TW201249980A - Nontoxic alcohol (ethanol) paste - Google Patents

Nontoxic alcohol (ethanol) paste Download PDF

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Publication number
TW201249980A
TW201249980A TW100120373A TW100120373A TW201249980A TW 201249980 A TW201249980 A TW 201249980A TW 100120373 A TW100120373 A TW 100120373A TW 100120373 A TW100120373 A TW 100120373A TW 201249980 A TW201249980 A TW 201249980A
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Taiwan
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alcohol
ethanol
paste
component
industrial
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TW100120373A
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Chinese (zh)
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kai-xiong Cai
Jian-Li Li
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kai-xiong Cai
Jian-Li Li
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Priority to TW100120373A priority Critical patent/TW201249980A/en
Priority to CN2012101034152A priority patent/CN102816622A/en
Publication of TW201249980A publication Critical patent/TW201249980A/en

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  • Jellies, Jams, And Syrups (AREA)
  • Bakery Products And Manufacturing Methods Therefor (AREA)
  • Cosmetics (AREA)
  • Food Preservation Except Freezing, Refrigeration, And Drying (AREA)

Abstract

A nontoxic alcohol (ethanol) paste comprises an alcohol (ethanol) component, a thickener component and the water. The alcohol (ethanol) component accounts for 18 wt% to 100 wt% based on the total weight. Thus, during the combustion of the alcohol (ethanol) component, the nontoxic alcohol (ethanol) paste can produce a high heat value. In addition, the alcohol (ethanol) has lower toxicity when being compared with the methanol (industrial alcohol) and does not produce the ingredient harmful to users easily to thereby ensure safety.

Description

201249980 六、發明說明: 【發明所屬之技術領域】 本發明是有關於一種酒精膏,特別是指一種無毒性酒 精(乙醇)膏。 【先前技術】 習知的酒精膏(工業酒精膏)是由曱醇(工業酒精)、濃铜 劑組份與水製成,其中甲醇(工業酒精)來自於石化原料煉製 ’且具有毒性,長期吸入或接觸會有致癌的危險,再者, 該酒精τ (工業酒精膏)燃燒不完全時,其燃燒後的廢氣可能 會產生甲醛,甲醛是無色易溶的刺激性氣體,可經呼吸道 吸收,進入人體的曱醛能和蛋白質的胺基結合,擾亂人體 細胞的代謝,對細胞有破壞作用,甲醛已被國際癌症研究 機構(IARC 1995)確定為可疑致癌物,因此,對於長期接 觸該酒精膏(工業酒精膏)的工作者或消費者造成了安全上的 危害。 中華民國消費者文教基金會曾對市售的14件酒精膏(工 業酒精膏)進行抽查’發現14件酒精膏(Jlf酒精膏)樣品中 的甲醇(工業酒精)含量皆超過5〇wt%(消費者報導雜諸201249980 VI. Description of the Invention: [Technical Field of the Invention] The present invention relates to an alcohol cream, and more particularly to a non-toxic alcohol (ethanol) paste. [Prior Art] The conventional alcohol cream (industrial alcohol paste) is made of sterol (industrial alcohol), a concentrated copper component and water, wherein methanol (industrial alcohol) is derived from petrochemical raw material refining and is toxic. Long-term inhalation or contact may cause cancer. In addition, when the alcohol τ (industrial alcohol cream) is not completely burned, the burned exhaust gas may produce formaldehyde. Formaldehyde is a colorless and irritating irritating gas that can be absorbed through the respiratory tract. The furfural that enters the human body can bind to the amine group of the protein, disturb the metabolism of the human cells, and has a destructive effect on the cells. Formaldehyde has been identified as a suspected carcinogen by the International Agency for Research on Cancer (IARC 1995). Therefore, for long-term exposure to the alcohol Workers or consumers of pastes (industrial alcohol creams) pose a safety hazard. The Consumers’ Culture and Education Foundation of the Republic of China conducted a spot check on 14 commercially available alcohol creams (industrial alcohol creams) and found that the content of methanol (industrial alcohol) in 14 samples of alcoholic cream (Jlf alcoholic paste) exceeded 5〇wt% ( Consumer reports

No.358,100年2月),除了顯·古隹%社立 ” ⑴除了顯不市售酒精膏(工業酒精膏)在 使用上有較高的危險外’還顯示該酒精#(卫業酒精幻的整 體燃燒熱值偏低’導致礙商藉由增加甲醇(工業酒精)的含量 以獲得較高的熱值表現。 為了降低該酒精膏(工章洒挤者、由& 精膏)中的Ψ醇(工業酒精)含 重所帶來的危險,該酒精膏( "(業酒精膏)中必須添加50wt% 201249980 以^的水,而水會吸收部分該酒精膏(工業酒精膏)燃燒時的 熱量,反而導致該酒精膏(工業酒精膏)的整體熱值不高,因 此,無法兼顧安全性與高熱值,所以該酒精膏(工業酒精膏) 的用途僅具有保溫的作用而已。 另方面該/酉精膏(工業酒精膏)中的濃稍劑組份多為 經丙基甲基纖維素(hydroxypropyl methylcellul〇se,MC)' 緩 甲基纖維素納(caroxy methyl cllulose sodium’ CMC)' 經+乙 基纖維素(hydroxy ethyl ceUui〇se,HEC)、乙基纖維素 cellulose,EC)、果膠、阿拉伯膠或pvA等高分子(p〇iymer) ,若燃燒不完全亦會釋放對人體有害的物質,所以,開發 不同的酒精膏組成仍存在一大需求。 【發明内容】 因此,本發明的目的,即在提供一種具有高熱值且安 全的無毒性酒精(乙醇)膏。 於是,本發明無毒性酒精(乙醇)膏,包含: 一酒精(乙醇)組份、一濃稠劑組份,及水,該酒精(乙 醇)組份以全部總重計介於18wt〇/1〇〇wt%之間。 本發明的功效在於:利用燃燒該酒精(乙醇)組份時,使 該無毒性酒精(乙醇)膏可產生高熱值的效果,並藉由該酒精 (乙醇)組份相較於曱醇(工業酒精)毒性低,不易產生對使用 者有害的成分,而具有安全的效果。 【實施方式】 有關本發明的前述及其他技術内容、特點與功效,在 以下配合參考圖式的一個較佳實施例的詳細說明中,將可 201249980 清楚的呈現。 本發明無毋性酒精(乙醇)膏的較佳實施例包含一酒精( 乙醇)組份、一濃稠劑組份,及水,該酒精(乙醇)組份以全 部總重計介於1 8wt%〜1 〇〇wt°/。之間。 由於燃燒每一公克的該酒精(乙醇)組份可產生的熱值為 6400卡,比燃燒每一公克的甲醇(工業酒精)可產生的熱值 4800卡高,因此,燃燒該較佳實施例的該酒精(乙醇)組份時 了產生尚熱值的效果,且該酒精(乙酵)組份相較於甲醇( 工業酒精)毒性低,不易產生對使用者有害的成分。值得一 提的是,以較高含量的該酒精(乙醇)組份所製成的該較佳實 施例,可以減少該酒精(乙醇)組份產生的熱值耗損在水的吸 熱反應上,可進一步保有高熱值的表現。 較佳地’該濃稠劑組份是選自於羥丙基甲基纖維素、 羧曱基纖維素鈉、羥乙基纖維素、乙基纖維素、果膠、阿 拉伯膠、糊精、硬酯酸鈉、海藻酸鈉、羥丙基甲基纖維素 與乙基纖維素混合物或羥乙基纖維素與乙基纖維素混合物 藉此,由天然物取得的該濃稠劑組份混合該酒精(乙醇)組 伤可減少該較佳實施例劇烈的燃燒,而獲得穩定且較長 的燃燒時間,並增加該較佳實施例的安全性。 較佳地,該酒精(乙醇)組份為生質酒精(乙醇),藉由, 十年前全面開放酒牌,使生質酒精(乙醇)的來源可更廣泛, 且該較佳實施例的成本也可進一步降低,而不用受限於僅 來自於石化原料煉製。 選擇性地,該較佳實施例還包含一食用色素,藉此,No.358, February, 2006), in addition to the display of the ancient 隹 社 社 ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( The low overall calorific value of the alcohol's illusion has caused the quotient to increase the methanol (industrial alcohol) content to obtain higher calorific value performance. In order to reduce the alcohol cream (industry sprinkler, by & fine cream) The sterol (industrial alcohol) contains the danger of heavy weight. In the alcohol paste, 50wt% of 201249980 must be added to the water, and the water will absorb part of the alcohol paste (industrial alcohol cream). The heat during burning causes the overall calorific value of the alcohol paste (industrial alcohol paste) to be low. Therefore, the safety and high calorific value cannot be balanced. Therefore, the use of the alcohol paste (industrial alcohol paste) only has the effect of heat preservation. On the other hand, the concentration component of the ointment (industrial alcohol cream) is mostly hydroxypropyl methylcellul〇se (MC)'s caroxy methyl cllulose sodium. CMC) '+ethylcellulose Hydroxy ethyl ceUui〇se, HEC), ethyl cellulose, EC), pectin, gum arabic or pvA (p〇iymer), if it is not completely burned, it will release harmful substances, so develop There is still a great demand for different alcohol paste compositions. SUMMARY OF THE INVENTION Accordingly, it is an object of the present invention to provide a non-toxic alcohol (ethanol) paste having a high calorific value and safety. Thus, the present invention is non-toxic alcohol (ethanol). The paste comprises: an alcohol (ethanol) component, a thickener component, and water, the alcohol (ethanol) component being between 18 wt 〇 / 1 〇〇 wt% based on the total weight. The effect is that when the alcohol (ethanol) component is burned, the non-toxic alcohol (ethanol) paste can produce a high calorific value, and the alcohol (ethanol) component is more toxic than the sterol (industrial alcohol). The invention has the following advantages: In the detailed description of the examples, it will be clearly shown in 201249980. A preferred embodiment of the non-steroidal alcohol (ethanol) paste of the present invention comprises an alcohol (ethanol) component, a thickener component, and water, the alcohol ( The ethanol) component is between 18% by weight and 1% by weight of total weight. Since burning the alcohol (ethanol) component per gram can produce a calorific value of 6,400 calories, compared to combustion per One gram of methanol (industrial alcohol) can produce a calorific value of 4,800 calories, so that when the alcohol (ethanol) component of the preferred embodiment is burned, the calorific value is produced, and the alcohol (ethyl yeast) group The fraction is less toxic than methanol (industrial alcohol) and is less prone to harmful components to the user. It is worth mentioning that the preferred embodiment made of the higher content of the alcohol (ethanol) component can reduce the calorific value of the alcohol (ethanol) component in the endothermic reaction of water. Further maintain the performance of high calorific value. Preferably, the thickener component is selected from the group consisting of hydroxypropylmethylcellulose, sodium carboxymethylcellulose, hydroxyethylcellulose, ethylcellulose, pectin, acacia, dextrin, hard Sodium sulphate, sodium alginate, a mixture of hydroxypropylmethylcellulose and ethylcellulose or a mixture of hydroxyethylcellulose and ethylcellulose whereby the thickener component obtained from the natural product is mixed with the alcohol The (ethanol) group injury can reduce the violent combustion of the preferred embodiment, resulting in a stable and longer burn time and increasing the safety of the preferred embodiment. Preferably, the alcohol (ethanol) component is bio-alcohol (ethanol), and the source of bio-alcohol (ethanol) can be more widely obtained by fully opening the liquor licence ten years ago, and the preferred embodiment The cost can be further reduced without being limited to refining from petrochemical feedstock only. Optionally, the preferred embodiment further comprises a food coloring agent whereby

S 5 201249980 可與般有毒的酒精膏(工業酒精膏)做出區別,並可在取用 含有顏色的該無毒性酒精(乙醇)膏時,能讓使用者方便確認 存量或取用量。 該較佳實施例可以下列製法製得: (a) 取水與該濃稠劑組份混合均勻,以形成一膏體;及 (b) 取該酒精(乙醇)組份與該膏體混合,並以國際標準篩 目的f帛網過篩,以獲得均勻的該無毒性酒精(乙醇)膏,該無 毒·性酒精(乙醇)膏中的該酒精(乙醇)組份以全部總重計介於 18wt% 〜l〇〇wt%之間。 以下分別透過下列具體例進一步說明本發明無毒性酒 精(乙醇)膏的燃燒熱值效果。 - &lt;比較例&gt;酒精膏(工業酒精膏)燃燒熱值 在環境25°C,一大氣壓,取一般的酒精膏(工業酒精膏 :_5〇wt%甲醇(工業酒精)+ 5〇wt%膏體,購自一般的化工原 料行)’其中該T體疋由水與MC混《合而成,MC的用量以 水的總重計為0.3wt%。 用每分鐘燃燒lcc的速度供給該酒精膏(工業酒精膏), 以加熱500cc的純水至100它。紀錄加熱時間需15分47 秒。 &lt;具體例1&gt; 取9.5g的水與〇.5g的海藻酸鈉混合均勻,以形成—膏 體,再取40g的生質酒精(乙醇)倒入該膏體中攪拌均勻,最 後再以國際標準篩目150mesh的篩網過篩,以獲得均勻的 該較佳實施例,該較佳實施例中的該酒精(乙醇)組份以全部 201249980 總重計為80wt%。 以該〈比較例&gt;相同的方法加熱純水,主要的不同處在 於:是取&lt;具額1&gt;的該較佳實施例進行燃燒。紀錄加執 時間需7分18秒,藉此,〈具體例卜的該較佳實施例其所 需加熱時間僅為該比較例的酒精膏(工業酒精膏)的一半左 右,顯示本較佳實施例確實能產生高熱值且安全的效果。 &lt;具鱧例2&gt; 取16g的水與0.4g的海藻酸鈉混合均勻,以形成一膏 體,再取3.6g的一般酒精(乙醇)倒入該膏體中攪拌均勻, 最後再以國際標準篩目1 〇〇mesh的篩網過篩,以獲得均勻 的該較佳實施例,該較佳實施例中的該酒精(乙醇)組份以全 部總重計為18wt%。 用每分鐘燃燒1CC的速度供給該酒精(乙醇)組份為 18wt%的該較佳實施例,以加熱25〇cc的純水至ι〇(Γ(:。紀 錄加熱時間需16分,顯示該較佳實施例的酒精(乙醇)組份 含罝較低時也可產生加熱的作用。進一步地,本發明無毒 性酒精(乙醇)膏可以由民間製造且未經分餾濃縮的生質酒 精(乙醇)製品直接製得,而產生方便生產、降低成本且安 全性高的效果。 歸納上述,本發明無毒性酒精(乙醇)膏,可獲致下述的 功效及優點’故能達到本發明的目的: 一、本發明藉由燃燒該酒精(乙醇)組份時,因燃燒每一 公克的該酒精(乙醇)組份可產生的熱值比燃燒每一公克的甲 醇(工業酒精)可產生的熱值高,而產生高熱值的效果。 7 201249980 二、本發明利用該酒精(乙醇)組份相較於甲醇(工業酒 精)毒性低,不易產生對使用者有害的成分,而具有安全的 效果。 、 二本發明藉由該酒精(乙醇)組份為生質酒精(乙醇), 使來源可更廣泛,且成本也可進一步降低。 四、本發明利用由天然物取得的該濃稠劑組份混合該 酒精(乙醇)組份,可減少該較佳實施例劇烈的燃燒,而獲得 穩定且較長的燃燒時間,並具有安全的效果。 惟以上所述者,僅為本發明的較佳實施例而已,當不 月b以此限疋本發明實施的範圍,即大凡依本發明申請專利 範圍及發明說明内容所作的簡單的等效變化與修飾,皆仍 屬本發明專利涵蓋的範圍内。 【圖式簡單說明】 201249980 【主要元件符號說明】S 5 201249980 can be distinguished from a typical toxic alcohol cream (industrial alcohol paste) and can be easily confirmed by the user when the non-toxic alcohol (ethanol) paste containing color is used. The preferred embodiment can be prepared by the following processes: (a) mixing water with the thickener component to form a paste; and (b) mixing the alcohol (ethanol) component with the paste, and Screening with an international standard sieve to obtain a uniform non-toxic alcohol (ethanol) paste. The alcohol (ethanol) component of the non-toxic alcoholic alcohol (ethanol) paste is 18 wt% of total weight. Between % and l〇〇wt%. Hereinafter, the combustion calorific value effect of the non-toxic alcohol (ethanol) paste of the present invention will be further explained by the following specific examples. - &lt;Comparative Example&gt; Alcohol cream (industrial alcohol paste) combustion calorific value in the environment at 25 ° C, atmospheric pressure, take a general alcohol paste (industrial alcohol paste: _5 〇 wt% methanol (industrial alcohol) + 5 〇 wt% Paste, purchased from general chemical raw materials) 'The T body is made up of water and MC mixed, and the amount of MC is 0.3% by weight based on the total weight of water. The alcohol paste (industrial alcohol paste) was supplied at a rate of 1 cc per minute to heat 500 cc of pure water to 100 liters. The recording heating time takes 15 minutes and 47 seconds. &lt;Specific Example 1&gt; 9.5 g of water and 〇. 5 g of sodium alginate were uniformly mixed to form a paste, and 40 g of bio-alcohol (ethanol) was poured into the paste to be evenly stirred, and finally An international standard mesh 150 mesh screen was screened to obtain a uniform preferred embodiment. The alcohol (ethanol) component of the preferred embodiment was 80 wt% based on the total weight of 201249980. The pure water was heated in the same manner as in the <Comparative Example>, and the main difference was that the preferred embodiment of the &lt;1&gt; was burned. The record addition time takes 7 minutes and 18 seconds, whereby the preferred embodiment of the specific example requires only about half of the heating time of the alcohol paste (industrial alcohol paste) of the comparative example, indicating that the preferred embodiment is implemented. The example does produce a high calorific value and is safe. &lt;Example 2&gt; 16 g of water is mixed with 0.4 g of sodium alginate to form a paste, and then 3.6 g of general alcohol (ethanol) is poured into the paste and stirred uniformly, and finally internationally. The sieve of a standard mesh 1 mesh was sieved to obtain a uniform preferred embodiment, and the alcohol (ethanol) component in the preferred embodiment was 18% by weight based on the total weight. The preferred embodiment was supplied with 18 wt% of the alcohol (ethanol) component at a rate of 1 cc per minute to heat 25 cc of pure water to 〇 (: (recording heating time required 16 minutes, indicating The alcohol (ethanol) component of the preferred embodiment may also have a heating effect when the cerium content is low. Further, the non-toxic alcohol (ethanol) paste of the present invention can be produced by the folk and is not fractionated and concentrated. The product is directly produced, and has the effect of facilitating production, reducing cost, and high safety. In summary, the non-toxic alcohol (ethanol) paste of the present invention can attain the following effects and advantages, so that the object of the present invention can be achieved: 1. In the present invention, by burning the alcohol (ethanol) component, the calorific value that can be produced by burning each kilogram of the alcohol (ethanol) component is greater than the calorific value that can be produced by burning each kilogram of methanol (industrial alcohol). High, and produces a high calorific value. 7 201249980 2. The present invention utilizes the alcohol (ethanol) component to be less toxic than methanol (industrial alcohol), and is less prone to harmful components to the user, and has an The effect of the invention is that the alcohol (ethanol) component is bio-alcohol (ethanol), the source can be more widely, and the cost can be further reduced. 4. The present invention utilizes the thickening obtained from natural products. Mixing the alcohol (ethanol) component of the agent component can reduce the violent combustion of the preferred embodiment, thereby obtaining a stable and long burning time and having a safe effect. However, the above is only the present invention. The preferred embodiment is not limited to the scope of the present invention, and the simple equivalent changes and modifications made by the present invention in the scope of the invention and the description of the invention are still covered by the present invention. In the range. [Simple description of the drawing] 201249980 [Description of main component symbols]

Claims (1)

201249980 七、申請專利範圍: 1. 一種無毒性酒精(乙醇)膏,包含: 一酒精(乙醇)組份、一濃稠劑組份’及水,該酒精( 乙醇)組份以全部總重計介於18wt%〜1 〇〇wt%之間。 2. 根據申明專利範圍第1項所述的無毒性酒精(乙醇)膏, 其中,該濃稠劑組份是選自於羥丙基曱基纖維素、羧曱 基纖維素鈉、羥乙基纖維素、乙基纖維素、果膠、阿拉 伯膠、糊精、硬酯酸鈉、海藻酸鈉、羥丙基甲基纖維音201249980 VII. Patent application scope: 1. A non-toxic alcohol (ethanol) paste containing: an alcohol (ethanol) component, a thickener component' and water, the alcohol (ethanol) component is based on the total weight Between 18wt%~1 〇〇wt%. 2. The non-toxic alcohol (ethanol) paste according to claim 1, wherein the thickener component is selected from the group consisting of hydroxypropyl decyl cellulose, sodium carboxymethyl cellulose, hydroxyethyl Cellulose, ethyl cellulose, pectin, gum arabic, dextrin, sodium stearate, sodium alginate, hydroxypropyl methyl fiber 4.根據申請專利範圍第 還包含一食用色素。 104. A food coloring is also included according to the scope of the patent application. 10
TW100120373A 2011-06-10 2011-06-10 Nontoxic alcohol (ethanol) paste TW201249980A (en)

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CN107090322A (en) * 2017-06-16 2017-08-25 易洁(北京)科技有限公司 A kind of preparation method of solid-state environment-friendly fuel
CN108929741B (en) * 2018-07-18 2020-08-18 冯林喜 Environment-friendly solid alcohol fuel and preparation method and application thereof
DE102021001028B4 (en) 2021-02-24 2024-08-08 Robert Meyer Flambé paste
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