TW201447294A - Sensor for detecting a gas content - Google Patents

Sensor for detecting a gas content Download PDF

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TW201447294A
TW201447294A TW103109844A TW103109844A TW201447294A TW 201447294 A TW201447294 A TW 201447294A TW 103109844 A TW103109844 A TW 103109844A TW 103109844 A TW103109844 A TW 103109844A TW 201447294 A TW201447294 A TW 201447294A
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Taiwan
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sensor
sensor body
sleeve
electrode chamber
longitudinal axis
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TW103109844A
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Chinese (zh)
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Johannes Ante
Philippe Grass
Markus Hien
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Continental Automotive Gmbh
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/403Cells and electrode assemblies
    • G01N27/406Cells and probes with solid electrolytes
    • G01N27/407Cells and probes with solid electrolytes for investigating or analysing gases
    • G01N27/4077Means for protecting the electrolyte or the electrodes
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/403Cells and electrode assemblies
    • G01N27/406Cells and probes with solid electrolytes
    • G01N27/4067Means for heating or controlling the temperature of the solid electrolyte

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Molecular Biology (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Measuring Oxygen Concentration In Cells (AREA)

Abstract

The invention relates to a sensor (S) for detecting a gas content in the environment of the sensor (S). The sensor (S) comprises a sensor body (SK), an electrode chamber (EK), which is formed in the sensor body (SK), a heating element, which is embedded in the sensor body (SK), a longitudinal axis (L), an end face (SF) of the sensor body (SK) extending substantially perpendicularly to the longitudinal axis (L), an inlet channel (EAK), which is coupled to the electrode chamber (EK) and has an inlet (EA) at the surface of the sensor body (SK), and a thermal insulation sleeve (IH) on the sensor body (SK), which thermal insulation sleeve extends at least axially in the direction of the longitudinal axis (L) over the region of the electrode chamber (EK).

Description

用於檢測氣體含量的感測器 Sensor for detecting gas content

本發明涉及一種於感測器之環境中用於檢測氣體含量的感測器。 The present invention relates to a sensor for detecting gas content in the environment of a sensor.

氣體感測器(特別是氧感測器)使用在內燃機(例如,鄂圖(Otto)馬達或笛塞爾(Diesel)馬達)之吸氣側翼或廢氣側翼中。此種氧感測器例如是線性藍博德(Lambda)感測器。此種感測器當然對熱衝擊是敏感的。例如,若一水滴觸及該感測器之敏感部份,則該部份在大部份情況下將受損。 Gas sensors (especially oxygen sensors) are used in the intake flank or exhaust flank of an internal combustion engine (eg, an Otto motor or a Diesel motor). Such an oxygen sensor is, for example, a linear Lambda sensor. Such sensors are of course sensitive to thermal shock. For example, if a water droplet touches a sensitive part of the sensor, the part will be damaged in most cases.

本發明的目的是提供一種感測器,其具有良好的熱衝擊安全性。 It is an object of the present invention to provide a sensor that has good thermal shock safety.

上述目的藉由申請專利範圍獨立項之特徵來達成。有利的構成顯示在申請專利範圍的附屬項中。 The above objects are achieved by the features of the independent patent application scope. Advantageous configurations are shown in the dependents of the scope of the patent application.

本發明的特徵為一種於感測器之環境中用於檢測氣體含量的感測器。此種感測器包含一感測器主體。此感測器另包含一電極室,其形成於該感測器主體中。該感測器包含一加熱元件,其埋置於該感測器主體中,藉此可使該電極室周圍的預設區加熱至一預設的操作溫度。該感 測器包含一縱軸和該感測器主體之一基本上垂直於該縱軸而延伸之正面。此外,該感測器包含一入口通道,其是與該電極室相耦接且在該感測器主體之表面上具有一入口。又,該感測器包含一在該感測器主體上之熱隔離套筒,其至少在軸向上在該縱軸的方向中在該電極室的區域上延伸。 A feature of the invention is a sensor for detecting gas content in the environment of a sensor. Such a sensor includes a sensor body. The sensor further includes an electrode chamber formed in the sensor body. The sensor includes a heating element embedded in the sensor body whereby the predetermined area around the electrode chamber is heated to a predetermined operating temperature. The feeling The detector includes a longitudinal axis and a front surface of one of the sensor bodies extending substantially perpendicular to the longitudinal axis. Additionally, the sensor includes an inlet channel coupled to the electrode chamber and having an inlet on a surface of the sensor body. Furthermore, the sensor comprises a thermal isolating sleeve on the body of the sensor which extends at least in the axial direction in the direction of the longitudinal axis over the region of the electrode chamber.

該入口特別是形成在該正面上。或是,該入口亦可形成在一與該正面相鄰的面上。 The inlet is formed in particular on the front side. Alternatively, the inlet may be formed on a face adjacent to the front side.

藉由該電極室之區域中的熱隔離,該感測器獲得一種很好的熱衝擊耐久性且不會因此使測量速率改變。此外,由於該隔離而使熱傳送大部份都不需藉由對流來進行。於是,可在感測器上接收更多的流量,這樣可使該感測器之反應速率獲得改善。 By thermal isolation in the region of the electrode chamber, the sensor achieves a good thermal shock durability without thereby changing the measurement rate. In addition, most of the heat transfer is not required to be performed by convection due to the isolation. Thus, more flow can be received on the sensor, which can result in improved response rates for the sensor.

一種預設的操作溫度例如是指一種介於600℃和850℃之間的溫度。 A preset operating temperature is, for example, a temperature between 600 ° C and 850 ° C.

依據一有利的形式,該正面未設有該隔離套筒且該隔離套筒預先與該正面相隔開。 According to an advantageous form, the front side is not provided with the separating sleeve and the separating sleeve is previously spaced apart from the front side.

該正面例如須預先相隔開,使得該感測器可輕易地由該隔離套筒突出。以此方式,若該入口形成在該感測器主體之正面上,則氣體的進入將與該隔離套筒不相關。 The front faces, for example, must be spaced apart in advance so that the sensor can easily protrude from the isolating sleeve. In this manner, if the inlet is formed on the front side of the sensor body, the entry of gas will be unrelated to the isolation sleeve.

依據另一有利的形式,該隔離套筒具有陶瓷纖維及/或金屬纖維。 According to another advantageous form, the isolating sleeve has ceramic fibers and/or metal fibers.

這些纖維具有高溫耐久性且因此使導熱性儘可能小。該隔離套筒例如是由大約2毫米厚的陶瓷纖維毛線構成。 These fibers have high temperature durability and thus make thermal conductivity as small as possible. The spacer sleeve is for example composed of ceramic fiber strands approximately 2 mm thick.

依據另一有利的形式,所述陶瓷纖維及/或金屬纖維配置在金屬套筒中。 According to another advantageous form, the ceramic fibers and/or metal fibers are arranged in a metal sleeve.

該金屬套筒例如固定地與該感測器焊接著,這樣可實現一儘可能穩定的隔離套筒。 The metal sleeve is for example fixedly welded to the sensor, so that a spacer sleeve which is as stable as possible is achieved.

依據另一有利的形式,所述陶瓷纖維及/或金屬纖維藉由氣隙而與該金屬套筒相隔開。 According to another advantageous form, the ceramic fibers and/or metal fibers are separated from the metal sleeve by an air gap.

於是,可藉由該氣隙來達成另一隔離作用。 Thus, another isolation can be achieved by the air gap.

本發明的實施例以下將依據圖式來詳述。 Embodiments of the invention will be described in detail below with reference to the drawings.

S‧‧‧感測器 S‧‧‧ sensor

SK‧‧‧感測器主體 SK‧‧‧Sensor body

EK‧‧‧電極室 EK‧‧‧electrode room

BB‧‧‧預設區 BB‧‧‧Preset area

H‧‧‧支件 H‧‧‧Support

K‧‧‧接觸層 K‧‧‧Contact layer

L‧‧‧縱軸 L‧‧‧ vertical axis

SF‧‧‧正面 SF‧‧ positive

DB‧‧‧擴散位障 DB‧‧‧Diffusion

EA‧‧‧入口 EA‧‧ entrance

EAK‧‧‧入口通道 EAK‧‧ Entrance Channel

IH‧‧‧隔離套筒 IH‧‧‧Isolation sleeve

P-‧‧‧第一電極 P-‧‧‧first electrode

P+‧‧‧第二電極 P+‧‧‧second electrode

YSZ‧‧‧釔-穩定化的氧化鋯 YSZ‧‧‧钇-stabilized zirconia

第1圖係一用於檢測氣體含量的感測器。 Figure 1 is a sensor for detecting gas content.

第2圖係該用於檢測氣體含量的感測器。 Figure 2 is a sensor for detecting the gas content.

以下將依據圖式來詳述本發明的實施例。相同構造或功能之元件在各圖式中以相同的參考符號來表示。 Embodiments of the present invention will be described in detail below with reference to the drawings. Elements of the same construction or function are denoted by the same reference numerals throughout the drawings.

第1圖係一於感測器S的環境中用於檢測氣體含量的感測器S。感測器S特別是形成為氧感測器,其在感測器S的環境中可確定氧含量。感測器S包含一感測器主體SK。感測器主體SK例如包含一由釔-穩定化的氧化鋯YSZ構成的基板。電極室EK形成於該感測器主體SK中。此外,感測器主體SK中埋置著一加熱元件,藉此可使該電極室EK周圍之一預設區BB加熱至一預設的操作溫度。此預設的操作溫度例如介於600℃和850℃之間或大約為700℃。 Figure 1 is a sensor S for detecting the gas content in the environment of the sensor S. The sensor S is in particular formed as an oxygen sensor, which determines the oxygen content in the environment of the sensor S. The sensor S includes a sensor body SK. The sensor body SK includes, for example, a substrate composed of yttrium-stabilized zirconia YSZ. An electrode chamber EK is formed in the sensor body SK. Furthermore, a heating element is embedded in the sensor body SK, whereby a predetermined area BB around the electrode chamber EK can be heated to a predetermined operating temperature. This preset operating temperature is, for example, between 600 ° C and 850 ° C or approximately 700 ° C.

此外,感測器S具有一縱軸L和該感測器主體SK之一基本上垂直於該縱軸L而延伸之正面SF。 Furthermore, the sensor S has a longitudinal axis L and a front surface SF of one of the sensor bodies SK extending substantially perpendicular to the longitudinal axis L.

又,感測器主體SK具有一入口通道EAK,其是與該電極室EK相耦接且在該感測器主體SK之表面中具有一入口EA,該入口EA形成在該感測器主體SK之正面SF上。 Further, the sensor body SK has an inlet passage EAK coupled to the electrode chamber EK and having an inlet EA in the surface of the sensor body SK, the inlet EA being formed in the sensor body SK On the front SF.

在該入口EA和該電極室EK之間形成一擴散位障DB,氧可經由此擴散位障DB而擴散至電極室EK中。 A diffusion barrier DB is formed between the inlet EA and the electrode chamber EK, through which oxygen can diffuse into the electrode chamber EK.

此外,感測器S具有熱隔離套筒IH,其形成在感測器主體SK上且至少在軸向上在該縱軸L的方向中在該電極室EK的區域上延伸。 Furthermore, the sensor S has a thermal isolating sleeve IH which is formed on the sensor body SK and extends at least in the axial direction in the direction of the longitudinal axis L over the region of the electrode chamber EK.

第2圖顯示該感測器S之第二種視圖。第2圖說明了感測器S之層形式的構造。第一電極P-係與電極室EK相連接且亦可稱為陰極。在第一電極P-和亦可稱為陽極的第二電極P+之間形成一固體電解質層,其例如藉由釔-穩定化的氧化鋯YSZ來形成。 Figure 2 shows a second view of the sensor S. Figure 2 illustrates the construction of the layer form of the sensor S. The first electrode P-system is connected to the electrode compartment EK and may also be referred to as a cathode. A solid electrolyte layer is formed between the first electrode P- and a second electrode P+, which may also be referred to as an anode, which is formed, for example, by ytterbium-stabilized zirconia YSZ.

感測器S另具有多個接觸層K(請參閱第1圖),其例如用來控制各加熱元件及用來施加電壓以操作該感測器S。 The sensor S further has a plurality of contact layers K (see Fig. 1), which are used, for example, to control the various heating elements and to apply a voltage to operate the sensor S.

此外,感測器S具有一支件H(請參閱第1圖),其亦可用來排熱。此支件H因此例如是由鋁形成且藉由黏合劑而固定在感測器主體SK上。 In addition, the sensor S has a piece H (see Fig. 1) which can also be used to dissipate heat. This support H is thus formed, for example, of aluminum and is fixed to the sensor body SK by an adhesive.

以下將說明該感測器S之作用方式。 The mode of operation of the sensor S will be described below.

為了檢測該感測器S之周圍的氣體含量,須在第一電極P-和第二電極P+之間施加一種例如0.8伏(V) 之電壓差。當陰極下方氧含量調整至0且感測器S安裝在含氧的環境中時,由於環境和陰極(其中幾乎無氧氣存在)下方區域之間的濃度差或分壓差,則氧原子經由擴散位障DB和陰極而擴散至感測器主體SK之基板中。氧原子擴散至感測器主體SK之基板中成為雙倍負充電之離子,其中氧原子離子化所需的電子係由可導電的陰極所提供。在各電極之間所施加的電壓中測量一種差動擴散極限電流(limiting current)。此種電流在含氧的測量氣體中係與氧分壓有關。氧離子在陽極上又轉換成氧原子且經由陽極又擴散至含氧的環境中。就足夠的離子導電性而言,感測器主體SK需要增高的溫度。因此,感測器主體SK藉由該加熱元件而在電極室EK之可加熱區BB中加熱至一預設的操作溫度,例如,此操作溫度介於600℃和850℃之間。 In order to detect the gas content around the sensor S, a kind of, for example, 0.8 volt (V) must be applied between the first electrode P- and the second electrode P+. The voltage difference. When the oxygen content under the cathode is adjusted to 0 and the sensor S is installed in an oxygen-containing environment, the oxygen atoms pass through the diffusion due to the concentration difference or partial pressure difference between the environment and the lower region of the cathode (where almost no oxygen is present). The barrier DB and the cathode diffuse into the substrate of the sensor body SK. The oxygen atoms diffuse into the substrate of the sensor body SK to become double negatively charged ions, wherein the electrons required for ionization of the oxygen atoms are provided by the conductive cathode. A differential diffusion limiting current is measured in the voltage applied between the electrodes. This current is related to the oxygen partial pressure in the oxygen-containing measuring gas. The oxygen ions are again converted to oxygen atoms on the anode and diffused again into the oxygen-containing environment via the anode. In terms of sufficient ionic conductivity, the sensor body SK requires an increased temperature. Therefore, the sensor body SK is heated by the heating element in the heatable region BB of the electrode chamber EK to a predetermined operating temperature, for example, the operating temperature is between 600 ° C and 850 ° C.

為了達成保護作用使不受熱衝擊的影響,感測器S具有上述隔離套筒IH。藉由電極室EK之區域中的熱隔離,該感測器S獲得很好的熱衝擊耐久性且不會因此使測量速率改變。此外,由於該隔離而使熱傳送大部份都不需藉由對流來進行。於是,可在感測器S上接收更多的流量,這樣可使該感測器S之反應速率獲得改善。 In order to achieve a protective effect against thermal shock, the sensor S has the above-described isolating sleeve IH. By thermal isolation in the region of the electrode chamber EK, the sensor S achieves good thermal shock durability and thus does not change the measurement rate. In addition, most of the heat transfer is not required to be performed by convection due to the isolation. Thus, more flow can be received on the sensor S, which can result in an improved reaction rate of the sensor S.

該隔離套筒IH例如具有陶瓷纖維及/或金屬纖維。所述陶瓷纖維及/或金屬纖維例如配置在金屬套筒中。或是,所述陶瓷纖維及/或金屬纖維藉由氣隙而與該金屬套筒相隔開。例如,該隔離套筒IH大致上具有2毫米的厚度。 The isolating sleeve IH has, for example, ceramic fibers and/or metal fibers. The ceramic fibers and/or metal fibers are for example arranged in a metal sleeve. Alternatively, the ceramic fibers and/or metal fibers are separated from the metal sleeve by an air gap. For example, the spacer sleeve IH has a thickness of approximately 2 mm.

該感測器S之正面SF例如未設有該隔離套筒IH且該隔離套筒IH預先與該正面SF相隔開。該正面SF例如須預先相隔開,使得該感測器S可輕易地由該隔離套筒IH突出。於是,該入口EA與該隔離套筒IH不相關,這樣就可使測量不會受影響。 For example, the front side SF of the sensor S is not provided with the isolating sleeve IH and the isolating sleeve IH is previously spaced apart from the front side SF. The front side SF, for example, must be spaced apart in advance so that the sensor S can easily protrude from the isolating sleeve IH. Thus, the inlet EA is not associated with the isolating sleeve IH, so that the measurement is not affected.

S‧‧‧感測器 S‧‧‧ sensor

SK‧‧‧感測器主體 SK‧‧‧Sensor body

EK‧‧‧電極室 EK‧‧‧electrode room

BB‧‧‧預設區 BB‧‧‧Preset area

H‧‧‧支件 H‧‧‧Support

K‧‧‧接觸層 K‧‧‧Contact layer

L‧‧‧縱軸 L‧‧‧ vertical axis

SF‧‧‧正面 SF‧‧ positive

DB‧‧‧擴散位障 DB‧‧‧Diffusion

EA‧‧‧入口 EA‧‧ entrance

EAK‧‧‧入口通道 EAK‧‧ Entrance Channel

IH‧‧‧隔離套筒 IH‧‧‧Isolation sleeve

Claims (5)

一種於感測器(S)環境中用於檢測氣體含量的感測器(S),包含:-感測器主體(SK),-電極室(EK),其形成在該感測器主體(SK)中,-加熱元件,其埋置於該感測器主體(SK)中,藉此可使該電極室(EK)周圍之一預設區(BB)加熱至一預設的操作溫度,-縱軸(L)和該感測器主體(SK)之一基本上垂直於該縱軸(L)而延伸之正面(SF),-入口通道(EAK),其是與該電極室(EK)相耦接且在該感測器主體(SK)之表面上具有一入口(EA),以及-該感測器主體(SK)上之熱隔離套筒(IH),其至少在軸向上在該縱軸(L)的方向中在該電極室(EK)的區域上延伸。 A sensor (S) for detecting a gas content in a sensor (S) environment, comprising: a sensor body (SK), an electrode chamber (EK) formed on the sensor body ( In SK), a heating element embedded in the sensor body (SK), whereby a predetermined area (BB) around the electrode chamber (EK) is heated to a predetermined operating temperature, a front side (SF) extending from a longitudinal axis (L) and one of the sensor body (SK) substantially perpendicular to the longitudinal axis (L), an inlet channel (EAK), which is associated with the electrode chamber (EK) Coupling and having an inlet (EA) on the surface of the sensor body (SK), and a thermal isolation sleeve (IH) on the sensor body (SK), at least in the axial direction The direction of the longitudinal axis (L) extends over the area of the electrode chamber (EK). 如請求項1之感測器(S),其中該正面(SF)未設有該隔離套筒(IH)且該隔離套筒(IH)預先與該正面(SF)相隔開。 The sensor (S) of claim 1, wherein the front side (SF) is not provided with the isolating sleeve (IH) and the isolating sleeve (IH) is previously spaced apart from the front side (SF). 如請求項1或2之感測器(S),其中該隔離套筒(IH)具有陶瓷纖維及/或金屬纖維。 A sensor (S) according to claim 1 or 2, wherein the isolating sleeve (IH) has ceramic fibers and/or metal fibers. 如請求項3之感測器(S),其中所述陶瓷纖維及/或金屬纖維配置在金屬套筒中。 The sensor (S) of claim 3, wherein the ceramic fibers and/or metal fibers are disposed in a metal sleeve. 如請求項4之感測器(S),其中所述陶瓷纖維及/或金屬纖維藉由氣隙而與該金屬套筒相隔開。 The sensor (S) of claim 4, wherein the ceramic fibers and/or metal fibers are separated from the metal sleeve by an air gap.
TW103109844A 2013-03-20 2014-03-17 Sensor for detecting a gas content TW201447294A (en)

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DE102013204943.9A DE102013204943A1 (en) 2013-03-20 2013-03-20 Sensor for detecting a gas content

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DE20004514U1 (en) * 2000-03-10 2001-07-26 Bosch Gmbh Robert Electrochemical sensor
DE10052005C2 (en) * 2000-10-20 2002-11-21 Bosch Gmbh Robert Sensor for gases
DE102004031770A1 (en) * 2004-07-01 2006-01-26 Robert Bosch Gmbh Sensor unit for determining physical parameter of test gas, especially oxygen content of internal combustion engine exhaust gas, has section for fixing protective device to end of solid electrolyte sensor
DE102004054014A1 (en) * 2004-11-09 2006-05-11 Robert Bosch Gmbh ceramic component
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