TW201241136A - Adhesive functional film - Google Patents

Abstract

An adhesive functional film, wherein an adhesive force between a substrate and a silicone layer is not decreased no matter the adhesive functional film is used indoors or outdoors, is provided. Further, an adhesive functional film, wherein an adhesive force between the silicone layer and a to-be-adhered body is not increased even if sun light directly irradiates the adhesive functional film, is provided. The adhesive functional film includes an adhesive layer and a silicone layer laminated on at least one surface of substrate. The resin included in the adhesive layer is selected from polyester resin having 7-100 of acid value. Further, the resin of the adhesive functional film includes carboxyl group.

Description

201241136 VI. Description of the Invention: [Technical Field] The present invention relates to a function of applying an organic energy film to a substrate to perform printing, and can impart a function other than printing to smoothness, such as ultraviolet rays. Blocking or seeding a functional membrane that is functional. Further, the present invention is directed to a wide range of field towels, such as blocking, which enables (4) (4) materials to be used in the industry [Prior Art]. In the base material, the adhesive film of the same layer is provided, and the smooth surface t of the window or the like is easily attached to the substrate (Patent Document 2). In addition, === and / or a multi-layer machine specific machine "silk viewability ^ pair 2 is provided with a paste phase film, cut _ b: = hard coat = attached to the liquid crystal face and used as 昼 two = : For other purposes, the substrate is set as a material for various materials, and it is used as an industrial material in various fields. It is used for sealing materials, cushioning materials, etc. In addition, a method of laminating a layer of a lifted compound on a substrate is provided. However, if it is attached to the adherend, the following problem occurs: the adhesion increases with time. In addition, the same problem can be noticed when the direct sunlight is irradiated. [Patent Document 1] Japanese Patent Real Fair 6-21711 [Publication] Patent Document 2] Japanese Patent Laid-Open Patent Publication No. Hei No. 95-71. [Invention] The present invention is an invention for solving the above problems. The present invention provides a functional film which does not deteriorate even when the substrate and the layer are adhered to outdoors or indoors. Furthermore, this kind of adherent ship film, even when the sun shines directly, the pin-reed adhesion is not fixed. The first invention is an adhesive functional film having an adhesive layer and an anthrone layer on at least one area of the substrate, and the grease contained in the adhesive layer is selected from the group consisting of an acid value of 7~ A resin of a polyester resin in the range of 110. According to a second aspect of the invention, the adhesive functional film according to the first aspect of the invention, wherein the carboxylic acid group is present in the polyester resin. According to a third aspect of the invention, in the adhesive functional film according to the first aspect of the invention, the linoleic acid layer comprises at least one of the following oxalicone (1) to linaloone (4) and a SiH group. a polyorgano oxyhydrogen obtained by crosslinking a hydroxyl group to carry out cross-linking, (1) an anthrone containing only a direct-bonded polyorganic gas having a fine B group; (2) comprising both ends and side chains a fluorenone having a linear polyorganosiloxane having a vinyl group; (3) a branched polyorganic having a vinyl group only at the end;

(4) An anthrone containing a branched polyorgano-oxane having a vinyl group at the terminal and side chains. According to a fourth aspect of the present invention, in the adhesive functional film according to the second aspect of the present invention, the above fluorenone layer contains the following fluorenone (1) to 矽g (4) as small as possible! a polyorgano-oxo-oxide obtained by reacting with a hydroxyl group of a SiH group to carry out crosslinking, (1) a linear-polyorganic oxygen-containing oxalic acid having only a vinyl group at both ends; (2) a fluorenone having a linear polyorganosiloxane having a vinyl group at both ends and a side chain; (3) an anthrone containing a branched polyorganocene having a vinyl group at the terminal; (4) An anthrone having a branched polyorgano-oxane of B. on the side chain. According to a fifth aspect of the invention, the adhesive property according to the second aspect of the present invention, wherein the substrate and/or the laminate are provided with at least one specific function. The above-mentioned laminate refers to an adhesive layer, a stone layer, a functional layer and/or a film and/or a fabric. According to a sixth aspect of the invention, in the adhesive functional film according to the third aspect of the invention, the substrate and/or the laminate are provided with at least one specific function/'. The above-mentioned laminate means an adhesive layer, a layer of linoleum, a functional layer and/or a film and/or a fabric. According to a seventh aspect of the present invention, in the adhesive functional film according to the fourth aspect of the present invention, at least one of the base material and/or the laminate is provided with at least one functional layer of a specific function 2 201241m upper layer adhesive layer And/or the film and/or cloth _ [effect of the invention] The printable person of the functional functional film can be attached to the glazing and can be attached or peeled several times. Since the place where the substrate is bonded to the inside is not limited to the outdoor room, that is, the body is peeled off, and the shaft layer remains free from being bonded, and the sealing material or the liquid crystal screen protection film is used for various purposes. _, inkjet ink developing film, [Embodiment]: === film containing various plastic films, resins, etc., but not limited to, acryl acid system = _, preferably; Ester = place: = use 4 handsome ~ _ qing's van _ thickness. 1_Thickness hanger, or the surface of the vinegar film (10)... "The adhesive film made of enamel on the surface of the enamel. It is a corona discharge treatment, purple = The treatment of the ray is bonded to the ray irradiation treatment, the plasma treatment, etc. As the layer 201241136, the actinic ray is applied to the surface of the easy-adhesion layer of the film with the easy-adhesion layer. The substrate for treating the actinic ray or the layer of the linoleic layer after the layer is easily adhered to the substrate, the adhesion between the substrate and the lithium layer is insufficient. When the light resistance test is performed, peeling occurs. The adhesion improving agent is formulated as a pair of the oleanol layer. However, the adhesive of the present invention adheres strongly to the linaloic layer even if it is not formulated with an adhesion improving agent. Even in the light resistance test. , 矽 _ layer will not: tree month = layer Γ selected from the acid price of 7 ~ 110 in the range of the vinegar t month 曰 tree month. Can also be used in combination with two or more types of polyg resin , the adhesion of the layer to the bonded body with time 4 so that r: ':? will be the present invention When the film is peeled off from the adherend, it becomes difficult to make a rubber-based resin having an acid value of more than the above range, and it is difficult to produce a polyester resin having a value of 8 to 100%. r Poly-resin is preferably water-soluble poly-resin or water-dispersed, 曰; =: when the adhesive layer is used to prevent the motor from being applied to the coating layer than the organic solvent =: Γ:: Many in the water relay (8) ^ wt% (weight ratio of 8%) 7 by the solid content of the adhesive layer containing 4 〇 百 ) 〜 〜 〜 〜 〜 〜 丨 丨 丨 丨 丨 丨The coating of Shi Xi g on the layer and the coating solution of the coating liquid on the surface of the coffee machine are adhered to the other side, so that the generation of static electricity can be prevented, that is, the so-called peeling electrification is carried out on the back side. 201241136 T J Λ* / When the above resin is used, the acid group in the resin is subjected to a parent-tie reaction with the SiH group remaining in the fluorenone layer, and the amount of SiH groups remaining after the cross-linking reaction of the fluorenone itself can be reduced. It can prevent the adhesion of the surface of the adherend, especially the reaction between the glass surface and the fluorenone layer, from sticking to the adhesion. The acid group may, for example, be a carboxylic acid group, a sulfonic acid group or a phosphoric acid group. The acid group is particularly preferably a carboxylic acid group. The thickness of the adhesive layer is preferably in the range of 0 01 gm to 5 μm, more preferably 0.1. When the thickness of the adhesive layer is less than the above range, the fluorenone layer is easily detached from the substrate. If it exceeds the above range, the softness of the adhesive layer itself disappears and becomes hard. In the adhesive layer, the thermoplastic resin other than the above resin may be added to the adhesive layer in a range in which the effect of the present invention is not lowered. Examples of the thermoplastic resin include acrylic resin. Further, one or more of these may be used as the polyamine resin, the xylene resin, the ethylene-vinyl acetate copolymer, the alkyd resin, the urethane resin, and the like. As the anthrone used in the layer of the linoleic acid of the present invention, for example, an addition polymerization type anthrone polymer can be used. The addition polymerization type fluorenone resin is exemplified by polymerization by a platinum catalyst. As the properties of the anthrone layer suitable for the purpose of the present invention, it is required to have rubber-like flexibility, and the surface of the ketone layer is also convex and concave with respect to the unevenness of the surface of the two surfaces to be bonded. Further, it is required to be easily peeled off with a small peeling force at the time of peeling. The anthrone of such a property can be obtained by crosslinking at least one anthrone selected from the group consisting of the following: 〇) a linear polyorganoquinone having only the base 201241136 alkenyl group at both ends The oxime chain of the oxyalkylene has a thin linear chain of m^(2) comprising both ends and a side only at the end of the bundle; (3) a branch containing an alkenyl group and having a polymorphic appearance When the ketone, (4) ^ terminal and the side chain have a vinyl group, there is a branched form of 石 烧 石 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 The following general formula (compound 0 represented by η [Chemical Formula 1]

R R R __ I I | CH2=CHSi (OSi)n0SiCH=CH2

I I I

R R R

R R R (CH2 = CH)2Si (〇Si)nOSi (CH = CH2)2

R

R (CH2 = CH)3Si (〇Si)n〇Si (CH = CH2>3

I

R (wherein R represents the following organic group 'n represents an integer) 201241136 [Chemical 2]

R

R

R

C H 2= C H S i O — S i 〇 I R 0 (S i 〇 )

R

R I s I R :CH,

R R—Si "nr,

CH

II

In the formula CH /, R represents the following organic group, and m represents a hetero atom of the fluorene atom other than the entire δ-vinyl group, and may be the same species. The specific example (9) may be an alkyl group such as a group or an aryl group such as a phenyl group or a tolyl group. Alternatively, a hexyl group, a propyl group, a cyano group or the like may be substituted for the carbon atom of the group, except for the _ group of the tooth portion or the all-fourth material. R atom - Moer 〇 /. The organic group or the like which is a methyl group may be a compound of -50 or a compound of two or more kinds. The direct-bonded polyorgannic oxalicone having an acetyl group at both ends and in the side chain is a part (tetra) (tetra) group = compound in the above formula (Chemical Formula 1). The linaloic acid containing a branched polyorganophylline having only the end of the B-zone at the end is a compound represented by the above formula (Chemical Formula 2). The branched polyorganosiloxane having a vinyl group at the terminal and the side chain is a compound in which a part of R in the above formula (Chemical Formula 2) is a vinyl group. Here, the crosslinking agent used for the crosslinking reaction may be a known crosslinking agent. For 201241136 as a cross-linker _ sub,, the organic hydrogenated sand Wei. Shixi oxygen burning is one in which at least 3 bonds are bonded to the inhibitor in one molecule: in terms of practical use, it is preferred to have 2 in the molecule as 5Gwt% of the total amount thereof, and the remaining portion It is set as the person who has 3 ^iH keys. The starting catalyst used for the crosslinking reaction may be a well-known one, and may be exemplified by a gas uronic acid white alcohol compound such as dichlorinated sulphuric acid or tetrakisonic acid, a brewing compound' or a gas mixture and various olefins. The chain of smoke tends to ^. The cross-linking reaction (4) is carried out to form a layer having a rubber-like y =, which makes it easy to adhere to the adherend. The commercially available product of the linoleic material of the present invention has a solvent-free type and a solvent type: an emulsion type, and any type can be used. Among them, the solvent-free type = the use of the agent, it is very good in terms of safety, hygiene, and air pollution. Outside, the coating thickness of the anthrone layer must exceed 11 μm. - a thickness of a few millimeters. Therefore, solvent ketone or emulsion type (4) = drying of the solvent at the time of coating requires a lot of energy, and becomes not (4) It is preferable to use (4) (4) in the present invention to use a non-solvent. As described above, the adhesive layer of the present invention is focused on the layer of the linoleum. If you need a higher adhesion, you can also = 嗣ί contains a small amount of artificial modifier. The hybrid modifier is a compound containing a functional group reactive with a radical reaction. The acrylic acid derivative 'methacrylic acid derivative, ^^, and the like can be exemplified. Among the above derivatives, 'the compound having two or more unsaturated bonds is preferred. These compounds are compounds widely used as crosslinking agents for rubber 11 201241136, and examples thereof include poly- acrylates of poly- phthalic acid: acrylic acid or methyl propyl cyanurate Wait. Isopropyl isopropyl cyanurate, triene propyl to prevent the surface of the enamel layer

Attached to the sex machine, the addition of a new film, 贱 着, or upgrade. As the separator, a separator such as a sapphire film is bonded to the olean layer. Generally, the thickness of the fluorenone layer is preferably a range of the enamel layer. For the second two: it becomes difficult to adhere to the bonded body, and the shear force in the direction of the contact surface of the mI (m, 2, t machine) becomes less than 1.0 N/cm2. It can be used for a long time. (4). The thickness of the thick__ machine is variable, resulting in a cost of more than 50 Qing, the use of Shi Xiyu is good in a 1 in industrial applications such as sealing materials and cushioning materials. The thickness of the lintelone layer is higher than that of the gonad μ^5(Κ) μηι. It is given the adhesion function 11 film 有 which has other special energy, and the thickness of the _ _ _ _ _ _ _ _ _ _ _ Various (four) syllabus is prepared by dissolving and dispersing a suitable solvent, and coating it on a substrate and drying it. As a coating method for the coating layer coating solution or the coating layer, it can be used as a coating method. The indirect gravure coater or the money coater is a representative coat, a direct gravure coater, a bar coater, an air knife coater, etc. The material of the body is usually glass, Resin plate, metal plate, or warp plate, etc. The surface that is difficult to reduce must be as smooth as possible. If the surface has large irregularities, the fluorenone layer is difficult to follow the unevenness, and it becomes impossible. 8 12 201241136 The specific functions of the present invention are properties, electromagnetic wave blocking, antistatic properties, conduction, breaking, infrared blocking, antibacterial, printing, ink acceptance, sex, deodorization, scratch resistance Properties, thermal conductivity, etc. >7, anti-fogging property, water repellency, and the above-mentioned specific function are any one or more of the above functions in which the functional layer and the layer are formed by only the layer containing the functionalizing agent, and the ultraviolet blocking Anyone who is preferably a transparent substrate is provided by two or two materials and a layered collector. The electromagnetic wave blocking property of the inorganic or organic ultraviolet absorbing and aligning transparent substrate and the laminated layer can be borrowed. It is made up of a film that is not a threat to the life of the Messi City or an organic conductive agent, or: 2, which is attached to the genus or the oxide film, and can be dreamed of a layer of money on the substrate. τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ The film is used to impart beauty and deodorization by means of a substrate and a laminate. In one case, it is preferred that the soil is formulated with an inorganic or organic deodorant or a deodorant. The antibacterial property can be imparted by adding an inorganic or organic antibacterial agent to the substrate and the laminate, and == The two-layer layer contains an active layer of a photocatalyst such as oxidized crystal to impart .g ^ 13 201241136 Printability can be imparted by adhering to the surface of the substrate or the adhesion of the toner. In addition, the aqueous polymer layer or the ink of the printing ink is provided. More than 9 1 = surface formed pro-printed or copied content, can be used as a poster and its: Guang 2: contact, notification method attached to the whiteboard or wall, =:: anti-layer::; on the substrate table * The laminated hydrophilic layer is imparted by forming a water-repellent layer containing a gas compound or a water-repellent layer of a composite of a fluorine compound and a photocatalyst on the surface of the substrate. Early body scratch resistance can be achieved by forming a hard coat layer containing a substance or a composite on the surface of the substrate, and the office is automatically 丄== aluminized bismuth, quartz, aluminum hydroxide, and the like. Composite = ί:: 'The adhesion of the substrate to the layer other than the ketone layer of the adhesive is two::. Namely, a film obtained by separately and affixing can be attached by an adhesive or a binder or heat bonding. It may be a method of direct integration by a coating method or a coating method, such as the 201241136 method or an extrusion lamination method. This direct integration approach is particularly good from an economic point of view. [Examples] The present invention will be more specifically illustrated by the following examples. [Formation of Ink Development Layer] The following development layer coating liquid was dispersed by a disperser to prepare a liquid. The coating liquid was applied to one side of a polyethylene terephthalate film having a thickness of 50 μm, and dried to form a developing layer for a black jet printer having a thickness of 25 μm. Synthetic layer coating liquid to synthesize amorphous ceria 4.2 parts by weight of hydrophilic amino phthalate resin 6.2 parts by weight of polyacrylate aqueous solution (solid content: 3% by weight) 1 part by weight of dicyandiamide-based resin aqueous solution ( Solid content: 25%) 2 parts by weight of decyl hydrazine. 6 weight: ^ 49 parts by weight σ 10,000 parts by weight [Synthesis of resin of adhesive layer] Adhesive layers of Examples 1 to 4 and Comparative Examples 1 to 2 The method for synthesizing the resin contained therein is as follows. The raw material compounds shown in Table 2, Table 2, were added to the reaction vessel in the amounts shown in Table 2 (moles). Under a nitrogen gas stream, a small catalytic reaction of 3 5 was carried out at a pressure of MP = G and a temperature of 2 thieves. Adding triterpenoids to the obtained acetate 2 5χ1〇-4 mol/acid component i mo 15 201241136 Ear. The pressure was reduced to 55 hPa, and a polycondensation reaction was carried out for 3 hours at 28 (TC) to obtain a polyester. Then, the depolymerizing agents shown in Table 1 and Table 2 were used in the amounts shown in Table 1 and Table 2 ( The molar amount was added to the polyester, and the depolymerization reaction was carried out at 250 ° C for 2 hours under normal pressure to obtain a polyester resin having the characteristics of Tables 1 and 2. Further, hot water of 9 ° C was added. A method of synthesizing a resin contained in the adhesive layer of Comparative Example 3 to Comparative Example 4 was as follows. The raw material compounds shown in Table 3 were as shown in Table 3. The indicated amount (molar parts) was added to the reaction vessel, and azobisisobutyronitrile 5 〇xl〇·2 mol parts was added to the reaction vessel. The reaction was carried out at 115 ° C for 3 hours under a nitrogen gas stream. After completion of the reaction, the equivalent amount was neutralized with dimercaptoethanolamine, and butyl cellosolve was further added to obtain an acrylic copolymer solution having a solid content of 20% and having the characteristics of Table 2. [Formation of Adhesive Layer] Example 1 The resin solution of Example 4 and Comparative Example 1 to Comparative Example 4 was applied to the opposite surface of the substrate and dried to form Adhesive layer having a thickness of 〇 3. [Formation of an fluorenone layer] The following fluorenone coating liquid was applied onto the adhesive layer of Example 4, Comparative Example 1 to Comparative Example 4, followed by 15 〇. Heating at °c for 1 〇〇 second to crosslink the fluorenone. The fluorenone layer having a thickness of 25 μm was formed to form a film for inkjet recording, and the film was coated with only vinyl at both ends. Chain-shaped poly-age _ (containing cross-linking part) type 1) (trade name "X_62-1347" Shin-Etsu Chemical Co., Ltd. (stock name "cat-pl-56" Shin-Etsu Chemical Industry Co., Ltd. 2 The evaluation method evaluates the heterogeneity of each sample. 2 aliquots [Method for the determination of the acid value of the fine fat] Accurately measure to the simmered simmered simmered 使 ^ ^ ^ ^ (toluene: methanol = 9:1 volume ratio) chest L , = 谷 solution 1 1% hope 酞 solution as a finger: ==== liquid 'will remain red _ point by the same operation to carry out the blank test. (BmL) acid value (mgKOH / g) = (A_B) xfx56J / s A in the above formula: The amount of use (mL) of the 0.1 m〇l/L alcoholic potassium hydroxide solution required in the sample is called the use of O.lm sputum required in the T 虱 milk blank test. (mL) (4) Potassium-cooled f: O.lmol/L of alcoholic potassium hydrosulfide solution S: Sample extraction amount (g) Evaluation method 201241136 1. Light resistance test Preparation of film of each example and comparative example The sample was cut into a suitable size. The ketone layer of the cut sample was attached to the transparent glass, and the carbon arc was irradiated for 100 hours in the carbon arc light resistance test for the glass side. Evaluation of A and B. A. Adhesive layer evaluation; adhesion evaluation of g-ketone layer The edge portion of the sample was cut with a finger and the degree of peeling of the same layer of the stone was evaluated by the following criteria. The evaluation results are shown in Table 1. 〇: No flaking occurs at all. △: Partially peeled off between the adhesive layer and the anthrone layer. x : Complete peeling off. B. Glass peeling evaluation; 6 eve layer peeling evaluation by 180. The polyethylene terephthalate film of the cut sample adhered to the glass was peeled off, and the degree of peeling of the anthrone layer was evaluated for the glass based on the following criteria. The evaluation results are shown in Table 。. ' 〇 : The fluorenone layer is completely peeled off from the glass. △: The fluorenone layer was transferred and adhered to the glass due to agglomeration failure of a part of the fluorenone layer. x. The ketone layer is transferred and adhered to the glass due to the cohesive failure of the fluorenone layer on the entire surface of the affixing portion. 2. Image Formability In the samples of the above Examples 1 to 3 and Comparative Examples 1 to 5, in order to protect the surface, a transparent polyethylene terephthalate (PET) film having a thickness of 25 μm was used as the film. The separator 201241136 is attached to the fluorenone layer. Each sample was cut into A4 size to prepare a sheet sample. A full-color image was formed on the sheet sample image layer using an ink jet printer PM_9〇〇c (dye, ink) manufactured by Seiko Epson. A clear full color image is formed in any sheet sample. [Table 1] Decomposition of a raw material compound deuterated acid adipic acid + ethylene glycol neopentyl glycol bisphenol A ethylene oxide adduct ~ trimellitic anhydride between stupid acid acid value ( mgKOH/g) resistance - frontal light test - adhesion evaluation of adhesive layer and anthrone layer evaluation of peeling of anthrone layer when glass is attached [Table 2] Test results of light resistance test of raw material compound depolymerizer Ethylene phthalate adipate neopentyl glycol

Acid value of bisphenol A ethylene oxide adduct m-benzoic acid isophthalic acid-5-sodium sulphate resin (mgKOH/g) Adhesion evaluation of adhesive layer and anthrone layer When glass is attached Peel evaluation of anthrone layer

4 3ό!〇 4J 36Ό Ϊ5Λ ~6Λ ~Q~ 2.5 U o Comparative Example 1 ~Xs~ ^5.0 6.0 ΤΓ 3.5 T — 丨_ 〇 △ 2 37.0 4.0 37.0 1^0 0 7.0丁 19 201241136 [Table 3]

Comparative Example 3 4 Starting material ethylene glycol monobutyl ether 60.0 40.0 decyl methacrylate 15.0 20.0 n-butyl acrylate 10.0 15.0 styrene 10.0 15.0 acrylic acid 5.0 10.0 acid value of resin (mgKOH/g) 40 87 $ Adhesion evaluation of the photo-adhesive layer and the anthrone layer of the test-resistance-resistant layer 〇X Peeling evaluation of the anthrone layer when the glass is attached XX [Simple description of the drawing] None. [Main component symbol description] None 0 20

Claims (1)

201241136 VII. Patent application scope: 1. An adhesive functional film which has at least an adhesive layer and a paste layer on a substrate, and the layer contained in the above adhesive layer has an acid value of 7 to 110. A range of polyester resins. Selection 2. The adhesive functional film described in the above Patent Application No. 2, wherein a tetacid group is present in the above polyester resin. , ~ 3. As claimed in the scope of the patent application, the above-mentioned anthrone layer contains the following ketone (丨) ~ fluorenone (4) ', less than 1 a poly(anthracene) obtained by reacting with a hydroxyl group of a SiH group to carry out crosslinking, and an oxygen (1) comprising an anthranone having a linear polyorganophosphoric acid having a vinyl group at both ends; (2) a fluorenone (3) comprising a straight-chain polyorgano-oxygenated oxo-oxygen group having an ethyl group on both ends and a side bond; the fluorenone (3) containing a vinyl group having only a vinyl group at the end ( 4) An anthrone comprising a branched polyorganosiloxane having a vinyl group at the terminal and side chains. 4. The adhesive functional film according to claim 2, wherein the anthrone layer comprises at least one of an anthrone (1) to an anthrone (4) and a hydroxyl group of an SiH group a polyorgano oxyhydrogen obtained by crosslinking the reaction, (1) a linear polyorgano-oxygenated oxazepine having a vinyl group at both ends; 21 201241136 (2) comprising both ends and sides a linear polyorgano-oxygenated alkaloid having a vinyl group in the chain; (3) an anthrone comprising a branched polyorganosiloxane having a vinyl group at the end; - (4) comprising a terminal and a side Branched polyorganooxylated alkaloids having a vinyl group on the chain. 5' The adhesive functional film according to claim 2, wherein the substrate and/or the laminate are provided with at least one specific function, and the laminate refers to an adhesive layer, Layers, other functional layers and/or films and/or fabrics that are added as needed. 6. The adhesive functional film according to claim 3, wherein the substrate and/or the laminate are provided with at least one specific energy, and the laminate refers to an adhesive layer or a stone. The ketone layer, other functional layers and/or films and/or fabrics that are attached as needed. The adhesive functional film according to Item 4, wherein the substrate and/or the laminate are provided with at least one specific function, and the laminate refers to an adhesive layer or an anthrone. Layer, other functional layers and/or membranes and/or fabrics attached to α as needed. ° 201241136 to-be-adhered body is not increased even if sun light directly irradiates the adhesive functional film, is provided. The adhesive functional film includes an adhesive layer and a silicone layer laminated on at least one surface of substrate. The adhesive layer is selected from the polyester resin having 7-100 of acid value. Further, the resin of the adhesive functional film includes the carboxyl group. 4. The designated representative figure: (1) The representative representative figure of the case is: none. (2) A brief description of the symbol of the representative figure: Benefit. 5. If there is a chemical formula in this case, the chemical formula is none. Please reveal the best features of the invention 2