TW201231602A - Optical adhesive resin composition, optical adhesive sheet using the composition and image display device - Google Patents

Optical adhesive resin composition, optical adhesive sheet using the composition and image display device Download PDF

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TW201231602A
TW201231602A TW100145743A TW100145743A TW201231602A TW 201231602 A TW201231602 A TW 201231602A TW 100145743 A TW100145743 A TW 100145743A TW 100145743 A TW100145743 A TW 100145743A TW 201231602 A TW201231602 A TW 201231602A
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Taiwan
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optical adhesive
mass
resin composition
image display
meth
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TW100145743A
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Chinese (zh)
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TWI534233B (en
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Tooru Takahashi
Hiromasa Kawai
Yoshinobu Ogawa
Katsuyoshi Sakamoto
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Hitachi Chemical Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate

Abstract

An optical adhesive resin composition and optical adhesive sheet formed by curing the optical adhesive resin composition as sheet are provided. The optical adhesive resin composition includes (A) (meth) acrylate polymer and (B) (meth) acrylate monomer, and is characterized by the acrylate polymer having the amide group. An optical adhesive resin composition and optical adhesive sheet using the composition suitable used for image display device are provided. The optical adhesive resin component has excellent transparency, has enough adhesion to the plastic front panel or touch panel, has necessary impact absorption for protecting the image display device, and has the necessary softness and handling property when manufacturing the image display device with the plastic front panel.

Description

201231602 六、發明說明： 【發明所屬之技術領域】 本發明是有關於-種適合作為影像顯示裝置的保 件等的光學用黏著材樹脂組成物、使用其的光學用黏著材 片及影像顯不裝置。 【先前技術】 —作為具有代表性的影像顯示裝置，可列舉液晶影像顯 示裝置（液日日顯示器（Liquid Crystal Display，LCD ))。液 晶影像顯示裝置具有包含液晶顯示單元、以及貼附於液= 顯示單元的兩外表面的偏光板等光學薄膜的液晶面板，^ 晶顯示單元是藉由在事先於表面形成有透明電極及像素圖 案等的具有約1 mm左右的厚度的一對玻璃基板之間，介 隔數μπι左右的間隙而填充液晶，然後進行密封來製作（液 晶面板）。以如此構成的液晶影像顯示裝置為代表的影像顯 示裝置是薄且容易受損的顯示用零件。因此，尤其於行動 電話、遊戲機、數位相機、車載零件等用途中，通常在影 像顯示裝置的前面介隔一定的空間而設置有透明的前面板 (保護面板）。 另外’於目前的大型的液晶影像液晶顯示裝置中，在 液晶面板的前面設置有偏光板。偏光板的表面實施了防眩 (Antiglare，AG)處理，藉由減少影像顯示裝置的前面的 光的反射來提昇可見度(visibility)。於大型的影像顯示裝置 的情況下，一般而言，為了提昇裝置的衝擊吸收性而不另 外設置前面板等構件，該些是以整個液晶面板及整個裝置 4 201231602 jpif 具有财衝擊性的方式構成。此種大型的液晶影像顯示裝置 的課題在於：因AG處理而導致影像看上去模糊；若觸碰 影像顯示裝置的表面’則液晶面板彎曲且影像紊亂；因AG 處理而導致表面的污垢難以掉落，另一方面，若強力擦拭， 則容易產生損傷。另外，可認為伴隨今後的液晶面板的大 型化，液晶面板本身的耐衝擊性下降，影像顯示裝置的耐 衝擊性會產生問題。 鑒於上述狀況，考慮在液晶面板的前面設置實施了抗 反射（Antirefledion，AR)處理的前面板，來謀求消除源 自AG處理的缺點。但是，當前面板與液晶面板之間存在 空氣’即職㈣時，可認為該㈣成以丨起光的散射的 原因，由此產生透過率的下降、由重像(gh〇st)所引起的畫 質的下降等。因此’提出有细樹脂等填埋前面板與液晶 面板之間的空間的技術（參照、專利文獻i、專利文獻2、專 利文獻3及專利文獻4)。 進而，近年來，開始於行動電話、遊戲機、數位相機、 車載零件、筆記翻人電腦、桌上型個人、個人電腦 二血視S等上搭截觸控面板。於此種液晶影像顯示裝置的 二：：’變成前面板(保護面板)、觸控面板及液晶面板以 =序積層而成的積層構造，在前面板（健面板）與觸 間、觸控面板與液晶面板之間存在—定的空間。 _因成為1起71的散射 由重像…λ! ί度或冗度、透過率下降，進而可能產生 重像所引起的畫質的下降。為了解決關題 201231602 ~r\J^U 々if 專填埋上述空間的技術亦重要。 然而，當將影像顯示裝置（顯示器）應用於電視機時， 根據優力國際安全認證有限公司（Underwrite Laboratcmes，UL)規格或電波取缔法f的規定，影像顯示 裝置於利關球落下㈣衝擊試驗時不能存在構件飛散、 或鋼，貫穿構件的情況。目前，於廣泛普及的玻璃製陰極 射線管（Cathode Ray Tube，CRT)中，為了滿足上述規格， 必需將玻璃板設計得較厚，而存在CRT整體的質量變重的 傾2。因此，作為不使玻璃板變厚，並對影像顯示裝置賦 予^散防止性的方法，提出有於玻璃板表面積層具有自我 修復性的合成樹脂保護薄膜的技術（參照專利文獻$及專 利文獻6 )。 另外’於近年來作為平板顯示器（Flat Panel Display， FPD )的一例而受到矚目的電漿顯示面板（Plasma Display Panel PDP )中’為了防止面板部的破損’在pDp前面（可 見面側）介隔1 mm〜5 mm左右的空間而設置有厚度為3 mm左右的玻璃等前面板。但是，伴隨PDP的大型化，前 面板的面積亦變大’故存在pDp整體的質量變重的傾向。 因此’為了防止影像顯示裝置（顯示器）的破損，提出有 將特定的樹脂積層於顯示器表面或將積層有特定的樹脂的 滤光器積層於顯示器表面的技術（參照專利文獻7、專利 文獻8、專歡獻9及專利文獻1〇)。 先前技術文獻 專利文獻 201231602 專利文獻1:日本專利特開平5 11239號 專利文獻2:日本專利特開平3_2觀6號 專利文獻3:日本專利_平6_59253號公報 專利文獻4 ·日本專利特開2〇〇4_125868號公 專利文獻5·日本專利特開平卜州仍號公報 專利文獻6:日本專利特開平6_333517號公報 專利文獻7 :日本專利特開2〇〇4_58376號公報 專利文獻8 :日本專利特開2〇〇5_1〇7199號公報 專利文獻9 :日本專利特開2〇〇4_263〇84號公報 專利文獻10 :日本專利特開2〇〇7_9115號公報 如上所述，報告有以保護影像顯示裝置為目的之各種 技術，但當將該些技術應用於大型的液晶影像顯示裝置 時，無法獲得可滿意的結果，而期望進一步的開發。尤其， 近年來自質量減輕及低成本化、良好的加工性的觀點出 兔，正研究將塑膠板用於前面板，但當使用塑膠製的前面 板時，其與玻璃製前面板相比，容易產生由溫度或濕度的 變化所引起的翹曲，因此容易產生剝離或氣泡等不良情 況。尤其’當前面板與影像顯示面板的密接力低時，容易 引起不良情況的產生’而要求與用以使前面板與影像顯示 面板密接的樹脂組成物之間具有高密接力。但是，於上迷 專利文獻所揭示的技術中’塑膠前面板與樹脂組成物的密 接性、或帶有塑膠前面板的影像顯示裝置的可靠性未必 分。 尤 【發明内容】 201231602^ 鑒於上述狀況，本發明的第1目的在於提供一種適合 於影像顯示裝置的用途的光學用黏著材樹脂組成物以及使 用其的光學用黏著材月，該光學用黏著材樹脂組成物的透 明性優異，對於塑膠前面板、觸控面板、影像顯示面板（液 晶面板、PDP面板、有機電致發光（Electroluminescence， EL)面板等）具有充分的密接力，具有保護影像顯示裝置 所需的衝擊吸收性，且具有製作帶有塑膠前面板的影像顯 示裝置時所需的柔軟性與處理性。另外，本發明的第2目 的在於提供一種適合於高溫可靠性或耐濕可靠性優異的影 像顯不裝置的用途的光學用黏著材樹脂組成物以及使用並 的光學用黏著材片。 〃 本發明為了解決上述課題而努力研究的結果，發現藉 由使用具有醯胺基的（曱基）丙烯酸酯聚合物，可解決上述 課題。本發明是基於上述發現而完成的發明。 、 不贫明提供 (1) 一種光學用黏著材樹脂組成物，其含有（Α) ，)丙稀酸S旨聚合物及⑻（甲基)丙稀酸s旨單體，其特徵 在於·該（甲基)丙稀酸g旨聚合物具有醯胺基； ⑺-種光學用黏著材片，其是將如上述⑴ 之光學用黏著材樹脂組成物硬化成片狀而成者； 述之=則顯稀置’其具有❹如上述（2)所 板上而二=:及將其他光學構件貼合於影像顯示面 ⑷-種祕顯示裝置，其包括影像顯示面板、觸控 8 201231602 面板、及前面板’且其是於影像顯示面板與觸控面板之間、 及觸控面板與如板之_至少—者巾具有由如上述⑴ 所述之，學用㈣材樹脂組成物、或如上述（2)所述之光 學用黏著材ϋ所形成的透明翻旨層而成者。 本發明的光學用黏著材樹脂組成物、作為1片狀硬化 物的光學用黏著材片因對於塑膠前面板的密接性高、且透 明性或衝擊吸錄優異，故可錄地祕影像顯示裝置及 影像顯示裝置用濾絲的用途。例如，當將本發明的光學 用黏著材樹脂喊物及黏著材片用作影像顯示裝置的透明 樹脂層時，可於影像顯示裝財實現優異的高溫可靠性、 而才濕可靠性及衝擊吸收性。 【實施方式】 本赉明的光學用黏著材樹脂組成物含有（Α)(曱基） 丙烯酸酯聚合物及（Β)(曱基)丙烯酸酯單體，其特徵在於： 該（曱基)丙烯酸酯聚合物具有醯胺基。 於本發明的光學用黏著材樹脂組成物中，如上述般將 具有特定結構的成分（Α)的聚合物與成為（Β)稀釋單體 的成分組合使用，藉此可提高相容性，尤其，藉由將構成 (Α)的聚合物的單體與（Β)稀釋單體設為相同的成分， 可提昇聚合物成分的溶解性。因此，即便於使用高分子量 的聚合物的情況下’亦可獲得透明性優異的樹脂組成物及 該些的硬化物。 另外’藉由製備並使用以比較高的濃度含有高分子量 的聚合物的樹脂組成物，即便膜厚較薄，亦可實現衝擊吸 201231602 收性優異的構件。 進而，於本發明的光學用黏著材樹脂組成物中，利 特疋的單體成分稀釋聚合物成分，藉此可不利用溶劑進 稀釋而使樹脂組成物成形，可容易地製作不易產生氣、包丁 且具有厚度的薄膜或片材。 ^ 以下，對構成本發明的光學用黏著材樹脂組成物的 (A)成分至（D)成分進行詳細說明。 (A)成分 本發明中所使用的（A)(曱基)丙烯酸酿聚合物的特徵 在於具有醯胺基。本發明中的醯胺基是以_c〇_nrr,來表示 結構式者’具體而言，可列舉R及R，分_立為氫原子或 貌基的情況、或者是，合二為—而形成環的結構的情 況。如此，藉由導人醯胺基，可提高黏著力與高溫可靠性， ^其對於塑膠前面板取得較高的效果。作為醯胺基，可列 ，祕胺基（必佩）、單絲_基、二絲醯胺基、 '成基醯絲、嗎琳紐結於麟㈣的基㈣為較佳者。 (Α)成分的（甲基)丙騎酯聚合物至少包含藉由塊狀 、溶《合、，特合及乳化聚合等先前公知的方法 fit具有1個（甲基)丙稀_聚合性不飽和鍵（（甲基） 7酿基）的單體的—種或兩種以上聚合而獲得的聚合 入，作為向（A)成分的（甲基)丙_®旨聚合物中導 丙嫌二，方法較佳為於製造⑷成分時，將（甲基） 物可石丨^化口物用作單體。作為（甲基)丙稀醯胺系化合 ㈠列牛.（甲基)丙稀醯胺、二甲基(甲基)丙稀酿胺、二 201231602 乙基（曱基）丙稀醯胺、異丙基（曱基）丙烯醯胺、羥乙基（曱 基)丙烯醯胺、（曱基)丙烯醯基嗎琳等。該些之中，較佳為 二乙基丙烯醯胺、異丙基丙烯醯胺、羥乙基丙烯醯胺及丙 稀醒基嗎琳’尤其’就可進一步抑制製成光學用黏著材片 日守的界邊性的觀點而言，更佳為丙烯醯基嗎琳。 藉由使用上述本發明的光學用黏著材樹脂組成物，當 製作薄膜或片材時可使其等顯現高黏著力。如上述般具有 黏著性的片材或薄膜構件可不使用接著劑而貼合於前面 板、觸控面板、影像顯示面板等光學構件的表面。 另外’（曱基）丙烯酿胺系化合物的比例以所使用的全 ，。單體化合物的質量為基準，較佳為設為3質量％〜3〇質 ，更佳為没為5質量％〜2〇質量％，特佳為設為7質 置％〜15質量％‘>若丙稀醯胺系化合物的比例為3質量％ 以上，則可獲得對於塑膠前面板的充分的黏著力，若為3〇 質量％以下，則貼合變得容易。 、再者’若根據（A)(甲基)丙烯酸醋聚合物的結構來敍 述，點，則是指較佳為源自側鏈上具有醯胺基的單體的結 構單元的含有比例於供聚合的全部單體中存在3質二 30質量％。 另外，若為可獲得本發明的效果的_，則亦 α下的聚合物，該聚合物是併时子内具有2個以 1烯酸的聚合性;飽和_其他單合物料單體化: ’並藉由該些化合物的共聚合而獲得的聚合物。° 另外，若為可獲得本發明的效果的範圍，則作為單體 11 201231602. =1=增基)丙雄酸酿單體化合物以外， 退向便用具有聚合性不飽和 些化合物共聚合而獲得的聚合物Γ他早體化5物，並使該 f 說明書_，（甲基)丙_是指_酸及 _。二:表 性，in (*=前面板或觸控面板等光學構件的黏著 予二===聚合物的分子内事先賦 t似fi、竣基、氛基、縮水甘油基等。該些極性基的 尸美^/Λ使具有極性基的單體化合物與（甲基)丙烯酸 1曰4(甲基)丙烯酸酯單體化合物共聚合而達成。藉由 向聚合物中導入經基等極性基，可使樹脂組成物具有^度 的極性，並防止吸濕時的白濁。 作為具有極性基的單體化合物，較佳為具有羥基的單 體化&物。具有羥基的單體化合物的比例並無特別限定， 以=使用的全部單體化合物的質量為基準，較佳為設為10 質罝％〜30質量％的比例。若該含量為10質量％以上，則 吸濕時不會發生白濁，另一方面，若為30質量％以下，則 吸濕時的尺寸變化不會變大，不會產生自應用部位露出、 或發生剝離等不良情況。 構成上述（Α)(甲基)丙烯酸酯聚合物的（甲基)丙缚酸 酿單體化合物包括丙烯酸及曱基丙烯酸、該些的衍生物。 作為分子内具有1個源自（甲基)丙烯酸的聚合性不飽和鍵 12 201231602 的單體化合物的具體例，可列舉：丙烯酸、曱基丙烯酸等 具有羧基的單體；（甲基）丙烯酸甲酯、（曱基）丙烯酸正丁 酯、（曱基）丙烯酸異丁酯、（曱基)丙烯酸2_乙基己酯、（曱 基）丙烯酸異壬酯、（曱基）丙烯酸正辛酯、（甲基）丙烯酸月 桂酉曰、（曱基)丙烯酸硬脂基酯等烷基的碳數為1〜18的（甲 基)丙烯酸烷基酯；（曱基)丙烯酸苄酯等芳烷基的碳數為7 =20的（曱基)丙稀酸芳烧基醋；（曱基)丙稀酸丁氧基乙醋 等烧氧基縣的碳數為2〜2G的（曱基)丙烯酸絲基烧基 ，，（甲基)丙稀酸N，N-二甲胺基乙醋等(單燒基或二烧基) 胺基烧基的總碳數為卜如的（甲基)丙烯酸胺基烧基醋； 一乙二醇乙醚的1〔甲基）丙烯酸酯、三乙二醇丁醚的（曱基） :烯酸酯、四乙二醇單曱醚的(甲基)丙烯酸酯、六乙二土醇 單甲越的（甲基)丙埽酸醋、八乙二醇的單甲峻（曱基)丙稀酸 酯、九乙二醇的單甲喊（甲基)丙稀酸醋、二丙二醇的單甲 喊(甲基)丙稀酸酯、七丙二醇的單甲趟(甲基)丙婦酸酿、四 乙二醇的單乙醚（甲基)丙婦酸酿等伸烷基鏈的碳數為1〜 10且末航細的碳數為的㈣二賴基鱗的 基)丙婦酸醋’·六乙二醇苯峻的(甲基)丙烯酸酯等伸燒乂 的碳數為1〜10且末端芳基_碳數為6〜2G的聚尸 芳細的（甲基)丙稀酸醋；（甲基)丙婦酸環己酯、（甲 環戊酯、(甲基)丙烯酸異莰酯、甲醛加成環癸; (甲基)丙稀義等具有脂環結構的總碳數為4〜 = 丙稀π基)丙烯酸十七氟御旨等總碳數為 (曱基)丙稀酸氣化烧基醋；（甲基)丙烯酸2_經基乙酿、（甲 201231602 基）丙稀酸3-經基丙g旨、（曱基）丙稀酸4_經基丁醋、三乙二 醇的單（曱基)丙烯酸酯、四乙二醇單（甲基)丙烯酸酯、六乙 二醇單（曱基)丙烯酸酯、八丙二醇單（甲基)丙烯酸酯、丙三 醇的單或二（曱基）丙烯酸酯等具有羥基的（曱基）丙烯酸 酯；（甲基）丙烯酸縮水甘油酯等具有縮水甘油基的（曱基） 丙烯酸酯；四乙二醇單（曱基）丙烯酸酯、六乙二醇單（曱基） 丙烯酸酯、八丙二醇單（曱基）丙烯酸酯等伸烷基鏈的碳數 為1〜10的聚乙二醇單（甲基)丙稀酸酯；（曱基)丙熵酿胺、 N，N-一曱基（曱基)丙烯醯胺、N_異丙基（曱基）丙烯醯胺、2_ 經乙基（甲基）丙烯醯胺、丙烯醯基嗎琳等（曱基）丙浠醯胺 等。 上述單體化合物之中，就為了顯現衝擊吸收性而降低 玻璃轉移溫度、降低皮膚刺激性、及材料比較廉價等的觀 點而β，較佳為烧基的碳數為4〜18的（甲基)丙婦酸院基 酉曰。另外，更佳為除該些以外，進而併用分子内具有羥基 的（曱基）丙烯酸酯。 於本發明中’上述（曱基）丙烯酸烷基酯的含有比例以 所使用的全部單體化合物的質量為基準，較佳為55質量％ 〜83質量％。若該含量為55質量％以上，則於可降低玻璃 轉移=這—點上有利，另—方面，若為83質量％以下， 則於提高接著力這—點祕持賴時的透明性這 一點上有 利。就以上的觀點而言，更佳的含量為55質量％〜7〇質 量％。 虽將分子内具有2個以上（曱基)丙烯醯基的單體化合 201231602 4uyi^pif 物、與1分子内具有1個上述（曱基)丙稀酸的聚合性不飽 和鍵（（曱基）丙烯醯基）的單體併用時，化合物只要分子 内具有2個以上有助於聚合反應的（甲基)丙烯酸的不飽和 鍵部位即可，並無㈣限定。作為此種單體化合物的具體 例，可列舉：1，4-丁二醇二（曱基)丙烯酸酯、i ，6-己二醇二（曱 f)丙烯酸酯、1，9-壬二醇二（甲基）丙烯酸酯等伸烷基鏈的 碳數為1〜20的烷二醇二（曱基)丙烯酸酯；聚乙二醇二（甲 基)丙烯酸S旨、聚丙二醇二(曱基)丙烯酸醋等伸絲鏈的碳 數為1〜20的聚烧二醇二（曱基)丙烯酸醋；三經曱基丙烷 三（曱基）丙烯酸酯、環氧乙烷加成三羥曱基丙烷三（曱基) 丙烯酸S旨等總碳數為10〜6G的三（曱基)丙烯酸醋；環氧乙 烷加成季戊四醇四（曱基)丙烯酸酯、二-三羥甲基丙烷四（曱 基）丙烯酸酯、季戊四醇四（甲基）丙烯酸酯等總碳數為10 〜100的四（甲基)丙稀酉复酿；二季戊四醇六（甲基)丙稀酸醋 等。 〇〇於過剩地使用分子内具有2個以上聚合性不飽和鍵的 單體化合物的情況下，當藉由該些化合物的聚合來合成（曱 基)丙，酸系衍生物聚合物時，膠化會進行。因此，當併用 上述單體化合物時，其比例以用作聚合物的構成原料的單 體化合物的總質量為基準，較佳為設為0.3質量％以下。 於本發明中可於製備（A)成分的聚合物時與上述（曱 基）丙烯酸酯單體化合物併用的其他單體化合物只要是分 子内八有（曱基)丙稀酿基以外的聚合性不飽和鍵的化合物 即可，並無特別限定。作為具體例，可列舉：丙烯腈、苯 15 201231602 jpif 乙稀、乙酸乙烯酉旨、乙稀、丙婦等具有$合性碳_碳不飽和 雙鍵的聚合性化合物。 =為本發明的（A )(曱基)丙稀酸醋聚合物成分的較佳 的形態，可列舉使（丨）烷基的碳數為4〜18的（曱基）丙烯 酸烧基S旨:（u)含經基的（甲基）丙稀酸醋及㈤）（甲基) 丙稀醯胺系化合物共聚合而獲得者。作為各單體的含量， 如上所述，以所使用的全部單體化合物的質量為基準，較 佳為（1)成分55質量％〜83質量％、（ii)成分1〇質量％ 〜30質量％及（出）成分7質量％〜15質量％，且較佳為 使用使該些成分共聚合而獲得的（A)成分。 … 尤其，作為本發明的較佳的一實施形態，可列舉併用 丙稀酸2_乙基己醋、丙婦g变2_經基乙醋及丙婦酿基嗎琳， 且將該些的共聚合物用作⑷（甲基)丙贼醋聚合 的情況。 藉由上述各種單體化合物的聚合而獲得的曱基) 丙烯酸酯聚合物的重量平均分子量較佳為8〇〇,〇〇〇1 3,000,0GG ’ 更佳 & 80〇,〇〇〇 〜2，咖，()()(），進而更佳為 1，000,000〜2,000,000。若聚合物成分的重量平均分子量為 800,000以上，則於受到衝擊時樹脂層不會裂開或變形， 可獲得充分的尚溫可靠性。另一方面，若重量平均分子量 為3,000,000訂’則黏度不會變得過高，於溶融樹脂的 送液時無需高壓力，而可容易地送液。另外，氣泡容易脫 離，硬化物中不會殘存氣泡。再者，本說明書中所記載的 重里平均为子里」疋指藉由凝膠參透層析法並利用標準 201231602 HUyJDTpif 聚苯乙稀的校準曲線進行測定所獲得的值。 本發明的光學用勒著村樹脂組成物中的 :=\合:1 含量相對於上述(A)成分、(B) S 及（C)成刀的總含量，較佳為1〇質量％〜6〇 圍，更佳為10質量％〜4〇質量％的範圍 、 問通’可b光學用樹脂材料的充分的衝擊吸收性。另外， 硬化收縮不會變得過大，可獲騎製作 卜 的充分的平坦性。另—方面，若含量為60質才量=的： 樹脂^物的黏度不會變得過高，容易製作片材。 成分 、 本發明中所使用的（Β)(曱基)丙婦 軸旨單體，作= _ 4()成分的說明中所例示的化合物相 _料:：=:=== ⑷成分的單 於構成⑻成分咐麵酸：趙:¾ 相等。所謂該聚合比率與含有比率大致 率的差以將各自的總含量 為成刀，較佳為當⑷（〒基)丙稀酸酯聚合物 17 201231602201231602 VI. [Technical Field] The present invention relates to an optical adhesive resin composition suitable for use as a security device for an image display device, an optical adhesive sheet using the same, and an image display. Device. [Prior Art] - As a representative image display device, a liquid crystal image display device (Liquid Crystal Display (LCD)) can be cited. The liquid crystal display device has a liquid crystal panel including a liquid crystal display unit and an optical film attached to a polarizing plate on both outer surfaces of the liquid=display unit, and the crystal display unit is formed by previously forming a transparent electrode and a pixel pattern on the surface. A pair of glass substrates having a thickness of about 1 mm or so are filled with a liquid crystal with a gap of about several μm, and then sealed to produce a liquid crystal panel. An image display device typified by a liquid crystal image display device having such a configuration is a thin display member that is easily damaged. Therefore, in particular, in applications such as mobile phones, game machines, digital cameras, and car parts, a transparent front panel (protective panel) is usually provided in a space between the front surface of the image display device. Further, in the conventional large-sized liquid crystal image display device, a polarizing plate is provided on the front surface of the liquid crystal panel. The surface of the polarizing plate is subjected to an anti-glare (AG) treatment to improve visibility by reducing reflection of light in front of the image display device. In the case of a large-sized image display device, in general, in order to improve the shock absorption of the device, a front panel or the like is not separately provided, and the whole liquid crystal panel and the entire device 4 201231602 jpif are financially impactful. . The problem of such a large-sized liquid crystal image display device is that the image appears blurred due to the AG processing; if the surface of the image display device is touched, the liquid crystal panel is curved and the image is disordered; the dirt on the surface is difficult to fall due to the AG processing. On the other hand, if it is strongly wiped, damage is likely to occur. In addition, it is considered that the impact resistance of the liquid crystal panel itself is lowered with the increase in the size of the liquid crystal panel in the future, and the impact resistance of the image display device is problematic. In view of the above situation, it is conceivable to provide a front panel to which an anti-reflection (AR) process is applied to the front surface of the liquid crystal panel, thereby eliminating the disadvantage of the source-AG processing. However, when there is air between the current panel and the liquid crystal panel, it can be considered that the (four) is caused by the scattering of the light, thereby causing a decrease in the transmittance and caused by the ghost image (gh〇st). The decline in image quality, etc. Therefore, there has been proposed a technique of filling a space between a front panel and a liquid crystal panel such as a fine resin (see, Patent Document 1, Patent Document 2, Patent Document 3, and Patent Document 4). Further, in recent years, touch panels have been set up in mobile phones, game machines, digital cameras, car parts, notebook-turning computers, desktop personal computers, personal computers, and blood-visual S. In the liquid crystal image display device, the second layer of the liquid crystal image display device is formed into a front panel (protective panel), a touch panel, and a liquid crystal panel in a stacking structure. The front panel (the health panel) and the touch panel and the touch panel are formed. There is a certain space between the liquid crystal panel and the liquid crystal panel. _Because of the scattering of 1 from 71, the image is reduced due to the re-image... λ! ί degree or redundancy, and the transmittance is lowered. In order to solve the problem, 201231602 ~r\J^U 々if is also important to fill in the above space. However, when the image display device (display) is applied to a television set, the image display device falls under the Lee Ball (four) impact test according to the Underwrite Laboratcmes (UL) specification or the radio wave banning method f. There must be no scattering of components, or steel, through the components. At present, in a glass cathode ray tube (CRT) widely used, in order to satisfy the above specifications, it is necessary to design a glass plate to be thick, and there is a tendency to increase the mass of the entire CRT. For this reason, a technique of providing a synthetic resin protective film having a self-healing property on a surface area of a glass plate has been proposed as a method of providing a film-protecting film to a surface of a glass plate without reducing the thickness of the glass plate (see Patent Document No. and Patent Document 6). ). In addition, in the plasma display panel (PDP) which has been attracting attention as an example of a flat panel display (FPD) in recent years, 'in order to prevent damage of the panel portion' is interposed in front of the pDp (visible side). A front panel such as glass having a thickness of about 3 mm is provided in a space of about 1 mm to 5 mm. However, as the size of the PDP increases, the area of the front panel also increases. Therefore, the mass of the entire pDp tends to become heavier. Therefore, in order to prevent the image display device (display) from being damaged, a technique of laminating a specific resin on the surface of the display or stacking a filter having a specific resin on the surface of the display has been proposed (see Patent Document 7, Patent Document 8, Special offer 9 and patent documents 1〇). PRIOR ART DOCUMENT Patent Document No. 201231602 Patent Document 1: Japanese Patent Laid-Open No. Hei No. Hei No. Hei No. Hei No. Hei No. Hei No. Hei No. Hei No. Hei No. Hei No. Hei No. Hei No. Hei. Japanese Patent Laid-Open Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. Patent Document 9: Japanese Patent Laid-Open Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. Various techniques of the purpose, but when these techniques are applied to a large-sized liquid crystal image display device, satisfactory results cannot be obtained, and further development is desired. In particular, in recent years, rabbits are studying the use of plastic sheets for the front panel from the viewpoint of quality reduction, cost reduction, and good processability. However, when using a plastic front panel, it is easier than a glass front panel. Warpage caused by changes in temperature or humidity occurs, and thus defects such as peeling or bubbles are likely to occur. In particular, when the adhesion between the current panel and the image display panel is low, it is likely to cause a problem of occurrence, and a high adhesion force is required between the resin composition for bringing the front panel into close contact with the image display panel. However, in the technique disclosed in the above patent document, the adhesion of the plastic front panel to the resin composition or the reliability of the image display device with the plastic front panel is not necessarily the same. In view of the above, a first object of the present invention is to provide an optical adhesive resin composition suitable for use in an image display device, and an optical adhesive material using the same, which is an optical adhesive material. The resin composition is excellent in transparency, and has sufficient adhesion to a plastic front panel, a touch panel, an image display panel (a liquid crystal panel, a PDP panel, an organic electroluminescence (EL) panel, etc.), and has a protective image display device. The required impact absorption and the flexibility and handleability required to produce an image display device with a plastic front panel. Further, a second object of the present invention is to provide an optical adhesive resin composition suitable for use in an image display device excellent in high-temperature reliability or moisture-resistant reliability, and an optical adhesive sheet for use. In order to solve the above problems, the present inventors have found that the above problems can be solved by using a (fluorenyl) acrylate polymer having a mercapto group. The present invention is an invention completed based on the above findings. (1) An optical adhesive resin composition comprising (Α), an acrylic acid S polymer, and (8) a (meth) acrylic acid s monomer, characterized in that (meth)acrylic acid g-polymer has a mercaptoamine group; (7) an optical adhesive sheet which is obtained by curing the optical adhesive resin composition of the above (1) into a sheet form; Then, it has a thinner display, such as the above (2) on the board and two =: and the other optical member is attached to the image display surface (4) - the secret display device, which includes the image display panel, the touch 8 201231602 panel, And the front panel 'and between the image display panel and the touch panel, and the touch panel and the at least one of the panels have a resin composition as described in (1) above, The transparent adhesive layer formed of the optical adhesive material according to the above (2) is a laminate. The optical adhesive resin composition of the present invention and the optical adhesive sheet which is a one-piece cured product have high adhesion to the plastic front panel, and are excellent in transparency or impact absorption, so that the image display device can be recorded. And the use of filter screens for image display devices. For example, when the optical adhesive resin and the adhesive sheet of the present invention are used as a transparent resin layer of an image display device, excellent high-temperature reliability, wet reliability, and impact absorption can be achieved in image display loading. Sex. [Embodiment] The optical adhesive resin composition of the present invention comprises a (fluorene) (fluorenyl) acrylate polymer and a (fluorene) (meth) acrylate monomer, characterized in that the (fluorenyl) acrylate The ester polymer has a guanamine group. In the optical adhesive resin composition of the present invention, as described above, a polymer having a specific structure (Α) is used in combination with a component which is a diluent monomer, whereby compatibility can be improved, in particular The solubility of the polymer component can be improved by setting the monomer constituting the (Α) polymer to the same component as the (Β) diluted monomer. Therefore, even when a high molecular weight polymer is used, a resin composition excellent in transparency and a cured product can be obtained. Further, by preparing and using a resin composition containing a polymer having a high molecular weight at a relatively high concentration, even if the film thickness is thin, it is possible to realize a member excellent in impact absorption 201231602. Further, in the optical adhesive resin composition of the present invention, the monomer component of the rituximab is diluted with the polymer component, whereby the resin composition can be molded without diluting with a solvent, and it is easy to produce a gas and a package. And a film or sheet having a thickness. In the following, the components (A) to (D) constituting the optical adhesive resin composition of the present invention will be described in detail. (A) Component The (A) (fluorenyl) acrylic styrene polymer used in the present invention is characterized by having a guanamine group. The guanamine group in the present invention is a structure represented by _c〇_nrr, and specifically, R and R may be enumerated, and a hydrogen atom or a topographical group may be used, or a combination may be And the case of forming a ring structure. Thus, by guiding the amine group, the adhesion and high temperature reliability can be improved, and the effect on the plastic front panel is obtained. As the guanamine group, it is preferred that the group of the amine group (Si), the monofilament-based group, the bis-decylamine group, the 'base group ruthenium group, and the lining knot is in the base (four). The (meth) cyanoacrylate polymer of the (Α) component contains at least one (meth) propylene-polymerizable property by a previously known method such as blocking, merging, special combination, and emulsion polymerization. Polymerization obtained by polymerization of a monomer of a saturated bond ((meth) 7-branched group) or two or more kinds of polymers, as a (methyl) propyl-based polymer of (A) component Preferably, the method (meth) is used as a monomer in the case of producing the component (4). As a (meth) acrylamide compound (I), ox. (meth) acrylamide, dimethyl (meth) acrylamide, two 201231602 ethyl (mercapto) acrylamide, different Propyl (mercapto) acrylamide, hydroxyethyl (decyl) acrylamide, (fluorenyl) propylene hydrazinyl, and the like. Among these, diethyl acrylamide, isopropyl acrylamide, hydroxyethyl acrylamide, and propyl carbaryl can be further suppressed to form an optical adhesive sheet. From the point of view of the boundary, it is better to be acrylonitrile. By using the above-mentioned optical adhesive resin composition of the present invention, when a film or sheet is produced, it can be made to exhibit high adhesion. The sheet or film member having adhesiveness as described above can be bonded to the surface of an optical member such as a front panel, a touch panel, or an image display panel without using an adhesive. In addition, the ratio of the '(mercapto) acrylamide compound is the total used. The mass of the monomer compound is preferably 3% by mass to 3 Å, more preferably 5% by mass to 2% by mass, and particularly preferably 7% by mass to 15% by mass. When the ratio of the acrylamide-based compound is 3% by mass or more, sufficient adhesion to the plastic front panel can be obtained, and if it is 3% by mass or less, the bonding becomes easy. Further, if it is described in terms of the structure of the (A) (meth)acrylic acid vinegar polymer, the point is preferably a ratio of the structural unit derived from a monomer having a mercapto group on the side chain. There were three masses and 30% by mass in all the monomers polymerized. Further, in the case of _ which can obtain the effect of the present invention, it is also a polymer under α which has two polymerizable properties with an enoic acid in a merging; saturation _ other monomer materials are singulated: 'and a polymer obtained by copolymerization of these compounds. In addition, in the range of the effect of the present invention, as a monomer 11 201231602. =1 = an agglomerate, a propionic acid styling monomer compound is used, and a repellent is copolymerized with a polymerizable unsaturated compound. The obtained polymer is used to pre-form the 5, and the f-form, _, (meth) propyl _ refers to _ acid and _. 2: phenotypic, in (* = adhesion of optical components such as front panel or touch panel to the second === the molecular weight of the polymer is pre-defined as fi, thiol, aryl, glycidyl, etc. The corpse of the base is obtained by copolymerizing a monomer compound having a polar group with a 1 曰 4 (meth) acrylate monomer compound (meth) acrylate. By introducing a polar group such as a base into the polymer The resin composition can have a polarity of a degree and prevent clouding during moisture absorption. As a monomer compound having a polar group, a monomeric compound having a hydroxyl group is preferred. A ratio of a monomer compound having a hydroxyl group. It is not particularly limited, and is preferably a ratio of 10% by mass to 30% by mass based on the mass of all the monomer compounds used. If the content is 10% by mass or more, moisture absorption does not occur. On the other hand, when it is 30% by mass or less, the dimensional change during moisture absorption does not become large, and there is no problem such as exposure from the application site or peeling. The above (Α) (meth)acrylic acid is formed. (meth)acrylic acid monomeric compound of ester polymer Acrylic acid and mercaptoacrylic acid, and derivatives thereof. Specific examples of the monomer compound having one polymerizable unsaturated bond 12 201231602 derived from (meth)acrylic acid in the molecule include acrylic acid and mercaptoacrylic acid. a monomer having a carboxyl group; methyl (meth)acrylate, n-butyl (meth)acrylate, isobutyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, (mercapto)acrylic acid An alkyl (meth)acrylate having an alkyl group having 1 to 18 carbon atoms such as isodecyl ester, n-octyl (meth) acrylate, lauryl (meth) acrylate or stearyl methacrylate (曱) benzyl acrylate such as aralkyl has a carbon number of 7 = 20 (mercapto) acrylic acid aryl vinegar; (mercapto) acrylic acid butoxy acetoacetate (曱)acrylic acid alkyl group having a carbon number of 2 to 2 G, N,N-dimethylaminoethyl acetonate (meth) acrylate, etc. (monoalkyl or dialkyl) amine group The total carbon number is ruthenium (meth) acrylate methacrylate; 1 ethylene glycol ether 1 [meth) acrylate, triethylene glycol butyl ether (mercapto) : (meth) acrylate of ethyl acrylate, tetraethylene glycol monoterpene ether, (meth) propionate vinegar of hexaethylene sulphate monomethyl methacrylate, singular sulphur of octaethylene glycol Acrylate, pentaethylene glycol monomethyl (meth) acrylate vinegar, dipropylene glycol monomethyl (meth) acrylate, heptapropane diol monomethyl hydrazine (methyl) propylene glycol Styrene, tetraethylene glycol monoethyl ether (methyl) propylene glycolic acid, etc. The alkyl chain has a carbon number of 1 to 10 and the carbon number of the terminal is a (four) lysine base) '························································ Vinegar; (methyl) propyl cyclohexanate, (methylcyclopentyl ester, isodecyl (meth) acrylate, formaldehyde addition oxime; (methyl) propyl equivalent, etc., total carbon number with alicyclic structure The total carbon number of the tetradecyl acrylate is 4~ = propylene π-based, and the total carbon number is (mercapto) acrylic acid vaporized vinegar; (meth)acrylic acid 2 _ base acetyl, (A 201231602 base) Acrylic acid 3-carbyl group, (mercapto) acrylic acid 4_ butyl acetonide, triethylene glycol mono (曱Acrylate, tetraethylene glycol mono(meth)acrylate, hexaethylene glycol mono(indenyl)acrylate, octapropylene glycol mono(meth)acrylate, glycerol mono or di(indenyl)acrylic acid (mercapto) acrylate having a hydroxyl group such as an ester; (mercapto) acrylate having a glycidyl group such as glycidyl (meth)acrylate; tetraethylene glycol mono(decyl) acrylate or hexaethylene glycol alone (mercapto) acrylate, propylene glycol mono(indenyl) acrylate, etc., alkyl group having a carbon number of 1 to 10, polyethylene glycol mono(methyl) acrylate; Amine, N,N-monodecyl (fluorenyl) acrylamide, N-isopropyl (decyl) acrylamide, 2_ethyl (meth) acrylamide, propylene hydrazine, etc. Base) propionamide and the like. Among the above-mentioned monomer compounds, in order to exhibit impact absorption, the glass transition temperature is lowered, the skin irritation is lowered, and the material is relatively inexpensive, and β is preferable. The carbon number of the alkyl group is preferably 4 to 18 (methyl group). ) B. Further, it is more preferable to use a (fluorenyl) acrylate having a hydroxyl group in the molecule in addition to the above. In the present invention, the content ratio of the above (indenyl)alkyl acrylate is preferably from 55% by mass to 83% by mass based on the mass of all the monomer compounds used. When the content is 55% by mass or more, it is advantageous in that it can reduce the glass transition = this point, and if it is 83% by mass or less, the transparency at the time of improving the adhesion force is improved. It is beneficial. From the above viewpoints, a more preferable content is 55% by mass to 7% by mass. A monomer having two or more (fluorenyl) acrylonitrile groups in the molecule is compounded into a 201231602 4uyi^pif substance, and a polymerizable unsaturated bond having one of the above (mercapto)acrylic acids in one molecule ((anthraceyl group) When the monomers of the acrylonitrile group are used in combination, the compound may have two or more unsaturated bond sites of (meth)acrylic acid which contribute to the polymerization reaction, and is not limited to (four). Specific examples of such a monomer compound include 1,4-butanediol di(indenyl)acrylate, i,6-hexanediol di(曱f)acrylate, and 1,9-nonanediol. An alkanediol bis(indenyl) acrylate having a carbon number of from 1 to 20, such as a di(meth)acrylate; an ethylene glycol di(meth)acrylic acid, a poly(propylene glycol) a polyalkylene glycol bis(indenyl)acrylic acid vinegar having a carbon number of 1 to 20, such as an acrylic vinegar or the like; a tris-propyl propane tris(mercapto) acrylate, an ethylene oxide addition trishydroxyl decyl group; Propane tris(fluorenyl) acrylic acid S is a tris(fluorenyl)acrylic acid vinegar having a total carbon number of 10 to 6 G; ethylene oxide addition pentaerythritol tetrakis(yl) acrylate, di-trimethylolpropane tetra (曱-) acrylate, pentaerythritol tetra(meth) acrylate, tetrakis(methyl) propylene oxime with a total carbon number of 10 to 100; dipentaerythritol hexa(methyl) acrylate vinegar. In the case where a monomer compound having two or more polymerizable unsaturated bonds in a molecule is excessively used, when a compound of a compound is synthesized by polymerization of the compound, an acid derivative polymer is used as a gel. The meeting will take place. Therefore, when the above monomer compound is used in combination, the ratio thereof is preferably 0.3% by mass or less based on the total mass of the monomer compound used as a constituent material of the polymer. In the present invention, other monomer compounds which are used in combination with the above (mercapto) acrylate monomer compound in the preparation of the polymer of the component (A) may be polymerized other than the intramolecular octyl aryl group. The compound having an unsaturated bond is not particularly limited. Specific examples thereof include a polymerizable compound having a conjugated carbon-carbon unsaturated double bond such as acrylonitrile, benzene 15 201231602 jpif ethylene, vinyl acetate, ethylene or propylene. = a preferred form of the (A) (fluorenyl) acrylate vinegar polymer component of the present invention, and a (fluorenyl) acrylonitrile group having a carbon number of 4 to 18 in the (丨) alkyl group is used. : (u) obtained by copolymerization of a (meth)acrylic acid vinegar containing a trans group and (5) a (meth) acrylamide compound. As described above, the content of each monomer is preferably from 55 mass% to 83 mass% of the component (1), and (ii) the mass of the component is from 1 mass% to 30 mass% based on the mass of all the monomer compounds to be used. The % and (out) components are 7 mass% to 15 mass%, and it is preferred to use the component (A) obtained by copolymerizing the components. In particular, as a preferred embodiment of the present invention, a combination of 2 - ethyl hexanoic acid acrylate, propylene glucosin 2 - ethyl acetoacetate and propyl ketone can be mentioned, and The copolymer was used as the case of (4) (meth)propionic vinegar polymerization. The weight average molecular weight of the mercapto) acrylate polymer obtained by the polymerization of the above various monomer compounds is preferably 8 Å, 〇〇〇1 3,000, 0 GG 'better & 80 〇, 〇〇〇 〜 2 , coffee, () () (), and further preferably 1,000,000 ~ 2,000,000. When the weight average molecular weight of the polymer component is 800,000 or more, the resin layer is not cracked or deformed upon impact, and sufficient temperature reliability can be obtained. On the other hand, if the weight average molecular weight is 3,000,000, the viscosity does not become too high, and high pressure is not required at the time of liquid supply of the molten resin, and liquid can be easily fed. Further, the bubbles are easily separated, and no bubbles remain in the cured product. Further, the average of the weights referred to in the present specification is a value obtained by gel permeation chromatography and using a calibration curve of the standard 201231602 HUyJDTpif polystyrene. In the optical resin composition of the present invention, the content of the compound: =\:1 is preferably 1% by mass based on the total content of the components (A), (B) S and (C). 6〇 circumference, more preferably in the range of 10% by mass to 4% by mass, and sufficient impact absorbability of the resin material for the b-b optical. In addition, the hardening shrinkage does not become too large, and the flatness of the ride can be obtained. On the other hand, if the content is 60 mass = the viscosity of the resin does not become too high, and it is easy to produce a sheet. The component, the (Β) (indenyl) propylene-based monomer used in the present invention, the compound phase exemplified in the description of the _ 4 () component::===== (4) In the composition of (8) ingredients, face acid: Zhao: 3⁄4 is equal. The difference between the polymerization ratio and the content ratio is such that the total content of each is a knife, preferably when (4) (fluorenyl) acrylate polymer 17 201231602

Jpif 是使（i)烷基的碳數為4〜18的（曱基)丙烯酸烷基酯、（ii) 含經基的（曱基)丙烯酸酯及（出）（曱基)丙稀醯胺系化合物 共聚合而獲得者時’（B)(曱基)丙烯酸酯單體是含有 烧基的碳數為4〜18 &(甲基)丙稀酸烧基酿、（ii)含經基 的（甲基)丙烯酸醋及（出）（甲基)丙烯醯胺系化合物者。 例如作為調配比例，較佳為(曱基)丙烯酸酯聚合 ^及（巧（甲基)丙烯酸醋單體均為⑴（甲基)丙烯酸烧基 ^5。/質置％〜83質量％、（幻含經基的（甲基)丙烯酸醋10 ^ 30質量％及（iii)(甲基)丙烯醯胺系化合物7質量 ° 質量％的共聚合物或調配物。 基)^WA) 甲 含量的比*早體的上述（ι〜m)的各成分的相對於總 述（i)〜;< ·、.與構成（B)成分的（曱基)丙烯酸酯單體的上 相等。〜（出）的各成分的相對於總含量的含有比率大致 含詈2明的光學用黏著材樹敝成物巾的⑻成分的 成分及的光學轉著樹驗成物的主成分包含⑷ %^60 成分的情況下，較佳為⑷成分為10質量 述的’⑻成分為4〇%〜90%，另外，於添加後 成分及〔ri聯材的情況下，相對於上述⑷成分、⑻ 量％ , 成分的總含量，較佳為39.9 f量％〜89·9質 成分的it50質量Γ89.9質量％的範圍。若上述⑻ 變得過古〔39.9 f 1%以上，則樹脂組成物的黏度不會 门夺易製作片材或薄膜。另一方面，若含量為9〇 201231602 質里:::斤製作的片材或薄膜的機械特性變得p好。 及二 上述二 飽和鍵的交聯材。藉由人右六(二）八有2個以上聚合性不 脂組成物形成薄^二二別’自該光學用黏著材樹 ，成桃時的相的機械特性變得良好。 西旨單==入成分’只要是具有2個以上與（甲基)丙稀酸 -曰早體進外合反朗不麵鍵者 :;自:r甲基)丙_基、乙縣、== 基專自由基聚合性基，但較佳為（甲基)_酿基。 j乍，二有2個以上(曱基)丙烯酉藍基的交聯材，可列舉： :丁一醇—（曱基)丙烯酸酉旨、^己二醇二（甲基)丙稀酸 ，.、i，9-壬二醇二（曱基)丙烯酸酯等烷二醇二（曱基)丙烯酸 聚乙二醇二（甲基)丙烯酸酯、聚丙二醇二（曱基)丙烯酸 酉曰等聚烷二醇二（曱基）丙烯酸酯；三羥曱基丙烷三（曱基） ，烯酸酯、環氧乙烷加成三羥曱基丙烷三（曱基)丙烯酸酯 等二（甲基)丙烯酸酯；環氧乙烷加成季戊四醇四（曱基)丙烯 酸酯、二三羥曱基丙烷四（曱基)丙烯酸酯、季戊四醇四（曱 基）丙烯酸酯等四（曱基)丙烯酸酯；二季戊四醇六（曱基）丙 稀酸醋等。 另外，亦可列舉如由以下所示的通式（a)〜通式（g) 所表示的化合物， 可列舉由下述通式（a): [化1] 19 201231602 jpif CHt II , N 0Jpif is an alkyl (meth) acrylate having (i) an alkyl group having a carbon number of 4 to 18, (ii) a mercapto group-containing (mercapto) acrylate, and (out) (fluorenyl) acrylamide When the compound is copolymerized to obtain a '(B) (fluorenyl) acrylate monomer, the carbon number of the alkyl group is 4 to 18 & (meth) acrylic acid, and (ii) (Meth)acrylic acid vinegar and (out) (meth)acrylamide compound. For example, as a blending ratio, it is preferred that (mercapto) acrylate polymerization and (a) (meth)acrylic acid vinegar monomer are (1) (meth)acrylic acid group ^5. / mass%% to 83% by mass, ( a copolymer or a compound of (iii) (meth) acrylamide compound 7 mass % by mass. base) ^WA) The components of the above (ι~m) of the *precursor are the same as those of the (mercapto) acrylate monomer constituting the component (B) with respect to the general description (i) to; The component of the component (8) and the component of the optically-rotating tree test of the optical adhesive material of the optical adhesive material of the component of the optical component of the optical component of the optical component of the component of the component (b) In the case of the ^60 component, it is preferred that the component (4) is 10% by mass, and the component (8) is 4% to 90%, and in the case of the component after the addition and the component of the ri, the component (4) is compared with the component (4). The amount % and the total content of the components are preferably in the range of 39.9 f-% to 89.9% of the on50 mass Γ 89.9 mass% of the mass component. If the above (8) becomes too old [39.9 f 1% or more, the viscosity of the resin composition is not easy to produce a sheet or a film. On the other hand, if the content is 9〇 201231602, the mechanical properties of the sheet or film made by the pound are good. And two crosslinked materials of the above two saturated bonds. By the right six (two) eight, there are two or more polymerizable non-fat compositions, and the optical properties of the phase are improved. Western purpose single == into the component 'as long as it has more than two (meth) acrylic acid - 曰 early body into the external combination of anti-language key:; from: r methyl) propyl _ base, B county, == The radical is a radical polymerizable group, but is preferably a (meth) group. j乍, two or more (fluorenyl) propylene indigo-based crosslinked materials, which may be exemplified by: butanol-(mercapto)acrylic acid, hexanediol di(meth)acrylic acid, ., i, 9-nonanediol di(indenyl) acrylate and other alkanediol bis(indenyl)acrylic acid polyethylene glycol di(meth)acrylate, polypropylene glycol bis(indenyl)acrylic acid, etc. Alkylene glycol bis(indenyl) acrylate; tris(hydroxy)propane tris(fluorenyl), enoate, ethylene oxide addition trihydroxymercaptopropane tris(decyl) acrylate, etc. Acrylate; ethylene oxide addition pentaerythritol tetrakis(meth) acrylate, ditrihydroxyhydrin propane tetrakis(meth) acrylate, pentaerythritol tetrakis(meth) acrylate, etc.; Pentaerythritol hexa(indenyl) acrylate vinegar and the like. In addition, examples of the compound represented by the following formula (a) to formula (g) include the following formula (a): [Chemical Formula 1] 19 201231602 jpif CHt II , N 0

0-{R- ，· («) (式U)巾’R表示伸乙基或伸丙基，m&n分別猶 =地表：1〜20的整數)所表示的雙酚A的環氧烷加成彩 的-丙烯W旨化合物、將該些化合物的_酿基換遵 丙烯醯基的化合物； 由通式（b): [化2]0-{R- , · («) (Formula U) towel 'R is an alkylene or a propyl group, and m&n is the surface: an integer of 1 to 20, respectively. Addition of a propylene-based compound, a compound of these compounds to an acryl-based compound; from the general formula (b): [Chemical 2]

(式（b)中’功及η分別獨立地表示1〜1〇的整數） 所表示的雙盼Α的表氣醇改質物與丙烯酸的加成酯化物、 將該些化合物的丙烯醯基換成曱基丙烯醯基的化合物； 由通式（c): [化3] 〇 •CH==CHa C fTa=C H~C—^〇~r^〇—p—〇—(^-〇 OH Λ〇 20 201231602 (式（C)中，R表示伸乙基或伸丙基，m及n分別獨 立地表示1〜20的整數）所表示的雄酸的環氧烧加成物的 二丙稀酸自旨化合物、將該些化合物的丙烯醯基換成曱基丙 烯醯基的化合物； 由通式（d): [化4](In the formula (b), 'work and η each independently represent an integer of 1 to 1 ), respectively.) The addition of the co-gas alcohol modified product of the double-anticipated oxime to the acrylic acid, and the propylene thiol group of the compounds are exchanged. a compound which is a fluorenyl fluorenyl group; from the formula (c): [Chemical 3] 〇•CH==CHa C fTa=CH~C—^〇~r^〇—p—〇—(^-〇OH Λ 〇20 201231602 (In the formula (C), R represents an exoethyl or propyl group, and m and n each independently represent an integer of 1 to 20) a compound of the present invention, a compound in which the acryloyl group of the compounds is replaced with a mercaptopropenyl group; from the formula (d): [Chemical 4]

OHOH

C—0-^CHa—CH—C Ηή—〇)^C—CH=CII (d)C—0—^CHa—CH—C Ηή—〇)^C—CH=CII (d)

LL

I (式（d)中，m及n分別獨立地表示1〜i〇的整數） 所表示的鄰苯二甲酸的工夕口 U >改質物與丙烯酸的加 成酯化物、將該些化合物的丙稀酼基換成曱基丙烯酸基的 化合物； 由通式（e): [化5] OH 〇H err,I (in the formula (d), m and n each independently represent an integer of 1 to i )), and the addition of the phthalic acid of the phthalic acid represented by the addition of the phthalic acid to the acrylic acid, and the addition of the compound The acrylonitrile group is replaced with a mercapto acrylate-based compound; from the general formula (e): [Chemical 5] OH 〇H err,

ClI-C-^OCIItCIICH.^O^cn.^O^CHiilCII.Ojh-c-cix.! (e) 〇 (式（e)中’ m及n分別獨立地表示1〜2〇的整數） 所表示的1,6-己二醇的工1£夕口 y y改質物與丙婦酸的加 成酯化物（一分子中具有2個丙烯醯基者）、將該些化合物 21 201231602 jpif 的丙烯醯基換成甲基丙烯醯基的化合物； 由通式（f): [化6] (f) o=p4o-(r—o^c—ch=ch2 (式⑴中，R表示伸乙基或伸丙基，3個m分別： 立地表示1〜20的整數）所表示的磷酸的7少伞7才伞其 卜加成物的三丙婦酸s旨化合物、 將該些化合物的丙 換成曱基丙烯醯基的化合物；以及 由通式（g): [化7] (g) CH2-〇-4R-O^C («Ο) -CH«CH2 CH3CH2C-CH2-〇-4R-〇4-/C (=Q) ~CH«CH2 Clig-o-<.R-〇4_C (m〇) _CH«CH2 (式（g)中，R表示伸乙基或伸丙基，m、m’及m·’ 分別獨立地表示1〜20的整數）所表示的三羥甲基丙烷的 環氧烷加成物的三丙烯酸酯化合物、將該些化合物的丙烯 醯基換成曱基丙烯醯基的化合物等。該些單體可單獨使用 或將兩種以上組合使用。 作為交聯材，較佳為1，6-己二醇二丙稀酸酯、1，9-壬二 22 201231602 三丙浠酸酯 =丙稀酸醋、聚丙二醇二丙烯酸，、環氧乙烧加成三經 曱基峨三丙烯酸_ ’難為環氧城域三財基丙烧 ΐ發明中所使用的（C)具有2個以上聚合性不飽和 鍵的乂聯材可單缝用上述化合物，亦可組合多種來使用。 本發明的光學用黏著材樹脂組成物中的（C)成分的 ^量於使用其的情況下，相對於上述⑷成分、（B)成 刀及C)成分的總含量，較佳為⑽質量％〜扣質量％ 的範圍，更佳為〇.〇3質量％〜2〇質量％的範圍。若上述（c) ^分的含量為0·(η質量％以上，則所製作的片材或薄膜的 機械特性充分，另-方面，若為3G f量％以下，則可對所 製作的片材或薄膜賦予充分的黏著性。 (D)成分 …於本發明的光學用黏著材樹脂組成物中，較佳為除上 述（A)成分、（B)成分及（c)成分以外，進而含有（d) 聚合，始劑。但是，於本發明巾，⑼成分的聚合起始劑 未必疋必需成分。本發明的光學祕著材_旨組成物於照 射例如電子束來f施其聚合反應的情況下，可無需聚合起 始劑而進行聚合反應。因此，於本發明中，聚合起始劑適 宜用於如若;f制其騎合反财進行的情況。可於本發 明中使用的聚合起始劑可為光聚合起始劑及熱聚合起始^ 的任一種，亦可併用該些聚合起始劑。 片 如上所述，若對本發明的光學用黏著材樹脂組成物照 射例如電子束，财時即便無聚合起始劑，聚合反應亦進 23 201231602 二卩用以使本發明的樹彳旨組成物硬化的聚合反靡 ^性㈣線的照射、熱、或併用該些的硬化方法來U :所謂「活性能量線」，是指紫外線、電子束、α射線、 Δ /射線等。上述硬化方法亦可用於樹脂組成物中的 i人If分的（甲基)丙_系衍生物聚合物的合成。由於執 寺間變長的情況較多’另外’因熱而導致樹脂 、，成物㈣度下降、料贿_轉規定的厚度因此 較佳，使料藉域而進行聚合㈣聚合起始劑。 與若=合起始劑過少，則聚合反應無法良好地進行，光 學用黏著材樹脂組成物的硬化變得不充分，反之若過多， 則聚合，始劑大量地殘存’光學躲或機械特性有可能會 產生問?ξ|。因此，聚合起始劑的含量相對於（八）成分、（B) 成刀及（C)成分的總含量1〇〇質量份，較佳為〇 〇1質量 份〜5質量份的範圍，更佳為001質量份〜3質量份的範 圍，特佳為〇.〇3質量份〜2質量份的範圍。尤其，當使用 光聚合起始劑時，相對於上述總含量100質量份，較佳為 〇.1質量份〜5質量份的範圍，更佳為〇3質量份〜3質量 份的範圍，特佳為〇.5質量份〜2質量份的範圍。當使用 熱聚合起始劑時’相對於上述總含量100質量份，較佳為 〇.〇1質量份〜1質量份的範圍，更佳為001質量份〜〇5 質量份的範圍。 ’ 本發明中所使用的光聚合起始劑可自二苯基酮系、蒽 醌系、安息香系、鈒鹽、重氮鹽、鑌鹽等公知的化合物中 選擇。該些光聚合起始劑對於光，特別是紫外線的感光度 24 201231602 HUVJjpif 高。 作為可用作光聚合起始劑的化合物的具體例，可列 舉：二苯基酮、N，N’-四曱基-4,4'-二胺基二苯基酮（米其勒 嗣）、Ν，Ν-四乙基-4,4*-二胺基-一本基3同、4-曱氧基-41-·—曱 胺基二苯基酮、（^羥基異丁基苯基酮、2-乙基蒽醌、第三 丁基蒽醌、1，4-二曱基蒽醌、1-氣蒽醌、2,3-二氣蒽醌、3-氣-2-曱基蒽醌、1,2-苯并蒽醌、2-苯基蒽醌、1，4-萘醌、9,10-菲醌、硫雜蒽酮、2-氣硫雜蒽酮、1-羥基環己基苯基酮、 2,2-二曱氧基-1，2.·二苯基乙烷-1-酮、2-羥基-2-甲基-1-苯基 丙烷-1-酮等芳香族酮化合物；安息香、甲基安息香、乙基 安息香等安息香化合物；安息香曱醚、安息香乙醚、安息 香異丁醚、安息香苯醚等安息香醚化合物；苯偶醯、2,2_ 二乙氧基苯乙酮、苄基二曱基縮酮、β-(吖啶_9_基）丙烯酸 等二酯化合物；9-苯基吖啶、9-吡啶基吖啶、l，7-二吖唆基 庚烧等吖啶化合物；2-(鄰氯苯基)-4,5-二苯基咪唑二聚體、 2-(鄰氯笨基)-4,5-二(間曱氧基苯基)咪唑二聚體、2_(鄰ι苯 基)-4,5-二苯基咪唑二聚體、2_(鄰曱氧基苯基)_4,5_二苯基 咪唑二聚體、2-(對曱氧基苯基)_4,5_二苯基咪唑二聚體、 2,4-二(對甲氧基笨基)5_苯基咪唑二聚體、2_(2,4_二曱氧基 苯基)-4,5-二苯基咪唑二聚體、2_(對甲基巯基苯基)_4,5_二 苯基咪唑二聚體等2,4,5-三芳基咪唑二聚體；2-苄基二 曱胺基-1-(4-嗎啉基苯基)_丨_丁酮、2_曱基444-(曱硫基)苯 基]-2-嗎啉基-l_丙烷、雙(2,4,6_三曱基苯甲醯基)_苯基氧化 膦、低聚(2-經基-2-甲基小(4_(1_曱基乙烯基)苯基)丙等。 25 201231602 於本發明中’上述作為光聚合起始劑所例示的化合物 可單獨使用、或將兩種以上組合使用，較佳為根據目的而 選擇適當的化合物。例如，為了不使樹脂組成物著色，較 佳為單獨使用以下的化合物、或將兩種以上組合使用。具 體為1-羥基環己基苯基酮、2_羥基-2_甲基_丨_苯基_丙烷 ，、1-[4-(2-羥基乙氧基)_苯基]_2_羥基_2_曱基_丨_丙烷_丨_酮 等α-羥基苯烷基酮系化合物；雙(2,4,6_三曱基苯曱醯基)— 苯基氧化膦、雙(2,6-二曱氧基苯曱醯基)_2,4,4_三曱基_戊基 氧化膦、2,4,6-三甲基苯甲醯基-二苯基氧化膦等醯基氧二 膦系化合物；低聚(2-經基_2_甲基]_(4仆甲基乙稀基)苯基) 丙酮）、經苯基乙酸2_[2_側氧基_2_苯基_乙醯氧基_乙氧基]_ 乙醋與經苯基乙酸2_|>經基_乙氧基乙g旨的混合物等。 為了製作厚的片材，至少作為光聚合起始劑，較佳為 使用雙(2,4,6-三甲基苯甲酸基)_苯基氧化膦、雙(2,6-二 基苯甲醯基>2,4,4_三甲基·戊基氧化膦、2,4,卜三甲基苯甲 醯基-二苯基氧化膦等醯基氧化膦系化合物。 ^外’為了減少月材的臭氣，較佳為使用低聚(2經基 基乙•基)苯基)_)、及鮮基乙酸 2 Γ2二基""乙酿氧基_乙氧基]_乙酯與經苯基乙酸 2-[2-祕-乙氧基]_乙醋的混合物的至少一者。 絲基乙酸2·[2_膝乙餘]_乙_ =氧基]•乙知與 上述熱聚合起始劑是指藉由熱而產生自由基的起始 26 201231602 劑’具體而言，可列舉：過氧化苯甲醯、過氧化苯甲酸第 一丁s曰、氫過氧化異丙苯、過氧化二碳酸二異丙酯'過氧 化一奴酸二-正丙酯、過氧化二碳酸二(2_乙氧基乙基)酯、 過氧化新癸酸第三丁g旨、過氧化特戊酸第三丁酉旨、（3,5,5_ 二甲基已醯基)過氧化物、二丙醯基過氧化物、二乙醯基過 氧化物、雙十二烷基過氧化物等有機過氧化物。另外，可 列舉· 2,2’-偶氮雙異丁腈、2,2，_偶氮雙(2_曱基丁赌）、 偶氮雙(¾己烧-1·.曱腈)、2,2，_偶氮雙(2,4_二曱基戊旬、2,2，_ =氮雙(2,4-二曱基_4_曱氧基戊腈）、二甲基2,2，_偶氮雙⑺ 酸2_甲酉旨）、4,4，-偶氮雙(4_氰基戊酸）、2,2|-偶氮雙(2_經甲 基丙腈)、2,2 ·偶氮雙[2_(2_咪基)丙院]等偶氮系化合 才勿0 ” 虽於本發明的光學用黏著材樹脂組成物中使用熱聚合 __。’較理想的是具有較佳為贼〜峨，更'佳: 二了特佳為贼〜65t的1G小時半衰期溫度。 逾ιΐ!小時半衰期溫度」’是指於1G小時内熱聚合起始 ，的=分解時的溫度。若1G ]、時半衰期溫度為航以 ，1樹脂組成物的保存穩定性變得良好，另一方面，若 二夺半衰期溫度為8(rc以下，則於硬化反應時不需要高 :，、加熱，而不會產生液晶或偏光板的特性的劣化。因 11不^產生液晶顯示器的顯示特性惡化等問題。當使用 ^小^半农期溫度比較高的熱聚合起始劑時，容易確保樹 呆存穩定性，但反應性降低，因此必需將該些 …承5起始劑的添加量設定得比較多。相反地，於10小時 27 201231602 半衰期溫度低的熱聚合起卜 的樹脂組成物的聚合及 」月况下，為了抑制保管時 少。該些聚合起始劍亦可^製^^將添加量設定得比較 物時使用。 、裏作（A)(甲基)丙烯酸酯聚合 含有各鮮定#丨*光學用轉材樹驗成物視需要亦可 ==2可於本發9种使用的穩定劑· 氧基苯酚等聚合:制穩定性而使用的對甲 耐熱性而使關“樹脂組成㈣硬化物的 #用的Α、—本基膦專抗氧化劑、為了提高财候性而 吏二的W系光穩定劑㈤ered A-e Li幽 "ze: HALS}等。亦可將上述多種穩定劑組合使用。 除此以外，只妓可料本發_效果的，則亦可使 用眾所周知的添加劑。 其-人’以下對包含本發明的光學用黏著材樹脂組成物 的片狀的硬化物的光學用黏著材片進行說明。 本發明的光學用黏著材片可藉由如下方式獲得：使用 通用的塗佈機將光學用黏著材樹脂組成物以原有的狀態塗 佈或洗鑄成形為所期望的厚度，其後進行硬化反應而製成 硬化物。於硬化反應中，可使用藉由熱的聚合方法。另外， 亦可藉由照射紫外線（Ultraviolet，UV )或電子束（ElectronClI-C-^OCIItCIICH.^O^cn.^O^CHiilCII.Ojh-c-cix.! (e) 〇 (in the formula (e), 'm and n each independently represent an integer of 1 to 2〇) The 1,6-hexanediol represented by the addition of the yy modified product of the 1,6-hexanediol to the addition of the bupropion acid (the one having two acrylonitrile groups in one molecule), and the propylene oxide of the compound 21 201231602 jpif a compound substituted with a methacrylinyl group; from the formula (f): [6] (f) o=p4o-(r-o^c-ch=ch2 (in the formula (1), R represents an ethyl group or Propyl group, three m: respectively: the standpoint indicates an integer of 1 to 20) The phosphoric acid represented by the 7-small umbrella 7 is the compound of the tripropionate compound, and the C of the compound is replaced by a mercapto acrylonitrile-based compound; and a compound of the formula (g): [Chem. 7] (g) CH2-〇-4R-O^C («Ο) -CH«CH2 CH3CH2C-CH2-〇-4R-〇4 -/C (=Q) ~CH«CH2 Clig-o-<.R-〇4_C (m〇) _CH«CH2 (in the formula (g), R represents an extended ethyl group or a propyl group, m, m' And a triacrylate compound of an alkylene oxide adduct of trimethylolpropane represented by m·' each independently representing an integer of 1 to 20, and an acrylonitrile group of these compounds is replaced with hydrazine. A propylene fluorenyl compound, etc. These monomers may be used singly or in combination of two or more. As the crosslinked material, 1,6-hexanediol diacrylate, 1,9-fluorene di 22 is preferred. 201231602 Tripropionate = Acrylic vinegar, polypropylene glycol diacrylate, Ethylene Ethylene Ethylene addition, triterpene, tris-acrylic acid _ 'Difficult for the use of Epoxy Metropolitan Sankyin Fibril in the invention ( C) The tantalum joint material having two or more polymerizable unsaturated bonds may be used in the form of a single slit, or may be used in combination. The amount of the component (C) in the optical adhesive resin composition of the present invention is used. In this case, the total content of the component (4), the component (B), and the component C) is preferably in the range of (10)% by mass to 5% by mass, more preferably 〇.3% by mass to 2% by mass. The range of %. When the content of the above (c) is 0% (η mass% or more, the mechanical properties of the produced sheet or film are sufficient, and in the case of the amount of 3 G f or less, the produced sheet can be produced. (D) Component In the optical adhesive resin composition of the present invention, it is preferable to contain, in addition to the above components (A), (B) and (c), further (d) Polymerization, starting agent. However, in the present invention, the polymerization initiator of the component (9) is not necessarily an essential component. The optically secret material of the present invention is a composition which is irradiated with, for example, an electron beam to carry out polymerization. In this case, the polymerization reaction can be carried out without using a polymerization initiator. Therefore, in the present invention, the polymerization initiator is suitably used in the case where it is carried out by riding the compound. The polymerization which can be used in the present invention The initiator may be either a photopolymerization initiator or a thermal polymerization initiator, and the polymerization initiator may be used in combination. As described above, if the optical adhesive resin composition of the present invention is irradiated with, for example, an electron beam, Even if there is no polymerization initiator, the polymerization will enter into 23 201231602 照射 照射 卩 卩 卩 31 31 31 31 2012 2012 2012 2012 2012 2012 2012 2012 2012 : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : 2012 : : : Beam, α-ray, Δ/ray, etc. The above-mentioned hardening method can also be used for the synthesis of a (meth)propene-based derivative polymer of i person If in a resin composition. 'In addition', the resin is caused by heat, and the degree of the product (four) is lowered, and the thickness of the material is changed to a predetermined thickness, so that the material is polymerized by the domain (4) polymerization initiator. If the amount of the initiator is too small, The polymerization reaction does not proceed well, and the curing of the optical adhesive resin composition is insufficient. On the other hand, if it is too large, the polymerization proceeds, and a large amount of the initiator remains. 'Optical hiding or mechanical properties may cause problems. The content of the polymerization initiator is preferably in the range of 1 part by mass to 5 parts by mass, more preferably 1 part by mass, based on the total content of the component (8) and the component (B), and the component (C). 001 parts by mass to 3 parts by mass, especially good for 〇.〇3 In the range of ～2 parts by mass, in particular, when the photopolymerization initiator is used, it is preferably in the range of 0.1 part by mass to 5 parts by mass, more preferably 〇3 by mass, based on 100 parts by mass of the total content. The range of parts to 3 parts by mass is particularly preferably in the range of 5 parts by mass to 2 parts by mass. When a thermal polymerization initiator is used, '100 parts by mass relative to the above total content is preferably 〇.〇1 parts by mass. The range of ~1 part by mass, more preferably 001 part by mass to 5 parts by mass. The photopolymerization initiator used in the present invention may be derived from a diphenylketone, an anthraquinone, a benzoin, or a sulfonium salt. A known compound such as a diazonium salt or a phosphonium salt is selected. The photopolymerization initiators are high in sensitivity to light, particularly ultraviolet rays, 24 201231602 HUVJjpif. Specific examples of the compound which can be used as the photopolymerization initiator include diphenyl ketone and N,N'-tetradecyl-4,4'-diaminodiphenyl ketone (Michele). ,Ν,Ν-tetraethyl-4,4*-diamino-one-based 3-, 4-decyloxy-41---nonylaminodiphenyl ketone, (^ hydroxyisobutylphenyl) Ketone, 2-ethyl hydrazine, tert-butyl hydrazine, 1,4-dioxyl hydrazine, 1- gas hydrazine, 2,3-dioxane, 3- ox-2-mercaptopurine Bismuth, 1,2-benzopyrene, 2-phenylindole, 1,4-naphthoquinone, 9,10-phenanthrenequinone, thioxanthone, 2-oxathioxanthone, 1-hydroxycyclohexyl An aromatic ketone such as phenyl ketone, 2,2-dimethoxyoxy-1,2.diphenylethane-1-one or 2-hydroxy-2-methyl-1-phenylpropan-1-one a compound; a benzoin compound such as benzoin, methyl benzoin, ethyl benzoin; a benzoin ether compound such as benzoin ether, benzoin ethyl ether, benzoin isobutyl ether, benzoin phenyl ether; benzoin, 2,2-diethoxyacetophenone, a diester compound such as benzyldidecyl ketal or β-(acridine-9-yl)acrylic acid; 9-phenyl acridine, 9-pyridyl acridine, l,7-didecylheptane, etc. Pyridine a compound; 2-(o-chlorophenyl)-4,5-diphenylimidazole dimer, 2-(o-chlorophenyl)-4,5-di(m-decyloxyphenyl)imidazole dimer, 2_(o-p-phenyl)-4,5-diphenylimidazole dimer, 2_(o-nonyloxyphenyl)_4,5-diphenylimidazole dimer, 2-(p-methoxyphenyl) ) 4,5-diphenylimidazole dimer, 2,4-di(p-methoxyphenyl) 5-phenylimidazole dimer, 2_(2,4-dimethoxyphenyl)-4 , 2,4,5-triarylimidazole dimer such as 5-diphenylimidazole dimer, 2-(p-methylmercaptophenyl)-4,5-diphenylimidazole dimer; 2-benzyldiyl曱-amino-1-(4-morpholinylphenyl)-indole-butanone, 2-hydrazino 444-(decylthio)phenyl]-2-morpholinyl-l-propane, bis (2, 4,6_trimethyl benzhydryl) phenylphosphine oxide, oligo(2-carbo-2-methyl small (4-(1-fluorenylvinyl)phenyl)propene, etc. 25 201231602 In the present invention, the compound exemplified as the photopolymerization initiator may be used singly or in combination of two or more. It is preferred to select an appropriate compound depending on the purpose. For example, in order not to color the resin composition, it is preferred. To use the following compounds alone, or two The above combination is used in combination, specifically 1-hydroxycyclohexyl phenyl ketone, 2-hydroxy-2-methyl-hydrazine-phenyl-propane, 1-[4-(2-hydroxyethoxy)-phenyl]_2 Α-hydroxyphenylalkyl ketone compound such as _hydroxy-2_fluorenyl-hydrazine-propane_丨-ketone; bis(2,4,6-trimercaptophenyl)-phenylphosphine oxide, bis( 2,6-dimethoxyphenyl fluorenyl) 2,4,4-tridecyl-pentylphosphine oxide, 2,4,6-trimethylbenzylidene-diphenylphosphine oxide Oxydiphosphine-based compound; oligomeric (2-transalkyl-2-methyl)-(4-dimethylethenyl)phenyl)acetone), 2-phenyl-2-acetic acid-2-phenylene A mixture of ethyl acetophenoxy-ethoxylated ketone and phenylacetic acid 2_|> In order to produce a thick sheet, at least as a photopolymerization initiator, it is preferred to use bis(2,4,6-trimethylbenzoate)-phenylphosphine oxide or bis(2,6-diylbenzophenone). a fluorenylphosphine-based compound such as fluorenyl>2,4,4-trimethylpentylphosphine oxide, 2,4, or trimethyl benzhydryl-diphenylphosphine oxide. The odor of the moon material is preferably oligo(2-based ethylidene)phenyl)-), and fresh-base acetic acid 2 Γ2 diyl"" ethoxylated ethoxylated_ethoxy] At least one of a mixture of an ester and 2-[2-myco-ethoxy]-ethyl acetoacetate. Silk-based acetic acid 2·[2_ knee 乙余]_乙_=oxy]• B and the above thermal polymerization initiator refer to the initiation of free radical generation by heat 26 201231602 agent 'specifically, List: benzoyl peroxide, benzoic acid benzoic acid, cumene hydroperoxide, diisopropyl peroxydicarbonate, peroxy-di-n-propyl acrylate, peroxydicarbonate (2_ethoxyethyl) ester, peroxidic neodecanoic acid third butyl, peroxidic pivalic acid tributyl, (3,5,5-dimethyl decyl) peroxide, two Organic peroxides such as propyl hydrazine peroxide, diethyl hydrazine peroxide, and dodecyl peroxide. Further, 2,2'-azobisisobutyronitrile, 2,2,-azobis(2-mercaptobutyl), azobis(3⁄4hexane-1), 2 , 2, _ azobis (2,4-dimercapto pentylene, 2,2, _ = nitrogen bis(2,4-didecyl _4_decyloxyvaleronitrile), dimethyl 2,2 , _ azobis(7) acid 2_methyl hydrazine), 4,4,-azobis(4-cyanovaleric acid), 2,2|-azobis(2_methylpropanenitrile), 2 , 2 · azobis [2_(2_m) propylamine] and other azo-based compounds are not 0". Although thermal polymerization __ is used in the optical adhesive resin composition of the present invention. It has better thief ~ 峨, more 'good: two has a good thief ~ 65t 1G hour half-life temperature. More than ΐ ΐ! hour half-life temperature" 'refers to the thermal polymerization start within 1G hours, = decomposition temperature. When the temperature is 1G] and the half-life temperature is aerodynamic, the storage stability of the resin composition is good. On the other hand, if the half-life temperature is 8 (rc or less, it is not required to be high during the hardening reaction: It does not cause deterioration of the characteristics of the liquid crystal or the polarizing plate. The problem of deterioration of display characteristics of the liquid crystal display is caused by the problem of the deterioration of the display characteristics of the liquid crystal display. When the thermal polymerization initiator having a relatively high temperature in the semi-agricultural period is used, it is easy to ensure the tree. Stability is stable, but the reactivity is lowered. Therefore, it is necessary to set the amount of the starting agent to be relatively large. Conversely, at 10 hours 27 201231602, the half-life temperature is low, and the thermal polymerization of the resin composition is low. In the case of polymerization and "monthly", in order to suppress the storage time, the polymerization initiation swords can also be used to set the amount of addition to the comparative substance. The (A) (meth) acrylate polymerization contains various fresh丨#丨*Optical material for the conversion of the material can also be used as needed ==2, which can be used in 9 kinds of stabilizers in this product. · Polymerization such as oxyphenol: the heat resistance of the heat used for stability Resin composition (4) hardened material Specialized in anti-oxidant, W-based light stabilizer for improving the financial performance (5) ered Ae Li You "ze: HALS}, etc. The above various stabilizers can also be used in combination. In addition, a known additive may be used. The optical adhesive sheet containing the sheet-like cured product of the optical adhesive resin composition of the present invention will be described below. The material sheet can be obtained by coating or casting the optical adhesive resin composition in a desired state into a desired thickness using a general-purpose coater, and then performing a hardening reaction to obtain a cured product. In the hardening reaction, a thermal polymerization method may be used. Alternatively, ultraviolet (Ultraviolet, UV) or electron beam (Electron) may be used.

Beam ’ EB)等活性能量線來進行硬化反應。亦可併用該 些硬化方法。 本發明的光學用黏著材片亦可將其貼合於玻璃、其他 基材等上來使用。 28 201231602 月的光學用黏著材樹脂組成物不會侵害液晶影像 L·丁t\s-PDP、有機见等影像顯示裝置中所使用的材 3署ΐΪΓ’的透明性，故可較佳地用作各種影像顯示 4讀片。因此’於本發明的較佳的實施形態的 罟述黏著材片用作影像顯示裝置及影像顯示裝 置用濾先咨中的衝擊吸收層或透明的填充層。 ㈣:將黏著材片作為影像顯示裝置的衝擊吸收層時，樹 :且成物的硬化物的玻璃轉移溫度（巧）較佳為屹以下。 右硬化物的玻璃轉移溫度為叱以下 =確保，不會因衝擊而裂開。就以上的=言 _gm2〇C〜6〇C。另外，當將黏著材片應用於影像 ;頁不虞置時，健為相對於可見光區域（波長·獅胍〜 780nm)的光線為80%以上，更佳為9〇%以上。 再者，可藉由光學祕騎樹驗成 =製作自立型的片材或薄膜，並使用該些片材或^作 2發明的先學用黏著材片。於此種光學用 作中，可利用洗鑄成形等方法。另外，光二= $物的硬化反應可藉由加熱’或照射紫外線等光線、、電 子束等放躲來進行。當將本發明的光學 ^成形為自立型的片材或薄膜時’其膜厚較 0.01 mm〜3 mm。若膜厚為0.01 mm以上，則可 面板或前面板的起伏等，且不會產生氣泡。 ‘、 以下，則可獲得良好的光學特性。就此種觀點而言為，更佳 為 0.05 mm〜3 mm。 29 201231602 蛀接ί為 材或薄膜的形狀料學用黏著材片可直 接積層於但亦可經由黏或接著劑而積層於影像顯示面 板或者影像顯示I置的表面或it光轉上。 、 再者，本發明的絲用黏著材樹脂組成物亦可於液狀 塗佈迦合於影像齡面板或前面板上、或填充至 所貼s的2片構件之間的空隙中來使用。 、 當藉由照射料線等光線來進行本發_光學用黏著 材树脂組成物的硬化反應時，若存在氧，财時聚合會受 於此種情況下，較佳為利㈣以將進行硬化的樹 月曰層的表面與氧隔絕的透_職透明朗覆蓋。另外， 2藉由在惰性環境下進行聚合來隔絕氧。此種方 备I隔絕氧時，可藉由增加聚合起始劑的添加量來降低 氧的影響。作為此時所使用的聚合起始劑，較佳為經苯基 乙酉夂2-[2-侧氧基_2_苯基_乙醯氧基·乙氧基]-乙酉旨與經苯基 乙酸2-[2-羥基乙氧基]_乙酯的混合物。 •、作為紫外線照射裝置，並無特別限定，可使用單片式、 輸送機式等眾所周知的紫外線照射裝i。另外，作為紫外 線照射用的光源，可為低壓水銀燈、巾壓水銀燈、高壓水 銀燈、金屬齒化物燈、發光二極體（Light Emitting 〇1〇此， LED)燈等，但較佳為使用高壓水銀燈、或金屬齒化物燈。 、、本發明中的前面板是用於影像顯示裝置的前面板，例 =液晶顯示裝置的透明保護基板等符合該前面板，可為一 般，光學用透明基板。具體而言，可列舉：玻璃板、石英 板等無機物的板，壓克力板、聚碳酸酯板等樹脂板，厚的 30 201231602 HUyjjpif 聚酯片等樹脂片。通常當使用塑膠基板時，與光學用黏著 材樹脂組成物的密接性變低的情況較多，但本發明的光學 用黏著材樹脂組成物對於塑膠基板的密接性優異。該些前 面板（透明保護基板）可將多片組合使用，亦可使用將多 片積層為—體而成者。視需要，亦可於該些前面板（透明 保濩基板）的表面積層抗反射層、防污層、色素層、硬塗 層等功能層。表面處理可對前面板（透明保護基板）的一 個面實施、或對兩個面實施。 —另外，本發明亦提供一種使用上述本發明的光學用黏 著材樹脂組成物或辟用黏著材片，將前面板或觸控面板 等光學構件貼付於f彡像鮮面板上而成的影賴示裝置。 再者’以下表示該黏著材片可應用的影像顯示裝置，並且 作為上述光學構件，可列舉以下所示的各種功能層。 =為可應用本發明的光學用黏著材樹脂組成物或光學 用黏著材片的衫像顯示裝置的例子，可列舉：電漿顯示器 (PDP)J液晶顯示器（LCD)、陰極射線管（CRT)、場i 射顯示器㈣d Emission Display，FED)、有機EL顯示 器、電子紙等。亦可於此種影像顯示裝置的表面積層功能 層。 处_作為功此層所例示的抗反射層只要具有對於可 見光的，射率達到5%以下的抗反射性即可，可使用藉由 ，的抗反射方法對透明塑膠薄膜等透明基材進行處^而 成的層。 另外’防>可層是用於防止污垢附著於表面的層，其可 31 201231602 HVyjjpif 所周知的材料。雖然無特別蚊，但為了使表面張 力下降，防抑較佳為包含氟諸脂切_樹脂等。 ，色素層是用於減少不需要的光、並提高色純度，其於 自液晶面板等影像顯示用面板發出的光的色純度低i有 j y藉由使吸收不需要的區域的光的色素溶解於樹脂 中，以後將其於聚乙烯薄臈、聚酯薄膜等基材薄膜上 製膜或積層’或者將上述色素混合於黏著射等方法來形 成色素層。 硬塗層是用於提高表面硬度。硬塗層可藉由將 胺基甲酸S旨或環氧丙烯_等㈣酸樹脂、環氧樹脂: 聚乙稀薄膜等基材薄膜上進行製膜或積層而形成。 為了將本發明的光學用黏著材樹脂組成物或光 著材片積層於前面板、觸控面板、影像顯示面板等上，^ 使用通常所使用的真空層壓機、輕層堡機、單片積 等裝置抑制貼合時的氣泡’較佳為使用真空層^機。 另外，貼^亦可藉由高壓域理來減少氣泡。 上述高壓爸處理可於4(rc〜8(rc (較佳為 〜 70°C )、〇.3 MPa〜〇.8 MPa (較佳為 〇 4 Mpa〜〇 7 m 分鐘〜60分鐘（為丨G分鐘〜％分鐘）的條件 以下士針對本發明的光學用黏著材樹脂組成物^丁傻 顯示裝置中的應用，列舉影像顯示裝置為液晶顯示褒2 情況為例進行更具體的說明。 置的 組裝入液晶顯示裴置中的液晶顯示單元 定，可為包含概_射糾周知騎紐料者、。2卜限 32 201231602 根據液晶材料的控制方法而分類為扭轉向列（TwistedActive energy lines such as Beam' EB) perform a hardening reaction. These hardening methods can also be used in combination. The optical adhesive sheet of the present invention may be used by being bonded to glass, another substrate or the like. 28 201231602 The optical adhesive resin composition of the month does not intrude on the transparency of the material used in the liquid crystal image L·丁t\s-PDP, organic display, etc., so it can be preferably used. A variety of images are displayed for 4 readings. Therefore, the adhesive sheet described in the preferred embodiment of the present invention is used as an impact absorbing layer or a transparent filling layer for filtering the image display device and the image display device. (4) When the adhesive sheet is used as the impact absorbing layer of the image display device, the glass transition temperature of the cured product of the object is preferably 屹 or less. The glass transition temperature of the right hardened material is below = = ensured that it will not crack due to impact. On the above = _gm2 〇 C ~ 6 〇 C. Further, when the adhesive sheet is applied to an image; when the page is not placed, the light is 80% or more, more preferably 9% or more, with respect to the visible light region (wavelength · Griffon ~ 780 nm). Furthermore, it is possible to make a self-standing sheet or film by using an optical secret tree, and use the sheets or the prior art adhesive sheets. For such optical use, methods such as die-casting can be used. Further, the hardening reaction of the light 2 = $ can be carried out by heating or irradiating light such as ultraviolet rays, electron beams, or the like. When the optical film of the present invention is formed into a self-supporting sheet or film, its film thickness is 0.01 mm to 3 mm. When the film thickness is 0.01 mm or more, the panel or the front panel can be undulated without generating bubbles. ‘, below, good optical properties are obtained. In this respect, it is more preferably 0.05 mm to 3 mm. 29 201231602 ί ί 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为 为Further, the wire adhesive resin composition of the present invention may be used by liquid-coating a space which is applied to an image-aged panel or a front panel or filled between two members to which the s is attached. When the curing reaction of the optical adhesive resin composition is carried out by irradiating a light such as a material line, if oxygen is present, the polymerization is likely to be carried out in such a case, preferably (4) to harden. The surface of the tree sap is layered with oxygen and transparent. In addition, 2 is insulated by performing polymerization under an inert environment. When such a method of isolating oxygen, the effect of oxygen can be reduced by increasing the amount of the polymerization initiator added. As the polymerization initiator to be used at this time, it is preferably phenylacetonitrile 2-[2-o-oxy-2-phenyl-ethoxycarbonyle-ethoxy]-ethene and phenylacetic acid. A mixture of 2-[2-hydroxyethoxy]-ethyl ester. The ultraviolet irradiation device is not particularly limited, and a well-known ultraviolet irradiation device i such as a one-piece type or a conveyor type can be used. Further, as the light source for ultraviolet irradiation, a low pressure mercury lamp, a towel pressure mercury lamp, a high pressure mercury lamp, a metal toothed lamp, a light emitting diode (LED) lamp, or the like may be used, but a high pressure mercury lamp is preferably used. Or a metal toothed lamp. The front panel of the present invention is a front panel for an image display device. For example, a transparent protective substrate of a liquid crystal display device or the like conforms to the front panel, and may be a transparent substrate for optical use. Specific examples thereof include a plate of an inorganic material such as a glass plate or a quartz plate, a resin plate such as an acrylic plate or a polycarbonate plate, and a resin sheet such as a thick glass sheet of 201231602 HUyjjpif polyester sheet. In general, when a plastic substrate is used, the adhesion to the optical adhesive resin composition is often lowered. However, the optical adhesive resin composition of the present invention is excellent in adhesion to a plastic substrate. These front panels (transparent protective substrates) can be used in combination of a plurality of sheets, or a plurality of sheets can be used as a body. If necessary, functional layers such as an antireflection layer, an antifouling layer, a pigment layer, and a hard coat layer on the surface areas of the front panels (transparent protective substrate) may be used. The surface treatment can be performed on one side of the front panel (transparent protective substrate) or on both sides. In addition, the present invention also provides a method for attaching an optical member such as a front panel or a touch panel to a fresh panel using the optical adhesive resin composition of the present invention or an adhesive sheet. Display device. Further, the image display device to which the adhesive sheet is applicable is shown below, and various functional layers described below are exemplified as the optical member. = An example of a shirt image display device to which the optical adhesive resin composition or the optical adhesive sheet of the present invention can be applied is a plasma display (PDP) J liquid crystal display (LCD) or a cathode ray tube (CRT). , field i-display (four) d Emission Display, FED), organic EL display, electronic paper and so on. It is also possible to use the surface layer functional layer of such an image display device. The antireflection layer exemplified as the active layer may have an antireflection property of 5% or less with respect to visible light, and a transparent substrate such as a transparent plastic film may be used by an antireflection method. ^ The layer formed. Further, the 'anti-> layer is a layer for preventing dirt from adhering to the surface, which is a material known from 201231602 HVyjjpif. Although there is no special mosquito, in order to lower the surface tension, it is preferable to contain a fluorine-based resin or the like. The pigment layer is used to reduce unnecessary light and to improve color purity. The color purity of light emitted from a panel for image display such as a liquid crystal panel is low, and jy is dissolved by light which absorbs light in an unnecessary region. In the resin, a pigment layer is formed by forming a film or laminating a base film such as a polyethylene thin film or a polyester film, or mixing the above-mentioned coloring matter by adhesion or the like. A hard coat is used to increase the surface hardness. The hard coat layer can be formed by forming a film or laminating a base film such as an amino formic acid S or an epoxy propylene or the like (tetra) acid resin or an epoxy resin: a polyethylene film. In order to laminate the optical adhesive resin composition or the optical material sheet of the present invention on a front panel, a touch panel, an image display panel, or the like, a vacuum laminator, a light layer, a single piece, which is generally used, is used. It is preferable to use a vacuum layer machine in order to suppress the bubble at the time of bonding. In addition, the paste can also reduce air bubbles by high pressure domain. The above high pressure dad treatment can be 4 (rc ~ 8 (rc (preferably ~ 70 ° C), 〇. 3 MPa ~ 〇. 8 MPa (preferably 〇 4 Mpa ~ 〇 7 m minutes ~ 60 minutes (for 丨Conditions of G minutes to % minutes) In the application of the optical adhesive resin composition of the present invention, the liquid crystal display 褒2 will be described in more detail as an example. The liquid crystal display unit incorporated in the liquid crystal display device can be set as a twisted nematic according to the control method of the liquid crystal material (Twisted).

Nematic，TN )，超扭轉向列（Super-twisted nematic，STN )， 垂直排列（Virtical Alignment，VA )，橫向電場切換 (In-Place-Switch.ing，IPS)等，但於本發明中，可為使用 任意控制方法的液晶顯示單元。 圖1及圖2是示意性地表示先前的液晶影像顯示装置 的構造的一例的側面剖面圖。圖1所示的液晶影像顯示裝 置包& .液sa顯示早元1 〇、貼附於液晶顯示單元1 〇的兩 面的偏光板20及偏光板22、介隔空隙30而配置於成為影 像顯不裝置的可見側的偏光板2 〇的上表面的前面板（透明 保護基板）4 0、以及設置於偏光板2 2的下表面的背光系統 50。液晶顯示單元10是將液晶材料封入至2片玻璃（未圖 示）中而成的構造體’於各個玻璃表面貼附有偏光板2〇 及偏光板22 m统5G具有代表性的是包含反射板等 反射機構與料_機構。另外，圖2所示晶影像顯 不裝置除不於成為液晶影像顯示裝置的可見侧的偏光板 20的上表面（前面）設置前面板（透明保護基板）以外， 與圖1所示的液晶顯示裝置同様地構成。 而播，於應用本發明的光學用黏著材樹脂組成物 影像顯示裝置中’將具備使用該光學用黏著 ㈣的液晶顯示裝置的構造=Nematic, TN), Super-twisted nematic (STN), Vertical Alignment (VA), In-Place-Switching (IPS), etc., but in the present invention, A liquid crystal display unit that uses any control method. 1 and 2 are side cross-sectional views schematically showing an example of a structure of a conventional liquid crystal image display device. The liquid crystal image display device package & liquid sa shown in FIG. 1 is displayed on the front side of the liquid crystal display unit 1 and is disposed on the polarizing plate 20 and the polarizing plate 22 on both sides of the liquid crystal display unit 1 and is disposed in the space. The front panel (transparent protective substrate) 40 of the upper surface of the polarizing plate 2 on the visible side of the device is not provided, and the backlight system 50 provided on the lower surface of the polarizing plate 2 2 . The liquid crystal display unit 10 is a structure in which a liquid crystal material is sealed in two sheets of glass (not shown). A polarizing plate 2 and a polarizing plate 22 are attached to the respective glass surfaces. Reflective mechanism such as plate and material_mechanism. In addition, the crystal image display device shown in FIG. 2 is different from the liquid crystal display shown in FIG. 1 except that the front surface (transparent protective substrate) is provided on the upper surface (front surface) of the polarizing plate 20 which is the visible side of the liquid crystal image display device. The device is constructed in the same manner. In the image display device for use in the optical adhesive resin composition of the present invention, the structure of the liquid crystal display device using the optical adhesive (four) will be provided.

Hi=液晶影像顯示裝置係與圖1所示的先前的 ㈣應’且將㈣30設為透明樹脂層 33 201231602 HVJi/Jjpif 者。即’圖3所示的液晶影像顯示裝置包含：液晶顯示 單元10貼附於液晶顯示單元10的兩面的偏光板20及偏 光板22、設置於成為影像顯示裝置的可見側的偏光板20 的土表面的透明樹脂層32、設置於透明樹脂層32的表面 的刖面，(透明保護基板）40、以及設置於偏光板22的下 表f的背光系統50。具有此種構成的液晶影像顯示裝置與 先前的液晶影像顯示衆置相比，因藉由前面板（透明保護 基板）與透鴨脂層的組合而提昇雜擊性，故不易破損。 另外’亦存在如下優點：即便於按壓影像顯 的情況下，亦難以產生顯示不均。 口衣面 再者，同様地，於電裳顯示器的構造中，當將本 == 才樹脂組成物填充至前面板與電漿顯示面板 板與電漿顯示面板加以貼付時，可抑;：片 看到的由重像起的書質下/^ft ^中所 “ w 降，另外，亦可提昇對比度。 :人，對將本發_光學雌著材樹脂組成物應用於 具有觸控面板的構造的影像顯示裝置的情況進行說日^。； 具有觸控面板的構造的影像顯傻 :::二 ☆述觸控面板之間、及/或上述觸控面板與 此處，於影像顯示裝置中，在力、、六曰 的偏光板被貼付於液晶顯示翠元上=曰曰衫像顯不裝置中 阳或為液晶面板的一部 34 201231602 分的情況、及被贴付於觸控面板上而成為觸控面板的一部 分的情況等，但於各種情況下，偏光板均作為所貼付的對 象物的一部分而包含於該對象物中。 圖4是示意性地表示具有觸控面板的先前的液晶影像 顯示裝置的構造的一例的側面剖面圖。其是於圖1中的成 為影像顯示裝置的可見側的偏光板20的上表面追加有介 隔空隙而配置的觸控面板60的構造。因此，圖4中於2 個部位存在空隙，可看到由界面的反射所引起的顯示品質 的下降。 另外，圖5所示的液晶影像顯示裝置是與圖4所示的 先洳的液晶影像顯示裝置相對應，且將2個空隙設為使用 本發明的光學用黏著材樹脂組成物或光學用黏著材片的透 明樹脂層32者。藉由採用此種構造，可使觸控面板的功能 與顯不品質並存。 圖6是示意性地表示被稱為外掛型的構造的一例的侧 面剖面圖。於液晶顯示單元1〇的可見側設置有觸控面板 60與偏光板20，於偏光板的可見侧設置有透明樹脂層32、 則面板（透明保護基板）40。藉由設為此種構造，可製成 具有與圖5相同的功能的更加薄型的構造體。 ，外’如圖7般，亦可製成賴控面板6〇與前面板（透 明保護基板）40而非液晶顯示單元一體化的構造。 再者，作為觸控面板60，可使用通常所使用的觸控面 板。 再者’當前面板、影像顯示面板或觸控面板具有 35 201231602 jpif 〜80 μιη的階差（未圖示）時，就於利用光學用黏著材片 將前面板與觸控面板、觸控面板與影像顯示面板、或前面 板與影像顯示面板加以貼合的步驟後，可進一步去除階差 附近的氣泡的觀點而言，較佳為進行上述高壓釜處理（加 熱加壓處理）。 [實例] 以下，藉由實例來詳述本發明，但本發明的範圍並不 限定於該些實例❶再者，以下所記載的用語「重量平均分 子量」是藉由利用將四氫π夫喃（Tetrahydrofuran，THF )作 為溶劑的凝膠滲透層析法進行測定，並使用標準聚苯乙烯 的校準曲線對其測定值進行換算所決定的值。 (評價方法） 1. 全光線透過率 針對各實例及比較例中所製作的片材，使用色差.濁度 測定器COH-300A (曰本電色工業（股份）製造）測定$ 光線透過率，藉此評價透明性。 2. 黏著力 將各實例及比較例中所製作的光學用黏著材片切成 25 mm的寬度並貼合於玻璃板或壓克力板上，利用剝離試 驗機進行180。剝離試驗，測定黏著力。於試驗溫度^ 80°C，剝離速度為300 mm/min下進行試驗。 3. 耐濕可靠性 將各實例及比較例中所製作的光學用黏著材片放人至 6〇C、90%RH的南溫南濕試驗槽中50小時並實施吸、、辱古戈 36 201231602 驗，其後以目視觀察黏著材片的外觀變化。將未於吸濕試 驗後的黏著材片上看到白濁而維持透明性者設為「A」。 4.高溫可靠性 利用輥層壓機將各實例及比較例中所製作的光學用黏 著材片貼合於透明塑膠前面板[厚度為丨mm的聚碳酸酯板 (40mmx50mm) MR-58 (三菱瓦斯化學（股份）製造）] 上，進而利用真空層壓機將其貼合於玻璃板上。其後，利 用高壓釜於0.5 MPa、6(TC下進行30分鐘處理’藉此去除 貼合時所產生的氣泡。其後，放入至85。〇的高溫試驗槽中 50小時並實施高溫試驗，然後以目視觀察外觀變化。將未 於咼溫試驗後的貼合物上看到氣泡者設為「A」，將看到氣 泡者設為「B」。 ” 製造例1 ((曱基)丙烯酸酯聚合物的製備） ^於安裝有冷卻管、溫度計、攪拌裝置、滴加漏斗及氮 氣注入官的反應容器中稱量丙烯酸2_乙基己酯84 〇 g、丙 烯酸2-羥基乙酯24.0 g、丙烯醯基嗎啉12 〇 g、及曱基異 丁基酮150.0 g作為初始單體，一面以mi/min的風量 進行氮氣置換’一面歷時15分鐘自常溫加熱至6〇°c為止。 其後，一面將溫度維持於60〇C，一面稱量丙烯酸2_乙基己 酯21.0 g、丙烯酸2-羥基乙酯6.〇 g、及丙烯醯基嗎啉3 〇g 作為追加單體，然後使月桂基過氧化物〇3 g溶解於該些 中來製備溶液，並歷時60分鐘滴加該溶液。滴加結束後， 進而歷時10小時進行反應。自所獲得的反應混合物中餾去 甲基異丁基酮，藉此獲得丙烯酸2_乙基己酯與丙烯酸2_ 37 201231602 羥基乙酯及丙烯醯基嗎啉的共聚合物（重量平均分子量為 850,000)。 實例1 (光學用黏著材樹脂組成物的製備） 分別稱量以下的化合物（A)、（B1)、（B2HB3MC) 及（D)，並添加至反應容器中，使用攪拌機（Three_〇ne Motor)於室溫（25°C )下歷時30分鐘進行授拌混合，藉 此製備光學用黏著材樹脂組成物。 (A)製造例1中所製備的共聚合物16 35 g (B1)丙烯酸2-乙基己酯（2EHA) 58.00 g (B2)丙烯酸2-羥基乙酯16.57 g (B3)丙烯醯基嗎啉（興人（股份）製造）8 28呂 (C) 環氧乙烷加成三羥曱基丙烷三丙烯酸酯（新中 村化學工業（股份）製造，商品名「TMPT-3EO」）〇.3〇g (D) 海·基-¼己基-本基-綱（BASF Japan (股份） 製造’商品名「Irgacure-184」）0.50 g 另外，將該光學用黏著材樹脂組成物灌入至寬度1〇〇 mm，縱深1〇〇 mm，深度〇 5 mm的框中，利用紫外線透 過性玻璃覆蓋框的上部後，使用紫外線照射裝置以累計曝 光量3，000 mJ/cm2照射紫外線來使組成物硬化，藉此製作 黏著材片。該黏著材片透明。繼而，對所製作的黏著材片 實施上述各種試驗，並評價其特性。將評價結果示於表1。 實例2 ' 分別稱量以下的化合物（A)、（B1)、（B2)、（B3)、（c) 及（D ) ’並添力σ至反應谷器中，使用擾摔機於室溫（) 38 201231602 下歷時30分鐘進行攪拌混合，藉此製備光學用黏著材樹脂 組成物。 (A)製造例1中所製備的共聚合物16.37 g (B1)丙烯酸2-乙基己酯（2EHA) 57,63 g (B2)丙烯酸2_羥基乙酯16.47 g (B3)丙烯醯基嗎啉（興人（股份）製造）8.23 g (C) 聚丙二醇二丙烯酸酯（新中村化學工業股份有 限公司製造，商品名「APG-700」）0.80 g (D) 1-羥基-環己基-苯基-酮（BASF Japan (股份） 製造，商品名「Irgacure-184」）0.50 g 使用所獲得的光學用黏著材樹脂組成物以與實例1相 同的方式製作黏著材片，然後實施各種試驗，並評價其特 性。將評價結果示於表1。 製造例2 ((甲基)丙烯酸酯聚合物的製備） ^於安裝有冷卻管、溫度計、攪拌裝置、滴加漏斗及氮 氣注入管的反應容器中稱量丙烯酸2_乙基己酯84 〇 g、丙 烯酸2-羥基乙酯24.0 g、丙烯醯基嗎啉12·〇 g、及甲基異 丁基酮150.0 g作為初始早體，一面以1〇〇 ml/min的風量 進行氮氣置換’-·面歷時15分鐘自常溫加熱至55<5(：為止。 ^後，一面將溫度維持於55t：，一面稱量丙烯酸2_乙基己 酉曰21.0 g、丙烯酸2_羥基乙酯6.0 g、及丙烯醯基嗎啉3.〇 g =為^加單體，然後使月桂基過氧化物Q 3 g溶解於該些 :來製備溶液，並歷時6G分鐘滴加該溶液。滴加結束後， 、而歷時15小時進行反應。自所獲得的反應混合物中館去 39 201231602 曱基異丁基嗣’措此獲得丙稀酸2-乙基己自旨與丙稀酸2-羥基乙酯及丙烯醯基嗎啉的共聚合物（重量平均分子量為 1，200,000)。 實例3(光學用黏著材樹脂組成物的製備） 分別稱量以下的化合物（A)、（B1)、（B2)、（B3)、（C) 及（D) ’並添加至反應容器中，使用攪拌機於室溫（25°C ) 下歷時30分鐘進行攪拌混合’藉此製備光學用黏著材樹脂 組成物。 (A)製造例2中所製備的共聚合物14.88 g (B1)丙烯酸2-乙基己酯（2EHA) 59.02 g (B2)丙烯酸2-羥基乙酯16.86g (B3)丙烯醯基嗎啉（興人（股份）製造）8 44g (c)環氧乙烷加成三羥曱基丙烷三丙烯酸酯（新中 村化學工業（股份）製造，商品名「TMPT-3EO」）0.30g (D) 1-羥基-環己基-苯基-酮（BASF Japan (股份） 製造，商品名「Irgacure-184」）0.50 g 使用所獲得的光學用黏著材樹脂組成物以與實例1相 同的方式製作黏著材片，然後實施各種試驗，並評價其特 性。將評價結果示於表1。 比較例1 為171 十對市售的透明的丙烯酸系黏著樹脂性樹脂片（厚度 μιη：)(包含未使用（曱基)丙烯醯胺系化合物的（甲基) 丙烯酸酷取人丨， 者），眘眾合物、（曱基）丙烯酸酯單體、及聚合起始劑 ’實施與實例1相同的試驗，並評價其特性。將評價結 果不於表1。 201231602 4uyj^pif [表1]The Hi = liquid crystal image display device is the same as the previous (four) should be shown in Fig. 1 and the (four) 30 is set as the transparent resin layer 33 201231602 HVJi/Jjpif. In other words, the liquid crystal image display device shown in FIG. 3 includes a polarizing plate 20 and a polarizing plate 22 which are attached to both surfaces of the liquid crystal display unit 10, and a polarizing plate 20 which is provided on the visible side of the image display device. The transparent resin layer 32 on the surface, the surface of the transparent resin layer 32, the transparent protective substrate 40, and the backlight system 50 provided in the lower surface f of the polarizing plate 22. The liquid crystal image display device having such a configuration is more resistant to breakage due to the combination of the front panel (transparent protective substrate) and the translucent layer, as compared with the conventional liquid crystal image display device. In addition, there is also an advantage that display unevenness is hard to occur even when the image is pressed. In the construction of the electric display, in the construction of the electric display, when the resin composition of the == is filled into the front panel and the plasma display panel and the plasma display panel are attached, it can be suppressed; Seen from the weight of the book quality / ^ ft ^ in the "w drop, in addition, can also improve the contrast.: People, the application of the _ optical female resin composition for touch panels The image display device of the structure is said to be a day; the image having the structure of the touch panel is stupid::: 2, between the touch panels, and/or the touch panel and the image display device In the case of the force, the six-inch polarizer is attached to the liquid crystal display Cuiyuan = the shirt is not installed in the middle of the sun or a part of the LCD panel 34 201231602 points, and is attached to the touch panel In the case where the touch panel is a part of the touch panel, the polarizing plate is included in the object as a part of the attached object. FIG. 4 is a view schematically showing a front surface having a touch panel. An example of the structure of a liquid crystal display device A side cross-sectional view of the touch panel 60 in which the gap is disposed on the upper surface of the polarizing plate 20 which is the visible side of the image display device in Fig. 1. Therefore, there are two locations in Fig. 4 In the gap, the deterioration of the display quality caused by the reflection of the interface can be seen. In addition, the liquid crystal image display device shown in FIG. 5 corresponds to the liquid crystal image display device shown in FIG. 4, and has two gaps. The transparent resin layer 32 using the optical adhesive resin composition of the present invention or the optical adhesive sheet is used. By adopting such a configuration, the function of the touch panel can be combined with the quality of the touch panel. A side cross-sectional view showing an example of a structure called a plug-in type. A touch panel 60 and a polarizing plate 20 are provided on the visible side of the liquid crystal display unit 1 , and a transparent resin layer 32 is provided on the visible side of the polarizing plate. Then, the panel (transparent protective substrate) 40. By adopting such a structure, a thinner structure having the same function as that of Fig. 5 can be obtained. Further, as shown in Fig. 7, a control panel 6 can be manufactured. 〇 and front panel The transparent protective substrate 40 is not integrated with the liquid crystal display unit. Further, as the touch panel 60, a commonly used touch panel can be used. Further, the current panel, the image display panel, or the touch panel has 35 201231602 Steps of jpif to 80 μιη (not shown), the steps of bonding the front panel to the touch panel, the touch panel and the image display panel, or the front panel and the image display panel using the optical adhesive sheet After that, it is preferable to carry out the above-described autoclave treatment (heat and pressure treatment) from the viewpoint of further removing bubbles in the vicinity of the step. [Examples] Hereinafter, the present invention will be described in detail by way of examples, but the scope of the present invention is The present invention is not limited to these examples. The term "weight average molecular weight" as described below is measured by gel permeation chromatography using Tetrahydrofuran (THF) as a solvent, and standards are used. The calibration curve of polystyrene is the value determined by converting the measured value. (Evaluation method) 1. The total light transmittance was measured for the light transmittance of the sheet produced in each of the examples and the comparative examples using a color difference turbidity measuring device COH-300A (manufactured by Sakamoto Denshoku Industries Co., Ltd.). This is used to evaluate transparency. 2. Adhesive force The optical adhesive sheets produced in the respective examples and comparative examples were cut into a width of 25 mm and attached to a glass plate or an acrylic plate, and subjected to a peeling tester for 180. Peel test to determine adhesion. The test was carried out at a test temperature of 80 ° C and a peeling speed of 300 mm/min. 3. Moisture resistance reliability The optical adhesive sheets produced in the respective examples and comparative examples were placed in a south-temperature and south-humidity test tank of 6 ° C and 90% RH for 50 hours and subjected to suction and humiliation. 201231602 test, after which the appearance change of the adhesive sheet was visually observed. It is set to "A" when the opaque material is not observed on the adhesive sheet after the moisture absorption test and the transparency is maintained. 4. High-temperature reliability The optical adhesive sheets produced in the respective examples and comparative examples were bonded to a transparent plastic front panel by a roll laminator [carbon polycarbonate sheet (40 mm x 50 mm) having a thickness of 丨mm MR-58 (Mitsubishi) The gas chemical (manufactured by the company) was applied to a glass plate by a vacuum laminator. Thereafter, the autoclave was treated at 0.5 MPa and 6 (TC for 30 minutes) to remove air bubbles generated during bonding, and then placed in a high temperature test tank of 85 Torr for 50 hours and subjected to a high temperature test. Then, the appearance change was visually observed. When the bubble was not observed on the laminate after the temperature test, the bubble was "A", and the bubble was "B"." Manufacturing Example 1 ((曱基) Preparation of acrylate polymer) ^ Weigh 2 - ethylhexyl acrylate 84 〇 g, 2-hydroxyethyl acrylate 24.0 in a reaction vessel equipped with a cooling tube, a thermometer, a stirring device, a dropping funnel and a nitrogen injection reactor. g, propylene decylmorpholine 12 〇g, and 150.0 g of decyl isobutyl ketone were used as the initial monomers, and nitrogen substitution was performed at a flow rate of mi/min, and the temperature was heated from ambient temperature to 6 ° C for 15 minutes. Thereafter, while maintaining the temperature at 60 ° C, 21.0 g of 2-ethylhexyl acrylate, 6. 〇g of acrylic acid, and 3 〇g of acryloylmorpholine were weighed as additional monomers. Then, 3 g of lauryl peroxide oxime was dissolved in the solution to prepare a solution, which lasted 60 times. The solution was added dropwise to the clock. After the completion of the dropwise addition, the reaction was carried out for 10 hours. Methyl isobutyl ketone was distilled off from the obtained reaction mixture, whereby 2-ethylhexyl acrylate and acrylic acid 2_37 201231602 hydroxyl group were obtained. Copolymer of ethyl ester and acryloylmorpholine (weight average molecular weight: 850,000). Example 1 (Preparation of optical adhesive resin composition) The following compounds (A), (B1), and (B2HB3MC) were weighed, respectively. And (D), and added to the reaction vessel, and mixed with a mixer (Three_〇ne Motor) at room temperature (25 ° C) for 30 minutes to prepare an optical adhesive resin composition. A) Copolymer prepared in Preparation Example 1 16 35 g (B1) 2-ethylhexyl acrylate (2EHA) 58.00 g (B2) 2-hydroxyethyl acrylate 16.57 g (B3) propylene hydrazinomorpholine (B3) Xingren (share) manufacturing) 8 28 Lu (C) Ethylene oxide addition trihydroxy decyl propane triacrylate (manufactured by Shin-Nakamura Chemical Industry Co., Ltd., trade name "TMPT-3EO") 〇.3〇g (D) Haiji--1⁄4 己基-本基-纲 (BASF Japan (share) Manufacture' trade name "Irgacure-18 4") 0.50 g In addition, the optical adhesive resin composition was poured into a frame having a width of 1 mm, a depth of 1 mm, and a depth of 5 mm, and the upper portion of the frame was covered with ultraviolet ray-permeable glass. The composition was cured by irradiating ultraviolet rays with an accumulated exposure amount of 3,000 mJ/cm 2 using an ultraviolet irradiation device, thereby producing an adhesive sheet. The adhesive sheet was transparent. Then, various tests were performed on the prepared adhesive sheet, and Evaluate its characteristics. The evaluation results are shown in Table 1. Example 2 'Weigh the following compounds (A), (B1), (B2), (B3), (c), and (D) ', respectively, and add σ to the reaction bar, using a spoiler at room temperature. () 38 201231602 The mixture was stirred and mixed for 30 minutes, thereby preparing an optical adhesive resin composition. (A) Copolymer prepared in Preparation Example 16.37 g (B1) 2-ethylhexyl acrylate (2EHA) 57, 63 g (B2) 2-hydroxyethyl acrylate 16.47 g (B3) acrylonitrile Porphyrin (manufactured by Xingren (Stock)) 8.23 g (C) Polypropylene glycol diacrylate (manufactured by Shin-Nakamura Chemical Co., Ltd., trade name "APG-700") 0.80 g (D) 1-hydroxy-cyclohexyl-benzene Base-ketone (manufactured by BASF Japan (trade name "Irgacure-184") 0.50 g Using the obtained optical adhesive resin composition, an adhesive sheet was produced in the same manner as in Example 1, and then various tests were carried out, and Evaluate its characteristics. The evaluation results are shown in Table 1. Production Example 2 (Preparation of (meth)acrylate polymer) ^Weighed 2 -ethylhexyl acrylate 84 〇g in a reaction vessel equipped with a cooling tube, a thermometer, a stirring device, a dropping funnel, and a nitrogen injection tube 2, 4-hydroxyethyl acrylate, 2,0 g of acryloyl morpholine 12 〇g, and 150.0 g of methyl isobutyl ketone were used as the initial body, and nitrogen was replaced by a volume of 1 〇〇 ml/min. After heating for 15 minutes from room temperature to 55 < 5 (: until ^, while maintaining the temperature at 55 t:, weigh 21.0 g of 2-ethylhexyl acrylate, 6.0 g of 2-hydroxyethyl acrylate, and Propylene decylmorpholine 3. 〇g = ^ monomer, and then lauryl peroxide Q 3 g is dissolved in the solution: to prepare a solution, and the solution is added dropwise over 6G minutes. After the end of the dropwise addition, The reaction was carried out for 15 hours. From the obtained reaction mixture, in the hall, 39 201231602 decyl isobutyl hydrazine was obtained to obtain 2-ethylhexyl acrylate and 2-hydroxyethyl acrylate and acrylonitrile. a morpholine copolymer (weight average molecular weight of 1,200,000). Example 3 (Optical Adhesive Resin Group) Preparation of the materials) The following compounds (A), (B1), (B2), (B3), (C) and (D) ' were weighed and added to the reaction vessel at room temperature (25 ° C using a stirrer). The mixture was stirred and stirred for 30 minutes to prepare an optical adhesive resin composition. (A) The copolymer prepared in Production Example 2. 14.88 g (B1) 2-ethylhexyl acrylate (2EHA) 59.02 g (B2) 2-hydroxyethyl acrylate 16.86 g (B3) propylene decylmorpholine (manufactured by Xingren (stock)) 8 44 g (c) ethylene oxide addition trihydroxy decyl propane triacrylate (Xin Nakamura Chemical Industrial (share) manufacturing, trade name "TMPT-3EO") 0.30g (D) 1-hydroxy-cyclohexyl-phenyl-ketone (manufactured by BASF Japan (trade name "Irgacure-184") 0.50 g The obtained optical adhesive resin composition was prepared into an adhesive sheet in the same manner as in Example 1, and various tests were carried out, and the characteristics thereof were evaluated. The evaluation results are shown in Table 1. Comparative Example 1 is 171 ten pairs of commercially available transparent Acrylic adhesive resin sheet (thickness μm:) (including unused (fluorenyl) acrylamide compound The (meth)acrylic acid, the compound, the (meth) acrylate monomer, and the polymerization initiator were subjected to the same test as in Example 1, and the properties were evaluated. Not in Table 1. 201231602 4uyj^pif [Table 1]

項目 單位 "―— 特性值 .....- 貫例1 實例2 實例3 比較例1 外觀 - 热〇通明 無色透明 無色透明 無色透明 全光線透過率 % -------- yi.5 91.2 91 , 玻璃 黏者力 -游七^一 N/25 mm (8(TC) 「6.8 6.0 6.2 ^ Λ 歷克力板 6.4 5.7 5‘9 1 Q 耐濕可霏性 A A A I .〇 A 高溫可靠性 A A A B 實例4 (片材貼合的實例） 使用實例1的光學用黏著材樹脂組成物以與實例1相 同的方式製作寬度30 mm、縱深4〇 mm、厚度〇2瓜瓜的 黏著材片。利用輥層壓機將該黏著材片貼合kMR_58 (上 述）上，其後，進而使用真空層壓機將其貼合於液晶面板 上。貼合後利用高壓爸於0.5 MPa、60°C下進行30分鐘處 理，藉此去除貼合時所產生的氣泡。將以上述方式所製作 的帶有前面板的液晶面板組裝入安裝有背光的框體中並使 影像顯示’結果亦無顯示不均而顯示良好的影像。 繼而’對該帶有前面板的液晶面板實施利用85°C的高 溫試驗槽的50小時的高溫試驗，及利用6(TC、90%RH的 高溫高濕槽的50小時的高溫高濕試驗，其後以目視觀察外 觀變化。於進行高溫試驗及高溫高濕試驗的任一試驗的情 況下’均未看到氣泡的產生。另外，亦未看到顏色的變化 或剝離而顯示良好的可靠性。另外，組裝入框體中進行動 作確認的結果，確認其無問題地動作。 實例5 (溶液貼合的實例） 201231602 4ϋ93^ρΐί 、將實例4中所製作的黏著材片切斷成5麵的寬度， 並貼附於液晶面板的4條邊上。繼而，滴加實例2的樹脂 組成物，進而以不使氣泡進入的方式蓋上乂以-別（上述） 的板。其後，使用紫外線照射裝置以累計曝光量3,〇〇〇mJ 照射紫外線來使組祕硬化，藉此製作帶有前面板的液晶 面板。將所製作的液晶面板組裝人安裝有背光的框體中並 使影像顯不，結果亦無顯示不均而顯示良好的影像。 、繼而，對該帶有前面板的液晶面板實施利用85。〇的高 溫試驗槽的50小時的高溫試驗，及利用6〇〇c、9〇%RH的 高溫高濕槽的50小時的高溫高濕試驗，其後以目視觀察外 觀麦化於進行尚溫s式驗及南溫南濕試驗的任一試驗的情 況下，均未看到氣泡的產生。另外，亦未看到顏色的變化 或剝離而顯示良好的可靠性。另外，組裝入框體中進行動 作確認的結果，確認其無問題地動作。 [產業上之可利用性] 根據本發明的光學用黏著材樹脂組成物，可製造對於 塑膠前面板的密接性高、透明性或衝擊吸收性優異的黏著 材片。該黏著材片可較佳地用於影像顯示裝置及影像顯示 褒置用滤光器的用途。例如，當將本發明的光學用黏著材 樹脂組成物及黏著材片用作影像顯示裝置的透明樹脂層 時’於影像顯示裝置中可實現優異的高溫可靠性、耐濕可 靠性及衝擊吸收性。 【圖式簡單說明】 圖1是示意性地表示先前的液晶顯示裝置的構成例的 42 201231602 4U935pif 側面剖面圖° 圖2是示意性地表示 側面剖面圖。 圖3是不意性地表示 先前的液晶顯示裝置的構成例的 的側面剖面圖。 圖4是示意性地表示 示本發明的液晶顯示裝置的構成例 農置的構成例的側面剖面圖。 具有觸控面板的先前的液晶顯示 圖5是不意性地表示具有觸控面板的本發明的液晶顯 不裝置的構成例的側面剖面圖。 一圖6是tf意性地表示具㈣掛顏造的本發明的液晶 顯不裝置的構成例的側面剖面圖。 一圖7是示意性地表示具有觸控面板的本發明的液晶顯 示裝置的構成例的側面剖面圖。 【主要元件符號說明】 .液晶顯示單元 20、22 :偏光板 30 :空隙（空氣層） 32 :透明樹脂層 40 :透明保護基板 50 :背光系統 60 :觸控面板 43Project unit "―- Characteristic value.....- Example 1 Example 2 Example 3 Comparative Example 1 Appearance - enthusiasm, clear, colorless, transparent, colorless, transparent, colorless, transparent, full light transmittance % -------- yi. 5 91.2 91 , Glass Adhesive Force - Tour Seven ^ One N/25 mm (8(TC) "6.8 6.0 6.2 ^ 历 Acrylic Sheet 6.4 5.7 5'9 1 Q Moisture Resistant AAAI .〇A High Temperature Reliable Sexual AAAB Example 4 (Example of sheet bonding) Using the optical adhesive resin composition of Example 1, an adhesive sheet having a width of 30 mm, a depth of 4 mm, and a thickness of 2 melons was produced in the same manner as in Example 1. The adhesive sheet was bonded to kMR_58 (described above) by a roll laminator, and then bonded to the liquid crystal panel by a vacuum laminator. After bonding, the high-pressure dad was used at 0.5 MPa and 60 ° C. The film was processed for 30 minutes to remove the air bubbles generated during the bonding. The liquid crystal panel with the front panel produced in the above manner was assembled into the frame in which the backlight was mounted, and the image display showed no unevenness in display. And display a good image. Then 'implement the LCD panel with the front panel A 50-hour high-temperature test using a high-temperature test cell at 85 ° C and a 50-hour high-temperature and high-humidity test using a high-temperature and high-humidity bath of 6 (TC, 90% RH), and then visually observing the change in appearance. In the case of any of the tests in the high-temperature and high-humidity test, no generation of bubbles was observed. Further, no change in color or peeling was observed, and good reliability was exhibited. As a result, it was confirmed that it was operating without problems. Example 5 (Example of solution bonding) 201231602 4ϋ93^ρΐί The sheet of the adhesive sheet produced in Example 4 was cut into a width of 5 faces and attached to 4 sides of the liquid crystal panel. Then, the resin composition of Example 2 was dropped, and the plate of the above-mentioned (above) was covered so as not to enter the bubble. Thereafter, the ultraviolet irradiation device was used to accumulate the exposure amount of 3, 〇〇〇mJ. The liquid crystal panel with the front panel was produced by irradiating ultraviolet rays to cure the composition. The assembled liquid crystal panel was mounted in a frame with a backlight and the image was not displayed. As a result, the display was not displayed unevenly. Shadow Then, the liquid crystal panel with the front panel is subjected to a 50-hour high-temperature test using a high temperature test tank of 85 〇, and a high-temperature high-humidity tank using 6 〇〇c, 9〇% RH for 50 hours. The high temperature and high humidity test, after visually observing the appearance of wheat, in the case of any test of the temperature s test and the south temperature and south humidity test, no bubble was observed. The result of the change or the peeling showed good reliability. In addition, the result of the operation confirmation in the assembly was confirmed, and it was confirmed that the operation was performed without any problem. [Industrial Applicability] According to the optical adhesive resin composition of the present invention, an adhesive sheet having high adhesion to a plastic front panel and excellent transparency or impact absorbability can be produced. The adhesive sheet can be preferably used for the image display device and the filter for the image display device. For example, when the optical adhesive resin composition and the adhesive sheet of the present invention are used as a transparent resin layer of an image display device, excellent high-temperature reliability, moisture resistance reliability, and impact absorption can be achieved in an image display device. . BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a side cross-sectional view schematically showing a configuration example of a conventional liquid crystal display device. Fig. 2 is a side cross-sectional view schematically showing a configuration of a liquid crystal display device. Fig. 3 is a side cross-sectional view showing an example of a configuration of a conventional liquid crystal display device. Fig. 4 is a side cross-sectional view schematically showing a configuration example of a configuration of a liquid crystal display device of the present invention. [Previous liquid crystal display having a touch panel] Fig. 5 is a side cross-sectional view showing an example of a configuration of a liquid crystal display device of the present invention having a touch panel. Fig. 6 is a side cross-sectional view schematically showing a configuration example of a liquid crystal display device of the present invention having a (4) hanging surface. Fig. 7 is a side cross-sectional view schematically showing a configuration example of a liquid crystal display device of the present invention having a touch panel. [Description of main component symbols]. Liquid crystal display unit 20, 22: Polarizing plate 30: Void (air layer) 32: Transparent resin layer 40: Transparent protective substrate 50: Backlight system 60: Touch panel 43

Claims (1)

201231602 七、申請專利範圍： 1. 一種光學用黏者材樹脂組成物，包括： (A) (甲基）丙烯酸酯聚合物；以及 (B) (甲基）丙烯酸酯單體， 其特徵在於上述（曱基）丙烯酸酯聚合物具有醯胺基。 2_如申請專利範圍第1項所述之光學用黏著材樹脂組 成物，其更含有（C)具有2個以上聚合性不飽和鍵的交 聯材。 3. 如申請專利範圍第1項或第2項所述之光學用黏著 材樹脂組成物，其更含有（D)聚合起始劑。 4. 如申請專利範圍第1項至第3項中任一項所述之光 學用黏著材樹脂組成物，其中上述（A)(甲基)丙烯酸酯聚 合物是使含有（曱基）丙烯醯胺系化合物的單體聚合而成 者。 5. 如申請專利範圍第4項所述之光學用黏著材樹脂組 成物’其中上述（曱基）丙烯醯胺系化合物是選自二乙基丙 烯酿胺、異丙基丙烯醯胺、羥乙基丙烯醯胺及丙烯醯基嗎 琳中的至少一種化合物。 6. 如申請專利範圍第4項所述之光學用黏著材樹脂組 成物’其中上述（A)(曱基)丙烯酸酯聚合物是使（i)烷 基的碳數為4〜18的（曱基)丙烯酸烷基酯、（ii)含羥基的（甲 基)丙稀峻酯以及（iii)(曱基)丙烯醯胺系化合物共聚合而 獲得者。 7. 如申請專利範圍第6項所述之光學用黏著材樹脂組 201231602 **tw 刀 JjJlf 置!/、中上述（A)(甲基）丙烯酸酯聚合物是使（i)烷 二。的石反數為4〜18的（甲基)丙烯酸烧基S旨55質量％〜83質 里/〇 (U)含搜基的（甲基)丙烯酸酯10質量％〜30質量％ 以及（m)(甲基)丙稀酿胺系化合物7質量％〜15質量％ 共聚合而獲得者。 ±匕8·如申請專利範圍第6項或第7項所述之光學用黏著 樹月曰組^物，其中上述⑻（曱基)丙烯酸S旨單體S含有⑴ &基的&數為4〜18 W(曱基)丙烯酸烧基自旨、（ii)含經基 的（曱基)丙酸醋及（Ui)(曱基)丙烯醯胺系化合物者。 9. 如申請專利範圍第8項所述之光學用黏著材樹脂組 成物’其中用以形成上述（A)成分的（〇〜（iii)的各 成分的相對於（i)〜（iu)的合計量的含有比率、與構成 (B)成分的（i)〜的各成分的相對於〜（iU) 的合計量的含有比率大致相等。 10. 如申請專利範圍第1項至第9項中任一項所述之 光學用黏著材樹脂組成物，其中上述（A)(甲基)丙烯酸酯 聚合物的重量平均分子量為8〇〇,〇〇〇〜3,000,000。 11. 如申請專利範圍第3項至第10項中任一項所述之 光學用黏著材樹脂組成物，其中上述（A)(曱基)丙烯酸醋 聚合物為10質量％〜60質量％，上述（B)(甲基)丙烯酸 酯單體為39.9質量％〜89.9質量％，上述（C)交聯材為 0.01質量％〜30質量％’上述（D)聚合起始劑相對於（I) 成分、（B)成分及（C)成分的合計量1〇〇質量份為 45 201231602 4uyj^pif 12. —種光學用黏著材片，其是將如申請專利範圍第 1項至第11項中任一項所述之光學用黏著材樹脂組成物硬 化成片狀而成者。 13. —種影像顯示裝置’其是具有使用如申請專利範 圍第12項所述之光學用黏著材片，將其他光學構件貼合於 影像顯示面板上的構造而成者。 14. 一種影像顯示裝置，其包括影像顯示面板、觸控 面板及前面板，且其是於上述影像顯示面板與上述觸控= 板之間、及上述觸控面板與上述前面板之間的至少一者中 具有树月曰層而成者，上述樹脂層由如申請專利範圍第【項 至第11财任—項所述之光學用黏著材樹脂組成物或如 申請專利範圍第12項所述之光學用黏著材片所形成。 Μ. —種影像顯示裝置的製造方法，其包括： 利用如申請專利範圍第12項所述之光學用黏著 =面板與觸控面板之間、觸控面板與影像顯示面板之間 或則面板與影像顯示面板之間加以貼合的步驟；以及 於上述貼合步驟後，以4(rc〜80oc、03 Mpa〜Μ a、及5分鐘〜6G分鐘的條件進行處理的步驟。 46201231602 VII. Patent application scope: 1. An optical adhesive resin composition comprising: (A) a (meth) acrylate polymer; and (B) a (meth) acrylate monomer, characterized by the above The (fluorenyl) acrylate polymer has a guanamine group. The optical adhesive resin composition according to claim 1, which further comprises (C) a crosslinked material having two or more polymerizable unsaturated bonds. 3. The optical adhesive resin composition according to claim 1 or 2, further comprising (D) a polymerization initiator. 4. The optical adhesive resin composition according to any one of claims 1 to 3, wherein the (A) (meth) acrylate polymer is a fluorene-containing (fluorene) propylene hydride. The monomer of the amine compound is polymerized. 5. The optical adhesive resin composition as described in claim 4, wherein the (mercapto) acrylamide compound is selected from the group consisting of diethyl acrylamide, isopropyl acrylamide, and hydroxyethyl At least one compound of acrylamide and acrylonitrile. 6. The optical adhesive resin composition as described in claim 4, wherein the (A) (fluorenyl) acrylate polymer has a carbon number of (i) alkyl groups of 4 to 18 (曱) The base is obtained by copolymerizing an alkyl acrylate, (ii) a hydroxyl group-containing (meth) propyl ester, and (iii) a (fluorenyl) acrylamide compound. 7. The optical adhesive resin group according to item 6 of the patent application scope of the invention, wherein the (A) (meth) acrylate polymer is (i) alkane. The (inverse) number of the (meth)acrylic acid group of 4 to 18 is 55 mass% to 83 mass% / 〇 (U) containing (meth) acrylate 10% by mass to 30% by mass and (m) The (meth)acrylic amine compound 7 mass% to 15 mass% is obtained by copolymerization. The optically bonded sapphire component of the above-mentioned (8) (fluorenyl) acrylate S monomer S contains the (1) & base & number, as described in claim 6 or claim 7 It is a 4 to 18 W (fluorenyl) acrylonitrile group, (ii) a mercapto group-containing (mercapto) propionic acid vinegar, and a (Ui) (fluorenyl) acrylamide compound. 9. The optical adhesive resin composition as described in claim 8, wherein the components ((a) to (iu) of (〇) ((iii)) for forming the above (A) component are The content ratio of the total amount and the content ratio of each component of (i) to constituting the component (B) to the total amount of 〜(iU) are substantially equal. 10. In the first to ninth items of the patent application range The optical adhesive resin composition according to any one of the preceding claims, wherein the weight average molecular weight of the (A) (meth) acrylate polymer is 8 Å, 〇〇〇 3,000,000. The optical adhesive resin composition according to any one of the items 10, wherein the (A) (mercapto)acrylic acid vinegar polymer is 10% by mass to 60% by mass, and the above (B) (methyl) The acrylate monomer is from 39.9 mass% to 89.9 mass%, and the above (C) crosslinked material is from 0.01% by mass to 30% by mass. The above (D) polymerization initiator is relative to the component (I), the component (B), and C) The total amount of the components is 1 part by mass. 45 201231602 4uyj^pif 12. A kind of optical adhesive sheet, which is The optical adhesive resin composition according to any one of the first to eleventh aspects of the invention is obtained by hardening into a sheet form. 13. A type of image display device which is used as the application patent number 12 The optical adhesive sheet according to the item, wherein the other optical member is attached to the image display panel. 14. An image display device comprising an image display panel, a touch panel and a front panel, and And the resin layer is formed by at least one of the image display panel and the touch panel, and between the touch panel and the front panel, wherein the resin layer is as claimed in the patent application. The optical adhesive resin composition according to the eleventh aspect of the invention, or the optical adhesive sheet according to claim 12, wherein the image display device is manufactured, comprising: The step of bonding between the optical adhesive layer as described in claim 12 and the touch panel, between the touch panel and the image display panel, or between the panel and the image display panel; And after the above-mentioned bonding step, the step of processing is carried out under the conditions of 4 (rc~80 oc, 03 Mpa Μ a, and 5 minutes to 6 G minutes).
TW100145743A 2010-12-10 2011-12-12 Optical adhesive resin composition, optical adhesive sheet using the composition and image display device TWI534233B (en)

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