TW201311553A - 結晶石墨烯及製造結晶石墨烯之方法 - Google Patents
結晶石墨烯及製造結晶石墨烯之方法 Download PDFInfo
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- TW201311553A TW201311553A TW100145124A TW100145124A TW201311553A TW 201311553 A TW201311553 A TW 201311553A TW 100145124 A TW100145124 A TW 100145124A TW 100145124 A TW100145124 A TW 100145124A TW 201311553 A TW201311553 A TW 201311553A
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- Prior art keywords
- graphene
- crystalline
- magnesium
- isolated
- electronic device
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 188
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 159
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 238000000034 method Methods 0.000 claims abstract description 56
- 239000011777 magnesium Substances 0.000 claims abstract description 43
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 29
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 22
- 239000000203 mixture Substances 0.000 claims abstract description 21
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 12
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 40
- 229910052751 metal Inorganic materials 0.000 claims description 27
- 239000002184 metal Substances 0.000 claims description 27
- 239000002245 particle Substances 0.000 claims description 21
- 239000007788 liquid Substances 0.000 claims description 14
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 10
- 239000001569 carbon dioxide Substances 0.000 claims description 10
- 238000001914 filtration Methods 0.000 claims description 10
- 239000000395 magnesium oxide Substances 0.000 claims description 9
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000000706 filtrate Substances 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 7
- 238000002441 X-ray diffraction Methods 0.000 claims description 6
- 239000011701 zinc Substances 0.000 claims description 6
- 229910052725 zinc Inorganic materials 0.000 claims description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 230000005855 radiation Effects 0.000 claims description 3
- 239000011260 aqueous acid Substances 0.000 claims description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 2
- 229910002483 Cu Ka Inorganic materials 0.000 claims 2
- 229910002090 carbon oxide Inorganic materials 0.000 claims 2
- 239000013078 crystal Substances 0.000 claims 1
- 239000000758 substrate Substances 0.000 claims 1
- 239000010410 layer Substances 0.000 description 28
- 239000000463 material Substances 0.000 description 20
- 235000011089 carbon dioxide Nutrition 0.000 description 18
- 239000000047 product Substances 0.000 description 14
- 229910002804 graphite Inorganic materials 0.000 description 11
- 239000010439 graphite Substances 0.000 description 11
- 239000011148 porous material Substances 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 8
- 239000002135 nanosheet Substances 0.000 description 7
- 238000002485 combustion reaction Methods 0.000 description 6
- 239000000725 suspension Substances 0.000 description 6
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 5
- 239000006227 byproduct Substances 0.000 description 5
- 150000002739 metals Chemical class 0.000 description 5
- 239000002356 single layer Substances 0.000 description 5
- 238000003786 synthesis reaction Methods 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 238000001069 Raman spectroscopy Methods 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 229910052723 transition metal Inorganic materials 0.000 description 4
- 150000003624 transition metals Chemical class 0.000 description 4
- 238000001237 Raman spectrum Methods 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 150000001342 alkaline earth metals Chemical class 0.000 description 3
- 150000001722 carbon compounds Chemical class 0.000 description 3
- 238000005119 centrifugation Methods 0.000 description 3
- 230000032798 delamination Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 229910052744 lithium Inorganic materials 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- -1 Li) Chemical class 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 238000003917 TEM image Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000013590 bulk material Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000002173 high-resolution transmission electron microscopy Methods 0.000 description 2
- 229910001338 liquidmetal Inorganic materials 0.000 description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 2
- 239000001095 magnesium carbonate Substances 0.000 description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 238000005554 pickling Methods 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000012265 solid product Substances 0.000 description 2
- 238000009210 therapy by ultrasound Methods 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- 229910052692 Dysprosium Inorganic materials 0.000 description 1
- 229910052691 Erbium Inorganic materials 0.000 description 1
- 229910052693 Europium Inorganic materials 0.000 description 1
- 229910052688 Gadolinium Inorganic materials 0.000 description 1
- 229910052689 Holmium Inorganic materials 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- 229910052779 Neodymium Inorganic materials 0.000 description 1
- 229910052777 Praseodymium Inorganic materials 0.000 description 1
- 229910052772 Samarium Inorganic materials 0.000 description 1
- 229910052771 Terbium Inorganic materials 0.000 description 1
- 229910052776 Thorium Inorganic materials 0.000 description 1
- 229910052775 Thulium Inorganic materials 0.000 description 1
- 229910052769 Ytterbium Inorganic materials 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000003872 anastomosis Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910021383 artificial graphite Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000724 energy-dispersive X-ray spectrum Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- 239000008241 heterogeneous mixture Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 239000002073 nanorod Substances 0.000 description 1
- 239000002077 nanosphere Substances 0.000 description 1
- 239000002070 nanowire Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/182—Graphene
- C01B32/184—Preparation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/182—Graphene
- C01B32/184—Preparation
- C01B32/19—Preparation by exfoliation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/182—Graphene
- C01B32/194—After-treatment
- C01B32/196—Purification
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/52—Electrically conductive inks
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2204/00—Structure or properties of graphene
- C01B2204/02—Single layer graphene
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Nanotechnology (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Composite Materials (AREA)
- Carbon And Carbon Compounds (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161533045P | 2011-09-09 | 2011-09-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW201311553A true TW201311553A (zh) | 2013-03-16 |
Family
ID=45464835
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW100145124A TW201311553A (zh) | 2011-09-09 | 2011-12-07 | 結晶石墨烯及製造結晶石墨烯之方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9340430B2 (enExample) |
| EP (1) | EP2753577B1 (enExample) |
| JP (1) | JP2014527950A (enExample) |
| KR (1) | KR20140092809A (enExample) |
| CN (1) | CN103906706A (enExample) |
| TW (1) | TW201311553A (enExample) |
| WO (1) | WO2013036272A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9340430B2 (en) | 2011-09-09 | 2016-05-17 | Board Of Trustees Of Northern Illinois University | Crystalline graphene and method of making crystalline graphene |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8420042B2 (en) * | 2010-09-21 | 2013-04-16 | High Temperature Physics, Llc | Process for the production of carbon graphenes and other nanomaterials |
| GB201218952D0 (en) * | 2012-10-22 | 2012-12-05 | Cambridge Entpr Ltd | Functional inks based on layered materials and printed layered materials |
| EP2832689A1 (en) * | 2013-07-30 | 2015-02-04 | Fundación Imdea Nanociencia | Graphene dried powder and method for its preparation |
| CN103539104A (zh) * | 2013-10-22 | 2014-01-29 | 中国科学院宁波材料技术与工程研究所 | 一种石墨烯量子点分散液的制备方法 |
| TW201515994A (zh) * | 2013-10-28 | 2015-05-01 | Enerage Inc | 奈米石墨烯空心粒子及其製作方法 |
| GB201401721D0 (en) * | 2014-01-31 | 2014-03-19 | Univ Manchester | Ink formulation |
| WO2015180163A1 (en) | 2014-05-30 | 2015-12-03 | East China University Of Science And Technology | Methods and systems for converting carbon dioxide into graphene |
| CN104277592B (zh) * | 2014-09-16 | 2016-07-20 | 中国科学院化学研究所 | 一种石墨烯基水性墨水及其喷墨打印透明的图案化导电电极的应用 |
| US10519268B2 (en) * | 2015-10-27 | 2019-12-31 | Jinan Shengquan Group Share Holding Co., Ltd. | Composite polyurethane foam comprising graphene, processes for preparing the same use thereof |
| CN106115675B (zh) * | 2016-06-24 | 2018-04-17 | 中国科学院电工研究所 | 一种制备介孔石墨烯的方法 |
| EP3541184A4 (en) | 2016-11-16 | 2020-05-13 | The Regents of The University of California | IDENTIFICATION AND OPTIMIZATION OF CARBON RADICALS ON HYDRATED GRAPHENE OXIDE FOR OMNIPRESENT ANTIBACTERIAL COATINGS |
| WO2018139979A1 (en) | 2017-01-27 | 2018-08-02 | Oezbek Murat | Performance enhancement material for accumulators |
| ES2928754T3 (es) * | 2017-03-31 | 2022-11-22 | Arcelormittal | Un procedimiento de fabricación de óxido de grafeno a partir de grafito Kish |
| CN109319765B (zh) * | 2017-07-31 | 2022-06-07 | 哈尔滨工业大学 | 生物质燃烧合成石墨烯制备方法及其应用 |
| US11781020B2 (en) * | 2019-08-16 | 2023-10-10 | Ppg Industries Ohio, Inc. | Silica-graphenic carbon composite particles and elastomeric materials including such particles |
| CN111003704B (zh) * | 2019-12-20 | 2021-11-30 | 上海昱瓴新能源科技有限公司 | 一种三维石墨烯锂离子电池超快充负极材料的制备方法及应用 |
| JP7505817B1 (ja) | 2023-04-18 | 2024-06-25 | 株式会社ジョンクェルコンサルティング | 二酸化炭素含有ガスの処理システム、および二酸化炭素含有ガスの処理方法 |
Family Cites Families (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU7092974A (en) | 1973-07-05 | 1976-01-08 | Commw Scient Ind Res Org | Graphite production |
| JPS52111490A (en) | 1976-03-16 | 1977-09-19 | Kobe Steel Ltd | Production of material containing lamellar graphite |
| EP0201696B1 (en) | 1985-03-20 | 1991-03-13 | Sharp Kabushiki Kaisha | Production of carbon films |
| JPH0635325B2 (ja) | 1986-09-22 | 1994-05-11 | 東洋炭素株式会社 | 高純度黒鉛材の製造方法 |
| JPS63139080A (ja) | 1986-11-29 | 1988-06-10 | 工業技術院長 | 黒鉛体およびその製造方法 |
| US5143709A (en) | 1989-06-14 | 1992-09-01 | Temple University | Process for production of graphite flakes and films via low temperature pyrolysis |
| US5149518A (en) | 1989-06-30 | 1992-09-22 | Ucar Carbon Technology Corporation | Ultra-thin pure flexible graphite calendered sheet and method of manufacture |
| US5472749A (en) | 1994-10-27 | 1995-12-05 | Northwestern University | Graphite encapsulated nanophase particles produced by a tungsten arc method |
| JP2002005581A (ja) * | 2000-06-20 | 2002-01-09 | Nkk Corp | Ｃｏ２分解装置 |
| JP2002348110A (ja) | 2001-05-28 | 2002-12-04 | Mitsui Mining Co Ltd | 黒鉛粒子、及びその製造方法 |
| US7097788B2 (en) | 2003-06-30 | 2006-08-29 | The Board Of Trustees Of The University Of Illinois | Conducting inks |
| AU2008314512B2 (en) | 2007-10-19 | 2014-07-24 | University Of Wollongong | Process for the preparation of graphene |
| KR100923304B1 (ko) | 2007-10-29 | 2009-10-23 | 삼성전자주식회사 | 그라펜 시트 및 그의 제조방법 |
| US8349142B2 (en) | 2008-03-26 | 2013-01-08 | Masaru Hori | Method for producing graphene |
| US20100000441A1 (en) * | 2008-07-01 | 2010-01-07 | Jang Bor Z | Nano graphene platelet-based conductive inks |
| US8163205B2 (en) * | 2008-08-12 | 2012-04-24 | The Boeing Company | Durable transparent conductors on polymeric substrates |
| US20100301212A1 (en) | 2009-05-18 | 2010-12-02 | The Regents Of The University Of California | Substrate-free gas-phase synthesis of graphene sheets |
| EP3865454A3 (en) | 2009-05-26 | 2021-11-24 | Belenos Clean Power Holding AG | Stable dispersions of single and multiple graphene layers in solution |
| US20100323113A1 (en) | 2009-06-18 | 2010-12-23 | Ramappa Deepak A | Method to Synthesize Graphene |
| US8236118B2 (en) | 2009-08-07 | 2012-08-07 | Guardian Industries Corp. | Debonding and transfer techniques for hetero-epitaxially grown graphene, and products including the same |
| US10167572B2 (en) | 2009-08-07 | 2019-01-01 | Guardian Glass, LLC | Large area deposition of graphene via hetero-epitaxial growth, and products including the same |
| US8507797B2 (en) | 2009-08-07 | 2013-08-13 | Guardian Industries Corp. | Large area deposition and doping of graphene, and products including the same |
| US8470400B2 (en) | 2009-10-21 | 2013-06-25 | Board Of Regents, The University Of Texas System | Graphene synthesis by chemical vapor deposition |
| US8992807B2 (en) | 2010-01-14 | 2015-03-31 | Samsung Techwin Co., Ltd. | Method of manufacturing deformation-capable graphene sheet, deformation-capable graphene sheet, and device using the same |
| US8377408B2 (en) | 2010-04-20 | 2013-02-19 | High Temperature Physics, Llc | Process for the production of carbon nanoparticles and sequestration of carbon |
| US8420042B2 (en) * | 2010-09-21 | 2013-04-16 | High Temperature Physics, Llc | Process for the production of carbon graphenes and other nanomaterials |
| EP2562766A1 (de) * | 2011-08-22 | 2013-02-27 | Bayer MaterialScience AG | Kohlenstoffnanoröhren und Graphenplättchen umfassende Dispersionen |
| EP2753577B1 (en) | 2011-09-09 | 2019-06-05 | Board Of Trustees Of Northern Illinois University | Method of making crystalline graphene |
-
2011
- 2011-12-06 EP EP11806019.3A patent/EP2753577B1/en not_active Not-in-force
- 2011-12-06 JP JP2014529696A patent/JP2014527950A/ja active Pending
- 2011-12-06 KR KR1020147009253A patent/KR20140092809A/ko not_active Withdrawn
- 2011-12-06 US US14/001,845 patent/US9340430B2/en active Active
- 2011-12-06 CN CN201180073354.3A patent/CN103906706A/zh active Pending
- 2011-12-06 WO PCT/US2011/063548 patent/WO2013036272A1/en not_active Ceased
- 2011-12-07 TW TW100145124A patent/TW201311553A/zh unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9340430B2 (en) | 2011-09-09 | 2016-05-17 | Board Of Trustees Of Northern Illinois University | Crystalline graphene and method of making crystalline graphene |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2753577A1 (en) | 2014-07-16 |
| KR20140092809A (ko) | 2014-07-24 |
| US9340430B2 (en) | 2016-05-17 |
| CN103906706A (zh) | 2014-07-02 |
| US20140193575A1 (en) | 2014-07-10 |
| EP2753577B1 (en) | 2019-06-05 |
| JP2014527950A (ja) | 2014-10-23 |
| WO2013036272A1 (en) | 2013-03-14 |
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