TW201417320A - Solar cell module, and method for producing same - Google Patents

Solar cell module, and method for producing same Download PDF

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TW201417320A
TW201417320A TW102133465A TW102133465A TW201417320A TW 201417320 A TW201417320 A TW 201417320A TW 102133465 A TW102133465 A TW 102133465A TW 102133465 A TW102133465 A TW 102133465A TW 201417320 A TW201417320 A TW 201417320A
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solar cell
solar
bus bar
electrode
solar battery
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TW102133465A
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Chinese (zh)
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Erika SATOMI
Kenichi Sugimura
Yasushi Yoshino
Kousuke Tsunoda
Yusuke Kawamoto
Tatsuya Baba
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Noritake Co Ltd
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Priority claimed from JP2013094726A external-priority patent/JP2014063978A/en
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Publication of TW201417320A publication Critical patent/TW201417320A/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/02002Arrangements for conducting electric current to or from the device in operations
    • H01L31/02005Arrangements for conducting electric current to or from the device in operations for device characterised by at least one potential jump barrier or surface barrier
    • H01L31/02008Arrangements for conducting electric current to or from the device in operations for device characterised by at least one potential jump barrier or surface barrier for solar cells or solar cell modules
    • H01L31/0201Arrangements for conducting electric current to or from the device in operations for device characterised by at least one potential jump barrier or surface barrier for solar cells or solar cell modules comprising specially adapted module bus-bar structures
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/048Encapsulation of modules
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/05Electrical interconnection means between PV cells inside the PV module, e.g. series connection of PV cells
    • H01L31/0504Electrical interconnection means between PV cells inside the PV module, e.g. series connection of PV cells specially adapted for series or parallel connection of solar cells in a module
    • H01L31/0512Electrical interconnection means between PV cells inside the PV module, e.g. series connection of PV cells specially adapted for series or parallel connection of solar cells in a module made of a particular material or composition of materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Photovoltaic Devices (AREA)

Abstract

Provided is a solar cell module having multiple solar cells on which five or more tub lines are formed. Also provided is a method for producing said solar cell module. Solar cells are placed on wiring sheets, to which bus bar electrodes are provided, and a contact is formed between the solar cells and the bus bar electrodes wired on the wiring sheets. Therefore, there is no need to use a solder ribbon when connecting solar cells in series or to use a heating device for heating the solder ribbon as was the case in prior art. As a consequence, the number of tab lines formed on the solar cells is no longer restricted by the number of heating devices, and it is possible to produce a solar cell module having multiple solar cells on which five tab lines are formed.

Description

太陽電池模組及其製造方法 Solar battery module and manufacturing method thereof 發明領域 Field of invention

本發明係有關於一種具有複數太陽電池組電池的太陽電池模組,尤其有關於一種可比習知設置更多配線在其太陽電池組電池之標記線數量的太陽電池模組及其製造方法。 The present invention relates to a solar cell module having a plurality of solar cell batteries, and more particularly to a solar cell module and a method of fabricating the same, which are provided with more marking lines for wiring the solar cell.

發明背景 Background of the invention

如專利文獻1、2所示,太陽電池模組中有一種將成列排列的複數太陽電池組電池複數串聯而成者。上述太陽電池模組例如係藉由下述步驟製造:金屬電極形成步驟,於前述太陽電池組電池之表面及背面形成標記線(母線電極)或其標記線及指狀電極;焊帶接著步驟,在鄰接之太陽電池組電池之間,藉由例如經焊塗佈之帶狀金屬箔的焊帶,使藉由前述金屬電極形成步驟而形成在一太陽電池組電池之表面的標記線及藉由前述金屬電極形成步驟而形成在另一太陽電池組電池之背面的標記線電性串聯;積層步驟,使密封材片材分別積層在藉由其焊帶接著步驟而電性串聯之複數太陽電池組電池之兩面,並使玻璃或透明樹脂積層在該等密封材片材之受光面側的密封材片材,並且, 於與該等密封材片材之受光面側為相反側的密封片材積層背部片材或透明樹脂;及疊合步驟,將藉由其積層步驟所積層之積層體以疊合機與前述密封材片材熱壓接成一體。在上述焊帶接著步驟中,例如在前述太陽電池組電池之兩面形成有2條標記線之情況下,係於該等2條標記線上配設2條焊帶,並藉由具有2個加熱裝置之加熱單元將其2條焊帶同時加熱,以使2條焊帶連接於2條標記線。而,上述標記線係用以適當彙集以上述太陽電池組電池所發電之電,且連接在其太陽電池組電池之表面或背面的電極並延伸於一方向的金屬線。又,上述指狀電極係將以上述太陽電池組電池所發電之電送至上述標記線的金屬線,而該金屬線相對於其標記線延伸於垂直方向。 As shown in Patent Documents 1 and 2, there is a solar battery module in which a plurality of solar battery cells arranged in series are connected in series. The solar cell module is manufactured, for example, by a metal electrode forming step of forming a marking line (bus bar electrode) or a marking line and a finger electrode on the front surface and the back surface of the solar cell battery; Between adjacent solar cell batteries, a marking line formed on the surface of a solar cell battery by the metal electrode forming step is formed by, for example, a solder ribbon of a strip-shaped metal foil which is applied by welding The metal electrode forming step is formed by electrically connecting the marking lines on the back surface of the other solar battery cell; and the laminating step is to laminate the sealing material sheets into the plurality of solar battery groups electrically connected in series by the welding strip. a sealing material sheet on both sides of the battery and having a glass or a transparent resin laminated on the light receiving surface side of the sealing material sheets, and Laminating the back sheet or the transparent resin on the sealing sheet opposite to the light-receiving side of the sealing material sheet; and the laminating step of laminating the laminated body laminated by the laminating step with the above-mentioned sealing machine The sheet material is thermocompression bonded into one. In the subsequent step of the solder ribbon, for example, when two marking lines are formed on both sides of the solar cell, two soldering strips are disposed on the two marking lines, and two heating devices are provided. The heating unit simultaneously heats the two strips so that the two strips are connected to the two marking lines. Further, the marking line is for appropriately collecting the electric power generated by the solar battery cell and connected to the electrode on the surface or the back surface of the solar battery cell and extending in one direction. Further, the finger electrode transmits electricity generated by the solar battery cell to the metal wire of the marking line, and the metal wire extends in a vertical direction with respect to the marking line.

先前技術文獻 Prior technical literature 專利文獻 Patent literature

專利文獻1:特開2010-287688號公報 Patent Document 1: JP-A-2010-287688

專利文獻2:特開2012-119458號公報 Patent Document 2: JP-A-2012-119458

發明概要 Summary of invention

另外,在如上述之太陽電池模組中,為了提升轉換效率而減低前述太陽電池組電池之電阻,故應增加標記線之條數。然而,於太陽電池組電池之兩面增加例如3條或4條的標記線時,在前述焊帶接著步驟中使配設在該等標記線上之焊帶同時加熱的加熱裝置即需要3個或4個,因此必 需依照其標記線之條數份配備前述加熱裝置,而在太陽電池組電池之大小(例如156mm×156mm)上供該等複數加熱裝置設置於加熱單元的空間有限。因此,習知中,非常難以製造具有複數個形成有5條以上標記線之太陽電池組電池的太陽電池模組。 Further, in the solar cell module as described above, in order to increase the conversion efficiency and reduce the resistance of the solar cell battery, the number of mark lines should be increased. However, when three or four marking lines are added to both sides of the solar battery, the heating means for simultaneously heating the welding strips disposed on the marking lines in the subsequent step of the welding strip requires three or four. So it must The foregoing heating device is required to be provided in accordance with the number of the marking lines, and the space for providing the plurality of heating devices to the heating unit is limited in the size of the solar battery cells (for example, 156 mm × 156 mm). Therefore, in the prior art, it is very difficult to manufacture a solar cell module having a plurality of solar battery cells in which five or more marking lines are formed.

本發明係以上述實際情況為背景所進行者,其目的在於提供一種具有複數個形成有5條以上標記線之太陽電池組電池的太陽電池模組及其製造方法。 The present invention has been made in view of the above-described actual circumstances, and an object thereof is to provide a solar battery module having a plurality of solar battery cells in which five or more marking lines are formed, and a method of manufacturing the same.

本發明人等以上述事實情況為背景重複各種研討的結果發現,藉由使用已預先將作為金屬電極之前述標記線或該標記線及指狀電極配線在作為密封材材料之透明片材上所形成的一對配線片材,並將前述太陽電池組電池配設於該一對配線片材之間加以熱壓接,則即便未如習知進行前述焊帶接著步驟,仍可使前述太陽電池組電池與配線在前述透明片材上之前述金屬電極之間電性串聯。本發明係依據上述見解所進行。 As a result of repeating various studies based on the above facts, the present inventors have found that by using the aforementioned marking line as a metal electrode or the marking line and the finger electrode wiring on a transparent sheet as a sealing material. The pair of wiring sheets are formed, and the solar battery cells are disposed between the pair of wiring sheets to be thermocompression bonded, and the solar battery can be formed even if the welding tape subsequent step is not conventionally performed. The assembled battery and the wiring are electrically connected in series between the aforementioned metal electrodes on the transparent sheet. The present invention has been made in light of the above findings.

為了達成前述目的,本發明之太陽電池模組之主旨在於一太陽電池模組,其特徵在於:(a)在配置有金屬電極之透明片材上設置太陽電池組電池,且該太陽電池組電池與配線在前述透明片材上之前述金屬電極之間形成有觸點;(b)前述金屬電極負有標記線的功能;(c)配線在前述太陽電池組電池之表面的前述標記線之條數在5條以上。 In order to achieve the above object, the solar cell module of the present invention is mainly directed to a solar cell module, characterized in that: (a) a solar cell battery is disposed on a transparent sheet provided with a metal electrode, and the solar cell battery a contact is formed between the metal electrode on the transparent sheet and the wiring; (b) the metal electrode has a function of a mark line; and (c) a strip of the mark line on the surface of the solar cell The number is more than five.

依據本發明之太陽電池模組:(a)在配置有金屬電極之透明片材上設置太陽電池組電池,且該太陽電池組電池與配線在前述透明片材上之前述金屬電極之間形成有觸點;(b)前述金屬電極負有標記線之功能;(c)配線在前述太陽電池組電池之表面的前述標記線之條數在5條以上。因此,因為在配置有金屬電極之透明片材上設置太陽電池組電池,且該太陽電池組電池與配線在前述透明片材上之前述金屬電極之間形成觸點,所以無須如習知在將太陽電池組電池彼此串聯時使用焊帶,並且無須使用將該焊帶加熱之加熱裝置。藉此,形成在前述太陽電池組電池之標記線的條數即不受前述加熱裝置之數量限制,因此可製造具有複數個形成5條以上標記線之太陽電池組電池的太陽電池模組。 A solar cell module according to the present invention: (a) a solar cell battery is disposed on a transparent sheet on which a metal electrode is disposed, and the solar cell battery and the wiring are formed between the metal electrodes on the transparent sheet (b) the metal electrode has a function of a mark line; (c) the number of the mark lines on the surface of the solar cell battery is five or more. Therefore, since the solar cell is disposed on the transparent sheet on which the metal electrode is disposed, and the solar cell and the wiring form a contact between the metal electrodes on the transparent sheet, it is not necessary to The solar cell batteries are used in series with each other, and it is not necessary to use a heating device that heats the ribbon. Thereby, the number of the marking lines formed in the solar battery cells is not limited by the number of the heating devices, so that a solar battery module having a plurality of solar battery cells forming five or more marking lines can be manufactured.

在此,本發明宜為:(a)於前述太陽電池組電池之兩面,將配置有前述金屬電極之一對透明片材及一對透明板積層成前述金屬電極接觸前述太陽電池組電池之兩面,藉由進行按壓同時進行加熱,可獲得前述太陽電池組電池與前述金屬電極之觸點狀態;且(b)前述一對透明片材之間配置有由絕緣組成物所構成之間隔物。因此,在對由前述太陽電池組電池、前述一對透明片材及前述一對透明板所構成之積層體進行按壓同時進行加熱的情況下,可藉由前述間隔物減低加諸於前述太陽電池組電池的負荷,故而可防止前述太陽電池組電池的破裂。 Here, the present invention is preferably: (a) on both sides of the solar cell battery, one of the metal electrodes is disposed on the transparent sheet and the pair of transparent plates are laminated to form the metal electrode contacting the two sides of the solar cell battery By heating while pressing, a contact state between the solar cell and the metal electrode can be obtained; and (b) a spacer composed of an insulating composition is disposed between the pair of transparent sheets. Therefore, when the laminated body including the solar cell, the pair of transparent sheets, and the pair of transparent plates is pressed and heated, the spacer can be added to the solar cell by the spacer. The load of the battery pack prevents the rupture of the aforementioned solar battery cells.

又,本發明宜為:(a)於前述太陽電池組電池之 兩面,將配置有前述金屬電極之一對透明片材積層成前述金屬電極接觸前述太陽電池組電池之兩面,並於表面側積層透明板,於背面側積層背部片材,藉由進行按壓同時進行加熱,可獲得前述太陽電池組電池與前述金屬電極之觸點狀態;且(b)前述一對透明片材之間配置有由絕緣組成物所構成之間隔物。因此,在對由前述太陽電池組電池、前述一對透明片材、前述透明板及前述背部片材所構成之積層體進行按壓同時進行加熱的情況下,可藉由前述間隔物減低加諸於前述太陽電池組電池的負荷,故而可防止前述太陽電池組電池的破裂。 Moreover, the present invention is preferably: (a) in the aforementioned solar battery cell On both sides, one of the metal electrodes is disposed so that the transparent sheet is laminated so that the metal electrode contacts both sides of the solar cell, and a transparent plate is laminated on the surface side, and the back sheet is laminated on the back side, and the pressing is performed simultaneously. By heating, a contact state between the solar cell and the metal electrode can be obtained; and (b) a spacer composed of an insulating composition is disposed between the pair of transparent sheets. Therefore, when the laminated body including the solar cell, the pair of transparent sheets, the transparent plate, and the back sheet is pressed and heated, the spacer can be reduced by the spacer. The load of the solar cell battery described above prevents the solar cell battery from being broken.

又,前述金屬電極宜負有標記線與手指的功能,因此可適當減低前述太陽電池組電池的電阻。 Further, since the metal electrode is preferably required to have a function of a mark line and a finger, the electric resistance of the solar cell battery can be appropriately reduced.

又,前述金屬電極宜為金屬線、金屬箔、熱硬化型導電性組成物、或低融點合金,如此可將前述金屬電極適當地配線在前述透明片材上。 Further, the metal electrode is preferably a metal wire, a metal foil, a thermosetting conductive composition, or a low melting point alloy, and the metal electrode can be appropriately wired on the transparent sheet.

又,由前述金屬線或前述金屬箔所構成之前述金屬電極宜透過熱硬化型透明接著劑或含有導電性微粒子之熱硬化型透明接著劑而固定在前述透明片材,因此可將由前述金屬線或前述金屬箔所構成之前述金屬電極適當地配線在前述透明片材上。 Further, the metal electrode composed of the metal wire or the metal foil is preferably fixed to the transparent sheet by a thermosetting transparent adhesive or a thermosetting transparent adhesive containing conductive fine particles, so that the metal wire can be used. Or the metal electrode formed of the metal foil is appropriately wired on the transparent sheet.

又,由前述熱硬化型導電性組成物所構成之前述金屬電極宜藉由印刷由金屬粒子及黏結劑樹脂所構成之組成物並使其乾燥而形成,因此可將由前述熱硬化型導電性組成物所構成之前述金屬電極適當地配線在前述透明片材 上。 Further, the metal electrode composed of the thermosetting conductive composition is preferably formed by printing a composition composed of metal particles and a binder resin and drying it, so that it can be composed of the aforementioned thermosetting conductive material. The aforementioned metal electrode composed of the object is appropriately wired on the aforementioned transparent sheet on.

又,負有標記線功能的前述金屬電極宜為線寬在0.8mm以下且長寬比在1/7以上。因此,可適當減低前述標記線在前述太陽電池組電池上的陰影面積,並且可適當減低前述太陽電池組電池的電阻。 Further, the metal electrode having the function of the mark line preferably has a line width of 0.8 mm or less and an aspect ratio of 1/7 or more. Therefore, the shadow area of the aforementioned marking line on the solar cell battery can be appropriately reduced, and the electric resistance of the solar cell can be appropriately reduced.

又,負有手指功能的前述金屬電極宜為70條以上,線寬在80μm以下且長寬比在1/7以上。因此,可適當減低前述手指在前述太陽電池組電池上的陰影面積,並且可適當減低前述太陽電池組電池的電阻。 Further, the number of the metal electrodes having a finger function is preferably 70 or more, the line width is 80 μm or less, and the aspect ratio is 1/7 or more. Therefore, the shadow area of the aforementioned finger on the solar cell battery can be appropriately reduced, and the electric resistance of the solar cell can be appropriately reduced.

又,前述透明片材宜為密封材材料,即PVB或EVA,因此可適當提升前述太陽電池模組的耐久性,又,前述太陽電池組電池宜為矽晶系太陽電池組電池、異質接合型太陽電池組電池、及CIGS等之化合物系太陽電池組電池。因此,可適當地於矽晶系太陽電池組電池、異質接合型太陽電池組電池、及CIGS等之化合物系太陽電池組電池配線5條以上的標記線。 Further, the transparent sheet is preferably a sealing material, that is, PVB or EVA, so that the durability of the solar cell module can be appropriately improved, and the solar cell battery is preferably a twin solar cell battery or a heterojunction type. Solar battery cells, and compounds such as CIGS are solar battery cells. Therefore, it is possible to suitably use five or more marking lines of a silicon germanium solar cell, a heterojunction solar cell, and a compound solar cell battery wiring such as CIGS.

又,前述透明板宜為透明的玻璃或樹脂。因此,例如可將前述太陽電池模組所受之光當中,使前述間隔物所受之光的一部分反射至前述透明的玻璃或前述樹脂,並使其入射至前述太陽電池組電池。 Further, the transparent plate is preferably a transparent glass or resin. Therefore, for example, among the light received by the solar cell module, a part of the light received by the spacer may be reflected to the transparent glass or the resin, and may be incident on the solar cell.

又,宜藉由下述製造方法來製造太陽電池模組:由前述太陽電池組電池、前述透明片材、及前述透明板所構成之積層體的加熱壓接係疊合時藉由按壓、加熱而一次形成。因此,無須如習知藉由焊帶將太陽電池組電池彼此 串聯的焊帶接著步驟,並且無須使用將該焊帶加熱的加熱裝置,故而形成於前述太陽電池組電池之標記線的條數即不受前述加熱裝置之數量限制,可製造具有複數個形成有5條以上標記線之太陽電池組電池的太陽電池模組。 Moreover, it is preferable to manufacture the solar cell module by the following manufacturing method: when the heating and pressure bonding of the laminated body which consists of said solar cell, the transparent sheet, and the said transparent board is superposed, it is press|compressed and heated. And formed once. Therefore, it is not necessary to use the welding tape to connect the solar battery cells to each other. The soldering strips in series are followed by the step, and the heating device for heating the soldering strip is not required, so that the number of marking lines formed in the solar cell battery is not limited by the number of the heating devices, and can be manufactured with a plurality of formed Solar cell module for solar cell batteries with more than 5 marking lines.

10‧‧‧太陽電池模組 10‧‧‧Solar battery module

12、60‧‧‧太陽電池組電池 12, 60‧‧‧ solar battery cells

12a、60c‧‧‧表面 12a, 60c‧‧‧ surface

12b、60d‧‧‧背面 12b, 60d‧‧‧back

14、59‧‧‧金屬電極 14, 59‧‧‧ metal electrodes

14a、14a'、14a"、14a'''、42、44、48、56、62、66‧‧‧母線電極 14a, 14a', 14a", 14a''', 42, 44, 48, 56, 62, 66‧‧‧ bus electrodes

14b、52、64‧‧‧指狀電極 14b, 52, 64‧‧‧ finger electrodes

14c、42a、44a、48a、56a‧‧‧連接部 14c, 42a, 44a, 48a, 56a‧‧‧ Connections

16a、16b、40、46、50、54‧‧‧配線片材(透明片材) 16a, 16b, 40, 46, 50, 54‧‧‧ wiring sheets (transparent sheets)

18、20‧‧‧玻璃 18, 20‧‧‧ glass

22、68‧‧‧間隔物 22, 68‧‧‧ spacers

22a‧‧‧縱框部 22a‧‧‧ vertical frame

22b‧‧‧橫框部 22b‧‧‧ transverse frame

24、70‧‧‧組電池收納空間 24, 70‧‧‧ battery storage space

26、72‧‧‧插入空間 26, 72‧‧‧ Insert space

28‧‧‧n型晶系矽基板 28‧‧‧n type crystal system substrate

28a、28b‧‧‧n型晶系矽基板28之兩面 28a, 28b‧‧‧n-type crystal system 两 substrate 28 on both sides

30‧‧‧薄膜非晶矽層 30‧‧‧ Film amorphous layer

32‧‧‧透明電極 32‧‧‧Transparent electrode

36‧‧‧積層體 36‧‧‧Layered body

58‧‧‧抗反射膜 58‧‧‧Anti-reflective film

60a‧‧‧n型半導體 60a‧‧n semiconductor

60b‧‧‧p型半導體 60b‧‧‧p-type semiconductor

A‧‧‧尺寸 A‧‧‧ size

B、C‧‧‧等間隔 B, C‧‧‧ equal intervals

D‧‧‧間隔物厚度 D‧‧‧ spacer thickness

E‧‧‧寬度 E‧‧‧Width

P1~P21‧‧‧步驟 P1~P21‧‧‧ steps

X、X'‧‧‧線寬 X, X'‧‧‧ line width

Y、Y'‧‧‧高度 Y, Y'‧‧‧ height

II、XI、XII‧‧‧截面線 II, XI, XII‧‧‧ section line

圖1係顯示本發明經適當應用之太陽電池模組之圖。 BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a view showing a properly applied solar cell module of the present invention.

圖2係圖1之II-II視截面圖。 Figure 2 is a cross-sectional view taken along line II-II of Figure 1.

圖3係顯示圖1之設於太陽電池模組之母線電極的截面形狀之截面圖。 3 is a cross-sectional view showing the cross-sectional shape of the bus bar electrode of the solar cell module of FIG. 1.

圖4係顯示圖1之設於太陽電池模組之指狀電極的截面形狀之截面圖。 4 is a cross-sectional view showing the cross-sectional shape of the finger electrode of the solar cell module of FIG. 1.

圖5係說明圖1之太陽電池模組之製造方法的步驟圖。 Fig. 5 is a view showing the steps of a method of manufacturing the solar cell module of Fig. 1.

圖6係說明圖5之製造方法中之太陽電池組電池形成步驟之圖。 Fig. 6 is a view for explaining a solar cell battery forming step in the manufacturing method of Fig. 5.

圖7係說明圖5之製造方法中之配線片材製造步驟之圖,該圖顯示圖1之設於太陽電池模組而配設在太陽電池組電池之表面側的配線片材。 Fig. 7 is a view for explaining a manufacturing process of the wiring sheet in the manufacturing method of Fig. 5, which shows a wiring sheet which is disposed on the surface side of the solar battery cell of Fig. 1 in the solar battery module.

圖8係說明圖5之製造方法中之配線片材製造步驟之圖,該圖顯示圖1之設於太陽電池模組而配設在太陽電池組電池之背面側的配線片材。 Fig. 8 is a view for explaining a manufacturing process of the wiring sheet in the manufacturing method of Fig. 5, which shows a wiring sheet which is disposed on the back side of the solar battery cell of Fig. 1 in the solar battery module.

圖9係說明圖5之製造方法中之配線片材製造步驟之圖,該圖顯示圖8之配線片材設有間隔物之狀態。 Fig. 9 is a view for explaining a manufacturing step of the wiring sheet in the manufacturing method of Fig. 5, which shows a state in which the wiring sheet of Fig. 8 is provided with a spacer.

圖10係說明圖5之製造方法中之積層步驟之圖,該圖顯 示圖9之配線片材積層太陽電池組電池而成之積層體。 Figure 10 is a view showing a step of laminating in the manufacturing method of Figure 5, which shows Fig. 9 is a laminate of a wiring sheet laminated solar battery cell.

圖11係說明圖5之製造方法中之積層步驟之圖10的XI-XI視截面圖,該圖顯示圖10之積層體積層有圖7之配線片材之狀態。 Figure 11 is a cross-sectional view taken along line XI-XI of Figure 10 illustrating the lamination step in the manufacturing method of Figure 5, showing the state in which the build-up volume layer of Figure 10 has the wiring sheet of Figure 7.

圖12係說明圖5之製造方法中之積層步驟之圖10的XII-XII視截面圖,該圖顯示圖10之積層體積層有圖7之配線片材之狀態。 Fig. 12 is a cross-sectional view taken along the line XII-XII of Fig. 10 showing the lamination step in the manufacturing method of Fig. 5, showing the state in which the build-up volume layer of Fig. 10 has the wiring sheet of Fig. 7.

圖13係顯示形成於太陽電池組電池之母線電極之條數與該太陽電池組電池之轉換效率等之關係圖。 Fig. 13 is a graph showing the relationship between the number of bus bar electrodes formed in a solar cell battery and the conversion efficiency of the solar cell.

圖14係顯示形成於太陽電池組電池之母線電極之條數與該太陽電池組電池之轉換效率等之關係圖,該圖顯示在指狀電極之寬20μm且其條數相同之太陽電池組電池下,母線電極從3條變成5條時轉換效率之上升幅度。 Figure 14 is a graph showing the relationship between the number of bus bar electrodes formed in a solar cell battery and the conversion efficiency of the solar cell, etc., which shows a solar cell battery having a width of 20 μm and the same number of fingers. Next, the increase in conversion efficiency when the bus electrode is changed from 3 to 5.

圖15係顯示形成於太陽電池組電池之母線電極之條數與該太陽電池組電池之轉換效率等之關係圖,該圖顯示在指狀電極之寬40μm且其條數相同之太陽電池組電池下,母線電極從3條變成5條時轉換效率之上升幅度。 Figure 15 is a graph showing the relationship between the number of bus bar electrodes formed in a solar cell battery and the conversion efficiency of the solar cell, etc., which shows a solar cell battery having a width of 40 μm and the same number of fingers. Next, the increase in conversion efficiency when the bus electrode is changed from 3 to 5.

圖16係顯示形成於太陽電池組電池之母線電極之條數與該太陽電池組電池之轉換效率等之關係圖,該圖顯示在指狀電極之寬60μm且其條數相同之太陽電池組電池下,母線電極從3條變成5條時轉換效率之上升幅度。 Figure 16 is a graph showing the relationship between the number of bus bar electrodes formed in a solar cell battery and the conversion efficiency of the solar cell, etc., which shows a solar cell battery having a width of 60 μm and the same number of fingers. Next, the increase in conversion efficiency when the bus electrode is changed from 3 to 5.

圖17係顯示形成於太陽電池組電池之母線電極之條數與該太陽電池組電池之轉換效率等之關係圖,該圖顯示在指狀電極之寬80μm且其條數相同之太陽電池組電池下,母 線電極從3條變成5條時轉換效率之上升幅度。 Figure 17 is a graph showing the relationship between the number of bus bar electrodes formed in a solar cell battery and the conversion efficiency of the solar cell, etc., which shows a solar cell battery having a width of 80 μm and the same number of fingers. Next, mother The increase in conversion efficiency when the line electrode is changed from 3 to 5.

圖18係顯示形成於太陽電池組電池之母線電極之條數與該太陽電池組電池之轉換效率等之關係圖,該圖顯示在指狀電極之寬100μm且其條數相同之太陽電池組電池下,母線電極從3條變成5條時轉換效率之上升幅度。 Figure 18 is a graph showing the relationship between the number of bus bar electrodes formed in a solar cell battery and the conversion efficiency of the solar cell, etc., which shows a solar cell battery having a width of 100 μm and the same number of fingers. Next, the increase in conversion efficiency when the bus electrode is changed from 3 to 5.

圖19係顯示本發明其他實施例之太陽電池模組之圖,即顯示設於該太陽電池模組之母線電極的截面形狀之截面圖。 Fig. 19 is a view showing a solar battery module according to another embodiment of the present invention, which is a cross-sectional view showing a sectional shape of a bus bar electrode provided in the solar battery module.

圖20係顯示本發明其他實施例之太陽電池模組之圖,即顯示設於該太陽電池模組之母線電極的截面形狀之截面圖。 Fig. 20 is a view showing a solar battery module according to another embodiment of the present invention, which is a cross-sectional view showing a sectional shape of a bus bar electrode provided in the solar battery module.

圖21係顯示本發明其他實施例之太陽電池模組之圖,即顯示設於該太陽電池模組之母線電極的截面形狀之截面圖。 Fig. 21 is a view showing a solar battery module according to another embodiment of the present invention, which is a cross-sectional view showing a sectional shape of a bus bar electrode provided in the solar battery module.

圖22係顯示本發明其他實施例之太陽電池模組之圖,該圖顯示設於該太陽電池模組而配設在太陽電池組電池之背面側的配線片材。 Fig. 22 is a view showing a solar battery module according to another embodiment of the present invention, which shows a wiring sheet disposed on the back side of the solar battery unit in the solar battery module.

圖23係顯示本發明其他實施例之太陽電池模組之圖,該圖顯示設於該太陽電池模組而配設在太陽電池組電池之表面側的配線片材。 Fig. 23 is a view showing a solar battery module according to another embodiment of the present invention, which shows a wiring sheet disposed on the surface side of the solar battery cell provided in the solar battery module.

圖24係顯示圖23之設於太陽電池模組而配設在太陽電池組電池之背面側的配線片材之圖。 Fig. 24 is a view showing a wiring sheet which is disposed on the back side of the solar battery unit in Fig. 23, which is provided in the solar battery module.

圖25係顯示本發明其他實施例之太陽電池模組之圖,該圖顯示設於該太陽電池模組而配設在太陽電池組電池之 表面側的配線片材。 Figure 25 is a view showing a solar battery module according to another embodiment of the present invention, which is shown in the solar battery module and is disposed in a solar battery unit. Wiring sheet on the surface side.

圖26係顯示圖25之設於太陽電池模組之太陽電池組電池之圖。 Fig. 26 is a view showing the solar battery unit of Fig. 25 provided in the solar battery module.

圖27係說明圖25之太陽電池模組之製造方法的步驟圖。 Fig. 27 is a view showing the steps of a method of manufacturing the solar battery module of Fig. 25.

圖28係顯示本發明其他實施例之太陽電池模組之圖,該圖顯示設於該太陽電池模組之太陽電池組電池。 Figure 28 is a view showing a solar battery module according to another embodiment of the present invention, which shows a solar battery unit provided in the solar battery module.

圖29係說明圖28之太陽電池模組之製造方法的步驟圖。 Fig. 29 is a view showing the steps of a method of manufacturing the solar battery module of Fig. 28.

圖30係顯示本發明其他實施例之太陽電池模組之圖,該圖顯示設於該太陽電池模組之間隔物。 Figure 30 is a view showing a solar battery module according to another embodiment of the present invention, which shows a spacer provided in the solar battery module.

用以實施發明之形態 Form for implementing the invention

以下參照圖式詳細說明本發明之一實施例。而,在以下實施例中,圖已經過適宜簡略化或變形,各部分之尺寸比及形狀等未必有經正確描繪。 An embodiment of the present invention will be described in detail below with reference to the drawings. However, in the following embodiments, the drawings have been appropriately simplified or deformed, and the dimensional ratios, shapes, and the like of the respective portions are not necessarily correctly depicted.

實施例1 Example 1

圖1係顯示本發明經適當應用的太陽電池模組10之圖。如圖1顯示,太陽電池模組10係形成為長條平板狀,並藉由該太陽電池模組10之一面或兩面受光而使設於該太陽電池模組10內之複數個(本實施例中為6個)太陽電池組電池12發電者。而,太陽電池組電池12係例如將晶矽及非晶矽積層的混成型(HIT型)太陽電池組電池,並藉由太陽電池組電池12之兩面12a及12b之至少一方受光而發電之兩面受 光型太陽電池組電池。 Fig. 1 is a view showing a solar cell module 10 to which the present invention is suitably applied. As shown in FIG. 1 , the solar cell module 10 is formed in a long flat shape and is received by the solar cell module 10 by receiving light on one or both sides of the solar cell module 10 (this embodiment). In the middle of the 6) solar cell battery 12 generator. On the other hand, the solar battery cell 12 is, for example, a hybrid battery (HIT type) solar battery cell in which a wafer and an amorphous germanium layer are combined, and two sides of the solar cell 12 are exposed to light by at least one of the two surfaces 12a and 12b. Subject to Light type solar battery.

如圖1顯示,複數個太陽電池組電池12分別為正方形,該太陽電池組電池12之尺寸即尺寸A係例如156mm,且在該太陽電池組電池12之兩面12a及12b之電極連接有例如5條母線電極14a,該母線電極14a係延伸於太陽電池模組10之長邊方向且負有標記線的功能。而,上述標記線係將以太陽電池組電池12所發電之電適當彙集之金屬線。 As shown in FIG. 1, a plurality of solar battery cells 12 are respectively square, and the size of the solar battery cells 12, that is, the size A is, for example, 156 mm, and electrodes of the two faces 12a and 12b of the solar battery cell 12 are connected with, for example, 5 The bus bar electrode 14a has a function of extending in the longitudinal direction of the solar cell module 10 and having a mark line. On the other hand, the marking line is a metal wire which is appropriately collected by the electricity generated by the solar battery cell 12.

如圖1顯示,連接在太陽電池組電池12之5條母線電極14a係在太陽電池模組10之相對於長邊方向的垂直方向分別以等間隔B例如30.6mm配置。又如圖2顯示,在太陽電池模組10之長邊方向鄰接之太陽電池組電池12之間,一太陽電池組電池12之表面12a與另一太陽電池組電池12之背面12b係藉由母線電極14a而電連接,即複數個太陽電池組電池12係藉由母線電極14a而串聯。 As shown in Fig. 1, the five bus bar electrodes 14a connected to the solar battery cells 12 are arranged at equal intervals B, for example, 30.6 mm, in the vertical direction of the solar cell module 10 with respect to the longitudinal direction. As shown in FIG. 2, between the solar cell 12 adjacent to the long side of the solar cell module 10, the surface 12a of one solar cell 12 and the back 12b of another solar cell 12 are supported by a bus bar. The electrodes 14a are electrically connected, that is, a plurality of solar battery cells 12 are connected in series by the bus bar electrodes 14a.

母線電極14a係如圖3顯示,該母線電極14a之截面為矩形,且在該母線電極14a之截面,線寬X與高度Y之長寬比Y/X為例如1/2(線寬X為0.8mm且高度Y為0.4mm時),在本實施例中係以長寬比Y/X在1/7以上且理想在1/7以上~7/4以下之範圍內來設計母線電極14a之截面。 The bus bar electrode 14a is shown in FIG. 3. The bus bar electrode 14a has a rectangular cross section, and the aspect ratio Y/X of the line width X and the height Y is, for example, 1/2 (the line width X is the cross section of the bus bar electrode 14a). In the present embodiment, the bus bar electrode 14a is designed to have an aspect ratio Y/X of 1/7 or more and preferably 1/7 or more to 7/4 or less. section.

如圖1顯示,於太陽電池組電池12之兩面12a及12b之電極連接有例如90條指狀電極14b,該指狀電極14b係相對於母線電極14a呈正交且負有手指的功能。而,上述手指係將以太陽電池組電池12所發電之電送至母線電極14a的金屬線。又,在本實施例中為了可較輕易地理解本實施 例,係以異於實際物品的方式來圖示連接在太陽電池組電池12之指狀電極14b的條數及其大小。 As shown in Fig. 1, for example, 90 finger electrodes 14b are connected to the electrodes of both faces 12a and 12b of the solar cell 12, and the finger electrodes 14b are orthogonal to the bus bar electrodes 14a and have a function of a finger. On the other hand, the above-mentioned finger system supplies electric power generated by the solar battery cell 12 to the metal wire of the bus bar electrode 14a. Also, in the present embodiment, the present embodiment can be understood relatively easily. For example, the number of the finger electrodes 14b connected to the solar battery cell 12 and the size thereof are illustrated in a manner different from the actual article.

如圖1顯示,連接在太陽電池組電池12之90條指狀電極14b係在太陽電池模組10之長邊方向分別以等間隔C例如1.64mm配置。又,指狀電極4b係如圖4顯示,該指狀電極14b之截面為矩形,且在該指狀電極14b之截面,線寬X'與高度Y'之長寬比Y'/X'為例如1/2(線寬X'為40μm且高度Y'為20μm時),在本實施例中係以長寬比Y'/X'在1/7以上且理想在1/7以上~7/4以下之範圍內來設計指狀電極14b之截面。 As shown in FIG. 1, the 90 finger electrodes 14b connected to the solar battery cell 12 are disposed at equal intervals C, for example, 1.64 mm, in the longitudinal direction of the solar cell module 10. Further, the finger electrode 4b is as shown in FIG. 4, the finger electrode 14b has a rectangular cross section, and the aspect ratio Y'/X' of the line width X' and the height Y' is a section of the finger electrode 14b. For example, 1/2 (when the line width X' is 40 μm and the height Y' is 20 μm), in the present embodiment, the aspect ratio Y'/X' is 1/7 or more and desirably 1/7 or more and ~7/ The cross section of the finger electrode 14b is designed within the range of 4 or less.

如圖2顯示,複數個太陽電池組電池12例如係以疊合機將分別配設在該等複數個太陽電池組電池12之兩面12a及12b的一對配線片材(透明片材)16a、16b熱壓接而被密封在配線片材16a、16b內,且一對配線片材16a、16b上分別設有透明的玻璃18、20,前述一對配線片材16a、16b係由例如EVA(乙烯乙酸乙烯共聚樹脂)、PVB(聚乙烯醇縮丁醛)等之密封材材料所構成。而,一對配線片材16a、16b上預先配線有上述母線電極14a及指狀電極14b等之金屬電極14。 As shown in FIG. 2, a plurality of solar battery cells 12 are respectively disposed, for example, by a laminating machine, a pair of wiring sheets (transparent sheets) 16a disposed on both sides 12a and 12b of the plurality of solar battery cells 12, 16b is thermocompression-bonded and sealed in the wiring sheets 16a and 16b, and the pair of wiring sheets 16a and 16b are respectively provided with transparent glass 18 and 20, and the pair of wiring sheets 16a and 16b are made of, for example, EVA ( A sealing material such as ethylene vinyl acetate copolymer resin or PVB (polyvinyl butyral). On the pair of wiring sheets 16a and 16b, the metal electrodes 14 such as the bus bar electrodes 14a and the finger electrodes 14b are preliminarily wired.

如圖2顯示,經熱壓接之配線片材16a、16內即一對配線片材16a、16之間設有一對長條狀的間隔物22,且該一對間隔物22係由絕緣組成物例如陶瓷或陶瓷與樹脂之混合物等所構成。長條狀的間隔物22如圖1顯示係由一對延伸於太陽電池模組10之長邊方向的縱框部22a及複數條(本實 施例中為7條)的橫框部22b所構成,該複數條的橫框部22b係相對於其縱框部22a延伸於垂直方向且以兩端部分別連結一對縱框部22a。又,於長條狀的間隔物22設有組電池收納空間24及插入空間26,組電池收納空間24係收納被一對縱框部22a及複數橫框部22b包圍之複數個(本實施例中為3個)太陽電池組電池12,而插入空間26係用以插入被一對縱框部22a及複數橫框部22b包圍之母線電極14a。又,在組電池收納空間24中,一對縱框部22a間的間隔及在太陽電池模組10之長邊方向鄰接之橫框部22b間的間隔與太陽電池組電池12之尺寸A相同,或比該太陽電池組電池12之尺寸A略大。又,如圖2顯示,間隔物22的厚度D與太陽電池組電池12之厚度相同,或比該太陽電池組電池12之厚度更厚。 As shown in Fig. 2, a pair of elongated spacers 22 are provided in the thermocompression bonded wiring sheets 16a, 16 between the pair of wiring sheets 16a, 16, and the pair of spacers 22 are composed of insulation. The material is composed of, for example, ceramic or a mixture of ceramic and resin. The strip-shaped spacer 22 is shown in FIG. 1 by a pair of vertical frame portions 22a extending in the longitudinal direction of the solar cell module 10, and a plurality of In the embodiment, the horizontal frame portion 22b of the seven pieces is formed, and the plurality of horizontal frame portions 22b extend in the vertical direction with respect to the vertical frame portion 22a, and the pair of vertical frame portions 22a are connected to the both end portions. Moreover, the assembled battery storage space 24 and the insertion space 26 are provided in the elongated spacer 22, and the assembled battery storage space 24 accommodates a plurality of the plurality of vertical frame portions 22a and the plurality of horizontal frame portions 22b (this embodiment) The middle is three solar battery cells 12, and the insertion space 26 is for inserting the bus electrode 14a surrounded by the pair of vertical frame portions 22a and the plurality of horizontal frame portions 22b. Further, in the assembled battery storage space 24, the interval between the pair of vertical frame portions 22a and the interval between the horizontal frame portions 22b adjacent to the longitudinal direction of the solar cell module 10 are the same as the size A of the solar battery cells 12. Or slightly larger than the size A of the solar battery cell 12. Further, as shown in FIG. 2, the thickness D of the spacer 22 is the same as or thicker than the thickness of the solar cell 12 .

以下,以圖5至圖12來說明具有複數個形成有5條母線電極14a之太陽電池組電池12的太陽電池模組10之製造方法。如圖6顯示,首先在圖5之太陽電池組電池形成步驟P1中,將由i型非晶矽層及p型非晶矽層所構成之薄膜非晶矽層30積層於由單晶矽、多晶矽等晶系半導體所構成之n型晶系矽基板28之兩面28a及28b成一體,並將由ITO(氧化銦錫)所構成之透明電極32積層於該等薄膜非晶矽層30成一體。藉此可形成太陽電池組電池12。 Hereinafter, a method of manufacturing the solar battery module 10 having a plurality of solar battery cells 12 in which five bus bar electrodes 14a are formed will be described with reference to FIGS. 5 to 12. As shown in FIG. 6, first, in the solar cell formation step P1 of FIG. 5, a thin film amorphous germanium layer 30 composed of an i-type amorphous germanium layer and a p-type amorphous germanium layer is laminated on a single crystal germanium or polycrystalline germanium. The both surfaces 28a and 28b of the n-type germanium substrate 28 composed of an isotactic semiconductor are integrated, and a transparent electrode 32 made of ITO (indium tin oxide) is laminated on the thin film amorphous layer 30. Thereby, the solar cell battery 12 can be formed.

接下來,在圖5之配線片材製造步驟P2中,如圖7顯示於長條平板狀之例如由EVA所構成之樹脂片材配線母線電極14a及指狀電極14b等之金屬電極14,以製造配線片材16a,並如圖8顯示於長條平板狀之由EVA所構成之樹脂 片材配線母線電極14a及指狀電極14b等之金屬電極14,以製造配線片材16b。於母線電極14a形成有連接部14c成一體,且該連接部14c係相對於配線片材16a、16b之長邊方向延伸於垂直方向。而,圖5中,太陽電池組電池形成步驟P1的下一步驟係進行配線片材製造步驟P2,亦可例如於配線片材製造步驟P2的下一步驟進行太陽電池組電池形成步驟P1。 Next, in the wiring sheet manufacturing step P2 of FIG. 5, as shown in FIG. 7, the metal electrode 14 such as the resin sheet wiring bus bar electrode 14a and the finger electrode 14b which are formed of, for example, EVA, is formed in a long flat shape. The wiring sheet 16a is manufactured, and as shown in FIG. 8, a resin composed of EVA is formed in a long flat plate shape. The metal wiring 14 such as the sheet wiring bus bar electrode 14a and the finger electrode 14b is manufactured to manufacture the wiring sheet 16b. The connection portion 14c is formed integrally with the bus bar electrode 14a, and the connection portion 14c extends in the vertical direction with respect to the longitudinal direction of the wiring sheets 16a and 16b. In FIG. 5, the next step of the solar battery cell forming step P1 is to perform the wiring sheet manufacturing step P2, and the solar battery cell forming step P1 may be performed, for example, in the next step of the wiring sheet manufacturing step P2.

而,在配線片材製造步驟P2中係透過熱硬化型透明接著劑或含有導電性微粒子之熱硬化型透明接著劑將金屬線或金屬箔固定在配線片材16a、16b,或將由金屬粒子(例如Cu、Ag、Ni、Al等)及黏結劑樹脂(熱硬化樹脂)所構成之熱硬化型導電性組成物印刷至配線片材16a、16b並使其乾燥,藉此將金屬電極14配線於配線片材16a、16b。又,亦可使用例如無鉛焊合金等低融點合金來替代上述金屬線或金屬箔。而,上述無鉛焊合金係例如含有基底合金及鎵之無鉛焊合金,前述基底合金具有奈米複合材結構且含有錫、鉍。又,相對於前述無鉛焊合金總量,前述鎵之含量在0.001~3重量%之範圍。 In the wiring sheet manufacturing step P2, the metal wire or the metal foil is fixed to the wiring sheets 16a, 16b or the metal particles by a thermosetting transparent adhesive or a thermosetting transparent adhesive containing conductive fine particles. For example, Cu, Ag, Ni, Al, and the like, and a thermosetting conductive composition composed of a binder resin (thermosetting resin) are printed on the wiring sheets 16a and 16b and dried, whereby the metal electrode 14 is wired. Wiring sheets 16a, 16b. Further, a low melting point alloy such as a lead-free solder alloy may be used instead of the above metal wire or metal foil. Further, the lead-free solder alloy includes, for example, a base alloy and a lead-free solder alloy of gallium, and the base alloy has a nano-composite structure and contains tin and antimony. Further, the content of the gallium is in the range of 0.001 to 3% by weight based on the total amount of the lead-free solder alloy.

又,在配線片材製造步驟P2中,例如係將陶瓷、或樹脂與陶瓷之混合物等的絕緣組成物藉由印刷或擠壓成形等而形成硬化來製造一對間隔物22,並如圖9顯示例如藉由接著劑而將一對間隔物22固定在配線片材16b上成一體,即固定在配線於配線片材16b之母線電極14a、指狀電極14b上成一體。又,在配線片材製造步驟P2中,係將長條 平板狀的透明的玻璃18、20或長條平板狀的透明的樹脂藉由例如接著劑而固定在配線片材16a、16b成一體。而,一對間隔物22未必得固定在配線片材16b成一體,亦可如後述之積層步驟P3中將一對間隔物22積層於配線片材16b。又,玻璃18、20未必得固定在配線片材16a、16b成一體,亦可如後述之積層步驟P3中將玻璃18、20積層於配線片材16a、16b。 Further, in the wiring sheet manufacturing step P2, for example, a pair of spacers 22 are produced by hardening an insulating composition such as ceramic or a mixture of a resin and a ceramic by printing or extrusion molding, and as shown in FIG. For example, the pair of spacers 22 are fixed to the wiring sheet 16b by an adhesive, that is, integrally fixed to the bus bar electrode 14a and the finger electrode 14b of the wiring sheet 16b. Moreover, in the wiring sheet manufacturing step P2, the strip is stripped The flat transparent glass 18, 20 or the long flat transparent resin is fixed to the wiring sheets 16a and 16b by, for example, an adhesive. Further, the pair of spacers 22 are not necessarily fixed to the wiring sheet 16b, and a pair of spacers 22 may be laminated on the wiring sheet 16b in the laminating step P3 to be described later. Further, the glass sheets 18 and 20 are not necessarily fixed to the wiring sheets 16a and 16b, and the glass sheets 18 and 20 may be laminated on the wiring sheets 16a and 16b in the laminating step P3 to be described later.

接下來,在圖5之積層步驟P3中如圖10顯示,將太陽電池組電池12積層至配線片材製造步驟P2中所製造之固定有玻璃20及一對間隔物22成一體的配線片材16b,並使太陽電池組電池12收納於間隔物22之組電池收納空間24內;如圖11及圖12顯示,將配線片材製造步驟P2中所製造之固定有玻璃18成一體的配線片材16a積層於複數個太陽電池組電池12之表面12a。即,在積層步驟P3中,將配置有母線電極14a及指狀電極14b等之金屬電極14的一對配線片材16a、16b以及一對玻璃18、20積層於太陽電池組電池12之兩面12a及12b,以使母線電極14a及指狀電極14b等之金屬電極14接觸太陽電池組電池12之兩面12a及12b。 Next, in the laminating step P3 of FIG. 5, as shown in FIG. 10, the solar cell battery 12 is laminated to the wiring sheet in which the glass 20 and the pair of spacers 22 are integrally formed and manufactured in the wiring sheet manufacturing step P2. 16b, and the solar battery cell 12 is housed in the assembled battery storage space 24 of the spacer 22; as shown in FIG. 11 and FIG. 12, the wiring piece in which the glass 18 is integrally formed in the wiring sheet manufacturing step P2 is integrated The material 16a is laminated on the surface 12a of the plurality of solar battery cells 12. In the laminating step P3, the pair of wiring sheets 16a and 16b and the pair of glasses 18 and 20 on which the metal electrodes 14 such as the bus bar electrodes 14a and the finger electrodes 14b are disposed are laminated on both sides 12a of the solar battery cells 12. And 12b, the metal electrode 14 such as the bus bar electrode 14a and the finger electrode 14b is brought into contact with both faces 12a and 12b of the solar cell stack 12.

接著如圖11及圖12顯示,在圖5之疊合(熱壓接)步驟P4中,將藉由積層步驟P3而積層有太陽電池組電池12、一對配線片材16a、16b、玻璃18、20及間隔物22之積層體36,例如以真空疊合機在真空中例如在130℃~150℃之範圍下進行加熱同時進行按壓,藉此以配線片材16a、16b來壓接密封複數個太陽電池組電池12。而,在疊合步驟P4 中一如圖12顯示以真空疊合機將複數個太陽電池組電池12以一對配線片材16a、16b壓接密封,配線在該等配線片材16a、16b之母線電極14a及指狀電極14b即可固定在太陽電池組電池12之兩面12a及12b成一體,且如圖12之點虛線的圓內所示,在鄰接之太陽電池組電池12中,固定在一太陽電池組電池12之背面12b的母線電極14a之連接部14c與固定在另一太陽電池組電池12之表面12a的母線電極14a之連接部14c便可連接、亦即接觸。藉此,可製造具有複數個形成有5條母線電極14a之太陽電池組電池12的太陽電池模組10。 Next, as shown in FIG. 11 and FIG. 12, in the superimposing (thermo-compression bonding) step P4 of FIG. 5, the solar cell 12, the pair of wiring sheets 16a, 16b, and the glass 18 are laminated by the laminating step P3. The laminated body 36 of the 20 and the spacer 22 is pressed while being heated in a vacuum, for example, at a temperature ranging from 130 ° C to 150 ° C in a vacuum laminator, whereby the wiring sheets 16a and 16b are crimped to seal the plural Solar battery cells 12. And, in the stacking step P4 As shown in FIG. 12, a plurality of solar battery cells 12 are pressure-sealed by a vacuum laminating machine with a pair of wiring sheets 16a, 16b, and bus bar electrodes 14a and finger electrodes wired to the wiring sheets 16a, 16b. 14b can be fixed to the two sides 12a and 12b of the solar cell 12, and is fixed to a solar cell 12 in the adjacent solar cell 12 as shown in the dotted circle of FIG. The connection portion 14c of the bus bar electrode 14a of the back surface 12b and the connection portion 14c of the bus bar electrode 14a fixed to the surface 12a of the other solar cell 12 can be connected, that is, contacted. Thereby, the solar cell module 10 having a plurality of solar battery cells 12 in which five bus bar electrodes 14a are formed can be manufactured.

而,在習知之太陽電池模組10之製造方法中,為了在鄰接之太陽電池組電池12彼此將例如形成在一太陽電池組電池12之母線電極14a與形成在另一太陽電池組電池12之母線電極14b串聯,係將經焊塗佈之帶狀金屬箔之焊帶載置於與其同寬尺寸的母線電極14a上,並藉由加熱單元將該焊帶加熱而連接於母線電極14a上。然而,若於母線電極14a上載置上述焊帶,可能會因位置偏移使焊帶從母線電極14a突出,而該焊帶從母線電極14a突出的部分導致太陽電池組電池12的受光面積減少,使太陽電池組電池12即太陽電池模組10之轉換效率(%)降低。此外,若在複數條的母線電極14a同時載置複數焊帶時產生位置偏移,母線電極14a之條數愈多,愈會因該等焊帶而使太陽電池組電池12之受光面積減少。即,例如於形成有2條母線電極14a的太陽電池組電池12中載置焊帶時,若在母線電極14a的寬度方向產 生0.1mm的偏移,在焊帶合計會突出0.2mm;於形成有4條母線電極14a的太陽電池組電池12中載置焊帶時,若在母線電極14a的寬度方向產生0.1mm的偏移,在焊帶合計會產生0.4mm的突出;因此,母線電極14a之條數愈多,愈會因該等焊帶而使太陽電池組電池12之受光面積減少。依據本實施例之太陽電池模組10之製造方法,係將太陽電池組電池12設置於配線有母線電極14a之一對配線片材16a、16b上,而在太陽電池組電池12與配線在配線片材16a、16b上之母線電極14a之間形成觸點,因此無須如習知在將太陽電池組電池12彼此串聯時使用焊帶,同時無須將該焊帶載置於母線電極14a。藉此即不會如習知因焊帶而使太陽電池組電池12之受光面積減少,可適當提升太陽電池模組10的轉換效率(%)。 However, in the manufacturing method of the conventional solar battery module 10, in order to form, for example, the adjacent solar battery cells 12 are formed between the bus electrode 14a of the solar battery cell 12 and the other solar battery cell 12, for example. The bus bar electrodes 14b are connected in series, and the solder ribbon of the strip-shaped metal foil to be solder-coated is placed on the bus bar electrode 14a of the same width, and the solder ribbon is heated by the heating unit to be connected to the bus bar electrode 14a. However, if the solder ribbon is placed on the bus bar electrode 14a, the solder ribbon may protrude from the bus bar electrode 14a due to the positional deviation, and the portion of the solder ribbon protruding from the bus bar electrode 14a causes the light receiving area of the solar cell stack 12 to decrease. The conversion efficiency (%) of the solar battery cell 12, that is, the solar battery module 10 is lowered. Further, when a plurality of soldering strips are simultaneously placed on the plurality of bus bar electrodes 14a, the positional shift occurs, and the more the number of the bus bar electrodes 14a, the more the light receiving area of the solar cell stack 12 is reduced by the soldering strips. In other words, for example, when the solder ribbon is placed on the solar battery cell 12 in which the two bus bar electrodes 14a are formed, the width of the bus bar electrode 14a is produced. When the offset of 0.1 mm is generated, the total amount of the soldering tape is 0.2 mm. When the soldering tape is placed on the solar battery cell 12 in which the four bus bar electrodes 14a are formed, a bias of 0.1 mm is generated in the width direction of the bus bar electrode 14a. When the welding is performed, a total of 0.4 mm of protrusion is generated; therefore, the more the number of the bus electrodes 14a is, the more the light receiving area of the solar battery unit 12 is reduced by the welding bands. According to the manufacturing method of the solar cell module 10 of the present embodiment, the solar cell 12 is disposed on one of the wiring bus electrodes 14a on the wiring sheets 16a and 16b, and the solar cell 12 and the wiring are in the wiring. The contacts are formed between the bus bar electrodes 14a on the sheets 16a, 16b, so that it is not necessary to use the solder ribbon as in the case where the solar cell batteries 12 are connected in series with each other, and it is not necessary to mount the solder ribbon on the bus bar electrodes 14a. Thereby, the light-receiving area of the solar battery cell 12 is not reduced as is conventionally known, and the conversion efficiency (%) of the solar battery module 10 can be appropriately increased.

在此,以圖13至圖18來說明形成於太陽電池組電池12之母線電極14a之條數與該太陽電池12組電池之轉換效率(%)等之關係。而,圖13至圖18係假設將母線電極14a之條數變更為3條、5條、7條、15條、20條且將該母線電極14a之寬度變更為1.4mm、0.8mm、0.57mm、0.27mm、0.2mm,將指狀電極14b之條數變更為70條、74條、90條且將該指狀電極14b之寬度變更為100μm、80μm、60μm、40μm、20μm,而製作出35種類的太陽電池組電池12,並且該35種類之太陽電池組電池12的轉換效率(%)等之測定結果係以模擬的方式算出。 Here, the relationship between the number of bus bar electrodes 14a formed in the solar cell stack 12 and the conversion efficiency (%) of the solar cell 12 cells will be described with reference to FIGS. 13 to 18. 13 to 18, it is assumed that the number of bus bar electrodes 14a is changed to three, five, seven, fifteen, and twenty, and the width of the bus bar electrode 14a is changed to 1.4 mm, 0.8 mm, and 0.57 mm. In the case of 0.27 mm and 0.2 mm, the number of the finger electrodes 14b is changed to 70, 74, and 90, and the width of the finger electrodes 14b is changed to 100 μm, 80 μm, 60 μm, 40 μm, and 20 μm to produce 35. The solar cell battery 12 of the type and the measurement results of the conversion efficiency (%) of the 35 types of solar cell 12 are calculated by simulation.

而,在圖13中,係以形成有3條寬1.4mm的母線 電極14及74條寬80μm的指狀電極14之太陽電池組電池12作為比較例物品1之太陽電池組電池12,以形成有3條寬1.4mm的母線電極14a及90條寬40μm的指狀電極14b之太陽電池組電池12作為比較例物品2之太陽電池組電池12,以形成有5條寬0.8mm的母線電極14a及90條寬40μm的指狀電極14b之太陽電池組電池12作為實施例物品1之太陽電池組電池12,以形成有7條寬0.57mm的母線電極14a及90條寬40μm的指狀電極14b之太陽電池組電池12作為實施例物品2之太陽電池組電池12,以形成有15條寬0.27mm的母線電極14a及90條寬40μm的指狀電極14b之太陽電池組電池12作為實施例物品3之太陽電池組電池12,以形成有20條寬0.2mm的母線電極14a及90條寬40μm的指狀電極14b之太陽電池組電池12作為實施例物品4之太陽電池組電池12,以形成有7條寬0.57mm的母線電極14a及90條寬20μm的指狀電極14b之太陽電池組電池12作為實施例物品5之太陽電池組電池12,以形成有15條寬0.27mm的母線電極14a及90條寬20μm的指狀電極14b之太陽電池組電池12作為實施例物品5之太陽電池組電池12。 However, in FIG. 13, three bus bars having a width of 1.4 mm are formed. The solar cell 12 of the electrodes 14 and 74 of the finger electrodes 14 having a width of 80 μm was used as the solar cell 12 of Comparative Example 1, to form three bus electrodes 14a having a width of 1.4 mm and 90 fingers having a width of 40 μm. The solar battery cell 12 of the electrode 14b is used as the solar battery cell 12 of the comparative example article 2, and the solar battery cell 12 having five bus bar electrodes 14a having a width of 0.8 mm and 90 finger electrodes 14b having a width of 40 μm is formed as an implementation. In the solar battery cell 12 of the article 1, the solar battery cell 12 in which seven bus bar electrodes 14a having a width of 0.57 mm and the finger electrodes 14b having a width of 40 μm are formed is used as the solar battery cell 12 of the article 2 of the embodiment. The solar battery cell 12 having 15 bus bar electrodes 14a having a width of 0.27 mm and 90 finger electrodes 14b having a width of 40 μm was formed as the solar cell battery 12 of the article 3 of the example to form 20 bus bars having a width of 0.2 mm. The electrode 14a and the solar cell 12 of 90 fingers 40b having a width of 40 μm are used as the solar cell 12 of the article 4 of the embodiment to form seven bus bar electrodes 14a having a width of 0.57 mm and 90 fingers of 20 m width and 20 μm. Solar cell battery 12 of electrode 14b as a real The article of Example 5 solar cell groups 12, 15 are formed to 0.27mm wide bus bar electrode 14a and the width 90 of 20μm finger electrode 14b of the solar cell 12 as the embodiment of the article of Example 5 the solar cell group 12.

又,在圖14中,係以形成有3條寬1.4mm的母線電極14a及70條寬20μm的指狀電極14b之太陽電池組電池12作為比較例物品3之太陽電池組電池12,以形成有3條寬1.4mm的母線電極14a及74條寬20μm的指狀電極14b之太陽電池組電池12作為比較例物品4之太陽電池組電池12,以形成有寬3條1.4mm的母線電極14a及90條寬20μm的指狀電極 14b之太陽電池組電池12作為比較例物品5之太陽電池組電池12,以形成有5條寬0.8mm的母線電極14a及70條寬20μm的指狀電極14b之太陽電池組電池12作為實施例物品7之太陽電池組電池12,以形成有5條寬0.8mm的母線電極14a及74條寬20μm的指狀電極14b之太陽電池組電池12作為實施例物品8之太陽電池組電池12,以形成有5條寬0.8mm的母線電極14a及90條寬20μm的指狀電極14b之太陽電池組電池12作為實施例物品9之太幅電池組電池12。 Further, in Fig. 14, a solar battery cell 12 in which three bus bar electrodes 14a having a width of 1.4 mm and ten finger electrodes 14b having a width of 20 μm are formed is used as the solar battery cell 12 of Comparative Example 3 to form A solar cell 12 having three busbar electrodes 14a having a width of 1.4 mm and 74 finger electrodes 14b having a width of 20 μm was used as the solar cell stack 12 of Comparative Article 4 to form busbar electrodes 14a having a width of three 1.4 mm. And 90 finger electrodes with a width of 20 μm The solar battery cell 12 of 14b is used as the solar battery cell 12 of the comparative example article 5, and the solar battery cell 12 having five bus bar electrodes 14a having a width of 0.8 mm and ten finger electrodes 14b having a width of 20 μm is formed as an embodiment. The solar battery cell 12 of the article 7 is formed of a solar battery cell 12 having five bus bar electrodes 14a having a width of 0.8 mm and 74 finger electrodes 14b having a width of 20 μm as the solar battery cell 12 of the article 8 of the embodiment. A solar battery cell 12 having five bus bar electrodes 14a having a width of 0.8 mm and 90 finger electrodes 14b having a width of 20 μm was formed as the battery cell 12 of the article 9 of the embodiment.

而,在圖15中,係以形成有3條寬1.4mm的母線電極14a及70條寬40μm的指狀電極14b之太陽電池組電池12作為比較例物品6之太陽電池組電池12,以形成有3條寬1.4mm的母線電極14a及74條寬40μm的指狀電極14b之太陽電池組電池12作為比較例物品7之太陽電池組電池12,以形成有5條寬0.8mm的母線電極14a及70條寬40μm的指狀電極14b之太陽電池組電池12作為實施例物品10之太陽電池組電池12,以形成有5條寬0.8mm的母線電極14a及74條寬40μm的指狀電極14b之太陽電池組電池12作為實施例物品11之太陽電池組電池12。 Further, in Fig. 15, a solar battery cell 12 in which three bus bar electrodes 14a having a width of 1.4 mm and ten finger electrodes 14b having a width of 40 μm are formed is used as the solar battery cell 12 of the comparative example article 6 to form The solar cell 12 having three bus bar electrodes 14a having a width of 1.4 mm and 74 finger electrodes 14b having a width of 40 m was used as the solar cell stack 12 of Comparative Article 7, to form five bus bar electrodes 14a having a width of 0.8 mm. And 70 solar cells 12 of the finger electrodes 14b having a width of 40 μm are used as the solar cell 12 of the article 10 of the embodiment to form five bus electrodes 14a having a width of 0.8 mm and 74 finger electrodes 14b having a width of 40 μm. The solar battery cell 12 serves as the solar battery cell 12 of the article 11 of the embodiment.

又,在圖16中,係以形成有3條寬1.4mm的母線電極14a及70條寬60μm的指狀電極14b之太陽電池組電池12作為比較例物品8之太陽電池組電池12,以形成有3條寬1.4mm的母線電極14a及74條寬60μm的指狀電極14b之太陽電池組電池12作為比較例物品9之太陽電池組電池12,以形成有3條寬1.4mm的母線電極14a及90條寬60μm的指狀電極 14b之太陽電池組電池12作為比較例物品10之太陽電池組電池12,以形成有5條寬0.8mm的母線電極14a及70條寬60μm的指狀電極14b之太陽電池組電池12作為實施例物品12之太陽電池組電池12,以形成有5條寬0.8mm的母線電極14a及74條寬60μm的指狀電極14b之太陽電池組電池12作為實施例物品13之太陽電池組電池12,以形成有5條寬0.8mm的母線電極14a及90條寬60μm的指狀電極14b之太陽電池組電池12作為實施例物品14之太陽電池組電池12。 Further, in Fig. 16, a solar battery cell 12 in which three bus bar electrodes 14a having a width of 1.4 mm and ten finger electrodes 14b having a width of 60 μm are formed is used as the solar battery cell 12 of the comparative article 8 to form The solar cell 12 having three busbar electrodes 14a having a width of 1.4 mm and 74 finger electrodes 14b having a width of 60 μm was used as the solar cell stack 12 of Comparative Article 9 to form three busbar electrodes 14a having a width of 1.4 mm. And 90 finger electrodes with a width of 60 μm The solar battery cell 12 of 14b is used as the solar battery cell 12 of the comparative article 10, and the solar battery cell 12 having five bus bar electrodes 14a having a width of 0.8 mm and 70 finger electrodes 14b having a width of 60 μm is formed as an embodiment. The solar battery cell 12 of the article 12 is formed of a solar cell 12 having five bus bar electrodes 14a having a width of 0.8 mm and 74 finger electrodes 14b having a width of 60 μm as the solar cell battery 12 of the article 13 of the embodiment. A solar cell 12 having five bus bar electrodes 14a having a width of 0.8 mm and 90 finger electrodes 14b having a width of 60 m was formed as the solar cell stack 12 of the article 14 of the example.

又,在圖17中,係以形成有3條寬1.4mm的母線電極14a及70條寬80μm的指狀電極14b之太陽電池組電池12作為比較例物品11之太陽電池組電池12,以形成有3條寬1.4mm的母線電極14a及90條寬80μm的指狀電極14b之太陽電池組電池12作為比較例物品12之太陽電池組電池12,以形成有5條寬0.8mm的母線電極14a及70條寬80μm的指狀電極14b之太陽電池組電池12作為實施例物品15之太陽電池組電池12,以形成有5條寬0.8mm的母線電極14a及74條寬80μm的指狀電極14b之太陽電池組電池12作為實施例物品16之太陽電池組電池12,以形成有5條寬0.8mm的母線電極14a及90條寬80μm的指狀電極14b之太陽電池組電池12作為實施例物品17之太陽電池組電池12。 Further, in Fig. 17, a solar battery cell 12 in which three bus bar electrodes 14a having a width of 1.4 mm and ten finger electrodes 14b having a width of 80 μm are formed is used as the solar battery cell 12 of the comparative article 11 to form The solar cell 12 having three busbar electrodes 14a having a width of 1.4 mm and 90 finger electrodes 14b having a width of 80 μm was used as the solar cell stack 12 of Comparative Article 12 to form five busbar electrodes 14a having a width of 0.8 mm. And 70 solar cells 12 of the finger electrodes 14b having a width of 80 μm are used as the solar cell 12 of the article 15 of the embodiment to form five bus electrodes 14a having a width of 0.8 mm and 74 finger electrodes 14b having a width of 80 μm. The solar battery cell 12 is the solar battery cell 12 of the article 16 of the embodiment, and the solar battery cell 12 having five bus bar electrodes 14a having a width of 0.8 mm and 90 finger electrodes 14b having a width of 80 μm is formed as an embodiment article. 17 solar battery pack battery 12.

又,在圖18中,係以形成有3條寬1.4mm的母線電極14a及70條寬100μm的指狀電極14b之太陽電池組電池12作為比較例物品13之太陽電池組電池12,以形成有3條寬1.4mm的母線電極14a及74條寬100μm的指狀電極14b之太 陽電池組電池12作為比較例物品14之太陽電池組電池12,以形成有3條寬1.4mm的母線電極14a及90條寬100μm的指狀電極14b之太陽電池組電池12作為比較例物品15之太陽電池組電池12,以形成有5條寬0.8mm的母線電極14a及70條寬100μm的指狀電極14b之太陽電池組電池12作為實施例物品18之太陽電池組電池12,以形成有5條寬0.8mm的母線電極14a及74條寬100μm的指狀電極14b之太陽電池組電池12作為實施例物品19之太陽電池組電池12,以形成有5條寬0.8mm的母線電極14a及90條寬100μm的指狀電極14b之太陽電池組電池12作為實施例物品20之太陽電池組電池12。 Further, in Fig. 18, a solar battery cell 12 in which three bus bar electrodes 14a having a width of 1.4 mm and ten finger electrodes 14b having a width of 100 μm are formed is used as the solar battery cell 12 of the comparative article article 13 to form There are three bus electrodes 14a with a width of 1.4mm and 74 finger electrodes 14b with a width of 100μm. The solar battery cell 12 was used as the solar battery cell 12 of the comparative example article 14 as a comparative example article 15 in which three bus bar electrodes 14a having a width of 1.4 mm and a finger electrode 14b having a width of 100 μm of 100 μm were formed. The solar battery cell 12 is formed of a solar battery cell 12 having five bus bar electrodes 14a having a width of 0.8 mm and 70 finger electrodes 14b having a width of 100 μm as the solar battery cells 12 of the article 18 of the embodiment. 5 solar cell electrodes 14a having a width of 0.8 mm and 74 solar cells 12 having a finger electrode 14b having a width of 100 μm are used as the solar cell 12 of the article 19 of the embodiment to form five bus electrodes 14a having a width of 0.8 mm and A solar battery cell 12 of 90 finger electrodes 14b having a width of 100 μm is used as the solar battery cell 12 of the article 20 of the embodiment.

又,圖13至圖18之Eff(轉換效率)(%)係以下述式(1)算出。又,在式(1)中Voc(開放電壓)(V)係以下述式(2)算出,Jsc(短路電流密度)(mA/cm2)係以下述式(3)算出,FF(填充因數)係以下述式(4)算出。又,在式(2)中Jo(total)係以下述(5)式算出,在式(4)中FFo係以下述(6)式算出,Rch係以下述(7)式算出。而,在下述式(1)至式(7)中,n係二極體之理想因數,k係波茲曼常數,T係溫度(凱氏溫度),q係元電荷,Fgl係以指狀電極14b覆蓋太陽電池組電池12之受光面的比率,Rs係串聯電阻,Jometal、Joemtter、JoBSF、JoBulk係預定的常數。 Moreover, Eff (conversion efficiency) (%) of FIG. 13 to FIG. 18 is calculated by the following formula (1). Further, in the formula (1), Voc (open voltage) (V) is calculated by the following formula (2), and Jsc (short-circuit current density) (mA/cm 2 ) is calculated by the following formula (3), and FF (fill factor) ) is calculated by the following formula (4). Further, in the formula (2), Jo (total) is calculated by the following formula (5), and in the formula (4), FFO is calculated by the following formula (6), and Rch is calculated by the following formula (7). However, in the following formulas (1) to (7), the ideal factor of the n-type diode, the k-system Boltzmann constant, the T-system temperature (Kjeldahl temperature), the q-system element charge, and the Fgl system are in the form of fingers. The electrode 14b covers the ratio of the light receiving surface of the solar cell 12, and Rs is a series resistor, and Jometal, Joemtter, JoBSF, and JoBulk are predetermined constants.

Eff(轉換效率)=Voc(開放電壓)×Jsc(短路電流密度)×FF(填充因數)…(1) Eff (conversion efficiency) = Voc (open voltage) × Jsc (short circuit current density) × FF (fill factor) (1)

Voc(開放電壓)=n×k×T/q×In(Jsc/Jo(total)-1)… (2) Voc (open voltage) = n × k × T / q × In (Jsc / Jo (total) - 1)... (2)

Jsc(短路電流密度)=38×(1-Fgl)…(3) Jsc (short circuit current density) = 38 × (1-Fgl)... (3)

FF(填充因數)=FFo×(l-Rs/Rch)…(4) FF (fill factor) = FFo × (l-Rs/Rch)... (4)

Jo(total)=Fgl×Jometal+(1-Fgl)×Joemitter+JoBSF+JoBulk…(5) Jo(total)=Fgl×Jometal+(1-Fgl)×Joemitter+JoBSF+JoBulk...(5)

FFo=(q×Voc/n×k×T-In(q×Voc/n×k×T+0.72))/(q×Voc/n×k×T+l)…(6) FFo=(q×Voc/n×k×T−In(q×Voc/n×k×T+0.72))/(q×Voc/n×k×T+l) (6)

Rch=Voc/Jsc…(7) Rch=Voc/Jsc...(7)

依據圖13之測定結果,比較例物品1、2之太陽電池組電池12與實施例物品1至6之太陽電池組電池12比較,Eff(轉換效率)(%)係以實施例物品1至6之太陽電池組電池12較高。此外,依據圖14至圖18之測定結果,在比較例物品1至15之太陽電池組電池12與實施例物品1、實施例物品7至20中,指狀電極14b之寬度及其條數相同,且在太陽電池組電池12中藉由將母線電極14a從3條變成5條可提升Eff(轉換效率)(%)。因此,藉由使母線電極14a之條數在5條以上,比例如形成有3條母線電極的習知太陽電池組電池更可提升Eff(轉換效率)(%)。又,依據圖13之測定結果,FF(填充因數)亦以實施例物品1至6之太陽電池組電池12較高,且太陽電池組電池12之輸出較高。因此,藉由使母線電極14a之條數在5條以上,比例如形成有3條母線電極14a的習知太陽電池組電池更可提升輸出。又,在比較例物品2、實施例物品1至實施例物品4之太陽電池組電池12中,Eff(轉換效率)(%)隨著母線電極14a之條數增加而提升。 According to the measurement results of FIG. 13, the solar battery cells 12 of the comparative articles 1 and 2 were compared with the solar battery cells 12 of the articles 1 to 6, and the Eff (conversion efficiency) (%) was based on the articles 1 to 6 of the examples. The solar battery cell 12 is higher. Further, according to the measurement results of Figs. 14 to 18, in the solar battery cells 12 of the comparative articles 1 to 15, and the article 1 and the articles 7 to 20 of the embodiment, the widths of the finger electrodes 14b and the number of the fingers thereof are the same. In the solar battery cell 12, Eff (conversion efficiency) (%) can be improved by changing the bus bar electrode 14a from three to five. Therefore, by making the number of the bus bar electrodes 14a five or more, Eff (conversion efficiency) (%) can be improved more than, for example, a conventional solar cell battery in which three bus bar electrodes are formed. Further, according to the measurement results of Fig. 13, the FF (fill factor) is also higher in the solar battery cells 12 of the articles 1 to 6 of the embodiment, and the output of the solar battery cells 12 is higher. Therefore, by making the number of bus bar electrodes 14a five or more, it is possible to increase the output more than a conventional solar cell battery in which, for example, three bus bar electrodes 14a are formed. Further, in the solar battery cell 12 of the comparative example article 2, the article 1 to the article 4 of the embodiment, the Eff (conversion efficiency) (%) increases as the number of the bus bar electrodes 14a increases.

又,依據圖14之測定結果,將母線電極14a從3條變更成5條時的Eff(轉換效率)(%)之上升幅度為0.53~0.68(%);依據圖15之測定結果,將母線電極14a從3條變更成5條時的Eff(轉換效率)(%)之上升幅度為0.27~0.34(%);依據圖16之測定結果,將母線電極14a從3條變更成5條時的Eff(轉換效率)(%)之上升幅度為0.18~0.23(%);依據圖17之測定結果,將母線電極14a從3條變更成5條時的Eff(轉換效率)(%)之上升幅度為0.13~0.17(%);依據圖18之測定結果,將母線電極14a從3條變更成5條時的Eff(轉換效率)(%)之上升幅度為0.11~0.13(%);由上述結果認為:將母線電極14a從3條變更成5條時的轉換效率之上升幅度(%)係隨著指狀電極14b之寬度縮窄而增大。又,在本實施例之太陽電池組電池12中,從圖14至圖18之測定結果認為藉由將指狀電極14b之寬度定在80μm以下(理想在60μm以下)並將母線電極14a之條數從3條變更成5條,理想上有望提升Eff(轉換效率)(%)。 Further, according to the measurement result of FIG. 14, the increase range of the Eff (conversion efficiency) (%) when the bus bar electrode 14a is changed from three to five is 0.53 to 0.68 (%); according to the measurement result of FIG. 15, the bus bar is used. When the electrode 14a is changed from three to five, the Eff (conversion efficiency) (%) is increased by 0.27 to 0.34 (%). According to the measurement result of FIG. 16, the bus electrode 14a is changed from three to five. The increase range of Eff (conversion efficiency) (%) is 0.18 to 0.23 (%). According to the measurement result of Fig. 17, the increase in Eff (conversion efficiency) (%) when the bus bar electrode 14a is changed from three to five 0.13 to 0.17 (%); according to the measurement result of FIG. 18, the Eff (conversion efficiency) (%) when the bus bar electrode 14a is changed from three to five is increased by 0.11 to 0.13 (%); It is considered that the increase rate (%) of the conversion efficiency when the bus bar electrode 14a is changed from three to five is increased as the width of the finger electrode 14b is narrowed. Further, in the solar battery cell 12 of the present embodiment, it is considered that the width of the finger electrode 14b is set to 80 μm or less (preferably 60 μm or less) and the strip of the bus bar electrode 14a is determined from the measurement results of FIGS. 14 to 18. The number is changed from 3 to 5, and it is expected to increase Eff (conversion efficiency) (%).

而,在圖13至圖18之測定結果中表示,藉由使母線電極14a在5條以上,可使其比母線電極14a為3條之習知太陽電池組電池12更加提升太陽電池組電池12的輸出,例如在具有複數個形成有3條母線電極14a之習知太陽電池組電池12之太陽電池模組10,與具有複數個形成有5條以上母線電極14a之太陽電池組電池12的太陽電池模組10相較之下,兩太陽電池模組10的個別輸出之差變較大。亦即,在太陽電池模組10中,將太陽電池組電池12彼此串聯並從複 數個太陽電池組電池12取出電力的母線電極14a等之連接電阻成分導致有電力損失,作為該電力損失的主要原因之連接電阻成分所產生的焦耳熱之量係與電阻及電流之平方積成比例。因此,例如,藉由將流至一條母線電極14a之電流減少1/2,即便電阻相同但所產生的損失(焦耳熱)亦僅1/4,故而藉由增加母線電極14a之條數使流至該母線電極14a之電流減少,可適當減低母線電極14a等之連接電阻成分所造成的損失,因此可使例如具有複數個實施例物品1至6之組電池的太陽電池模組10之輸出適當提升。 As shown in the measurement results of FIGS. 13 to 18, by making the bus bar electrodes 14a five or more, the solar cell stack 12 can be further reinforced by the conventional solar cell stack 12 having three bus bar electrodes 14a. The output is, for example, a solar battery module 10 having a plurality of conventional solar battery cells 12 in which three bus bar electrodes 14a are formed, and a sun having a plurality of solar battery cells 12 in which five or more bus bar electrodes 14a are formed. In contrast to the battery module 10, the difference between the individual outputs of the two solar cell modules 10 becomes larger. That is, in the solar cell module 10, the solar cell batteries 12 are connected in series to each other and recovered from The connection resistance component of the bus bar electrode 14a or the like from which the plurality of solar battery cells 12 are taken out causes power loss, and the amount of Joule heat generated by the connection resistance component which is a cause of the power loss is the square product of the resistance and the current. proportion. Therefore, for example, by reducing the current flowing to one bus electrode 14a by 1/2, even if the resistance is the same, the loss (Joule heat) is only 1/4, so that the flow is increased by increasing the number of bus electrodes 14a. The current to the bus bar electrode 14a is reduced, and the loss due to the connection resistance component of the bus bar electrode 14a or the like can be appropriately reduced. Therefore, for example, the output of the solar cell module 10 having the battery of the plurality of embodiments of the articles 1 to 6 can be appropriately made. Upgrade.

依據本實施例之太陽電池模組10,係於配置有母線電極14a之配線片材16a、16b上設置太陽電池組電池12,使該太陽電池組電池12與配線於配線片材16a、16b上之母線電極14a之間形成觸點,母線電極14a負有標記線的功能,且配線於太陽電池組電池12之表面12a的前述標記線之條數在5條以上。因此,於配置有母線電極14a之配線片材16a、16b上設置太陽電池組電池12,使該太陽電池組電池12與配線在配線片材16a、16b上之母線電極14a之間形成觸點,故無須如習知在將太陽電池組電池彼此串聯時使用焊帶,並且無須使用將該焊帶加熱之加熱裝置。藉此,形成於太陽電池組電池12之標記線之條數即不受前述加熱裝置之數量限制,因此可製造具有複數個形成有5條標記線之太陽電池組電池12的太陽電池模組10。 According to the solar battery module 10 of the present embodiment, the solar battery cells 12 are disposed on the wiring sheets 16a and 16b on which the bus bar electrodes 14a are disposed, so that the solar battery cells 12 and the wirings are on the wiring sheets 16a and 16b. A contact is formed between the bus bar electrodes 14a, and the bus bar electrode 14a functions as a mark line, and the number of the mark lines wired on the surface 12a of the solar cell 12 is five or more. Therefore, the solar cell 12 is placed on the wiring sheets 16a and 16b on which the bus bar electrodes 14a are disposed, and the solar cell stack 12 and the bus bar electrodes 14a on the wiring sheets 16a and 16b are formed to form contacts. Therefore, it is not necessary to use a solder ribbon as in the case of connecting the solar battery cells in series with each other, and it is not necessary to use a heating device that heats the solder ribbon. Thereby, the number of the marking lines formed in the solar battery cell 12 is not limited by the number of the above-described heating means, so that the solar battery module 10 having the plurality of solar battery cells 12 formed with five marking lines can be manufactured. .

又,依據本實施例之太陽電池模組10,係將配線有母線電極14a之一對配線片材16a、16b及一對玻璃18、20 積層於太陽電池組電池12之兩面12a、12b,以使母線電極接觸太陽電池組電池12之兩面12a、12b,進行按壓同時進行加熱,藉此可獲得太陽電池組電池12與母線電極14a之觸點狀態,且一對配線片材16a、16b之間配置有由絕緣組成物所構成之間隔物22。因此,由太陽電池組電池12、一對配線片材16a、16b及一對玻璃18、20所構成之積層體36在進行按壓同時加熱的情況下,可藉由間隔物22減低加諸於太陽電池組電池12之負荷,故而可防止太陽電池組電池12之破裂。 Further, according to the solar battery module 10 of the present embodiment, one of the bus bar electrodes 14a is wired to the wiring sheets 16a and 16b and the pair of glasses 18 and 20 The two sides 12a, 12b of the solar cell 12 are laminated so that the bus electrodes are in contact with both sides 12a, 12b of the solar cell 12, and are heated while being pressed, whereby the contact between the solar cell 12 and the bus electrode 14a can be obtained. In the dot state, a spacer 22 composed of an insulating composition is disposed between the pair of wiring sheets 16a and 16b. Therefore, when the laminated body 36 composed of the solar battery cell 12, the pair of wiring sheets 16a and 16b, and the pair of glasses 18 and 20 is heated while being pressed, it can be added to the sun by the spacer 22 The load of the battery cells 12 prevents the solar battery cells 12 from being broken.

又,依據本實施例之太陽電池模組10,配線於配線片材16a、16b之金屬電極14負有母線電極14a與指狀電極14b之功能,因此可適當減低太陽電池組電池12之電阻。 Further, according to the solar battery module 10 of the present embodiment, the metal electrodes 14 wired on the wiring sheets 16a and 16b function as the bus bar electrodes 14a and the finger electrodes 14b, so that the electric resistance of the solar battery cells 12 can be appropriately reduced.

又,依據本實施例之太陽電池模組10,配線於配線片材16a、16b之母線電極14a、指狀電極14b等金屬電極14係金屬線、或金屬箔、或熱硬化型導電性組成物、或低融點合金,因此可將金屬電極14適當地配線在配線片材16a、16b上。 Further, according to the solar battery module 10 of the present embodiment, the metal electrode 14 such as the bus bar electrode 14a and the finger electrode 14b of the wiring sheets 16a and 16b is a metal wire or a metal foil or a thermosetting conductive composition. Or a low melting point alloy, so that the metal electrode 14 can be appropriately wired on the wiring sheets 16a and 16b.

又,依據本實施例之太陽電池模組10,由前述金屬線或前述金屬箔所構成之母線電極14a、指狀電極14b等金屬電極14係透過熱硬化型透明接著劑或含有導電性微粒子之熱硬化型透明接著劑而固定在配線片材16a、16b,因此可將由前述金屬線或前述金屬箔所構成之母線電極14a、指狀電極14b等金屬電極14適當地配線在配線片材16a、16b上。 Further, according to the solar battery module 10 of the present embodiment, the metal electrode 14 such as the bus bar electrode 14a and the finger electrode 14b composed of the metal wire or the metal foil is transmitted through a thermosetting transparent adhesive or containing conductive fine particles. The heat-curable transparent adhesive is fixed to the wiring sheets 16a and 16b. Therefore, the metal electrode 14 such as the bus bar electrode 14a and the finger electrode 14b composed of the metal wire or the metal foil can be appropriately wired on the wiring sheet 16a. On 16b.

又,依據本實施例之太陽電池模組10,由前述熱硬化型導電性組成物所構成之母線電極14a、指狀電極14b等金屬電極14可藉由印刷由金屬粒子及黏結劑樹脂所構成之組成物並使其乾燥而形成,故而可將由前述熱硬化型導電性組成物所構成之母線電極14a、指狀電極14b等金屬電極14適當地配線在配線片材16a、16b上。 Further, according to the solar battery module 10 of the present embodiment, the metal electrode 14 such as the bus bar electrode 14a and the finger electrode 14b composed of the thermosetting conductive composition can be composed of metal particles and a binder resin by printing. The composition is formed by drying and drying, and the metal electrode 14 such as the bus bar electrode 14a and the finger electrode 14b composed of the thermosetting conductive composition can be appropriately wired on the wiring sheets 16a and 16b.

又,依據本實施例之太陽電池模組10,負有標記線功能的母線電極14a之線寬在0.8mm以下且長寬比在1/7以上。因此,可適當減低母線電極14a在太陽電池組電池12上的陰影面積,並且可適當減低太陽電池組電池12之電阻。 Further, according to the solar battery module 10 of the present embodiment, the bus bar electrode 14a having the function of the mark line has a line width of 0.8 mm or less and an aspect ratio of 1/7 or more. Therefore, the shadow area of the bus bar electrode 14a on the solar cell 12 can be appropriately reduced, and the electric resistance of the solar cell 12 can be appropriately reduced.

又,依據本實施例之太陽電池模組10,負有手指功能的指狀電極14b在70條以上,線寬在80μm以下,且長寬比在1/7以上。因此,可適當減低指狀電極14b在太陽電池組電池12上的陰影面積,並且可適當減低太陽電池組電池12之電阻,而可適當使轉換效率提升。 Further, according to the solar battery module 10 of the present embodiment, the number of finger electrodes 14b having a finger function is 70 or more, the line width is 80 μm or less, and the aspect ratio is 1/7 or more. Therefore, the shaded area of the finger electrode 14b on the solar cell 12 can be appropriately reduced, and the electric resistance of the solar cell 12 can be appropriately reduced, and the conversion efficiency can be appropriately improved.

又,依據本實施例之太陽電池模組10,配線片材16a、16b係密封材材料,為PVB或EVA,因此可適當提升太陽電池模組10之耐久性。 Further, according to the solar battery module 10 of the present embodiment, the wiring sheets 16a and 16b are made of a sealing material, which is PVB or EVA, so that the durability of the solar battery module 10 can be appropriately improved.

又,依據本實施例之太陽電池模組10之製造方法,係藉由疊合步驟P4來製造太陽電池模組10,即以真空疊合機在疊合時藉由按壓、加熱而一次形成由太陽電池組電池12、一對配線片材16a、16b及一對玻璃18、20所構成之積層體36的加熱壓接。因此,不需要如習知以焊帶將太陽電池組電池彼此串聯的焊帶接著步驟,且無須使用將該 焊帶加熱之加熱裝置,故而形成於太陽電池組電池12之母線電極14a之條數不受前述加熱裝置之數量限制,可製造具有複數個形成有5條母線電極14a之太陽電池組電池12的太陽電池模組10。 Moreover, according to the manufacturing method of the solar cell module 10 of the embodiment, the solar cell module 10 is manufactured by the laminating step P4, that is, the vacuum laminating machine is formed by pressing and heating at the time of lamination. The solar cell 12, the pair of wiring sheets 16a and 16b, and the laminated body 36 of the pair of glasses 18 and 20 are heated and pressure-bonded. Therefore, there is no need for a solder ribbon in which the solar cell batteries are connected in series with each other as a conventional step, and it is not necessary to use the same. The heating device for heating the ribbon is such that the number of bus bar electrodes 14a formed in the solar cell 12 is not limited by the number of the heating devices, and a plurality of solar cells 12 having five bus electrodes 14a can be fabricated. Solar battery module 10.

實施例2 Example 2

接下來說明本發明其他實施例。而,以下說明中,實施例相互間共通的部分係附以相同符號並省略說明。 Next, other embodiments of the present invention will be described. In the following description, the parts that are common to the embodiments are denoted by the same reference numerals, and the description thereof will be omitted.

本實施例之太陽電池模組與前述實施例1之太陽電池模組10比較,在具有母線電極14a之截面形狀不同的母線電極14a'一點上有所不同,其他則與實施例1之太陽電池模組10相同。 The solar cell module of the present embodiment is different from the solar cell module 10 of the first embodiment in that it has a different bus bar electrode 14a' having a different cross-sectional shape of the bus bar electrode 14a, and the other is the solar cell of the first embodiment. Module 10 is identical.

如圖19顯示,母線電極14a'之截面呈圓形。因此,若以母線電極14a'來反射太陽電池模組所受之光,其反射之光的一部分會被反射至玻璃18再入射至太陽電池組電池12,因此比使用截面形狀為矩形的母線電極14之實施例1之太陽電池模組10可更有效地利用在太陽電池模組所受之光。而,母線電極14a'係藉由軋延加工或模拉伸加工等由截面形狀為圓形之金屬線形成。 As shown in Fig. 19, the bus bar electrode 14a' has a circular cross section. Therefore, if the light received by the solar cell module is reflected by the bus bar electrode 14a', a part of the reflected light is reflected to the glass 18 and then incident on the solar cell stack 12, so that a bus bar electrode having a rectangular cross-sectional shape is used. The solar cell module 10 of Embodiment 1 of the present invention can more effectively utilize the light received by the solar cell module. Further, the bus bar electrode 14a' is formed of a metal wire having a circular cross section by rolling, die stretching, or the like.

實施例3 Example 3

本實施例之太陽電池模組與前述實施例1之太陽電池模組10比較,在具有母線電極14a之截面形狀不同的母線電極14a"一點上有所不同,其他則與實施例1之太陽電池模組10相同。 The solar cell module of the present embodiment is different from the solar cell module 10 of the first embodiment in that the bus bar electrode 14a having a different cross-sectional shape of the bus bar electrode 14a differs, and the other is the solar cell of the first embodiment. Module 10 is identical.

如圖20顯示,母線電極14a"之截面呈三角形。因 此,若以母線電極14a"來反射太陽電池模組所受之光,其反射之光的一部分會被反射至玻璃18再入射至太陽電池組電池12,故而比使用截面形狀為矩形的母線電極14之實施例1之太陽電池模組10相比可更有效地利用在太陽電池模組所受之光。而,母線電極14a"係藉由軋延加工或模拉伸加工等由截面形狀為三角形之金屬線形成。 As shown in Fig. 20, the bus bar electrode 14a" has a triangular cross section. Therefore, if the bus electrode 14a" reflects the light received by the solar cell module, a part of the reflected light is reflected to the glass 18 and then incident on the solar cell 12, so that a bus electrode having a rectangular cross-sectional shape is used. The solar cell module 10 of the first embodiment can utilize the light received by the solar cell module more effectively than the solar cell module 10 of the first embodiment. The bus bar electrode 14a is formed by a rolling process or a die drawing process. A metal wire of a triangle is formed.

實施例4 Example 4

本實施例之太陽電池模組與前述實施例1之太陽電池模組10比較,在具有母線電極14a之截面形狀不同的母線電極14a'''一點上有所不同,其他則與實施例1之太陽電池模組10相同。 The solar cell module of the present embodiment is different from the solar cell module 10 of the first embodiment in that the bus bar electrodes 14a'' having different cross-sectional shapes of the bus bar electrodes 14a are different, and the other is the same as that of the first embodiment. The solar cell module 10 is the same.

如圖21顯示,母線電極14a'''之截面呈四角形,且其受光面側的表面經表面處理成凹凸。因此,若以母線電極14a"'之表面來反射太陽電池模組所受之光,其反射之光的一部分會被反射至玻璃18再入射至太陽電池組電池12,故而比使用截面形狀為矩形的母線電極14之實施例1之太陽電池模組10相比可更有效利用在太陽電池模組所受之光。而,母線電極14a"'係對經加工使金屬截面形狀呈四角的金屬線表面進行噴砂加工等而形成。又,用以取代上述噴砂加工,亦可使用砂刷、砂紙等使上述金屬線表面附上切痕。 As shown in Fig. 21, the bus bar electrode 14a''' has a quadrangular cross section, and the surface on the light-receiving surface side is surface-treated into irregularities. Therefore, if the light received by the solar cell module is reflected by the surface of the bus bar electrode 14a", a part of the reflected light is reflected to the glass 18 and then incident on the solar cell 12, so that the cross-sectional shape is rectangular. The bus electrode 14 of the embodiment 1 can utilize the light received by the solar cell module more effectively than the solar cell module 10 of the first embodiment. The bus bar electrode 14a" is a pair of metal wires processed to have a metal cross-sectional shape at four corners. The surface is formed by sandblasting or the like. Further, in place of the above-described sandblasting, a surface of the above-mentioned metal wire may be attached with a sand brush, sandpaper or the like.

實施例5 Example 5

本實施例之太陽電池模組與前述實施例1之太陽電池模組10比較,在下述兩點有所不同,其他則與實施例1 之太陽電池模組10略微相同:為單面受光型太陽電池組電池一點,即太陽電池組電池12係由例如n型矽及p型矽所構成,並以太陽電池組電池12之表面12a受光而發電;以及配線片材16b係未配線指狀電極14b之配線片材40一點,該配線片材16b係配設在與該太陽電池組電池12之受光面12a側相反之側。 The solar cell module of the present embodiment is different from the solar cell module 10 of the first embodiment in the following two points, and the other is the same as the first embodiment. The solar battery module 10 is slightly identical: it is a single-sided light-receiving solar battery unit, that is, the solar battery unit 12 is composed of, for example, an n-type p and a p-type ,, and is received by the surface 12a of the solar battery unit 12. On the other hand, the wiring sheet 16b is one end of the wiring sheet 40 of the finger electrode 14b, and the wiring sheet 16b is disposed on the side opposite to the light receiving surface 12a side of the solar battery cell 12.

如圖22顯示,於長條平板狀且由EVA所構成之配線片材(透明片材)40上6處分別配線5條母線電極42,並於該等5條母線電極42分別形成有相對於配線片材40之長邊方向延伸於垂直方向的連接部42a成一體,該母線電極42係延伸於配線片材40之長邊方向且負有標記線功能的金屬電極。而,母線電極42之寬度比實施例1之母線電極14a的寬度更寬,因此即便未在配線片材40配線指狀電極,仍可適當減低太陽電池組電池12之電阻。又,配線在配線片材40之母線電極42與實施例1之配線在配線片材16b之母線電極14a及指狀電極14b等金屬電極14同樣地,係由金屬線、或金屬箔、或熱硬化型導電性組成物、或低融點合金形成。 As shown in Fig. 22, five bus bar electrodes 42 are respectively wired at six places on a wiring sheet (transparent sheet) 40 composed of a long flat plate and formed of EVA, and the five bus bar electrodes 42 are respectively formed with respect to the five bus bar electrodes 42. The connection portion 42a extending in the longitudinal direction of the wiring sheet 40 is integrated, and the bus bar electrode 42 is a metal electrode that extends in the longitudinal direction of the wiring sheet 40 and has a function of a mark line. On the other hand, since the width of the bus bar electrode 42 is wider than the width of the bus bar electrode 14a of the first embodiment, the electric resistance of the solar cell stack 12 can be appropriately reduced even if the finger electrode is not wired on the wiring sheet 40. Further, the bus bar electrode 42 of the wiring sheet 40 and the wiring of the first embodiment are made of a metal wire, a metal foil, or a heat, similarly to the metal electrode 14 such as the bus bar electrode 14a and the finger electrode 14b of the wiring sheet 16b. A hardened conductive composition or a low melting point alloy is formed.

如圖22顯示,於配線片材40固定有一對間隔物22,且該配線片材40之設有間隔物22之側的相反側設置有未圖示之背部片材。又,若將太陽電池組電池12收納至配線片材40上之間隔物22之組電池收納空間24,則配線片材40之母線電極42接觸與該太陽電池組電池12之受光面12a側為相反側之面12b。 As shown in Fig. 22, a pair of spacers 22 are fixed to the wiring sheet 40, and a back sheet (not shown) is provided on the opposite side of the side of the wiring sheet 40 on which the spacers 22 are provided. When the solar battery cell 12 is housed in the battery storage space 24 of the spacer 22 on the wiring sheet 40, the bus bar electrode 42 of the wiring sheet 40 is in contact with the light receiving surface 12a side of the solar battery cell 12. The opposite side of the face 12b.

在本實施例之太陽電池模組中,與實施例1之太 陽電池模組10之製造方法略微同樣地,在積層步驟P3中係於單面受光型太陽電池組電池12之兩面12a、12b積層配線有母線電極42的配線片材40及配線有母線電極14a、指狀電極14b等金屬電極14的配線片材16a,並於單面受光型太陽電池組電池12之表面12a側即受光面側積層玻璃18,於該太陽電池組電池12之背面12b側即與受光面側相反之側積層背部片材,使母線電極14a及指狀電極14b接觸於太陽電池組電池12之表面12a,且使母線電極42接觸於太陽電池組電池12之背面12b。接著在疊合步驟P4中將藉由積層步驟P3積層而成之積層體,例如以真空疊合機進行按壓同時進行加熱,藉此以配線片材16a及配線片材40將該太陽電池組電池12壓接密封,如此一來在鄰接之太陽電池組電池12中即可將母線電極14a之連接部14c與母線電極42之連接部42a連接。而,在藉由上述積層步驟P3所積層之積層體中,間隔物22係配置在配線片材40與配線片材16a之間。 In the solar cell module of the embodiment, the embodiment 1 is too In the laminating step P3, the wiring sheet 40 in which the bus bar electrodes 42 are wired and the bus bar electrodes 14a are wired on the both surfaces 12a and 12b of the single-sided light-receiving solar cell 12 in the laminating step P3. The wiring sheet 16a of the metal electrode 14 such as the finger electrode 14b is placed on the surface 12a of the single-sided light-receiving solar cell 12, that is, the light-receiving side laminated glass 18, and the back surface 12b side of the solar battery cell 12 is The side back sheet is opposite to the light receiving surface side, and the bus bar electrode 14a and the finger electrode 14b are brought into contact with the surface 12a of the solar cell 12, and the bus bar electrode 42 is brought into contact with the back surface 12b of the solar cell 12 . Then, in the lamination step P4, the laminate body which is laminated by the lamination step P3 is heated while being pressed by a vacuum laminator, whereby the solar cell battery is formed by the wiring sheet 16a and the wiring sheet 40. The pressure-sealing seal is such that the connecting portion 14c of the bus bar electrode 14a and the connecting portion 42a of the bus bar electrode 42 can be connected to each other in the adjacent solar battery cell 12. On the other hand, the spacer 22 is disposed between the wiring sheet 40 and the wiring sheet 16a in the laminated body laminated by the laminating step P3.

依據本實施例之太陽電池模組,於太陽電池組電池12之兩面12a及12b積層配線有母線電極42或母線電極14a及指狀電極14b之一對配線片材16a、40,並於單面受光型太陽電池組電池12之表面12a側即受光面側積層玻璃18,於單面受光型太陽電池組電池12之背面12b側即與受光面側相反之側積層背部片材,使母線電極42、母線電極14a及指狀電極14b接觸於太陽電池組電池12之兩面12a、12b,並在疊合步驟P4中進行按壓同時進行加熱,藉此可獲得太陽電池組電池12與母線電極42、母線電極14a及指狀電極 14b之觸點狀態,並且在一對配線片材16a、40之間配置有一對由絕緣組成物所構成之間隔物22。因此,由太陽電池組電池12、一對配線片材16a、40、玻璃18及前述背部片材所構成之積層體在進行按壓同時加熱的情況下,可藉由一對間隔物22減低加諸於太陽電池組電池12之負荷,故而可防止太陽電池組電池12之破裂。 According to the solar cell module of the present embodiment, the bus bar electrode 42 or one of the bus bar electrode 14a and the finger electrode 14b is laminated on the both sides 12a and 12b of the solar cell stack 12, and is on one side of the wiring sheet 16a, 40. The light-receiving surface side laminated glass 18 on the surface 12a side of the light-receiving solar battery cell 12 is laminated on the back surface 12b side of the single-sided light-receiving solar battery cell 12, that is, on the side opposite to the light-receiving surface side, and the bus bar electrode 42 is laminated. The bus bar electrode 14a and the finger electrode 14b are in contact with both faces 12a and 12b of the solar cell stack 12, and are heated while being pressed in the laminating step P4, whereby the solar cell 12 and the bus bar electrode 42 and the bus bar can be obtained. Electrode 14a and finger electrode In the contact state of 14b, a pair of spacers 22 composed of an insulating composition are disposed between the pair of wiring sheets 16a and 40. Therefore, when the laminated body composed of the solar battery cell 12, the pair of wiring sheets 16a and 40, the glass 18, and the back sheet is heated while being pressed, it can be reduced by a pair of spacers 22 The load on the solar battery cell 12 prevents the solar battery cell 12 from being broken.

實施例6 Example 6

本實施例之太陽電池模組與前述實施例1之太陽電池模組10比較,在下述兩點有所不同,其他則與實施例1之太陽電池模組10略微相同:配設在太陽電池組電池12之表面12a側的配線片材16a係不具指狀電極且配線有10條金屬電極之母線電極44的配線片材46一點;以及配設在太陽電池組電池12之背面12b側的配線片材16b係不具指狀電極且配線有10條金屬電極之母線電極48的配線片材50一點。 The solar cell module of the present embodiment is different from the solar cell module 10 of the first embodiment in the following two points, and the other is slightly the same as the solar cell module 10 of the first embodiment: it is disposed in the solar cell module. The wiring sheet 16a on the surface 12a side of the battery 12 is a wiring sheet 46 having no finger electrodes and having the bus bar electrodes 44 of the ten metal electrodes, and a wiring sheet disposed on the back surface 12b side of the solar battery cell 12. The material 16b is a wiring sheet 50 which does not have a finger electrode and is wired with the bus electrode 48 of ten metal electrodes.

如圖23顯示,於長條平板狀且由EVA所構成之配線片材(透明片材)46上6處分別配線10條延伸於該配線片材46之長邊方向且負有標記線功能的母線電極44,並於該等10條母線電極44分別形成有相對於配線片材46之長邊方向延伸於垂直方向的連接部44a成一體。 As shown in FIG. 23, in the wiring sheet (transparent sheet) 46 composed of a long strip and formed of EVA, six wirings are respectively extended in the longitudinal direction of the wiring sheet 46 and have a mark line function. The bus bar electrodes 44 are integrally formed with the connection portions 44a extending in the vertical direction with respect to the longitudinal direction of the wiring sheet 46, respectively, in the ten bus bar electrodes 44.

如圖24顯示,於長條平板狀且由EVA所構成之配線片材(透明片材)50上6處分別配線10條延伸於該配線片材50之長邊方向且負有標記線功能的母線電極48,並於該等10條母線電極48分別形成有相對於配線片材50之長邊方向延伸於垂直方向的連接部48a成一體。而,配線在一對配線 片材46、50之母線電極44、48與實施例1之配線在一對配線片材16a、16b之母線電極14a及指狀電極14b等金屬電極14同樣地,係由金屬線、或金屬箔、或熱硬化型導電性組成物、或低融點合金形成。 As shown in FIG. 24, in the wiring sheet (transparent sheet) 50 composed of an EVA, the wiring is extended in the longitudinal direction of the wiring sheet 50 and has a mark line function. The bus bar electrodes 48 are integrally formed with the connection portions 48a extending in the vertical direction with respect to the longitudinal direction of the wiring sheet 50, respectively, in the ten bus bar electrodes 48. And, the wiring is in a pair of wiring The bus bar electrodes 44 and 48 of the sheets 46 and 50 and the wiring of the first embodiment are made of a metal wire or a metal foil in the same manner as the metal electrode 14 such as the bus bar electrode 14a and the finger electrode 14b of the pair of wiring sheets 16a and 16b. Or a thermosetting conductive composition or a low melting point alloy.

如圖24顯示,在配線片材50固定有一對間隔物22,若將太陽電池組電池12收納至配線片材50上之間隔物22之組電池收納空間24,則配線片材50之母線電極48接觸該太陽電池組電池12之背面12b。又,在配線片材46固定有玻璃18,並在配線片材50固定有玻璃20。 As shown in FIG. 24, a pair of spacers 22 are fixed to the wiring sheet 50, and when the solar battery cells 12 are housed in the battery storage space 24 of the spacers 22 on the wiring sheet 50, the bus bar electrodes of the wiring sheets 50 are provided. 48 contacts the back side 12b of the solar cell battery 12. Moreover, the glass 18 is fixed to the wiring sheet 46, and the glass 20 is fixed to the wiring sheet 50.

在本實施例之太陽電池模組中,以與實施例1之太陽電池模組10之製造方法略微同樣地,在積層步驟P3中係於太陽電池組電池12之兩面12a及12b將配線有母線電極44之配線片材46及配線有母線電極48之配線片材50及一對玻璃18、20,積層成配線片材46、50之母線電極44、48接觸於太陽電池組電池12之兩面12a及12b。接著在疊合步驟P4中將藉由積層步驟P3積層而成之積層體例如以真空疊合機進行按壓同時進行加熱,藉此以配線片材46及配線片材50將該太陽電池組電池12壓接密封,如此一來,即可在鄰接之太陽電池組電池12中將母線電極44之連接部44a與母線電極48之連接部48a連接。因此,依據本實施例之太陽電池模組,可製造具有複數個形成有10條母線電極44、48之太陽電池組電池12的太陽電池模組。 In the solar cell module of the present embodiment, in the laminating step P3, the solar cell module 10 of the first embodiment is connected to the busbars 12a and 12b of the solar cell stack 12 in the laminating step P3. The wiring sheet 46 of the electrode 44 and the wiring sheet 50 on which the bus bar electrode 48 is wired and the pair of glasses 18 and 20, and the bus bar electrodes 44 and 48 laminated to the wiring sheets 46 and 50 are in contact with both sides 12a of the solar battery cell 12. And 12b. Then, in the laminating step P4, the layered body laminated by the laminating step P3 is heated while being pressed by a vacuum laminator, for example, thereby heating the solar cell 12 with the wiring sheet 46 and the wiring sheet 50. The pressure-sealing seal is such that the connecting portion 44a of the bus bar electrode 44 and the connecting portion 48a of the bus bar electrode 48 can be connected to the adjacent solar battery cell 12. Therefore, according to the solar battery module of the present embodiment, a solar battery module having a plurality of solar battery cells 12 formed with ten bus electrodes 44, 48 can be manufactured.

實施例7 Example 7

本實施例之太陽電池模組與前述實施例1之太陽 電池模組10比較,在下述三點有所不同,其他則與實施例1之太陽電池模組10略微相同:太陽電池組電池12之兩面12a、12b預先連接有指狀電極52一點;配設在太陽電池組電池12之表面12a側的配線片材16a係未配線指狀電極之配線片材54一點;以及配設在太陽電池組電池12之背面12b側的配線片材16b係未配線指狀電極之上述實施例5之配線片材40一點。 The solar cell module of the present embodiment and the sun of the foregoing embodiment 1 The battery module 10 is different from the following three points, and the other is slightly the same as the solar battery module 10 of the first embodiment: the two sides 12a, 12b of the solar battery unit 12 are pre-connected with a finger electrode 52; The wiring sheet 16a on the surface 12a side of the solar cell 12 is a point of the wiring sheet 54 on which the finger electrodes are not wired, and the wiring sheet 16b disposed on the back surface 12b side of the solar cell 12 is an unwiring finger The wiring sheet 40 of the above-described Embodiment 5 of the electrode is a little.

如圖25顯示,於長條平板狀且由EVA所構成之配線片材(透明片材)54上6處分別配線5條母線電極56,且於該等5條母線電極56形成有相對於配線片材54之長邊方向延伸於垂直方向的連接部56a成一體,該母線電極56係延伸於該配線片材54之長邊方向且負有標記線功能的金屬電極。 As shown in FIG. 25, five bus bar electrodes 56 are respectively wired at six places on a wiring sheet (transparent sheet) 54 composed of an EVA, and five bus bar electrodes 56 are formed with respect to the wiring. The connecting portion 56a extending in the longitudinal direction of the sheet 54 is integrated, and the bus bar electrode 56 is a metal electrode extending in the longitudinal direction of the wiring sheet 54 and having a function of a marking line.

如圖26顯示,於太陽電池組電池12之兩面12a、12b預先連接有複數條例如90條的指狀電極52。又,在圖26中為了可較輕易地理解本實施例,係以異於實際物品的方式來圖示連接在太陽電池組電池12之指狀電極52之條數及其大小。 As shown in Fig. 26, a plurality of, for example, 90 finger electrodes 52 are previously connected to both sides 12a, 12b of the solar battery cell 12. Further, in Fig. 26, in order to facilitate the understanding of the present embodiment, the number and size of the finger electrodes 52 connected to the solar battery cells 12 are illustrated in a manner different from the actual articles.

以下,以本實施例之太陽電池模組之製造方法來進行說明。如圖26顯示,首先在圖27之太陽電池組電池形成步驟P5中,與太陽電池組電池形成步驟P1同樣地形成太陽電池組電池12。 Hereinafter, the method of manufacturing the solar cell module of the present embodiment will be described. As shown in Fig. 26, first, in the solar battery cell forming step P5 of Fig. 27, the solar battery cell 12 is formed in the same manner as the solar battery cell forming step P1.

接著,在圖27之太陽電池組電池表面指狀電極形成步驟P6中,以印刷於太陽電池組電池12之表面12a形成例如由銀等所構成之指狀電極52,其後將指狀電極52乾燥使 該指狀電極52硬化,藉此如圖26顯示地於太陽電池組電池12之表面12a形成指狀電極52。 Next, in the solar cell battery surface finger electrode forming step P6 of FIG. 27, a finger electrode 52 composed of, for example, silver or the like is formed on the surface 12a of the solar cell stack 12, and thereafter the finger electrode 52 is formed. Drying The finger electrode 52 is hardened, whereby the finger electrode 52 is formed on the surface 12a of the solar cell 12 as shown in FIG.

接下來在圖27之太陽電池組電池背面指狀電極形成步驟P7中,以印刷於太陽電池組電池12之背面12b形成例如由銀等所構成之指狀電極52,其後將指狀電極52乾燥使指狀電極52硬化,藉此於太陽電池組電池12之背面12b形成指狀電極52。 Next, in the solar cell battery back finger electrode forming step P7 of Fig. 27, a finger electrode 52 made of, for example, silver or the like is formed on the back surface 12b of the solar cell 12, and thereafter the finger electrode 52 is formed. Drying causes the finger electrode 52 to harden, whereby the finger electrode 52 is formed on the back surface 12b of the solar cell 12 .

接著在圖27之配線片材製造步驟P8中,如圖25顯示地於長條平板狀且由EVA所構成之樹脂片材配線母線電極56以製造配線片材54,並如圖22顯示地於長條平板狀且由EVA所構成之樹脂片材配線母線電極42以製造配線片材40。又,與配線片材製造步驟P2同樣地,配線在配線片材40、54之母線電極42、56係由金屬線、或金屬箔、或熱硬化型導電性組成物、或低融點合金形成。而,在圖27中係在太陽電池組電池背面指狀電極形成步驟P7後接著進行配線片材製造步驟P8,例如配線片材製造步驟P8可在太陽電池組電池形成步驟P5至太陽電池組電池背面指狀電極形成步驟P7之任一步驟後進行,亦可在太陽電池組電池形成步驟P5前進行。又,亦可在太陽電池組電池背面指狀電極形成步驟P7後接著進行太陽電池組電池表面指狀電極形成步驟P6。 Next, in the wiring sheet manufacturing step P8 of Fig. 27, a resin sheet wiring bus bar electrode 56 composed of an EVA is formed as shown in Fig. 25 to manufacture a wiring sheet 54, and is shown in Fig. 22 The resin sheet wiring bus bar electrode 42 made of a flat plate and made of EVA is used to manufacture the wiring sheet 40. Further, similarly to the wiring sheet manufacturing step P2, the bus bar electrodes 42 and 56 wired on the wiring sheets 40 and 54 are formed of a metal wire, a metal foil, a thermosetting conductive composition, or a low melting point alloy. . 27, in the solar cell battery back finger electrode forming step P7, the wiring sheet manufacturing step P8 is performed, for example, the wiring sheet manufacturing step P8 can be performed in the solar cell forming step P5 to the solar battery cell. The step of forming the back finger electrode in step P7 may be performed before the solar cell battery forming step P5. Further, the solar cell battery surface finger electrode forming step P6 may be followed by the solar cell battery back finger electrode forming step P7.

在配線片材製造步驟P8中,與配線片材製造步驟P2同樣地製造一對間隔物22,並以例如接著劑等將該一對間隔物22固定在配線片材40成一體。又,在配線片材製造 步驟P8中,與配線片材製造步驟P2同樣地以例如接著劑將長條平板狀的透明的玻璃18、20固定在配線片材40、54成一體。 In the wiring sheet manufacturing step P8, a pair of spacers 22 are produced in the same manner as the wiring sheet manufacturing step P2, and the pair of spacers 22 are fixed to the wiring sheet 40 by, for example, an adhesive. Also, in the manufacture of wiring sheets In the step P8, similarly to the wiring sheet manufacturing step P2, the long flat transparent glass 18, 20 is fixed to the wiring sheets 40, 54 by, for example, an adhesive.

接下來在圖27之積層步驟P9中,於配線片材製造步驟P8中所製造之固定有玻璃20及一對間隔物22成一體的配線片材40積層太陽電池組電池12,使太陽電池組電池12被收納至間隔物22之組電池收納空間24內,並將配線片材製造步驟P8中所製造之固定有玻璃18成一體之配線片材54積層於太陽電池組電池12之表面12a。即,在積層步驟P9中,於預先連接有指狀電極52之太陽電池組電池12之兩面12a及12b,將配線有母線電極42、56之一對配線片材40、54及一對玻璃18、20積層成母線電極42、56接觸於太陽電池組電池12之兩面12a及12b。而,圖26之點虛線係表示連接有指狀電極52之太陽電池組電池12的表面12a已積層配線片材54時的母線電極56之位置。 Next, in the laminating step P9 of FIG. 27, the wiring sheet 40 in which the glass 20 and the pair of spacers 22 are fixed in the wiring sheet manufacturing step P8 is laminated with the solar battery cell 12 to make the solar battery pack The battery 12 is housed in the assembled battery storage space 24 of the spacer 22, and the wiring sheet 54 in which the glass 18 is fixed and manufactured by the wiring sheet manufacturing step P8 is laminated on the surface 12a of the solar battery cell 12. In other words, in the lamination step P9, the both surfaces 12a and 12b of the solar cell 12 to which the finger electrodes 52 are connected in advance are connected, and one of the bus electrodes 42 and 56 is wired to the wiring sheets 40 and 54 and the pair of glasses 18 The 20-layered bus bar electrodes 42, 56 are in contact with both sides 12a and 12b of the solar battery cell 12. In addition, the dotted line in FIG. 26 indicates the position of the bus bar electrode 56 when the wiring sheet 54 has been laminated on the surface 12a of the solar cell 12 to which the finger electrode 52 is connected.

接著在圖27之疊合(熱壓接)步驟P10中,與疊合步驟P4同樣地例如以真空疊合機在真空中例如在130℃~150℃之範圍下進行加熱,藉此以配線片材40、54將複數個太陽電池組電池12壓接密封,如此一來即可將鄰接之太陽電池組電池12中固定於一太陽電池組電池12之背面12b的母線電極42之連接部42a與固定在另一太陽電池組電池12之表面12a的母線電極56之連接部56a連接。藉此,可製造具有複數個形成有5條母線電極42、56之太陽電池組電池12的太陽電池模組。 Next, in the superimposing (thermocompression bonding) step P10 of FIG. 27, heating is performed in a vacuum, for example, at a temperature ranging from 130 ° C to 150 ° C, for example, in a vacuum laminator, in the same manner as in the laminating step P4. The materials 40, 54 crimp and seal a plurality of solar battery cells 12, so that the connecting portion 42a of the adjacent bus battery 12 fixed to the rear surface 12b of the solar battery cell 12 can be connected to the connecting portion 42a of the solar battery cell 12 The connecting portion 56a of the bus bar electrode 56 fixed to the surface 12a of the other solar battery cell 12 is connected. Thereby, a solar cell module having a plurality of solar battery cells 12 formed with five bus bar electrodes 42, 56 can be manufactured.

實施例8 Example 8

本實施例之太陽電池模組與前述實施例1之太陽電池模組10比較,在下述四點有所不同,其他則與實施例1之太陽電池模組10略微相同:其太陽電池組電池12係具有抗反射膜58及金屬電極59且由例如n型半導體60a及p型半導體60b所構成的單面受光型太陽電池組電池60一點;其太陽電池組電池60之表面60c預先連接有母線電極62及指狀電極64,且於太陽電池組電池60之背面60d預先連接有母線電極66一點;配設在太陽電池組電池60之表面60c側的配線片材16a係未配線指狀電極之上述實施例7之配線片材54一點;以及配設在太陽電池組電池60之背面60d側的配線片材16b係未配線指狀電極之上述實施例5條配線片材40一點。 The solar cell module of the present embodiment is different from the solar cell module 10 of the first embodiment in the following four points, and the others are slightly the same as the solar cell module 10 of the first embodiment: the solar cell battery 12 thereof. A single-sided light-receiving solar cell 60 having an anti-reflection film 58 and a metal electrode 59 and composed of, for example, an n-type semiconductor 60a and a p-type semiconductor 60b; a surface 60c of the solar cell 60 is previously connected with a bus electrode 62 and the finger electrode 64, and the bus bar electrode 66 is connected in advance to the back surface 60d of the solar cell 60; the wiring sheet 16a disposed on the surface 60c side of the solar cell 60 is the above-mentioned unwired finger electrode. One point of the wiring sheet 54 of the seventh embodiment; and a wiring sheet 16b disposed on the back surface 60d side of the solar battery cell 60 is a point of the wiring sheet 40 of the above-described fifth embodiment in which the finger electrodes are not wired.

如圖28顯示,於太陽電池組電池60之表面60c預先連接有5條母線電極62及複數條例如90條的指狀電極64。又,如圖28顯示,於太陽電池組電池60之背面60d預先連接有5條母線電極66。而,5條母線電極62、66的各間隔與配線在配線片材40、54之母線電極42、56的各間隔皆同。又,在圖28中為了可較輕易地理解本實施例,係以異於實際物品的方式來圖示連接在太陽電池組電池60之指狀電極64之條數及其大小。 As shown in Fig. 28, five bus bar electrodes 62 and a plurality of, for example, 90 finger electrodes 64 are connected in advance to the surface 60c of the solar cell battery 60. Further, as shown in FIG. 28, five bus bar electrodes 66 are connected in advance to the back surface 60d of the solar battery cell 60. Further, the intervals of the five bus bar electrodes 62, 66 and the wiring are the same in the respective intervals of the bus bar electrodes 42, 56 of the wiring sheets 40, 54. Further, in Fig. 28, in order to facilitate the understanding of the present embodiment, the number and size of the finger electrodes 64 connected to the solar battery cells 60 are illustrated in a manner different from the actual articles.

以下係以本實施例之太陽電池模組之製造方法來進行說明。首先,在圖29之太陽電池組電池形成步驟P11中,如圖28顯示於p型半導體60b上積層n型半導體60a成一體,以形成太陽電池組電池60,其後於太陽電池組電池60 之表面60c積層抗反射膜58成一體。 Hereinafter, the method of manufacturing the solar cell module of the present embodiment will be described. First, in the solar cell formation step P11 of FIG. 29, as shown in FIG. 28, the n-type semiconductor 60a is laminated on the p-type semiconductor 60b to form a solar cell 60, and thereafter to the solar cell 60. The surface 60c is laminated with the anti-reflection film 58 in one body.

接下來,在圖29之太陽電池組電池背面母線電極印刷步驟P12中以印刷於太陽電池組電池60之背面60d形成例如由銀等所構成之母線電極66。接下來,在圖29之第1乾燥步驟P13中使形成於太陽電池組電池60之背面60d的母線電極66乾燥。 Next, in the solar cell battery back bus electrode printing step P12 of FIG. 29, a bus electrode 66 made of, for example, silver or the like is formed on the back surface 60d of the solar cell battery 60. Next, the bus bar electrode 66 formed on the back surface 60d of the solar battery cell 60 is dried in the first drying step P13 of FIG.

接著在圖29之太陽電池組電池背面金屬電極印刷步驟P14中,以印刷於太陽電池組電池60之背面60d形成例如由鋁等所構成之平板狀的金屬電極59。接著在圖29之第2乾燥步驟P15中,將印刷在太陽電池組電池60之背面60d的金屬電極59乾燥。 Next, in the solar cell rear surface metal electrode printing step P14 of Fig. 29, a flat metal electrode 59 made of, for example, aluminum or the like is formed on the back surface 60d of the solar battery cell 60. Next, in the second drying step P15 of Fig. 29, the metal electrode 59 printed on the back surface 60d of the solar battery cell 60 is dried.

再來,在圖29之太陽電池組電池表面指狀、母線電極同時印刷步驟P16中,以同時印刷於抗反射膜58形成例如由銀等所構成之母線電極62及指狀電極64,且該抗反射膜58係形成在太陽電池組電池60之表面60c。接著在圖29之第3乾燥步驟P17中,將形成在太陽電池組電池60之抗反射膜58的母線電極62及指狀電極64乾燥。 Further, in the solar cell battery surface finger-like and bus-bar electrode simultaneous printing step P16 of FIG. 29, the bus bar electrode 62 and the finger electrode 64 composed of, for example, silver or the like are formed by simultaneously printing on the anti-reflection film 58. The anti-reflection film 58 is formed on the surface 60c of the solar cell battery 60. Next, in the third drying step P17 of FIG. 29, the bus bar electrode 62 and the finger electrode 64 formed on the anti-reflection film 58 of the solar cell 60 are dried.

再來,在圖29之燒成(fire through)步驟P18中,在750℃~800℃之範圍內將太陽電池組電池60進行燒成,藉以將形成在太陽電池組電池60之抗反射膜58上的母線電極62及指狀電極64之下的抗反射膜58蝕刻,並如圖28顯示地將母線電極62及指狀電極64連接至太陽電池組電池60之表面60c。 Further, in the fire through step P18 of FIG. 29, the solar cell battery 60 is fired in the range of 750 ° C to 800 ° C, whereby the anti-reflection film 58 formed on the solar cell 60 is formed. The upper bus bar electrode 62 and the anti-reflection film 58 under the finger electrode 64 are etched, and the bus bar electrode 62 and the finger electrode 64 are connected to the surface 60c of the solar cell battery 60 as shown in FIG.

接著在圖29之配線片材製造步驟P19中,與配線 片材製造步驟P8同樣地製造配線有母線電極42之配線片材40及配線有母線電極56之配線片材54。而,在配線片材製造步驟P19中,與配線片材製造步驟P8同樣地例如以接著劑於配線片材40固定一對間隔物22及未圖示之背部片材成一體,並以例如接著劑於配線片材54固定玻璃18成一體。在圖29中係在燒成步驟P18後接著進行配線片材製造步驟P19,而配線片材製造步驟P19例如可在太陽電池組電池形成步驟P11至燒成步驟P18之任一步驟後進行,亦可在太陽電池組電池形成步驟P11前進行。又,亦可在太陽電池組電池背面金屬電極印刷步驟P12至第2乾燥步驟P15之前,進行太陽電池組電池表面指狀、母線電極同時印刷步驟P16及第3乾燥步驟P17。 Next, in the wiring sheet manufacturing step P19 of Fig. 29, and wiring In the sheet manufacturing step P8, the wiring sheet 40 on which the bus bar electrode 42 is wired and the wiring sheet 54 on which the bus bar electrode 56 is wired are manufactured in the same manner. In the wiring sheet manufacturing step P19, similarly to the wiring sheet manufacturing step P8, for example, a pair of spacers 22 and a back sheet (not shown) are fixed to the wiring sheet 40 by an adhesive, and for example, The agent fixes the glass 18 to the wiring sheet 54 in one piece. In FIG. 29, the wiring sheet manufacturing step P19 is performed after the firing step P18, and the wiring sheet manufacturing step P19 can be performed, for example, after any of the steps of the solar cell formation step P11 to the firing step P18. This can be performed before the solar cell battery forming step P11. Moreover, the solar cell surface finger shape, the bus bar electrode simultaneous printing step P16, and the third drying step P17 may be performed before the solar cell battery back metal electrode printing step P12 to the second drying step P15.

接下來在圖29之積層步驟P20中,於固定有配線片材製造步驟P19中所製造之一對間隔物22及前述背部片材成一體的配線片材40積層太陽電池組電池60,使太陽電池組電池60被收納至間隔物22之組電池收納空間24內,並將固定有配線片材製造步驟P19中所製造之玻璃18成一體的配線片材54積層於太陽電池組電池60之表面60c側。即,在積層步驟P20中,係於表面60c側預先連接有母線電極62及指狀電極64且背面60d側預先連接有金屬電極59及母線電極66之太陽電池組電池60的兩面60c、60d,積層配線有母線電極42、56之一對配線片材40、54,並於表面60c側積層玻璃18,在背面60d側積層前述背部片材,以使配線片材54之母線電極56接觸於形成在太陽電池組電池60之表面 60c的母線電極62,且使配線片材40之母線電極42接觸於形成在太陽電池組電池60之背面60d的金屬電極59。而,圖28之點虛線係表示在連接有母線電極62及指狀電極64之太陽電池組電池60的表面60c已積層配線片材54時的母線電極56之位置。 Next, in the laminating step P20 of FIG. 29, the solar cell battery 60 is laminated on the wiring sheet 40 in which the spacer 22 and the back sheet are integrally formed in the wiring sheet manufacturing step P19. The battery cell 60 is housed in the assembled battery storage space 24 of the spacer 22, and the wiring sheet 54 in which the glass 18 manufactured in the wiring sheet manufacturing step P19 is integrated is laminated on the surface of the solar battery cell 60. 60c side. In other words, in the laminating step P20, the bus bar electrodes 62 and the finger electrodes 64 are connected to the surface 60c side, and the both surfaces 60c and 60d of the solar cell stack 60 of the metal electrode 59 and the bus bar electrode 66 are connected to the back surface 60d side. The laminated wiring has one of the bus bar electrodes 42, 56 facing the wiring sheets 40 and 54, and the laminated glass 18 is laminated on the surface 60c side, and the back sheet is laminated on the back surface 60d side so that the bus bar electrode 56 of the wiring sheet 54 is in contact with the formation. On the surface of the solar cell battery 60 The bus bar electrode 62 of 60c contacts the bus bar electrode 42 of the wiring sheet 40 to the metal electrode 59 formed on the back surface 60d of the solar cell battery 60. In addition, the dotted line in FIG. 28 indicates the position of the bus bar electrode 56 when the wiring sheet 54 has been laminated on the surface 60c of the solar cell 60 to which the bus bar electrode 62 and the finger electrode 64 are connected.

接著在圖29之疊合(熱壓接)步驟P21中,與疊合步驟P4同樣地例如以真空疊合機在真空中例如在130℃~150℃之範圍下進行加熱,藉此以配線片材40、54將複數個太陽電池組電池60壓接密封,如此一來即可在鄰接之太陽電池組電池60中將固定在一太陽電池組電池60之背面60d的母線電極42之連接部42a與固定在另一太陽電池組電池60之表面60c的母線電極56之連接部56a連接。藉此,可製造具有複數個形成有5條母線電極42、56之太陽電池組電池60的太陽電池模組。 Next, in the lamination (thermo-compression bonding) step P21 of FIG. 29, as in the lamination step P4, for example, a vacuum laminator is used in a vacuum, for example, in the range of 130 ° C to 150 ° C, whereby the wiring piece is used. The materials 40, 54 crimp and seal a plurality of solar battery cells 60, so that the connecting portion 42a of the bus bar electrode 42 fixed to the back surface 60d of the solar battery cell 60 in the adjacent solar battery cell 60 can be fixed. It is connected to the connection portion 56a of the bus bar electrode 56 fixed to the surface 60c of the other solar battery cell 60. Thereby, a solar cell module having a plurality of solar battery cells 60 in which five bus bar electrodes 42, 56 are formed can be manufactured.

實施例9 Example 9

本實施例之太陽電池模組與前述實施例1之太陽電池模組10比較,在設於配線片材16b之一對間隔物22被間隔物68取代一點有所不同,其他則與實施例1之太陽電池模組10略微相同。 The solar cell module of the present embodiment is different from the solar cell module 10 of the first embodiment in that one of the wiring sheets 16b is different from the spacers 22 by the spacers 68, and the other is the same as the first embodiment. The solar cell module 10 is slightly identical.

如圖30顯示,間隔物68係由絕緣組成物例如陶瓷或陶瓷與樹脂之混合物等所構成且形成為長條平板狀,在該間隔物68形成有收納太陽電池組電池12之組電池收納空間70,及使配線在配線片材16a、16b之母線電極14a的連接部14c插入之插入空間72。又,組電池收納空間70的寬度E 與太陽電池組電池12之尺寸A相同,或僅比該太陽電池組電池12之尺寸A略大。又,間隔物60之厚度與太陽電池組電池12之厚度相同,或比該太陽電池組電池12之厚度更厚。 As shown in FIG. 30, the spacer 68 is formed of an insulating composition such as ceramic or a mixture of ceramic and resin, and is formed into a long flat plate shape, and a battery storage space for accommodating the solar battery cell 12 is formed in the spacer 68. 70, and an insertion space 72 into which the wiring is inserted into the connection portion 14c of the bus bar electrode 14a of the wiring sheets 16a and 16b. Moreover, the width E of the assembled battery storage space 70 It is the same as the size A of the solar battery cell 12, or only slightly larger than the size A of the solar battery cell 12. Moreover, the thickness of the spacer 60 is the same as or thicker than the thickness of the solar cell 12 .

又,間隔物68如圖30顯示係設置成相對於太陽電池模組之受光面埋置在複數個太陽電池組電池12間,且該間隔物68之顏色係例如較易將光反射之白色。因此,太陽電池模組所受之光當中被反射至間隔物68之光會被反射至玻璃18、20後再入射至太陽電池組電池12。 Further, the spacer 68 is disposed so as to be embedded between the plurality of solar battery cells 12 with respect to the light receiving surface of the solar battery module, and the color of the spacer 68 is, for example, white which is more easily reflected by light. Therefore, light reflected by the solar cell module to be reflected to the spacer 68 is reflected to the glass 18, 20 and then incident on the solar cell 12 .

依據本實施例之太陽電池模組,一對配線片材16a、16b設有透明的玻璃18、20或透明的樹脂。因此,可將例如在太陽電池模組所受之光中被間隔物68所受之光的一部分反射至透明的玻璃18、20或前述樹脂後,再使其入射至太陽電池組電池12。 According to the solar cell module of the present embodiment, the pair of wiring sheets 16a, 16b are provided with transparent glass 18, 20 or a transparent resin. Therefore, for example, a part of the light received by the spacer 68 in the light received by the solar cell module can be reflected to the transparent glass 18, 20 or the resin, and then incident on the solar cell 12 .

以上係依據圖式詳細說明本發明之實施例,惟本發明亦可適用在其他態樣上。 The embodiments of the present invention are described in detail above with reference to the drawings, but the invention may be applied to other aspects.

在本實施例之太陽電池模組10中,太陽電池組電池12係使用積層有晶矽與非晶矽之混成型(HIT型)太陽電池組電池,例如太陽電池組電池12可為矽晶系太陽電池組電池、異質接合型太陽電池組電池、及CIGS等之化合物系太陽電池組電池等。因此,藉由適用本發明,可於矽晶系太陽電池組電池、異質接合型太陽電池組電池、及CIGS等之化合物系太陽電池組電池等之太陽電池組電池適當配線5條以上的母線電極14a。 In the solar cell module 10 of the present embodiment, the solar cell battery 12 is a hybrid battery (HIT type) solar cell battery in which a wafer and an amorphous crucible are laminated, for example, the solar cell 12 can be a twin system. A solar battery cell, a heterojunction solar cell battery, and a compound such as CIGS are solar battery cells. Therefore, by applying the present invention, it is possible to appropriately wire five or more bus electrodes in a solar cell such as a twin crystal solar cell, a heterojunction solar cell, or a compound solar cell such as CIGS. 14a.

又,在實施例1至4、6、7、9之太陽電池模組中, 太陽電池組電池係使用兩面受光型太陽電池組電池,亦可使用單面受光型太陽電池組電池。又,在實施例5、8之太陽電池模組中,太陽電池組電池係使用單面受光型太陽電池組電池,亦可使用兩面受光型太陽電池組電池。 Moreover, in the solar cell modules of Embodiments 1 to 4, 6, 7, and 9, The solar cell battery uses a double-sided light-receiving solar cell battery, and a single-sided light-receiving solar cell battery can also be used. Further, in the solar battery modules of the fifth and eighth embodiments, the solar battery cell uses a single-sided light-receiving solar battery, and a double-sided light-receiving solar battery can also be used.

又,在實施例9之太陽電池模組中,間隔物68之顏色係使用較易將光反射之白色,惟間隔物68之顏色可為任意色。例如,當間隔物68之顏色為建築物等偏好的黑色時,可適當提升太陽電池模組10在建物中的美感。 Further, in the solar battery module of the ninth embodiment, the color of the spacer 68 is white which is more easily reflected by light, but the color of the spacer 68 may be any color. For example, when the color of the spacer 68 is a black color such as a building, the aesthetics of the solar cell module 10 in the construction can be appropriately improved.

在實施例1之太陽電池模組10中,形成在太陽電池組電池12之母線電極14a為5條且其線寬為0.8mm,亦可例如將母線電極14a之條數增加超過5條,使其線寬比0.8mm更細。又,形成在太陽電池組電池12之指狀電極14b為90條且其線寬為40μm,亦可例如將指狀電極14b之條數增加超過90條,使其線寬比40μm更細。 In the solar battery module 10 of the first embodiment, the number of the bus bar electrodes 14a formed in the solar battery cells 12 is five and the line width thereof is 0.8 mm. For example, the number of the bus bar electrodes 14a can be increased by more than five. Its line width is finer than 0.8mm. Further, the number of finger electrodes 14b formed in the solar cell 12 is 90 and the line width thereof is 40 μm. For example, the number of the finger electrodes 14b may be increased by more than 90, and the line width may be made thinner than 40 μm.

又,在實施例1之太陽電池模組10中,間隔物22係以縱框部22a及橫框部22b包圍太陽電池組電池12而形成為環狀,間隔物22亦可為非環狀。例如,可僅使上述縱框部22a固定在配線片材16a、16b上,或可僅使上述橫框部22b固定在配線片材16a、16b上。亦即,在疊合步驟P4中只要可減低加諸於太陽電池組電池12之負荷,間隔物22可為任意形狀。 Further, in the solar battery module 10 of the first embodiment, the spacer 22 is formed in a ring shape by surrounding the solar battery cell 12 with the vertical frame portion 22a and the horizontal frame portion 22b, and the spacer 22 may be acyclic. For example, only the vertical frame portion 22a may be fixed to the wiring sheets 16a and 16b, or only the horizontal frame portion 22b may be fixed to the wiring sheets 16a and 16b. That is, the spacer 22 may have any shape as long as the load applied to the solar battery cell 12 can be reduced in the laminating step P4.

又,在本實施例中,金屬電極14係透過接著劑而固定在配線片材16a、16b,未必非得使用接著劑。即,可使金屬電極14、配線片材16a、16b等積層於太陽電池組電 池12之兩面12a及12b,藉由疊合步驟P4將其積層體36熱壓接,藉此使密封材材料之配線片材16a、16b溶解後固化,即不必透過接著劑而僅以物理接觸地將金屬電極14固定在配線片材16a、16b上。 Further, in the present embodiment, the metal electrode 14 is fixed to the wiring sheets 16a and 16b by the adhesive, and it is not necessary to use an adhesive. That is, the metal electrode 14, the wiring sheets 16a, 16b, and the like can be laminated on the solar battery pack. The two faces 12a and 12b of the pool 12 are thermocompression bonded by the laminate body 36 by the laminating step P4, whereby the wiring sheets 16a, 16b of the sealing material are dissolved and solidified, that is, it is not necessary to pass through the adhesive and only physically contact. The metal electrode 14 is fixed to the wiring sheets 16a, 16b.

而,上述內容僅為一實施形態,本發明可在依據熟知此項技藝之人士的知識附加各種變更、改良的態樣下實施。 However, the above description is only one embodiment, and the present invention can be implemented in various modifications and improvements in accordance with the knowledge of those skilled in the art.

10‧‧‧太陽電池模組 10‧‧‧Solar battery module

12‧‧‧太陽電池組電池 12‧‧‧Solar battery cell

14‧‧‧金屬電極 14‧‧‧Metal electrode

14a‧‧‧母線電極 14a‧‧‧ Busbar electrodes

14b‧‧‧指狀電極 14b‧‧‧ finger electrode

14c‧‧‧連接部 14c‧‧‧Connecting Department

16b‧‧‧配線片材(透明片材) 16b‧‧‧Wiring sheet (transparent sheet)

22‧‧‧間隔物 22‧‧‧ spacers

22a‧‧‧縱框部 22a‧‧‧ vertical frame

22b‧‧‧橫框部 22b‧‧‧ transverse frame

24‧‧‧組電池收納空間 24‧‧‧ battery storage space

26‧‧‧插入空間 26‧‧‧Insert space

A‧‧‧尺寸 A‧‧‧ size

B、C‧‧‧等間隔 B, C‧‧‧ equal intervals

II‧‧‧截面線 II‧‧‧ section line

Claims (13)

一種太陽電池模組,其係在配置有金屬電極之透明片材上設置太陽電池組電池,且該太陽電池組電池與配線在前述透明片材上之前述金屬電極之間形成有觸點;前述太陽電池模組之特徵在於:前述金屬電極負有標記線的功能,配線在前述太陽電池組電池之表面的前述標記線之條數在5條以上。 A solar cell module in which a solar cell battery is disposed on a transparent sheet on which a metal electrode is disposed, and a contact is formed between the solar cell and the wiring on the transparent metal sheet; The solar battery module is characterized in that the metal electrode has a function of a mark line, and the number of the mark lines on the surface of the solar battery unit is five or more. 如請求項1之太陽電池模組,其中於前述太陽電池組電池之兩面,將配置有前述金屬電極之一對透明片材及一對透明板積層成前述金屬電極接觸前述太陽電池組電池之兩面,藉由進行按壓同時進行加熱,可獲得前述太陽電池組電池與前述金屬電極之觸點狀態;且前述一對透明片材之間配置有由絕緣組成物所構成之間隔物。 The solar cell module of claim 1, wherein one of the metal electrodes is disposed on the two sides of the solar cell, and the transparent sheet and the pair of transparent plates are laminated to form the metal electrode contacting the two sides of the solar cell. By heating while pressing, a contact state between the solar cell and the metal electrode can be obtained, and a spacer composed of an insulating composition is disposed between the pair of transparent sheets. 如請求項1之太陽電池模組,其中於前述太陽電池組電池之兩面,將配置有前述金屬電極之一對透明片材積層成前述金屬電極接觸前述太陽電池組電池之兩面,並於表面側積層透明板,於背面側積層背部片材,藉由進行按壓同時進行加熱,可獲得前述太陽電池組電池與前述金屬電極之觸點狀態;且前述一對透明片材之間配置有由絕緣組成物所構成之間隔物。 The solar cell module of claim 1, wherein one of the metal electrodes is disposed on both sides of the solar cell, and the transparent sheet is laminated to form the metal electrode contacting the two sides of the solar cell, and is on the surface side. a laminated transparent plate is formed on the back side, and the back sheet is laminated and heated to obtain a contact state between the solar cell and the metal electrode; and the pair of transparent sheets are disposed with insulation a spacer formed by the object. 如請求項1之太陽電池模組,其中金屬電極負有標記線與手指的功能。 The solar cell module of claim 1, wherein the metal electrode has a function of marking a line and a finger. 如請求項1之太陽電池模組,其中金屬電極係金屬線、金屬箔、熱硬化型導電性組成物、或低融點合金。 The solar cell module of claim 1, wherein the metal electrode is a metal wire, a metal foil, a thermosetting conductive composition, or a low melting point alloy. 如請求項5之太陽電池模組,其中由前述金屬線或前述金屬箔所構成之前述金屬電極係透過熱硬化型透明接著劑或含有導電性微粒子之熱硬化型透明接著劑而固定在前述透明片材。 The solar cell module according to claim 5, wherein the metal electrode composed of the metal wire or the metal foil is fixed to the transparent portion by a thermosetting transparent adhesive or a thermosetting transparent adhesive containing conductive fine particles. Sheet. 如請求項5之太陽電池模組,其中由前述熱硬化型導電性組成物所構成之前述金屬電極係藉由印刷由金屬粒子及黏結劑樹脂所構成之組成物並使其乾燥而形成。 The solar cell module according to claim 5, wherein the metal electrode composed of the thermosetting conductive composition is formed by printing a composition composed of metal particles and a binder resin and drying the composition. 如請求項1之太陽電池模組,其中負有標記線功能的前述金屬電極係線寬在0.8mm以下且長寬比在1/7以上。 The solar cell module according to claim 1, wherein the metal electrode line having the function of the mark line has a line width of 0.8 mm or less and an aspect ratio of 1/7 or more. 如請求項1之太陽電池模組,其中負有手指功能的前述金屬電極係70條以上,線寬在80μm以下且長寬比在1/7以上。 The solar cell module according to claim 1, wherein the metal electrode system having a finger function is 70 or more, the line width is 80 μm or less, and the aspect ratio is 1/7 or more. 如請求項1之太陽電池模組,其中透明片材係密封材材料,為PVB或EVA。 The solar cell module of claim 1, wherein the transparent sheet is a sealing material, which is PVB or EVA. 如請求項1之太陽電池模組,其中太陽電池組電池係矽晶系太陽電池組電池、異質接合型太陽電池組電池、及CIGS等之化合物系太陽電池組電池。 The solar cell module of claim 1, wherein the solar cell battery is a silicon solar cell battery, a heterojunction solar cell battery, and a compound such as CIGS is a solar cell battery. 如請求項2或3之太陽電池模組,其中透明板係透明的玻璃或樹脂。 The solar cell module of claim 2 or 3, wherein the transparent plate is a transparent glass or resin. 一種太陽電池模組之製造方法,其係如請求項1至12中 任一項之太陽電池模組之製造方法,其特徵在於:由前述太陽電池組電池、前述透明片材、及前述透明板所構成之積層體的加熱壓接係疊合時藉由按壓、加熱而一次形成。 A method of manufacturing a solar cell module, as in claims 1 to 12 In a method of manufacturing a solar cell module according to any one of the preceding claims, the heating and pressure bonding of the laminated body comprising the solar cell, the transparent sheet, and the transparent plate is performed by pressing and heating And formed once.
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