TW201446731A - 羰基化催化劑及方法 - Google Patents

羰基化催化劑及方法 Download PDF

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Publication number
TW201446731A
TW201446731A TW103107651A TW103107651A TW201446731A TW 201446731 A TW201446731 A TW 201446731A TW 103107651 A TW103107651 A TW 103107651A TW 103107651 A TW103107651 A TW 103107651A TW 201446731 A TW201446731 A TW 201446731A
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Taiwan
Prior art keywords
zeolite
catalyst
carbonylation
directing agent
carbon monoxide
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TW103107651A
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English (en)
Chinese (zh)
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John Glenn Sunley
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Bp Chem Int Ltd
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Publication of TW201446731A publication Critical patent/TW201446731A/zh

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    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/87—Gallosilicates; Aluminogallosilicates; Galloborosilicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
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    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
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    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B01J29/185—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
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    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B01J29/20—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing iron group metals, noble metals or copper
    • B01J29/24—Iron group metals or copper
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    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/50—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the erionite or offretite type, e.g. zeolite T, as exemplified by patent document US2950952
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
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    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
TW103107651A 2013-03-08 2014-03-06 羰基化催化劑及方法 TW201446731A (zh)

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KR (1) KR20150126850A (enExample)
CN (1) CN105339343B (enExample)
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Families Citing this family (13)

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US9708192B2 (en) * 2014-11-25 2017-07-18 Chevron U.S.A. Inc. Method for preparing aluminosilicate molecular sieves having the CHA framework type
WO2018004993A1 (en) 2016-07-01 2018-01-04 Res Usa, Llc Reduction of greenhouse gas emission
WO2018004992A1 (en) 2016-07-01 2018-01-04 Res Usa, Llc Conversion of methane to dimethyl ether
US9938217B2 (en) 2016-07-01 2018-04-10 Res Usa, Llc Fluidized bed membrane reactor
WO2018103089A1 (zh) * 2016-12-09 2018-06-14 中国科学院大连化学物理研究所 合成丝光沸石mor分子筛的方法、及其产品和应用
US10734133B2 (en) * 2018-09-28 2020-08-04 Daikin America, Inc. Fluoropolymer insulated communications cable
CN111790452B (zh) * 2019-04-09 2021-11-23 中国科学院大连化学物理研究所 一种甲醇羰基化催化剂及其制备方法、应用
CN110560150B (zh) * 2019-09-12 2020-09-01 厦门大学 一种甲醇羰基化制乙酸甲酯催化剂及其应用
US12083504B2 (en) 2019-11-14 2024-09-10 The Regents Of The University Of California Catalysts and methods for gas phase carbonylation
CN111905801A (zh) * 2020-08-17 2020-11-10 鲁雪 一种可见光催化剂及其制备方法和应用
CN114516640B (zh) * 2020-11-18 2024-04-16 中国科学院大连化学物理研究所 一种丝光沸石、其制备方法及应用
KR20220148517A (ko) * 2021-04-29 2022-11-07 현대자동차주식회사 디메틸에테르의 가솔린화 반응용 촉매, 이의 제조 방법, 및 이를 이용한 가솔린의 제조 방법
KR102607444B1 (ko) * 2021-07-02 2023-11-30 성균관대학교산학협력단 디메틸에테르의 카르보닐화 반응을 위한 촉매 및 이의 제조 방법

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3606169A1 (de) 1986-02-26 1987-08-27 Basf Ag Verfahren zur herstellung von essigsaeure, methylacetat und/oder dimethylether
KR19990066988A (ko) * 1995-10-24 1999-08-16 그레이스 스티븐 에스. 알루미노실리케이트와 실리카의 다공성을 변화시키는 방법 및이로부터 유도된 메조다공질 조성물
WO2000006494A1 (en) * 1998-07-29 2000-02-10 Exxon Chemical Patents, Inc. Crystalline molecular sieves
GB9816508D0 (en) 1998-07-29 1998-09-23 Exxon Chemical Patents Inc Molecular sieves and processes for their manufacture
IT1314001B1 (it) 1999-11-19 2002-12-03 Enichem Spa Metodo per la rimozione del templante da zeoliti sintetiche
IT1314237B1 (it) * 1999-11-19 2002-12-06 Venezia Tecnologie S P A Procedimento di sintesi diretta di fosfuro di indio
EP1421044B1 (en) * 2001-07-02 2007-03-07 Exxonmobil Chemical Patents Inc. Inhibiting catalyst coke formation in the manufacture of an olefin
US7745678B2 (en) * 2003-03-21 2010-06-29 Uop Llc Alkyl aromatic isomerization process using a catalyst comprising a UZM-8HS composition
GB0409490D0 (en) * 2004-04-28 2004-06-02 Bp Chem Int Ltd Process
CA2602517C (en) 2005-04-04 2013-12-24 Avantium International B.V. System and method for performing a chemical experiment
US7465822B2 (en) * 2005-05-05 2008-12-16 Bp Chemicals Ltd. Process for carbonylation of alkyl ethers
ES2685497T3 (es) * 2006-09-25 2018-10-09 Chevron U.S.A. Inc. Preparación de tamices moleculares utilizando un agente director de estructura y un catión de amonio cuaternario de N,N,N-trialquil bencilo
US7507855B2 (en) 2006-12-15 2009-03-24 The Regents Of The University Of California Process for carbonylation of aliphatic alcohols and/or ester derivatives thereof
RU2458909C2 (ru) 2006-12-15 2012-08-20 Дзе Риджентс Оф Дзе Юниверсити Оф Калифорния Способ карбонилирования алифатических спиртов и/или их реакционноспособных производных
EP1985607A1 (en) 2007-04-26 2008-10-29 BP Chemicals Limited Process for the carbonylation of dimethyl ether
EP2072491A1 (en) 2007-12-17 2009-06-24 BP p.l.c. Process for the conversion of alcohol(s) into alcohol(s) with increased carbon-chain
CN101284673B (zh) 2008-04-24 2011-11-30 中国石油化工股份有限公司 Sapo分子筛的制备方法
EP2251083A1 (en) * 2009-05-14 2010-11-17 BP Chemicals Limited Carbonylation catalyst and process
EP2251082A1 (en) * 2009-05-14 2010-11-17 BP Chemicals Limited Carbonylation catalyst and process
FR2974801B1 (fr) * 2011-05-04 2013-04-26 IFP Energies Nouvelles Procede d'isomerisation d'une coupe c8 aromatique en presence d'un catalyseur specifique constitue par un composite de type zeolithe/carbure de silicium et d'une fonction hydro-deshydrogenante
EP2780284A4 (en) * 2011-11-18 2015-08-26 Basf Se METHOD FOR ION EXCHANGE ON ZEOLITES
TW201441188A (zh) * 2013-03-08 2014-11-01 Bp Chem Int Ltd 羰基化方法(一)
RU2656599C2 (ru) * 2013-03-08 2018-06-06 Бп Кемикэлз Лимитед Способ карбонилирования диметилового эфира
CN104801337A (zh) * 2015-03-19 2015-07-29 沈阳化工大学 一种合成气、二甲醚一步法制备的乙醇催化剂及其制备方法

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WO2014135661A1 (en) 2014-09-12
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SG11201507097VA (en) 2015-10-29
US20160016155A1 (en) 2016-01-21
BR112015021850A2 (pt) 2017-07-18
KR20150126850A (ko) 2015-11-13
RU2696266C2 (ru) 2019-08-01
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US10583426B2 (en) 2020-03-10

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