201233399 六、發明說明： 【發明所屬之技術領域】 本發明係關於毛髮用化妝料生成劑，尤其是關於互相 混合時自我起泡而成泡沫狀毛髮用化妝料之由多數用劑而 成之毛髮用化妝料生成劑及其製造方法。 【先前技術】 傳統上’作爲毛髮脫色劑或染髮劑之毛髮用化妝料， 液狀或膏狀物普及。然而’現在與液狀或膏狀毛髮用化妝 料比較’可以簡便地塗抹而且具有塗抹時不會不均勻之優 點之泡沫狀毛髮用化妝料逐漸普及。作爲泡沫狀毛髮用化 妝料’已知有例如氣溶膠型毛髮用化妝料（例如專利文獻 1)、及無氣溶膠型之毛髮用化妝料（例如專利文獻2)。 氣溶膠型毛髮用化妝料係使用噴射劑而使毛髮用化妝 料成泡沫狀’所以需要特殊容器，有耐壓容器腐蝕或內壓 上升之虞’以及使用後容器難以廢棄之問題。另外，無氣 溶膠型毛髮用化妝料，爲簡易地取得泡沫狀毛髮用化妝料 ’所以調低毛髮用化妝料之混合藥劑之黏度，而有容易發 生使用時滴落之問題。 [先前技術文獻] [專利文獻1]特開平1 0-2 8 75 3 4號公報 [專利文獻2]特開2004-33 92 1 6號公報 201233399 【發明內容】 發明所欲解決之課題 本發明係提供爲無氣溶膠型，可簡易取得之具有使用 時可抑制滴落之黏度之泡沫狀毛髮用化妝料之毛髮用化妝 料生成劑爲目的。 課題之解決手段 本發明係爲解決至少部份前述課題所實施者，以後述 型態或使用例而可實現。 [使用例1] 藉由混合複數用劑而自我起泡，用以生成泡沬狀毛髮 用化妝料之毛髮用化妝料生成劑， 前述複數用劑包含至少含有碳酸鹽之第1劑、及含有 可分解前述碳酸鹽總量的酸之第2劑， 前述複數用劑中至少任一種用劑含有使前述毛髮用化 妝料黏度於1500mPa· s〜83000mPa· s之範圍內之增黏劑 之毛髮用化妝料生成劑。 若爲如此之組成時，作爲毛髮用化妝料生成劑之複數 用劑中至少任一種用劑含有使毛髮用化妝料黏度於1 500 mPa · s〜83 000mPa . s之範圍內之增黏劑，所以可以抑制 藉由混合複數用劑而發生的二氧化碳所成的泡沫消泡，使 毛髮用化妝料之泡沫持久。此結果係可提供爲無氣溶膠（ Non-aero sol )型，可簡易取得之具有使用時（塗抹時或放 -6 - 201233399 置時）可抑制滴落之黏度之泡沫狀毛髮用化妝料之毛髮用 化妝料生成劑。 [使用例2 ] 爲使用例1記載之毛髮用化妝料生成劑’前述增黏劑 係締合型增黏劑之毛髮用化妝料生成劑。 若爲如此組成時，因爲作爲毛髮用化妝料生成劑之複 數用劑中至少任一種用劑含有締合型增黏劑，所以各個複 數用劑可以低黏度狀態下製造毛髮用化妝料生成劑，而且 可以提供混合複數用劑時，爲適當的pH範圍，可生成增 黏之毛髮用化妝料之毛髮用化妝料生成劑。 [使用例3] 爲使用例1或2記載之毛髮用化妝料生成劑，前述碳 酸鹽係含有至少一種選自碳酸根離子之鹼金屬鹽或鹼土金 屬鹽、碳酸氫根離子之鹼金屬鹽或鹼土金屬鹽、碳酸銨、 碳酸氫銨所成群之碳酸鹽之毛髮用化妝料生成劑。 若爲如此組成時，因爲第1劑係含有至少一種選自碳 酸根離子之鹼金屬鹽或鹼土金屬鹽、碳酸氫根離子之鹼金 屬鹽或驗土金屬鹽、碳酸銨、碳酸氫銨所成群之碳酸鹽， 可提供對水溶解性、與酸之反應性良好之第丨劑。此結果 係可更加提高作爲毛髮用化妝料生成劑之複數用劑混合時 之起泡性。 201233399 [使用例4] 使用例1至3中任一項記載之毛髮用化妝料生成劑， 前述毛髮用化妝料中前述碳酸鹽所占含量爲1.0質量 %〜30.0質量％之毛髮用化妝料生成劑。 若爲如此組成時，因爲毛髮用化妝料中碳酸鹽所占含 量爲1 · 〇質量％〜3 0 · 0質量％，所以可以實現作爲毛髮用 化妝料生成劑之複數用劑混合時之自我起泡。 [使用例5] 使用例1至4中任一項記載之毛髮用化妝料生成劑， 前述毛髮用化妝料係使用於毛髮染色之化妝料， 前述毛髮用化妝料係於pHl.O〜9.0之範圍內之毛髮 用化妝料生成劑。 若爲如此組成時，因爲使用於毛髮的染色之毛髮用化 妝料將於pH 1.0〜9.0之範圍內，所以可得到高染髮力以 及適當的黏度。另外，因爲將可使毛髮用化妝料生成劑所 含之碳酸鹽與酸有效率地反應，所以可得到細緻的毛髮用 化妝料泡沫。 [使用例6] 使用例1至4中任一項記載之毛髮用化妝料生成劑， 前述毛髮用化妝料係使用於毛髮染色或漂白、脫色之 化妝料， 前述毛髮用化妝料係於pH6.0〜9.0之範圍內之毛髮 201233399 用化妝料生成劑。 若爲如此組成時，因爲使用於毛髮的染色或漂白、脫 色之毛髮用化妝料將於pH6.0〜9.0之範圍內，所以可得 到高染髮力及脫色力以及適當的黏度。另外，將可使毛髮 用化妝料生成劑所含之碳酸鹽與酸有效率地反應，可得到 細緻的毛髮用化妝料泡沫。 [使用例7] 使用例1至6中任一項記載之毛髮用化妝料生成劑， 前述複數用劑中至少任一種用劑係更含有碳數爲10〜 30之直鏈烷基或碳數爲10〜30之烯基之高級醇之毛髮用 化妝料生成劑。 若爲如此組成時，作爲毛髮用化妝料生成劑之複數用 劑中至少任一種用劑係含有碳數爲1 0〜3 0之直鏈烷基或 碳數爲1〇〜30之烯基之高級醇·。因爲高級醇係可賦予毛 髮用化妝料硬度，所以可以抑制藉由混合複數用劑而發生 的二氧化碳所成的泡沫消泡，使毛髮用化妝料之泡沫持久 。並且可得到細緻的泡沫。 [使用例8 ] 藉由混合複數用劑而自我起泡，在用以生成泡沫狀毛 髮用化妝料之毛髮用化妝料生成劑中，至少含有碳酸鹽之 第1劑之製造方法，包含 乳化混合非酸性之基劑成分及還原劑成分之第1步驟 201233399 、及 對前述藉由第1步驟生成之乳化混合物，添加前述含 碳酸鹽之鹼劑成分之第2步驟、及 對前述藉由第2步驟生成之乳化混合物，添加酸性之 基劑成分之第3步驟之第1劑之製造方法。 若爲如此組成時，毛髮用化妝料生成劑中，至少含有 碳酸鹽之第1劑之製造方法，因爲對乳化混合非酸性之基 劑成分及還原劑成分之乳化混合物，添加含碳酸鹽之鹼劑 成分後，添加酸性之基劑成分，所以保持乳化混合物於鹼 性之狀態下，可添加鹼劑成分，亦即碳酸鹽。此結果係於 製造第1劑時，可抑制因碳酸鹽與酸性狀態的乳化混合物 接觸之起泡。因此，可提供爲無氣溶膠型，可簡易取得之 具有使用時可抑制滴落之黏度之泡沫狀毛髮用化妝料之毛 髮用化妝料生成劑。 另外，本發明係可以各種型態實現。例如本發明係可 以毛髮用化妝料生成劑、毛髮用化妝料生成劑之製造方法 、使用毛髮用化妝料生成劑之毛髮用化妝料、及使用毛髮 用化妝料生成劑之毛髮用化妝料之生成方法等之型態實現 用以實施發明之最佳型態 接著’以後述順序說明本發明之實施型態。 【實施方式】 -10- 201233399 A.實施型態 A - 1.毛髮用化妝料組之組成： 圖1槪略地表示本發明之實施型態中毛髮用化妝料組 1 〇之組成之說明圖。毛髮用化妝料組1 0係包含混合用容 器10 0、混合用器具2 0 0、第1劑3 0 0、及第2劑4 0 0。後 續總稱第1劑300及第2劑400，亦稱爲「毛髮用化妝料 生成劑j 。 第1劑3 00及第2劑400係各個分別收納於收納容器 (例如管狀容器）之液狀或膏狀劑。第1劑3 00及第2劑 400的組成係設定成互相混合時而成毛髮用化妝料（染髮 劑或脫色劑）。另外，第1劑3 0 0含有碳酸鹽（碳酸氫鈉 )成分，第2劑400係含有分解碳酸鹽之酸成分。因此， 混合第1劑3 0 0及第2劑4 0 0時，第1劑3 0 0所含的碳酸 鹽與第2劑400所含的酸反應，產生氣泡（二氧化泡）。 另外’關於第1劑3 00及第2劑400的詳細成分敍述如後 〇 混合用容器100係混合第1劑3 00及第2劑400時收 納之杯狀容器’由樹脂（例如PP )所形成。混合用器具 200係用以混合收納於混合用容器1〇〇之第1劑3 00及第 2劑400時之平板狀（匙狀）器具，由樹脂（例如PP )所 形成。 A- 2_毛髮用化妝料製造處理： 圖2係表示使用毛髮用化妝料組丨〇之毛髮用化妝料 -11 - 201233399 生成處理流程之流程圖。另外，圖3及圖4 用化妝料組10之毛髮用化妝料生成處理槪要 最先準備如圖1所示之包含混合用容器 器具200、第1劑300及第2劑400之毛髮j (步驟S110)。接著，將第1劑300及第 納容器移至混合用容器100內（步驟S120: 示第1劑3 00及第2劑400由收納容器移 1 〇 〇內之狀態。 接著’將移至混合用容器100內之第！ 劑4 00 ’使用混合用器具200混合（步驟S1 表示使用混合用器具200混合第1劑300及 狀態。使用混合用器具2 0 0混合第1劑3 0 0 時，第1劑3 00含的碳酸鹽與第2劑400所 產生氣泡（二氧化碳）。藉此於混合用容器 沫狀毛髮用化妝料。圖4係表示於混合用容 泡沫狀毛髮用化妝料FO之狀態。另外，如 合用器具200亦作爲撈取混合用容器1〇〇內 狀毛髮用化妝料FO用之器具使用。使用者 具200’榜取毛髮用化妝料f〇，以手拿取混 上之毛髮用化妝料FO，塗抹於毛髮上。 如前述說明，本實施型態之使用毛髮用 之毛髮用化妝料生成處理係藉由混合互相混 而成泡沫狀毛髮用化妝料之複數用劑，可不 或噴射劑而得到泡沬狀毛髮用化妝料。此時 表示使用毛髮 :之說明圖。 100、混合用 甩化妝料組1 0 2劑400由收 )。圖3係表 至混合用容器 劑3 00及第2 30)。圖3係 第2劑400之 及第2劑400 含的酸反應， 1〇〇內生成泡 器1 00內生成 _ 4所示，混 所生成之泡沫 使用混合用器 合用器具200 丨化妝料組1 0 合時自我起泡 使用特殊容器 ，使用者無須 -12- 201233399 進行振動收納用劑之容器之作業，只要進行使用混合用器 具200，攪拌混合混合用容器1〇〇內所收納之第i劑300 及第2劑400之簡單作業即可。另外，本實施型態之使用 毛髮用化妝料組10之毛髮用化妝料生成處理，因爲使用 者可以觀察藉由混合複數用劑而產生氣泡，液狀或膏狀之 複數用劑緩緩地成爲泡沫狀毛髮用化妝料F〇之狀態，所 以可以提高演出性（快樂、興奮感）。 A — 3.毛髮用化妝料生成劑之製造方法： 圖5係表示毛髮用化妝料生成劑中第1劑300之製造 步驟之流程圖。首先，將成爲第1劑300之原料成分，分 爲鹼劑（A)、非酸性之基劑（B )、酸性之基劑（C )、 還原劑（D )，分別選擇（步驟S2 1 0 )。 作爲鹼劑（A )成分係選擇碳酸鹽。作爲鹼劑（a ) 成分係可選擇至少1種以上選自例如碳酸根離子之鹼金屬 鹽或驗土金屬鹽、碳酸氫根離子之鹼金屬鹽或鹼土金屬鹽 '碳酸銨、碳酸氫銨所成群之碳酸鹽。另外，毛髮用化妝 料（亦即混合第1劑300及第2劑4〇〇之混合藥劑）之碳 酸鹽含量係以1 . 0質量％〜3 0 · 0質量％爲宜，以1 · 5質量％ 〜20_0質量％尤佳。另外，除了碳酸鹽，亦可添加適當的 氨水等。 非酸性之基劑（B )係除了非酸性之外，並無特別的 限定°非酸性之基劑（B)成分係依目的之毛髮用化妝料 之用途（染髮劑、脫色劑等）及劑型等，可選擇1種或其 -13- 201233399 以上之成分組合。作爲非酸性之基劑（B )成分，可使用 例如氧化染料、烴、酯、聚矽氧烷、高級醇、動植物油、 界面活性劑、植物萃取物、醇類、天然或合成高分子、香 料、精製水等。作爲高級醇，尤其以含有1種以上之碳數 爲10〜30(以12〜24爲宜，以14〜22尤佳）直鏈烷基或 碳數爲10〜30 (以12〜24爲宜，以14〜22尤佳）之烯基 之高級醇（例如十六烷醇、硬脂醇）尤佳。 酸性之基劑（C )成分係除了酸性之外，並無特別的 限定。酸性之基劑（C)成分係可依目的之毛髮用化妝料 生成劑之用途及劑型等，選擇1種或其以上之成分組合。 因爲本實施型態係採用第1劑3 00中含增黏劑之組成，所 以作爲酸性之基劑（C )成分，可選擇例如L -抗壞血酸 、檸檬酸、乙醇酸等之有機酸、磷酸、硫酸等之無機酸等 、或作爲增黏劑之羧乙烯聚合物。另外，作爲增黏劑，雖 可使用任意種類之增黏劑，但以使用於特定pH範圍具有 增黏性質之締合型增黏劑（中和型增黏劑）尤佳。另外， 毛髮用化妝料（混合藥劑）中增黏劑含量係以使毛髮用化 妝料（混合藥劑）之黏度於1500mPa· s〜83000mPa· s之 範圍內之份量爲宜，以使於1500mPa· s〜30000mPa· s之 範圍內之份量更佳。 作爲還原劑（D)成分，可自例如光胱胺酸或其衍生 物、硫代蘋果酸等之毓基羧酸、硫甘油等之毓醇類、甘油 毓基乙酸酯等之巯基羧酸酯類、锍基乙胺（cysteamine ) 、cysteinamide等之毓基化合物、亞硫酸、亞硫酸鈉等之 -14- 201233399 亞硫酸鹽、亞硫酸氫鈉等之亞硫酸氫鹽 '抗壞血酸或其衍 生物等選擇1種以上成分。 接著，將於步驟S210選擇之非酸性之基劑（B)、還 原劑（D )之各劑分類爲由油溶性成分而成之油相、由水 溶性成分而成之水相、於高溫化不安定成分而成之添加劑 相進行秤量。另外，亦對於鹼劑（A )、酸性之基劑（C )之各劑，進行秤量（步驟S2 12 )。之後，分別加溫溶 解經秤量之油相成分及水相成分（步驟S2 14 )。加入調 節成一定溫度之水相於調節成一定溫度之油相，進行乳化 混合（步驟 S 2 1 6 )。另外，前述之所謂一定溫度係考慮 構成各劑之成分特性等而可任意決定。此事於後述亦同。 調節於步驟S2 16生成之乳化混合物成一定溫度後， 加入添加劑相之成分（步驟S2 1 8 )。之後，調節於步驟 S2 1 8所得之乳化混合物成一定溫度後，加入經秤量之鹼 劑（A )成分（步驟S220 )。另外，添加鹼劑（A )成分 係以低溫進行爲宜。於此階段，乳化溫合物整體成爲鹼性 。之後，調節於步驟S220所得之鹼性乳化混合物成一定 溫度後’加入經秤量之酸性之基劑（C )成分（步驟S 2 2 2 )。另外，添加酸性之基劑（C )成分係以低溫進行爲宜 。最後，收納步驟S222所得之乳化混合物於一定容器（ 步驟S224 )。另外，亦稱步驟S216爲第1步驟，步驟 S220爲第2步驟，步驟S222爲第3步驟。 如此地，本實施型態中第1劑300之製造步驟中，對 於乳化混合物，添加鹼劑（A )成分後，添加酸性之基劑 -15- 201233399 (c )成分。對乳化混合物，藉由如前述之順序添加成分 ，因爲保持鹼性狀態下，可添加鹼劑（a )成分，亦即碳 酸鹽，所以可抑制碳酸鹽與酸性狀態之乳化混合物接觸而 起泡。 圖6係表示毛髮用化妝料生成劑中第2劑400之製造 步驟之流程圖。首先，分類第2劑400之原料成分爲基劑 (E ) 、pH調整劑（F )、氧化劑（G )，分別選擇（步驟 S3 10 ) 〇 作爲基劑（E )成分，並無特別的限制。作爲基劑（E )成分，可依目的之毛髮用化妝料生成劑之用途及劑型等 ，選擇1種或其以上之成分組合。作爲基劑（E)成分， 可使用例如烴、酯、聚矽氧烷、高級醇、動植物油、界面 活性劑、植物萃取物、醇類、天然或合成高分子、香料、 精製水等。 作爲pH調整劑（F)成分，選擇可分解第1劑300所 含之碳酸鹽的酸。可選擇至少1種以上選自例如檸檬酸、 乙醇酸等之有機酸、磷酸、硫酸等之無機酸等的酸。另外 ’使用於降低毛髮明度用之染色之毛髮用化妝料時，pH 調整劑係以選擇使毛髮用化妝料（混合藥劑）於ρ Η 1 〇〜 9.0之範圍內之份量爲宜’以選擇使於ρΗ3〇〜7〇之範圍 內之份量尤佳。另一方面’使用於提高毛髮明度用之染色 或漂白、脫色之毛髮用化妝料時，ρΗ調整劑係以選擇使 毛髮用化妝料（混合藥劑）於ρΗ6〇〜9〇之範圍內之份 量爲宜，以選擇使於ρΗ7·0〜8.5之範圍內之份量尤佳。 -16- 201233399 另外，所謂「毛髮之漂白、脫色」係指進行毛髮中黑色素 脫色。另外，所謂「毛髮之染色」係指藉由氧化染料之氧 化而改變毛髮的色度及明度。另外，「毛髮之染色」時， 亦可進行毛髮之漂白、脫色的同時，藉由氧化染料之氧化 而改變毛髮的色度及明度。 作爲（G )酸化劑成分，可選擇例如過氧化氫、過氧 化氫或氧之產生劑之過氧化脲、過氧化三聚氰胺、過硼酸 鈉、過硼酸鉀、過碳酸鉀等。 接著，將於步驟S3 10選擇之基劑（E) 、pH調整劑 (F )、氧化劑（G )之各劑分類爲由油溶性成分而成之油 相、由水溶性成分而成之水相、於高溫化不安定成分而成 之添加劑相，進行秤量（步驟S3 12 )。之後，分別加溫 溶解經秤量之油相成分及水相成分（步驟S3 1 4 )。加入 調節成一定溫度之水相於調節成一定溫度之油相，進行乳 化混合（步驟S316)。調節於步驟S316生成之乳化混合 物成一定溫度後，加入添加劑相之成分（步驟S3 1 8 )。 最後，收納步驟S3 1 8所得之乳化混合物於一定容器（步 驟 S324 )。 B.實驗結果： 對於上述實施型態說明之毛髮用化妝料生成劑，對毛 髮用化妝料生成劑所含成分、及其含量進行各種變更，經 實施之各種實驗結果如下所示。 於後述之各種實驗，使用內容量爲5 5 0ml混合用容器 -17- 201233399 (圖1 )及混合用器具200 (圖1 )，將依據圖5說明之方 法製造之第1劑300之樣品及依據圖6說明之方法製造之 第2劑400之樣品，以混合比（重量比）1 : 1混合’對所 得之毛髮用化妝料（混合藥劑）進行評估。另外，混合係 依照圖2說明之毛髮用化妝料製造處理之步驟實施。 B-1·實驗結果1(關於毛髮用化妝料黏度之實驗結果）： 圖7係表示關於毛髮用化妝料黏度之實驗中使用之第 1劑3 00樣品之說明圖。圖8係表示關於毛髮用化妝料黏 度之實驗中使用之第2劑400樣品之說明圖。圖9係表示 關於毛髮用化妝料黏度之實驗結果之說明圖。另外，爲了 方便，圖中第1劑僅記爲「1劑」，第2劑僅記爲「2劑 」。另外，圖中樣品號碼係對應相同物（亦即，例如圖9 所示樣品# 1 0之評估結果係表示對於混合圖7之樣品# 1〇 之第1劑與圖8之樣品# 1 0之第2劑所得之毛髮用化妝料 之評估結果）。此等事情對於後續表示之其他實驗結果亦 相同。 此實驗中，首先準備藉由改變第1劑之碳酸鹽（碳酸 鉀及碳酸氫銨）之含量及增黏劑（羧乙烯聚合物）之含量 而改變毛髮用化妝料（混合藥劑）黏度之複數個樣品（樣 品# 1 0〜# 1 9 )。接著，對於樣品# 1 〇〜# 1 9，對於（1 一 1 )維持混合藥劑之泡沫、（1 一 2 )塗抹時液體滴落、 (1 一 3)放置時液體滴落、（1 一 4)塗抹時對毛髮之滲透 性之各項目，進行評估。另外，混合藥劑之黏度係使用於 -18- 201233399 20°C條件下，對混合藥劑進行消泡（以真空狀· 脫氣），使用B型旋轉黏度計之滾輪Νο·4，使J 轉1分鐘後之値。評估方法及評估基準如後所示 (1 _ 1 )維持混合藥劑之泡沫係對於混合第 及第2劑樣品時之狀況，以目視確認而進行評伯 在此所謂「消泡」係指藉由碳酸鹽與酸反應而曹 泡沫顯示減少的趨勢。另外，攪拌次數係使用捐 (圖1)，繞混合用容器（圖1)之內周一圈頃 「1次」。 維持混合藥劑泡沫之評估基準 Α:即使攪拌100次以上，仍未消泡 Β:即使攪拌50次以上，仍未消泡 C :攪拌至50次，開始消泡 D :未起泡，或攪拌立即開始消泡 (1_2)塗抹時液體滴落係由20名評估員 150g於25t條件下混合藥劑之泡沬於毛髮整 滴落，進行評估。 塗抹時液體滴落之評估基準 A:塗抹於頭時，完全無液體滴落 B:塗抹於頭時，幾乎無液體滴落 C:塗抹於頭時，僅些微液體滴落 D :塗抹於頭時，相當多液體滴落 下將泡沫 .6rpm 旋 〇 1劑樣品 。另外， 時生成的 合用器具 ，計數爲 ，對塗抹 時之液體 -19- 201233399 (1 - 3 )放置時之液體滴落係對3 5 t條件下塗抹 1 5 0g之混合藥劑之泡沬於染髮用試驗人偶之毛髮整體後放 置者，進行評估。 放置時液體滴落之評估基準 A:完全無液體滴落 B:放置30分鐘以內，無液體滴落 C:放置30分鐘以內，僅些微液體滴落 D:放置30分鐘以內，相當多液體滴落 (1 - 4 )對毛髮之滲透性係由20名評估員，對塗抹 於25 °C條件下.混合藥劑之泡沫於染髮用試驗人偶之毛髮整 體時對毛髮之滲透狀況，進行評估。另外，在此，所謂「 對毛髮之滲透性」係指混合藥劑迅速滲透於毛髮間。 對毛髮之滲透性之評估基準 A :對毛髮之滲透性優異 B:對毛髮之滲透性良好 C:對毛髮之滲透性差 D:對毛髮幾乎無滲透性 於此評估試驗之結果，混合藥劑之黏度於1500mPa· s〜30000mPa.s之範圍內之樣品#10〜#13係全部評估 項目得到評估A。亦即，樣品# 1 〇〜# 1 3係即使攪拌混合 藥劑的泡沬100次以上，仍不消泡（亦即沫泡持久）’塗 抹時及放置時完全不發生液體滴落，對毛髮之滲透性亦優 -20- 201233399 異，》另外，混合藥劑之黏度爲75400mPa· s之樣品#15 及混合藥劑之黏度爲82600mPa· s之樣品#18’雖然攪拌 混合藥劑的泡沫至5 0次即消泡’對毛髮之滲透性差’但 塗抹時及放置時完全不發生液體滴落。 另一方面，混合藥劑之黏度爲7 5 0 mP a . s之樣品# 1 4 及混合藥劑之黏度爲1200mPa.s之樣品#17，攪拌混合 藥劑的泡沫至50次即消泡’塗抹時及放置時發生相當多 液體滴落。混合藥劑之黏度爲1 0萬mPa · S以上之樣品# 16、#19，混合藥劑之泡沫無法起泡，並且對毛髮亦完全 沒有滲透性（換言之，對毛髮之滲透性差，缺乏使用性） 〇 由此評估試驗結果，可知毛髮用化妝料（混合藥劑） 中之增黏劑含量係使毛髮用化妝料之黏度於15 OOmPa · s 〜83000mPa· s之範圍內之份量爲宜。毛髮用化妝料之黏 度若於前述範圍內時，因爲可藉由適當的黏度抑制藉由混 合第1劑及第2劑（亦即碳酸鹽與酸的混合）所產生之二 氧化碳而成的泡沬消泡，所以可簡易取得無氣溶膠型之具 有使用時可抑制滴落之黏度之泡沫狀毛髮用化妝料。 由此評估試驗結果’進一步可知毛髮用化妝料（混合 藥劑）之增黏劑含量係使毛髮用化妝料之黏度於1 500mPa • s〜30000mPa· s之範圍內之份量尤佳。毛髮用化妝料 之黏度若於前述範圍內時，將可得到因適當的黏度而毛髮 用化妝料的泡沫持久’而且塗抹時之手指疏通性更佳，使 用性良好的毛髮用化妝料。 -21 - 201233399 B — 2 .實驗結果2 (關於增黏劑種類之實驗結果1 ): 圖1〇係表示關於增黏劑種類之實驗中使用之第 3〇〇樣品之說明圖。圖11係表示關於增黏劑種類之實 使用之第2劑400樣品之說明圖。圖12係表示關於 劑種類之實驗結果之說明圖。 此實驗中，首先準備改變第1劑所含之增黏劑種 羧乙烯聚合物、丙烯酸·甲基丙烯酸烷基酯共聚物、 基纖維素鈉、黃原膠）及其含量之複數個樣品（樣品 〜#24)。接著，對於樣品#20〜#24，求出混合藥 黏度，並同時對於（2— 1)維持混合藥劑之泡沫、（ )第1劑生成時增黏劑之分散性之各項目，進行評估 外，混合藥劑黏度之測定方法係與B — 1 .實驗結果1 說明相同。 對於（2 — 1)維持混合藥劑之泡沫之評估方法及 基準係與B—1.實驗結果1之（1_1)相同》 (2 — 2 )第1劑生成時增黏劑之分散性係於第1 造步驟中加入增黏劑混合之步驟，對於增黏劑是否容 製劑中分散，以目測確認而進行評估。 第1劑生成時增黏劑之分散性之評估基準 A :增黏劑可以容易地分散於製劑 B :增黏劑可以分散於製劑 C :增黏劑可以分散於製劑，但形成小粒 1劑 驗中 增黏 類（ 羧甲 #20 劑之 2-2 。另 中之 評估 劑製 易於 -22- 201233399 D :增黏劑幾乎不能分散於製劑 此評估試驗的結果中，混合藥劑泡沫之持久 樣品得到評估A (即使攪拌1 〇 〇次以上，仍不消 外’使用締合型增黏劑之樣品#20〜#22，加入 合時，增黏劑容易地分散於製劑中。另一方面， 合型增黏劑之增黏劑之樣品# 2 3係加入增黏劑混 劑中因增黏劑而發生小粒。同樣地，使用非締合 之增黏劑之樣品# 2 4係加入增黏劑混合時，增黏 於製劑整體。 由此評估結果，可知毛髮用化妝料生成劑所 係使用締合型增黏劑（成爲特定pH範圍時才發 果之增黏劑）爲宜。若使用締合型增黏劑時，於: 製造步驟中加入增黏劑混合之步驟，可得到對製 分散性。 B - 3.實驗結果3 (關於增黏劑種類之其他實驗結: 圖13係表示關於增黏劑種類之其他實驗中使 劑3 00樣品之說明圖。圖1 4係表示關於增黏劑 他實驗中使用之第2劑400樣品之說明圖《圖1 關於增黏劑種類之其他實驗結果之說明圖。 此實驗係準備藉由改變第1劑之氫氧化鉀含 劑之磷酸含量而改變第1劑及第2劑之p Η，進 混作爲增黏劑之羧乙烯聚合物或羧甲基纖維素鈉 複數個樣品（樣品# 3 0〜# 3 3 )。接著，對於樣 力係全部 泡）。另 增黏劑混 使用非締 合時，製 型增黏劑 劑未分散 含增黏劑 揮增黏效 舊1劑之 劑良好的 果）： 用之第1 種類之其 5係表示 XL λ 里及第2 而改變摻 之用劑之 品# 3 0〜 -23- 201233399 # 3 3，求出第1劑之黏度、第2劑之黏度、混合藥劑之黏 度、及混合藥劑之pH，並同時對於（3 _ 1 )維持混合藥 劑之泡沫'(3 — 2 )含增黏劑之用劑（第1劑、第2劑） 生成時增黏劑之分散性之各項目，進行評估。另外，混合 藥劑黏度之測定方法係與B - 1 ·實驗結果1中之說明相同 。另外，第1劑及第2劑之黏度係於20°C之條件下，使用 B型旋轉黏度計之滾輪No.4，使以6rpm旋轉1分鐘後之 値。 對於（3 - 1 )維持混合藥劑之泡沬之評估方法及評估 基準係與B _ 1 ·實驗結果1之（1 — 1 )相同。 對於（3 - 2 )含增黏.劑之用劑（第1劑、第2劑）生 成時增黏劑之分散性之評估方法及評估基準係與B - 2.實 驗結果2之（2 — 2 )相同。 此評估試驗結果，第1劑所含氫氧化鉀之份量相同之 樣品#30、#'32中，使用締合型增黏劑（羧乙烯聚合物） 之樣品# 30比使用非締合型增黏劑（羧甲基纖維素鈉）之 樣品# 3 0，第1劑之黏度低，而且可減少增黏劑含量。另 外，第2劑所含磷酸之份量相同之樣品# 3 1、# 3 3中，使 用締合型增黏劑（羧乙烯聚合物）之樣品#31比使用非締 合型增黏劑（羧甲基纖維素鈉）之樣品# 3 3，第2劑之黏 度低，而且可減少增黏劑含量。 進而，使用締合型增黏劑（羧乙烯聚合物）之樣品# 3 〇、# 3 1，於含增黏劑之用劑（第1劑、第2劑）之製造 步驟中加入增黏劑混合之步驟，增黏劑對製劑容易分散。 -24- 201233399 另一方面’使用非締合型增黏劑之樣品#32、#33，增黏 劑未分散於製劑中。 由此評估試驗之結果，可知毛髮用化妝料生成劑（混 合藥劑）所含增黏劑係使用締合型增黏劑（成爲特定pH 範圍時才發揮增黏效果之增黏劑）爲宜。若使用締合型增 黏劑時’壓低增黏劑之含量成低配合量，可製造維持摻混 增黏劑之用劑或其他用劑黏度低之毛髮用化妝料生成劑， 而旦’混合複數個用劑（第1劑、第2劑）時，藉由碳酸 鹽與酸反應而引起之中和反應，毛髮用化妝料（混合藥劑 )成爲適於增黏之pH範圍，可發揮增黏效果。另外，可 使含增黏劑之用劑（第1劑 '第2劑）生成時增黏劑之分 散性提高。另外，由前述評估試驗之結果，可知締合型增 黏劑係可摻混於第1劑、第2劑中任一種。 B — 4.實驗結果4 (關於碳酸鹽種類之實驗結果）： 圖16係表示關於碳酸鹽種類之實驗中使用之第1劑 3〇〇樣品之說明圖。圖17係表示關於碳酸鹽種類之實驗中 使用之第2劑400樣品之說明圖。圖1 8係表示關於碳酸 鹽種類之實驗結果之說明圖。 此實驗係準備改變第1劑之碳酸鹽種類（碳酸鉀、碳 酸氫銨、碳酸鈉、碳酸氫鈉、碳酸氫鉀、碳酸鈣、碳酸鋇 、碳酸丙烯酯、碳酸乙烯酯）及其含量之複數個樣品（樣 品# 40〜# 50 )。接著，對於樣品# 40〜# 50，對於（4 -1)混合時之起泡性，進行評估。進而，對於樣品# 40 -25- 201233399 〜#50所使用之各種碳酸鹽，另外評估（4— 2)碳酸鹽之 溶解性。 (4 一 1 )混合時之起泡性係對於第1劑樣品及第2劑 樣品混合時之起泡狀況，以目測確認，進行評估。 混合時起泡性之評估基準 A:顯示優異的起泡性 B :顯示良好的起泡性 C :顯示弱起泡性 D:幾乎未顯示起泡性 (4 - 2)碳酸鹽之溶解性係對於放入碳酸鹽於水中， 攪拌時之溶解性，以目測確認，進行評估。 碳酸鹽溶解性之評估基準 A :顯示對水溶解性優異 B :顯示對水溶解性良好 C :顯示對水溶解性弱 D :顯示對水幾乎無溶解性 此評估試驗結果，作爲碳酸鹽，含碳酸氫銨之樣品# 40及43、含碳酸鉀及碳酸氫銨之樣品#41、含碳酸鉀之 樣品# 42、含碳酸鈉之樣品# 44、含碳酸氫鈉之樣品# 4 5 、含碳酸氫鉀之樣品# 46、含碳酸鈣之樣品# 47、及含碳 酸鋇之樣品# 48於混合第1劑及第2劑時，顯示優異的起 泡性。另一方面，含作爲碳酸鹽之碳酸丙烯酯之樣品# 49 -26- 201233399 、含作爲碳酸鹽之碳酸乙烯酯之樣品#50於混合第1劑及 第2劑時，幾乎未起泡。 另外，樣品# 40〜# 46所使用之碳酸鹽（碳酸鉀、碳 酸氫銨、碳酸鈉、碳酸氫鈉、碳酸氫鉀）係顯示對水溶解 性優異。另一方面，樣品# 5 0所使用之碳酸鹽（碳酸乙烯 酯）係顯示對水溶解性弱。樣品# 4 7所使用之碳酸鹽（碳 酸鈣）、樣品# 48所使用之碳酸鹽（碳酸鋇）與樣品# 49 所使用之碳酸鹽（碳酸丙烯酯）係顯示對水幾乎無溶解性 〇 由此評估試驗之結果，可知第1劑所含碳酸鹽係含有 至少一種選自碳酸根離.子之鹼金屬鹽或鹼土金屬鹽、碳酸 氫根離子之鹼金屬鹽或鹼土金屬鹽、碳酸銨、碳酸氫鞍所 成群之碳酸鹽爲宜。如此一來，因爲可提供對水溶解性、 與酸反應性良好之第1劑，所以可以更加提高作爲毛髮用 化妝料生成劑之複數用劑混合時之起泡性。 B- 5.實驗結果5 (關於提高毛髮明度用之染色或漂白、脫 色所使用之毛髮用化妝料之pH之實驗結果）： 圖19係表不關於提尚毛髮明度用之染色或漂白、脫 色所使用之毛髮用化妝料之PH之實驗中使用之第丨劑 3 0 0樣品之說明圖。圖2 0係表示關於提高毛髮明度用之染 色或漂白、脫色所使用之毛髮用化妝料之pH之實驗中使 用之第2劑400樣品之說明圖。圖21係表示關於提高毛 髮明度用之染色或漂白、脫色所使用之毛髮用化妝料之 -27- 201233399 pH之實驗結果之說明圖。 此實驗係首先準備藉由改變第1劑之氨水含量、第2 劑之磷酸含量而改變毛髮用化妝料（混合藥劑）之pH之 複數個樣品（樣品# 60〜# 64 )。接著，對於樣品# 60〜 #64，對於（5-1)明度、（5 — 2)混合時之起泡性之各 項目，進行評估。另外，本實驗中之各樣品係任一種皆生 成提高毛髮明度用之染色或漂白、脫色所使用（亦即使暗 的髮色變明亮用）之毛髮用化妝料。 (5 - 1 )明度係由2 0名評估員之實際染髮進行評估 。具體上，對塗抹150g於25 °C之條件下混合藥劑之泡沫 於毛髮整體之狀態，放置20分鐘，.沖洗掉混合藥劑後， 乾燥後毛髮之明度，以目測確認，進行評估。 明度之評估基準 A:顯示優異的明度 B :顯示良好的明度 C :顯示微弱的明度 D:幾乎未顯示明度 關於（5 - 2 )混合時起泡性之評估方法及評估基準係 與B— 4.實驗結果4之（4 — 1 )相同。 此評估試驗的結果，混合藥劑爲pH6.0之樣品# 60、 pH7_5之樣品# 61顯示良好的明度，並且混合第1劑及第 2劑時顯示優異的起泡性。另外，混合藥劑爲p Η 9.0之樣 品# 62顯示優異的明度，並且混合第1劑及第2劑時顯示 -28- 201233399 良好的起泡性。另一方面，混合藥劑爲pH5.0之樣品# 63 ，幾乎未顯示明度。混合藥劑爲pH 10.0之樣品# 64，即 使混合第1劑及第2劑，幾乎未起泡。 由此評估試驗之結果，提高毛髮明度用之染色或漂白 、脫色所使用之毛髮用化妝料，可知毛髮用化妝料（混合 藥劑）係於PH6.0〜9.0之範圍內爲宜。如此一來，對於 毛髮用化妝料，可得到高染髮力及脫色力，以及適當的黏 度。並且可使毛髮用化妝料生成劑所含之碳酸鹽與酸有效 率地進行反應。適當的黏度以及碳酸鹽與酸反應效率佳之 結果，可得到細緻有黏性之乳霜狀毛髮用化妝料之泡沫， 可得到抑制使用時（塗抹時.、放置時）液體滴落之效果， 或抑制染色不均之效果。 B - 6.實驗結果6(關於提高毛髮明度用之染色或漂白、脫 色所使用之毛髮用化妝料中碳酸鹽所占含量之實驗結果） 圖22係表示關於提高毛髮明度用之染色或漂白、脫 色所使用之毛髮用化妝料中碳酸鹽所占含量之實驗結果之 說明圖。 此實驗係準備對B- 5.實驗結果5之樣品#61，改變 作爲碳酸鹽之碳酸鉀及碳酸氫銨之含量合計1.0質量％〜 4 0.0質量％之複數個樣品（樣品# 610〜615 )。接著，對 於樣品# 6 1 0〜# 6 1 5，對於（6 — 1 )混合時之起泡性、（ 6 ~ 2 )自容器湧出、（6 _ 3 )使用感之各項目，進行評估 -29- 201233399 關於（6 - 1 )混合時起泡性之評估方法及評估基準係 與B - 4.實驗結果4之（4 — 1 )相同。 (6 — 2 )自容器湧出係對於混合第1劑樣品與第2劑 樣品時有無自混合用容器湧出泡沫，以目測確認，進行評 估。 自容器湧出之評估基準 A :不論如何混合，幾乎不湧出 B :混合時需小心，但不湧出 C :雖小心地混合，但有些微湧出 D :即使小心地混合，但湧出激烈 (6 - 3 )使用感係由20名評估員，對塗抹於25°C條 件下混合藥劑之泡沫於染髮用試驗人偶之毛髮整體時之塗 抹容易度，進行評估。 使用感之評估基準 A:非常容易展開，容易塗抹 B :展開普通，但塗抹沒問題 C :難以塗抹 此評估試驗的結果，碳酸鹽含量爲1〇.〇質量％之樣品 #612係混合第1劑與第2劑時顯示良好的起泡性，並且 雖然混合時需要注意，但未見有泡沫自混合用容器湧出。 另外，樣品# 6 1 2係塗抹於毛髮時非常容易展開，容易塗 -30- 201233399 抹。碳酸鹽含量爲2 0.0質量％之樣品# ό 1 3係混合第丨劑 與第2劑時顯示良好的起泡性，並且即使混合時小心注意 ，但仍見有些微泡沫自混合用容器湧出。另外，樣品# 613係塗抹於毛髮時非常容易展開’容易塗抹。碳酸鹽含 量爲30.0質量％之樣品# 614係混合第1劑與第2劑時顯 示優異的起泡性，並且即使混合時小心注意，但仍見有些 微泡沬自混合用容器湧出。另外，樣品#614係塗抹於毛 髮時無展開的問題，可以塗抹的程度。 另一方面，碳酸鹽含量爲1 .〇質量％之樣品# 6 1 0係 即使混合第1劑與第2劑時幾乎不起泡。碳酸鹽含量爲 5.0質量％之樣品# 6 1 1係即使混合第1劑與第2劑，雖只 顯示弱起泡性，但未見自混合用容器湧出泡沬。另外，樣 品#610係塗抹於毛髮時之展開良好。碳酸鹽含量爲40.0 質量％之樣品# 6 1 5係混合第1劑與第2劑時即使小心注 意’但仍自混合用容器激烈湧出泡沫，塗抹於毛髮時之展 開亦差。 由此評估試驗的結果，可知提高毛髮明度用之染色或 漂白、脫色所使用之毛髮用化妝料時，毛髮用化妝料（混 合藥劑）中碳酸鹽所占含量係以1 . 〇質量％〜3 0.0質量％ 爲宜，以10.0質量％〜20.0質量％尤佳。毛髮用化妝料中 碳酸鹽所占含量若於前述範圍內時，混合作爲毛髮用化妝 料生成劑之複數個用劑時，可得到適當的自我起泡效果。 Β - 7.實驗結果7 (關於降低毛髮明度用之染色所使用之毛 -31 - 201233399 髮用化妝料之pH之實驗結果）： 圖23係表示關於降低毛髮明度用之染色所使用 髮用化妝料之pH之實驗中使用之第1劑3 00樣品之 圖。圖24係表示關於降低毛髮明度用之染色所使用 髮用化'妝料之pH之實驗中使用之第2劑400樣品之 圖。圖25係表示關於降低毛髮明度用之染色所使用 髮用化妝料之pH之實驗結果之說明圖。 此實驗係首先準備藉由改變第1劑之氨水含量及 劑之磷酸含量，而改變毛髮用化妝料（混合藥劑）之 之樣品（樣品# 70〜# 75 )。接著，對於樣品# 70〜 ，對於（7— 1)混合時之起泡性、（7 - 2)對頭皮之 之各項目進行評估。另外，於本實驗中各樣品係任一 生成降低毛髮明度用之染色所使用（亦即，使明亮髮 暗用）之毛髮用化妝料。 關於（7 - 1 )混合時起泡性之評估方法及評估基 與B — 4.實驗結果4之（4— 1)相同。 (7 — 2 )對頭皮之刺激係由20名評估員，對於 150g於25°C條件下混合藥劑之泡沫於毛髮整體時對 有無刺激（疼痛、癢），進行評估。 對頭皮刺激之評估基準 A :頭皮完全不感到刺激 B :頭皮幾乎不感到刺激 C :頭皮感到刺激 之毛 說明 之毛 說明 之毛 第2 :pH #75 刺激 種皆 色變 準係 塗沫 頭皮 -32- 201233399 D :頭皮感到非常刺激 此評估試驗的結果，混合藥劑爲pH3.2 5之樣品# 7 1 、pH6.80之樣品# 72係混合第1劑及第2劑時顯示優異 的起泡性’並且塗抹混合藥劑於頭皮時，亦對頭皮完全無 刺激。另外’混合藥劑爲pH 1 · 0之樣品# 70雖然混合第1 劑及第2劑時顯示優異的起泡性，但塗抹混合藥劑於頭皮 時’對頭皮刺激。混合藥劑爲pH 8.80之樣品# 73係混合 第1劑及第2劑時顯示良好的起泡性，塗抹混合藥劑於頭 皮時，亦對頭皮完全無剌激。 另一方面’混合藥劑爲pHO.57之樣品#74係塗抹混 合藥劑於頭皮時，對頭皮的刺激強烈。另外，混合藥劑爲 p Η 9 · 3 0之樣品# 7 5係混合第1劑及第2劑時幾乎不起泡 〇 由此評估試驗之結果，可知降低毛髮明度用之染色所 使用之毛髮用化妝料’毛髮用化妝料（混合藥劑）係於 pHl.O〜9·0之範圍內爲宜，以ρΗ3·0〜7.0之範圍內尤佳 。如此一來，毛髮用化妝料可得到高染髮力及適當的黏度 。另外’將可使毛髮用化妝料生成劑所含之碳酸鹽與酸有 效率地進行反應。適當的黏度以及碳酸鹽與酸反應效率佳 之結果’可得到細緻有黏性之乳霜狀毛髮用化妝料之泡沫 ，可得到抑制使用時（塗抹時、放置時）液體滴落之效果 或抑制染色不均之效果。 Β — 8.實驗結果8 (關於降低毛髮明度用之染色所使用之毛 -33- 201233399 髮用化妝料中碳酸鹽所占含量之實驗結果）： 圖26係表示關於降低毛髮明度用之染色所使用之毛 髮用化妝料中碳酸鹽所占含量之實驗結果之說明圖。 此實驗係準備對B- 7.實驗結果7之樣品#71，改變 作爲碳酸鹽之碳酸氫敍之含量1.0質量％〜1〇.〇質量％之 複數個樣品（樣品# 7 1 0〜# 7 1 5 )»接著，對於樣品# 7 1 0 〜#715，對於（7-1)混合時之起泡性、（7—2)自容 器湧出、（7 — 3)使用感之各項目，進行評估。 關於（7- 1)混合時起泡性之評估方法及評估基準係 與B - 4.實驗結果4之（4_ 1 )相同。 關於（7- 2)自容器湧出之評估方法及評估基準係與 B — 6.實驗結果6之（6_2)相同。 關於（7 - 3)使用感之評估方法及評估基準係與B — 6.實驗結果6之（6 — 3)相同。 此評估試驗的結果，碳酸鹽含量爲1 · 5質量％之樣品 # 71 1及2.0質量％之樣品# 712係混合第1劑與第2劑時 顯示良好的起泡性’並且雖然混合時需要注意，但未見有 泡沫自混合用容器湧出。另外，樣品# 7 1 1、# 7 1 2係塗抹 於毛髮時非常容易展開，容易塗抹。碳酸鹽含量爲3.0質 量°/❶之樣品# 7 1 3係混合第1劑與第2劑時顯示良好的起 泡性’但即使混合時小心注意’仍見有些微泡沬自混合用 容器湧出。另外，樣品# 7 1 3係塗抹於毛髮時非常容易展 開，容易塗抹。 另一方面’碳酸鹽含量爲1.0質量％之樣品# 710係 -34- 201233399 即使混合第1劑與第2劑時，雖只顯示弱起泡性，但未見 有泡沬自混合用容器湧出，塗抹於毛髮時展開佳。碳酸鹽 含量爲5.0質量％之樣品# 714及10.0質量％之樣品# 715 係即使小心地混合第1劑與第2劑，但仍自混合用容器激 烈地湧出泡沬。 由此評估試驗之結果，可知降低毛髮明度用之染色所 使用之毛髮用化妝料，毛髮用化妝料（混合藥劑）中碳酸 鹽所占含量係於1.5〜10.0質量％之範圍內尤佳。毛髮用 化妝料中碳酸鹽所占含量若於前述範圍內時，混合作爲毛 髮用化妝料生成劑之複數用劑時，可得到適當的自我起泡 效果。 B — 9.實驗結果9(關於高級醇之實驗結果）： 圖27係表示關於高級醇之實驗中使用之第1劑300 樣品之說明圖。圖2 8係表示關於高級醇之實驗中使用之 第2劑400樣品之說明圖。圖29係表示關於高級醇之實 驗結果之說明圖。 此實驗係準備改變第1劑所含醇類種類（肉豆蔻醇、 十六烷醇、硬脂醇、二十二烷醇、辛醇、月桂醇、二十四 烷醇、三十烷醇、辛醯醇（Caprylyl alcohol)、三十二烷 醇）及其含量之複數個樣品（樣品# 80〜# 89 )。接著， 對於樣品# 80〜# 89，對於（9 — 1 )維持混合藥劑之泡沫 、（9 一 2)塗抹時液體滴落、（9— 3)放置時液體滴落、 (9 - 4 )明度、（9 一 5 )染色性之各項目，進行評估。 -35- 201233399 關於（9 - 1)維持混合藥劑之泡沫之評估方法及評估 基準係與B — 1 .實驗結果1之（1 一 1 )相同。 關於（9 - 2)塗抹時液體滴落之評估方法及評估基準 係與B _ 1 ·實驗結果1之（1 一 2 )相同。 關於（9 - 3)放置時液體滴落之評估方法及評估基準 係與B _ 1 .實驗結果1之（1 一 3 )相同。 關於（9 - 4)明度之評估方法及評估基準係與b一 5. 實驗結果5之（5 — 1 )相同。 關於（9 - 5)染色性係由20名評估員以實際染髮進 行評估。具體上，塗抹1 5 0 g於2 5 °C之條件下混合藥劑之 泡沫於毛髮整體之狀態，放置20分鐘，沖洗掉混合藥劑 後，對於乾燥後毛髮之染色性，以目測確認，進行評估》 染色性之評估基準 A:顯示優異的染色性 B :顯示良好的染色性 C:顯示微弱的染色性 D:幾乎未顯示染色性 此評估試驗的結果，含肉豆蔻醇之樣品#80、含十六 烷醇之樣品# 8 1、含硬脂醇之樣品# 82於全部的評估項目 得到評估A »亦即，樣品# 8 0〜8 2係即使攪拌混合藥劑的 泡沫100次以上，仍不消泡（亦即沬泡持久），塗抹時及 放置時亦不發生液體滴落，顯示優異的明度及優異的染色 性。含二十二烷醇之樣品# 83，即使攪拌混合藥劑的泡沫 -36- 201233399 100次以上仍不消泡，塗抹時及放置時亦不發 ，顯示良好的明度及優異的染色性。 含月桂醇之樣品#85及含二十四烷醇之I 全部的評估項目得到評估B。亦即，樣品# 8 5 使攪拌混合藥劑的泡沫5 0次程度，仍不消泡 大致未見有液體滴落，放置30分鐘之內亦未 落。另外，顯示良好的明度及良好的染色性。 品# 8 4及含三十烷醇之樣品# 8 7係即使攪拌 泡沬50次程度，仍不消泡，塗抹時亦大致未 落，放置30分鐘之內亦未見有液體滴落，但 的明度及微弱的染色性。 含辛醯醇之樣品#88及含三十二烷醇之| 攪拌混合藥劑的泡沫至50次即消泡，塗抹時 生液體滴落，並且幾乎未顯示明度，對於染色 由此評估試驗結果，可知作爲毛髮用化妝 複數用劑中至少任一種用劑係含有碳數爲10-烷基或碳數爲10〜30之烯基之高級醇爲宜。 可賦予毛髮用化妝料硬度，可以抑制藉由混合 而產生的二氧化碳所成的泡沫消泡，使毛髮用 沬持久。另外’藉由含高級醇，因爲可使毛髮 泡沫細緻’可得到抑制使用時（塗抹時、放置 落之效果，或抑制染色不均之效果。 C.變形例： 生液體滴落 I品# 86於 、# 86係即 ，塗抹時亦 見有液體滴 含辛醇之樣 混合藥劑的 見有液體滴 僅顯示微弱 I品# 8 9係 及放置時發 性亦弱。 料生成劑之 -3 0之直鏈 因爲高級醇 碳酸鹽及酸 化妝料之泡 用化妝料之 時）液體滴 -37- 201233399 另外’此發明並非局限於前述實施例或實施型態，於 不超出該要旨之範圍，可採取各種組成。例如可如下變形 C1.變形例1 ·‘ 於前述實施型態及實驗例，毛髮用化妝料生成劑係由 2劑（第1劑、第2劑）所組成者，並對摻混於各劑之成 分舉一例說明。然而，毛髮用化妝料生成劑係包含至少含 有碳酸鹽之第1劑、及含有可分解碳酸鹽的酸之第2劑即 足夠，並不限定於前述舉例的型態。具體上，可任意改變 毛髮用化妝料生成劑所含成分、及其含量。 例如於前述實施型態，記載於第1劑中含增黏劑者， 但增黏劑係包含於構成毛髮用化妝料生成劑之複數用劑中 至少任1個用劑即足夠。具體上，毛髮用化妝料生成劑係 由3劑所組成時，亦可於第3劑中摻混增黏劑，毛髮用化 妝料生成劑係由2劑所組成時，亦可於第2劑中摻混增黏 劑。進而，亦可爲全部複數用劑摻混增黏劑之型態。 例如於前述實施型態，記載於第1劑中含高級醇者， 但高級醇係包含於構成毛髮用化妝料生成劑之複數用劑中 至少任1個用劑即足夠。具體上，毛髮用化妝料生成劑係 由3劑所組成時，亦可於第3劑中摻混高級醇，毛髮用化 妝料生成劑係由2劑所組成時，亦可於第2劑中摻混高級 醇。進而，亦可爲全部複數用劑摻混高級醇之型態。 -38- 201233399 C2.變形例2 : 於前述實施型態（圖1 )係表示毛髮用化妝料組組成 之一例。然而’毛髮用化妝料組組成係可有各種變形。例 如可改變混合用容器、或混合用器具之形狀、材質等。例 如亦可使用混合用容器與混合用器具一體成型之容器等。 C3.變形例3 : 於前述實施型態（圖2 )係表示使用毛髮用化妝料組 之毛髮用化妝料製造處理流程之一例。然而，毛髮用化妝 料製造處理流程係可有各種變形。 C 4 .變形例4 : 於前述實施型態（圖5、圖6 )係對於第1劑及第2 劑之製造步驟進行說明。然而，此製造步驟僅爲一例，可 有各種變形。例如可以省略部份第1劑製造步驟中之步驟 ，或改變步驟排列順序。但是，就抑制碳酸鹽起泡之觀點 上，添加（A )鹼劑成分之步驟（步驟S220 )與添加（B )酸性之基劑成分之步驟（步驟S222 )之順序以不改變 爲宜。 C5.變形例5 ’· 於前述實施型態，以塗抹於毛髮’改變毛髮明度用之 毛髮用化妝料爲例，進行說明。然而’本發明亦可採取其 他型態而不局限於前述型態。具體上’亦可作爲構成例如 -39- 201233399 塗抹於體毛，用以改變體毛明度之泡沫狀化妝料用之生成 劑。 【圖式簡單說明】 [圖1]槪略地表示本發明之實施型態中毛髮用化妝料 組之組成之說明圖。 [圖2]表示使用毛髮用化妝料組之毛髮用化妝料生成 處理流程之流程圖。 [圖3]表示使用毛髮用化妝料組之毛髮用化妝料生成 處理槪要之說明圖。 [圖4]表示使用毛髮用化妝料組之毛髮用化妝料生成 處理槪要之說明圖。 [圖5]表示毛髮用化妝料生成劑中第1劑之製造步驟 之流程圖。 [圖6]表示毛髮用化妝料生成劑中第2劑之製造步驟 之流程圖。 [圖7]表示關於毛髮用化妝料黏度之實驗中使用之第1 劑樣品之說明圖。 [圖8]表示關於毛髮用化妝料黏度之實驗中使用之第2 劑樣品之說明圖。 [圖9]表示關於毛髮用化妝料黏度之實驗結果之說明 圖。 [圖10]表示關於增黏劑種類之實驗中使用之第1劑樣 品之說明圖。 -40- 201233399 [圖11]表示關於增黏劑種類之實驗中使用之第2劑樣 品β說明圖。 [圖12]表示關於增黏劑種類之實驗結果之說明圖。 [圖13]表示關於增黏劑種類之其他實驗中使用之第i 劑樣品之說明圖。 [圖14]表示關於增黏劑種類之其他實驗.中使用之第2 劑樣品之說明圖。 [圖15]表示關於增黏劑種類之其他實驗結果之說明圖 〇 [圖16]表示關於碳酸鹽種類之實驗中使用之第丨劑樣 品之說明圖。 [圖17]表示關於碳酸鹽種類之實驗中使用之第2劑樣 品之說明圖。 [圖18]表示關於碳酸鹽種類之實驗結果之說明圖。 [圖19]表示關於提高毛髮明度用之染色或漂白、脫色 所使用之毛髮用化妝料之pH之實驗中使用之第1劑樣品 之說明圖。 [圖20]表示關於提高毛髮明度用之染色或漂白、脫色 所使用之毛髮用化妝料之pH之實驗中使用之第2劑樣品 之說明圖。 [圖21]表示關於提高毛髮明度用之染色或漂白、脫色 所使用之毛髮用化妝料之PH之實驗結果之說明圖。 [圖22]表示關於提高毛髮明度用之染色或漂白、脫色 所使用之毛髮用化妝料中碳酸鹽所占含量之實驗結果之說 -41 - 201233399 明圖。 [圖23]表示關於降低毛髮明度用之染色所使用之毛髮 用化妝料之PH之實驗中使用之第1劑樣品之說明圖。 [圖24]表示關於降低毛髮明度用之染色所使用之毛髮 用化妝料之PH之實驗中使用之第2劑樣品之說明圖。 [圖25]表示關於降低毛髮明度用之染色所使用之毛髮 用化妝料之pH之實驗結果之說明圖。 [圖26]表示關於降低毛髮明度用之染色所使用之毛髮 用化妝料中碳酸鹽所占含量之實驗結果之說明圖。 [圖27]表示關於高級醇之實驗中使用之第1劑樣品之 說明圖。 [圖28]表示關於高級醇之實驗中使用之第2劑樣品之 說明圖。 [圖29]表示關於高級醇之實驗結果之說明圖。 【主要元件符號說明】 1 〇 :毛髮用化妝料組 100 :混合用容器 200 :混合用器具 300 :第1劑 400 :第 2 齊！1 -42-201233399 VI. Description of the Invention: [Technical Field] The present invention relates to a hair cosmetic preparation for hair, and more particularly to a hair made of a multi-agent for a foam-like hair cosmetic which is self-foaming when mixed with each other. A cosmetic preparation agent and a method for producing the same. [Prior Art] Conventionally, a hair cosmetic, a liquid or a paste, which is used as a hair bleaching agent or a hair dye, is popular. However, the present invention has been increasingly popular for foam-like hair cosmetics which can be easily applied in comparison with cosmetics for liquid or creamy hair and which have the advantage of not being uneven when applied. As a cosmetic for foamy hair, for example, a cosmetic for an aerosol type hair (for example, Patent Document 1) and a cosmetic for hair without an aerosol type (for example, Patent Document 2) are known. The cosmetic for aerosol type hair uses a propellant to foam the hair cosmetic product. Therefore, a special container is required, and there is a problem that the pressure vessel is corroded or the internal pressure rises, and the container is difficult to be discarded after use. In addition, in the case of a non-aerosol-type hair cosmetic, it is easy to obtain a foam-like hair cosmetic ‘, so that the viscosity of the mixed cosmetic of the hair cosmetic is lowered, and there is a problem that it is likely to drip when used. [Prior Art Document] [Patent Document 1] Japanese Laid-Open Patent Publication No. Hei No. Hei No. Hei No. 2004-33 No. Hei. No. 2004-33. It is intended to be a non-aerosol type, and it is easy to obtain a hair cosmetic preparation for a foam-like hair cosmetic which can suppress the viscosity of dripping when used. Solution to Problem The present invention has been made to solve at least some of the above problems, and can be realized in a later-described form or use example. [Use Example 1] A cosmetic preparation for hair which is self-foaming by mixing a plurality of agents to form a cosmetic for foaming hair, and the plurality of agents include a first agent containing at least a carbonate and containing a second agent for decomposing the total amount of the above-mentioned carbonate, and at least one of the plurality of agents contains a tackifier for making the hair cosmetic having a viscosity of 1500 mPa·s to 83000 mPa·s. Cosmetic preparation agent. In the case of such a composition, at least one of the plurality of agents for use as a hair cosmetic preparation contains a hair cosmetic having a viscosity of from 1 500 mPa·s to 83 000 mPa. Since the tackifier is in the range of s, it is possible to suppress foam defoaming by carbon dioxide which is generated by mixing a plurality of agents, and to make the foam of the hair cosmetic last. This result can be provided as a non-aero sol type, which can be easily obtained with a foam-like hair cosmetic which can suppress the viscosity of dripping when used (at the time of application or when it is placed at -6 - 201233399). Cosmetic preparation for hair. [Use Example 2] The hair cosmetic preparation agent according to Example 1 is the hair cosmetic preparation agent for the tackifier-based associative tackifier. In the case of the above-mentioned composition, at least one of the plurality of agents for the hair cosmetic preparation contains an associative tackifier, and therefore, each of the plurality of agents can produce a cosmetic preparation for hair in a low viscosity state. Further, when a mixed multi-component agent is provided, it is possible to produce a hair cosmetic preparation for hair-adhesive cosmetics in an appropriate pH range. [Use Example 3] The cosmetic preparation for hair according to the first aspect or the second aspect, wherein the carbonate contains at least one alkali metal salt or alkaline earth metal salt selected from a carbonate ion or an alkali metal salt of a hydrogencarbonate ion or A cosmetic preparation for hair of carbonates in the group of alkaline earth metal salts, ammonium carbonate, and ammonium hydrogencarbonate. In the case of such a composition, the first agent contains at least one alkali metal salt or alkaline earth metal salt selected from a carbonate ion, an alkali metal salt of a hydrogencarbonate ion or a soil metal salt, ammonium carbonate or ammonium hydrogencarbonate. The carbonate of the group provides a second agent which is soluble in water and has good reactivity with acid. As a result, the foaming property at the time of mixing the plurality of agents as the hair cosmetic preparation can be further improved. The use of the cosmetic preparation for hair according to any one of the first to third aspects, wherein the content of the carbonate in the hair cosmetic is 1. 0 mass %~30. 0% by mass of a hair cosmetic preparation. In the case of such a composition, since the content of the carbonate in the cosmetic material for hair is from 1% by mass to 30,000% by mass, it is possible to realize self-initiation when the plurality of agents for the hair cosmetic preparation are mixed. bubble. [Application Example 5] The hair cosmetic preparation according to any one of Examples 1 to 4, wherein the hair cosmetic is used for a hair dyeing cosmetic, and the hair cosmetic is at pH 1. O~9. Hair in the range of 0 With a cosmetic preparation. If it is such a composition, since the hair dyed for hair is used, the makeup will be at pH 1. 0~9. Within the range of 0, high dyeing power and appropriate viscosity are obtained. Further, since the carbonate contained in the hair cosmetic preparation can be efficiently reacted with the acid, a fine cosmetic foam for hair can be obtained. The use of the hair cosmetic preparation according to any one of the first to fourth aspects, wherein the hair cosmetic is used for hair dyeing, bleaching or decolorizing, and the hair cosmetic is at pH 6. 0~9. Hair within the range of 0 201233399 A cosmetic preparation. If it is such a composition, the cosmetic for hair dyeing or bleaching and decolorizing hair will be at pH 6. 0~9. Within the range of 0, high dyeing power and decolorizing power and proper viscosity are obtained. Further, the hair carbonate contained in the cosmetic preparation can be efficiently reacted with an acid to obtain a fine cosmetic foam for hair. The use of the cosmetic preparation for hair according to any one of the first to sixth aspects, wherein the at least one of the plurality of agents further contains a linear alkyl group having a carbon number of 10 to 30 or a carbon number. It is a cosmetic preparation for hair of a higher alcohol of 10 to 30 alkenyl groups. When it is such a composition, at least one of the plurality of agents for use as a cosmetic preparation for hair contains a linear alkyl group having a carbon number of 10 to 30 or an alkenyl group having a carbon number of 1 to 30. Higher alcohol ·. Since the higher alcohol system imparts hardness to the hair cosmetic, it is possible to suppress foam defoaming by carbon dioxide generated by mixing a plurality of agents, and to make the foam of the hair cosmetic material last. And a fine foam can be obtained. [Example 8] A method for producing a first agent containing at least a carbonate in a cosmetic preparation for hair which is used to form a foam-like hair cosmetic by mixing a plurality of agents, comprising an emulsion mixture a first step of the non-acid base component and the reducing agent component 201233399, and a second step of adding the carbonate-containing alkaline agent component to the emulsified mixture produced by the first step, and the second step The emulsified mixture produced in the step, and the method for producing the first agent in the third step of the acidic base component. In the case of such a composition, the method for producing the first agent containing at least a carbonate in the cosmetic preparation for hair is to add a carbonate-containing base to the emulsified mixture of the emulsified mixed non-acid base component and the reducing agent component. After the agent component is added, the acidic base component is added. Therefore, the alkali component can be added while maintaining the emulsified mixture in an alkaline state, that is, the carbonate. As a result, when the first agent is produced, foaming due to contact of the carbonate with the emulsified mixture in an acidic state can be suppressed. Therefore, it can be provided as an aerosol-free type cosmetic preparation which is easily obtained and which has a viscosity which can suppress the dripping of the foam. In addition, the present invention can be implemented in various forms. For example, the present invention is a hair cosmetic preparation, a hair cosmetic preparation production method, a hair cosmetic preparation using a hair cosmetic preparation, and a hair cosmetic preparation using a hair cosmetic preparation. Embodiments of the method and the like implement the best mode for carrying out the invention. Next, the embodiment of the present invention will be described in the following description. [Embodiment] -10- 201233399 A. Implementation type A - 1. Composition of hair cosmetic group: Fig. 1 is a schematic view showing the composition of the hair cosmetic group 1 in the embodiment of the present invention. The hair cosmetic group 10 includes a mixing container 100, a mixing device 200, a first agent 300, and a second agent 400. Hereinafter, the first agent 300 and the second agent 400 are collectively referred to as "hair cosmetic preparation agent j." The first agent 300 and the second agent 400 are each stored in a liquid state of a storage container (for example, a tubular container) or The composition of the first agent 300 and the second agent 400 is set to be a hair cosmetic (dyeing agent or decolorizing agent) when mixed with each other. Further, the first agent 300 contains carbonate (hydrocarbonate) The sodium component of the second component 400 contains an acid component which decomposes carbonate. Therefore, when the first agent 300 and the second agent 400 are mixed, the carbonate and the second agent contained in the first agent 300 are mixed. The acid contained in 400 reacts to generate bubbles (oxidation bubbles). Further, the detailed components of the first agent 300 and the second agent 400 are described in the case where the container 100 for mixing the first agent is mixed with the first agent 300 and the second agent. The cup-shaped container "received at 400 o'clock is formed of a resin (for example, PP). The mixing device 200 is used to mix and store the first agent 300 and the second agent 400 in the mixing container 1 The device is formed of a resin (for example, PP). A- 2_ Hair cosmetic treatment process: Fig. 2 shows the use of hair cosmetics. The hair cosmetic -11 - 201233399 generates a flow chart of the processing flow. In addition, in Fig. 3 and Fig. 4, the hair cosmetic preparation processing of the cosmetic group 10 is first prepared as shown in Fig. 1 including the mixing container. The appliance 200, the first agent 300, and the hair j of the second agent 400 (step S110). Next, the first agent 300 and the fourth container are moved into the mixing container 100 (step S120: the first agent 300 and the first The two doses 400 are transferred from the storage container to the inside of the container. Then, the "agent 4 00 ' moved to the mixing container 100 is mixed using the mixing device 200 (step S1 indicates that the first agent is mixed using the mixing device 200). 300 and state. When the first agent 300 is mixed with the mixing device 200, the carbonate contained in the first agent 300 and the second agent 400 (carbon dioxide) are generated. Fig. 4 is a state in which the cosmetic material FO for a mixed foaming hair is used, and the use device 200 is also used as an apparatus for picking up the mixing container 1 for the inner hair cosmetic FO. With 200' list of hair cosmetics, f〇, take the hand to mix The above-mentioned hair cosmetic preparation FO is applied to the hair. As described above, the hair cosmetic preparation for hair according to the present embodiment is a plurality of agents for mixing the foam-like hair cosmetic by mixing with each other. A cosmetic material for foaming hair can be obtained without using a propellant. In this case, a description will be given of the use of hair: 100, a mixture of enamel cosmetic materials for mixing 205, and a container for mixing. Figure 3 is a container for mixing. Agent 3 00 and 2 30). Fig. 3 shows the acid reaction of the second agent 400 and the second agent 400, and the bubble generation in the first generation is shown as _4 in the bubble generation, and the foam formed by mixing is used in the mixing device 200. 1 0 When the time is self-foaming, the special container is used, and the user does not need to carry out the operation of the container for the vibration-receiving agent in the case of the use of the mixing device 200, and the first container stored in the mixing and mixing container 1 is stored. The simple operation of the agent 300 and the second agent 400 is sufficient. Further, in the present embodiment, the hair cosmetic preparation process using the hair cosmetic set 10 is used, and the user can observe that bubbles are generated by mixing the plurality of agents, and the liquid or paste-like plural agent gradually becomes Since the foamy hair is in the state of the cosmetic material, it is possible to improve the performance (happiness, excitement). A — 3. Method for producing hair cosmetic preparation: Fig. 5 is a flow chart showing a manufacturing procedure of the first agent 300 in the cosmetic preparation for hair. First, the raw material component of the first agent 300 is divided into an alkali agent (A), a non-acid base (B), an acidic base (C), and a reducing agent (D), and are respectively selected (step S2 1 0). ). The carbonate is selected as the alkali agent (A) component. As the alkali agent (a) component, at least one or more selected from the group consisting of an alkali metal salt such as a carbonate ion or an earth metal salt, an alkali metal salt of a hydrogencarbonate ion or an alkaline earth metal salt 'ammonium carbonate or ammonium hydrogencarbonate can be selected. Groups of carbonates. Further, the toner content of the cosmetic for hair (that is, the mixed agent of the first agent 300 and the second agent) is 1 . 0% by mass to 3 0 · 0% by mass is preferable, and particularly preferably 1 · 5 % by mass to 20 - 20% by mass. Further, in addition to the carbonate, an appropriate ammonia water or the like may be added. The non-acid base (B) is not particularly limited except for non-acidity. The non-acid base (B) component is used for the purpose of the hair cosmetic (hair dye, decolorizer, etc.) and dosage form. Etc., you can choose one or a combination of components above -13 - 201233399. As the non-acid base (B) component, for example, an oxidation dye, a hydrocarbon, an ester, a polyoxyalkylene, a higher alcohol, an animal or vegetable oil, a surfactant, a plant extract, an alcohol, a natural or synthetic polymer, or a fragrance can be used. , refined water, etc. As a higher alcohol, in particular, it has a carbon number of 10 to 30 (preferably 12 to 24, preferably 14 to 22), and a linear alkyl group or a carbon number of 10 to 30 (equivalent to 12 to 24). Higher alcohols such as cetyl alcohol and stearyl alcohol having an alkenyl group of 14 to 22 are particularly preferred. The acidic base (C) component is not particularly limited except for its acidity. The acidic base (C) component can be selected from a combination of one or more components depending on the intended use and dosage form of the cosmetic preparation for hair. Since the present embodiment adopts a composition containing a tackifier in the first agent 300, an organic acid such as L-ascorbic acid, citric acid or glycolic acid, phosphoric acid, or the like can be selected as the acidic base (C) component. A carboxylic acid polymer such as an inorganic acid such as sulfuric acid or a tackifier. Further, as the tackifier, any type of tackifier may be used, but an associative tackifier (neutralizing tackifier) having a tackifying property for use in a specific pH range is particularly preferable. Further, the content of the tackifier in the cosmetic for hair (mixed drug) is preferably such that the viscosity of the cosmetic for hair (mixed drug) is in the range of 1500 mPa·s to 83000 mPa·s, so that it is 1500 mPa·s. The amount in the range of ~30000 mPa·s is better. The reducing agent (D) component may be, for example, a mercaptocarboxylic acid such as photocysteine or a derivative thereof, a mercaptocarboxylic acid such as thiomalic acid or a mercaptocarboxylic acid such as thioglycerol or a mercaptocarboxylic acid such as glyceryl mercaptoacetate. Sulfone, thiolamine, cysteinamide, sulfhydryl compounds, sulfurous acid, sodium sulfite, etc. -14-201233399 Sulfite, sodium bisulfite, etc., ascorbic acid or its derivatives One or more ingredients. Next, each of the non-acid base (B) and the reducing agent (D) selected in step S210 is classified into an oil phase obtained from an oil-soluble component and an aqueous phase obtained from a water-soluble component, and is heated. The additive phase formed by the unstable component is weighed. Further, each of the alkali agent (A) and the acidic base (C) is weighed (step S2 12). Thereafter, the weighed oil phase component and the water phase component are separately dissolved by heating (step S2 14). The aqueous phase adjusted to a certain temperature is added to the oil phase adjusted to a certain temperature, and emulsified and mixed (step S 2 16). In addition, the above-mentioned constant temperature can be arbitrarily determined in consideration of the component characteristics of the respective agents. This matter is also the same in the following. After adjusting the emulsified mixture generated in the step S26 to a certain temperature, the components of the additive phase are added (step S2 18). Thereafter, after adjusting the emulsified mixture obtained in the step S2 18 to a certain temperature, the weighed alkali agent (A) component is added (step S220). Further, it is preferred to add the alkali agent (A) component at a low temperature. At this stage, the emulsified temperature is alkaline as a whole. Thereafter, the alkaline emulsified mixture obtained in the step S220 is adjusted to a certain temperature, and then the weighed acidic base (C) component is added (step S 2 2 2 ). Further, it is preferred to add an acidic base (C) component at a low temperature. Finally, the emulsified mixture obtained in step S222 is stored in a predetermined container (step S224). Further, step S216 is also referred to as a first step, step S220 is a second step, and step S222 is a third step. As described above, in the production step of the first agent 300 in the present embodiment, the alkaline agent (A) component is added to the emulsified mixture, and then the acidic base agent -15-201233399 (c) is added. In the emulsified mixture, by adding the components in the order as described above, since the alkali component (a) component, i.e., the carbonate, can be added while maintaining the alkaline state, the carbonate can be prevented from coming into contact with the emulsified mixture in an acidic state to cause foaming. Fig. 6 is a flow chart showing the steps of manufacturing the second agent 400 in the cosmetic preparation for hair. First, the raw material components of the second agent 400 are classified as a base (E), a pH adjuster (F), and an oxidizing agent (G), and are selected (step S3 10) as a base (E) component, and are not particularly limited. . As the base (E) component, a combination of one or more components can be selected depending on the intended use and dosage form of the cosmetic preparation for hair. As the component (E) component, for example, a hydrocarbon, an ester, a polyoxyalkylene, a higher alcohol, an animal or vegetable oil, an surfactant, a plant extract, an alcohol, a natural or synthetic polymer, a fragrance, purified water or the like can be used. As the pH adjuster (F) component, an acid which can decompose the carbonate contained in the first agent 300 is selected. At least one or more acids selected from the group consisting of organic acids such as citric acid and glycolic acid, inorganic acids such as phosphoric acid and sulfuric acid, and the like can be selected. In addition, when the cosmetic for hair dyeing for reducing the degree of hairy invention is used, the pH adjuster is selected to make the cosmetic for hair (mixed medicine) at ρ Η 1 〇 〜 9. It is preferred that the amount in the range of 0 is selected so that the amount in the range of ρ Η 3 〇 to 7 〇 is particularly preferable. On the other hand, when the cosmetic for hair dyeing, bleaching, or bleaching is used to increase the degree of hair dyeing, the amount of the hair cosmetic (mixing agent) is selected to be within the range of ρΗ6〇~9〇. It is advisable to choose ρΗ7·0~8. The amount within the range of 5 is particularly good. -16- 201233399 In addition, "bleaching and bleaching of hair" means decolorization of melanin in hair. Further, "staining of hair" means changing the chromaticity and brightness of hair by oxidation of an oxidative dye. In addition, in the case of "dyeing of hair", the tingescence and brightness of the hair can be changed by oxidation of the oxidative dye while bleaching and decolorizing the hair. As the (G) acidifying agent component, for example, urea peroxide, melamine peroxide, sodium perborate, potassium perborate, potassium percarbonate or the like can be selected, for example, hydrogen peroxide, hydrogen peroxide or an oxygen generating agent. Next, each of the base (E), pH adjuster (F), and oxidizing agent (G) selected in step S3 10 is classified into an oil phase composed of an oil-soluble component and an aqueous phase derived from a water-soluble component. The additive phase formed by increasing the temperature of the unstable component is weighed (step S3 12). Thereafter, the weighed oil phase component and the water phase component are separately heated (step S3 14). The aqueous phase adjusted to a certain temperature is added to the oil phase adjusted to a certain temperature to carry out emulsification mixing (step S316). After the emulsified mixture produced in the step S316 is adjusted to a certain temperature, the components of the additive phase are added (step S3 18). Finally, the emulsified mixture obtained in the step S3 18 is stored in a predetermined container (step S324). B. Experimental results: The hair cosmetic preparations described in the above-described embodiments were variously modified in terms of the components and contents of the hair cosmetic preparation, and various experimental results were carried out as follows. For each of the experiments described later, a sample of the first agent 300 manufactured by the method described with reference to FIG. 5 and a mixture of contents 750-201233399 (FIG. 1) and a mixing device 200 (FIG. 1) were used. The sample of the second agent 400 produced by the method described in Fig. 6 was evaluated by mixing the mixing ratio (weight ratio) of 1:1 to the obtained hair cosmetic (mixed drug). Further, the mixing is carried out in accordance with the steps of the hair cosmetic manufacturing process described with reference to Fig. 2 . B-1. Experimental Results 1 (Experimental Results on Viscosity of Cosmetics for Hair): Fig. 7 is an explanatory view showing a sample of the first dose of 300 00 used in the experiment of viscosity of a cosmetic for hair. Fig. 8 is an explanatory view showing a sample of the second agent 400 used in the experiment of the viscosity of the cosmetic for hair. Fig. 9 is an explanatory view showing the results of an experiment on the viscosity of a cosmetic for hair. Further, for convenience, the first agent in the figure is only referred to as "one dose", and the second dose is only referred to as "two doses". In addition, the sample numbers in the figure correspond to the same substance (that is, for example, the evaluation result of the sample #10 shown in FIG. 9 indicates that the first dose of the sample #1〇 of FIG. 7 and the sample #1 0 of FIG. 8 are mixed. Evaluation result of hair cosmetic obtained by the second agent). These things are the same for other experimental results that are subsequently expressed. In this experiment, first, it is necessary to change the viscosity of the hair cosmetic (mixed drug) by changing the content of the first agent carbonate (potassium carbonate and ammonium hydrogencarbonate) and the content of the tackifier (carboxyvinyl polymer). Samples (sample # 1 0~# 1 9 ). Next, for sample #1 〇~#1 9, for (1 -1) to maintain the foam of the mixed medicament, (1 - 2) when the liquid dripping, (1 - 3) when the liquid drops, (1 - 4 The items for the permeability of the hair during application are evaluated. In addition, the viscosity of the mixed drug is used at -18-201233399 20 °C to defoam the mixed agent (in vacuum and degassing), and use the B-type rotary viscometer roller Νο·4 to make J to 1 After a minute. The evaluation method and the evaluation criteria are as follows (1 _ 1 ). The foam of the mixed drug is maintained for the purpose of mixing the second and second dose samples, and the evaluation is performed by visual confirmation. The so-called "defoaming" refers to The carbonate reacts with the acid and the Cao foam shows a decreasing tendency. In addition, the number of agitation is used as a donation (Fig. 1), and the circle around the mixing container (Fig. 1) is “1 time”. Evaluation criteria for maintaining the blended foam: Even if it is stirred more than 100 times, it has not been defoamed. Even if it is stirred more than 50 times, it has not defoamed. C: Stirring to 50 times, defoaming starts D: no foaming, or stirring immediately At the beginning of defoaming (1_2), the liquid dripping was evaluated by a panel of 150 assessors 150g of the medicament mixed with the medicament under 25t conditions. Evaluation criteria for liquid dripping during application A: No liquid dripping when applied to the head B: Almost no liquid dripping when applied to the head C: When applied to the head, only a small amount of liquid dripping D: When applied to the head , quite a lot of liquid drops will drop the foam. Rotate 1 dose of sample at 6 rpm. In addition, when the combined apparatus is generated, the count is the liquid drips when the liquid is applied at the time of -19-201233399 (1 - 3 ), and the immersion of 150 gram of the mixed agent is applied to the dyed hair under the condition of 3 5 t. The evaluation was carried out by placing the hair of the test person as a whole. Evaluation criteria for liquid dripping when placed A: No liquid dripping completely B: Placed within 30 minutes, no liquid dripping C: Placed within 30 minutes, only a few micro liquids drip D: Placed within 30 minutes, quite a lot of liquid dripping (1 - 4) The permeability to hair is determined by 20 assessors, applied at 25 °C. The foam of the mixed medicament was evaluated for the penetration of the hair when the hair of the test doll was dyed. Here, the term "permeability to hair" means that the mixed drug rapidly penetrates between the hairs. Evaluation of the permeability of hair A: Excellent permeability to hair B: Good permeability to hair C: Poor permeability to hair D: Almost no permeability to hair The result of this evaluation test, the viscosity of the mixed agent At 1500mPa·s~30000mPa. Samples #10 to #13 in the range of s are all evaluated. The project is evaluated A. That is, the sample #1 〇~# 1 3 is not defoamed even if the foam of the mixed drug is stirred more than 100 times (that is, the foam is long-lasting), and there is no liquid dripping at the time of application and penetration, and penetration into the hair. Sex is also excellent -20- 201233399 different," In addition, the viscosity of the mixed agent is 75400mPa·s sample #15 and the viscosity of the mixed agent is 82600mPa·s sample #18' although the foam of the mixed agent is stirred up to 50 times The bubble 'poor to the hair' is not liquid dripping at the time of application and placement. On the other hand, the viscosity of the mixed agent is 750 mPa. s sample # 1 4 and the viscosity of the mixed agent is 1200mPa. Sample #s of s, stirring and mixing the foam of the medicament to 50 times, that is, defoaming, and a considerable amount of liquid dripping occurred during application and placement. The sample has a viscosity of 100,000 mPa·s or more of samples #16 and #19. The foam of the mixed drug cannot be foamed and has no permeability to the hair (in other words, poor permeability to hair and lack of usability) 〇 From the evaluation of the test results, it is understood that the content of the tackifier in the cosmetic for hair (mixed drug) is preferably such that the viscosity of the cosmetic for hair is in the range of from 15 to 100 mPa·s to 83,000 mPa·s. When the viscosity of the cosmetic for hair is within the above range, the foam which is formed by mixing the carbon dioxide generated by the first agent and the second agent (that is, the mixture of the carbonate and the acid) can be suppressed by an appropriate viscosity. Since the defoaming is carried out, it is possible to easily obtain a non-aerosol type cosmetic for foamy hair which has a viscosity which can suppress dripping when used. From this, the test results are evaluated. Further, it is understood that the tackifier content of the cosmetic for hair (mixed drug) is particularly preferably such that the viscosity of the cosmetic for hair is in the range of from 1,500 mPa s to 30,000 mPa·s. When the viscosity of the cosmetic for hair is within the above range, it is possible to obtain a cosmetic for hair which has a long-lasting foam for the cosmetic with appropriate viscosity, and which has better finger patency during application and is excellent in usability. -21 - 201233399 B — 2 . Experimental result 2 (Experimental result 1 on the type of tackifier): Fig. 1 is an explanatory view showing a sample of the third sample used in the experiment on the type of tackifier. Fig. 11 is an explanatory view showing a sample of the second agent 400 used for the type of the tackifier. Fig. 12 is an explanatory view showing the results of experiments on the types of agents. In this experiment, first, it is prepared to change a plurality of samples of the tackifier carboxyvinyl polymer, acrylic acid alkyl methacrylate copolymer, sodium cellulose silicate, xanthan gum, and the content thereof contained in the first agent ( Sample ~ #24). Next, for the samples #20 to #24, the viscosity of the mixed drug was determined, and at the same time, the items of the foam of the mixed drug and the dispersibility of the tackifier at the time of the formation of the first agent were evaluated for (2-1). The method for determining the viscosity of the mixed agent is B-1. Experimental result 1 is the same. For (2 - 1) evaluation methods and benchmarks for maintaining the foam of the mixed agent and B-1. Experimental result 1 (1_1) is the same" (2 - 2) The dispersibility of the tackifier in the formation of the first agent is the step of adding a tackifier in the first manufacturing step, and whether the tackifier is dispersed in the preparation, The evaluation was carried out by visual confirmation. Evaluation criteria for the dispersibility of the tackifier when the first agent is formed A: The tackifier can be easily dispersed in the preparation B: the tackifier can be dispersed in the preparation C: the tackifier can be dispersed in the preparation, but the small particle 1 test is formed Medium viscosity increase (Carboxy #20 agent 2-2. The other evaluation agent is easy -22- 201233399 D: The adhesion promoter can hardly be dispersed in the preparation. The result of this evaluation test, the long-lasting sample of the mixed drug foam is obtained. Evaluation A (even if it is stirred more than 1 time, it is not necessary to use the associative tackifier sample #20~#22, when added, the tackifier is easily dispersed in the formulation. On the other hand, the combination Sample of tackifier for tackifier # 2 3 is added to the tackifier mixture to cause small particles due to tackifier. Similarly, sample with non-associated tackifier # 2 4 is added with tackifier In this case, it is preferable to use the associative tackifier (the tackifier which becomes a specific pH range) in the hair cosmetic preparation. When the tackifier is added, the step of adding the tackifier is added in the manufacturing step. Obtained dispersibility manufactured B -. 3. EXPERIMENTAL RESULTS 3 (Other experimental knots on the type of tackifier: Figure 13 is an explanatory diagram showing the sample of the agent 300 in other experiments on the type of tackifier. Figure 1 shows the use of the tackifier in his experiment. Illustration of the second dose 400 sample. Fig. 1 is an explanatory diagram of other experimental results of the type of tackifier. This experiment is to change the first dose and the first dose by changing the phosphoric acid content of the first dose of the potassium hydroxide containing agent. 2 doses of p Η, mixed as a tackifier carboxyvinyl polymer or carboxymethyl cellulose sodium multiple samples (sample # 3 0~# 3 3 ). Next, for the sample force system all bubbles). When the tackifier is mixed and used, the type of tackifier does not disperse the agent containing the tackifier and the stickiness of the old one. The 5th line of the first type is XL λ. And the second change of the mixed agent product # 3 0~ -23- 201233399 # 3 3, determine the viscosity of the first agent, the viscosity of the second agent, the viscosity of the mixed agent, and the pH of the mixed agent, and at the same time For each item (3 _ 1 ) which maintains the dispersibility of the tackifier (the first agent and the second agent) in the foam of the mixed drug (3-2), the tackifier is evaluated. Further, the method for measuring the viscosity of the mixed drug is the same as that described in B-1 and Experimental Results 1. In addition, the viscosity of the first agent and the second agent is at 20 ° C, and the roller No. of the B-type rotary viscometer is used. 4. Let the 値 after 1 minute of rotation at 6 rpm. The evaluation method and evaluation criteria for the (3 - 1 ) maintenance of the mixed agent foam are the same as those of B _ 1 · Experimental result 1 (1 - 1). For (3 - 2) contains tackifier. The evaluation method and evaluation basis of the dispersibility of the tackifier in the preparation of the agent (the first agent and the second agent) and B- 2. The experimental results 2 (2 - 2) are the same. As a result of the evaluation test, in the samples #30 and #'32 in which the amount of potassium hydroxide contained in the first agent was the same, the sample #30 using the associative tackifier (carboxyvinyl polymer) was more than the non-associated type. Sample of the adhesive (carboxymethylcellulose sodium) # 3 0, the viscosity of the first agent is low, and the tackifier content can be reduced. Further, in the samples #3 1 and #3 3 in which the amount of the phosphoric acid contained in the second agent was the same, the sample #31 using the associative tackifier (carboxyvinyl polymer) was used as the non-associative tackifier (carboxyl). Sample of methylcellulose sodium) # 3 3, the second agent has a low viscosity and can reduce the tackifier content. Further, using the associative tackifier (carboxyvinyl polymer) sample #3 〇, #3 1, a tackifier is added to the manufacturing step of the tackifier-containing agent (first agent, second agent). In the mixing step, the tackifier is easy to disperse into the formulation. -24- 201233399 On the other hand, samples #32 and #33 using non-associative tackifiers were not dispersed in the formulation. As a result of the evaluation of the test, it is understood that the tackifier contained in the cosmetic preparation for hair (mixed drug) is an associative tackifier (a tackifier which exhibits a viscosity-increasing effect when it is in a specific pH range). If an associative tackifier is used, the content of the tackifier is reduced to a low blending amount, and a cosmetic preparation for hair which maintains the viscosity of the blending tackifier or other agents can be produced. When a plurality of agents (the first agent and the second agent) are used, the neutralization reaction is caused by the reaction of the carbonate with the acid, and the cosmetic material for hair (mixed drug) becomes a pH range suitable for viscosity enhancement, and the viscosity can be exhibited. effect. Further, the dispersibility of the tackifier can be improved when the agent containing the tackifier (the first agent 'the second agent') is formed. Further, as a result of the above evaluation test, it is understood that the associative tackifier can be blended in either the first agent or the second agent. B — 4. Experimental result 4 (Experimental result on carbonate type): Fig. 16 is an explanatory view showing a first dose of a sample of a carbonate used in an experiment of a carbonate type. Fig. 17 is an explanatory view showing a sample of the second agent 400 used in the experiment on the type of carbonate. Fig. 1 is an explanatory diagram showing the results of experiments on the types of carbonates. This experiment is intended to change the carbonate content of the first agent (potassium carbonate, ammonium hydrogencarbonate, sodium carbonate, sodium hydrogencarbonate, potassium hydrogencarbonate, calcium carbonate, barium carbonate, propylene carbonate, ethylene carbonate) and its content Samples (sample # 40~# 50 ). Next, for the samples #40 to #50, the foaming property at the time of (4-1) mixing was evaluated. Further, for each of the carbonates used in the samples #40-25-201233399 to #50, the solubility of the (4-2) carbonate was additionally evaluated. (4-1) The foaming property at the time of mixing is evaluated by visual inspection for the foaming state of the first dose sample and the second dose sample. Evaluation of foaming property at the time of mixing A: shows excellent foaming property B: shows good foaming property C: shows weak foaming property D: hardly shows foaming property of (4-2) carbonate The solubility in the case where the carbonate was placed in water and stirred was visually confirmed and evaluated. Evaluation of carbonate solubility Benchmark A: shows excellent solubility in water B: shows good solubility in water C: shows poor solubility in water D: shows almost no solubility in water This evaluation test result, as carbonate, contains Ammonium bicarbonate sample #40 and 43, sample containing potassium carbonate and ammonium bicarbonate #41, sample containing potassium carbonate #42, sample containing sodium carbonate #44, sample containing sodium bicarbonate # 4 5, containing carbonic acid Sample #46 of potassium hydrogen, sample #47 containing calcium carbonate, and sample #48 containing cesium carbonate showed excellent foaming properties when the first agent and the second agent were mixed. On the other hand, a sample containing a propylene carbonate as a carbonate #49-26-201233399 and a sample #50 containing a carbonate as a carbonate hardly foamed when the first agent and the second agent were mixed. Further, the carbonates (potassium carbonate, ammonium hydrogencarbonate, sodium carbonate, sodium hydrogencarbonate, potassium hydrogencarbonate) used in the samples #40 to #46 showed excellent solubility in water. On the other hand, the carbonate (ethylene carbonate) used in the sample #50 showed weak solubility in water. Carbonate (calcium carbonate) used in sample #4, carbonate (carbonate) used in sample #48, and carbonate (propylene carbonate) used in sample #49 showed almost no solubility in water. As a result of this evaluation test, it is known that the carbonate contained in the first agent contains at least one selected from the group consisting of carbonate. Preferably, the alkali metal salt or the alkaline earth metal salt, the alkali metal salt or the alkaline earth metal salt of the hydrogencarbonate ion, the ammonium carbonate or the hydrogen carbonate saddle are preferred. In this way, since the first agent which is excellent in water solubility and acid reactivity can be provided, the foaming property at the time of mixing the plurality of agents as the hair cosmetic preparation can be further improved. B- 5. EXPERIMENTAL RESULTS 5 (Experimental results on the pH of the hair cosmetic used for dyeing or bleaching and bleaching for hair coloring): Figure 19 shows the hair used for dyeing or bleaching and bleaching of the hair dye invention. An illustration of the third dose of the sample used in the experiment of the PH of the cosmetic. Fig. 20 is an explanatory view showing a sample of the second agent 400 used in the experiment for improving the pH of the hair cosmetic used for dyeing or bleaching or bleaching. Fig. 21 is an explanatory view showing the results of an experiment on pH -27-201233399 for a cosmetic for hair dyeing, bleaching, and bleaching for improving the degree of hair dyeing. In this experiment, a plurality of samples (samples #60 to #64) of the pH of the hair cosmetic (mixed drug) were changed by changing the ammonia content of the first agent and the phosphoric acid content of the second agent. Next, for each of the samples #60 to #64, the items of the foaming property at the time of (5-1) brightness and (5-2) mixing were evaluated. Further, each of the samples in the present experiment was used to produce a hair cosmetic for use in dyeing or bleaching or decoloring for hair coloring (and even for dark hair coloring). (5 - 1) The brightness is assessed by the actual coloring of 20 assessors. Specifically, the foam of the medicament is mixed with 150 g at 25 ° C in the state of the hair as a whole, and left for 20 minutes. After the mixed drug was rinsed off, the brightness of the hair after drying was visually confirmed and evaluated. Evaluation of brightness: A: shows excellent brightness B: shows good brightness C: shows weak brightness D: almost no display of brightness (5 - 2) evaluation of foaming property and evaluation criteria and B-4 . The experimental result 4 is the same as (4 - 1). As a result of this evaluation test, the mixed agent was pH 6. Sample #0 of 60, sample #61 of pH 7_5 showed good lightness, and showed excellent foaming property when the first agent and the second agent were mixed. In addition, the mixed agent is p Η 9. Sample # 0 shows excellent brightness, and shows the good foaming property when mixing the first agent and the second agent. -28- 201233399 On the other hand, the mixed agent is pH 5. 0 sample # 63, almost no brightness. The mixture is pH 10. Sample #0 of 0, even if the first agent and the second agent were mixed, almost no foaming occurred. From this, the results of the test were evaluated to improve the hair cosmetic materials used for dyeing, bleaching, and bleaching, and it was found that the hair cosmetic (mixed drug) was attached to PH6. 0~9. Within the range of 0 is appropriate. In this way, for hair cosmetic materials, high hair dyeing power and decolorizing power, as well as appropriate viscosity, can be obtained. Further, the carbonate contained in the hair cosmetic preparation can be efficiently reacted with the acid. As a result of the appropriate viscosity and the good reaction efficiency of the carbonate and the acid, a foam of a finely viscous cream-like hair cosmetic can be obtained, which can be suppressed (when applied). When placed, the effect of liquid dripping, or the effect of uneven dyeing. B - 6. EXPERIMENTAL RESULTS 6 (Experimental results on the content of carbonate in the cosmetic for hair used for dyeing or bleaching and bleaching for hair coloring) FIG. 22 shows the use of dyeing or bleaching and bleaching for improving the degree of hair invention. An explanatory diagram of the experimental results of the content of carbonate in the cosmetic material for hair. This experiment is prepared for B- 5. Experimental result 5, sample #61, changed as a total of potassium carbonate and ammonium hydrogencarbonate as a carbonate. 0% by mass to 4 0. A plurality of samples of 0% by mass (sample # 610 to 615). Next, for the samples #6 1 0 to # 6 1 5, the evaluation of the foaming property at the time of (6-1) mixing, (6 to 2) from the container, and the feeling of use (6 _ 3 ) were evaluated - 29- 201233399 Evaluation method and evaluation criteria for (6 - 1) foaming during mixing and B - 4. The experimental result 4 is the same as (4 - 1). (6-2) From the container, the foam was ejected from the container for self-mixing when mixing the first dose sample and the second dose sample, and was visually confirmed and evaluated. Evaluation criteria A from the container: No matter how mixed, almost no B: Care should be taken when mixing, but not C: Although carefully mixed, some slightly gush D: Even if carefully mixed, it is intense (6 - 3 The feeling of use was evaluated by 20 assessors for the ease of application of the foam of the test agent mixed at 25 ° C to the hair of the test doll for hair dyeing. Evaluation criteria for feeling of use A: Very easy to spread, easy to apply B: Unfolding ordinary, but no problem with application C: Difficult to apply The result of this evaluation test is that the carbonate content is 1〇. 〇% by mass of sample #612 showed good foaming when mixing the first agent and the second agent, and although attention was paid during mixing, no foam was observed from the mixing container. In addition, Sample # 6 1 2 is very easy to spread when applied to hair, and it is easy to apply -30-201233399. The carbonate content is 2 0. 0% by mass of the sample # ό 1 3 mixed sputum agent and the second agent showed good foaming property, and even if careful attention was observed during mixing, some micro-foam was observed from the mixing container. In addition, the sample # 613 is very easy to spread when applied to the hair 'easy to apply. The carbonate content is 30. 0% by mass of the sample # 614 showed excellent foaming properties when the first agent and the second agent were mixed, and even though careful attention was observed when mixing, some microbubbles were observed to flow from the mixing container. In addition, sample #614 is a problem that does not spread when applied to the hair, and can be applied. On the other hand, the carbonate content is 1. 〇% by mass of sample #6 1 0 system Even when the first agent and the second agent are mixed, there is almost no foaming. The carbonate content is 5. 0% by mass of the sample # 6 1 1 Even if the first agent and the second agent were mixed, only the weak foaming property was exhibited, but no foam was poured out from the mixing container. In addition, Sample #610 was well developed when applied to hair. The carbonate content is 40. 0% by mass of the sample # 6 1 5 When the first agent and the second agent were mixed, even if careful attention was made, the foam was violently poured out from the mixing container, and spread when applied to the hair. From the results of the evaluation of the test, it was found that the amount of carbonate in the cosmetic for hair (mixed drug) was 1 in the case of the cosmetic for hair dyeing or bleaching or bleaching. 〇质量%~3 0. 0% by mass is appropriate, to 10. 0% by mass to 20. 0% by mass is especially preferred. When the content of the carbonate in the hair cosmetic is within the above range, a suitable self-foaming effect can be obtained when a plurality of agents for the hair cosmetic preparation are mixed. Β - 7. Experimental result 7 (Experimental results of the pH of the hair cosmetic used for dyeing for reducing the degree of hair invention) 31: Fig. 23 shows the pH of the hair cosmetic used for dyeing for reducing the hairiness of the invention. A plot of the first dose of 300 00 samples used in the experiment. Fig. 24 is a view showing a sample of the second agent 400 used in the experiment for reducing the pH of the makeup used for dyeing for dyeing. Fig. 25 is an explanatory view showing the results of an experiment for reducing the pH of the hair cosmetic used for dyeing for the hairiness of the invention. This experiment was first prepared by changing the sample of the hair cosmetic (mixed drug) by changing the ammonia content of the first agent and the phosphoric acid content of the agent (sample #70 to #75). Next, for the sample #70~, the foaming property at the time of (7-1) mixing and (7-2) evaluation of each item of the scalp were evaluated. Further, in each of the samples in the present experiment, a cosmetic for hair which was used for dyeing for reducing the degree of hair invention (i.e., for brightening) was used. Evaluation method and evaluation basis for (7 - 1) foaming during mixing and B - 4. The experimental result 4 (4-1) is the same. (7-2) The scalp stimuli were evaluated by 20 assessors for the presence or absence of irritation (pain, itching) when 150 g of the foam of the mixture was applied to the hair at 25 °C. Evaluation of scalp irritation A: The scalp is not irritated at all B: The scalp is hardly irritated C: The scalp is irritated by the hair Description The hair is 2: pH #75 Stimulates the variability of the scalp - 32- 201233399 D : The scalp is very irritating to the results of this evaluation test, the mixture is pH 3. 2 5 sample # 7 1 , pH 6. Sample No. 80 of 72 showed excellent foaming property when the first agent and the second agent were mixed, and the scalp was completely irritated when the medicinal agent was applied to the scalp. Further, the sample #70 having a mixed drug of pH 1 · 0 showed excellent foaming properties when the first agent and the second agent were mixed, but was irritated to the scalp when the mixed drug was applied to the scalp. The mixed agent is pH 8. Sample No. 80 #73 Mixing The first agent and the second agent showed good foaming properties, and when the mixture was applied to the scalp, the scalp was completely irritated. On the other hand, the mixed agent is pHO. Sample #57 of 57 was strongly irritated to the scalp when the medicinal agent was applied to the scalp. In addition, when the mixed drug was a sample of p Η 9 · 300, the sample was mixed with the first agent and the second agent, and the result of the test was evaluated, and it was found that the hair used for dyeing for reducing the degree of hair invention was used. Cosmetics 'hair cosmetics (mixture) are attached to pHl. It is suitable to be in the range of O~9·0, and ρΗ3·0~7. Especially within the range of 0. In this way, the hair cosmetic can achieve high hair color and proper viscosity. Further, the carbonate contained in the hair cosmetic preparation can be efficiently reacted with the acid. The appropriate viscosity and the result of the reaction efficiency of the carbonate and the acid are good, and the foam of the cosmetic cream for the fine and viscous hair can be obtained, and the effect of suppressing the liquid dripping or suppressing the dyeing when used (at the time of application) can be suppressed. The effect of unevenness. Β — 8. EXPERIMENTAL RESULTS 8 (Experimental results of the amount of carbonate in the hair cosmetic used for the dyeing of the hair dyeing method - 33 - 201233399) Fig. 26 shows the hair used for dyeing for reducing the hair coloring degree An explanatory diagram of the experimental results of the content of carbonate in the cosmetic. This experiment is prepared for B- 7. Experimental result 7 sample #71, changed as a carbonate of hydrogen carbonate content 1. 0% by mass to 1〇. 复 mass % of multiple samples (sample # 7 1 0~# 7 1 5 )» Next, for sample # 7 1 0 ~ #715, for (7-1) foaming when mixed, (7-2) Evaluate each item from the container, (7-3) use sense. (7-1) Evaluation method and evaluation criteria for foaming during mixing and B - 4. The experimental result 4 (4_1) is the same. (7-2) Evaluation methods and evaluation criteria from the container and B. The experimental result 6 (6_2) is the same. About (7 - 3) assessment methods and assessment criteria and B - 6. The experimental result 6 (6-3) is the same. As a result of this evaluation test, a sample having a carbonate content of 1.25 mass% was #71 1 and 2. 0% by mass of the sample # 712 showed good foaming property when the first agent and the second agent were mixed, and although care was taken during mixing, no foam was observed from the container for mixing. In addition, Sample # 7 1 1 and # 7 1 2 are very easy to spread when applied to hair, and are easy to apply. The carbonate content is 3. 0 mass ° / ❶ sample # 7 1 3 shows a good foaming property when mixing the first agent and the second agent 'but careful attention even when mixing'. Some microbubbles are still emerging from the mixing container. In addition, Sample # 7 1 3 is very easy to spread when applied to hair and easy to apply. On the other hand, the carbonate content is 1. 0% by mass of sample #710-34-201233399 Even when the first agent and the second agent were mixed, only the weak foaming property was exhibited, but no foaming was observed from the mixing container, and it was developed when applied to the hair. The carbonate content is 5. 0% by mass of samples #714 and 10. 0% by mass of sample # 715 Even if the first agent and the second agent were carefully mixed, the foam was vigorously ejected from the mixing container. From the results of the evaluation of the test, it was found that the amount of carbonate in the hair cosmetic (mixture) used in the dyeing of the hair dyeing method was reduced to 1. 5~10. Especially in the range of 0% by mass. When the content of the carbonate in the cosmetic composition is within the above range, a suitable self-foaming effect can be obtained when a plurality of agents for the hair cosmetic preparation are mixed. B — 9. Experimental result 9 (Experimental results on higher alcohols): Fig. 27 is an explanatory view showing a sample of the first agent 300 used in the experiment of higher alcohol. Fig. 2 is an explanatory view showing a sample of the second agent 400 used in the experiment on higher alcohol. Fig. 29 is an explanatory view showing the results of experiments on higher alcohols. This experiment is intended to change the alcohol content of the first agent (myristyl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, octanol, lauryl alcohol, tetracosyl alcohol, triacontanol, A plurality of samples of Caprylyl alcohol, tridodecyl alcohol, and their contents (sample #80~#89). Next, for samples #80 to #89, for (9-1) to maintain the foam of the mixed medicament, (9-2) when the liquid is dripped, (9-3) when the liquid drops, (9 - 4) lightness And (9-5) dyeing items are evaluated. -35- 201233399 About (9 - 1) Evaluation Method and Evaluation of Foam for Maintaining Mixed Medicament Baseline and B-1. The experimental result 1 (1 - 1) is the same. The evaluation method and evaluation criteria for liquid dripping at (9 - 2) application are the same as B _ 1 · Experimental result 1 (1 - 2). The evaluation method and evaluation criteria for liquid dripping during (9 - 3) placement are with B _ 1 . The experimental results 1 (1 - 3) are the same. The evaluation method and evaluation criteria for (9 - 4) brightness are compared with b. The experimental result 5 (5 - 1) is the same. About (9 - 5) Dyeing was evaluated by 20 assessors with actual hair coloring. Specifically, apply 150 kg of the foam of the medicament to the whole hair state under the condition of 25 ° C, place it for 20 minutes, rinse off the mixed medicament, and confirm the dyeability of the dried hair by visual inspection. Evaluation of staining criteria A: shows excellent dyeability B: shows good dyeability C: shows weak dyeability D: hardly shows staining results of this evaluation test, sample containing myristyl alcohol #80, containing Sample of cetyl alcohol # 8 1. Samples containing stearyl alcohol # 82 were evaluated in all evaluation items A » That is, sample # 8 0~8 2 is even if the foam of the mixed drug is stirred more than 100 times. The foam (that is, the foam is durable) does not cause liquid dripping during application and placement, and exhibits excellent brightness and excellent dyeability. Sample #83 containing behenyl alcohol, even if the foam of the mixture was stirred -36-201233399, it was not defoamed 100 times or more, and it was not applied during application and placement, showing good brightness and excellent dyeability. The evaluation items of sample #85 containing lauryl alcohol and I containing all of tetracosyl alcohol were evaluated B. That is, the sample # 8 5 was stirred for 50 times of the foam of the mixed drug, and still did not defoam. There was almost no liquid dripping, and it remained within 30 minutes. In addition, it shows good brightness and good dyeability. Product # 8 4 and the sample containing triacontanol # 8 7 is not defoamed even if the foam is stirred 50 times, and it is not dropped when applied. No liquid dripping is observed within 30 minutes. Brightness and weak dyeability. Octyl alcohol-containing sample #88 and tridecyl alcohol-containing | The foam of the mixed drug was stirred for 50 times to defoam, and the liquid was dropped when applied, and almost no brightness was observed, and the test result was evaluated for the dyeing, It is preferable that at least one of the agents for use as a cosmetic powder for hair contains a higher alcohol having a 10-alkyl group or an alkenyl group having 10 to 30 carbon atoms. The hardness of the cosmetic material for hair can be imparted, and foam defoaming by carbon dioxide generated by mixing can be suppressed, and the hair can be made to last. Further, by containing a higher alcohol, the hair foam can be made fine, and the effect of suppressing use (the effect of applying, falling, or suppressing uneven dyeing) can be obtained. Modifications: Raw liquid dripping I product #86于, #86 series, when the application is also seen, there is a liquid drip containing octanol-like mixed agent, see liquid droplets only show weak I products # 8 9 series and placed Sex is also weak. The straight chain of -3 0 of the material generating agent is used as a liquid for the use of a high-alcohol carbonate and an acid cosmetic. -37-201233399 In addition, the invention is not limited to the foregoing embodiment or embodiment, Beyond the scope of the gist, various components can be adopted. For example, it can be modified as follows C1. [Modification 1] In the above-described embodiment and experimental examples, the cosmetic preparation for hair is composed of two (first agent, second agent) components, and an example of blending each of the agents is described. However, the hair cosmetic preparation is sufficient to contain the first agent containing at least the carbonate and the second agent containing the acid capable of decomposing the carbonate, and is not limited to the above-exemplified form. Specifically, the components and contents of the cosmetic preparation for hair can be arbitrarily changed. For example, in the above-described embodiment, the tackifier is contained in the first agent, and the tackifier is sufficient to contain at least one of the plurality of agents constituting the hair cosmetic preparation. Specifically, when the cosmetic preparation for hair is composed of three doses, the tackifier may be blended in the third dose, and the cosmetic preparation for hair may be composed of two doses, or the second dose may be used. Medium blending tackifier. Further, the type of the tackifier may be blended for all of the plurality of agents. For example, in the above-mentioned embodiment, it is described that the first agent contains a higher alcohol, and the higher alcohol is contained in at least one of the plurality of agents constituting the hair cosmetic preparation. Specifically, when the cosmetic preparation for hair is composed of three agents, a higher alcohol may be blended in the third agent, and when the cosmetic preparation for hair is composed of two agents, the second agent may be used in the second agent. Blending higher alcohols. Further, a form of a higher alcohol may be blended for all of the plurality of agents. -38- 201233399 C2. Modification 2: The above embodiment (Fig. 1) shows an example of the composition of the cosmetic composition for hair. However, the composition of the hair cosmetic composition can have various modifications. For example, the shape and material of the mixing container or the mixing device can be changed. For example, a container in which a mixing container and a mixing device are integrally molded can be used. C3. (Modification 3) The above-described embodiment (Fig. 2) shows an example of a process for producing a cosmetic material for hair using a cosmetic composition for hair. However, the hair cosmetic manufacturing process can be variously modified. C 4 . Modification 4: The manufacturing steps of the first agent and the second agent will be described in the above embodiment (Figs. 5 and 6). However, this manufacturing step is only an example and can be variously modified. For example, some of the steps in the first agent manufacturing step may be omitted, or the order of the steps may be changed. However, from the viewpoint of suppressing foaming of the carbonate, the order of adding the (A) alkali component (step S220) and the step of adding (B) the acidic component (step S222) are preferably not changed. C5. (Variation 5) In the above-described embodiment, a cosmetic for hair which is applied to the hair to change the degree of hair invention will be described as an example. However, the invention may take other forms and is not limited to the foregoing. Specifically, it can also be used as a preparation for foam-like cosmetic materials which are applied to body hair, for example, to -39-201233399 for changing the brightness of body hair. BRIEF DESCRIPTION OF THE DRAWINGS [Fig. 1] is a schematic view showing the composition of a cosmetic composition for hair in an embodiment of the present invention. Fig. 2 is a flow chart showing a flow of a cosmetic preparation process for hair using a cosmetic composition for hair. Fig. 3 is an explanatory view showing a hair cosmetic preparation process using a hair cosmetic group. Fig. 4 is an explanatory view showing a hair cosmetic preparation process using a hair cosmetic group. Fig. 5 is a flow chart showing a manufacturing procedure of a first agent in a cosmetic preparation for hair. Fig. 6 is a flow chart showing a manufacturing procedure of a second agent in a cosmetic preparation for hair. Fig. 7 is an explanatory view showing a first dose sample used in an experiment for viscosity of a cosmetic for hair. Fig. 8 is an explanatory view showing a second dose sample used in an experiment for viscosity of a cosmetic for hair. Fig. 9 is an explanatory view showing the results of an experiment on the viscosity of a cosmetic for hair. Fig. 10 is an explanatory view showing a first dose of the sample used in the experiment on the type of the tackifier. -40-201233399 [Fig. 11] is a diagram showing the second dose sample β used in the experiment on the type of tackifier. Fig. 12 is an explanatory view showing the results of experiments on the types of tackifiers. Fig. 13 is an explanatory view showing a sample of the i-th agent used in another experiment on the type of the tackifier. [Fig. 14] shows other experiments on the type of tackifier. An illustration of the second dose of the sample used in the test. Fig. 15 is an explanatory view showing other experimental results regarding the type of the tackifier. Fig. 16 is an explanatory view showing a sample of the third dose used in the experiment on the type of carbonate. Fig. 17 is an explanatory view showing a second dose sample used in the experiment on the type of carbonate. Fig. 18 is an explanatory diagram showing the results of experiments on carbonate species. Fig. 19 is an explanatory view showing a first dose sample used in an experiment for improving the pH of the hair cosmetic used for dyeing, bleaching, or bleaching. Fig. 20 is an explanatory view showing a second dose sample used in an experiment for improving the pH of the hair cosmetic used for dyeing, bleaching, and bleaching. Fig. 21 is an explanatory view showing the results of an experiment for increasing the pH of the hair cosmetic used for dyeing, bleaching, and bleaching. Fig. 22 is a view showing an experimental result of the content of carbonate in the cosmetic material for hair which is used for dyeing, bleaching or decolorization for improving the degree of hair invention. -41 - 201233399. Fig. 23 is an explanatory view showing a first dose sample used in an experiment for reducing the pH of the hair cosmetic for use in dyeing for hairiness. Fig. 24 is an explanatory view showing a second dose sample used in the experiment for reducing the pH of the hair cosmetic for use in dyeing for hairiness. Fig. 25 is an explanatory view showing the results of an experiment for lowering the pH of the cosmetic for hair used for dyeing for the degree of hair invention. Fig. 26 is an explanatory view showing an experimental result of the content of carbonate in the cosmetic for hair used for dyeing for reducing the degree of hair invention. Fig. 27 is an explanatory view showing a first dose sample used in an experiment for a higher alcohol. Fig. 28 is an explanatory view showing a second dose sample used in an experiment for a higher alcohol. Fig. 29 is an explanatory diagram showing the results of experiments on higher alcohols. [Description of main component symbols] 1 〇 : Cosmetics for hair group 100 : Container for mixing 200 : Apparatus for mixing 300 : First dose 400 : 2nd! 1 -42-