TW201304942A - Manufacturing method of roller used for manufacturing patterned retardation film - Google Patents
Manufacturing method of roller used for manufacturing patterned retardation film Download PDFInfo
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- TW201304942A TW201304942A TW100126474A TW100126474A TW201304942A TW 201304942 A TW201304942 A TW 201304942A TW 100126474 A TW100126474 A TW 100126474A TW 100126474 A TW100126474 A TW 100126474A TW 201304942 A TW201304942 A TW 201304942A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D17/00—Forming single grooves in sheet metal or tubular or hollow articles
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Abstract
Description
本發明是有關於一種滾輪的製造方法,且特別是有關於一種用於製造相位差薄膜之滾輪的製造方法。The present invention relates to a method of manufacturing a roller, and more particularly to a method of manufacturing a roller for manufacturing a retardation film.
隨著顯示科技的進步,發展出一種相位差薄膜。透過相位差薄膜可產生光學上的不同的相位延遲,進而產生立體視覺效果。相位差薄膜可應用於立體顯示眼鏡、立體顯示電視等顯示產品。With the advancement of display technology, a phase difference film has been developed. The phase difference film can produce optically different phase delays, which in turn produces a stereoscopic effect. The phase difference film can be applied to display products such as stereoscopic display glasses and stereoscopic display televisions.
相位差薄膜必須維持在一定程度的精確度,才能確保其光學品質。然而,在精確度的要求下,相位差薄膜的製造速度無法有效提昇。因此,研究人員目前均致力於發展一種工具與方法來快速且精準地製造相位差薄膜,以符合產業界的需求。The retardation film must be maintained to a certain degree of accuracy to ensure its optical quality. However, the manufacturing speed of the retardation film cannot be effectively improved under the requirement of accuracy. Therefore, researchers are currently working on developing a tool and method to quickly and accurately produce retardation films to meet the needs of the industry.
本發明係有關於一種用於製造相位差薄膜之滾輪的製造方法,其利用雕刻工具對滾輪進行雕刻,以使滾輪之表面呈現各種特殊紋路。具有特殊紋路之滾輪進而可快速且精確地以壓印之方式製造出相位差薄膜。The present invention relates to a method of manufacturing a roller for manufacturing a retardation film, which engraves a roller using an engraving tool so that the surface of the roller exhibits various special textures. The roller with special grain can in turn quickly and accurately produce a retardation film by imprinting.
根據本發明之一方面,提出一種用於製造相位差薄膜之滾輪的製造方法。用於製造相位差薄膜之滾輪的製造方法包括以下步驟。提供一滾輪。滾輪具有一轉軸及一滾輪表面。滾輪表面具有一第一端及一相對於第一端的一第二端。提供一雕刻工具。雕刻工具具有一雕刻端,雕刻端具有平行排列之數個微結構。以轉軸為軸心使滾輪以一旋轉速度朝一旋轉方向滾動,同時雕刻工具以一第一深度朝向第二端雕刻一第一距離。雕刻工具於第一距離內雕刻出數個第一刻紋後離開滾輪表面並移動至第二端,以形成一第一雕刻區。以轉軸為軸心使滾輪以旋轉速度朝旋轉方向滾動,同時雕刻工具以一第二深度朝向第一端雕刻一第二距離,雕刻工具於第二距離內雕刻出數個第二刻紋後離開滾輪表面並移動至第一端,以形成一第二雕刻區。According to an aspect of the invention, a method of manufacturing a roller for manufacturing a retardation film is proposed. The manufacturing method of the roller for manufacturing a retardation film includes the following steps. Provide a scroll wheel. The roller has a rotating shaft and a roller surface. The roller surface has a first end and a second end opposite the first end. Provide a carving tool. The engraving tool has an engraved end, and the engraved end has a plurality of microstructures arranged in parallel. The rotating shaft is used as an axis to roll the roller in a rotating direction at a rotational speed, and the engraving tool engraves a first distance toward the second end at a first depth. The engraving tool engraves a plurality of first engravings in a first distance, exits the surface of the roller and moves to the second end to form a first engraving area. Taking the rotating shaft as the axis, the roller is rolled in the rotating direction at the rotating speed, and the engraving tool engraves a second distance toward the first end at a second depth, and the engraving tool engraves a plurality of second engravings in the second distance and leaves The roller surface is moved to the first end to form a second engraved area.
根據本發明之另一方面,提出一種用於製造相位差薄膜之滾輪的製造方法。用於製造相位差薄膜之滾輪的製造方法包括以下步驟。提供一滾輪,滾輪具有一轉軸及一滾輪表面,滾輪表面具有一第一端及一相對於第一端的一第二端。提供一雕刻工具。雕刻工具具有一雕刻端,雕刻端具有平行排列之數個微結構。以轉軸為軸心使滾輪以一旋轉速度朝一第一旋轉方向滾動。同時雕刻工具以一第一深度朝向第二端雕刻一第一距離。雕刻工具於第一距離內雕刻出數個第一刻紋後離開滾輪表面,以形成一第一雕刻區。以轉軸為軸心使滾輪以一旋轉速度朝一相反於第一旋轉方向之一第二旋轉方向滾動,同時雕刻工具於離開滾輪表面移動第一距離後,接近該滾輪表面以一第二深度朝向該第二端雕刻一第二距離。雕刻工具於第二距離內雕刻出數個第二刻紋後離開滾輪表面並移動至第二端,以形成一第二雕刻區。According to another aspect of the present invention, a method of manufacturing a roller for manufacturing a retardation film is proposed. The manufacturing method of the roller for manufacturing a retardation film includes the following steps. A roller is provided. The roller has a rotating shaft and a roller surface. The roller surface has a first end and a second end opposite to the first end. Provide a carving tool. The engraving tool has an engraved end, and the engraved end has a plurality of microstructures arranged in parallel. The roller is pivoted at a rotational speed in a first direction of rotation with the axis of rotation as the axis. At the same time, the engraving tool engraves a first distance toward the second end at a first depth. The engraving tool engraves a plurality of first engravings in a first distance and leaves the surface of the roller to form a first engraving area. Rotating the roller at a rotational speed in a second rotational direction opposite to the first rotational direction with the rotational axis as an axis, and while the engraving tool moves a first distance away from the surface of the roller, approaching the surface of the roller at a second depth toward the axis The second end engraves a second distance. The engraving tool engraves a plurality of second engravings in the second distance and then leaves the roller surface and moves to the second end to form a second engraving area.
為讓本發明之上述內容能更明顯易懂,下文特舉各種較佳實施例,並配合所附圖式,作詳細說明如下:In order to make the above description of the present invention more comprehensible, various preferred embodiments are described below, and in conjunction with the drawings, the detailed description is as follows:
以下係提出實施例進行詳細說明,其利用雕刻工具對滾輪進行雕刻,以使滾輪之表面呈現各種特殊紋路。具有特殊紋路之滾輪進而可快速且精確地以壓印之方式製造出相位差薄膜。然而,實施例僅用以作為範例說明,並不會限縮本發明欲保護之範圍。此外,實施例中之圖式係省略部份元件,以清楚顯示本發明之技術特點。The following is a detailed description of the embodiment, which uses an engraving tool to engrave the roller so that the surface of the roller presents various special lines. The roller with special grain can in turn quickly and accurately produce a retardation film by imprinting. However, the examples are for illustrative purposes only and are not intended to limit the scope of the invention. Further, the drawings in the embodiments are omitted to partially illustrate the technical features of the present invention.
第一實施例First embodiment
請參照第1圖及第2A~2E圖,第1圖繪示第一實施例之用於製造相位差薄膜700(繪示於第3圖)之滾輪100的製造方法的流程圖,第2A~2E圖繪示第1圖之各步驟示意圖。首先,在步驟S110中,如第2A圖所示,提供一滾輪100,滾輪100具有一轉軸100c及一滾輪表面100a,滾輪表面100a具有一第一端E11及一相對於第一端E11的一第二端E12。在尚未雕刻前,滾輪表面100a係為平滑的圓柱型表面,也就是說,沿著轉軸100c之各個直徑100d均相同,且滾輪表面100a任一點至轉軸100c之垂直距離實質上均相等。在本實施例中,滾輪100之材質例如是銅(Cu)。Referring to FIG. 1 and FIGS. 2A-2E, FIG. 1 is a flow chart showing a method of manufacturing the roller 100 for manufacturing the retardation film 700 (shown in FIG. 3) according to the first embodiment, and FIG. 2A 2E is a schematic view showing the steps of the first figure. First, in step S110, as shown in FIG. 2A, a roller 100 is provided. The roller 100 has a rotating shaft 100c and a roller surface 100a. The roller surface 100a has a first end E11 and a first end E11. Second end E12. Before the engraving has been performed, the roller surface 100a is a smooth cylindrical surface, that is, each diameter 100d along the rotation axis 100c is the same, and the vertical distance from any point of the roller surface 100a to the rotation axis 100c is substantially equal. In the present embodiment, the material of the roller 100 is, for example, copper (Cu).
接著,在步驟S120中,如第2B圖所示,提供一雕刻工具900,雕刻工具900具有一雕刻端910。雕刻端910具有平行排列之數個微結構911。雕刻工具900之硬度大於滾輪100,其材質例如是鑽石。微結構911之寬度W911與間距D911實質上相同。Next, in step S120, as shown in FIG. 2B, an engraving tool 900 is provided, the engraving tool 900 having an engraving end 910. The engraved end 910 has a plurality of microstructures 911 arranged in parallel. The engraving tool 900 has a hardness greater than that of the roller 100 and is made of, for example, a diamond. The width W911 of the microstructure 911 is substantially the same as the pitch D911.
然後,在步驟S130中,如第2C圖所示,以轉軸100c為軸心使滾輪100以一旋轉速度朝一旋轉方向C11滾動,同時雕刻工具900以一第一深度D11(標示於第2E圖,其中第2E圖之虛線表示為雕刻前之滾輪表面100a)朝向滾輪100之第二端E12雕刻一第一距離L11。雕刻工具900於第一距離L11內雕刻出數個第一刻紋111後離開滾輪表面100a並移動至第二端E12,在滾輪表面100a上形成一第一雕刻區110。Then, in step S130, as shown in FIG. 2C, the roller 100 is rotated at a rotational speed toward a rotational direction C11 with the rotational axis 100c as an axis, and the engraving tool 900 is at a first depth D11 (indicated in FIG. 2E, The broken line in FIG. 2E indicates that the roller surface 100a before engraving is engraved with a first distance L11 toward the second end E12 of the roller 100. The engraving tool 900 engraves a plurality of first engravings 111 in the first distance L11 and then leaves the roller surface 100a and moves to the second end E12 to form a first engraving area 110 on the roller surface 100a.
在步驟S130中,第一深度D11係介於5微米至10微米之間,旋轉速度係介於1 rpm至300 rpm之間,雕刻工具900之移動速度則介於10 mm/min至20000 mm/min之間。雕刻工具900之作動可以由一快刀伺服(Fast-tool-servo)系統所控制。In step S130, the first depth D11 is between 5 micrometers and 10 micrometers, the rotational speed is between 1 rpm and 300 rpm, and the engraving tool 900 is moving between 10 mm/min and 20000 mm/ Between min. The actuation of the engraving tool 900 can be controlled by a Fast-tool-servo system.
請參照第2D圖,重複執行步驟S130,以在滾輪表面100a上形成數個第一雕刻區110。此些第一雕刻區110之組合形成環狀結構。Referring to FIG. 2D, step S130 is repeatedly performed to form a plurality of first engraving regions 110 on the roller surface 100a. The combination of the first engraved regions 110 forms a ring structure.
接著,在步驟S140,如第2D圖所示,以轉軸100c為軸心使滾輪100以前述旋轉速度朝旋轉方向C11滾動,同時雕刻工具900以一第二深度D12(標示於第2E圖,其中第2E圖之虛線表示為雕刻前之滾輪表面100a)朝向滾輪100之第一端E11雕刻一第二距離L12,雕刻工具900於第二距離L12內雕刻出數個第二刻紋121後離開滾輪表面100a並移動至第一端E11,形成一第二雕刻區120。Next, in step S140, as shown in FIG. 2D, the roller 100 is rotated at the aforementioned rotational speed toward the rotational direction C11 with the rotational axis 100c as an axis, and the engraving tool 900 is at a second depth D12 (indicated in FIG. 2E, wherein The dashed line in FIG. 2E indicates that the roller surface 100a before engraving is engraved with a second distance L12 toward the first end E11 of the roller 100. The engraving tool 900 engraves a plurality of second engravings 121 in the second distance L12 and then leaves the roller. The surface 100a is moved to the first end E11 to form a second engraving area 120.
在步驟S140中,第二深度D12係介於0.1微米至10微米之間,旋轉速度係介於1 rpm至300 rpm之間,雕刻工具900之移動速度則介於10 mm/min至20000 mm/min之間。雕刻工具900之作動可以由快刀伺服(Fast-tool-servo)系統所控制。In step S140, the second depth D12 is between 0.1 micrometers and 10 micrometers, the rotational speed is between 1 rpm and 300 rpm, and the engraving tool 900 is moved from 10 mm/min to 20000 mm/ Between min. The actuation of the engraving tool 900 can be controlled by a Fast-tool-servo system.
請參照第2E圖,重複執行步驟S140,以在滾輪表面100a上形成數個第二雕刻區120。此些第二雕刻區120之組合形成數個環狀結構。此外,本實施例之第一深度D11小於第二深度D12,第一深度D11與第二深度D12之差小於2微米。因此,第一刻紋111之高度大於第二刻紋121的高度。在其他實施例中,第一深度D11與第二深度D12亦可相等;或者,第一深度D11亦可大於第二深度D12。Referring to FIG. 2E, step S140 is repeatedly performed to form a plurality of second engraving regions 120 on the roller surface 100a. The combination of these second engraving zones 120 forms a plurality of annular structures. In addition, the first depth D11 of the embodiment is smaller than the second depth D12, and the difference between the first depth D11 and the second depth D12 is less than 2 micrometers. Therefore, the height of the first scribe 111 is greater than the height of the second scribe 121. In other embodiments, the first depth D11 and the second depth D12 may also be equal; or the first depth D11 may be greater than the second depth D12.
上述步驟S130、步驟S140重複在滾輪表面100a上形成第一雕刻區110及第二雕刻區120,使滾輪表面100a布滿此些第一雕刻區110及此些第二雕刻區120。此些第一雕刻區110及此些第二雕刻區120之組合係為一柵狀帶形結構且此些第一雕刻區110與此些第二雕刻區120彼此互相平行交錯。The step S130 and the step S140 are repeated to form the first engraving area 110 and the second engraving area 120 on the roller surface 100a, so that the roller surface 100a fills the first engraving area 110 and the second engraving area 120. The combination of the first engraving area 110 and the second engraving areas 120 is a grid-like strip structure and the first engraving areas 110 and the second engraving areas 120 are parallel to each other.
請參照第3圖,其繪示採用第一實施例之滾輪100所製造之相位差薄膜700的分解示意圖。採用此滾輪100於一含有可壓印樹脂層之基材701壓印相位差圖案710,第一刻紋111所轉印的第一薄膜紋路711位於較低之位置,第二刻紋121所轉印成的第二薄膜紋路721位較高之位置,在此相位差圖案710上塗覆可聚合液晶層720後,可形成具有相位差效果的相位差膜700。Referring to FIG. 3, an exploded perspective view of the retardation film 700 manufactured by the roller 100 of the first embodiment is shown. The roller 100 is used to imprint a phase difference pattern 710 on a substrate 701 containing an embossable resin layer. The first film line 711 transferred by the first pattern 111 is located at a lower position, and the second pattern 121 is rotated. The printed second film line 721 has a higher position, and after the polymerizable liquid crystal layer 720 is coated on the phase difference pattern 710, the phase difference film 700 having a phase difference effect can be formed.
第二實施例Second embodiment
請參照第4圖及第5A~5E圖,第4圖繪示第二實施例之用於製造相位差薄膜700(繪示於第3圖)之滾輪200的製造方法的流程圖,第5A~5E圖繪示第4圖之各步驟的示意圖。本實施例之用於製造相位差薄膜700之滾輪200的製造方法與第一實施例之用於製造相位差薄膜700之滾輪100的製造方法不同之處在於雕刻之步驟S230、S240,其餘相同之處不再重複敘述。Referring to FIG. 4 and FIGS. 5A-5E, FIG. 4 is a flow chart showing a method of manufacturing the roller 200 for manufacturing the retardation film 700 (shown in FIG. 3) according to the second embodiment, and FIG. 5A~ Figure 5E shows a schematic diagram of the steps of Figure 4. The manufacturing method of the roller 200 for manufacturing the retardation film 700 of the present embodiment is different from the manufacturing method of the roller 100 for manufacturing the retardation film 700 of the first embodiment in steps S230 and S240 of engraving, and the rest are the same. The description will not be repeated.
在步驟S110~S120之後,進入步驟S230。如第5C圖所示,以轉軸200c為軸心使滾輪200以一旋轉速度朝一第一旋轉方向C21滾動,同時雕刻工具900以一第一深度D21(繪示於第5E圖,其中第5E圖之虛線表示為雕刻前之滾輪表面200a)朝向滾輪200之第二端雕刻一第一距離L21,雕刻工具900於第一距離L21內雕刻出數個第一刻紋211後離開滾輪表面200a,形成一第一雕刻區210。After steps S110 to S120, the process proceeds to step S230. As shown in FIG. 5C, the roller 200 is pivoted at a rotational speed toward a first rotational direction C21 with the rotational axis 200c as an axis, and the engraving tool 900 is at a first depth D21 (shown in FIG. 5E, wherein FIG. 5E The dashed line indicates that the roller surface 200a before engraving is engraved with a first distance L21 toward the second end of the roller 200. The engraving tool 900 engraves a plurality of first engravings 211 in the first distance L21 and leaves the roller surface 200a. A first engraving area 210.
接著,在步驟S240中,以轉軸200c為軸心使滾輪200以相同於步驟S130之旋轉速度朝一相反於第一旋轉方向C21之一第二旋轉方向C22滾動,同時雕刻工具900以一第二深度D12朝向第二端E22雕刻一第二距離L22,雕刻工具900於第二距離L22內雕刻出數個第二刻紋221後離開滾輪表面200a並移動至第二端E22,形成一第二雕刻區220。Next, in step S240, the roller 200 is rotated with the rotation axis 200c as a rotation direction of the step S130 toward a second rotation direction C22 opposite to the first rotation direction C21, while the engraving tool 900 is at a second depth. D12 engraves a second distance L22 toward the second end E22. The engraving tool 900 engraves a plurality of second engravings 221 in the second distance L22 and then leaves the roller surface 200a and moves to the second end E22 to form a second engraving area. 220.
如第2C、2D圖所示,在第一實施例之步驟S130與步驟S140中,滾輪100係採用相同的旋轉方向C11,但雕刻工具900採用不同的移動方向。如第5C、5D圖所示,在第二實施例之步驟S230與步驟S240中,滾輪200則採用不同的第一旋轉方向C21與第二旋轉方向C22,但雕刻工具900採用相同的移動方向。如第2E圖及第5E圖所示,上述兩種實施例的作法都可導致相同的結果。As shown in FIGS. 2C and 2D, in steps S130 and S140 of the first embodiment, the roller 100 adopts the same rotational direction C11, but the engraving tool 900 adopts different moving directions. As shown in FIGS. 5C and 5D, in steps S230 and S240 of the second embodiment, the roller 200 adopts different first rotation directions C21 and second rotation directions C22, but the engraving tool 900 adopts the same movement direction. As shown in Figures 2E and 5E, the above two embodiments can all lead to the same result.
本發明上述實施例所揭露之用於製造相位差薄膜之滾輪的製造方法係利用雕刻工具對滾輪進行雕刻,以使滾輪之表面呈現各種特殊紋路。具有特殊紋路之滾輪進而可快速且精確地以壓印之方式製造出相位差薄膜。The manufacturing method of the roller for manufacturing a phase difference film disclosed in the above embodiment of the present invention engraves the roller by using an engraving tool so that the surface of the roller presents various special lines. The roller with special grain can in turn quickly and accurately produce a retardation film by imprinting.
綜上所述,雖然本發明已以各種較佳實施例揭露如上,然其並非用以限定本發明。本發明所屬技術領域中具有通常知識者,在不脫離本發明之精神和範圍內,當可作各種之更動與潤飾。因此,本發明之保護範圍當視後附之申請專利範圍所界定者為準。In the above, the present invention has been disclosed in the above preferred embodiments, and is not intended to limit the invention. A person skilled in the art can make various changes and modifications without departing from the spirit and scope of the invention. Therefore, the scope of the invention is defined by the scope of the appended claims.
100、200...滾輪100, 200. . . Wheel
100a、200a...滾輪表面100a, 200a. . . Roller surface
100c、200c...轉軸100c, 200c. . . Rotating shaft
110、210...第一雕刻區110, 210. . . First engraving area
111、211...第一刻紋111, 211. . . First engraving
120、220...第二雕刻區120, 220. . . Second engraving area
121、221...第二刻紋121, 221. . . Second engraving
700...相位差薄膜700. . . Phase difference film
701...基材701. . . Substrate
710...相位差圖案710. . . Phase difference pattern
711...第一薄膜紋路711. . . First film texture
721...第二薄膜紋路721. . . Second film texture
900...雕刻工具900. . . Sculpting tool
911...微結構911. . . microstructure
C11...旋轉方向C11. . . turn around
C21...第一旋轉方向C21. . . First direction of rotation
C22...第二旋轉方向C22. . . Second direction of rotation
D11、D21...第一深度D11, D21. . . First depth
D12、D22...第二深度D12, D22. . . Second depth
D911...間距D911. . . spacing
E11、E21...第一端E11, E21. . . First end
E12、E22...第二端E12, E22. . . Second end
L11、L21...第一距離L11, L21. . . First distance
L12、L22...第二距離L12, L22. . . Second distance
S110~S140、S230~S240...流程步驟S110~S140, S230~S240. . . Process step
W911...寬度W911. . . width
第1圖繪示第一實施例之用於製造相位差薄膜之滾輪的製造方法的流程圖。Fig. 1 is a flow chart showing a method of manufacturing a roller for manufacturing a retardation film of the first embodiment.
第2A~2E圖繪示第1圖之各步驟示意圖。2A-2E are schematic views showing the steps of the first figure.
第3圖繪示採用第一實施例之滾輪所製造之相位差薄膜的分解示意圖。Fig. 3 is a schematic exploded view showing the phase difference film manufactured by the roller of the first embodiment.
第4圖繪示第二實施例之用於製造相位差薄膜之滾輪的製造方法的流程圖。Fig. 4 is a flow chart showing the manufacturing method of the roller for manufacturing a retardation film of the second embodiment.
第5A~5E圖繪示第4圖之各步驟的示意圖。5A-5E are schematic views showing the steps of FIG. 4.
S110~S140...流程步驟S110~S140. . . Process step
Claims (12)
Priority Applications (2)
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TW100126474A TWI458623B (en) | 2011-07-26 | 2011-07-26 | Manufacturing method of roller used for manufacturing patterned retardation film |
US13/557,228 US20130025342A1 (en) | 2011-07-26 | 2012-07-25 | Manufacturing method of roller for manufacturing patterned retarder film |
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TW100126474A TWI458623B (en) | 2011-07-26 | 2011-07-26 | Manufacturing method of roller used for manufacturing patterned retardation film |
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TW201304942A true TW201304942A (en) | 2013-02-01 |
TWI458623B TWI458623B (en) | 2014-11-01 |
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US10031183B2 (en) * | 2013-03-07 | 2018-07-24 | Rai Strategic Holdings, Inc. | Spent cartridge detection method and system for an electronic smoking article |
US9220302B2 (en) * | 2013-03-15 | 2015-12-29 | R.J. Reynolds Tobacco Company | Cartridge for an aerosol delivery device and method for assembling a cartridge for a smoking article |
CN107363153A (en) * | 2017-08-17 | 2017-11-21 | 安徽开诚电器有限公司 | Knurling mould |
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US5946991A (en) * | 1997-09-03 | 1999-09-07 | 3M Innovative Properties Company | Method for knurling a workpiece |
US20040045419A1 (en) * | 2002-09-10 | 2004-03-11 | Bryan William J. | Multi-diamond cutting tool assembly for creating microreplication tools |
JP4887025B2 (en) * | 2005-10-27 | 2012-02-29 | パナソニック株式会社 | Mold manufacturing method and optical element manufacturing method |
US20080032096A1 (en) * | 2006-08-07 | 2008-02-07 | Eastman Kodak Company | Microstructured film containing polysulfone polymer |
TW200920521A (en) * | 2007-04-05 | 2009-05-16 | Toshiba Machine Co Ltd | Method and apparatus for machining surface of roll |
CN101835597B (en) * | 2007-09-21 | 2013-05-22 | 3M创新有限公司 | Optical film |
US20090163307A1 (en) * | 2007-12-19 | 2009-06-25 | Fujii Kinzoku Kako Co., Ltd. | Bat for baseball or softball and manufacturing method thereof |
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TWI458623B (en) | 2014-11-01 |
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