TW201243321A - Electric field generator and electric field generation method - Google Patents

Electric field generator and electric field generation method Download PDF

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Publication number
TW201243321A
TW201243321A TW101107025A TW101107025A TW201243321A TW 201243321 A TW201243321 A TW 201243321A TW 101107025 A TW101107025 A TW 101107025A TW 101107025 A TW101107025 A TW 101107025A TW 201243321 A TW201243321 A TW 201243321A
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Taiwan
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electrode
liquid
alternating current
electric field
asymmetric
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TW101107025A
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Chinese (zh)
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Akihide Shibata
Kenji Komiya
Tetsu Negishi
Hiroshi Iwata
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Sharp Kk
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/416Systems
    • G01N27/447Systems using electrophoresis
    • G01N27/44704Details; Accessories
    • G01N27/44743Introducing samples

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  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Structures Of Non-Positive Displacement Pumps (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)
  • Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)

Abstract

An electric filed generator comprising: a container containing a liquid; a first electrode and a second electrode, said electrodes being placed at a preset interval in a state where at least a part of each electrode is soaked in the liquid contained in said container; and an alternating current generator, which is connected to the first and second electrodes, for applying an unsymmetrical alternating current between the electrodes. This electric filed generator is characterized in that said alternating current generator generates in said liquid either an electric field that flows substantially from the first electrode toward the second electrode or an electric field that flows substantially from the second electrode toward the first electrode.

Description

201243321 六、發明說明: 【發明所屬之技術領域】 本發明係關於在液體.中產生電場之電場產生裝置及電場 產生方法。再者,關於使液體中浮游之固體移動之浮游體 移動褒置及浮游體移動方法、電㈣置及電泳方法、電渗 流泵及其動作方法。 【先前技術】 先刖以來,為進行荷電粒子或蛋白質等之分子之分離、 分析,向來使用將一對電極浸於包含分子等之溶液中並將 直流電壓施加於其電極間之電泳法。如此,若將直流電壓 施加於一對電極間,則由於溶液中會產生單向之電場,故 可使荷電粒子向一方之電極之方向移動。 例如’專利文獻1中,記載有用於決定DNA之鹼基序列 之電泳裝置。 該專利文獻1之電泳裝置中,在相當於溶液之扁塊狀泳 動凝膠之兩端配置有收容於電解液中之電極層,且於該電 極層連接有施加泳動電壓之泳動電源。泳動電源為直流電 源’若於電極層間施加單向之直流電壓(電場),則直流電 流於單向流動,而被注入於電泳凝膠中之分析對象之DN A 片段試樣在泳動凝膠中泳動並分離。 又’將一對之電極配置於液體中並將直流電壓施加於該 電極間而於液體中產生單向之電場之裝置,被運用在電滲 流泵或使帶電之細微粒子移動之裝置等各種領域中。 [先行技術文獻] 162130.doc 201243321 [專利文獻] [專利文獻1 ]日本特開平7 _ 15 16 8 7號公報 【發明内容】 [發明所欲解決之問題] 然而,藉由使直流電流在電極間流動而於液體内產生電 場之情形,存在因電流長時間向單向流動使得液體電解或 因電化學反應而腐触電極等之問題。 進而,由於該等之反應,亦會發生於液體中產生氣泡、 或液體被污染等之問題。又,該等之問題在電泳裝置中與 試樣之污染相關,且在電滲流泵中導致因氣泡引起之動作 不良。 因此,本發明係考慮如上所述之情況而完成者,且以提 供不會引起液體之電解或電化學反應等而可於液體中之單 向使電場產生之電場產生裝置及電場產生方法為課題。 [解決問題之技術手段] 本發明提供一種電場·產生裝置,其特徵為包含:注入有 液體之容器;以各自至少一部份浸於注入於上述容器之液 體中之方式空開特定之間隔而配置之第丨電極及第2電極; 及連接於上述第丨電極及第2電極、且使非對稱之交流施加 於兩電極間之交流產生H,上述交流產生器於上述液 體中產生實質上自上述第1電極朝向第2電極之電場、哎實 質上自上述第2電極朝向第1電極之電場之任一方之電場。 藉此,由於在第丨電極與第2電極之間施加非對稱I交 流,故可在液體内實質地產生單向之電場,且幾乎不會引 162130.doc 201243321 起液體電解或電化學反應,從而可抑制電極腐姓。 此處,上述之電場產生裝置中,可行的是,上述第1電 極與第2電極以與注入於上述容器之上述液體直接接觸之 方式配置;上述非對稱交流中,將上述第丨電極與第2電極 之間之電壓V(t)(t為時間)經過交流之丨週期積分而得之式 Veff=JV(t)dt 之值實質上為0,且不具有實質之直流成分。 藉此,由於第1電極與第2電極之間不會流動純正之直流 電流,故不易引起液體之電解或電化學反應,從而可確實 地防止電極腐蝕。 又,電場產生裝置中,可行的是,上述第丨電極與第2電 極之至少一方被絕緣膜覆蓋而不與液體直接接觸。 藉此由於第1電極及第2電極之至少一方被絕緣膜覆 蓋,故於2個電極間不會流動直流電流。因此,幾乎不會 引起液體電解或電化學反應,從而可更確實地防止電極腐 钱。 又,本發明提供-種浮游體移動裝i,其特徵為包含: 注入有物體浮游之液體之容器 :以各自至少一部份浸於注 入於上述容器之液體中之方式空開特定之間隔而配置之第 1電極及第2電極;及連接於上述第丨電極及第2電極、且使 非對稱之交流施加於兩電極間之交流產生器;且,藉由上 述交流產生器施加之非對稱交流,對於上述液體中浮游之 物體’使其進行自上述第!電極向第2電極之移動,或自上 述第2電極向第丨電極之移動之任一方之移動。 162130.doc 201243321 藉此,由於在第1電極與第2雷 '2電極之間施加非對稱之交 故可使在液體内浮游之物體於單向移動,且幾乎不會 引起液體電解或電化學反應’從而可抑制電極腐敍。 此處,上述之浮游體移動裝置中,可行的是上述第! 電極與第2電極以任-者皆與液體直接接觸之方式配置; 上述非對稱交流中,將上述第1電極與第2«之以電壓 V(t)(t為時間)經過交流之i週期積分而得之式201243321 VI. Description of the Invention: [Technical Field] The present invention relates to an electric field generating device and an electric field generating method for generating an electric field in a liquid. Further, a floating body moving device for moving a suspended solid in a liquid, a floating body moving method, an electric (four) setting and an electrophoresis method, an electroosmotic flow pump, and an operating method thereof. [Prior Art] In order to separate and analyze molecules such as charged particles or proteins, an electrophoresis method in which a pair of electrodes are immersed in a solution containing molecules or the like and a direct current voltage is applied between the electrodes is used. As described above, when a DC voltage is applied between a pair of electrodes, a unidirectional electric field is generated in the solution, so that the charged particles can be moved in the direction of one of the electrodes. For example, Patent Document 1 describes an electrophoresis apparatus for determining a base sequence of DNA. In the electrophoresis apparatus of Patent Document 1, an electrode layer accommodated in an electrolytic solution is disposed at both ends of a flat block-shaped swimming gel corresponding to a solution, and a traveling power source to which a running voltage is applied is connected to the electrode layer. The swimming power source is a DC power source. If a unidirectional DC voltage (electric field) is applied between the electrode layers, the DC current flows in one direction, and the DN A fragment sample of the analysis object injected into the electrophoresis gel is in the swimming gel. Swim and separate. Further, a device in which a pair of electrodes are disposed in a liquid and a direct current voltage is applied between the electrodes to generate a unidirectional electric field in the liquid is used in various fields such as an electroosmotic flow pump or a device for moving charged fine particles. in. [Provisional Technical Documents] 162130.doc 201243321 [Patent Document 1] [Patent Document 1] Japanese Laid-Open Patent Publication No. Hei 7- 15 16 8 (Convention) [Problems to be Solved by the Invention] However, by causing a direct current at the electrode In the case where an electric field is generated between the liquids and flows in the liquid, there is a problem that the liquid is electrolyzed by the current for a long period of time, or the electrodes are corroded by the electrochemical reaction. Further, due to such reactions, problems such as generation of bubbles in the liquid or contamination of the liquid may occur. Moreover, such problems are associated with contamination of the sample in the electrophoresis apparatus, and cause malfunction due to bubbles in the electroosmotic flow pump. Therefore, the present invention has been made in consideration of the above-described circumstances, and an electric field generating device and an electric field generating method capable of generating an electric field in a liquid in a liquid without causing electrolysis or electrochemical reaction of a liquid or the like. . [Technical means for solving the problem] The present invention provides an electric field generating apparatus characterized by comprising: a container in which a liquid is injected; and a specific interval is opened in such a manner that at least a part thereof is immersed in a liquid injected into the container. a second electrode and a second electrode disposed; and an alternating current generating H connected between the second electrode and the second electrode and applying an asymmetric alternating current between the electrodes, wherein the alternating current generator generates substantially The electric field of the first electrode toward the second electrode and the electric field substantially from one of the electric fields of the second electrode toward the first electrode. Thereby, since an asymmetric I alternating current is applied between the second electrode and the second electrode, a unidirectional electric field can be substantially generated in the liquid, and liquid electrolysis or electrochemical reaction is hardly caused by 162130.doc 201243321. Thereby, the electrode rot can be suppressed. Here, in the electric field generating apparatus described above, it is preferable that the first electrode and the second electrode are disposed in direct contact with the liquid injected into the container; and in the asymmetric alternating current, the third electrode and the second electrode are The voltage V(t) between the two electrodes (t is time) is integrated by the cycle of alternating current, and the value of the formula Veff=JV(t)dt is substantially zero and does not have a substantial DC component. As a result, since a pure DC current does not flow between the first electrode and the second electrode, electrolysis or electrochemical reaction of the liquid is less likely to occur, and electrode corrosion can be reliably prevented. Further, in the electric field generating device, it is possible that at least one of the second electrode and the second electrode is covered with an insulating film and is not in direct contact with the liquid. Thereby, since at least one of the first electrode and the second electrode is covered with the insulating film, a direct current does not flow between the two electrodes. Therefore, liquid electrolysis or electrochemical reaction is hardly caused, so that electrode rot can be more reliably prevented. Moreover, the present invention provides a floating body moving device, characterized in that it comprises: a container in which a liquid floating in an object is injected: a specific interval is opened in such a manner that at least a part of each is immersed in a liquid injected into the container. a first electrode and a second electrode disposed; and an alternating current generator connected to the second electrode and the second electrode and having an asymmetric alternating current applied between the electrodes; and the asymmetry applied by the alternating current generator The alternating current moves to the object floating in the liquid to move from the second electrode to the second electrode or from the second electrode to the second electrode. 162130.doc 201243321 Thereby, an asymmetric movement between the first electrode and the second thunder '2 electrode can cause the object floating in the liquid to move in one direction, and hardly cause liquid electrolysis or electrochemistry. The reaction 'can thereby inhibit electrode rot. Here, in the above-described floating body moving device, it is possible that the first electrode and the second electrode are disposed in direct contact with the liquid; in the asymmetric alternating current, the first electrode and the second electrode are The voltage V(t) (t is time) is obtained by integrating the i-cycle of the alternating current

Veff=iV(t)dt 之值實質上為0,且不具有實質之直流成分。 藉此’由於第!電極與第2電極之間不會流動純正之直流 電流’故不易引起液體之電解或電化學反應,從而可確實 地防止電極腐蝕。 又,浮游體移動裝置中,可行的是,上述第】電極與第2 電極之至少一方被絕緣膜覆蓋而不與液體直接接觸。 上述實施形態中,由於第1電極及第2電極之至少一方被 絕緣膜覆蓋,故於2個電極間不會流動直流電流。因此, 幾乎不會引起液體電解或電化學反應,從而可更確實地防 止電極腐姓。 又’本發明提供一種電泳裝置,其特徵為包含:注入有 包含試樣之液體之泳動槽;以各自至少一部份浸於注入於 上述泳動槽之液體中之方式空開特定之間隔而配置之第1 電極及第2電極;及連接於上述第1電極及第2電極、且使 非對稱之交流施加於兩電極間之交流產生器;且,利用上 述交流產生器施加之非對稱交流,使液體中所含之試樣在 162130.doc • 6 · 201243321 液體中之第1電極與第2電極之間泳動;上述第1電極與第2 電極之至少一方被絕緣膜覆蓋而不與上述液體直接接觸。 藉此,由於在第1電極與第2電極之間施加非對稱之交 流’故可使試樣電泳,在進行電泳時,可防止液體電解而 產生氣泡’從而可防止因電化學反應引起電極腐蝕從而液 體受到污染。因此,利用電泳,可對試樣進行更精確之解 析。 又,本發明提供一種電泳顯示裝置,其特徵為包含:空 開特定之間隔而對向配置之第i電極及第2電極;配置於由 上述第1電極及第2電極相夾之空間,且包含内包電泳粒子 與分散液之複數個膠囊之電泳元件;連接於上述第i電極 與第2電極,並使非對稱之交流施加於兩電極間之交流產 生器;且,利用上述非對稱交流’使各膠囊内之電泳粒子 向一方之電極之方向移動。 藉此’由於在第1電極與第 流,故可使各膠囊内之電泳粒 移動’且在將各膠囊之位置作 泳進行顯示。 2電極之間施加非對稱之交 子向一方之電極之方向持續 為像素之情形下,可基於電 …〜爪取,丹符做為包含:流動洛 體之流道;各自離間配置於上述流道之上游部與下游部、 並具有複數個孔之第極與第2電極;連接於上述 極與第2電極,並使非對稱之 〇 父机施加於兩電極間之交济 產生器;且,藉由施加上述非對 仰父"IL,將流入上述流ϋ 内之液體自位於流道内之上游部 符。卩之第1電極向位於流道户 162130.doc 201243321 之下游部之第2電極之方向輸送。 藉此’由於在第1電極與第2電極之間施加非對稱之交 流,故可於單向搬送流道内之液體,可防止液體電解而產 生氣泡’且可防止因電化學反應引起電極腐蝕。因此,由 於不需要用以去除氣泡之裝置,故可使電滲流泵之構造簡 單化,且可提高電滲流泵之可靠性。 此處,上述之電滲流泵中,可行的是,上述第丨電極與 第2電極以與流入上述流道之上述液體直接接觸之方式配 置;上述非對稱交流中,將上述第1電極與第2電極之間之 電壓V (t)(t為時間)經過交流之1週期積分而得之式The value of Veff=iV(t)dt is substantially zero and does not have a substantial DC component. By this, due to the first! Since a pure direct current does not flow between the electrode and the second electrode, it is less likely to cause electrolysis or electrochemical reaction of the liquid, and the electrode corrosion can be surely prevented. Further, in the floating body moving device, it is possible that at least one of the first electrode and the second electrode is covered with an insulating film and is not in direct contact with the liquid. In the above embodiment, at least one of the first electrode and the second electrode is covered with the insulating film, so that no direct current flows between the two electrodes. Therefore, liquid electrolysis or electrochemical reaction is hardly caused, so that the electrode rot can be more reliably prevented. Further, the present invention provides an electrophoresis apparatus comprising: a migration tank into which a liquid containing a sample is injected; and a configuration in which at least a part of each is immersed in a liquid injected into the migration tank at a specific interval a first electrode and a second electrode; and an alternating current generator connected to the first electrode and the second electrode and having an asymmetric alternating current applied between the electrodes; and the asymmetric alternating current applied by the alternating current generator The sample contained in the liquid is moved between the first electrode and the second electrode in the liquid of 162130.doc • 6 · 201243321; at least one of the first electrode and the second electrode is covered with an insulating film and is not covered with the liquid direct contact. Thereby, since an asymmetric alternating current is applied between the first electrode and the second electrode, the sample can be electrophoresed, and when electrophoresis is performed, liquid can be prevented from being electrolyzed to generate bubbles, thereby preventing electrode corrosion due to electrochemical reaction. Thereby the liquid is contaminated. Therefore, with electrophoresis, the sample can be more accurately resolved. Moreover, the present invention provides an electrophoretic display device comprising: an i-th electrode and a second electrode disposed opposite to each other at a predetermined interval; and is disposed in a space sandwiched by the first electrode and the second electrode, and An electrophoretic element comprising a plurality of capsules encapsulating the electrophoretic particles and the dispersion; an alternating current generator connected to the ith electrode and the second electrode, and applying an asymmetric alternating current between the electrodes; and using the asymmetric communication The electrophoretic particles in each capsule are moved in the direction of one of the electrodes. Thereby, the electrophoretic particles in the respective capsules can be moved by the first electrode and the second flow, and the positions of the respective capsules can be displayed by swimming. In the case where an asymmetric cross between two electrodes is continued to be a pixel in the direction of one of the electrodes, it may be based on the electric ...~ claw, and the Danfu is included as a flow passage including a flowing body; a first pole and a second electrode having a plurality of holes in the upstream portion and the downstream portion of the channel; a cross-connector coupled between the pole and the second electrode, and applying an asymmetric parent device between the electrodes; By applying the above-mentioned non-opposite parent "IL, the liquid flowing into the flow chamber is self-located from the upstream portion of the flow path. The first electrode of the crucible is transported in the direction of the second electrode located downstream of the runner 162130.doc 201243321. Thereby, since an asymmetrical exchange is applied between the first electrode and the second electrode, the liquid in the flow path can be transported in one direction, and the liquid can be prevented from being electrolyzed to generate bubbles, and the electrode corrosion can be prevented from being caused by the electrochemical reaction. Therefore, since the means for removing the bubbles is not required, the structure of the electroosmotic flow pump can be simplified, and the reliability of the electroosmotic flow pump can be improved. Here, in the electroosmotic flow pump described above, it is preferable that the second electrode and the second electrode are disposed in direct contact with the liquid flowing into the flow channel; and in the asymmetric alternating current, the first electrode and the first electrode are The voltage V (t) between the two electrodes (t is time) is obtained by integrating the 1 cycle of the alternating current.

Veff=JV(t)dt 之值實質上為0,且不具有實質之直流成分。 藉此,由於第1電極與第2電極之間不會流動純正之直流 電流,故不易發生液體之電解或電化學反應,從而可確實 地防止電極腐蝕。 又,電滲流泵中,可行的是,上述第丨電極與第2電極之 至少一方被絕緣膜覆蓋而不與液體直接接觸。 藉此,由於第1電極及第2電極之至少一方被絕緣膜覆 蓋’故2個電極間不會流動直流電流。因此,不會因液體 電解而產生氣泡,且可更確實地防止因電化學反應導致電 極腐姓。 進而,電滲流泵中,可行的是,在上述第丨電極與第2電 極之間之上述流道内,設置有由多孔質材構成之電滲材。 又’本發明之電渗流果可設置於燃料電池上。 162130.doc 201243321 再者’本發明之電滲流泵亦可作為冷卻泵或使藥液供給 裝置驅動之裝置使用。 又本發明提供-種電場產生方法,其特徵為包含··將 液體注入於容器之步驟;以各自至少一部份浸於注入於上 述泳動槽之液體中之方式空開特定之間隔而配置第】電極 第電極之配置步驟,及將非對稱交流施加於上述第1電 極及第2電極之間,並於上述液體中產生實質上自上述第^ 電極朝向第2電極之電場、或實質上自上述第2電極朝向第 1電極之電場之任一方之電場之電場產生步驟。 ㈣本發明’由於在第1電極與第2電極之間施加非對稱 之交流可在㈣内f質上產生單向之電場,且幾乎不 會引起液體電解或引起電化學反應,從而可抑制 蝕。 又,本發明之特徵為其係上述之電場產生方法,且上述 第1電極與第2電極以任一者皆與液體直接接觸之方式配 置;上述非對稱交流中’冑上述第1電極與第2電極之間之 電壓V(t)(t為時間)經過交流之丨週期積分而得之式The value of Veff=JV(t)dt is substantially zero and does not have a substantial DC component. As a result, since a pure DC current does not flow between the first electrode and the second electrode, electrolysis or electrochemical reaction of the liquid is less likely to occur, and electrode corrosion can be surely prevented. Further, in the electroosmotic flow pump, it is possible that at least one of the second electrode and the second electrode is covered with an insulating film without being in direct contact with the liquid. As a result, at least one of the first electrode and the second electrode is covered by the insulating film, so that no direct current flows between the two electrodes. Therefore, bubbles are not generated by liquid electrolysis, and the electrode rot caused by the electrochemical reaction can be more reliably prevented. Further, in the electroosmotic flow pump, it is possible to provide an electroosmotic material composed of a porous material in the flow path between the second electrode and the second electrode. Further, the electroosmotic fruit of the present invention can be disposed on a fuel cell. 162130.doc 201243321 Furthermore, the electroosmotic flow pump of the present invention can also be used as a cooling pump or a device for driving a chemical supply device. Further, the present invention provides a method for generating an electric field, comprising the steps of: injecting a liquid into a container; and arranging at least a portion of each of the liquids injected into the swimming tank to vacate a specific interval a step of disposing the electrode first electrode, and applying an asymmetric alternating current between the first electrode and the second electrode, and generating an electric field substantially from the first electrode toward the second electrode or substantially from the liquid An electric field generating step of the electric field of the second electrode toward the electric field of the first electrode. (4) In the present invention, since an asymmetric alternating current is applied between the first electrode and the second electrode, a unidirectional electric field can be generated in the (f) inner mass, and the liquid electrolysis or the electrochemical reaction is hardly caused, thereby suppressing the etching. . Further, the present invention is characterized by the electric field generating method described above, wherein the first electrode and the second electrode are disposed in direct contact with the liquid; and in the asymmetric alternating current, the first electrode and the first electrode The voltage V(t) between the two electrodes (t is time) is obtained by integrating the cycle of the alternating current cycle.

Veff=|V(t)dt 之值實質上為0’且不具有實質之直流成分。 藉此,由於第1電極與第2電極之間不會流動純正之直流 電流’故不易引起液體之電解或電化學反應’從而可確實 地防止電極腐钱。 又,可行的是,上述第丨電極與第2電極之至少—方被絕 緣膜覆蓋而不與液體直接接觸。 162I30.doc •9· 201243321 藉此,由於第1電極及第2電極之至少一方被絕緣膜覆 蓋’故2個電極間不會流動直流電流。因此,幾乎不會引 起液體電解或引起電化學反應’從而可更確實地防止電極 腐飯。 又’作為上述非對稱交流’較佳為使用高電位持續時間 與低電位持續時間不同之矩形波。 藉此,用以使非對稱交流產生之電路比較單純,可有效 地使液體中實質上產生單向之電場。 又’作為上述非對稱交流,較佳為使用上升時間與下降 時間不同之三角波或鋸齒波。 藉此,用以使非對稱交流產生之電路比較單純,可有效 地使液體中實質上產生單向之電場。 又’本發明提供一種浮游體移動方法,其特徵為包含: 將浮游有物體之液體注入於容器之準備步驟;以各自至少 一部份浸於上述液體中之方式空開特定之間隔而配置第ι 電極與第2電極之配置步驟;及將非對稱交流施加於上述 第1電極與第2電極之間,且對於於上述液體中浮游之物 體’使其進行自上述第1電極向第2電極之移動,或自上述 第2電極向第1電極之移動中任一方之移動之移動步驟。 藉此,由於在第1電極與第2電極之間施加非對稱之交 流,故可使在液體内浮游之物體於單向移動,且幾乎不會 引起液體電解或引起電化學反應,從而可抑制電極腐蝕。 此處,上述之浮游體移動方法中,可行的是,上述第丄 電極與第2電極以任一者皆與液體直接接觸之方式配置; I62130.doc •10· 201243321 上述非對稱交流中,將上述第i電極與第2電極之間之電壓 v(t)(t為時間)經過交流之丨週期積分而得之式The value of Veff = |V(t)dt is substantially 0' and does not have a substantial DC component. As a result, since a pure DC current does not flow between the first electrode and the second electrode, electrolysis or electrochemical reaction of the liquid is less likely to occur, so that electrode burnt can be reliably prevented. Further, it is possible that at least the above-mentioned second electrode and the second electrode are covered by the insulating film without being in direct contact with the liquid. 162I30.doc •9·201243321 Thereby, at least one of the first electrode and the second electrode is covered with an insulating film, so that a direct current does not flow between the two electrodes. Therefore, the liquid electrolysis or the electrochemical reaction is hardly caused, so that the electrode rice can be more reliably prevented. Further, it is preferable to use a rectangular wave having a high potential duration and a low potential duration as the above-described asymmetric alternating current. Thereby, the circuit for generating the asymmetric alternating current is relatively simple, and the unidirectional electric field can be substantially generated in the liquid. Further, as the above-described asymmetric communication, it is preferable to use a triangular wave or a sawtooth wave having a different rise time and fall time. Thereby, the circuit for generating the asymmetric alternating current is relatively simple, and the unidirectional electric field can be substantially generated in the liquid. Further, the present invention provides a method for moving a floating body, comprising: preparing a liquid for injecting a liquid to the container; and arranging at least a portion of each of the liquids in a manner that is vacant at a specific interval a step of disposing the ι electrode and the second electrode; and applying an asymmetric alternating current between the first electrode and the second electrode, and performing an object floating in the liquid from the first electrode to the second electrode The movement or the movement step of the movement from the second electrode to the first electrode. Thereby, since an asymmetric alternating current is applied between the first electrode and the second electrode, the object floating in the liquid can be moved in one direction, and the liquid electrolysis or the electrochemical reaction is hardly caused, thereby suppressing The electrode is corroded. Here, in the above method for moving a floating body, it is possible that the second electrode and the second electrode are disposed in direct contact with the liquid; I62130.doc •10·201243321 In the above asymmetric communication, The voltage v(t) between the ith electrode and the second electrode (t is time) is obtained by integrating the 丨 period of the alternating current

Veff=JV(t)dt 之值實質上為0,且不具有實質之直流成分。 藉此,由於第丨電極與第2電極之間不會流動純正之直流 電流,故不易發生液體之電解或電化學反應,從而可確實 地防止電極腐蝕。 又,浮游體移動方法中,可行的是,上述第丨電極與第2 電極之至少一方被絕緣膜覆蓋而不與液體直接接觸。 藉此,由於第1電極及第2電極之至少一方被絕緣膜覆 蓋’故2個電極間不會流動直流電流。因此,幾乎不會引 起液體電解或引起電化學反應,從而可更確實地防止電極 腐姓。 又’本發明提供一種電泳方法’其特徵為包含:將包含 利用電泳而移動之試樣之液體注入泳動槽之準備步驟;以 各自至少一部份浸於上述液體中之方式空開特定之間隔而 配置第1電極與第2電極之配置步驟;及將非對稱交流施加 於上述第1電極與第2電極之間,並使上述試樣在液體中之 第1電極與第2電極之間泳動之泳動步驟;且,上述第1電 極與第2電極之至少一方被絕緣膜覆蓋而不與上述液體直 接接觸。 藉此,由於在第1電極與第2電極之間施加非對稱之交 流,故可使試樣電泳,在進行電泳時,可防止液體電解而 產生氣泡,且可防止因電化學反應而腐蝕電極因而污染液 162130.doc 201243321 。因此,利用電泳,可對於試樣進行更精確之解析。 又本發明提供一種電滲流泵之動作方法,其特徵為: 將第1電極與第2電極各自離間配置於電滲流泵之流道内之 上游部與下游部;將非對稱交流施加於上述第1電極與第2 電極之間;且,將流入上述流道内之液體,自位於上述流 道内之上游部之第1電極向位於流道内之下游部之第2電極 輸送。 藉此,由於在第丨電極與第2電極之間施加非對稱之交 流,,可於單向搬送流道内之液體,且可防止液體電解而 產生氣泡’ m止因電化學反應導致電極貞因此, 由於不需要用以去除氣泡之機構,故可使電滲流果之構造 簡單化’且可提高電滲流泵之可靠性。 此處,上述之電滲流泵之動作方法中,可行的是,上述 第1電極與第2電極以任一者皆與液體直接接觸之方式配 置;上述非對稱交流中,將上述第1電極與第2電極之間之 電壓V(t)(t為時間)經過交流之丨週期積分而得之式The value of Veff=JV(t)dt is substantially zero and does not have a substantial DC component. Thereby, since a pure DC current does not flow between the second electrode and the second electrode, electrolysis or electrochemical reaction of the liquid is less likely to occur, and electrode corrosion can be surely prevented. Further, in the floating body moving method, it is possible that at least one of the second electrode and the second electrode is covered with an insulating film and is not in direct contact with the liquid. As a result, at least one of the first electrode and the second electrode is covered by the insulating film, so that no direct current flows between the two electrodes. Therefore, the liquid electrolysis or the electrochemical reaction is hardly caused, so that the electrode rot can be more surely prevented. Further, the present invention provides an electrophoresis method characterized by comprising: a preparation step of injecting a liquid containing a sample moved by electrophoresis into a swimming tank; and vacating a specific interval in such a manner that at least a portion thereof is immersed in the liquid a step of disposing the first electrode and the second electrode; and applying an asymmetric alternating current between the first electrode and the second electrode, and moving the sample between the first electrode and the second electrode in the liquid And a step of migrating; at least one of the first electrode and the second electrode is covered with an insulating film and is not in direct contact with the liquid. Thereby, since an asymmetric alternating current is applied between the first electrode and the second electrode, the sample can be electrophoresed, and when electrophoresis is performed, the liquid can be prevented from being electrolyzed to generate bubbles, and the electrode can be prevented from being corroded by the electrochemical reaction. Thus polluted liquid 162130.doc 201243321. Therefore, with electrophoresis, a more accurate analysis of the sample can be performed. Further, the present invention provides a method of operating an electroosmotic flow pump, characterized in that: a first electrode and a second electrode are disposed apart from each other in an upstream portion and a downstream portion in a flow path of an electroosmotic flow pump; and an asymmetric alternating current is applied to the first portion The electrode and the second electrode are connected to each other, and the liquid flowing into the flow path is transported from the first electrode located in the upstream portion of the flow path to the second electrode located in the downstream portion of the flow path. Thereby, since an asymmetric alternating current is applied between the second electrode and the second electrode, the liquid in the flow path can be transported in one direction, and the liquid can be prevented from being electrolyzed to generate a bubble, which is caused by an electrochemical reaction. Since the mechanism for removing bubbles is not required, the structure of the electroosmotic flow can be simplified, and the reliability of the electroosmotic flow pump can be improved. Here, in the method of operating the electroosmotic flow pump described above, it is preferable that the first electrode and the second electrode are disposed in direct contact with the liquid; and in the asymmetric alternating current, the first electrode and the first electrode are The voltage V(t) between the second electrodes (t is time) is obtained by integrating the cycle of the alternating current

Veff=/V(t)dt 之值實質上為0,且不具有實質之直流成分。 藉此,由於第1電極與第2電極之間不會流動純正之直流 電流,故可防止液體電解而產生氣泡,且可更確實地防止 因電化學反應導致電極腐蝕。 又,電滲流泵之動作方法中,可行的是,上述第丨電極 與第2電極之至少一方被絕緣膜覆蓋而不與液體直接接 觸0 162130.doc -12 201243321 藉此,由於^電極及第2電極之至少—方被絕緣膜覆 蓋,故2個電極間不會流動直流電流。因此,不會因液體 電解而產生氣泡,從而亦可更確實地防止因電化學反應導 致電極腐触。 [發明之效果] . 根據本發明,由於將非對稱之交流施加於液體中之—對 之電極即第1及第2電極間,故可使液體中實質上產生單向 之電場,無需在電極間持續施加由直流電流產生之單向之 電場,可抑制液體中產生電解及電化學反應,從而可抑制 電極之腐蝕。 【實施方式】 〈用s吾之定義〉 首先,使用圖1〜圖4說明本發明中使用之「非對稱交 流」之定義》 圖1係舉例說明非非對稱、即對稱之電流之波形者。圖之 及圖3係舉例說明非對稱之交流之波形者。圖4係說明判定 是否為非對稱之具體之方法之圖。 . 圖1舉4個例說明非非對稱、即對稱之電流之波形(顯示 電壓V與時間t之關係之圖表)。 圖1(a)係對稱之正弦波。圖表上丨丨丨係電壓為最小值之 點,112係電壓為最大值之點,113係電壓再次成為最小值 之點。波形之一部份114(自111至112之區間)為升壓過程, 波形之另一部份115(自112至113之區間)為降壓過程。自點 111至點113為交流之1週期。 162130.doc 201243321 此處,以圖4(a)及(b)說明判斷圖1(a)之正弦波為對稱之 標準》 圖4(a)係再次顯示圖l(a)者。圖4(b)t,擷取圖氕叻之波 形之升壓過程114,並使電壓軸反轉(114〇。當然該u4r 與波形之降壓過程U5正確地重合。即,將升壓過程與降 壓過程完全重合之交流稱為非非對稱之交流或對稱交流。 圖1(b)係對稱之矩形波。該情形,電壓為最小之點不僅 一個,亦可為121a或121c,或該等2點之間之1211)。同樣 地’電壓為最大之點亦不僅一個’可以是為122&amp;或122〇, 或該等2點之間之122b » 然而,爲了如上所述進行是否對稱之判定,有必要確定 波形之升壓過程124與降壓過程125之範圍。今後,電壓為 最小(最大)之點有複數個之情形,採用其最終之點。即, 升壓過程124設為之間,降壓過程設為122&amp;與 123a之間。由於升壓過程124(自121&amp;至1223之區間)與降壓 過程125(自122a至123a之區間)藉由使電壓軸反轉而完全重 合,故圖1(b)之矩形波之交流亦明顯為對稱。 圖1(c)係對稱之三角波。升壓過程134(自U1至ι32之區 間)與降壓過程135(自132至133之區間)藉由使電壓軸反轉 而完全重合。雖然圖1(d)之波形較複雜,但仍為對稱之交 流。升壓過程144(自141至142之區間)與降壓過程145(自 142至143之區間)藉由使電壓軸反轉而完全重合。 另一方面,圖2舉4個例說明非對稱之交流之波形。 圖2(a)雖波形為正弦變化,但為非對稱之交流。其原因 162130.doc •14· 201243321 如圖4(c)及(d)所示,因為即使升壓過程214(自211至212之 區間)在電壓軸反轉(214r),仍不會與降壓過程215(自212 至213之區間)重合。 圖2(b)係處於高電位之時間(高電位持續時間)與處於低 電位之時間(低電位持續時間)不同之非對稱之矩形波。因 為即使升壓過程224(自221至222之區間)在電壓轴反轉,仍 不會與降壓過程225(自222至223之區間)重合。 圖2(c)係非對稱之三角波。因為即使升壓過程234(自23 J 至232之區間)在電壓轴反轉,仍不會與降壓過程ns(自232 至233之區間)重合。 圖2(d)之波形雖複雜,但仍為非對稱之交流。因為即使 升壓過程244(自241至242之區間)在電壓軸反轉,仍不會與 降壓過程245(自242至243之區間)重合。 此外,雖然未圖示,但作為非對稱之交流,亦可使用上 升時間與下降時間不同之鋸齒波。 圖3係週期或振幅與時間一起變化之非對稱之交流之 例0 圖3⑷中週期與時間皆增加。由於即使升壓過程314(自 3U至3Π之區間)在電壓軸反轉’仍不會與降壓過程315(自 312至313之區間)重合,故為非對稱之交流。 圖3(b)中週期與時間皆增加。ώ於 θ刀 由於即使升壓過程324(自 321至322之區間)在電壓軸反轉,仍 科1/5不會與降壓過程325(自 322至323之區間)重合,故為非對稱之交流。 若對以上進行總結’如圖2盥圖3中 一圆13〒所不之例,所謂非對 162130.doc 15 201243321 稱之交流,定義為交流之升壓過程與降壓過程、即使使其 中一方之電壓軸反轉,兩者仍不會重合之交流,亦稱為非 對稱交流。 以下,就使用非對稱之交流於液體中實質上產生單向之 電場之裝置及方法,使用具體例進行說明》 &lt;實施形態1&gt; 使用圖5說明作為本發明之第1實施形態之於液體中產生 單向之電場之電場產生裝置及電場產生方法。 圖5中顯示使液體中產生單向之電場之裝置(電場產生裝 置)1100之概略剖面圖。 容器1111充滿液體1112。第1電極m3與第2電極1114之 其中至少一部份浸於液體1112中。第1電極1113與第2電極 1114上連接有產生非對稱之交流之交流電源丨丨丨5(亦稱為交 流產生器)。 此處’容器1111只要為可保持液體1112者即可。 液體1112為有效地產生單向電場,較佳為離子濃度較小 者。例如,較佳為乙醇、甲醇、IPA(Is〇pr〇pyl Alc〇h〇1 : 異丙醇)等之醇類、輕油精、丙酮等之有機溶劑等。使用 水之情形,較佳為使用純水、無離子水等。 第1電極1113及第2電極1114只要具有充足之導電性即 VJ&quot; 〇 另,第1電極1113與第2電極1114藉由以相互對向之方式 配置、’可使2個電極間之電場之朝向與強度均…因此, 後述之實施例中所不,使液體中之帶電之物體於單向移 162130.doc 201243321 動或於進仃電冰時,可正確控制物體或電泳之對象物。 又作為電極材料,例如可使用銅、金、鎢、鋁等之金 屬’或添加賦予導電性之雜質之矽等之半導體。 電極之形狀例如為平板狀’電極之尺寸、面積為5 cmx5 em左右°使1對之電極僅分隔特定之距離而對向配置,其 冑極間之距離例如為10⑽左右。惟電極之形狀或配置並 不限於此,亦可為以夹著欲使電場產生之區域之方式配置 ’祠狀%狀、塊狀之形狀之電極。又,電極間之距離,較 佳為對應欲使電場產生之區域而決亦有設為數叫〜數 十cm之情形。 在父流電源1115中產生並施加於第1電極1113與第2電極 1114之非對稱交流,例如可使用圖2或圖3中所示者。將圖 2及圖3之交流電壓值v作為以第2電極1U4為基準電壓而施 加於第1電極1113之電壓。此時,例如施加圖2所示之非對 稱交流時,於液體1112内實質上產生之電場之朝向為朝右 (圖5之箭頭符號1117之朝向)。 非對稱交流之較佳之頻率因液體之種類而各不相同。一 .般而言,液體包含離子,液體中之離子濃度越高,對應電 極之電位變化而於液體中產生之電場越快消失。在非對稱 交流之電壓變化(與頻率成比例)較液體中產生之電場消失 之時間更長之情形下’幾乎不能於液體中產生電場。因 此,在離子濃度低之液體中降低頻率,在離子濃度高之液 體中提高頻率。 作為例子,使用IPA作為液體之情形,較佳為5 Hz〜50 162130.doc 201243321 kHz ’使用純水作為液體之情形為5〇〇 Hz〜5 MHz。然而, 由於液體之污染而使離子濃度較高之情形下,有必要提高 頻率。 液體1112之離子濃度較高之情形,將非對稱交流施加於 第1電極1113及第2電極1114時,阻礙液體m2中於單向產 生電極之效果會變得更強。 這是因為第1電極1113及第2電極1114之表面附近存在較 多之離子,且第1電極1113及第2電極1114之表面附近之電 荷數之變化相對於第1電極1113及第2電極1114之電位之變 化快速追隨之故。 因此’液體1112之離子濃度較高之情形,則有必要提高 非對稱交流之頻率。液體1112之離子濃度較高之情形之液 體1112之離子之行為亦將於後在模擬結果之最後進行說 明。 非對稱交流之較佳之電壓根據必要之電場之強度而適宜 決定。例如,電極間之距離為1 cm時,可使用1 V以上500 V 以下之電壓。 如此’藉由將非對稱之交流施加於第1電極i丨丨3與第2電 極1114,液體1112内實質上於單向產生電場。根據後述之 模擬結果說明其理由。 然而’因液體電解或電化學反應而腐蝕電極等之問題皆 由流經電極間之直流電流成份決定,在交流中幾乎不成問 題。 電化學反應(電腐蝕)中,直流電流流動之情形,雖在陽 162130.doc •18· 201243321 極發生氧化反應從而開始腐蝕’但在陰極發生還原反應從 而不會發生腐姓。 另一方面,交流電流流動之情形,由於相同程度之氧化 反應與還原反應各自交替發生’故2個電極都幾乎不會發 生腐姓*電解亦相同。 貫際上,由於反應產物藉由擴散而移動,故在低頻率下 並不限於氡化反應與還原反應完全相抵,一般而言交流中 之電化學反應或電解較直流之情形小得多。 因此,因交流而於液體中可單向產生電場,意味著幾乎 不引起電化學反應或電解就可在液體中單向產生電場。 如此,使直流電流流動之情形下會發生陽極之腐蝕,相 對於此’交流電流流動之情形則由於電化學反應或電解不 易發生,幾乎不會發生故電解之腐蝕》 又’在交流之情形下’無論是對稱交流與非對稱交流之 任一者之情形,氧化反應與還原反應皆會交替發生,故幾 乎不會發生電極之腐蝕。 於液體1112中,實質上使電場單向產生之步驟主要包含 以下步驟: (1) 將液體1Π2注入容器1111之準備步驟; (2) 以各自至少一部份浸於液體丨丨12之方式,空開特定 之間隔配置第1電極1113與第2電極1114之配置步驟; (3) 將非對稱交流施加於第1電極1113與第2電極1114之 間’而於液體1112中實質上產生自第1電極m3朝向第2電 極1114之電場、或實質上自第2電極1114朝向第1電極1113 162130.doc •19- 201243321 之電場之任—方之電場產生之電場產生步驟。 藉由使用如上所述之方法或裝置,將非對稱之交流施加 於2個電極⑴3、1114間,可在液體實質上產生單 向之電場。 又’非對稱交流中,雖電場之方向瞬間交替反轉,但如 上所述,由於升壓與降壓之過程不會重合,故實質上: 單向之電場。所謂實質上單向,意味著將液體中產生之電 場矢量以非對稱交流之丨週期、整週期或足夠長之時間積 分時,電場矢量不為0而是以有限之大小朝向單一方向。 因此,並不意味著電場矢量之朝向始終朝向單一方向。實 際上,施加非對稱交流之情形,電場矢量之朝向以非對稱 交流之週期反轉》 如此般實質上產生單向之電場之情形,由於如上所述般 氧化與還原交替發生,故液體幾乎不會被 學反應幾乎不會發生。然而,施加對稱交流:情形,= 樣地不易發生電極之腐蝕,但無法使單向之電場產生。 因此,施加非對稱交流之情形’與直流電流相同,可於 液體内產生單向之電場’且與電場交流相@,可抑制因液 體電解或電化學反應而引起電極腐银。 本實施形態中,由於第1電極1113與第2電極1114皆與液 體1112直接接觸,故若將直流施加於2個電極間則直流電 流流動。因此,較佳的是,非對稱交流不具有實質之直流 成份,即經過交流之1週期對上述第丨電極與第2電極之間 之電壓V⑴積分之veff實質上為〇。原因是因為如此一來在 162130.doc •20· 201243321 步確實地 蝕等之問 2個電極間不會流動純正之直流電流,故可進— :避因液體電解、或電化學反應而引起電極腐 題0 形:二t對稱交流較佳之例為如圖2(b)所示之非對稱之矩 ^電位持續時間與低電位持續時間*同之矩形 之矩形波疋因為其用以使波形產生之電路比較簡 故可有效地在液體中實質上產生單向之電場1,圓2⑻ 之例中两電位持續時間較短、低電位持續時間較長,而若 延長高2位持續時間而縮短低電位持續時間,可^液體^ 產生之實質上單向之電場之朝向反向。 作為非對稱交流,亦可像用圖2(c)中所示之非對稱之三 角波(上升時間與下降時間$同之m鑛齒波)。如此 之三角波亦同樣地,其用以使波形產生之電路比較簡單, 可有效地在液體中實質上產生單向之電場。另,該例中上 升時間較短、下降時間較長,但若延長上升時間而縮短下 降時間,可使液體中產生之實質上單向之電場之朝向反 向0 圖2(b)或圖2(c)之波形較佳之理由與後述之模擬結果之 解釋一起進行詳細說明。 &lt;實施形態2 &gt; 使用圖6說明作為本發明之第2實施形態之於液體中之單 向產生電場之電場產生裝置及電場產生方法。 本實施形態與實施形態1不同的是第1電極與第2電極之 至少一方被絕緣膜覆蓋。 162130.doc -21- 201243321 圖6係本實施形態之於液體中之單向產生電場之裝置 1200之概略剖面圖。 容器1211充滿液體1212。第丨電極1213與第2電極1214其 中至少一部份浸於液體1212中。第丨電極1213與第2電極 1214被絕緣膜1216覆蓋,且連接有產生非對稱之交流之交 流電源1215 » 此處,容器1211只要為可保持液體丨2丨2者即可。液體 1212較佳為離子濃度較小者。例如,較佳為乙醇、甲醇、 IPA(Is〇pr〇Pyl Alcohol :異丙醇)等之醇類、輕油精、丙酮 等之有機溶劑等。使用水之情形,較佳為使用純水、無離 子水等。第1電極1213及第2f極1214只要具有充足之導電 性即可。 又’ §亥情形亦與實施形態1相同’爲了使2個電極間之電 場之朝向與強度均一,較佳的是,第1電極1213與第2電極 1214以相互對向之方式配置》藉此正確控制液體中之帶電 物體向單向之移動或電泳之對象物之移動。 絕緣膜1216可使用矽氧化膜、矽氮化膜、樹脂薄膜等。 又’絕緣膜1216以覆蓋電極整體之方式形成,例如電極 由銅、金、鎢、鋁等之金屬或添加賦予導電性之雜質之矽 等之半導體材料形成之情形,可形成10 nm〜2 μπι左右之膜 厚之石夕氧化膜。絕緣膜只要利用眾所周知之先前技術、例 如CVD(Chemical Vapor Deposition :化學氣相沉積)法形成 即可。 在交流電源1215中產生並施加於第1電極1213與第2電極 162130.doc -22· 201243321 1214上之非對稱交流,例如可使用圖2或圖3中所示者。將 圖2及圖3之V作為以第2電極1214為基準電壓而施加於第ι 電極1213之電壓。此時,例如施加圖2所示之非對稱交流 時,於液體1212内實質上產生之電場之朝向為朝右(圖6之 箭頭符號1217之朝向)》 又,非對稱交流例如可使用圖7中所示之波形之交流。 圖7(a)、(b)、⑷及(d)中所示之波形為將直流成份Vsa、 Vsb、Vsc及Vsd分別施加於圖2(a)、(b)、⑷及(d)中所示之 波形者。 圖2中所不之波形係於交流之一週期間使電壓平均者為 〇,但圖7中所示之波形中不會為然而,由於第1電極 1213與第2電極1214被絕緣膜1216覆蓋,故2個電極間不會 流動直流電流。因此,即使為如圖7中所示之波形,亦不 會有特別不良之影響,可於液體1212中實質上產生單向之 電場。 圖6所不之本實施形態中,雖第丨電極1213及第2電極 1214皆被絕緣膜1216覆蓋,但只要任一方之電極被絕緣膜 1216覆蓋即可。因為該情形亦可防止直流電流流動於2個 電極間之故。 非對稱電流之較佳之頻率及電壓只要與實施形態丨相同 地設定即可。 實施形態2中,由於第丨電極及第2電極之至少一方被絕 緣膜1216覆蓋,故於2個電極間不會流動直流電流。即, 由於在電極與液體間發生直接電子之移動,故不會發生氧 162130.doc •23· 201243321 化反應或還原反應。 因此’可確實地防止因液體電解或電化學反應而引起電 極腐蝕等之問題。 又’由於第1電極及第2電極之至少一方被絕緣膜覆蓋, 故不會有直接電子自第1電極到達第2電極從而流動電流之 情況。因此’期間消耗之電力僅為取決於覆蓋電極之絕緣 膜所構成之電容之充放電者。因此,可顯著減少消耗電 力’且可顯著減少焦耳熱之產生。 本實施形態2之情形亦較佳為圖2(b)或圖2(c)之波形。 &lt;模擬&gt; 以下,說明在將如此之非對稱交流施加於液體中之2個 電極之情形下,模擬液體中產生之電場、及帶電物體之運 動之結果。 (1)模擬模型 使用圖8〜圖26說明在將非對稱交流施加於浸於液體中之 2個電極之情形下產生之電場及帶電物體之運動之模擬結 果。 圖8係說明自時間τ=0將一定之直流電壓施加於浸於液體 中之2個電極之情形下發生之現象之圖。 第1電極1213與第2電極1214之間為充滿液體1212者。第 1電極1213及第2電極1214為分別被絕緣膜1216覆蓋者《該 情形’ 2個電極間不流動電流。第1電極1213與第2電極 1214上連接有電源1215。 在Τ=0時,自電源1215開始將電壓施加於第1電極1213與 162130.doc -24- 201243321 第2電極1214 ’則如圖8(a)所示,液體1212中,於以箭頭符 號1217表示之方向上產生電場。 液體中,存在依存於液體之種類之濃度之正離子與負離 子。因此,自電壓施加時間開始經過時間T1後,如圖8(b) 所示,於覆蓋第1電極及第2電極之絕緣膜1216上,與在各 個電極誘發之電荷相反符號之電荷開始集中。於絕緣膜 1216上誘發之電荷會終止自各個電極誘發之電荷所產生之 電力線,故液體1212中之電場之強度隨著時間經過而逐漸 變弱。 自電壓施加開始經過充分之時間T2後,如圖8(c)所示, 由於自各個電極誘發之電荷所產生之電力線被絕緣膜1216 上誘發之電荷完全終止’故液體1212中之電場之強度為 0。 直至液體中之電場幾乎為〇所需之時間(時間常數)依存 於液體中存在之離子之濃度,離子濃度越小所需時間越 長。例如,在IPA中為10秒以内,在純水中為〇1秒以内。 在溶解有鹽類之水中則更短。 如此’為了使可動離子存在於液體中並可集中於電極之 絕緣膜上,先前,即使將電壓施加於浸於液體中之電極, 仍難以在液體中使單向之電場持續產生。 又,若使用未被絕緣膜覆蓋之裸露之電極施加直流電 壓,雖可在液體中持續產生單向之電場,但若單向電場持 續,則有因液體電解或電化學反應而引起電極腐蝕等之問 題。 162130.doc •25· 201243321 另’若將交流電壓施加於被絕緣膜覆蓋之2個電極間, 則可於液體中產生交流電場。將交流施加於2個電極間之 情形’由於其頻率之倒數較上述時間常數更小時,於電極 誘發之電荷無法相對於電極之電位之變化而追隨,故液體 中侵入電場。然而,液體中之電場之時間平均為〇,無法 於液體中產生單向之電場。 圖9及圖1〇中顯示模擬之模型之說明圖。 如圖9所示,第丨電極1313及第2電極1314分別被絕緣膜 1316覆蓋。於被絕緣膜1316覆蓋之2個電極1313、1314間 充滿液體1312。第1電極1313及第2電極1314上連接有可產 生任意之波形之電源1315。液體1312中,浮游有帶電之物 體1318。使用如此之模型,思考如下之模擬。 對第2電極1314施加接地電位((}&gt;11)),於時間1對第1電極 13 13施加電壓V(t) ^原本系統不帶電之情形,將第i電極 1313表面上誘發之電荷量作為£^〇),將覆蓋第1電極1313 之絕緣膜1316上誘發之電荷量作為qs⑴’則第2電極1314 上誘發之電荷量為-qe(t) ’覆蓋第2電極1314之絕緣膜1316 上誘發之電荷量為-qs(t)。 將絕緣膜13 16之介電常數設為。,將液體1312之介電 常數設為。%。此處,%及€3分別為絕緣膜1316及液體1312 之介電常數,ε。為真空中之介電常數。又,將液體中之電 場之強度設為E(t)。 若將第1電極丨3丨3上之絕緣膜1316之兩端之電容作為 Cdl,將第2電極1314上之絕緣膜1316之兩端之電容作為 162130.doc -26- 201243321The value of Veff=/V(t)dt is substantially zero and does not have a substantial DC component. Thereby, since a pure DC current does not flow between the first electrode and the second electrode, it is possible to prevent the liquid from being electrolyzed to generate bubbles, and it is possible to more reliably prevent the electrode from being corroded by the electrochemical reaction. Further, in the method of operating the electroosmotic flow pump, it is possible that at least one of the second electrode and the second electrode is covered with an insulating film and is not in direct contact with the liquid. 162130.doc -12 201243321 At least the square of the 2 electrodes is covered by the insulating film, so that no direct current flows between the two electrodes. Therefore, bubbles are not generated by the liquid electrolysis, and the electrode corrosion can be prevented more reliably due to the electrochemical reaction. [Effects of the Invention] According to the present invention, since an asymmetric alternating current is applied between the first electrode and the second electrode, which is an electrode, the unidirectional electric field can be substantially generated in the liquid without the need for an electrode. Continuous application of a unidirectional electric field generated by a direct current can suppress electrolysis and electrochemical reactions in the liquid, thereby suppressing corrosion of the electrode. [Embodiment] <Definition by sigma> First, the definition of "asymmetric AC" used in the present invention will be described with reference to Figs. 1 to 4. Fig. 1 is a diagram illustrating a waveform of a non-asymmetric, that is, symmetrical current. Figure 3 and Figure 3 illustrate the waveform of an asymmetric AC. Fig. 4 is a view showing a concrete method of determining whether or not it is asymmetrical. Figure 1 shows four examples of non-asymmetric, i.e., symmetrical, current waveforms (a graph showing the relationship between voltage V and time t). Figure 1 (a) is a symmetrical sine wave. On the graph, the 丨丨丨 system voltage is the minimum point, the 112 series voltage is the maximum point, and the 113 series voltage is again the minimum value. One portion of the waveform 114 (from 111 to 112) is the boosting process, and another portion of the waveform 115 (from the 112 to 113 interval) is the buck process. From point 111 to point 113 is a cycle of alternating current. 162130.doc 201243321 Here, the standard for judging the sine wave of Fig. 1(a) is determined as shown in Figs. 4(a) and (b). Fig. 4(a) shows Fig. 1(a) again. Figure 4(b)t, taking the boosting process 114 of the waveform of the graph and inverting the voltage axis (114 〇. Of course, the u4r and the waveform bucking process U5 correctly coincide. That is, the boosting process The alternating with the decompression process is called non-asymmetric alternating or symmetrical alternating. Figure 1(b) is a symmetrical rectangular wave. In this case, the voltage is the smallest, not only one, but also 121a or 121c, or Wait for 1211 between 2 points). Similarly, the point at which the voltage is maximum is not only a 'can be 122& or 122, or 122b between the two points. However, in order to determine whether the symmetry is as described above, it is necessary to determine the boost of the waveform. The range of process 124 and buck process 125. In the future, there are a plurality of points where the voltage is the smallest (maximum), and the final point is adopted. That is, the boosting process 124 is set to be between and the step-down process is set between 122 & and 123a. Since the boosting process 124 (from the interval of 121 & to 1223) and the step-down process 125 (from the interval of 122a to 123a) are completely coincident by inverting the voltage axis, the alternating wave of Fig. 1(b) is also Obviously symmetrical. Figure 1 (c) is a symmetrical triangular wave. The boosting process 134 (from U1 to ι32) and the buck process 135 (from 132 to 133) are completely coincident by inverting the voltage axis. Although the waveform of Figure 1(d) is more complex, it is still a symmetric intersection. The boosting process 144 (from the interval 141 to 142) and the buck process 145 (the interval from 142 to 143) are completely coincident by inverting the voltage axis. On the other hand, Fig. 2 shows four examples of the waveform of the asymmetric alternating current. Fig. 2(a) shows a sinusoidal change in waveform but an asymmetrical exchange. The reason is 162130.doc •14· 201243321 As shown in Figures 4(c) and (d), because even if the boosting process 214 (from the interval of 211 to 212) is reversed in the voltage axis (214r), it will not fall. The pressure process 215 (from the interval 212 to 213) coincides. Fig. 2(b) shows an asymmetric rectangular wave at a high potential (high potential duration) and a low potential (low potential duration). Because even if the boosting process 224 (from the interval 221 to 222) is reversed in the voltage axis, it will not coincide with the buck process 225 (from the interval of 222 to 223). Figure 2(c) is an asymmetrical triangular wave. Because even if the boosting process 234 (from the interval of 23 J to 232) is reversed in the voltage axis, it does not coincide with the buck process ns (from the interval of 232 to 233). The waveform of Figure 2(d) is complex but still asymmetric. Because even if the boosting process 244 (from the interval 241 to 242) is reversed in the voltage axis, it does not coincide with the buck process 245 (from the interval 242 to 243). Further, although not shown, a sawtooth wave having a different rising time and falling time may be used as the asymmetric alternating current. Figure 3 is an example of an asymmetrical exchange in which the period or amplitude changes with time. Example 0 In Figure 3(4), the period and time increase. Since the boosting process 314 (in the interval from 3U to 3Π) does not overlap with the step-down process 315 (from the interval of 312 to 313), it is an asymmetrical alternating current. Both cycle and time increase in Figure 3(b). Since the θ knife is even if the boosting process 324 (from the interval of 321 to 322) is reversed in the voltage axis, the section 1/5 does not coincide with the step-down process 325 (from the interval of 322 to 323), so it is asymmetric. Communication. If we summarize the above, as shown in Figure 2, Figure 3, a circle of 13 〒, the so-called non-pair 162130.doc 15 201243321 called the exchange, defined as the AC boost process and the buck process, even if one of them The voltage axis is reversed, and the two still do not coincide with each other, also known as asymmetric communication. In the following, an apparatus and method for asymmetrically generating a unidirectional electric field in a liquid are used, and a specific example will be described. <Embodiment 1> A liquid according to a first embodiment of the present invention will be described with reference to Fig. 5 . An electric field generating device and an electric field generating method for generating a one-way electric field. Fig. 5 is a schematic cross-sectional view showing a device (electric field generating means) 1100 for generating a unidirectional electric field in a liquid. The container 1111 is filled with the liquid 1112. At least a portion of the first electrode m3 and the second electrode 1114 are immersed in the liquid 1112. An AC power source 丨丨丨5 (also referred to as an AC generator) that generates an asymmetric AC is connected to the first electrode 1113 and the second electrode 1114. Here, the container 1111 may be any one that can hold the liquid 1112. The liquid 1112 is effective to generate a unidirectional electric field, preferably a smaller ion concentration. For example, an alcohol such as ethanol, methanol, IPA (Is〇pr〇pyl Alc〇h〇1: isopropanol), an organic solvent such as light oil essence or acetone, or the like is preferable. In the case of using water, it is preferred to use pure water, ion-free water or the like. As long as the first electrode 1113 and the second electrode 1114 have sufficient conductivity, VJ&quot;, the first electrode 1113 and the second electrode 1114 are disposed to face each other, and the electric field between the two electrodes can be made. Both the orientation and the intensity are... Therefore, in the embodiment described later, the object to be charged or the object to be electrophoresis can be properly controlled when the charged object in the liquid is moved in one direction or in the case of electric ice. Further, as the electrode material, for example, a metal such as copper, gold, tungsten or aluminum or a semiconductor to which an impurity imparting conductivity is added may be used. The shape of the electrode is, for example, a flat plate-shaped electrode having an area of about 5 cm x 5 em. The pair of electrodes are disposed opposite each other only by a predetermined distance, and the distance between the electrodes is, for example, about 10 (10). The shape or arrangement of the electrodes is not limited thereto, and an electrode having a shape of a 祠-shaped or block-shaped shape may be disposed so as to sandwich a region where an electric field is generated. Further, the distance between the electrodes is preferably set to be several to tens of cm in accordance with the region where the electric field is to be generated. The asymmetric alternating current generated in the parent current source 1115 and applied to the first electrode 1113 and the second electrode 1114 can be, for example, as shown in Fig. 2 or Fig. 3. The AC voltage value v of Figs. 2 and 3 is used as the voltage applied to the first electrode 1113 with the second electrode 1U4 as a reference voltage. At this time, for example, when the asymmetric alternating current shown in Fig. 2 is applied, the direction of the electric field substantially generated in the liquid 1112 is toward the right (the direction of the arrow symbol 1117 in Fig. 5). The preferred frequency of asymmetric communication varies from one liquid to another. Generally, a liquid contains ions, and the higher the concentration of ions in the liquid, the faster the electric field generated in the liquid disappears corresponding to the potential change of the electrode. In the case where the voltage change of the asymmetric alternating current (proportional to the frequency) is longer than the time when the electric field generated in the liquid disappears, the electric field is hardly generated in the liquid. Therefore, the frequency is lowered in the liquid having a low ion concentration, and the frequency is increased in the liquid having a high ion concentration. As an example, in the case of using IPA as a liquid, it is preferably 5 Hz to 50 162130.doc 201243321 kHz 'The case where pure water is used as the liquid is 5 〇〇 Hz to 5 MHz. However, in the case where the concentration of ions is high due to contamination of the liquid, it is necessary to increase the frequency. When the ion concentration of the liquid 1112 is high, when the asymmetric alternating current is applied to the first electrode 1113 and the second electrode 1114, the effect of preventing the liquid m2 from being generated in the unidirectional electrode becomes stronger. This is because a large amount of ions are present in the vicinity of the surface of the first electrode 1113 and the second electrode 1114, and the change in the number of charges in the vicinity of the surface of the first electrode 1113 and the second electrode 1114 is opposite to the first electrode 1113 and the second electrode 1114. The change in potential quickly catches up. Therefore, in the case where the ion concentration of the liquid 1112 is high, it is necessary to increase the frequency of the asymmetric exchange. The behavior of the ions of the liquid 1112 in the case where the ion concentration of the liquid 1112 is high will also be described later at the end of the simulation results. The preferred voltage for asymmetric communication is suitably determined by the strength of the necessary electric field. For example, when the distance between the electrodes is 1 cm, a voltage of 1 V or more and 500 V or less can be used. Thus, by applying an asymmetric alternating current to the first electrode i丨丨3 and the second electrode 1114, an electric field is generated in the liquid 1112 substantially in one direction. The reason is explained based on the simulation results described later. However, the problem of etching electrodes or the like due to liquid electrolysis or electrochemical reaction is determined by the DC current flowing between the electrodes, and there is almost no problem in the communication. In the electrochemical reaction (electro-corrosion), when the direct current flows, although the oxidation reaction occurs in the anode 162130.doc •18·201243321, the corrosion starts to occur, but the reduction reaction occurs at the cathode so that the corrosion does not occur. On the other hand, in the case where the alternating current flows, since the oxidation reaction and the reduction reaction of the same degree alternately occur, the two electrodes are hardly rotted and the electrolysis is the same. Conversely, since the reaction product moves by diffusion, it is not limited to the deuteration reaction and the reduction reaction at a low frequency. Generally, the electrochemical reaction or electrolysis in the alternating current is much smaller than that of the direct current. Therefore, an electric field can be generated in one direction in the liquid due to the exchange, which means that an electric field can be generated unidirectionally in the liquid with little or no electrochemical reaction or electrolysis. In this way, the anode is corroded in the case where the direct current flows, and the case where the alternating current flows is not easily caused by the electrochemical reaction or the electrolysis, and the corrosion of the electrolysis is hardly occurred. 'Whether it is either symmetrical or asymmetric, the oxidation reaction and the reduction reaction alternate, so that corrosion of the electrode hardly occurs. In the liquid 1112, the step of substantially unidirectionally generating the electric field mainly comprises the following steps: (1) preparing a liquid 1Π2 into the container 1111; and (2) immersing at least a part of the liquid in the liquid crucible 12, The arrangement of the first electrode 1113 and the second electrode 1114 is arranged at a predetermined interval; (3) an asymmetric alternating current is applied between the first electrode 1113 and the second electrode 1114', and substantially generated in the liquid 1112. An electric field generating step of the electric field generated by the electric field of the first electrode m3 toward the second electrode 1114 or substantially from the second electrode 1114 toward the electric field of the first electrode 1113 162130.doc • 19-201243321. By applying an asymmetric alternating current between the two electrodes (1) 3, 1114 by using the method or apparatus as described above, a unidirectional electric field can be substantially generated in the liquid. Further, in the asymmetric communication, although the direction of the electric field is alternately reversed, as described above, since the processes of step-up and step-down do not overlap, substantially: a one-way electric field. The term "substantially unidirectional" means that when the electric field vector generated in the liquid is integrated in a period of asymmetrical alternating current, a full period, or a sufficiently long time, the electric field vector is not zero but is oriented in a finite direction toward a single direction. Therefore, it does not mean that the direction of the electric field vector always faces a single direction. In fact, in the case where asymmetric communication is applied, the direction of the electric field vector is reversed by the period of the asymmetric alternating current. Thus, the unidirectional electric field is substantially generated. Since oxidation and reduction alternately occur as described above, the liquid hardly occurs. The reaction will be almost impossible to happen. However, applying a symmetrical alternating current: the situation, = the corrosion of the electrode is not easy to occur, but the unidirectional electric field cannot be generated. Therefore, the case where an asymmetric alternating current is applied is the same as the direct current, and a unidirectional electric field can be generated in the liquid and the alternating phase with the electric field can suppress the electrode rot silver caused by the liquid electrolysis or the electrochemical reaction. In the present embodiment, since both the first electrode 1113 and the second electrode 1114 are in direct contact with the liquid 1112, DC current flows when DC is applied between the two electrodes. Therefore, it is preferable that the asymmetric alternating current does not have a substantial direct current component, i.e., the vev which integrates the voltage V(1) between the second electrode and the second electrode through one cycle of the alternating current is substantially 〇. The reason is that because of the fact that in the 162130.doc •20·201243321 step, the grounding does not flow a pure DC current between the two electrodes, so it can be moved to avoid the liquid electrolysis or electrochemical reaction. Corruption 0: The preferred example of the two-t-symmetric alternating current is the asymmetrical moment shown in Figure 2(b). The potential duration and the low-potential duration* are the same as the rectangular rectangular wave because it is used to generate the waveform. The circuit is relatively simple and can effectively generate a unidirectional electric field 1 in the liquid. In the case of the circle 2 (8), the two potentials have a short duration and a low potential duration, and the length of the high 2 bits is shortened and the length is shortened. The potential duration can be reversed by the direction of the substantially unidirectional electric field generated by the liquid ^. As the asymmetric communication, it is also possible to use the asymmetric triangular wave shown in Fig. 2(c) (rise time and fall time is the same as m mineral tooth wave). Similarly, such a triangular wave is relatively simple in that the circuit for generating a waveform can effectively generate a unidirectional electric field in the liquid. In addition, in this example, the rise time is short and the fall time is long. However, if the rise time is extended and the fall time is shortened, the direction of the substantially unidirectional electric field generated in the liquid can be reversed. FIG. 2(b) or FIG. The reason why the waveform of (c) is better is explained in detail together with the explanation of the simulation result described later. &lt;Embodiment 2&gt; An electric field generating device and an electric field generating method for generating an electric field in a liquid in a liquid according to a second embodiment of the present invention will be described with reference to Fig. 6 . This embodiment differs from the first embodiment in that at least one of the first electrode and the second electrode is covered with an insulating film. 162130.doc -21- 201243321 Figure 6 is a schematic cross-sectional view of a device 1200 for generating an electric field in a liquid in the present embodiment. The container 1211 is filled with a liquid 1212. At least a portion of the second electrode 1213 and the second electrode 1214 are immersed in the liquid 1212. The second electrode 1213 and the second electrode 1214 are covered by the insulating film 1216, and an alternating current source 1215 for generating an asymmetrical alternating current is connected. Here, the container 1211 is only required to hold the liquid 丨2丨2. The liquid 1212 is preferably one having a smaller ion concentration. For example, an alcohol such as ethanol, methanol, IPA (Is〇pr〇Pyl Alcohol: isopropanol), an organic solvent such as light oil essence or acetone, or the like is preferable. In the case of using water, it is preferred to use pure water, no ion water or the like. The first electrode 1213 and the second f-pole 1214 may have sufficient conductivity. Further, the case of §H is the same as that of the first embodiment. In order to make the orientation and intensity of the electric field between the two electrodes uniform, it is preferable that the first electrode 1213 and the second electrode 1214 are disposed to face each other. Correctly control the movement of a charged object in a liquid to a one-way movement or electrophoresis. As the insulating film 1216, a tantalum oxide film, a tantalum nitride film, a resin film, or the like can be used. Further, the insulating film 1216 is formed to cover the entire electrode. For example, when the electrode is formed of a metal such as copper, gold, tungsten, aluminum or the like, or a semiconductor material to which a conductive impurity is added, 10 nm to 2 μm can be formed. The film thickness of the stone is etched on the left and right. The insulating film may be formed by a well-known prior art, for example, a CVD (Chemical Vapor Deposition) method. The asymmetric communication generated in the alternating current power source 1215 and applied to the first electrode 1213 and the second electrode 162130.doc -22·201243321 1214 can be, for example, as shown in Fig. 2 or Fig. 3. V of Figs. 2 and 3 is a voltage applied to the first electrode 1213 with the second electrode 1214 as a reference voltage. At this time, for example, when the asymmetric alternating current shown in FIG. 2 is applied, the direction of the electric field substantially generated in the liquid 1212 is toward the right (the direction of the arrow symbol 1217 in FIG. 6). Further, for example, the asymmetric alternating current can be used in FIG. The communication of the waveforms shown in the figure. The waveforms shown in Figures 7(a), (b), (4), and (d) are applied to the DC components Vsa, Vsb, Vsc, and Vsd in Figures 2(a), (b), (4), and (d), respectively. The waveform shown. The waveform shown in FIG. 2 is such that the average voltage is 〇 during one cycle of the alternating current, but the waveform shown in FIG. 7 is not. However, since the first electrode 1213 and the second electrode 1214 are covered by the insulating film 1216, Therefore, no direct current flows between the two electrodes. Therefore, even if it is a waveform as shown in Fig. 7, there is no particular adverse effect, and a unidirectional electric field can be substantially generated in the liquid 1212. In the present embodiment, the second electrode 1213 and the second electrode 1214 are covered by the insulating film 1216, but any one of the electrodes may be covered with the insulating film 1216. This also prevents direct current from flowing between the two electrodes. The preferred frequency and voltage of the asymmetrical current may be set in the same manner as in the embodiment. In the second embodiment, since at least one of the second electrode and the second electrode is covered by the insulating film 1216, a direct current does not flow between the two electrodes. That is, since direct electron movement occurs between the electrode and the liquid, oxygen or 162130.doc •23·201243321 does not occur. Therefore, it is possible to reliably prevent problems such as electrode corrosion caused by liquid electrolysis or electrochemical reaction. Further, since at least one of the first electrode and the second electrode is covered with the insulating film, there is no case where direct electrons flow from the first electrode to the second electrode to flow a current. Therefore, the power consumed during the period is only a charge and discharge depending on the capacitance of the insulating film covering the electrodes. Therefore, the power consumption can be significantly reduced and the generation of Joule heat can be significantly reduced. The case of the second embodiment is also preferably a waveform of Fig. 2 (b) or Fig. 2 (c). &lt;Simulation&gt; Hereinafter, the results of simulating the electric field generated in the liquid and the movement of the charged object in the case where such an asymmetric alternating current is applied to the two electrodes in the liquid will be described. (1) Simulation model The simulation results of the electric field generated by the application of the asymmetric alternating current to the two electrodes immersed in the liquid and the movement of the charged object will be described with reference to Figs. 8 to 26 . Fig. 8 is a view for explaining a phenomenon in which a certain DC voltage is applied to two electrodes immersed in a liquid from time τ = 0. The liquid 1212 is filled between the first electrode 1213 and the second electrode 1214. When the first electrode 1213 and the second electrode 1214 are covered by the insulating film 1216, respectively, the current does not flow between the two electrodes. A power source 1215 is connected to the first electrode 1213 and the second electrode 1214. When Τ = 0, a voltage is applied from the power source 1215 to the first electrode 1213 and 162130.doc -24 - 201243321 the second electrode 1214 ' is as shown in Fig. 8 (a), in the liquid 1212, at the arrow symbol 1217 An electric field is generated in the direction indicated. In the liquid, there are positive ions and negative ions depending on the concentration of the liquid. Therefore, after the elapse of the time T1 from the voltage application time, as shown in Fig. 8(b), on the insulating film 1216 covering the first electrode and the second electrode, charges opposite to the charges induced by the respective electrodes start to concentrate. The electric charge induced on the insulating film 1216 terminates the electric power line generated by the electric charges induced by the respective electrodes, so the intensity of the electric field in the liquid 1212 gradually becomes weak as time passes. After a sufficient time T2 has elapsed since the application of the voltage, as shown in Fig. 8(c), the electric field induced in the electric charge induced by each electrode is completely terminated by the electric charge induced on the insulating film 1216, so the electric field strength in the liquid 1212 Is 0. The time (time constant) required until the electric field in the liquid is almost enthalpy depends on the concentration of ions present in the liquid, and the smaller the ion concentration, the longer it takes. For example, it is within 10 seconds in IPA and within 1 second in pure water. It is shorter in water in which salts are dissolved. Thus, in order to allow movable ions to exist in the liquid and to concentrate on the insulating film of the electrode, it has been difficult to continuously generate a unidirectional electric field in the liquid even if a voltage is applied to the electrode immersed in the liquid. Further, when a DC voltage is applied to a bare electrode that is not covered with an insulating film, a unidirectional electric field can be continuously generated in the liquid, but if the unidirectional electric field continues, electrode corrosion occurs due to liquid electrolysis or electrochemical reaction. The problem. 162130.doc •25· 201243321 In addition, when an alternating voltage is applied between two electrodes covered with an insulating film, an alternating electric field can be generated in the liquid. When the alternating current is applied between the two electrodes, the reciprocal of the frequency is smaller than the above-described time constant, and the electric charge induced by the electrode cannot follow the change with the potential of the electrode, so that the liquid intrudes into the electric field. However, the electric field in the liquid has an average time of 〇 and cannot generate a unidirectional electric field in the liquid. An explanatory diagram of the model of the simulation is shown in Fig. 9 and Fig. 1A. As shown in Fig. 9, the second electrode 1313 and the second electrode 1314 are covered by an insulating film 1316, respectively. The liquid 1312 is filled between the two electrodes 1313 and 1314 covered by the insulating film 1316. A power source 1315 capable of generating an arbitrary waveform is connected to the first electrode 1313 and the second electrode 1314. In the liquid 1312, the charged object 1318 is floated. Using such a model, consider the simulation below. A ground potential ((}&gt;11) is applied to the second electrode 1314, and a voltage V(t) is applied to the first electrode 13 13 at time 1. When the system is not charged, the charge induced on the surface of the ith electrode 1313 is applied. The amount of charge induced on the insulating film 1316 covering the first electrode 1313 is taken as qs(1)', and the amount of charge induced on the second electrode 1314 is -qe(t)'. The insulating film covering the second electrode 1314 is covered. The amount of charge induced on 1316 is -qs(t). The dielectric constant of the insulating film 13 16 is set. The dielectric constant of the liquid 1312 is set to . %. Here, % and €3 are the dielectric constants of the insulating film 1316 and the liquid 1312, respectively. It is the dielectric constant in vacuum. Further, the intensity of the electric field in the liquid is set to E(t). When the capacitance of both ends of the insulating film 1316 on the first electrode 丨3丨3 is taken as Cd1, the capacitance at both ends of the insulating film 1316 on the second electrode 1314 is taken as 162130.doc -26-201243321

Cd2’將液體1312之兩端之電容作為cs,則·· [數1]Cd2' takes the capacitance of both ends of the liquid 1312 as cs, then · [·1]

Cdl = 8d80-~ (1)Cdl = 8d80-~ (1)

Cd2=sd80-^ (2)Cd2=sd80-^ (2)

Cs —S(i£〇~(3) 中ddl 及ds为別為覆蓋第1電極1313之絕緣膜1316 之厚度、覆蓋第2電極1314之絕緣膜1316之厚度、及液體 1312之厚度。電極之面積設為1。 此時,宰聯連接cdl、cs及Cd2之3個電容之模型整體之電 容CA表示如下: [數2] _J___L , 1 1In the case of Cs - S (i), dd and ds are the thickness of the insulating film 1316 covering the first electrode 1313, the thickness of the insulating film 1316 covering the second electrode 1314, and the thickness of the liquid 1312. The area is set to 1. At this time, the capacitance CA of the model of the three capacitors connecting the cdl, cs, and Cd2 of the slaughter is expressed as follows: [Number 2] _J___L , 1 1

Ca - cdl +~c: (4) 另一方面,將液體1312作為導電體,串聯連接Cdi與cd2 之2個電容之情形之整體電容(^表示如下: [數3] _i___L_ 1Ca - cdl +~c: (4) On the other hand, the liquid 1312 is used as a conductor, and the overall capacitance of the two capacitors of Cdi and cd2 is connected in series (^ is expressed as follows: [Number 3] _i___L_ 1

Cb ~ cdl +~c^7 ⑺ 此處,使用圖10說明電源1315產生任意之波形之情形之 模擬之指針。 首先,考慮將波形依較短時間分割。藉由思考每該時 間Δί瞬時使電壓變化之電壓變化步階與不使電壓變化之電 壓固定步階之2階段’用階梯狀之步階求取任意之波形之 近似。 I62130.doc •27·Cb ~ cdl +~c^7 (7) Here, a pointer for simulating the case where the power supply 1315 generates an arbitrary waveform will be described using FIG. First, consider splitting the waveform in a shorter time. By considering each time Δί instantaneously, the voltage change step of the voltage change and the voltage step of the step of not changing the voltage are fixed, and the step of the step is used to obtain an approximation of the arbitrary waveform. I62130.doc •27·

S 201243321 (a) 電壓變化步驟 在此電壓變化步驟中,設電壓瞬時變化^乂^者。此 時,在電壓之變化下,液體中之離子無法追隨移動。即, qs⑴及-qs(t)不變。惟,由於電極之電荷與液體中之離子相 比移動速度夠快,故設qe⑴及-qe(t)立即追隨電壓變化 △V⑴而變化。此時,2個電極間之電容如Ca般誘發。 藉由以上所示,電壓變化步驟中以下之式成立。S 201243321 (a) Voltage change step In this voltage change step, set the voltage to change instantaneously. At this time, the ions in the liquid cannot follow the movement under the change of the voltage. That is, qs(1) and -qs(t) are unchanged. However, since the charge of the electrode is faster than the ion in the liquid, qe(1) and -qe(t) are immediately changed following the voltage change ΔV(1). At this time, the capacitance between the two electrodes is induced like Ca. As shown above, the following equation in the voltage change step is established.

Aqe(t)=CAAV(t) (6) △qs ⑴=〇 (7) 此處,及Aqs⑴根據時刻t之電壓變化avg)而分別表 示qe⑴及qs(t)變化之量。 (b) 電壓固定步驟 該電壓固定步驟中,設電壓不變化而經過時間仏者。電 壓不變化之情形’如圖8中說明所示,爲了減弱液體中之 電場’即爲使液體中之離子移動至接近平衡狀態,qs⑴變 化。所謂平衡狀態是指液體中之電場為〇之狀態,可將液 體視為導電體。因此,可將2個電極間之電容視為CB。 又,由於qs(t)變化,Aqe⑴亦變化。 基於上述之故,qs(t)之變化可用下式表示: [數4] qs ( t+Δί) - qs ( t)Aqe(t)=CAAV(t) (6) Δqs (1)=〇 (7) Here, and Aqs(1) represent the amount of change of qe(1) and qs(t), respectively, according to the voltage change avg) at time t. (b) Voltage fixing step In the voltage fixing step, it is assumed that the voltage does not change and the elapsed time is exceeded. The case where the voltage does not change 'As shown in Fig. 8, in order to weaken the electric field in the liquid, the qs(1) changes in order to move the ions in the liquid to a near equilibrium state. The equilibrium state refers to a state in which the electric field in the liquid is 〇, and the liquid can be regarded as a conductor. Therefore, the capacitance between the two electrodes can be regarded as CB. Also, since qs(t) changes, Aqe(1) also changes. Based on the above, the change of qs(t) can be expressed by the following formula: [Number 4] qs ( t+Δί) - qs ( t)

At =-a{qs(t)-qeq(t)}n (8) 此處’ qeq(t)為時間t之qs⑴之平衡狀態之值,且滿足以下 關係: 162130.doc •28· 201243321 qeq(t)=cB v(t) (9) n為規定qs⑴之變化率與q⑴之 干衡狀態之偏差{qs(t)_ qeq(t)}之關係之量。η=ι之情形,斑 興qs⑴之平衡狀態之偏差 越大則qs(t)之變化率越大,且,變仆 雙化率與平衡狀態之偏差 成正比(處於線形關係)。 另一方面,0&lt;n&lt;1之情形,變化率雖依存於與平衡狀 態之偏差(即,平衡狀態之偏差越大變化率越大),作變化 率與平衡狀態之偏差不成正比(非線形關係為表示_ 接近qeq(t)之速度之量。 由於液體中之離子濃度越高Μ⑴可越快速地變化,故 a變大。 另-方面,qe⑴之變化率可根據qs⑴之變化率如下求 得。首先,時間上’施加於2個電極間之電壓v⑴作為施加 於cdl、Cs及Cd2之兩端之電壓之和,以下式表示.At =-a{qs(t)-qeq(t)}n (8) where 'qeq(t) is the value of the equilibrium state of qs(1) at time t and satisfies the following relationship: 162130.doc •28· 201243321 qeq (t)=cB v(t) (9) n is an amount that defines the relationship between the rate of change of qs(1) and the deviation of the dry-balance state of q(1) {qs(t)_qeq(t)}. In the case of η=ι, the larger the deviation of the equilibrium state of the qs(1) is, the larger the rate of change of qs(t) is, and the divergence rate is proportional to the deviation of the equilibrium state (in a linear relationship). On the other hand, in the case of 0 &lt; n &lt; 1, the rate of change depends on the deviation from the equilibrium state (that is, the deviation of the equilibrium state is larger as the rate of change is larger), and the rate of change is not proportional to the deviation of the equilibrium state (non-linear relationship) To indicate the speed of _ close to qeq(t), the higher the ion concentration in the liquid, the faster the Μ(1) can change, so a becomes larger. On the other hand, the rate of change of qe(1) can be obtained from the rate of change of qs(1) as follows. First, the voltage v(1) applied between the two electrodes in time is the sum of the voltages applied to the two ends of cdl, Cs, and Cd2, and is expressed by the following equation.

[數5] V⑴=七(t )丨 9e ( t) +qs ( t ) Cdi Cs若計算兩邊之變化率,則為[數6] qe ( t) c d2 (10) V ( t+At) - V ( t) At qe ( t+At) — qe ( t)[Equation 5] V(1)=seven(t)丨9e(t) +qs(t) Cdi Cs If the rate of change of both sides is calculated, it is [number 6] qe ( t) c d2 (10) V ( t+At) - V ( t) At qe ( t+At) — qe ( t)

Cdi At + ~~s . ^-(t+At) -qe (t)_+ qs (t+At)_-3::_rj^ 」 Qe ( t+At ) — qe ( t )Cd2 * At ~~ (11) 另一方面,電壓固定步驟中,由於 162130.doc •29- 201243321 [數7] t) AtCdi At + ~~s . ^-(t+At) -qe (t)_+ qs (t+At)_-3::_rj^ ” Qe ( t+At ) — qe ( t )Cd2 * At ~ ~ (11) On the other hand, in the voltage fixing step, due to 162130.doc •29- 201243321 [7] t) At

V =0 (12) 故根據(11)式與(12)式,為: [數8] Η£ΐίίΔ〇_--^ (t) △t (13) ;得到qe⑴之變化率與qs⑴之變化率之關係 之液體中之電場之強度E⑴表示為: [數9] +qs (t) ε5ε〇 (14) (c)液體令之帶電物體之運動 右將物體所具有之實質之電荷量作為qcb,將黏性電阻係 數作為C ’將物體之速度作為v(t),將物體之質量作為m, 將物體之加速度作為a(t),則液體中之帶電物體受到之力 F(t)為: F(t)=q〇bE(t)-cv(t)=ma(t) (15) 藉由解出該運動方程式,可記述液體中之物體之運動。 另’若思考存在於黏度η之液體中之半徑r之球狀物體’ 則雷諾數較小時,根據斯托克定理,黏性電阻係數e表示 為 6 πηΓ 〇 (2)模擬結果 以下,將數個交流波形作為例子,說明模擬之結果。 162130.doc • 30 - 201243321 該模擬中使用之常數如下。 物體之質量爪為匕…一㈣,物體之半徑⑷嗜”㈣, 物體之實質之電荷量q〇b為3.72xl〇-14[C],液體之黏度為 8xl04[ps],電極上之絕緣膜之相對介電常數〜為4,電極 上之絕緣膜之厚度ddl及心為4xl〇-8[m] ’液體之相對介電 常數、為20,液體之厚度ds為lxl〇.2[m],常數3為1〇。 又,在無尤其不合理之情形下,常數η為0.8,qs⑴之變 化率與qs(t)之平衡i態之偏差%⑴_qeq(t)}之關係為非線 形。 [第1實施例之結果] 第1貫施例中,如圖11所示,將振幅200 V、頻率5 HZ之 非對稱之矩形波(高電位持續時間與低電位持續時間不同 之矩形波)施加於第i電極1313與第2電極1314之間。v⑴為 將第2電極1314作為基準之第1電極之電位。假設時刻。之 前未施加電壓。 此時,qs⑴及qe(t)分別如圖12及圖13般變化,除去開始 施加電壓之時刻〇附近以外,分別呈週期性變化。液體中 之電場之強度E(t)如圖14所示,除去開始施加電壓之時刻〇 附近以外呈週期性變化。 此處,圖15中,顯示自電壓施加開始經過充足之時間成 為穩定狀態時之平均電場E a v與表示非線形性之常數η之關 係。 平均電場Eav自電壓施加開始經過充足時間時,經過交 流之m期求取電場E⑴之平均。平均電場Eav不為G之情況 162130.doc 71 201243321 表示液體中實質上存在單向之電場。 表示非線形性之常數„為!時(非線形性不存在),為 〇,液體中純粹僅存在交流電場。 另一方面,隨著η變得比丨更小、即隨著非線形性變強, L變大,液體中實質上單向之電場變強。這暗示著作為 本發明之本質之液體中之實質上產生單向之電場,具有 1⑴之變化率與qs⑴之平衡狀態之偏差{qs⑴d間:非 線形f·生另,所谓Eav為正,表示圖中實質上單向之電 場為朝下。 圖16中,顯示置於液體中之帶電物體之位置χ⑴(圖⑺之 上下方向)之時間變化。 物體在時刻0於反方向(圖10之上方向)移動後,一面振 動一面於正方向(圖10之下方向)移動。這是因為電場 之時間平均Eav為正。據此可知,藉由將非對稱交流施加 於2個電極間’會使帶電物體單向移動。 自以上所述而得知,即使在電極被絕緣膜覆蓋且液體中 不流動電流之情形下,藉由將非對稱交流施加於電極間, 仍可於液體中之單向產生實質之電場,且可使物體移動。 根據非對稱之矩形波,液體中之物體於單向移動之情形 在實驗中亦得到確認,且其方向與模擬預測之方向一致。 [第2實施例之結果] 第2實施例中,如圓η所示,將振幅2〇〇 v下頻率5 Hz之 非對稱之矩形波(南電位持續時間與低電位持續時間不同 之矩形波)施加於第1電極1313與第2電極1314之間。與第1 162130.doc •32· 201243321 實施例不同的是’將圖17之V(t)於一週期内平均為〇之方 式,對圖11所示之波形施加直流偏壓。 圖18中,顯示置於液體中之帶電物體之位置x(t)之時間 變化。 雖然電壓施加後之行為與第1實施例之情形(圖丨6)不 同’但物體仍一面振動一面朝正方向移動。又,朝正方白 移動之速度與第1例之情形完全相同。 這顯示,電極被絕緣膜覆蓋之情形下,即使相對於非對 稱交流增加直流成份,仍不會對液體内部產生之電場或於 液體内部浮游之帶電物體之運動帶來影響β此事在實際之 實驗中亦得到確認。 [第3實施例之結果] 本第3實施例係施加對稱之交流者,且係為與第1及第2 實施例作比較而顯示之實施例。 第3實施例中,如圖19所示,將振幅2〇〇 ν下頻率5 Ηζ之 對稱之矩形波施加於第1電極1313與第2電極1314之間。 圖20中’顯示置於液體中之帶電物體之位置_之時間 變化。 ’’對稱之交流中, 又,亦無法實質上 物體雖振動’但不會於單向移動。即 無法於液體中產生單向之實質之電場, 使物體移動。 [第4實施例之結果] 第4實施例,如圖21所示,為振幅⑽v下頻率5 Hz之非 對稱之三角波(上升時間與下降時間不同之三角波或鋸齒 162130.doc • 33 · 201243321 波)。 在此例中,在升壓過程中電壓急劇變化,在降壓過程中 電壓緩慢變化。 此時’ qs⑴及qe⑴分別如圖22及圖23般變化,除去開始 電壓之施加之時刻0附近以外,分別呈週期性變化。液體 中之電場之強度E(t),如圖24所示,除去開始電壓之施加 之時刻0附近以外呈週期性變化。 此處,將自電壓施加開始經過充足時間成為穩定狀態時 之平均電場Eav與表示非線形性之常數n之關係,在圖25中 顯示。 表示非線形性之常數η為丨時(非線形性不存在),為 〇 ’液體中純粹僅存在交流電場。 另一方面,隨著η變得比1更小,即隨著非線形性變強, Eav變大,液體中之實質之單向之電場變強。此點與第^列 之情形(圖15)相同’但圖表之曲線之形狀不同。 圖26中,顯示置於液體中之帶電物體之位置x(t)之時間 變化。 物體一面振動一面朝正方向移動。這是因為強度E(t)之 時間平均Eav為正所致。 另,將圖21之波形變形,並施加在升壓過程中電壓緩慢 變化、在降壓過程中電壓劇烈變化之非對稱交流之情形, 根據模擬預測物體之運動方向為反方向,並在實際之實驗 中亦得到確認。 若對以上進行總結,則根據模擬結果,可預測下述之情 162130.doc •34, 201243321 形: (1) 若將非對稱交流施加於2個電極,則雖可於液體中 實質上產生單向之電場,但在對稱之交流中不行。 (2) 若將非對稱交流施加於2個電極則雖可使液體中 汗游之帶電之物體單向移動,但在對稱之交流中不行。 (3) 該等之效果係由於電極上之絕緣膜上之電荷感應速 度與自平衡狀態之偏差之大小不成正比之故。 根據該模擬模型與模擬結果,非對稱之交流於液體中實 質上產生單向之電場之理由,可如下解釋。 所謂非對稱交流,如既已定義般,係為即使使交流之升 壓過程與降壓過程其中一方之電壓軸反轉,$者仍不會重 合之交流。 若將如此之非對稱之交流施加於電極,則在升壓過程與 降麗過程中,與〜⑴之平衡狀態之偏差Us⑴-qeq(t)}各^ 相同。在該模擬之模型中,將非線形性導入1⑴之變化率 與{qs⑴-qeq(t)}之間。因此,即使將q$⑴之變化率與以式 (13)及式(14)結合而得之E(t)經過交流丨週期求取平均仍= 會為〇,而於液體令實質上產生單向之電場。 又,根據以上所述,得知較佳之非對稱之交流為升壓過 程或降壓過程中電塵劇烈變化之交流。這是因為電遷劇烈 變化之瞬間,{qs⑴_qeq⑴}變大,因而qs(t)之變化率與 {qs⑴-qeq(t)}之間之非線形性變大之故。根據該點,較佳 為如圖2(b)或圖2(c)般之非對稱之矩形波或三角波,其效 果大之點在實驗中亦得到確句、。 162130.doc •35· 201243321 另,即使為電極上無絕緣膜之情形,藉由將非對稱交流 施加於2個電極間,可實質上於液體中產生單向之電場, 又’可使帶電物體單向移動。 然而,該情形,為抑制電極之腐蝕,較佳的是,非對稱 交流不具有實質之直流成份。亦即將上述第丨電極與第2電 極之間之電壓V(t)經過交流之1週期積分得到之Veff較佳 為:V =0 (12), so according to equations (11) and (12), it is: [8] ΐ£ΐίίΔ〇_--^ (t) Δt (13) ; get the change rate of qe(1) and qs(1) The intensity E(1) of the electric field in the liquid of the relationship is expressed as: [9] +qs (t) ε5ε〇(14) (c) The movement of the charged object by the liquid right The right amount of charge of the object is taken as qcb The viscosity coefficient is taken as C', the velocity of the object is taken as v(t), the mass of the object is taken as m, and the acceleration of the object is taken as a(t), then the force F(t) of the charged object in the liquid is : F(t)=q〇bE(t)-cv(t)=ma(t) (15) By solving the equation of motion, the motion of the object in the liquid can be described. Another 'If you think about the spherical object of radius r in the liquid of viscosity η', then when the Reynolds number is small, according to Stoke's theorem, the viscous resistivity e is expressed as 6 πηΓ 2(2) below the simulation result, Several AC waveforms are used as examples to illustrate the results of the simulation. 162130.doc • 30 - 201243321 The constants used in this simulation are as follows. The mass of the object is 匕... one (four), the radius of the object (4) is “(4), the substantial charge of the object q〇b is 3.72xl〇-14[C], the viscosity of the liquid is 8xl04[ps], the insulation on the electrode The relative dielectric constant of the film is 4, the thickness ddl of the insulating film on the electrode and the core is 4xl 〇 -8 [m] 'the relative dielectric constant of the liquid is 20, and the thickness ds of the liquid is lxl 〇.2 [m ], the constant 3 is 1 〇. Further, in the case where there is no particular irrationality, the constant η is 0.8, and the relationship between the rate of change of qs(1) and the deviation of the equilibrium i state of qs(t) %(1)_qeq(t)} is non-linear. [Results of the first embodiment] In the first embodiment, as shown in Fig. 11, an asymmetric rectangular wave having an amplitude of 200 V and a frequency of 5 HZ (a rectangular wave having a high potential duration and a low potential duration) is used. It is applied between the i-th electrode 1313 and the second electrode 1314. v(1) is the potential of the first electrode using the second electrode 1314 as a reference. The time is assumed. No voltage is applied before. qs(1) and qe(t) are respectively shown in the figure. 12 and FIG. 13 change periodically, except for the vicinity of the time when the voltage is applied, and periodically change. The intensity of the electric field in the liquid E(t) As shown in Fig. 14, the periodic change is made except for the vicinity of the time when the application of the voltage is started. Here, in Fig. 15, the average electric field E av and the constant indicating the nonlinearity are shown when the sufficient time has elapsed since the voltage application is applied. The relationship between η. The average electric field Eav is obtained by averaging the electric field E(1) through the m period of the alternating current when the voltage is applied. The average electric field Eav is not G. 162130.doc 71 201243321 indicates that there is substantially one-way in the liquid. Electric field. Constant representing non-linearity „ is! Time (non-linearity does not exist), 〇, there is purely an alternating electric field in the liquid. On the other hand, as η becomes smaller than 丨, that is, as the nonlinearity becomes stronger, L becomes larger, and the substantially unidirectional electric field in the liquid becomes stronger. This implies that the work is essentially a one-way electric field in the liquid of the essence of the invention, and has a deviation between the rate of change of 1(1) and the equilibrium state of qs(1) {qs(1)d: non-linear f·sheng, so-called Eav is positive, indicating The substantially unidirectional electric field is facing downwards. In Fig. 16, the time change of the position χ(1) (up and down direction of Fig. 7) of the charged object placed in the liquid is shown. When the object moves in the opposite direction (upward direction in Fig. 10) at time 0, the vibration moves in the positive direction (the direction below Fig. 10). This is because the time average Eav of the electric field is positive. From this, it can be seen that the charged object is unidirectionally moved by applying an asymmetric alternating current between the two electrodes. As described above, even in the case where the electrode is covered by the insulating film and no current flows in the liquid, by applying an asymmetric alternating current between the electrodes, a substantial electric field can be generated in one direction in the liquid, and Move the object. According to the asymmetric rectangular wave, the case where the object in the liquid moves in one direction is also confirmed in the experiment, and its direction is consistent with the direction of the simulation prediction. [Results of the second embodiment] In the second embodiment, as shown by the circle η, an asymmetric rectangular wave having a frequency of 2 〇〇v and a frequency of 5 Hz (a rectangular wave having a south potential duration and a low potential duration) ) is applied between the first electrode 1313 and the second electrode 1314 . The difference from the first embodiment is that the V(t) of Fig. 17 is averaged as 〇 in one cycle, and a DC bias is applied to the waveform shown in Fig. 11. In Fig. 18, the time variation of the position x(t) of the charged object placed in the liquid is shown. Although the behavior after the voltage application is different from that of the first embodiment (Fig. 6), the object moves while moving in the positive direction while vibrating. Moreover, the speed of moving toward the square is exactly the same as in the case of the first example. This shows that in the case where the electrode is covered by the insulating film, even if the DC component is added with respect to the asymmetric alternating current, the electric field generated inside the liquid or the movement of the charged object floating inside the liquid is not affected. It was also confirmed in the experiment. [Results of the third embodiment] The third embodiment is a symmetrical alternating current, and is an embodiment shown in comparison with the first and second embodiments. In the third embodiment, as shown in Fig. 19, a symmetrical rectangular wave having a frequency of 5 振幅 at an amplitude of 2 〇〇 ν is applied between the first electrode 1313 and the second electrode 1314. In Fig. 20, 'the time change of the position of the charged object placed in the liquid is shown. In the symmetrical communication, it is impossible to substantially vibrate the object, but it does not move in one direction. That is, it is impossible to generate a one-way substantial electric field in the liquid to move the object. [Results of the fourth embodiment] The fourth embodiment, as shown in Fig. 21, is an asymmetrical triangular wave having a frequency of 5 Hz at an amplitude of (10) v (a triangular wave or sawtooth having a different rise time and fall time 162130.doc • 33 · 201243321 ). In this case, the voltage changes abruptly during the boosting process, and the voltage changes slowly during the step-down process. At this time, 'qs(1) and qe(1) are changed as shown in Fig. 22 and Fig. 23, respectively, and periodically change except for the vicinity of time 0 at which the start voltage is applied. The intensity E(t) of the electric field in the liquid, as shown in Fig. 24, periodically changes except for the vicinity of the time 0 at which the start voltage is applied. Here, the relationship between the average electric field Eav when the sufficient time has elapsed from the application of the voltage and the constant n indicating the non-linearity is shown in Fig. 25. When the constant η indicating the non-linearity is 丨 (non-linearity does not exist), there is purely an alternating electric field in the 〇 'liquid. On the other hand, as η becomes smaller than 1, that is, as the nonlinearity becomes stronger, Eav becomes larger, and the substantial one-way electric field in the liquid becomes stronger. This point is the same as in the case of the column (Fig. 15) but the shape of the curve of the graph is different. In Fig. 26, the time variation of the position x(t) of the charged object placed in the liquid is shown. The object moves in the positive direction while vibrating. This is because the time average Eav of the intensity E(t) is positive. In addition, the waveform of FIG. 21 is deformed, and a situation in which the voltage is slowly changed during the step-up process and the voltage is drastically changed during the step-down process is applied, and the direction of motion of the object is predicted to be the opposite direction according to the simulation, and in practice It was also confirmed in the experiment. If the above is summarized, according to the simulation results, the following can be predicted 162130.doc • 34, 201243321 Shape: (1) If asymmetric AC is applied to two electrodes, the substance can be substantially produced in the liquid. To the electric field, but not in the symmetrical communication. (2) If an asymmetric alternating current is applied to two electrodes, the charged object in the liquid can be moved in one direction, but not in a symmetrical alternating current. (3) These effects are not proportional to the magnitude of the deviation between the charge sensing speed on the insulating film on the electrode and the self-balancing state. Based on the simulation model and the simulation results, the reason why the asymmetric exchange generates a unidirectional electric field in the liquid substantially can be explained as follows. The so-called asymmetric communication, as defined, is such that even if the voltage axis of one of the voltage rise and reverse steps of the AC is reversed, the $ will not overlap. If such an asymmetric alternating current is applied to the electrodes, the deviations Us(1)-qeq(t)} of the equilibrium state of ~(1) are the same in the boosting process and the falling process. In the model of the simulation, the non-linearity is introduced between the rate of change of 1(1) and {qs(1)-qeq(t)}. Therefore, even if the rate of change of q$(1) is compared with E(t) obtained by combining equations (13) and (14), the average is still 〇, and the liquid order is substantially To the electric field. Further, based on the above, it is known that the preferred asymmetric AC is an alternating current in which the electric dust changes drastically during the step-up or step-down process. This is because {qs(1)_qeq(1)} becomes larger at the moment when the electromigration changes drastically, so the non-linearity between the rate of change of qs(t) and {qs(1)-qeq(t)} becomes larger. According to this point, it is preferably an asymmetrical rectangular wave or a triangular wave as shown in Fig. 2(b) or Fig. 2(c), and the effect is large in the experiment. 162130.doc •35· 201243321 In addition, even if there is no insulating film on the electrode, by applying asymmetric alternating current between the two electrodes, a unidirectional electric field can be generated substantially in the liquid, and the charged object can be made One-way movement. However, in this case, in order to suppress corrosion of the electrode, it is preferable that the asymmetric alternating current does not have a substantial direct current component. That is, the Veff obtained by integrating the voltage V(t) between the second electrode and the second electrode through one cycle of the alternating current is preferably:

Veff= /V(t)dt=0 (16) 藉由如此般使積分值為〇,由於2個電極間未流動純正之 直流電流,故幾乎不會發生液體電解,也不會發生電化學 反應。因此,可抑制電極腐蝕。 然而’ qs(t)達到平衡狀態之時間(與a之倒數成正比之時 間常數)較非對稱交流之頻率之倒數更短之情形,由於電 場無法侵入液體中,故亦不會產生單向之電場。又,由於 爲了使qs⑴發生變化’有必要使散佈於液體中之離子在液 體中移動並在電極上集中,故液體之離子濃度越高上述時 間常數變得越短。 因此,液體中之離子濃度較高之情形,為使電場侵入液 體中並使單向之電場產生,而有必要使電極之電位更快速 地變化,故有必要提高非對稱交流之頻率。 另一方面,液體中之離子濃度較低之情形,由於上述時 間常數可非常容易地使qs⑴自平衡狀態大幅遠離(即增大 {qs(t)-qeq(t)}),故可容易地產生單向之電場。 根據以上之理由,液體中之離子濃度越低越可有效地於 I62130.doc -36· 201243321 液體中產生單向之電場’又,由於降低非對稱交流之頻 率,故較佳。 &lt;實施形態3 &gt; 使用圖27說明作為本發明之第3實施形態之於液體中浮 游之物體移動之浮游體移動裝置及浮游體移動方法。 圖27中顯示本實施形態之使液體中浮游之物體移動之浮 游體移動之裝置2100之概略剖面圖。 容器2111充滿液體2112。第1電極2113與第2電極2114其 中至少一部份浸於液體2112中。第1電極2113與第2電極 2 114上’連接有產生非對稱之交流之交流電源2丨丨5 » 此處’容器2111與實施形態1相同,只要為可保持液體 2112者即可。液體2112與實施形態1相同,較佳為離子濃 度較小者。 施加於第1電極2113與第2電極2114之非對稱交流亦同樣 地’只要使用圖2或圖3中所示者即可。例如,將第2電極 2114作為基準電壓而施加圖2中所示之非對稱交流時,於 液體2112内實質上產生之電場之朝向為朝右(圖27之箭頭 符號2117之朝向)。 因此,於液體中浮游之物體2118帶負電之情形,如圖27 所示朝左(圖27之箭頭符號2119之朝向)移動。物體以“帶 正電之情形,朝反方向(朝右)移動。 非對稱交流之較佳之頻率及電壓只要與實施形態丨同樣 地設定即可。 ’ 於液體中浮游之物體2118只要實質上帶電即可。 162130.doc £ -37· 201243321 所謂實質上帶電’意味著可將物體中產生之電荷作為物 體2118與液體2112之界面誘發之電荷、與利用其電荷而於 物體附近之液體中誘發並與固體一起移動之電荷之總和。 換言之’可以說液體中之界達電位不為〇。 使用實質上不帶電之物體之情形,可使用非離子系之界 面活性劑改變物體之界達電位。 物體之具體例’例如為自納米級尺寸1 mm以下之尺寸 之介電體微粒子、半導體微粒子 '金屬微粒子、細微之半 導體元件、細胞、DNA、RNA、蛋白質等。 如此,藉由將非對稱之交流施加於第1電極2113與第2電 極2114,而於液體1112内實質上於單向產生電場且可使 液體2112中浮游之物體2118單向移動。該移動原理與上述 之模擬相同。 於液體1112中,實質上使電場於單向產生之步驟主要包 含以下步驟: (1) 將物體2118浮游之液體2112注入容器2111之準備步 驟; (2) 將第1電極2113與第2電極2114以各自至少一部份浸 於液體2112之方式,空出特定之間隔而配置之配置步驟; (3) 將非對稱交流施加於第丨電極2113與第2電極MM之 間,並使液體2112中浮游之物體2118自第丨電極2113向第2 電極2114移動、或使上述物體自第2電極2114向第1電極 2113移動之移動步驟。 藉由使用如上所述之方法或裝置,將非對稱之交流施加 162130.doc -38 201243321 於2個電極2113、2114間,可使液體2112内浮游之物體 2 11 8於單向移動。 因此’由於為使液體内浮游之物體於單向移動,而利用 非對稱交流施加實質之單向之電場,故可抑制因液體電解 或電化學反應而引起電極腐蝕。 本實施形態中’第1電極2113與第2電極2114任一者皆與 液體2112直接接觸’故若將直流施加於2個電極間則直流 電流流動。因此’與上述實施形態1相同,為避免發生腐 姓’較佳的是’非對稱交流不具有實質之直流成份,亦即 使上述第1電極與第2電極之間之電壓v⑴經過交流之1週期 積分而得之Veff實質上為〇。 又,根據與實施形態1相同之理由,為使液體中浮游之 物體有效率地單向移動,作為非對稱交流,較佳為圖2(b) 或圖2(c)之波形。 &lt;實施形態4 &gt; 使用圖2 8說明作為本發明之第4實施形態之使液體中浮 游之物體移動之浮游體移動裝置及浮游體移動方法。 本實施形態與實施形態3不同的是,第1電極與第2電極 之至少一方被絕緣膜覆蓋。 圖28中顯示使本實施形態之液體中浮游之物體移動之浮 游體移動之裝置2200之概略剖面圖。 容器2211充滿液體2212。第1電極2213與第2電極2214其 中至少一部份浸於液體2212中。第1電極2213與第2電極 2214被絕緣膜2216覆蓋,且連接有產生非對稱之交流之交 162130.doc •39· 201243321 流電源2215。 此處,容器2211與實施形態1相同,只要為可保持液體 2212者即可。液體22〗2較佳為離子濃度較小者。絕緣膜 2216與實施形態2相同,可使用矽氧化膜、矽氮化膜、樹 脂薄膜等β 施加於第1電極2213與第2電極2214之非對稱交流亦同樣 地,只要使用圖2或圖3中所示者即可。例如,將第2電極 2214作為基準電壓而施加圖2中所示之非對稱交流時,於 液體2212内貫質上產生之電場之朝向為朝右(圖28之箭頭 符號2217之朝向)。 因此液體中浮游之物體2218帶負電之情形,如圖28所 不,朝左(圖28之箭頭符號2219之朝向)移動。物體2218帶 正電之情形’朝反方向(朝右)移動。 又,非對稱交流與實施形態2相同,亦可使用圖7中所示 之波形之交流。由於第i電極2213及第2電極2214被絕緣膜 22 16覆蓋,且由於2個電極間不會流動直流電流,故即使 為如圖7中所示之波形,亦不會有特別不良之影響,可使 液體22丨2中浮游之物體2218單向移動。又,本實施形態 中’只要任一方之電極被絕緣膜2216覆蓋即可。 非對稱交流之較佳之頻率及電壓只要與實施形態^目同 地設定即可。 又,液體中浮游之物體2218只要實質上帶電即可。物體 之具體例可使用與實施形態3中所示者相同者。 如此,即使在以絕緣膜覆蓋電極之至少一方之情形下, 162130.doc •40· 201243321 藉由將非對稱之交流施加於第1電極2213與第2電極2214, 而於液體2212内實質上於單向產生電場,可使液體2212中 浮游之物體2218於單向移動。 實施形態4中,由於第1電極及第2電極之至少一方被絕 緣膜覆蓋,故2個電極間不會流動直流電流❶因此,可確 實地防止因液體電解或電化學反應而引起電極腐蝕等之問 題。又,由於第1電極及第2電極之至少一方被絕緣膜覆 蓋,故電子不會自第丨電極直接到達第2電極而流動電流。 因此’該線路中消耗之電力僅為取決於覆蓋電極之絕緣膜 所構成之電容之充放電者。因此,可顯著減少消耗電力, 且可顯著減少焦耳熱之產生。 該實施形態4之情形亦較佳為圖2(b)或圖2(匀之波形。 &lt;實施形態5 &gt; 使用圖29說明作為本發明之第5實施形態之於液體中浮 游之物體移動之浮游體移動裝置及浮游體移動方法。 本實施形態與實施形態4不同的是,於第1電極及第2電 極形成於對向之2個基板上’液體中浮游之物體在該2個電 極間於單向移動。 圖29中顯示使本實施形態之液體中浮游之物體移動之浮 游體移動之裝置2300之概略剖面圖。 第1基板2321與第2基板2322對向,其間充滿液體2312。 第1基板2321之與液體2312接觸之側之表面上,形成有第1 電極2313。在第2基板2322之與液體2312接觸之側上,形 成有第2電極23 14。 162130.doc • 41 - 201243321 第1電極2313及第2電極2314之表面上形成有絕緣膜 2316,防止第1電極2313與第2電極2314之間流動直流電 流。又’第1電極2313與第2電極2314中,於未被絕緣膜 2 3 16覆蓋之側上’連接有產生非對稱之交流之交流電源 2315。 此處’作為第1基板2 3 21及第2基板2 3 2 2,可使用玻璃、 樹脂、陶瓷等之絕緣體。 液體23 12與實施形態1相同,較佳為離子濃度較小者。 施加於第1電極23 13與第2電極23 14之非對稱交流亦同樣 地’只要使用圖2或圖3中所示者即可。例如,將第2電極 23 14作為基準電壓而施加圖2中所示之非對稱交流時,液 體23 12内實質上產生之電場之朝向為朝下(圖29之箭頭符 號2317之朝向)。 因此,於液體中浮游之物體23 18帶負電之情形,如圖29 所示,朝上(圖29之箭頭符號2319之朝向)移動。物體2318 帶正電之情形,朝反方向(朝下)移動。 圖29中,第1電極2313較第2電極2314在鉛直方向上配置 於更上方。該情形亦同,即使如圖29般使電場之朝向為鉛 直方向朝下’物體仍朝與重力反方向之上方向移動。 另’對向之一對之電極之配置並不限於圖29中所示者, 例如’第1電極及第2電極並不是各一塊之電極,亦可為各 自分割為複數之電極並隔開間隙而配置。或2個電極可為 網狀。如此之情形’藉由與透明之基板組合,可自外部觀 察液體中浮游之物體。 162130.doc 42· 201243321 又’非對稱交流與上述之實施形態2相同,亦可使用圖7 中所示之波形。即使為如圖7中所示之波形,仍不會有特 別不良之影響,可使液體2312中浮游之物體2川於單向移 動。只要任一方之電極被絕緣膜2316覆蓋即可,在該情形 下,仍可防止直流電流於2個電極間流動。 非對稱交流之較佳之頻率及電壓只要與實施形態i相同 地設定即可。 又,液體中浮游之物體2318只要實質上帶電即可。物體 之具體例只要使用與實施形態相同者即可。 另,如本實施形態般’ 2個電極形成於2個對向之基板 上,於2個基板之間充滿物體浮游之液體之情形,可如下 利用物體之移動。 多數之物體2318在液體2312中浮游,重力作用於圖“之 朝下方向。即,朝下設置第2基板2322。該情形,若對2個 電極2313、2314施加單向電場朝上之非對稱交流,則由於 附加重力,故可使物體2318快速地移動至第2基板UK 側。即,可使物體231 8快速地沉澱。 又,若對2個電極2313、2314施加單向電場朝下之如圖 29般之非對稱交流,使物體23 18朝上移動,則可防止物體 2318因重力而下沉。 使用如上所述之方法或裝置,藉由將非對稱之交流施加 於2個電極2313、23 14間,可使液體23 12内浮游之物體 2318於單向移動。 又由於第1電極及第2電極之至少一方被絕緣膜覆蓋, 162130.doc -43- 201243321 故2個電極間不會流動直流電流。因此,可確實地防止因 液體電解或電化學反應而引起電極腐蝕等之問題。又,由 於第1電極及第2電極之至少一方被絕緣膜覆蓋,故電子不 會自第1電極直接到達第2電極而流動電流。因此,該線路 中消耗之電力僅為取決於覆蓋電極之絕緣膜所構成之電容 之充放電者。因此,可顯著減少消耗電力,且可顯著減少 焦耳熱之產生。 本實施形態5之情形亦較佳為圖2(b)或圖2(c)之波形。 &lt;實施形態6 &gt; 使用圖3 0說明作為本發明之第6實施形態之電泳裝置及 電泳方法。 圖30中顯示本實施形態之電泳裝置3〗〇〇之概略剖面圖。 於容器3123之兩側設置有第1電極3113及第2電極3114。 第1電極3113與第2電極3114上連接有產生非對稱之交流之 交流電源3115 »第1電極3113及第2電極3114之表面上形成 有絕緣膜3 116。 進行電泳時’以特定之液體充滿容器3123,且在容器 3123内設置形成有井3125之瓊脂醣凝膠3124。井3125係用 以注入試樣之洞。 其次’將DNA等之試樣注入井3 125,且將非對稱之交流 施加於第1電極3113與第2電極3114。藉此可進行使試樣於 特定之方向移動之電泳。 作為上述液體,在先前之電泳中,由於使直流電流在2 個電極間流動’故使用具導電性者。然而,本實施形態 162130.doc •44· 201243321 中’由於液體之離子濃度小較容易於液體中產生單向之電 場從而使試樣泳動,故較佳為使用純水等離子濃度小且不 會使試樣改質者。 施加於第1電極3 113與第2電極3 114之非對稱交流,例如 使用圖2或圖3争所示者》例如,將第2電極3114作為基準 電壓而施加圖2中所示之非對稱交流時,液體内實質上產 生之電場之朝向為朝右(圖3〇之箭頭符號3117之朝向)。因 此,液體中之試樣帶負電之情形,如圖3〇所示,朝左(圖 30之箭頭符號3119之朝向)移動。由於試樣在瓊脂醣凝膠 3124中前進之距離因試樣之分子量而異,故可將試樣中所 含之分子等分離,而可使試樣之分子量可視化。 又,非對稱父流與實施形態2相同,亦可使用圖7中所示 之波形之交流。即使為如圖7中所示之波形,亦不會有特 別不良之影響,仍可進行電泳。丨,只要任一方之電極被 絕緣膜3116覆蓋即可,可防止直流電流於2個電極間流 動。 非對稱交流之較佳之頻率及電壓只要肖實施形態i相同 地設定即可。 如此,藉由將非對稱之交流施加於第丨電極3113與第2電 極3U4,於液體内實質上於單向產生電場,可使液體中之 試樣早向移動。 進行電泳之步驟主要包含以下步驟: (υ準備具備分別至少一部份以液體浸沒之第丨電極 3113與第2電極3114及所要測定之試樣之泳動槽之步驟; 162130.doc -45· 201243321 (2)將非對稱交流施加於第丨電極3113與第2電極3ιΐ4之 間而使試樣泳動之步驟。 使用如上所述之方法或裝置,藉由將非對稱之交流施加 於2個電極3113、3114間,可進行電泳。又,由於施加非 對稱交流所產生之實質上單向之電場,故進行電泳時,不 會發生因液體電解而產生氣泡、不會引起電化學反應、電 極亦不會腐蝕而污染液體、且亦可避免產生焦耳熱等之問 題。因此,可更精確地檢測分子之大小之差。 本實施形態6之情形亦較佳為圖2(b)或圖2(c)之波形。 &lt;實施形態7 &gt; 使用圖3 1說明作為本發明之第7實施形態之電泳顯示裝 置》 圖31為本實施形態之電泳顯示裝置4100之概略剖面圖。 第1基板4131與第2基板4132對向配置。第1基板4131上 形成有第1電極(對向電極)4113,第2基板4132上針對每個 像素形成有第2電極(像素電極)4114。 於第1電極4113與第2電極4114之間配置有電泳元件 4134。電泳元件4134係由圓形之膠囊4135、分散介質 4136、白色電泳粒子4137及黑色電泳粒子4138構成。 對第1電極4113與第2電極4114經由選擇電晶體4139而連 接有產生非對稱交流之電源4115。 於第2電極4114與電泳元件4134之間設置有接著層 4133。又,第2電極411 4依每個像素被分離,且連接有選 擇電晶體4139。 162I30.doc -46- 201243321 電泳顯示裝置41 00之第1基板413 1側為顯示面。第1基板 4131只要使用例如玻璃或透明薄膜等之透明之基板即可。 第2基板4132不一定要為透明,可使用玻璃、樹脂薄旗、 表面上形成有絕緣膜之金屬板。 第1電極4113可使用ΙΤΟ等之透明電極,且可為對所有像 素共用者。第2電極4114可使用Al、Cu、Au等之金屬電 極。 構成電泳元件4134之圓形之膠囊4135係由例如直徑為 20〜100 μηι之透明樹脂構成。分散介質4136由於離子濃度 小較容易於分散介質中產生單向之電場,而使電泳粒子泳 動,故較佳為離子濃度為較小者。例如,較佳為乙醇、甲 醇' ΙΡΑ等之醇類、輕油精、丙_等之有機溶劑等。使用 水之情形,較佳為使用純水、無離子水等。 2種電泳粒子4137、4138可使用碳煙等之黑色顏料、二 氧化鈦等之白色顏料。惟由於2種電泳粒子有必要相對於 分散介質令產生之實質上單向之電場而相互於相反方向移 動’故2種電泳粒子有必要實質地相互於相反極性帶電。 電泳顯示裝置4100之動作,首先,利用選擇電晶體選擇 應該顯示為白色(或黑色)之像素,其次將非對稱之交流施 加於所選擇之像素巾之第2電極411續第i電極4⑴之間。 藉此,所選擇之像素中,白色(黑色)之電泳粒子 4释138)例如移動至上側,黑色(白色)之電泳粒子 4138(4137)移動至下側,而顯示白色(黑色卜 相反的,進行反轉顯示之情形,利用選擇電晶體選擇應 162130.doc •47- 201243321 該顯示為黑色(或白色)之像素,且將使各電泳粒子4137、 4138朝反向移動之非對稱之交流施加於所選擇之像素中之 第2電極4114與第!電極4113之間。藉由以上之動作,可在 電泳顯示裝置41 〇〇中顯示像素。 又,非對稱交流與實施形態2相同,亦可使用圖2或圖3 中顯示之波形之交流、或圖7中顯示之波形之交流。 非對稱交流之較佳之頻率因分散介質4136之種類而異, -般而言如為離子濃度低之分散介f則降低頻率,如為離 子濃度高之分散介質則提高頻率。例如,使用純水作為分 散&quot;質4136之情形只要為5〇〇 Hz〜5 MHz即可。然而,在因 分散介質之污染而使得濃度較高之情形下,有必要適宜地 提高頻率。 如此,藉由將非對稱之交流施加於第丨電極4113與第2電 極4114之間,於分散介質内實質上於單向產生電場,可使 分散介質中之電泳粒子單向移動,可使其作為電泳顯示裝 置而驅動。 先前之電泳顯示裝置將直流電流施加於像素電極與共用 電極間。施加直流電壓之瞬間,由於在膠囊之内側中不會 誘發足以抵銷内部之電場之電荷,故電場會侵入膠囊之内 部。因此,可使電泳粒子短距離(膠囊之直徑左右)移動。 又,由於一度到達膠囊内側之電泳粒子會因靜電力而吸附 於膠囊之内壁,故停止電壓之施加後仍可保存圖像。然 而,先前之裝置中,相對於電泳粒子之驅動力係與時間一 起急速衰減,而必須在衰減前完成移動,故存在受膠囊之 162130.doc • 48 · 201243321 直徑、分散介質之種類及電泳粒子之種類等限制之問題。 又’需要相對於較大之電泳粒子之驅動力之情形,亦存在 需要更高之電壓之問題。 另一方面,本實施形態之電泳顯示裝置藉由將非對稱之 父/瓜施加於像素電極(第2電極)與共通電極(第1電極)間, 可使電泳粒子持續於單向移動。因此,例如,用黑白2色 進行顯示之情形,無需增大施加於電極之電壓,藉由對應 於使用之膠囊、分散介質及電泳粒子,而將非對稱交流施 加於電極間達足夠之時間,可更確實地進行像素之黑白轉 換。又,由於可自由改變驅動電泳粒子之時間,故在像素 之大小、分散介質之種類及電泳粒子之種類等方面,設計 之自由度增高。 本實施形態7之情形中,作為非對稱交流,亦較佳為圖 2(b)或圖2(c)之波形。 &lt;實施形態8 &gt; 使用圖32說明作為本發明之第8實施形態之電滲流泵與 其動作方法》 圖32係本實施形態之電滲流泵51〇〇之概略剖面圖。 管件5141之内部為流道,且充滿所要搬送之液體5ii2。 於管件5141之上游部與下游部,離間配置設有複數之孔之 第1電極5113及第2電極5114。第1電極5113與第2電極5114 上,連接有產生非對稱之交流之交流電源5115。 管件5141可使用樹脂、玻璃等。 由於液體之離子濃度小則較容易於液體中產生單向之電 162130.doc -49- £ 201243321 場從而易於搬送液體,故所要搬送之液體5112較佳為離子 濃度較小者。例如,較佳為乙醇、甲醇、IPA等之醇類、 輕油精、丙酮等之有機溶劑等。使用水之情形,較佳為使 用純水、無離子水等》 搬送離子濃度高之液體之情形,可將該電滲流泵作為動 力間接搬送。 於第1電極5113及第2電極5114中,為使液體可通過,設 置0.1 mm〜1 mm左右之大小之孔。 施加於第1電極5113與第2電極5114上之非對稱交流與上 述實施形態相同,只要使用圖2或圖3中所示者即可。例 如,將第2電極5 114作為基準電壓而施加圖2中所示之非對 稱交流時,於液體5112内實質上產生之電場之朝向為朝右 (圖32之箭頭符號5117之朝向)。 此時,管件514〗之内壁帶負電之情形,如圖32所示,於 管件5141之内壁附近之液體5112中誘發正電荷。 在較固著於内壁之液體與流動之液體之交界面即滑移面 5142更遠離内壁之區域t,液體5112不會固著於管件η。 之内壁而可自由移動。 又,由於液體5112内實質上存在單向(箭頭符號5117之 朝向)之電場,故正電荷中帶電之液體分子向第2電極方行 進’液體5112向右搬送。 非對稱交流之較佳之頻率及電壓只要與實施形態丨同樣 地設定即可》 如此,藉由將非對稱交流施加於第丨電極5113與第2電極 162130.doc •50. 201243321 5114 ’可於液體5112内產生實質上單向之電場。 又’在各自離間配置於流道内之上游部與下游部之第i 電極與第2電極之間,如圖3 2所示般藉由施加非對稱交 流’可將充滿該流道内之液體5112自上述流道内之上游部 向下游部輸送。 又’由於施加使實質上單向之電場產生之非對稱交流, 故即使於單向搬送液體’亦不會因液體電解而產生氣泡, 亦不會引起電化學反應’從而可防止電極腐蚀。因此,由 於不需要用以去除氣泡之機構,故可使電滲流泵之構造簡 單化,進而,可提高電滲流泵之可靠性。 本實施形態中,由於第1電極5113與第2電極5114皆與液 體5 11 2直接接觸,故若將直流施加於2個電極間則直流電 流流動。因此,較佳為非對稱交流不具有實質之直流成 伤,即將上述第1電極與第2電極之間之電壓v⑴經過交流 之1週期積分而得之Veff實質上為〇。 因此,由於2個電極間不會流動純正之直流電流,故不 會因液體電解而產生氣泡,亦不會引起電化學反應,從而 可更確實地防止電極腐蝕。 本實施形態8之情形亦同,為有效率地搬送液體,非對 稱交流較佳為圖2(b)或圖2(c)之波形。 &lt;實施形態9 &gt; 使用圖33說明作為本發明之第9實施形態之電滲流泵與 其動作方法。 本實施形態與實施形態8不同的是,第〗電極與第2電極 162130.doc ,, 201243321 之至少一方被絕緣膜覆蓋。 圖33係本實施形態之電渗流果52〇〇之概略剖面圖。 管件5241之内部為流道,且充滿所要搬送之液體mu。 管件5241之上游部與下游部令,離間配置設有複數之孔之 第1電極5213及第2電極5214。 第1電極5213與第2電極5214被絕緣膜5216覆蓋,且連接 有產生非對稱之交流之交流電源52丨5。 管件5241與實施形態8相同,使用樹脂、玻璃等,且所 要傳送之液體5212較佳為離子濃度較小者。 施加於第丨電極52丨3與第2電極5214之非對稱交流與上述 實施形態相同,只要使用圖2或圖3中所示者即可。例如, 將第2電極5214作為基準電壓而施加圖2中所示之非對稱交 流時,於液體5212内實質上產生之電場之朝向為朝右(圖 33之箭頭符號5217之朝向)。 此時,管件5241之内壁帶負電之情形,於管件5241之内 壁附近之液體5212辛誘發正電荷。在較滑移面更遠離内壁 之區域中,液體5212不會固著於管件5241之内壁而可自由 移動。 又’由於液體5212内存在實質上單向(箭頭符號52i7之 朝向)之電場’故液體5212向右搬送。以上之動作與實施 形態8相同。 又’非對稱交流亦可.與上述實施形態相同,使用圖7中 所示者。由於第1電極5213與第2電極5214被絕緣膜5216覆 蓋’故於2個電極間不會流動直流電流。因此,即使為如 162130.doc •52- 201243321 圖7所示之波形亦不舍 个會有特別不良之影響,可於單向搬送 液體5212。另,σ並/j. 八受任一方之電極被絕緣膜5216覆蓋即 可’可防止於2個電極間流動直流電流。 非對稱乂流之較佳之頻率及電壓只要與實施形態i同樣 地設定即可。 .如此藉由將非對稱之交流施加於第1電極5213與第2電 極5214,可使液體5212内實質上於單向產生電場。 又,使用如上所述之方法或裝置,藉由將非對稱之交流 施加於2個電極5213、5214間,可於單向搬送液體5212。 又,由於施加使實質上單向之電場產生之非對稱交流,故 即使單向搬送液體,亦不會因液體電解而產生氣泡,亦不 會引起電化學反應,從而可防止電極腐蝕。因此,由於不 而要用以去除氣泡之機構,故可使電滲流泵之構造簡單 化’進而,可提高電滲流泵之可靠性。 進而’藉由以絕緣膜覆蓋第丨電極及第2電極之至少一 方,由於2個電極間不會流動直流電流’故可更確實地防 止電極腐蝕。又,由於第1電極及第2電極之至少一方被絕 緣膜覆蓋,故電子不會自第1電極直接到達第2電極而流動 電流。因此’該線路中消耗之電力僅為取決於覆蓋電極之 絕緣膜構成之電容之充放電者。因此,可顯著減少消耗電 力,且可顯著減少焦耳熱之產生。 本實施形態9之情形亦同,爲了有效率地搬送液體,非 對稱交流較佳為圖2(b)或圖2(c)之波形。 &lt;實施形態10 &gt; 162130.doc -53· 201243321 使用圖34說明作為本發明之第1〇實施形態之電滲流泵之 其他之實施例。 本實施形態與實施形態9不同的是,第丨電極與第2電極 之間之流道中,設置有由多孔質構成之電滲材。 圖34係本實施形態之電滲流系5300之概略剖面圖。 管件5341之内部為流道,且充滿所要搬送之液體5312。 管件5341之上游部與下游部中,離開配置設有複數之孔之 第1電極53 13及第2電極53 14。第1電極53 13與第2電極5314 被絕緣膜53!6覆蓋,且連接有產生非對稱之交流之交流電 源5315 。 在流道内且第1電極5313與第2電極5314之間,配置有由 多孔質構成之電滲材5343。 所謂電滲材5343例如為由二氧化矽纖維材料、多孔質陶 瓷構成之構件,並為發揮使液體通過且實質上增大流道之 内壁之面積之作用者。 藉由如圖34般配置該電滲材5343,電滲材與液體於設置 於電滲材内部之細微之孔中接觸,利用因非對稱交流產生 之單向電場之作用而搬送液體。由於電滲材内部之多孔質 使電滲材與液體之接觸面積增大,故液體之搬送能力亦增 強。 根據本實施形態之電滲流泵,與實施形態9相同,不會 因液體電解而產生氣泡,亦不會引起電化學反應,從而可 防止電極腐蝕。 因此,由於不需要用以去除氣泡之機構,故可使電滲流 162l30.doc -54 - 201243321 泵之構造簡單化,可提高電滲流泵之可靠性。 又,由於第1電極及第2電極之至少一方被絕緣膜覆蓋, 故可更確實地防止電極之腐蝕。又,可顯著減少消耗電 力,且可顯著減少焦耳熱之產生。 進而’藉由在第1電極5313與第2電極5314之間配置由多 孔質構成之電滲材而可提高電滲效果,故可飛躍性提高泵 之能力。 &lt;實施形態11 &gt; 使用圖3 5說明作為本發明之第11實施形態之燃料電池。 燃料電池6100具備本發明之實施形態§、9或1 〇之任一者 之電滲泵61H。又,自燃料箱6丨53向燃料電池單元6152、 通過燃料輸送管615 4輸送燃料。 燃料電池單元61 52上連接有燃料電池狀態感測器6156, 檢測燃料電池之狀態。 將燃料電池之狀態自燃料電池狀態感測器615 6傳送至燃 料供給控制電路6157,燃料供給控制電路6157控制燃料電 池6151之燃料供給量。 燃料電池狀態感測器615 6及燃料供給控制電路6丨5 7所需 之電力由連接於燃料電池單元6152之DC/DC轉換器6155供 給。於DC/DC轉換器6155上,連接有用以供給電力至外部 之端子6158。 本實施形態之燃料電池由於具備本發明之電滲流泵,故 藉由電滲流泵而輸it之燃料不會電解而產生氣泡,且不會 引起電化學反應,從而電極不會腐#。因此,由於不需要 162130.doc •55· 201243321 用以去除氣泡之機構,故可使電滲流泵之構造簡單化,且 可提高電滲流泵之可靠性》 &lt;實施形態12 &gt; 使用圖36說明作為本發明之第12實施形態之冷卻泵》 冷卻泵6200具備本發明之實施形態8、9或10之任一者之 電滲泵6251。又,於受熱部6259與熱交換器6260間,通過 冷媒輸送管6263使冷媒循環。 受熱部6259中設置有溫度感測器6261,將受熱部6259之 溫度傳達給泵控制電路6262。泵控制電路6262根據來自溫 度感測器6261之資訊控制電滲泵6251,且使冷卻液移動, 而適當保持受熱部6259之溫度。 本實施形態之冷卻泵,由於具備本發明之電滲流泵,故 藉由電滲流泵而輸送之燃料不會電解而產生氣泡,且不會 引起電化學反應,從而電極不會腐蝕。因此,由於不需要 用以去除氣泡之機構,故可使冷卻泵之構造簡單化,且可 提高冷卻泵之可靠性。 &lt;實施形態13&gt; 使用圖37說明作為本發明之第13實施形態之藥液供給裝 置6300 。 藥液供給裝置6300具備本發明之實施形態8、9或10之任 一者之電滲泵63 51。又,自藥液槽63 64通過藥液輸送管 63 68向藥液供給目的地輸送藥液。 於藥液輸送管6368之中途設置有流量感測器6365,將流 量資訊傳送至藥液供給控制電路6366。藥液供給控制電路 162130.doc -56- 201243321 6366根據自藥液供給程式輸入裝置預先傳達之指示與 自肌量感測器6365所傳送之流量資訊,控制電渗栗6351, 並調節輸送之藥液之流量。 本實施形態之藥液供給裝置,由於具備本發明之電渗流 I ’故藉由電渗流泵而輸送之藥液不會電解而產生氣泡, 1不會引起電化學反應’從而電極不會腐融。因此,由於 不而要用以去除氣泡之機構,故可使藥液供給裝置之構造 簡單化,且可提高藥液供給裝置之可靠性。 【圖式簡單說明】 圖Ua)〜(d)係對稱之交流之波形之一實施例之說明圖。 圖2(a)〜(d)係該發明之非對稱之交流之波形之一實施例 之說明圖。 圖30)、(b)係該發明之非對稱之交流之波形之一實施例 之說明圖。 圖4(a)〜(d)係為非對稱交流一事之判定方法之一實施例 之說明圖。 圖5係該發明之電場產生裝置之一實施例之概略構成 圖。 圖6係該發明之實施形態2之電場產生裝置之概略構成 圖。 圖7(a)〜(d)係該發明之非對稱之交流之波形之一實施例 之說明圖。 圖8(a)〜(c)係將直流電壓施加於液體中之電極間之情形 之電場產生現象之說明圖。 162130.doc -57- 201243321 圖9係該發明之非對稱交流之模擬模型之說明圖。 圖10係該發明之非對稱交流之模擬模型之說明圖。 圖11係該發明之第丨模擬中使用之非對稱之矩形波之一 實施例之波形圖。 圖12係該發明之第1模擬感應到之電荷量之圖表。 圖13係該發明之第1模擬感應到之電荷量之圖表。 圖14係該發明之第i模擬之液體中之電場之強度之圖 表。 圖15係顯示該發明之第i模擬中,平均電場與常數n之關 係之圖表。 圖16係該發明之第丨模擬中,液體中之物體之位置之時 間之變化之圖表。 圖17係該發明之第2模擬中使用之非對稱之矩形波之一 實施例之波形圖。 圖18係該發明之第2模擬中’液體中之物體之位置之時 間之變化之圖表。 圖19係該發明之第3模擬中使用之對稱之矩形波之一實 施例之波形圖。 圖20係該發明之第3模擬令’液體中之物體之位置之時 間之變化之圖表。 圖21係該發明之第4模擬中使用之非對稱之三角波之一 實施例之波形圖。 圖22係該發明之第4模擬感應到之電荷量之圖表。 圖23係該發明之第4模擬感應到之電荷量之圖表。 162130.doc -58- 201243321 圖24係該發明之第4模擬之液體中之電場之強度之圖 表。 ^ 圖25係顯示該發明之第4模擬中,平均電場與常數n之關 係之圖表。 圖26係該發明之第4模擬中,液體中之物體之位置之時 間之變化之圖表。 圖27係該發明之實施形態3之浮游體移動裝置之概略構 成圖。 圖28係該發明之實施形態4之浮游體移動裝置之概略構 成圖。 圖29係該發明之實施形態5之浮游體移動裝置之概略構 成圖。 圖3 0係該發明之實施形態6之電泳裝置之概略構成圖。 圖3 1係該發明之實施形態7之電泳顯示裝置之概略構成 圖。 圖3 2係該發明之實施形態8之電滲流泵之概略構成圖。 圖33係該發明之實施形態9之電滲流泵之概略構成圖。 圖34係該發明之實施形態10之電滲流泵之概略構成圖。 圖35係該發明之實施形態丨丨之燃料電池之概略構成圖。 圖36係該發明之實施形態12之冷卻泵之概略構成圖。 圖37係該發明之實施形態13之藥液供給裝置之概略構成 圖。 【主要元件符號說明】 1100 電場產生裝置 162130.doc •59- 201243321 1111 容器 1112 液體 1113 第1電極 1114 第2電極 1115 交流電源 1117 箭頭符號 1216 絕緣膜 2100 浮游體移動裝置 2111 容器 2112 液體 2113 第1電極 2114 第2電極 2115 交流電源 2118 物體 2216 絕緣膜 3100 電泳裝置 3124 瓊脂醣凝膠 3125 井 4100 電泳顯示裝置 4131 第1基板 4132 第2基板 4134 電泳元件 4135 .膠囊 4136 分散介質 •60- 162130.doc 201243321 4137 電泳粒子 4138 電泳粒子 4139 選擇電晶體 5100 電渗流泉 5141 管件 5142 滑移面 5216 絕緣膜 5343 電渗材 6100 燃料電池 6151 電渗流栗 6152 燃料電池單元 6153 燃料箱 6154 燃料輸送管 6155 DC/DC轉換器 6156 燃料電池狀態感測器 6157 燃料供給控制電路 6158 燃料供給端子 6200 冷卻泵 6251 電參流果 6263 冷卻劑輸送管 6300 藥液供給裝置 635 1 電渗流系 6368 藥液輸送管 162130.doc -61 -Veff= /V(t)dt=0 (16) By thus making the integral value 〇, since pure DC current does not flow between the two electrodes, liquid electrolysis hardly occurs and electrochemical reaction does not occur. . Therefore, electrode corrosion can be suppressed. However, the time when qs(t) reaches equilibrium (the time constant proportional to the reciprocal of a) is shorter than the reciprocal of the frequency of asymmetric AC. Since the electric field cannot penetrate into the liquid, it does not produce one-way electric field. Further, in order to change qs(1), it is necessary to move the ions dispersed in the liquid in the liquid and concentrate them on the electrodes. Therefore, the higher the ion concentration of the liquid, the shorter the time constant becomes. Therefore, in the case where the concentration of ions in the liquid is high, in order to invade the liquid in the liquid and generate a unidirectional electric field, it is necessary to change the potential of the electrode more rapidly, so it is necessary to increase the frequency of the asymmetric alternating current. On the other hand, in the case where the concentration of ions in the liquid is low, since the above time constant can easily make the qs(1) self-balancing state greatly distant (i.e., increase {qs(t)-qeq(t)}), it is easy to A unidirectional electric field is generated. For the above reasons, the lower the ion concentration in the liquid, the more effective it is to generate a unidirectional electric field in the liquid. It is preferable because the frequency of the asymmetric alternating current is lowered. &lt;Embodiment 3&gt; A floating body moving device and a floating body moving method for moving an object floating in a liquid according to a third embodiment of the present invention will be described with reference to Fig. 27 . Fig. 27 is a schematic cross-sectional view showing the apparatus 2100 for moving a floating body which moves an object floating in a liquid in the embodiment. The container 2111 is filled with a liquid 2112. At least a portion of the first electrode 2113 and the second electrode 2114 are immersed in the liquid 2112. The first electrode 2113 and the second electrode 2 114 are connected to an alternating current power source 2丨丨5 that generates an asymmetrical alternating current. Here, the container 2111 is the same as the first embodiment, and any liquid 2112 can be held. The liquid 2112 is the same as that of the first embodiment, and preferably has a small ion concentration. Similarly, the asymmetric communication applied to the first electrode 2113 and the second electrode 2114 may be the same as that shown in Fig. 2 or Fig. 3. For example, when the second electrode 2114 is applied as the reference voltage to the asymmetric alternating current shown in Fig. 2, the direction of the electric field substantially generated in the liquid 2112 is directed to the right (the direction of the arrow symbol 2117 in Fig. 27). Therefore, the case where the object 2118 floating in the liquid is negatively charged moves to the left (the direction of the arrow symbol 2119 of Fig. 27) as shown in Fig. 27. The object moves "in the opposite direction (to the right) in the case of "positive charging." The preferred frequency and voltage of the asymmetric alternating current may be set in the same manner as in the embodiment. 'The object 2118 floating in the liquid is substantially charged. 162130.doc £ -37· 201243321 The term “substantially charged” means that the charge generated in the object can be induced as the charge induced by the interface between the object 2118 and the liquid 2112 and the liquid in the vicinity of the object by using the charge. The sum of the charges moving together with the solid. In other words, it can be said that the potential in the liquid is not 〇. In the case of an object that is substantially uncharged, a nonionic surfactant can be used to change the boundary potential of the object. Specific examples are, for example, dielectric fine particles having a size of 1 mm or less from a nanometer scale, semiconductor fine particles 'metal fine particles, fine semiconductor elements, cells, DNA, RNA, proteins, etc.. Thus, by asymmetric communication Applied to the first electrode 2113 and the second electrode 2114, an electric field is generated substantially in one direction in the liquid 1112 and the liquid 2112 can be floated The movement of the object 2118 is one-way. The principle of movement is the same as the above simulation. In the liquid 1112, the step of substantially generating the electric field in one direction mainly comprises the following steps: (1) injecting the liquid 2112 floating from the object 2118 into the container 2111 (2) arranging the first electrode 2113 and the second electrode 2114 so as to be immersed in the liquid 2112 at least partially at a predetermined interval; (3) applying an asymmetric alternating current to the first step a step of moving the object 2118 floating in the liquid 2112 from the second electrode 2113 to the second electrode 2114 or moving the object from the second electrode 2114 to the first electrode 2113 between the second electrode 2113 and the second electrode MM By using the method or apparatus as described above, an asymmetric alternating current is applied 162130.doc -38 201243321 between the two electrodes 2113, 2114, so that the floating object 2 11 8 in the liquid 2112 can be moved in one direction. 'Because the object in the liquid floats in one direction, a substantially unidirectional electric field is applied by asymmetric alternating current, so that electrode corrosion caused by liquid electrolysis or electrochemical reaction can be suppressed. In the state, either the first electrode 2113 and the second electrode 2114 are in direct contact with the liquid 2112. Therefore, if a direct current is applied between the two electrodes, a direct current flows. Therefore, in order to avoid rot, as in the first embodiment. The last name 'preferably' is that the asymmetric alternating current does not have a substantial DC component, and even if the voltage v(1) between the first electrode and the second electrode is integrated by one cycle of the alternating current, the Veff is substantially 〇. For the same reason as in the first embodiment, in order to efficiently move the object floating in the liquid in one direction, the waveform of FIG. 2(b) or FIG. 2(c) is preferably used as the asymmetric communication. &lt;Embodiment 4&gt; A floating body moving device and a floating body moving method for moving an object floating in a liquid according to a fourth embodiment of the present invention will be described with reference to FIG. In the present embodiment, unlike the third embodiment, at least one of the first electrode and the second electrode is covered with an insulating film. Fig. 28 is a schematic cross-sectional view showing a device 2200 for moving a floating body in which an object floating in a liquid in the embodiment moves. The container 2211 is filled with a liquid 2212. At least a portion of the first electrode 2213 and the second electrode 2214 are immersed in the liquid 2212. The first electrode 2213 and the second electrode 2214 are covered by the insulating film 2216, and are connected to an alternating current source 162130.doc • 39·201243321. Here, the container 2211 is the same as that of the first embodiment, and may be any one that can hold the liquid 2212. The liquid 22 is preferably a smaller ion concentration. Similarly to the second embodiment, the insulating film 2216 can be applied to the asymmetric alternating current of the first electrode 2213 and the second electrode 2214 by using a ruthenium oxide film, a tantalum nitride film, or a resin film, etc., as well as using FIG. 2 or FIG. The one shown can be. For example, when the second electrode 2214 is applied as the reference voltage to the asymmetric alternating current shown in Fig. 2, the direction of the electric field generated in the liquid 2212 is directed to the right (the direction of the arrow symbol 2217 in Fig. 28). Therefore, the floating object 2218 in the liquid is negatively charged, as shown in Fig. 28, moving to the left (the direction of the arrow symbol 2219 in Fig. 28). The object 2218 is positively charged and moves in the opposite direction (to the right). Further, the asymmetrical alternating current is the same as that of the second embodiment, and the alternating current of the waveform shown in Fig. 7 can also be used. Since the i-th electrode 2213 and the second electrode 2214 are covered by the insulating film 22 16 and since no direct current flows between the two electrodes, even if it is a waveform as shown in FIG. 7, there is no particular adverse effect. The object 2218 floating in the liquid 22丨2 can be moved in one direction. Further, in the present embodiment, any one of the electrodes may be covered with the insulating film 2216. The preferred frequency and voltage of the asymmetric communication may be set in the same manner as the embodiment. Further, the object 2218 floating in the liquid may be charged substantially. The specific example of the object can be the same as that shown in the third embodiment. In this manner, even when at least one of the electrodes is covered with the insulating film, 162130.doc •40·201243321 is substantially applied to the liquid 2212 by applying an asymmetric alternating current to the first electrode 2213 and the second electrode 2214. The unidirectional generation of an electric field causes the floating object 2218 in the liquid 2212 to move in one direction. In the fourth embodiment, since at least one of the first electrode and the second electrode is covered with the insulating film, a direct current does not flow between the two electrodes, so that electrode corrosion due to liquid electrolysis or electrochemical reaction can be reliably prevented. The problem. Further, since at least one of the first electrode and the second electrode is covered with the insulating film, electrons do not directly flow from the second electrode to the second electrode to flow an electric current. Therefore, the power consumed in the circuit is only a charge and discharge depending on the capacitance of the insulating film covering the electrodes. Therefore, power consumption can be significantly reduced, and the generation of Joule heat can be significantly reduced. The case of the fourth embodiment is also preferably FIG. 2(b) or FIG. 2 (a uniform waveform). &lt;Embodiment 5&gt; A floating body moving device and a floating body moving method for moving an object floating in a liquid according to a fifth embodiment of the present invention will be described with reference to FIG. In the fourth embodiment, the object in which the first electrode and the second electrode are formed on the opposite substrates, the liquid floating in the liquid moves in one direction between the two electrodes. Fig. 29 is a schematic cross-sectional view showing a device 2300 for moving a floating body in which an object floating in a liquid in the embodiment moves. The first substrate 2321 is opposed to the second substrate 2322, and is filled with the liquid 2312 therebetween. The first electrode 2313 is formed on the surface of the first substrate 2321 on the side in contact with the liquid 2312. On the side of the second substrate 2322 that is in contact with the liquid 2312, a second electrode 23 14 is formed. 162130.doc • 41 - 201243321 An insulating film 2316 is formed on the surface of the first electrode 2313 and the second electrode 2314, and direct current is prevented from flowing between the first electrode 2313 and the second electrode 2314. Further, in the first electrode 2313 and the second electrode 2314, an alternating current power supply 2315 that generates an asymmetrical alternating current is connected to the side not covered by the insulating film 2 3 16 . Here, as the first substrate 2 3 21 and the second substrate 2 3 2 2, an insulator such as glass, resin, or ceramic can be used. The liquid 23 12 is the same as that of the first embodiment, and preferably has a small ion concentration. The asymmetrical alternating current applied to the first electrode 23 13 and the second electrode 23 14 is also the same as that shown in Fig. 2 or Fig. 3. For example, when the asymmetric current shown in Fig. 2 is applied with the second electrode 23 14 as the reference voltage, the direction of the electric field substantially generated in the liquid 23 12 is downward (the direction of the arrow symbol 2317 in Fig. 29). Therefore, the case where the object 23 18 floating in the liquid is negatively charged, as shown in Fig. 29, moves upward (the direction of the arrow symbol 2319 of Fig. 29). When the object 2318 is positively charged, it moves in the opposite direction (downward). In Fig. 29, the first electrode 2313 is disposed above the second electrode 2314 in the vertical direction. In this case as well, even if the direction of the electric field is directed downward in the direction of Fig. 29, the object moves in the direction opposite to the opposite direction of gravity. The arrangement of the electrodes of the opposite pair is not limited to those shown in FIG. 29. For example, the first electrode and the second electrode are not electrodes of each block, and may be divided into a plurality of electrodes and separated by a gap. And configuration. Or 2 electrodes can be meshed. In this case, by combining with a transparent substrate, objects floating in the liquid can be observed from the outside. 162130.doc 42·201243321 Further, the asymmetric communication is the same as that of the above-described second embodiment, and the waveform shown in Fig. 7 can also be used. Even if it is a waveform as shown in Fig. 7, there is no particular adverse effect, and the object 2 floating in the liquid 2312 can be moved in one direction. As long as either electrode is covered by the insulating film 2316, in this case, direct current can be prevented from flowing between the two electrodes. The preferred frequency and voltage of the asymmetric communication may be set in the same manner as in the embodiment i. Further, the object 2318 floating in the liquid may be charged substantially. Specific examples of the object may be the same as those of the embodiment. Further, as in the present embodiment, the two electrodes are formed on the two opposing substrates, and the liquid floating between the two substrates is filled with the object, and the movement of the object can be utilized as follows. A plurality of objects 2318 float in the liquid 2312, and gravity acts on the downward direction of the drawing. That is, the second substrate 2322 is disposed downward. In this case, if a unidirectional electric field is applied to the two electrodes 2313 and 2314, the asymmetry is upward. AC, because of the additional gravity, the object 2318 can be quickly moved to the UK side of the second substrate. That is, the object 2318 can be quickly precipitated. Also, if the two electrodes 2313, 2314 are applied with a unidirectional electric field facing downward The asymmetric communication as shown in Fig. 29 causes the object 23 18 to move upward, thereby preventing the object 2318 from sinking due to gravity. Using the method or apparatus as described above, by applying an asymmetric alternating current to the two electrodes 2313 Between 23 and 14 , the object 2318 floating in the liquid 23 12 can be moved in one direction. Since at least one of the first electrode and the second electrode is covered with an insulating film, 162130.doc -43-201243321 Since a direct current is generated, it is possible to surely prevent problems such as corrosion of the electrode due to liquid electrolysis or electrochemical reaction. Further, since at least one of the first electrode and the second electrode is covered with an insulating film, the electron does not come from the first 1 electrode directly The current flows in the second electrode. Therefore, the power consumed in the circuit is only charged and discharged depending on the capacitance of the insulating film covering the electrode. Therefore, the power consumption can be remarkably reduced, and the generation of Joule heat can be remarkably reduced. The case of the fifth embodiment is also preferably the waveform of Fig. 2 (b) or Fig. 2 (c). &lt;Embodiment 6&gt; An electrophoresis apparatus and an electrophoresis method according to a sixth embodiment of the present invention will be described with reference to Fig. 30. Fig. 30 is a schematic cross-sectional view showing the electrophoresis apparatus 3 of the embodiment. The first electrode 3113 and the second electrode 3114 are provided on both sides of the container 3123. An AC power supply 3115 is formed on the first electrode 3113 and the second electrode 3114 to which an asymmetric alternating current is generated. The first electrode 3113 and the second electrode 3114 are formed with an insulating film 3116 on the surface. When performing electrophoresis, the container 3123 is filled with a specific liquid, and an agarose gel 3124 having a well 3125 formed therein is disposed in the container 3123. Well 3125 is used to inject the sample into the hole. Next, a sample of DNA or the like is injected into the well 3 125, and an asymmetric alternating current is applied to the first electrode 3113 and the second electrode 3114. Thereby, electrophoresis for moving the sample in a specific direction can be performed. As the above-mentioned liquid, in the prior electrophoresis, since a direct current flows between the two electrodes, a person having conductivity is used. However, in the embodiment 162130.doc •44·201243321, since the ion concentration of the liquid is small, it is easy to generate a unidirectional electric field in the liquid to cause the sample to move. Therefore, it is preferable to use pure water to have a small plasma concentration and not to cause The sample is modified. The asymmetric alternating current applied to the first electrode 3 113 and the second electrode 3 114 is used, for example, as shown in FIG. 2 or FIG. 3, for example, applying the second electrode 3114 as a reference voltage to apply the asymmetry shown in FIG. When communicating, the direction of the electric field substantially generated in the liquid is toward the right (the direction of the arrow symbol 3117 in Fig. 3). Therefore, the sample in the liquid is negatively charged, as shown in Fig. 3A, moving to the left (the direction of the arrow symbol 3119 in Fig. 30). Since the distance traveled by the sample in the agarose gel 3124 varies depending on the molecular weight of the sample, the molecules contained in the sample can be separated to visualize the molecular weight of the sample. Further, the asymmetric parent flow is the same as that of the second embodiment, and the communication of the waveform shown in Fig. 7 can also be used. Even if it is a waveform as shown in Fig. 7, there is no particular adverse effect, and electrophoresis can still be performed. That is, as long as either electrode is covered by the insulating film 3116, direct current can be prevented from flowing between the two electrodes. The preferred frequency and voltage of the asymmetric communication may be set in the same manner as in the embodiment i. Thus, by applying an asymmetric alternating current to the second electrode 3113 and the second electrode 3U4, an electric field is generated substantially in one direction in the liquid, so that the sample in the liquid can be moved early. The step of performing electrophoresis mainly comprises the following steps: (Step of preparing a swimming tank having at least a portion of the third electrode 3113 and the second electrode 3114 immersed in the liquid and the sample to be measured; 162130.doc -45· 201243321 (2) A step of applying an asymmetric alternating current between the second electrode 3113 and the second electrode 3ι4 to cause the sample to move. Using the method or apparatus as described above, by applying an asymmetric alternating current to the two electrodes 3113 In the 3114, electrophoresis can be performed. Moreover, due to the application of a substantially unidirectional electric field generated by asymmetric alternating current, when electrophoresis is performed, bubbles do not occur due to liquid electrolysis, electrochemical reactions are not caused, and electrodes are not Corrosion can contaminate the liquid, and problems such as Joule heat can be avoided. Therefore, the difference in size of the molecules can be detected more accurately. The case of the sixth embodiment is also preferably FIG. 2(b) or FIG. 2(c). ) The waveform. &lt;Embodiment 7&gt; An electrophoretic display device according to a seventh embodiment of the present invention will be described with reference to Fig. 31. Fig. 31 is a schematic cross-sectional view showing an electrophoretic display device 4100 of the present embodiment. The first substrate 4131 and the second substrate 4132 are arranged to face each other. A first electrode (opposing electrode) 4113 is formed on the first substrate 4131, and a second electrode (pixel electrode) 4114 is formed on each of the second substrate 4132. An electrophoretic element 4134 is disposed between the first electrode 4113 and the second electrode 4114. The electrophoresis element 4134 is composed of a circular capsule 4135, a dispersion medium 4136, white electrophoretic particles 4137, and black electrophoretic particles 4138. The first electrode 4113 and the second electrode 4114 are connected to a power source 4115 that generates an asymmetrical AC via a selection transistor 4139. An adhesive layer 4133 is provided between the second electrode 4114 and the electrophoretic element 4134. Further, the second electrode 411 4 is separated for each pixel, and the selective transistor 4139 is connected. 162I30.doc -46- 201243321 The first substrate 413 1 side of the electrophoretic display device 41 00 is a display surface. As the first substrate 4131, a transparent substrate such as glass or a transparent film may be used. The second substrate 4132 does not have to be transparent, and a glass, a resin flag, or a metal plate having an insulating film formed on its surface can be used. The first electrode 4113 can use a transparent electrode such as ruthenium or the like, and can be shared by all the pixels. As the second electrode 4114, a metal electrode such as Al, Cu, or Au can be used. The circular capsule 4135 constituting the electrophoresis element 4134 is made of, for example, a transparent resin having a diameter of 20 to 100 μm. The dispersion medium 4136 preferably has a smaller ion concentration because the ion concentration is smaller and it is easier to generate a unidirectional electric field in the dispersion medium to cause the electrophoretic particles to move. For example, an alcohol such as ethanol, methanol or the like, an organic solvent such as light oil essence or propylene or the like is preferable. In the case of using water, it is preferred to use pure water, ion-free water or the like. As the two types of electrophoretic particles 4137 and 4138, a black pigment such as soot or a white pigment such as titanium dioxide can be used. However, since it is necessary for the two types of electrophoretic particles to move in opposite directions with respect to the substantially unidirectional electric field generated by the dispersion medium, it is necessary for the two types of electrophoretic particles to be substantially electrically charged to each other in opposite polarities. The operation of the electrophoretic display device 4100 first selects a pixel which should be displayed as white (or black) by using a selective transistor, and secondly applies an asymmetric alternating current to the second electrode 411 of the selected pixel towel between the i-th electrodes 4(1). . Thereby, among the selected pixels, the white (black) electrophoretic particles 4 release 138), for example, move to the upper side, and the black (white) electrophoretic particles 4138 (4137) move to the lower side, and display white (black opposite, In the case of reverse display, select transistor selection 162130.doc •47- 201243321 The display is black (or white) pixels, and will make the electrophoretic particles 4137, 4138 move asymmetrically in the opposite direction. Between the second electrode 4114 and the fourth electrode 4113 in the selected pixel, the pixel can be displayed on the electrophoretic display device 41 by the above operation. Further, the asymmetric alternating current is the same as that of the second embodiment. Use the AC of the waveform shown in Figure 2 or Figure 3, or the waveform of the waveform shown in Figure 7. The preferred frequency of asymmetric communication varies with the type of dispersion medium 4136, and is generally a dispersion of low ion concentration. In the case of f, the frequency is lowered, for example, the dispersion medium having a high ion concentration increases the frequency. For example, the use of pure water as the dispersion &quot;quality 4136 may be as long as 5 〇〇 Hz to 5 MHz. However, due to dispersion In the case where the concentration is high and the concentration is high, it is necessary to appropriately increase the frequency. Thus, by applying an asymmetric alternating current between the second electrode 4113 and the second electrode 4114, it is substantially single in the dispersion medium. The generation of an electric field causes the electrophoretic particles in the dispersion medium to move in one direction, and can be driven as an electrophoretic display device. Previous electrophoretic display devices applied a direct current between the pixel electrode and the common electrode. In the inner side of the capsule, no electric charge is generated to offset the internal electric field, so the electric field will invade the inside of the capsule. Therefore, the electrophoretic particles can be moved for a short distance (about the diameter of the capsule). The particles are adsorbed on the inner wall of the capsule by electrostatic force, so the image can be saved after the application of the stop voltage. However, in the previous device, the driving force with respect to the electrophoretic particles is rapidly attenuated along with the time, and must be before the decay. Complete the movement, so there are capsules 162130.doc • 48 · 201243321 diameter, type of dispersion medium and electrophoresis particles The problem of the type of the sub-type, etc. Further, there is a problem that a higher voltage is required in comparison with the driving force of the larger electrophoretic particle. On the other hand, the electrophoretic display device of the present embodiment is asymmetric The father/melon is applied between the pixel electrode (second electrode) and the common electrode (first electrode), so that the electrophoretic particles can be continuously moved in one direction. Therefore, for example, when the display is performed in two colors of black and white, it is not necessary to increase the application. At the voltage of the electrode, by applying asymmetrical alternating current to the electrodes for a sufficient time corresponding to the capsule, dispersion medium and electrophoretic particles used, the black and white conversion of the pixel can be performed more surely. Since the time of the electrophoretic particles is increased, the degree of freedom in design is increased in terms of the size of the pixels, the type of the dispersion medium, and the type of the electrophoretic particles. In the case of the seventh embodiment, the waveform of Fig. 2 (b) or Fig. 2 (c) is preferably used as the asymmetric communication. &lt;Embodiment 8&gt; An electroosmotic flow pump according to an eighth embodiment of the present invention and an operation method thereof will be described with reference to Fig. 32. Fig. 32 is a schematic cross-sectional view showing an electroosmotic flow pump 51 of the present embodiment. The inside of the tube 5141 is a flow path and is filled with the liquid 5ii2 to be conveyed. The first electrode 5113 and the second electrode 5114 having a plurality of holes are disposed apart from the upstream portion and the downstream portion of the tube 5141. An AC power source 5115 that generates an asymmetric AC is connected to the first electrode 5113 and the second electrode 5114. The tube 5141 can be made of resin, glass, or the like. Since the liquid ion concentration is small, it is easier to generate a unidirectional electric current in the liquid, so that the liquid 5112 is preferably a liquid having a smaller ion concentration. For example, an alcohol such as ethanol, methanol or IPA, an organic solvent such as light oil essence or acetone, or the like is preferable. In the case of using water, it is preferable to use a pure water, a non-ionized water or the like to transport a liquid having a high ion concentration, and the electroosmotic flow pump can be indirectly conveyed as a power. In the first electrode 5113 and the second electrode 5114, a hole having a size of about 0.1 mm to 1 mm is provided so that the liquid can pass therethrough. The asymmetric alternating current applied to the first electrode 5113 and the second electrode 5114 is the same as that of the above embodiment, and any one as shown in Fig. 2 or Fig. 3 may be used. For example, when the second electrode 5 114 is used as the reference voltage to apply the asymmetric alternating current shown in Fig. 2, the direction of the electric field substantially generated in the liquid 5112 is directed to the right (the direction of the arrow symbol 5117 in Fig. 32). At this time, in the case where the inner wall of the tube member 514 is negatively charged, as shown in Fig. 32, a positive charge is induced in the liquid 5112 near the inner wall of the tube member 5141. The liquid 5112 is not fixed to the tube n at the interface t which is closer to the inner wall and the flowing liquid, i.e., the sliding surface 5142 is further away from the inner wall. The inner wall is free to move. Further, since the electric field of the unidirectional direction (the direction of the arrow symbol 5117) is substantially present in the liquid 5112, the liquid molecules charged in the positive charge are carried to the second electrode and the liquid 5112 is transported to the right. The preferred frequency and voltage of the asymmetric alternating current may be set in the same manner as in the embodiment 》. Thus, the asymmetric alternating current is applied to the second electrode 5113 and the second electrode 162130.doc • 50. 201243321 5114 'is available in liquid A substantially unidirectional electric field is generated within 5112. Further, between the i-th electrode and the second electrode disposed in the upstream and downstream portions of the flow path, as shown in FIG. 3, the liquid 5112 in the flow path can be filled by applying asymmetric communication. The upstream portion in the flow path is transported to the downstream portion. Further, since the asymmetric alternating current generated by the substantially unidirectional electric field is applied, even if the liquid is unidirectionally transported, bubbles are not generated by the liquid electrolysis, and the electrochemical reaction is not caused, thereby preventing electrode corrosion. Therefore, since the mechanism for removing the air bubbles is not required, the structure of the electroosmotic flow pump can be simplified, and the reliability of the electroosmotic flow pump can be improved. In the present embodiment, since both the first electrode 5113 and the second electrode 5114 are in direct contact with the liquid 5 11 2, DC current flows when DC is applied between the two electrodes. Therefore, it is preferable that the asymmetric alternating current does not have substantial DC damage, that is, the voltage v(1) between the first electrode and the second electrode is integrated by one cycle of alternating current, and Veff is substantially 〇. Therefore, since a pure direct current does not flow between the two electrodes, bubbles are not generated by liquid electrolysis, and an electrochemical reaction is not caused, so that electrode corrosion can be more reliably prevented. In the case of the eighth embodiment, in order to efficiently transport the liquid, the asymmetric alternating current is preferably the waveform of Fig. 2 (b) or Fig. 2 (c). &lt;Embodiment 9&gt; An electroosmotic flow pump according to a ninth embodiment of the present invention and an operation method thereof will be described with reference to Fig. 33. In the present embodiment, unlike the eighth embodiment, at least one of the first electrode and the second electrode 162130.doc, 201243321 is covered with an insulating film. Figure 33 is a schematic cross-sectional view showing an electroosmotic flow 52 of the present embodiment. The inside of the pipe member 5241 is a flow path and is filled with the liquid mu to be conveyed. The upstream portion and the downstream portion of the tube member 5241 are provided with a first electrode 5213 and a second electrode 5214 having a plurality of holes interposed therebetween. The first electrode 5213 and the second electrode 5214 are covered by an insulating film 5216, and an AC power source 52丨5 that generates an asymmetric alternating current is connected. The tube member 5241 is the same as that of the eighth embodiment, and a resin, glass, or the like is used, and the liquid 5212 to be transported is preferably one having a smaller ion concentration. The asymmetrical alternating current applied to the second electrode 52丨3 and the second electrode 5214 is the same as that of the above embodiment, and any one as shown in Fig. 2 or Fig. 3 may be used. For example, when the asymmetrical current shown in Fig. 2 is applied as the reference voltage of the second electrode 5214, the direction of the electric field substantially generated in the liquid 5212 is directed to the right (the direction of the arrow symbol 5217 in Fig. 33). At this time, in the case where the inner wall of the tube 5241 is negatively charged, the liquid 5212 near the inner wall of the tube 5241 induces a positive charge. In the region of the slip surface that is further away from the inner wall, the liquid 5212 is not fixed to the inner wall of the tube 5241 and is free to move. Further, since the liquid 5212 has an electric field substantially unidirectional (the direction of the arrow symbol 52i7), the liquid 5212 is transported to the right. The above operation is the same as that of the eighth embodiment. Further, the asymmetric communication may be the same as in the above embodiment, and the one shown in Fig. 7 is used. Since the first electrode 5213 and the second electrode 5214 are covered by the insulating film 5216, a direct current does not flow between the two electrodes. Therefore, even if the waveform shown in Fig. 7 of 162130.doc • 52- 201243321 is not particularly adverse, the liquid 5212 can be transported in one direction. Further, σ and /j. 8 are either covered by the insulating film 5216 to prevent the direct current from flowing between the two electrodes. The preferred frequency and voltage of the asymmetric turbulence may be set in the same manner as in the embodiment i. Thus, by applying an asymmetric alternating current to the first electrode 5213 and the second electrode 5214, an electric field can be generated substantially in one direction in the liquid 5212. Further, by applying the asymmetric alternating current between the two electrodes 5213 and 5214 by the method or apparatus as described above, the liquid 5212 can be transported in one direction. Further, since the asymmetric alternating current generated by the substantially unidirectional electric field is applied, even if the liquid is transported unidirectionally, bubbles are not generated by the liquid electrolysis, and the electrochemical reaction is not caused, and the electrode corrosion can be prevented. Therefore, since the mechanism for removing bubbles is not required, the structure of the electroosmotic flow pump can be simplified. Further, the reliability of the electroosmotic flow pump can be improved. Further, by covering at least one of the second electrode and the second electrode with an insulating film, since no direct current flows between the two electrodes, electrode corrosion can be more reliably prevented. Further, since at least one of the first electrode and the second electrode is covered with the insulating film, electrons do not directly flow from the first electrode to the second electrode, and a current flows. Therefore, the power consumed in the circuit is only a charge and discharge depending on the capacitance of the insulating film covering the electrodes. Therefore, the power consumption can be remarkably reduced, and the generation of Joule heat can be remarkably reduced. In the case of the ninth embodiment, in order to efficiently transport the liquid, the asymmetric alternating current is preferably the waveform of Fig. 2 (b) or Fig. 2 (c). &lt;Embodiment 10&gt; 162130.doc -53·201243321 Another embodiment of the electroosmotic flow pump according to the first embodiment of the present invention will be described with reference to Fig. 34. In the present embodiment, unlike the ninth embodiment, an electroosmotic material made of a porous material is provided in a flow path between the second electrode and the second electrode. Fig. 34 is a schematic cross-sectional view showing an electroosmotic flow system 5300 of the present embodiment. The inside of the pipe member 5341 is a flow path and is filled with the liquid 5312 to be conveyed. In the upstream portion and the downstream portion of the tube member 5341, the first electrode 53 13 and the second electrode 53 14 having a plurality of holes are disposed apart from each other. The first electrode 53 13 and the second electrode 5314 are covered by the insulating film 53!6, and an alternating current source 5315 which generates an asymmetrical alternating current is connected. An electro-permeable material 5343 made of a porous material is disposed between the first electrode 5313 and the second electrode 5314 in the flow path. The electro-permeable material 5343 is, for example, a member made of a ceria fiber material or a porous ceramic, and functions to pass the liquid and substantially increase the area of the inner wall of the flow path. By disposing the electroosmotic material 5343 as shown in Fig. 34, the electro-permeable material is brought into contact with the liquid in a fine hole provided inside the electro-osmotic material, and the liquid is transported by the action of a unidirectional electric field generated by asymmetric alternating current. Since the porous material inside the electroosmotic material increases the contact area between the electroosmotic material and the liquid, the liquid transporting ability is also enhanced. According to the electroosmotic flow pump of the present embodiment, as in the ninth embodiment, bubbles are not generated by liquid electrolysis, and an electrochemical reaction is not caused, thereby preventing electrode corrosion. Therefore, since the mechanism for removing the bubbles is not required, the structure of the electroosmotic flow can be simplified, and the reliability of the electroosmotic flow pump can be improved. Further, since at least one of the first electrode and the second electrode is covered with the insulating film, corrosion of the electrode can be more reliably prevented. Moreover, the power consumption can be significantly reduced, and the generation of Joule heat can be significantly reduced. Further, by providing an electroosmotic material composed of a porous material between the first electrode 5313 and the second electrode 5314, the electroosmotic effect can be improved, so that the pump capacity can be drastically improved. &lt;Embodiment 11&gt; A fuel cell according to an eleventh embodiment of the present invention will be described with reference to Fig. 35. The fuel cell 6100 is provided with an electroosmotic pump 61H according to any one of the embodiments §, 9 or 1 of the present invention. Further, fuel is supplied from the fuel tank 6丨53 to the fuel cell unit 6152 and through the fuel delivery pipe 6154. A fuel cell state sensor 6156 is connected to the fuel cell unit 61 52 to detect the state of the fuel cell. The state of the fuel cell is transmitted from the fuel cell state sensor 6156 to the fuel supply control circuit 6157, and the fuel supply control circuit 6157 controls the fuel supply amount of the fuel cell 6151. The power required by the fuel cell state sensor 615 6 and the fuel supply control circuit 6丨5 7 is supplied by a DC/DC converter 6155 connected to the fuel cell unit 6152. A terminal 6158 for supplying power to the outside is connected to the DC/DC converter 6155. Since the fuel cell of the present embodiment includes the electroosmotic flow pump of the present invention, the fuel which is supplied by the electroosmotic flow pump does not electrolyze to generate bubbles, and does not cause an electrochemical reaction, so that the electrode does not rot #. Therefore, since the mechanism for removing bubbles is not required, the structure of the electroosmotic flow pump can be simplified, and the reliability of the electroosmotic flow pump can be improved. &lt;Fourth Embodiment&gt; A cooling pump according to a twelfth embodiment of the present invention will be described with reference to Fig. 36. The cooling pump 6200 includes an electroosmotic pump 6251 according to any one of the eighth, ninth or tenth embodiments of the present invention. Further, between the heat receiving portion 6259 and the heat exchanger 6260, the refrigerant is circulated through the refrigerant delivery pipe 6263. A temperature sensor 6261 is provided in the heat receiving portion 6259, and the temperature of the heat receiving portion 6259 is transmitted to the pump control circuit 6262. The pump control circuit 6262 controls the electroosmotic pump 6251 based on the information from the temperature sensor 6261, and moves the coolant to appropriately maintain the temperature of the heat receiving portion 6259. Since the cooling pump of the present embodiment includes the electroosmotic flow pump of the present invention, the fuel transported by the electroosmotic flow pump does not cause electrolysis to generate bubbles, and does not cause an electrochemical reaction, so that the electrode does not corrode. Therefore, since the mechanism for removing the air bubbles is not required, the structure of the cooling pump can be simplified, and the reliability of the cooling pump can be improved. &lt;Embodiment 13&gt; A chemical solution supply device 6300 according to a thirteenth embodiment of the present invention will be described with reference to Fig. 37. The chemical solution supply device 6300 includes the electroosmotic pump 63 51 of any one of the embodiments 8, 9, or 10 of the present invention. Further, the drug solution tank 63 64 is supplied to the drug solution supply destination by the drug solution delivery tube 63 68. A flow rate sensor 6365 is provided in the middle of the chemical liquid transfer tube 6368 to transmit the flow rate information to the chemical supply control circuit 6366. The liquid medicine supply control circuit 162130.doc -56-201243321 6366 controls the electroosmotic valve 6351 according to the instruction previously transmitted from the liquid medicine supply program input device and the flow rate information transmitted from the muscle mass sensor 6365, and adjusts the liquid medicine to be transported. Traffic. Since the chemical solution supply device of the present embodiment includes the electroosmotic flow I' of the present invention, the chemical solution transported by the electroosmotic flow pump does not cause electrolysis to generate bubbles, and 1 does not cause an electrochemical reaction, so that the electrode does not rot. . Therefore, since the mechanism for removing the air bubbles is not required, the structure of the chemical supply device can be simplified, and the reliability of the chemical supply device can be improved. BRIEF DESCRIPTION OF THE DRAWINGS FIGS. Ua) to (d) are explanatory diagrams of an embodiment of a waveform of a symmetrical alternating current. Fig. 2 (a) to (d) are explanatory views of an embodiment of an asymmetrical alternating current waveform of the invention. 30) and (b) are explanatory views of an embodiment of the waveform of the asymmetric alternating current of the invention. 4(a) to 4(d) are explanatory diagrams showing an embodiment of a method of determining asymmetric communication. Fig. 5 is a schematic block diagram showing an embodiment of an electric field generating device of the invention. Fig. 6 is a view showing the schematic configuration of an electric field generating device according to a second embodiment of the present invention. Fig. 7 (a) to (d) are explanatory views of an embodiment of the waveform of the asymmetric alternating current of the invention. Fig. 8 (a) to (c) are explanatory diagrams of an electric field generation phenomenon in a case where a direct current voltage is applied between electrodes in a liquid. 162130.doc -57- 201243321 FIG. 9 is an explanatory diagram of a simulation model of asymmetric communication of the present invention. Fig. 10 is an explanatory view showing a simulation model of the asymmetric communication of the invention. Fig. 11 is a waveform diagram showing an embodiment of an asymmetric rectangular wave used in the third simulation of the invention. Fig. 12 is a graph showing the amount of charge sensed by the first simulation of the invention. Figure 13 is a graph showing the amount of charge sensed by the first simulation of the present invention. Fig. 14 is a graph showing the intensity of an electric field in the liquid of the i-th simulation of the invention. Fig. 15 is a graph showing the relationship between the average electric field and the constant n in the i-th simulation of the invention. Fig. 16 is a graph showing the change in the position of the object in the liquid in the third simulation of the invention. Fig. 17 is a waveform diagram showing an embodiment of an asymmetric rectangular wave used in the second simulation of the invention. Fig. 18 is a graph showing changes in the time of the position of the object in the liquid in the second simulation of the invention. Fig. 19 is a waveform diagram showing an embodiment of a symmetrical rectangular wave used in the third simulation of the invention. Fig. 20 is a graph showing the change in the position of the object in the liquid in the third simulation command of the invention. Fig. 21 is a waveform diagram showing an embodiment of an asymmetric triangular wave used in the fourth simulation of the invention. Figure 22 is a graph showing the amount of charge sensed by the fourth simulation of the invention. Figure 23 is a graph showing the amount of charge sensed by the fourth simulation of the present invention. 162130.doc -58- 201243321 Figure 24 is a graph showing the intensity of the electric field in the liquid of the fourth simulation of the invention. Fig. 25 is a graph showing the relationship between the average electric field and the constant n in the fourth simulation of the invention. Fig. 26 is a graph showing the change in the position of the object in the liquid in the fourth simulation of the invention. Fig. 27 is a view showing the schematic configuration of a floating body moving device according to a third embodiment of the present invention. Fig. 28 is a view showing the schematic configuration of a floating body moving device according to a fourth embodiment of the present invention. Fig. 29 is a view showing the schematic configuration of a floating body moving device according to a fifth embodiment of the present invention. Fig. 30 is a schematic configuration diagram of an electrophoresis apparatus according to a sixth embodiment of the present invention. Fig. 3 is a schematic configuration diagram of an electrophoretic display device according to a seventh embodiment of the present invention. Fig. 3 is a schematic configuration diagram of an electroosmotic flow pump according to an eighth embodiment of the present invention. Figure 33 is a schematic configuration diagram of an electroosmotic flow pump according to Embodiment 9 of the present invention. Figure 34 is a schematic configuration diagram of an electroosmotic flow pump according to Embodiment 10 of the present invention. Fig. 35 is a schematic configuration diagram of a fuel cell according to an embodiment of the present invention. Figure 36 is a schematic configuration diagram of a cooling pump according to Embodiment 12 of the present invention. Figure 37 is a schematic configuration diagram of a chemical supply device according to a thirteenth embodiment of the present invention. [Main component symbol description] 1100 Electric field generating device 162130.doc •59- 201243321 1111 Container 1112 Liquid 1113 First electrode 1114 Second electrode 1115 AC power supply 1117 Arrow symbol 1216 Insulating film 2100 Floating body moving device 2111 Container 2112 Liquid 2113 1 Electrode 2114 second electrode 2115 AC power supply 2118 object 2216 insulating film 3100 electrophoresis device 3124 agarose gel 3125 well 4100 electrophoretic display device 4131 first substrate 4132 second substrate 4134 electrophoresis element 4135. capsule 4136 dispersion medium • 60-162130.doc 201243321 4137 Electrophoretic particle 4138 Electrophoretic particle 4139 Selective transistor 5100 Electroosmotic flow 5141 Pipe 5142 Slip surface 5216 Insulating film 5343 Electroseptic material 6100 Fuel cell 6151 Electroosmosis runner 6152 Fuel cell unit 6153 Fuel tank 6154 Fuel delivery tube 6155 DC/DC Converter 6156 Fuel cell state sensor 6157 Fuel supply control circuit 6158 Fuel supply terminal 6200 Cooling pump 6251 Electric energy flow 6263 Coolant delivery pipe 6300 Chemical liquid supply device 635 1 Electroosmotic flow system 6368 Chemical liquid delivery pipe 162130.doc -61 -

Claims (1)

201243321 七、申請專利範圍: ι —種電場產生裝置,其特徵為包含: 注入有液體之容器; 以各自至少一部份浸於注入於上述容器之液體中之方 式空開特定之間隔而配置之第1電極及第2電極;及 連接於上述第1電極及第2電極、且使非對稱之交流施 加於兩電極間之交流產生器;且 上述交流產生器於上述液體中產生實質上自上述第1 電極朝向第2電極之電場、或實質上自上述第2電極朝向 第1電極之電場之任一方之電場。 2_如請求項1之電場產生裝置,其中 上述第1電極與第2電極以與注入於上述容器之上述液 體直接接觸之方式配置; 上述非對稱交流中,將上述第1電極與第2電極之間之 電壓V⑴(t為時間)經過交流之1週期積分而得之式 Veff=IV(t)dt 之值實質上為0,且不具有實質之直流成分。 3. 如請求項1之電場產生裝置,其中 上述第1電極與第2電極之至少一方被絕緣膜覆蓋而不 與上述液體直接接觸。 4. 一種浮游體移動裝置,其特徵為包含: 注入有物體浮游之液體之容器; 以各自至少一部份浸於注入於上述容器之液體中之方 式空開特定之間隔而配置之第1電極及第2電極;及 162130.doc 201243321 連接於上述第丨電極及第2電極、且使非對稱之交流施 加於兩電極間之交流產生器;且 藉由上述交流產生器施加之非對稱交流,對於上述液 體中浮游之物體,使其進行自上述以電極向第2電極之 移動,或自上述第2電極向第丨電極之移動之任一方之移 動。 5 ·如請求項4之浮游體移動裝置,其中 上述第1電極與第2電極以任一者皆與液體直接接觸之 方式配置; 上述非對稱交流中,將上述第丨電極與第2電極之間之 電磨V(t)(t為時間)經過交流之1週期積分而得之式 Veff=/V(t)dt 之值實質上為0,且不具有實質之直流成分。 6.如請求項4之浮游體移動裝置,其中 上述第1電極與第2電極之至少一方被絕緣膜覆蓋而不 與上述液體直接接觸。 7· 一種電泳裝置,其特徵為包含: 注入有包含試樣之液體之泳動槽; 以各自至少一部份浸於注入於上述泳動槽之液體中之 方式空開特定之間隔而配置之第!電極及第2電極;及 連接於上述第1電極及第2電極、且使非對稱之交流施 加於兩電極間之交流產生器;且 利用上述交流產生器施加之非對稱交流,使液體中所 含之試樣在液體中之第1電極與第2電極之間泳動; 162130.doc 201243321 上述第1電極與第2電極之至少一方被絕緣膜覆蓋而不 與上述液體直接接觸。 8. —種電泳顯示裝置,其特徵為包含: 空開特定之間隔而對向配置之第1電極及第2電極; . 配置於由上述第1電極及第2電極相夾之空間,且包含 内包電泳粒子與分散液之複數個膠囊之電泳元件;及 連接於上述第1電極與第2電極,並使非對稱之交流施 加於兩電極間之交流產生器;且 利用上述非對稱交流’使各膠囊内之電泳粒子向一方 之電極之方向移動。 9. 一種電滲流泵,其特徵為包含: 流動液體之流道; 各自離間配置於上述流道之上游部與下游部、並具有 複數個孔之第1電極與第2電極;及 連接於上述第1電極與第2電極,並使非對稱之交流施 加於兩電極間之交流產生器;且 藉由施加上述非對稱交流,將流入上述流道内之液體 自位於流道内之上游部之第丨電極向位於流道内之下游 部之第2電極之方向輸送。 10. 如請求項9之電滲流泵,其中 上述第1電極與第2電極以與流入上述流道之上述液體 直接接觸之方式配置; 上述非對稱交流中’將上述第!電極與第2電極之間之 電壓V(t)(t為時間)經過交流之丨週期積分而得之式 162I30.doc 201243321 Veff=JV(t)dt 之值實質上為0,且不具有實質之直流成分。 11 ·如請求項9或1 〇之電滲流泵,其中 上述第1電極與第2電極之至少一方被絕緣膜覆蓋而不 與上述液體直接接觸》 12. 如請求項9或10之電滲流泵,其中 於上述第1電極與第2電極之間之上述流道内,設置有 由多孔質構成之電滲材。 13. 如請求項11之電滲流泵,其中 上述第1電極與第2電極之間之上述流道内,設有由多 孔質構成之電滲材。 14. 一種燃料電池,其具備如請求項9至13中任一項之電渗 流栗19 15. —種冷卻泵’其藉由如請求項9至13中任一項之電渗流 泵驅動。 16. —種藥液供給裝置’其藉由如請求項9至13中任一項之 電滲流泵驅動。 17. —種電場產生方法,其特徵為包含: 將液體注入於容器之準備步驟; 以各自至少一部份浸於上述液體中之方式空開特定之 間隔而配置第1電極及第2電極之配置步驟;及 將非對稱交流施加於上述第1電極及第2電極之間,並 於上述液體中產生實質上自上述第丨電極朝向第2電極之 電場、或實質上自上述第2電極朝向第丨電極之電場之任 162130.doc 201243321 一方之電場之電場產生步驟。 18.如請求項17之電場產生方法,其中 上述第1電極與第2電極係以任—者㈣Μ直接㈣ 之方式配置; 上述非對稱交流中,將上述第丨電極與第2電極之間之 電壓V(t)(t為時間)經過交流之丨週期積分而得之式 Veff=JV(t)dt 之值實質上為0,且不具有實質之直流成分。 19·如請求項17之電場產生方法,其中 上述第!電極與第2電極之至少—方被絕緣膜覆蓋而不 與上述液體直接接觸。 20. 如請求項17之電場產生方法,其中 上述非對稱交流為高電位持續時間與低電位持續時間 不同之矩形波。 21. 如請求項17之電場產生方法,其中 上述非對稱交流為上升時間與下降時間不同之三角波 或鑛齒波。 22· —種浮游體移動方法,其特徵為包含: 將浮游有物體之液體注入於容器之準備步驟; 以各自至少一部份浸於上述液體中之方式空開特定之 間隔而配置第1電極與第2電極之配置步驟;及 將非對稱交流施加於上述第1電極與第2電極之間,且 對於於上述液體中浮游之物體,使其進行自上述第1電 極向第2電極之移動,或自上述第2電極向第1電極之移 162130.doc 201243321 動中任一方之移動之移動步驟β 23.如請求項22之浮游體移動方法,其中 上述第1電極與第2電極俾以体 .^ , 之方式配置; 任一者均與液體直接接觸 上述非對稱交流中,將上述第i電極與第2電極之間之 電壓V (t) (t為時間)經過交流之】週期積分而得之式 Veff=/V(t)dt 之值實質上為G,且不具有實f之直流成分。 24. 如請求項22之浮游體移動方法,其中 上述第^電極與第2電極之至少—方被絕緣膜覆蓋而不 與上述液體直接接觸。 25. —種電泳方法,其特徵為包含: 將包含利用電泳而移動之試樣之液體注入泳動槽之準 備步驟; 以各自至少-部份浸於上述液體中之方式空開特定之 間隔而配置第1電極與第2電極之配置步驟;及 將非對稱交流施加於上述第丨電極與第2電極之間,並 使上述試樣在液體中之第!電極與第2電極之間泳動之泳 動步驟;且 上述第1電極與第2電極之至少一方被絕緣膜覆蓋而不 與上述液體直接接觸。 26. —種電滲流泵之動作方法,其特徵為: 將第1電極與第2電極分別離開配置於電滲流泵之流道 内之上游部與下游部; 162130.doc 201243321 將非對稱交流施加於上述第1電極與第2電極之間;且 將流入上述流道内之液體自位於上述流道内之上游部 之第1電極向位於流道内之下游部之第2電極輸送。 27. 28. 如請求項26之電滲流泵之動作方法,其中 上述第1電極與第2電極係以任一者均與液體直接接觸 之方式配置; 上述非對稱交流中,將上述第丨電極與第2電極之間之 電壓V (t) (t為時間)經過交流之丨週期積分而得之式 Veff=JV(t)dt 之值實質上為0,且不具有實質之直流成分。 如請求項26之電滲流泵之動作方法,其中 上述第1電極與第2電極之至少-方被絕緣膜覆蓋而不 與上述液體直接接觸。 162130.doc201243321 VII. Patent application scope: ι - an electric field generating device, comprising: a container filled with a liquid; configured by vacating at least a part of each of the liquids injected into the container at a specific interval a first electrode and a second electrode; and an alternating current generator connected to the first electrode and the second electrode and having an asymmetric alternating current applied between the electrodes; and the alternating current generator is generated in the liquid substantially The electric field of the first electrode toward the second electrode or the electric field substantially from the second electrode toward the electric field of the first electrode. The electric field generating device according to claim 1, wherein the first electrode and the second electrode are disposed in direct contact with the liquid injected into the container; and the first electrode and the second electrode are in the asymmetric alternating current. The voltage V(1) (t is time) is integrated over one cycle of the alternating current, and the value of the formula Veff=IV(t)dt is substantially zero and does not have a substantial DC component. 3. The electric field generating apparatus according to claim 1, wherein at least one of the first electrode and the second electrode is covered with an insulating film and is not in direct contact with the liquid. A floating body moving device, comprising: a container in which a liquid floating with an object is injected; and a first electrode disposed at a predetermined interval in such a manner that at least a portion thereof is immersed in a liquid injected into the container And a second electrode; and 162130.doc 201243321 is connected to the second electrode and the second electrode, and an asymmetric alternating current is applied to the alternating current generator between the two electrodes; and the asymmetric alternating current applied by the alternating current generator, The object floating in the liquid is moved from the electrode to the second electrode or from the second electrode to the second electrode. The floating body moving device according to claim 4, wherein the first electrode and the second electrode are disposed in direct contact with the liquid; and in the asymmetric alternating current, the second electrode and the second electrode are The electric grinder V(t) (t is time) is integrated by one cycle of alternating current, and the value of the formula Veff=/V(t)dt is substantially zero and does not have a substantial DC component. 6. The floating body moving device according to claim 4, wherein at least one of the first electrode and the second electrode is covered with an insulating film and is not in direct contact with the liquid. An electrophoresis apparatus comprising: a migration tank into which a liquid containing a sample is injected; and a portion which is disposed at a predetermined interval by immersing at least a part of each of the liquids injected into the swimming tank; An electrode and a second electrode; and an alternating current generator connected to the first electrode and the second electrode and having an asymmetric alternating current applied between the electrodes; and the asymmetric alternating current applied by the alternating current generator is used in the liquid The sample containing the sample moves between the first electrode and the second electrode in the liquid; 162130.doc 201243321 At least one of the first electrode and the second electrode is covered with an insulating film and is not in direct contact with the liquid. 8. An electrophoretic display device comprising: a first electrode and a second electrode disposed opposite to each other at a predetermined interval; and being disposed in a space sandwiched by the first electrode and the second electrode, and including An electrophoretic element enclosing a plurality of capsules of the electrophoretic particles and the dispersion; and an alternating current generator connected to the first electrode and the second electrode and applying an asymmetric alternating current between the electrodes; and using the asymmetric communication The electrophoretic particles in each capsule move in the direction of one of the electrodes. An electroosmotic flow pump comprising: a flow channel for flowing a liquid; a first electrode and a second electrode each having a plurality of holes disposed at an upstream portion and a downstream portion of the flow channel; and a first electrode and a second electrode, and an asymmetric alternating current is applied to the alternating current generator between the two electrodes; and by applying the asymmetric alternating current, the liquid flowing into the flow path is from the third portion located in the upstream portion of the flow path The electrode is transported in the direction of the second electrode located in the downstream portion of the flow path. 10. The electroosmotic flow pump according to claim 9, wherein the first electrode and the second electrode are disposed in direct contact with the liquid flowing into the flow channel; and the first electrode and the second electrode are in the asymmetric alternating current The voltage V(t) (t is time) is obtained by integrating the cycle of the alternating current cycle. 162I30.doc 201243321 The value of Veff=JV(t)dt is substantially zero and does not have a substantial DC component. 11. The electroosmotic flow pump of claim 9 or 1 wherein at least one of said first electrode and said second electrode is covered by an insulating film and is not in direct contact with said liquid. 12. Electroosmotic flow pump according to claim 9 or 10. An electroosmotic material made of a porous material is provided in the flow path between the first electrode and the second electrode. 13. The electroosmotic flow pump according to claim 11, wherein an electroosmotic material composed of a porous material is provided in the flow path between the first electrode and the second electrode. A fuel cell, which is provided with an electroosmotic flow pump 19, according to any one of claims 9 to 13, a cooling pump, which is driven by an electroosmotic flow pump according to any one of claims 9 to 13. 16. A liquid chemical supply device' which is driven by an electroosmotic flow pump according to any one of claims 9 to 13. 17. An electric field generating method, comprising: preparing a liquid into a container; and arranging the first electrode and the second electrode at a predetermined interval by at least partially immersing each of the liquids in the liquid And disposing an asymmetric alternating current between the first electrode and the second electrode, and generating an electric field substantially from the second electrode toward the second electrode or substantially from the second electrode in the liquid The electric field of the second electrode is 162130.doc 201243321 The electric field generating step of the electric field of one side. 18. The electric field generating method according to claim 17, wherein the first electrode and the second electrode are disposed in any one of (4) Μ directly (four); and in the asymmetric alternating current, between the second electrode and the second electrode The voltage V(t) (t is time) is integrated by the alternating cycle and the value of the formula Veff=JV(t)dt is substantially zero and does not have a substantial DC component. 19. The method of generating an electric field according to claim 17, wherein the above is the first! At least the electrode and the second electrode are covered by the insulating film without being in direct contact with the liquid. 20. The electric field generating method of claim 17, wherein the asymmetric alternating current is a rectangular wave having a high potential duration and a low potential duration. 21. The electric field generating method of claim 17, wherein the asymmetric alternating current is a triangular wave or a mineral tooth wave having a different rise time and fall time. A method for moving a floating body, comprising: preparing a liquid for injecting a liquid to the container; and arranging the first electrode at a predetermined interval by at least partially immersing each of the liquids in the liquid And a step of disposing the second electrode; and applying an asymmetric alternating current between the first electrode and the second electrode, and moving the object floating from the first electrode to the second electrode Or a movement step of the movement from the second electrode to the first electrode 162130.doc 201243321. The method of moving the floating body according to claim 22, wherein the first electrode and the second electrode are In the above-mentioned asymmetric alternating current, the voltage V (t) (t is time) between the ith electrode and the second electrode is subjected to periodic integration. The resulting value of Veff=/V(t)dt is substantially G and does not have a DC component of real f. 24. The method of moving a floating body according to claim 22, wherein at least one of said first electrode and said second electrode is covered by an insulating film without being in direct contact with said liquid. 25. An electrophoresis method comprising: preparing a step of injecting a liquid containing a sample moved by electrophoresis into a migration tank; arranging at a specific interval by at least partially immersing in the liquid a step of disposing the first electrode and the second electrode; and applying an asymmetric alternating current between the second electrode and the second electrode, and making the sample in the liquid! a step of migrating between the electrode and the second electrode; and at least one of the first electrode and the second electrode is covered with an insulating film and is not in direct contact with the liquid. 26. A method of operating an electroosmotic flow pump, comprising: separating a first electrode and a second electrode from an upstream portion and a downstream portion disposed in a flow path of an electroosmotic flow pump; 162130.doc 201243321 applying asymmetric alternating current to The first electrode and the second electrode are disposed between the first electrode and the second electrode, and the liquid flowing into the flow path is transported from the first electrode located in the upstream portion of the flow path to the second electrode located in the downstream portion of the flow path. 27. The method of operating an electroosmotic flow pump according to claim 26, wherein the first electrode and the second electrode are disposed in direct contact with the liquid; and in the asymmetric alternating current, the third electrode is The voltage V (t) between the second electrode and the second electrode is integrated by the cycle of alternating current, and the value of the formula Veff = JV(t)dt is substantially zero and does not have a substantial DC component. The method of operating an electroosmotic flow pump according to claim 26, wherein at least one of said first electrode and said second electrode is covered with an insulating film and is not in direct contact with said liquid. 162130.doc
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