TW201437009A - Laminated plate and method producing the same - Google Patents

Abstract

The present invention provides a metal-based laminated plate having excellent drill workability and bending workability. The present laminated plate comprising: a metal plate obtained by calendering method, an insulating layer provided on the metal plate which includes a resin, and a metal foil provided on the insulating layer. To the metal plate, a Rz(MD), i.e., 10 points mean roughness in a calendering direction, and a Rz(TD), i.e., 10 points means roughness in a direction perpendicular to the calendering direction of a surface in contact with the insulating layer are each independently 4 to 20 μ m, and the ratio of the Rz(TD) to the Rz(MD) (Rz(TD)/Rz(MD)) is 1.5 or less.

Description

Laminated board and manufacturing method thereof

The present invention relates to a laminate and a method of manufacturing the same.

In recent years, with the miniaturization, high performance, and high power of electric and electronic devices, it is required that the heat generated by the packaged components is easily dissipated in the circuit board, that is, the heat dissipation property is excellent. A circuit board which can cope with this requirement is a metal base circuit board having a metal plate, an insulating layer provided thereon, and a circuit pattern provided thereon. The metal base circuit substrate can be obtained by patterning the metal foil from a laminate having a metal plate, an insulating layer provided thereon, and a metal foil provided thereon (for example, refer to Patent Document 1) To 8).

Prior technical literature Patent literature

Patent Document 1: Japanese Patent Laid-Open No. Hei 5-172712

Patent Document 2: Japanese International Publication No. 2010/117023

Patent Document 3: Japanese Laid-Open Patent Publication No. 2011-32316

Patent Document 4: Japanese Laid-Open Patent Publication No. 2011-77270

Patent Document 5: Japanese Laid-Open Patent Publication No. 2011-181833

Patent Document 6: Japanese Laid-Open Patent Publication No. 2011-219749

Patent Document 7: Japanese Laid-Open Patent Publication No. 2011-249606

Patent Document 8: JP-A-2012-4323

In the conventional metal base circuit board described above, it is easy to cause a defect in the insulating layer during the chiseling process. Further, at the time of bending, the insulating layer may be easily peeled off from the metal plate. Therefore, an object of the present invention is to provide a laminated board excellent in chiseling workability and bending workability, and to provide a metal base circuit board excellent in punching workability and bending workability.

In order to achieve the above object, the present invention provides a laminate comprising: a metal plate obtained by a calendering method, an insulating layer provided on the metal plate and containing a resin, and a laminate of a metal foil provided on the insulating layer. The plate, the metal plate is: a ten point average roughness Rz (MD) in a rolling direction of a surface of the insulating layer and a ten point average roughness Rz (TD) perpendicular to the direction of the rolling direction are independent The ground is 4 to 20 μm, and the ratio of the aforementioned Rz (TD) to the aforementioned Rz (MD) (Rz (TD) / Rz (MD)) is 1.5 or less. Further, according to the present invention, there is provided a method for producing a laminated board, which is characterized in that the method for producing a laminated board has a step of roughening at least one surface of a raw material metal sheet obtained by a rolling method and obtaining the metal sheet.

The laminated board of the present invention is excellent in chiseling workability and bending workability, and is excellent in heat dissipation.

The laminate of the present invention is a laminate having a metal plate, an insulating layer disposed thereon, and a metal foil disposed thereon.

In the present invention, the following metal plate is used, that is, the metal plate obtained by the calendering method, wherein at least one side has a ten point average roughness in the rolling direction and a ten point average roughness perpendicular to the direction of the rolling direction are independent. The ground is 4 to 20 μm, and the ratio of the ten-point average roughness perpendicular to the rolling direction to the ten-point average roughness in the rolling direction (the ten-point average roughness in the direction perpendicular to the rolling direction/the ten-point average of the rolling direction) A rough metal plate having a roughness of 1.5 or less is laminated so that the rough surface is in contact with the insulating layer. That is, on the surface of the metal plate that is in contact with the insulating layer, the ten-point average roughness in the rolling direction is Rz (MD), and the ten-point average roughness in the direction perpendicular to the rolling direction is Rz (TD). Rz(MD) and Rz(TD) are each independently 4 to 20 μm, and Rz(TD)/Rz(MD) is 1.5 or less. Thereby, a laminated board which is excellent in the punching workability and the bending workability and which is excellent in heat dissipation properties can be obtained.

The other side of the metal plate, that is, the surface opposite to the surface that is in contact with the insulating layer, may be a mirror surface or a rough surface. When it is a rough surface, it may be the same as the surface that is in contact with the insulating layer, and may be rolled in the same direction. Ten point average roughness and vertical The ten-point average roughness in the direction perpendicular to the rolling direction is independently 4 to 20 μm, and the ratio of the ten-point average roughness perpendicular to the rolling direction to the ten-point average roughness in the rolling direction (perpendicular to the rolling direction) The ten-point average roughness in the direction/the ten-point average roughness in the rolling direction is a rough surface of 1.5 or less, or a rough surface other than this.

Preferably, Rz (MD) and Rz (TD) are each independently 4 to 10 μm, and Rz(TD)/Rz(MD) is preferably 1.2 or less, whereby the chiseling workability or bending of the laminate can be further improved. Processability.

The ten-point average roughness of the surface of the metal plate was measured in accordance with JIS B0601:1994.

Such a metal plate is obtained by uniformly and appropriately roughening at least one surface of the raw material metal plate obtained by the rolling method so as to be the predetermined rough surface. The roughening may be performed on both sides or on only one side, but in order to further improve the punching workability or bending workability of the laminated board, it is preferable to carry out the double-sided.

The roughening can be carried out by a dry roughening method such as sandblasting or polishing, or by a wet roughening method such as anodizing or etching. Among them, it is preferable to perform roughening by sandblasting, whereby the chiseling workability or bending workability of the laminated plate can be further improved. Sand blasting is a method in which an abrasive such as alumina, steel granules, sand, glass beads or the like is blown to a metal plate by air pressure or centrifugal force to roughen the metal plate.

Examples of the material of the metal plate include aluminum, iron, and copper, and may be an alloy such as an aluminum alloy or stainless steel. Among them, copper and aluminum alloy are preferred. The metal plate may contain a non-metal such as carbon, and may, for example, contain aluminum compounded with carbon. The metal plate preferably has a high thermal conductivity, and the thermal conductivity is preferably 60 W‧ m ^-1 ‧ K ^-1 or more.

The thickness of the metal plate is generally 0.2 mm or more, preferably 0.5 mm or more, whereby the heat dissipation property of the laminated board can be easily improved. Further, the thickness of the metal plate is generally 5 mm or less, preferably 1.5 mm or less, whereby the chiseling workability or the bending workability of the laminated plate can be easily improved. The metal plate can be flexible or not flexible. The metal plate may have a single layer configuration or a multilayer construction.

The insulating layer is provided on the metal plate and contains a resin. The resin functions as an adhesive for adhering a metal plate and a metal foil, and a function of flattening the surface of the insulating layer.

Examples of the resin include polypropylene, polyamide, polyester other than liquid crystal polyester, liquid crystal polyester, polyphenylene sulfide, polyether ketone, polycarbonate, polyether oxime, polyphenylene ether, and polyether oxime. A thermoplastic resin such as an amine or a thermosetting resin such as a phenol resin, an epoxy resin, a polyimide resin, or a cyanate resin may be used. Among them, liquid crystal polyester is preferred because of its high heat resistance and low dielectric loss.

The liquid crystal polyester is a polyester which exhibits liquid crystallinity in a molten state, and is preferably a liquid crystal polyester which is melted at a temperature of 450 ° C or lower. The liquid crystal polyester may be a liquid crystal polyester decylamine, or a liquid crystal polyester ether, a liquid crystal polyester carbonate, or a liquid crystal polyester quinone. The liquid crystal polyester is preferably a wholly aromatic liquid crystal polyester using only an aromatic compound as a raw material monomer.

Typical examples of the liquid crystal polyester include: making aromatic a liquid crystal polyester obtained by polymerizing (polycondensing) a hydroxycarboxylic acid and an aromatic dicarboxylic acid with at least one compound selected from the group consisting of an aromatic diol, an aromatic hydroxyamine, and an aromatic diamine, and a plurality of A liquid crystal polyester obtained by polymerizing an aromatic hydroxycarboxylic acid, and a liquid crystal obtained by polymerizing an aromatic dicarboxylic acid and at least one compound selected from the group consisting of an aromatic diol, an aromatic hydroxylamine, and an aromatic diamine. A polyester, and a liquid crystal polyester obtained by polymerizing a polyester such as polyethylene terephthalate with an aromatic hydroxycarboxylic acid. Here, the aromatic hydroxycarboxylic acid, the aromatic dicarboxylic acid, the aromatic diol, the aromatic hydroxylamine, and the aromatic diamine may be used in place of a part or all of the polymerizable derivative.

Examples of the polymerizable derivative of a compound having a carboxyl group of an aromatic hydroxycarboxylic acid and an aromatic dicarboxylic acid include derivatives (esters) obtained by converting a carboxyl group into an alkoxycarbonyl group or an aryloxycarbonyl group. A derivative (oxyhalide) obtained by converting a carboxyl group into a halomethyl group, and a derivative (anhydride) obtained by converting a carboxyl group into a fluorenyloxy group. Examples of the polymerizable derivative of a compound having a hydroxyl group like an aromatic hydroxycarboxylic acid, an aromatic diol, and an aromatic hydroxyamine include a derivative obtained by thiolation of a hydroxy group into a methoxy group. Matter (telluride). Examples of the polymerizable derivative of the compound having an amine group such as an aromatic hydroxylamine and an aromatic diamine include a derivative obtained by hydrazylating an amine group and converting it into a mercapto group. ).

The liquid crystal polyester preferably has a repeating unit represented by the following formula (1) (hereinafter sometimes referred to as "repeating unit (1)"), and particularly preferably has a repeating unit (1) and is represented by the following formula (2) Repeat unit (hereinafter, sometimes referred to as "Repeating unit (2)") and a repeating unit expressed by the following formula (3) (hereinafter, sometimes referred to as "repetitive unit (3)").

(1)-O-Ar ¹ -CO-

(2)-CO-Ar ² -CO-

(3)-X-Ar ³ -Y-

(Ar ¹ represents a phenyl group, an extended naphthyl group or a biphenyl group; and Ar ² and Ar ³ each independently represent a phenyl group, a naphthyl group, a phenyl group or a group represented by the following formula (4); And Y each independently represent an oxygen atom or an imido group (-NH-); a hydrogen atom located in the above-mentioned group represented by Ar ¹ , Ar ² or Ar ³ may be independently a halogen atom, an alkyl group or an aryl group, respectively. Replaced by)

(4)-Ar ⁴ -Z-Ar ⁶ -

(Ar ⁴ and Ar ⁶ each independently represent a phenyl or anthracene group; Z represents an oxygen atom, a sulfur atom, a carbonyl group, a sulfonyl group or an alkylene group)

Examples of the halogen atom system include a fluorine atom, a chlorine atom, a bromine atom, and an iodine atom. Examples of the alkyl group include methyl group, ethyl group, n-propyl group, isopropyl group, n-butyl group, isobutyl group, secondary butyl group, tert-butyl group, n-hexyl group, and 2-ethylhexyl group. , n-octyl and n-decyl, the carbon number is generally from 1 to 10. Examples of the above aryl group include a phenyl group, an o-tolyl group, a m-tolyl group, a p-tolyl group, a 1-naphthyl group and a 2-naphthyl group, and the carbon number is usually from 6 to 20. When the hydrogen atom is substituted by such a group, the number of each of the groups represented by Ar ¹ , Ar ² or Ar ³ is generally 2 or less, preferably 1 or less.

Examples of the above alkylene group include a methylene group, an ethylene group, an isopropylidene group, a n-butylene group, and a 2-ethylhexylene group, and the carbon number thereof is generally It is from 1 to 10.

The repeating unit (1) is a repeating unit derived from a predetermined aromatic hydroxycarboxylic acid. Repeating unit (1) is preferably based on the repeat unit Ar ¹ is phenylene of (1) (repeating units derived from hydroxybenzoic acid on), and Ar ¹ is 2,6-naphthalene group The repeating unit (1) (from Repeat unit of 6-hydroxy-2-naphthoic acid).

The repeating unit (2) is a repeating unit derived from a predetermined aromatic dicarboxylic acid. The repeating unit (2) is preferably Ar ² is a repeating unit of the pendant phenyl group (2) (repeating unit derived from terephthalic acid), and Ar ² is a repeating unit of the extended phenyl group (2) (from isophthalic acid) Repeat unit of formic acid), Ar ² is a repeating unit of phenylene (2) (repeating unit derived from terephthalic acid), and Ar ² is a repeating unit of 2,6-anthranyl group (2) (from 2, Repeating unit of 6-naphthalenedicarboxylic acid), and Ar ² is a repeating unit of diphenyl ether-4,4'-diyl (2) (repeated from diphenyl ether-4,4'-dicarboxylic acid) unit).

The repeating unit (3) is a repeating unit derived from a predetermined aromatic diol, an aromatic hydroxylamine or an aromatic diamine. The repeating unit (3) is preferably Ar ³ is a repeating unit (3) of a pendant phenyl group (a repeating unit derived from hydroquinone, p-aminophenol or p-phenylenediamine).

The content of the repeating unit (1) is a total amount with respect to all the repeating units (by dividing the mass of each repeating unit constituting the liquid crystal polyester by the formula of each repeating unit, the mass equivalent of each repeating unit is obtained. The ear), and the sum of these values, is generally 30% by mole or more, preferably 30 to 80% by mole, particularly preferably 30 to 60% by mole, more preferably 30 to 40% by mole. . The content of the repeating unit (2) is generally 35 mol% or more, preferably 10 to 35 mol%, based on the total amount of all repeating units. It is preferably 20 to 35 mol%, more preferably 30 to 35 mol%. The content of the repeating unit (3) is generally 35 mol% or more, preferably 10 to 35 mol%, particularly preferably 20 to 35 mol%, more preferably 30 to 30% by mole based on the total of all repeating units. 35 moles %. The more the content of the repeating unit (1), the easier it is to improve heat resistance, strength, and rigidity, and if too much, the solubility in a solvent is liable to lower.

The ratio of the content of the repeating unit (2) to the content of the repeating unit (3) is expressed by [content of repeating unit (2)] / [content of repeating unit (3)] (mol/mole), generally From 0.9/1 to 1/0.9, preferably from 0.95/1 to 1 to 0.95, particularly preferably from 0.98/1 to 1/0.98.

The liquid crystal polyester system may independently have two or more kinds of repeating units (1) to (3). Further, the liquid crystal polyester may have a repeating unit other than the repeating units (1) to (3), and the content is generally 10 mol% or less, preferably 5 mol%, based on the total amount of all repeating units. the following.

The liquid crystal polyester has a repeating unit (3) in which X and/or Y is an imine group as a repeating unit (3), that is, has a repeating unit derived from a predetermined aromatic hydroxylamine and/or derived from an aromatic diamine. The repeating unit is preferably excellent in solubility in a solvent, and more preferably a repeating unit (3) having only X and/or Y as an imine group as a repeating unit (3).

The liquid crystal polyester is preferably produced by melt-polymerizing a raw material monomer corresponding to the repeating unit constituting the liquid crystal, and solid-phase polymerizing the obtained polymer (prepolymer). Thereby, a high molecular weight liquid crystal polyester having high heat resistance, strength, and rigidity can be produced with good operability. The melt polymerization can be carried out in the presence of a catalyst, and examples of the catalyst include magnesium acetate and stannous acetate. a metal compound such as tetrabutyl titanate, lead acetate, sodium acetate, potassium acetate or antimony trioxide, or a nitrogen-containing heterocyclic compound such as 4-(dimethylamino)pyridine or 1-methylimidazole. It is preferred to use a nitrogen-containing heterocyclic compound.

The liquid crystal polyester has a flow initiation temperature of usually 250 ° C or higher, preferably 250 to 350 ° C, and particularly preferably 260 to 330 ° C. The higher the flow initiation temperature, the easier it is to improve heat resistance, strength, and rigidity. If it is too high, the solubility in a solvent is liable to lower, or the viscosity of a liquid composition tends to be high.

The flow initiation temperature is also referred to as a melt flow temperature or a flow temperature, and the liquid crystal polyester is melted while being heated at a rate of 4 ° C/min under a load of 9.8 MPa (100 kg/cm ² ) using a capillary rheometer. When extruded from a nozzle having an inner diameter of 1 mm and a length of 10 mm, the temperature of the viscosity of 4800 Pa ‧ (48,000 poise) is displayed, which is the standard of the molecular weight of the liquid crystal polyester (refer to the small liquid crystal, synthetic, forming) And application - (Japanese original: LCD - Synthesis, Forming, Application -", CMC Corporation, June 5, 1987, p. 95).

The ratio of the resin to the insulating layer is preferably from 30 to 60% by volume, particularly preferably from 35 to 55% by volume. If the ratio is excessively lowered, the adhesion of the insulating layer to the metal plate or the metal foil is lowered, or the surface flatness of the insulating layer is lowered. Further, if the ratio is excessively increased, the heat dissipation property of the laminated board is lowered.

The insulating layer preferably further contains at least one inorganic filler selected from the group consisting of alumina, cerium oxide, boron nitride, and aluminum nitride. Since the insulating layer contains the inorganic filler, the heat dissipation property of the laminated board can be improved.

At least a part of the inorganic filler may be a surface-treated inorganic filler in order to improve the adhesion to the resin or the dispersibility in the resin composition described later. Examples of the surface treatment agent which can be used for the surface treatment thereof include a decane coupling agent, a titanium coupling agent, an aluminum coupling agent, a zirconium coupling agent, a long-chain fatty acid, an isocyanate compound, and an epoxy group or a methoxyalkyl group. A polymer of an amine group or a hydroxyl group.

The ratio of the above inorganic filler to the insulating layer is preferably from 40 to 70% by volume, particularly preferably from 45 to 65% by volume. If the ratio is excessively lowered, the heat dissipation of the laminate is lowered. Further, if the ratio is excessively increased, the chiseling workability or the bending workability of the laminated sheet is lowered.

The insulating layer may contain a resin and a component other than the inorganic filler, for example, an organic filler or an additive, and the ratio of the insulating layer is generally 0 to 10% by volume. Examples of the organic filler include a hardened epoxy resin, a crosslinked benzoguanamine resin, and a crosslinked acrylic resin. Examples of the additives include a leveling agent, an antifoaming agent, an antioxidant, an ultraviolet absorber, a flame retardant, and a coloring agent.

Further, the insulating layer may contain an inorganic filler other than alumina, cerium oxide, boron nitride or aluminum nitride, and when it is contained in a plurality of kinds, the total amount is generally from 0 to 10% by volume.

The metal foil is placed on the insulating layer with the insulating layer interposed therebetween to face the metal plate. Examples of the material of the metal foil include copper and aluminum, and may be an alloy. The thickness of the metal foil is generally from 10 to 500 μm.

The laminate of the present invention can be manufactured by (A): firstly, a laminated intermediate of a metal foil and an insulating layer is formed, and then the insulating layer is used. As a bonding surface, the laminated intermediate body is bonded to the rough surface of the metal plate by thermocompression bonding or the like; or (B): first, the rough surface of the metal plate is used as a bonding surface to form a metal plate and insulation. a laminated intermediate layer, and then the insulating layer is used as a bonding surface, and the laminated intermediate is bonded to the metal foil by thermocompression bonding or the like; or (C): first, insulating layer is formed as an insulating layer In the film, the rough surface of the metal plate is used as a bonding surface, and the insulating film is sandwiched between a metal plate and a metal foil, and bonded by thermal pressing or the like.

The formation of the insulating layer is preferably carried out by applying a liquid composition containing a resin and a solvent to a support and drying the obtained coating film (solvent removal). At this time, by using a metal foil as a support, a laminated intermediate of the metal foil and the insulating layer in the above (A) can be produced. Further, by using a metal plate as a support, a laminated intermediate body of the metal plate and the insulating layer in the above (B) can be produced. Further, when a metal foil and a support other than the metal plate, for example, a resin film such as a polyester film, a polypropylene film, a fluororesin film, a nylon film, or a polymethylpentene film, are used as the support, by thermocompression And the like, the insulating layer formed on the support is transferred from the support to the metal foil, whereby the laminated intermediate of the metal foil and the insulating layer in the above (A) can be manufactured, or by thermocompression bonding or the like, The insulating layer formed on the support is transferred from the support to the metal plate, whereby the laminated intermediate body of the metal plate and the insulating layer in the above (B) can be manufactured, or the support can be formed on the support. The insulating layer is peeled off, whereby the insulating film in the above (C) can be produced.

In the solvent, a solvent capable of dissolving the resin to be used can be appropriately selected, and specifically, a solvent which is soluble at a concentration of 1% by mass or more ([resin] / [resin + solvent]) at 50 ° C can be used.

Examples of the solvent include halogenated hydrocarbons such as dichloromethane, chloroform, 1,2-dichloroethane, 1,1,2,2-tetrachloroethane, o-dichlorobenzene, and the like; a halogenated phenol such as chlorophenol or pentafluorophenol; an ether such as diethyl ether, tetrahydrofuran or 1,4-dioxane; a ketone such as acetone or cyclohexanone; an ester of ethyl acetate or γ-butyrolactone; a carbonate such as vinyl ester or propylene carbonate; an amine such as triethylamine; a nitrogen-containing heterocyclic aromatic compound such as pyridine; a nitrile such as acetonitrile or succinonitrile; N,N-dimethylformamide, N, a guanamine such as N-dimethylacetamide or N-methylpyrrolidone; a urea compound such as tetramethylurea; a nitro compound such as nitromethane or nitrobenzene; a dimethyl hydrazine or a ring; A sulphide such as butyl sulfonate or a phosphide such as hexamethylene phosphine amide or tri-n-butyl phosphonic acid may be used.

Since the solvent is low in corrosiveness and easy to handle, it is preferably a solvent which is an aprotic compound, particularly an aprotic compound having no halogen atom, and a ratio of the aprotic compound to the entire solvent, preferably 50 to 100% by mass, particularly preferably 70 to 100% by mass, more preferably 90 to 100% by mass. Further, since the aprotic compound is easily dissolved in the resin, it is preferably N,N-dimethylformamide, N,N-dimethylacetamide or N-methylpyrrolidone. amine.

Further, since the solvent is easily dissolved in the resin, it is preferably a solvent containing a compound having a dipole moment of 3 to 5 as a main component, and a compound having a dipole moment of 3 to 5 is a ratio of the entire solvent, preferably 50 to 100. The mass %, particularly preferably from 70 to 100% by mass, more preferably from 90 to 100% by mass, is preferably a compound having a dipole moment of from 3 to 5 as the aprotic compound.

Further, since the solvent is easily removed, it is preferably 1 A solvent having a boiling point of 220 ° C or less at atmospheric pressure as a main component, and a compound having a boiling point of 220 ° C or less at 1 atm. as a whole of the solvent, preferably 50 to 100% by mass, particularly preferably 70 to 100% by mass. More preferably, it is 90 to 100% by mass, and the aprotic compound is preferably a compound having a boiling point of 220 ° C or less at 1 atm.

The content of the resin in the liquid composition is usually from 5 to 60% by mass, preferably from 10 to 50% by mass, particularly preferably from 15 to 45% by mass, based on the total amount of the resin and the solvent, and can be appropriately adjusted. A liquid composition having a desired viscosity can be obtained.

The preparation of the liquid composition is preferably carried out by dispersing the inorganic filler and other components as needed in a solution in which a resin and other components as needed are dissolved in a solvent. The inorganic filler can be dispersed in the solution while being pulverized by a ball mill, a three-roll mill, a centrifugal mixer, a bead mill or the like.

Examples of the method of applying the liquid composition to the support include a roll coating method, a bar coating method, a screen printing method, a die coating method, and a slanting wheel coating method, and may be continuous or Batch type (single board).

Drying of the coating film is preferably carried out by evaporating the solvent from the coating film. When a support other than the metal foil and the metal plate is used as a support, the coating film formed on the support is dried, and the obtained dried film is transferred from the support to the metal foil or the metal plate by thermocompression bonding or the like. In this case, it is preferred to carry out a part of the solvent remaining in the dried film. At this time, the amount of the solvent in the dried film is preferably from 1 to 25% by mass. The drying temperature is usually from 50 to 180 ° C, preferably from 80 to 150 ° C.

The dried film formed on the support or the dried film transferred to the metal foil or the metal plate is preferably subjected to heat treatment when a thermoplastic resin is used as the resin, whereby the molecular weight and the degree of crystallization can be adjusted to obtain adhesion. An insulating film excellent in properties or thermal conductivity. The heat treatment is carried out under an inert gas atmosphere such as nitrogen, generally at 250 to 350 ° C, preferably at 270 to 320 ° C.

When the laminated intermediate of the metal foil and the insulating layer is obtained in this way, as described in the above (A), the insulating layer is used as a bonding surface, and the laminated intermediate body and the metal plate are thickened by thermocompression bonding or the like. The laminated sheets of the present invention can be obtained by surface bonding. In addition, when the laminated surface of the metal plate and the insulating layer is obtained by using the rough surface of the metal plate as the bonding surface, as described in the above (B), the insulating layer is used as the bonding surface, and by thermocompression bonding or the like. The laminated intermediate is bonded to a metal foil, whereby the laminated board of the present invention can be obtained. Further, when the insulating layer formed on the support is peeled off from the support to obtain an insulating film, as described in the above (C), the rough surface of the metal plate is used as a bonding surface, and the metal plate and the metal foil are sandwiched between the metal plate and the metal foil. The insulating film is bonded to the insulating film by heat pressing or the like, whereby the laminated board of the present invention can be obtained.

From the laminated board obtained in this way, the metal foil is patterned to form a circuit pattern, and if necessary, a cutting process such as a cutting process or a hole drilling process, a bending process, or the like is performed, thereby obtaining a metal base circuit. Substrate. For the patterning of the metal foil, for example, a mask pattern can be formed on the metal foil, and the exposed portion of the metal foil can be removed by etching.

Example [Determination of Flow Starting Temperature of Liquid Crystal Polyester]

Using a melt flow tester ("CFT-500 type" of Shimadzu Corporation,), about 2 g of liquid crystal polyester was loaded on a cylinder equipped with a die having a nozzle having an inner diameter of 1 mm and a length of 10 mm, while being at 9.8 MPa. The temperature was raised at a rate of 4 ° C /min under a load of (100 kg / cm ² ), and the liquid crystal polyester was melted, extruded from a nozzle, and a temperature at which a viscosity of 4800 Pa ‧ (48000 P) was measured was measured.

[Determination of Viscosity of Liquid Crystalline Polyester Solution]

Using a B-type viscometer ("TVL-20 type" of Toki Sangyo Co., Ltd.), the rotor of No. 21 was measured at a number of revolutions of 20 rpm.

[Determination of ten-point average roughness of the surface of a metal plate]

Using a surface roughness measuring device (KLA Tencor Co., Ltd., calculation standard JIS B0601-1994), it was measured under the conditions of a measurement speed: 5 μm/sec and an evaluation length: 1.0 mm in accordance with JIS B0601:1994.

[Metal plate]

For the use of a metal plate: by means of sandblasting, the double-sided surface obtained by the calendering method is mirror-finished (ten-point average roughness in the rolling direction: 1.2 μm, ten-point average roughness in the direction perpendicular to the rolling direction: 2.4 μm) A metal plate obtained by roughening one surface of an aluminum alloy plate having a thickness of 1.0 mm is a rough surface having a ten-point average roughness shown in Table 1 on one side, and a metal plate having a mirror surface thickness of 1.0 mm on the other side ( 1) to (4). Further, the aforementioned aluminum alloy plate was directly used as the metal plate (5).

[Chiseling processability]

The total chiseling die for the aluminum alloy plate was laminated by a molding machine ("80 Ton Press" of Aida Engineering Co., Ltd.) under the conditions of a clamping pressure of 20 kN, a releasing force of 59 kN, and a molding speed of 60 SPN. After the board was subjected to the chiseling process, it was confirmed by an optical microscope whether or not the insulating layer of the cutting surface was defective.

[bending workability]

The metal foil of the laminated board cut into a size of 10 mm × 30 mm was removed by etching, and the laminated body of the obtained metal plate and the insulating layer was bent by using the insulating layer as the outer side so that the bent portion became 15 mm in diameter. After 180°, it was visually observed whether or not the insulating layer was peeled off from the metal plate.

[The heat dissipation of the insulating layer]

The metal foil of the laminate cut into a size of 30 mm × 40 mm was partially removed by etching to form an island portion of 14 mm × 10 mm. Mounting the transistor ("C2233" of Toshiba Co., Ltd.) to the island using solder In the section, the obtained laminated plate with the transistor is attached to the water cooling device so that the metal plate is opposed to the cooling surface of the water cooling device via the polyoxygen oxide grease layer. Next, 30 W of power P is supplied to the transistor, and the temperature T1 of the transistor and the temperature T2 of the cooling surface of the water-cooling device are measured, and the ratio of the difference T1-T2 between the temperature T1 and the temperature T2 to the power P (T1- T2)/P acts as a thermal resistance.

Examples 1 and 2 and Comparative Examples 1 to 3 [Manufacture of Liquid Crystal Polyester]

6-hydroxy-2-naphthoic acid 1976 g (10.5 mol), 4-hydroxyacetonitrile 1474 g (9.75 mol), isophthalic acid 1620 g (9.75 mol) and acetic anhydride 2374 g (23.25 mol) were charged in A reactor equipped with a stirring device, a torque meter, a nitrogen gas introduction tube, a thermometer, and a reflux condenser, and replacing the gas in the reactor with nitrogen gas, and then raising the temperature from room temperature to 150 in 15 minutes while stirring under nitrogen gas under reflux. °C, reflux at 150 ° C for 3 hours. Next, while distilling off by-product acetic acid and unreacted acetic anhydride, the temperature was raised from 150 ° C to 300 ° C in 2 hours and 50 minutes, and after maintaining at 300 ° C for 1 hour, the contents were taken out from the reactor and cooled to Room temperature. The obtained solid matter was pulverized by a pulverizer to obtain a powdery prepolymer. The prepolymer had a flow initiation temperature of 235 °C. Next, the prepolymer was heated from room temperature to 223 ° C in 6 hours under a nitrogen atmosphere, and maintained at 223 ° C for 3 hours to carry out solid phase polymerization, followed by cooling to obtain a powdery liquid crystal polyester. The liquid crystal polyester had a flow initiation temperature of 270 °C.

[Modulation of Liquid Crystal Polyester Solution]

2200 g of liquid crystal polyester was added to 7800 g of N,N-dimethylacetamide. The mixture was heated at 100 ° C for 2 hours to obtain a liquid crystal polyester solution. The viscosity of the solution was 400 cP.

[Modulation of liquid composition]

Boron nitride and alumina were added to the liquid crystal polyester solution, and stirred by a centrifugal stirring deaerator for 5 minutes to obtain a liquid composition. Here, the ratio of the liquid crystal polyester to the boron nitride to the alumina is based on the specific gravity (liquid crystal polyester 1.37 g/cm ³ , alumina 3.98 g/cm ³ , boron nitride 2.28 g/cm ^{3 ).} The temperature was adjusted to 50% by volume of the liquid crystal polyester, 25% by volume of the alumina, and 25% by volume of the boron nitride.

[Manufacture of laminated intermediates of copper foil and insulating layer]

The liquid composition was applied to a polyester film having a thickness of 100 μm so that the thickness of the coating film was about 90 μm, and then dried at 100 ° C for 20 minutes. The laminated intermediate film of the obtained polyester film and the dried film is laminated with a copper foil having a thickness of 35 μm in such a manner that the dried film is in contact with the copper foil, and is heated to a temperature between 150 ° C and the hot roll to dry the film. The copper foil is thermocompression bonded. Next, the polyester film was peeled off, and the obtained intermediate layer of the copper foil and the dried film was heat-treated at 290 ° C for 3 hours to obtain a laminated intermediate of the copper foil and the insulating layer.

[Manufacture of laminate]

The laminated intermediate of the copper foil and the insulating layer is laminated with the metal plate. At this time, when the metal plates (1) to (4) are used as the metal plates, the rough faces of the metal plates are brought into contact with the insulating layer, and when the metal plates (5) are used as the metal plates, one side of the metal plates is brought into contact with each other. In the insulation layer. Next, heat treatment was performed at 340 ° C for 20 minutes while applying a pressure of 20 MPa to thermally press-bond the insulating layer to the metal plate. Evaluation of the chiseling process and bending workability of the obtained laminate The thermal resistance of the insulating layer was measured and measured, and the results are shown in Table 2.

Claims (7)

A laminated board comprising: a metal plate obtained by a rolling method, an insulating layer provided on the metal plate and containing a resin, and a metal foil provided on the insulating layer, the laminated board being characterized by: the metal plate The ten-point average roughness Rz (MD) of the rolling direction of the surface of the insulating layer and the ten-point average roughness Rz (TD) perpendicular to the direction of the rolling direction are each independently 4 to 20 μm, and the foregoing The ratio of Rz (TD) to the aforementioned Rz (MD) (Rz (TD) / Rz (MD)) is 1.5 or less. The laminate according to claim 1, wherein the resin is a liquid crystal polyester. The laminate according to the second aspect of the invention, wherein the liquid crystal polyester has a repeating unit represented by the following formula (1), a repeating unit represented by the following formula (2), and is represented by the following formula (3) The liquid crystal polyester of the repeating unit, (1)-O-Ar ¹ -CO-(2)-CO-Ar ² -CO-(3)-X-Ar ³ -Y- (Ar ¹ represents a phenyl group, a stretch a naphthyl group or a biphenyl group; Ar ² and Ar ³ each independently represent a phenylene group, a naphthyl group, a biphenyl group or a group represented by the following formula (4); and X and Y each independently represent an oxygen atom or An imino group; a hydrogen atom located in the aforementioned group represented by Ar ¹ , Ar ² or Ar ³ , which may be independently substituted by a halogen atom, an alkyl group or an aryl group) (4)-Ar ⁴ -Z-Ar ⁶ - (Ar ⁴ and Ar ⁶ each independently represent a phenyl or anthracene group; and Z represents an oxygen atom, a sulfur atom, a carbonyl group, a sulfonyl group or an alkylene group). The laminate according to claim 3, wherein the liquid crystal polyester has a repeating unit represented by the above formula (1) of 30 to 80 mol% with respect to a total of all repeating units constituting the liquid crystal polyester. A liquid crystal polyester having a repeating unit of 10 to 35 mol% represented by the above formula (2) and a repeating unit of 10 to 35 mol% represented by the above formula (3). The laminate according to claim 3, wherein X and/or Y are each an imine group. The laminate according to any one of claims 1 to 5, wherein the insulating layer further comprises at least one inorganic selected from the group consisting of alumina, cerium oxide, boron nitride, and aluminum nitride. Insulation of the filler. A method for producing a laminated board according to any one of claims 1 to 6, which has a method of manufacturing at least one side of a raw metal sheet obtained by a calendering method. The step of obtaining the aforementioned metal plate is carried out.