step is to burn the waste in a vacuum environment to crack the waste to produce carbon black.

該過篩步驟是以篩網針對碳黑的粒徑進行篩選,得到粒徑為特定尺寸以下的碳黑顆粒。 The sieving step is to screen the particle size of the carbon black by a sieve to obtain carbon black particles having a particle size of a specific size or less.

該磁選步驟是以磁力吸附碳黑中的部分金屬殘渣,排除碳黑中不需要的金屬成分。 The magnetic separation step is to magnetically adsorb a part of the metal residue in the carbon black to exclude unnecessary metal components in the carbon black.

該分析步驟是確認該碳黑中的固定碳在70%以上,並當作煉鋼製程中所需的造渣劑及助熔劑使用。 The analysis step is to confirm that the fixed carbon in the carbon black is above 70%, and is used as a slag forming agent and a flux required in the steel making process.

本發明之功效在於:將廢棄物在真空環境下燃燒使其裂解,所產生的碳黑在經過該過篩步驟及該磁選步驟後,經分析確認固定碳成分在70%以上後,能當作造渣劑及助熔劑而供煉鋼製程中使用。 The effect of the invention is that the waste is burned in a vacuum environment to be cracked, and the generated carbon black can be regarded as a build after confirming that the fixed carbon component is above 70% after passing through the screening step and the magnetic separation step. The slag and flux are used in the steel making process.

11‧‧‧裂解步驟 11‧‧‧Cleaning step

12‧‧‧過篩步驟 12‧‧‧ screening step

13‧‧‧磁選步驟 13‧‧‧Magnetic selection steps

14‧‧‧分析步驟 14‧‧‧Analysis steps

102‧‧‧細篩步驟 102‧‧‧ fine screening steps

103‧‧‧再磁選步驟 103‧‧‧Re-magnetic separation step

本發明之其他的特徵及功效,將於參照圖式的實施方式中清楚地呈現,其中:圖1是一流程圖,說明本發明將廢棄物製成造渣劑及助熔劑之方法的較佳實施例。 Other features and effects of the present invention will be apparent from the following description of the drawings. FIG. 1 is a flow chart illustrating a preferred method of the invention for making waste into a slagging agent and a fluxing agent. Example.

參閱圖1,本發明將廢棄物製成造渣劑及助熔劑 之方法的較佳實施例包含一裂解步驟11、一過篩步驟12、一磁選步驟13、一細篩步驟102、一再磁選步驟103,及一分析步驟14。 Referring to Figure 1, the present invention uses waste as a slag forming agent and a fluxing agent. A preferred embodiment of the method includes a cracking step 11, a screening step 12, a magnetic separation step 13, a fine screening step 102, a re-magnetic separation step 103, and an analysis step 14.

該裂解步驟11是將廢棄物在真空環境下燃燒,使廢棄物裂解產生碳黑。在真空環境下燃燒,由於未與氧氣接觸,能維持物質的熱值,避免完全燃燒而讓所需成分氧化,使得燃燒過後的產物無法再做他用。其中,在該裂解步驟11中是以500℃至900℃範圍的溫度進行燃燒。 The cracking step 11 is to burn the waste in a vacuum environment to cleave the waste to produce carbon black. Combustion in a vacuum environment, because it is not in contact with oxygen, can maintain the calorific value of the substance, avoid complete combustion and oxidize the desired components, so that the burned product can no longer be used for other purposes. Among them, in the cracking step 11, the combustion is carried out at a temperature ranging from 500 °C to 900 °C.

該過篩步驟12是以篩網針對碳黑的粒徑進行篩選,得到粒徑為特定尺寸以下的碳黑顆粒。在該過篩步驟12中,是利用篩網將該碳黑的粒徑篩選為1公厘以下。 The sieving step 12 is performed by screening the particle size of the carbon black by a sieve to obtain carbon black particles having a particle size of a specific size or less. In the sieving step 12, the particle size of the carbon black is screened to 1 mm or less by a sieve.

該磁選步驟13是以磁力吸附碳黑中的部分金屬殘渣,排除碳黑中不需要的金屬成分。 The magnetic separation step 13 is to magnetically adsorb a part of the metal residue in the carbon black to exclude unnecessary metal components in the carbon black.

該細篩步驟102是利用較該過篩步驟12中要細的篩網將該碳黑的粒徑篩選為0.25公厘以下。 The fine screening step 102 is to screen the particle size of the carbon black to 0.25 mm or less by using a sieve which is finer than the screening step 12.

該再磁選步驟103是再次對經過細篩的碳黑進行磁選,經過該細篩步驟102的碳黑,粒徑更加細小,僅經過該過篩步驟12的碳黑,其中粒徑較小的金屬成分可能被阻擋於眾多粒徑較大的碳黑中,無法經由該磁選步驟13而排除。經過該細篩步驟102後再進行該再磁選步驟103,能排除在該磁選步驟13中因粒徑過小而未被排除的金屬成分。 The remagnetic separation step 103 is to magnetically refine the finely sieved carbon black, and the carbon black passing through the fine screening step 102 has a finer particle size, and only passes through the carbon black of the screening step 12, wherein the metal having a smaller particle size The composition may be blocked in a plurality of carbon blacks having a large particle size and cannot be excluded by the magnetic separation step 13. After the fine screening step 102, the re-magnetic separation step 103 is performed, and the metal component which is not excluded due to the excessively small particle size in the magnetic separation step 13 can be excluded.

該分析步驟14是確認該碳黑中的固定碳在70%以上,並當作煉鋼製程中所需的造渣劑及助熔劑使用。參 閱表一,該分析步驟14是對該碳黑的灰分、揮發分、固定碳,及總硫分比例進行分析,而進行測試時是使用美國材料與試驗協會(American Society for Testing and Materials,ASTM)所公定的測試方法。其中A.D.(Air Dried Basis)代表為空氣乾燥基成分,空氣乾燥基的意義是表示樣品在實驗室正常條件(室溫20℃;相對濕度60%)下放置時所呈現的數據。而D.B.(Dry Basis)則是代表乾燥基成分,乾燥基的意義是將水分變化的因素去除,也就是除去水分後所呈現的數據。 The analysis step 14 confirms that the fixed carbon in the carbon black is 70% or more, and is used as a slag forming agent and a flux required in the steel making process. Reference Referring to Table 1, the analysis step 14 is to analyze the ash, volatile matter, fixed carbon, and total sulfur ratio of the carbon black, and the American Society for Testing and Materials (ASTM) is used for testing. ) The test method specified. Among them, A.D. (Air Dried Basis) represents the air drying base component, and the meaning of the air drying base is the data presented when the sample is placed under normal laboratory conditions (room temperature 20 ° C; relative humidity 60%). D.B. (Dry Basis) is a dry-based component. The meaning of the drying base is to remove the moisture change factor, that is, the data presented after removing the water.

由表一可得知,經由上述各步驟處理後所製成的碳黑,其中的固定碳成分,不論是在空氣乾燥基成分或者乾燥基成分的測量,均達到70%以上。煉鋼製程中使用造渣劑主要是為了調整爐渣的成分,而添加助熔劑則是為了使熔化材料的過程能較為順利。經由上述各步驟處理後所製成的碳黑,經比對成分後發現與煉鋼製程中所使用的 造渣劑及助熔劑的成分相似,且依據多次實際於煉鋼製程中添加使用的情形,確實能達到預期的造渣和助熔效果,故證實可以替代原本使用的造渣劑及助熔劑,因此以廢輪胎、塑膠、橡膠等廢棄物製成的造渣劑及助熔劑,能有效降低原本花費於習用之造渣劑及助燃劑上的煉鋼成本。 As can be seen from Table 1, the carbon black produced by the above-described respective steps has a fixed carbon component of 70% or more in terms of measurement of the air-drying component or the dry component. The slagging agent used in the steelmaking process is mainly to adjust the composition of the slag, and the flux is added to make the process of melting the material smoother. The carbon black produced after the above various steps is processed and compared with the components used in the steelmaking process. The composition of the slag-forming agent and the fluxing agent is similar, and according to the fact that it is actually added to the steel-making process, the slagging and fluxing effect can be achieved as expected, so it can be confirmed that it can replace the slag-forming agent and flux used originally. Therefore, the slagging agent and the fluxing agent made of waste tires, plastics, rubber and the like can effectively reduce the steelmaking cost originally spent on the conventional slagging agent and combustion improver.

綜上所述,將廢輪胎、塑膠,及橡膠等廢棄物,經由該裂解步驟11、該過篩步驟12、該磁選步驟13、該細篩步驟102、該再磁選步驟103,及該分析步驟14,能製造出替代煉鋼製程中所使用之造渣劑及助熔劑的碳黑,且經實際使用於煉鋼製程,確實具有替代造渣劑及助熔劑的效果,故確實能達成本發明之目的。 In summary, waste materials such as waste tires, plastics, and rubber are passed through the cracking step 11, the screening step 12, the magnetic separation step 13, the fine screening step 102, the remagnetic separation step 103, and the analysis step. 14. It can produce carbon black which replaces the slag-forming agent and flux used in the steelmaking process, and is actually used in the steel-making process, and has the effect of replacing the slag-forming agent and the fluxing agent, so the invention can be achieved. The purpose.

惟以上所述者,僅為本發明之較佳實施例而已,當不能以此限定本發明實施之範圍,即大凡依本發明申請專利範圍及專利說明書內容所作之簡單的等效變化與修飾,皆仍屬本發明專利涵蓋之範圍內。 The above is only the preferred embodiment of the present invention, and the scope of the present invention is not limited thereto, that is, the simple equivalent changes and modifications made by the patent application scope and patent specification content of the present invention, All remain within the scope of the invention patent.

11‧‧‧裂解步驟 11‧‧‧Cleaning step

12‧‧‧過篩步驟 12‧‧‧ screening step

13‧‧‧磁選步驟 13‧‧‧Magnetic selection steps

14‧‧‧分析步驟 14‧‧‧Analysis steps

102‧‧‧細篩步驟 102‧‧‧ fine screening steps

103‧‧‧再磁選步驟 103‧‧‧Re-magnetic separation step

Claims (6)

一種將廢棄物製成造渣劑及助熔劑之方法,包含:一裂解步驟,將廢棄物在真空環境下燃燒,使廢棄物裂解產生碳黑;一過篩步驟,以篩網針對碳黑的粒徑進行篩選;一磁選步驟,以磁力吸附碳黑中的部分金屬殘渣;及一分析步驟,確認該碳黑中的固定碳在70%以上,並當作造渣劑及助熔劑使用。 A method for preparing waste into a slag forming agent and a fluxing agent, comprising: a cracking step of burning the waste in a vacuum environment to crack the waste to produce carbon black; and a screening step to screen the carbon black The particle size is screened; a magnetic separation step is used to magnetically adsorb a part of the metal residue in the carbon black; and an analysis step confirms that the fixed carbon in the carbon black is more than 70%, and is used as a slag forming agent and a fluxing agent. 如請求項1所述將廢棄物製成造渣劑及助熔劑之方法,其中,該裂解步驟中是以500℃至900℃之間的溫度進行燃燒。 A method of preparing waste into a slagging agent and a flux according to claim 1, wherein the cracking step is performed at a temperature between 500 ° C and 900 ° C. 如請求項1所述將廢棄物製成造渣劑及助熔劑之方法,其中,該過篩步驟中是利用篩網將該碳黑的粒徑篩選為1公厘以下。 A method of forming a waste into a slagging agent and a flux according to claim 1, wherein the sieve step is to screen the particle size of the carbon black to 1 mm or less by using a sieve. 如請求項1所述將廢棄物製成造渣劑及助熔劑之方法,其中,該分析步驟還對該碳黑的灰分、揮發分,及總硫分比例進行分析。 The method of preparing waste into a slagging agent and a flux according to claim 1, wherein the analysis step further analyzes the ash, volatile matter, and total sulfur ratio of the carbon black. 如請求項1所述將廢棄物製成造渣劑及助熔劑之方法,在進行該分析步驟之前,還包含一細篩步驟及一再磁選步驟。 The method of preparing waste into a slagging agent and a flux as described in claim 1 further comprises a fine screening step and a re-magnetic separation step before performing the analyzing step. 如請求項5所述將廢棄物製成造渣劑及助熔劑之方法,其中,該細篩步驟中是利用篩網將該碳黑的粒徑篩選為0.25公厘以下。 The method of preparing waste into a slag forming agent and a flux according to claim 5, wherein the fine screening step is to screen the carbon black particle size to 0.25 mm or less by using a sieve.
TW103122541A 2014-06-30 2014-06-30 Method of converting waste into slag forming agent and flux TW201600541A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
TW103122541A TW201600541A (en) 2014-06-30 2014-06-30 Method of converting waste into slag forming agent and flux

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
TW103122541A TW201600541A (en) 2014-06-30 2014-06-30 Method of converting waste into slag forming agent and flux

Publications (2)

Publication Number Publication Date
TWI504644B TWI504644B (en) 2015-10-21
TW201600541A true TW201600541A (en) 2016-01-01

Family

ID=54851783

Family Applications (1)

Application Number Title Priority Date Filing Date
TW103122541A TW201600541A (en) 2014-06-30 2014-06-30 Method of converting waste into slag forming agent and flux

Country Status (1)

Country Link
TW (1) TW201600541A (en)

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2011127682A (en) * 2010-01-04 2014-02-20 Родольфо Антонио М. ГОМЕС ADVANCED METHOD FOR COAL ENRICHMENT FOR POWER PLANTS

Also Published As

Publication number Publication date
TWI504644B (en) 2015-10-21

Similar Documents

Publication Publication Date Title
Kua et al. Effect of indoor contamination on carbon dioxide adsorption of wood-based biochar–lessons for direct air capture
RU2012127208A (en) MODIFIED METHOD OF SEPARATION IN A STRONG MAGNETIC FIELD (SSMP)
CN103880007A (en) Activated carbon or activated coke prepared from oily sludge and preparation device and method thereof
Bisson et al. Chemical–mechanical bromination of biomass ash for mercury removal from flue gases
JP2013013843A (en) Method for treating alkali metal-containing waste
Zhao et al. Levels of polycyclic aromatic hydrocarbons in different types of hospital waste incinerator ashes
KR20160145699A (en) Process for producing coke, coke, and method for evaluating homogeneity of coal blend
JP2013193078A (en) Method and device of treating fly ash
Gabryszewska et al. Impact of municipal and industrial waste incinerators on PCBs content in the environment
Saini et al. A novel approach for reducing toxic emissions during high temperature processing of electronic waste
TW201600541A (en) Method of converting waste into slag forming agent and flux
TWI314879B (en)
JP2013138975A (en) Incineration ash treatment system
TWI529282B (en) A Method for Making Recycled Building Materials from Submerged Aggregate
JP2004275973A (en) Method for treating contaminated soil
WO2019071996A1 (en) Method for purifying heavy metal-contaminated soil
Hryb et al. Mercury content in refuse-derived fuels
PL359320A1 (en) Method of processing the combustion process residues from the combustion plant
JP2013095605A (en) Incineration ash treatment method
KR20170040823A (en) Removal method of mercury contained in exhaust gas by ferro-nickel slag
DE112014003542T5 (en) Coal as boiler fuel
Szulik et al. Petrographic and Chemical Research on Furnace Wastes From Individual Heating Furnaces and Boilers–Method for Identification of Co-Burning Municipal Waste
JP6603918B2 (en) Heat separation type CH analysis measurement system in transparent heating furnace
JP6075790B2 (en) Method for recovering valuable metals in waste
Goel et al. Examination of Particle Characteristics and Quantification of Emission Factors for Smoke Generated from a Popular Indian Incense Burnt in an Experimental Chamber

Legal Events

Date Code Title Description
MM4A Annulment or lapse of patent due to non-payment of fees