TW201437309A - Double-faced pressure-sensitive adhesive sheet and wound body - Google Patents

Abstract

A double-faced pressure-sensitive adhesive sheet of the present invention includes a pressure sensitive adhesive layer, a first release film and a second release film. A peel force of the second release film from the pressure sensitive adhesive layer is weaker than a peel force of the first release film from the pressure sensitive adhesive layer. The pressure sensitive adhesive layer is formed by using a pressure sensitive adhesive containing an active energy ray curable resin. A gel fraction of the pressure sensitive adhesive layer just after it is formed is 70% or more. When the gel fraction of the pressure sensitive adhesive layer just after it is formed is defined as X [%] and a gel fraction of the pressure sensitive adhesive layer of 7 days after it is formed is defined as Y [%], the X and Y satisfies a relation of X/Y ≥ 0.9. A ratio of irregularities falling beyond the range of plus or minus 200 nm from a reference plane in a first surface and a second surface of the pressure sensitive adhesive layer is 20% or less. It is possible for such a double-faced pressure-sensitive adhesive sheet to prevent minute irregularities from generating on the surfaces of the pressure sensitive adhesive layer when it is wound in a roll shape and stored.

Description

Double-sided adhesive sheet and rewinder

The present invention relates to a double-sided adhesive sheet and a rewinding body.

An optical functional film system such as a polarizing plate is fixed to a member such as a liquid crystal cell by using a double-sided adhesive sheet made of an adhesive. Wherein, the double-sided adhesive sheet is manufactured, for example, by applying an adhesive on the first release film to form a coating film, and then bonding the second release film to the formed coating film, and then irradiating The coating film is cured by ultraviolet rays or the like to form an adhesive layer. Moreover, the double-sided adhesive sheet thus produced is generally wound into a roll shape (rolling) for storage or handling.

In recent years, in order to improve productivity, the winding length of a double-sided adhesive sheet wound into such a roll shape has gradually increased. Therefore, due to the winding of the long-sized double-sided adhesive sheet, excessive tension is applied during winding, so that the double-sided adhesive sheet is wound up in the core portion of the drum. As a result, problems that did not occur in the past have now occurred in the case where a plurality of minute irregularities (orange peels) are generated on the surface of the adhesive layer.

For this reason, it has been attempted to prevent such an orange peel by making the surface roughness Ra of the release-shaped surface of the release film 100 nm or less (see, for example, Patent Document 1, Japanese Patent Laid-Open Publication No. 2010-185038).

However, with the increase in the length of the drum winding in recent years, the conventional double-sided The adhesive sheet cannot sufficiently prevent the double-sided adhesive sheet from having orange peel on the core portion of the drum.

Moreover, the conventional technique is to apply a polarizing plate with an adhesive to the liquid. The crystal unit is then subjected to an autoclave treatment. However, in recent years, it has been to simplify the process without autoclaving. Therefore, if orange peel is formed in the adhesive layer, there is a possibility that the fine bubbles are mixed and the yield is lowered. Further, if orange peel is formed in the adhesive layer, when the liquid crystal cell with the polarizing plate is assembled in the display, appearance defects occur, resulting in a low yield.

The object of the present invention is to provide a double-sided adhesive sheet and a rewinding body which is formed by bending the double-sided adhesive sheet, and the double-sided adhesive sheet can prevent a plurality of minute irregularities on the surface of the adhesive layer when the roll is rolled into a roll shape. (orange peel).

The object is achieved by the present invention of (1) to (5) below.

(1) A double-sided adhesive sheet comprising an adhesive layer, a first release film, and a second release film. The adhesive layer has a first surface and a second surface. The first release film is attached to the aforementioned first surface of the aforementioned adhesive layer. A second release film is attached to the aforementioned second surface of the adhesive layer. The release force of the second release film peeled off from the adhesive layer is smaller than the release force of the first release film peeled off from the adhesive layer. The adhesive layer is formed using an adhesive containing an active energy ray-curable resin. The gel fraction at the time after the formation of the above adhesive layer is 70% or more. The gel fraction of the current adhesive layer after formation is expressed as X [%] When the gel fraction of the above-mentioned adhesive layer 7 days after the formation of the above-mentioned adhesive layer is expressed as Y [%], the relationship of X/Y ≧ 0.9 is satisfied. The ratio of the unevenness outside the range of ±0.2 μm from the reference surface to the first surface and the second surface of the adhesive layer is 20% or less.

(2) The double-sided adhesive sheet according to (1) above, wherein the aforementioned adhesive When the primer layer was formed at 23 ° C after 7 days, the storage elastic modulus of the adhesive layer was 0.15 MPa or more.

(3) The double-sided adhesive sheet according to (1) or (2) above, wherein The surface of the first release film and the second release film in the opposite direction to the surface in contact with the adhesive layer has an arithmetic mean roughness Ra of 50 nm or less and a maximum protrusion height Rp of 1000 nm or less.

(4) Double-sided adhesive as described in one of the above (1) to (3) a sheet in which the release force of the first release film peeled off from the adhesive layer is expressed as X [mN/25 mm], and the release force of the second release film peeled off from the adhesive layer is expressed When Y[mN/25mm], the relationship of XY≧5 is satisfied.

(5) A rewinding body as described in (1) to (4) above One of the double-sided adhesive sheets is rolled and formed.

According to the present invention, it is possible to provide a double-sided adhesive sheet which can be used, for example, for pasting An optical functional film body such as a polarizing plate is attached, and when the double-sided adhesive sheet is wound into a roll shape (rolling) for storage, a plurality of minute irregularities are prevented from occurring on the surface of the adhesive layer.

1‧‧‧Double-sided adhesive sheet

10‧‧‧Adhesive layer

101‧‧‧ first surface

102‧‧‧ second surface

11‧‧‧First release film

111‧‧‧First release agent layer

112‧‧‧First substrate film

12‧‧‧Second release film

121‧‧‧Second release agent layer

122‧‧‧Second substrate film

Fig. 1 is a side sectional view showing the double-sided adhesive sheet of the present invention.

The invention will be described in detail below with reference to preferred embodiments.

The double-sided adhesive sheet will be described below.

The double-sided adhesive sheet of the present invention is used, for example, to bond an optical functional film such as a polarizing plate to a member such as a liquid crystal cell.

Fig. 1 is a side sectional view showing the double-sided adhesive sheet of the present invention.

As shown in FIG. 1, the double-sided adhesive sheet 1 includes an adhesive layer 10, a first release film 11, and a second release film 12. The adhesive layer 10 has a first surface 101 and a second surface 102. The first release film 11 is disposed on the first surface 101 of the adhesive layer 10. The second release film 12 is disposed on the second surface 102 of the adhesive layer 10. Further, with respect to the adhesive layer 10, after the first release film 11 and the second release film 12 are removed, there is no support.

As described above, the double-sided adhesive sheet 1 of the present invention has the adhesive layer 10, the first release film 11 and the second release film 12, and has the following features (1) to (5). That is, the double-sided adhesive sheet 1 of the present invention has the following features: (1) the release force of the second release film 12 peeled off from the adhesive layer 10 is smaller than that of the first release film 11 peeled off from the adhesive layer 10. The release force is downward, (2) the adhesive layer 10 is formed using an adhesive composition containing an active energy ray-curable resin, and (3) the gel fraction of the adhesive layer 10 is 70% or more. (4) When the current gel fraction of the adhesive layer 10 is expressed as X [%], and the aforementioned adhesive layer 10 is formed for 7 days When the gel fraction of the adhesive layer 10 is expressed as Y [%], the relationship of X/Y ≧ 0.9 is satisfied, and (5) the first surface and the second surface of the adhesive layer 10 are from the reference surface ± The ratio of the unevenness outside the range of 0.2 μm is 20% or less.

By having such a feature, the double-sided adhesive sheet 1 is wound into a roll When the tubular shape is stored or transported, it is possible to prevent the occurrence of minute irregularities (orange peel) on the surface of the adhesive layer 10. It will be considered for the following reasons.

That is, by using an adhesive containing an active energy ray-hardening resin The coating composition forms the adhesive layer 10, and the gel fraction of the adhesive layer 10 can be increased more. Further, by increasing the gel fraction immediately after the formation of the adhesive layer 10, it is possible to suppress the occurrence of minute irregularities (orange peel) during curling. Furthermore, by reducing the change in the gel fraction over time, it is possible to suppress the occurrence of minute irregularities (orange peel) which evolve with time.

As the adhesive fraction of the adhesive layer 10 is increased, the current gel fraction is increased. At the same time, by reducing the change in the gel fraction over time, it is possible to reduce the proportion of the unevenness outside the range of ±0.2 μm from the reference surface on the first surface and the second surface of the adhesive layer 10, and Can prevent the occurrence of orange peel.

Furthermore, the second release film is peeled off from the adhesive layer 10 The shape force is smaller than the release force of the first release film peeled off from the adhesive layer, and can prevent the occurrence of the transfer phenomenon called crying separation, which is the second release film from the adhesive layer 10 When peeled off, one portion of the adhesive layer 10 is also attached to the second release film, and the adhesive layer does not remain on the first release film in a good appearance in a smooth appearance.

Moreover, in the present specification, the release from the adhesive layer is released. Force, the force of the force measured as follows.

Deformation force is measured according to Japanese Industrial Standards (Japanese) Industrial Standards) JIS-Z0237, which cuts the double-sided adhesive sheet into a width of 25 mm and a length of 200 mm. Using a tensile tester, in the state of fixing the adhesive layer, by a direction of 180 degrees at a speed of 300 mm per minute. The method of stretching the film is carried out.

Moreover, in the present specification, the storage elastic modulus of the adhesive layer, A test piece of a cylindrical shape having a diameter of 8 mm and a thickness of 3 mm was formed by stacking the adhesive, and the storage elastic modulus was measured by a torsional shear method under the following conditions.

Measuring device: Dynamic viscoelasticity test manufactured by RHEOMETRIC Fixing device "DYNAMICANALYZER RDA II", frequency: 1Hz, temperature: 23 degrees Celsius.

Hereinafter, the double-sided adhesion constituting the present embodiment will be described in detail. The layers of the sheet 1.

The adhesive layer 10 will be described below.

The adhesive layer 10 has a first surface 101 and a second surface 102.

After the adhesive layer 10 is formed, the current gel fraction is 70% or more, and when the adhesive fraction of the adhesive layer 10 is formed as X [%], and the adhesive layer 10 is formed for 7 days, the adhesive layer 10 is formed. When the gel fraction is expressed as Y [%], the relationship of X/Y ≧ 0.9 is satisfied, and the ratio of the unevenness outside the range of ± 0.2 μm from the reference surface to the first surface 101 and the second surface 102 is 20 %the following. Thereby, in the adhesive layer 10 When attached to an adhesive, it can prevent the appearance of defects.

After the adhesive layer 10 is formed, the current gel fraction is 70%. Above, but more than 75% is preferred. Thereby, when the adhesive layer 10 is attached to the adherend, it is possible to more effectively prevent the occurrence of appearance defects.

On the first surface 101 and the second surface 102 of the adhesive layer 10, Although the ratio of the unevenness outside the range of ±0.2 μm of the reference surface is 20% or less, it is preferably 10% or less. Thereby, when the adhesive layer 10 is attached to the adherend, it is possible to more reliably prevent the occurrence of appearance defects.

In addition, the adhesive layer 10 is formed at 7 degrees Celsius after 7 days. The storage elastic modulus is preferably 0.15 MPa or more, and more preferably 0.3 MPa or more. Thereby, when the double-sided adhesive sheet 1 is rolled, it is possible to more effectively prevent the orange peel phenomenon from occurring on the surface of the adhesive layer 10. Further, it is possible to suppress dimensional changes caused by factors such as heat of the optical functional film body such as a polarizing plate.

The adhesive constituting the adhesive layer 10 is not particularly limited, but is used It is preferable that the adhesive composition is irradiated with an active energy ray, and the adhesive composition contains (A) an acryl-based copolymer and (B) an active energy ray-curable compound. Thereby, the storage elastic modulus of the adhesive layer 10 can be increased, and the durability (heat resistance, low temperature resistance, moisture resistance, and the like) of the adhesive layer 10 can be further improved.

The propylene-based copolymer (A) can be (meth) acrylate ((meth)acrylic acid ester) copolymer. Here, in the present specification, (meth) acrylate means both acrylate and (meth) acrylate. Other similar terms The same.

(meth)acrylate copolymer is capable of having various kinds of crosslinks The cross-linking point of the cross-linking method is preferred. The (meth) acrylate-based copolymer having such a crosslinking point is not particularly limited, and an appropriate copolymerization can be arbitrarily selected from (meth) acrylate-based copolymers which are conventionally used as a resin component of an adhesive. Use it for use.

a (meth) acrylate copolymer having such a crosslinking point It is preferred to use a copolymer which is an alkyl group of an ester moiety having an alkyl group of 1 to 20 carbon atoms and a crosslinkable functional group in the molecule. Copolymers of monomers and other monomers used as desired. Wherein the alkyl group of the ester moiety has 1 to 20 carbon alkyl (meth)acrylates, for example, methyl (meth)acrylate or ethyl (meth)acrylate (ethyl(meth)acrylate), propyl(meth)acrylate,butyl(meth)acrylate,pentyl(meth) Acrylate), hexyl (meth)acrylate, cyclohexyl(meth)acrylate, 2-ethylhexyl (2-ethylhexyl) Meth)acrylate), isooctyl(meth)acrylate,decyl(meth)acrylate,dodecyl(meth)acrylate ), myristyl (meth)acrylate, palmityl (meth)acrylate, and stearyl (meth)acrylate One or a combination of two or more materials is preferred.

On the other hand, a monomer having a crosslinkable functional group in the molecule is preferably at least one of a hydroxyl group, a carboxyl group and an amino group as a functional group. Specific examples of the monomer include 2-hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, and (methyl). ) 3-hydroxypropyl (meth)acrylate, 2-hydroxybutyl (meth)acrylate, 3-hydroxybutyl (meth)acrylate (3- Hydroxybutyl (meth)acrylate) and (meth)acrylic acid hydroxy alkyl ester (4-hydroxybutyl(meth)acrylate); Monomethylaminoethyl (meth) acrylate, monoethylaminoethyl (meth) acrylate, monomethylaminopropyl (meth) Meth)acrylate) and monoalkylaminoalkyl(meth)acrylate, such as monoethylaminopropyl (meth)acrylate; acrylic acid, methacrylic acid , Crotonic acid (2-butenoic acid), maleic acid (maleic acid), itaconic acid (itaconic acid, Ethyl succinic acid) and ethylenic unsaturation carboxylic acid such as citraconic acid (methyl maleic acid). These monomers may be used singly or in combination of two or more.

(Meth)acrylate copolymer (A) in the adhesive composition The copolymerization form is not particularly limited, and may be any random, block, or graft copolymer.

Furthermore, the mass average score of the (meth) acrylate copolymer (A) The sub-quantity is preferably 500,000 or more, preferably 600,000 to 2,000,000, and more preferably 700,000 to 1.8 million. Thereby, it is possible to have sufficient tightness and adhesion durability with the adherend, and it is possible to more effectively prevent the occurrence of floating and peeling of the adhesive layer 10. Here, the mass average molecular weight is a value obtained by measuring a (meth)acrylate copolymer (A) by a gel permeation chromatography (GPC) method and converting it into a standard polystyrene. The value.

In addition, the (meth) acrylate copolymer has intramolecular The content of the monomer unit of the crosslinkable functional group is preferably in the range of 0.01 to 10% by mass. When the content is 0.01% by mass or more, the crosslinking can be sufficiently carried out by a reaction between a crosslinking agent and a crosslinkable functional group described later, and the durability is good. On the other hand, when the content is 10% by mass or less, the crosslinkability is too high, so that the suitability for the liquid crystal glass unit and the retardation film is not low. If the durability and the suitability for the liquid crystal glass unit and the phase difference plate are considered, the preferred content of the monomer unit having the crosslinkable functional group is 0.05 to 7.0% by mass, and more preferably 0.2 to 6.0. The range of mass percentages is preferred.

Among them, one type or a combination of two or more materials may be used. It is a (meth)acrylate type copolymer (A).

In the adhesive composition, it is possible to use an official with a molecular weight of less than 1,000 A (meth)acrylate monomer is used as an active energy ray-curable compound (B).

For example, polyfunctional (meth)acrylic acid having a molecular weight of less than 1000 The ester monomer may be one or a combination of two or more kinds of materials: 1,4-butanediol di(meth)acrylate, 1 ,6-hexanediol di(meth)acrylate, neopentyllglycol di(meth)acrylate, polyethylene glycol Polyethylene glycol di(meth)acrylate, neopentyllgic acid adipate di(meth)acrylate, neopentyl glycol hydroxypivalate Hydroxy pivalic acid neopentylglycol di (meth)acrylate, dicyclopentanyl di(meth)acrylate, caprolactone denatured dicyclopentenyl di Dicyclopentenyl di(meth)acrylate modified with caprolactone, phosphoric acid di(meth)acrylate modified with ethylene oxide, bis(propylene oxide) Di(acryloxyethyl)ococyanurate and allylated cyclohexyl di(meth)acrylate (allylating) Difunctional type such as cyclohexyl di(meth)acrylate); trimethylol propane tri(meth)acrylate, dipentaerythritol tri(meth) Acrylate, dipentaerythritol tri(meth)acrylate modified with Propionic acid), pentaerythritol tri(meth)acrylate, propylene oxide modified trimethylol propane tri(meth)acrylate modified with propylene oxide And a trifunctional type such as tris(acryloxyethyl)isocyanurate; diglycerine tetra(meth)acrylate and pentaerythritol tetra(methyl) a tetrafunctional type such as pentaerythritol tetra(meth)acrylate; a pentafunctional type such as dipentaerythritol penta (meth)acrylate modified with propionic acid; dipentaerythritol Dipentaerythritol hexa (meth) acrylate and dihexaerythritol hexa (meth) acrylate modified with caprolactone. Among them, in the above polyfunctional (meth)acrylate monomer, a monomer having a cyclic structure as a skeleton structure may be preferably used. The annular structure may be a carbon ring structure or a heterocyclic structure, and may have a single ring structure or a multi-ring structure. Such a polyfunctional (meth) acrylate monomer is, for example, an isocyanurate such as bis(acryloyloxyethyl)isocyanurate or tris(propylene oxyethyl)isocyanurate ( Hexahydrophthalic acid diacrylate modified with ethylene oxide , tricyclodecane dimethanol acrylate (tricyclodecane dimethanol Acrylate, neomethyl glycol propane diacrylate modified with neopentylglycol and adamantane diacrylate.

In addition, an active energy ray-curable acrylate can be used. An acrylate is an active energy ray-curable compound (B). The acrylate-based oligomer preferably has a mass average molecular weight of 50,000 or less. Such acrylate-based oligomers are, for example, polyester acrylate oligomers, epoxy acrylate oligomers, and urethane acrylate oligomers. Materials such as polyether acrylate oligomers, polybutadiene acrylate oligomers, and silicone acrylate oligomers.

Among them, the polyester acrylate oligomer can be condensed by, for example, a carboxylic acid and a polyvalent alcohol to obtain a polyester oligomer having a hydroxyl group at both terminals, and obtained by esterification of a hydroxyl group with (meth)acrylic acid, or by, for example, adding an alkylene oxide The hydroxyl group at the terminal of the oligomer obtained from the polyvalent carboxylic acid is obtained by esterification reaction with (meth)acrylic acid. The epoxy acrylate-based oligomer can be, for example, ethylene oxide by reacting (meth)acrylic acid with a lower molecular weight bisphenol epoxy resin or a novolak epoxy resin. The (oxirane) ring is obtained by carrying out an esterification reaction. Further, as the epoxy acrylate-based oligomer, a carboxyl-denatured epoxy acrylate oligomer partially denatured with a bis-carboxylic carboxylic acid anhydride can also be used. amine A urethane acrylate oligomer can be, for example, a polyurethane oligopolymer obtained by reacting a polyether polyol or a polyester polyol with a polyisocyanate. (polyurethane oligomer) is obtained by esterification reaction with (meth)acrylic acid. A polyol acrylate oligomer can be obtained by esterifying a hydroxyl group of a polyether polyol with (meth)acrylic acid.

The mass average molecular weight of the above acrylate oligomer is by The value calculated by the GPC method and converted by the standard polymethyl methacrylate (PMMA) is preferably 50,000 or less, preferably 500 to 50,000, and more preferably 3,000 to 40,000. good.

These acrylate oligomers may be used alone or in combination. More than two types are used.

Moreover, it is possible to introduce a group having a (meth)acryl fluorenyl group An adduct acrylate-based polymer to the side chain is used as the active energy ray-curable compound (B). Such an adduct type acrylate-based polymer can be used by using a (meth) acrylate described in the (meth) acrylate-based copolymer (A) and a monomer having a crosslinkable functional group in the molecule. The copolymer is obtained by reacting a compound having a (meth) acrylonitrile group and having a group reactive with a crosslinkable functional group, as a part of a crosslinkable functional group of the copolymer. The mass average molecular weight of the adduct type acrylate-based polymer is usually from 500,000 to 2,000,000 in terms of standard polystyrene.

Among them, the above polyfunctional acrylate monomer, propylene can also be used. One type of the acid ray-curable compound (B) is appropriately selected and used as the active energy ray-curable compound (B), and two or more kinds may be used in combination.

(Meth)acrylate copolymer (A) in the adhesive composition And the ratio of the active energy ray-curable compound (B), the mass ratio is preferably 100:1 to 100:100, and preferably 100:5 to 100:50, depending on the performance of the obtained adhesive. 100:10~100:40 is better.

Further, the adhesive composition may contain a photopolymerization initiator depending on the demand.

The photopolymerization initiator may also be, for example, benzoin, benzoin methyl ether, benzoin ethyl ether, benzoin isopropyl ether, Benzoin-n-butyl ether, benzoin isobutyl ether, acetophenone, dimethylamino acetophenone, 2,2- 2,2-dimethoxy-2-phenyl acetophenone, 2,2-diethoxy-2-phenylacetophenone (2,2-diethoxy-2- Phenyl acetophenone), 2-hydroxy-2-methyl-1-phenyl propane-1-one, 1-hydroxycyclohexyl phenyl ketone (1-hydroxy cyclohexyl phenyl ketone), 2-methyl-1-[4-(methylthio)phenyl]-2-morpholinopropan-1-one (2-methyl-1[4-(methylthio)) Phenyl]-2-morpholinopropane-1-one) 4-(2-hydroxyethoxy)phenyl-2-(hydroxy-2-propyl)ketone, two Benzophenone, p-phenyl benzophenone, 4,4'-diethylamino benzophenone, dichloro Dichloro-benzophenone, 2-methyl anthraquinone, 2-ethyl anthraquinone, 2-tert-butyl-(2-tertiary- Butyl anthraquinone), 2-amino anthraquinone, 2-methyl thioxanthone, 2-ethyl thioxanthone, 2-chlorothioxanthone (2-chlorothioxanthone), 2,4-dimethyl thioxanthone, 2,4-diethyl thioxanthone, benzyl dimethyl condensate Benzyl dimethyl ketal, acetophenone dimethyl ketal, p-dimethyl aminobenzoate, oligomeric [2-hydroxy-2-methyl- 1-[4-(1-methylvinyl)phenyl]propanone] (Oligo[2-hydroxy-2-methyl-1-[4-(1-methyl vinyl)phenyl]prop Anone]) and 2,4,6-trimethylbenzylidene-diphenyl-phosphine oxide (2,4,6-trimethylbenzoyl-diphenyl-phosphineoxide) and the like, one or a combination of two or more materials .

Moreover, in the adhesive composition, for 100 parts by mass of activity The content of the energy ray-curable compound (B) and the photopolymerization initiator is preferably 0.2 to 20 parts by mass.

Furthermore, the adhesive composition may also contain cross-linking depending on the demand. Agent.

The crosslinking agent is not particularly limited, and can also be used for propylene oxime from the past. Any suitable acrylonitrile-based adhesive which is used as a crosslinking agent in the adhesive is arbitrarily selected and used. Such a crosslinking agent may also be, for example, a polyisocyanate compound, an epoxy resin, a melamine resin, a urea resin, a dialdehyde type, a methylol polymer, or aziridine. One or a combination of two or more kinds of materials, such as a compound, a metal chelate compound, an alkoxide, and a metal salt. Among these materials, it is preferred to use a polyisocyanate compound as a crosslinking agent.

The polyisocyanate compound can be an aromatic polyisocyanate such as tolylene diisocyanate, diphenyl methane diisocyanate or xylylene diisocyanate, or hexamethylene diene. A material such as an aliphatic polyisocyanate such as hexamethylene diisocyanate, an isophorone diisocyanate or an alicyclic polyisocyanate such as hydrogenation diphenyl methane diisocyanate, and a biuret thereof (biuret) body, isocyanurate body, even with ethylene glycol, propylene glycol, neopentyl glycol, trimethylol propane And an adduct obtained by reacting a low molecular weight active hydrogen-containing compound such as castor oil.

For 100 parts by mass of (meth) acrylate copolymer (A) The amount of the crosslinking agent added is preferably 0.01 to 20 parts by mass, more preferably 0.1 to 10 parts by mass.

Furthermore, the adhesive composition may also contain decane depending on the demand. A silane coupling agent. When the optical functional film such as a polarizing plate is bonded to, for example, a liquid crystal glass unit or the like by containing the decane coupling agent, the adhesion between the adhesive and the glass unit is improved. The decane coupling agent is an organic hydrazine compound having at least one alkoxysilyl group in the molecule, which has good mutual solubility with the adhesive component and has light transmissivity, and is preferably transparent, for example.

For an adhesive composition having a solid content of 100 parts by mass The amount of the decane coupling agent to be added is preferably 0.001 to 10 parts by mass, preferably 0.005 to 5 parts by mass.

A specific example of a decane coupling agent is vinyl trimethoxy decane. (vinyl trimethoxy silane), vinyl triethoxy silane Silane) and methacyloxypropyl propyl trimethoxy silane, etc., a compound containing a polymerizable unsaturated group, 3-glycidoxypropyltrimethoxydecane (3-glycidoxy) Propylene compound such as propyl trimethoxy silane) and 2-(3,4-epoxycyclohexyl)ethyl trimethoxy silane 3-aminopropyl trimethoxy silane, N-(2-aminoethyl)-3-aminopropyl trimethoxy silane, and N-(2-aminoethyl)-3-aminopropyl trimethoxy silane N-(2-aminoethyl)-3-aminopropyl A A material such as an amino group-containing compound such as N-(2-aminoethyl)-3-aminopropyl methyl dimethoxy silane or 3-chloropropyl trimethoxy silane. These materials may be used alone or in combination of two or more.

In the adhesive composition, the object of the present invention is not impaired Various additives commonly used in acryl-based adhesives such as tackifiers, antistatic agents, antioxidants, ultraviolet absorbers, light stabilizers, softeners, and fillers can be added as needed.

The adhesive constituting the adhesive layer 10 is a pair as described above The adhesive composition is formed by irradiating an active energy ray.

The active energy ray may be radiation such as ultraviolet rays and electron beams. Above The ultraviolet rays can be obtained by a lamp such as a high pressure mercury lamp, an electrodeless lamp, or a xenon lamp. Furthermore, the electron beam can be obtained by means of an electron beam accelerator or the like.

Among the active energy rays, ultraviolet rays are particularly preferably used. In addition, In the case of using an electron beam, an adhesive can be formed without adding a photopolymerization initiator.

The amount of exposure of the active energy ray to the composition of the adhesive, although It is appropriately selected in such a manner as to have an adhesive of the gel fraction immediately after the formation of the above, but in the case of ultraviolet rays, the illuminance is 50 to 1000 mW per square centimeter, and the amount of light is preferably 50 to 1000 mJ per square centimeter. In the case of an electron beam, it is preferably in the range of 10 to 1000 krad.

The average thickness of the adhesive layer 10 is preferably 3 to 30 μm, and is 4~. 28 μm is more preferred. Thereby, it can be suitably applied to the thickness of a thin display.

The first release film will be described below.

The first release film 11 is attached to the first surface 101 of the adhesive layer 10.

This first release film 11 has a function of protecting the adhesive layer 10.

As shown in Fig. 1, the first release film 11 is formed by stacking the first release agent layer 111 and the first base material film 112 from the surface position in contact with the adhesive layer 10 to form a stacked body.

The first base film 112 has a function of imparting physical strength such as rigidity and flexibility to the first release film 11 .

The material constituting the first base film 112 may be various synthetic resins, for example, a polybutylene terephthalate (PBT) resin or a polyethylene terephthalate (PET) resin. A polyester resin such as a polyethylene naphthalate (PEN) resin or the like is preferred, and a polyethylene terephthalate resin is preferably used. The first base film 112 may be a single layer film, or may be a multilayer film of two or more layers composed of the same or different materials. Such a multilayer film can be formed by laminating an adhesive layer interposed between the film bodies formed in advance, or by caking the resin layer on the film formed in advance. Formed by the composition. In order to form a resin layer-forming composition for a resin layer, a compound such as an epoxy compound, an acrylate compound, a urethane acrylate compound, or a polyester compound may be contained as a main material, and may be used according to requirements. It contains a crosslinking agent, a catalyst, a photopolymerization initiator, and a UV absorber. These resin layer forming compositions may also have curability. This hardenability can be, for example, heat Any of hardenability such as hardenability, photocurability, or electron beam curability. Therefore, the multilayer film body in which the resin layer is formed by coating the resin layer forming composition on the film body formed in advance, the arithmetic mean roughness Ra and the maximum protrusion height of the outer surface of the first base film 112 can be adjusted. R.

In addition, the first base film 112 may also contain a filler. Filler For example, it is a material such as silica, titania, calcium carbonate, kaolin, and alumina.

Although the thickness of the first base film 112 is not particularly limited, it is 10~ 300 μm is preferred, and 15 to 200 μm is preferred.

In addition, the surface of the first release film 11 that is in contact with the adhesive layer 10 The surface in the opposite direction has an arithmetic mean roughness Ra of preferably 50 nm or less, and preferably 5 to 25 nm. Thereby, when the double-sided adhesive sheet 1 is wound into a roll shape, it is possible to more effectively prevent the orange peel phenomenon from occurring on the first surface 101 and the second surface 102 of the adhesive layer 10.

Furthermore, the surface of the first release film 11 that is in contact with the adhesive layer 10 In the opposite direction, the maximum protrusion height Rp is preferably 1000 nm or less, and preferably 50 to 250 nm. Thereby, when the double-sided adhesive sheet 1 is rolled, it is possible to more effectively prevent the orange peel phenomenon from occurring on the first surface 101 and the second surface 102 of the adhesive layer 10.

The first release agent layer 111 has a property of imparting a property to the first release film 11 The function.

The first release agent layer 111 is the first to contain the first release agent The composition for forming a release agent layer is applied onto the surface of the first base film 112 and dried.

The first release agent is not particularly limited and may be alkyd-based A compound such as a compound, a propylene oxime compound, a silicone compound, a compound containing a long-chain alkyl group, or a fluoride. Among these materials, an alkyd compound, an acrylonitrile compound, an anthrone compound, or a compound having a long-chain alkyl group is preferably used as the first release agent.

An alkyd compound usually uses an alkyd system having a crosslinked structure Compound. For example, the formation of the alkyd compound layer having a crosslinked structure can be a method of heating and hardening a layer formed of an alkyd compound, a crosslinking agent, and a thermosetting composition containing a curing catalyst as required. . Further, the alkyd compound may be a denatured product such as a long-chain alkyl-modified alkyd compound or an anthrone-modified alkyd compound.

Propylene oxime compounds usually use propylene fluorene with crosslinked structure a compound. Among them, the propylene oxime compound may be a denatured product such as a long-chain olefin-modified acryl oxime compound or an fluorenone-modified acryl oxime compound.

The anthrone-based compound may be an anthrone-based compound containing polydimethyl siloxane as a basic skeleton. The anthrone-based compound contains a compound such as an addition reaction type anthrone type compound, a condensation reaction type anthrone type compound, an ultraviolet curing type anthrone type compound, and an electron beam curing type anthrone type compound. Compared with the condensation reaction type fluorenone compound, the addition reaction type fluorenone compound has high reactivity and can optimize productivity, and has a change in release force after production. Small and no hardening shrinkage and other advantages.

Specifically, the above-mentioned addition reaction type fluorenone compound can be It is an organopolysiloxane having two or more at the molecular terminal and/or side chain such as vinyl, allyl, propenyl, or hexenyl. The number of carbon atoms is 2 to 10 alkenyl groups. When such an addition reaction type anthrone compound is used, it is preferred to use a crosslinking agent and a catalyst in combination.

The above crosslinking agent is, for example, having one molecule and at least two hydrazines An organic polyoxane of an atom-bonded hydrogen atom, specifically, for example, a dimethyl hydrogen siloxy-terminated dimethyl siloxane-methylhydroquinone (methyl hydrogen siloxane) copolymer, trimethyl siloxy-terminated dimethyl methoxy oxane-methylhydroquinoxane copolymer, trimethyl siloxy-terminated Methylhydrogen polysiloxane, poly(hydrogen silsesquioxane), etc.

In addition, the above catalyst may be particulate platinum and adsorbed on carbon powder. A platinum-based metal compound such as particulate fine platinum, chloroplatinic acid, alcohol-modified chloroplatinic acid, olefinic complex of chloroplatinic acid, palladium or rhodium. By using such a catalyst, the hardening reaction of the composition for forming a release agent layer can be performed more efficiently.

The long-chain alkyl-containing compound is used, for example, in a polyvinyl alcohol-based polymer to have a long chain of 8 to 30 carbon atoms. A polyvinyl carbamate obtained by using a long-chain alkyl isocyanate, and a long chain having a reaction carbon number of 8 to 30, for example, used in polyethyleneimine (PEI) An alkyl urea (urea) derivative obtained by alkyl isocyanate.

As the fluoride, a compound such as a fluorine silicone compound or a boron compound can be used.

In the composition for forming the first release agent layer, an additive may be appropriately mixed. The additives may be materials such as catalysts, dyes, and dispersants.

In the first release agent layer 111, the material of the first release agent layer forming composition is appropriately selected in such a manner that the release force of the first release film 11 is greater than the release force of the second release film 12. .

In the case where a resin made of an anthrone compound is used as the first release agent, it is preferred to add an MQ resin as a heavy release controlling agent in an appropriate amount.

The first release agent composition may also suitably contain a dispersant or a solvent for the viscosity at the time of coating to fall within an appropriate range.

The dispersant or solvent is aromatic hydrocarbons such as toluene, fatty acid esters such as ethyl acetate, and methyl ethyl ketone (MEK). It is preferably an organic solvent such as a ketone or an aliphatic hydrocarbon such as hexane or heptane.

In the first release agent composition, the content of the first release agent is not particularly limited, but is preferably from 0.3 to 10% by mass.

Among them, the coating method can, for example, use a gravure coating (gravure) Coat method, bar coat method, spray coat method, spin coat method, air knife coat method, roll coat method, blade coat The method, the gate roll coating method, the die coating method, and the like, wherein the gravure coating method and the bar coating method are preferred, and the bar coating method is particularly preferable.

Furthermore, the drying temperature is not particularly limited, in the range of 100 to 150 degrees Celsius Preferably, the drying time is preferably from 10 seconds to 1 minute.

The thickness of the first release agent layer is preferably 0.01~5μm, and 0.03~ 3μm is especially good.

The surface of the first release film 11 that is in contact with the adhesive layer 10 (first The arithmetic mean roughness Ra of the outer surface of the release agent layer 111 is preferably 50 nm or less, and the maximum protrusion height Rp is preferably 800 nm or less, while being on the outer surface of the first release agent layer 111 from the reference surface. The proportion of the unevenness outside the range of 0.2 μm is preferably 20% or less. Thereby, when the adhesive layer 10 is formed on the first release film 11, the surface shape of the first surface 101 of the adhesive layer 10 can be kept good.

The second release film will be described below.

The second release film 12 is attached to the second surface 102 of the adhesive layer 10.

This second release film 12 has a function of protecting the adhesive layer 10.

As shown in Fig. 1, the second release film 12 is formed by stacking the second release agent layer 121 and the second base film 122 in this order from the surface contact with the adhesive layer 10.

The second base film 122 can be from the item of the first release film 11 described above Among the materials constituting the first base film 112, which have been described, are appropriately selected and used.

In addition, the surface of the second release film 12 that is in contact with the adhesive layer 10 The surface in the opposite direction has an arithmetic mean roughness Ra of preferably 50 nm or less, and preferably 5 to 25 nm. Thereby, when the double-sided adhesive sheet 1 is rolled, it is possible to more effectively prevent the orange peel phenomenon from occurring on the first surface 101 and the second surface 102 of the adhesive layer 10.

Furthermore, the surface of the second release film 12 that is in contact with the adhesive layer 10 In the opposite direction, the maximum protrusion height Rp is preferably 1000 nm or less, and preferably 50 to 250 nm. Thereby, when the double-sided adhesive sheet 1 is rolled, it is possible to more effectively prevent the orange peel phenomenon from occurring on the first surface 101 and the second surface 102 of the adhesive layer 10.

The second release agent layer 121 is formed by the second agent containing the second release agent The composition for forming a release agent layer is applied onto the surface of the second base film 122 and dried.

The second release agent can be illustrated from the item of the first release film described above The material constituting the first release agent is appropriately selected for use.

In the second release agent layer 121, the second release film 12 is separated from the shape The material of the second release agent layer-forming composition is appropriately selected in such a manner that the force is smaller than the release force of the first release film 11.

The second release agent layer 121 may have only one layer or two layers. In order to simplify the operation, it is better to use one layer.

The thickness of the second release agent layer 121 is preferably 0.01 to 5 μm, 0.03 to 3 μm is preferred.

The surface of the second release film 12 that is in contact with the adhesive layer 10 (second The arithmetic mean roughness Ra of the outer surface of the release agent layer 121 is preferably 50 nm or less, and the maximum protrusion height Rp is preferably 800 nm or less, while the outer surface of the second release agent layer 121 is from the reference surface. The proportion of the unevenness outside the range of 0.2 μm is preferably 20% or less. Thereby, when the second release film 12 is attached to the second surface 102 of the adhesive layer 10 to form the double-sided adhesive sheet 1, the surface shape of the second surface 102 of the adhesive layer 10 can be kept good.

The release force table of the first release film 11 peeled off from the adhesive layer 10 When X [mN/25 mm] is shown, and the release force of the second release film 12 peeled off from the adhesive layer 10 is expressed as Y [mN/25 mm], it is preferable to satisfy the relationship of XY≧5. It is preferable to satisfy the relationship of 60 ≧ XY ≧ 10. Thereby, the occurrence of the transfer phenomenon called crying separation can be more effectively prevented, and when the second release film 12 is peeled off from the adhesive layer 10, a part of the adhesive layer 10 is attached to the first portion. The two release films 12, and the adhesive layer does not remain on the first release film in a good appearance in a smooth appearance.

The rewind body will be explained below.

The rewinding system of the present invention is formed by bending the double of the present invention as described above The face is adhered to the piece. Therefore, it is possible to prevent a plurality of minute irregularities (orange peel) from occurring on the surface of the adhesive layer.

Although the present invention has been described in detail based on preferred embodiments, the present invention Ming is not limited to this.

The embodiment will be described below.

Next, a specific embodiment of the double-sided adhesive sheet relating to the present invention will be explained.

The production of the double-sided adhesive sheet will be described below.

Embodiment 1 will be explained below.

The production of the first release film will be described below.

A polyethylene terephthalate (PET) film (thickness: 38 μm, arithmetic mean roughness Ra: 15 nm, maximum protrusion height Rp: 159 nm) having the same roughness on the back surface was prepared as the first substrate film.

Next, the first release agent layer-forming composition A having the following composition was applied to one of the surfaces of the first substrate film by a bar coater in a thickness of 0.1 μm after drying to Celsius The first release agent layer was set by continuously drying at 120 degrees for 1 minute. Thereby a first release film is obtained. The calculated surface average roughness Ra and the maximum of the surface of the first release film in the direction of the first release agent layer and the surface of the first substrate film (the surface opposite to the surface in contact with the adhesive layer) The protrusion height Rp and the ratio of the surface of the first release film in the direction of the first release agent layer from the reference surface ± 0.2 μm are described in Tables 1-1 to 1-3. .

The preparation of the first release agent layer-forming composition A will be described below.

An anthrone resin solution containing an organic polysiloxane having a vinyl group and an organopolyoxane having a hydrogenated hydrosilyl group (manufactured by Dow Corning Toray, trade name "BY24-561", a solid content of 30 The mass percentage) is 30 parts by mass based on the solid content, and the MQ with vinyl Resin (manufactured by Dow Corning Toray, trade name "SD7292", solid content of 71% by mass), 15 parts by mass calculated as solid content, and diluted and mixed with toluene in a solid content concentration of 1.0 by mass Solvent. A platinum catalyst (manufactured by Dow Corning Toray Co., Ltd., trade name "SRX-212", a solid content of 100% by mass) was added to the solution in an amount of 2 parts by mass to prepare a composition for forming a first release agent layer. A.

The production of the second release film will be described below.

A polyethylene terephthalate (PET) film (thickness: 38 μm, arithmetic mean roughness Ra: 30 nm, maximum protrusion height Rp: 535 nm) having the same roughness on the back surface was prepared as a second substrate film.

Next, a second release agent layer-forming composition B having the following composition was applied to a surface of the second substrate film by a bar coater in a thickness of 0.1 μm after drying to Celsius The second release agent layer was set by continuously drying at 120 degrees for 1 minute. Thereby, a second release film is produced. The calculated average roughness Ra and the maximum of the surface of the second release film in the direction of the second release agent layer and the surface of the second substrate film (the surface opposite to the surface in contact with the adhesive layer) The protrusion height Rp and the ratio of the surface of the second release film in the direction of the second release agent layer from the reference surface ± 0.2 μm are described in Tables 1-1 to 1-3. .

The preparation of the second release agent layer-forming composition B will be described below.

Anthrone resin (manufactured by Shin-Etsu Chemical Co., Ltd.: trade name "KS-847H", a solid content concentration of 30% by mass), 100 parts by mass, and platinum catalyst (manufactured by Shin-Etsu Chemical Co., Ltd.: trade name "CAT-PL50T", a solid content concentration of 2% by mass), and the above-mentioned composition of the second release agent layer-forming composition B is prepared by diluting the above toluene to prepare a solid content concentration of 1 by mass. .

The production of the adhesive composition will be described below.

95.0 parts by mass of n-butyl acrylate (n-butyl) Acrylate), 5.0 parts by mass of 2-hydroxyethyl acrylate, 200 parts by mass of ethyl acetate and 0.08 parts by mass of 2,2' azobisisobutyronitrile- (2-2'-azobisisobutyronitrile) was added to a reaction vessel equipped with a stirrer, a thermometer, a reflux condenser, a dropping device, and a nitrogen introduction tube to obtain a reaction liquid. Next, the air in the reaction vessel was replaced with nitrogen. Under the nitrogen atmosphere, the reaction solution was heated to 60 ° C while stirring the reaction solution, and after reacting for 16 hours, the reaction solution was cooled to room temperature. At this time, a part of the obtained solution was measured by a GPC method, and it was confirmed that the produced polymer (A) had a mass average molecular weight of 1.6 million. To 100 parts by mass (solid content) of the above polymer (A), 20 parts by mass of tris(propylene oxyethyl) isocyanurate (manufactured by Toagosei Co., Ltd., trade name "ARONIX M-315" was added. "), 2.0 parts by mass of a photopolymerization initiator (manufactured by CIBA SPECIALTY CHAMICALS, trade name "IRGACURE 500"), and 4 parts by mass of a polyisocyanate crosslinking agent (manufactured by Nippon Polyurethane (NIPPON POLYURETHANE) Co., Ltd. "CORONATE L" and 0.1 parts by mass of a decane coupling agent ("KBM-403" manufactured by Shin-Etsu Chemical Co., Ltd.) were mixed and mixed to obtain a mixed liquid. In this mixture, more toluene as a solvent is added to adjust the mass to a solid content of 15 The percentage of the adhesive composition A was prepared.

The production of the double-sided adhesive sheet will be described below.

Adhesive composition in a manner of a thickness of 20 μm after drying A is applied to the release agent layer of the first release film and dried at 90 ° C for 1 minute to form an adhesive layer. Next, the second release film is adhered to the adhesive layer in such a manner that the release agent layer of the second release film contacts the formed adhesive layer to obtain a stacked body. The laminating step is to adjust the lamination pressure between the silicone gum roll (glue hardness: 80) and the metal roll to 0.5 MPa and sandwich the stack between the two at normal temperature. Executed at a speed of 50m per minute. Next, ultraviolet rays (UV) were irradiated from below the first release film under the following conditions to prepare a double-sided adhesive sheet.

The UV irradiation conditions will be explained below.

‧Using the electrodeless lamp H VALVE manufactured by FUSION.

‧ Illumination is 600mW per square centimeter, and the amount of light is 150mJ per square centimeter.

The UV illuminance and the amount of light were measured using "UVPF-36" manufactured by EYEGRAPHICS.

Embodiment 2 will be described below.

In addition to changing 20 parts by mass of the adhesive composition A (propylene oxyethyl) isocyanurate (manufactured by Toagosei Co., Ltd., trade name "ARONIX M-315") to 15 parts by mass, The adhesive composition B was prepared in the same manner as in the above Example 1 to prepare a double-sided adhesive sheet.

Embodiment 3 will be explained below.

In addition to 20 parts by mass of the adhesive composition A (propylene oxime) The oxyethyl)isocyanurate (manufactured by Toagosei Co., Ltd., trade name "ARONIX M-315") was changed to 10 parts by mass, and the adhesive composition C was prepared in the same manner as in the above-mentioned Example 1. Make double-sided adhesive sheets.

Embodiment 4 will be explained below.

In addition to 20 parts by mass of the adhesive composition A (propylene oxime) The oxyethyl)isocyanurate (manufactured by Toagosei Co., Ltd., trade name "ARONIX M-315") was changed to 5 parts by mass, and the adhesive composition D was prepared in the same manner as in the above-mentioned Example 1. Make double-sided adhesive sheets.

Embodiment 5 will be explained below.

In addition to changing the second substrate film to the same roughness of the surface and back surface A double-sided adhesive sheet was produced in the same manner as in the above Example 1, except that a polyethylene terephthalate (PET) film (thickness: 38 μm, arithmetic mean roughness Ra: 45 nm, maximum protrusion height Rp: 935 nm) was used.

Embodiment 6 will be explained below.

In addition to changing the second substrate film to the same roughness of the surface and back surface A double-sided adhesive sheet was produced in the same manner as in the above Example 1, except that a polyethylene terephthalate (PET) film (thickness: 38 μm, arithmetic mean roughness Ra: 15 nm, maximum protrusion height Rp: 159 nm) was used.

Comparative Example 1 will be described below.

In addition to changing the adhesive composition as follows, A double-sided adhesive sheet was produced in the same manner as in the foregoing Example 1.

99.0 parts by mass of n-butyl acrylate (n-butyl) Acrylate), 1.0 parts by mass of 2-hydroxyethyl acrylate, 200 parts by mass of ethyl acetate, and 0.08 parts by mass of 2,2' azobisisobutyronitrile- (2-2'-azobisisobutyronitrile) was added to a reaction vessel equipped with a stirrer, a thermometer, a reflux condenser, a dropping device, and a nitrogen introduction tube to obtain a reaction liquid. Next, the air in the reaction vessel was replaced with nitrogen. Under the nitrogen atmosphere, the reaction solution was heated to 60 ° C while stirring the reaction solution, and after reacting for 16 hours, the reaction solution was cooled to room temperature. Here, a part of the obtained solution was measured by a GPC method, and it was confirmed that the produced polymer (B) had a mass average molecular weight of 1.6 million. To 100 parts by mass (solid content) of the above polymer (B), 0.15 parts by mass of a polyisocyanate crosslinking agent (manufactured by Mitsui Chemicals, Inc., trade name "TAKENATE D-110N") and 0.1 parts by mass are added. The decane coupling agent ("KBM-403" manufactured by Shin-Etsu Chemical Co., Ltd.) was mixed and mixed to obtain a mixed liquid. In the mixed solution, toluene as a solvent was further added to adjust the solid content to 15% by mass to prepare an adhesive composition E.

Comparative Example 2 will be described below.

In addition to changing the adhesive composition as follows, A double-sided adhesive sheet was produced in the same manner as in the foregoing Example 1.

77.0 parts by mass of n-butyl acrylate (n-butyl) Acrylate), 20.0 parts by mass of methyl acrylate, 3.0 Parts by mass of acrylic acid, 200 parts by mass of ethyl acetate and 0.08 parts by mass of 2,2' azobisisobutyronitrile-(2-2'-azobisisobutyronitrile) were added with a stirrer, thermometer, reflux The reaction liquid was obtained in a reaction vessel of a cooler, a drip device, and a nitrogen gas introduction tube. Next, the air in the reaction vessel was replaced with nitrogen. Under the nitrogen atmosphere, the reaction solution was heated to 60 ° C while stirring the reaction solution, and after reacting for 16 hours, the reaction solution was cooled to room temperature. Here, a part of the obtained solution was measured by a GPC method, and it was confirmed that the produced polymer (C) had a mass average molecular weight of 1.6 million. To 100 parts by mass (solid content) of the above polymer (C), two parts by mass of a polyisocyanate crosslinking agent (manufactured by Nippon Polyurethane Co., Ltd., trade name "CORONATE L"), 1.5 pieces are added. A part by mass of an aluminum chelate crosslinking agent (manufactured by Amika Chemical Co., Ltd., trade name "M-5A") and 0.1 parts by mass of a decane coupling agent ("KBM-403" manufactured by Shin-Etsu Chemical Co., Ltd.) and mixed A mixture was obtained. In the mixture, the toluene as a solvent was further added to adjust the solid content to 15% by mass to prepare the adhesive composition F.

Comparative Example 3 will be described below.

In addition to 20 parts by mass of the adhesive composition A (propylene oxime) The oxyethyl)isocyanurate (manufactured by Toagosei Co., Ltd., trade name "ARONIX M-315") was changed to three parts by mass, and the adhesive composition G was prepared in the same manner as in the above-mentioned Example 1. Make double-sided adhesive sheets.

Among them, the double-sided adhesive sheets used in the respective examples and comparative examples The first release film and the second release film, the arithmetic mean roughness Ra of the surfaces of the two The maximum protrusion height Rp was measured using a surface roughness measuring machine SV3000S4 (stylus type) manufactured by Mitutoyo Co., Ltd. and in accordance with Japanese Industrial Standard JIS B 0601-1994.

Among them, the double-sided adhesive sheets used in the respective examples and comparative examples The ratio of the unevenness of the surface of the first release film and the second release film in the direction of the adhesive layer from the reference surface of ±0.2 μm is the use of the optical interference type surface shape observation device "Wyko". NT-1100" (manufactured by Veeco Co., Ltd.) was obtained. This device performs a stitching measurement at 2.5 times by the VSI mode. In the obtained surface shape profile in the range of 4 × 4 mm, the contour map is binarized so as to be divided into a portion outside the range of ±0.2 μm from the reference surface and a portion within the range of ±0.2 μm. . Thereby, the ratio of the unevenness outside the range of ±0.2 μm from the reference surface was calculated.

In addition, the double-sided adhesive sheets used in the respective examples and comparative examples were used. The release force of each of the first release film and the second release film with respect to the adhesive layer was measured using a tensile tester in accordance with Japanese Industrial Standard JIS-Z0237. The measurement was carried out after the double-sided adhesive sheet was formed, and then solidified for 7 days at 23 ° C and a relative humidity of 50%, and then cut into a width of 20 mm and a length of 200 mm in the state of fixing the adhesive layer. The first release film or the second release film is stretched in a direction of 180 degrees at a speed of 300 mm per minute.

In addition, the double-sided adhesive sheets used in the respective examples and comparative examples, After the production, the film was continuously cured for 7 days at 23 ° C and 50% relative humidity, and the adhesive layer was made into a size of 80 mm × 80 mm. Sample. Thereafter, the adhesive layer of the sample was coated on a polyester mesh (mesh size 200), and only the weight of the adhesive was measured by a precision balance. The weight at this time is expressed as M1. The adhesive was immersed in an ethyl acetate solvent using a Soxhlet and subjected to reflux for 16 hours. Thereafter, the adhesive was taken out and the adhesive was air-dried for 24 hours at 23 ° C and a relative humidity of 50%. It was further dried by an oven at 80 degrees Celsius for 12 hours. The weight of only the adhesive after drying was measured by a precision balance. The weight at this time is expressed as M2. The gel fraction is expressed by (M2/M1) × 100 (%).

The results are shown in Tables 1-1~1-3.

Furthermore, after the double-sided adhesive sheets of the respective examples and comparative examples were produced, After 7 days of continuous curing at 23 ° C and 50% relative humidity, the first surface (first release film direction) and the second surface (second release film direction) of the adhesive layer were each measured. The ratio of the unevenness outside the range of ±0.2 μm on the reference surface. If the surface of the adhesive layer is smooth, this value will be close to 0%. The splicing measurement was performed at a magnification of 2.5 by the VSI mode using the optical interference type surface shape observation device "Wyko NT-1100" (manufactured by Veeco Co., Ltd.). In the obtained surface shape profile in the range of 4 × 4 mm, the contour map is binarized so as to be divided into a portion outside the range of ±0.2 μm from the reference surface and a portion within the range of ±0.2 μm. . Thereby, the ratio of the unevenness outside the range of ±0.2 μm from the reference surface was calculated. The results are shown in Tables 1-1 to 1-3.

The evaluation of each of the examples and the comparative examples will be described below.

Evaluation of the double-sided adhesive sheet obtained as described above was carried out below.

The orange peel evaluation of the first surface of the adhesive layer will be described below. Sight).

After the double-sided adhesive sheets of the respective examples and comparative examples were produced, The curing was continued for 7 days under conditions of 23 degrees and a relative humidity of 50%. Next, each of the second release films of each of the double-sided adhesive sheets is peeled off to expose the respective adhesive layers. Next, the exposed adhesive layer was attached to a black acrylic plate (manufactured by MITSUBISHI RAYON Co., Ltd.). Thereafter, the first release film is peeled off, and the light of the fluorescent lamp is reflected on the black acrylic plate for observation. The image of the fluorescent lamp illuminated on the black acrylic sheet was judged to be good in appearance when it was not warped (○), and it was judged that the appearance was poor (×) in the case of distortion.

The orange peel evaluation of the second surface of the adhesive layer will be described below. Sight).

After the double-sided adhesive sheets of the respective examples and comparative examples were produced, The curing was continued for 7 days under conditions of 23 degrees and a relative humidity of 50%. Next, each of the second release films of each of the double-sided adhesive sheets is peeled off to expose the respective adhesive layers. Next, the double-sided adhesive sheet was placed on a black acrylic sheet (manufactured by MITSUBISHI RAYON Co., Ltd.) with the exposed adhesive layer facing upward. The light from the fluorescent lamp is reflected on the black acrylic plate for observation. The image of the fluorescent lamp illuminated on the black acrylic sheet was judged to be good in appearance when it was not warped (○), and it was judged that the appearance was poor (×) in the case of distortion.

The evaluation of the transfer phenomenon (cry separation) will be described below.

The double-sided adhesive sheets of the respective examples and the comparative examples were wound into a wide width 500mm drum form. Next, after the double-sided adhesive sheet was produced, the double-sided adhesive sheet was continuously cured for 7 days at 23 ° C and a relative humidity of 50%. Next, when the second release film of each double-sided adhesive sheet was peeled off by 10 m under the conditions of a peeling speed of 10 m per minute and a peeling angle of 90 degrees, it was visually confirmed whether or not the adhesive was transferred to the second. Release film. As a result, the judgment is made based on the following criteria.

○: Not transferred to the second release film.

×: A case where the transfer to the second release film occurs.

These results are shown in Table 2.

As can be seen from Table 2, the double-sided adhesive sheet of the present invention prevents the occurrence of orange peel. Moreover, the double-sided adhesive sheet of the present invention prevents the occurrence of crying separation.

On the contrary, the comparative example did not give satisfactory results.

1‧‧‧Double-sided adhesive sheet

10‧‧‧Adhesive layer

101‧‧‧ first surface

102‧‧‧ second surface

11‧‧‧First release film

111‧‧‧First release agent layer

112‧‧‧First substrate film

12‧‧‧Second release film

121‧‧‧Second release agent layer

122‧‧‧Second substrate film

Claims (5)

A double-sided adhesive sheet comprising: an adhesive layer having a first surface and a second surface; a first release film attached to the first surface of the adhesive layer; and a second release a film attached to the second surface of the adhesive layer; wherein the release force of the second release film from the adhesive layer is less than the peeling of the first release film from the adhesive layer a release force; wherein the adhesive layer is formed using an adhesive containing an active energy ray-curable resin; wherein the adhesive layer has a gel fraction of 70% or more; wherein the adhesive layer When the gel fraction of the current layer after formation is expressed as X [%], and the gel fraction of the adhesive layer after 7 days from the formation of the adhesive layer is expressed as Y [%], the relationship of X/Y ≧ 0.9 is satisfied. The ratio of the unevenness outside the range of ±0.2 μm from the reference surface to the first surface and the second surface of the adhesive layer is 20% or less. The double-sided adhesive sheet according to claim 1, wherein the adhesive layer has a storage elastic modulus of 0.15 MPa or more at 7 degrees Celsius after 7 days. The double-sided adhesive sheet according to claim 1, wherein the first release film and the surface of the second release film opposite to the surface in contact with the adhesive layer have an arithmetic mean roughness Ra of 50 nm or less. And the maximum protrusion height Rp is 1000 nm or less. The double-sided adhesive sheet according to claim 1, wherein the release force of the first release film peeled off from the adhesive layer is represented by X [mN/25 mm], and the second release film is adhered to the adhesive film. When the release force of the agent layer peeled off is expressed as Y [mN / 25 mm], the relationship of XY ≧ 5 is satisfied. A rewinder formed by bending a double-sided adhesive sheet as described in any one of claims 1 to 4.