TW201501946A - Adhesive tape for flat panel display - Google Patents

Adhesive tape for flat panel display Download PDF

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Publication number
TW201501946A
TW201501946A TW103121932A TW103121932A TW201501946A TW 201501946 A TW201501946 A TW 201501946A TW 103121932 A TW103121932 A TW 103121932A TW 103121932 A TW103121932 A TW 103121932A TW 201501946 A TW201501946 A TW 201501946A
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Taiwan
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tape
adhesive layer
flat
panel display
flat display
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TW103121932A
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Chinese (zh)
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TWI565598B (en
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Kosaku Yamada
Hirofumi Murakami
Kazuya Fujita
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Hayakawa Rubber
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22Plastics; Metallised plastics
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J9/00Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F9/00Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements

Abstract

Disclosed is an adhesive tape for flat panel display 10 used to bond the flat panel display 20 onto the housing 30. The adhesive tape for flat panel display 10 is border-shaped of which the width is equal to or below 0.7 mm, and comprises an adhesion layer for adhering the bonding surface of the flat panel display 20 wherein the height of the adhesion layer is equal to or above 100[mu]m. The surface roughness of the adhesion layer is equal to or below 0.1[mu]m with respect to the arithmetic mean roughness, and equal to or below 1.5[mu]m with respect to the ten-point average roughness. Thus, it is easy for the adhesive tape to be bonded with the bonding surface even when the adhesive tape, and the is narrowly border-shaped bonding strength and the water resistantce are duly secured.

Description

平面顯示器用膠帶 Flat display tape

本發明關於一種平面顯示器用膠帶,該平面顯示器用膠帶用於將機體(用於收納裝置之主要部件的塑膠、金屬容器)和使用在例如智慧型手機等裝置的平面顯示器接合。 The present invention relates to a tape for a flat panel display for bonding a body (a plastic or metal container for accommodating a main part of the device) to a flat display for use in a device such as a smart phone.

迄今為止,例如智慧型手機、平板終端、相機、攜帶式音樂播放器等電子裝置具備平面顯示器和用於收納CPU、充電電池等的機體,該些平面顯示器和機體一般利用膠帶接合在一起。 Up to now, electronic devices such as smart phones, tablet terminals, cameras, portable music players, and the like have flat-panel displays and a body for housing a CPU, a rechargeable battery, and the like, and the flat displays and the body are generally joined together by tape.

為了確保對機體接合面的追隨性以及平面顯示器與機體之間的防水性,並且為了吸收掉落時等的衝擊,使用在發泡體基材的兩面設有黏合層之雙面膠帶作為在將平面顯示器和機體接合在一起而製成最終產品時使用之膠帶(例如參照專利文獻1~3)。 In order to ensure the followability to the joint surface of the body and the waterproof property between the flat display and the body, and to absorb the impact such as dropping, a double-sided tape provided with an adhesive layer on both sides of the foam substrate is used. An adhesive tape used when the flat display and the body are joined together to form a final product (for example, refer to Patent Documents 1 to 3).

在專利文獻1中公開了:在發泡體基材的兩面上具有黏合層之雙面膠帶中,作為發泡體基材,使用25%抗壓強度在40~160kPa的範圍內、抗拉強度在300~500N/cm2的範圍內之發泡體基材,這樣一來,即使是在將剛體相互接合的情況下,也能夠提升雙面膠帶與被黏合體之間的緊密接合性,從而防止水進入機體內。 Patent Document 1 discloses that a double-sided tape having an adhesive layer on both surfaces of a foam substrate is used as a foam substrate, and a tensile strength of 25% is used in a range of 40 to 160 kPa, and tensile strength is used. The foam base material in the range of 300 to 500 N/cm 2 , so that even when the rigid bodies are joined to each other, the adhesion between the double-sided tape and the adherend can be improved, thereby Prevent water from entering the body.

在專利文獻2中公開了一種雙面膠帶,該雙面膠帶在發泡體基材的兩面上設有黏合層,並且使總厚度在250μm以下、抗拉強度在0.5~20MPa的範圍內,由此獲得良好的防水性(止水性)和加工性。 Patent Document 2 discloses a double-sided tape which is provided with an adhesive layer on both sides of a foam substrate, and has a total thickness of 250 μm or less and a tensile strength of 0.5 to 20 MPa. Thereby, good water repellency (water repellency) and processability are obtained.

在專利文獻3中公開了一種雙面膠帶,該雙面膠帶在發泡體基材的兩面上具有黏合層,發泡體基材的層間強度在12N/cm以上且25%抗壓強度在30~170kPa之間,黏合層由含有丙烯酸系共聚物和聚合松酯系增黏樹脂的丙烯酸系黏合劑組成物構成,該丙烯酸系共聚物具有下述物質作為單體成分,即:碳數4~12的(甲基)丙烯酸酯;以及具有羧基的乙烯基單體。並且,在專利文獻3中還記載了:在將剛體相互黏合時也能夠提高雙面膠帶與被黏合體之間的緊密接合性,並且能夠實現再加工適合性和再剝離性,還能夠有效地防止水進入。 Patent Document 3 discloses a double-sided tape having an adhesive layer on both sides of a foam substrate, the interlayer strength of the foam substrate being 12 N/cm or more and 25% compressive strength at 30 Between ~170 kPa, the adhesive layer is composed of an acrylic adhesive composition containing an acrylic copolymer and a polymeric terpine ester-based tackifying resin, and the acrylic copolymer has the following components as a monomer component, that is, a carbon number of 4~ a (meth) acrylate of 12; and a vinyl monomer having a carboxyl group. Further, Patent Document 3 describes that the adhesion between the double-sided tape and the adherend can be improved when the rigid bodies are bonded to each other, and the reworkability and re-peelability can be achieved, and the re-peelability can be effectively achieved. Prevent water from entering.

〔專利文獻〕 [Patent Document]

[專利文獻1]日本特開2009-108314號公報 [Patent Document 1] Japanese Patent Laid-Open Publication No. 2009-108314

[專利文獻2]日本特開2010-155969號公報 [Patent Document 2] Japanese Patent Laid-Open Publication No. 2010-155969

[專利文獻3]日本特開2010-260880號公報 [Patent Document 3] Japanese Patent Laid-Open Publication No. 2010-260880

根據專利文獻1~3的雙面膠帶,由於基材係發泡體且非常柔軟,因此具有下述優點:能夠容易地追隨平面顯示器中的與機體接合之接合面以及機體中的與平面顯示器接合之接合面上的凹凸。 According to the double-sided tapes of Patent Documents 1 to 3, since the base material-based foam is extremely soft, it has the advantage that it can easily follow the joint surface joined to the body in the flat-panel display and the joint with the flat display in the machine body. Concavities and convexities on the joint surface.

但是,專利文獻1~3的雙面膠帶存在以下問題。 However, the double-sided tapes of Patent Documents 1 to 3 have the following problems.

也就是說,由於要求平面顯示器在不改變外形尺寸的前提下盡可能地擴大有效顯示區域、亦即要求所謂的窄邊框化,因此平面顯示器用於和機體接合之接合面的寬度變窄。接合面的寬度變窄意味著膠帶的寬度也必須對應地變窄。對膠帶要求的寬度例如在1.0mm以下,也有例如在0.7mm以下的情況。 That is to say, since the flat display is required to expand the effective display area as much as possible without changing the outer size, that is, the so-called narrow frame is required, the width of the joint surface for the flat display to be joined to the body is narrowed. The narrowing of the width of the joint surface means that the width of the tape must also be correspondingly narrowed. The width required for the tape is, for example, 1.0 mm or less, and may be, for example, 0.7 mm or less.

然而,為了確保追隨性,專利文獻1~3中的基材使用了具有封閉氣泡構造的發泡體。在膠帶之基材上的、與機體等接合之接合面上,封閉氣泡以形成有開口的狀態存在,開口狀態的封閉氣泡的開口寬度為200μm~600μm,也有大於200μm~600μm的情況,開口的寬度參差不齊。由此,如果例如使膠帶的寬度窄於1.0mm,那麽在每單位面積之接合面上開口之封閉氣泡的數量增加,此外,封閉氣泡的開口寬度大於接合面寬度的可能性增高。這意味著膠帶的接合強度會下降,並且防水性能會急遽地下降。 However, in order to ensure followability, the base materials in Patent Documents 1 to 3 use a foam having a closed cell structure. On the joint surface of the base material of the tape which is joined to the body or the like, the closed cells are formed in an open state, and the open width of the closed cells in the open state is 200 μm to 600 μm, and is also larger than 200 μm to 600 μm. The width is uneven. Thus, if, for example, the width of the tape is narrowed by 1.0 mm, the number of closed cells opened at the joint surface per unit area increases, and further, the possibility that the opening width of the closed cells is larger than the width of the joint surface is increased. This means that the bonding strength of the tape is lowered, and the waterproof performance is drastically lowered.

在專利文獻1~3中,基材係發泡體,由此,在要形成黏合層的基材面上存在有封閉氣泡的開口。其結果是,黏合層的平滑性下降。此外,在為了降低價格而使用廉價的紙製分離膜的情況下,黏合層的平滑性也會下降。為此,當平面顯示器或機體的接合面呈平滑狀的情況下,為了使黏合層與該接合面緊密接合,需要較大的壓力。 In Patent Documents 1 to 3, the base material is a foam, and thus an opening for closing the air bubbles is present on the surface of the substrate on which the adhesive layer is to be formed. As a result, the smoothness of the adhesive layer is lowered. Further, in the case where an inexpensive paper separation film is used in order to lower the price, the smoothness of the adhesive layer is also lowered. For this reason, when the joint surface of the flat display or the body is smooth, a large pressure is required in order to make the adhesive layer tightly joined to the joint surface.

一般而言,在將平面顯示器與機體接合後,會對裝置的合格/不合格進行判斷,此時,當平面顯示器和機體中的任一方不合格時,從降低成本的觀點來看,較佳為將平面 顯示器從機體上剝離下來進行修理。 In general, after the flat display is bonded to the body, the pass/fail of the device is judged. In this case, when either of the flat display and the body fails, it is preferable from the viewpoint of cost reduction. For the plane The display is peeled off from the body for repair.

然而,在使用發泡體基材情況下,當施加剝離力時,由於發泡體基材中存在封閉氣泡,因此發泡體基材容易發生內聚破壞,從而發泡體基材、黏合層會殘留在平面顯示器和機體雙方的接合面上,該發泡體基材、黏合層非常難以去除。 However, in the case of using a foam substrate, when a peeling force is applied, since the closed cells are present in the foam substrate, the foam substrate is liable to undergo cohesive failure, thereby foaming the substrate and the adhesive layer. It remains on the joint surface of both the flat display and the body, and the foam base material and the adhesive layer are very difficult to remove.

就這一點來說,在專利文獻3中記載了膠帶具有良好的再加工性。然而,由於該膠帶係具有發泡體基材的膠帶,因此發泡體基材容易發生內聚破壞這一點並沒有改變,無法僅靠手指拉扯膠帶來將膠帶從平面顯示器或機體的接合面上完全剝下却不使膠帶破裂。 In this regard, Patent Document 3 describes that the tape has good reworkability. However, since the tape is a tape having a foam substrate, the foam substrate is liable to undergo cohesive failure and does not change, and it is not possible to pull the tape from the joint surface of the flat display or the body by merely pulling the tape by fingers. Stripped completely without rupturing the tape.

由於一般的丙烯酸系黏合劑為了提升內聚力而進行了交聯,因此難以將黏合劑從發泡體基材分離並回收,例如在將膠帶切割成框狀時,形成在內側之較大的切割餘料只能廢棄,這樣就無法有效地利用資源。 Since a general acrylic adhesive is crosslinked for enhancing the cohesive force, it is difficult to separate and recover the binder from the foam substrate, for example, when the tape is cut into a frame shape, a large cutting allowance is formed on the inner side. It can only be discarded, so that resources cannot be used effectively.

本發明係有鑒於上述問題而完成的,其目的在於:使膠帶即使成為寬度在0.7mm以下的窄邊框狀時,也能夠容易地與接合面接觸,並且能夠確保充分的接合強度和防水性。 The present invention has been made in view of the above-described problems, and it is an object of the present invention to enable a tape to be easily brought into contact with a joint surface even when the tape has a narrow frame shape having a width of 0.7 mm or less, and to secure sufficient joint strength and water repellency.

並且,在解決上述問題的前提下,做到:使膠帶比以往的膠帶能夠完全地且容易地進行再加工,並且使切割膠帶成為邊框狀時產生的切割餘料能夠回收,從而能有效地利用資源。 In addition, in order to solve the above problem, the tape can be completely and easily reworked than the conventional tape, and the cutting residue generated when the dicing tape is formed into a frame shape can be recovered, so that the tape can be effectively utilized. Resources.

為達成上述目的,本發明人進行了潛心研究,發現具 備以下結構的膠帶能夠解決上述問題,從而完成了本發明。 In order to achieve the above object, the inventors conducted intensive research and found that The tape having the following structure can solve the above problems, thereby completing the present invention.

第一型態的發明係一種平面顯示器用膠帶,其用於接合平面顯示器和機體,其特徵在於:該平面顯示器用膠帶形成為帶寬0.7mm以下的邊框形狀,具有與上述平面顯示器之接合面黏合的黏合層,上述黏合層的厚度設定為100μm以上,上述黏合層的表面粗糙度以算數平均粗糙度計為0.1μm以下,並且以十點平均粗糙度計為1.5μm以下。 The invention of the first type is a tape for a flat display, which is used for joining a flat display and a body, wherein the flat display is formed of a tape having a width of 0.7 mm or less and having a bonding surface with the flat display. In the adhesive layer, the thickness of the adhesive layer is set to 100 μm or more, and the surface roughness of the adhesive layer is 0.1 μm or less in terms of arithmetic mean roughness and 1.5 μm or less in terms of ten-point average roughness.

根據這樣的結構,黏合層成為各個邊的寬度為0.7mm以下的窄邊框形狀的膠帶。由於黏合層的厚度為100μm以上,因此黏合層能夠充分地變形而容易地追隨平面顯示器以及機體之接合面的形狀,從而容易地與接合面接觸。 According to such a configuration, the adhesive layer is a tape having a narrow frame shape in which the width of each side is 0.7 mm or less. Since the thickness of the adhesive layer is 100 μm or more, the adhesive layer can be sufficiently deformed to easily follow the shape of the joint surface of the flat display and the body, and is easily brought into contact with the joint surface.

使黏合層的表面粗糙度以算數平均粗糙度計為0.1μm以下且以十點平均粗糙度計為1.5μm以下,使黏合層的表面成為了充分平滑的面。這樣一來,由於黏合層的表面粗糙度比以往的膠帶的黏合層的表面粗糙度平滑了10倍左右,因此黏合層能夠容易地與平滑的面接觸。由此,能夠確保充分的接合強度和防水性。 The surface roughness of the adhesive layer is 0.1 μm or less in terms of arithmetic mean roughness and 1.5 μm or less in terms of ten-point average roughness, so that the surface of the adhesive layer becomes a sufficiently smooth surface. In this way, since the surface roughness of the adhesive layer is smoothed by about 10 times than the surface roughness of the adhesive layer of the conventional tape, the adhesive layer can be easily brought into contact with the smooth surface. Thereby, sufficient joint strength and water repellency can be ensured.

第二型態的發明係:在第一型態的發明中,將形成為厚度100μm且寬度25mm的上述黏合層壓接在不銹鋼板的表面時,180度剝離強度為50N以上,並且剝離狀態為界面剝離,厚度為100μm的上述黏合層以啞鈴狀3號試片進行測試時,伸長率25%時的抗拉強度在0.5MPa以上1.0MPa以下的範圍內。 In the first type of invention, in the first type of invention, when the above-mentioned adhesive laminate having a thickness of 100 μm and a width of 25 mm is attached to the surface of a stainless steel plate, the 180-degree peel strength is 50 N or more, and peeling off When the adhesive layer having a thickness of 100 μm was tested with a dumbbell-shaped No. 3 test piece, the tensile strength at an elongation of 25% was in the range of 0.5 MPa to 1.0 MPa.

根據這樣的結構,能夠確保使膠帶成為帶寬0.7mm以 下的窄邊框形狀時的具體的接合強度與具有以往一般使用的發泡體基材之膠帶在寬度1mm以上時的接合強度相同,或者能夠確保使膠帶成為帶寬0.7mm以下的窄邊框形狀時的具體的接合強度高於具有以往一般使用的發泡體基材之膠帶在寬度1mm以上時的接合強度。由於剝離時為界面剝離的狀態,因此不會有一部分黏合層殘留在平面顯示器或機體上的情況發生,再加工能夠容易地進行。 According to such a configuration, it is possible to ensure that the tape has a bandwidth of 0.7 mm. When the tape has a narrow frame shape with a width of 0.7 mm or less, the specific bonding strength in the case of the narrow frame shape is the same as the bonding strength when the tape of the foam substrate which has been conventionally used has a width of 1 mm or more. The specific bonding strength is higher than the bonding strength when the tape having the conventionally used foam substrate has a width of 1 mm or more. Since the interface is peeled off at the time of peeling, a part of the adhesive layer does not remain on the flat display or the body, and the reworking can be easily performed.

由於使伸長率25%時的抗拉強度在0.5MPa以上1.0MPa以下的範圍內,因此黏合層具有適度的柔軟性,能夠良好地追隨平面顯示器的接合面形狀和機體的接合面形狀。 Since the tensile strength at an elongation of 25% is in the range of 0.5 MPa to 1.0 MPa, the adhesive layer has moderate flexibility and can satisfactorily follow the joint surface shape of the flat display and the joint surface shape of the machine body.

第三型態的發明係:在第一型態的發明中,該膠帶具有下述的接合強度,即:將寬度0.5mm的上述膠帶佈置在50mm×100mm的兩片板材的周緣部之間,以上述膠帶接合該兩片板材,在冷卻到零下20℃的狀態下,水平地佈置該兩片板材並固定上方的板材,當使杜邦式衝擊試驗的下落重物300g落在下方的板材上時,在該重物的下落距離到達30cm之前,上述下方的板材不會從上方的板材剝離。 The invention of the third type: in the invention of the first type, the tape has the joint strength that the above-mentioned tape having a width of 0.5 mm is disposed between the peripheral portions of two sheets of 50 mm × 100 mm, The two sheets were joined by the above-mentioned tape, and the two sheets were horizontally arranged and fixed to the upper sheet while being cooled to minus 20 ° C, when the weight of the DuPont-type impact test 300 g was dropped on the lower sheet. The lower plate is not peeled off from the upper plate until the falling distance of the weight reaches 30 cm.

根據這樣的結構,由於能夠以黏合層充分地吸収常溫和低溫下的衝擊,因此當使用本發明的膠帶製成的產品受到衝擊或者掉落時,也能夠抑制平面顯示器的剝離而提高可靠性。 According to such a configuration, since the impact at normal temperature and low temperature can be sufficiently absorbed by the adhesive layer, when the product made of the tape of the present invention is impacted or dropped, the peeling of the flat display can be suppressed and the reliability can be improved.

第四型態的發明係:在第一型態的發明中,厚度為100μm的上述黏合層以啞鈴狀3號試片進行測試時,伸長率 1000%時的抗拉強度在3.0MPa以上6.0MPa以下的範圍內。 The fourth type of invention: In the first type of invention, when the adhesive layer having a thickness of 100 μm is tested with a dumbbell-shaped test piece No. 3, the tensile strength at an elongation of 1000% is 3.0 MPa or more. Within the range of 6.0 MPa or less.

根據這樣的結構,黏合層將會具有橡膠彈性,因此黏合層在再加工時的途中不會破裂,能夠從平面顯示器的接合面或機體的接合面上將他乾淨地剝離下來。 According to such a configuration, the adhesive layer will have rubber elasticity, so that the adhesive layer does not break during the reworking, and it can be cleanly peeled off from the joint surface of the flat display or the joint surface of the body.

第五型態的發明係:在第一型態的發明中,上述黏合層的組成物係彈性體與增黏劑的重量比率在1/0.3以上1/1以下的範圍內的組成物,上述彈性體為苯乙烯系彈性體且具有可逆性。 According to a fifth aspect of the invention, in the first aspect of the invention, the composition of the adhesive layer is a composition having a weight ratio of the elastomer to the tackifier in a range of 1/0.3 or more and 1/1 or less, The elastomer is a styrene elastomer and is reversible.

根據這樣的結構,由於彈性體為苯乙烯系彈性體,因此溶劑溶解性良好,塗布等的加工性獲得改善。由於增黏劑的比率在比以往的一般的膠帶低的範圍內,因此能夠充分地維持彈性體的弾性。 According to such a configuration, since the elastomer is a styrene-based elastomer, solvent solubility is improved, and workability such as coating is improved. Since the ratio of the tackifier is in a range lower than that of the conventional general tape, the elasticity of the elastic body can be sufficiently maintained.

由於黏合層不像交聯後的一般黏合劑那樣不可逆,而是具有可逆性,因此能夠使黏合層再次溶解到溶劑中,能夠將切割時大量產生的切割餘料再次製作成膠帶的黏合層來再利用。 Since the adhesive layer is not irreversible like the general adhesive after cross-linking, but is reversible, the adhesive layer can be dissolved again in the solvent, and the cutting residue which is generated in a large amount during cutting can be made into the adhesive layer of the adhesive tape again. Reuse.

當膠帶的黏合層為單層時,能夠將切割餘料全部直接溶解到有機溶劑中來製造黏合組成物溶液。 When the adhesive layer of the tape is a single layer, the entire composition of the cutting material can be directly dissolved in an organic solvent to produce a solution of the adhesive composition.

第六型態的發明係:在第一型態的發明中,該平面顯示器用膠帶係由以下方法中的任一方法製造,即:利用塗布方式形成上述黏合層後切割成規定形狀的方法,該塗布方式係利用具有流動性的黏合劑來覆蓋被塗布物;利用撒布器塗布具有流動性的黏合劑來形成規定形狀的上述黏合 層的方法;以及將具有流動性的黏合劑印刷在被印刷物上來形成規定形狀的上述黏合層的方法。 According to a sixth aspect of the invention, in the first aspect of the invention, the flat panel display tape is produced by any one of the following methods, that is, a method of forming the adhesive layer by a coating method and then cutting into a predetermined shape, The coating method covers the object to be coated by using a fluidity adhesive; and the fluidity adhesive is applied by a spreader to form the above-described bonding of a predetermined shape. A method of forming a layer; and a method of forming a binder having a fluidity on a printed matter to form the above-described adhesive layer having a predetermined shape.

根據這樣的結構,除了能夠採用與一般的膠帶相同的塗布方式以外,還能夠採用下述方式來形成黏合層,因此能夠避免製作出切割餘料等不必要的東西。所述方式即:撒布方式,該撒布方式利用了對熱可逆的熱可塑性的熱熔黏合劑;印刷方式,在該印刷方式中,黏合劑係在溶解在有機溶劑中的狀態下或熱熔的狀態下印刷到被印刷物上。 According to such a configuration, in addition to the same coating method as that of a general tape, the adhesive layer can be formed in the following manner, and thus it is possible to avoid unnecessary things such as cutting residual materials. The manner is: a spreading method, which utilizes a thermo-compressible hot-melt adhesive for heat reversal; and a printing method in which the adhesive is dissolved in an organic solvent or thermally melted. Printed on the printed matter in the state.

根據第一型態的發明,能夠滿足平面顯示器中的較高的要求,即寬度0.7mm以下的窄邊框這樣的要求。由於黏合層的厚度為100μm以上,因此黏合層能夠充分地追隨平面顯示器之接合面或機體之接合面上的凹凸,並且由於黏合層的表面平滑,因此能夠容易地與平滑的接合面接觸。由此,能夠充分地提高黏合強度,還能確保穩定且較高的防水性。 According to the first aspect of the invention, it is possible to meet the high requirements in the flat panel display, that is, the narrow frame having a width of 0.7 mm or less. Since the thickness of the adhesive layer is 100 μm or more, the adhesive layer can sufficiently follow the unevenness of the joint surface of the flat display or the joint surface of the body, and can easily contact the smooth joint surface because the surface of the adhesive layer is smooth. . Thereby, the adhesive strength can be sufficiently improved, and stable and high water repellency can be ensured.

根據第二型態的發明,即使形成為以往難以達成的寬度0.7mm以下的窄邊框形狀,也能夠獲得與具有一般發泡體基材的膠帶相同或更高的接合強度。由於將伸長率25%時的抗拉強度設定在規定的範圍內,黏合層不會像一般的膠帶那樣過於柔軟,並且也不會硬到難以追隨平面顯示器或機體,因此能夠以較弱的夾緊力來使黏合層追隨平面顯示器或機體,從而能夠充分地提高黏合強度,並且能夠確保穩定且較高的防水性。在剝離下來時,不會有一部分膠帶殘留在平面顯示器或機體上的情況發生,能夠良好地進 行再加工。 According to the second aspect of the invention, even if it is formed into a narrow frame shape having a width of 0.7 mm or less which has been difficult to achieve in the past, the bonding strength equal to or higher than that of the tape having a general foam substrate can be obtained. Since the tensile strength at an elongation of 25% is set within a predetermined range, the adhesive layer is not too soft like a general tape, and is not hard to follow a flat display or a body, so that a weaker clip can be used. The tightening force causes the adhesive layer to follow the flat display or the body, thereby sufficiently improving the bonding strength and ensuring stable and high water repellency. When peeling off, there is no part of the tape remaining on the flat display or the body, and it can progress well. Reprocessing.

根據第三型態的發明,由於在低溫下的杜邦衝擊試驗的結果比具有一般發泡基材的膠帶好,當使用本發明的膠帶製成的產品受到衝擊或者掉落時,黏合層能夠吸收受到衝擊或掉落時的衝擊,因此能夠抑制平面顯示器的剝離而提高可靠性。 According to the invention of the third type, since the result of the DuPont impact test at a low temperature is better than that of a tape having a general foamed substrate, when the product made using the tape of the present invention is impacted or dropped, the adhesive layer can absorb Since it is impacted or impacted when dropped, it is possible to suppress peeling of the flat display and improve reliability.

根據第四型態的發明,由於黏合層在伸長了1000%的狀態下仍然具有充分的抗拉強度,因此即使在再加工時以手指撕下膠帶,膠帶也不會在途中破裂,能夠從平面顯示器或機體上將他乾淨地剝離下來。 According to the invention of the fourth type, since the adhesive layer still has sufficient tensile strength in the state of elongation of 1000%, the tape is not broken on the way even when the tape is peeled off by the finger during reworking, and the adhesive layer can be flat. He is peeled off cleanly on the display or on the body.

根據第五型態的發明,由於黏合劑組成物的主成分為苯乙烯系的彈性體,並且對增黏劑設定了規定的比例,因此溶劑溶解性或塗布等的加工性良好,並且維持了苯乙烯系彈性體的弾性特性,能夠均衡地確保黏合性、衝擊吸収性、抗拉強度、再加工性。 According to the fifth aspect of the invention, since the main component of the binder composition is a styrene-based elastomer and a predetermined ratio is set to the tackifier, the solvent solubility or the workability such as coating is good, and the maintenance is maintained. The bismuth properties of the styrene elastomer can ensure adhesion, impact absorption, tensile strength, and reworkability in a balanced manner.

由於黏合劑組成物沒有像一般黏合劑那樣進行交聯,因此能夠可逆地溶解在溶劑中,能夠將切割時的大量切割餘料再次溶解於有機溶劑中後進行塗布而再生為膠帶,與一般的膠帶相比,對環境較友善且能夠有效利用資源。 Since the binder composition is not crosslinked like a general binder, it can be reversibly dissolved in a solvent, and a large amount of the cutting residue at the time of cutting can be dissolved again in an organic solvent, and then coated and regenerated into a tape. Compared to tape, it is more environmentally friendly and can use resources efficiently.

根據第六型態的發明,能夠與一般的發泡體基材同樣地採用塗布方式來形成黏合層,從而能夠容易地加工成0.7mm以下的窄邊框形狀。由於通過使黏合層具有熱熔性和對有機溶劑的穩定的溶解性而賦予了黏合層流動性,因此也能夠利用不產生切割餘料的撒布方式或印刷方式來進 行窄邊框加工,比起一般的膠帶,對環境較友善且能夠有效地利用資源。 According to the sixth aspect of the invention, the adhesive layer can be formed by a coating method in the same manner as a general foam substrate, and can be easily processed into a narrow frame shape of 0.7 mm or less. Since the adhesive layer is provided with hot meltability and stable solubility to an organic solvent to impart fluidity to the adhesive layer, it is also possible to use a spreading method or a printing method that does not generate a cutting residual material. Narrow frame processing, which is more friendly to the environment and can effectively utilize resources than ordinary tape.

1‧‧‧智慧型手機 1‧‧‧Smart mobile phone

10‧‧‧平面顯示器用膠帶 10‧‧‧Panel for flat panel display

20‧‧‧平面顯示器 20‧‧‧ flat panel display

30‧‧‧機體 30‧‧‧ body

圖1係本發明實施方式的智慧型手機的分解圖。 1 is an exploded view of a smart phone according to an embodiment of the present invention.

圖2係平面顯示器用膠帶的俯視圖。 Figure 2 is a top plan view of a tape for a flat panel display.

下面,根據圖式對本發明的實施方式進行詳細的說明。需要說明的是,以下較佳實施方式的說明是本質上的示例,並沒有意圖對本發明、其應用對象或其用途的範圍加以限制。 Hereinafter, embodiments of the present invention will be described in detail based on the drawings. It should be noted that the following description of the preferred embodiments is merely an essential example and is not intended to limit the scope of the invention, its application, or its use.

圖1係使用本發明實施方式的平面顯示器用膠帶10製造而成的智慧型手機1的立體分解圖。該智慧型手機1具備平面顯示器20、機體30以及平面顯示器用膠帶10。該平面顯示器20具備液晶表示面板或有機電致發光面板等。該平面顯示器用膠帶10用於接合平面顯示器20和機體30。 Fig. 1 is an exploded perspective view of a smartphone 1 manufactured by using the tape 10 for a flat panel display according to an embodiment of the present invention. The smart phone 1 includes a flat display 20, a body 30, and a tape 10 for a flat display. The flat display 20 includes a liquid crystal display panel, an organic electroluminescence panel, or the like. The flat panel display is used with the tape 10 for joining the flat panel display 20 and the body 30.

平面顯示器20上的與機體30接合的部分例如由樹脂板、玻璃板構成。在該實施方式中,採用了在不改變平面顯示器20的外形尺寸的前提下擴大了有效顯示區域的平面顯示器20,即所謂的窄邊框化平面顯示器20。在此,邊框部指的是為了不讓與液晶元件等連接的端子等從平面顯示器20的正面側被看見而以較深的顏色(例如黑色)將平面 顯示器20的周緣部上了色的部分。在本實施方式中,將平面顯示器20的邊框部的寬度設定為0.7mm,但是本發明不在此限,平面顯示器20的邊框部的寬度只要是在0.7mm以下即可,也可以設定為例如0.6mm或0.5mm、0.4mm。 The portion of the flat display 20 that is joined to the body 30 is made of, for example, a resin plate or a glass plate. In this embodiment, the flat display 20, which is a so-called narrow bezel flat display 20, which expands the effective display area without changing the outer dimensions of the flat display 20 is employed. Here, the frame portion refers to a plane having a darker color (for example, black) so that a terminal or the like connected to the liquid crystal element or the like is not seen from the front side of the flat display 20. The colored portion of the peripheral portion of the display 20 is colored. In the present embodiment, the width of the frame portion of the flat display 20 is set to 0.7 mm. However, the present invention is not limited thereto, and the width of the frame portion of the flat display 20 may be 0.7 mm or less, and may be set to, for example, 0.6. Mm or 0.5mm, 0.4mm.

需要說明的是,平面顯示器20不限於使用上述面板,還可以使用各種顯示裝置。在該平面顯示器20上還可以裝設觸控面板感測器。 It should be noted that the flat display 20 is not limited to the use of the above panel, and various display devices can also be used. A touch panel sensor can also be mounted on the flat display 20.

機體30係用於收納例如控制裝置、揚聲器、相機、充電電池等(都未圖示出)的箱形容器,例如能夠由樹脂、金屬等構成。 The body 30 is a box-shaped container for accommodating, for example, a control device, a speaker, a camera, a rechargeable battery, or the like (all not shown), and can be made of, for example, resin, metal, or the like.

在該實施方式的說明中係對製造智慧型手機1的情況進行說明,但是平面顯示器用膠帶10還能夠使用在製造例如平板終端、相機、攜帶式音樂播放器等的情況,具有平面顯示器和機體的各種電子裝置都是本發明的應用對象。 In the description of this embodiment, the case of manufacturing the smart phone 1 will be described, but the flat display tape 10 can also be used in the case of manufacturing, for example, a tablet terminal, a camera, a portable music player, etc., having a flat display and a body. Various electronic devices are the application objects of the present invention.

如圖2所示,平面顯示器用膠帶10呈具有四個邊的矩形邊框形狀,該形狀與平面顯示器20的邊框部的形狀一致。平面顯示器用膠帶10的各個邊的寬度即帶寬A在0.7mm以下。由於帶寬A設定為與上述平面顯示器20的邊框部的各個邊的寬度大致相同,因此使用時只要讓平面顯示器用膠帶10對齊邊框部的各個邊即可。平面顯示器用膠帶10具有僅以黏合層構成的單層構造,該黏合層與平面顯示器20的接合面黏合。即使是這樣的單層構造,平面顯示器用膠帶10仍然成為雙面膠帶。 As shown in FIG. 2, the flat display tape 10 has a rectangular frame shape having four sides, which conforms to the shape of the frame portion of the flat display 20. The width A of each side of the tape 10 for flat panel display, that is, the bandwidth A is 0.7 mm or less. Since the bandwidth A is set to be substantially the same as the width of each side of the frame portion of the flat display 20, it is only necessary to align the flat display with the tape 10 on each side of the frame portion. The flat display tape 10 has a single-layer structure composed only of an adhesive layer, and the adhesive layer is bonded to the joint surface of the flat display 20. Even with such a single layer construction, the flat panel display tape 10 is still a double-sided tape.

需要說明的是,平面顯示器用膠帶10也可以是在基材 兩面上設置了100μm以上的黏合層的雙面膠帶。在此,如果基材像以往的膠帶那樣使用發泡層,那麽當切割為窄邊框形狀時,防水性和接合強度會因為上述理由而顯著地下降,這是不理想的。在本實施方式中,使用如PET(聚對苯二甲酸乙二酯)、PP(聚丙烯)這樣的硬而密度高的基材。在該情況下,雖然模切性比單層構造來的好,但是該基材成為絕緣層,即使在該基材兩面設置了100μm的黏合層而使平面顯示器用膠帶10的厚度達到200μm以上,實質上也只能得到100μm的黏合層的效果(對接合面的追隨性)。也就是說,如果使用硬的基材,那麽基材就難以變形,基材對平面顯示器20之接合面或機體30之接合面的追隨性會下降,因此,較佳為使基材兩面的黏合層的厚度分別在100μm以上。 It should be noted that the flat display tape 10 can also be used as a substrate. Double-sided tape with an adhesive layer of 100 μm or more on both sides. Here, if the base material uses a foamed layer like a conventional tape, when it is cut into a narrow frame shape, the water repellency and the joint strength are remarkably lowered for the above reasons, which is not preferable. In the present embodiment, a hard and dense substrate such as PET (polyethylene terephthalate) or PP (polypropylene) is used. In this case, although the die-cut property is better than that of the single-layer structure, the base material serves as an insulating layer, and the thickness of the flat display tape 10 is 200 μm or more even if an adhesive layer of 100 μm is provided on both surfaces of the substrate. In essence, only the effect of the adhesive layer of 100 μm (following the joint surface) can be obtained. That is to say, if a hard substrate is used, the substrate is hard to be deformed, and the followability of the substrate to the joint surface of the flat display 20 or the joint surface of the body 30 is lowered. Therefore, it is preferable to bond the two sides of the substrate. The thickness of the layer is 100 μm or more.

如果使平面顯示器用膠帶10的黏合層為單層構造,則使黏合層的厚度在100μm以上。並且,黏合層是以彈性體為主成分的、不含有氣泡的層。 If the adhesive layer of the flat display panel tape 10 is a single layer structure, the thickness of the adhesive layer is made 100 μm or more. Further, the adhesive layer is a layer containing no elastomer as a main component of the elastomer.

就使用發泡體基材的以往的雙面膠帶來說,如上所述,發泡體基材中的封閉氣泡的大小為200μm到600μm,也有大於200μm~600μm的情況,封閉氣泡的大小參差不齊。由此,如果例如使膠帶的寬度窄於1.0mm,那麽在每單位面積之接合面上開口之封閉氣泡的數量增加。這意味著發泡體基材的強度會顯著地下降。此外,封閉氣泡的開口寬度大於接合面寬度的可能性增高,封閉氣泡成為水路,從而有可能變得無法確保防水性。 In the conventional double-sided tape using a foam substrate, as described above, the size of the closed cells in the foam substrate is 200 μm to 600 μm, and the size of the closed cells is not more than 200 μm to 600 μm. Qi. Thus, if, for example, the width of the tape is narrowed by 1.0 mm, the number of closed cells opened at the joint surface per unit area increases. This means that the strength of the foam substrate is significantly lowered. Further, the possibility that the opening width of the closed bubble is larger than the width of the joint surface is increased, and the closed bubble becomes a water path, so that it may become impossible to ensure water repellency.

而且,就使用發泡體基材的以往的雙面膠帶來說,當切割成窄邊框狀時,在膠帶外表面上開口的封閉氣泡的數量增加,發泡體基材的強度下降且對外部壓力的抵抗力顯著地下降,從而在水壓作用下變得容易漏水。使用發泡體基材的以往的雙面膠帶還存在當剝離力作用時發泡體基材容易被破壞的缺點。 Further, in the case of the conventional double-sided tape using the foam substrate, when cutting into a narrow frame shape, the number of closed cells opened on the outer surface of the tape increases, and the strength of the foam substrate decreases and the outside The resistance to pressure drops significantly, making it easy to leak under water pressure. A conventional double-sided tape using a foam base material has a drawback that the foam base material is easily broken when a peeling force acts.

相對於此,在本實施方式中,黏合層是以彈性體為主成分的、不含有氣泡的層(實心結構)。因此,即使是模切成帶寬A為0.7mm以下的窄邊框狀,也不會出現在外側面上開口的氣泡。由此,對外部壓力的抵抗力不會急遽地下降,利用對平面顯示器20或機體30的黏合力以及黏合層本身的強度,能夠充分地確保平面顯示器20與機體30之間的防水性。在該情況下,平面顯示器用膠帶10對平面顯示器20或機體30的接合強度高,為一般發泡基材膠帶的2倍以上。並且由於黏合組成物的主成分是由具有橡膠彈性的彈性體構成,因此對水壓的伸長性和抵抗力較大(受水壓作用時容易伸長但不容易破裂),能夠容易地確保可靠性高而穩定的防水性。 On the other hand, in the present embodiment, the adhesive layer is a layer (solid structure) which does not contain bubbles as a main component of the elastomer. Therefore, even if it is die-cut into a narrow frame shape having a bandwidth A of 0.7 mm or less, bubbles which are open on the outer side surface do not occur. Thereby, the resistance to the external pressure is not drastically lowered, and the waterproofness between the flat display 20 and the body 30 can be sufficiently ensured by the adhesion to the flat display 20 or the body 30 and the strength of the adhesive layer itself. In this case, the bonding strength of the flat display display tape 10 to the flat display 20 or the body 30 is twice as high as that of the general foamed base tape. Further, since the main component of the adhesive composition is composed of an elastomer having rubber elasticity, the elongation and resistance to water pressure are large (it is easy to elongate when subjected to water pressure but is not easily broken), and reliability can be easily ensured. High and stable water resistance.

具體而言,平面顯示器用膠帶10的黏合層的組成物含有增黏劑以及苯乙烯系彈性體,彈性體/增黏劑的重量比率在1/0.3到1/1的範圍內。 Specifically, the composition of the adhesive layer of the flat display display tape 10 contains a tackifier and a styrene-based elastomer, and the weight ratio of the elastomer/tackifier is in the range of 1/0.3 to 1/1.

作為苯乙烯系彈性體能夠舉出:SBS(聚苯乙烯-聚(丁烯)嵌段-聚苯乙烯)、SIS(聚苯乙烯-聚(異戊二烯)嵌段-聚苯乙烯)、SIBS(聚苯乙烯-聚(異戊二烯/丁烯)嵌段-聚苯乙 烯)、SEP(聚苯乙烯-聚(乙烯/丙烯)嵌段)、SEPS(聚苯乙烯-聚(乙烯/丙烯)嵌段-聚苯乙烯)、SEBS(聚苯乙烯-聚(乙烯/丁烯)嵌段-聚苯乙烯)、SEEPS(聚苯乙烯-聚(乙烯-乙烯/丙烯)嵌段-聚苯乙烯)等。 Examples of the styrene-based elastomer include SBS (polystyrene-poly(butylene) block-polystyrene) and SIS (polystyrene-poly(isoprene) block-polystyrene). SIBS (polystyrene-poly(isoprene/butene) block-polyphenylene Aene, SEP (polystyrene-poly(ethylene/propylene) block), SEPS (polystyrene-poly(ethylene/propylene) block-polystyrene), SEBS (polystyrene-poly(ethylene/butyl) Alkene block-polystyrene), SEEPS (polystyrene-poly(ethylene-ethylene/propylene) block-polystyrene), and the like.

作為增黏劑能夠單獨使用或混合使用松香系增黏劑、萜烯系增黏劑及烴系增黏劑,作為液狀低聚物能夠使用丙烯酸系、苯乙烯系、橡膠系和聚酯系的、分子量在數百到數千左右的高黏度聚合體。 As the tackifier, a rosin-based tackifier, a terpene-based tackifier, and a hydrocarbon-based tackifier can be used alone or in combination, and as the liquid oligomer, acrylic, styrene, rubber, and polyester can be used. High viscosity polymers with molecular weights ranging from hundreds to thousands.

當彈性體/增黏劑的比率小於1/0.3時,無法呈現黏合性,無法充分地獲得初期緊密接合力,這作為黏合劑是不理想的。並且,當彈性體/增黏劑的比率小於1/0.3時,對平面顯示器20之接合面形狀或機體30之接合面形狀的追隨性下降,這是不理想的。 When the ratio of the elastomer/tackifier is less than 1/0.3, the adhesiveness cannot be exhibited, and the initial intimate bonding force cannot be sufficiently obtained, which is not preferable as the binder. Further, when the ratio of the elastomer/tackifier is less than 1/0.3, the followability to the joint surface shape of the flat display 20 or the joint surface shape of the body 30 is lowered, which is not preferable.

相反地,當彈性體/增黏劑的比率大於1/1時,雖然能充分地呈現出黏合性,但黏合層的內聚力下降,在再加工中進行剝離時,黏合層會引起內聚破壞,一部分黏合層會殘留在平面顯示器20之接合面或機體30之接合面的一部分上。這樣一來,在接下來的製程中需要費時費力來將黏合層從平面顯示器20的接合面或機體30的接合面上剝下來,這是不理想的。 On the contrary, when the ratio of the elastomer/tackifier is more than 1/1, although the adhesiveness can be sufficiently exhibited, the cohesive force of the adhesive layer is lowered, and when the peeling is performed during the reworking, the adhesive layer causes cohesive failure. A portion of the adhesive layer may remain on the joint surface of the flat display 20 or a portion of the joint surface of the body 30. As a result, it takes time and effort to peel the adhesive layer from the joint surface of the flat display 20 or the joint surface of the body 30 in the subsequent process, which is not preferable.

此外,當彈性體/增黏劑的比率在上述範圍外時,後述伸長率25%時的抗拉強度不會落在0.5MPa到1.0MPa的範圍內且後述1000%的抗拉強度不會落在3.0MPa到6.0MPa的範圍內,因此無法追隨平面顯示器20之接合面的凹凸或 機體30之接合面的凹凸進行變形,並且在再加工中進行剝離時,黏合層會破裂而使得作業性降低,這是不理想的。 Further, when the ratio of the elastomer/tackifier is outside the above range, the tensile strength at the elongation of 25% described later does not fall within the range of 0.5 MPa to 1.0 MPa, and the tensile strength of 1000% described later does not fall. In the range of 3.0 MPa to 6.0 MPa, it is impossible to follow the unevenness of the joint surface of the flat display 20 or When the unevenness of the joint surface of the body 30 is deformed, and the peeling is performed during the reworking, the adhesive layer is broken and the workability is lowered, which is not preferable.

苯乙烯系彈性體對有機溶劑的溶解性良好,並且該溶解性係可逆的,因此當黏合層係單層構造時,能夠以有機溶劑將模切時大量產生的餘料(切割餘料)都溶解,並且再以塗布的方式將溶解的餘料塗布到被塗布物上,從而再生為黏合層。 The styrene-based elastomer has good solubility in an organic solvent, and the solubility is reversible. Therefore, when the adhesive layer is a single-layer structure, it is possible to use an organic solvent to form a large amount of residual material (cutting residual material) during die-cutting. The solution is dissolved, and the dissolved residue is applied to the object to be coated in a coating manner to be regenerated into an adhesive layer.

在平面顯示器用膠帶10具有基材的情況下,也能夠在只溶解黏合層並將基材分離、回收後,再以塗布方式來再利用溶解的黏合層。像這樣,就本實施方式的平面顯示器用膠帶來說,能夠做到資源的有效利用,對環境是友善的。 When the flat-panel display tape 10 has a base material, the dissolved adhesive layer can be reused by coating only after the adhesive layer is dissolved and the substrate is separated and recovered. As described above, the tape for a flat panel display of the present embodiment can effectively utilize resources and is friendly to the environment.

若黏合層的厚度小於100μm,則對平面顯示器20之接合面形狀或機體30之接合面形狀的追隨性下降,變得難以獲得穩定的防水性。並且,若黏合層的厚度小於100μm,則當平面顯示器20和機體30接合後剝離力作用在平面顯示器20或機體30上時,黏合層的變形量變少,由此,來自於黏合層之變形的作功量下降,從而接合強度下降。 When the thickness of the adhesive layer is less than 100 μm, the followability of the joint surface shape of the flat display 20 or the joint surface shape of the body 30 is lowered, and it becomes difficult to obtain stable water repellency. Further, if the thickness of the adhesive layer is less than 100 μm, when the peeling force acts on the flat display 20 or the body 30 after the flat display 20 and the body 30 are joined, the amount of deformation of the adhesive layer becomes small, thereby causing deformation from the adhesive layer. The amount of work is reduced, so that the joint strength is lowered.

黏合層的厚度更佳為在200μm以上。黏合層的厚度上限因電子裝置的種類而異,例如為1000μm左右。 The thickness of the adhesive layer is more preferably 200 μm or more. The upper limit of the thickness of the adhesive layer varies depending on the type of the electronic device, and is, for example, about 1000 μm .

以塗布方式獲得平面顯示器用膠帶10的情況下,當黏合層的厚度在500μm以上時,可以認為難以進行黏合層的製造。但是,就撒布方式來說,即使黏合層的厚度在500μm以上也能夠進行製造。當以塗布方式來製造厚度200μm以上的黏合層時,能夠通過先形成厚度小於200μm 的黏合層後,再沿著厚度方向貼合幾片該些黏合層的方式來得到不含基材的較厚的黏合層。在該情況下也因為黏合層不含基材,所以黏合層成為單層構造。 When the flat display tape 10 is obtained by coating, when the thickness of the adhesive layer is 500 μm or more, it is considered that it is difficult to manufacture the adhesive layer. However, in terms of the spreading method, it is possible to manufacture even if the thickness of the adhesive layer is 500 μm or more. When the adhesive layer having a thickness of 200 μm or more is produced by coating, the base layer can be formed by first forming an adhesive layer having a thickness of less than 200 μm and then bonding a plurality of the adhesive layers in the thickness direction. Thicker bonding layer of the material. Also in this case, since the adhesive layer does not contain the substrate, the adhesive layer has a single layer structure.

黏合層的表面粗糙度以算數平均粗糙度計為0.1μm以下,且以十點平均粗糙度為1.5μm以下。若黏合層的表面粗糙度大於上述表面粗糙度,則黏合層對於平面顯示器20之接合面或機體30之接合面的平滑表面的接觸性下降,相對於平面顯示器20或機體30需要過度的按壓力或固化時間,這是不理想的。 The surface roughness of the adhesive layer is 0.1 μm or less in terms of arithmetic mean roughness, and the average roughness of ten points is 1.5 μm or less. If the surface roughness of the adhesive layer is greater than the surface roughness, the contact between the adhesive layer and the smooth surface of the joint surface of the flat display 20 or the joint surface of the body 30 is lowered, and an excessive pressing force is required with respect to the flat display 20 or the body 30. Or curing time, which is not ideal.

只要使用PET、PP、PE(聚乙烯)等平滑材料製成的分離膜,並在該分離膜上塗布黏合劑組成物,就能夠使黏合層的表面粗糙度維持在上述數值的範圍內。需要說明的是,使用紙製的分離膜的情況下,由於黏合層的表面粗糙度以算數平均粗糙度計為1.0μm以上、以十點平均粗糙度計為8.0μm以上,平滑性顯著地下降,因此是不理想的。 When a separation film made of a smooth material such as PET, PP, or PE (polyethylene) is used, and a binder composition is applied to the separation film, the surface roughness of the adhesive layer can be maintained within the above numerical range. In the case of using a separation membrane made of paper, the surface roughness of the adhesive layer is 1.0 μm or more in terms of arithmetic mean roughness and 8.0 μm or more in ten-point average roughness, and the smoothness is remarkable. The ground is falling, so it is not ideal.

作為測量黏合層表面的平滑性的方法,能夠使用:接觸式的觸針式表面粗糙度測量儀;非接觸式的雷射顯微鏡;光干涉方式。 As a method of measuring the smoothness of the surface of the adhesive layer, a contact type stylus type surface roughness measuring instrument; a non-contact type laser microscope; and an optical interference method can be used.

算數平均粗糙度Ra是指:從粗糙度曲線中按其平均線方向取樣一段基準長度,求取從該取樣部分的平均線到測量曲線之間的偏差的絕對值的和且進行平均之後所得到的數值。十點平均粗糙度Rz是指:從粗糙度曲線中按其平均線方向取樣一段基準長度,從該取樣部分的平均線起算的、最高的峰頂到第五高峰頂的標高絕對值的平均值與 最低的谷底到第五低谷底的標高絕對值的平均值之和。Ra、Rz都是以μm表示。 The arithmetic mean roughness Ra means that a reference length is sampled from the roughness curve in the mean line direction, and the sum of the absolute values of the deviations from the average line of the sampled portion to the measurement curve is obtained and averaged. The value. The ten-point average roughness Rz refers to: sampling a reference length from the roughness curve in the mean line direction, and the average value of the absolute value from the highest peak to the fifth peak from the average of the sampling portion. The sum of the average values of the absolute values of the elevation from the lowest valley to the fifth bottom. Both Ra and Rz are expressed in μ m .

將厚度為100μm且寬度為25mm的平面顯示器用膠帶10的黏合層壓接在不銹鋼板的表面上時,180度剝離強度為50N以上,並且平面顯示器用膠帶10的黏合層係以界面剝離的狀態從不銹鋼板上剝離下來。若180度剝離強度小於50N,則使邊框部的寬度為0.7mm以下時,平面顯示器用膠帶10的接合強度會低於具有一般發泡體基材的以往的膠帶在寬度為1mm以上時的接合強度,因此是不理想的。180度剝離強度更佳為在60N以上。180度剝離強度的測試方法詳見下文所述。 When the adhesive for the flat-panel display tape 10 having a thickness of 100 μm and a width of 25 mm is bonded to the surface of the stainless steel plate, the 180-degree peeling strength is 50 N or more, and the adhesive layer of the flat-panel display tape 10 is peeled off by the interface. The state is peeled off from the stainless steel plate. When the 180-degree peeling strength is less than 50 N, when the width of the frame portion is 0.7 mm or less, the bonding strength of the flat display tape 10 is lower than that of the conventional tape having a general foam substrate at a width of 1 mm or more. Strength is therefore not ideal. The 180 degree peel strength is more preferably 60 N or more. The test method for the 180 degree peel strength is detailed below.

如果像以往的膠帶那樣具有受剝離力作用時會發生內聚破壞的構造,則為了進行再加工而將膠帶從平面顯示器20或機體30上剝離下來時,一部分膠帶會殘留在平面顯示器20的接合面或機體30的接合面上,在接下來的製程中有必要進行將殘留的膠帶剝離下來的工作,這非常的費時費力,因此是不理想的。 If a structure in which cohesive failure occurs when subjected to a peeling force like a conventional tape, when the tape is peeled off from the flat display 20 or the body 30 for reworking, a part of the tape remains on the flat display 20 On the joint surface of the surface or the body 30, it is necessary to perform the work of peeling off the residual tape in the subsequent process, which is very time consuming and laborious, and thus is not preferable.

為了同時滿足強大的接合強度和界面剝離,有必要邊提高黏合層的接合強度,邊使該黏合層的內聚力大於接合強度。為了實現此目的,在本實施方式中,以具有橡膠彈性的彈性體作為黏合組成物的主原料。而且,為了不降低橡膠彈性地賦予強大的黏合力,彈性體/增黏劑的比率較佳為在上述範圍內。 In order to simultaneously satisfy the strong joint strength and the interface peeling, it is necessary to increase the joint strength of the adhesive layer while making the cohesive force of the adhesive layer larger than the joint strength. In order to achieve this, in the present embodiment, an elastomer having rubber elasticity is used as a main raw material of the binder composition. Further, in order to impart a strong adhesive force without lowering the elasticity of the rubber, the ratio of the elastomer/tackifier is preferably within the above range.

在該實施方式中,厚度為100μm的上述黏合層以啞 鈴狀3號試片進行測試時,伸長率25%時的抗拉強度在0.5MPa以上1.0MPa以下的範圍內。若抗拉強度小於0.5MPa,則黏合層太過柔軟,後述伸長率1000%時的抗拉強度不會落在3.0MPa以上6.0MPa以下的範圍內,當從平面顯示器20或機體30剝離平面顯示器用膠帶10時,平面顯示器用膠帶10會發生內聚破壞,並且在再加工中將平面顯示器用膠帶10剝離下來時,平面顯示器用膠帶10會在剝離途中破裂而導致作業性降低,這是不理想的。 In this embodiment, when the adhesive layer having a thickness of 100 μm is tested with a dumbbell-shaped No. 3 test piece, the tensile strength at an elongation of 25% is in a range of 0.5 MPa to 1.0 MPa. When the tensile strength is less than 0.5 MPa, the adhesive layer is too soft, and the tensile strength at an elongation of 1000%, which will be described later, does not fall within the range of 3.0 MPa to 6.0 MPa, and the flat display is peeled off from the flat display 20 or the body 30. When the tape 10 is used, the flat display display tape 10 is cohesively broken, and when the flat display is peeled off by the tape 10 during the rework, the flat display tape 10 is broken during the peeling process, resulting in a decrease in workability, which is not ideal.

相反地,當黏合層在伸長率25%時的抗拉強度大於1.0MPa時,黏合層的彈性模數過高(太硬),黏合層無法追隨平面顯示器20的凹凸或機體30的凹凸,從而無法確保防水性,這是不理想的。 Conversely, when the tensile strength of the adhesive layer at 25% elongation is greater than 1.0 MPa, the elastic modulus of the adhesive layer is too high (too hard), and the adhesive layer cannot follow the unevenness of the flat display 20 or the unevenness of the body 30, thereby It is not ideal to ensure water resistance.

在該實施方式中,厚度為100μm的黏合層以啞鈴狀3號試片進行測試時,伸長率1000%時的抗拉強度在3.0MPa以上6.0MPa以下的範圍內。若伸長率1000%時的抗拉強度小於3.0MPa,則在再加工中剝離膠帶時,在剝離黏合層的途中黏合層會破裂而導致作業性降低,這是不理想的。相反地,若伸長率1000%時的抗拉強度大於6.0MPa,則黏合層的彈性模數過高,伸長率25%時的抗拉強度不會落在上述0.5MPa以上1.0MPa以下的範圍內,黏合層對平面顯示器20或機體30的初期緊密接合性或凹凸追隨性會下降,這是不理想的。 In this embodiment, when the adhesive layer having a thickness of 100 μm is tested with a dumbbell-shaped No. 3 test piece, the tensile strength at an elongation of 1000% is in the range of 3.0 MPa to 6.0 MPa. When the tensile strength at an elongation of 1000% is less than 3.0 MPa, when the tape is peeled off during the reworking, the adhesive layer is broken during the peeling of the adhesive layer, and workability is lowered, which is not preferable. On the other hand, if the tensile strength at an elongation of 1000% is more than 6.0 MPa, the elastic modulus of the adhesive layer is too high, and the tensile strength at an elongation of 25% does not fall within the above range of 0.5 MPa to 1.0 MPa. The initial adhesion or unevenness of the adhesive layer to the flat display 20 or the body 30 may be lowered, which is not preferable.

平面顯示器用膠帶10的黏接力還能夠按照下述方式測量。將帶寬A被設定為0.5mm的平面顯示器用膠帶10 佈置在50mm×100mm板材的其中一個面的周緣部後,隔著該平面顯示器用膠帶10將該板材接合到100mm×100mm板材的中央部,在將整體冷卻到零下20℃的狀態下,將整體水平地佈置成100mm×100mm板材位於上方,並且僅固定住100mm×100mm板材。在該100mm×100mm板材的中央部先設置好通孔,再在該通孔中穿設重物承接夾具,使該夾具與下方的板(50mm×100mm板材)抵接。平面顯示器用膠帶10具有下述的接合強度,即:當使杜邦式衝擊試驗的下落重物300g落在重物承接夾具上而對下方的板施加衝擊力時,在該重物的下落距離到達30cm之前,下方的板不會從上方的板剝離下來。衝擊試驗方法詳見下文所述。該衝擊試驗的結果顯示出平面顯示器用膠帶10具有的吸収力能夠吸收就連化學強化玻璃都會被破壞那樣大的衝擊。需要說明的是,以具有一般發泡體基材的雙面膠帶進行相同測試時,在重物的下落距離到達30cm之前,下方的板就會從上方的板剝離下來。 The adhesive force of the flat display tape 10 can also be measured in the following manner. Tape 10 for flat panel display with bandwidth A set to 0.5 mm After being disposed on the peripheral portion of one of the faces of the 50 mm × 100 mm plate, the plate is bonded to the central portion of the 100 mm × 100 mm plate with the tape 10 through the flat display, and the whole is cooled to minus 20 ° C. The horizontally arranged 100 mm x 100 mm sheet is located above and only the 100 mm x 100 mm sheet is fixed. A through hole is first provided in a central portion of the 100 mm × 100 mm plate, and a weight receiving jig is bored in the through hole to abut the lower plate (50 mm × 100 mm plate). The flat display display tape 10 has the joint strength, that is, when the drop weight of the DuPont-type impact test is dropped on the weight receiving jig to apply an impact force to the lower plate, the falling distance of the heavy object is reached. Before 30cm, the lower plate will not peel off from the upper plate. The impact test method is described in detail below. As a result of the impact test, it was revealed that the flat-bed display tape 10 has an absorption force capable of absorbing as much impact as the chemically strengthened glass is destroyed. It should be noted that when the same test was carried out with a double-sided tape having a general foam substrate, the lower plate was peeled off from the upper plate before the falling distance of the weight reached 30 cm.

本實施方式的平面顯示器用膠帶10所具有的良好的衝擊吸収力係起因於例如:構成平面顯示器用膠帶10黏合層的黏合組成物的主成分為伸縮性較大的、具有橡膠彈性的彈性體,該彈性體能夠將衝擊能轉換為熱能;黏合層的厚度厚達100μm以上,通過黏合層變形所吸收的能量大於衝擊能的作功量;對平面顯示器20或機體30的黏合力高達具有一般發泡體基材的以往的雙面膠帶的2倍以上,因此不會從平面顯示器20的接合面或機體30的接合面上剝 離。 The good impact absorption force of the adhesive tape 10 for a flat display of the present embodiment is caused by, for example, a rubber-elastic elastomer having a large stretchable component of the adhesive composition constituting the adhesive layer of the flat display display tape 10 The elastic body can convert the impact energy into heat energy; the thickness of the adhesive layer is more than 100 μm thick, and the energy absorbed by the deformation of the adhesive layer is greater than the work energy of the impact energy; the adhesion to the flat display 20 or the body 30 is as high as Since the conventional double-sided tape of the foam base material is twice or more, it is not peeled off from the joint surface of the flat display 20 or the joint surface of the machine body 30. from.

平面顯示器用膠帶10能夠以下述方法中的任一方法來製造,即:利用塗布方式形成黏合層後切割成規定形狀的方法,該塗布方式係利用具有流動性的黏合劑來覆蓋被塗布物;利用撒布器(dispenser)塗布具有流動性的黏合劑來形成規定形狀黏合層的方法;將具有流動性的黏合劑印刷在被印刷物上來形成規定形狀黏合層的方法。 The flat display display tape 10 can be manufactured by any one of the following methods, that is, a method of forming an adhesive layer by a coating method and then cutting into a predetermined shape by using a fluidity adhesive to cover the coated object; A method of applying a fluidity adhesive to form a predetermined shape of an adhesive layer by using a dispenser, and a method of forming a fluid having a fluidity on a to-be-printed material to form a predetermined shape of an adhesive layer.

在利用塗布方式的情況下,能夠在一般的甲苯或醋酸乙酯等有機溶劑中溶解黏合層材料,並以覆蓋被塗布物的方式塗布來進行塗布後,使有機溶劑蒸發來獲得黏合層,之後,利用切割繪圖機(cutting plotter)或模切來形成窄邊框形狀的膠帶。 In the case of the coating method, the adhesive layer material can be dissolved in an organic solvent such as general toluene or ethyl acetate, and coated with the coating material, and then the organic solvent is evaporated to obtain an adhesive layer. , using a cutting plotter or die cutting to form a tape with a narrow bezel shape.

作為此時的塗布方式,當要一次塗布形成厚膜時,模塗布機(die coater)、缺角輪塗布機(comma coater)和淋幕式塗佈機係有效的,而當要多層地層壓來形成厚膜時,能夠利用一般的輥塗機、反轉式塗佈機、凹版塗布機等。 As a coating method at this time, when a thick film is to be applied at one time, a die coater, a comma coater, and a curtain coater are effective, and when laminated, it is laminated. When a thick film is formed, a general roll coater, a reverse coater, a gravure coater, etc. can be utilized.

在利用撒布方式的情況下,由於黏合組成物具有熱塑性,因此利用熱熔型的撒布裝置,或利用黏合組成物高濃度地在有機溶劑中溶解而成的高黏度溶液來形成窄邊框形狀即可。利用黏合組成物在有機溶劑中溶解而成的高黏度溶液來形成窄邊框形狀的情況下,設置使有機溶劑蒸發的製程。 In the case of using the spreading method, since the bonding composition has thermoplasticity, it is possible to form a narrow frame shape by using a hot-melt type spreading device or a high-viscosity solution in which a bonding composition is dissolved in an organic solvent at a high concentration. . In the case where a high viscosity solution in which an adhesive composition is dissolved in an organic solvent forms a narrow frame shape, a process for evaporating the organic solvent is provided.

在利用印刷方式的情況下,能夠以下述方式來印刷厚膜,即:由於黏合組成物具有熱塑性,因此加熱黏合組成 物使黏合組成物熔融後,使用凹版來印刷厚膜;以熱熔黏合劑、或黏合組成物在有機溶劑中溶解而成的高黏度溶液進行孔版印刷來印刷厚膜。利用黏合組成物在有機溶劑中溶解而成的高黏度溶液來形成邊框的情況下,設置使有機溶劑蒸發的製程。 In the case of using a printing method, a thick film can be printed in such a manner that since the adhesive composition has thermoplasticity, the heat bonding composition is After the adhesive composition is melted, a thick film is printed using a gravure, and a thick film is printed by stencil printing with a high-viscosity solution in which a hot-melt adhesive or a binder composition is dissolved in an organic solvent. In the case where a frame is formed by using a high-viscosity solution in which an adhesive composition is dissolved in an organic solvent, a process of evaporating the organic solvent is provided.

使用模切或切割繪圖機的情況下,黏合層上的與平面顯示器20等黏合的面會成為平整的面。相對於此,使用撒布或印刷方式的情況下,黏合層的截面成為朝上方凸出的半圓柱狀,當往形成的窄邊框形狀黏合層上按壓平面顯示器20或機體30時會是線接觸,由此能夠得到O型環所帶來的密封效果,從而防水性更加提升,因此是理想的。 In the case of using a die-cutting or cutting plotter, the surface of the adhesive layer that is bonded to the flat display 20 or the like becomes a flat surface. On the other hand, when a spreading or printing method is used, the cross section of the adhesive layer is a semi-cylindrical shape that protrudes upward, and when the flat display 20 or the body 30 is pressed against the formed narrow-frame-shaped adhesive layer, it is a line contact. As a result, the sealing effect by the O-ring can be obtained, and the water repellency is further improved, which is desirable.

在使用模切的情況下,具有PET或PP基材的平面顯示器用膠帶10(多層構造)的模切性良好。 In the case of using die-cutting, the flat-panel display tape 10 (multilayer structure) having a PET or PP substrate has good die-cut properties.

當以平面顯示器20和機體30夾住平面顯示器用膠帶10來接合時,為了確保緊密接合性並提高防水性,有必要對平面顯示器20整體施加夾緊力。 When the flat display 20 and the body 30 are sandwiched by the flat display tape 10, it is necessary to apply a clamping force to the entire flat display 20 in order to secure the tightness and improve the waterproofness.

此時,夾緊力的適當數值在0.3MPa以上3.0MPa以下的範圍內。若夾緊力小於0.3MPa,則平面顯示器用膠帶10的整個周邊對平面顯示器20和機體30的緊密接合度不足,變得難以確保防水性。相反地,當夾緊力大於3.0MPa時,則平面顯示器20上承受過多的壓力,有可能導致平面顯示器20損壞,這是不理想的。為了提升平面顯示器用膠帶10的緊密接合性,在不對平面顯示器20產生影響的程度下進行加熱來使平面顯示器用膠帶10固化也是有效的。 At this time, an appropriate value of the clamping force is in the range of 0.3 MPa to 3.0 MPa. When the clamping force is less than 0.3 MPa, the degree of close contact between the flat display 20 and the body 30 is insufficient for the entire periphery of the flat display tape 10, and it becomes difficult to ensure waterproofness. Conversely, when the clamping force is greater than 3.0 MPa, the flat display 20 is subjected to excessive pressure, which may cause damage to the flat display 20, which is not desirable. In order to improve the close adhesion of the flat-panel display tape 10, it is also effective to heat the flat display with the tape 10 without affecting the flat display 20.

【實施例】 [Examples]

以下,對本發明的實施例進行說明,但本發明不受限於實施例。在說明實施例之前,對各項目的測量方法進行說明。 Hereinafter, the embodiments of the present invention will be described, but the present invention is not limited to the embodiments. Before describing the embodiment, the measurement methods of each item will be described.

1.表面粗糙度的測量 1. Measurement of surface roughness

將平面顯示器用膠帶10的分離膜剝離,使用3D測量用雷射顯微鏡(LEXT OSL4000奧林巴斯股份有限公司製)對黏合層的面測量了4mm長的基準長度,測量出算數平均粗糙度Ra和十點平均粗糙度Rz。Ra、Rz都是數值越小代表越平滑。 The separation film of the flat-panel display tape 10 was peeled off, and a reference length of 4 mm was measured on the surface of the adhesive layer using a 3D measurement laser microscope (LEXT OSL4000 Olympus Co., Ltd.), and the arithmetic mean roughness Ra was measured. And ten points average roughness Rz. Ra and Rz are the smaller the value, the smoother the representation.

2.180度剝離強度測試 2.180 degree peel strength test

在平面顯示器用膠帶10的其中一個面上貼合25μm的PET膜(東麗股份有限公司製lumirror)作為背板之後,切割成25mm寬度的長條狀。將PET分離膜剝離並往不銹鋼板(SUS304BA)上僅貼合長度100mm,之後水平地擺放,並在背板面上往返移動2kg的橡膠滾輪兩次,將平面顯示器用膠帶10壓接在不銹鋼板上。 A 25 μm PET film (lumirror manufactured by Toray Industries, Inc.) was attached to one surface of the flat-panel display tape 10 as a back sheet, and then cut into a strip shape having a width of 25 mm. The PET separation membrane was peeled off and attached to a stainless steel plate (SUS304BA) only to a length of 100 mm, and then placed horizontally, and a 2 kg rubber roller was moved back and forth twice on the back plate surface, and the flat display was crimped to the stainless steel with the tape 10 On the board.

在壓接後並在室內放置了24小時之後,在AUTOGRAPH(萬能試驗機;AG-IS島津製作所製)上分別夾住不銹鋼板和平面顯示器用膠帶10的未黏合部分,以300mm/min的速度沿著不銹鋼板的黏合面在180度的方向(剝離方向)上施力來測量了平面顯示器用膠帶10和不銹鋼板的剝離強度。測量值越大代表黏接力越高。 After the pressure was applied and placed indoors for 24 hours, the unbonded portions of the stainless steel plate and the flat display tape 10 were sandwiched at AUTOGRAPH (Universal Testing Machine; AG-IS Shimadzu Manufacturing Co., Ltd.) at a speed of 300 mm/min. The peel strength of the flat display tape 10 and the stainless steel plate was measured by applying a force in a direction of 180 degrees (peeling direction) along the bonding surface of the stainless steel plate. The larger the measured value, the higher the adhesion.

3.抗拉強度測試 3. Tensile strength test

將厚度100μm的黏合層(單層構造)衝裁成啞鈴狀3號試片,將衝裁得到的試片兩端夾持於AUTOGRAPH(萬能試驗機;AG-IS島津製作所製)上,以300mm/min的速度進行拉伸,測量了伸長率25%和伸長率1000%時的抗拉強度。伸長率25%時的抗拉強度作為判斷對平面顯示器20之接合面或機體30之接合面的追隨性時的大體上的基準,伸長率1000%時的抗拉強度作為判斷再加工中的界面剝離性和破裂難度時的大體上的基準。抗拉強度越高代表彈性模數越高。 The adhesive layer (single layer structure) having a thickness of 100 μm was punched out into a dumbbell-shaped test piece No. 3, and both ends of the test piece obtained by punching were clamped on an AUTOGRAPH (Universal Testing Machine; manufactured by AG-IS Shimadzu Manufacturing Co., Ltd.). The tensile strength was measured at a speed of 300 mm/min, and the tensile strength at 25% elongation and 1000% elongation was measured. The tensile strength at an elongation of 25% is a general criterion for judging the followability to the joint surface of the flat display 20 or the joint surface of the body 30, and the tensile strength at an elongation of 1000% is used as an interface for judging rework. A general basis for peelability and difficulty in rupture. The higher the tensile strength, the higher the modulus of elasticity.

4.杜邦式衝擊試驗 4. DuPont impact test

首先,準備厚度0.7mm、縱向長度50mm×橫向長度100mm的長方形化學強化玻璃(康寧公司製Gorilla Glass)。以黑色絲網印刷在該玻璃的其中一面的周緣部整個周向上形成邊框部。然後,在玻璃的邊框部的整個周向上黏貼帶寬A0.5mm的平面顯示器用膠帶10。 First, a rectangular chemically strengthened glass (Gorilla Glass manufactured by Corning Incorporated) having a thickness of 0.7 mm, a longitudinal length of 50 mm, and a lateral length of 100 mm was prepared. A frame portion is formed on the peripheral portion of one of the one side of the glass by black screen printing. Then, the flat display tape 10 having a bandwidth of A0.5 mm was adhered to the entire circumference of the frame portion of the glass.

接著,準備厚度3mm、縱向長度100mm×橫向長度100mm的正方形透明聚碳酸酯板,該聚碳酸酯板在中心處形成有10mm的圓形孔。將聚碳酸酯板疊在化學強化玻璃上的平面顯示器用膠帶10上。也就是說,將寬度0.5mm的平面顯示器用膠帶10佈置在50mm×100mm的化學強化玻璃的板材周緣部上,以平面顯示器用膠帶10將化學強化玻璃的板材和聚碳酸酯板接合在一起。在接合狀態下,以1MPa的夾緊力夾持了30秒。 Next, a square transparent polycarbonate sheet having a thickness of 3 mm, a longitudinal length of 100 mm, and a lateral length of 100 mm was prepared, and the polycarbonate sheet was formed with a circular hole of 10 mm at the center. A polycarbonate sheet was laminated on a flat display tape 10 on a chemically strengthened glass. That is, the flat-panel display tape 10 having a width of 0.5 mm was placed on the peripheral portion of the plate of the chemically strengthened glass of 50 mm × 100 mm, and the plate of the chemically strengthened glass and the polycarbonate plate were bonded together with the tape 10 for the flat display. In the joined state, it was clamped for 30 seconds with a clamping force of 1 MPa.

之後,使用杜邦式衝擊試驗機(TESTER產業股份有限 公司製)進行了衝擊試驗。將接合狀態的化學強化玻璃和聚碳酸酯板在零下20℃冷卻了2小時後,水平地佈置為化學強化玻璃位於下方,在將重物承接夾具插入到聚碳酸酯板的孔內的狀態下,使300g的重物落在重物承接夾具上而對化學強化玻璃施加衝擊。對化學強化玻璃板因為該衝擊而從聚碳酸酯板剝離下來時的重物高度(下落距離)進行了測量。也就是說,重物的高度越高代表耐衝擊性越高。 After that, use the DuPont impact tester (TESTER Industry Limited) The company system) conducted an impact test. After the chemically strengthened glass and the polycarbonate sheet in the joined state were cooled at minus 20 ° C for 2 hours, the chemically strengthened glass was placed horizontally below, and the weight receiving jig was inserted into the hole of the polycarbonate sheet. A weight of 300 g was dropped on the weight receiving jig to apply an impact to the chemically strengthened glass. The height (falling distance) of the weight when the chemically strengthened glass plate was peeled off from the polycarbonate sheet due to the impact was measured. That is to say, the higher the height of the weight, the higher the impact resistance.

5.漏氣試驗 5. Air leak test

首先,準備厚度0.7mm、縱向長度50mm×橫向長度100mm的長方形化學強化玻璃(康寧公司製Gorilla Glass)。以黑色絲網印刷在該玻璃的其中一面的周緣部整個周向上形成邊框部。然後,在玻璃的邊框部的整個周向上黏貼帶寬A0.5mm的平面顯示器用膠帶10。 First, a rectangular chemically strengthened glass (Gorilla Glass manufactured by Corning Incorporated) having a thickness of 0.7 mm, a longitudinal length of 50 mm, and a lateral length of 100 mm was prepared. A frame portion is formed on the peripheral portion of one of the one side of the glass by black screen printing. Then, the flat display tape 10 having a bandwidth of A0.5 mm was adhered to the entire circumference of the frame portion of the glass.

接著,準備厚度3mm、縱向長度100mm×橫向長度100mm的正方形透明聚碳酸酯板,該聚碳酸酯板在中心處形成有10mm的圓形孔。將聚碳酸酯板疊在化學強化玻璃上的平面顯示器用膠帶10上。在該接合狀態下,以1MPa的夾緊力夾持了30秒 Next, a square transparent polycarbonate sheet having a thickness of 3 mm, a longitudinal length of 100 mm, and a lateral length of 100 mm was prepared, and the polycarbonate sheet was formed with a circular hole of 10 mm at the center. A polycarbonate sheet was laminated on a flat display tape 10 on a chemically strengthened glass. In this engaged state, it is clamped for 30 seconds with a clamping force of 1 MPa.

以連接有空氣軟管的橡皮塞在氣密狀態下塞住聚碳酸酯板的圓孔,在該狀態下將化學強化玻璃和聚碳酸酯板放入水中,在化學強化玻璃和聚碳酸酯板之間施加0.02MPa的空氣壓力,對空氣是否從接合部分洩漏進行了確認,試驗時間最長為12分鐘。也就是說,時間越長代表防水性越高。該空氣壓力相當於水深2m時的水壓。 A rubber plug to which an air hose is attached is used to plug the circular hole of the polycarbonate sheet in an airtight state, and in this state, the chemically strengthened glass and the polycarbonate sheet are placed in water, in chemically strengthened glass and polycarbonate sheet. An air pressure of 0.02 MPa was applied between them to confirm whether the air leaked from the joint portion, and the test time was up to 12 minutes. That is to say, the longer the time, the higher the water resistance. This air pressure corresponds to the water pressure at a water depth of 2 m.

在表1中,對比示出了本發明實施例的平面顯示器用膠帶10的基礎試驗結果和比較例1的基礎試驗結果。 In Table 1, the comparison shows the basic test results of the tape 10 for flat panel display of the embodiment of the present invention and the basic test results of Comparative Example 1.

在表2中,示出了將本發明實施例的平面顯示器用膠帶10模切為規定形狀且模切為寬度0.5mm後進行了試驗的結果,並且對比示出了比較例1的試驗結果。比較例1 的一般的發泡基材膠帶的寬度定為1.0mm。 In Table 2, the results of tests conducted by die-cutting the flat-panel display tape 10 of the embodiment of the present invention into a predetermined shape and die-cutting to a width of 0.5 mm are shown, and the test results of Comparative Example 1 are shown in comparison. Comparative example 1 The width of the general foamed substrate tape was set to 1.0 mm.

【實施例1】 [Example 1]

將苯乙烯-丁二烯-苯乙烯共聚物即所謂的SBS(Kraton製D-1118)56重量份和SBS(JSR股份有限公司製TR2601)44重量份、以及作為增黏劑的萜烯酚醛樹脂(YASUHARA CHEMICAL股份有限公司製YS PolysterT-115)50重量份、油(股份有限公司可樂麗製LBR-305)10重量份、抗氧化劑(Ciba Japan股份有限公司製IRGANOX 1010)1重量份溶解到甲苯中,製備了固體成分占40重量%的黏合劑溶液。 56 parts by weight of a styrene-butadiene-styrene copolymer, so-called SBS (D-1118 manufactured by Kraton), and 44 parts by weight of SBS (TR2601 manufactured by JSR Co., Ltd.), and a terpene phenol resin as a tackifier. 50 parts by weight of YS Polyster T-115 (YASUHARA CHEMICAL CO., LTD.), 10 parts by weight of oil (LBR-305 manufactured by Kura Co., Ltd.), and 1 part by weight of an antioxidant (IRGANOX 1010 manufactured by Ciba Japan Co., Ltd.) were dissolved in toluene. Among them, a binder solution having a solid content of 40% by weight was prepared.

使用塗敷器(applicator)在38μmPET分離膜(SBK-1 Fujico股份有限公司製)上塗布上述黏合劑溶液並使該黏合劑溶液乾燥,使乾燥膜厚成為100μm,從而製作成單層的膠帶,將兩片單層的膠帶貼合在一起而製作成不含基材的200μm的膠帶。 The adhesive solution was applied onto a 38 μm PET separation membrane (manufactured by SBK-1 Fujico Co., Ltd.) using an applicator, and the binder solution was dried to have a dry film thickness of 100 μm to prepare a single sheet. A layer of tape is used to bond two sheets of single-layer tape together to form a 200 μm tape without a substrate.

以上述1的方法測量了黏合層的表面粗糙度,結果是:Ra為0.05μm、Rz為1.3μm,得到了非常平滑的黏合面。 The surface roughness of the adhesive layer was measured by the method described above, and as a result, Ra was 0.05 μm and Rz was 1.3 μm , and a very smooth adhesive surface was obtained.

接著,按照上述2的方法測量了180度的剝離強度,結果是:剝離強度為65N,得到了充分的接合強度。 Next, the peel strength of 180 degrees was measured by the method of the above 2, and as a result, the peel strength was 65 N, and sufficient joint strength was obtained.

還按照上述3的方法測量了伸長率25%和伸長率1000%時的抗拉強度,結果是:伸長率25%時的抗拉強度為1.0MPa,伸長率1000%時的抗拉強度為5.5MPa,黏合層雖然柔軟但不容易彎折,以手指拉扯也不容易破裂。 The tensile strength at 25% elongation and 1000% elongation was also measured according to the method of the above 3, and as a result, the tensile strength at an elongation of 25% was 1.0 MPa, and the tensile strength at an elongation of 1000% was 5.5. MPa, although the adhesive layer is soft, it is not easy to bend, and it is not easy to be broken by pulling with a finger.

將實施例1的平面顯示器用膠帶10衝裁成帶寬A0.5mm、外周長50mm×100mm的邊框形狀,以上述4的方法進行了衝擊試驗,結果是:在重物高度到達40cm之前,化學強化玻璃都不會從聚碳酸酯板上剝離,當重物高度到達40cm時,化學強化玻璃被破壞了。也就是說,能夠得到充分的接合強度。 The flat panel display tape 10 of Example 1 was punched out into a frame shape having a width A of 0.5 mm and an outer circumference of 50 mm × 100 mm, and an impact test was carried out by the above method. As a result, chemical strengthening was performed before the height of the weight reached 40 cm. None of the glass was peeled off from the polycarbonate sheet, and when the weight reached 40 cm, the chemically strengthened glass was broken. That is to say, sufficient joint strength can be obtained.

按照上述5的試驗方法,使用實施例1的平面顯示器用膠帶10進行了漏氣試驗,結果是:在12分鐘內施加了空氣壓力,但在水中沒有發現氣泡。 According to the test method of the above 5, the air leakage test was carried out using the flat display tape 10 of Example 1, and as a result, air pressure was applied within 12 minutes, but no air bubbles were observed in the water.

【實施例2】 [Example 2]

將苯乙烯-丁二烯-苯乙烯共聚物即所謂的SBS(Kraton製D-1118)80重量份、SBS(JSR股份有限公司製TR2601)10重量份和SBS(Kraton製D-1170BT)10重量份、以及作為增黏劑的萜烯酚醛樹脂(YASUHARA CHEMICAL股份有限公司製YS PolysterT-115)50重量份、油(股份有限公司可樂麗製LBR-305)10重量份、抗氧化劑(Ciba Japan股份有限公司製IRGANOX 1010)1重量份溶解到甲苯中,製備了固體成分占40重量%的黏合劑溶液。 80 parts by weight of a styrene-butadiene-styrene copolymer, so-called SBS (D-1118 manufactured by Kraton), 10 parts by weight of SBS (TR2601 manufactured by JSR Co., Ltd.), and 10 parts by weight of SBS (D-1170BT manufactured by Kraton) And 50 parts by weight of terpene phenolic resin (YS Polyhast Chemical Co., Ltd. YS Polyster T-115) as a tackifier, 10 parts by weight of oil (LBR-305 manufactured by Kuraray Co., Ltd.), and antioxidant (Ciba Japan shares) 1 part by weight of IRGANOX 1010) was dissolved in toluene to prepare a binder solution having a solid content of 40% by weight.

以塗敷器將上述黏合劑溶液塗到38μm易黏接PET膜(A-4300東洋紡股份有限公司製)的兩面上,使乾燥膜厚成為100μm,以38μmPET分離膜(SBK-1 Fujico股份有限公司製)將其夾住,利用橡膠滾輪從分離膜上方進行壓接,製作成在基材的兩面上具有黏合層的、多層構造的平面顯示器用膠帶10。 The above adhesive solution was applied to both sides of a 38 μm easy-adhering PET film (A-4300 Toyobo Co., Ltd.) by an applicator to make a dry film thickness of 100 μm, and a 38 μm PET separation membrane (SBK-1 Fujico Co., Ltd.) The film was sandwiched between the separation film by a rubber roller, and a tape 10 for a flat display having a multilayer structure having an adhesive layer on both surfaces of the substrate was produced.

與實施例1同樣地測量了黏合層的表面粗糙度,結果是:Ra為0.03μm、Rz為1.0μm,得到了非常平滑的黏合面。 The surface roughness of the adhesive layer was measured in the same manner as in Example 1. As a result, Ra was 0.03 μm and Rz was 1.0 μm , and a very smooth adhesive surface was obtained.

接著,測量了180度的剝離強度,結果是:剝離強度為58N,得到了充分的接合強度。還測量了伸長率25%和伸長率1000%時的抗拉強度,結果是:伸長率25%時的抗拉強度為0.6MPa,伸長率1000%時的抗拉強度為3.5MPa,黏合層雖然柔軟但不容易彎折,以手指拉扯也不容易破裂。 Next, the peel strength of 180 degrees was measured, and as a result, the peel strength was 58 N, and sufficient joint strength was obtained. The tensile strength at an elongation of 25% and an elongation of 1000% was also measured, and as a result, the tensile strength at an elongation of 25% was 0.6 MPa, and the tensile strength at an elongation of 1000% was 3.5 MPa, although the adhesive layer was It is soft but not easy to bend, and it is not easy to break with fingers.

將實施例2的平面顯示器用膠帶10衝裁成帶寬A0.5mm、外周長50mm×100mm的邊框形狀,以上述4的方法進行了衝擊試驗,結果是:在重物高度到達40cm之前,化學強化玻璃都不會從聚碳酸酯板上剝離,當重物高度到達40cm時,化學強化玻璃被破壞了。也就是說,能夠得到充分的接合強度。 The flat panel display of Example 2 was punched out into a frame shape having a width A of 0.5 mm and an outer circumference of 50 mm × 100 mm, and an impact test was carried out by the above-described method. As a result, chemical strengthening was performed before the height of the weight reached 40 cm. None of the glass was peeled off from the polycarbonate sheet, and when the weight reached 40 cm, the chemically strengthened glass was broken. That is to say, sufficient joint strength can be obtained.

還進行了漏氣試驗,結果是:在12分鐘內施加了空氣壓力,但在水中沒有發現氣泡 A gas leak test was also performed, and as a result, air pressure was applied within 12 minutes, but no air bubbles were found in the water.

【實施例3】 [Example 3]

以樹脂滾輪(KANSAI ROLL股份有限公司製)在130℃的溫度下將苯乙烯-丁二烯-苯乙烯共聚物即所謂的SBS(Kraton製D-1118)56重量份和SBS(JSR股份有限公司製TR2601)44重量份、以及作為增黏劑的萜烯酚醛樹脂(YASUHARA CHEMICAL股份有限公司製YS PolysterT-115)50重量份、油(股份有限公司可樂麗製 LBR-305)10重量份、抗氧化劑(Ciba Japan股份有限公司製IRGANOX 1010)1重量份混煉而得到樹脂塊。 A styrene-butadiene-styrene copolymer, so-called SBS (D-1118 manufactured by Kraton), 56 parts by weight and SBS (JSR Co., Ltd.) at a temperature of 130 ° C using a resin roller (manufactured by KANSAI ROLL Co., Ltd.) 44 parts by weight of TR2601) and a terpene phenolic resin (YS Polytera T-115, manufactured by YASUHARA CHEMICAL CO., LTD.) as a tackifier, 50 parts by weight, oil (manufactured by Kura Co., Ltd.) LBR-305) 10 parts by weight of an antioxidant (IRGANOX 1010 manufactured by Ciba Japan Co., Ltd.) was kneaded in an amount of 1 part by weight to obtain a resin block.

將樹脂塊溶解到有機溶劑中並塗布,就能得到180度剝離強度和25%、1000%抗拉強度與實施例1的性能相同的膠帶。 The resin block was dissolved in an organic solvent and coated to obtain a tape having a 180-degree peel strength and a 25%, 1000% tensile strength which was the same as that of Example 1.

將黏合劑組成物裝填到熱熔撒布器(DP300S股份有限公司SUNTOOL製)內,在溫度150℃下使其熔融。使用該撒布器,沿著化學強化玻璃的外周以噴嘴速度10mm/sec塗布了黏合劑組成物,使塗布的黏合劑組成物的寬度為0.7mm且使從化學強化玻璃塗布面起算的黏合劑組成物的高度為300μm,結果是在化學強化玻璃和環境的吸熱作用下,黏合劑組成物立刻固化了。固化後的黏合劑組成物成為平面顯示器用膠帶10。 The adhesive composition was placed in a hot melt spreader (manufactured by DP300S Co., Ltd., manufactured by SUNTOOL Co., Ltd.), and melted at a temperature of 150 °C. Using the spreader, the adhesive composition was applied at a nozzle speed of 10 mm/sec along the outer periphery of the chemically strengthened glass so that the width of the applied adhesive composition was 0.7 mm and the adhesive composed from the chemically strengthened glass coated surface was composed. The height of the object is 300 μm , and as a result, the binder composition solidifies immediately under the heat absorption of the chemically strengthened glass and the environment. The cured adhesive composition becomes the tape 10 for flat display.

接著,與實施例1同樣地測量了平面顯示器用膠帶10的最高處的表面粗糙度,結果是Ra為0.08μm、Rz為1.4μm。在衝擊試驗和漏氣試驗中得到了與實施例1相同的結果。 Next, the surface roughness of the highest portion of the flat display tape 10 was measured in the same manner as in Example 1. As a result, Ra was 0.08 μm and Rz was 1.4 μm . The same results as in Example 1 were obtained in the impact test and the gas leak test.

【實施例4】 [Embodiment 4]

在130℃的溫度下將苯乙烯-丁二烯-苯乙烯共聚物即所謂的SBS(Kraton製D-1118)80重量份、SBS(JSR股份有限公司製TR2601)10重量份和SBS(Kraton製D-1170BT)10重量份、以及作為增黏劑的萜烯酚醛樹脂(YASUHARA CHEMICAL股份有限公司製YS PolysterT-115)50重量份、油(股份有限公司可樂麗製LBR-305)10重量份、抗 氧化劑(Ciba Japan股份有限公司製IRGANOX 1010)1重量份混煉而得到樹脂塊。 80 parts by weight of a styrene-butadiene-styrene copolymer, so-called SBS (D-1118 manufactured by Kraton), 10 parts by weight of SBS (TR2601 manufactured by JSR Co., Ltd.) and SBS (manufactured by Kraton) at a temperature of 130 °C 10 parts by weight of D-1170BT), and 50 parts by weight of a terpene phenol resin (YS Polyhast Chemical Co., Ltd. YS Polyster T-115) as a tackifier, and 10 parts by weight of oil (LBR-305 manufactured by Kuraray Co., Ltd.) anti- 1 part by weight of an oxidizing agent (IRGANOX 1010, manufactured by Ciba Japan Co., Ltd.) was kneaded to obtain a resin block.

將樹脂塊溶解到有機溶劑中並塗布,就能得到180度剝離強度和25%、1000%抗拉強度與實施例2的性能相同的膠帶。 The resin block was dissolved in an organic solvent and coated to obtain a tape having a 180-degree peel strength and a 25%, 1000% tensile strength which was the same as that of Example 2.

在直徑20cm的金屬製旋轉圓筒(凹版印刷裝置)的周面上雕刻了與上述化學強化玻璃的邊框形狀對應的框狀,該框狀的深度為400μm、寬度為3mm。 A frame shape corresponding to the frame shape of the chemically strengthened glass was engraved on the circumferential surface of a metal rotating cylinder (gravure printing apparatus) having a diameter of 20 cm, and the frame shape had a depth of 400 μm and a width of 3 mm.

將熱熔盤(hot-melt pan)和圓筒加熱到160℃並將混煉後的樹脂塊放入,使樹脂塊整體熔融。 The hot-melt pan and the cylinder were heated to 160 ° C, and the kneaded resin block was placed to melt the resin block as a whole.

準備厚度38μm的易黏接PET A-4300作為膜狀基材,在該基材的兩面上印刷熔融後的黏合劑組成物,得到單面膜厚為210μm、兩面膜厚為420μm的印刷物。該印刷物成為平面顯示器用膠帶10。 An easy-bond PET A-4300 with a thickness of 38 μm was prepared as a film-like substrate, and the melted adhesive composition was printed on both sides of the substrate to obtain a single-sided film thickness of 210 μm and a double-sided film thickness of 420 μ. Print of m. This printed matter becomes the tape 10 for flat display.

接著,與實施例1同樣地測量了平面顯示器用膠帶10的最高處的表面粗糙度,結果是Ra為0.05μm、Rz為1.4μm。在衝擊試驗和漏氣試驗中得到了與實施例1相同的結果。 Next, the surface roughness of the highest position of the flat display tape 10 was measured in the same manner as in Example 1. As a result, Ra was 0.05 μm and Rz was 1.4 μm . The same results as in Example 1 were obtained in the impact test and the gas leak test.

【比較例1】 [Comparative Example 1]

準備了市面上出售的移動裝置專用發泡基材雙面膠帶(#57125總厚度250μm、PE發泡基材厚度200μm、單面黏合層厚度25μm、日東電工股份有限公司製)。該移動裝置專用發泡基材雙面膠帶使用紙製的分離膜。與實施例1同樣地測量了移動裝置專用發泡基材雙面膠帶的黏合層 的表面粗糙度,結果是:Ra為1.3μm、Rz為17.0μm,黏合層表面的平滑性較低。將移動裝置專用發泡基材雙面膠帶黏貼在平滑的面上之後,為了使整體接觸,需要經過一段固化時間。 Prepared a commercially available foam-coated double-sided tape for mobile devices (#57125 total thickness 250 μm , PE foam substrate thickness 200 μm , single-sided adhesive layer thickness 25 μm , manufactured by Nitto Denko Corporation) ). The foaming substrate double-sided tape for the mobile device uses a paper separation membrane. The surface roughness of the adhesive layer of the foamed base material double-sided tape for a mobile device was measured in the same manner as in Example 1. As a result, Ra was 1.3 μm and Rz was 17.0 μm , and the surface of the adhesive layer was low in smoothness. After the double-sided tape of the foaming substrate for the mobile device is adhered to the smooth surface, it takes a certain curing time to make the whole contact.

與實施例1同樣地進行了剝離強度試驗,結果是:剝離強度較低,為20N。 The peel strength test was carried out in the same manner as in Example 1. As a result, the peel strength was low and was 20 N.

移動裝置專用發泡基材雙面膠帶的寬度定為1.0mm,與實施例1同樣地模切成為邊框形狀後,進行了上述4的杜邦式衝擊試驗,當重物高度為16cm時玻璃板剝離了。 The width of the double-coated tape for the foaming substrate for the mobile device was set to 1.0 mm, and after molding into a frame shape in the same manner as in Example 1, the Dupont impact test of the above 4 was carried out, and when the weight height was 16 cm, the glass plate was peeled off. It is.

還與實施例1同樣地進行了漏氣試驗,結果是:在試驗開始進行2分鐘後出現了氣泡。這可以認為是因為發泡體基材柔軟而物理性的力較弱,無法抵抗空氣壓力所致。 Further, a gas leakage test was conducted in the same manner as in Example 1. As a result, bubbles appeared two minutes after the start of the test. This is considered to be because the foam substrate is soft and the physical force is weak and cannot withstand the air pressure.

上述實施方式從各個方面來看都只是示例,不得作限定的解釋。並且,在專利範圍的均等範圍內的變形或修改都包含在本發明的範圍內。 The above embodiments are merely examples in all respects and are not to be construed as limiting. Further, variations or modifications within the equivalent scope of the patent range are included in the scope of the invention.

〔產業上的可利用性〕 [Industrial Availability]

如上所述,本發明的平面顯示器用膠帶例如能夠用於接合電子裝置的平面顯示器和機體。 As described above, the flat panel display tape of the present invention can be used, for example, for bonding a flat display of an electronic device and a body.

1‧‧‧智慧型手機 1‧‧‧Smart mobile phone

10‧‧‧平面顯示器用膠帶 10‧‧‧Panel for flat panel display

20‧‧‧平面顯示器 20‧‧‧ flat panel display

30‧‧‧機體 30‧‧‧ body

Claims (6)

一種平面顯示器用膠帶,其用於接合平面顯示器和機體,其特徵在於:該平面顯示器用膠帶形成為帶寬0.7mm以下的邊框形狀,具有與上述平面顯示器之接合面黏合的黏合層,上述黏合層的厚度設定為100μm以上,上述黏合層的表面粗糙度以算數平均粗糙度計為0.1μm以下,並且以十點平均粗糙度計為1.5μm以下。 A flat panel display tape for bonding a flat panel display and a body, wherein the flat panel display is formed of a tape having a width of 0.7 mm or less and having an adhesive layer bonded to a joint surface of the flat display, the adhesive layer The thickness of the adhesive layer is set to be 100 μm or more, and the surface roughness of the above-mentioned adhesive layer is 0.1 μm or less in terms of arithmetic mean roughness and 1.5 μm or less in terms of ten-point average roughness. 如請求項1項所記載之平面顯示器用膠帶,其中:將形成為厚度100μm且寬度25mm的上述黏合層壓接在不銹鋼板的表面時,180度剝離強度為50N以上,並且剝離狀態為界面剝離,厚度為100μm的上述黏合層以啞鈴狀3號試片進行測試時,伸長率25%時的抗拉強度在0.5MPa以上1.0MPa以下的範圍內。 The tape for a flat-panel display according to claim 1, wherein when the adhesive layer formed to have a thickness of 100 μm and a width of 25 mm is attached to the surface of the stainless steel plate, the 180-degree peel strength is 50 N or more, and the peeling state is When the interface was peeled off and the adhesive layer having a thickness of 100 μm was tested with a dumbbell-shaped No. 3 test piece, the tensile strength at an elongation of 25% was in the range of 0.5 MPa to 1.0 MPa. 如請求項1項所記載之平面顯示器用膠帶,其中:該膠帶具有下述的接合強度,即:將寬度0.5mm的上述膠帶佈置在50mm×100mm的兩片板材的周緣部之間,以上述膠帶接合該兩片板材,在冷卻到零下20℃的狀態下,水平地佈置該兩片板材並固定上方的板材,當使杜邦式衝擊試驗的下落重物300g落在下 方的板材上時,在該重物的下落距離到達30cm之前,上述下方的板材不會從上方的板材剝離。 The tape for a flat panel display according to claim 1, wherein the tape has a bonding strength, that is, a tape having a width of 0.5 mm is disposed between peripheral portions of two sheets of 50 mm × 100 mm, The two sheets of the sheet were joined by a tape, and the two sheets were horizontally arranged and fixed to the upper sheet while being cooled to minus 20 ° C, when the weight of the DuPont-type impact test 300 g was dropped. In the case of a square plate, the lower plate is not peeled off from the upper plate until the falling distance of the weight reaches 30 cm. 如請求項1項所記載之平面顯示器用膠帶,其中:厚度為100μm的上述黏合層以啞鈴狀3號試片進行測試時,伸長率1000%時的抗拉強度在3.0MPa以上6.0MPa以下的範圍內。 The tape for a flat display according to the item 1 of the present invention, wherein the adhesive layer having a thickness of 100 μm is tested with a dumbbell-shaped test piece No. 3, and the tensile strength at an elongation of 1000% is 3.0 MPa or more and 6.0 MPa. Within the scope below. 如請求項1項所記載之平面顯示器用膠帶,其中:上述黏合層的組成物係彈性體與增黏劑的重量比率在1/0.3以上1/1以下的範圍內的組成物,上述彈性體為苯乙烯系彈性體且具有可逆性。 The tape for a flat panel display according to the above aspect, wherein the composition of the adhesive layer is a composition in which a weight ratio of the elastomer to the tackifier is in a range of 1/0.3 or more and 1/1 or less, the elastomer It is a styrene elastomer and is reversible. 如請求項1項所記載之平面顯示器用膠帶,其中:該平面顯示器用膠帶係由以下方法中的任一方法製造,即:利用塗布方式形成上述黏合層後切割成規定形狀的方法,該塗布方式係利用具有流動性的黏合劑來覆蓋被塗布物;利用撒布器塗布具有流動性的黏合劑來形成規定形狀的上述黏合層的方法;以及將具有流動性的黏合劑印刷在被印刷物上來形成規定形狀的上述黏合層的方法。 The tape for a flat-panel display according to claim 1, wherein the flat-panel display tape is produced by any one of the following methods, that is, a method of forming the adhesive layer by a coating method and then cutting into a predetermined shape, the coating The method uses a fluidity adhesive to cover the object to be coated; a method of applying a fluidity adhesive to form the adhesive layer of a predetermined shape by using a spreader; and printing a fluidity adhesive on the object to be printed. A method of defining the above-described adhesive layer in a shape.
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