TW201248890A - Full color pattern solar cell with transparent coating and manufacturing method thereof - Google Patents

Full color pattern solar cell with transparent coating and manufacturing method thereof Download PDF

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TW201248890A
TW201248890A TW100118814A TW100118814A TW201248890A TW 201248890 A TW201248890 A TW 201248890A TW 100118814 A TW100118814 A TW 100118814A TW 100118814 A TW100118814 A TW 100118814A TW 201248890 A TW201248890 A TW 201248890A
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substrate
transparent
full
solar cell
film
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TW100118814A
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TWI508316B (en
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Shui-Yang Lian
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Shui-Yang Lian
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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Abstract

The present invention provides a full color pattern solar cell with transparent coating and a manufacturing method. The solar cell comprises a first substrate, a transparent photoelectric conversion film formed on the surface of the first substrate, a second substrate, a full color pattern layer, and an encapsulation adhesive film configured between the second substrate and the transparent photoelectric conversion film. In which, the transparent photoelectric conversion film has a first transparent conductive layer connected with the first substrate, a second transparent conductive layer, and a semiconductor layer formed between the first transparent conductive layer and the second transparent conductive layers. With the configuration of the transparent photoelectric conversion film, the present invention may make the entire solar cell having transparent display effect, and achieve the black/white, gray scale or color display effect on the solar panel in association with the full color display of the full color pattern layer.

Description

201248890 六、發明說明: 【發明所屬之技術領域】 [0001] 本發明係有關一種太陽能電池,尤指一種具有透明 鍍膜之全彩圖像太陽能電池。 [0002] 【先前技術】 為了解決近年來日益短缺的能源問題,並且減少能 源製造對地球產生的污染問題,綠色能源被積極的開發 使用中,而太陽能電池由於其設置地點較無限制,且能 〇 量取得來源容易,因而被積極的發展中。其中薄膜太陽 能電池因為其低成本以及具大量製造的特性,而於市場 中快速成長,薄膜太陽能電池之基板,由於可以使用價 格低廉的玻璃、塑膠、陶瓷、石墨,金屬片等不同材料 ,並且形成可產生電壓的薄膜厚度僅需數微米,除此之 外,由於薄膜可使用軟性基材,應用彈性也較大。因此 ,習知所使用的薄膜太陽能電池,使用玻璃作為基板, 並常見使用於雨棚、遮光罩、屋頂以及大樓窗戶等,藉 ❹ 此產生發電的效果,進而節省大量的電費,並有效達到 節能省碳的效果。 [0003] 如美國專利公告US7259321號專利「METHOD OF MANUFACTURING THIN FILM PHOTOVOLTAIC MODULES 」’其揭露了一種薄膜太陽能電池的製作方法,但其模 組中係使用不透光之金屬層,透視度不佳。由於不透明 的太陽能電池模組將遮擋使用者的視野,因而無法應用 於要求透光度高的窗戶上❶而為了增加薄膜太陽能電池 應用於窗戶之附加價值以及室内採光性,其係利用雷射 100118814 表單編號A0101 第3頁/共21頁 1002031757-0 201248890 對該太陽能電池進行熔蝕而形成一具圖案化的顯示區域 ,進而利用該顯示區域而使整體窗戶更具有美感以及藝 術價值,除此之外,更利用顯示區域具有比其他區域更 高的光穿透性,而提高室内的採光度。 [0004] [0005] [0006] [0007] [0008] [0009] [0010] 100118814 但,一般雷射係以電腦控制光束開關(on/of f )的方 式而對薄膜太陽能電池進行熔蝕以形成該顯示區域,但 因無法準確的控制所欲溶姓之位置,因而有顯示圖案解 析度不佳的問題。另外,開關方式的雷射僅能做到黑白 圖案的顯示,並無法達到灰階或彩色圖案顯示的功能, 因此,亦無法提高使用者的使用意願。綜上所述,提高 圖案顯示的解析度以及如何進行彩色顯現,便為薄膜太 陽能電池之改進目標之一。 【發明内容】 本發明之主要目的,在於解決習知技術之薄膜太陽 能電池之圖案顯示解析度低的問題。 本發明之另一目的,在於解決習知技術之薄膜太陽 能電池無法以灰階或彩色顯示圖案的問題。 為達上述目的,本發明提供一種具有透明鍍膜之全 彩圖像太陽能電池之製作方法,包含有以下步驟: 51 :在一第一基板表面形成一透明光電轉換膜; 52 :製備一第二基板以及一設置於該第一基板與該 第二基板之間的封裝膠膜; 53 :利用一彩色顏料於該第一基板與該第二基板之 間進行上色以形成一全彩圖案層;以及 表單編號A0101 第4頁/共21頁 1002031757-0 201248890 [0011] S4 :透過該封裝膠膜結合該第一基板以及該第二基 板,該第一基板以具有該透明光電轉換膜之一面透過該 封裝膠膜與該第二基板結合固定,形成一太陽能電池。 [0012] 除此之外,本發明亦提供一種具有透明鍍膜之全彩 圖像太陽能電池,其包含有一第一基板、一形成於該第 一基板表面的透明光電轉換膜、一第二基板、一設置於 該第二基板與該透明光電轉換膜之間的封裝膠膜,以及 一設置於該第一基板與該第二基板之間的全彩圖案層。 0 該第一基板與該第二基板藉由該封裝膠膜進行結合,並 該透明光電轉換膜以及該全彩圖案層設置於該第一基板 與該第二基板之間,配合光線之照射,而可為灰階或彩 色圖案之顯示。 [0013] 由上述說明可知,本發明藉由該透明光電轉換膜而 可具有較佳的透光率,因而應用於窗戶時具有絕對之優 勢,並且配合該全彩圖案層之設置,而可進行灰階或彩 色的圖案顯示。除此之外,本發明不需要使用雷射進行 > 圖案的熔蝕,因而具有較為簡單的製程步驟,而可降低 生產成本。 【實施方式】 [0014] 有關本發明之詳細說明及技術内容,現就配合圖式 說明如下: [0015] 請參閱「圖1」及「圖2」所示,係本發明一較佳實 施例之步驟流程及製程結構示意圖,如圖所示:本發明 係為一種具有透明鍍膜之全彩圖像太陽能電池之製作方 法,包含有以下步驟: 100118814 表單編號 A0101 第 5 頁/共 21 頁 1002031757-0 201248890 [0016] [0017] [0018] [0019] [0020] SI :形成一透明光電轉換膜20,在一第一基板10表 面形成該透明光電轉換膜20,而為了形成該透明光電轉 換膜20,可更包含以下步驟。 S1A :表面粗糙化處理,於該第一基板10表面進行 粗链化處理,而形成一粗糙;表面。 S1B :形成一第一透明導電層21,於該第一基板10 之表面形成該第一透明導電層21,其材質可為氧化鋅 (ZnO)、氟化錫氧化物(FTO)、鋁鋅氧化物(AZO)、鋅鎵 氧化物(Ga 11 ium-doped z i nc oxi de,GZ0)或上述材 〇 料之組合。 SIC :形成一半導體層22,於該第一透明導電層21 遠離該第一基板10之一面形成該半導體層22,該半導體 層22是利用PIN半導體結構等具有P型半導體以及N型半導 體結合之結構進行收光並轉換為電能。 S1D :形成一第二透明導電層23,於該半導體層22 遠離該第一透明導電層21之一面形成該第二透明導電層 〇 23,其材質可為氧化鋅(ZnO)、氟化錫氧化物(FT0)、鋁 鋅氧化物(AZ0)、鋅鎵氧化物(Gallium-doped zinc oxide,GZ0)或上述材料之組合。需另外說明的是,由 上述材質所製作之第一透明導電層21以及該第二透明導 電層23因含有金屬元素,而為半透明或透明之呈現。本 發明所指之透明光電轉換膜20是相較於鍍上金屬而完全 無法透光的膜體而言,並非指完全的透明,舉例來說, 如該第一透明導電層21與該第二透明導電層23為鋅鎵氧 100118814 表單編號A0101 第6頁/共21頁 1002031757-0 201248890 化物材質,則該透明光電轉換膜2〇整體會呈現橘紅色, 而為半透明之呈現,如使用不同材料,則有可能呈現不 同的半透明效果。 S2 :製備一第二基板3〇以及一封裝膠膜4〇,請配合 參閲「圖3」所示,該封裝膠膜4〇設置於該第一基板1〇與 該第二基板30之間,且其材質為彈性膠或熱塑膠,彈性 膠係如乙烯-乙酸乙烯酯共聚物、聚胺基甲酸酯膠黏劑( polyurethane cast resins)、聚丙烯酸酿膠黏劑( polyacrylate cast resins)、矽膠(siUc〇nes) 等;而熱塑膠則如熱塑性聚胺基甲酸酯(Therm〇一 Plastic p〇iyurethane,TPU)、聚氣乙烯(L〇n〇_ Plast) ' 酸改性聚烯烴(modified p〇ly〇lefines) 等。 [0022] 必双ιυ興琢弟 〇 二基板30之間形成該全彩圖案層50,需先說明的是,全 彩係指黑白、灰階以及彩色顯示,並非單指彩色而已。 本實施例中’該全彩圖案㈣係形成於該封裝膠膜叙 表面。除此之外,請配合參閱「圖4」所示,其係將該全 彩圖案層5G形成於該封裝膠賴之表面。亦可如 所示’將該全_案㈣形成於«二基板30鄰近該封」 裝膠膜4G之表面。而為了增加彩色顯示的功能,这一併 參閱「圖6」所示’其係利用一彩色顏料於該封裝:賴 之表面進行上色以形成該全彩圖 案層50Α,而上色的方戈 可以印刷、喷墨、雷射、麗印或人工上色完成。亦可/ 該彩色顏料於該透明光電轉換膜2〇遠離該第一基板1〇之 100118814 表單編號Α0101 1002031757-0 第7頁/共21頁 201248890 進行上色,或者該第二基板3〇鄰近該封裝膠膜4〇之 表面進行上色以形成該全彩圖案層50A。 [0023] S4 :透過該封裝膠膜40結合該第一基板1〇以及該第 土板30該第一基板10以具有該透明光電轉換膜2〇之 一面透過該封裝膠膜4G與該第二基板㈣合固定,形成 一太陽能電池。 [0024]201248890 VI. Description of the Invention: [Technical Field of the Invention] [0001] The present invention relates to a solar cell, and more particularly to a full-color image solar cell having a transparent coating. [0002] [Prior Art] In order to solve the problem of increasing shortage of energy in recent years and reduce the pollution caused by energy manufacturing to the earth, green energy is actively developed and used, and solar cells are more limited in their installation locations and can It is easy to obtain a source of quantity and is thus actively developing. Among them, thin-film solar cells are rapidly growing in the market because of their low cost and large-scale manufacturing characteristics. The substrate of thin-film solar cells can be formed by using inexpensive materials such as glass, plastic, ceramics, graphite, metal sheets and the like. The film thickness at which the voltage can be generated is only a few micrometers. In addition, since the film can be used as a soft substrate, the application flexibility is also large. Therefore, conventionally used thin film solar cells use glass as a substrate, and are commonly used in canopies, hoods, roofs, and building windows, thereby generating power generation effects, thereby saving a large amount of electricity and effectively achieving energy saving. The effect of saving carbon. [0003] A method of fabricating a thin film solar cell is disclosed in the "METHOD OF MANUFACTURING THIN FILM PHOTOVOLTAIC MODULES" by the US Patent Publication No. US7259321, but the opaque metal layer is used in the mold set, and the transparency is not good. Since the opaque solar cell module will block the user's field of view, it cannot be applied to windows requiring high transmittance, and in order to increase the added value and indoor lighting of thin film solar cells applied to windows, the system utilizes laser 100118814. Form No. A0101 Page 3 of 21 1002031757-0 201248890 The solar cell is etched to form a patterned display area, which in turn makes the overall window more aesthetic and artistic. In addition, the display area has higher light transmittance than other areas, and the indoor lighting is improved. However, in general, lasers are used to etch a thin film solar cell by means of a computer controlled beam switch (on/of f). The display area is formed, but since the position of the desired surname cannot be accurately controlled, there is a problem that the resolution of the display pattern is not good. In addition, the laser of the switch mode can only display the black and white pattern, and cannot achieve the function of gray scale or color pattern display, and therefore, the user's willingness to use can not be improved. In summary, improving the resolution of the pattern display and how to perform color display is one of the improvement goals of the thin film solar cell. SUMMARY OF THE INVENTION The main object of the present invention is to solve the problem of low resolution of pattern display of a thin film solar cell of the prior art. Another object of the present invention is to solve the problem that the thin film solar cell of the prior art cannot display a pattern in gray scale or color. To achieve the above object, the present invention provides a method for fabricating a full-color image solar cell having a transparent coating, comprising the steps of: forming a transparent photoelectric conversion film on a surface of a first substrate; 52: preparing a second substrate And an encapsulation film disposed between the first substrate and the second substrate; 53: coloring between the first substrate and the second substrate by using a color pigment to form a full color pattern layer; Form No. A0101, page 4 / 21 pages, 1002031757-0 201248890 [0011] S4: bonding the first substrate and the second substrate through the encapsulation film, the first substrate having the surface of the transparent photoelectric conversion film The encapsulation film is bonded and fixed to the second substrate to form a solar cell. [0012] In addition, the present invention also provides a full-color image solar cell having a transparent coating, comprising a first substrate, a transparent photoelectric conversion film formed on the surface of the first substrate, a second substrate, An encapsulation film disposed between the second substrate and the transparent photoelectric conversion film, and a full color pattern layer disposed between the first substrate and the second substrate. The first substrate and the second substrate are combined by the encapsulation film, and the transparent photoelectric conversion film and the full color pattern layer are disposed between the first substrate and the second substrate, and are combined with light irradiation. It can be a grayscale or color pattern display. [0013] As can be seen from the above description, the present invention can have a better light transmittance by the transparent photoelectric conversion film, and thus has an absolute advantage when applied to a window, and can be combined with the setting of the full color pattern layer. Grayscale or colored pattern display. In addition, the present invention does not require the use of a laser for the etching of the pattern, and thus has a relatively simple process step, which can reduce the production cost. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS [0014] The detailed description and technical contents of the present invention will now be described with reference to the following drawings: [0015] Referring to FIG. 1 and FIG. 2, a preferred embodiment of the present invention is shown. The process flow and the process structure diagram are as shown in the figure: The invention is a method for manufacturing a full-color image solar cell with transparent coating, comprising the following steps: 100118814 Form No. A0101 Page 5 of 21 1002031757- [0020] [0020] SI: forming a transparent photoelectric conversion film 20, forming the transparent photoelectric conversion film 20 on the surface of a first substrate 10, and forming the transparent photoelectric conversion film 20, can further include the following steps. S1A: surface roughening treatment, roughening the surface of the first substrate 10 to form a rough surface; S1B: forming a first transparent conductive layer 21, forming the first transparent conductive layer 21 on the surface of the first substrate 10, and the material thereof may be zinc oxide (ZnO), tin fluoride oxide (FTO), aluminum zinc oxide (AZO), zinc gallium oxide (Ga 11 ium-doped zi nc oxi de, GZ0) or a combination of the above materials. SIC: forming a semiconductor layer 22, the semiconductor layer 22 is formed on a surface of the first transparent conductive layer 21 away from the first substrate 10. The semiconductor layer 22 is a P-type semiconductor and an N-type semiconductor bonded by a PIN semiconductor structure or the like. The structure is harvested and converted to electrical energy. S1D: forming a second transparent conductive layer 23, the second transparent conductive layer 〇23 is formed on the surface of the semiconductor layer 22 away from the first transparent conductive layer 21, and the material thereof may be zinc oxide (ZnO) or tin fluoride oxide. (FT0), aluminum zinc oxide (AZ0), gallium-doped zinc oxide (GZ0) or a combination of the above. It should be noted that the first transparent conductive layer 21 and the second transparent conductive layer 23 made of the above materials are semi-transparent or transparent because they contain a metal element. The transparent photoelectric conversion film 20 referred to in the present invention is a film body which is completely incapable of transmitting light compared to metal plating, and does not mean complete transparency, for example, the first transparent conductive layer 21 and the second. The transparent conductive layer 23 is zinc gallium oxide 100118814 Form No. A0101 Page 6 / 21 pages 1002031757-0 201248890 material, the transparent photoelectric conversion film 2 〇 overall will be orange-red, and is semi-transparent, if used differently Materials may have different translucent effects. S2: preparing a second substrate 3 and an encapsulation film 4, as shown in FIG. 3, the encapsulation film 4 is disposed between the first substrate 1 and the second substrate 30. And the material is elastic rubber or hot plastic, elastic rubber such as ethylene-vinyl acetate copolymer, polyurethane cast resins, polyacrylate cast resins, Silicone (siUc〇nes), etc.; and hot plastics such as thermoplastic polyurethane (Therm〇-Plastic p〇iyurethane, TPU), polyethylene (L〇n〇_ Plast) 'acid modified polyolefin ( Modified p〇ly〇lefines) and so on. [0022] The full color pattern layer 50 is formed between the two substrates 30. It should be noted that the full color refers to black and white, gray scale and color display, and is not a single color. In the present embodiment, the full color pattern (4) is formed on the surface of the encapsulating film. In addition, as shown in Fig. 4, the full color pattern layer 5G is formed on the surface of the package. Alternatively, the whole case (four) may be formed on the surface of the "two substrates 30 adjacent to the seal" film 4G. In order to increase the function of color display, this is also referred to as "Figure 6", which uses a color pigment to color the surface of the package: to form the full-color pattern layer 50Α, and to color the square Can be printed, inkjet, laser, lithography or artificial coloring. Alternatively, the color pigment is colored on the transparent photoelectric conversion film 2 away from the first substrate 1100118814 Form No. 1010101 1002031757-0 Page 7 / 21 pages 201248890, or the second substrate 3 is adjacent to the The surface of the encapsulation film 4 is colored to form the full color pattern layer 50A. [0023] S4: the first substrate 1 is bonded to the first substrate 1 through the encapsulating film 40, and the first substrate 10 has the surface of the transparent photoelectric conversion film 2 through the encapsulating film 4G and the second The substrate (4) is fixed together to form a solar cell. [0024]

心本發明更揭露了一種具有透明鍍膜之全彩圖像太陽 此電池,包含有一第一基板10、—形成於該第-基板10 表面的透明先電轉換膜2〇、—第二基板3G、—設置於該 第二基板30與該透明光電轉換膜2〇之間的封裝膠膜4〇, 以及—設置於該第—基板1G與該第二基板3()之間的全彩 圖案層5G °該第二基板3G設置於該透明光電轉換膜20遠 人集基板10之一側,該第一基板10以及該第二基板 30藉由錢裝膠膜4()進行結合,並該透明光電轉換膜 、及亥王力圖案層5G設置於該第__基板1Q與該第二基板 3〇之間,配合光細之照射,而可為灰階或彩色圖案之 顯示,需制㈣岐,埃所謂配合光線6〇之照射, 並非指必須藉由光照射發電後才可顯示圖案,而是將圖 案透過光的反射或透射而進人人眼,以顯示圖案。 100118814 [0025] 請配合參閱「圖2」所示,該透明光電轉換膜20具有 -與該第-基板1G連接的第—透明導電層2卜一相對該 第-透明導電層21的第二透明導電層23,以及一形成於 該第-透明導電層21及該第二透明導電層23之間的半導 體層22 °其中該第—透明導電層21及該第二透明導電層 23之材質可為氧化鋅、氟化踢氧化物、紹鋅氧化物或辞 表單編號A0101 苐8頁/共21頁 1002031757-0 201248890 嫁氧化物等。而該第-基板10係以具有該透明光電轉換 臈20之一面透過該封裝膠臈4〇而與該第二基板加連貼接 合。其中該封裝膠膜40之材質可為彈性膠或熱塑膠,彈 性膠係如乙稀-乙酸乙烯醋共聚物、聚胺基甲酸_黏劑 (polyurethane cast resins)、聚丙烯酸酯膠黏劑 (polyacrylate cast resins)、矽膠(silic〇nes )等;而熱塑膠則如熱塑性聚胺基甲酸酯(Therm〇_ Plastic p〇lyUrethane,τρυ)、聚氣乙烯(L〇n〇一 q Plast)、酸改性聚烯烴(modified p〇ly〇iefines) 等。 [0026] 該全彩圖案層50除了可如「圖3j所示,以印刷、喷 墨、雷射或人工上色的方式形成於該封裝膠膜4〇之表面 之外,亦可如「圖4」所示,形成於該透明光電轉換膜2〇 之表面,以及如「圖5」所示,設置於該第二基板3〇鄰近 該封裝膠膜40之表面。而「圖6」中,其係藉由彩色上色 的方式而使該全彩圖案層5〇a呈現多彩變化。該透明光電 Ο 轉換膜20並不一定為全透明之膜體,而是根據該第一透 明導電層21以及該第二透明導電層23之材質不同,而會 有不同半透明之顏色呈現。而於進行彩色圖案之呈現時 ,該全彩圖案層50A之色彩會因為該透明光電轉換膜2〇之 半透明顏色,而有混色之現象產生,也就是說,觀察者 所看到的顏色是由該光線60進入該透明光電轉換膜2〇所 形成之顏色混合上該全彩圖案層50A之顏色。舉例來說, 若該透明光電轉換膜20呈現橘紅色時,則必須預料到實 際觀察到的圖案顏色為該全彩圖案層50A之顏色混合福紅 100118814 表單編號A0101 第9頁/共21頁 1002031757-0 201248890 色,而根據透明光電轉換膜20厚度的不同,橘紅色的深 淺也會不同,因而必須根據實際顏色顯示狀況而進行設 計。 [0027] [0028] [0029] [0030] [0031] [0032] [0033] [0034] [0035] [0036] 綜上所述,相較於習知技術,本發明具有下列特點 一、 透過該透明光電轉換膜20以及該全彩圖案層50 之設置,不需要進行雷射熔蝕,而可減少製程步驟。 二、 利用簡易的印刷或喷墨方式而提高解析度且達 到灰階顯示或彩色顯示的目的。 三、 其製程簡易,方便製造,且具有成本低之優勢 ,因而可適用於大量製造。 因此本發明極具進步性及符合申請發明專利之要件 ,爰依法提出申請,祈鈞局早日賜准專利,實感德便。 以上已將本發明做一詳細說明,惟以上所述者,僅 爲本發明之一較佳實施例而已,當不能限定本發明實施 之範圍。即凡依本發明申請範圍所作之均等變化與修飾 等,皆應仍屬本發明之專利涵蓋範圍内。 【圖式簡單說明】 圖1,係本發明一較佳實施例之步驟流程示意圖。 圖2,係本發明一較佳實施例之製程結構示意圖。 圖3,係本發明第一實施例之結構分解示意圖。 圖4,係本發明第二實施例之結構分解示意圖。 100118814 表單編號A0101 第10頁/共21頁 1002031757-0 201248890 [0037] 圖5,係本發明第三實施例之結構分解示意圖。 [0038] 圖6,係本發明第四實施例之結構分解示意圖。 【主要元件符號說明】 [0039] 10 :第一基板 20 :透明光電轉換膜 21 :第一透明導電層 22 :半導體層 23 :第二透明導電層 ^ 30 :第二基板 40 :封裝膠膜 50、50A :全彩圖案層 60 :光線 S1〜S4 :步驟 S1A〜S1D :步驟 100118814 表單編號A0101 第11頁/共21頁 1002031757-0The present invention further discloses a full-color image solar cell having a transparent coating, comprising a first substrate 10, a transparent electroconversion film 2〇 formed on the surface of the first substrate 10, a second substrate 3G, - an encapsulation film 4A disposed between the second substrate 30 and the transparent photoelectric conversion film 2A, and a full color pattern layer 5G disposed between the first substrate 1G and the second substrate 3 () The second substrate 3G is disposed on one side of the transparent photoelectric conversion film 20 on the far side of the substrate 10, and the first substrate 10 and the second substrate 30 are bonded by the money film 4 (), and the transparent photoelectric The conversion film and the Hawang force pattern layer 5G are disposed between the first __substrate 1Q and the second substrate 3 ,, and can be displayed in a gray scale or a color pattern in accordance with the irradiation of the light, and the (4) 需 is required. The so-called ray irradiation with light ray does not mean that the pattern must be displayed after power generation by light irradiation, but the pattern is transmitted through the reflection or transmission of light into the human eye to display the pattern. 100118814 [0025] As shown in FIG. 2, the transparent photoelectric conversion film 20 has a first transparent conductive layer 2 connected to the first substrate 1G and a second transparent surface opposite to the first transparent conductive layer 21. a conductive layer 23, and a semiconductor layer 22 formed between the first transparent conductive layer 21 and the second transparent conductive layer 23, wherein the material of the first transparent conductive layer 21 and the second transparent conductive layer 23 may be Zinc Oxide, Fluorinated Kick Oxide, Sodium Zinc Oxide or Form No. A0101 苐8 pages/Total 21 pages 1002031757-0 201248890 Marriage oxides, etc. The first substrate 10 is bonded to the second substrate by passing through one side of the transparent photoelectric conversion layer 20 through the package. The material of the encapsulating film 40 can be elastic rubber or hot plastic, and the elastic rubber is such as ethylene-vinyl acetate copolymer, polyurethane cast resins, polyacrylate adhesive (polyacrylate). Cast resins), silica gels (silic〇nes), etc.; and thermoplastics such as thermoplastic polyurethane (Therm〇_Plastic p〇lyUrethane, τρυ), polyethylene (L〇n〇-q Plast), acid Modified polyolefin (modified p〇ly〇iefines) and the like. [0026] The full-color pattern layer 50 can be formed on the surface of the encapsulation film 4 by printing, inkjet, laser or artificial coloring as shown in FIG. 3j. 4" is formed on the surface of the transparent photoelectric conversion film 2, and as shown in FIG. 5, is disposed on the surface of the second substrate 3 adjacent to the encapsulation film 40. In Fig. 6, the full-color pattern layer 5〇a is colored in a colorful manner by coloring. The transparent photoelectric conversion film 20 is not necessarily a completely transparent film body, but may be formed in a different translucent color depending on the materials of the first transparent conductive layer 21 and the second transparent conductive layer 23. When the color pattern is presented, the color of the full color pattern layer 50A may be mixed due to the translucent color of the transparent photoelectric conversion film 2, that is, the color seen by the observer is The color formed by the light 60 entering the transparent photoelectric conversion film 2 is mixed with the color of the full color pattern layer 50A. For example, if the transparent photoelectric conversion film 20 is orange-red, it is necessary to expect that the actually observed pattern color is the color of the full-color pattern layer 50A. Fuhong 100118814 Form No. A0101 Page 9/Total 21 Page 1002031757 -0 201248890 Color, and depending on the thickness of the transparent photoelectric conversion film 20, the depth of the orange color will be different, so it is necessary to design according to the actual color display condition. [0036] [0036] [0036] In summary, the present invention has the following features as compared with the prior art. The transparent photoelectric conversion film 20 and the arrangement of the full color pattern layer 50 do not require laser ablation, and the process steps can be reduced. Second, the use of simple printing or inkjet method to improve the resolution and achieve the purpose of grayscale display or color display. Third, the process is simple, easy to manufacture, and has the advantage of low cost, so it can be applied to mass production. Therefore, the present invention is highly progressive and conforms to the requirements of the invention patent application, and the application is made according to law, and the praying office grants the patent as soon as possible. The invention has been described in detail above, but the foregoing is only a preferred embodiment of the invention, and is not intended to limit the scope of the invention. That is, the equivalent changes and modifications made by the scope of the present application should remain within the scope of the patent of the present invention. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a flow chart showing the steps of a preferred embodiment of the present invention. 2 is a schematic view showing a process structure of a preferred embodiment of the present invention. Figure 3 is a schematic exploded view of the first embodiment of the present invention. Figure 4 is a schematic exploded view of the second embodiment of the present invention. 100118814 Form No. A0101 Page 10 of 21 1002031757-0 201248890 [0037] FIG. 5 is a schematic exploded view of a third embodiment of the present invention. 6 is a schematic exploded view of a fourth embodiment of the present invention. [Main Element Symbol Description] [0039] 10: First substrate 20: Transparent photoelectric conversion film 21: First transparent conductive layer 22: Semiconductor layer 23: Second transparent conductive layer 30: Second substrate 40: Package film 50 , 50A: full color pattern layer 60: light S1 ~ S4: steps S1A ~ S1D: step 100118814 form number A0101 page 11 / total 21 page 1002031757-0

Claims (1)

201248890 七、申請專利範圍: 1 . 一種具有透明鍍膜之全彩圖像太陽能電池,包含有: 一第一基板; 一形成於該第一基板表面的透明光電轉換膜; 一第二基板,設置於該透明光電轉換膜遠離該第一基板之 一側; 一設置於該第二基板與該透明光電轉換膜之間的封裝膠膜 ,藉此結合具有該透明光電轉換膜之第一基板以及該第二 基板; 一全彩圖案層,設置於該第一基板與該第二基板之間。 2 .如申請專利範圍第1項所述之具有透明鍍膜之全彩圖像太 陽能電池,其中該透明光電轉換膜具有一與該第一基板連 接的第一透明導電層、一相對該第一透明導電層的第二透 明導電層,以及一形成於該第一透明導電層及該第二透明 導電層之間的半導體層。 3 .如申請專利範圍第2項所述之具有透明鍍膜之全彩圖像太 陽能電池,其中該第一透明導電層及該第二透明導電層之 材質選自於由氧化鋅、氟化錫氧化物、鋁鋅氧化物、鋅鎵 氧化物及其組合所組成之群組。 4 .如申請專利範圍第1項所述之具有透明鍍膜之全彩圖像太 陽能電池,其中該全彩圖案層係以印刷、喷墨、雷射或人 工上色的方式形成於該封裝膠膜之表面。 5 .如申請專利範圍第1項所述之具有透明鍍膜之全彩圖像太 陽能電池,其中該全彩圖案層係以印刷、喷墨、雷射或人 工上色的方式形成於該透明光電轉換膜之表面。 100118814 表單編號A0101 第12頁/共21頁 1002031757-0 201248890 6 .如申請專利範圍第1項所述之具有透明鍍膜之全彩圖像太 7 . 8 . 陽能電池,其中該全彩圖案層係以印刷、喷墨、雷射或人 工上色的方式形成於該第二基板鄰近該封裝膠膜之表面。 如申請專利範圍第1項所述之具有透明鍍膜之全彩圖像太 陽能電池,其中該封裝膠膜係為彈性膠或熱塑膠。 如申請專利範圍第1項所述之具有透明鍍膜之全彩圖像太 陽能電池,其中該封裝膠膜係之材質選自於由乙烯-乙酸 乙烯酯共聚物、聚胺基甲酸酯膠黏劑、聚丙烯酸酯膠黏劑 〇 9 . 、矽膠及其組合所組成之群組。 如申請專利範圍第1項所述之具有透明鍍膜之全彩圖像太 陽能電池,其中該封裝膠膜之材質係選自於熱塑性聚胺基 甲酸酯、聚氣乙烯、酸改性聚烯烴及其組合所組成之群組 10 . 〇 一種具有透明鍍膜之全彩圖像太陽能電池之製作方法,包 含有以下步驟: 51 :在一第一基板表面形成一透明光電轉換膜; 52 :製備一第二基板以及一設置於該第一基板與該第二基 板之間的封裝膠膜; 53 :形成一全彩圖案層於該第一基板與該第二基板之間; 以及 54 :透過該封裝膠膜結合該第一基板以及該第二基板,該 第一基板以具有該透明光電轉換膜之一面透過該封裝膠膜 與該第二基板結合固定,形成一太陽能電池。 11 . ,如申請專利範圍第10項所述之具有透明鍍膜之全彩圖像太 陽能電池之製作方法,其中步驟S1更包含有下列步驟: S1A :於該第一基板表面進行粗糙化處理,而形成一粗糙 100118814 表單編號A0101 第13頁/共21頁 1002031757-0 201248890 表面; SIB :於該第_基板之表面形成—第—透明導電層; S1C:於該第—透明導電層之遠離該第-基板之-面形成 一半導體層;以及 S1D .於該半導體層遠離該第 第二透明導電層。 一透明導電層之一面形成一 12 ·=巾睛專利範圍第1()項所述之具有透明㈣之全彩圖像太 陽月b電池之製作方法,其中於步驟幻中,利用一彩色顏料 於-玄第I板與該第二基板之間進行上色以形成該全彩圖 案層。 13 .如申凊專利範圍第1〇項所述之具有透明鑛膜之全彩圖像太 陽能電池之製作方法,其中於步驟83中,該全彩圖案層係 形成於該透明光電轉換膜遠離該第一基板之表面。 14 .如申吻專利範圍第1〇項所述之具有透明鑛膜之全彩圖像太 陽能電池之製作方法,其中該全彩圖案層係形成於該封裝 膠膜之表面。 15 .如申凊專利範圍第1〇項所述之具有透明鍵膜之全彩圖像太 陽能電池之製作方法’其令該全彩圖案層係形成於該第二 基板之表面。 16 ·如申凊專利範圍第1〇項所述之具有透明鍍膜之全彩圖像太 陽能電池之製作方法,其中於步驟S2中所製備的該封裝膠 膜係為彈性膠或熱塑膠。 17 .如申請專利範圍第1〇項所述之具有透明鍍膜之全彩圖像太 陽能電池之製作方法,其中該封裝膠膜之材質係選自於由 乙烯-乙酸乙烯酯共聚物、聚胺基甲酸酯膠黏劑、聚丙烯 酸酯膠黏劑、碎膠及其組合所組成之群組。 100118814 表單編號A0101 第14頁/共21頁 1002031757-0 201248890 18 .如申請專利範圍第10項所述之具有透明鍍膜之全彩圖像太 陽能電池之製作方法,其中該封裝膠膜之材質係選自於熱 塑性聚胺基甲酸酯、聚氣乙烯、酸改性聚烯烴及其組合所 組成之群組。 19 .如申請專利範圍第10項所述之具有透明鍍膜之全彩圖像太 陽能電池之製作方法,其中於步驟S3中,該彩色顏料係以 印刷、喷墨、雷射或人工上色的方式進行上色以形成該全 彩圖案層。 Ο 〇 100118814 表單編號 A0101 第 15 頁/共 21 頁 1002031757-0201248890 VII. Patent application scope: 1. A full-color image solar cell with transparent coating, comprising: a first substrate; a transparent photoelectric conversion film formed on the surface of the first substrate; and a second substrate disposed on The transparent photoelectric conversion film is away from one side of the first substrate; an encapsulation film disposed between the second substrate and the transparent photoelectric conversion film, thereby combining the first substrate having the transparent photoelectric conversion film and the first a second substrate; a full color pattern layer disposed between the first substrate and the second substrate. 2. The full-color image solar cell with transparent coating according to claim 1, wherein the transparent photoelectric conversion film has a first transparent conductive layer connected to the first substrate, and a first transparent layer a second transparent conductive layer of the conductive layer, and a semiconductor layer formed between the first transparent conductive layer and the second transparent conductive layer. 3. The full-color image solar cell with transparent coating according to claim 2, wherein the first transparent conductive layer and the second transparent conductive layer are selected from the group consisting of zinc oxide and tin fluoride. a group of materials, aluminum zinc oxides, zinc gallium oxides, and combinations thereof. 4. The full-color image solar cell with transparent coating according to claim 1, wherein the full-color pattern layer is formed on the encapsulation film by printing, inkjet, laser or artificial coloring. The surface. 5. The full-color image solar cell with transparent coating according to claim 1, wherein the full-color pattern layer is formed in the transparent photoelectric conversion by printing, inkjet, laser or artificial coloring. The surface of the film. 100118814 Form No. A0101 Page 12 of 21 1002031757-0 201248890 6. Full color image with transparent coating as described in claim 1 of the patent scope is too 7. 8 . Solar battery, wherein the full color pattern layer Formed on the surface of the second substrate adjacent to the encapsulation film by printing, inkjet, laser or artificial coloring. A full-color image solar cell with a transparent coating as described in claim 1 wherein the encapsulating film is an elastic or thermoplastic. The full-color image solar cell with transparent coating according to claim 1, wherein the material of the encapsulating film is selected from the group consisting of ethylene-vinyl acetate copolymer and polyurethane adhesive. , a group of polyacrylate adhesives, phthalocyanines and combinations thereof. The full-color image solar cell with transparent coating as described in claim 1, wherein the material of the encapsulation film is selected from the group consisting of thermoplastic polyurethane, polyethylene, acid-modified polyolefin, and The group consisting of the combination 10. The method for manufacturing a full-color image solar cell with transparent coating comprises the following steps: 51: forming a transparent photoelectric conversion film on the surface of the first substrate; 52: preparing one a second substrate and an encapsulation film disposed between the first substrate and the second substrate; 53: forming a full color pattern layer between the first substrate and the second substrate; and 54: transmitting the package The film is bonded to the first substrate and the second substrate. The first substrate is bonded to the second substrate through a surface of the transparent photoelectric conversion film to form a solar cell. The method for manufacturing a full-color image solar cell having a transparent coating according to claim 10, wherein the step S1 further comprises the following steps: S1A: roughening the surface of the first substrate, and Forming a roughness 100118814 Form No. A0101 Page 13 of 21 page 1002031757-0 201248890 Surface; SIB: forming a --transparent conductive layer on the surface of the first substrate; S1C: away from the first transparent conductive layer Forming a semiconductor layer on the surface of the substrate; and S1D. the semiconductor layer is away from the second transparent conductive layer. One surface of a transparent conductive layer forms a method for producing a transparent (four) full-color image solar moon b battery as described in item 1 () of the patent scope, wherein in the step illusion, a color pigment is used - coloring between the Xuan I board and the second substrate to form the full color pattern layer. The method for fabricating a full-color image solar cell having a transparent ore film according to the first aspect of the invention, wherein in step 83, the full-color pattern layer is formed on the transparent photoelectric conversion film away from the method The surface of the first substrate. 14. The method of fabricating a full-color image solar cell having a transparent mineral film as described in claim 1, wherein the full-color pattern layer is formed on a surface of the encapsulating film. 15. A method of fabricating a full color image solar cell having a transparent key film as described in claim 1 of the patent application, wherein the full color pattern layer is formed on a surface of the second substrate. The method of manufacturing a full-color image solar cell having a transparent coating according to the first aspect of the invention, wherein the encapsulating film prepared in the step S2 is an elastic rubber or a thermoplastic. 17. The method of fabricating a full-color image solar cell having a transparent coating according to claim 1, wherein the material of the encapsulant film is selected from the group consisting of ethylene-vinyl acetate copolymer and polyamine. A group of formate adhesives, polyacrylate adhesives, broken gels, and combinations thereof. 100118814 Form No. A0101 Page 14 of 21 1002031757-0 201248890 18 . The method for manufacturing a full-color image solar cell with transparent coating according to claim 10, wherein the material of the encapsulating film is selected From the group consisting of thermoplastic polyurethanes, polyethylenes, acid modified polyolefins, and combinations thereof. 19. The method of manufacturing a full-color image solar cell having a transparent coating according to claim 10, wherein in step S3, the color pigment is printed, inkjet, laser or artificially colored. Coloring is performed to form the full color pattern layer. Ο 〇 100118814 Form No. A0101 Page 15 of 21 1002031757-0
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Publication number Priority date Publication date Assignee Title
CN110952689A (en) * 2018-09-25 2020-04-03 汉能移动能源控股集团有限公司 Front plate, solar glass curtain wall and preparation method thereof

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US20110114178A1 (en) * 2009-11-17 2011-05-19 Du Pont Apollo Limited Solar cell module

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110952689A (en) * 2018-09-25 2020-04-03 汉能移动能源控股集团有限公司 Front plate, solar glass curtain wall and preparation method thereof

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